NC0000396_App B Lab Reports - CAMA BKGD - J16070200report_20160831

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16070200
Project Name:ASHEVILLE - AB GW ASSESSMENT WATER
Lab Contact:Anne Pridgeon
Date:7/28/2016
Customer Address:200 CP and L Drive
Customer Name(s):Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
Arden,NC 28704
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Method 218.7: The matrix spike sample associated with MW-22D was outside method limits. Batch quality as evaluated by
MB/LCS were acceptable. Please note that volume was supplied to the lab for hexavalent chromium analysis on the equipment
blank, however it was determined after sample preparation that it was not required.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Duke Energy Analytical Lab
Page 1 of 79
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016020916 ASHEVILLE 07-Jul-16 9:45 AM BD MW-21D
2016020917 ASHEVILLE 07-Jul-16 11:57 AM BD MW-22BR
2016020918 ASHEVILLE 07-Jul-16 10:45 AM BD MW-22D
2016020919 ASHEVILLE 07-Jul-16 2:30 PM BD MW-18BR
2016020920 ASHEVILLE 07-Jul-16 3:35 PM BD MW-18D
2016020921 ASHEVILLE 07-Jul-16 3:40 PM BD Filter Blank
2016020922 ASHEVILLE 07-Jul-16 3:40 PM BD Equipment Blank
7 Total Samples
Duke Energy Analytical Lab
Page 2 of 79
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Anne Pridgeon Date:7/28/2016
Electronic Data Deliverable (EDD) Sent Separatel
Duke Energy Analytical Lab
Page 3 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
2016020916
Collection Date:07-Jul-16 9:45 AM
Site:MW-21D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.018 mg-N/L EPA 353.2 07/11/2016 11:38 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 28 mg/L EPA 300.0 07/15/2016 18:20 BGN90340.5 5
Sulfate 31 mg/L EPA 300.0 07/15/2016 18:20 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/25/2016 13:34 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/25/2016 12:48 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.025 mg/L EPA 200.7 07/11/2016 14:48 JJMACKE0.005 1
Barium (Ba)0.045 mg/L EPA 200.7 07/11/2016 14:48 JJMACKE0.005 1
Boron (B)0.090 mg/L EPA 200.7 07/11/2016 14:48 JJMACKE0.05 1
Iron (Fe)3.79 mg/L EPA 200.7 07/11/2016 14:48 JJMACKE0.01 1
Manganese (Mn)0.625 mg/L EPA 200.7 07/11/2016 14:48 JJMACKE0.005 1
Strontium (Sr)0.077 mg/L EPA 200.7 07/11/2016 14:48 JJMACKE0.005 1
Zinc (Zn)0.014 mg/L EPA 200.7 07/11/2016 14:48 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)9.44 mg/L EPA 200.7 07/13/2016 12:27 JJMACKE0.01 1
Magnesium (Mg)3.76 mg/L EPA 200.7 07/13/2016 12:27 JJMACKE0.005 1
Potassium (K)1.55 mg/L EPA 200.7 07/13/2016 12:27 JJMACKE0.1 1
Sodium (Na)15.4 mg/L EPA 200.7 07/13/2016 12:27 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.037 mg/L EPA 200.7 07/12/2016 10:22 JJMACKE0.005 1
Barium (Ba)0.044 mg/L EPA 200.7 07/12/2016 10:22 JJMACKE0.005 1
Boron (B)0.087 mg/L EPA 200.7 07/12/2016 10:22 JJMACKE0.05 1
Iron (Fe)4.03 mg/L EPA 200.7 07/12/2016 10:22 JJMACKE0.01 1
Manganese (Mn)0.586 mg/L EPA 200.7 07/12/2016 10:22 JJMACKE0.005 1
Strontium (Sr)0.073 mg/L EPA 200.7 07/12/2016 10:22 JJMACKE0.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 07/12/2016 10:22 JJMACKE0.005 1
Duke Energy Analytical Lab
Page 4 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
2016020916
Collection Date:07-Jul-16 9:45 AM
Site:MW-21D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/14/2016 22:03 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/14/2016 22:03 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/14/2016 22:03 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/14/2016 22:03 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/14/2016 22:03 CWSPEN311
Cobalt (Co)1.19 ug/L EPA 200.8 07/14/2016 22:03 CWSPEN311
Copper (Cu)3.67 ug/L EPA 200.8 07/14/2016 22:03 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/14/2016 22:03 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/14/2016 22:03 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 07/14/2016 22:03 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/14/2016 22:03 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/14/2016 22:03 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/14/2016 22:03 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/11/2016 21:17 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/11/2016 21:17 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/11/2016 21:17 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/11/2016 21:17 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/11/2016 21:17 CWSPEN311
Cobalt (Co)1.13 ug/L EPA 200.8 07/11/2016 21:17 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 07/11/2016 21:17 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/11/2016 21:17 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/11/2016 21:17 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 07/11/2016 21:17 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/11/2016 21:17 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/11/2016 21:17 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/11/2016 21:17 CWSPEN30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 100 mg/L SM2540C 07/13/2016 14:37 PARMSTR251
Duke Energy Analytical Lab
Page 5 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
2016020916
Collection Date:07-Jul-16 9:45 AM
Site:MW-21D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.363 mg/L SM5310C/EPA9060A 07/15/2016 14:48 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/13/2016 09:30 PARMSTR51
Duke Energy Analytical Lab
Page 6 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
2016020917
Collection Date:07-Jul-16 11:57 AM
Site:MW-22BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.019 mg-N/L EPA 353.2 07/11/2016 11:46 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 48 mg/L EPA 300.0 07/15/2016 17:17 BGN9034110
Sulfate 19 mg/L EPA 300.0 07/15/2016 17:17 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/25/2016 13:37 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/25/2016 13:29 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.019 mg/L EPA 200.7 07/11/2016 14:52 JJMACKE0.005 1
Barium (Ba)0.018 mg/L EPA 200.7 07/11/2016 14:52 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/11/2016 14:52 JJMACKE0.05 1
Iron (Fe)14.3 mg/L EPA 200.7 07/11/2016 14:52 JJMACKE0.01 1
Manganese (Mn)0.319 mg/L EPA 200.7 07/11/2016 14:52 JJMACKE0.005 1
Strontium (Sr)0.098 mg/L EPA 200.7 07/11/2016 14:52 JJMACKE0.005 1
Zinc (Zn)0.031 mg/L EPA 200.7 07/11/2016 14:52 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)10.9 mg/L EPA 200.7 07/13/2016 12:31 JJMACKE0.01 1
Magnesium (Mg)4.23 mg/L EPA 200.7 07/13/2016 12:31 JJMACKE0.005 1
Potassium (K)3.06 mg/L EPA 200.7 07/13/2016 12:31 JJMACKE0.1 1
Sodium (Na)15.3 mg/L EPA 200.7 07/13/2016 12:31 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.030 mg/L EPA 200.7 07/12/2016 10:33 JJMACKE0.005 1
Barium (Ba)0.020 mg/L EPA 200.7 07/12/2016 10:33 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/12/2016 10:33 JJMACKE0.05 1
Iron (Fe)14.5 mg/L EPA 200.7 07/12/2016 10:33 JJMACKE0.01 1
Manganese (Mn)0.316 mg/L EPA 200.7 07/12/2016 10:33 JJMACKE0.005 1
Strontium (Sr)0.098 mg/L EPA 200.7 07/12/2016 10:33 JJMACKE0.005 1
Zinc (Zn)0.029 mg/L EPA 200.7 07/12/2016 10:33 JJMACKE0.005 1
Duke Energy Analytical Lab
Page 7 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
2016020917
Collection Date:07-Jul-16 11:57 AM
Site:MW-22BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/14/2016 22:29 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/14/2016 22:29 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/14/2016 22:29 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/14/2016 22:29 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/14/2016 22:29 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 07/14/2016 22:29 CWSPEN311
Copper (Cu)3.04 ug/L EPA 200.8 07/14/2016 22:29 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/14/2016 22:29 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/14/2016 22:29 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 07/14/2016 22:29 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/14/2016 22:29 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/14/2016 22:29 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/14/2016 22:29 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/11/2016 20:31 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/11/2016 20:31 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/11/2016 20:31 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/11/2016 20:31 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/11/2016 20:31 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 07/11/2016 20:31 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 07/11/2016 20:31 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/11/2016 20:31 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/11/2016 20:31 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 07/11/2016 20:31 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/11/2016 20:31 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/11/2016 20:31 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/11/2016 20:31 CWSPEN30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 150 mg/L SM2540C 07/13/2016 14:37 PARMSTR251
Duke Energy Analytical Lab
Page 8 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
2016020917
Collection Date:07-Jul-16 11:57 AM
Site:MW-22BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.425 mg/L SM5310C/EPA9060A 07/15/2016 14:48 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/13/2016 09:30 PARMSTR51
Duke Energy Analytical Lab
Page 9 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
2016020918
Collection Date:07-Jul-16 10:45 AM
Site:MW-22D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.258 mg-N/L EPA 353.2 07/11/2016 11:47 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 30 mg/L EPA 300.0 07/15/2016 18:36 BGN90340.5 5
Sulfate 11 mg/L EPA 300.0 07/15/2016 18:36 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/25/2016 13:39 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/25/2016 13:22 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.027 mg/L EPA 200.7 07/11/2016 14:56 JJMACKE0.005 1
Barium (Ba)0.028 mg/L EPA 200.7 07/11/2016 14:56 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/11/2016 14:56 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/11/2016 14:56 JJMACKE0.01 1
Manganese (Mn)0.092 mg/L EPA 200.7 07/11/2016 14:56 JJMACKE0.005 1
Strontium (Sr)0.047 mg/L EPA 200.7 07/11/2016 14:56 JJMACKE0.005 1
Zinc (Zn)0.010 mg/L EPA 200.7 07/11/2016 14:56 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)5.40 mg/L EPA 200.7 07/13/2016 12:48 JJMACKE0.01 1
Magnesium (Mg)3.92 mg/L EPA 200.7 07/13/2016 12:48 JJMACKE0.005 1
Potassium (K)1.27 mg/L EPA 200.7 07/13/2016 12:48 JJMACKE0.1 1
Sodium (Na)11.9 mg/L EPA 200.7 07/13/2016 12:48 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.068 mg/L EPA 200.7 07/12/2016 10:37 JJMACKE0.005 1
Barium (Ba)0.029 mg/L EPA 200.7 07/12/2016 10:37 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/12/2016 10:37 JJMACKE0.05 1
Iron (Fe)0.048 mg/L EPA 200.7 07/12/2016 10:37 JJMACKE0.01 1
Manganese (Mn)0.092 mg/L EPA 200.7 07/12/2016 10:37 JJMACKE0.005 1
Strontium (Sr)0.048 mg/L EPA 200.7 07/12/2016 10:37 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/12/2016 10:37 JJMACKE0.005 1
Duke Energy Analytical Lab
Page 10 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
2016020918
Collection Date:07-Jul-16 10:45 AM
Site:MW-22D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/15/2016 12:41 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/15/2016 12:41 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/15/2016 12:41 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/15/2016 12:41 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/15/2016 12:41 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 07/15/2016 12:41 CWSPEN311
Copper (Cu)6.65 ug/L EPA 200.8 07/15/2016 12:41 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/15/2016 12:41 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/15/2016 12:41 CWSPEN311
Nickel (Ni)5.01 ug/L EPA 200.8 07/15/2016 12:41 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/15/2016 12:41 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/15/2016 12:41 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/15/2016 12:41 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/11/2016 21:23 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/11/2016 21:23 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/11/2016 21:23 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/11/2016 21:23 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/11/2016 21:23 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 07/11/2016 21:23 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 07/11/2016 21:23 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/11/2016 21:23 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/11/2016 21:23 CWSPEN311
Nickel (Ni)4.90 ug/L EPA 200.8 07/11/2016 21:23 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/11/2016 21:23 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/11/2016 21:23 CWSPEN30.2 1
Vanadium (V) Low Level 0.342 ug/L EPA 200.8 07/11/2016 21:23 CWSPEN30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 90 mg/L SM2540C 07/13/2016 14:37 PARMSTR251
Duke Energy Analytical Lab
Page 11 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
2016020918
Collection Date:07-Jul-16 10:45 AM
Site:MW-22D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.331 mg/L SM5310C/EPA9060A 07/15/2016 14:48 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/13/2016 09:30 PARMSTR51
Duke Energy Analytical Lab
Page 12 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
2016020919
Collection Date:07-Jul-16 2:30 PM
Site:MW-18BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.069 mg-N/L EPA 353.2 07/11/2016 11:48 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 98 mg/L EPA 300.0 07/15/2016 19:24 BGN9034220
Sulfate 300 mg/L EPA 300.0 07/15/2016 19:24 BGN9034550
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/25/2016 13:42 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/25/2016 14:11 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.006 mg/L EPA 200.7 07/11/2016 14:59 JJMACKE0.005 1
Barium (Ba)0.040 mg/L EPA 200.7 07/11/2016 14:59 JJMACKE0.005 1
Boron (B)0.920 mg/L EPA 200.7 07/11/2016 14:59 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/11/2016 14:59 JJMACKE0.01 1
Manganese (Mn)0.315 mg/L EPA 200.7 07/11/2016 14:59 JJMACKE0.005 1
Strontium (Sr)0.412 mg/L EPA 200.7 07/11/2016 14:59 JJMACKE0.005 1
Zinc (Zn)0.015 mg/L EPA 200.7 07/11/2016 14:59 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)129 mg/L EPA 200.7 07/13/2016 13:09 JJMACKE0.1 10
Magnesium (Mg)28.5 mg/L EPA 200.7 07/13/2016 13:09 JJMACKE0.05 10
Potassium (K)9.07 mg/L EPA 200.7 07/13/2016 13:09 JJMACKE0.1 1
Sodium (Na)14.3 mg/L EPA 200.7 07/13/2016 13:09 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.011 mg/L EPA 200.7 07/12/2016 10:41 JJMACKE0.005 1
Barium (Ba)0.041 mg/L EPA 200.7 07/12/2016 10:41 JJMACKE0.005 1
Boron (B)0.927 mg/L EPA 200.7 07/12/2016 10:41 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/12/2016 10:41 JJMACKE0.01 1
Manganese (Mn)0.326 mg/L EPA 200.7 07/12/2016 10:41 JJMACKE0.005 1
Strontium (Sr)0.419 mg/L EPA 200.7 07/12/2016 10:41 JJMACKE0.005 1
Zinc (Zn)0.008 mg/L EPA 200.7 07/12/2016 10:41 JJMACKE0.005 1
Duke Energy Analytical Lab
Page 13 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
2016020919
Collection Date:07-Jul-16 2:30 PM
Site:MW-18BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/15/2016 12:48 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/15/2016 12:48 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/15/2016 12:48 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/15/2016 12:48 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/15/2016 12:48 CWSPEN311
Cobalt (Co)2.21 ug/L EPA 200.8 07/15/2016 12:48 CWSPEN311
Copper (Cu)6.52 ug/L EPA 200.8 07/15/2016 12:48 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/15/2016 12:48 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/15/2016 12:48 CWSPEN311
Nickel (Ni)5.09 ug/L EPA 200.8 07/15/2016 12:48 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/15/2016 12:48 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/15/2016 12:48 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/15/2016 12:48 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/11/2016 21:30 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/11/2016 21:30 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/11/2016 21:30 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/11/2016 21:30 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/11/2016 21:30 CWSPEN311
Cobalt (Co)2.10 ug/L EPA 200.8 07/11/2016 21:30 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 07/11/2016 21:30 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/11/2016 21:30 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/11/2016 21:30 CWSPEN311
Nickel (Ni)5.27 ug/L EPA 200.8 07/11/2016 21:30 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/11/2016 21:30 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/11/2016 21:30 CWSPEN30.2 1
Vanadium (V) Low Level 0.340 ug/L EPA 200.8 07/11/2016 21:30 CWSPEN30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 650 mg/L SM2540C 07/13/2016 14:37 PARMSTR251
Duke Energy Analytical Lab
Page 14 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
2016020919
Collection Date:07-Jul-16 2:30 PM
Site:MW-18BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.335 mg/L SM5310C/EPA9060A 07/15/2016 14:48 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/13/2016 09:30 PARMSTR51
Duke Energy Analytical Lab
Page 15 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
2016020920
Collection Date:07-Jul-16 3:35 PM
Site:MW-18D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.082 mg-N/L EPA 353.2 07/11/2016 11:49 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 99 mg/L EPA 300.0 07/15/2016 19:40 BGN9034220
Sulfate 300 mg/L EPA 300.0 07/15/2016 19:40 BGN9034550
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/25/2016 13:44 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/25/2016 14:01 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.011 mg/L EPA 200.7 07/11/2016 15:03 JJMACKE0.005 1
Barium (Ba)0.037 mg/L EPA 200.7 07/11/2016 15:03 JJMACKE0.005 1
Boron (B)0.878 mg/L EPA 200.7 07/11/2016 15:03 JJMACKE0.05 1
Iron (Fe)3.63 mg/L EPA 200.7 07/11/2016 15:03 JJMACKE0.01 1
Manganese (Mn)1.29 mg/L EPA 200.7 07/11/2016 15:03 JJMACKE0.005 1
Strontium (Sr)0.283 mg/L EPA 200.7 07/11/2016 15:03 JJMACKE0.005 1
Zinc (Zn)0.016 mg/L EPA 200.7 07/11/2016 15:03 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)121 mg/L EPA 200.7 07/13/2016 13:13 JJMACKE0.1 10
Magnesium (Mg)30.1 mg/L EPA 200.7 07/13/2016 13:13 JJMACKE0.05 10
Potassium (K)7.85 mg/L EPA 200.7 07/13/2016 13:13 JJMACKE0.1 1
Sodium (Na)13.6 mg/L EPA 200.7 07/13/2016 13:13 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.016 mg/L EPA 200.7 07/12/2016 10:45 JJMACKE0.005 1
Barium (Ba)0.038 mg/L EPA 200.7 07/12/2016 10:45 JJMACKE0.005 1
Boron (B)0.875 mg/L EPA 200.7 07/12/2016 10:45 JJMACKE0.05 1
Iron (Fe)3.96 mg/L EPA 200.7 07/12/2016 10:45 JJMACKE0.01 1
Manganese (Mn)1.29 mg/L EPA 200.7 07/12/2016 10:45 JJMACKE0.005 1
Strontium (Sr)0.284 mg/L EPA 200.7 07/12/2016 10:45 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/12/2016 10:45 JJMACKE0.005 1
Duke Energy Analytical Lab
Page 16 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
2016020920
Collection Date:07-Jul-16 3:35 PM
Site:MW-18D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/15/2016 13:13 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/15/2016 13:13 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/15/2016 13:13 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/15/2016 13:13 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/15/2016 13:13 CWSPEN311
Cobalt (Co)3.85 ug/L EPA 200.8 07/15/2016 13:13 CWSPEN311
Copper (Cu)6.28 ug/L EPA 200.8 07/15/2016 13:13 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/15/2016 13:13 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/15/2016 13:13 CWSPEN311
Nickel (Ni)2.20 ug/L EPA 200.8 07/15/2016 13:13 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/15/2016 13:13 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/15/2016 13:13 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/15/2016 13:13 CWSPEN30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/11/2016 21:36 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/11/2016 21:36 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/11/2016 21:36 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/11/2016 21:36 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/11/2016 21:36 CWSPEN311
Cobalt (Co)3.40 ug/L EPA 200.8 07/11/2016 21:36 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 07/11/2016 21:36 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/11/2016 21:36 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/11/2016 21:36 CWSPEN311
Nickel (Ni)2.24 ug/L EPA 200.8 07/11/2016 21:36 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/11/2016 21:36 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/11/2016 21:36 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/11/2016 21:36 CWSPEN30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 660 mg/L SM2540C 07/13/2016 14:37 PARMSTR251
Duke Energy Analytical Lab
Page 17 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
2016020920
Collection Date:07-Jul-16 3:35 PM
Site:MW-18D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Total Carbon
TOC 0.436 mg/L SM5310C/EPA9060A 07/15/2016 14:48 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/13/2016 09:30 PARMSTR51
Duke Energy Analytical Lab
Page 18 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
2016020921
Collection Date:07-Jul-16 3:40 PM
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/25/2016 13:49 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 07/11/2016 15:07 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 07/11/2016 15:07 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/11/2016 15:07 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/11/2016 15:07 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 07/11/2016 15:07 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 07/11/2016 15:07 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/11/2016 15:07 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/15/2016 13:20 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/15/2016 13:20 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/15/2016 13:20 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/15/2016 13:20 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/15/2016 13:20 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 07/15/2016 13:20 CWSPEN311
Copper (Cu)4.41 ug/L EPA 200.8 07/15/2016 13:20 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/15/2016 13:20 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/15/2016 13:20 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 07/15/2016 13:20 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/15/2016 13:20 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/15/2016 13:20 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/15/2016 13:20 CWSPEN30.3 1
Duke Energy Analytical Lab
Page 19 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
2016020922
Collection Date:07-Jul-16 3:40 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 07/11/2016 11:50 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 07/15/2016 18:05 BGN90340.1 1
Sulfate 0.13 mg/L EPA 300.0 07/15/2016 18:05 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/25/2016 13:46 DMFRANC0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)< 0.01 mg/L EPA 200.7 07/13/2016 13:25 JJMACKE0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 07/13/2016 13:25 JJMACKE0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 07/13/2016 13:25 JJMACKE0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 07/13/2016 13:25 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 07/12/2016 10:48 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 07/12/2016 10:48 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/12/2016 10:48 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/12/2016 10:48 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 07/12/2016 10:48 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 07/12/2016 10:48 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 07/12/2016 10:48 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/11/2016 21:43 CWSPEN311
Arsenic (As)< 1 ug/L EPA 200.8 07/11/2016 21:43 CWSPEN311
Beryllium (Be)< 1 ug/L EPA 200.8 07/11/2016 21:43 CWSPEN311
Cadmium (Cd)< 1 ug/L EPA 200.8 07/11/2016 21:43 CWSPEN311
Chromium (Cr)< 1 ug/L EPA 200.8 07/11/2016 21:43 CWSPEN311
Cobalt (Co)< 1 ug/L EPA 200.8 07/11/2016 21:43 CWSPEN311
Copper (Cu)< 1 ug/L EPA 200.8 07/11/2016 21:43 CWSPEN311
Lead (Pb)< 1 ug/L EPA 200.8 07/11/2016 21:43 CWSPEN311
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/11/2016 21:43 CWSPEN311
Nickel (Ni)< 1 ug/L EPA 200.8 07/11/2016 21:43 CWSPEN311
Selenium (Se)< 1 ug/L EPA 200.8 07/11/2016 21:43 CWSPEN311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/11/2016 21:43 CWSPEN30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/11/2016 21:43 CWSPEN30.3 1
Duke Energy Analytical Lab
Page 20 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
2016020922
Collection Date:07-Jul-16 3:40 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 07/13/2016 14:37 PARMSTR251
Total Carbon
TOC 0.355 mg/L SM5310C/EPA9060A 07/15/2016 14:48 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 07/13/2016 09:30 PARMSTR51
Duke Energy Analytical Lab
Page 21 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
Q16070193 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.001 mg-N/L -10.001 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0033 mg-N/L -10.0033 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 3
RDL Relative Concentration
Nitrite + Nitrate
(Colorimetric)
0.0018 mg-N/L -10.0018 0.01 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.295 3.01 98.2mg-N/L -11090102.96
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.297 3.01 98.8mg-N/L -11090102.97
Final QualifierDilMeasuredUnits:Parameter
LCS # 3
% Recovery LCL UCLSpike
Nitrite + Nitrate
(Colorimetric)
0.29 3.01 96.3mg-N/L -11090102.9
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16060269 -- 2016016737
Nitrite + Nitrate
(Colorimetric)
0.237 0.25 92.6mg-N/L -1109010.237
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16060269 -- 2016016737
Nitrite + Nitrate
(Colorimetric)
0.238 0.25 92.9 0.345mg-N/L -1109010.238
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021092
Nitrite + Nitrate
(Colorimetric)
0.0712 0.25 25.3mg-N/L -1109010.0712
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021092
Nitrite + Nitrate
(Colorimetric)
0.0712 0.25 25.3 0mg-N/L -1109010.0712
Duke Energy Analytical Lab
Page 22 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
Q16070193 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021093
Nitrite + Nitrate
(Colorimetric)
0.461 0.25 102mg-N/L -1109010.461
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021093
Nitrite + Nitrate
(Colorimetric)
0.458 0.25 101 1.11mg-N/L -1109010.458
Final QualifierDilMeasuredUnits:Parameter
MS # 4
% Recovery LCL UCLSpike
Parent Sample: J16070215 -- 2016021005
Nitrite + Nitrate
(Colorimetric)
0.237 0.25 92mg-N/L -1109010.237
Final QualifierDilMeasuredUnits:Parameter
MSD # 4
RPD% Recovery LCL UCLSpike
Parent Sample: J16070215 -- 2016021005
Nitrite + Nitrate
(Colorimetric)
0.233 0.25 90.5 1.67mg-N/L -1109010.233
Duke Energy Analytical Lab
Page 23 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
Q16070352 Dionex INORGANIC IONS BY IC
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Chloride 0.0034 mg/L -10.0034 0.1 < 1/2 RDL
Sulfate -0.0366 mg/L -1-0.0366 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Chloride 9.56 5 95.8mg/L -1208019.56
Sulfate 6.7 5 95.8mg/L -1208016.7
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Chloride 9.55 5 95.7 0.153mg/L -1208019.55
Sulfate 6.7 5 95.8 0.00835mg/L -1208016.7
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Chloride 5.24 5 105mg/L -1109015.24
Sulfate 5.22 5 104mg/L -1109015.22
Duke Energy Analytical Lab
Page 24 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
Q16070616 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.003 ug/L -10.003 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.01 ug/L -10.01 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.01 1 100ug/L -1307011.01
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.991 1 98.2 1.92ug/L -1307010.991
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 0.994 1 97.3ug/L -1307010.994
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Mercury (Hg) 1 1 97.9 0.615ug/L -1307011
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.91 2 95.5ug/L -1158511.91
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.88 2 93.9ug/L -1158511.88
Duke Energy Analytical Lab
Page 25 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
Q16070618 HG 245.1 Dissolved Mercury Dissolved (cold vapor) in Water (Filtered)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.003 ug/L -10.003 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Mercury (Hg) 0.01 ug/L -10.01 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.91 2 95.5ug/L -1158511.91
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 1.88 2 93.9ug/L -1158511.88
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020916
Mercury (Hg) 0.983 1 97.2ug/L -1307010.983
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020916
Mercury (Hg) 1.01 1 99.5 2.34ug/L -1307011.01
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020918
Mercury (Hg) 1.01 1 100ug/L -1307011.01
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020918
Mercury (Hg) 0.991 1 98.2 1.92ug/L -1307010.991
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020920
Mercury (Hg) 0.994 1 97.3ug/L -1307010.994
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020920
Mercury (Hg) 1 1 97.9 0.615ug/L -1307011
Duke Energy Analytical Lab
Page 26 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
Q16070211 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) -0.000647 mg/L -1-0.000647 0.005 < 1/2 RDL
Barium (Ba) -0.000142 mg/L -1-0.000142 0.005 < 1/2 RDL
Boron (B) -0.00238 mg/L -1-0.00238 0.05 < 1/2 RDL
Iron (Fe) -0.00117 mg/L -1-0.00117 0.01 < 1/2 RDL
Manganese (Mn) -0.000442 mg/L -1-0.000442 0.005 < 1/2 RDL
Strontium (Sr) 0.00006 mg/L -10.00006 0.005 < 1/2 RDL
Zinc (Zn) -0.000932 mg/L -1-0.000932 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 2.06 2 103mg/L -1158512.06
Barium (Ba) 1 1 100mg/L -1158511
Boron (B) 2.02 2 101mg/L -1158512.02
Iron (Fe) 2.05 2 103mg/L -1158512.05
Manganese (Mn) 0.99 1 99mg/L -1158510.99
Strontium (Sr) 1.93 2 96.3mg/L -1158511.93
Zinc (Zn) 1.04 1 104mg/L -1158511.04
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021083
Aluminum (Al) 5.53 5 110mg/L -1307015.53
Barium (Ba) 5.34 5 107mg/L -1307015.34
Boron (B) 5.2 5 104mg/L -1307015.2
Iron (Fe) 5.23 5 103mg/L -1307015.23
Manganese (Mn) 5.5 5 109mg/L -1307015.5
Strontium (Sr) 5.11 5 102mg/L -1307015.11
Zinc (Zn) 5.34 5 107mg/L -1307015.34
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021083
Aluminum (Al) 5.52 5 110 0.145mg/L -1307015.52
Barium (Ba) 5.31 5 106 0.677mg/L -1307015.31
Boron (B) 5.2 5 104 0mg/L -1307015.2
Iron (Fe) 5.23 5 103 0mg/L -1307015.23
Manganese (Mn) 5.49 5 109 0.184mg/L -1307015.49
Strontium (Sr) 5.12 5 102 0.137mg/L -1307015.12
Zinc (Zn) 5.35 5 107 0.0751mg/L -1307015.35
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021092
Aluminum (Al) 5.49 5 108mg/L -1307015.49
Duke Energy Analytical Lab
Page 27 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
Q16070211 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021092
Barium (Ba) 5.58 5 106mg/L -1307015.58
Boron (B) 5.31 5 103mg/L -1307015.31
Iron (Fe) 5.73 5 79.6mg/L -130701057.3
Manganese (Mn) 6.14 5 108mg/L -1307016.14
Strontium (Sr) 5.37 5 102mg/L -1307015.37
Zinc (Zn) 5.26 5 105mg/L -1307015.26
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021092
Aluminum (Al) 5.48 5 108 0.203mg/L -1307015.48
Barium (Ba) 5.61 5 107 0.678mg/L -1307015.61
Boron (B) 5.32 5 104 0.174mg/L -1307015.32
Iron (Fe) 5.76 5 85.5 7.17mg/L -130701057.6
Manganese (Mn) 6.11 5 108 0.445mg/L -1307016.11
Strontium (Sr) 5.39 5 102 0.372mg/L -1307015.39
Zinc (Zn) 5.24 5 105 0.286mg/L -1307015.24
Duke Energy Analytical Lab
Page 28 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
Q16070266 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Calcium (Ca) 0.000804 mg/L -10.000804 0.01 < 1/2 RDL
Magnesium (Mg) -0.000016 mg/L -1-0.000016 0.005 < 1/2 RDL
Potassium (K) 0.0121 mg/L -10.0121 0.1 < 1/2 RDL
Sodium (Na) -0.0204 mg/L -1-0.0204 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Calcium (Ca) 0.0025 mg/L -10.0025 0.01 < 1/2 RDL
Magnesium (Mg) 0.000113 mg/L -10.000113 0.005 < 1/2 RDL
Potassium (K) 0.00296 mg/L -10.00296 0.1 < 1/2 RDL
Sodium (Na) -0.0187 mg/L -1-0.0187 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Calcium (Ca) 2.04 2 102mg/L -1158512.04
Magnesium (Mg) 1.99 2 99.3mg/L -1158511.99
Potassium (K) 3.98 4 99.5mg/L -1158513.98
Sodium (Na) 8.29 8.1 102mg/L -1158518.29
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Calcium (Ca) 2.07 2 103mg/L -1158512.07
Magnesium (Mg) 2.01 2 101mg/L -1158512.01
Potassium (K) 4.01 4 100mg/L -1158514.01
Sodium (Na) 8.36 8.1 103mg/L -1158518.36
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070215 -- 2016021004
Calcium (Ca) 179 5 0mg/L -130701179
Magnesium (Mg) 6.53 5 100mg/L -1307016.53
Potassium (K) 148 5 272mg/L -130701148
Sodium (Na) 460 5 0mg/L -130701460
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070215 -- 2016021004
Calcium (Ca) 178 5 0 0mg/L -130701178
Magnesium (Mg) 6.49 5 99.2 0.763mg/L -1307016.49
Potassium (K) 146 5 246 10mg/L -130701146
Sodium (Na) 457 5 0 0mg/L -130701457
Duke Energy Analytical Lab
Page 29 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
Q16070266 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021089
Calcium (Ca) 12 5 102mg/L -13070112
Magnesium (Mg) 11.5 5 96mg/L -13070111.5
Potassium (K) 6.76 5 103mg/L -1307016.76
Sodium (Na) 14 5 82.3mg/L -13070114
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021089
Calcium (Ca) 12 5 101 0.0197mg/L -13070112
Magnesium (Mg) 11.5 5 96 0.0208mg/L -13070111.5
Potassium (K) 6.78 5 103 0.331mg/L -1307016.78
Sodium (Na) 14 5 82 0.438mg/L -13070114
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020918
Calcium (Ca) 10.6 5 104mg/L -13070110.6
Magnesium (Mg) 9.21 5 106mg/L -1307019.21
Potassium (K) 6.52 5 105mg/L -1307016.52
Sodium (Na) 16.4 5 88.3mg/L -13070116.4
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020918
Calcium (Ca) 10.6 5 104 0.154mg/L -13070110.6
Magnesium (Mg) 9.17 5 105 0.797mg/L -1307019.17
Potassium (K) 6.5 5 105 0.325mg/L -1307016.5
Sodium (Na) 16.2 5 86.3 2.36mg/L -13070116.2
Duke Energy Analytical Lab
Page 30 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
Q16070184 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.000268 mg/L -10.000268 0.005 < 1/2 RDL
Barium (Ba) 0.000015 mg/L -10.000015 0.005 < 1/2 RDL
Boron (B) 0.00104 mg/L -10.00104 0.05 < 1/2 RDL
Iron (Fe) -0.000114 mg/L -1-0.000114 0.01 < 1/2 RDL
Manganese (Mn) 0.000029 mg/L -10.000029 0.005 < 1/2 RDL
Strontium (Sr) 0.000153 mg/L -10.000153 0.005 < 1/2 RDL
Zinc (Zn) 0.000267 mg/L -10.000267 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 5.24 5 105mg/L -1158515.24
Barium (Ba) 5.08 5 102mg/L -1158515.08
Boron (B) 5.1 5 102mg/L -1158515.1
Iron (Fe) 4.97 5 99.5mg/L -1158514.97
Manganese (Mn) 5.18 5 104mg/L -1158515.18
Strontium (Sr) 5.03 5 101mg/L -1158515.03
Zinc (Zn) 5.01 5 100mg/L -1158515.01
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020916
Aluminum (Al) 5.34 5 106mg/L -1307015.34
Barium (Ba) 5.15 5 102mg/L -1307015.15
Boron (B) 5.24 5 103mg/L -1307015.24
Iron (Fe) 9.17 5 103mg/L -1307019.17
Manganese (Mn) 5.82 5 105mg/L -1307015.82
Strontium (Sr) 5.13 5 101mg/L -1307015.13
Zinc (Zn) 5.07 5 101mg/L -1307015.07
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020916
Aluminum (Al) 5.29 5 105 0.91mg/L -1307015.29
Barium (Ba) 5.15 5 102 0.0587mg/L -1307015.15
Boron (B) 5.21 5 103 0.545mg/L -1307015.21
Iron (Fe) 9.08 5 101 1.86mg/L -1307019.08
Manganese (Mn) 5.77 5 104 0.883mg/L -1307015.77
Strontium (Sr) 5.12 5 101 0.0989mg/L -1307015.12
Zinc (Zn) 5.01 5 100 1.05mg/L -1307015.01
Duke Energy Analytical Lab
Page 31 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
Q16070310 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.0542 ug/L -1-0.0542 1 < 1/2 RDL
Arsenic (As) 0.0161 ug/L -10.0161 1 < 1/2 RDL
Beryllium (Be) 0.0021 ug/L -10.0021 1 < 1/2 RDL
Cadmium (Cd) 0.0011 ug/L -10.0011 1 < 1/2 RDL
Chromium (Cr) -0.017 ug/L -1-0.017 1 < 1/2 RDL
Cobalt (Co) 0.0031 ug/L -10.0031 1 < 1/2 RDL
Copper (Cu) -0.0854 ug/L -1-0.0854 1 < 1/2 RDL
Lead (Pb) 0.0054 ug/L -10.0054 1 < 1/2 RDL
Molybdenum (Mo) 0.0016 ug/L -10.0016 1 < 1/2 RDL
Nickel (Ni) -0.0156 ug/L -1-0.0156 1 < 1/2 RDL
Selenium (Se) -0.0743 ug/L -1-0.0743 1 < 1/2 RDL
Thallium (Tl) Low Level -0.0362 ug/L -1-0.0362 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.0274 ug/L -10.0274 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 49.7 50 99.5ug/L -11585149.7
Arsenic (As) 48.6 50 97.3ug/L -11585148.6
Beryllium (Be) 49.2 50 98.5ug/L -11585149.2
Cadmium (Cd) 48.9 50 97.8ug/L -11585148.9
Chromium (Cr) 49.1 50 98.2ug/L -11585149.1
Cobalt (Co) 47.9 50 95.8ug/L -11585147.9
Copper (Cu) 47.7 50 95.4ug/L -11585147.7
Lead (Pb) 49.3 50 98.5ug/L -11585149.3
Molybdenum (Mo) 48.6 50 97.3ug/L -11585148.6
Nickel (Ni) 48.3 50 96.7ug/L -11585148.3
Selenium (Se) 47.2 50 94.5ug/L -11585147.2
Thallium (Tl) Low Level 46.9 50 93.7ug/L -11585146.9
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020916
Antimony (Sb) 53.6 50 107ug/L -13070153.6
Arsenic (As) 51.7 50 103ug/L -13070151.7
Beryllium (Be) 58 50 116ug/L -13070158
Cadmium (Cd) 52 50 104ug/L -13070152
Chromium (Cr) 53.3 50 106ug/L -13070153.3
Cobalt (Co) 52.1 50 102ug/L -13070152.1
Copper (Cu) 55.1 50 103ug/L -13070155.1
Lead (Pb) 53.2 50 105ug/L -13070153.2
Molybdenum (Mo) 52.4 50 105ug/L -13070152.4
Duke Energy Analytical Lab
Page 32 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
Q16070310 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020916
Nickel (Ni) 52.4 50 104ug/L -13070152.4
Selenium (Se) 47.5 50 95ug/L -13070147.5
Thallium (Tl) Low Level 47.4 50 94.7ug/L -13070147.4
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020916
Antimony (Sb) 50.2 50 100 6.49ug/L -13070150.2
Arsenic (As) 48.4 50 96.6 6.63ug/L -13070148.4
Beryllium (Be) 51.3 50 102 12.3ug/L -13070151.3
Cadmium (Cd) 48.9 50 97.8 6.19ug/L -13070148.9
Chromium (Cr) 49.8 50 99.4 6.83ug/L -13070149.8
Cobalt (Co) 48.7 50 95 6.9ug/L -13070148.7
Copper (Cu) 51.6 50 95.8 7.08ug/L -13070151.6
Lead (Pb) 50.2 50 98.7 5.95ug/L -13070150.2
Molybdenum (Mo) 49.1 50 98.2 6.39ug/L -13070149.1
Nickel (Ni) 48.4 50 95.8 8.06ug/L -13070148.4
Selenium (Se) 48 50 95.9 0.977ug/L -13070148
Thallium (Tl) Low Level 44.8 50 89.6 5.56ug/L -13070144.8
Duke Energy Analytical Lab
Page 33 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
Q16070187 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.0316 ug/L -1-0.0316 1 < 1/2 RDL
Arsenic (As) 0.0155 ug/L -10.0155 1 < 1/2 RDL
Beryllium (Be) -0.0381 ug/L -1-0.0381 1 < 1/2 RDL
Cadmium (Cd) -0.001 ug/L -1-0.001 1 < 1/2 RDL
Chromium (Cr) -0.0382 ug/L -1-0.0382 1 < 1/2 RDL
Cobalt (Co) -0.0018 ug/L -1-0.0018 1 < 1/2 RDL
Copper (Cu) -0.0724 ug/L -1-0.0724 1 < 1/2 RDL
Lead (Pb) 0.004 ug/L -10.004 1 < 1/2 RDL
Molybdenum (Mo) 0.008 ug/L -10.008 1 < 1/2 RDL
Nickel (Ni) -0.032 ug/L -1-0.032 1 < 1/2 RDL
Selenium (Se) -0.0569 ug/L -1-0.0569 1 < 1/2 RDL
Thallium (Tl) Low Level -0.0096 ug/L -1-0.0096 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.0599 ug/L -10.0599 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 50.7 50 101ug/L -11585150.7
Arsenic (As) 49.1 50 98.3ug/L -11585149.1
Beryllium (Be) 53.4 50 107ug/L -11585153.4
Cadmium (Cd) 49.4 50 98.8ug/L -11585149.4
Chromium (Cr) 49.8 50 99.6ug/L -11585149.8
Cobalt (Co) 48.2 50 96.3ug/L -11585148.2
Copper (Cu) 49.3 50 98.6ug/L -11585149.3
Lead (Pb) 49.4 50 98.7ug/L -11585149.4
Molybdenum (Mo) 50.1 50 100ug/L -11585150.1
Nickel (Ni) 49.1 50 98.1ug/L -11585149.1
Selenium (Se) 47.4 50 94.8ug/L -11585147.4
Thallium (Tl) Low Level 48.4 50 96.8ug/L -11585148.4
Vanadium (V) Low Level 49.8 50 99.5ug/L -11585149.8
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020917
Antimony (Sb) 50.4 50 100ug/L -13070150.4
Arsenic (As) 49.4 50 98.7ug/L -13070149.4
Beryllium (Be) 52.3 50 104ug/L -13070152.3
Cadmium (Cd) 48.5 50 97ug/L -13070148.5
Chromium (Cr) 49.4 50 98.7ug/L -13070149.4
Cobalt (Co) 47.4 50 94.7ug/L -13070147.4
Copper (Cu) 48.3 50 96.6ug/L -13070148.3
Lead (Pb) 49 50 98ug/L -13070149
Duke Energy Analytical Lab
Page 34 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
Q16070187 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020917
Molybdenum (Mo) 49.5 50 98.7ug/L -13070149.5
Nickel (Ni) 48.5 50 96.9ug/L -13070148.5
Selenium (Se) 47.4 50 94.9ug/L -13070147.4
Thallium (Tl) Low Level 48 50 95.8ug/L -13070148
Vanadium (V) Low Level 50.3 50 100ug/L -13070150.3
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020917
Antimony (Sb) 51.3 50 102 1.77ug/L -13070151.3
Arsenic (As) 49.8 50 99.5 0.806ug/L -13070149.8
Beryllium (Be) 53.3 50 106 1.82ug/L -13070153.3
Cadmium (Cd) 48.4 50 96.8 0.168ug/L -13070148.4
Chromium (Cr) 50.6 50 101 2.28ug/L -13070150.6
Cobalt (Co) 47.6 50 95.2 0.484ug/L -13070147.6
Copper (Cu) 48.7 50 97.4 0.821ug/L -13070148.7
Lead (Pb) 49 50 98 0.058ug/L -13070149
Molybdenum (Mo) 50 50 99.8 1.06ug/L -13070150
Nickel (Ni) 48.4 50 96.7 0.235ug/L -13070148.4
Selenium (Se) 48 50 96 1.18ug/L -13070148
Thallium (Tl) Low Level 48.3 50 96.4 0.588ug/L -13070148.3
Vanadium (V) Low Level 50.5 50 101 0.488ug/L -13070150.5
Duke Energy Analytical Lab
Page 35 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
Q16070252 TDS TOTAL DISSOLVED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TDS mg/L -1-1 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TDS mg/L -1-1 25 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16070200 -- 2016020918
TDS 6.9mg/L -184
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16070200 -- 2016020919
TDS 2.48mg/L -1637
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 3
RPD
Parent Sample: J16070200 -- 2016020920
TDS 1.07mg/L -1649
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TDS 100 103mg/L -110901103
Duke Energy Analytical Lab
Page 36 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
Q16070374 Total Carbon Total Carbon
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TOC mg/L -10.023 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
TOC mg/L -10.04 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
TOC 2 105mg/L -1208012.46
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
TOC 2 102 3.1mg/L -1208012.39
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
TOC 2 89.7mg/L -1208014.61
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
TOC 2 92.3 2.8mg/L -1208014.66
Final QualifierDilMeasuredUnits:Parameter
IS # 3
% Recovery LCL UCLSpike
TOC 2 95.8mg/L -1208013.89
Final QualifierDilMeasuredUnits:Parameter
ISD # 3
RPD% Recovery LCL UCLSpike
TOC 2 99.5 3.84mg/L -1208013.96
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TOC 2.87 101mg/L -1158512.91
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
TOC 2.87 104mg/L -1158512.98
Duke Energy Analytical Lab
Page 37 of 79
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070200
Q16070249 TSS TOTAL SUSPENDED SOLIDS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TSS mg/L -10 5 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 1
RPD
Parent Sample: J16060233 -- 2016016599
TSS 10.5mg/L -15.4
Final QualifierDilMeasuredUnits:Parameter
Duplicate # 2
RPD
Parent Sample: J16070200 -- 2016020916
TSS 0mg/L -11.2
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TSS 50 102mg/L -11090151.2
Duke Energy Analytical Lab
Page 38 of 79
#=CL#
July 15, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92304420
92304420
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16070200
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on July 08, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 24
Duke Energy Analytical Lab
Page 39 of 79
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92304420
J16070200
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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[phone]
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Duke Energy Analytical Lab
Page 40 of 79
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92304420
J16070200
Lab ID Sample ID Matrix Date Collected Date Received
92304420001 2016020916 Water 07/07/16 09:45 07/08/16 11:50
92304420002 2016020917 Water 07/07/16 11:57 07/08/16 11:50
92304420003 2016020918 Water 07/07/16 10:45 07/08/16 11:50
92304420004 2016020919 Water 07/07/16 14:30 07/08/16 11:50
92304420005 2016020920 Water 07/07/16 15:35 07/08/16 11:50
92304420006 2016020922 Water 07/07/16 15:40 07/08/16 11:50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Huntersville, NC 28078
[phone]
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Duke Energy Analytical Lab
Page 41 of 79
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92304420
J16070200
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92304420001 2016020916 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304420002 2016020917 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304420003 2016020918 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304420004 2016020919 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304420005 2016020920 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304420006 2016020922 RSK 175 Modified 1 PASI-CZDO
SM 2320B 3 PASI-AKDF
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 24
Duke Energy Analytical Lab
Page 42 of 79
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92304420
J16070200
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92304420001 2016020916
Alkalinity,Bicarbonate (CaCO3)12.9 mg/L 07/14/16 00:155.0SM 2320B
Alkalinity, Total as CaCO3 12.9 mg/L 07/14/16 00:155.0SM 2320B
92304420002 2016020917
Methane 21.0 ug/L 07/14/16 01:0210.0RSK 175 Modified
Alkalinity,Bicarbonate (CaCO3)23.3 mg/L 07/14/16 00:265.0SM 2320B
Alkalinity, Total as CaCO3 23.3 mg/L 07/14/16 00:265.0SM 2320B
92304420003 2016020918
Alkalinity,Bicarbonate (CaCO3)12.3 mg/L 07/14/16 00:375.0SM 2320B
Alkalinity, Total as CaCO3 12.3 mg/L 07/14/16 00:375.0SM 2320B
Chromium, Hexavalent 0.64 ug/L 07/12/16 17:02 M10.090EPA 218.7
92304420004 2016020919
Alkalinity,Bicarbonate (CaCO3)34.9 mg/L 07/14/16 00:515.0SM 2320B
Alkalinity, Total as CaCO3 34.9 mg/L 07/14/16 00:515.0SM 2320B
92304420005 2016020920
Alkalinity,Bicarbonate (CaCO3)36.9 mg/L 07/14/16 17:275.0SM 2320B
Alkalinity, Total as CaCO3 36.9 mg/L 07/14/16 17:275.0SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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[phone]
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Duke Energy Analytical Lab
Page 43 of 79
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304420
J16070200
Method:
Client:Duke Energy
RSK 175 Modified
Date:July 15, 2016
Description:RSK 175 Headspace
General Information:
6 samples were analyzed for RSK 175 Modified. All samples were received in acceptable condition with any exceptions noted below or
on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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Duke Energy Analytical Lab
Page 44 of 79
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304420
J16070200
Method:
Client:Duke Energy
SM 2320B
Date:July 15, 2016
Description:2320B Alkalinity
General Information:
6 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 320941
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92304313005,92304313006
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1778410)
• Alkalinity, Total as CaCO3
• MSD (Lab ID: 1778411)
• Alkalinity, Total as CaCO3
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 24
Duke Energy Analytical Lab
Page 45 of 79
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304420
J16070200
Method:
Client:Duke Energy
SM 4500-S2D
Date:July 15, 2016
Description:4500S2D Sulfide Water
General Information:
6 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 321057
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92303930034,92304304001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1779215)
• Sulfide
• MSD (Lab ID: 1779216)
• Sulfide
M3: Matrix spike recovery was outside laboratory control limits due to matrix interferences.
• MS (Lab ID: 1779213)
• Sulfide
• MSD (Lab ID: 1779214)
• Sulfide
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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Duke Energy Analytical Lab
Page 46 of 79
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304420
J16070200
Method:
Client:Duke Energy
EPA 218.7
Date:July 15, 2016
Description:Hexavalent Chromium by IC
General Information:
6 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 308142
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92303966001,92304420003
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1632880)
• Chromium, Hexavalent
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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[phone]
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Duke Energy Analytical Lab
Page 47 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304420
J16070200
Sample:2016020916 Lab ID:92304420001 Collected:07/07/16 09:45 Received:07/08/16 11:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/14/16 00:47 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)12.9 mg/L 07/14/16 00:155.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/14/16 00:155.0 1
Alkalinity, Total as CaCO3 12.9 mg/L 07/14/16 00:155.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 07/12/16 16:36 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/15/2016 06:56 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 24
Duke Energy Analytical Lab
Page 48 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304420
J16070200
Sample:2016020917 Lab ID:92304420002 Collected:07/07/16 11:57 Received:07/08/16 11:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 21.0 ug/L 07/14/16 01:02 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)23.3 mg/L 07/14/16 00:265.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/14/16 00:265.0 1
Alkalinity, Total as CaCO3 23.3 mg/L 07/14/16 00:265.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 07/12/16 16:49 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/15/2016 06:56 PM
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9800 Kincey Ave. Suite 100
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[phone]
Page 11 of 24
Duke Energy Analytical Lab
Page 49 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304420
J16070200
Sample:2016020918 Lab ID:92304420003 Collected:07/07/16 10:45 Received:07/08/16 11:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/14/16 01:17 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)12.3 mg/L 07/14/16 00:375.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/14/16 00:375.0 1
Alkalinity, Total as CaCO3 12.3 mg/L 07/14/16 00:375.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.64 ug/L 07/12/16 17:02 18540-29-9 M10.090 3
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/15/2016 06:56 PM
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Duke Energy Analytical Lab
Page 50 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304420
J16070200
Sample:2016020919 Lab ID:92304420004 Collected:07/07/16 14:30 Received:07/08/16 11:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/14/16 01:32 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)34.9 mg/L 07/14/16 00:515.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/14/16 00:515.0 1
Alkalinity, Total as CaCO3 34.9 mg/L 07/14/16 00:515.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 07/12/16 17:41 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/15/2016 06:56 PM
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Duke Energy Analytical Lab
Page 51 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304420
J16070200
Sample:2016020920 Lab ID:92304420005 Collected:07/07/16 15:35 Received:07/08/16 11:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/14/16 01:48 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)36.9 mg/L 07/14/16 17:275.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/14/16 17:275.0 1
Alkalinity, Total as CaCO3 36.9 mg/L 07/14/16 17:275.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 07/12/16 17:54 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/15/2016 06:56 PM
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Duke Energy Analytical Lab
Page 52 of 79
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304420
J16070200
Sample:2016020922 Lab ID:92304420006 Collected:07/07/16 15:40 Received:07/08/16 11:50 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/14/16 02:03 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 07/14/16 18:045.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 07/14/16 18:045.0 1
Alkalinity, Total as CaCO3 ND mg/L 07/14/16 18:045.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/13/16 16:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 07/12/16 18:07 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/15/2016 06:56 PM
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Duke Energy Analytical Lab
Page 53 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304420
J16070200
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321035
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92304420001, 92304420002, 92304420003, 92304420004, 92304420005, 92304420006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1779009
Associated Lab Samples:92304420001, 92304420002, 92304420003, 92304420004, 92304420005, 92304420006
Matrix:Water
Analyzed
Methane ug/L ND 10.0 N207/13/16 22:29
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1779010LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 306 N23967770-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1779011MATRIX SPIKE SAMPLE:
MSSpike
Result
92304357001
Methane ug/L 392 N23969970-130ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92304357002
1779012SAMPLE DUPLICATE:
Methane ug/L ND N220ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 07/15/2016 06:56 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 24
Duke Energy Analytical Lab
Page 54 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304420
J16070200
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
320941
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92304420001, 92304420002, 92304420003, 92304420004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1778406
Associated Lab Samples:92304420001, 92304420002, 92304420003, 92304420004
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 07/13/16 17:28
Alkalinity, Total as CaCO3 mg/L ND 5.0 07/13/16 17:28
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 07/13/16 17:28
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1778407LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 50.850 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1778408MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304313005
1778409
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 102 80-12092 4 255065.7 117 112
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1778410MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304313006
1778411
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L M1504380-12040 2 255056.2 77.9 76.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/15/2016 06:56 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 24
Duke Energy Analytical Lab
Page 55 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304420
J16070200
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321132
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92304420005, 92304420006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1779577
Associated Lab Samples:92304420005, 92304420006
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 07/14/16 17:06
Alkalinity, Total as CaCO3 mg/L ND 5.0 07/14/16 17:06
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 07/14/16 17:06
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1779578LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 48.450 97 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1779579MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304420005
1779580
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 85 80-12087 1 255036.9 79.6 80.4
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1779581MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304520002
1779582
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 91 80-12090 1 255033.0 78.5 78.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/15/2016 06:56 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 24
Duke Energy Analytical Lab
Page 56 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304420
J16070200
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321057
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92304420001, 92304420002, 92304420003, 92304420004, 92304420005, 92304420006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1779211
Associated Lab Samples:92304420001, 92304420002, 92304420003, 92304420004, 92304420005, 92304420006
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 07/13/16 16:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1779212LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.51.5 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1779213MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304304001
1779214
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L M3.5 6 90-1106 10.5ND ND ND
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1779215MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92303930034
1779216
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L M1.5 120 90-110120 0 10.5ND 0.60 0.60
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/15/2016 06:56 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 24
Duke Energy Analytical Lab
Page 57 of 79
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304420
J16070200
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
308142
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92304420001, 92304420002, 92304420003, 92304420004, 92304420005, 92304420006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1632876
Associated Lab Samples:92304420001, 92304420002, 92304420003, 92304420004, 92304420005, 92304420006
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 07/12/16 11:46
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1632877LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.074.075 99 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1632878MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92303966001
1632879
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .22 92 85-115106 5 20.220.38 0.58 0.62
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1632880MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304420003
1632881
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.075 53 85-11596 5 20.0750.64 0.68 0.72
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/15/2016 06:56 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 24
Duke Energy Analytical Lab
Page 58 of 79
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92304420
J16070200
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Matrix spike recovery was outside laboratory control limits due to matrix interferences.M3
The lab does not hold TNI accreditation for this parameter.N2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/15/2016 06:56 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 24
Duke Energy Analytical Lab
Page 59 of 79
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92304420
J16070200
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92304420001 3210352016020916RSK 175 Modified
92304420002 3210352016020917RSK 175 Modified
92304420003 3210352016020918RSK 175 Modified
92304420004 3210352016020919RSK 175 Modified
92304420005 3210352016020920RSK 175 Modified
92304420006 3210352016020922RSK 175 Modified
92304420001 3209412016020916SM 2320B
92304420002 3209412016020917SM 2320B
92304420003 3209412016020918SM 2320B
92304420004 3209412016020919SM 2320B
92304420005 3211322016020920SM 2320B
92304420006 3211322016020922SM 2320B
92304420001 3210572016020916SM 4500-S2D
92304420002 3210572016020917SM 4500-S2D
92304420003 3210572016020918SM 4500-S2D
92304420004 3210572016020919SM 4500-S2D
92304420005 3210572016020920SM 4500-S2D
92304420006 3210572016020922SM 4500-S2D
92304420001 3081422016020916EPA 218.7
92304420002 3081422016020917EPA 218.7
92304420003 3081422016020918EPA 218.7
92304420004 3081422016020919EPA 218.7
92304420005 3081422016020920EPA 218.7
92304420006 3081422016020922EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/15/2016 06:56 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 24
Duke Energy Analytical Lab
Page 60 of 79
Page 23 of 24
Duke Energy Analytical Lab
Page 61 of 79
Page 24 of 24
Duke Energy Analytical Lab
Page 62 of 79

July 28, 2016

Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment Water
Work Order: 401189
SDG: J16070200

Dear Mary :
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on July 08, 2016. This original data report has been prepared and reviewed in accordance
with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 1250944
Enclosures
Page 1 of 16
Chelsea Seagle for
Duke Energy Analytical Lab
Page 63 of 79
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO002 Duke Energy
Client SDG: J16070200 GEL Work Order: 401189
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
for
Page 2 of 16
Duke Energy Analytical Lab
Page 64 of 79
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 28, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1580514
1580514
1580990
1580552
0830
0907
1403
0945
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/13/16
07/14/16
07/25/16
07/26/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401189001
Water
07-JUL-16 09:45
08-JUL-16
2016020916 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.743
0.306
1
2
3
4
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
0.852
0.417
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"94 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/11/16 15805130734SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 3 of 16
Duke Energy Analytical Lab
Page 65 of 79
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 28, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1580514
1580514
1580990
1580552
0904
0918
1403
0945
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/13/16
07/14/16
07/25/16
07/26/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401189002
Water
07-JUL-16 11:57
08-JUL-16
2016020917 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.750
0.359
1
2
3
4
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
1.32
1.25
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"79.7 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/11/16 15805130734SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 4 of 16
Duke Energy Analytical Lab
Page 66 of 79
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 28, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1580514
1580514
1580990
1580552
0906
0919
1403
1015
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/13/16
07/14/16
07/25/16
07/26/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401189003
Water
07-JUL-16 10:45
08-JUL-16
2016020918 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.434
0.285
1
2
3
4
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
1.02
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"91.3 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/11/16 15805130734SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 5 of 16
Duke Energy Analytical Lab
Page 67 of 79
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 28, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1580514
1580514
1580990
1580552
0907
0921
1407
1015
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/13/16
07/14/16
07/25/16
07/26/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401189004
Water
07-JUL-16 14:30
08-JUL-16
2016020919 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.655
0.295
1
2
3
4
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
1.63
0.308
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"78.7 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/11/16 15805130734SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 6 of 16
Duke Energy Analytical Lab
Page 68 of 79
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 28, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1580514
1580514
1580990
1580552
0909
0922
1407
1015
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/13/16
07/14/16
07/25/16
07/26/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
401189005
Water
07-JUL-16 15:35
08-JUL-16
2016020920 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.502
0.342
1
2
3
4
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
0.523
ND
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"83.7 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/11/16 15805130734SXW1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1580514Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Parmname
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, North Carolina
July 28, 2016Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
Anlst Date Time
SKJ 07/14/16 09:08
07/13/16 08:32
07/13/16 08:29
07/14/16 09:05
07/14/16 09:04
07/13/16 08:27
07/13/16 08:33
07/14/16 09:10
07/14/16 09:11
QC
ND
ND
ND
ND
0.0549
0.000558
0.000565
0.0054
ND
ND
ND
ND
0.0533
0.000527
0.00055
0.00527
ND
NOM Sample
ND
ND
ND
ND
ND
ND
ND
ND
ND
Range
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
U
U
U
QC1203581851 401189001
QC1203581849
QC1203581850
QC1203581848
QC1203581852 401189001
QC1203581853 401189001
QC1203581854 401189001
N/A
N/A
N/A
N/A
N/A
REC%
111
112
103
108
107
105
100
105
0.0496
0.0005
0.00055
0.005
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
MS
MS
SDILT
401189Workorder:
Mail Code: MGO3A2
U
U
U
U
U
U
U
U
U
RPD%
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
Rad Ra-226
1580514
1580990
1580552
Batch
Batch
Batch
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-228
Radium-228
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
ug/L
ug/L
ug/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
SKJ
AXM6
LXP1
07/14/16 09:11
07/13/16 08:35
07/25/16 15:36
07/25/16 14:06
07/25/16 14:06
07/26/16 10:50
07/26/16 10:50
07/26/16 10:50
07/26/16 10:50
QC
ND
ND
ND
0.703
16.7
0.304
1.98
25.8
0.165
119
NOM Sample
ND
ND
ND
1.63
2.29
2.29
Range
(0%-10%)
(0%-10%)
(0% - 100%)
(75%-125%)
(0%-20%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
QC1203582996 401189004
QC1203582997
QC1203582995
QC1203581946 401113001
QC1203581948
QC1203581945
QC1203581947 401113001
The Qualifiers in this report are defined as follows:
N/A
N/A
N/A
79.5
14.3
REC%
111
106
95.5
15.0
24.4
122
DUP
LCS
MB
DUP
LCS
MB
MS
401189Workorder:
**
<
>
BD
E
FA
FB
H
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
U
U
U
RPD%
Notes:
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 3 of 3
Units Anlst Date TimeQCNOMSampleRangeQualREC%
401189Workorder:
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
U
UI
UJ
UL
X
Y
^
h
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
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Technical Case Narrative
Duke Energy (DUPO)
SDG #: J16070200
Work Order #: 401189

Metals

Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1580514

Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1580513
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
401189001 2016020916
401189002 2016020917
401189003 2016020918
401189004 2016020919
401189005 2016020920
1203581848 Method Blank (MB)ICP-MS
1203581849 Laboratory Control Sample (LCS)
1203581850 Laboratory Control Sample (LCS)
1203581854 401189001(2016020916L) Serial Dilution (SD)
1203581851 401189001(2016020916D) Sample Duplicate (DUP)
1203581852 401189001(2016020916S) Matrix Spike (MS)
1203581853 401189001(2016020916S) Matrix Spike (MS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Radiochemistry

Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1580990
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
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401189001 2016020916
401189002 2016020917
401189003 2016020918
401189004 2016020919
401189005 2016020920
1203582995 Method Blank (MB)
1203582996 401189004(2016020919) Sample Duplicate (DUP)
1203582997 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Technical Information

Recounts
Sample 1203582996 (2016020919DUP) was recounted due to high MDC. The recount is reported.

Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1580552
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
401189001 2016020916
401189002 2016020917
401189003 2016020918
401189004 2016020919
401189005 2016020920
1203581945 Method Blank (MB)
1203581946 401113001(NonSDG) Sample Duplicate (DUP)
1203581947 401113001(NonSDG) Matrix Spike (MS)
1203581948 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Miscellaneous Information

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Additional Comments
The matrix spike, 1203581947 (Non SDG 401113001MS), aliquot was reduced to conserve sample volume.

Certification Statement

Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
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State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
North Dakota
Oklahoma
Pennsylvania NELAP
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-0110
88-0651
42D0904046
2940
SC00012
PH-0169
SC00012
2567.01
E87156
P330-15-00283, P330-15-00253
SC00012
967
SC00012
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA160006
270
M-SC012
9976
SC00012
NE-OS-26-13
SC000122016-1
205415
SC002
SC00012
11501
233
45709
R-158
9904
68-00485
10120002
10120001
TN 02934
T104704235-16-11
SC000122016-20
VT87156
460202
C780
997404
List of current GEL Certifications as of 28 July 2016
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