NC0000396_App B Lab Reports - CAMA BKGD - J16070079report_20160831

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16070079
Project Name:ASHEVILLE - AB GW ASSESSMENT WATER
Lab Contact:Anne Pridgeon
Date:8/2/2016
Customer Address:200 CP and L Drive
Customer Name(s):Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
Arden,NC 28704
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Anne Pridgeon) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Anne Pridgeon
Page 1 of 51
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016020135 ASHEVILLE 05-Jul-16 9:16 AM BD CB-9
2016020145 ASHEVILLE 05-Jul-16 3:38 PM BD CB-1
2 Total Samples
Page 2 of 51
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:8/2/2016
Electronic Data Deliverable (EDD) Sent Separatel
Page 3 of 51
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070079
2016020135
Collection Date:05-Jul-16 9:16 AM
Site:CB-9
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.253 mg-N/L EPA 353.2 07/07/2016 13:31 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/21/2016 13:46 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/14/2016 13:02 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.022 mg/L EPA 200.7 07/11/2016 14:40 JJMACKE0.005 1
Barium (Ba)0.026 mg/L EPA 200.7 07/11/2016 14:40 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/11/2016 14:40 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/11/2016 14:40 JJMACKE0.01 1
Manganese (Mn)0.034 mg/L EPA 200.7 07/11/2016 14:40 JJMACKE0.005 1
Strontium (Sr)0.007 mg/L EPA 200.7 07/11/2016 14:40 JJMACKE0.005 1
Zinc (Zn)0.015 mg/L EPA 200.7 07/11/2016 14:40 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.478 mg/L EPA 200.7 07/13/2016 12:19 JJMACKE0.01 1
Magnesium (Mg)0.926 mg/L EPA 200.7 07/13/2016 12:19 JJMACKE0.005 1
Potassium (K)0.685 mg/L EPA 200.7 07/13/2016 12:19 JJMACKE0.1 1
Sodium (Na)3.85 mg/L EPA 200.7 07/13/2016 12:19 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.185 mg/L EPA 200.7 07/21/2016 12:21 JJMACKE0.005 1
Barium (Ba)0.029 mg/L EPA 200.7 07/21/2016 12:21 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/21/2016 12:21 JJMACKE0.05 1
Iron (Fe)0.345 mg/L EPA 200.7 07/21/2016 12:21 JJMACKE0.01 1
Manganese (Mn)0.044 mg/L EPA 200.7 07/21/2016 12:21 JJMACKE0.005 1
Strontium (Sr)0.008 mg/L EPA 200.7 07/21/2016 12:21 JJMACKE0.005 1
Zinc (Zn)0.010 mg/L EPA 200.7 07/21/2016 12:21 JJMACKE0.005 1
Page 4 of 51
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070079
2016020135
Collection Date:05-Jul-16 9:16 AM
Site:CB-9
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/19/2016 21:44 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/19/2016 21:44 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/19/2016 21:44 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/19/2016 21:44 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/19/2016 21:44 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 07/19/2016 21:44 JAHERMA11
Copper (Cu)6.54 ug/L EPA 200.8 07/19/2016 21:44 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/19/2016 21:44 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/19/2016 21:44 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/19/2016 21:44 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/19/2016 21:44 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/19/2016 21:44 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/19/2016 21:44 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/29/2016 14:16 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/29/2016 14:16 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/29/2016 14:16 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/29/2016 14:16 JAHERMA11
Chromium (Cr)1.00 ug/L EPA 200.8 07/29/2016 14:16 JAHERMA11
Cobalt (Co)1.16 ug/L EPA 200.8 07/29/2016 14:16 JAHERMA11
Copper (Cu)1.24 ug/L EPA 200.8 07/29/2016 14:16 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/29/2016 14:16 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/29/2016 14:16 JAHERMA11
Nickel (Ni)1.86 ug/L EPA 200.8 07/29/2016 14:16 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/29/2016 14:16 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/29/2016 14:16 JAHERMA0.2 1
Vanadium (V) Low Level 0.550 ug/L EPA 200.8 07/29/2016 14:16 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Total Carbon
TOC 0.226 mg/L SM5310C/EPA9060A 07/07/2016 15:44 GHUTCHI0.1 1
Page 5 of 51
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070079
2016020145
Collection Date:05-Jul-16 3:38 PM
Site:CB-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.370 mg-N/L EPA 353.2 07/07/2016 13:32 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/21/2016 13:49 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 07/14/2016 13:04 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.064 mg/L EPA 200.7 07/11/2016 14:44 JJMACKE0.005 1
Barium (Ba)0.018 mg/L EPA 200.7 07/11/2016 14:44 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/11/2016 14:44 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 07/11/2016 14:44 JJMACKE0.01 1
Manganese (Mn)0.023 mg/L EPA 200.7 07/11/2016 14:44 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 07/11/2016 14:44 JJMACKE0.005 1
Zinc (Zn)0.017 mg/L EPA 200.7 07/11/2016 14:44 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.040 mg/L EPA 200.7 07/13/2016 12:23 JJMACKE0.01 1
Magnesium (Mg)0.395 mg/L EPA 200.7 07/13/2016 12:23 JJMACKE0.005 1
Potassium (K)0.436 mg/L EPA 200.7 07/13/2016 12:23 JJMACKE0.1 1
Sodium (Na)0.983 mg/L EPA 200.7 07/13/2016 12:23 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.467 mg/L EPA 200.7 07/21/2016 12:34 JJMACKE0.005 1
Barium (Ba)0.022 mg/L EPA 200.7 07/21/2016 12:34 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 07/21/2016 12:34 JJMACKE0.05 1
Iron (Fe)0.492 mg/L EPA 200.7 07/21/2016 12:34 JJMACKE0.01 1
Manganese (Mn)0.032 mg/L EPA 200.7 07/21/2016 12:34 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 07/21/2016 12:34 JJMACKE0.005 1
Zinc (Zn)0.012 mg/L EPA 200.7 07/21/2016 12:34 JJMACKE0.005 1
Page 6 of 51
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070079
2016020145
Collection Date:05-Jul-16 3:38 PM
Site:CB-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 07/19/2016 22:13 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/19/2016 22:13 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/19/2016 22:13 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/19/2016 22:13 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/19/2016 22:13 JAHERMA11
Cobalt (Co)1.91 ug/L EPA 200.8 07/19/2016 22:13 JAHERMA11
Copper (Cu)10.6 ug/L EPA 200.8 07/19/2016 22:13 JAHERMA11
Lead (Pb)1.06 ug/L EPA 200.8 07/19/2016 22:13 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/19/2016 22:13 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 07/19/2016 22:13 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/19/2016 22:13 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/19/2016 22:13 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 07/19/2016 22:13 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 07/29/2016 13:49 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 07/29/2016 13:49 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 07/29/2016 13:49 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 07/29/2016 13:49 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 07/29/2016 13:49 JAHERMA11
Cobalt (Co)2.32 ug/L EPA 200.8 07/29/2016 13:49 JAHERMA11
Copper (Cu)1.37 ug/L EPA 200.8 07/29/2016 13:49 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 07/29/2016 13:49 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 07/29/2016 13:49 JAHERMA11
Nickel (Ni)1.36 ug/L EPA 200.8 07/29/2016 13:49 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 07/29/2016 13:49 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 07/29/2016 13:49 JAHERMA0.2 1
Vanadium (V) Low Level 0.397 ug/L EPA 200.8 07/29/2016 13:49 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Total Carbon
TOC 0.189 mg/L SM5310C/EPA9060A 07/07/2016 15:44 GHUTCHI0.1 1
Page 7 of 51
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070079
Q16070552 HG 245.1 MERCURY (COLD VAPOR) IN WATER
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.021 ug/L -10.021 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Spiked Sample # 1
Mercury (Hg) 0.0922 ug/L -201.84 0.05
Final QualifierDilMeasuredUnits:Parameter
Spiked Sample # 2
Mercury (Hg) 0.0171 ug/L -200.343 0.05
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 0.953 20 86ug/L -130702019.1
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.951 20 85.9 0.175ug/L -130702019
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 0.941 20 92.4ug/L -130702018.8
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.949 20 93.1 0.809ug/L -130702019
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.97 2 98.3ug/L -1158511.97
Page 8 of 51
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070079
Q16070325 HG 245.1 Dissolved Mercury Dissolved (cold vapor) in Water (Filtered)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Mercury (Hg) 0.016 ug/L -10.016 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Spiked Sample # 1
Mercury (Hg) 0.014 ug/L -1001.4 0.05
Final QualifierDilMeasuredUnits:Parameter
Spiked Sample # 2
Mercury (Hg) 0.017 ug/L -10.017 0.05
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 0.926 100 91.2ug/L -1307010092.6
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.898 100 88.4 3.12ug/L -1307010089.8
Final QualifierDilMeasuredUnits:Parameter
IS # 2
% Recovery LCL UCLSpike
Mercury (Hg) 0.734 1 71.7ug/L -1307010.734
Final QualifierDilMeasuredUnits:Parameter
ISD # 2
RPD% Recovery LCL UCLSpike
Mercury (Hg) 0.734 1 71.7 0ug/L -1307010.734
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Mercury (Hg) 1.96 2 97.8ug/L -1158511.96
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070328 -- 2016021492
Mercury (Hg) 0.622 1 61.8ug/L -1307010.622
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070328 -- 2016021492
Mercury (Hg) 0.64 1 63.6 2.87ug/L -1307010.64
Page 9 of 51
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070079
Q16070211 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) -0.000647 mg/L -1-0.000647 0.005 < 1/2 RDL
Barium (Ba) -0.000142 mg/L -1-0.000142 0.005 < 1/2 RDL
Boron (B) -0.00238 mg/L -1-0.00238 0.05 < 1/2 RDL
Iron (Fe) -0.00117 mg/L -1-0.00117 0.01 < 1/2 RDL
Manganese (Mn) -0.000442 mg/L -1-0.000442 0.005 < 1/2 RDL
Strontium (Sr) 0.00006 mg/L -10.00006 0.005 < 1/2 RDL
Zinc (Zn) -0.000932 mg/L -1-0.000932 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 2.06 2 103mg/L -1158512.06
Barium (Ba) 1 1 100mg/L -1158511
Boron (B) 2.02 2 101mg/L -1158512.02
Iron (Fe) 2.05 2 103mg/L -1158512.05
Manganese (Mn) 0.99 1 99mg/L -1158510.99
Strontium (Sr) 1.93 2 96.3mg/L -1158511.93
Zinc (Zn) 1.04 1 104mg/L -1158511.04
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021083
Aluminum (Al) 5.53 5 110mg/L -1307015.53
Barium (Ba) 5.34 5 107mg/L -1307015.34
Boron (B) 5.2 5 104mg/L -1307015.2
Iron (Fe) 5.23 5 103mg/L -1307015.23
Manganese (Mn) 5.5 5 109mg/L -1307015.5
Strontium (Sr) 5.11 5 102mg/L -1307015.11
Zinc (Zn) 5.34 5 107mg/L -1307015.34
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021083
Aluminum (Al) 5.52 5 110 0.145mg/L -1307015.52
Barium (Ba) 5.31 5 106 0.677mg/L -1307015.31
Boron (B) 5.2 5 104 0mg/L -1307015.2
Iron (Fe) 5.23 5 103 0mg/L -1307015.23
Manganese (Mn) 5.49 5 109 0.184mg/L -1307015.49
Strontium (Sr) 5.12 5 102 0.137mg/L -1307015.12
Zinc (Zn) 5.35 5 107 0.0751mg/L -1307015.35
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021092
Aluminum (Al) 5.49 5 108mg/L -1307015.49
Page 10 of 51
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070079
Q16070211 ICP Dissolved DISSOLVED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021092
Barium (Ba) 5.58 5 106mg/L -1307015.58
Boron (B) 5.31 5 103mg/L -1307015.31
Iron (Fe) 5.73 5 79.6mg/L -130701057.3
Manganese (Mn) 6.14 5 108mg/L -1307016.14
Strontium (Sr) 5.37 5 102mg/L -1307015.37
Zinc (Zn) 5.26 5 105mg/L -1307015.26
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021092
Aluminum (Al) 5.48 5 108 0.203mg/L -1307015.48
Barium (Ba) 5.61 5 107 0.678mg/L -1307015.61
Boron (B) 5.32 5 104 0.174mg/L -1307015.32
Iron (Fe) 5.76 5 85.5 7.17mg/L -130701057.6
Manganese (Mn) 6.11 5 108 0.445mg/L -1307016.11
Strontium (Sr) 5.39 5 102 0.372mg/L -1307015.39
Zinc (Zn) 5.24 5 105 0.286mg/L -1307015.24
Page 11 of 51
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070079
Q16070266 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Calcium (Ca) 0.000804 mg/L -10.000804 0.01 < 1/2 RDL
Magnesium (Mg) -0.000016 mg/L -1-0.000016 0.005 < 1/2 RDL
Potassium (K) 0.0121 mg/L -10.0121 0.1 < 1/2 RDL
Sodium (Na) -0.0204 mg/L -1-0.0204 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Blank # 2
RDL Relative Concentration
Calcium (Ca) 0.0025 mg/L -10.0025 0.01 < 1/2 RDL
Magnesium (Mg) 0.000113 mg/L -10.000113 0.005 < 1/2 RDL
Potassium (K) 0.00296 mg/L -10.00296 0.1 < 1/2 RDL
Sodium (Na) -0.0187 mg/L -1-0.0187 0.05 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Calcium (Ca) 2.04 2 102mg/L -1158512.04
Magnesium (Mg) 1.99 2 99.3mg/L -1158511.99
Potassium (K) 3.98 4 99.5mg/L -1158513.98
Sodium (Na) 8.29 8.1 102mg/L -1158518.29
Final QualifierDilMeasuredUnits:Parameter
LCS # 2
% Recovery LCL UCLSpike
Calcium (Ca) 2.07 2 103mg/L -1158512.07
Magnesium (Mg) 2.01 2 101mg/L -1158512.01
Potassium (K) 4.01 4 100mg/L -1158514.01
Sodium (Na) 8.36 8.1 103mg/L -1158518.36
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070215 -- 2016021004
Calcium (Ca) 179 5 0mg/L -130701179
Magnesium (Mg) 6.53 5 100mg/L -1307016.53
Potassium (K) 148 5 272mg/L -130701148
Sodium (Na) 460 5 0mg/L -130701460
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070215 -- 2016021004
Calcium (Ca) 178 5 0 0mg/L -130701178
Magnesium (Mg) 6.49 5 99.2 0.763mg/L -1307016.49
Potassium (K) 146 5 246 10mg/L -130701146
Sodium (Na) 457 5 0 0mg/L -130701457
Page 12 of 51
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070079
Q16070266 ICP Undigested UNDIGESTED METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 2
% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021089
Calcium (Ca) 12 5 102mg/L -13070112
Magnesium (Mg) 11.5 5 96mg/L -13070111.5
Potassium (K) 6.76 5 103mg/L -1307016.76
Sodium (Na) 14 5 82.3mg/L -13070114
Final QualifierDilMeasuredUnits:Parameter
MSD # 2
RPD% Recovery LCL UCLSpike
Parent Sample: J16070225 -- 2016021089
Calcium (Ca) 12 5 101 0.0197mg/L -13070112
Magnesium (Mg) 11.5 5 96 0.0208mg/L -13070111.5
Potassium (K) 6.78 5 103 0.331mg/L -1307016.78
Sodium (Na) 14 5 82 0.438mg/L -13070114
Final QualifierDilMeasuredUnits:Parameter
MS # 3
% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020918
Calcium (Ca) 10.6 5 104mg/L -13070110.6
Magnesium (Mg) 9.21 5 106mg/L -1307019.21
Potassium (K) 6.52 5 105mg/L -1307016.52
Sodium (Na) 16.4 5 88.3mg/L -13070116.4
Final QualifierDilMeasuredUnits:Parameter
MSD # 3
RPD% Recovery LCL UCLSpike
Parent Sample: J16070200 -- 2016020918
Calcium (Ca) 10.6 5 104 0.154mg/L -13070110.6
Magnesium (Mg) 9.17 5 105 0.797mg/L -1307019.17
Potassium (K) 6.5 5 105 0.325mg/L -1307016.5
Sodium (Na) 16.2 5 86.3 2.36mg/L -13070116.2
Page 13 of 51
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070079
Q16070484 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Aluminum (Al) 0.000785 mg/L -10.000785 0.005 < 1/2 RDL
Barium (Ba) 0.000284 mg/L -10.000284 0.005 < 1/2 RDL
Boron (B) 0.00198 mg/L -10.00198 0.05 < 1/2 RDL
Iron (Fe) -0.000577 mg/L -1-0.000577 0.01 < 1/2 RDL
Manganese (Mn) -0.000024 mg/L -1-0.000024 0.005 < 1/2 RDL
Strontium (Sr) 0.000116 mg/L -10.000116 0.005 < 1/2 RDL
Zinc (Zn) -0.000372 mg/L -1-0.000372 0.005 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Aluminum (Al) 5.19 5 104mg/L -1158515.19
Barium (Ba) 5.02 5 100mg/L -1158515.02
Boron (B) 4.9 5 97.9mg/L -1158514.9
Iron (Fe) 4.96 5 99.3mg/L -1158514.96
Manganese (Mn) 5.16 5 103mg/L -1158515.16
Strontium (Sr) 4.87 5 97.4mg/L -1158514.87
Zinc (Zn) 5.01 5 100mg/L -1158515.01
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070079 -- 2016020135
Aluminum (Al) 5.46 5 105mg/L -1307015.46
Barium (Ba) 4.99 5 99.1mg/L -1307014.99
Boron (B) 4.89 5 97.6mg/L -1307014.89
Iron (Fe) 5.18 5 96.7mg/L -1307015.18
Manganese (Mn) 5.1 5 101mg/L -1307015.1
Strontium (Sr) 4.84 5 96.7mg/L -1307014.84
Zinc (Zn) 4.92 5 98.3mg/L -1307014.92
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070079 -- 2016020135
Aluminum (Al) 5.37 5 104 1.64mg/L -1307015.37
Barium (Ba) 4.93 5 98 1.12mg/L -1307014.93
Boron (B) 4.89 5 97.5 0.082mg/L -1307014.89
Iron (Fe) 5.1 5 95.1 1.63mg/L -1307015.1
Manganese (Mn) 5.02 5 99.5 1.64mg/L -1307015.02
Strontium (Sr) 4.87 5 97.3 0.618mg/L -1307014.87
Zinc (Zn) 4.83 5 96.3 1.99mg/L -1307014.83
Page 14 of 51
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070079
Q16070309 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) -0.117 ug/L -1-0.117 1 < 1/2 RDL
Arsenic (As) 0.0036 ug/L -10.0036 1 < 1/2 RDL
Beryllium (Be) 0 ug/L -10 1 < 1/2 RDL
Cadmium (Cd) -0.0072 ug/L -1-0.0072 1 < 1/2 RDL
Chromium (Cr) -0.0182 ug/L -1-0.0182 1 < 1/2 RDL
Cobalt (Co) -0.0128 ug/L -1-0.0128 1 < 1/2 RDL
Copper (Cu) -0.0308 ug/L -1-0.0308 1 < 1/2 RDL
Lead (Pb) -0.0056 ug/L -1-0.0056 1 < 1/2 RDL
Molybdenum (Mo) 0.0162 ug/L -10.0162 1 < 1/2 RDL
Nickel (Ni) -0.448 ug/L -1-0.448 1 < 1/2 RDL
Selenium (Se) 0.0078 ug/L -10.0078 1 < 1/2 RDL
Thallium (Tl) Low Level 0.0068 ug/L -10.0068 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.0236 ug/L -10.0236 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 50.2 50 100ug/L -11585150.2
Arsenic (As) 50.8 50 102ug/L -11585150.8
Beryllium (Be) 49.3 50 98.7ug/L -11585149.3
Cadmium (Cd) 48.9 50 97.7ug/L -11585148.9
Chromium (Cr) 51.7 50 103ug/L -11585151.7
Cobalt (Co) 51.2 50 102ug/L -11585151.2
Copper (Cu) 51.1 50 102ug/L -11585151.1
Lead (Pb) 48.7 50 97.5ug/L -11585148.7
Molybdenum (Mo) 49.3 50 98.6ug/L -11585149.3
Nickel (Ni) 49.9 50 99.9ug/L -11585149.9
Selenium (Se) 51.5 50 103ug/L -11585151.5
Thallium (Tl) Low Level 44.9 50 89.8ug/L -11585144.9
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070079 -- 2016020135
Antimony (Sb) 49.9 50 99.9ug/L -13070149.9
Arsenic (As) 51.1 50 102ug/L -13070151.1
Beryllium (Be) 51 50 102ug/L -13070151
Cadmium (Cd) 48.8 50 97.6ug/L -13070148.8
Chromium (Cr) 53.4 50 106ug/L -13070153.4
Cobalt (Co) 52 50 102ug/L -13070152
Copper (Cu) 57.6 50 102ug/L -13070157.6
Lead (Pb) 49.6 50 98ug/L -13070149.6
Molybdenum (Mo) 49.6 50 99.2ug/L -13070149.6
Page 15 of 51
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070079
Q16070309 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070079 -- 2016020135
Nickel (Ni) 51.4 50 101ug/L -13070151.4
Selenium (Se) 49.3 50 98.4ug/L -13070149.3
Thallium (Tl) Low Level 43.1 50 85.9ug/L -13070143.1
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070079 -- 2016020135
Antimony (Sb) 49 50 98.1 1.84ug/L -13070149
Arsenic (As) 51.4 50 103 0.546ug/L -13070151.4
Beryllium (Be) 51.5 50 103 0.918ug/L -13070151.5
Cadmium (Cd) 49 50 98 0.388ug/L -13070149
Chromium (Cr) 52.3 50 104 2.19ug/L -13070152.3
Cobalt (Co) 51.8 50 102 0.274ug/L -13070151.8
Copper (Cu) 57.5 50 102 0.176ug/L -13070157.5
Lead (Pb) 49.9 50 98.5 0.549ug/L -13070149.9
Molybdenum (Mo) 48.3 50 96.6 2.7ug/L -13070148.3
Nickel (Ni) 52.1 50 103 1.39ug/L -13070152.1
Selenium (Se) 51.2 50 102 3.92ug/L -13070151.2
Thallium (Tl) Low Level 42.6 50 85.1 0.982ug/L -13070142.6
Page 16 of 51
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070079
Q16070487 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
Antimony (Sb) 0.024 ug/L -10.024 1 < 1/2 RDL
Arsenic (As) 0.008 ug/L -10.008 1 < 1/2 RDL
Beryllium (Be) -0.002 ug/L -1-0.002 1 < 1/2 RDL
Cadmium (Cd) 0.004 ug/L -10.004 1 < 1/2 RDL
Chromium (Cr) -0.005 ug/L -1-0.005 1 < 1/2 RDL
Cobalt (Co) 0.003 ug/L -10.003 1 < 1/2 RDL
Copper (Cu) -0.044 ug/L -1-0.044 1 < 1/2 RDL
Lead (Pb) 0.006 ug/L -10.006 1 < 1/2 RDL
Molybdenum (Mo) 0.003 ug/L -10.003 1 < 1/2 RDL
Nickel (Ni) 0.012 ug/L -10.012 1 < 1/2 RDL
Selenium (Se) 0.013 ug/L -10.013 1 < 1/2 RDL
Thallium (Tl) Low Level 0.031 ug/L -10.031 0.2 < 1/2 RDL
Vanadium (V) Low Level 0.008 ug/L -10.008 0.3 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
Antimony (Sb) 53.3 50 107ug/L -11585153.3
Arsenic (As) 50.1 50 100ug/L -11585150.1
Beryllium (Be) 47.3 50 94.7ug/L -11585147.3
Cadmium (Cd) 49.9 50 99.8ug/L -11585149.9
Chromium (Cr) 48.6 50 97.3ug/L -11585148.6
Cobalt (Co) 49.6 50 99.3ug/L -11585149.6
Copper (Cu) 49 50 98ug/L -11585149
Lead (Pb) 49.9 50 99.8ug/L -11585149.9
Molybdenum (Mo) 49.5 50 99ug/L -11585149.5
Nickel (Ni) 49.7 50 99.4ug/L -11585149.7
Selenium (Se) 49.6 50 99.2ug/L -11585149.6
Thallium (Tl) Low Level 46.7 50 93.3ug/L -11585146.7
Vanadium (V) Low Level 48.7 50 97.4ug/L -11585148.7
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070079 -- 2016020145
Antimony (Sb) 53.1 50 106ug/L -13070153.1
Arsenic (As) 50 50 99.6ug/L -13070150
Beryllium (Be) 48.9 50 97.6ug/L -13070148.9
Cadmium (Cd) 50.2 50 100ug/L -13070150.2
Chromium (Cr) 49.8 50 99.1ug/L -13070149.8
Cobalt (Co) 51.9 50 99.1ug/L -13070151.9
Copper (Cu) 50.6 50 98.5ug/L -13070150.6
Lead (Pb) 50.2 50 100ug/L -13070150.2
Page 17 of 51
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070079
Q16070487 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
MS # 1
% Recovery LCL UCLSpike
Parent Sample: J16070079 -- 2016020145
Molybdenum (Mo) 49.1 50 98.1ug/L -13070149.1
Nickel (Ni) 51.9 50 101ug/L -13070151.9
Selenium (Se) 49.4 50 98.8ug/L -13070149.4
Thallium (Tl) Low Level 47.5 50 94.8ug/L -13070147.5
Vanadium (V) Low Level 50.1 50 99.4ug/L -13070150.1
Final QualifierDilMeasuredUnits:Parameter
MSD # 1
RPD% Recovery LCL UCLSpike
Parent Sample: J16070079 -- 2016020145
Antimony (Sb) 53.6 50 107 0.997ug/L -13070153.6
Arsenic (As) 50.3 50 100 0.764ug/L -13070150.3
Beryllium (Be) 48.4 50 96.7 0.98ug/L -13070148.4
Cadmium (Cd) 50.3 50 101 0.205ug/L -13070150.3
Chromium (Cr) 49.9 50 99.2 0.115ug/L -13070149.9
Cobalt (Co) 52.1 50 99.6 0.499ug/L -13070152.1
Copper (Cu) 50.8 50 98.8 0.29ug/L -13070150.8
Lead (Pb) 50.5 50 101 0.497ug/L -13070150.5
Molybdenum (Mo) 49.4 50 98.8 0.715ug/L -13070149.4
Nickel (Ni) 51.8 50 101 0.127ug/L -13070151.8
Selenium (Se) 49.4 50 98.7 0.0466ug/L -13070149.4
Thallium (Tl) Low Level 47.7 50 95.2 0.455ug/L -13070147.7
Vanadium (V) Low Level 49.9 50 98.9 0.442ug/L -13070149.9
Page 18 of 51
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16070079
Q16070180 Total Carbon Total Carbon
Level II QC Summary
Final QualifierDilMeasuredUnits:Parameter
Blank # 1
RDL Relative Concentration
TOC 0.023 mg/L -10.023 0.1 < 1/2 RDL
Final QualifierDilMeasuredUnits:Parameter
Spiked Sample # 1
TOC 0.819 mg/L -10.819 0.1
Final QualifierDilMeasuredUnits:Parameter
IS # 1
% Recovery LCL UCLSpike
TOC 2.86 2 102mg/L -1208012.86
Final QualifierDilMeasuredUnits:Parameter
ISD # 1
RPD% Recovery LCL UCLSpike
TOC 2.81 2 99.8 2.33mg/L -1208012.81
Final QualifierDilMeasuredUnits:Parameter
LCS # 1
% Recovery LCL UCLSpike
TOC 2.97 2.87 103mg/L -1158512.97
Page 19 of 51
#=CL#
July 15, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92304135
92304135
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16070079
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on July 06, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Anne Pifer
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 18
Page 20 of 51
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92304135
J16070079
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 18
Page 21 of 51
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92304135
J16070079
Lab ID Sample ID Matrix Date Collected Date Received
92304135001 2016020135 Water 07/05/16 09:16 07/06/16 12:46
92304135002 2016020145 Water 07/05/16 15:38 07/06/16 12:46
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 18
Page 22 of 51
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92304135
J16070079
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92304135001 2016020135 RSK 175 Modified 1 PASI-CZDO
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
92304135002 2016020145 RSK 175 Modified 1 PASI-CZDO
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OAEM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 18
Page 23 of 51
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92304135
J16070079
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92304135001 2016020135
Chromium, Hexavalent 0.085 ug/L 07/12/16 15:440.030EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 18
Page 24 of 51
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304135
J16070079
Method:
Client:Duke Energy
RSK 175 Modified
Date:July 15, 2016
Description:RSK 175 Headspace
General Information:
2 samples were analyzed for RSK 175 Modified. All samples were received in acceptable condition with any exceptions noted below or
on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 18
Page 25 of 51
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304135
J16070079
Method:
Client:Duke Energy
SM 4500-S2D
Date:July 15, 2016
Description:4500S2D Sulfide Water
General Information:
2 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 18
Page 26 of 51
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92304135
J16070079
Method:
Client:Duke Energy
EPA 218.7
Date:July 15, 2016
Description:Hexavalent Chromium by IC
General Information:
2 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 308142
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92303966001,92304420003
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1632880)
• Chromium, Hexavalent
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 18
Page 27 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304135
J16070079
Sample:2016020135 Lab ID:92304135001 Collected:07/05/16 09:16 Received:07/06/16 12:46 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/13/16 08:35 74-82-810.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/12/16 13:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.085 ug/L 07/12/16 15:44 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/15/2016 04:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 18
Page 28 of 51
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92304135
J16070079
Sample:2016020145 Lab ID:92304135002 Collected:07/05/16 15:38 Received:07/06/16 12:46 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 07/13/16 22:44 74-82-810.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 07/12/16 13:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 07/12/16 15:57 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/15/2016 04:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 18
Page 29 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304135
J16070079
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
320851
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92304135001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1777777
Associated Lab Samples:92304135001
Matrix:Water
Analyzed
Methane ug/L ND 10.0 N207/12/16 22:52
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1777778LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 425 N239610770-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1777779MATRIX SPIKE SAMPLE:
MSSpike
Result
92303604001
Methane ug/L 435 N239610970-130ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92303604003
1777780SAMPLE DUPLICATE:
Methane ug/L ND N220ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/15/2016 04:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 18
Page 30 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304135
J16070079
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
321035
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples:92304135002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1779009
Associated Lab Samples:92304135002
Matrix:Water
Analyzed
Methane ug/L ND 10.0 N207/13/16 22:29
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1779010LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 306 N23967770-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1779011MATRIX SPIKE SAMPLE:
MSSpike
Result
92304357001
Methane ug/L 392 N23969970-130ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92304357002
1779012SAMPLE DUPLICATE:
Methane ug/L ND N220ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/15/2016 04:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 18
Page 31 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304135
J16070079
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
320825
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92304135001, 92304135002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1777612
Associated Lab Samples:92304135001, 92304135002
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 07/12/16 13:30
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1777613LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.48.5 97 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1777614MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92303850002
1777615
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 100 90-110100 0 10.5ND 0.54 0.54
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1777616MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92303965001
1777617
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 99 90-11099 0 10.5ND 0.50 0.50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/15/2016 04:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 18
Page 32 of 51
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92304135
J16070079
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
308142
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92304135001, 92304135002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1632876
Associated Lab Samples:92304135001, 92304135002
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 07/12/16 11:46
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1632877LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.074.075 99 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1632878MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92303966001
1632879
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .22 92 85-115106 5 20.220.38 0.58 0.62
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1632880MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92304420003
1632881
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.075 53 85-11596 5 20.0750.64 0.68 0.72
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/15/2016 04:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 18
Page 33 of 51
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92304135
J16070079
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold TNI accreditation for this parameter.N2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/15/2016 04:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 18
Page 34 of 51
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92304135
J16070079
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92304135001 3208512016020135RSK 175 Modified
92304135002 3210352016020145RSK 175 Modified
92304135001 3208252016020135SM 4500-S2D
92304135002 3208252016020145SM 4500-S2D
92304135001 3081422016020135EPA 218.7
92304135002 3081422016020145EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 07/15/2016 04:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 18
Page 35 of 51
Page 17 of 18
Page 36 of 51
Page 18 of 18
Page 37 of 51

July 27, 2016

Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment Water
Work Order: 400979
SDG: J16070079

Dear Mary :
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on July 06, 2016. This original data report has been prepared and reviewed in accordance
with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 1250944
Enclosures
Page 1 of 13
Chelsea Seagle for
Page 38 of 51
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO002 Duke Energy
Client SDG: J16070079 GEL Work Order: 400979
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
for
Page 2 of 13
Page 39 of 51
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 27, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1580072
1580072
1580940
1580551
0815
0934
1110
0810
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/13/16
07/14/16
07/26/16
07/20/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
400979001
Water
05-JUL-16 09:16
06-JUL-16
2016020135 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.522
0.304
1
2
3
4
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
1.49
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"95 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/07/16 15800711700JP1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 3 of 13
Page 40 of 51
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: July 27, 2016
Parameter Result UnitsQualifier Analyst Date TimeDF Batch MethodRLDLPF
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
1580072
1580072
1580940
1580551
0821
0940
1110
0810
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
07/13/16
07/14/16
07/26/16
07/20/16
SKJ
SKJ
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
1.00
1.00
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
400979002
Water
05-JUL-16 15:38
06-JUL-16
2016020145 DUKE00225Project:
DUPO002Client ID:
Client
Sample ID:
Receive Date:
Mail Code: MGO3A2
Client Sample ID:
Surrogate/Tracer Recovery
Matrix:
Collect Date:
Collector:
Recovery%Test Acceptable Limits
0.000067
0.00001
0.00001
0.00001
0.365
0.407
1
2
3
4
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Uranium Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000252
ND
ND
ND
ND
6.55
1.00
1.00
1.00
1.00
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"94.2 (15%-125%)
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 07/07/16 15800711700JP1
Method Description Analyst Date Time Prep Batch
The following Analytical Methods were performed:
1
2
3
4
Method Description
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
NominalResult
Notes:

Lc/LC: Critical Level
PF: Prep Factor
RL: Reporting Limit
SQL: Sample Quantitation Limit
Column headers are defined as follows:
DF: Dilution Factor
DL: Detection Limit
MDA: Minimum Detectable Activity
MDC: Minimum Detectable Concentration
Page 4 of 13
Page 41 of 51
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1580072Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Parmname
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, North Carolina
July 27, 2016Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
Anlst Date Time
SKJ 07/14/16 09:36
07/13/16 08:17
07/13/16 08:14
07/14/16 09:33
07/14/16 09:31
07/13/16 08:13
07/13/16 08:18
07/14/16 09:37
07/14/16 09:39
QC
ND
ND
ND
ND
0.0449
0.000541
0.000553
0.00519
ND
ND
ND
0.000069
0.0455
0.000544
0.000558
0.00517
ND
NOM Sample
ND
ND
ND
ND
ND
ND
ND
ND
ND
Range
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
U
J
U
QC1203580781 400979001
QC1203580780
QC1203580784
QC1203580779
QC1203580782 400979001
QC1203580785 400979001
QC1203580783 400979001
N/A
N/A
N/A
N/A
N/A
REC%
90.4
108
101
104
91.6
109
101
103
0.0496
0.0005
0.00055
0.005
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
MS
MS
SDILT
400979Workorder:
Mail Code: MGO3A2
U
U
U
U
U
U
U
U
U
RPD%
Page 1 of 3
Page 5 of 13
Page 42 of 51
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
Rad Ra-226
1580072
1580940
1580551
Batch
Batch
Batch
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-228
Radium-228
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
ug/L
ug/L
ug/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
SKJ
AXM6
LXP1
07/14/16 09:39
07/13/16 08:20
07/26/16 11:11
07/26/16 12:39
07/26/16 11:11
07/21/16 03:30
07/20/16 10:00
07/20/16 09:26
07/20/16 10:00
QC
ND
ND
ND
-0.205
11.6
0.291
1.98
23.5
0.174
104
NOM Sample
ND
ND
ND
0.015
0.911
0.911
Range
(0%-10%)
(0%-10%)
N/A
(75%-125%)
(0%-20%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
QC1203582872 400954008
QC1203582873
QC1203582871
QC1203581942 401056004
QC1203581944
QC1203581941
QC1203581943 401056004
The Qualifiers in this report are defined as follows:
N/A
N/A
N/A
N/A
73.8
REC%
77.5
96.1
84.6
15.0
24.4
122
DUP
LCS
MB
DUP
LCS
MB
MS
400979Workorder:
**
<
>
BD
E
FA
FB
H
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
U
U
U
U
*
RPD%
Notes:
Page 2 of 3
Page 6 of 13
Page 43 of 51
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 3 of 3
Units Anlst Date TimeQCNOMSampleRangeQualREC%
400979Workorder:
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
U
UI
UJ
UL
X
Y
^
h
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
Page 7 of 13
Page 44 of 51
Page 8 of 13
Page 45 of 51
Page 9 of 13
Page 46 of 51

Technical Case Narrative
Duke Energy (DUPO)
SDG #: J16070079
Work Order #: 400979

Metals

Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1580072

Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1580071
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
400979001 2016020135
400979002 2016020145
1203580779 Method Blank (MB)ICP-MS
1203580780 Laboratory Control Sample (LCS)
1203580784 Laboratory Control Sample (LCS)
1203580783 400979001(2016020135L) Serial Dilution (SD)
1203580781 400979001(2016020135D) Sample Duplicate (DUP)
1203580782 400979001(2016020135S) Matrix Spike (MS)
1203580785 400979001(2016020135S) Matrix Spike (MS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Radiochemistry

Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1580940
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
400979001 2016020135
400979002 2016020145
1203582871 Method Blank (MB)
Page 10 of 13
Page 47 of 51
1203582872 400954008(NonSDG) Sample Duplicate (DUP)
1203582873 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Technical Information

Recounts
Samples were re-eluted and recounted due to a suspected blank false positive. The recounts are reported.

Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1580551
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
400979001 2016020135
400979002 2016020145
1203581941 Method Blank (MB)
1203581942 401056004(NonSDG) Sample Duplicate (DUP)
1203581943 401056004(NonSDG) Matrix Spike (MS)
1203581944 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Quality Control (QC) Information

QC Information
All of the QC samples meet the required acceptance limits with the following exceptions: The sample and the
duplicate,1203581942 (Non SDG 401056004DUP), did not meet the relative percent difference requirement;
however, they do meet the relative error ratio requirement with a value of 2.8056.

Technical Information

Recounts
Sample 1203581942 (Non SDG 401056004DUP) was recounted due to high relative percent difference/relative
Page 11 of 13
Page 48 of 51
error ratio. The recount is reported. Samples were recounted to verify sample results. The recount results are
similar to the original results. Original results are reported 400979001 (2016020135) and 400979002
(2016020145). Sample was recounted due to detector error. Recount is reported. 1203581942 (Non SDG
401056004DUP).

Certification Statement

Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Page 12 of 13
Page 49 of 51
State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
North Dakota
Oklahoma
Pennsylvania NELAP
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-0110
88-0651
42D0904046
2940
SC00012
PH-0169
SC00012
2567.01
E87156
P330-15-00283, P330-15-00253
SC00012
967
SC00012
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA160006
270
M-SC012
9976
SC00012
NE-OS-26-13
SC000122016-1
205415
SC002
SC00012
11501
233
45709
R-158
9904
68-00485
10120002
10120001
TN 02934
T104704235-16-11
SC000122016-20
VT87156
460202
C780
997404
List of current GEL Certifications as of 27 July 2016
Page 13 of 13
Page 50 of 51
Page 51 of 51