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Home My WebLink AboutNC0000396_App B Lab Reports - CAMA BKGD - J16040379report_2016083113339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number: J16040379 Project Name:ASHEVILLE - AB GW ASSESSMENT WATER Lab Contact:Mary Ann Ogle Date:4/27/2016 Customer Address:200 CP and L Drive Customer Name(s):Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu Arden,NC 28704 Phone:980-875-5274 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Mary Ann Ogle Analytical Lab Page 1 of 35 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2016010628 ASHEVILLE 14-Apr-16 11:28 AM illegible ABMW-11BR 1 Total Samples Analytical Lab Page 2 of 35 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:Mary Ann Ogle Date:4/27/2016 Electronic Data Deliverable (EDD) Sent Separately Analytical Lab Page 3 of 35 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16040379 2016010628 Collection Date:14-Apr-16 11:28 AM Site:ABMW-11BR Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.02 mg-N/L EPA 353.2 04/18/2016 13:16 LSTARL10.02 2 CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE INORGANIC IONS BY IC Chloride 3.2 mg/L EPA 300.0 04/20/2016 23:09 BGN90340.1 1 Sulfate 40 mg/L EPA 300.0 04/20/2016 23:09 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 04/23/2016 08:48 DMFRANC0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 04/23/2016 09:19 DMFRANC0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.126 mg/L EPA 200.7 04/19/2016 15:49 JJMACKE0.005 1 Barium (Ba)0.012 mg/L EPA 200.7 04/19/2016 15:49 JJMACKE0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 04/19/2016 15:49 JJMACKE0.05 1 Iron (Fe)0.020 mg/L EPA 200.7 04/19/2016 15:49 JJMACKE0.01 1 Manganese (Mn)0.043 mg/L EPA 200.7 04/19/2016 15:49 JJMACKE0.005 1 Strontium (Sr)0.100 mg/L EPA 200.7 04/19/2016 15:49 JJMACKE0.005 1 Zinc (Zn)0.019 mg/L EPA 200.7 04/19/2016 15:49 JJMACKE0.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)26.6 mg/L EPA 200.7 04/15/2016 13:25 JJMACKE0.01 1 Magnesium (Mg)2.82 mg/L EPA 200.7 04/15/2016 13:25 JJMACKE0.005 1 Potassium (K)15.9 mg/L EPA 200.7 04/15/2016 13:25 JJMACKE0.1 1 Sodium (Na)19.3 mg/L EPA 200.7 04/15/2016 13:25 JJMACKE0.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.992 mg/L EPA 200.7 04/18/2016 11:06 JJMACKE0.005 1 Barium (Ba)0.018 mg/L EPA 200.7 04/18/2016 11:06 JJMACKE0.005 1 Boron (B)< 0.05 mg/L EPA 200.7 04/18/2016 11:06 JJMACKE0.05 1 Iron (Fe)3.47 mg/L EPA 200.7 04/18/2016 11:06 JJMACKE0.01 1 Manganese (Mn)0.085 mg/L EPA 200.7 04/18/2016 11:06 JJMACKE0.005 1 Strontium (Sr)0.104 mg/L EPA 200.7 04/18/2016 11:06 JJMACKE0.005 1 Zinc (Zn)0.024 mg/L EPA 200.7 04/18/2016 11:06 JJMACKE0.005 1 Analytical Lab Page 4 of 35 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J16040379 2016010628 Collection Date:14-Apr-16 11:28 AM Site:ABMW-11BR Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 04/19/2016 14:14 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 04/19/2016 14:14 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 04/19/2016 14:14 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 04/19/2016 14:14 JAHERMA11 Chromium (Cr)1.28 ug/L EPA 200.8 04/19/2016 14:14 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 04/19/2016 14:14 JAHERMA11 Copper (Cu)9.19 ug/L EPA 200.8 04/19/2016 14:14 JAHERMA11 Lead (Pb)1.63 ug/L EPA 200.8 04/19/2016 14:14 JAHERMA11 Molybdenum (Mo)12.4 ug/L EPA 200.8 04/19/2016 14:14 JAHERMA11 Nickel (Ni)4.98 ug/L EPA 200.8 04/19/2016 14:14 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 04/19/2016 14:14 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/19/2016 14:14 JAHERMA0.2 1 Vanadium (V) Low Level 0.534 ug/L EPA 200.8 04/19/2016 14:14 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/19/2016 15:47 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 04/19/2016 15:47 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 04/19/2016 15:47 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 04/19/2016 15:47 JAHERMA11 Chromium (Cr)87.2 ug/L EPA 200.8 04/19/2016 15:47 JAHERMA11 Cobalt (Co)2.22 ug/L EPA 200.8 04/19/2016 15:47 JAHERMA11 Copper (Cu)6.11 ug/L EPA 200.8 04/19/2016 15:47 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 04/19/2016 15:47 JAHERMA11 Molybdenum (Mo)15.4 ug/L EPA 200.8 04/19/2016 15:47 JAHERMA11 Nickel (Ni)52.0 ug/L EPA 200.8 04/19/2016 15:47 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 04/19/2016 15:47 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/19/2016 15:47 JAHERMA0.2 1 Vanadium (V) Low Level 2.31 ug/L EPA 200.8 04/19/2016 15:47 JAHERMA0.3 1 METHANE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE RADIOLOGICAL - (Analysis Performed by GEL) Vendor Parameter Complete Vendor Method v_GEL SULFIDE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL DISSOLVED SOLIDS TDS 190 mg/L SM2540C 04/18/2016 14:25 PARMSTR251 Total Carbon TOC 1.3 mg/L SM5310C/EPA9060A 04/19/2016 14:02 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS 100 mg/L SM2540D 04/15/2016 10:50 PARMSTR51 Analytical Lab Page 5 of 35 #=CL# April 25, 2016 LIMS USE: FR - PROGRAM MANAGER LIMS OBJECT ID: 92294093 92294093 Project: Pace Project No.: RE: Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 J16040379 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on April 15, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc:Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Anne Pifer Rodney Wike, Duke Energy REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 18 Analytical Lab Page 6 of 35 #=CP# CERTIFICATIONS Pace Project No.: Project: 92294093 J16040379 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 525 N 8th Street, Salina, KS 67401 A2LA Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA #: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 North Dakota Certification #: R-216 Oklahoma Certification #: D9947 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Wyoming Certification: FL NELAC Reciprocity West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 18 Analytical Lab Page 7 of 35 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92294093 J16040379 Lab ID Sample ID Matrix Date Collected Date Received 92294093001 2016010628 Water 04/14/16 11:28 04/15/16 14:15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 18 Analytical Lab Page 8 of 35 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92294093 J16040379 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92294093001 2016010628 RSK 175 1 PASI-MDR1 SM 2320B 3 PASI-ATEP SM 4500-S2D 1 PASI-AWRC EPA 218.7 1 PASI-OTK1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 18 Analytical Lab Page 9 of 35 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92294093 J16040379 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92294093001 2016010628 Methane 26.3 ug/L 04/18/16 21:3110.0RSK 175 Alkalinity,Bicarbonate (CaCO3)95.4 mg/L 04/21/16 18:265.0SM 2320B Alkalinity, Total as CaCO3 95.4 mg/L 04/21/16 18:265.0SM 2320B REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 18 Analytical Lab Page 10 of 35 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92294093 J16040379 Method: Client:Duke Energy RSK 175 Date:April 25, 2016 Description:RSK 175 AIR Headspace General Information: 1 sample was analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: AIR/25714 R1: RPD value was outside control limits. • DUP (Lab ID: 2235966) • Methane Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 18 Analytical Lab Page 11 of 35 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92294093 J16040379 Method: Client:Duke Energy SM 2320B Date:April 25, 2016 Description:2320B Alkalinity General Information: 1 sample was analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 18 Analytical Lab Page 12 of 35 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92294093 J16040379 Method: Client:Duke Energy SM 4500-S2D Date:April 25, 2016 Description:4500S2D Sulfide Water General Information: 1 sample was analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WET/44377 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92293980001,92294063001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1715002) • Sulfide • MSD (Lab ID: 1715003) • Sulfide M3: Matrix spike recovery was outside laboratory control limits due to matrix interferences. • MS (Lab ID: 1715004) • Sulfide • MSD (Lab ID: 1715005) • Sulfide Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 18 Analytical Lab Page 13 of 35 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92294093 J16040379 Method: Client:Duke Energy EPA 218.7 Date:April 25, 2016 Description:Hexavalent Chromium by IC General Information: 1 sample was analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WETA/57123 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92293975006,92294145002 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1550400) • Chromium, Hexavalent • MSD (Lab ID: 1550401) • Chromium, Hexavalent Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 18 Analytical Lab Page 14 of 35 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92294093 J16040379 Sample:2016010628 Lab ID:92294093001 Collected:04/14/16 11:28 Received:04/15/16 14:15 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: RSK 175RSK 175 AIR Headspace Methane 26.3 ug/L 04/18/16 21:31 74-82-810.0 1 Analytical Method: SM 2320B2320B Alkalinity Alkalinity,Bicarbonate (CaCO3)95.4 mg/L 04/21/16 18:265.0 1 Alkalinity, Carbonate (CaCO3)ND mg/L 04/21/16 18:265.0 1 Alkalinity, Total as CaCO3 95.4 mg/L 04/21/16 18:265.0 1 Analytical Method: SM 4500-S2D4500S2D Sulfide Water Sulfide ND mg/L 04/21/16 12:30 18496-25-80.10 1 Analytical Method: EPA 218.7Hexavalent Chromium by IC Chromium, Hexavalent ND ug/L 04/23/16 14:27 18540-29-90.030 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/25/2016 10:45 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 18 Analytical Lab Page 15 of 35 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294093 J16040379 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: AIR/25714 RSK 175 RSK 175 RSK 175 AIR HEADSPACE Associated Lab Samples:92294093001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2234083 Associated Lab Samples:92294093001 Matrix:Water Analyzed Methane ug/L ND 10.0 04/18/16 21:23 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2234084LABORATORY CONTROL SAMPLE & LCSD: LCSSpike LCSD % Rec RPD Max RPD LCSD Result 2234085 Methane ug/L 59.760.7 98 85-1159054.8 9 20 Parameter Units Dup Result Max RPD QualifiersRPDResult 92293934021 2235966SAMPLE DUPLICATE: Methane ug/L 6220 R144203970 Parameter Units Dup Result Max RPD QualifiersRPDResult 92294093001 2235967SAMPLE DUPLICATE: Methane ug/L 24.6 7 2026.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/25/2016 10:45 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 18 Analytical Lab Page 16 of 35 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294093 J16040379 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/44349 SM 2320B SM 2320B 2320B Alkalinity Associated Lab Samples:92294093001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1714319 Associated Lab Samples:92294093001 Matrix:Water Analyzed Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 04/21/16 14:05 Alkalinity, Total as CaCO3 mg/L ND 5.0 04/21/16 14:05 Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 04/21/16 14:05 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1714320LABORATORY CONTROL SAMPLE: LCSSpike Alkalinity, Total as CaCO3 mg/L 48.850 98 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1714321MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92293978003 1714322 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Alkalinity, Total as CaCO3 mg/L 50 105 80-120101 1 2550120172171 Parameter Units MS Result % Rec Limits Qual% RecConc. 1714323MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92293983005 1714324 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Alkalinity, Total as CaCO3 mg/L 50 86 80-12086 0 255036.8 79.9 79.7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/25/2016 10:45 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 18 Analytical Lab Page 17 of 35 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294093 J16040379 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/44377 SM 4500-S2D SM 4500-S2D 4500S2D Sulfide Water Associated Lab Samples:92294093001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1715000 Associated Lab Samples:92294093001 Matrix:Water Analyzed Sulfide mg/L ND 0.10 04/21/16 12:30 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1715001LABORATORY CONTROL SAMPLE: LCSSpike Sulfide mg/L 0.51.5 103 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1715002MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92293980001 1715003 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfide mg/L M1.5 111 90-110111 0 10.5ND 0.55 0.55 Parameter Units MS Result % Rec Limits Qual% RecConc. 1715004MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92294063001 1715005 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfide mg/L M3.5 3 90-1103 10.5ND ND ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/25/2016 10:45 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 18 Analytical Lab Page 18 of 35 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92294093 J16040379 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/57123 EPA 218.7 EPA 218.7 Chromium, Hexavalent IC Associated Lab Samples:92294093001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1550398 Associated Lab Samples:92294093001 Matrix:Water Analyzed Chromium, Hexavalent ug/L ND 0.030 04/23/16 09:45 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1550399LABORATORY CONTROL SAMPLE: LCSSpike Chromium, Hexavalent ug/L 0.075.075 99 85-115 Parameter Units MS Result % Rec Limits Qual% RecConc. 1550400MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92293975006 1550401 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chromium, Hexavalent ug/L M1.025 68 85-11559 20.025ND .017J .015J Parameter Units MS Result % Rec Limits Qual% RecConc. 1550402MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92294145002 1550403 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chromium, Hexavalent ug/L .75 89 85-115102 4 20.752.0 2.6 2.7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/25/2016 10:45 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 18 Analytical Lab Page 19 of 35 #=QL# QUALIFIERS Pace Project No.: Project: 92294093 J16040379 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - MinneapolisPASI-M Pace Analytical Services - Ormond BeachPASI-O ANALYTE QUALIFIERS Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 Matrix spike recovery was outside laboratory control limits due to matrix interferences.M3 RPD value was outside control limits.R1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/25/2016 10:45 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 18 Analytical Lab Page 20 of 35 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92294093 J16040379 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92294093001 AIR/257142016010628RSK 175 92294093001 WET/443492016010628SM 2320B 92294093001 WET/443772016010628SM 4500-S2D 92294093001 WETA/571232016010628EPA 218.7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/25/2016 10:45 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 18 Analytical Lab Page 21 of 35 Page 17 of 18 Analytical Lab Page 22 of 35 Page 18 of 18 Analytical Lab Page 23 of 35 April 22, 2016 Mary Ann Ogle Duke Energy Analytical Laboratory 13339 Hagers Ferry Road Mail Code: MGO3A2 Huntersville, North Carolina 28078 Re: AB GW Assessment Water Work Order: 395455 SDG: J16040379 Dear Mary : GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received on April 15, 2016. This original data report has been prepared and reviewed in accordance with GEL’s standard operating procedures. Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time. We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at (843) 556-8171, ext. 4443. Sincerely, PM_SIGN_HERE Lindsay Fabra Project Manager Purchase Order: 1142110 DPNNGO Enclosures Page 1 of 11 Analytical Lab Page 24 of 35 Reviewed by USER_SIGN_HERE GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Report DUPO002 Duke Energy Client SDG: J16040379 GEL Work Order: 395455 Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the Certificate of Analysis. The designation ND, if present, appears in the result column when the analyte concentration is not detected above the limit as defined in the ’U’ qualifier above. This data report has been prepared and reviewed in accordance with GEL Laboratories LLC standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra. The Qualifiers in this report are defined as follows: * A quality control analyte recovery is outside of specified acceptance criteria ** Analyte is a Tracer compound ** Analyte is a surrogate compound U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD. for Page 2 of 11 Analytical Lab Page 25 of 35 Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: April 22, 2016 Metals Analysis-ICP-MS Rad Gas Flow Proportional Counting Rad Radium-226 Parameter Result UnitsQualifier Analyst Date Time 1560300 1560300 1560300 1560419 1560375 1449 1542 2246 1130 0905 ug/mL ug/mL ug/mL ug/mL pCi/L pCi/L 04/19/16 04/20/16 04/20/16 04/21/16 04/21/16 SKJ PRB PRB AXM6 LXP1 0.0002 0.00005 0.00005 0.00005 3.00 1.00 DF 1 1 1 1 Mary Ann Ogle Contact: Duke Energy Analytical Laboratory Company : 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Address : AB GW Assessment WaterProject: 395455001 Water 14-APR-16 11:28 15-APR-16 2016010628 DUKE00225Project: DUPO002Client ID: Client Mail Code: MGO3A2 Surrogate/Tracer Recovery Recovery%Test Acceptable Limits Sample ID: Receive Date: Client Sample ID: Matrix: Collect Date: Collector: Batch Barium-133 Tracer GFPC, Ra228, Liquid "As Received"78 (15%-125%) 0.000067 0.00001 0.00001 0.00001 1.59 0.640 The following Prep Methods were performed: SW846 3010A SW 846 3010 Acid Digestion 04/15/16 15602992040JP1 Method Description Analyst Date Time Prep Batch Method The following Analytical Methods were performed: 1 2 3 4 5 Method Description 1 2 3 4 5 SW846 3010A/6020A SW846 3010A/6020A SW846 3010A/6020A EPA 904.0/SW846 9320 Modified EPA 903.1 Modified Analyst Comments U U U U Uranium-238 Uranium-236 Uranium-233 Uranium-234 Radium-228 Radium-226 SW846 3010A/6020A Liquid "As Received" GFPC, Ra228, Liquid "As Received" Lucas Cell, Ra226, liquid "As Received" 0.0017 ND ND ND ND 1.31 NominalResult RLDL Notes: Page 3 of 11 Analytical Lab Page 26 of 35 QC Summary GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com Metals Analysis - ICPMS 1560300Batch Uranium-233 Uranium-234 Uranium-236 Uranium-238 Uranium-238 Uranium-233 Uranium-234 Uranium-236 Uranium-233 Uranium-234 Uranium-236 Uranium-238 Uranium-238 Uranium-233 Uranium-234 Uranium-236 Uranium-233 Parmname Mary Ann Ogle Contact: Duke Energy Analytical Laboratory 13339 Hagers Ferry Road Huntersville, North Carolina April 22, 2016Report Date: Units ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/L Anlst Date Time PRB SKJ PRB SKJ PRB 04/20/16 22:48 04/20/16 15:43 04/19/16 14:50 04/19/16 14:47 04/20/16 22:45 04/20/16 15:40 04/20/16 22:43 04/20/16 15:38 04/19/16 14:46 04/19/16 14:52 04/20/16 22:50 04/20/16 15:45 04/20/16 22:52 QC ND ND ND 0.00172 0.0535 0.000525 0.000596 0.00474 ND ND ND ND 0.0552 0.000496 0.000564 0.00469 ND NOM Sample ND ND ND 0.0017 0.0017 ND ND ND ND Range (0%-20%) (80%-120%) (80%-120%) (80%-120%) (80%-120%) (75%-125%) (75%-125%) (75%-125%) (75%-125%) Qual U U U U U U U U QC1203529611 395455001 QC1203529610 QC1203529699 QC1203529609 QC1203529612 395455001 QC1203529700 395455001 QC1203529613 395455001 N/A N/A N/A 1.35 N/A REC% 108 105 108 94.8 108 99.2 103 93.9 0.0496 0.0005 0.00055 0.005 0.0496 0.0005 0.00055 0.005 DUP LCS LCS MB MS MS SDILT 395455Workorder: Mail Code: MGO3A2 U U U U U U U RPD% Page 1 of 3 Page 4 of 11 Analytical Lab Page 27 of 35 QC Summary GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com Metals Analysis - ICPMS Rad Gas Flow Rad Ra-226 1560300 1560419 1560375 Batch Batch Batch Uranium-234 Uranium-236 Uranium-238 Radium-228 Radium-228 Radium-228 Radium-226 Radium-226 Radium-226 Radium-226 Parmname Units ug/L ug/L ug/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L Anlst Date Time PRB SKJ AXM6 LXP1 04/20/16 15:47 04/19/16 14:53 04/21/16 11:30 04/21/16 11:30 04/22/16 11:25 04/21/16 09:05 04/21/16 09:35 04/21/16 09:05 04/21/16 09:35 QC ND ND 0.363 0.434 51.1 -0.256 1.55 23.4 0.413 132 NOM Sample ND ND 1.70 1.28 1.31 1.31 Range (0%-10%) (0%-10%) N/A (75%-125%) (0% - 100%) (75%-125%) (75%-125%) Qual U U U U U QC1203529991 395455001 QC1203529992 QC1203529990 QC1203529848 395455001 QC1203529850 QC1203529847 QC1203529849 395455001 The Qualifiers in this report are defined as follows: N/A N/A 6.72 N/A 17.3 REC% 110 95.9 107 46.5 24.4 122 DUP LCS MB DUP LCS MB MS 395455Workorder: ** < > BD E FA FB H Analyte is a Tracer compound Result is less than value reported Result is greater than value reported Results are either below the MDC or tracer recovery is low %difference of sample and SD is >10%. Sample concentration must meet flagging criteria Failed analysis. Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed invalid for reporting to regulatory agencies Analytical holding time was exceeded U U U RPD% Notes: Page 2 of 3 Page 5 of 11 Analytical Lab Page 28 of 35 QC Summary GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com Parmname Page 3 of 3 Units Anlst Date TimeQCNOMSampleRangeQualREC% 395455Workorder: J K L M M N N/A N1 ND NJ Q R U UI UJ UL X Y ^ h Value is estimated Analyte present. Reported value may be biased high. Actual value is expected to be lower. Analyte present. Reported value may be biased low. Actual value is expected to be higher. M if above MDC and less than LLD REMP Result > MDC/CL and < RDL Metals--The Matrix spike sample recovery is not within specified control limits RPD or %Recovery limits do not apply. See case narrative Analyte concentration is not detected above the detection limit Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier One or more quality control criteria have not been met. Refer to the applicable narrative or DER. Sample results are rejected Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD. Gamma Spectroscopy--Uncertain identification Gamma Spectroscopy--Uncertain identification Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias. Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Other specific qualifiers were required to properly define the results. Consult case narrative. RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry. Preparation or preservation holding time was exceeded N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable. ^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the RL is used to evaluate the DUP result. * Indicates that a Quality Control parameter was not within specifications. For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations. Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the QC Summary. RPD% Page 6 of 11 Analytical Lab Page 29 of 35 Page 7 of 11 Analytical Lab Page 30 of 35 Page 8 of 11 Analytical Lab Page 31 of 35 Technical Case Narrative Duke Energy (DUPO) SDG #: J16040379 Work Order #: 395455 Metals Product: Determination of Metals by ICP-MS Analytical Method: SW846 3010A/6020A Analytical Procedure: GL-MA-E-014 REV# 28 Analytical Batch: 1560300 Preparation Method: SW846 3010A Preparation Procedure: GL-MA-E-008 REV# 18 Preparation Batch: 1560299 The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 395455001 2016010628 1203529609 Method Blank (MB)ICP-MS 1203529610 Laboratory Control Sample (LCS) 1203529699 Laboratory Control Sample (LCS) 1203529613 395455001(2016010628L) Serial Dilution (SD) 1203529611 395455001(2016010628D) Sample Duplicate (DUP) 1203529612 395455001(2016010628S) Matrix Spike (MS) 1203529700 395455001(2016010628S) Matrix Spike (MS) The samples in this SDG were analyzed on an "as received" basis. Data Summary: There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable. Radiochemistry Product: GFPC, Ra228, Liquid Analytical Method: EPA 904.0/SW846 9320 Modified Analytical Procedure: GL-RAD-A-009 REV# 17 Analytical Batch: 1560419 The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 395455001 2016010628 1203529990 Method Blank (MB) 1203529991 395455001(2016010628) Sample Duplicate (DUP) 1203529992 Laboratory Control Sample (LCS) Page 9 of 11 Analytical Lab Page 32 of 35 The samples in this SDG were analyzed on an "as received" basis. Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable, with the following exceptions. Technical Information Recounts Sample 1203529990 (MB) was re-eluted due to a suspected blank false positive. The recount is reported. Product: Lucas Cell, Ra226, liquid Analytical Method: EPA 903.1 Modified Analytical Procedure: GL-RAD-A-008 REV# 14 Analytical Batch: 1560375 The following samples were analyzed using the above methods and analytical procedure(s). GEL Sample ID# Client Sample Identification 395455001 2016010628 1203529847 Method Blank (MB) 1203529848 395455001(2016010628) Sample Duplicate (DUP) 1203529849 395455001(2016010628) Matrix Spike (MS) 1203529850 Laboratory Control Sample (LCS) The samples in this SDG were analyzed on an "as received" basis. Data Summary: All sample data provided in this report met the acceptance criteria specified in the analytical methods and procedures for initial calibration, continuing calibration, instrument controls and process controls where applicable, with the following exceptions. Miscellaneous Information Additional Comments The matrix spike, 1203529849 (2016010628MS), aliquot was reduced to conserve sample volume. Certification Statement Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless otherwise noted in the analytical case narrative. Page 10 of 11 Analytical Lab Page 33 of 35 State Certification Alaska Arkansas CLIA California Colorado Connecticut Delaware DoD ELAP/ ISO17025 A2LA Florida NELAP Foreign Soils Permit Georgia Georgia SDWA Hawaii Idaho Chemistry Idaho Radiochemistry Illinois NELAP Indiana Kansas NELAP Kentucky SDWA Kentucky Wastewater Louisiana NELAP Louisiana SDWA Maryland Massachusetts Michigan Mississippi Nebraska Nevada New Hampshire NELAP New Jersey NELAP New Mexico New York NELAP North Carolina North Carolina SDWA North Dakota Oklahoma Pennsylvania NELAP S.Carolina Radchem South Carolina Chemistry Tennessee Texas NELAP Utah NELAP Vermont Virginia NELAP Washington West Virginia UST-0110 88-0651 42D0904046 2940 SC00012 PH-0169 SC00012 2567.01 E87156 P330-15-00283, P330-15-00253 SC00012 967 SC00012 SC00012 SC00012 200029 C-SC-01 E-10332 90129 90129 03046 (AI33904) LA160006 270 M-SC012 9976 SC00012 NE-OS-26-13 SC000122016-1 205415 SC002 SC00012 11501 233 45709 R-158 9904 68-00485 10120002 10120001 TN 02934 T104704235-16-11 SC000122016-20 VT87156 460202 C780 997404 List of current GEL Certifications as of 22 April 2016 Page 11 of 11 Analytical Lab Page 34 of 35 Analytical Lab Page 35 of 35