NC0000396_App B Lab Reports - CAMA BKGD - J16040290report_20160831

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16040290
Project Name:ASHEVILLE - AB GW ASSESSMENT WATER
Lab Contact:Mary Ann Ogle
Date:4/28/2016
Customer Address:200 CP and L Drive
Customer Name(s):Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
Arden,NC 28704
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Mary Ann Ogle
Page 1 of 67
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016010294 ASHEVILLE 12-Apr-16 8:30 AM illegible MW-17A
2016010297 ASHEVILLE 12-Apr-16 10:18 AM illegible MW-24S
2016010298 ASHEVILLE 12-Apr-16 1:10 PM illegible AMW-3B
2016010299 ASHEVILLE 12-Apr-16 1:33 PM illegible MW-10
2016010300 ASHEVILLE 12-Apr-16 3:46 PM illegible MW-21D
2016010301 ASHEVILLE 12-Apr-16 10:18 AM illegible DUP
2016010302 ASHEVILLE 12-Apr-16 5:00 PM illegible Equipment Blank
7 Total Samples
Page 2 of 67
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:4/28/2016
Electronic Data Deliverable (EDD) Sent Separately
Page 3 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
2016010294
Collection Date:12-Apr-16 8:30 AM
Site:MW-17A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/18/2016 13:48 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.257 mg/L EPA 200.7 04/14/2016 15:44 JJMACKE0.005 1
Barium (Ba)0.165 mg/L EPA 200.7 04/14/2016 15:44 JJMACKE0.005 1
Boron (B)1.88 mg/L EPA 200.7 04/14/2016 15:44 JJMACKE0.05 1
Iron (Fe)20.4 mg/L EPA 200.7 04/14/2016 15:44 JJMACKE0.01 1
Manganese (Mn)5.96 mg/L EPA 200.7 04/14/2016 15:44 JJMACKE0.005 1
Strontium (Sr)0.622 mg/L EPA 200.7 04/14/2016 15:44 JJMACKE0.005 1
Zinc (Zn)0.023 mg/L EPA 200.7 04/14/2016 15:44 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/15/2016 13:15 JAHERMA11
Arsenic (As)1.05 ug/L EPA 200.8 04/15/2016 13:15 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 04/15/2016 13:15 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/15/2016 13:15 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 04/15/2016 13:15 JAHERMA11
Cobalt (Co)19.8 ug/L EPA 200.8 04/15/2016 13:15 JAHERMA11
Copper (Cu)2.37 ug/L EPA 200.8 04/15/2016 13:15 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/15/2016 13:15 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/15/2016 13:15 JAHERMA11
Nickel (Ni)4.19 ug/L EPA 200.8 04/15/2016 13:15 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/15/2016 13:15 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/15/2016 13:15 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/15/2016 13:15 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
TOTAL DISSOLVED SOLIDS
TDS 1200 mg/L SM2540C 04/18/2016 14:25 PARMSTR251
TOTAL SUSPENDED SOLIDS
TSS 10 mg/L SM2540D 04/15/2016 10:50 PARMSTR51
Page 4 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
2016010297
Collection Date:12-Apr-16 10:18 AM
Site:MW-24S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)1.2 mg-N/L EPA 353.2 04/14/2016 12:09 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 14 mg/L EPA 300.0 04/15/2016 13:04 BGN90340.5 5
Sulfate 0.74 mg/L EPA 300.0 04/15/2016 13:04 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/18/2016 13:36 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/18/2016 13:51 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.034 mg/L EPA 200.7 04/14/2016 15:48 JJMACKE0.005 1
Barium (Ba)0.054 mg/L EPA 200.7 04/14/2016 15:48 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/14/2016 15:48 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/14/2016 15:48 JJMACKE0.01 1
Manganese (Mn)0.148 mg/L EPA 200.7 04/14/2016 15:48 JJMACKE0.005 1
Strontium (Sr)0.038 mg/L EPA 200.7 04/14/2016 15:48 JJMACKE0.005 1
Zinc (Zn)0.018 mg/L EPA 200.7 04/14/2016 15:48 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)3.10 mg/L EPA 200.7 04/14/2016 13:36 JJMACKE0.01 1
Magnesium (Mg)3.73 mg/L EPA 200.7 04/14/2016 13:36 JJMACKE0.005 1
Potassium (K)1.54 mg/L EPA 200.7 04/14/2016 13:36 JJMACKE0.1 1
Sodium (Na)3.38 mg/L EPA 200.7 04/14/2016 13:36 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.271 mg/L EPA 200.7 04/14/2016 17:15 JJMACKE0.005 1
Barium (Ba)0.253 mg/L EPA 200.7 04/14/2016 17:15 JJMACKE0.005 1
Boron (B)0.232 mg/L EPA 200.7 04/14/2016 17:15 JJMACKE0.05 1
Iron (Fe)0.235 mg/L EPA 200.7 04/14/2016 17:15B2 JJMACKE0.01 1
Manganese (Mn)0.359 mg/L EPA 200.7 04/14/2016 17:15 JJMACKE0.005 1
Strontium (Sr)0.228 mg/L EPA 200.7 04/14/2016 17:15 JJMACKE0.005 1
Zinc (Zn)0.232 mg/L EPA 200.7 04/14/2016 17:15 JJMACKE0.005 1
Page 5 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
2016010297
Collection Date:12-Apr-16 10:18 AM
Site:MW-24S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/15/2016 13:20 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 04/15/2016 13:20 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 04/15/2016 13:20 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/15/2016 13:20 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 04/15/2016 13:20 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 04/15/2016 13:20 JAHERMA11
Copper (Cu)10.0 ug/L EPA 200.8 04/15/2016 13:20 JAHERMA11
Lead (Pb)1.54 ug/L EPA 200.8 04/15/2016 13:20 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/15/2016 13:20 JAHERMA11
Nickel (Ni)1.01 ug/L EPA 200.8 04/15/2016 13:20 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/15/2016 13:20 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/15/2016 13:20 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/15/2016 13:20 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/19/2016 12:01 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 04/19/2016 12:01 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 04/19/2016 12:01 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 04/19/2016 12:01 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 04/19/2016 12:01 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 04/19/2016 12:01 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 04/19/2016 12:01 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 04/19/2016 12:01 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/19/2016 12:01 SLS256011
Nickel (Ni)1.04 ug/L EPA 200.8 04/19/2016 12:01 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 04/19/2016 12:01 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/19/2016 12:01 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/19/2016 12:01 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 63 mg/L SM2540C 04/18/2016 14:25 PARMSTR251
Total Carbon
TOC 0.214 mg/L SM5310C/EPA9060A 04/14/2016 11:05 GHUTCHI0.1 1
Page 6 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
2016010297
Collection Date:12-Apr-16 10:18 AM
Site:MW-24S
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/15/2016 10:50 PARMSTR51
Page 7 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
2016010298
Collection Date:12-Apr-16 1:10 PM
Site:AMW-3B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.192 mg-N/L EPA 353.2 04/14/2016 12:10 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 0.60 mg/L EPA 300.0 04/15/2016 11:19 BGN90340.1 1
Sulfate 1.1 mg/L EPA 300.0 04/15/2016 11:19 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/18/2016 13:38 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/18/2016 13:53 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 04/14/2016 15:52 JJMACKE0.005 1
Barium (Ba)0.006 mg/L EPA 200.7 04/14/2016 15:52 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/14/2016 15:52 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/14/2016 15:52 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 04/14/2016 15:52 JJMACKE0.005 1
Strontium (Sr)0.056 mg/L EPA 200.7 04/14/2016 15:52 JJMACKE0.005 1
Zinc (Zn)0.018 mg/L EPA 200.7 04/14/2016 15:52 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)6.07 mg/L EPA 200.7 04/14/2016 13:40 JJMACKE0.01 1
Magnesium (Mg)1.83 mg/L EPA 200.7 04/14/2016 13:40 JJMACKE0.005 1
Potassium (K)1.63 mg/L EPA 200.7 04/14/2016 13:40 JJMACKE0.1 1
Sodium (Na)5.18 mg/L EPA 200.7 04/14/2016 13:40 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.017 mg/L EPA 200.7 04/14/2016 17:26 JJMACKE0.005 1
Barium (Ba)0.007 mg/L EPA 200.7 04/14/2016 17:26 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/14/2016 17:26 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/14/2016 17:26B2 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 04/14/2016 17:26 JJMACKE0.005 1
Strontium (Sr)0.056 mg/L EPA 200.7 04/14/2016 17:26 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/14/2016 17:26 JJMACKE0.005 1
Page 8 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
2016010298
Collection Date:12-Apr-16 1:10 PM
Site:AMW-3B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/14/2016 22:54 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 04/14/2016 22:54 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 04/14/2016 22:54 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2016 22:54 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 04/14/2016 22:54 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 04/14/2016 22:54 JAHERMA11
Copper (Cu)11.5 ug/L EPA 200.8 04/14/2016 22:54 JAHERMA11
Lead (Pb)1.53 ug/L EPA 200.8 04/14/2016 22:54 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/14/2016 22:54 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 04/14/2016 22:54 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/14/2016 22:54 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/14/2016 22:54 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/14/2016 22:54 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/19/2016 11:38 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 04/19/2016 11:38 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 04/19/2016 11:38 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 04/19/2016 11:38 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 04/19/2016 11:38 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 04/19/2016 11:38 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 04/19/2016 11:38 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 04/19/2016 11:38 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/19/2016 11:38 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 04/19/2016 11:38 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 04/19/2016 11:38 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/19/2016 11:38 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/19/2016 11:38 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 67 mg/L SM2540C 04/18/2016 14:25 PARMSTR251
Total Carbon
TOC < 0.1 mg/L SM5310C/EPA9060A 04/14/2016 11:05 GHUTCHI0.1 1
Page 9 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
2016010298
Collection Date:12-Apr-16 1:10 PM
Site:AMW-3B
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/15/2016 10:50 PARMSTR51
Page 10 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
2016010299
Collection Date:12-Apr-16 1:33 PM
Site:MW-10
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.104 mg-N/L EPA 353.2 04/14/2016 12:11 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 12 mg/L EPA 300.0 04/15/2016 13:21 BGN90340.5 5
Sulfate 0.43 mg/L EPA 300.0 04/15/2016 13:21 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/18/2016 13:29 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/18/2016 13:55 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.037 mg/L EPA 200.7 04/14/2016 15:56 JJMACKE0.005 1
Barium (Ba)0.051 mg/L EPA 200.7 04/14/2016 15:56 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/14/2016 15:56 JJMACKE0.05 1
Iron (Fe)0.260 mg/L EPA 200.7 04/14/2016 15:56 JJMACKE0.01 1
Manganese (Mn)0.241 mg/L EPA 200.7 04/14/2016 15:56 JJMACKE0.005 1
Strontium (Sr)0.026 mg/L EPA 200.7 04/14/2016 15:56 JJMACKE0.005 1
Zinc (Zn)0.034 mg/L EPA 200.7 04/14/2016 15:56 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)2.30 mg/L EPA 200.7 04/14/2016 13:44 JJMACKE0.01 1
Magnesium (Mg)2.58 mg/L EPA 200.7 04/14/2016 13:44 JJMACKE0.005 1
Potassium (K)1.33 mg/L EPA 200.7 04/14/2016 13:44 JJMACKE0.1 1
Sodium (Na)4.15 mg/L EPA 200.7 04/14/2016 13:44 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.039 mg/L EPA 200.7 04/14/2016 17:30 JJMACKE0.005 1
Barium (Ba)0.050 mg/L EPA 200.7 04/14/2016 17:30 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/14/2016 17:30 JJMACKE0.05 1
Iron (Fe)0.054 mg/L EPA 200.7 04/14/2016 17:30B2 JJMACKE0.01 1
Manganese (Mn)0.142 mg/L EPA 200.7 04/14/2016 17:30 JJMACKE0.005 1
Strontium (Sr)0.024 mg/L EPA 200.7 04/14/2016 17:30 JJMACKE0.005 1
Zinc (Zn)0.014 mg/L EPA 200.7 04/14/2016 17:30 JJMACKE0.005 1
Page 11 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
2016010299
Collection Date:12-Apr-16 1:33 PM
Site:MW-10
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/15/2016 13:25 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 04/15/2016 13:25 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 04/15/2016 13:25 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/15/2016 13:25 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 04/15/2016 13:25 JAHERMA11
Cobalt (Co)2.99 ug/L EPA 200.8 04/15/2016 13:25 JAHERMA11
Copper (Cu)13.8 ug/L EPA 200.8 04/15/2016 13:25 JAHERMA11
Lead (Pb)1.92 ug/L EPA 200.8 04/15/2016 13:25 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/15/2016 13:25 JAHERMA11
Nickel (Ni)2.89 ug/L EPA 200.8 04/15/2016 13:25 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/15/2016 13:25 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/15/2016 13:25 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/15/2016 13:25 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/19/2016 12:07 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 04/19/2016 12:07 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 04/19/2016 12:07 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 04/19/2016 12:07 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 04/19/2016 12:07 SLS256011
Cobalt (Co)2.12 ug/L EPA 200.8 04/19/2016 12:07 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 04/19/2016 12:07 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 04/19/2016 12:07 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/19/2016 12:07 SLS256011
Nickel (Ni)2.44 ug/L EPA 200.8 04/19/2016 12:07 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 04/19/2016 12:07 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/19/2016 12:07 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/19/2016 12:07 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 46 mg/L SM2540C 04/18/2016 14:25 PARMSTR251
Total Carbon
TOC 0.595 mg/L SM5310C/EPA9060A 04/14/2016 11:05 GHUTCHI0.1 1
Page 12 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
2016010299
Collection Date:12-Apr-16 1:33 PM
Site:MW-10
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/15/2016 10:50 PARMSTR51
Page 13 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
2016010300
Collection Date:12-Apr-16 3:46 PM
Site:MW-21D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/14/2016 12:13 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 28 mg/L EPA 300.0 04/15/2016 11:52 BGN90340.5 5
Sulfate 34 mg/L EPA 300.0 04/15/2016 11:52 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/18/2016 13:41 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/18/2016 14:07 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.019 mg/L EPA 200.7 04/14/2016 16:08 JJMACKE0.005 1
Barium (Ba)0.043 mg/L EPA 200.7 04/14/2016 16:08 JJMACKE0.005 1
Boron (B)0.082 mg/L EPA 200.7 04/14/2016 16:08 JJMACKE0.05 1
Iron (Fe)1.63 mg/L EPA 200.7 04/14/2016 16:08 JJMACKE0.01 1
Manganese (Mn)0.562 mg/L EPA 200.7 04/14/2016 16:08 JJMACKE0.005 1
Strontium (Sr)0.073 mg/L EPA 200.7 04/14/2016 16:08 JJMACKE0.005 1
Zinc (Zn)0.023 mg/L EPA 200.7 04/14/2016 16:08 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)9.38 mg/L EPA 200.7 04/14/2016 13:48 JJMACKE0.01 1
Magnesium (Mg)3.84 mg/L EPA 200.7 04/14/2016 13:48 JJMACKE0.005 1
Potassium (K)1.40 mg/L EPA 200.7 04/14/2016 13:48 JJMACKE0.1 1
Sodium (Na)15.0 mg/L EPA 200.7 04/14/2016 13:48 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.024 mg/L EPA 200.7 04/14/2016 17:34 JJMACKE0.005 1
Barium (Ba)0.045 mg/L EPA 200.7 04/14/2016 17:34 JJMACKE0.005 1
Boron (B)0.079 mg/L EPA 200.7 04/14/2016 17:34 JJMACKE0.05 1
Iron (Fe)1.98 mg/L EPA 200.7 04/14/2016 17:34B2 JJMACKE0.01 1
Manganese (Mn)0.552 mg/L EPA 200.7 04/14/2016 17:34 JJMACKE0.005 1
Strontium (Sr)0.072 mg/L EPA 200.7 04/14/2016 17:34 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/14/2016 17:34 JJMACKE0.005 1
Page 14 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
2016010300
Collection Date:12-Apr-16 3:46 PM
Site:MW-21D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/15/2016 16:51 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 04/15/2016 16:51 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 04/15/2016 16:51 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/15/2016 16:51 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 04/15/2016 16:51 JAHERMA11
Cobalt (Co)2.35 ug/L EPA 200.8 04/15/2016 16:51 JAHERMA11
Copper (Cu)9.42 ug/L EPA 200.8 04/15/2016 16:51 JAHERMA11
Lead (Pb)1.82 ug/L EPA 200.8 04/15/2016 16:51 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/15/2016 16:51 JAHERMA11
Nickel (Ni)1.81 ug/L EPA 200.8 04/15/2016 16:51 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/15/2016 16:51 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/15/2016 16:51 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/15/2016 16:51 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/19/2016 12:13 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 04/19/2016 12:13 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 04/19/2016 12:13 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 04/19/2016 12:13 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 04/19/2016 12:13 SLS256011
Cobalt (Co)1.63 ug/L EPA 200.8 04/19/2016 12:13 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 04/19/2016 12:13 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 04/19/2016 12:13 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/19/2016 12:13 SLS256011
Nickel (Ni)1.01 ug/L EPA 200.8 04/19/2016 12:13 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 04/19/2016 12:13 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/19/2016 12:13 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/19/2016 12:13 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 130 mg/L SM2540C 04/18/2016 14:25 PARMSTR251
Total Carbon
TOC 0.298 mg/L SM5310C/EPA9060A 04/14/2016 11:05 GHUTCHI0.1 1
Page 15 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
2016010300
Collection Date:12-Apr-16 3:46 PM
Site:MW-21D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/15/2016 10:50 PARMSTR51
Page 16 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
2016010301
Collection Date:12-Apr-16 10:18 AM
Site:DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)1.2 mg-N/L EPA 353.2 04/14/2016 12:14 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 15 mg/L EPA 300.0 04/15/2016 13:37 BGN90340.5 5
Sulfate 0.78 mg/L EPA 300.0 04/15/2016 13:37 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/18/2016 13:43 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/18/2016 14:15 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.033 mg/L EPA 200.7 04/14/2016 16:19 JJMACKE0.005 1
Barium (Ba)0.057 mg/L EPA 200.7 04/14/2016 16:19 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/14/2016 16:19 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/14/2016 16:19 JJMACKE0.01 1
Manganese (Mn)0.149 mg/L EPA 200.7 04/14/2016 16:19 JJMACKE0.005 1
Strontium (Sr)0.040 mg/L EPA 200.7 04/14/2016 16:19 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/14/2016 16:19 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)3.07 mg/L EPA 200.7 04/14/2016 13:52 JJMACKE0.01 1
Magnesium (Mg)3.68 mg/L EPA 200.7 04/14/2016 13:52 JJMACKE0.005 1
Potassium (K)1.54 mg/L EPA 200.7 04/14/2016 13:52 JJMACKE0.1 1
Sodium (Na)3.34 mg/L EPA 200.7 04/14/2016 13:52 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.055 mg/L EPA 200.7 04/14/2016 17:38 JJMACKE0.005 1
Barium (Ba)0.059 mg/L EPA 200.7 04/14/2016 17:38 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/14/2016 17:38 JJMACKE0.05 1
Iron (Fe)0.016 mg/L EPA 200.7 04/14/2016 17:38B2 JJMACKE0.01 1
Manganese (Mn)0.153 mg/L EPA 200.7 04/14/2016 17:38 JJMACKE0.005 1
Strontium (Sr)0.040 mg/L EPA 200.7 04/14/2016 17:38 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/14/2016 17:38 JJMACKE0.005 1
Page 17 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
2016010301
Collection Date:12-Apr-16 10:18 AM
Site:DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/15/2016 16:57 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 04/15/2016 16:57 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 04/15/2016 16:57 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/15/2016 16:57 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 04/15/2016 16:57 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 04/15/2016 16:57 JAHERMA11
Copper (Cu)2.57 ug/L EPA 200.8 04/15/2016 16:57 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/15/2016 16:57 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/15/2016 16:57 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 04/15/2016 16:57 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/15/2016 16:57 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/15/2016 16:57 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/15/2016 16:57 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/19/2016 12:36 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 04/19/2016 12:36 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 04/19/2016 12:36 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 04/19/2016 12:36 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 04/19/2016 12:36 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 04/19/2016 12:36 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 04/19/2016 12:36 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 04/19/2016 12:36 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/19/2016 12:36 SLS256011
Nickel (Ni)1.05 ug/L EPA 200.8 04/19/2016 12:36 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 04/19/2016 12:36 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/19/2016 12:36 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/19/2016 12:36 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 57 mg/L SM2540C 04/18/2016 14:25 PARMSTR251
Total Carbon
TOC 0.207 mg/L SM5310C/EPA9060A 04/14/2016 11:05 GHUTCHI0.1 1
Page 18 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
2016010301
Collection Date:12-Apr-16 10:18 AM
Site:DUP
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/15/2016 10:50 PARMSTR51
Page 19 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
2016010302
Collection Date:12-Apr-16 5:00 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/14/2016 12:15 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 04/15/2016 09:37 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 04/15/2016 09:37 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/18/2016 13:46 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/18/2016 14:17 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 04/14/2016 16:24 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 04/14/2016 16:24 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/14/2016 16:24 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/14/2016 16:24 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 04/14/2016 16:24 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 04/14/2016 16:24 JJMACKE0.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 04/14/2016 16:24 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.012 mg/L EPA 200.7 04/14/2016 13:55 JJMACKE0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 04/14/2016 13:55 JJMACKE0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 04/14/2016 13:55 JJMACKE0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 04/14/2016 13:55 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 04/14/2016 17:42 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 04/14/2016 17:42 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/14/2016 17:42 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/14/2016 17:42B2 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 04/14/2016 17:42 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 04/14/2016 17:42 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/14/2016 17:42 JJMACKE0.005 1
Page 20 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
2016010302
Collection Date:12-Apr-16 5:00 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/15/2016 13:58 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 04/15/2016 13:58 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 04/15/2016 13:58 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/15/2016 13:58 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 04/15/2016 13:58 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 04/15/2016 13:58 JAHERMA11
Copper (Cu)5.00 ug/L EPA 200.8 04/15/2016 13:58 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/15/2016 13:58 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/15/2016 13:58 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 04/15/2016 13:58 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/15/2016 13:58 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/15/2016 13:58 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/15/2016 13:58 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/19/2016 12:42 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 04/19/2016 12:42 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 04/19/2016 12:42 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 04/19/2016 12:42 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 04/19/2016 12:42 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 04/19/2016 12:42 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 04/19/2016 12:42 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 04/19/2016 12:42 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/19/2016 12:42 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 04/19/2016 12:42 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 04/19/2016 12:42 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/19/2016 12:42 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/19/2016 12:42 SLS25600.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Total Carbon
TOC 0.236 mg/L SM5310C/EPA9060A 04/14/2016 11:05 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/15/2016 10:50 PARMSTR51
Qualifiers:
Page 21 of 67
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040290
B2 Target analyte was detected in blank(s) at a concentration greater than ½ the reporting limit but less than the
reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.
Page 22 of 67

April 21, 2016

Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment Water
Work Order: 395205
SDG: J16040290

Dear Mary :
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on April 13, 2016. This original data report has been prepared and reviewed in accordance
with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 1142110 DPNNGO
Enclosures
Page 1 of 19
Page 23 of 67
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO002 Duke Energy
Client SDG: J16040290 GEL Work Order: 395205
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
for
Page 2 of 19
Page 24 of 67
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: April 21, 2016
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1559603
1559603
1559603
1559959
1559634
1424
1434
1557
1506
0830
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
04/19/16
04/15/16
04/20/16
04/20/16
04/19/16
SKJ
SKJ
PRB
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
395205001
Water
12-APR-16 08:30
13-APR-16
2016010294 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"102 (15%-125%)
0.000067
0.00001
0.00001
0.00001
1.53
0.427
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 04/13/16 15596012100JP1
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
5
Method Description
1
2
3
4
5
SW846 3010A/6020A
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
J
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.0000945
ND
ND
ND
2.37
0.891
NominalResult
RLDL
Notes:
Page 3 of 19
Page 25 of 67
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: April 21, 2016
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1559603
1559603
1559603
1559959
1559634
1434
1443
1609
1506
0830
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
04/19/16
04/15/16
04/20/16
04/20/16
04/19/16
SKJ
SKJ
PRB
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
395205002
Water
12-APR-16 10:18
13-APR-16
2016010297 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"92.9 (15%-125%)
0.000067
0.00001
0.00001
0.00001
2.15
0.518
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 04/13/16 15596012100JP1
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
5
Method Description
1
2
3
4
5
SW846 3010A/6020A
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
J
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.000168
ND
ND
ND
ND
1.76
NominalResult
RLDL
Notes:
Page 4 of 19
Page 26 of 67
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: April 21, 2016
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1559603
1559603
1559603
1559959
1559634
1435
1444
1610
1506
0900
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
04/19/16
04/15/16
04/20/16
04/20/16
04/19/16
SKJ
SKJ
PRB
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
395205003
Water
12-APR-16 13:10
13-APR-16
2016010298 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"98.6 (15%-125%)
0.000067
0.00001
0.00001
0.00001
1.23
0.441
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 04/13/16 15596012100JP1
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
5
Method Description
1
2
3
4
5
SW846 3010A/6020A
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
7.41
NominalResult
RLDL
Notes:
Page 5 of 19
Page 27 of 67
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: April 21, 2016
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1559603
1559603
1559603
1559959
1559634
1437
1446
1612
1506
0900
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
04/19/16
04/15/16
04/20/16
04/20/16
04/19/16
SKJ
SKJ
PRB
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
395205004
Water
12-APR-16 13:33
13-APR-16
2016010299 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"100 (15%-125%)
0.000067
0.00001
0.00001
0.00001
1.26
0.439
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 04/13/16 15596012100JP1
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
5
Method Description
1
2
3
4
5
SW846 3010A/6020A
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
1.17
NominalResult
RLDL
Notes:
Page 6 of 19
Page 28 of 67
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: April 21, 2016
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1559603
1559603
1559603
1559959
1559634
1438
1448
1614
1506
0900
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
04/19/16
04/15/16
04/20/16
04/20/16
04/19/16
SKJ
SKJ
PRB
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
395205005
Water
12-APR-16 15:46
13-APR-16
2016010300 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"98.5 (15%-125%)
0.000067
0.00001
0.00001
0.00001
2.24
0.535
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 04/13/16 15596012100JP1
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
5
Method Description
1
2
3
4
5
SW846 3010A/6020A
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
2.63
2.35
NominalResult
RLDL
Notes:
Page 7 of 19
Page 29 of 67
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: April 21, 2016
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1559603
1559603
1559603
1559959
1559634
1440
1449
1615
1506
0900
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
04/19/16
04/15/16
04/20/16
04/20/16
04/19/16
SKJ
SKJ
PRB
AXM6
LXP1
0.0002
0.00005
0.00005
0.00005
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
395205006
Water
12-APR-16 10:18
13-APR-16
2016010301 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"99.7 (15%-125%)
0.000067
0.00001
0.00001
0.00001
1.75
0.446
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 04/13/16 15596012100JP1
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
5
Method Description
1
2
3
4
5
SW846 3010A/6020A
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
3.42
2.54
NominalResult
RLDL
Notes:
Page 8 of 19
Page 30 of 67
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1559603Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Parmname
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, North Carolina
April 21, 2016Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
Anlst Date Time
SKJ
PRB
SKJ
PRB
SKJ
PRB
SKJ
PRB
SKJ
04/15/16 14:35
04/20/16 15:58
04/19/16 14:25
04/19/16 14:22
04/15/16 14:32
04/20/16 15:55
04/15/16 14:31
04/20/16 15:53
04/19/16 14:21
04/19/16 14:27
04/15/16 14:37
04/20/16 16:00
04/15/16 14:38
QC
ND
ND
ND
ND
0.0529
0.000504
0.00057
0.00473
ND
ND
ND
ND
0.0527
0.000483
0.000553
0.00483
ND
NOM Sample
ND
ND
ND
0.0000945
0.0000945
ND
ND
ND
ND
Range
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
U
U
U
QC1203527741 395205001
QC1203527740
QC1203527778
QC1203527739
QC1203527742 395205001
QC1203527779 395205001
QC1203527743 395205001
N/A
N/A
N/A
200
N/A
REC%
107
101
104
94.5
106
96.6
101
96.5
0.0496
0.0005
0.00055
0.005
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
MS
MS
SDILT
395205Workorder:
Mail Code: MGO3A2
U
U
U
J
J
U
U
U
U
^
RPD%
Page 1 of 3
Page 9 of 19
Page 31 of 67
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
Rad Ra-226
1559603
1559959
1559634
Batch
Batch
Batch
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-228
Radium-228
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
ug/L
ug/L
ug/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
PRB
SKJ
AXM6
LXP1
04/20/16 16:02
04/19/16 14:28
04/20/16 15:09
04/20/16 15:06
04/20/16 15:09
04/19/16 09:00
04/19/16 09:30
04/19/16 09:00
04/19/16 09:30
QC
ND
ND
ND
1.68
84.0
0.413
0.908
30.4
0.319
128
NOM Sample
ND
ND
0.0945
3.42
0.747
0.747
Range
(0%-10%)
(0%-10%)
(0% - 100%)
(75%-125%)
(0% - 100%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
QC1203528625 395205006
QC1203528626
QC1203528624
QC1203527795 395096001
QC1203527797
QC1203527794
QC1203527796 395096001
The Qualifiers in this report are defined as follows:
N/A
N/A
N/A
68.5
19.6
REC%
90.3
125
104
93.0
24.4
122
DUP
LCS
MB
DUP
LCS
MB
MS
395205Workorder:
**
<
>
BD
E
FA
FB
H
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
U
U
J
RPD%
Notes:
Page 2 of 3
Page 10 of 19
Page 32 of 67
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 3 of 3
Units Anlst Date TimeQCNOMSampleRangeQualREC%
395205Workorder:
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
U
UI
UJ
UL
X
Y
^
h
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
Page 11 of 19
Page 33 of 67
Page 12 of 19
Page 34 of 67
Page 13 of 19
Page 35 of 67
Page 14 of 19
Page 36 of 67
Page 15 of 19
Page 37 of 67

Technical Case Narrative
Duke Energy (DUPO)
SDG #: J16040290
Work Order #: 395205

Metals

Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1559603

Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1559601
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
395205001 2016010294
395205002 2016010297
395205003 2016010298
395205004 2016010299
395205005 2016010300
395205006 2016010301
1203527739 Method Blank (MB)ICP-MS
1203527740 Laboratory Control Sample (LCS)
1203527778 Laboratory Control Sample (LCS)
1203527743 395205001(2016010294L) Serial Dilution (SD)
1203527741 395205001(2016010294D) Sample Duplicate (DUP)
1203527742 395205001(2016010294S) Matrix Spike (MS)
1203527779 395205001(2016010294S) Matrix Spike (MS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Radiochemistry

Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1559959
Page 16 of 19
Page 38 of 67
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
395205001 2016010294
395205002 2016010297
395205003 2016010298
395205004 2016010299
395205005 2016010300
395205006 2016010301
1203528624 Method Blank (MB)
1203528625 395205006(2016010301) Sample Duplicate (DUP)
1203528626 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1559634
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
395205001 2016010294
395205002 2016010297
395205003 2016010298
395205004 2016010299
395205005 2016010300
395205006 2016010301
1203527794 Method Blank (MB)
1203527795 395096001(2016010154) Sample Duplicate (DUP)
1203527796 395096001(2016010154) Matrix Spike (MS)
1203527797 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Miscellaneous Information

Page 17 of 19
Page 39 of 67
Additional Comments
The matrix spike, 1203527796 (2016010154MS), aliquot was reduced to conserve sample volume.

Certification Statement

Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Page 18 of 19
Page 40 of 67
State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
North Dakota
Oklahoma
Pennsylvania NELAP
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-0110
88-0651
42D0904046
2940
SC00012
PH-0169
SC00012
2567.01
E87156
P330-15-00283, P330-15-00253
SC00012
967
SC00012
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA160006
270
M-SC012
9976
SC00012
NE-OS-26-13
SC000122016-1
205415
SC002
SC00012
11501
233
45709
R-158
9904
68-00485
10120002
10120001
TN 02934
T104704235-16-11
SC000122016-20
VT87156
460202
C780
997404
List of current GEL Certifications as of 21 April 2016
Page 19 of 19
Page 41 of 67
#=CL#
April 20, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92293592
92293592
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16040290
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on April 13, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
Vials received with no headspace, liquid poured off before analysis.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Mary Ann Ogle, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92293592
J16040290
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
525 N 8th Street, Salina, KS 67401
A2LA Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA #: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
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Nevada Certification: FL NELAC Reciprocity
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North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
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South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
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Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92293592
J16040290
Lab ID Sample ID Matrix Date Collected Date Received
92293592001 2016010294 Water 04/12/16 08:30 04/13/16 10:30
92293592002 2016010297 Water 04/12/16 10:18 04/13/16 10:30
92293592003 2016010298 Water 04/12/16 13:10 04/13/16 10:30
92293592004 2016010299 Water 04/12/16 13:33 04/13/16 10:30
92293592005 2016010300 Water 04/12/16 15:46 04/13/16 10:30
92293592006 2016010301 Water 04/12/16 10:18 04/13/16 10:30
92293592007 2016010302 Water 04/12/16 17:00 04/13/16 10:30
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 44 of 67
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92293592
J16040290
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92293592001 2016010294 RSK 175 1 PASI-MDR1
92293592002 2016010297 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92293592003 2016010298 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92293592004 2016010299 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92293592005 2016010300 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92293592006 2016010301 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AMJP
EPA 218.7 1 PASI-OTK1
92293592007 2016010302 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AMJP
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92293592
J16040290
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92293592002 2016010297
Alkalinity,Bicarbonate (CaCO3)15.8 mg/L 04/16/16 10:105.0SM 2320B
Alkalinity, Total as CaCO3 15.8 mg/L 04/16/16 10:105.0SM 2320B
Chromium, Hexavalent 0.26 ug/L 04/15/16 19:350.030EPA 218.7
92293592003 2016010298
Alkalinity,Bicarbonate (CaCO3)33.1 mg/L 04/16/16 10:205.0SM 2320B
Alkalinity, Total as CaCO3 33.1 mg/L 04/16/16 10:205.0SM 2320B
Chromium, Hexavalent 0.18 ug/L 04/15/16 19:480.030EPA 218.7
92293592004 2016010299
Methane 32.7 ug/L 04/15/16 16:3710.0RSK 175
Alkalinity,Bicarbonate (CaCO3)10.8 mg/L 04/16/16 10:465.0SM 2320B
Alkalinity, Total as CaCO3 10.8 mg/L 04/16/16 10:465.0SM 2320B
Chromium, Hexavalent 0.12 ug/L 04/15/16 20:010.030EPA 218.7
92293592006 2016010301
Alkalinity,Bicarbonate (CaCO3)6.4 mg/L 04/16/16 11:145.0SM 2320B
Alkalinity, Total as CaCO3 6.4 mg/L 04/16/16 11:145.0SM 2320B
Chromium, Hexavalent 0.26 ug/L 04/15/16 20:270.030EPA 218.7
REPORT OF LABORATORY ANALYSIS
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Page 46 of 67
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92293592
J16040290
Method:
Client:Duke Energy
RSK 175
Date:April 20, 2016
Description:RSK 175 AIR Headspace
General Information:
7 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92293592
J16040290
Method:
Client:Duke Energy
SM 2320B
Date:April 20, 2016
Description:2320B Alkalinity
General Information:
6 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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Page 48 of 67
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92293592
J16040290
Method:
Client:Duke Energy
SM 4500-S2D
Date:April 20, 2016
Description:4500S2D Sulfide Water
General Information:
6 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 49 of 67
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92293592
J16040290
Method:
Client:Duke Energy
EPA 218.7
Date:April 20, 2016
Description:Hexavalent Chromium by IC
General Information:
5 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 50 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92293592
J16040290
Sample:2016010294 Lab ID:92293592001 Collected:04/12/16 08:30 Received:04/13/16 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 04/15/16 16:05 74-82-810.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/20/2016 11:21 AM
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Page 51 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92293592
J16040290
Sample:2016010297 Lab ID:92293592002 Collected:04/12/16 10:18 Received:04/13/16 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 04/15/16 16:21 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)15.8 mg/L 04/16/16 10:105.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/16/16 10:105.0 1
Alkalinity, Total as CaCO3 15.8 mg/L 04/16/16 10:105.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/19/16 11:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.26 ug/L 04/15/16 19:35 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/20/2016 11:21 AM
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Page 11 of 25
Page 52 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92293592
J16040290
Sample:2016010298 Lab ID:92293592003 Collected:04/12/16 13:10 Received:04/13/16 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 04/15/16 16:29 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)33.1 mg/L 04/16/16 10:205.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/16/16 10:205.0 1
Alkalinity, Total as CaCO3 33.1 mg/L 04/16/16 10:205.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/19/16 11:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.18 ug/L 04/15/16 19:48 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/20/2016 11:21 AM
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Page 53 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92293592
J16040290
Sample:2016010299 Lab ID:92293592004 Collected:04/12/16 13:33 Received:04/13/16 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 32.7 ug/L 04/15/16 16:37 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)10.8 mg/L 04/16/16 10:465.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/16/16 10:465.0 1
Alkalinity, Total as CaCO3 10.8 mg/L 04/16/16 10:465.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/19/16 11:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.12 ug/L 04/15/16 20:01 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/20/2016 11:21 AM
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[phone]
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Page 54 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92293592
J16040290
Sample:2016010300 Lab ID:92293592005 Collected:04/12/16 15:46 Received:04/13/16 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 04/15/16 16:45 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 04/16/16 11:005.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/16/16 11:005.0 1
Alkalinity, Total as CaCO3 ND mg/L 04/16/16 11:005.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/19/16 11:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 04/15/16 20:14 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/20/2016 11:21 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 55 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92293592
J16040290
Sample:2016010301 Lab ID:92293592006 Collected:04/12/16 10:18 Received:04/13/16 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 04/15/16 16:54 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)6.4 mg/L 04/16/16 11:145.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/16/16 11:145.0 1
Alkalinity, Total as CaCO3 6.4 mg/L 04/16/16 11:145.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/19/16 11:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.26 ug/L 04/15/16 20:27 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/20/2016 11:21 AM
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Page 56 of 67
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92293592
J16040290
Sample:2016010302 Lab ID:92293592007 Collected:04/12/16 17:00 Received:04/13/16 10:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 04/15/16 17:02 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 04/17/16 12:165.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/17/16 12:165.0 1
Alkalinity, Total as CaCO3 ND mg/L 04/17/16 12:165.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/19/16 11:30 18496-25-80.10 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/20/2016 11:21 AM
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Page 57 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92293592
J16040290
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/25707
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92293592001, 92293592002, 92293592003, 92293592004, 92293592005, 92293592006, 92293592007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2232579
Associated Lab Samples:92293592001, 92293592002, 92293592003, 92293592004, 92293592005, 92293592006, 92293592007
Matrix:Water
Analyzed
Methane ug/L ND 10.0 04/15/16 14:18
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2232580LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2232581
Methane ug/L 59.660.7 98 85-1159658.0 3 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
10344553008
2234671SAMPLE DUPLICATE:
Methane ug/L 1.7J 20ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92293592001
2234672SAMPLE DUPLICATE:
Methane ug/L 4.8J 20ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/20/2016 11:21 AM
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Page 58 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92293592
J16040290
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/44279
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92293592002, 92293592003, 92293592004, 92293592005, 92293592006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1711312
Associated Lab Samples:92293592002, 92293592003, 92293592004, 92293592005, 92293592006
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 04/15/16 23:44
Alkalinity, Total as CaCO3 mg/L ND 5.0 04/15/16 23:44
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 04/15/16 23:44
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1711313LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 50.150 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1711314MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293530004
1711315
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 90 80-12091 1 2550ND44.8 45.3
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1711316MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293539005
1711317
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 100 80-120101 1 255014.4 64.3 64.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/20/2016 11:21 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 25
Page 59 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92293592
J16040290
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/44287
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92293592007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1711827
Associated Lab Samples:92293592007
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 04/17/16 11:55
Alkalinity, Total as CaCO3 mg/L ND 5.0 04/17/16 11:55
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 04/17/16 11:55
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1711828LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 49.250 98 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1711829MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293592007
1711830
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 97 80-12097 0 2550ND48.6 48.6
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1711831MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293750005
1711832
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 97 80-12098 0 2550ND48.7 48.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/20/2016 11:21 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 25
Page 60 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92293592
J16040290
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/44329
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92293592002, 92293592003, 92293592004, 92293592005, 92293592006, 92293592007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1713758
Associated Lab Samples:92293592002, 92293592003, 92293592004, 92293592005, 92293592006, 92293592007
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 04/19/16 11:30
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1713759LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.53.5 106 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1713760MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293519001
1713761
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 104 90-110104 0 10.5ND 0.52 0.52
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1713762MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293592006
1713763
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 104 90-110104 0 10.5ND 0.52 0.52
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/20/2016 11:21 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 25
Page 61 of 67
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92293592
J16040290
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/56904
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92293592002, 92293592003, 92293592004, 92293592005, 92293592006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1543057
Associated Lab Samples:92293592002, 92293592003, 92293592004, 92293592005, 92293592006
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 04/15/16 17:51
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1543058LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.074.075 98 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1543059MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293516003
1543060
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .025 91 85-115103 4 20.0250.061 0.083 0.086
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/20/2016 11:21 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 25
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92293592
J16040290
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - MinneapolisPASI-M
Pace Analytical Services - Ormond BeachPASI-O
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/20/2016 11:21 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 25
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92293592
J16040290
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92293592001 AIR/257072016010294RSK 175
92293592002 AIR/257072016010297RSK 175
92293592003 AIR/257072016010298RSK 175
92293592004 AIR/257072016010299RSK 175
92293592005 AIR/257072016010300RSK 175
92293592006 AIR/257072016010301RSK 175
92293592007 AIR/257072016010302RSK 175
92293592002 WET/442792016010297SM 2320B
92293592003 WET/442792016010298SM 2320B
92293592004 WET/442792016010299SM 2320B
92293592005 WET/442792016010300SM 2320B
92293592006 WET/442792016010301SM 2320B
92293592007 WET/442872016010302SM 2320B
92293592002 WET/443292016010297SM 4500-S2D
92293592003 WET/443292016010298SM 4500-S2D
92293592004 WET/443292016010299SM 4500-S2D
92293592005 WET/443292016010300SM 4500-S2D
92293592006 WET/443292016010301SM 4500-S2D
92293592007 WET/443292016010302SM 4500-S2D
92293592002 WETA/569042016010297EPA 218.7
92293592003 WETA/569042016010298EPA 218.7
92293592004 WETA/569042016010299EPA 218.7
92293592005 WETA/569042016010300EPA 218.7
92293592006 WETA/569042016010301EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/20/2016 11:21 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 25
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