NC0000396_App B Lab Reports - CAMA BKGD - J16040242report_20160831

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16040242
Project Name:ASHEVILLE - AB GW ASSESSMENT WATER
Lab Contact:Mary Ann Ogle
Date:4/21/2016
Customer Address:200 CP and L Drive
Customer Name(s):Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
Arden,NC 28704
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Mary Ann Ogle
Page 1 of 60
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016010154 ASHEVILLE 11-Apr-16 10:02 AM Synterra MW-18D
2016010155 ASHEVILLE 11-Apr-16 10:28 AM Synterra MW-18BR
2016010156 ASHEVILLE 11-Apr-16 9:00 AM Synterra MW-17A
2016010157 ASHEVILLE 11-Apr-16 1:17 PM Synterra MW-22D
2016010158 ASHEVILLE 11-Apr-16 1:42 PM Synterra MW-22BR
2016010159 ASHEVILLE 11-Apr-16 2:45 PM Synterra MW-17A
2016010160 ASHEVILLE 11-Apr-16 4:20 PM Synterra Filter Blank 3
2016010161 ASHEVILLE 11-Apr-16 4:20 PM Synterra Equipment Blank 3
8 Total Samples
Page 2 of 60
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:4/21/2016
Electronic Data Deliverable (EDD) Sent Separately
Page 3 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
2016010154
Collection Date:11-Apr-16 10:02 AM
Site:MW-18D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.037 mg-N/L EPA 353.2 04/14/2016 12:16 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 97 mg/L EPA 300.0 04/13/2016 02:34 BGN9034550
Sulfate 280 mg/L EPA 300.0 04/13/2016 02:34 BGN9034550
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/15/2016 10:47 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/15/2016 11:02 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.010 mg/L EPA 200.7 04/14/2016 15:23 JJMACKE0.005 1
Barium (Ba)0.045 mg/L EPA 200.7 04/14/2016 15:23 JJMACKE0.005 1
Boron (B)0.842 mg/L EPA 200.7 04/14/2016 15:23 JJMACKE0.05 1
Iron (Fe)2.39 mg/L EPA 200.7 04/14/2016 15:23 JJMACKE0.01 1
Manganese (Mn)1.19 mg/L EPA 200.7 04/14/2016 15:23 JJMACKE0.005 1
Strontium (Sr)0.280 mg/L EPA 200.7 04/14/2016 15:23 JJMACKE0.005 1
Zinc (Zn)0.022 mg/L EPA 200.7 04/14/2016 15:23 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)118 mg/L EPA 200.7 04/14/2016 12:38 JJMACKE0.1 10
Magnesium (Mg)29.8 mg/L EPA 200.7 04/14/2016 12:38 JJMACKE0.05 10
Potassium (K)8.17 mg/L EPA 200.7 04/14/2016 12:38 JJMACKE0.1 1
Sodium (Na)13.8 mg/L EPA 200.7 04/14/2016 12:38 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.015 mg/L EPA 200.7 04/13/2016 14:24 JJMACKE0.005 1
Barium (Ba)0.050 mg/L EPA 200.7 04/13/2016 14:24 JJMACKE0.005 1
Boron (B)0.887 mg/L EPA 200.7 04/13/2016 14:24 JJMACKE0.05 1
Iron (Fe)1.62 mg/L EPA 200.7 04/13/2016 14:24 JJMACKE0.01 1
Manganese (Mn)1.26 mg/L EPA 200.7 04/13/2016 14:24 JJMACKE0.005 1
Strontium (Sr)0.291 mg/L EPA 200.7 04/13/2016 14:24 JJMACKE0.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 04/13/2016 14:24 JJMACKE0.005 1
Page 4 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
2016010154
Collection Date:11-Apr-16 10:02 AM
Site:MW-18D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/14/2016 15:50 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 04/14/2016 15:50 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 04/14/2016 15:50 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2016 15:50 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 04/14/2016 15:50 JAHERMA11
Cobalt (Co)4.67 ug/L EPA 200.8 04/14/2016 15:50 JAHERMA11
Copper (Cu)9.66 ug/L EPA 200.8 04/14/2016 15:50 JAHERMA11
Lead (Pb)1.62 ug/L EPA 200.8 04/14/2016 15:50 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/14/2016 15:50 JAHERMA11
Nickel (Ni)2.74 ug/L EPA 200.8 04/14/2016 15:50 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/14/2016 15:50 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/14/2016 15:50M2 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/14/2016 15:50 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/14/2016 17:06 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 04/14/2016 17:06 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 04/14/2016 17:06 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2016 17:06 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 04/14/2016 17:06 JAHERMA11
Cobalt (Co)4.09 ug/L EPA 200.8 04/14/2016 17:06 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 04/14/2016 17:06 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/14/2016 17:06 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/14/2016 17:06 JAHERMA11
Nickel (Ni)2.60 ug/L EPA 200.8 04/14/2016 17:06 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/14/2016 17:06 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/14/2016 17:06 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/14/2016 17:06 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 620 mg/L SM2540C 04/14/2016 13:17 PARMSTR251
Total Carbon
TOC 0.309 mg/L SM5310C/EPA9060A 04/14/2016 11:05 GHUTCHI0.1 1
Page 5 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
2016010154
Collection Date:11-Apr-16 10:02 AM
Site:MW-18D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/14/2016 10:00 PARMSTR51
Page 6 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
2016010155
Collection Date:11-Apr-16 10:28 AM
Site:MW-18BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.291 mg-N/L EPA 353.2 04/14/2016 12:17 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 97 mg/L EPA 300.0 04/13/2016 02:50 BGN9034550
Sulfate 290 mg/L EPA 300.0 04/13/2016 02:50 BGN9034550
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/15/2016 10:50 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/15/2016 11:18 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.008 mg/L EPA 200.7 04/14/2016 15:11 JJMACKE0.005 1
Barium (Ba)0.038 mg/L EPA 200.7 04/14/2016 15:11 JJMACKE0.005 1
Boron (B)0.887 mg/L EPA 200.7 04/14/2016 15:11 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/14/2016 15:11 JJMACKE0.01 1
Manganese (Mn)0.210 mg/L EPA 200.7 04/14/2016 15:11 JJMACKE0.005 1
Strontium (Sr)0.407 mg/L EPA 200.7 04/14/2016 15:11 JJMACKE0.005 1
Zinc (Zn)0.023 mg/L EPA 200.7 04/14/2016 15:11 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)123 mg/L EPA 200.7 04/14/2016 12:41 JJMACKE0.1 10
Magnesium (Mg)28.0 mg/L EPA 200.7 04/14/2016 12:41 JJMACKE0.05 10
Potassium (K)8.76 mg/L EPA 200.7 04/14/2016 12:41 JJMACKE0.1 1
Sodium (Na)14.6 mg/L EPA 200.7 04/14/2016 12:41 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.017 mg/L EPA 200.7 04/13/2016 14:12 JJMACKE0.005 1
Barium (Ba)0.039 mg/L EPA 200.7 04/13/2016 14:12 JJMACKE0.005 1
Boron (B)0.906 mg/L EPA 200.7 04/13/2016 14:12 JJMACKE0.05 1
Iron (Fe)0.014 mg/L EPA 200.7 04/13/2016 14:12 JJMACKE0.01 1
Manganese (Mn)0.216 mg/L EPA 200.7 04/13/2016 14:12 JJMACKE0.005 1
Strontium (Sr)0.413 mg/L EPA 200.7 04/13/2016 14:12 JJMACKE0.005 1
Zinc (Zn)0.008 mg/L EPA 200.7 04/13/2016 14:12 JJMACKE0.005 1
Page 7 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
2016010155
Collection Date:11-Apr-16 10:28 AM
Site:MW-18BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/14/2016 16:06 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 04/14/2016 16:06 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 04/14/2016 16:06 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2016 16:06 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 04/14/2016 16:06 JAHERMA11
Cobalt (Co)1.21 ug/L EPA 200.8 04/14/2016 16:06 JAHERMA11
Copper (Cu)11.6 ug/L EPA 200.8 04/14/2016 16:06 JAHERMA11
Lead (Pb)1.88 ug/L EPA 200.8 04/14/2016 16:06 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/14/2016 16:06 JAHERMA11
Nickel (Ni)4.54 ug/L EPA 200.8 04/14/2016 16:06 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/14/2016 16:06 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/14/2016 16:06 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/14/2016 16:06 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/14/2016 17:28 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 04/14/2016 17:28 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 04/14/2016 17:28 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2016 17:28 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 04/14/2016 17:28 JAHERMA11
Cobalt (Co)1.14 ug/L EPA 200.8 04/14/2016 17:28 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 04/14/2016 17:28 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/14/2016 17:28 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/14/2016 17:28 JAHERMA11
Nickel (Ni)4.31 ug/L EPA 200.8 04/14/2016 17:28 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/14/2016 17:28 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/14/2016 17:28 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/14/2016 17:28 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 650 mg/L SM2540C 04/14/2016 13:17 PARMSTR251
Total Carbon
TOC 0.264 mg/L SM5310C/EPA9060A 04/14/2016 11:05 GHUTCHI0.1 1
Page 8 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
2016010155
Collection Date:11-Apr-16 10:28 AM
Site:MW-18BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/14/2016 10:00 PARMSTR51
Page 9 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
2016010156
Collection Date:11-Apr-16 9:00 AM
Site:MW-17A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/14/2016 12:19 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 410 mg/L EPA 300.0 04/13/2016 03:07 BGN9034550
Sulfate 190 mg/L EPA 300.0 04/13/2016 03:07 BGN9034550
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Total Carbon
TOC 1.5 mg/L SM5310C/EPA9060A 04/14/2016 11:05 GHUTCHI0.1 1
Page 10 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
2016010157
Collection Date:11-Apr-16 1:17 PM
Site:MW-22D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.290 mg-N/L EPA 353.2 04/14/2016 12:23 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 35 mg/L EPA 300.0 04/13/2016 03:23 BGN9034110
Sulfate 11 mg/L EPA 300.0 04/13/2016 03:23 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)0.05 ug/L EPA 245.1 04/15/2016 10:52 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/15/2016 11:25 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.026 mg/L EPA 200.7 04/14/2016 15:27 JJMACKE0.005 1
Barium (Ba)0.030 mg/L EPA 200.7 04/14/2016 15:27 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/14/2016 15:27 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/14/2016 15:27 JJMACKE0.01 1
Manganese (Mn)0.093 mg/L EPA 200.7 04/14/2016 15:27 JJMACKE0.005 1
Strontium (Sr)0.054 mg/L EPA 200.7 04/14/2016 15:27 JJMACKE0.005 1
Zinc (Zn)0.021 mg/L EPA 200.7 04/14/2016 15:27 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)6.08 mg/L EPA 200.7 04/14/2016 12:45 JJMACKE0.01 1
Magnesium (Mg)4.53 mg/L EPA 200.7 04/14/2016 12:45 JJMACKE0.005 1
Potassium (K)1.35 mg/L EPA 200.7 04/14/2016 12:45 JJMACKE0.1 1
Sodium (Na)12.7 mg/L EPA 200.7 04/14/2016 12:45 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.091 mg/L EPA 200.7 04/13/2016 14:28 JJMACKE0.005 1
Barium (Ba)0.034 mg/L EPA 200.7 04/13/2016 14:28 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/13/2016 14:28 JJMACKE0.05 1
Iron (Fe)0.062 mg/L EPA 200.7 04/13/2016 14:28 JJMACKE0.01 1
Manganese (Mn)0.107 mg/L EPA 200.7 04/13/2016 14:28 JJMACKE0.005 1
Strontium (Sr)0.055 mg/L EPA 200.7 04/13/2016 14:28 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/13/2016 14:28 JJMACKE0.005 1
Page 11 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
2016010157
Collection Date:11-Apr-16 1:17 PM
Site:MW-22D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/14/2016 16:11 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 04/14/2016 16:11 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 04/14/2016 16:11 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2016 16:11 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 04/14/2016 16:11 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 04/14/2016 16:11 JAHERMA11
Copper (Cu)12.4 ug/L EPA 200.8 04/14/2016 16:11 JAHERMA11
Lead (Pb)1.89 ug/L EPA 200.8 04/14/2016 16:11 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/14/2016 16:11 JAHERMA11
Nickel (Ni)6.22 ug/L EPA 200.8 04/14/2016 16:11 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/14/2016 16:11 JAHERMA11
Thallium (Tl) Low Level 0.326 ug/L EPA 200.8 04/14/2016 16:11 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/14/2016 16:11 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/14/2016 17:33 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 04/14/2016 17:33 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 04/14/2016 17:33 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2016 17:33 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 04/14/2016 17:33 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 04/14/2016 17:33 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 04/14/2016 17:33 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/14/2016 17:33 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/14/2016 17:33 JAHERMA11
Nickel (Ni)5.49 ug/L EPA 200.8 04/14/2016 17:33 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/14/2016 17:33 JAHERMA11
Thallium (Tl) Low Level 0.209 ug/L EPA 200.8 04/14/2016 17:33 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/14/2016 17:33 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 98 mg/L SM2540C 04/14/2016 13:17 PARMSTR251
Total Carbon
TOC 0.301 mg/L SM5310C/EPA9060A 04/14/2016 11:05 GHUTCHI0.1 1
Page 12 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
2016010157
Collection Date:11-Apr-16 1:17 PM
Site:MW-22D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/14/2016 10:00 PARMSTR51
Page 13 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
2016010158
Collection Date:11-Apr-16 1:42 PM
Site:MW-22BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/14/2016 12:27 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 49 mg/L EPA 300.0 04/13/2016 03:40 BGN9034110
Sulfate 19 mg/L EPA 300.0 04/13/2016 03:40 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/15/2016 10:54 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/15/2016 11:28 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.019 mg/L EPA 200.7 04/14/2016 15:30 JJMACKE0.005 1
Barium (Ba)0.018 mg/L EPA 200.7 04/14/2016 15:30 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/14/2016 15:30 JJMACKE0.05 1
Iron (Fe)15.1 mg/L EPA 200.7 04/14/2016 15:30 JJMACKE0.01 1
Manganese (Mn)0.306 mg/L EPA 200.7 04/14/2016 15:30 JJMACKE0.005 1
Strontium (Sr)0.097 mg/L EPA 200.7 04/14/2016 15:30 JJMACKE0.005 1
Zinc (Zn)0.025 mg/L EPA 200.7 04/14/2016 15:30 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)11.0 mg/L EPA 200.7 04/14/2016 12:49 JJMACKE0.01 1
Magnesium (Mg)4.39 mg/L EPA 200.7 04/14/2016 12:49 JJMACKE0.005 1
Potassium (K)3.01 mg/L EPA 200.7 04/14/2016 12:49 JJMACKE0.1 1
Sodium (Na)16.0 mg/L EPA 200.7 04/14/2016 12:49 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.061 mg/L EPA 200.7 04/13/2016 14:31 JJMACKE0.005 1
Barium (Ba)0.019 mg/L EPA 200.7 04/13/2016 14:31 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/13/2016 14:31 JJMACKE0.05 1
Iron (Fe)16.9 mg/L EPA 200.7 04/13/2016 14:31 JJMACKE0.01 1
Manganese (Mn)0.310 mg/L EPA 200.7 04/13/2016 14:31 JJMACKE0.005 1
Strontium (Sr)0.101 mg/L EPA 200.7 04/13/2016 14:31 JJMACKE0.005 1
Zinc (Zn)0.020 mg/L EPA 200.7 04/13/2016 14:31 JJMACKE0.005 1
Page 14 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
2016010158
Collection Date:11-Apr-16 1:42 PM
Site:MW-22BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/14/2016 16:33 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 04/14/2016 16:33 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 04/14/2016 16:33 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2016 16:33 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 04/14/2016 16:33 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 04/14/2016 16:33 JAHERMA11
Copper (Cu)3.90 ug/L EPA 200.8 04/14/2016 16:33 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/14/2016 16:33 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/14/2016 16:33 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 04/14/2016 16:33 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/14/2016 16:33 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/14/2016 16:33 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/14/2016 16:33 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/14/2016 17:55 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 04/14/2016 17:55 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 04/14/2016 17:55 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2016 17:55 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 04/14/2016 17:55 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 04/14/2016 17:55 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 04/14/2016 17:55 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/14/2016 17:55 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/14/2016 17:55 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 04/14/2016 17:55 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/14/2016 17:55 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/14/2016 17:55 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/14/2016 17:55 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 160 mg/L SM2540C 04/14/2016 13:17 PARMSTR251
Total Carbon
TOC 0.405 mg/L SM5310C/EPA9060A 04/14/2016 11:05 GHUTCHI0.1 1
Page 15 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
2016010158
Collection Date:11-Apr-16 1:42 PM
Site:MW-22BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS 5.0 mg/L SM2540D 04/14/2016 10:00 PARMSTR51
Page 16 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
2016010159
Collection Date:11-Apr-16 2:45 PM
Site:MW-17A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/15/2016 10:57 DMFRANC0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)178 mg/L EPA 200.7 04/14/2016 13:01 JJMACKE0.1 10
Magnesium (Mg)56.1 mg/L EPA 200.7 04/14/2016 13:01 JJMACKE0.05 10
Potassium (K)4.46 mg/L EPA 200.7 04/14/2016 13:01 JJMACKE0.1 1
Sodium (Na)14.9 mg/L EPA 200.7 04/14/2016 13:01 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)1.02 mg/L EPA 200.7 04/13/2016 14:35 JJMACKE0.005 1
Barium (Ba)0.141 mg/L EPA 200.7 04/13/2016 14:35 JJMACKE0.005 1
Boron (B)1.98 mg/L EPA 200.7 04/13/2016 14:35 JJMACKE0.05 1
Iron (Fe)30.0 mg/L EPA 200.7 04/13/2016 14:35 JJMACKE0.01 1
Manganese (Mn)5.90 mg/L EPA 200.7 04/13/2016 14:35 JJMACKE0.005 1
Strontium (Sr)0.625 mg/L EPA 200.7 04/13/2016 14:35 JJMACKE0.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 04/13/2016 14:35 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/14/2016 18:00 JAHERMA11
Arsenic (As)1.40 ug/L EPA 200.8 04/14/2016 18:00 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 04/14/2016 18:00 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2016 18:00 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 04/14/2016 18:00 JAHERMA11
Cobalt (Co)22.4 ug/L EPA 200.8 04/14/2016 18:00 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 04/14/2016 18:00 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/14/2016 18:00 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/14/2016 18:00 JAHERMA11
Nickel (Ni)4.77 ug/L EPA 200.8 04/14/2016 18:00 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/14/2016 18:00 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/14/2016 18:00 JAHERMA0.2 1
Vanadium (V) Low Level 1.17 ug/L EPA 200.8 04/14/2016 18:00 JAHERMA0.3 1
Page 17 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
2016010160
Collection Date:11-Apr-16 4:20 PM
Site:Filter Blank 3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/15/2016 11:30 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 04/14/2016 15:34 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 04/14/2016 15:34 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/14/2016 15:34 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/14/2016 15:34 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 04/14/2016 15:34 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 04/14/2016 15:34 JJMACKE0.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 04/14/2016 15:34 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/14/2016 16:39 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 04/14/2016 16:39 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 04/14/2016 16:39 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2016 16:39 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 04/14/2016 16:39 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 04/14/2016 16:39 JAHERMA11
Copper (Cu)4.95 ug/L EPA 200.8 04/14/2016 16:39 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/14/2016 16:39 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/14/2016 16:39 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 04/14/2016 16:39 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/14/2016 16:39 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/14/2016 16:39 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/14/2016 16:39 JAHERMA0.3 1
Page 18 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
2016010161
Collection Date:11-Apr-16 4:20 PM
Site:Equipment Blank 3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/14/2016 12:28 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 04/13/2016 00:06 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 04/13/2016 00:06 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/15/2016 10:59 DMFRANC0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)< 0.01 mg/L EPA 200.7 04/14/2016 13:33 JJMACKE0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 04/14/2016 13:33 JJMACKE0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 04/14/2016 13:33 JJMACKE0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 04/14/2016 13:33 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 04/13/2016 14:39 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 04/13/2016 14:39 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/13/2016 14:39 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/13/2016 14:39 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 04/13/2016 14:39 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 04/13/2016 14:39 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/13/2016 14:39 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/14/2016 18:06 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 04/14/2016 18:06 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 04/14/2016 18:06 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2016 18:06 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 04/14/2016 18:06 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 04/14/2016 18:06 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 04/14/2016 18:06 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 04/14/2016 18:06 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/14/2016 18:06 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 04/14/2016 18:06 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 04/14/2016 18:06 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/14/2016 18:06 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/14/2016 18:06 JAHERMA0.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 19 of 60
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040242
2016010161
Collection Date:11-Apr-16 4:20 PM
Site:Equipment Blank 3
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Total Carbon
TOC 0.315 mg/L SM5310C/EPA9060A 04/14/2016 11:05 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/14/2016 10:00 PARMSTR51
Qualifiers:
M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable.
Page 20 of 60

April 19, 2016

Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment Water
Work Order: 395096
SDG: J16040242

Dear Mary :
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on April 12, 2016. This original data report has been prepared and reviewed in accordance
with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 1250944 DPNNGO
Enclosures
Page 1 of 15
Page 21 of 60
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO002 Duke Energy
Client SDG: J16040242 GEL Work Order: 395096
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
for
Page 2 of 15
Page 22 of 60
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: April 19, 2016
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1559298
1559298
1559316
1559634
1332
1840
1246
0830
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
04/15/16
04/14/16
04/18/16
04/19/16
SKJ
PRB
AXM6
LXP1
0.00005
0.00005
0.00005
0.0002
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
395096001
Water
11-APR-16 10:02
12-APR-16
2016010154 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"89.6 (15%-125%)
0.00001
0.00001
0.00001
0.000067
1.88
0.447
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 04/13/16 15592970738JXM5
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
U
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
0.747
NominalResult
RLDL
Notes:
Page 3 of 15
Page 23 of 60
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: April 19, 2016
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1559298
1559298
1559316
1559634
1338
1847
1246
0830
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
04/15/16
04/14/16
04/18/16
04/19/16
SKJ
PRB
AXM6
LXP1
0.00005
0.00005
0.00005
0.0002
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
395096002
Water
11-APR-16 10:28
12-APR-16
2016010155 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"92.1 (15%-125%)
0.00001
0.00001
0.00001
0.000067
1.75
0.446
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 04/13/16 15592970738JXM5
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
U
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
1.21
NominalResult
RLDL
Notes:
Page 4 of 15
Page 24 of 60
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: April 19, 2016
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1559298
1559298
1559316
1559634
1339
1849
1246
0830
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
04/15/16
04/14/16
04/18/16
04/19/16
SKJ
PRB
AXM6
LXP1
0.00005
0.00005
0.00005
0.0002
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
395096003
Water
11-APR-16 13:17
12-APR-16
2016010157 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"92.4 (15%-125%)
0.00001
0.00001
0.00001
0.000067
1.30
0.421
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 04/13/16 15592970738JXM5
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
1.33
0.497
NominalResult
RLDL
Notes:
Page 5 of 15
Page 25 of 60
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: April 19, 2016
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1559298
1559298
1559316
1559634
1341
1851
1246
0830
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
04/15/16
04/14/16
04/18/16
04/19/16
SKJ
PRB
AXM6
LXP1
0.00005
0.00005
0.00005
0.0002
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
395096004
Water
11-APR-16 13:42
12-APR-16
2016010158 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"93.3 (15%-125%)
0.00001
0.00001
0.00001
0.000067
1.28
0.493
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 04/13/16 15592970738JXM5
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
1.40
4.85
NominalResult
RLDL
Notes:
Page 6 of 15
Page 26 of 60
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1559298Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Parmname
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, North Carolina
April 19, 2016Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
Anlst Date Time
SKJ
PRB
SKJ
PRB
SKJ
04/15/16 13:33
04/14/16 18:42
04/14/16 18:39
04/15/16 13:27
04/15/16 13:26
04/14/16 18:37
04/14/16 18:44
04/15/16 13:35
04/15/16 13:36
QC
ND
ND
ND
ND
0.0547
0.000532
0.000605
0.00525
ND
ND
ND
ND
0.0548
0.000521
0.000584
0.00513
ND
NOM Sample
ND
ND
ND
ND
ND
ND
ND
ND
ND
Range
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
U
U
U
QC1203526807 395096001
QC1203526805
QC1203526806
QC1203526804
QC1203526808 395096001
QC1203526809 395096001
QC1203526810 395096001
N/A
N/A
N/A
N/A
N/A
REC%
110
106
110
105
110
104
106
102
0.0496
0.0005
0.00055
0.005
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
MS
MS
SDILT
395096Workorder:
Mail Code: MGO3A2
U
U
U
U
U
U
U
U
U
RPD%
Page 1 of 3
Page 7 of 15
Page 27 of 60
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
Rad Ra-226
1559298
1559316
1559634
Batch
Batch
Batch
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-228
Radium-228
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
ug/L
ug/L
ug/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
SKJ
PRB
AXM6
LXP1
04/15/16 13:36
04/14/16 18:46
04/18/16 12:46
04/18/16 12:46
04/18/16 12:46
04/19/16 09:00
04/19/16 09:30
04/19/16 09:00
04/19/16 09:30
QC
ND
ND
50.5
2.54
46.4
0.758
0.908
30.4
0.319
128
NOM Sample
ND
ND
ND
1.40
0.747
0.747
Range
(0%-10%)
(0%-10%)
(0% - 100%)
(75%-125%)
(0% - 100%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
QC1203526838 395096004
QC1203526839
QC1203526837
QC1203527795 395096001
QC1203527797
QC1203527794
QC1203527796 395096001
The Qualifiers in this report are defined as follows:
N/A
N/A
N/A
58.1
19.6
REC%
99.8
125
104
46.5
24.4
122
DUP
LCS
MB
DUP
LCS
MB
MS
395096Workorder:
**
<
>
BD
E
FA
FB
H
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
U
U
U
RPD%
Notes:
Page 2 of 3
Page 8 of 15
Page 28 of 60
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 3 of 3
Units Anlst Date TimeQCNOMSampleRangeQualREC%
395096Workorder:
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
U
UI
UJ
UL
X
Y
^
h
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
Page 9 of 15
Page 29 of 60
Page 10 of 15
Page 30 of 60
Page 11 of 15
Page 31 of 60

Technical Case Narrative
Duke Energy (DUPO)
SDG #: J16040242
Work Order #: 395096

Metals

Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1559298

Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1559297
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
395096001 2016010154
395096002 2016010155
395096003 2016010157
395096004 2016010158
1203526804 Method Blank (MB)ICP-MS
1203526805 Laboratory Control Sample (LCS)
1203526806 Laboratory Control Sample (LCS)
1203526810 395096001(2016010154L) Serial Dilution (SD)
1203526807 395096001(2016010154D) Sample Duplicate (DUP)
1203526808 395096001(2016010154S) Matrix Spike (MS)
1203526809 395096001(2016010154S) Matrix Spike (MS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Radiochemistry

Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1559316
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
395096001 2016010154
Page 12 of 15
Page 32 of 60
395096002 2016010155
395096003 2016010157
395096004 2016010158
1203526837 Method Blank (MB)
1203526838 395096004(2016010158) Sample Duplicate (DUP)
1203526839 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1559634
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
395096001 2016010154
395096002 2016010155
395096003 2016010157
395096004 2016010158
1203527794 Method Blank (MB)
1203527795 395096001(2016010154) Sample Duplicate (DUP)
1203527796 395096001(2016010154) Matrix Spike (MS)
1203527797 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Miscellaneous Information

Additional Comments
The matrix spike, 1203527796 (2016010154MS), aliquot was reduced to conserve sample volume.

Page 13 of 15
Page 33 of 60
Certification Statement

Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Page 14 of 15
Page 34 of 60
State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
North Dakota
Oklahoma
Pennsylvania NELAP
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-0110
88-0651
42D0904046
2940
SC00012
PH-0169
SC00012
2567.01
E87156
P330-15-00283, P330-15-00253
SC00012
967
SC00012
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA160006
270
M-SC012
9976
SC00012
NE-OS-26-13
SC000122016-1
205415
SC002
SC00012
11501
233
45709
R-158
9904
68-00485
10120002
10120001
TN 02934
T104704235-16-11
SC000122016-20
VT87156
460202
C780
997404
List of current GEL Certifications as of 19 April 2016
Page 15 of 15
Page 35 of 60
#=CL#
April 19, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92293408
92293408
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16040242
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on April 12, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Mary Ann Ogle, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 24
Page 36 of 60
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92293408
J16040242
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
525 N 8th Street, Salina, KS 67401
A2LA Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA #: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 24
Page 37 of 60
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92293408
J16040242
Lab ID Sample ID Matrix Date Collected Date Received
92293408001 2016010154 Water 04/11/16 10:02 04/12/16 13:46
92293408002 2016010155 Water 04/11/16 10:28 04/12/16 13:46
92293408003 2016010156 Water 04/11/16 09:00 04/12/16 13:46
92293408004 2016010157 Water 04/11/16 13:17 04/12/16 13:46
92293408005 2016010158 Water 04/11/16 13:42 04/12/16 13:46
92293408006 2016010161 Water 04/11/16 16:20 04/12/16 13:46
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 24
Page 38 of 60
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92293408
J16040242
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92293408001 2016010154 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OTK1
92293408002 2016010155 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OTK1
92293408003 2016010156 SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OTK1
92293408004 2016010157 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OTK1
92293408005 2016010158 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OTK1
92293408006 2016010161 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AWRC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 24
Page 39 of 60
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92293408
J16040242
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92293408001 2016010154
Alkalinity,Bicarbonate (CaCO3)30.1 mg/L 04/15/16 16:085.0SM 2320B
Alkalinity, Total as CaCO3 30.1 mg/L 04/15/16 16:085.0SM 2320B
92293408002 2016010155
Alkalinity,Bicarbonate (CaCO3)28.0 mg/L 04/15/16 16:205.0SM 2320B
Alkalinity, Total as CaCO3 28.0 mg/L 04/15/16 16:205.0SM 2320B
Chromium, Hexavalent 0.043 ug/L 04/15/16 18:290.030EPA 218.7
92293408003 2016010156
Alkalinity,Bicarbonate (CaCO3)20.8 mg/L 04/15/16 16:315.0SM 2320B
Alkalinity, Total as CaCO3 20.8 mg/L 04/15/16 16:315.0SM 2320B
92293408004 2016010157
Chromium, Hexavalent 0.75 ug/L 04/18/16 09:41 M10.15EPA 218.7
92293408005 2016010158
Alkalinity,Bicarbonate (CaCO3)20.6 mg/L 04/15/16 17:105.0SM 2320B
Alkalinity, Total as CaCO3 20.6 mg/L 04/15/16 17:105.0SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 24
Page 40 of 60
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92293408
J16040242
Method:
Client:Duke Energy
RSK 175
Date:April 19, 2016
Description:RSK 175 AIR Headspace
General Information:
5 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 24
Page 41 of 60
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92293408
J16040242
Method:
Client:Duke Energy
SM 2320B
Date:April 19, 2016
Description:2320B Alkalinity
General Information:
6 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 24
Page 42 of 60
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92293408
J16040242
Method:
Client:Duke Energy
SM 4500-S2D
Date:April 19, 2016
Description:4500S2D Sulfide Water
General Information:
6 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 43 of 60
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92293408
J16040242
Method:
Client:Duke Energy
EPA 218.7
Date:April 19, 2016
Description:Hexavalent Chromium by IC
General Information:
5 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WETA/56898
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92293293006,92293408003
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MSD (Lab ID: 1542726)
• Chromium, Hexavalent
QC Batch: WETA/56918
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92293408004,92293525003
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1544168)
• Chromium, Hexavalent
• MS (Lab ID: 1544170)
• Chromium, Hexavalent
• MSD (Lab ID: 1544169)
• Chromium, Hexavalent
R1: RPD value was outside control limits.
• MSD (Lab ID: 1544171)
• Chromium, Hexavalent
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Huntersville, NC 28078
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Page 9 of 24
Page 44 of 60
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92293408
J16040242
Sample:2016010154 Lab ID:92293408001 Collected:04/11/16 10:02 Received:04/12/16 13:46 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 04/15/16 08:56 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)30.1 mg/L 04/15/16 16:085.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/15/16 16:085.0 1
Alkalinity, Total as CaCO3 30.1 mg/L 04/15/16 16:085.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/14/16 19:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 04/15/16 18:16 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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Page 10 of 24
Page 45 of 60
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92293408
J16040242
Sample:2016010155 Lab ID:92293408002 Collected:04/11/16 10:28 Received:04/12/16 13:46 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 04/15/16 09:37 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)28.0 mg/L 04/15/16 16:205.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/15/16 16:205.0 1
Alkalinity, Total as CaCO3 28.0 mg/L 04/15/16 16:205.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/14/16 19:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.043 ug/L 04/15/16 18:29 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 11 of 24
Page 46 of 60
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92293408
J16040242
Sample:2016010156 Lab ID:92293408003 Collected:04/11/16 09:00 Received:04/12/16 13:46 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)20.8 mg/L 04/15/16 16:315.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/15/16 16:315.0 1
Alkalinity, Total as CaCO3 20.8 mg/L 04/15/16 16:315.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/14/16 19:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 04/15/16 19:08 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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Page 12 of 24
Page 47 of 60
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92293408
J16040242
Sample:2016010157 Lab ID:92293408004 Collected:04/11/16 13:17 Received:04/12/16 13:46 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 04/15/16 09:46 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 04/15/16 17:025.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/15/16 17:025.0 1
Alkalinity, Total as CaCO3 ND mg/L 04/15/16 17:025.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/14/16 19:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.75 ug/L 04/18/16 09:41 18540-29-9 M10.15 5
REPORT OF LABORATORY ANALYSIS
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92293408
J16040242
Sample:2016010158 Lab ID:92293408005 Collected:04/11/16 13:42 Received:04/12/16 13:46 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 04/15/16 09:54 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)20.6 mg/L 04/15/16 17:105.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/15/16 17:105.0 1
Alkalinity, Total as CaCO3 20.6 mg/L 04/15/16 17:105.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/14/16 19:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 04/15/16 20:00 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 14 of 24
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92293408
J16040242
Sample:2016010161 Lab ID:92293408006 Collected:04/11/16 16:20 Received:04/12/16 13:46 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 04/15/16 10:02 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 04/15/16 17:225.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/15/16 17:225.0 1
Alkalinity, Total as CaCO3 ND mg/L 04/15/16 17:225.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/14/16 19:00 18496-25-80.10 1
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 15 of 24
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92293408
J16040242
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/25691
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92293408001, 92293408002, 92293408004, 92293408005, 92293408006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2231173
Associated Lab Samples:92293408001, 92293408002, 92293408004, 92293408005, 92293408006
Matrix:Water
Analyzed
Methane ug/L ND 10.0 04/15/16 07:20
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2231174LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2231175
Methane ug/L 60.260.7 99 85-1159859.6 1 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92293276005
2234656SAMPLE DUPLICATE:
Methane ug/L 1.6J 201.4J
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 16 of 24
Page 51 of 60
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92293408
J16040242
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/44242
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92293408001, 92293408002, 92293408003, 92293408004, 92293408005, 92293408006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1709856
Associated Lab Samples:92293408001, 92293408002, 92293408003, 92293408004, 92293408005, 92293408006
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 04/15/16 13:07
Alkalinity, Total as CaCO3 mg/L ND 5.0 04/15/16 13:07
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 04/15/16 13:07
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1709857LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 49.450 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1709858MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293293003
1709859
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 98 80-12097 1 255012.8 62.0 61.4
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1709860MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293293013
1709861
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 97 80-12097 1 2550ND48.6 48.3
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 17 of 24
Page 52 of 60
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92293408
J16040242
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/44258
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92293408001, 92293408002, 92293408003, 92293408004, 92293408005, 92293408006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1710637
Associated Lab Samples:92293408001, 92293408002, 92293408003, 92293408004, 92293408005, 92293408006
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 04/14/16 19:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1710638LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.51.5 102 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1710639MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293293007
1710640
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 105 90-110105 0 10.5ND 0.53 0.53
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1710641MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293408004
1710642
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 104 90-110104 0 10.5ND 0.52 0.52
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 18 of 24
Page 53 of 60
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92293408
J16040242
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/56898
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92293408001, 92293408002, 92293408003, 92293408005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1542723
Associated Lab Samples:92293408001, 92293408002, 92293408003, 92293408005
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 04/15/16 15:33
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1542724LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.066.075 88 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1542725MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293293006
1542726
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.025 86 85-11560 20.0250.011J 0.033 .026J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1542727MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293408003
1542728
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L .075 94 85-115102 8 20.075ND 0.071 0.076
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 19 of 24
Page 54 of 60
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92293408
J16040242
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/56918
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92293408004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1544166
Associated Lab Samples:92293408004
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 04/18/16 09:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1544167LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.078.075 104 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1544168MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293408004
1544169
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.12 41 85-11552 2 20.120.75 0.80 0.81
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1544170MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293525003
1544171
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1,R1.075 116 85-11585 30 20.075ND 0.087 0.064
REPORT OF LABORATORY ANALYSIS
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Page 20 of 24
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92293408
J16040242
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - MinneapolisPASI-M
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92293408
J16040242
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92293408001 AIR/256912016010154RSK 175
92293408002 AIR/256912016010155RSK 175
92293408004 AIR/256912016010157RSK 175
92293408005 AIR/256912016010158RSK 175
92293408006 AIR/256912016010161RSK 175
92293408001 WET/442422016010154SM 2320B
92293408002 WET/442422016010155SM 2320B
92293408003 WET/442422016010156SM 2320B
92293408004 WET/442422016010157SM 2320B
92293408005 WET/442422016010158SM 2320B
92293408006 WET/442422016010161SM 2320B
92293408001 WET/442582016010154SM 4500-S2D
92293408002 WET/442582016010155SM 4500-S2D
92293408003 WET/442582016010156SM 4500-S2D
92293408004 WET/442582016010157SM 4500-S2D
92293408005 WET/442582016010158SM 4500-S2D
92293408006 WET/442582016010161SM 4500-S2D
92293408001 WETA/568982016010154EPA 218.7
92293408002 WETA/568982016010155EPA 218.7
92293408003 WETA/568982016010156EPA 218.7
92293408004 WETA/569182016010157EPA 218.7
92293408005 WETA/568982016010158EPA 218.7
REPORT OF LABORATORY ANALYSIS
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