NC0000396_App B Lab Reports - CAMA BKGD - J16040210report_20160831

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16040210
Project Name:ASHEVILLE - AB GW ASSESSMENT WATER
Lab Contact:Mary Ann Ogle
Date:4/19/2016
Customer Address:200 CP and L Drive
Customer Name(s):Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
Arden,NC 28704
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Mary Ann Ogle
Page 1 of 52
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016009988 ASHEVILLE 08-Apr-16 8:37 AM illegible MW-15D
2016009989 ASHEVILLE 08-Apr-16 10:04 AM illegible MW-16A
2016009990 ASHEVILLE 08-Apr-16 11:22 AM illegible MW-16BR
2016009991 ASHEVILLE 08-Apr-16 illegible Filter Blank
2016009992 ASHEVILLE 08-Apr-16 12:05 PM illegible Equipment Blank
5 Total Samples
Page 2 of 52
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:4/19/2016
Electronic Data Deliverable (EDD) Sent Separately
Page 3 of 52
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040210
2016009988
Collection Date:08-Apr-16 8:37 AM
Site:MW-15D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.823 mg-N/L EPA 353.2 04/09/2016 12:08 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 19 mg/L EPA 300.0 04/12/2016 11:32 BGN90340.5 5
Sulfate 0.34 mg/L EPA 300.0 04/12/2016 11:32 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/11/2016 13:35 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/11/2016 14:45 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.006 mg/L EPA 200.7 04/09/2016 13:01 JJMACKE0.005 1
Barium (Ba)0.088 mg/L EPA 200.7 04/09/2016 13:01 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/09/2016 13:01 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/09/2016 13:01 JJMACKE0.01 1
Manganese (Mn)0.020 mg/L EPA 200.7 04/09/2016 13:01 JJMACKE0.005 1
Strontium (Sr)0.150 mg/L EPA 200.7 04/09/2016 13:01 JJMACKE0.005 1
Zinc (Zn)0.018 mg/L EPA 200.7 04/09/2016 13:01 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)10.4 mg/L EPA 200.7 04/11/2016 12:03 JJMACKE0.01 1
Magnesium (Mg)3.17 mg/L EPA 200.7 04/11/2016 12:03 JJMACKE0.005 1
Potassium (K)3.07 mg/L EPA 200.7 04/11/2016 12:03 JJMACKE0.1 1
Sodium (Na)8.19 mg/L EPA 200.7 04/11/2016 12:03 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.060 mg/L EPA 200.7 04/11/2016 16:49 JJMACKE0.005 1
Barium (Ba)0.070 mg/L EPA 200.7 04/11/2016 16:49 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/11/2016 16:49 JJMACKE0.05 1
Iron (Fe)0.141 mg/L EPA 200.7 04/11/2016 16:49 JJMACKE0.01 1
Manganese (Mn)0.025 mg/L EPA 200.7 04/11/2016 16:49 JJMACKE0.005 1
Strontium (Sr)0.144 mg/L EPA 200.7 04/11/2016 16:49 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/11/2016 16:49 JJMACKE0.005 1
Page 4 of 52
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040210
2016009988
Collection Date:08-Apr-16 8:37 AM
Site:MW-15D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/10/2016 16:09 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/10/2016 16:09 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/10/2016 16:09 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/10/2016 16:09 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/10/2016 16:09 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/10/2016 16:09 MHALL311
Copper (Cu)10.5 ug/L EPA 200.8 04/10/2016 16:09 MHALL311
Lead (Pb)1.57 ug/L EPA 200.8 04/10/2016 16:09 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/10/2016 16:09 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 04/10/2016 16:09 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/10/2016 16:09 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/10/2016 16:09 MHALL30.2 1
Vanadium (V) Low Level 0.424 ug/L EPA 200.8 04/10/2016 16:09 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/11/2016 00:10 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/11/2016 00:10 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/11/2016 00:10 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/11/2016 00:10 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/11/2016 00:10 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/11/2016 00:10 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 04/11/2016 00:10 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/11/2016 00:10 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/11/2016 00:10 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 04/11/2016 00:10 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/11/2016 00:10 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/11/2016 00:10 MHALL30.2 1
Vanadium (V) Low Level 0.726 ug/L EPA 200.8 04/11/2016 00:10 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 91 mg/L SM2540C 04/14/2016 13:17 PARMSTR251
Total Carbon
TOC 0.193 mg/L SM5310C/EPA9060A 04/14/2016 11:05 GHUTCHI0.1 1
Page 5 of 52
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040210
2016009988
Collection Date:08-Apr-16 8:37 AM
Site:MW-15D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/13/2016 10:30 PARMSTR51
Page 6 of 52
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040210
2016009989
Collection Date:08-Apr-16 10:04 AM
Site:MW-16A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/09/2016 12:12 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 100 mg/L EPA 300.0 04/11/2016 21:53 BGN9034220
Sulfate 65 mg/L EPA 300.0 04/11/2016 21:53 BGN9034220
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/11/2016 13:42 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/11/2016 14:48 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.281 mg/L EPA 200.7 04/09/2016 13:12 JJMACKE0.005 1
Barium (Ba)0.136 mg/L EPA 200.7 04/09/2016 13:12 JJMACKE0.005 1
Boron (B)0.451 mg/L EPA 200.7 04/09/2016 13:12 JJMACKE0.05 1
Iron (Fe)0.048 mg/L EPA 200.7 04/09/2016 13:12 JJMACKE0.01 1
Manganese (Mn)1.55 mg/L EPA 200.7 04/09/2016 13:12 JJMACKE0.005 1
Strontium (Sr)0.238 mg/L EPA 200.7 04/09/2016 13:12 JJMACKE0.005 1
Zinc (Zn)0.019 mg/L EPA 200.7 04/09/2016 13:12 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)41.2 mg/L EPA 200.7 04/11/2016 12:06 JJMACKE0.01 1
Magnesium (Mg)14.6 mg/L EPA 200.7 04/11/2016 12:06 JJMACKE0.005 1
Potassium (K)2.48 mg/L EPA 200.7 04/11/2016 12:06 JJMACKE0.1 1
Sodium (Na)19.3 mg/L EPA 200.7 04/11/2016 12:06 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.333 mg/L EPA 200.7 04/11/2016 17:00 JJMACKE0.005 1
Barium (Ba)0.142 mg/L EPA 200.7 04/11/2016 17:00 JJMACKE0.005 1
Boron (B)0.447 mg/L EPA 200.7 04/11/2016 17:00 JJMACKE0.05 1
Iron (Fe)0.053 mg/L EPA 200.7 04/11/2016 17:00 JJMACKE0.01 1
Manganese (Mn)1.56 mg/L EPA 200.7 04/11/2016 17:00 JJMACKE0.005 1
Strontium (Sr)0.240 mg/L EPA 200.7 04/11/2016 17:00 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/11/2016 17:00 JJMACKE0.005 1
Page 7 of 52
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040210
2016009989
Collection Date:08-Apr-16 10:04 AM
Site:MW-16A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/10/2016 15:47 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/10/2016 15:47 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/10/2016 15:47 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/10/2016 15:47 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/10/2016 15:47 MHALL311
Cobalt (Co)1.57 ug/L EPA 200.8 04/10/2016 15:47 MHALL311
Copper (Cu)11.0 ug/L EPA 200.8 04/10/2016 15:47 MHALL311
Lead (Pb)2.03 ug/L EPA 200.8 04/10/2016 15:47 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/10/2016 15:47 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 04/10/2016 15:47 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/10/2016 15:47 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/10/2016 15:47M2 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/10/2016 15:47 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/11/2016 00:16 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/11/2016 00:16 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/11/2016 00:16 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/11/2016 00:16 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/11/2016 00:16 MHALL311
Cobalt (Co)2.00 ug/L EPA 200.8 04/11/2016 00:16 MHALL311
Copper (Cu)1.20 ug/L EPA 200.8 04/11/2016 00:16 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/11/2016 00:16 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/11/2016 00:16 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 04/11/2016 00:16 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/11/2016 00:16 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/11/2016 00:16 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/11/2016 00:16 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 310 mg/L SM2540C 04/14/2016 13:17 PARMSTR251
Total Carbon
TOC 0.823 mg/L SM5310C/EPA9060A 04/14/2016 11:05 GHUTCHI0.1 1
Page 8 of 52
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040210
2016009989
Collection Date:08-Apr-16 10:04 AM
Site:MW-16A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/13/2016 10:30 PARMSTR51
Page 9 of 52
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040210
2016009990
Collection Date:08-Apr-16 11:22 AM
Site:MW-16BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/09/2016 12:13 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 120 mg/L EPA 300.0 04/11/2016 22:58 BGN9034220
Sulfate 35 mg/L EPA 300.0 04/11/2016 22:58 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/11/2016 13:49 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/11/2016 14:55 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.072 mg/L EPA 200.7 04/09/2016 13:16 JJMACKE0.005 1
Barium (Ba)0.276 mg/L EPA 200.7 04/09/2016 13:16 JJMACKE0.005 1
Boron (B)0.127 mg/L EPA 200.7 04/09/2016 13:16 JJMACKE0.05 1
Iron (Fe)50.0 mg/L EPA 200.7 04/09/2016 13:16 JJMACKE0.01 1
Manganese (Mn)0.701 mg/L EPA 200.7 04/09/2016 13:16 JJMACKE0.005 1
Strontium (Sr)0.267 mg/L EPA 200.7 04/09/2016 13:16 JJMACKE0.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 04/09/2016 13:16 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)21.6 mg/L EPA 200.7 04/11/2016 12:10 JJMACKE0.01 1
Magnesium (Mg)4.76 mg/L EPA 200.7 04/11/2016 12:10 JJMACKE0.005 1
Potassium (K)3.34 mg/L EPA 200.7 04/11/2016 12:10 JJMACKE0.1 1
Sodium (Na)21.1 mg/L EPA 200.7 04/11/2016 12:10 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.086 mg/L EPA 200.7 04/11/2016 17:04 JJMACKE0.005 1
Barium (Ba)0.271 mg/L EPA 200.7 04/11/2016 17:04 JJMACKE0.005 1
Boron (B)0.140 mg/L EPA 200.7 04/11/2016 17:04 JJMACKE0.05 1
Iron (Fe)52.5 mg/L EPA 200.7 04/11/2016 17:04 JJMACKE0.1 10
Manganese (Mn)0.678 mg/L EPA 200.7 04/11/2016 17:04 JJMACKE0.005 1
Strontium (Sr)0.259 mg/L EPA 200.7 04/11/2016 17:04 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/11/2016 17:04 JJMACKE0.005 1
Page 10 of 52
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040210
2016009990
Collection Date:08-Apr-16 11:22 AM
Site:MW-16BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/10/2016 16:14 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/10/2016 16:14 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/10/2016 16:14 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/10/2016 16:14 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/10/2016 16:14 MHALL311
Cobalt (Co)2.05 ug/L EPA 200.8 04/10/2016 16:14 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 04/10/2016 16:14 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/10/2016 16:14 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/10/2016 16:14 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 04/10/2016 16:14 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/10/2016 16:14 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/10/2016 16:14 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/10/2016 16:14 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/11/2016 00:21 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/11/2016 00:21 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/11/2016 00:21 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/11/2016 00:21 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/11/2016 00:21 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/11/2016 00:21 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 04/11/2016 00:21 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/11/2016 00:21 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/11/2016 00:21 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 04/11/2016 00:21 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/11/2016 00:21 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/11/2016 00:21 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/11/2016 00:21 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 280 mg/L SM2540C 04/14/2016 13:17 PARMSTR251
Total Carbon
TOC 0.425 mg/L SM5310C/EPA9060A 04/14/2016 11:05 GHUTCHI0.1 1
Page 11 of 52
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040210
2016009990
Collection Date:08-Apr-16 11:22 AM
Site:MW-16BR
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/13/2016 10:30 PARMSTR51
Page 12 of 52
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040210
2016009991
Collection Date:08-Apr-16
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/11/2016 15:02 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 04/09/2016 13:20 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 04/09/2016 13:20 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/09/2016 13:20 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/09/2016 13:20 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 04/09/2016 13:20 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 04/09/2016 13:20 JJMACKE0.005 1
Zinc (Zn)0.007 mg/L EPA 200.7 04/09/2016 13:20 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/10/2016 16:19 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/10/2016 16:19 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/10/2016 16:19 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/10/2016 16:19 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/10/2016 16:19 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/10/2016 16:19 MHALL311
Copper (Cu)4.40 ug/L EPA 200.8 04/10/2016 16:19 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/10/2016 16:19 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/10/2016 16:19 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 04/10/2016 16:19 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/10/2016 16:19 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/10/2016 16:19 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/10/2016 16:19 MHALL30.3 1
Page 13 of 52
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040210
2016009992
Collection Date:08-Apr-16 12:05 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/09/2016 12:14 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 04/11/2016 22:25 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 04/11/2016 22:25 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/11/2016 13:52 DMFRANC0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)< 0.01 mg/L EPA 200.7 04/11/2016 12:14 JJMACKE0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 04/11/2016 12:14 JJMACKE0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 04/11/2016 12:14 JJMACKE0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 04/11/2016 12:14 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 04/11/2016 17:08 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 04/11/2016 17:08 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/11/2016 17:08 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/11/2016 17:08 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 04/11/2016 17:08 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 04/11/2016 17:08 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/11/2016 17:08 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/11/2016 00:27 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/11/2016 00:27 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/11/2016 00:27 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/11/2016 00:27 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/11/2016 00:27 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/11/2016 00:27 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 04/11/2016 00:27 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/11/2016 00:27 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/11/2016 00:27 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 04/11/2016 00:27 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/11/2016 00:27 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/11/2016 00:27 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/11/2016 00:27 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 14 of 52
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040210
2016009992
Collection Date:08-Apr-16 12:05 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Total Carbon
TOC 0.296 mg/L SM5310C/EPA9060A 04/14/2016 11:05 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/13/2016 10:30 PARMSTR51
Qualifiers:
M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable.
Page 15 of 52

April 18, 2016

Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment Water
Work Order: 394975
SDG: J16040210

Dear Mary :
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on April 11, 2016. This original data report has been prepared and reviewed in accordance
with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 1142110 DPNNGO
Enclosures
Page 1 of 14
Page 16 of 52
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO002 Duke Energy
Client SDG: J16040210 GEL Work Order: 394975
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
for
Page 2 of 14
Page 17 of 52
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: April 18, 2016
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1558923
1558923
1558974
1558964
0951
1315
1242
0840
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
04/15/16
04/15/16
04/18/16
04/15/16
SKJ
PRB
AXM6
CXP3
0.00005
0.00005
0.00005
0.0002
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
394975001
Water
08-APR-16 08:37
11-APR-16
2016009988 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"70.9 (15%-125%)
0.00001
0.00001
0.00001
0.000067
2.48
0.588
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 04/12/16 15589222015JP1
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
U
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
2.21
NominalResult
RLDL
Notes:
Page 3 of 14
Page 18 of 52
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: April 18, 2016
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1558923
1558923
1558974
1558964
0957
1328
1243
0840
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
04/15/16
04/15/16
04/18/16
04/15/16
SKJ
PRB
AXM6
CXP3
0.00005
0.00005
0.00005
0.0002
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
394975002
Water
08-APR-16 10:04
11-APR-16
2016009989 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"61.1 (15%-125%)
0.00001
0.00001
0.00001
0.000067
2.32
0.402
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 04/12/16 15589222015JP1
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
U
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
7.56
NominalResult
RLDL
Notes:
Page 4 of 14
Page 19 of 52
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: April 18, 2016
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1558923
1558923
1558974
1558964
1002
1330
1152
0840
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
04/15/16
04/15/16
04/15/16
04/15/16
SKJ
PRB
AXM6
CXP3
0.00005
0.00005
0.00005
0.0002
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
394975003
Water
08-APR-16 11:22
11-APR-16
2016009990 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"95.8 (15%-125%)
0.00001
0.00001
0.00001
0.000067
1.63
0.791
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 04/12/16 15589222015JP1
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
2.11
3.04
NominalResult
RLDL
Notes:
Page 5 of 14
Page 20 of 52
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1558923Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Parmname
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, North Carolina
April 18, 2016Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
Anlst Date Time
SKJ
PRB
SKJ
PRB
SKJ
04/15/16 09:53
04/15/16 13:16
04/15/16 13:13
04/15/16 09:50
04/15/16 09:48
04/15/16 13:11
04/15/16 13:18
04/15/16 09:54
04/15/16 09:56
QC
ND
ND
ND
ND
0.0483
0.000515
0.000588
0.00517
ND
ND
ND
ND
0.0482
0.000519
0.0006
0.00531
ND
NOM Sample
ND
ND
ND
ND
ND
ND
ND
ND
ND
Range
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
U
U
U
QC1203525868 394975001
QC1203525867
QC1203525884
QC1203525866
QC1203525869 394975001
QC1203525885 394975001
QC1203525870 394975001
N/A
N/A
N/A
N/A
N/A
REC%
97.4
103
107
103
97
104
109
106
0.0496
0.0005
0.00055
0.005
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
MS
MS
SDILT
394975Workorder:
Mail Code: MGO3A2
U
U
U
U
U
U
U
U
U
RPD%
Page 1 of 3
Page 6 of 14
Page 21 of 52
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
Rad Ra-226
1558923
1558974
1558964
Batch
Batch
Batch
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-228
Radium-228
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
ug/L
ug/L
ug/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
SKJ
PRB
AXM6
CXP3
04/15/16 09:56
04/15/16 13:22
04/15/16 11:54
04/15/16 11:48
04/15/16 11:54
04/15/16 09:15
04/15/16 09:15
04/15/16 09:15
04/15/16 09:15
QC
ND
ND
ND
2.65
46.3
-0.75
2.69
29.7
-0.157
150
NOM Sample
ND
ND
ND
2.11
2.21
2.21
Range
(0%-10%)
(0%-10%)
(0% - 100%)
(75%-125%)
(0% - 100%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
QC1203525966 394975003
QC1203525967
QC1203525965
QC1203525933 394975001
QC1203525935
QC1203525932
QC1203525934 394975001
The Qualifiers in this report are defined as follows:
N/A
N/A
N/A
22.7
19.6
REC%
99.5
122
121
46.6
24.4
122
DUP
LCS
MB
DUP
LCS
MB
MS
394975Workorder:
**
<
>
BD
E
FA
FB
H
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
U
U
U
RPD%
Notes:
Page 2 of 3
Page 7 of 14
Page 22 of 52
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 3 of 3
Units Anlst Date TimeQCNOMSampleRangeQualREC%
394975Workorder:
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
U
UI
UJ
UL
X
Y
^
h
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
Page 8 of 14
Page 23 of 52
Page 9 of 14
Page 24 of 52
Page 10 of 14
Page 25 of 52

Technical Case Narrative
Duke Energy (DUPO)
SDG #: J16040210
Work Order #: 394975

Metals

Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1558923

Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1558922
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
394975001 2016009988
394975002 2016009989
394975003 2016009990
1203525866 Method Blank (MB)ICP-MS
1203525867 Laboratory Control Sample (LCS)
1203525884 Laboratory Control Sample (LCS)
1203525870 394975001(2016009988L) Serial Dilution (SD)
1203525868 394975001(2016009988D) Sample Duplicate (DUP)
1203525869 394975001(2016009988S) Matrix Spike (MS)
1203525885 394975001(2016009988S) Matrix Spike (MS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Radiochemistry

Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1558974
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
394975001 2016009988
394975002 2016009989
Page 11 of 14
Page 26 of 52
394975003 2016009990
1203525965 Method Blank (MB)
1203525966 394975003(2016009990) Sample Duplicate (DUP)
1203525967 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Technical Information

Recounts
Samples 394975001 (2016009988) and 394975002 (2016009989) were re-eluted to verify sample results. The
re-eluted counts are reported.

Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1558964
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
394975001 2016009988
394975002 2016009989
394975003 2016009990
1203525932 Method Blank (MB)
1203525933 394975001(2016009988) Sample Duplicate (DUP)
1203525934 394975001(2016009988) Matrix Spike (MS)
1203525935 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Miscellaneous Information

Additional Comments
The matrix spike, 1203525934 (2016009988MS), aliquot was reduced to conserve sample volume.

Page 12 of 14
Page 27 of 52

Certification Statement

Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Page 13 of 14
Page 28 of 52
State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
North Dakota
Oklahoma
Pennsylvania NELAP
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-0110
88-0651
42D0904046
2940
SC00012
PH-0169
SC00012
2567.01
E87156
P330-15-00283, P330-15-00253
SC00012
967
SC00012
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA160006
270
M-SC012
9976
SC00012
NE-OS-26-13
SC000122016-1
205415
SC002
SC00012
11501
233
45709
R-158
9904
68-00485
10120002
10120001
TN 02934
T104704235-16-11
SC000122016-20
VT87156
460202
C780
997404
List of current GEL Certifications as of 18 April 2016
Page 14 of 14
Page 29 of 52
#=CL#
April 15, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92293223
92293223
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16040210
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on April 11, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Mary Ann Ogle, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 30 of 52
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92293223
J16040210
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
525 N 8th Street, Salina, KS 67401
A2LA Certification #: 2926.01
Alaska Certification #: UST-078
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Idaho Certification #: MN00064
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Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
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Louisiana DEQ Certification #: 3086
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Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
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Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
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Pennsylvania Certification #: 68-00563
Puerto Rico Certification
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Texas Certification #: T104704192
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Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
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Wisconsin Certification #: 999407970
Ormond Beach Certification IDs
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Delaware Certification: FL NELAC Reciprocity
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Hawaii Certification: FL NELAC Reciprocity
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Oklahoma Certification #: D9947
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Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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Page 31 of 52
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92293223
J16040210
Lab ID Sample ID Matrix Date Collected Date Received
92293223001 2016009988 Water 04/08/16 08:37 04/11/16 10:00
92293223002 2016009989 Water 04/08/16 10:04 04/11/16 10:00
92293223003 2016009990 Water 04/08/16 11:22 04/11/16 10:00
92293223004 2016009992 Water 04/08/16 12:05 04/11/16 10:00
REPORT OF LABORATORY ANALYSIS
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Page 32 of 52
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92293223
J16040210
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92293223001 2016009988 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OTK1
92293223002 2016009989 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OTK1
92293223003 2016009990 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OTK1
92293223004 2016009992 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AWRC
REPORT OF LABORATORY ANALYSIS
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Page 33 of 52
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92293223
J16040210
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92293223001 2016009988
Alkalinity,Bicarbonate (CaCO3)28.4 mg/L 04/13/16 12:525.0SM 2320B
Alkalinity, Total as CaCO3 28.4 mg/L 04/13/16 12:525.0SM 2320B
Chromium, Hexavalent 0.15 ug/L 04/13/16 18:540.030EPA 218.7
92293223003 2016009990
Methane 17.1 ug/L 04/13/16 22:3910.0RSK 175
Alkalinity,Bicarbonate (CaCO3)22.6 mg/L 04/13/16 13:385.0SM 2320B
Alkalinity, Total as CaCO3 22.6 mg/L 04/13/16 13:385.0SM 2320B
REPORT OF LABORATORY ANALYSIS
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Page 34 of 52
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92293223
J16040210
Method:
Client:Duke Energy
RSK 175
Date:April 15, 2016
Description:RSK 175 AIR Headspace
General Information:
4 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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Page 35 of 52
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92293223
J16040210
Method:
Client:Duke Energy
SM 2320B
Date:April 15, 2016
Description:2320B Alkalinity
General Information:
4 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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Page 7 of 22
Page 36 of 52
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92293223
J16040210
Method:
Client:Duke Energy
SM 4500-S2D
Date:April 15, 2016
Description:4500S2D Sulfide Water
General Information:
4 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WET/44192
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92293169003,92293223002
M3: Matrix spike recovery was outside laboratory control limits due to matrix interferences.
• MS (Lab ID: 1708516)
• Sulfide
• MSD (Lab ID: 1708517)
• Sulfide
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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Page 37 of 52
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92293223
J16040210
Method:
Client:Duke Energy
EPA 218.7
Date:April 15, 2016
Description:Hexavalent Chromium by IC
General Information:
3 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WETA/56791
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92293144001,92293219004
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1538578)
• Chromium, Hexavalent
• MSD (Lab ID: 1538577)
• Chromium, Hexavalent
• MSD (Lab ID: 1538579)
• Chromium, Hexavalent
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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Page 38 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92293223
J16040210
Sample:2016009988 Lab ID:92293223001 Collected:04/08/16 08:37 Received:04/11/16 10:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 04/13/16 22:22 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)28.4 mg/L 04/13/16 12:525.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/13/16 12:525.0 1
Alkalinity, Total as CaCO3 28.4 mg/L 04/13/16 12:525.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/13/16 17:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.15 ug/L 04/13/16 18:54 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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Page 10 of 22
Page 39 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92293223
J16040210
Sample:2016009989 Lab ID:92293223002 Collected:04/08/16 10:04 Received:04/11/16 10:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 04/13/16 22:30 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 04/13/16 13:295.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/13/16 13:295.0 1
Alkalinity, Total as CaCO3 ND mg/L 04/13/16 13:295.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/13/16 17:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 04/13/16 19:07 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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Page 11 of 22
Page 40 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92293223
J16040210
Sample:2016009990 Lab ID:92293223003 Collected:04/08/16 11:22 Received:04/11/16 10:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane 17.1 ug/L 04/13/16 22:39 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)22.6 mg/L 04/13/16 13:385.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/13/16 13:385.0 1
Alkalinity, Total as CaCO3 22.6 mg/L 04/13/16 13:385.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/13/16 17:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 04/13/16 19:20 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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Page 12 of 22
Page 41 of 52
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92293223
J16040210
Sample:2016009992 Lab ID:92293223004 Collected:04/08/16 12:05 Received:04/11/16 10:00 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 04/13/16 22:47 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 04/13/16 13:505.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/13/16 13:505.0 1
Alkalinity, Total as CaCO3 ND mg/L 04/13/16 13:505.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/13/16 17:00 18496-25-80.10 1
REPORT OF LABORATORY ANALYSIS
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Page 42 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92293223
J16040210
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/25684
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92293223001, 92293223002, 92293223003, 92293223004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2230656
Associated Lab Samples:92293223001, 92293223002, 92293223003, 92293223004
Matrix:Water
Analyzed
Methane ug/L ND 10.0 04/13/16 20:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2230657LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2230658
Methane ug/L 57.360.7 94 85-1159557.4 0 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92293173008
2231610SAMPLE DUPLICATE:
Methane ug/L 1.8J 202.0J
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92293219004
2231611SAMPLE DUPLICATE:
Methane ug/L 4.8J 20ND
REPORT OF LABORATORY ANALYSIS
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Page 14 of 22
Page 43 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92293223
J16040210
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/44167
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92293223001, 92293223002, 92293223003, 92293223004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1707437
Associated Lab Samples:92293223001, 92293223002, 92293223003, 92293223004
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 04/13/16 12:30
Alkalinity, Total as CaCO3 mg/L ND 5.0 04/13/16 12:30
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 04/13/16 12:30
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1707438LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 47.850 96 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1707439MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293223001
1707440
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 94 80-12094 0 255028.4 75.6 75.4
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1707441MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293169002
1707442
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 92 80-12098 3 255051.1 97.1 99.9
REPORT OF LABORATORY ANALYSIS
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Page 15 of 22
Page 44 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92293223
J16040210
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/44191
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92293223001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1708503
Associated Lab Samples:92293223001
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 04/13/16 17:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1708504LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.52.5 104 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1708505MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293023005
1708506
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 91 90-11091 0 10.5ND 0.46 0.46
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1708507MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293130003
1708508
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 92 90-11092 0 10.5ND 0.46 0.46
REPORT OF LABORATORY ANALYSIS
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Page 45 of 52
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92293223
J16040210
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/44192
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92293223002, 92293223003, 92293223004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1708512
Associated Lab Samples:92293223002, 92293223003, 92293223004
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 04/13/16 17:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1708513LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.52.5 104 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1708514MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293223002
1708515
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 94 90-11094 0 10.5ND 0.47 0.47
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1708516MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293169003
1708517
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L M3.5 0 90-1100 10.5ND ND ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/15/2016 10:19 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 22
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92293223
J16040210
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/56791
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92293223001, 92293223002, 92293223003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1538574
Associated Lab Samples:92293223001, 92293223002, 92293223003
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 04/13/16 13:42
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1538575LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.068.075 91 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1538576MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293144001
1538577
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.025 85 85-11578 20.025ND .021J .02J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1538578MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293219004
1538579
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.075 77 85-11578 2 20.075ND 0.058 0.059
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/15/2016 10:19 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 22
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92293223
J16040210
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - MinneapolisPASI-M
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Matrix spike recovery was outside laboratory control limits due to matrix interferences.M3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/15/2016 10:19 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 22
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92293223
J16040210
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92293223001 AIR/256842016009988RSK 175
92293223002 AIR/256842016009989RSK 175
92293223003 AIR/256842016009990RSK 175
92293223004 AIR/256842016009992RSK 175
92293223001 WET/441672016009988SM 2320B
92293223002 WET/441672016009989SM 2320B
92293223003 WET/441672016009990SM 2320B
92293223004 WET/441672016009992SM 2320B
92293223001 WET/441912016009988SM 4500-S2D
92293223002 WET/441922016009989SM 4500-S2D
92293223003 WET/441922016009990SM 4500-S2D
92293223004 WET/441922016009992SM 4500-S2D
92293223001 WETA/567912016009988EPA 218.7
92293223002 WETA/567912016009989EPA 218.7
92293223003 WETA/567912016009990EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/15/2016 10:19 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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