NC0000396_App B Lab Reports - CAMA BKGD - J16040163report_20160831

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16040163
Project Name:ASHEVILLE - AB GW ASSESSMENT WATER
Lab Contact:Mary Ann Ogle
Date:4/18/2016
Customer Address:200 CP and L Drive
Customer Name(s):Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
Arden,NC 28704
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Mary Ann Ogle
Page 1 of 54
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016009888 ASHEVILLE 07-Apr-16 9:44 AM illegible CB-1
2016009889 ASHEVILLE 07-Apr-16 12:12 PM illegible MW-11
2016009890 ASHEVILLE 07-Apr-16 1:42 PM illegible MW-11D
2016009891 ASHEVILLE 07-Apr-16 3:22 PM illegible MW-15A
2016009892 ASHEVILLE 07-Apr-16 illegible Filter Blank
2016009893 ASHEVILLE 07-Apr-16 4:20 PM illegible Equipment Blank
6 Total Samples
Page 2 of 54
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:4/18/2016
Electronic Data Deliverable (EDD) Sent Separately
Page 3 of 54
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040163
2016009888
Collection Date:07-Apr-16 9:44 AM
Site:CB-1
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.399 mg-N/L EPA 353.2 04/09/2016 12:30 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/11/2016 14:33 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.047 mg/L EPA 200.7 04/09/2016 12:08 JJMACKE0.005 1
Barium (Ba)0.016 mg/L EPA 200.7 04/09/2016 12:08 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/09/2016 12:08 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/09/2016 12:08 JJMACKE0.01 1
Manganese (Mn)0.022 mg/L EPA 200.7 04/09/2016 12:08 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 04/09/2016 12:08 JJMACKE0.005 1
Zinc (Zn)0.031 mg/L EPA 200.7 04/09/2016 12:08 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/10/2016 17:35 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/10/2016 17:35 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/10/2016 17:35 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/10/2016 17:35 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/10/2016 17:35 MHALL311
Cobalt (Co)1.85 ug/L EPA 200.8 04/10/2016 17:35 MHALL311
Copper (Cu)11.2 ug/L EPA 200.8 04/10/2016 17:35 MHALL311
Lead (Pb)1.53 ug/L EPA 200.8 04/10/2016 17:35 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/10/2016 17:35 MHALL311
Nickel (Ni)1.27 ug/L EPA 200.8 04/10/2016 17:35 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/10/2016 17:35 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/10/2016 17:35 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/10/2016 17:35 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Total Carbon
TOC 0.121 mg/L SM5310C/EPA9060A 04/08/2016 14:05 CJELLIO0.1 1
Page 4 of 54
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040163
2016009889
Collection Date:07-Apr-16 12:12 PM
Site:MW-11
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)1.4 mg-N/L EPA 353.2 04/09/2016 12:31 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 97 mg/L EPA 300.0 04/12/2016 00:53 BGN9034220
Sulfate 28 mg/L EPA 300.0 04/12/2016 00:53 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/11/2016 13:25 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/11/2016 14:35 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.076 mg/L EPA 200.7 04/09/2016 12:12 JJMACKE0.005 1
Barium (Ba)0.078 mg/L EPA 200.7 04/09/2016 12:12 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/09/2016 12:12 JJMACKE0.05 1
Iron (Fe)0.011 mg/L EPA 200.7 04/09/2016 12:12 JJMACKE0.01 1
Manganese (Mn)0.177 mg/L EPA 200.7 04/09/2016 12:12 JJMACKE0.005 1
Strontium (Sr)0.119 mg/L EPA 200.7 04/09/2016 12:12 JJMACKE0.005 1
Zinc (Zn)0.018 mg/L EPA 200.7 04/09/2016 12:12 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)23.8 mg/L EPA 200.7 04/08/2016 11:54 JJMACKE0.01 1
Magnesium (Mg)11.4 mg/L EPA 200.7 04/08/2016 11:54 JJMACKE0.005 1
Potassium (K)1.07 mg/L EPA 200.7 04/08/2016 11:54 JJMACKE0.1 1
Sodium (Na)38.4 mg/L EPA 200.7 04/08/2016 11:54 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.098 mg/L EPA 200.7 04/11/2016 15:39 JJMACKE0.005 1
Barium (Ba)0.088 mg/L EPA 200.7 04/11/2016 15:39 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/11/2016 15:39 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/11/2016 15:39 JJMACKE0.01 1
Manganese (Mn)0.281 mg/L EPA 200.7 04/11/2016 15:39 JJMACKE0.005 1
Strontium (Sr)0.125 mg/L EPA 200.7 04/11/2016 15:39 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/11/2016 15:39 JJMACKE0.005 1
Page 5 of 54
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040163
2016009889
Collection Date:07-Apr-16 12:12 PM
Site:MW-11
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/10/2016 17:57 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/10/2016 17:57 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/10/2016 17:57 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/10/2016 17:57 MHALL311
Chromium (Cr)1.72 ug/L EPA 200.8 04/10/2016 17:57 MHALL311
Cobalt (Co)1.02 ug/L EPA 200.8 04/10/2016 17:57 MHALL311
Copper (Cu)5.72 ug/L EPA 200.8 04/10/2016 17:57 MHALL311
Lead (Pb)1.57 ug/L EPA 200.8 04/10/2016 17:57 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/10/2016 17:57 MHALL311
Nickel (Ni)1.40 ug/L EPA 200.8 04/10/2016 17:57 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/10/2016 17:57 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/10/2016 17:57 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/10/2016 17:57 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/09/2016 16:59 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/09/2016 16:59 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/09/2016 16:59 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/09/2016 16:59 MHALL311
Chromium (Cr)2.89 ug/L EPA 200.8 04/09/2016 16:59 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/09/2016 16:59 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 04/09/2016 16:59 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/09/2016 16:59 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/09/2016 16:59 MHALL311
Nickel (Ni)2.54 ug/L EPA 200.8 04/09/2016 16:59 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/09/2016 16:59 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/09/2016 16:59 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/09/2016 16:59 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 220 mg/L SM2540C 04/13/2016 13:02 PARMSTR251
Total Carbon
TOC 1.1 mg/L SM5310C/EPA9060A 04/08/2016 14:05 CJELLIO0.1 1
Page 6 of 54
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040163
2016009889
Collection Date:07-Apr-16 12:12 PM
Site:MW-11
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/13/2016 10:30 PARMSTR51
Page 7 of 54
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040163
2016009890
Collection Date:07-Apr-16 1:42 PM
Site:MW-11D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)2.4 mg-N/L EPA 353.2 04/09/2016 12:43 LSTARL10.05 5
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 160 mg/L EPA 300.0 04/12/2016 02:32 BGN90342.5 25
Sulfate 13 mg/L EPA 300.0 04/12/2016 02:32 BGN90340.5 5
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/11/2016 13:27 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/11/2016 14:38 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.117 mg/L EPA 200.7 04/09/2016 12:16 JJMACKE0.005 1
Barium (Ba)0.304 mg/L EPA 200.7 04/09/2016 12:16 JJMACKE0.005 1
Boron (B)0.059 mg/L EPA 200.7 04/09/2016 12:16 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/09/2016 12:16 JJMACKE0.01 1
Manganese (Mn)0.142 mg/L EPA 200.7 04/09/2016 12:16 JJMACKE0.005 1
Strontium (Sr)0.339 mg/L EPA 200.7 04/09/2016 12:16 JJMACKE0.005 1
Zinc (Zn)0.019 mg/L EPA 200.7 04/09/2016 12:16 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)33.0 mg/L EPA 200.7 04/08/2016 11:58 JJMACKE0.01 1
Magnesium (Mg)14.4 mg/L EPA 200.7 04/08/2016 11:58 JJMACKE0.005 1
Potassium (K)3.71 mg/L EPA 200.7 04/08/2016 11:58 JJMACKE0.1 1
Sodium (Na)42.9 mg/L EPA 200.7 04/08/2016 11:58 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.161 mg/L EPA 200.7 04/11/2016 16:10 JJMACKE0.005 1
Barium (Ba)0.307 mg/L EPA 200.7 04/11/2016 16:10 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/11/2016 16:10 JJMACKE0.05 1
Iron (Fe)0.074 mg/L EPA 200.7 04/11/2016 16:10 JJMACKE0.01 1
Manganese (Mn)0.140 mg/L EPA 200.7 04/11/2016 16:10 JJMACKE0.005 1
Strontium (Sr)0.326 mg/L EPA 200.7 04/11/2016 16:10 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/11/2016 16:10 JJMACKE0.005 1
Page 8 of 54
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040163
2016009890
Collection Date:07-Apr-16 1:42 PM
Site:MW-11D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/10/2016 18:02 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/10/2016 18:02 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/10/2016 18:02 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/10/2016 18:02 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/10/2016 18:02 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/10/2016 18:02 MHALL311
Copper (Cu)8.85 ug/L EPA 200.8 04/10/2016 18:02 MHALL311
Lead (Pb)1.73 ug/L EPA 200.8 04/10/2016 18:02 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/10/2016 18:02 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 04/10/2016 18:02 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/10/2016 18:02 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/10/2016 18:02 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/10/2016 18:02 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/09/2016 16:10 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/09/2016 16:10 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/09/2016 16:10 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/09/2016 16:10 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/09/2016 16:10 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/09/2016 16:10 MHALL311
Copper (Cu)1.01 ug/L EPA 200.8 04/09/2016 16:10 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/09/2016 16:10 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/09/2016 16:10 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 04/09/2016 16:10 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/09/2016 16:10 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/09/2016 16:10 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/09/2016 16:10 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 380 mg/L SM2540C 04/13/2016 13:02 PARMSTR251
Total Carbon
TOC 0.429 mg/L SM5310C/EPA9060A 04/08/2016 14:05 CJELLIO0.1 1
Page 9 of 54
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040163
2016009890
Collection Date:07-Apr-16 1:42 PM
Site:MW-11D
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/13/2016 10:30 PARMSTR51
Page 10 of 54
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040163
2016009891
Collection Date:07-Apr-16 3:22 PM
Site:MW-15A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.132 mg-N/L EPA 353.2 04/09/2016 12:33 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 36 mg/L EPA 300.0 04/12/2016 02:48 BGN9034110
Sulfate 4.8 mg/L EPA 300.0 04/12/2016 02:48 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/11/2016 13:30 DMFRANC0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/11/2016 14:40 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.108 mg/L EPA 200.7 04/09/2016 12:35 JJMACKE0.005 1
Barium (Ba)0.080 mg/L EPA 200.7 04/09/2016 12:35 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/09/2016 12:35 JJMACKE0.05 1
Iron (Fe)0.058 mg/L EPA 200.7 04/09/2016 12:35 JJMACKE0.01 1
Manganese (Mn)0.727 mg/L EPA 200.7 04/09/2016 12:35 JJMACKE0.005 1
Strontium (Sr)0.090 mg/L EPA 200.7 04/09/2016 12:35 JJMACKE0.005 1
Zinc (Zn)0.018 mg/L EPA 200.7 04/09/2016 12:35 JJMACKE0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)6.26 mg/L EPA 200.7 04/08/2016 12:02 JJMACKE0.01 1
Magnesium (Mg)3.97 mg/L EPA 200.7 04/08/2016 12:02 JJMACKE0.005 1
Potassium (K)0.898 mg/L EPA 200.7 04/08/2016 12:02 JJMACKE0.1 1
Sodium (Na)11.0 mg/L EPA 200.7 04/08/2016 12:02 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.121 mg/L EPA 200.7 04/11/2016 16:14 JJMACKE0.005 1
Barium (Ba)0.083 mg/L EPA 200.7 04/11/2016 16:14 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/11/2016 16:14 JJMACKE0.05 1
Iron (Fe)0.063 mg/L EPA 200.7 04/11/2016 16:14 JJMACKE0.01 1
Manganese (Mn)0.673 mg/L EPA 200.7 04/11/2016 16:14 JJMACKE0.005 1
Strontium (Sr)0.090 mg/L EPA 200.7 04/11/2016 16:14 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/11/2016 16:14 JJMACKE0.005 1
Page 11 of 54
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040163
2016009891
Collection Date:07-Apr-16 3:22 PM
Site:MW-15A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/10/2016 18:08 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/10/2016 18:08 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/10/2016 18:08 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/10/2016 18:08 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/10/2016 18:08 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/10/2016 18:08 MHALL311
Copper (Cu)8.43 ug/L EPA 200.8 04/10/2016 18:08 MHALL311
Lead (Pb)1.62 ug/L EPA 200.8 04/10/2016 18:08 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/10/2016 18:08 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 04/10/2016 18:08 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/10/2016 18:08 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/10/2016 18:08 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/10/2016 18:08 MHALL30.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/09/2016 17:04 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/09/2016 17:04 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/09/2016 17:04 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/09/2016 17:04 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/09/2016 17:04 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/09/2016 17:04 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 04/09/2016 17:04 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/09/2016 17:04 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/09/2016 17:04 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 04/09/2016 17:04 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/09/2016 17:04 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/09/2016 17:04 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/09/2016 17:04 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
TOTAL DISSOLVED SOLIDS
TDS 69 mg/L SM2540C 04/13/2016 13:02 PARMSTR251
Total Carbon
TOC 0.334 mg/L SM5310C/EPA9060A 04/08/2016 14:05 CJELLIO0.1 1
Page 12 of 54
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040163
2016009891
Collection Date:07-Apr-16 3:22 PM
Site:MW-15A
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/13/2016 10:30 PARMSTR51
Page 13 of 54
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040163
2016009892
Collection Date:07-Apr-16
Site:Filter Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/11/2016 14:43 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 04/09/2016 12:46 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 04/09/2016 12:46 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/09/2016 12:46 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/09/2016 12:46 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 04/09/2016 12:46 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 04/09/2016 12:46 JJMACKE0.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 04/09/2016 12:46 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/10/2016 18:13 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/10/2016 18:13 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/10/2016 18:13 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/10/2016 18:13 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/10/2016 18:13 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/10/2016 18:13 MHALL311
Copper (Cu)5.01 ug/L EPA 200.8 04/10/2016 18:13 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/10/2016 18:13 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/10/2016 18:13 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 04/10/2016 18:13 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/10/2016 18:13 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/10/2016 18:13 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/10/2016 18:13 MHALL30.3 1
Page 14 of 54
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040163
2016009893
Collection Date:07-Apr-16 4:20 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/09/2016 12:35 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 04/11/2016 11:37 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 04/11/2016 11:37 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/11/2016 13:32 DMFRANC0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)< 0.01 mg/L EPA 200.7 04/08/2016 12:06 JJMACKE0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 04/08/2016 12:06 JJMACKE0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 04/08/2016 12:06 JJMACKE0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 04/08/2016 12:06 JJMACKE0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 04/11/2016 16:18 JJMACKE0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 04/11/2016 16:18 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/11/2016 16:18 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/11/2016 16:18 JJMACKE0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 04/11/2016 16:18 JJMACKE0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 04/11/2016 16:18 JJMACKE0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 04/11/2016 16:18 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 04/09/2016 17:09 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/09/2016 17:09 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/09/2016 17:09 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/09/2016 17:09 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/09/2016 17:09 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/09/2016 17:09 MHALL311
Copper (Cu)< 1 ug/L EPA 200.8 04/09/2016 17:09 MHALL311
Lead (Pb)< 1 ug/L EPA 200.8 04/09/2016 17:09 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/09/2016 17:09 MHALL311
Nickel (Ni)< 1 ug/L EPA 200.8 04/09/2016 17:09 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/09/2016 17:09 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/09/2016 17:09 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/09/2016 17:09 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Page 15 of 54
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040163
2016009893
Collection Date:07-Apr-16 4:20 PM
Site:Equipment Blank
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Total Carbon
TOC 0.138 mg/L SM5310C/EPA9060A 04/08/2016 14:05 CJELLIO0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 04/13/2016 10:30 PARMSTR51
Page 16 of 54

April 14, 2016

Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment Water
Work Order: 394930
SDG: J16040163

Dear Mary :
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on April 08, 2016. This original data report has been prepared and reviewed in accordance
with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 1142110 DPNNGO
Enclosures
Page 1 of 15
Page 17 of 54
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO002 Duke Energy
Client SDG: J16040163 GEL Work Order: 394930
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
N Metals--The Matrix spike sample recovery is not within specified control limits
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
for
Page 2 of 15
Page 18 of 54
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: April 14, 2016
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1558577
1558577
1558649
1558609
1824
1224
1126
0850
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
04/11/16
04/12/16
04/14/16
04/14/16
PRB
PRB
AXM6
CXP3
0.0002
0.00005
0.00005
0.00005
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterClient prefers Chem and RadChem on the same CoA excluding the uncertainty valueProject:
394930001
Water
07-APR-16 09:44
08-APR-16
2016009888 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"92.4 (15%-125%)
0.000067
0.00001
0.00001
0.00001
1.45
0.801
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 04/11/16 15585760800JXM5
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
14.4
NominalResult
RLDL
Notes:
Page 3 of 15
Page 19 of 54
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: April 14, 2016
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1558577
1558577
1558649
1558609
1826
1225
1124
0920
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
04/11/16
04/12/16
04/14/16
04/14/16
PRB
PRB
AXM6
CXP3
0.0002
0.00005
0.00005
0.00005
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterClient prefers Chem and RadChem on the same CoA excluding the uncertainty valueProject:
394930002
Water
07-APR-16 12:12
08-APR-16
2016009889 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"88.9 (15%-125%)
0.000067
0.00001
0.00001
0.00001
1.46
0.755
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 04/11/16 15585760800JXM5
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
2.19
1.31
NominalResult
RLDL
Notes:
Page 4 of 15
Page 20 of 54
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: April 14, 2016
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1558577
1558577
1558649
1558609
1828
1227
1124
0920
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
04/11/16
04/12/16
04/14/16
04/14/16
PRB
PRB
AXM6
CXP3
0.0002
0.00005
0.00005
0.00005
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterClient prefers Chem and RadChem on the same CoA excluding the uncertainty valueProject:
394930003
Water
07-APR-16 13:42
08-APR-16
2016009890 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"100 (15%-125%)
0.000067
0.00001
0.00001
0.00001
1.42
0.814
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 04/11/16 15585760800JXM5
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
J
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.0000844
ND
ND
ND
ND
3.53
NominalResult
RLDL
Notes:
Page 5 of 15
Page 21 of 54
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: April 14, 2016
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1558577
1558577
1558649
1558609
1829
1229
1124
0920
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
04/11/16
04/12/16
04/14/16
04/14/16
PRB
PRB
AXM6
CXP3
0.0002
0.00005
0.00005
0.00005
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterClient prefers Chem and RadChem on the same CoA excluding the uncertainty valueProject:
394930004
Water
07-APR-16 15:22
08-APR-16
2016009891 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"100 (15%-125%)
0.000067
0.00001
0.00001
0.00001
1.44
0.678
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 04/11/16 15585760800JXM5
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
ND
ND
1.76
NominalResult
RLDL
Notes:
Page 6 of 15
Page 22 of 54
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1558577Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Parmname
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, North Carolina
April 14, 2016Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
Anlst Date Time
PRB 04/12/16 12:10
04/11/16 18:09
04/11/16 18:06
04/12/16 12:06
04/12/16 12:05
04/11/16 18:04
04/11/16 18:11
04/12/16 12:12
04/12/16 12:13
QC
ND
ND
ND
0.000986
0.0531
0.000511
0.000595
0.0054
ND
ND
ND
ND
0.0518
0.000512
0.000598
0.00525
ND
NOM Sample
ND
ND
ND
0.000932
0.000932
ND
ND
ND
ND
Range
(+/-0.0002)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
U
U
QC1203524851 394929001
QC1203524849
QC1203524850
QC1203524848
QC1203524852 394929001
QC1203524853 394929001
QC1203524854 394929001
N/A
N/A
N/A
5.61
N/A
REC%
107
102
108
108
102
102
109
105
0.0496
0.0005
0.00055
0.005
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
MS
MS
SDILT
394930Workorder:
Mail Code: MGO3A2
U
U
U
U
U
U
U
^
RPD%
Page 1 of 3
Page 7 of 15
Page 23 of 54
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
Rad Ra-226
1558577
1558649
1558609
Batch
Batch
Batch
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-228
Radium-228
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
ug/L
ug/L
ug/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
PRB
AXM6
CXP3
04/12/16 12:13
04/11/16 18:14
04/14/16 11:26
04/14/16 11:26
04/14/16 11:26
04/14/16 09:20
04/14/16 09:55
04/14/16 09:20
04/14/16 09:55
QC
ND
ND
0.190
3.05
43.0
0.950
1.07
23.1
0.112
116
NOM Sample
ND
ND
0.932
1.67
2.16
2.16
Range
(0%-10%)
(0%-10%)
(0% - 100%)
(75%-125%)
(0% - 100%)
(75%-125%)
(75%-125%)
Qual
U
U
J
U
U
QC1203525064 394929003
QC1203525065
QC1203525063
QC1203524945 394929001
QC1203524947
QC1203524944
QC1203524946 394929001
The Qualifiers in this report are defined as follows:
N/A
N/A
1.89
58.7
67.4
REC%
92.3
94.5
93.3
46.6
24.4
122
DUP
LCS
MB
DUP
LCS
MB
MS
394930Workorder:
**
<
>
BD
E
FA
FB
H
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
U
U
RPD%
Notes:
Page 2 of 3
Page 8 of 15
Page 24 of 54
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 3 of 3
Units Anlst Date TimeQCNOMSampleRangeQualREC%
394930Workorder:
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
U
UI
UJ
UL
X
Y
^
h
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
Page 9 of 15
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Page 10 of 15
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Page 11 of 15
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Technical Case Narrative
Duke Energy (DUPO)
SDG #: J16040163
Work Order #: 394930

Metals

Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1558577

Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1558576
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
394930001 2016009888
394930002 2016009889
394930003 2016009890
394930004 2016009891
1203524848 Method Blank (MB)ICP-MS
1203524849 Laboratory Control Sample (LCS)
1203524850 Laboratory Control Sample (LCS)
1203524854 394929001(2016009880L) Serial Dilution (SD)
1203524851 394929001(2016009880D) Sample Duplicate (DUP)
1203524852 394929001(2016009880S) Matrix Spike (MS)
1203524853 394929001(2016009880S) Matrix Spike (MS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Radiochemistry

Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1558649
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
394930001 2016009888
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394930002 2016009889
394930003 2016009890
394930004 2016009891
1203525063 Method Blank (MB)
1203525064 394929003(2016009882) Sample Duplicate (DUP)
1203525065 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1558609
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
394930001 2016009888
394930002 2016009889
394930003 2016009890
394930004 2016009891
1203524944 Method Blank (MB)
1203524945 394929001(2016009880) Sample Duplicate (DUP)
1203524946 394929001(2016009880) Matrix Spike (MS)
1203524947 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Miscellaneous Information

Additional Comments
The matrix spike, 1203524946 (2016009880MS), aliquot was reduced to conserve sample volume.

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Certification Statement

Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Page 14 of 15
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State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
North Dakota
Oklahoma
Pennsylvania NELAP
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-0110
88-0651
42D0904046
2940
SC00012
PH-0169
SC00012
2567.01
E87156
P330-15-00283, P330-15-00253
SC00012
967
SC00012
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA160006
270
M-SC012
9976
SC00012
NE-OS-26-13
SC000122016-1
205415
SC002
SC00012
11501
233
45709
R-158
9904
68-00485
10120002
10120001
TN 02934
T104704235-16-11
SC000122016-20
VT87156
460202
C780
997404
List of current GEL Certifications as of 14 April 2016
Page 15 of 15
Page 31 of 54
#=CL#
April 14, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92293130
92293130
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16040163
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on April 08, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Mary Ann Ogle, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 22
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#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92293130
J16040163
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
525 N 8th Street, Salina, KS 67401
A2LA Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA #: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 22
Page 33 of 54
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92293130
J16040163
Lab ID Sample ID Matrix Date Collected Date Received
92293130001 2016009888 Water 04/07/16 09:44 04/08/16 14:46
92293130002 2016009889 Water 04/07/16 12:12 04/08/16 14:46
92293130003 2016009890 Water 04/07/16 13:42 04/08/16 14:46
92293130004 2016009891 Water 04/07/16 15:22 04/08/16 14:46
92293130005 2016009893 Water 04/07/16 16:20 04/08/16 14:46
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 22
Page 34 of 54
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92293130
J16040163
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92293130001 2016009888 RSK 175 1 PASI-MDR1
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OTK1
92293130002 2016009889 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OTK1
92293130003 2016009890 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OTK1
92293130004 2016009891 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OTK1
92293130005 2016009893 RSK 175 1 PASI-MDR1
SM 2320B 3 PASI-ATEP
SM 4500-S2D 1 PASI-AWRC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 22
Page 35 of 54
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92293130
J16040163
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92293130002 2016009889
Alkalinity,Bicarbonate (CaCO3)25.0 mg/L 04/11/16 16:025.0SM 2320B
Alkalinity, Total as CaCO3 25.0 mg/L 04/11/16 16:025.0SM 2320B
Chromium, Hexavalent 0.41 ug/L 04/14/16 08:220.060EPA 218.7
92293130003 2016009890
Alkalinity,Bicarbonate (CaCO3)7.0 mg/L 04/11/16 16:135.0SM 2320B
Alkalinity, Total as CaCO3 7.0 mg/L 04/11/16 16:135.0SM 2320B
Chromium, Hexavalent 0.13 ug/L 04/13/16 15:260.030EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 22
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#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92293130
J16040163
Method:
Client:Duke Energy
RSK 175
Date:April 14, 2016
Description:RSK 175 AIR Headspace
General Information:
5 samples were analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 22
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#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92293130
J16040163
Method:
Client:Duke Energy
SM 2320B
Date:April 14, 2016
Description:2320B Alkalinity
General Information:
4 samples were analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 22
Page 38 of 54
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92293130
J16040163
Method:
Client:Duke Energy
SM 4500-S2D
Date:April 14, 2016
Description:4500S2D Sulfide Water
General Information:
5 samples were analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 22
Page 39 of 54
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92293130
J16040163
Method:
Client:Duke Energy
EPA 218.7
Date:April 14, 2016
Description:Hexavalent Chromium by IC
General Information:
4 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WETA/56791
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92293144001,92293219004
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1538578)
• Chromium, Hexavalent
• MSD (Lab ID: 1538577)
• Chromium, Hexavalent
• MSD (Lab ID: 1538579)
• Chromium, Hexavalent
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 22
Page 40 of 54
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92293130
J16040163
Sample:2016009888 Lab ID:92293130001 Collected:04/07/16 09:44 Received:04/08/16 14:46 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 04/12/16 20:46 74-82-810.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/13/16 17:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 04/13/16 15:00 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/14/2016 03:30 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 22
Page 41 of 54
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92293130
J16040163
Sample:2016009889 Lab ID:92293130002 Collected:04/07/16 12:12 Received:04/08/16 14:46 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 04/12/16 20:54 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)25.0 mg/L 04/11/16 16:025.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/11/16 16:025.0 1
Alkalinity, Total as CaCO3 25.0 mg/L 04/11/16 16:025.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/13/16 17:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.41 ug/L 04/14/16 08:22 18540-29-90.060 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/14/2016 03:30 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 22
Page 42 of 54
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92293130
J16040163
Sample:2016009890 Lab ID:92293130003 Collected:04/07/16 13:42 Received:04/08/16 14:46 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 04/12/16 21:03 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)7.0 mg/L 04/11/16 16:135.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/11/16 16:135.0 1
Alkalinity, Total as CaCO3 7.0 mg/L 04/11/16 16:135.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/13/16 17:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.13 ug/L 04/13/16 15:26 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/14/2016 03:30 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 22
Page 43 of 54
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92293130
J16040163
Sample:2016009891 Lab ID:92293130004 Collected:04/07/16 15:22 Received:04/08/16 14:46 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 04/12/16 21:11 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 04/11/16 16:425.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/11/16 16:425.0 1
Alkalinity, Total as CaCO3 ND mg/L 04/11/16 16:425.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/13/16 17:00 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent ND ug/L 04/13/16 15:39 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/14/2016 03:30 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 22
Page 44 of 54
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92293130
J16040163
Sample:2016009893 Lab ID:92293130005 Collected:04/07/16 16:20 Received:04/08/16 14:46 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 04/12/16 21:19 74-82-810.0 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity,Bicarbonate (CaCO3)ND mg/L 04/11/16 16:515.0 1
Alkalinity, Carbonate (CaCO3)ND mg/L 04/11/16 16:515.0 1
Alkalinity, Total as CaCO3 ND mg/L 04/11/16 16:515.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/13/16 17:00 18496-25-80.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/14/2016 03:30 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 22
Page 45 of 54
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92293130
J16040163
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/25676
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92293130001, 92293130002, 92293130003, 92293130004, 92293130005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2229612
Associated Lab Samples:92293130001, 92293130002, 92293130003, 92293130004, 92293130005
Matrix:Water
Analyzed
Methane ug/L ND 10.0 04/12/16 20:05
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2229613LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2229614
Methane ug/L 58.860.7 97 85-11510261.6 5 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92293138002
2230460SAMPLE DUPLICATE:
Methane ug/L 4.9J 203.9J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/14/2016 03:30 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 22
Page 46 of 54
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92293130
J16040163
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/44149
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92293130002, 92293130003, 92293130004, 92293130005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1706782
Associated Lab Samples:92293130002, 92293130003, 92293130004, 92293130005
Matrix:Water
Analyzed
Alkalinity, Carbonate (CaCO3)mg/L ND 5.0 04/11/16 14:33
Alkalinity, Total as CaCO3 mg/L ND 5.0 04/11/16 14:33
Alkalinity,Bicarbonate (CaCO3)mg/L ND 5.0 04/11/16 14:33
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1706783LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 mg/L 50.950 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1706784MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293023011
1706785
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 95 80-120101 2 2550141188191
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1706786MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293138003
1706787
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 mg/L 50 99 80-12099 0 255036.4 85.7 85.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/14/2016 03:30 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 22
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92293130
J16040163
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/44191
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92293130001, 92293130002, 92293130003, 92293130004, 92293130005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1708503
Associated Lab Samples:92293130001, 92293130002, 92293130003, 92293130004, 92293130005
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 04/13/16 17:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1708504LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.52.5 104 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1708505MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293023005
1708506
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 91 90-11091 0 10.5ND 0.46 0.46
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1708507MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293130003
1708508
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 92 90-11092 0 10.5ND 0.46 0.46
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/14/2016 03:30 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 22
Page 48 of 54
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92293130
J16040163
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/56791
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92293130001, 92293130002, 92293130003, 92293130004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1538574
Associated Lab Samples:92293130001, 92293130002, 92293130003, 92293130004
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 04/13/16 13:42
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1538575LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.068.075 91 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1538576MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293144001
1538577
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.025 85 85-11578 20.025ND .021J .02J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1538578MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293219004
1538579
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.075 77 85-11578 2 20.075ND 0.058 0.059
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/14/2016 03:30 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 22
Page 49 of 54
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92293130
J16040163
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - MinneapolisPASI-M
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/14/2016 03:30 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 22
Page 50 of 54
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92293130
J16040163
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92293130001 AIR/256762016009888RSK 175
92293130002 AIR/256762016009889RSK 175
92293130003 AIR/256762016009890RSK 175
92293130004 AIR/256762016009891RSK 175
92293130005 AIR/256762016009893RSK 175
92293130002 WET/441492016009889SM 2320B
92293130003 WET/441492016009890SM 2320B
92293130004 WET/441492016009891SM 2320B
92293130005 WET/441492016009893SM 2320B
92293130001 WET/441912016009888SM 4500-S2D
92293130002 WET/441912016009889SM 4500-S2D
92293130003 WET/441912016009890SM 4500-S2D
92293130004 WET/441912016009891SM 4500-S2D
92293130005 WET/441912016009893SM 4500-S2D
92293130001 WETA/567912016009888EPA 218.7
92293130002 WETA/567912016009889EPA 218.7
92293130003 WETA/567912016009890EPA 218.7
92293130004 WETA/567912016009891EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/14/2016 03:30 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 22
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