NC0000396_App B Lab Reports - CAMA BKGD - J16040148report_20160831

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number:J16040148
Project Name:ASHEVILLE - AB GW ASSESSMENT WATER
Lab Contact:Mary Ann Ogle
Date:4/18/2016
Customer Address:200 CP and L Drive
Customer Name(s):Todd Plating, Brandon Russo, Fred Holt, Kathy Webb, John Toepfer, Tim Hunsu
Arden,NC 28704
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Mary Ann Ogle
Page 1 of 34
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2016009799 ASHEVILLE 06-Apr-16 2:41 PM illegible CB-9
1 Total Samples
Page 2 of 34
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:DBA Account Date:4/18/2016
Electronic Data Deliverable (EDD) Sent Separately
Page 3 of 34
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J16040148
2016009799
Collection Date:06-Apr-16 2:41 PM
Site:CB-9
Matrix:GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.251 mg-N/L EPA 353.2 04/07/2016 14:37 LSTARL10.01 1
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 04/11/2016 14:01 DMFRANC0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.022 mg/L EPA 200.7 04/09/2016 12:57 JJMACKE0.005 1
Barium (Ba)0.026 mg/L EPA 200.7 04/09/2016 12:57 JJMACKE0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 04/09/2016 12:57 JJMACKE0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 04/09/2016 12:57 JJMACKE0.01 1
Manganese (Mn)0.033 mg/L EPA 200.7 04/09/2016 12:57 JJMACKE0.005 1
Strontium (Sr)0.007 mg/L EPA 200.7 04/09/2016 12:57 JJMACKE0.005 1
Zinc (Zn)0.033 mg/L EPA 200.7 04/09/2016 12:57 JJMACKE0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 04/08/2016 19:05 MHALL311
Arsenic (As)< 1 ug/L EPA 200.8 04/08/2016 19:05 MHALL311
Beryllium (Be)< 1 ug/L EPA 200.8 04/08/2016 19:05 MHALL311
Cadmium (Cd)< 1 ug/L EPA 200.8 04/08/2016 19:05 MHALL311
Chromium (Cr)< 1 ug/L EPA 200.8 04/08/2016 19:05 MHALL311
Cobalt (Co)< 1 ug/L EPA 200.8 04/08/2016 19:05 MHALL311
Copper (Cu)10.6 ug/L EPA 200.8 04/08/2016 19:05 MHALL311
Lead (Pb)1.56 ug/L EPA 200.8 04/08/2016 19:05 MHALL311
Molybdenum (Mo)< 1 ug/L EPA 200.8 04/08/2016 19:05 MHALL311
Nickel (Ni)1.50 ug/L EPA 200.8 04/08/2016 19:05 MHALL311
Selenium (Se)< 1 ug/L EPA 200.8 04/08/2016 19:05 MHALL311
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/08/2016 19:05 MHALL30.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/08/2016 19:05 MHALL30.3 1
METHANE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
Total Carbon
TOC 0.161 mg/L SM5310C/EPA9060A 04/08/2016 14:05 CJELLIO0.1 1
Page 4 of 34

April 14, 2016

Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment Water
Work Order: 394827
SDG: J16040148

Dear Mary :
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on April 07, 2016. This original data report has been prepared and reviewed in accordance
with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 1250944 DPNNGO
Enclosures
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Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO002 Duke Energy
Client SDG: J16040148 GEL Work Order: 394827
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
for
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Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: April 14, 2016
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1558182
1558182
1558331
1558202
0215
1547
1436
0915
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
04/12/16
04/12/16
04/13/16
04/12/16
SKJ
PRB
AXM6
CXP3
0.00005
0.00005
0.00005
0.0002
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterClient prefers Chem and RadChem on the same CoA excluding the uncertainty valueProject:
394827001
Water
06-APR-16 14:41
07-APR-16
2016009799 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"89.9 (15%-125%)
0.00001
0.00001
0.00001
0.000067
1.64
0.476
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 04/08/16 15581640800JXM5
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
ND
ND
ND
0.00124
2.18
1.80
NominalResult
RLDL
Notes:
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1558182Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Parmname
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, North Carolina
April 14, 2016Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
Anlst Date Time
SKJ
PRB
SKJ
PRB
SKJ
04/12/16 02:23
04/12/16 15:52
04/12/16 15:45
04/12/16 02:13
04/12/16 02:12
04/12/16 15:43
04/12/16 15:53
04/12/16 02:24
04/12/16 02:26
QC
ND
ND
ND
0.0000759
0.0494
0.000537
0.000588
0.00468
ND
ND
ND
0.0000956
0.0492
0.000544
0.00059
0.00467
ND
NOM Sample
ND
ND
ND
0.000188
0.000188
ND
ND
ND
ND
Range
(+/-0.0002)
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
Qual
U
U
U
J
U
U
U
J
U
QC1203523785 394841001
QC1203523783
QC1203523784
QC1203523782
QC1203523786 394841001
QC1203523787 394841001
QC1203523788 394841001
N/A
N/A
N/A
85
N/A
REC%
99.5
107
107
93.7
98.7
109
107
93.4
0.0496
0.0005
0.00055
0.005
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
MS
MS
SDILT
394827Workorder:
Mail Code: MGO3A2
U
U
U
J
J
U
U
U
U
^
RPD%
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
Rad Ra-226
1558182
1558331
1558202
Batch
Batch
Batch
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-228
Radium-228
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
ug/L
ug/L
ug/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
SKJ
PRB
AXM6
CXP3
04/12/16 02:26
04/12/16 15:55
04/13/16 14:40
04/13/16 12:49
04/13/16 12:49
04/12/16 10:20
04/12/16 10:20
04/12/16 10:20
04/12/16 10:20
QC
ND
ND
ND
2.76
48.4
-0.271
1.62
23.6
0.284
116
NOM Sample
ND
ND
0.188
2.18
1.80
1.80
Range
(0%-10%)
(0%-10%)
(0% - 100%)
(75%-125%)
(0% - 100%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
QC1203524143 394827001
QC1203524144
QC1203524142
QC1203523834 394827001
QC1203523836
QC1203523833
QC1203523835 394827001
The Qualifiers in this report are defined as follows:
N/A
N/A
N/A
23.4
10.1
REC%
104
96.6
93.5
46.6
24.4
122
DUP
LCS
MB
DUP
LCS
MB
MS
394827Workorder:
**
<
>
BD
E
FA
FB
H
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
U
U
J
RPD%
Notes:
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 3 of 3
Units Anlst Date TimeQCNOMSampleRangeQualREC%
394827Workorder:
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
U
UI
UJ
UL
X
Y
^
h
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
Analyte was analyzed for, but not detected above the MDL, MDA, MDC or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
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Technical Case Narrative
Duke Energy (DUPO)
SDG #: J16040148
Work Order #: 394827

Metals

Product: Determination of Metals by ICP-MS
Analytical Method: SW846 3010A/6020A
Analytical Procedure: GL-MA-E-014 REV# 28
Analytical Batch: 1558182

Preparation Method: SW846 3010A
Preparation Procedure: GL-MA-E-008 REV# 18
Preparation Batch: 1558164
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
394827001 2016009799
1203523782 Method Blank (MB)ICP-MS
1203523783 Laboratory Control Sample (LCS)
1203523784 Laboratory Control Sample (LCS)
1203523788 394841001(2016009694L) Serial Dilution (SD)
1203523785 394841001(2016009694D) Sample Duplicate (DUP)
1203523786 394841001(2016009694S) Matrix Spike (MS)
1203523787 394841001(2016009694S) Matrix Spike (MS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

There are no exceptions, anomalies or deviations from the specified methods. All sample data provided in this
report met the acceptance criteria specified in the analytical methods and procedures for initial calibration,
continuing calibration, instrument controls and process controls where applicable.

Radiochemistry

Product: GFPC, Ra228, Liquid
Analytical Method: EPA 904.0/SW846 9320 Modified
Analytical Procedure: GL-RAD-A-009 REV# 17
Analytical Batch: 1558331
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
394827001 2016009799
1203524142 Method Blank (MB)
1203524143 394827001(2016009799) Sample Duplicate (DUP)
1203524144 Laboratory Control Sample (LCS)
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The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Technical Information

Recounts
Samples 1203524143 (2016009799DUP) and 394827001 (2016009799) were recounted due to high relative
percent difference/relative error ratio. The recounts are reported.

Product: Lucas Cell, Ra226, liquid
Analytical Method: EPA 903.1 Modified
Analytical Procedure: GL-RAD-A-008 REV# 14
Analytical Batch: 1558202
The following samples were analyzed using the above methods and analytical procedure(s).

GEL Sample ID# Client Sample Identification
394827001 2016009799
1203523833 Method Blank (MB)
1203523834 394827001(2016009799) Sample Duplicate (DUP)
1203523835 394827001(2016009799) Matrix Spike (MS)
1203523836 Laboratory Control Sample (LCS)

The samples in this SDG were analyzed on an "as received" basis.
Data Summary:

All sample data provided in this report met the acceptance criteria specified in the analytical methods and
procedures for initial calibration, continuing calibration, instrument controls and process controls where
applicable, with the following exceptions.

Miscellaneous Information

Additional Comments
The matrix spike, 1203523835 (2016009799MS), aliquot was reduced to conserve sample volume.

Certification Statement

Where the analytical method has been performed under NELAP certification, the analysis has met all of the
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requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
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State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
North Dakota
Oklahoma
Pennsylvania NELAP
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-0110
88-0651
42D0904046
2940
SC00012
PH-0169
SC00012
2567.01
E87156
P330-15-00283, P330-15-00253
SC00012
967
SC00012
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA160006
270
M-SC012
9976
SC00012
NE-OS-26-13
SC000122016-1
205415
SC002
SC00012
11501
233
45709
R-158
9904
68-00485
10120002
10120001
TN 02934
T104704235-16-11
SC000122016-20
VT87156
460202
C780
997404
List of current GEL Certifications as of 14 April 2016
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#=CL#
April 14, 2016
LIMS USE: FR - PROGRAM MANAGER
LIMS OBJECT ID: 92292984
92292984
Project:
Pace Project No.:
RE:
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
J16040148
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on April 07, 2016. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc:Program Manager, Duke Energy
Mary Ann Ogle, Duke Energy
Anne Pifer
Rodney Wike, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 16
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#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92292984
J16040148
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
525 N 8th Street, Salina, KS 67401
A2LA Certification #: 2926.01
Alaska Certification #: UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA #: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
Virginia/VELAP Certification #: Pace
Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 16
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92292984
J16040148
Lab ID Sample ID Matrix Date Collected Date Received
92292984001 2016009799 Water 04/06/16 14:41 04/07/16 15:15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 16
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#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92292984
J16040148
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92292984001 2016009799 RSK 175 1 PASI-MDR1
SM 4500-S2D 1 PASI-AWRC
EPA 218.7 1 PASI-OTK1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92292984
J16040148
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92292984001 2016009799
Chromium, Hexavalent 0.089 ug/L 04/13/16 15:520.030EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
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[phone]
Page 5 of 16
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#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92292984
J16040148
Method:
Client:Duke Energy
RSK 175
Date:April 14, 2016
Description:RSK 175 AIR Headspace
General Information:
1 sample was analyzed for RSK 175. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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[phone]
Page 6 of 16
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#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92292984
J16040148
Method:
Client:Duke Energy
SM 4500-S2D
Date:April 14, 2016
Description:4500S2D Sulfide Water
General Information:
1 sample was analyzed for SM 4500-S2D. All samples were received in acceptable condition with any exceptions noted below or on
the chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 16
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#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92292984
J16040148
Method:
Client:Duke Energy
EPA 218.7
Date:April 14, 2016
Description:Hexavalent Chromium by IC
General Information:
1 sample was analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: WETA/56791
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92293144001,92293219004
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1538578)
• Chromium, Hexavalent
• MSD (Lab ID: 1538577)
• Chromium, Hexavalent
• MSD (Lab ID: 1538579)
• Chromium, Hexavalent
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Huntersville, NC 28078
[phone]
Page 8 of 16
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92292984
J16040148
Sample:2016009799 Lab ID:92292984001 Collected:04/06/16 14:41 Received:04/07/16 15:15 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: RSK 175RSK 175 AIR Headspace
Methane ND ug/L 04/12/16 09:40 74-82-810.0 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND mg/L 04/12/16 19:30 18496-25-80.10 1
Analytical Method: EPA 218.7Hexavalent Chromium by IC
Chromium, Hexavalent 0.089 ug/L 04/13/16 15:52 18540-29-90.030 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/14/2016 11:00 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 16
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92292984
J16040148
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/25665
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples:92292984001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2228970
Associated Lab Samples:92292984001
Matrix:Water
Analyzed
Methane ug/L ND 10.0 04/12/16 06:28
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2228971LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2228972
Methane ug/L 59.560.7 98 85-1159758.6 2 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92292984001
2230336SAMPLE DUPLICATE:
Methane ug/L 1.4J 20ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92293020020
2230337SAMPLE DUPLICATE:
Methane ug/L 2.3J 202.2J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/14/2016 11:00 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 16
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92292984
J16040148
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/44159
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92292984001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1707185
Associated Lab Samples:92292984001
Matrix:Water
Analyzed
Sulfide mg/L ND 0.10 04/12/16 19:30
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1707186LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide mg/L 0.52.5 103 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1707187MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92292995005
1707188
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 93 90-11093 0 10.5ND 0.48 0.48
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1707189MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293027001
1707190
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide mg/L .5 103 90-110103 0 10.5ND 0.52 0.52
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/14/2016 11:00 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 16
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#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92292984
J16040148
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/56791
EPA 218.7
EPA 218.7
Chromium, Hexavalent IC
Associated Lab Samples:92292984001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1538574
Associated Lab Samples:92292984001
Matrix:Water
Analyzed
Chromium, Hexavalent ug/L ND 0.030 04/13/16 13:42
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1538575LABORATORY CONTROL SAMPLE:
LCSSpike
Chromium, Hexavalent ug/L 0.068.075 91 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1538576MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293144001
1538577
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.025 85 85-11578 20.025ND .021J .02J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1538578MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92293219004
1538579
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chromium, Hexavalent ug/L M1.075 77 85-11578 2 20.075ND 0.058 0.059
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/14/2016 11:00 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 16
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#=QL#
QUALIFIERS
Pace Project No.:
Project:
92292984
J16040148
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - MinneapolisPASI-M
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 04/14/2016 11:00 AM
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9800 Kincey Ave. Suite 100
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[phone]
Page 13 of 16
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92292984
J16040148
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92292984001 AIR/256652016009799RSK 175
92292984001 WET/441592016009799SM 4500-S2D
92292984001 WETA/567912016009799EPA 218.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 04/14/2016 11:00 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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