NC0001422_ATT 5 - Water - J15060658report_20150805

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number: J15060658
Project Name:SUTTON - AB GW ASSESSMENT WATER
Lab Contact:Mary Ann Ogle
Date:6/30/2015
Customer Address:
Customer Name(s): Perry Waldrep, Tim Hunsucker, Kathy Webb, John Toepfer
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Mary Ann Ogle
Analytical Lab
Page 1 of 47
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2015020187 Sutton 17-Jun-15 1:00 PM ILLEGIBLE ABMW-1D
2015020189 Sutton 17-Jun-15 12:40 PM ILLEGIBLE ABMW-1S
2015020190 Sutton 17-Jun-15 9:55 AM ILLEGIBLE Equipment Blank
2015020191 Sutton 17-Jun-15 9:55 AM ILLEGIBLE Filter Blank
4 Total Samples
Analytical Lab
Page 2 of 47
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Mary Ann Ogle Date:6/30/2015
Electronic Data Deliverable (EDD) Sent Separately
Analytical Lab
Page 3 of 47
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060658
2015020187
Collection Date: 17-Jun-15 1:00 PM
Site: ABMW-1D
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/26/2015 10:48 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 53 mg/L EPA 300.0 06/23/2015 15:04 BGN9034110
Sulfate 1.6 mg/L EPA 300.0 06/23/2015 15:04 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/19/2015 14:31 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/19/2015 15:12 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.010 mg/L EPA 200.7 06/22/2015 10:26 FCJORDA0.005 1
Barium (Ba)0.016 mg/L EPA 200.7 06/22/2015 10:26 FCJORDA0.005 1
Boron (B)0.176 mg/L EPA 200.7 06/22/2015 10:26 FCJORDA0.05 1
Iron (Fe)0.042 mg/L EPA 200.7 06/22/2015 10:26 FCJORDA0.01 1
Manganese (Mn)0.079 mg/L EPA 200.7 06/22/2015 10:26 FCJORDA0.005 1
Strontium (Sr)0.179 mg/L EPA 200.7 06/22/2015 10:26 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/22/2015 10:26 FCJORDA0.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)31.7 mg/L EPA 200.7 06/22/2015 12:29 FCJORDA0.01 1
Magnesium (Mg)9.84 mg/L EPA 200.7 06/22/2015 12:29 FCJORDA0.005 1
Potassium (K)5.75 mg/L EPA 200.7 06/22/2015 12:29 FCJORDA0.1 1
Sodium (Na)59.5 mg/L EPA 200.7 06/22/2015 12:29 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.052 mg/L EPA 200.7 06/23/2015 10:16 MHH71310.005 1
Barium (Ba)0.017 mg/L EPA 200.7 06/23/2015 10:16 MHH71310.005 1
Boron (B)0.167 mg/L EPA 200.7 06/23/2015 10:16 MHH71310.05 1
Iron (Fe)0.475 mg/L EPA 200.7 06/23/2015 10:16 MHH71310.01 1
Manganese (Mn)0.082 mg/L EPA 200.7 06/23/2015 10:16 MHH71310.005 1
Strontium (Sr)0.179 mg/L EPA 200.7 06/23/2015 10:16 MHH71310.005 1
Zinc (Zn)0.008 mg/L EPA 200.7 06/23/2015 10:16 MHH71310.005 1
Analytical Lab
Page 4 of 47
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060658
2015020187
Collection Date: 17-Jun-15 1:00 PM
Site: ABMW-1D
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/23/2015 05:12 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/23/2015 05:12 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/23/2015 05:12 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/23/2015 05:12 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/23/2015 05:12 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/23/2015 05:12 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/23/2015 05:12 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/23/2015 05:12 SLS256011
Molybdenum (Mo)8.78 ug/L EPA 200.8 06/23/2015 05:12 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/23/2015 05:12 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/23/2015 05:12 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/23/2015 05:12 SLS25600.2 1
Vanadium (V) Low Level 0.380 ug/L EPA 200.8 06/23/2015 05:12 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/23/2015 09:05 SLS256011
Arsenic (As)1.03 ug/L EPA 200.8 06/23/2015 09:05 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/23/2015 09:05 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/23/2015 09:05 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/23/2015 09:05 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/23/2015 09:05 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/23/2015 09:05 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/23/2015 09:05 SLS256011
Molybdenum (Mo)11.2 ug/L EPA 200.8 06/23/2015 09:05 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/23/2015 09:05 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/23/2015 09:05 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/23/2015 09:05 SLS25600.2 1
Vanadium (V) Low Level 0.642 ug/L EPA 200.8 06/23/2015 09:05 SLS25600.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 350 mg/L SM2540C 06/22/2015 14:30 AGIBBS5251
Total Carbon
TOC 40 mg/L SM5310C/EPA9060A 06/25/2015 12:17 GHUTCHI1.5 15
Analytical Lab
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Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060658
2015020187
Collection Date: 17-Jun-15 1:00 PM
Site: ABMW-1D
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL SUSPENDED SOLIDS
TSS 12 mg/L SM2540D 06/22/2015 07:54 AGIBBS551
Analytical Lab
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Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060658
2015020189
Collection Date: 17-Jun-15 12:40 PM
Site: ABMW-1S
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
Analytical Lab
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Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060658
2015020190
Collection Date: 17-Jun-15 9:55 AM
Site: Equipment Blank
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/26/2015 10:49 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 06/24/2015 09:34 BGN90340.1 1
Sulfate < 0.1 mg/L EPA 300.0 06/24/2015 09:34 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/19/2015 14:33 ACPAYNE0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)< 0.01 mg/L EPA 200.7 06/22/2015 12:41 FCJORDA0.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 06/22/2015 12:41 FCJORDA0.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 06/22/2015 12:41 FCJORDA0.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 06/22/2015 12:41 FCJORDA0.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.005 mg/L EPA 200.7 06/23/2015 10:21 MHH71310.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 06/23/2015 10:21 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/23/2015 10:21 MHH71310.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 06/23/2015 10:21 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 06/23/2015 10:21 MHH71310.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 06/23/2015 10:21 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/23/2015 10:21 MHH71310.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/23/2015 09:13 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/23/2015 09:13 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/23/2015 09:13 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/23/2015 09:13 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/23/2015 09:13 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/23/2015 09:13 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/23/2015 09:13 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/23/2015 09:13 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/23/2015 09:13 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/23/2015 09:13 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/23/2015 09:13 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/23/2015 09:13 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/23/2015 09:13 SLS25600.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
Analytical Lab
Page 8 of 47
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060658
2015020190
Collection Date: 17-Jun-15 9:55 AM
Site: Equipment Blank
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 06/22/2015 14:30 AGIBBS5251
Total Carbon
TOC 0.223 mg/L SM5310C/EPA9060A 06/25/2015 12:17 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 06/22/2015 07:54 AGIBBS551
Analytical Lab
Page 9 of 47
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060658
2015020191
Collection Date: 17-Jun-15 9:55 AM
Site: Filter Blank
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/19/2015 15:14 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 06/22/2015 10:29 FCJORDA0.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 06/22/2015 10:29 FCJORDA0.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/22/2015 10:29 FCJORDA0.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 06/22/2015 10:29 FCJORDA0.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 06/22/2015 10:29 FCJORDA0.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 06/22/2015 10:29 FCJORDA0.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/22/2015 10:29 FCJORDA0.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/23/2015 07:39 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/23/2015 07:39 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/23/2015 07:39 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/23/2015 07:39 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/23/2015 07:39 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/23/2015 07:39 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/23/2015 07:39 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/23/2015 07:39 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/23/2015 07:39 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/23/2015 07:39 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/23/2015 07:39 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/23/2015 07:39 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/23/2015 07:39 SLS25600.3 1
Analytical Lab
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June 29, 2015

Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment Water
Work Order: 375516
SDG: J15060658

Dear Mary :
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on June 22, 2015. This original data report has been prepared and reviewed in accordance
with GEL’s standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 1142110
Enclosures
Page 1 of 11
Analytical Lab
Page 17 of 47
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO002 Duke Energy
Client SDG: J15060658 GEL Work Order: 375516
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
for
Page 2 of 11
Analytical Lab
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Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: June 29, 2015
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1487792
1487792
1487751
1488322
1426
1622
1124
0730
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
06/25/15
06/25/15
06/26/15
06/29/15
SKJ
SKJ
AXM6
CXP3
0.0002
0.00005
0.00005
0.00005
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
375516001
Water
17-JUN-15 13:00
22-JUN-15
2015020187 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"92.3 (15%-125%)
0.000067
0.00001
0.00001
0.00001
1.25
0.526
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 06/23/15 14877911100JXM5
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
J
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.0000978
0.00
0.00
4.00E-06
2.00
0.651
NominalResult
RLDL
Notes:
Page 3 of 11
Analytical Lab
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Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: June 29, 2015
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1487792
1487792
1487751
1488322
1427
1623
1124
0730
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
06/25/15
06/25/15
06/26/15
06/29/15
SKJ
SKJ
AXM6
CXP3
0.0002
0.00005
0.00005
0.00005
3.00
1.00
DF
1
1
1
1
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
375516002
Water
17-JUN-15 12:40
22-JUN-15
2015020189 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"89.7 (15%-125%)
0.000067
0.00001
0.00001
0.00001
2.47
0.656
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 06/23/15 14877911100JXM5
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.0415
0.00
2.00E-06
2.00E-06
1.35
1.62
NominalResult
RLDL
Notes:
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QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1487792Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Parmname
Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, North Carolina
June 29, 2015Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
Anlst Date Time
SKJ 06/25/15 16:29
06/25/15 14:32
06/25/15 14:24
06/25/15 16:21
06/25/15 16:19
06/25/15 14:23
06/25/15 14:34
06/25/15 16:30
06/25/15 16:31
QC
ND
ND
ND
ND
0.0555
0.000517
0.000543
0.00575
ND
ND
ND
ND
0.0557
0.000529
0.000557
0.00589
ND
NOM Sample
ND
ND
ND
ND
ND
ND
ND
ND
ND
Range
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
U
U
U
QC1203342284 375519001
QC1203342283
QC1203342287
QC1203342282
QC1203342285 375519001
QC1203342288 375519001
QC1203342286 375519001
N/A
N/A
N/A
N/A
N/A
REC%
112
103
98.7
115
112
106
101
118
0.0496
0.0005
0.00055
0.005
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
MS
MS
SDILT
375516Workorder:
Mail Code: MGO3A2
U
U
U
U
U
U
U
U
U
RPD%
Page 1 of 3
Page 5 of 11
Analytical Lab
Page 21 of 47
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
Rad Ra-226
1487792
1487751
1488322
Batch
Batch
Batch
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-228
Radium-228
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
ug/L
ug/L
ug/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
SKJ
AXM6
CXP3
06/25/15 16:31
06/25/15 14:35
06/26/15 11:24
06/26/15 11:24
06/26/15 11:24
06/29/15 08:05
06/29/15 08:40
06/29/15 08:05
06/29/15 08:05
QC
ND
ND
ND
0.914
33.8
-0.42
0.893
25.1
0.474
118
NOM Sample
ND
ND
ND
-0.309
0.651
0.651
Range
(0%-10%)
(0%-10%)
N/A
(75%-125%)
(0% - 100%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
QC1203342157 375519002
QC1203342158
QC1203342156
QC1203343639 375516001
QC1203343641
QC1203343638
QC1203343640 375516001
The Qualifiers in this report are defined as follows:
N/A
N/A
N/A
N/A
31.3
REC%
110
102
95
30.7
24.7
124
DUP
LCS
MB
DUP
LCS
MB
MS
375516Workorder:
**
<
>
BD
E
FA
FB
H
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
U
U
U
U
RPD%
Notes:
Page 2 of 3
Page 6 of 11
Analytical Lab
Page 22 of 47
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 3 of 3
Units Anlst Date TimeQCNOMSampleRangeQualREC%
375516Workorder:
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
U
UI
UJ
UL
X
Y
^
h
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
Page 7 of 11
Analytical Lab
Page 23 of 47
Page 8 of 11
Analytical Lab
Page 24 of 47
Page 9 of 11
Analytical Lab
Page 25 of 47
State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
Oklahoma
Pennsylvania NELAP
Plant Material Permit
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-110
88-0651
42D0904046
2940 Interim
SC00012
PH-0169
SC000122013-10
2567.01
E87156
P330-12-00283, P330-12-00284
SC00012
967
SC000122013-10
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA150001
270
M-SC012
9976
SC000122013-10
NE-OS-26-13
SC000122014-1
2054
SC002
SC00012
11501
233
45709
9904
68-00485
PDEP-12-00260
10120002
10120001
TN 02934
T104704235-15-10
SC000122015-17
VT87156
460202
C780
997404
List of current GEL Certifications as of 29 June 2015
Page 10 of 11
Analytical Lab
Page 26 of 47
There are no "Data Exception Reports" associated with this analytical report.
Page 11 of 11
Analytical Lab
Page 27 of 47
SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
QF20016Lot Number:
J15060658Project Number:
AB GW Assessment Water - SuttonProject Name:
06/29/2015Date Completed:
Grant Wilton
Project Manager
*QF20016*

This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
Page: 1 of 8
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
Case Narrative
Duke Energy
Lot Number: QF20016
SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329
Project Name: AB GW Assessment Water - Sutton
Project Number: J15060658
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page.
Page: 2 of 8
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QF20016

Project Name: AB GW Assessment Water - Sutton
Project Number: J15060658
Sample Number Sample ID Matrix Date Sampled Date Received
001 06/17/2015 13002015020187Aqueous 06/20/2015
003 06/17/2015 09552015020190Aqueous 06/20/2015
(2 samples)
Page: 3 of 8
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QF20016

Project Name: AB GW Assessment Water - Sutton
Project Number: J15060658
Sample Sample ID Matrix Parameter Method Result Q Units Page
001 2015020187 Aqueous Alkalinity SM 2320B-140 mg/L 5
001 2015020187 Aqueous Bicarbonate Alkalinity SM 2320B-140 mg/L 5
001 2015020187 Aqueous Methane RSK - 175 1700 ug/L 6
(3 detections)
Page: 4 of 8
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015020187
QF20016-001
06/17/2015 1300
06/20/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060658
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 06/26/2015 1859 HMA 78167
1 (Bicarbonate ) SM 2320B-2011 1 06/26/2015 1859 HMA
1 (Carbonate Al) SM 2320B-2011 1 06/26/2015 1859 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 140 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 140 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 5 of 8
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015020187
QF20016-001
06/17/2015 1300
06/20/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060658
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 5 06/29/2015 1248 DCS 78365
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 1700 2ug/L50
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 6 of 8
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015020190
QF20016-003
06/17/2015 0955
06/20/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060658
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 06/26/2015 1904 HMA 78167
1 (Bicarbonate ) SM 2320B-2011 1 06/26/2015 1904 HMA
1 (Carbonate Al) SM 2320B-2011 1 06/26/2015 1904 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 ND 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 7 of 8
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015020190
QF20016-003
06/17/2015 0955
06/20/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060658
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/27/2015 1347 DCS 78294
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 8 of 8
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
QC Summary
QC Data for Lot Number: QF20016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals - MB
Batch:
Sample ID:QQ78167-001
78167
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Alkalinity ND 06/26/2015 162110mg/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF20016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals - LCS
Batch:
Sample ID:QQ78167-002
78167
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(mg/L)(mg/L)
Alkalinity 98 06/26/2015 16279810090-1101
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF20016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - MB
Batch:
Sample ID:QQ78294-001
78294
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Methane ND 06/27/2015 122810ug/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF20016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - LCS
Batch:
Sample ID:QQ78294-002
78294
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
Methane 120 06/27/2015 11567915070-1301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF20016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - LCSD
Batch:
Sample ID:QQ78294-003
78294
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
LimitDil(ug/L)(ug/L)
Methane 110 06/27/2015 12187315070-1308.5 301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF20016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - MB
Batch:
Sample ID:QQ78365-001
78365
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Methane ND 06/29/2015 101510ug/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF20016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - LCS
Batch:
Sample ID:QQ78365-002
78365
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
Methane 130 06/29/2015 09498315070-1301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF20016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - LCSD
Batch:
Sample ID:QQ78365-003
78365
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
LimitDil(ug/L)(ug/L)
Methane 110 06/29/2015 10027515070-13010 301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF20016
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
SHEALY ENVIRONMENTAL SERVICES, INC.

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
SHEALY ENVIRONMENTAL SERVICES, INC.
Shyly BnV lFUnMt'JnW I servviees, UW_
'rJncmn;nt Namber% r-A 16
Rnision Number.. I?
p4gto 1 a r
ReTlic s r 1IMP 14
Et%etiwe Dam; N;'3 l I
Sample Receipt Checklist (SRC-)
ti Cooler Inspected bye;date, l to 16 Lol #: Q F A! ] 6 [ �
Means of receipt-, SESI ❑ Clieric ©UPS ❑ FedEx ❑ Airbarne Exp Officr
Ycs �o 1. 17lireeusm-d $s � 85�r1t Gti ttl cooief':'
Yes ❑ =Vo ❑ I NA K 1 -2, ifcustody reels were present, were they intact and unbroken?
Cooler lDiOrigi.nal temperature upon receipllDeriverl (eoi7tcred) temperature upuu receipt:
Mt[hod: - -Temperature Blank ❑ Against Battles IR Gun ID: — IR{3unConvv1 t_Ln Fau1vr
Method of coolant: [ R'vt Ica Blue lee ❑ Dry ree ❑ None
ices ❑
No ❑
KA
3, 1f temperature of auv coaler rxr_ drd 6.0'C, was Project Manager ncdificd?
PKI ootified by SRC_, phone, note (circle one), other.
(For coolers rbe-eiver9 via c4mmercial courier, Phis are to be aolzified
inarncdiatcl .
Yes ❑
Yo
NA
A. is the uummertial ecmrier'a packin slip att=bed to chi& form?
yms
No ©
5, Were proper ci1qtody procedures relin ished,rrecirived followed?
Yes ❑
o ❑
NA
5 u'i = sygiples rehm uished by client to con menial courier?
Yes
©
i i. V e7r, sample IDs listed on theCOC?
Yes Ellyo
Cl
7. We= s= leIDs listed on all sample contairlers.1
: yc '
hen ❑
li- Was col loction date & tine listed ran the COC?
Yc�
N- ❑I
1 9 _ Was collection date &. time listed can all sautple containers?
Ye& MNo
10. Did all cortta ties label infomiation (ID, date, time.) agree with the COC?
Yes 31
-00 Cl
I
11. Wem tests to be pmforined listed on, t hf COC?
v
N,'� ❑
L
12. Did al I samples arrive in the proper containurs for each test?
❑
13. Did all containers arrive in good condition (unbmken, lids on, etc.)?
_es
Yes
No ❑
14. Was adequate scorn le ► coarse avaiIable?
Yes ❑No
15- Were. ail samples received within i/2 the holding time or 48 hour:&, %VLchever
cortles fust"?
Yes ❑
t o .
16. Mere ally sa.l>ta les eolxtaiaers wiwm ,,
VMS ❑
No
17. Were there any excess samples not listed on COC? �_
19. Wem hubhlea wam ent �°; e$-sire"(�f."€Ir6mm in dieter in an y VIIDA ,^ als?
Yi•s
Ito
NA ❑
cs ❑
Na ❑
NA Z
19. Wee. all metals/G&.C, NE,h1Vnutrient sails ies reocivcd at a p1l of <2?
Yes ❑
No ❑
NA
20. Were all cyanide and-ror sulfide samples received at a pH >12?
❑
r ❑
N
?1, Were Ill applicable NH1+TI�Noey;anide!pbenol (=0.2mpJL.) samples free of
residual chlorine?
Ycs d
No ❑
NA
22. Were collection temperatures doctimemed. on the C C for NC sum les?
Yes
Le2r.No
Nki ❑
NA
23. Were client rcmarks�'roquests (i.e_ rc qucstod. dilutions; N Sli«fSD desienation_g,
etc,..) corrcutl�r tratts+:ribcd from i1w CDC into t11c uari must section in I.1 4S?
24. Was the quote nu:nher used talon from the co ntainer label?
SamplePrve irrvaliort (MLUt t be 0C)rttp1eted foratly sample(s) inccrrectlyprerc"cd(rr wills h"abipaw.)
sample(s) vaerc received incorrectly pre5tned and were adjusted
accordingly In HMplc rCC lvin with H SDI HNO2 HC NaDH using SR #
Sam lc(s) were received with '-uhl5les >6 mm its dulmrtrr.
Sample(s) were received with TRC >0.2 piglL if 421 is No
SC Drinking Water Project Sample(s) pH veri tied to bt > 2 by
Sant lets) w"e net received at a pH of ;2 ,and were Adjusted accordingly using SR-k
Sample labels a lied by--- Verified by- mate: }
C.ornments:
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Analytical Lab
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