NC0001422_ATT 5 - Water - J15060424report_20150805

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number: J15060424
Project Name:SUTTON - AB GW ASSESSMENT WATER
Lab Contact:Mary Ann Ogle
Date:6/25/2015
Customer Address:
Customer Name(s): Perry Waldrep, Tim Hunsucker, Kathy Webb, John Toepfer
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Mary Ann Ogle
Analytical Lab
Page 1 of 38
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2015018968 Sutton 11-Jun-15 1:20 PM ILLEGIBLE AW-6E
2015018971 Sutton 11-Jun-15 5:25 PM ILLEGIBLE PZ-10D
2015018972 Sutton 11-Jun-15 5:15 PM ILLEGIBLE Filter Blank
2015018973 Sutton 11-Jun-15 5:15 PM ILLEGIBLE Equipment Blank
4 Total Samples
Analytical Lab
Page 2 of 38
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Mary Ann Ogle Date:6/25/2015
Electronic Data Deliverable (EDD) Sent Separately
Analytical Lab
Page 3 of 38
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060424
2015018968
Collection Date: 11-Jun-15 1:20 PM
Site: AW-6E
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/17/2015 13:02 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 490 mg/L EPA 300.0 06/17/2015 11:02 BGN9034550
Sulfate 120 mg/L EPA 300.0 06/17/2015 11:02 BGN90342.5 25
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/16/2015 14:26 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/16/2015 11:46 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.016 mg/L EPA 200.7 06/16/2015 11:24 MHALL30.005 1
Barium (Ba)0.005 mg/L EPA 200.7 06/16/2015 11:24 MHALL30.005 1
Boron (B)2.49 mg/L EPA 200.7 06/16/2015 11:24 MHALL30.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 06/16/2015 11:24 MHALL30.01 1
Manganese (Mn)0.016 mg/L EPA 200.7 06/16/2015 11:24 MHALL30.005 1
Strontium (Sr)0.161 mg/L EPA 200.7 06/16/2015 11:24 MHALL30.005 1
Zinc (Zn)0.052 mg/L EPA 200.7 06/16/2015 11:24 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)13.8 mg/L EPA 200.7 06/17/2015 11:31 MHALL30.1 10
Magnesium (Mg)10.1 mg/L EPA 200.7 06/17/2015 11:31 MHALL30.05 10
Potassium (K)25.7 mg/L EPA 200.7 06/17/2015 11:31 MHALL3110
Sodium (Na)536 mg/L EPA 200.7 06/17/2015 11:31 MHALL30.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.577 mg/L EPA 200.7 06/16/2015 15:15 MHALL30.005 1
Barium (Ba)0.008 mg/L EPA 200.7 06/16/2015 15:15 MHALL30.005 1
Boron (B)2.47 mg/L EPA 200.7 06/16/2015 15:15 MHALL30.05 1
Iron (Fe)0.704 mg/L EPA 200.7 06/16/2015 15:15 MHALL30.01 1
Manganese (Mn)0.024 mg/L EPA 200.7 06/16/2015 15:15 MHALL30.005 1
Strontium (Sr)0.174 mg/L EPA 200.7 06/16/2015 15:15 MHALL30.005 1
Zinc (Zn)0.063 mg/L EPA 200.7 06/16/2015 15:15 MHALL30.005 1
Analytical Lab
Page 4 of 38
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060424
2015018968
Collection Date: 11-Jun-15 1:20 PM
Site: AW-6E
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/22/2015 19:12 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/22/2015 19:12 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/22/2015 19:12 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/22/2015 19:12 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/22/2015 19:12 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/22/2015 19:12 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/22/2015 19:12 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/22/2015 19:12 SLS256011
Molybdenum (Mo)5.60 ug/L EPA 200.8 06/22/2015 19:12 SLS256011
Nickel (Ni)1.52 ug/L EPA 200.8 06/22/2015 19:12 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/22/2015 19:12 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/22/2015 19:12 SLS25600.2 1
Vanadium (V) Low Level 0.711 ug/L EPA 200.8 06/22/2015 19:12 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/22/2015 11:48 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/22/2015 11:48 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/22/2015 11:48 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/22/2015 11:48 SLS256011
Chromium (Cr)14.7 ug/L EPA 200.8 06/22/2015 11:48 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/22/2015 11:48 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/22/2015 11:48 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/22/2015 11:48 SLS256011
Molybdenum (Mo)6.63 ug/L EPA 200.8 06/22/2015 11:48 SLS256011
Nickel (Ni)7.53 ug/L EPA 200.8 06/22/2015 11:48 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/22/2015 11:48 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/22/2015 11:48 SLS25600.2 1
Vanadium (V) Low Level 1.77 ug/L EPA 200.8 06/22/2015 11:48 SLS25600.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 1500 mg/L SM2540C 06/16/2015 10:47 AGIBBS5251
Total Carbon
TOC 3.4 mg/L SM5310C/EPA9060A 06/24/2015 14:12 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS 33 mg/L SM2540D 06/15/2015 11:50 AGIBBS551
Analytical Lab
Page 5 of 38
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060424
2015018971
Collection Date: 11-Jun-15 5:25 PM
Site: PZ-10D
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/17/2015 13:03 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 120 mg/L EPA 300.0 06/16/2015 19:32 BGN90342.5 25
Sulfate 25 mg/L EPA 300.0 06/16/2015 19:32 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/16/2015 14:33 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/16/2015 11:49 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 06/16/2015 12:06 MHALL30.005 1
Barium (Ba)0.053 mg/L EPA 200.7 06/16/2015 12:06 MHALL30.005 1
Boron (B)0.363 mg/L EPA 200.7 06/16/2015 12:06 MHALL30.05 1
Iron (Fe)0.244 mg/L EPA 200.7 06/16/2015 12:06 MHALL30.01 1
Manganese (Mn)0.052 mg/L EPA 200.7 06/16/2015 12:06 MHALL30.005 1
Strontium (Sr)0.107 mg/L EPA 200.7 06/16/2015 12:06 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/16/2015 12:06 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)16.1 mg/L EPA 200.7 06/17/2015 11:27 MHALL30.1 10
Magnesium (Mg)7.38 mg/L EPA 200.7 06/17/2015 11:27 MHALL30.05 10
Potassium (K)5.04 mg/L EPA 200.7 06/17/2015 11:27 MHALL3110
Sodium (Na)114 mg/L EPA 200.7 06/17/2015 11:27 MHALL30.5 10
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.091 mg/L EPA 200.7 06/16/2015 15:26 MHALL30.005 1
Barium (Ba)0.055 mg/L EPA 200.7 06/16/2015 15:26 MHALL30.005 1
Boron (B)0.368 mg/L EPA 200.7 06/16/2015 15:26 MHALL30.05 1
Iron (Fe)0.347 mg/L EPA 200.7 06/16/2015 15:26 MHALL30.01 1
Manganese (Mn)0.053 mg/L EPA 200.7 06/16/2015 15:26 MHALL30.005 1
Strontium (Sr)0.109 mg/L EPA 200.7 06/16/2015 15:26 MHALL30.005 1
Zinc (Zn)0.015 mg/L EPA 200.7 06/16/2015 15:26 MHALL30.005 1
Analytical Lab
Page 6 of 38
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060424
2015018971
Collection Date: 11-Jun-15 5:25 PM
Site: PZ-10D
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/22/2015 19:41 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/22/2015 19:41 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/22/2015 19:41 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/22/2015 19:41 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/22/2015 19:41 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/22/2015 19:41 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/22/2015 19:41 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/22/2015 19:41 SLS256011
Molybdenum (Mo)2.45 ug/L EPA 200.8 06/22/2015 19:41 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/22/2015 19:41 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/22/2015 19:41 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/22/2015 19:41 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/22/2015 19:41 SLS25600.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/22/2015 11:05 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/22/2015 11:05 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/22/2015 11:05 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/22/2015 11:05 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/22/2015 11:05 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/22/2015 11:05 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/22/2015 11:05 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/22/2015 11:05 SLS256011
Molybdenum (Mo)2.38 ug/L EPA 200.8 06/22/2015 11:05 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/22/2015 11:05 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/22/2015 11:05 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/22/2015 11:05 SLS25600.2 1
Vanadium (V) Low Level 0.397 ug/L EPA 200.8 06/22/2015 11:05 SLS25600.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS 380 mg/L SM2540C 06/16/2015 10:47 AGIBBS5251
Total Carbon
TOC 1.5 mg/L SM5310C/EPA9060A 06/24/2015 14:12 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 06/15/2015 11:50 AGIBBS551
Analytical Lab
Page 7 of 38
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060424
2015018972
Collection Date: 11-Jun-15 5:15 PM
Site: Filter Blank
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/16/2015 11:51 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 06/16/2015 12:10 MHALL30.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 06/16/2015 12:10 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/16/2015 12:10 MHALL30.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 06/16/2015 12:10 MHALL30.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 06/16/2015 12:10 MHALL30.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 06/16/2015 12:10 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/16/2015 12:10 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/22/2015 19:48 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/22/2015 19:48 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/22/2015 19:48 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/22/2015 19:48 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/22/2015 19:48 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/22/2015 19:48 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/22/2015 19:48 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/22/2015 19:48 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/22/2015 19:48 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/22/2015 19:48 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/22/2015 19:48 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/22/2015 19:48 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/22/2015 19:48 SLS25600.3 1
Analytical Lab
Page 8 of 38
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060424
2015018973
Collection Date: 11-Jun-15 5:15 PM
Site: Equipment Blank
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.021 mg-N/L EPA 353.2 06/17/2015 13:04 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride < 0.1 mg/L EPA 300.0 06/16/2015 19:49 BGN90340.1 1
Sulfate 0.21 mg/L EPA 300.0 06/16/2015 19:49 BGN90340.1 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/16/2015 14:35 ACPAYNE0.05 1
UNDIGESTED METALS BY ICP
Calcium (Ca)< 0.01 mg/L EPA 200.7 06/17/2015 10:01 MHALL30.01 1
Magnesium (Mg)< 0.005 mg/L EPA 200.7 06/17/2015 10:01 MHALL30.005 1
Potassium (K)< 0.1 mg/L EPA 200.7 06/17/2015 10:01 MHALL30.1 1
Sodium (Na)< 0.05 mg/L EPA 200.7 06/17/2015 10:01 MHALL30.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)< 0.005 mg/L EPA 200.7 06/16/2015 15:30 MHALL30.005 1
Barium (Ba)< 0.005 mg/L EPA 200.7 06/16/2015 15:30 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/16/2015 15:30 MHALL30.05 1
Iron (Fe)0.022 mg/L EPA 200.7 06/16/2015 15:30 MHALL30.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 06/16/2015 15:30 MHALL30.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 06/16/2015 15:30 MHALL30.005 1
Zinc (Zn)0.263 mg/L EPA 200.7 06/16/2015 15:30 MHALL30.005 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/22/2015 11:56 SLS256011
Arsenic (As)< 1 ug/L EPA 200.8 06/22/2015 11:56 SLS256011
Beryllium (Be)< 1 ug/L EPA 200.8 06/22/2015 11:56 SLS256011
Cadmium (Cd)< 1 ug/L EPA 200.8 06/22/2015 11:56 SLS256011
Chromium (Cr)< 1 ug/L EPA 200.8 06/22/2015 11:56 SLS256011
Cobalt (Co)< 1 ug/L EPA 200.8 06/22/2015 11:56 SLS256011
Copper (Cu)< 1 ug/L EPA 200.8 06/22/2015 11:56 SLS256011
Lead (Pb)< 1 ug/L EPA 200.8 06/22/2015 11:56 SLS256011
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/22/2015 11:56 SLS256011
Nickel (Ni)< 1 ug/L EPA 200.8 06/22/2015 11:56 SLS256011
Selenium (Se)< 1 ug/L EPA 200.8 06/22/2015 11:56 SLS256011
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/22/2015 11:56 SLS25600.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/22/2015 11:56 SLS25600.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
Analytical Lab
Page 9 of 38
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060424
2015018973
Collection Date: 11-Jun-15 5:15 PM
Site: Equipment Blank
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 06/16/2015 10:47 AGIBBS5251
Total Carbon
TOC 0.163 mg/L SM5310C/EPA9060A 06/24/2015 14:12 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 06/15/2015 11:50 AGIBBS551
Analytical Lab
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SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
QF15008Lot Number:
J15060424Project Number:
AB GW Assessment Water - SuttonProject Name:
06/19/2015Date Completed:
Grant Wilton
Project Manager
*QF15008*

This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
Page: 1 of 10
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
Case Narrative
Duke Energy
Lot Number: QF15008
SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329
Project Name: AB GW Assessment Water - Sutton
Project Number: J15060424
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page.
Page: 2 of 10
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QF15008

Project Name: AB GW Assessment Water - Sutton
Project Number: J15060424
Sample Number Sample ID Matrix Date Sampled Date Received
001 06/11/2015 13202015018968Aqueous 06/15/2015
002 06/11/2015 17252015018971Aqueous 06/15/2015
003 06/11/2015 17152015018973Aqueous 06/15/2015
(3 samples)
Page: 3 of 10
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QF15008

Project Name: AB GW Assessment Water - Sutton
Project Number: J15060424
Sample Sample ID Matrix Parameter Method Result Q Units Page
001 2015018968 Aqueous Alkalinity SM 2320B-410 mg/L 5
001 2015018968 Aqueous Bicarbonate Alkalinity SM 2320B-400 mg/L 5
001 2015018968 Aqueous Methane RSK - 175 13 ug/L 6
002 2015018971 Aqueous Alkalinity SM 2320B-110 mg/L 7
002 2015018971 Aqueous Bicarbonate Alkalinity SM 2320B-110 mg/L 7
002 2015018971 Aqueous Methane RSK - 175 12 ug/L 8
003 2015018973 Aqueous Methane RSK - 175 11 ug/L 10
(7 detections)
Page: 4 of 10
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015018968
QF15008-001
06/11/2015 1320
06/15/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060424
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 06/17/2015 0333 HMA 77409
1 (Bicarbonate ) SM 2320B-2011 1 06/17/2015 0333 HMA
1 (Carbonate Al) SM 2320B-2011 1 06/17/2015 0333 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 410 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 400 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 5 of 10
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015018968
QF15008-001
06/11/2015 1320
06/15/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060424
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/18/2015 2304 JJG 77629
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 13 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 6 of 10
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015018971
QF15008-002
06/11/2015 1725
06/15/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060424
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 06/17/2015 0341 HMA 77409
1 (Bicarbonate ) SM 2320B-2011 1 06/17/2015 0341 HMA
1 (Carbonate Al) SM 2320B-2011 1 06/17/2015 0341 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 110 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 110 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 7 of 10
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015018971
QF15008-002
06/11/2015 1725
06/15/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060424
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/18/2015 2316 JJG 77629
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 12 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 8 of 10
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015018973
QF15008-003
06/11/2015 1715
06/15/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060424
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 06/17/2015 0346 HMA 77409
1 (Bicarbonate ) SM 2320B-2011 1 06/17/2015 0346 HMA
1 (Carbonate Al) SM 2320B-2011 1 06/17/2015 0346 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 ND 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 9 of 10
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015018973
QF15008-003
06/11/2015 1715
06/15/2015
Aqueous
Project Name: AB GW Assessment Water -
Project Number: J15060424
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/18/2015 2339 JJG 77629
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 11 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 10 of 10
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
QC Summary
QC Data for Lot Number: QF15008
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals - MB
Batch:
Sample ID:QQ77409-001
77409
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Alkalinity ND 06/17/2015 014910mg/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF15008
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals - LCS
Batch:
Sample ID:QQ77409-002
77409
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(mg/L)(mg/L)
Alkalinity 94 06/17/2015 01549410090-1101
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF15008
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - MB
Batch:
Sample ID:QQ77629-001
77629
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Methane ND 06/18/2015 163510ug/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF15008
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - LCS
Batch:
Sample ID:QQ77629-002
77629
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
Methane 44 06/18/2015 1554875070-1301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF15008
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - LCSD
Batch:
Sample ID:QQ77629-003
77629
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
LimitDil(ug/L)(ug/L)
Methane 41 06/18/2015 1614825070-1306.0 301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF15008
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
SHEALY ENVIRONMENTAL SERVICES, INC.

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
SHEALY ENVIRONMENTAL SERVICES, INC.

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Analytical Lab
Page 38 of 38