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HomeMy WebLinkAboutNC0001422_ATT 5 - Water - J15060408report_2015080513339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number: J15060408 Project Name:SUTTON - AB GW ASSESSMENT WATER Lab Contact:Mary Ann Ogle Date:6/26/2015 Customer Address: Customer Name(s): Perry Waldrep, Tim Hunsucker, Kathy Webb, John Toepfer Phone: 980-875-5274 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Mary Ann Ogle Analytical Lab Page 1 of 74 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015018820 Sutton 10-Jun-15 3:34 PM ILLEGIBLE MW-20 2015018821 Sutton 10-Jun-15 3:30 PM ILLEGIBLE MW-20D 2015018822 Sutton 10-Jun-15 3:55 PM ILLEGIBLE MW-20D DUP 2015018823 Sutton 10-Jun-15 12:14 PM ILLEGIBLE MW-16D 2015018824 Sutton 10-Jun-15 11:45 AM ILLEGIBLE MW-16 2015018825 Sutton 10-Jun-15 5:20 PM ILLEGIBLE MW-15 2015018826 Sutton 10-Jun-15 5:15 PM ILLEGIBLE MW-15D 2015018827 Sutton 11-Jun-15 11:10 AM ILLEGIBLE AW-3B 2015018828 Sutton 11-Jun-15 11:19 AM ILLEGIBLE AW-3C 2015018829 Sutton 10-Jun-15 6:18 PM ILLEGIBLE Filter Blank 2015018830 Sutton 10-Jun-15 6:18 PM ILLEGIBLE Equipment Blank 11 Total Samples Analytical Lab Page 2 of 74 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:Mary Ann Ogle Date:6/26/2015 Electronic Data Deliverable (EDD) Sent Separately Analytical Lab Page 3 of 74 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060408 2015018820 Collection Date: 10-Jun-15 3:34 PM Site: MW-20 Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/17/2015 13:40 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 26 mg/L EPA 300.0 06/15/2015 17:53 BGN9034110 Sulfate 45 mg/L EPA 300.0 06/15/2015 17:53 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/16/2015 13:30 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/18/2015 14:20 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.028 mg/L EPA 200.7 06/16/2015 10:42 MHALL30.005 1 Barium (Ba)0.059 mg/L EPA 200.7 06/16/2015 10:42 MHALL30.005 1 Boron (B)0.065 mg/L EPA 200.7 06/16/2015 10:42 MHALL30.05 1 Iron (Fe)0.607 mg/L EPA 200.7 06/16/2015 10:42 MHALL30.01 1 Manganese (Mn)0.114 mg/L EPA 200.7 06/16/2015 10:42 MHALL30.005 1 Strontium (Sr)0.356 mg/L EPA 200.7 06/16/2015 10:42 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/16/2015 10:42 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)49.1 mg/L EPA 200.7 06/17/2015 10:12 MHALL30.01 1 Magnesium (Mg)4.27 mg/L EPA 200.7 06/17/2015 10:12 MHALL30.005 1 Potassium (K)3.73 mg/L EPA 200.7 06/17/2015 10:12 MHALL30.1 1 Sodium (Na)20.5 mg/L EPA 200.7 06/17/2015 10:12 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.039 mg/L EPA 200.7 06/17/2015 10:46 MHH71310.005 1 Barium (Ba)0.055 mg/L EPA 200.7 06/17/2015 10:46 MHH71310.005 1 Boron (B)0.052 mg/L EPA 200.7 06/17/2015 10:46 MHH71310.05 1 Iron (Fe)0.747 mg/L EPA 200.7 06/17/2015 10:46 MHH71310.01 1 Manganese (Mn)0.107 mg/L EPA 200.7 06/17/2015 10:46 MHH71310.005 1 Strontium (Sr)0.350 mg/L EPA 200.7 06/17/2015 10:46 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/17/2015 10:46 MHH71310.005 1 Analytical Lab Page 4 of 74 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060408 2015018820 Collection Date: 10-Jun-15 3:34 PM Site: MW-20 Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 02:29 SLS256011 Arsenic (As)1.00 ug/L EPA 200.8 06/21/2015 02:29 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 02:29 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 02:29 SLS256011 Chromium (Cr)1.10 ug/L EPA 200.8 06/21/2015 02:29 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 02:29 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 02:29 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 02:29 SLS256011 Molybdenum (Mo)6.95 ug/L EPA 200.8 06/21/2015 02:29 SLS256011 Nickel (Ni)11.1 ug/L EPA 200.8 06/21/2015 02:29 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 02:29 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 02:29 SLS25600.2 1 Vanadium (V) Low Level 26.0 ug/L EPA 200.8 06/21/2015 02:29 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 14:05 SLS256011 Arsenic (As)1.12 ug/L EPA 200.8 06/21/2015 14:05 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 14:05 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 14:05 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 14:05 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 14:05 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 14:05 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 14:05 SLS256011 Molybdenum (Mo)6.53 ug/L EPA 200.8 06/21/2015 14:05 SLS256011 Nickel (Ni)14.3 ug/L EPA 200.8 06/21/2015 14:05 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 14:05 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 14:05 SLS25600.2 1 Vanadium (V) Low Level 39.6 ug/L EPA 200.8 06/21/2015 14:05 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 220 mg/L SM2540C 06/15/2015 14:29 AGIBBS5251 Total Carbon TOC 4.1 mg/L SM5310C/EPA9060A 06/25/2015 12:17 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/15/2015 08:48 AGIBBS551 Analytical Lab Page 5 of 74 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060408 2015018821 Collection Date: 10-Jun-15 3:30 PM Site: MW-20D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/17/2015 13:42 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 78 mg/L EPA 300.0 06/15/2015 18:09 BGN9034110 Sulfate 66 mg/L EPA 300.0 06/15/2015 18:09 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/16/2015 13:37 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/18/2015 12:59 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 06/16/2015 10:31 MHALL30.005 1 Barium (Ba)0.049 mg/L EPA 200.7 06/16/2015 10:31 MHALL30.005 1 Boron (B)0.313 mg/L EPA 200.7 06/16/2015 10:31 MHALL30.05 1 Iron (Fe)0.324 mg/L EPA 200.7 06/16/2015 10:31 MHALL30.01 1 Manganese (Mn)0.115 mg/L EPA 200.7 06/16/2015 10:31 MHALL30.005 1 Strontium (Sr)0.181 mg/L EPA 200.7 06/16/2015 10:31 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/16/2015 10:31 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)55.0 mg/L EPA 200.7 06/17/2015 13:41 MHALL30.01 1 Magnesium (Mg)5.36 mg/L EPA 200.7 06/17/2015 13:41 MHALL30.005 1 Potassium (K)3.23 mg/L EPA 200.7 06/17/2015 13:41 MHALL30.1 1 Sodium (Na)57.9 mg/L EPA 200.7 06/17/2015 13:41 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.010 mg/L EPA 200.7 06/17/2015 10:50 MHH71310.005 1 Barium (Ba)0.051 mg/L EPA 200.7 06/17/2015 10:50 MHH71310.005 1 Boron (B)0.305 mg/L EPA 200.7 06/17/2015 10:50 MHH71310.05 1 Iron (Fe)0.864 mg/L EPA 200.7 06/17/2015 10:50 MHH71310.01 1 Manganese (Mn)0.131 mg/L EPA 200.7 06/17/2015 10:50 MHH71310.005 1 Strontium (Sr)0.187 mg/L EPA 200.7 06/17/2015 10:50 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/17/2015 10:50 MHH71310.005 1 Analytical Lab Page 6 of 74 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060408 2015018821 Collection Date: 10-Jun-15 3:30 PM Site: MW-20D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 02:51 SLS256011 Arsenic (As)1.80 ug/L EPA 200.8 06/21/2015 02:51 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 02:51 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 02:51 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 02:51 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 02:51 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 02:51 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 02:51 SLS256011 Molybdenum (Mo)13.6 ug/L EPA 200.8 06/21/2015 02:51 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 02:51 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 02:51 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 02:51 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 02:51 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 14:34 SLS256011 Arsenic (As)2.25 ug/L EPA 200.8 06/21/2015 14:34 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 14:34 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 14:34 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 14:34 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 14:34 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 14:34 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 14:34 SLS256011 Molybdenum (Mo)14.0 ug/L EPA 200.8 06/21/2015 14:34 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 14:34 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 14:34 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 14:34 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 14:34 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 340 mg/L SM2540C 06/15/2015 14:29 AGIBBS5251 Total Carbon TOC 1.2 mg/L SM5310C/EPA9060A 06/25/2015 12:17 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/15/2015 08:48 AGIBBS551 Analytical Lab Page 7 of 74 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060408 2015018822 Collection Date: 10-Jun-15 3:55 PM Site: MW-20D DUP Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/17/2015 13:43 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 77 mg/L EPA 300.0 06/15/2015 18:25 BGN9034110 Sulfate 67 mg/L EPA 300.0 06/15/2015 18:25 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/16/2015 13:39 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/18/2015 13:09 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 06/16/2015 10:46 MHALL30.005 1 Barium (Ba)0.053 mg/L EPA 200.7 06/16/2015 10:46 MHALL30.005 1 Boron (B)0.385 mg/L EPA 200.7 06/16/2015 10:46 MHALL30.05 1 Iron (Fe)0.538 mg/L EPA 200.7 06/16/2015 10:46 MHALL30.01 1 Manganese (Mn)0.166 mg/L EPA 200.7 06/16/2015 10:46 MHALL30.005 1 Strontium (Sr)0.218 mg/L EPA 200.7 06/16/2015 10:46 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/16/2015 10:46 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)56.4 mg/L EPA 200.7 06/17/2015 10:20 MHALL30.01 1 Magnesium (Mg)5.98 mg/L EPA 200.7 06/17/2015 10:20 MHALL30.005 1 Potassium (K)3.89 mg/L EPA 200.7 06/17/2015 10:20 MHALL30.1 1 Sodium (Na)59.2 mg/L EPA 200.7 06/17/2015 10:20 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.017 mg/L EPA 200.7 06/17/2015 10:54 MHH71310.005 1 Barium (Ba)0.055 mg/L EPA 200.7 06/17/2015 10:54 MHH71310.005 1 Boron (B)0.408 mg/L EPA 200.7 06/17/2015 10:54 MHH71310.05 1 Iron (Fe)1.27 mg/L EPA 200.7 06/17/2015 10:54 MHH71310.01 1 Manganese (Mn)0.192 mg/L EPA 200.7 06/17/2015 10:54 MHH71310.005 1 Strontium (Sr)0.227 mg/L EPA 200.7 06/17/2015 10:54 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/17/2015 10:54 MHH71310.005 1 Analytical Lab Page 8 of 74 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060408 2015018822 Collection Date: 10-Jun-15 3:55 PM Site: MW-20D DUP Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 02:58 SLS256011 Arsenic (As)4.53 ug/L EPA 200.8 06/21/2015 02:58 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 02:58 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 02:58 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 02:58 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 02:58 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 02:58 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 02:58 SLS256011 Molybdenum (Mo)23.6 ug/L EPA 200.8 06/21/2015 02:58 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 02:58 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 02:58 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 02:58 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 02:58 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 14:41 SLS256011 Arsenic (As)5.23 ug/L EPA 200.8 06/21/2015 14:41 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 14:41 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 14:41 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 14:41 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 14:41 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 14:41 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 14:41 SLS256011 Molybdenum (Mo)24.9 ug/L EPA 200.8 06/21/2015 14:41 SLS256011 Nickel (Ni)1.12 ug/L EPA 200.8 06/21/2015 14:41 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 14:41 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 14:41 SLS25600.2 1 Vanadium (V) Low Level 0.358 ug/L EPA 200.8 06/21/2015 14:41 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 340 mg/L SM2540C 06/15/2015 14:29 AGIBBS5251 Total Carbon TOC 1.2 mg/L SM5310C/EPA9060A 06/25/2015 12:17 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/15/2015 08:48 AGIBBS551 Analytical Lab Page 9 of 74 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060408 2015018823 Collection Date: 10-Jun-15 12:14 PM Site: MW-16D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/17/2015 13:44 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 110 mg/L EPA 300.0 06/16/2015 12:26 BGN90342.5 25 Sulfate 120 mg/L EPA 300.0 06/16/2015 12:26 BGN90342.5 25 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/16/2015 13:42 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/18/2015 13:11 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.096 mg/L EPA 200.7 06/16/2015 10:50 MHALL30.005 1 Barium (Ba)0.041 mg/L EPA 200.7 06/16/2015 10:50 MHALL30.005 1 Boron (B)0.733 mg/L EPA 200.7 06/16/2015 10:50 MHALL30.05 1 Iron (Fe)0.517 mg/L EPA 200.7 06/16/2015 10:50 MHALL30.01 1 Manganese (Mn)0.345 mg/L EPA 200.7 06/16/2015 10:50 MHALL30.005 1 Strontium (Sr)0.226 mg/L EPA 200.7 06/16/2015 10:50 MHALL30.005 1 Zinc (Zn)0.033 mg/L EPA 200.7 06/16/2015 10:50 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)26.8 mg/L EPA 200.7 06/17/2015 12:09 MHALL30.01 1 Magnesium (Mg)7.50 mg/L EPA 200.7 06/17/2015 12:09 MHALL30.005 1 Potassium (K)5.53 mg/L EPA 200.7 06/17/2015 12:09 MHALL30.1 1 Sodium (Na)79.5 mg/L EPA 200.7 06/17/2015 12:09 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.106 mg/L EPA 200.7 06/17/2015 10:58 MHH71310.005 1 Barium (Ba)0.040 mg/L EPA 200.7 06/17/2015 10:58 MHH71310.005 1 Boron (B)0.680 mg/L EPA 200.7 06/17/2015 10:58 MHH71310.05 1 Iron (Fe)1.02 mg/L EPA 200.7 06/17/2015 10:58 MHH71310.01 1 Manganese (Mn)0.311 mg/L EPA 200.7 06/17/2015 10:58 MHH71310.005 1 Strontium (Sr)0.215 mg/L EPA 200.7 06/17/2015 10:58 MHH71310.005 1 Zinc (Zn)0.033 mg/L EPA 200.7 06/17/2015 10:58 MHH71310.005 1 Analytical Lab Page 10 of 74 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060408 2015018823 Collection Date: 10-Jun-15 12:14 PM Site: MW-16D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 03:06 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 03:06 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 03:06 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 03:06 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 03:06 SLS256011 Cobalt (Co)5.18 ug/L EPA 200.8 06/21/2015 03:06 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 03:06 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 03:06 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 03:06 SLS256011 Nickel (Ni)1.04 ug/L EPA 200.8 06/21/2015 03:06 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 03:06 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 03:06 SLS25600.2 1 Vanadium (V) Low Level 0.534 ug/L EPA 200.8 06/21/2015 03:06 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 14:48 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 14:48 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 14:48 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 14:48 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 14:48 SLS256011 Cobalt (Co)5.22 ug/L EPA 200.8 06/21/2015 14:48 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 14:48 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 14:48 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 14:48 SLS256011 Nickel (Ni)1.89 ug/L EPA 200.8 06/21/2015 14:48 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 14:48 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 14:48 SLS25600.2 1 Vanadium (V) Low Level 2.09 ug/L EPA 200.8 06/21/2015 14:48 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 350 mg/L SM2540C 06/15/2015 14:29 AGIBBS5251 Total Carbon TOC 1.1 mg/L SM5310C/EPA9060A 06/25/2015 12:17 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/15/2015 08:48 AGIBBS551 Analytical Lab Page 11 of 74 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060408 2015018824 Collection Date: 10-Jun-15 11:45 AM Site: MW-16 Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/17/2015 13:45M2 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 19 mg/L EPA 300.0 06/16/2015 13:15 BGN9034110 Sulfate 22 mg/L EPA 300.0 06/16/2015 13:15 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/16/2015 13:44 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/18/2015 13:14 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.090 mg/L EPA 200.7 06/16/2015 10:54 MHALL30.005 1 Barium (Ba)0.020 mg/L EPA 200.7 06/16/2015 10:54 MHALL30.005 1 Boron (B)0.098 mg/L EPA 200.7 06/16/2015 10:54 MHALL30.05 1 Iron (Fe)0.095 mg/L EPA 200.7 06/16/2015 10:54 MHALL30.01 1 Manganese (Mn)0.010 mg/L EPA 200.7 06/16/2015 10:54 MHALL30.005 1 Strontium (Sr)0.080 mg/L EPA 200.7 06/16/2015 10:54 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/16/2015 10:54 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)5.55 mg/L EPA 200.7 06/17/2015 12:13 MHALL30.01 1 Magnesium (Mg)2.44 mg/L EPA 200.7 06/17/2015 12:13 MHALL30.005 1 Potassium (K)4.79 mg/L EPA 200.7 06/17/2015 12:13 MHALL30.1 1 Sodium (Na)16.6 mg/L EPA 200.7 06/17/2015 12:13 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.123 mg/L EPA 200.7 06/17/2015 11:02 MHH71310.005 1 Barium (Ba)0.020 mg/L EPA 200.7 06/17/2015 11:02 MHH71310.005 1 Boron (B)0.090 mg/L EPA 200.7 06/17/2015 11:02 MHH71310.05 1 Iron (Fe)0.113 mg/L EPA 200.7 06/17/2015 11:02 MHH71310.01 1 Manganese (Mn)0.009 mg/L EPA 200.7 06/17/2015 11:02 MHH71310.005 1 Strontium (Sr)0.080 mg/L EPA 200.7 06/17/2015 11:02 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/17/2015 11:02 MHH71310.005 1 Analytical Lab Page 12 of 74 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060408 2015018824 Collection Date: 10-Jun-15 11:45 AM Site: MW-16 Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 03:35 SLS256011 Arsenic (As)1.59 ug/L EPA 200.8 06/21/2015 03:35 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 03:35 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 03:35 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 03:35 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 03:35 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 03:35 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 03:35 SLS256011 Molybdenum (Mo)2.91 ug/L EPA 200.8 06/21/2015 03:35 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 03:35 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 03:35 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 03:35 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 03:35 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 15:03 SLS256011 Arsenic (As)1.49 ug/L EPA 200.8 06/21/2015 15:03 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 15:03 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 15:03 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 15:03 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 15:03 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 15:03 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 15:03 SLS256011 Molybdenum (Mo)3.00 ug/L EPA 200.8 06/21/2015 15:03 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 15:03 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 15:03 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 15:03 SLS25600.2 1 Vanadium (V) Low Level 0.316 ug/L EPA 200.8 06/21/2015 15:03 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 84 mg/L SM2540C 06/15/2015 14:29 AGIBBS5251 Total Carbon TOC 3.0 mg/L SM5310C/EPA9060A 06/25/2015 12:17 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/15/2015 08:48 AGIBBS551 Analytical Lab Page 13 of 74 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060408 2015018825 Collection Date: 10-Jun-15 5:20 PM Site: MW-15 Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/17/2015 13:46 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 7.6 mg/L EPA 300.0 06/16/2015 15:26 BGN90340.1 1 Sulfate 17 mg/L EPA 300.0 06/16/2015 15:26 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/16/2015 13:46 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/18/2015 13:16 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.048 mg/L EPA 200.7 06/16/2015 10:58 MHALL30.005 1 Barium (Ba)0.031 mg/L EPA 200.7 06/16/2015 10:58 MHALL30.005 1 Boron (B)0.064 mg/L EPA 200.7 06/16/2015 10:58 MHALL30.05 1 Iron (Fe)3.23 mg/L EPA 200.7 06/16/2015 10:58 MHALL30.01 1 Manganese (Mn)0.079 mg/L EPA 200.7 06/16/2015 10:58 MHALL30.005 1 Strontium (Sr)0.373 mg/L EPA 200.7 06/16/2015 10:58 MHALL30.005 1 Zinc (Zn)0.015 mg/L EPA 200.7 06/16/2015 10:58 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)77.4 mg/L EPA 200.7 06/17/2015 12:17 MHALL30.01 1 Magnesium (Mg)4.08 mg/L EPA 200.7 06/17/2015 12:17 MHALL30.005 1 Potassium (K)2.50 mg/L EPA 200.7 06/17/2015 12:17 MHALL30.1 1 Sodium (Na)6.24 mg/L EPA 200.7 06/17/2015 12:17 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.090 mg/L EPA 200.7 06/17/2015 11:06 MHH71310.005 1 Barium (Ba)0.030 mg/L EPA 200.7 06/17/2015 11:06 MHH71310.005 1 Boron (B)0.054 mg/L EPA 200.7 06/17/2015 11:06 MHH71310.05 1 Iron (Fe)3.69 mg/L EPA 200.7 06/17/2015 11:06 MHH71310.01 1 Manganese (Mn)0.076 mg/L EPA 200.7 06/17/2015 11:06 MHH71310.005 1 Strontium (Sr)0.365 mg/L EPA 200.7 06/17/2015 11:06 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/17/2015 11:06 MHH71310.005 1 Analytical Lab Page 14 of 74 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060408 2015018825 Collection Date: 10-Jun-15 5:20 PM Site: MW-15 Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 03:42 SLS256011 Arsenic (As)20.5 ug/L EPA 200.8 06/21/2015 03:42 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 03:42 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 03:42 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 03:42 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 03:42 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 03:42 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 03:42 SLS256011 Molybdenum (Mo)9.12 ug/L EPA 200.8 06/21/2015 03:42 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 03:42 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 03:42 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 03:42 SLS25600.2 1 Vanadium (V) Low Level 2.19 ug/L EPA 200.8 06/21/2015 03:42 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 14:55 SLS256011 Arsenic (As)23.6 ug/L EPA 200.8 06/21/2015 14:55 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 14:55 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 14:55 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 14:55 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 14:55 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 14:55 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 14:55 SLS256011 Molybdenum (Mo)9.60 ug/L EPA 200.8 06/21/2015 14:55 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 14:55 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 14:55 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 14:55 SLS25600.2 1 Vanadium (V) Low Level 3.88 ug/L EPA 200.8 06/21/2015 14:55 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 250 mg/L SM2540C 06/15/2015 14:29 AGIBBS5251 Total Carbon TOC 12 mg/L SM5310C/EPA9060A 06/25/2015 12:17 GHUTCHI0.5 5 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/15/2015 08:48 AGIBBS551 Analytical Lab Page 15 of 74 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060408 2015018826 Collection Date: 10-Jun-15 5:15 PM Site: MW-15D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/17/2015 13:33 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 130 mg/L EPA 300.0 06/16/2015 13:48 BGN90342.5 25 Sulfate 85 mg/L EPA 300.0 06/16/2015 13:48 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/16/2015 13:49 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/18/2015 13:18 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 06/16/2015 11:01 MHALL30.005 1 Barium (Ba)0.042 mg/L EPA 200.7 06/16/2015 11:01 MHALL30.005 1 Boron (B)0.555 mg/L EPA 200.7 06/16/2015 11:01 MHALL30.05 1 Iron (Fe)0.021 mg/L EPA 200.7 06/16/2015 11:01 MHALL30.01 1 Manganese (Mn)0.811 mg/L EPA 200.7 06/16/2015 11:01 MHALL30.005 1 Strontium (Sr)0.575 mg/L EPA 200.7 06/16/2015 11:01 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/16/2015 11:01 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)57.4 mg/L EPA 200.7 06/17/2015 12:20 MHALL30.01 1 Magnesium (Mg)7.79 mg/L EPA 200.7 06/17/2015 12:20 MHALL30.005 1 Potassium (K)7.68 mg/L EPA 200.7 06/17/2015 12:20 MHALL30.1 1 Sodium (Na)69.8 mg/L EPA 200.7 06/17/2015 12:20 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.005 mg/L EPA 200.7 06/17/2015 11:19 MHH71310.005 1 Barium (Ba)0.041 mg/L EPA 200.7 06/17/2015 11:19 MHH71310.005 1 Boron (B)0.560 mg/L EPA 200.7 06/17/2015 11:19 MHH71310.05 1 Iron (Fe)0.085 mg/L EPA 200.7 06/17/2015 11:19 MHH71310.01 1 Manganese (Mn)0.940 mg/L EPA 200.7 06/17/2015 11:19 MHH71310.005 1 Strontium (Sr)0.571 mg/L EPA 200.7 06/17/2015 11:19 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/17/2015 11:19 MHH71310.005 1 Analytical Lab Page 16 of 74 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060408 2015018826 Collection Date: 10-Jun-15 5:15 PM Site: MW-15D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 03:49 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 03:49 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 03:49 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 03:49 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 03:49 SLS256011 Cobalt (Co)10.9 ug/L EPA 200.8 06/21/2015 03:49 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 03:49 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 03:49 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 03:49 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 03:49 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 03:49 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 03:49 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 03:49 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 15:24 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 15:24 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 15:24 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 15:24 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 15:24 SLS256011 Cobalt (Co)13.5 ug/L EPA 200.8 06/21/2015 15:24 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 15:24 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 15:24 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 15:24 SLS256011 Nickel (Ni)1.19 ug/L EPA 200.8 06/21/2015 15:24 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 15:24 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 15:24 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 15:24 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 430 mg/L SM2540C 06/15/2015 14:29 AGIBBS5251 Total Carbon TOC 1.2 mg/L SM5310C/EPA9060A 06/25/2015 12:17 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/15/2015 08:48 AGIBBS551 Analytical Lab Page 17 of 74 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060408 2015018827 Collection Date: 11-Jun-15 11:10 AM Site: AW-3B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/17/2015 12:50M2 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 3.8 mg/L EPA 300.0 06/16/2015 15:59 BGN90340.1 1 Sulfate 4.0 mg/L EPA 300.0 06/16/2015 15:59 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/16/2015 13:51 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/18/2015 13:21 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.035 mg/L EPA 200.7 06/16/2015 11:05 MHALL30.005 1 Barium (Ba)0.009 mg/L EPA 200.7 06/16/2015 11:05 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/16/2015 11:05 MHALL30.05 1 Iron (Fe)6.60 mg/L EPA 200.7 06/16/2015 11:05 MHALL30.01 1 Manganese (Mn)0.015 mg/L EPA 200.7 06/16/2015 11:05 MHALL30.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 06/16/2015 11:05 MHALL30.005 1 Zinc (Zn)0.012 mg/L EPA 200.7 06/16/2015 11:05 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)0.607 mg/L EPA 200.7 06/17/2015 12:24 MHALL30.01 1 Magnesium (Mg)0.629 mg/L EPA 200.7 06/17/2015 12:24 MHALL30.005 1 Potassium (K)1.28 mg/L EPA 200.7 06/17/2015 12:24 MHALL30.1 1 Sodium (Na)1.29 mg/L EPA 200.7 06/17/2015 12:24 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.032 mg/L EPA 200.7 06/17/2015 11:31 MHH71310.005 1 Barium (Ba)0.010 mg/L EPA 200.7 06/17/2015 11:31 MHH71310.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/17/2015 11:31 MHH71310.05 1 Iron (Fe)6.29 mg/L EPA 200.7 06/17/2015 11:31 MHH71310.01 1 Manganese (Mn)0.013 mg/L EPA 200.7 06/17/2015 11:31 MHH71310.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 06/17/2015 11:31 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/17/2015 11:31 MHH71310.005 1 Analytical Lab Page 18 of 74 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060408 2015018827 Collection Date: 11-Jun-15 11:10 AM Site: AW-3B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 03:56 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 03:56 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 03:56 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 03:56 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 03:56 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 03:56 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 03:56 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 03:56 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 03:56 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 03:56 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 03:56 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 03:56 SLS25600.2 1 Vanadium (V) Low Level 0.421 ug/L EPA 200.8 06/21/2015 03:56 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/22/2015 00:57 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/22/2015 00:57 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/22/2015 00:57 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/22/2015 00:57 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/22/2015 00:57 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/22/2015 00:57 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/22/2015 00:57 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/22/2015 00:57 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/22/2015 00:57 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/22/2015 00:57 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/22/2015 00:57 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/22/2015 00:57 SLS25600.2 1 Vanadium (V) Low Level 0.427 ug/L EPA 200.8 06/22/2015 00:57 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 29 mg/L SM2540C 06/16/2015 10:47 AGIBBS5251 Total Carbon TOC 2.7 mg/L SM5310C/EPA9060A 06/25/2015 12:17 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/15/2015 08:48 AGIBBS551 Analytical Lab Page 19 of 74 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060408 2015018828 Collection Date: 11-Jun-15 11:19 AM Site: AW-3C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.015 mg-N/L EPA 353.2 06/17/2015 12:54 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 160 mg/L EPA 300.0 06/17/2015 09:07 BGN90342.5 25 Sulfate 140 mg/L EPA 300.0 06/17/2015 09:07 BGN90342.5 25 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/16/2015 14:03 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/18/2015 13:23 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.026 mg/L EPA 200.7 06/16/2015 11:17 MHALL30.005 1 Barium (Ba)0.098 mg/L EPA 200.7 06/16/2015 11:17 MHALL30.005 1 Boron (B)1.43 mg/L EPA 200.7 06/16/2015 11:17 MHALL30.05 1 Iron (Fe)11.7 mg/L EPA 200.7 06/16/2015 11:17 MHALL30.01 1 Manganese (Mn)1.94 mg/L EPA 200.7 06/16/2015 11:17 MHALL30.005 1 Strontium (Sr)0.700 mg/L EPA 200.7 06/16/2015 11:17 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/16/2015 11:17 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)46.8 mg/L EPA 200.7 06/17/2015 12:28 MHALL30.01 1 Magnesium (Mg)11.5 mg/L EPA 200.7 06/17/2015 12:28 MHALL30.005 1 Potassium (K)8.14 mg/L EPA 200.7 06/17/2015 12:28 MHALL30.1 1 Sodium (Na)91.1 mg/L EPA 200.7 06/17/2015 12:28 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.022 mg/L EPA 200.7 06/17/2015 11:35 MHH71310.005 1 Barium (Ba)0.096 mg/L EPA 200.7 06/17/2015 11:35 MHH71310.005 1 Boron (B)1.37 mg/L EPA 200.7 06/17/2015 11:35 MHH71310.05 1 Iron (Fe)11.3 mg/L EPA 200.7 06/17/2015 11:35 MHH71310.01 1 Manganese (Mn)1.83 mg/L EPA 200.7 06/17/2015 11:35 MHH71310.005 1 Strontium (Sr)0.672 mg/L EPA 200.7 06/17/2015 11:35 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/17/2015 11:35 MHH71310.005 1 Analytical Lab Page 20 of 74 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060408 2015018828 Collection Date: 11-Jun-15 11:19 AM Site: AW-3C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 04:03 SLS256011 Arsenic (As)1.54 ug/L EPA 200.8 06/21/2015 04:03 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 04:03 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 04:03 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 04:03 SLS256011 Cobalt (Co)6.35 ug/L EPA 200.8 06/21/2015 04:03 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 04:03 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 04:03 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 04:03 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 04:03 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 04:03 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 04:03 SLS25600.2 1 Vanadium (V) Low Level 0.596 ug/L EPA 200.8 06/21/2015 04:03 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 15:39 SLS256011 Arsenic (As)1.54 ug/L EPA 200.8 06/21/2015 15:39 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 15:39 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 15:39 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 15:39 SLS256011 Cobalt (Co)6.91 ug/L EPA 200.8 06/21/2015 15:39 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 15:39 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 15:39 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 15:39 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 15:39 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 15:39 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 15:39 SLS25600.2 1 Vanadium (V) Low Level 0.750 ug/L EPA 200.8 06/21/2015 15:39 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 510 mg/L SM2540C 06/16/2015 10:47 AGIBBS5251 Total Carbon TOC 1.7 mg/L SM5310C/EPA9060A 06/25/2015 12:17 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/15/2015 08:48 AGIBBS551 Analytical Lab Page 21 of 74 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060408 2015018829 Collection Date: 10-Jun-15 6:18 PM Site: Filter Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/18/2015 13:25 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 06/16/2015 11:20 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 06/16/2015 11:20 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/16/2015 11:20 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 06/16/2015 11:20 MHALL30.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 06/16/2015 11:20 MHALL30.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 06/16/2015 11:20 MHALL30.005 1 Zinc (Zn)0.005 mg/L EPA 200.7 06/16/2015 11:20 MHALL30.005 1 TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 04:11 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 04:11 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 04:11 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 04:11 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 04:11 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 04:11 SLS256011 Copper (Cu)5.46 ug/L EPA 200.8 06/21/2015 04:11 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 04:11 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 04:11 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 04:11 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 04:11 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 04:11 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 04:11 SLS25600.3 1 Analytical Lab Page 22 of 74 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060408 2015018830 Collection Date: 10-Jun-15 6:18 PM Site: Equipment Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/17/2015 12:55 LSTARL10.01 1 INORGANIC IONS BY IC Chloride < 0.1 mg/L EPA 300.0 06/16/2015 14:37 BGN90340.1 1 Sulfate < 0.1 mg/L EPA 300.0 06/16/2015 14:37 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/16/2015 13:56 ACPAYNE0.05 1 UNDIGESTED METALS BY ICP Calcium (Ca)< 0.01 mg/L EPA 200.7 06/17/2015 09:49 MHALL30.01 1 Magnesium (Mg)< 0.005 mg/L EPA 200.7 06/17/2015 09:49 MHALL30.005 1 Potassium (K)< 0.1 mg/L EPA 200.7 06/17/2015 09:49 MHALL30.1 1 Sodium (Na)< 0.05 mg/L EPA 200.7 06/17/2015 09:49 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 06/17/2015 11:39 MHH71310.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 06/17/2015 11:39 MHH71310.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/17/2015 11:39 MHH71310.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 06/17/2015 11:39 MHH71310.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 06/17/2015 11:39 MHH71310.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 06/17/2015 11:39 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/17/2015 11:39 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 16:08 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 16:08 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 16:08 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 16:08 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 16:08 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 16:08 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 16:08 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 16:08 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 16:08 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 16:08 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 16:08 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 16:08 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 16:08 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY Analytical Lab Page 23 of 74 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060408 2015018830 Collection Date: 10-Jun-15 6:18 PM Site: Equipment Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 06/15/2015 14:29 AGIBBS5251 Total Carbon TOC 0.157 mg/L SM5310C/EPA9060A 06/25/2015 12:17 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/15/2015 08:48 AGIBBS551 Qualifiers: M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable. Analytical Lab Page 24 of 74 Analytical Lab Page 25 of 74 Analytical Lab Page 26 of 74 Analytical Lab Page 27 of 74 Analytical Lab Page 28 of 74 Analytical Lab Page 29 of 74 Analytical Lab Page 30 of 74 Analytical Lab Page 31 of 74 Analytical Lab Page 32 of 74 SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle QF13009Lot Number: J15060408Project Number: AB GW Assessment Water - SuttonProject Name: 06/19/2015 06/22/2015 Date Completed: Date Revised: Grant Wilton Project Manager *QF13009* This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. Page: 1 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Case Narrative Duke Energy Lot Number: QF13009 SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329 Project Name: AB GW Assessment Water - Sutton Project Number: J15060408 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. REVISION 1 Change "Weatherspoon" to "Sutton". Page: 2 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: QF13009 Project Name: AB GW Assessment Water - Sutton Project Number: J15060408 Sample Number Sample ID Matrix Date Sampled Date Received 001 06/10/2015 15342015018820Aqueous 06/13/2015 002 06/10/2015 15302015018821Aqueous 06/13/2015 003 06/10/2015 15552015018822Aqueous 06/13/2015 004 06/10/2015 12142015018823Aqueous 06/13/2015 005 06/10/2015 11452015018824Aqueous 06/13/2015 006 06/10/2015 17202015018825Aqueous 06/13/2015 007 06/10/2015 17152015018826Aqueous 06/13/2015 008 06/11/2015 11102015018827Aqueous 06/13/2015 009 06/11/2015 11192015018828Aqueous 06/13/2015 010 06/10/2015 18182015018830Aqueous 06/13/2015 (10 samples) Page: 3 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: QF13009 Project Name: AB GW Assessment Water - Sutton Project Number: J15060408 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2015018820 Aqueous Alkalinity SM 2320B-100 mg/L 5 001 2015018820 Aqueous Bicarbonate Alkalinity SM 2320B-100 mg/L 5 001 2015018820 Aqueous Methane RSK - 175 420 ug/L 6 002 2015018821 Aqueous Alkalinity SM 2320B-110 mg/L 7 002 2015018821 Aqueous Bicarbonate Alkalinity SM 2320B-110 mg/L 7 002 2015018821 Aqueous Methane RSK - 175 35 ug/L 8 003 2015018822 Aqueous Alkalinity SM 2320B-120 mg/L 9 003 2015018822 Aqueous Bicarbonate Alkalinity SM 2320B-110 mg/L 9 003 2015018822 Aqueous Methane RSK - 175 40 ug/L 10 004 2015018823 Aqueous Alkalinity SM 2320B-14 mg/L 11 004 2015018823 Aqueous Bicarbonate Alkalinity SM 2320B-14 mg/L 11 004 2015018823 Aqueous Methane RSK - 175 28 ug/L 12 005 2015018824 Aqueous Alkalinity SM 2320B-15 mg/L 13 005 2015018824 Aqueous Bicarbonate Alkalinity SM 2320B-15 mg/L 13 005 2015018824 Aqueous Methane RSK - 175 45 ug/L 14 006 2015018825 Aqueous Alkalinity SM 2320B-180 mg/L 15 006 2015018825 Aqueous Bicarbonate Alkalinity SM 2320B-180 mg/L 15 006 2015018825 Aqueous Methane RSK - 175 870 ug/L 16 007 2015018826 Aqueous Alkalinity SM 2320B-73 mg/L 17 007 2015018826 Aqueous Bicarbonate Alkalinity SM 2320B-73 mg/L 17 007 2015018826 Aqueous Methane RSK - 175 26 ug/L 18 008 2015018827 Aqueous Methane RSK - 175 24 ug/L 20 009 2015018828 Aqueous Alkalinity SM 2320B-43 mg/L 21 009 2015018828 Aqueous Bicarbonate Alkalinity SM 2320B-43 mg/L 21 009 2015018828 Aqueous Methane RSK - 175 21 ug/L 22 (25 detections) Page: 4 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015018820 QF13009-001 06/10/2015 1534 06/13/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060408 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/17/2015 1228 HMA 77408 1 (Bicarbonate ) SM 2320B-2011 1 06/17/2015 0028 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/17/2015 0028 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 100 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 100 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 5 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015018820 QF13009-001 06/10/2015 1534 06/13/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060408 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/18/2015 1251 DCS 77596 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 420 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 6 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015018821 QF13009-002 06/10/2015 1530 06/13/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060408 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/17/2015 1234 HMA 77408 1 (Bicarbonate ) SM 2320B-2011 1 06/17/2015 0034 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/17/2015 0034 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 110 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 110 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 7 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015018821 QF13009-002 06/10/2015 1530 06/13/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060408 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/18/2015 1304 DCS 77596 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 35 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 8 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015018822 QF13009-003 06/10/2015 1555 06/13/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060408 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/17/2015 1242 HMA 77408 1 (Bicarbonate ) SM 2320B-2011 1 06/17/2015 0042 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/17/2015 0042 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 120 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 110 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 9 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015018822 QF13009-003 06/10/2015 1555 06/13/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060408 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/18/2015 1323 DCS 77596 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 40 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 10 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015018823 QF13009-004 06/10/2015 1214 06/13/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060408 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/17/2015 1247 HMA 77408 1 (Bicarbonate ) SM 2320B-2011 1 06/17/2015 0047 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/17/2015 0047 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 14 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 14 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 11 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015018823 QF13009-004 06/10/2015 1214 06/13/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060408 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/18/2015 1335 DCS 77596 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 28 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 12 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015018824 QF13009-005 06/10/2015 1145 06/13/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060408 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/17/2015 0100 HMA 77408 1 (Bicarbonate ) SM 2320B-2011 1 06/17/2015 0106 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/17/2015 0106 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 15 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 15 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 13 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015018824 QF13009-005 06/10/2015 1145 06/13/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060408 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/18/2015 1351 DCS 77596 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 45 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 14 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015018825 QF13009-006 06/10/2015 1720 06/13/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060408 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/17/2015 0106 HMA 77408 1 (Bicarbonate ) SM 2320B-2011 1 06/17/2015 0114 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/17/2015 0114 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 180 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 180 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 15 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015018825 QF13009-006 06/10/2015 1720 06/13/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060408 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 RSK - 175 2 06/18/2015 1738 JJG 77629 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 870 2ug/L20 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 16 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015018826 QF13009-007 06/10/2015 1715 06/13/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060408 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/17/2015 0114 HMA 77408 1 (Bicarbonate ) SM 2320B-2011 1 06/17/2015 0135 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/17/2015 0135 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 73 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 73 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 17 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015018826 QF13009-007 06/10/2015 1715 06/13/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060408 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/18/2015 1436 DCS 77596 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 26 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 18 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015018827 QF13009-008 06/11/2015 1110 06/13/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060408 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/17/2015 0200 HMA 77409 1 (Bicarbonate ) SM 2320B-2011 1 06/17/2015 0200 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/17/2015 0200 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 19 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015018827 QF13009-008 06/11/2015 1110 06/13/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060408 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/18/2015 1450 DCS 77596 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 24 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 20 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015018828 QF13009-009 06/11/2015 1119 06/13/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060408 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/17/2015 0218 HMA 77409 1 (Bicarbonate ) SM 2320B-2011 1 06/17/2015 0218 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/17/2015 0218 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 43 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 43 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 21 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015018828 QF13009-009 06/11/2015 1119 06/13/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060408 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/18/2015 2042 JJG 77629 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 21 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 22 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015018830 QF13009-010 06/10/2015 1818 06/13/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060408 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/17/2015 0224 HMA 77409 1 (Bicarbonate ) SM 2320B-2011 1 06/17/2015 0224 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/17/2015 0224 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 23 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015018830 QF13009-010 06/10/2015 1818 06/13/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060408 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/18/2015 2053 JJG 77629 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 24 of 24 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 QC Summary QC Data for Lot Number: QF13009 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MB Batch: Sample ID:QQ77408-001 77408 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Alkalinity ND 06/16/2015 222610mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF13009 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - LCS Batch: Sample ID:QQ77408-002 77408 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Alkalinity 96 06/16/2015 22329610090-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF13009 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MS Batch: Sample ID:QF13009-006MS 77408 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Alkalinity 270 06/17/2015 01218610070-1301801 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF13009 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MSD Batch: Sample ID:QF13009-006MD 77408 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Alkalinity 270 06/17/2015 01298410070-1300.81 201801 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF13009 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MB Batch: Sample ID:QQ77409-001 77409 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Alkalinity ND 06/17/2015 014910mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF13009 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - LCS Batch: Sample ID:QQ77409-002 77409 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Alkalinity 94 06/17/2015 01549410090-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF13009 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MS Batch: Sample ID:QF13009-008MS 77409 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Alkalinity 91 06/17/2015 02069110070-130ND1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF13009 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MSD Batch: Sample ID:QF13009-008MD 77409 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Alkalinity 93 06/17/2015 02129310070-1301.8 20ND1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF13009 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - MB Batch: Sample ID:QQ77596-001 77596 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 06/18/2015 092110ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF13009 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCS Batch: Sample ID:QQ77596-002 77596 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 52 06/18/2015 08531035070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF13009 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCSD Batch: Sample ID:QQ77596-003 77596 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 44 06/18/2015 0904885070-13016 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF13009 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - MB Batch: Sample ID:QQ77629-001 77629 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 06/18/2015 163510ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF13009 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCS Batch: Sample ID:QQ77629-002 77629 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 44 06/18/2015 1554875070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF13009 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCSD Batch: Sample ID:QQ77629-003 77629 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 41 06/18/2015 1614825070-1306.0 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF13009 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Analytical Lab Page 74 of 74