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HomeMy WebLinkAboutNC0001422_ATT 5 - Water - J15060224report_2015080513339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number: J15060224 Project Name:SUTTON - AB GW ASSESSMENT WATER Lab Contact:Mary Ann Ogle Date:6/25/2015 Customer Address: Customer Name(s): Perry Waldrep, Tim Hunsucker, Kathy Webb, John Toepfer Phone: 980-875-5274 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Mary Ann Ogle Analytical Lab Page 1 of 86 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015017698 Sutton 05-Jun-15 9:05 AM ILLEGIBLE SMW-1B 2015017699 Sutton 05-Jun-15 11:18 AM ILLEGIBLE SMW-1C 2015017700 Sutton 05-Jun-15 8:30 AM ILLEGIBLE SMW-4B 2015017701 Sutton 05-Jun-15 11:03 AM ILLEGIBLE SMW-4C 2015017702 Sutton 05-Jun-15 12:30 PM ILLEGIBLE SMW-5B 2015017703 Sutton 05-Jun-15 11:48 AM ILLEGIBLE SMW-5C 2015017704 Sutton 05-Jun-15 12:14 PM ILLEGIBLE AW-4B 2015017705 Sutton 05-Jun-15 1:48 PM ILLEGIBLE AW-4C 2015017706 Sutton 05-Jun-15 10:51 AM ILLEGIBLE AW-7B/MW-31B 2015017707 Sutton 05-Jun-15 10:29 AM ILLEGIBLE AW-7C/MW-31C 2015017708 Sutton 05-Jun-15 8:56 AM ILLEGIBLE AW-7D 2015017709 Sutton 05-Jun-15 1:45 PM ILLEGIBLE Filter Blank 2015017710 Sutton 05-Jun-15 1:45 PM ILLEGIBLE Equipment Blank 13 Total Samples Analytical Lab Page 2 of 86 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:Mary Ann Ogle Date:6/25/2015 Electronic Data Deliverable (EDD) Sent Separately Analytical Lab Page 3 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017698 Collection Date: 05-Jun-15 9:05 AM Site: SMW-1B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.441 mg-N/L EPA 353.2 06/09/2015 12:15 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 6.2 mg/L EPA 300.0 06/12/2015 16:02 BGN90340.1 1 Sulfate 45 mg/L EPA 300.0 06/12/2015 16:02 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/12/2015 11:33 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 13:36 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.770 mg/L EPA 200.7 06/12/2015 09:47 MHALL30.005 1 Barium (Ba)0.074 mg/L EPA 200.7 06/12/2015 09:47 MHALL30.005 1 Boron (B)0.099 mg/L EPA 200.7 06/12/2015 09:47 MHALL30.05 1 Iron (Fe)0.014 mg/L EPA 200.7 06/12/2015 09:47 MHALL30.01 1 Manganese (Mn)0.013 mg/L EPA 200.7 06/12/2015 09:47 MHALL30.005 1 Strontium (Sr)0.035 mg/L EPA 200.7 06/12/2015 09:47 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/12/2015 09:47 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)9.29 mg/L EPA 200.7 06/13/2015 12:37 MHALL30.01 1 Magnesium (Mg)0.792 mg/L EPA 200.7 06/13/2015 12:37 MHALL30.005 1 Potassium (K)1.85 mg/L EPA 200.7 06/13/2015 12:37 MHALL30.1 1 Sodium (Na)4.41 mg/L EPA 200.7 06/13/2015 12:37 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.769 mg/L EPA 200.7 06/09/2015 14:38 MHALL30.005 1 Barium (Ba)0.078 mg/L EPA 200.7 06/09/2015 14:38 MHALL30.005 1 Boron (B)0.100 mg/L EPA 200.7 06/09/2015 14:38 MHALL30.05 1 Iron (Fe)0.030 mg/L EPA 200.7 06/09/2015 14:38 MHALL30.01 1 Manganese (Mn)0.014 mg/L EPA 200.7 06/09/2015 14:38 MHALL30.005 1 Strontium (Sr)0.035 mg/L EPA 200.7 06/09/2015 14:38 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 14:38 MHALL30.005 1 Analytical Lab Page 4 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017698 Collection Date: 05-Jun-15 9:05 AM Site: SMW-1B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 12:00 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 12:00 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 12:00 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 12:00 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 12:00 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 12:00 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 12:00 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 12:00 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 12:00 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 12:00 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 12:00 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 12:00 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 12:00 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/18/2015 13:05 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 06/18/2015 13:05 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/18/2015 13:05 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/18/2015 13:05 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/18/2015 13:05 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 06/18/2015 13:05 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 06/18/2015 13:05 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/18/2015 13:05 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/18/2015 13:05 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 06/18/2015 13:05 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 06/18/2015 13:05 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/18/2015 13:05 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/18/2015 13:05 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 57 mg/L SM2540C 06/11/2015 11:45 AGIBBS5251 Total Carbon TOC 0.885 mg/L SM5310C/EPA9060A 06/23/2015 14:43 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/09/2015 13:12 AGIBBS551 Analytical Lab Page 5 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017699 Collection Date: 05-Jun-15 11:18 AM Site: SMW-1C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.032 mg-N/L EPA 353.2 06/09/2015 12:16 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 66 mg/L EPA 300.0 06/13/2015 08:42 BGN9034110 Sulfate 140 mg/L EPA 300.0 06/13/2015 08:42 BGN90342.5 25 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/12/2015 11:35 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 13:43 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.040 mg/L EPA 200.7 06/12/2015 09:58 MHALL30.005 1 Barium (Ba)0.035 mg/L EPA 200.7 06/12/2015 09:58 MHALL30.005 1 Boron (B)0.791 mg/L EPA 200.7 06/12/2015 09:58 MHALL30.05 1 Iron (Fe)4.21 mg/L EPA 200.7 06/12/2015 09:58 MHALL30.01 1 Manganese (Mn)0.810 mg/L EPA 200.7 06/12/2015 09:58 MHALL30.005 1 Strontium (Sr)0.499 mg/L EPA 200.7 06/12/2015 09:58 MHALL30.005 1 Zinc (Zn)0.010 mg/L EPA 200.7 06/12/2015 09:58 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)39.0 mg/L EPA 200.7 06/13/2015 12:48 MHALL30.01 1 Magnesium (Mg)8.04 mg/L EPA 200.7 06/13/2015 12:48 MHALL30.005 1 Potassium (K)5.67 mg/L EPA 200.7 06/13/2015 12:48 MHALL30.1 1 Sodium (Na)45.2 mg/L EPA 200.7 06/13/2015 12:48 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.099 mg/L EPA 200.7 06/09/2015 14:42 MHALL30.005 1 Barium (Ba)0.034 mg/L EPA 200.7 06/09/2015 14:42 MHALL30.005 1 Boron (B)0.776 mg/L EPA 200.7 06/09/2015 14:42 MHALL30.05 1 Iron (Fe)4.25 mg/L EPA 200.7 06/09/2015 14:42 MHALL30.01 1 Manganese (Mn)0.807 mg/L EPA 200.7 06/09/2015 14:42 MHALL30.005 1 Strontium (Sr)0.488 mg/L EPA 200.7 06/09/2015 14:42 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 14:42 MHALL30.005 1 Analytical Lab Page 6 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017699 Collection Date: 05-Jun-15 11:18 AM Site: SMW-1C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 12:07 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 12:07 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 12:07 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 12:07 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 12:07 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 12:07 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 12:07 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 12:07 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 12:07 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 12:07 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 12:07 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 12:07 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 12:07 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/18/2015 13:12 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 06/18/2015 13:12 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/18/2015 13:12 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/18/2015 13:12 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/18/2015 13:12 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 06/18/2015 13:12 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 06/18/2015 13:12 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/18/2015 13:12 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/18/2015 13:12 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 06/18/2015 13:12 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 06/18/2015 13:12 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/18/2015 13:12 JAHERMA0.2 1 Vanadium (V) Low Level 0.402 ug/L EPA 200.8 06/18/2015 13:12 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 340 mg/L SM2540C 06/11/2015 11:45 AGIBBS5251 Total Carbon TOC 1.3 mg/L SM5310C/EPA9060A 06/23/2015 14:43 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/09/2015 13:12 AGIBBS551 Analytical Lab Page 7 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017700 Collection Date: 05-Jun-15 8:30 AM Site: SMW-4B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.039 mg-N/L EPA 353.2 06/09/2015 12:21M2 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 4.3 mg/L EPA 300.0 06/12/2015 18:14 BGN90340.1 1 Sulfate 6.6 mg/L EPA 300.0 06/12/2015 18:14 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/12/2015 11:38 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 13:45 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.020 mg/L EPA 200.7 06/12/2015 10:02 MHALL30.005 1 Barium (Ba)0.016 mg/L EPA 200.7 06/12/2015 10:02 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/12/2015 10:02 MHALL30.05 1 Iron (Fe)7.47 mg/L EPA 200.7 06/12/2015 10:02 MHALL30.01 1 Manganese (Mn)0.083 mg/L EPA 200.7 06/12/2015 10:02 MHALL30.005 1 Strontium (Sr)0.013 mg/L EPA 200.7 06/12/2015 10:02 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/12/2015 10:02 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)5.42 mg/L EPA 200.7 06/13/2015 12:52 MHALL30.01 1 Magnesium (Mg)0.499 mg/L EPA 200.7 06/13/2015 12:52 MHALL30.005 1 Potassium (K)0.350 mg/L EPA 200.7 06/13/2015 12:52 MHALL30.1 1 Sodium (Na)2.66 mg/L EPA 200.7 06/13/2015 12:52 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.086 mg/L EPA 200.7 06/09/2015 14:53 MHALL30.005 1 Barium (Ba)0.017 mg/L EPA 200.7 06/09/2015 14:53 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/09/2015 14:53 MHALL30.05 1 Iron (Fe)7.59 mg/L EPA 200.7 06/09/2015 14:53 MHALL30.01 1 Manganese (Mn)0.085 mg/L EPA 200.7 06/09/2015 14:53 MHALL30.005 1 Strontium (Sr)0.014 mg/L EPA 200.7 06/09/2015 14:53 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 14:53 MHALL30.005 1 Analytical Lab Page 8 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017700 Collection Date: 05-Jun-15 8:30 AM Site: SMW-4B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 12:14 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 12:14 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 12:14 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 12:14 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 12:14 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 12:14 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 12:14 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 12:14 SLS256011 Molybdenum (Mo)1.89 ug/L EPA 200.8 06/21/2015 12:14 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 12:14 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 12:14 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 12:14 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 12:14 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/18/2015 14:12 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 06/18/2015 14:12 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/18/2015 14:12 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/18/2015 14:12 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/18/2015 14:12 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 06/18/2015 14:12 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 06/18/2015 14:12 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/18/2015 14:12 JAHERMA11 Molybdenum (Mo)2.66 ug/L EPA 200.8 06/18/2015 14:12 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 06/18/2015 14:12 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 06/18/2015 14:12 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/18/2015 14:12 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/18/2015 14:12 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 42 mg/L SM2540C 06/11/2015 11:45 AGIBBS5251 Total Carbon TOC 1.1 mg/L SM5310C/EPA9060A 06/23/2015 14:43 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/09/2015 13:12 AGIBBS551 Analytical Lab Page 9 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017701 Collection Date: 05-Jun-15 11:03 AM Site: SMW-4C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.044 mg-N/L EPA 353.2 06/09/2015 12:24 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 18 mg/L EPA 300.0 06/12/2015 18:30 BGN9034110 Sulfate 16 mg/L EPA 300.0 06/12/2015 18:30 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/12/2015 11:52 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 13:47 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.019 mg/L EPA 200.7 06/12/2015 10:06 MHALL30.005 1 Barium (Ba)0.032 mg/L EPA 200.7 06/12/2015 10:06 MHALL30.005 1 Boron (B)0.079 mg/L EPA 200.7 06/12/2015 10:06 MHALL30.05 1 Iron (Fe)8.86 mg/L EPA 200.7 06/12/2015 10:06 MHALL30.01 1 Manganese (Mn)0.124 mg/L EPA 200.7 06/12/2015 10:06 MHALL30.005 1 Strontium (Sr)0.055 mg/L EPA 200.7 06/12/2015 10:06 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/12/2015 10:06 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)9.59 mg/L EPA 200.7 06/13/2015 12:56 MHALL30.01 1 Magnesium (Mg)3.49 mg/L EPA 200.7 06/13/2015 12:56 MHALL30.005 1 Potassium (K)1.15 mg/L EPA 200.7 06/13/2015 12:56 MHALL30.1 1 Sodium (Na)22.1 mg/L EPA 200.7 06/13/2015 12:56 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.260 mg/L EPA 200.7 06/09/2015 15:04 MHALL30.005 1 Barium (Ba)0.036 mg/L EPA 200.7 06/09/2015 15:04 MHALL30.005 1 Boron (B)0.085 mg/L EPA 200.7 06/09/2015 15:04 MHALL30.05 1 Iron (Fe)9.66 mg/L EPA 200.7 06/09/2015 15:04 MHALL30.01 1 Manganese (Mn)0.132 mg/L EPA 200.7 06/09/2015 15:04 MHALL30.005 1 Strontium (Sr)0.054 mg/L EPA 200.7 06/09/2015 15:04 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 15:04 MHALL30.005 1 Analytical Lab Page 10 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017701 Collection Date: 05-Jun-15 11:03 AM Site: SMW-4C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 12:21 SLS256011 Arsenic (As)2.09 ug/L EPA 200.8 06/21/2015 12:21 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 12:21 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 12:21 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 12:21 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 12:21 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 12:21 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 12:21 SLS256011 Molybdenum (Mo)1.66 ug/L EPA 200.8 06/21/2015 12:21 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 12:21 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 12:21 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 12:21 SLS25600.2 1 Vanadium (V) Low Level 0.328 ug/L EPA 200.8 06/21/2015 12:21 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/18/2015 13:51 JAHERMA11 Arsenic (As)2.56 ug/L EPA 200.8 06/18/2015 13:51 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/18/2015 13:51 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/18/2015 13:51 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/18/2015 13:51 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 06/18/2015 13:51 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 06/18/2015 13:51 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/18/2015 13:51 JAHERMA11 Molybdenum (Mo)2.69 ug/L EPA 200.8 06/18/2015 13:51 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 06/18/2015 13:51 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 06/18/2015 13:51 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/18/2015 13:51 JAHERMA0.2 1 Vanadium (V) Low Level 0.803 ug/L EPA 200.8 06/18/2015 13:51 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 110 mg/L SM2540C 06/11/2015 11:45 AGIBBS5251 Total Carbon TOC 3.2 mg/L SM5310C/EPA9060A 06/23/2015 14:43 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS 21 mg/L SM2540D 06/09/2015 13:12 AGIBBS551 Analytical Lab Page 11 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017702 Collection Date: 05-Jun-15 12:30 PM Site: SMW-5B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.135 mg-N/L EPA 353.2 06/09/2015 12:26 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 5.2 mg/L EPA 300.0 06/12/2015 21:55 BGN90340.1 1 Sulfate 49 mg/L EPA 300.0 06/12/2015 21:55 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/12/2015 11:45 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 13:50 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.039 mg/L EPA 200.7 06/12/2015 10:10 MHALL30.005 1 Barium (Ba)0.036 mg/L EPA 200.7 06/12/2015 10:10 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/12/2015 10:10 MHALL30.05 1 Iron (Fe)11.4 mg/L EPA 200.7 06/12/2015 10:10 MHALL30.01 1 Manganese (Mn)0.148 mg/L EPA 200.7 06/12/2015 10:10 MHALL30.005 1 Strontium (Sr)0.065 mg/L EPA 200.7 06/12/2015 10:10 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/12/2015 10:10 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)27.3 mg/L EPA 200.7 06/13/2015 13:00 MHALL30.01 1 Magnesium (Mg)2.26 mg/L EPA 200.7 06/13/2015 13:00 MHALL30.005 1 Potassium (K)4.46 mg/L EPA 200.7 06/13/2015 13:00 MHALL30.1 1 Sodium (Na)3.60 mg/L EPA 200.7 06/13/2015 13:00 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.042 mg/L EPA 200.7 06/09/2015 15:08 MHALL30.005 1 Barium (Ba)0.036 mg/L EPA 200.7 06/09/2015 15:08 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/09/2015 15:08 MHALL30.05 1 Iron (Fe)9.91 mg/L EPA 200.7 06/09/2015 15:08 MHALL30.01 1 Manganese (Mn)0.139 mg/L EPA 200.7 06/09/2015 15:08 MHALL30.005 1 Strontium (Sr)0.065 mg/L EPA 200.7 06/09/2015 15:08 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 15:08 MHALL30.005 1 Analytical Lab Page 12 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017702 Collection Date: 05-Jun-15 12:30 PM Site: SMW-5B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 12:29 SLS256011 Arsenic (As)1.34 ug/L EPA 200.8 06/21/2015 12:29 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 12:29 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 12:29 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 12:29 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 12:29 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 12:29 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 12:29 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 12:29 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 12:29 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 12:29 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 12:29 SLS25600.2 1 Vanadium (V) Low Level 0.770 ug/L EPA 200.8 06/21/2015 12:29 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/18/2015 14:19 JAHERMA11 Arsenic (As)1.47 ug/L EPA 200.8 06/18/2015 14:19 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/18/2015 14:19 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/18/2015 14:19 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/18/2015 14:19 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 06/18/2015 14:19 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 06/18/2015 14:19 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/18/2015 14:19 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/18/2015 14:19 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 06/18/2015 14:19 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 06/18/2015 14:19 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/18/2015 14:19 JAHERMA0.2 1 Vanadium (V) Low Level 0.810 ug/L EPA 200.8 06/18/2015 14:19 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 150 mg/L SM2540C 06/11/2015 11:45 AGIBBS5251 Total Carbon TOC 0.706 mg/L SM5310C/EPA9060A 06/23/2015 14:43 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/09/2015 13:12 AGIBBS551 Analytical Lab Page 13 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017703 Collection Date: 05-Jun-15 11:48 AM Site: SMW-5C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/09/2015 12:27 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 33 mg/L EPA 300.0 06/12/2015 19:03 BGN9034110 Sulfate 53 mg/L EPA 300.0 06/12/2015 19:03 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/12/2015 11:54 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 13:52 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.109 mg/L EPA 200.7 06/12/2015 10:13 MHALL30.005 1 Barium (Ba)0.076 mg/L EPA 200.7 06/12/2015 10:13 MHALL30.005 1 Boron (B)0.365 mg/L EPA 200.7 06/12/2015 10:13 MHALL30.05 1 Iron (Fe)0.078 mg/L EPA 200.7 06/12/2015 10:13 MHALL30.01 1 Manganese (Mn)0.131 mg/L EPA 200.7 06/12/2015 10:13 MHALL30.005 1 Strontium (Sr)0.226 mg/L EPA 200.7 06/12/2015 10:13 MHALL30.005 1 Zinc (Zn)0.006 mg/L EPA 200.7 06/12/2015 10:13 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)15.2 mg/L EPA 200.7 06/13/2015 13:03 MHALL30.01 1 Magnesium (Mg)3.24 mg/L EPA 200.7 06/13/2015 13:03 MHALL30.005 1 Potassium (K)2.37 mg/L EPA 200.7 06/13/2015 13:03 MHALL30.1 1 Sodium (Na)18.0 mg/L EPA 200.7 06/13/2015 13:03 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.121 mg/L EPA 200.7 06/09/2015 15:12 MHALL30.005 1 Barium (Ba)0.079 mg/L EPA 200.7 06/09/2015 15:12 MHALL30.005 1 Boron (B)0.362 mg/L EPA 200.7 06/09/2015 15:12 MHALL30.05 1 Iron (Fe)0.175 mg/L EPA 200.7 06/09/2015 15:12 MHALL30.01 1 Manganese (Mn)0.130 mg/L EPA 200.7 06/09/2015 15:12 MHALL30.005 1 Strontium (Sr)0.228 mg/L EPA 200.7 06/09/2015 15:12 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 15:12 MHALL30.005 1 Analytical Lab Page 14 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017703 Collection Date: 05-Jun-15 11:48 AM Site: SMW-5C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/19/2015 13:25 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 06/19/2015 13:25 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/19/2015 13:25 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/19/2015 13:25 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/19/2015 13:25 JAHERMA11 Cobalt (Co)2.44 ug/L EPA 200.8 06/19/2015 13:25 JAHERMA11 Copper (Cu)1.27 ug/L EPA 200.8 06/19/2015 13:25 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/19/2015 13:25 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/19/2015 13:25 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 06/19/2015 13:25 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 06/19/2015 13:25 JAHERMA11 Thallium (Tl) Low Level 0.260 ug/L EPA 200.8 06/19/2015 13:25 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/19/2015 13:25 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/18/2015 14:26 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 06/18/2015 14:26 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/18/2015 14:26 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/18/2015 14:26 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/18/2015 14:26 JAHERMA11 Cobalt (Co)2.60 ug/L EPA 200.8 06/18/2015 14:26 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 06/18/2015 14:26 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/18/2015 14:26 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/18/2015 14:26 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 06/18/2015 14:26 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 06/18/2015 14:26 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/18/2015 14:26 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/18/2015 14:26 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 120 mg/L SM2540C 06/11/2015 11:45 AGIBBS5251 Total Carbon TOC 0.429 mg/L SM5310C/EPA9060A 06/23/2015 14:43 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/09/2015 13:12 AGIBBS551 Analytical Lab Page 15 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017704 Collection Date: 05-Jun-15 12:14 PM Site: AW-4B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.062 mg-N/L EPA 353.2 06/09/2015 12:28 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 3.9 mg/L EPA 300.0 06/12/2015 22:27 BGN90340.1 1 Sulfate 5.4 mg/L EPA 300.0 06/12/2015 22:27 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/12/2015 11:57 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 13:54 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 06/12/2015 10:17 MHALL30.005 1 Barium (Ba)0.011 mg/L EPA 200.7 06/12/2015 10:17 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/12/2015 10:17 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 06/12/2015 10:17 MHALL30.01 1 Manganese (Mn)0.023 mg/L EPA 200.7 06/12/2015 10:17 MHALL30.005 1 Strontium (Sr)0.012 mg/L EPA 200.7 06/12/2015 10:17 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/12/2015 10:17 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)4.28 mg/L EPA 200.7 06/13/2015 13:38 MHALL30.01 1 Magnesium (Mg)0.438 mg/L EPA 200.7 06/13/2015 13:38 MHALL30.005 1 Potassium (K)0.899 mg/L EPA 200.7 06/13/2015 13:38 MHALL30.1 1 Sodium (Na)1.40 mg/L EPA 200.7 06/13/2015 13:38 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.007 mg/L EPA 200.7 06/09/2015 15:16 MHALL30.005 1 Barium (Ba)0.012 mg/L EPA 200.7 06/09/2015 15:16 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/09/2015 15:16 MHALL30.05 1 Iron (Fe)0.041 mg/L EPA 200.7 06/09/2015 15:16 MHALL30.01 1 Manganese (Mn)0.022 mg/L EPA 200.7 06/09/2015 15:16 MHALL30.005 1 Strontium (Sr)0.013 mg/L EPA 200.7 06/09/2015 15:16 MHALL30.005 1 Zinc (Zn)0.009 mg/L EPA 200.7 06/09/2015 15:16 MHALL30.005 1 Analytical Lab Page 16 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017704 Collection Date: 05-Jun-15 12:14 PM Site: AW-4B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/19/2015 13:32 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 06/19/2015 13:32 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/19/2015 13:32 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/19/2015 13:32 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/19/2015 13:32 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 06/19/2015 13:32 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 06/19/2015 13:32 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/19/2015 13:32 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/19/2015 13:32 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 06/19/2015 13:32 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 06/19/2015 13:32 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/19/2015 13:32 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/19/2015 13:32 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/18/2015 14:33 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 06/18/2015 14:33 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/18/2015 14:33 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/18/2015 14:33 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/18/2015 14:33 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 06/18/2015 14:33 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 06/18/2015 14:33 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/18/2015 14:33 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/18/2015 14:33 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 06/18/2015 14:33 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 06/18/2015 14:33 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/18/2015 14:33 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/18/2015 14:33 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 06/11/2015 11:45 AGIBBS5251 Total Carbon TOC 0.478 mg/L SM5310C/EPA9060A 06/23/2015 14:43 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/09/2015 13:12 AGIBBS551 Analytical Lab Page 17 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017705 Collection Date: 05-Jun-15 1:48 PM Site: AW-4C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.038 mg-N/L EPA 353.2 06/09/2015 12:32 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 49 mg/L EPA 300.0 06/13/2015 09:31 BGN9034110 Sulfate 120 mg/L EPA 300.0 06/13/2015 09:31 BGN90342.5 25 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/12/2015 11:59 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 13:57 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.010 mg/L EPA 200.7 06/12/2015 10:21 MHALL30.005 1 Barium (Ba)0.039 mg/L EPA 200.7 06/12/2015 10:21 MHALL30.005 1 Boron (B)1.44 mg/L EPA 200.7 06/12/2015 10:21 MHALL30.05 1 Iron (Fe)4.42 mg/L EPA 200.7 06/12/2015 10:21 MHALL30.01 1 Manganese (Mn)0.797 mg/L EPA 200.7 06/12/2015 10:21 MHALL30.005 1 Strontium (Sr)0.836 mg/L EPA 200.7 06/12/2015 10:21 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/12/2015 10:21 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)41.7 mg/L EPA 200.7 06/13/2015 13:07 MHALL30.01 1 Magnesium (Mg)6.87 mg/L EPA 200.7 06/13/2015 13:07 MHALL30.005 1 Potassium (K)7.72 mg/L EPA 200.7 06/13/2015 13:07 MHALL30.1 1 Sodium (Na)39.4 mg/L EPA 200.7 06/13/2015 13:07 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.038 mg/L EPA 200.7 06/09/2015 15:20 MHALL30.005 1 Barium (Ba)0.037 mg/L EPA 200.7 06/09/2015 15:20 MHALL30.005 1 Boron (B)1.45 mg/L EPA 200.7 06/09/2015 15:20 MHALL30.05 1 Iron (Fe)3.99 mg/L EPA 200.7 06/09/2015 15:20 MHALL30.01 1 Manganese (Mn)0.787 mg/L EPA 200.7 06/09/2015 15:20 MHALL30.005 1 Strontium (Sr)0.877 mg/L EPA 200.7 06/09/2015 15:20 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 15:20 MHALL30.005 1 Analytical Lab Page 18 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017705 Collection Date: 05-Jun-15 1:48 PM Site: AW-4C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/19/2015 13:04 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 06/19/2015 13:04 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/19/2015 13:04 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/19/2015 13:04 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/19/2015 13:04 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 06/19/2015 13:04 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 06/19/2015 13:04 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/19/2015 13:04 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/19/2015 13:04 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 06/19/2015 13:04 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 06/19/2015 13:04M2 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/19/2015 13:04 JAHERMA0.2 1 Vanadium (V) Low Level 0.394 ug/L EPA 200.8 06/19/2015 13:04 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/18/2015 14:40 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 06/18/2015 14:40 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/18/2015 14:40 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/18/2015 14:40 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/18/2015 14:40 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 06/18/2015 14:40 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 06/18/2015 14:40 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/18/2015 14:40 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/18/2015 14:40 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 06/18/2015 14:40 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 06/18/2015 14:40 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/18/2015 14:40 JAHERMA0.2 1 Vanadium (V) Low Level 0.518 ug/L EPA 200.8 06/18/2015 14:40 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 310 mg/L SM2540C 06/11/2015 11:45 AGIBBS5251 Total Carbon TOC 1.3 mg/L SM5310C/EPA9060A 06/24/2015 14:12 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/09/2015 13:12 AGIBBS551 Analytical Lab Page 19 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017706 Collection Date: 05-Jun-15 10:51 AM Site: AW-7B/MW-31B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.010 mg-N/L EPA 353.2 06/09/2015 12:33 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 3.7 mg/L EPA 300.0 06/12/2015 23:00 BGN90340.1 1 Sulfate 8.0 mg/L EPA 300.0 06/12/2015 23:00 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/12/2015 12:01 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 13:59 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.015 mg/L EPA 200.7 06/12/2015 10:25 MHALL30.005 1 Barium (Ba)0.036 mg/L EPA 200.7 06/12/2015 10:25 MHALL30.005 1 Boron (B)0.054 mg/L EPA 200.7 06/12/2015 10:25 MHALL30.05 1 Iron (Fe)0.649 mg/L EPA 200.7 06/12/2015 10:25 MHALL30.01 1 Manganese (Mn)0.068 mg/L EPA 200.7 06/12/2015 10:25 MHALL30.005 1 Strontium (Sr)0.121 mg/L EPA 200.7 06/12/2015 10:25 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/12/2015 10:25 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)5.61 mg/L EPA 200.7 06/13/2015 13:11 MHALL30.01 1 Magnesium (Mg)1.05 mg/L EPA 200.7 06/13/2015 13:11 MHALL30.005 1 Potassium (K)1.01 mg/L EPA 200.7 06/13/2015 13:11 MHALL30.1 1 Sodium (Na)2.21 mg/L EPA 200.7 06/13/2015 13:11 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.203 mg/L EPA 200.7 06/09/2015 15:23 MHALL30.005 1 Barium (Ba)0.035 mg/L EPA 200.7 06/09/2015 15:23 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/09/2015 15:23 MHALL30.05 1 Iron (Fe)1.18 mg/L EPA 200.7 06/09/2015 15:23 MHALL30.01 1 Manganese (Mn)0.073 mg/L EPA 200.7 06/09/2015 15:23 MHALL30.005 1 Strontium (Sr)0.115 mg/L EPA 200.7 06/09/2015 15:23 MHALL30.005 1 Zinc (Zn)0.012 mg/L EPA 200.7 06/09/2015 15:23 MHALL30.005 1 Analytical Lab Page 20 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017706 Collection Date: 05-Jun-15 10:51 AM Site: AW-7B/MW-31B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/19/2015 13:39 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 06/19/2015 13:39 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/19/2015 13:39 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/19/2015 13:39 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/19/2015 13:39 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 06/19/2015 13:39 JAHERMA11 Copper (Cu)1.41 ug/L EPA 200.8 06/19/2015 13:39 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/19/2015 13:39 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/19/2015 13:39 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 06/19/2015 13:39 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 06/19/2015 13:39 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/19/2015 13:39 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/19/2015 13:39 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/18/2015 14:47 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 06/18/2015 14:47 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/18/2015 14:47 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/18/2015 14:47 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/18/2015 14:47 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 06/18/2015 14:47 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 06/18/2015 14:47 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/18/2015 14:47 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/18/2015 14:47 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 06/18/2015 14:47 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 06/18/2015 14:47 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/18/2015 14:47 JAHERMA0.2 1 Vanadium (V) Low Level 0.378 ug/L EPA 200.8 06/18/2015 14:47 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 40 mg/L SM2540C 06/11/2015 11:45 AGIBBS5251 Total Carbon TOC 2.6 mg/L SM5310C/EPA9060A 06/24/2015 14:12 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/09/2015 13:12 AGIBBS551 Analytical Lab Page 21 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017707 Collection Date: 05-Jun-15 10:29 AM Site: AW-7C/MW-31C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.024 mg-N/L EPA 353.2 06/09/2015 12:34 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 170 mg/L EPA 300.0 06/13/2015 09:47 BGN90342.5 25 Sulfate 160 mg/L EPA 300.0 06/13/2015 09:47 BGN90342.5 25 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/12/2015 12:04 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 14:01 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.015 mg/L EPA 200.7 06/12/2015 10:29 MHALL30.005 1 Barium (Ba)0.057 mg/L EPA 200.7 06/12/2015 10:29 MHALL30.005 1 Boron (B)1.19 mg/L EPA 200.7 06/12/2015 10:29 MHALL30.05 1 Iron (Fe)2.70 mg/L EPA 200.7 06/12/2015 10:29 MHALL30.01 1 Manganese (Mn)1.75 mg/L EPA 200.7 06/12/2015 10:29 MHALL30.005 1 Strontium (Sr)0.674 mg/L EPA 200.7 06/12/2015 10:29 MHALL30.005 1 Zinc (Zn)0.055 mg/L EPA 200.7 06/12/2015 10:29 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)55.6 mg/L EPA 200.7 06/13/2015 13:15 MHALL30.01 1 Magnesium (Mg)14.4 mg/L EPA 200.7 06/13/2015 13:15 MHALL30.005 1 Potassium (K)7.18 mg/L EPA 200.7 06/13/2015 13:15 MHALL30.1 1 Sodium (Na)88.1 mg/L EPA 200.7 06/13/2015 13:15 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.019 mg/L EPA 200.7 06/09/2015 15:27 MHALL30.005 1 Barium (Ba)0.057 mg/L EPA 200.7 06/09/2015 15:27 MHALL30.005 1 Boron (B)1.18 mg/L EPA 200.7 06/09/2015 15:27 MHALL30.05 1 Iron (Fe)2.69 mg/L EPA 200.7 06/09/2015 15:27 MHALL30.01 1 Manganese (Mn)1.74 mg/L EPA 200.7 06/09/2015 15:27 MHALL30.005 1 Strontium (Sr)0.690 mg/L EPA 200.7 06/09/2015 15:27 MHALL30.005 1 Zinc (Zn)0.050 mg/L EPA 200.7 06/09/2015 15:27 MHALL30.005 1 Analytical Lab Page 22 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017707 Collection Date: 05-Jun-15 10:29 AM Site: AW-7C/MW-31C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/19/2015 13:46 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 06/19/2015 13:46 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/19/2015 13:46 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/19/2015 13:46 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/19/2015 13:46 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 06/19/2015 13:46 JAHERMA11 Copper (Cu)7.59 ug/L EPA 200.8 06/19/2015 13:46 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/19/2015 13:46 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/19/2015 13:46 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 06/19/2015 13:46 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 06/19/2015 13:46 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/19/2015 13:46 JAHERMA0.2 1 Vanadium (V) Low Level 0.316 ug/L EPA 200.8 06/19/2015 13:46 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/18/2015 14:54 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 06/18/2015 14:54 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/18/2015 14:54 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/18/2015 14:54 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/18/2015 14:54 JAHERMA11 Cobalt (Co)1.10 ug/L EPA 200.8 06/18/2015 14:54 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 06/18/2015 14:54 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/18/2015 14:54 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/18/2015 14:54 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 06/18/2015 14:54 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 06/18/2015 14:54 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/18/2015 14:54 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/18/2015 14:54 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 540 mg/L SM2540C 06/11/2015 11:45 AGIBBS5251 Total Carbon TOC 0.630 mg/L SM5310C/EPA9060A 06/24/2015 14:12 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/09/2015 13:12 AGIBBS551 Analytical Lab Page 23 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017708 Collection Date: 05-Jun-15 8:56 AM Site: AW-7D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.016 mg-N/L EPA 353.2 06/09/2015 12:35 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 120 mg/L EPA 300.0 06/13/2015 10:04 BGN90342.5 25 Sulfate 5.7 mg/L EPA 300.0 06/13/2015 10:04 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/12/2015 12:06 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 14:08 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.015 mg/L EPA 200.7 06/12/2015 10:40 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 06/12/2015 10:40 MHALL30.005 1 Boron (B)0.804 mg/L EPA 200.7 06/12/2015 10:40 MHALL30.05 1 Iron (Fe)0.033 mg/L EPA 200.7 06/12/2015 10:40 MHALL30.01 1 Manganese (Mn)0.013 mg/L EPA 200.7 06/12/2015 10:40 MHALL30.005 1 Strontium (Sr)0.085 mg/L EPA 200.7 06/12/2015 10:40 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/12/2015 10:40 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)11.4 mg/L EPA 200.7 06/13/2015 13:23 MHALL30.01 1 Magnesium (Mg)6.34 mg/L EPA 200.7 06/13/2015 13:23 MHALL30.005 1 Potassium (K)8.93 mg/L EPA 200.7 06/13/2015 13:23 MHALL30.1 1 Sodium (Na)171 mg/L EPA 200.7 06/13/2015 13:23 MHALL30.5 10 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.136 mg/L EPA 200.7 06/09/2015 15:31 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 06/09/2015 15:31 MHALL30.005 1 Boron (B)0.815 mg/L EPA 200.7 06/09/2015 15:31 MHALL30.05 1 Iron (Fe)0.220 mg/L EPA 200.7 06/09/2015 15:31 MHALL30.01 1 Manganese (Mn)0.014 mg/L EPA 200.7 06/09/2015 15:31 MHALL30.005 1 Strontium (Sr)0.089 mg/L EPA 200.7 06/09/2015 15:31 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 15:31 MHALL30.005 1 Analytical Lab Page 24 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017708 Collection Date: 05-Jun-15 8:56 AM Site: AW-7D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/19/2015 13:53 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 06/19/2015 13:53 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/19/2015 13:53 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/19/2015 13:53 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/19/2015 13:53 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 06/19/2015 13:53 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 06/19/2015 13:53 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/19/2015 13:53 JAHERMA11 Molybdenum (Mo)8.33 ug/L EPA 200.8 06/19/2015 13:53 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 06/19/2015 13:53 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 06/19/2015 13:53 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/19/2015 13:53 JAHERMA0.2 1 Vanadium (V) Low Level 0.626 ug/L EPA 200.8 06/19/2015 13:53 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/18/2015 15:01 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 06/18/2015 15:01 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/18/2015 15:01 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/18/2015 15:01 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/18/2015 15:01 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 06/18/2015 15:01 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 06/18/2015 15:01 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/18/2015 15:01 JAHERMA11 Molybdenum (Mo)8.53 ug/L EPA 200.8 06/18/2015 15:01 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 06/18/2015 15:01 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 06/18/2015 15:01 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/18/2015 15:01 JAHERMA0.2 1 Vanadium (V) Low Level 0.992 ug/L EPA 200.8 06/18/2015 15:01 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 510 mg/L SM2540C 06/11/2015 11:45 AGIBBS5251 Total Carbon TOC 8.2 mg/L SM5310C/EPA9060A 06/24/2015 14:12 GHUTCHI0.5 5 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/09/2015 13:12 AGIBBS551 Analytical Lab Page 25 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017709 Collection Date: 05-Jun-15 1:45 PM Site: Filter Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 14:16 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 06/12/2015 10:52 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 06/12/2015 10:52 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/12/2015 10:52 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 06/12/2015 10:52 MHALL30.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 06/12/2015 10:52 MHALL30.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 06/12/2015 10:52 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/12/2015 10:52 MHALL30.005 1 TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/19/2015 14:00 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 06/19/2015 14:00 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/19/2015 14:00 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/19/2015 14:00 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/19/2015 14:00 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 06/19/2015 14:00 JAHERMA11 Copper (Cu)2.09 ug/L EPA 200.8 06/19/2015 14:00 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/19/2015 14:00 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/19/2015 14:00 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 06/19/2015 14:00 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 06/19/2015 14:00 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/19/2015 14:00 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/19/2015 14:00 JAHERMA0.3 1 Analytical Lab Page 26 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017710 Collection Date: 05-Jun-15 1:45 PM Site: Equipment Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/09/2015 12:41 LSTARL10.01 1 INORGANIC IONS BY IC Chloride < 0.1 mg/L EPA 300.0 06/12/2015 20:49 BGN90340.1 1 Sulfate < 0.1 mg/L EPA 300.0 06/12/2015 20:49 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/12/2015 12:09 ACPAYNE0.05 1 UNDIGESTED METALS BY ICP Calcium (Ca)0.023 mg/L EPA 200.7 06/13/2015 13:49 MHALL30.01 1 Magnesium (Mg)< 0.005 mg/L EPA 200.7 06/13/2015 13:49 MHALL30.005 1 Potassium (K)< 0.1 mg/L EPA 200.7 06/13/2015 13:49 MHALL30.1 1 Sodium (Na)< 0.05 mg/L EPA 200.7 06/13/2015 13:49 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 06/09/2015 15:35 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 06/09/2015 15:35 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/09/2015 15:35 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 06/09/2015 15:35 MHALL30.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 06/09/2015 15:35 MHALL30.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 06/09/2015 15:35 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 15:35 MHALL30.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/18/2015 15:08 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 06/18/2015 15:08 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/18/2015 15:08 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/18/2015 15:08 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/18/2015 15:08 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 06/18/2015 15:08 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 06/18/2015 15:08 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/18/2015 15:08 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/18/2015 15:08 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 06/18/2015 15:08 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 06/18/2015 15:08 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/18/2015 15:08 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/18/2015 15:08 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY Analytical Lab Page 27 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060224 2015017710 Collection Date: 05-Jun-15 1:45 PM Site: Equipment Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 06/11/2015 11:45 AGIBBS5251 Total Carbon TOC 0.481 mg/L SM5310C/EPA9060A 06/24/2015 14:12 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/09/2015 13:12 AGIBBS551 Qualifiers: M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable. Analytical Lab Page 28 of 86 Analytical Lab Page 29 of 86 Analytical Lab Page 30 of 86 Analytical Lab Page 31 of 86 Analytical Lab Page 32 of 86 Analytical Lab Page 33 of 86 Analytical Lab Page 34 of 86 Analytical Lab Page 35 of 86 Analytical Lab Page 36 of 86 Analytical Lab Page 37 of 86 Analytical Lab Page 38 of 86 Analytical Lab Page 39 of 86 Analytical Lab Page 40 of 86 Analytical Lab Page 41 of 86 SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle QF08014Lot Number: J15060224Project Number: AB GW Assessment Water - SuttonProject Name: 06/17/2015Date Completed: Grant Wilton Project Manager *QF08014* This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. Page: 1 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Case Narrative Duke Energy Lot Number: QF08014 SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329 Project Name: AB GW Assessment Water - Sutton Project Number: J15060224 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. Page: 2 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: QF08014 Project Name: AB GW Assessment Water - Sutton Project Number: J15060224 Sample Number Sample ID Matrix Date Sampled Date Received 001 06/05/2015 09052015017698Aqueous 06/08/2015 002 06/05/2015 11182015017699Aqueous 06/08/2015 003 06/05/2015 08302015017700Aqueous 06/08/2015 004 06/05/2015 11032015017701Aqueous 06/08/2015 005 06/05/2015 12302015017702Aqueous 06/08/2015 006 06/05/2015 11482015017703Aqueous 06/08/2015 007 06/05/2015 12142015017704Aqueous 06/08/2015 008 06/05/2015 13482015017705Aqueous 06/08/2015 009 06/05/2015 10512015017706Aqueous 06/08/2015 010 06/05/2015 10292015017707Aqueous 06/08/2015 011 06/05/2015 08562015017708Aqueous 06/08/2015 012 06/05/2015 13452015017710Aqueous 06/08/2015 (12 samples) Page: 3 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: QF08014 Project Name: AB GW Assessment Water - Sutton Project Number: J15060224 Sample Sample ID Matrix Parameter Method Result Q Units Page 002 2015017699 Aqueous Alkalinity SM 2320B-16 mg/L 7 002 2015017699 Aqueous Bicarbonate Alkalinity SM 2320B-16 mg/L 7 003 2015017700 Aqueous Alkalinity SM 2320B-21 mg/L 9 003 2015017700 Aqueous Bicarbonate Alkalinity SM 2320B-21 mg/L 9 003 2015017700 Aqueous Methane RSK - 175 19 ug/L 10 004 2015017701 Aqueous Alkalinity SM 2320B-41 mg/L 11 004 2015017701 Aqueous Bicarbonate Alkalinity SM 2320B-41 mg/L 11 005 2015017702 Aqueous Alkalinity SM 2320B-50 mg/L 13 005 2015017702 Aqueous Bicarbonate Alkalinity SM 2320B-50 mg/L 13 005 2015017702 Aqueous Methane RSK - 175 130 ug/L 14 008 2015017705 Aqueous Alkalinity SM 2320B-46 mg/L 19 008 2015017705 Aqueous Bicarbonate Alkalinity SM 2320B-46 mg/L 19 008 2015017705 Aqueous Methane RSK - 175 19 ug/L 20 009 2015017706 Aqueous Alkalinity SM 2320B-11 mg/L 21 009 2015017706 Aqueous Bicarbonate Alkalinity SM 2320B-11 mg/L 21 009 2015017706 Aqueous Methane RSK - 175 33 ug/L 22 010 2015017707 Aqueous Alkalinity SM 2320B-14 mg/L 23 010 2015017707 Aqueous Bicarbonate Alkalinity SM 2320B-14 mg/L 23 010 2015017707 Aqueous Methane RSK - 175 10 ug/L 24 011 2015017708 Aqueous Alkalinity SM 2320B-240 mg/L 25 011 2015017708 Aqueous Bicarbonate Alkalinity SM 2320B-240 mg/L 25 (21 detections) Page: 4 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017698 QF08014-001 06/05/2015 0905 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 1713 HMA 76943 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 1713 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 1713 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 5 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017698 QF08014-001 06/05/2015 0905 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/12/2015 2115 JJG 77223 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 6 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017699 QF08014-002 06/05/2015 1118 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 1719 HMA 76943 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 1719 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 1719 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 16 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 16 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 7 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017699 QF08014-002 06/05/2015 1118 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/12/2015 2125 JJG 77223 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 8 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017700 QF08014-003 06/05/2015 0830 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 1724 HMA 76943 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 1724 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 1724 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 21 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 21 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 9 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017700 QF08014-003 06/05/2015 0830 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/12/2015 2135 JJG 77223 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 19 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 10 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017701 QF08014-004 06/05/2015 1103 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 1729 HMA 76943 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 1729 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 1729 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 41 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 41 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 11 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017701 QF08014-004 06/05/2015 1103 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/12/2015 2146 JJG 77223 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 12 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017702 QF08014-005 06/05/2015 1230 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 1735 HMA 76943 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 1735 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 1735 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 50 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 50 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 13 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017702 QF08014-005 06/05/2015 1230 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/12/2015 2156 JJG 77223 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 130 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 14 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017703 QF08014-006 06/05/2015 1148 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 1739 HMA 76943 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 1739 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 1739 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 15 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017703 QF08014-006 06/05/2015 1148 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/12/2015 2208 JJG 77223 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 16 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017704 QF08014-007 06/05/2015 1214 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 1746 HMA 76943 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 1746 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 1746 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 17 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017704 QF08014-007 06/05/2015 1214 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/12/2015 2224 JJG 77223 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 18 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017705 QF08014-008 06/05/2015 1348 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 1752 HMA 76943 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 1752 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 1752 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 46 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 46 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 19 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017705 QF08014-008 06/05/2015 1348 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/12/2015 2234 JJG 77223 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 19 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 20 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017706 QF08014-009 06/05/2015 1051 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 1811 HMA 76943 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 1811 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 1811 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 11 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 11 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 21 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017706 QF08014-009 06/05/2015 1051 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/12/2015 2249 JJG 77223 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 33 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 22 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017707 QF08014-010 06/05/2015 1029 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 1817 HMA 76943 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 1817 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 1817 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 14 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 14 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 23 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017707 QF08014-010 06/05/2015 1029 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/12/2015 2259 JJG 77223 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 10 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 24 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017708 QF08014-011 06/05/2015 0856 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 1824 HMA 76943 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 1824 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 1824 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 240 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 240 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 25 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017708 QF08014-011 06/05/2015 0856 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/16/2015 1333 DCS 77379 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 26 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017710 QF08014-012 06/05/2015 1345 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 1829 HMA 76943 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 1829 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 1829 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 27 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017710 QF08014-012 06/05/2015 1345 06/08/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060224 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/16/2015 2141 JJG 77428 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 28 of 28 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 QC Summary QC Data for Lot Number: QF08014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MB Batch: Sample ID:QQ76943-001 76943 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Alkalinity ND 06/10/2015 155210mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF08014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - LCS Batch: Sample ID:QQ76943-002 76943 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Alkalinity 100 06/10/2015 155810010090-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF08014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MS Batch: Sample ID:QF08014-012MS 76943 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Alkalinity 96 06/10/2015 18359610070-130ND1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF08014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MSD Batch: Sample ID:QF08014-012MD 76943 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Alkalinity 92 06/10/2015 18419210070-1303.9 20ND1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF08014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - MB Batch: Sample ID:QQ77223-001 77223 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 06/12/2015 172010ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF08014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCS Batch: Sample ID:QQ77223-002 77223 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 45 06/12/2015 1626885070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF08014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCSD Batch: Sample ID:QQ77223-003 77223 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 49 06/12/2015 1659965070-1308.8 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF08014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - MB Batch: Sample ID:QQ77379-001 77379 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 06/16/2015 120710ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF08014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCS Batch: Sample ID:QQ77379-002 77379 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 43 06/16/2015 1142865070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF08014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCSD Batch: Sample ID:QQ77379-003 77379 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 50 06/16/2015 1156995070-13014 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF08014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - MB Batch: Sample ID:QQ77428-001 77428 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 06/16/2015 170110ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF08014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCS Batch: Sample ID:QQ77428-002 77428 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 43 06/16/2015 1632855070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF08014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCSD Batch: Sample ID:QQ77428-003 77428 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 44 06/16/2015 1646875070-1302.2 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF08014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. qrm y Y L I s -- Ivry#f0 rl � in FF� I + S1W�N �j i Y ix,ixo # n� 0i J i LL N. V> � - s �a ra. �y¢[ + p % 18 ■ f '� 6 Hl H I r k� S 3 S {i . ra r-ar' MLJM PWJFIWa a1119:k�14R a'Id :l1 YI.16�1I `I'MaYGQ�I'� i 5� .06 ^ivy 1} JE c� I � a A a 16 .. ti I Qw4sl — W Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Analytical Lab Page 86 of 86