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HomeMy WebLinkAboutNC0001422_ATT 5 - Water - J15060200report_2015080513339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number: J15060200 Project Name:SUTTON - AB GW ASSESSMENT WATER Lab Contact:Mary Ann Ogle Date:6/24/2015 Customer Address: Customer Name(s): Perry Waldrep, Tim Hunsucker, Kathy Webb, John Toepfer Phone: 980-875-5274 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Mary Ann Ogle Analytical Lab Page 1 of 109 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015017559 Sutton 04-Jun-15 1:47 PM ILLEGIBLE SMW-6C 2015017560 Sutton 04-Jun-15 11:37 AM ILLEGIBLE AW-5D 2015017561 Sutton 04-Jun-15 11:26 AM ILLEGIBLE ABMW-02S 2015017562 Sutton 04-Jun-15 10:33 AM ILLEGIBLE ABMW-02D 2015017563 Sutton 04-Jun-15 2:02 PM ILLEGIBLE AW-9B 2015017564 Sutton 04-Jun-15 1:02 PM ILLEGIBLE AW-9C 2015017565 Sutton 04-Jun-15 12:19 PM ILLEGIBLE AW-9D 2015017566 Sutton 04-Jun-15 3:06 PM ILLEGIBLE SMW-3c 2015017567 Sutton 04-Jun-15 4:05 PM ILLEGIBLE SMW-3B 2015017568 Sutton 04-Jun-15 3:55 PM ILLEGIBLE ABMW-1S 2015017569 Sutton 04-Jun-15 5:35 PM ILLEGIBLE SMW-2B 2015017570 Sutton 04-Jun-15 5:04 PM ILLEGIBLE SMW-2C 2015017571 Sutton 04-Jun-15 5:54 PM ILLEGIBLE ABMW-02S 2015017572 Sutton 04-Jun-15 6:16 PM ILLEGIBLE ABMW-02D 2015017573 Sutton 04-Jun-15 2:10 PM RICHARD Filter Blank 2015017575 Sutton 04-Jun-15 2:10 PM Jacobs Equipment Blank 16 Total Samples Analytical Lab Page 2 of 109 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:Mary Ann Ogle Date:6/24/2015 Electronic Data Deliverable (EDD) Sent Separately Analytical Lab Page 3 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017559 Collection Date: 04-Jun-15 1:47 PM Site: SMW-6C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.017 mg-N/L EPA 353.2 06/09/2015 13:11 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 20 mg/L EPA 300.0 06/11/2015 14:44 BGN9034110 Sulfate 40 mg/L EPA 300.0 06/11/2015 14:44 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/08/2015 15:35 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/11/2015 11:15 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.038 mg/L EPA 200.7 06/09/2015 11:21 MHALL30.005 1 Barium (Ba)0.051 mg/L EPA 200.7 06/09/2015 11:21 MHALL30.005 1 Boron (B)0.199 mg/L EPA 200.7 06/09/2015 11:21 MHALL30.05 1 Iron (Fe)1.31 mg/L EPA 200.7 06/09/2015 11:21 MHALL30.01 1 Manganese (Mn)0.276 mg/L EPA 200.7 06/09/2015 11:21 MHALL30.005 1 Strontium (Sr)0.133 mg/L EPA 200.7 06/09/2015 11:21 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 11:21 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)15.5 mg/L EPA 200.7 06/11/2015 09:17 MHALL30.01 1 Magnesium (Mg)2.83 mg/L EPA 200.7 06/11/2015 09:17 MHALL30.005 1 Potassium (K)2.02 mg/L EPA 200.7 06/11/2015 09:17 MHALL30.1 1 Sodium (Na)11.6 mg/L EPA 200.7 06/11/2015 09:17 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.063 mg/L EPA 200.7 06/10/2015 14:43 MHALL30.005 1 Barium (Ba)0.053 mg/L EPA 200.7 06/10/2015 14:43 MHALL30.005 1 Boron (B)0.197 mg/L EPA 200.7 06/10/2015 14:43 MHALL30.05 1 Iron (Fe)1.32 mg/L EPA 200.7 06/10/2015 14:43 MHALL30.01 1 Manganese (Mn)0.273 mg/L EPA 200.7 06/10/2015 14:43 MHALL30.005 1 Strontium (Sr)0.132 mg/L EPA 200.7 06/10/2015 14:43 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/10/2015 14:43 MHALL30.005 1 Analytical Lab Page 4 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017559 Collection Date: 04-Jun-15 1:47 PM Site: SMW-6C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/19/2015 01:49 JAHERMA11 Arsenic (As)2.55 ug/L EPA 200.8 06/19/2015 01:49 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/19/2015 01:49 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/19/2015 01:49 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/19/2015 01:49 JAHERMA11 Cobalt (Co)3.69 ug/L EPA 200.8 06/19/2015 01:49 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 06/19/2015 01:49 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/19/2015 01:49 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/19/2015 01:49 JAHERMA11 Nickel (Ni)1.50 ug/L EPA 200.8 06/19/2015 01:49 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 06/19/2015 01:49 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/19/2015 01:49 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/19/2015 01:49 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 19:15 SLS256011 Arsenic (As)2.79 ug/L EPA 200.8 06/20/2015 19:15 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 19:15 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 19:15 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 19:15 SLS256011 Cobalt (Co)3.65 ug/L EPA 200.8 06/20/2015 19:15 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 19:15 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 19:15 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/20/2015 19:15 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 19:15 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 19:15 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 19:15 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 19:15 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 110 mg/L SM2540C 06/09/2015 16:06 AGIBBS5251 Total Carbon TOC 2.4 mg/L SM5310C/EPA9060A 06/23/2015 14:43 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/09/2015 08:20 AGIBBS551 Analytical Lab Page 5 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017560 Collection Date: 04-Jun-15 11:37 AM Site: AW-5D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/09/2015 13:12 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 96 mg/L EPA 300.0 06/11/2015 15:33 BGN9034110 Sulfate 24 mg/L EPA 300.0 06/11/2015 15:33 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/08/2015 15:38 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/11/2015 11:17 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.018 mg/L EPA 200.7 06/09/2015 11:25 MHALL30.005 1 Barium (Ba)0.008 mg/L EPA 200.7 06/09/2015 11:25 MHALL30.005 1 Boron (B)0.301 mg/L EPA 200.7 06/09/2015 11:25 MHALL30.05 1 Iron (Fe)0.027 mg/L EPA 200.7 06/09/2015 11:25 MHALL30.01 1 Manganese (Mn)0.037 mg/L EPA 200.7 06/09/2015 11:25 MHALL30.005 1 Strontium (Sr)0.085 mg/L EPA 200.7 06/09/2015 11:25 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 11:25 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)12.9 mg/L EPA 200.7 06/11/2015 10:18 MHALL30.01 1 Magnesium (Mg)5.58 mg/L EPA 200.7 06/11/2015 10:18 MHALL30.005 1 Potassium (K)6.36 mg/L EPA 200.7 06/11/2015 10:18 MHALL30.1 1 Sodium (Na)97.7 mg/L EPA 200.7 06/11/2015 10:18 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.149 mg/L EPA 200.7 06/10/2015 14:55 MHALL30.005 1 Barium (Ba)0.009 mg/L EPA 200.7 06/10/2015 14:55 MHALL30.005 1 Boron (B)0.306 mg/L EPA 200.7 06/10/2015 14:55 MHALL30.05 1 Iron (Fe)0.298 mg/L EPA 200.7 06/10/2015 14:55 MHALL30.01 1 Manganese (Mn)0.038 mg/L EPA 200.7 06/10/2015 14:55 MHALL30.005 1 Strontium (Sr)0.087 mg/L EPA 200.7 06/10/2015 14:55 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/10/2015 14:55 MHALL30.005 1 Analytical Lab Page 6 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017560 Collection Date: 04-Jun-15 11:37 AM Site: AW-5D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/19/2015 01:56 JAHERMA11 Arsenic (As)1.32 ug/L EPA 200.8 06/19/2015 01:56 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/19/2015 01:56 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/19/2015 01:56 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/19/2015 01:56 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 06/19/2015 01:56 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 06/19/2015 01:56 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/19/2015 01:56 JAHERMA11 Molybdenum (Mo)34.2 ug/L EPA 200.8 06/19/2015 01:56 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 06/19/2015 01:56 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 06/19/2015 01:56 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/19/2015 01:56 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/19/2015 01:56 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 18:54 SLS256011 Arsenic (As)1.36 ug/L EPA 200.8 06/20/2015 18:54 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 18:54 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 18:54 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 18:54 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/20/2015 18:54 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 18:54 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 18:54 SLS256011 Molybdenum (Mo)50.7 ug/L EPA 200.8 06/20/2015 18:54 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 18:54 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 18:54 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 18:54 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 18:54 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 330 mg/L SM2540C 06/09/2015 16:06 AGIBBS5251 Total Carbon TOC 1.9 mg/L SM5310C/EPA9060A 06/23/2015 14:43 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/09/2015 08:20 AGIBBS551 Analytical Lab Page 7 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017561 Collection Date: 04-Jun-15 11:26 AM Site: ABMW-02S Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.050 mg-N/L EPA 353.2 06/09/2015 13:14 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 14 mg/L EPA 300.0 06/11/2015 18:34 BGN9034110 Sulfate < 0.1 mg/L EPA 300.0 06/11/2015 18:34 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/08/2015 15:40 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/11/2015 11:19 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.060 mg/L EPA 200.7 06/09/2015 11:29 MHALL30.005 1 Barium (Ba)1.84 mg/L EPA 200.7 06/09/2015 11:29 MHALL30.005 1 Boron (B)0.237 mg/L EPA 200.7 06/09/2015 11:29 MHALL30.05 1 Iron (Fe)24.7 mg/L EPA 200.7 06/09/2015 11:29 MHALL30.01 1 Manganese (Mn)0.812 mg/L EPA 200.7 06/09/2015 11:29 MHALL30.005 1 Strontium (Sr)1.78 mg/L EPA 200.7 06/09/2015 11:29 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 11:29 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)60.8 mg/L EPA 200.7 06/11/2015 10:52 MHALL30.01 1 Magnesium (Mg)7.76 mg/L EPA 200.7 06/11/2015 10:52 MHALL30.005 1 Potassium (K)8.09 mg/L EPA 200.7 06/11/2015 10:52 MHALL30.1 1 Sodium (Na)37.4 mg/L EPA 200.7 06/11/2015 10:52 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.064 mg/L EPA 200.7 06/10/2015 14:58 MHALL30.005 1 Barium (Ba)1.81 mg/L EPA 200.7 06/10/2015 14:58 MHALL30.005 1 Boron (B)0.234 mg/L EPA 200.7 06/10/2015 14:58 MHALL30.05 1 Iron (Fe)24.1 mg/L EPA 200.7 06/10/2015 14:58 MHALL30.01 1 Manganese (Mn)0.784 mg/L EPA 200.7 06/10/2015 14:58 MHALL30.005 1 Strontium (Sr)1.75 mg/L EPA 200.7 06/10/2015 14:58 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/10/2015 14:58 MHALL30.005 1 Analytical Lab Page 8 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017561 Collection Date: 04-Jun-15 11:26 AM Site: ABMW-02S Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/19/2015 02:03 JAHERMA11 Arsenic (As)54.6 ug/L EPA 200.8 06/19/2015 02:03 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/19/2015 02:03 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/19/2015 02:03 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/19/2015 02:03 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 06/19/2015 02:03 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 06/19/2015 02:03 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/19/2015 02:03 JAHERMA11 Molybdenum (Mo)5.05 ug/L EPA 200.8 06/19/2015 02:03 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 06/19/2015 02:03 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 06/19/2015 02:03 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/19/2015 02:03 JAHERMA0.2 1 Vanadium (V) Low Level 1.46 ug/L EPA 200.8 06/19/2015 02:03 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 19:23 SLS256011 Arsenic (As)53.4 ug/L EPA 200.8 06/20/2015 19:23 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 19:23 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 19:23 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 19:23 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/20/2015 19:23 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 19:23 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 19:23 SLS256011 Molybdenum (Mo)5.18 ug/L EPA 200.8 06/20/2015 19:23 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 19:23 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 19:23 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 19:23 SLS25600.2 1 Vanadium (V) Low Level 1.28 ug/L EPA 200.8 06/20/2015 19:23 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 330 mg/L SM2540C 06/09/2015 16:06 AGIBBS5251 Total Carbon TOC 12 mg/L SM5310C/EPA9060A 06/23/2015 14:43 GHUTCHI110 TOTAL SUSPENDED SOLIDS TSS 39 mg/L SM2540D 06/09/2015 08:20 AGIBBS551 Analytical Lab Page 9 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017562 Collection Date: 04-Jun-15 10:33 AM Site: ABMW-02D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.011 mg-N/L EPA 353.2 06/09/2015 13:15 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 43 mg/L EPA 300.0 06/11/2015 16:06 BGN9034110 Sulfate 91 mg/L EPA 300.0 06/11/2015 16:06 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/08/2015 15:43 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/11/2015 11:22 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.006 mg/L EPA 200.7 06/09/2015 11:32 MHALL30.005 1 Barium (Ba)0.065 mg/L EPA 200.7 06/09/2015 11:32 MHALL30.005 1 Boron (B)0.604 mg/L EPA 200.7 06/09/2015 11:32 MHALL30.05 1 Iron (Fe)1.23 mg/L EPA 200.7 06/09/2015 11:32 MHALL30.01 1 Manganese (Mn)0.150 mg/L EPA 200.7 06/09/2015 11:32 MHALL30.005 1 Strontium (Sr)1.22 mg/L EPA 200.7 06/09/2015 11:32 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 11:32 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)34.8 mg/L EPA 200.7 06/11/2015 10:56 MHALL30.01 1 Magnesium (Mg)11.9 mg/L EPA 200.7 06/11/2015 10:56 MHALL30.005 1 Potassium (K)9.63 mg/L EPA 200.7 06/11/2015 10:56 MHALL30.1 1 Sodium (Na)45.8 mg/L EPA 200.7 06/11/2015 10:56 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.023 mg/L EPA 200.7 06/10/2015 15:02 MHALL30.005 1 Barium (Ba)0.065 mg/L EPA 200.7 06/10/2015 15:02 MHALL30.005 1 Boron (B)0.600 mg/L EPA 200.7 06/10/2015 15:02 MHALL30.05 1 Iron (Fe)1.27 mg/L EPA 200.7 06/10/2015 15:02 MHALL30.01 1 Manganese (Mn)0.150 mg/L EPA 200.7 06/10/2015 15:02 MHALL30.005 1 Strontium (Sr)1.23 mg/L EPA 200.7 06/10/2015 15:02 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/10/2015 15:02 MHALL30.005 1 Analytical Lab Page 10 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017562 Collection Date: 04-Jun-15 10:33 AM Site: ABMW-02D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/19/2015 02:10 JAHERMA11 Arsenic (As)167 ug/L EPA 200.8 06/19/2015 02:10 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/19/2015 02:10 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/19/2015 02:10 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/19/2015 02:10 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 06/19/2015 02:10 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 06/19/2015 02:10 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/19/2015 02:10 JAHERMA11 Molybdenum (Mo)113 ug/L EPA 200.8 06/19/2015 02:10 JAHERMA11 Nickel (Ni)2.61 ug/L EPA 200.8 06/19/2015 02:10 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 06/19/2015 02:10 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/19/2015 02:10 JAHERMA0.2 1 Vanadium (V) Low Level 0.504 ug/L EPA 200.8 06/19/2015 02:10 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 19:30 SLS256011 Arsenic (As)170 ug/L EPA 200.8 06/20/2015 19:30 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 19:30 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 19:30 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 19:30 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/20/2015 19:30 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 19:30 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 19:30 SLS256011 Molybdenum (Mo)117 ug/L EPA 200.8 06/20/2015 19:30 SLS256011 Nickel (Ni)2.22 ug/L EPA 200.8 06/20/2015 19:30 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 19:30 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 19:30 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 19:30 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 300 mg/L SM2540C 06/09/2015 16:06 AGIBBS5251 Total Carbon TOC 2.0 mg/L SM5310C/EPA9060A 06/23/2015 14:43 GHUTCHI0.2 2 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/09/2015 08:20 AGIBBS551 Analytical Lab Page 11 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017563 Collection Date: 04-Jun-15 2:02 PM Site: AW-9B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.158 mg-N/L EPA 353.2 06/12/2015 09:28 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 4.4 mg/L EPA 300.0 06/11/2015 19:07 BGN90340.1 1 Sulfate 18 mg/L EPA 300.0 06/11/2015 19:07 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/08/2015 15:45 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/11/2015 11:24 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)1.08 mg/L EPA 200.7 06/09/2015 11:36 MHALL30.005 1 Barium (Ba)0.016 mg/L EPA 200.7 06/09/2015 11:36 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/09/2015 11:36 MHALL30.05 1 Iron (Fe)0.039 mg/L EPA 200.7 06/09/2015 11:36 MHALL30.01 1 Manganese (Mn)0.018 mg/L EPA 200.7 06/09/2015 11:36 MHALL30.005 1 Strontium (Sr)0.012 mg/L EPA 200.7 06/09/2015 11:36 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 11:36 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)1.21 mg/L EPA 200.7 06/11/2015 11:00 MHALL30.01 1 Magnesium (Mg)0.391 mg/L EPA 200.7 06/11/2015 11:00 MHALL30.005 1 Potassium (K)0.656 mg/L EPA 200.7 06/11/2015 11:00 MHALL30.1 1 Sodium (Na)2.07 mg/L EPA 200.7 06/11/2015 11:00 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)1.42 mg/L EPA 200.7 06/10/2015 15:17 MHALL30.005 1 Barium (Ba)0.018 mg/L EPA 200.7 06/10/2015 15:17 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/10/2015 15:17 MHALL30.05 1 Iron (Fe)0.225 mg/L EPA 200.7 06/10/2015 15:17 MHALL30.01 1 Manganese (Mn)0.018 mg/L EPA 200.7 06/10/2015 15:17 MHALL30.005 1 Strontium (Sr)0.011 mg/L EPA 200.7 06/10/2015 15:17 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/10/2015 15:17 MHALL30.005 1 Analytical Lab Page 12 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017563 Collection Date: 04-Jun-15 2:02 PM Site: AW-9B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 08:59 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 08:59 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 08:59 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 08:59 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 08:59 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 08:59 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 08:59 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 08:59 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 08:59 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 08:59 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 08:59 SLS256011 Thallium (Tl) Low Level 0.272 ug/L EPA 200.8 06/21/2015 08:59 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 08:59 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 19:37 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/20/2015 19:37 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 19:37 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 19:37 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 19:37 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/20/2015 19:37 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 19:37 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 19:37 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/20/2015 19:37 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 19:37 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 19:37 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 19:37 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 19:37 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 06/09/2015 16:06 AGIBBS5251 Total Carbon TOC 0.760 mg/L SM5310C/EPA9060A 06/23/2015 14:43 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/09/2015 08:20 AGIBBS551 Analytical Lab Page 13 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017564 Collection Date: 04-Jun-15 1:02 PM Site: AW-9C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.435 mg-N/L EPA 353.2 06/12/2015 09:30 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 31 mg/L EPA 300.0 06/11/2015 16:39 BGN9034110 Sulfate 99 mg/L EPA 300.0 06/11/2015 16:39 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/08/2015 15:47 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/11/2015 11:36 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.169 mg/L EPA 200.7 06/09/2015 11:40 MHALL30.005 1 Barium (Ba)0.104 mg/L EPA 200.7 06/09/2015 11:40 MHALL30.005 1 Boron (B)0.566 mg/L EPA 200.7 06/09/2015 11:40 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 06/09/2015 11:40 MHALL30.01 1 Manganese (Mn)0.304 mg/L EPA 200.7 06/09/2015 11:40 MHALL30.005 1 Strontium (Sr)0.190 mg/L EPA 200.7 06/09/2015 11:40 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 11:40 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)19.8 mg/L EPA 200.7 06/11/2015 11:03 MHALL30.01 1 Magnesium (Mg)4.93 mg/L EPA 200.7 06/11/2015 11:03 MHALL30.005 1 Potassium (K)3.96 mg/L EPA 200.7 06/11/2015 11:03 MHALL30.1 1 Sodium (Na)24.4 mg/L EPA 200.7 06/11/2015 11:03 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.199 mg/L EPA 200.7 06/10/2015 15:21 MHALL30.005 1 Barium (Ba)0.118 mg/L EPA 200.7 06/10/2015 15:21 MHALL30.005 1 Boron (B)0.554 mg/L EPA 200.7 06/10/2015 15:21 MHALL30.05 1 Iron (Fe)0.102 mg/L EPA 200.7 06/10/2015 15:21 MHALL30.01 1 Manganese (Mn)0.289 mg/L EPA 200.7 06/10/2015 15:21 MHALL30.005 1 Strontium (Sr)0.193 mg/L EPA 200.7 06/10/2015 15:21 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/10/2015 15:21 MHALL30.005 1 Analytical Lab Page 14 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017564 Collection Date: 04-Jun-15 1:02 PM Site: AW-9C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 09:06 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 09:06 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 09:06 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 09:06 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 09:06 SLS256011 Cobalt (Co)1.18 ug/L EPA 200.8 06/21/2015 09:06 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 09:06 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 09:06 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 09:06 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 09:06 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 09:06 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 09:06 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 09:06 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 19:44 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/20/2015 19:44 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 19:44 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 19:44 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 19:44 SLS256011 Cobalt (Co)1.13 ug/L EPA 200.8 06/20/2015 19:44 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 19:44 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 19:44 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/20/2015 19:44 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 19:44 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 19:44 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 19:44 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 19:44 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 190 mg/L SM2540C 06/09/2015 16:06 AGIBBS5251 Total Carbon TOC 0.390 mg/L SM5310C/EPA9060A 06/23/2015 14:43 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/09/2015 08:20 AGIBBS551 Analytical Lab Page 15 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017565 Collection Date: 04-Jun-15 12:19 PM Site: AW-9D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/12/2015 09:31 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 220 mg/L EPA 300.0 06/12/2015 09:13 BGN9034550 Sulfate 53 mg/L EPA 300.0 06/12/2015 09:13 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/08/2015 15:54 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/11/2015 11:43 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.006 mg/L EPA 200.7 06/09/2015 11:44 MHALL30.005 1 Barium (Ba)0.008 mg/L EPA 200.7 06/09/2015 11:44 MHALL30.005 1 Boron (B)0.590 mg/L EPA 200.7 06/09/2015 11:44 MHALL30.05 1 Iron (Fe)0.062 mg/L EPA 200.7 06/09/2015 11:44 MHALL30.01 1 Manganese (Mn)0.039 mg/L EPA 200.7 06/09/2015 11:44 MHALL30.005 1 Strontium (Sr)0.134 mg/L EPA 200.7 06/09/2015 11:44 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 11:44 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)16.7 mg/L EPA 200.7 06/11/2015 10:10 MHALL30.01 1 Magnesium (Mg)9.33 mg/L EPA 200.7 06/11/2015 10:10 MHALL30.005 1 Potassium (K)10.0 mg/L EPA 200.7 06/11/2015 10:10 MHALL30.1 1 Sodium (Na)207 mg/L EPA 200.7 06/11/2015 10:10 MHALL30.5 10 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.046 mg/L EPA 200.7 06/10/2015 15:25 MHALL30.005 1 Barium (Ba)0.007 mg/L EPA 200.7 06/10/2015 15:25 MHALL30.005 1 Boron (B)0.581 mg/L EPA 200.7 06/10/2015 15:25 MHALL30.05 1 Iron (Fe)0.194 mg/L EPA 200.7 06/10/2015 15:25 MHALL30.01 1 Manganese (Mn)0.040 mg/L EPA 200.7 06/10/2015 15:25 MHALL30.005 1 Strontium (Sr)0.133 mg/L EPA 200.7 06/10/2015 15:25 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/10/2015 15:25 MHALL30.005 1 Analytical Lab Page 16 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017565 Collection Date: 04-Jun-15 12:19 PM Site: AW-9D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 08:37 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 08:37 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 08:37 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 08:37 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 08:37 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 08:37 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 08:37 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 08:37 SLS256011 Molybdenum (Mo)7.71 ug/L EPA 200.8 06/21/2015 08:37 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 08:37 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 08:37 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 08:37 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 08:37 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 19:52 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/20/2015 19:52 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 19:52 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 19:52 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 19:52 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/20/2015 19:52 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 19:52 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 19:52 SLS256011 Molybdenum (Mo)8.23 ug/L EPA 200.8 06/20/2015 19:52 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 19:52 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 19:52 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 19:52 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 19:52 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 630 mg/L SM2540C 06/09/2015 16:06 AGIBBS5251 Total Carbon TOC 2.4 mg/L SM5310C/EPA9060A 06/23/2015 14:43 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/09/2015 08:20 AGIBBS551 Analytical Lab Page 17 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017566 Collection Date: 04-Jun-15 3:06 PM Site: SMW-3c Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.012 mg-N/L EPA 353.2 06/12/2015 09:33 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 35 mg/L EPA 300.0 06/11/2015 17:12 BGN9034110 Sulfate 93 mg/L EPA 300.0 06/11/2015 17:12 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/08/2015 16:01 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/11/2015 11:45 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.153 mg/L EPA 200.7 06/09/2015 11:48 MHALL30.005 1 Barium (Ba)0.084 mg/L EPA 200.7 06/09/2015 11:48 MHALL30.005 1 Boron (B)0.418 mg/L EPA 200.7 06/09/2015 11:48 MHALL30.05 1 Iron (Fe)1.49 mg/L EPA 200.7 06/09/2015 11:48 MHALL30.01 1 Manganese (Mn)0.591 mg/L EPA 200.7 06/09/2015 11:48 MHALL30.005 1 Strontium (Sr)0.216 mg/L EPA 200.7 06/09/2015 11:48 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 11:48 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)24.9 mg/L EPA 200.7 06/11/2015 11:11 MHALL30.01 1 Magnesium (Mg)4.72 mg/L EPA 200.7 06/11/2015 11:11 MHALL30.005 1 Potassium (K)3.39 mg/L EPA 200.7 06/11/2015 11:11 MHALL30.1 1 Sodium (Na)22.5 mg/L EPA 200.7 06/11/2015 11:11 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.163 mg/L EPA 200.7 06/10/2015 15:29 MHALL30.005 1 Barium (Ba)0.086 mg/L EPA 200.7 06/10/2015 15:29 MHALL30.005 1 Boron (B)0.417 mg/L EPA 200.7 06/10/2015 15:29 MHALL30.05 1 Iron (Fe)1.51 mg/L EPA 200.7 06/10/2015 15:29 MHALL30.01 1 Manganese (Mn)0.584 mg/L EPA 200.7 06/10/2015 15:29 MHALL30.005 1 Strontium (Sr)0.218 mg/L EPA 200.7 06/10/2015 15:29 MHALL30.005 1 Zinc (Zn)0.006 mg/L EPA 200.7 06/10/2015 15:29 MHALL30.005 1 Analytical Lab Page 18 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017566 Collection Date: 04-Jun-15 3:06 PM Site: SMW-3c Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 09:14 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 09:14 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 09:14 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 09:14 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 09:14 SLS256011 Cobalt (Co)9.95 ug/L EPA 200.8 06/21/2015 09:14 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 09:14 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 09:14 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 09:14 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 09:14 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 09:14 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 09:14 SLS25600.2 1 Vanadium (V) Low Level 0.424 ug/L EPA 200.8 06/21/2015 09:14 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 19:59 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/20/2015 19:59 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 19:59 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 19:59 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 19:59 SLS256011 Cobalt (Co)9.21 ug/L EPA 200.8 06/20/2015 19:59 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 19:59 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 19:59 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/20/2015 19:59 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 19:59 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 19:59 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 19:59 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 19:59 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 190 mg/L SM2540C 06/09/2015 16:06 AGIBBS5251 Total Carbon TOC 0.504 mg/L SM5310C/EPA9060A 06/23/2015 14:43 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/09/2015 08:20 AGIBBS551 Analytical Lab Page 19 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017567 Collection Date: 04-Jun-15 4:05 PM Site: SMW-3B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)15 mg-N/L EPA 353.2 06/09/2015 12:07M2 LSTARL10.1 10 INORGANIC IONS BY IC Chloride 6.9 mg/L EPA 300.0 06/11/2015 20:12 BGN90340.1 1 Sulfate 38 mg/L EPA 300.0 06/11/2015 20:12 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/08/2015 16:04 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/11/2015 11:48 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.021 mg/L EPA 200.7 06/09/2015 12:07 MHALL30.005 1 Barium (Ba)0.052 mg/L EPA 200.7 06/09/2015 12:07 MHALL30.005 1 Boron (B)0.052 mg/L EPA 200.7 06/09/2015 12:07 MHALL30.05 1 Iron (Fe)1.32 mg/L EPA 200.7 06/09/2015 12:07 MHALL30.01 1 Manganese (Mn)0.092 mg/L EPA 200.7 06/09/2015 12:07 MHALL30.005 1 Strontium (Sr)0.080 mg/L EPA 200.7 06/09/2015 12:07 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 12:07 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)41.0 mg/L EPA 200.7 06/11/2015 11:15 MHALL30.01 1 Magnesium (Mg)4.80 mg/L EPA 200.7 06/11/2015 11:15 MHALL30.005 1 Potassium (K)5.85 mg/L EPA 200.7 06/11/2015 11:15 MHALL30.1 1 Sodium (Na)5.57 mg/L EPA 200.7 06/11/2015 11:15 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.025 mg/L EPA 200.7 06/10/2015 15:33 MHALL30.005 1 Barium (Ba)0.053 mg/L EPA 200.7 06/10/2015 15:33 MHALL30.005 1 Boron (B)0.050 mg/L EPA 200.7 06/10/2015 15:33 MHALL30.05 1 Iron (Fe)1.31 mg/L EPA 200.7 06/10/2015 15:33 MHALL30.01 1 Manganese (Mn)0.091 mg/L EPA 200.7 06/10/2015 15:33 MHALL30.005 1 Strontium (Sr)0.082 mg/L EPA 200.7 06/10/2015 15:33 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/10/2015 15:33 MHALL30.005 1 Analytical Lab Page 20 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017567 Collection Date: 04-Jun-15 4:05 PM Site: SMW-3B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 09:21 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 09:21 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 09:21 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 09:21 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 09:21 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 09:21 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 09:21 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 09:21 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 09:21 SLS256011 Nickel (Ni)1.41 ug/L EPA 200.8 06/21/2015 09:21 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 09:21 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 09:21 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 09:21 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 20:28 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/20/2015 20:28 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 20:28 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 20:28 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 20:28 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/20/2015 20:28 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 20:28 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 20:28 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/20/2015 20:28 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 20:28 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 20:28 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 20:28 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 20:28 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 250 mg/L SM2540C 06/09/2015 16:06 AGIBBS5251 Total Carbon TOC 3.2 mg/L SM5310C/EPA9060A 06/23/2015 14:43 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/09/2015 08:20 AGIBBS551 Analytical Lab Page 21 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017568 Collection Date: 04-Jun-15 3:55 PM Site: ABMW-1S Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.049 mg-N/L EPA 353.2 06/09/2015 12:03 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 83 mg/L EPA 300.0 06/11/2015 17:45 BGN9034110 Sulfate 83 mg/L EPA 300.0 06/11/2015 17:45 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/08/2015 16:06 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/11/2015 11:50 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.084 mg/L EPA 200.7 06/09/2015 12:18 MHALL30.005 1 Barium (Ba)0.585 mg/L EPA 200.7 06/09/2015 12:18 MHALL30.005 1 Boron (B)3.95 mg/L EPA 200.7 06/09/2015 12:18 MHALL30.05 1 Iron (Fe)0.094 mg/L EPA 200.7 06/09/2015 12:18 MHALL30.01 1 Manganese (Mn)0.088 mg/L EPA 200.7 06/09/2015 12:18 MHALL30.005 1 Strontium (Sr)6.18 mg/L EPA 200.7 06/09/2015 12:18 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 12:18 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)128 mg/L EPA 200.7 06/11/2015 10:03 MHALL30.1 10 Magnesium (Mg)51.0 mg/L EPA 200.7 06/11/2015 10:03 MHALL30.05 10 Potassium (K)16.3 mg/L EPA 200.7 06/11/2015 10:03 MHALL30.1 1 Sodium (Na)54.5 mg/L EPA 200.7 06/11/2015 10:03 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.143 mg/L EPA 200.7 06/10/2015 15:44 MHALL30.005 1 Barium (Ba)0.594 mg/L EPA 200.7 06/10/2015 15:44 MHALL30.005 1 Boron (B)3.94 mg/L EPA 200.7 06/10/2015 15:44 MHALL30.05 1 Iron (Fe)0.152 mg/L EPA 200.7 06/10/2015 15:44 MHALL30.01 1 Manganese (Mn)0.088 mg/L EPA 200.7 06/10/2015 15:44 MHALL30.005 1 Strontium (Sr)6.28 mg/L EPA 200.7 06/10/2015 15:44 MHALL30.005 1 Zinc (Zn)0.014 mg/L EPA 200.7 06/10/2015 15:44 MHALL30.005 1 Analytical Lab Page 22 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017568 Collection Date: 04-Jun-15 3:55 PM Site: ABMW-1S Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 09:50 SLS256011 Arsenic (As)654 ug/L EPA 200.8 06/21/2015 09:50 SLS25601010 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 09:50 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 09:50 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 09:50 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 09:50 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 09:50 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 09:50 SLS256011 Molybdenum (Mo)159 ug/L EPA 200.8 06/21/2015 09:50 SLS256011 Nickel (Ni)1.04 ug/L EPA 200.8 06/21/2015 09:50 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 09:50 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 09:50 SLS25600.2 1 Vanadium (V) Low Level 2.87 ug/L EPA 200.8 06/21/2015 09:50 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 20:35 SLS256011 Arsenic (As)634 ug/L EPA 200.8 06/20/2015 20:35 SLS25601010 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 20:35 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 20:35 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 20:35 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/20/2015 20:35 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 20:35 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 20:35 SLS256011 Molybdenum (Mo)162 ug/L EPA 200.8 06/20/2015 20:35 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 20:35 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 20:35 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 20:35 SLS25600.2 1 Vanadium (V) Low Level 3.45 ug/L EPA 200.8 06/20/2015 20:35 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 680 mg/L SM2540C 06/09/2015 16:06 AGIBBS5251 Total Carbon TOC 2.1 mg/L SM5310C/EPA9060A 06/23/2015 14:43 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/09/2015 08:20 AGIBBS551 Analytical Lab Page 23 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017569 Collection Date: 04-Jun-15 5:35 PM Site: SMW-2B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.054 mg-N/L EPA 353.2 06/09/2015 12:04 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 8.3 mg/L EPA 300.0 06/12/2015 17:54 BGN90340.1 1 Sulfate 3.2 mg/L EPA 300.0 06/12/2015 17:54 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/08/2015 16:09 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/11/2015 11:52 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.070 mg/L EPA 200.7 06/09/2015 12:22 MHALL30.005 1 Barium (Ba)0.059 mg/L EPA 200.7 06/09/2015 12:22 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/09/2015 12:22 MHALL30.05 1 Iron (Fe)27.9 mg/L EPA 200.7 06/09/2015 12:22 MHALL30.01 1 Manganese (Mn)0.412 mg/L EPA 200.7 06/09/2015 12:22 MHALL30.005 1 Strontium (Sr)0.059 mg/L EPA 200.7 06/09/2015 12:22 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 12:22 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)28.3 mg/L EPA 200.7 06/11/2015 10:41 MHALL30.01 1 Magnesium (Mg)1.01 mg/L EPA 200.7 06/11/2015 10:41 MHALL30.005 1 Potassium (K)1.25 mg/L EPA 200.7 06/11/2015 10:41 MHALL30.1 1 Sodium (Na)5.58 mg/L EPA 200.7 06/11/2015 10:41 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.084 mg/L EPA 200.7 06/10/2015 15:55 MHALL30.005 1 Barium (Ba)0.061 mg/L EPA 200.7 06/10/2015 15:55 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/10/2015 15:55 MHALL30.05 1 Iron (Fe)28.8 mg/L EPA 200.7 06/10/2015 15:55 MHALL30.01 1 Manganese (Mn)0.413 mg/L EPA 200.7 06/10/2015 15:55 MHALL30.005 1 Strontium (Sr)0.059 mg/L EPA 200.7 06/10/2015 15:55 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/10/2015 15:55 MHALL30.005 1 Analytical Lab Page 24 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017569 Collection Date: 04-Jun-15 5:35 PM Site: SMW-2B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 09:57 SLS256011 Arsenic (As)1.04 ug/L EPA 200.8 06/21/2015 09:57 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 09:57 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 09:57 SLS256011 Chromium (Cr)2.34 ug/L EPA 200.8 06/21/2015 09:57 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 09:57 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 09:57 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 09:57 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 09:57 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 09:57 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 09:57 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 09:57 SLS25600.2 1 Vanadium (V) Low Level 1.61 ug/L EPA 200.8 06/21/2015 09:57 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 20:42 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/20/2015 20:42 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 20:42 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 20:42 SLS256011 Chromium (Cr)2.29 ug/L EPA 200.8 06/20/2015 20:42 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/20/2015 20:42 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 20:42 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 20:42 SLS256011 Molybdenum (Mo)1.01 ug/L EPA 200.8 06/20/2015 20:42 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 20:42 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 20:42 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 20:42 SLS25600.2 1 Vanadium (V) Low Level 1.42 ug/L EPA 200.8 06/20/2015 20:42 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 140 mg/L SM2540C 06/09/2015 16:06 AGIBBS5251 Total Carbon TOC 11 mg/L SM5310C/EPA9060A 06/23/2015 14:43 GHUTCHI110 TOTAL SUSPENDED SOLIDS TSS 38 mg/L SM2540D 06/09/2015 08:20 AGIBBS551 Analytical Lab Page 25 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017570 Collection Date: 04-Jun-15 5:04 PM Site: SMW-2C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.039 mg-N/L EPA 353.2 06/09/2015 12:05 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 23 mg/L EPA 300.0 06/12/2015 15:49 BGN9034110 Sulfate 49 mg/L EPA 300.0 06/12/2015 15:49 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/08/2015 16:11 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/11/2015 11:55 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.016 mg/L EPA 200.7 06/09/2015 12:26 MHALL30.005 1 Barium (Ba)0.035 mg/L EPA 200.7 06/09/2015 12:26 MHALL30.005 1 Boron (B)0.329 mg/L EPA 200.7 06/09/2015 12:26 MHALL30.05 1 Iron (Fe)5.31 mg/L EPA 200.7 06/09/2015 12:26 MHALL30.01 1 Manganese (Mn)0.539 mg/L EPA 200.7 06/09/2015 12:26 MHALL30.005 1 Strontium (Sr)0.216 mg/L EPA 200.7 06/09/2015 12:26 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 12:26 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)19.5 mg/L EPA 200.7 06/11/2015 11:23 MHALL30.01 1 Magnesium (Mg)3.35 mg/L EPA 200.7 06/11/2015 11:23 MHALL30.005 1 Potassium (K)3.40 mg/L EPA 200.7 06/11/2015 11:23 MHALL30.1 1 Sodium (Na)15.5 mg/L EPA 200.7 06/11/2015 11:23 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.142 mg/L EPA 200.7 06/10/2015 15:59 MHALL30.005 1 Barium (Ba)0.037 mg/L EPA 200.7 06/10/2015 15:59 MHALL30.005 1 Boron (B)0.337 mg/L EPA 200.7 06/10/2015 15:59 MHALL30.05 1 Iron (Fe)5.37 mg/L EPA 200.7 06/10/2015 15:59 MHALL30.01 1 Manganese (Mn)0.539 mg/L EPA 200.7 06/10/2015 15:59 MHALL30.005 1 Strontium (Sr)0.221 mg/L EPA 200.7 06/10/2015 15:59 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/10/2015 15:59 MHALL30.005 1 Analytical Lab Page 26 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017570 Collection Date: 04-Jun-15 5:04 PM Site: SMW-2C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 10:04 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 10:04 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 10:04 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 10:04 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 10:04 SLS256011 Cobalt (Co)2.85 ug/L EPA 200.8 06/21/2015 10:04 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 10:04 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 10:04 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 10:04 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 10:04 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 10:04 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 10:04 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 10:04 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 21:04 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/20/2015 21:04 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 21:04 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 21:04 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 21:04 SLS256011 Cobalt (Co)3.37 ug/L EPA 200.8 06/20/2015 21:04 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 21:04 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 21:04 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/20/2015 21:04 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 21:04 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 21:04 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 21:04 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 21:04 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 130 mg/L SM2540C 06/10/2015 14:35 AGIBBS5251 Total Carbon TOC 1.9 mg/L SM5310C/EPA9060A 06/23/2015 14:43 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/09/2015 08:20 AGIBBS551 Analytical Lab Page 27 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017571 Collection Date: 04-Jun-15 5:54 PM Site: ABMW-02S Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF RADIOLOGICAL - (Analysis Performed by GEL) Vendor Parameter Complete Vendor Method v_GEL Analytical Lab Page 28 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017572 Collection Date: 04-Jun-15 6:16 PM Site: ABMW-02D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF RADIOLOGICAL - (Analysis Performed by GEL) Vendor Parameter Complete Vendor Method v_GEL Analytical Lab Page 29 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017573 Collection Date: 04-Jun-15 2:10 PM Site: Filter Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/11/2015 11:57 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 06/09/2015 12:29 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 06/09/2015 12:29 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/09/2015 12:29 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 06/09/2015 12:29 MHALL30.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 06/09/2015 12:29 MHALL30.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 06/09/2015 12:29 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 12:29 MHALL30.005 1 TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 10:11 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 10:11 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 10:11 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 10:11 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 10:11 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 10:11 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 10:11 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 10:11 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 10:11 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 10:11 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 10:11 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 10:11 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 10:11 SLS25600.3 1 Analytical Lab Page 30 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017575 Collection Date: 04-Jun-15 2:10 PM Site: Equipment Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/09/2015 12:08 LSTARL10.01 1 INORGANIC IONS BY IC Chloride < 0.1 mg/L EPA 300.0 06/12/2015 16:07 BGN90340.1 1 Sulfate < 0.1 mg/L EPA 300.0 06/12/2015 16:07 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/08/2015 16:13 ACPAYNE0.05 1 UNDIGESTED METALS BY ICP Calcium (Ca)< 0.01 mg/L EPA 200.7 06/11/2015 11:53 MHALL30.01 1 Magnesium (Mg)< 0.005 mg/L EPA 200.7 06/11/2015 11:53 MHALL30.005 1 Potassium (K)< 0.1 mg/L EPA 200.7 06/11/2015 11:53 MHALL30.1 1 Sodium (Na)< 0.05 mg/L EPA 200.7 06/11/2015 11:53 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 06/10/2015 16:03 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 06/10/2015 16:03 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/10/2015 16:03 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 06/10/2015 16:03 MHALL30.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 06/10/2015 16:03 MHALL30.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 06/10/2015 16:03 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/10/2015 16:03 MHALL30.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 21:11 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/20/2015 21:11 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 21:11 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 21:11 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 21:11 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/20/2015 21:11 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 21:11 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 21:11 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/20/2015 21:11 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 21:11 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 21:11 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 21:11 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 21:11 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY Analytical Lab Page 31 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060200 2015017575 Collection Date: 04-Jun-15 2:10 PM Site: Equipment Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 06/10/2015 14:35 AGIBBS5251 Total Carbon TOC 0.182 mg/L SM5310C/EPA9060A 06/23/2015 14:43 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/09/2015 08:20 AGIBBS551 Qualifiers: M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable. Analytical Lab Page 32 of 109 Analytical Lab Page 33 of 109 Analytical Lab Page 34 of 109 Analytical Lab Page 35 of 109 Analytical Lab Page 36 of 109 Analytical Lab Page 37 of 109 Analytical Lab Page 38 of 109 Analytical Lab Page 39 of 109 Analytical Lab Page 40 of 109 Analytical Lab Page 41 of 109 Analytical Lab Page 42 of 109 Analytical Lab Page 43 of 109 Analytical Lab Page 44 of 109 Analytical Lab Page 45 of 109 Analytical Lab Page 46 of 109 SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle QF06007Lot Number: J15060200Project Number: AB GW Assessment Water - SuttonProject Name: 06/16/2015Date Completed: Grant Wilton Project Manager *QF06007* This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. Page: 1 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Case Narrative Duke Energy Lot Number: QF06007 SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329 Project Name: AB GW Assessment Water - Sutton Project Number: J15060200 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. Page: 2 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: QF06007 Project Name: AB GW Assessment Water - Sutton Project Number: J15060200 Sample Number Sample ID Matrix Date Sampled Date Received 001 06/04/2015 13472015017559Aqueous 06/06/2015 002 06/04/2015 11372015017560Aqueous 06/06/2015 003 06/04/2015 11262015017561Aqueous 06/06/2015 004 06/04/2015 10332015017562Aqueous 06/06/2015 005 06/04/2015 14022015017563Aqueous 06/06/2015 006 06/04/2015 13022015017564Aqueous 06/06/2015 007 06/04/2015 12192015017565Aqueous 06/06/2015 008 06/04/2015 15062015017566Aqueous 06/06/2015 009 06/04/2015 16052015017567Aqueous 06/06/2015 010 06/04/2015 15552015017568Aqueous 06/06/2015 011 06/04/2015 17352015017569Aqueous 06/06/2015 012 06/04/2015 17042015017570Aqueous 06/06/2015 016 06/04/2015 14102015017575Aqueous 06/06/2015 (13 samples) Page: 3 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: QF06007 Project Name: AB GW Assessment Water - Sutton Project Number: J15060200 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2015017559 Aqueous Alkalinity SM 2320B-12 mg/L 5 001 2015017559 Aqueous Bicarbonate Alkalinity SM 2320B-12 mg/L 5 002 2015017560 Aqueous Alkalinity SM 2320B-120 mg/L 7 002 2015017560 Aqueous Bicarbonate Alkalinity SM 2320B-120 mg/L 7 003 2015017561 Aqueous Alkalinity SM 2320B-240 mg/L 9 003 2015017561 Aqueous Bicarbonate Alkalinity SM 2320B-240 mg/L 9 003 2015017561 Aqueous Methane RSK - 175 3800 ug/L 10 004 2015017562 Aqueous Alkalinity SM 2320B-96 mg/L 11 004 2015017562 Aqueous Bicarbonate Alkalinity SM 2320B-96 mg/L 11 004 2015017562 Aqueous Methane RSK - 175 49 ug/L 12 007 2015017565 Aqueous Alkalinity SM 2320B-170 mg/L 17 007 2015017565 Aqueous Bicarbonate Alkalinity SM 2320B-160 mg/L 17 007 2015017565 Aqueous Methane RSK - 175 11 ug/L 18 009 2015017567 Aqueous Alkalinity SM 2320B-43 mg/L 21 009 2015017567 Aqueous Bicarbonate Alkalinity SM 2320B-43 mg/L 21 010 2015017568 Aqueous Alkalinity SM 2320B-410 mg/L 23 010 2015017568 Aqueous Bicarbonate Alkalinity SM 2320B-400 mg/L 23 010 2015017568 Aqueous Methane RSK - 175 130 ug/L 24 011 2015017569 Aqueous Alkalinity SM 2320B-90 mg/L 25 011 2015017569 Aqueous Bicarbonate Alkalinity SM 2320B-90 mg/L 25 011 2015017569 Aqueous Methane RSK - 175 830 ug/L 26 012 2015017570 Aqueous Alkalinity SM 2320B-24 mg/L 27 012 2015017570 Aqueous Bicarbonate Alkalinity SM 2320B-23 mg/L 27 (23 detections) Page: 4 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017559 QF06007-001 06/04/2015 1347 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 0148 HMA 76880 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 0148 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 0148 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 12 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 12 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 5 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017559 QF06007-001 06/04/2015 1347 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 2012 JJG 77131 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 6 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017560 QF06007-002 06/04/2015 1137 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 0154 HMA 76880 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 0154 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 0154 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 120 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 120 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 7 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017560 QF06007-002 06/04/2015 1137 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 2025 JJG 77131 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 8 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017561 QF06007-003 06/04/2015 1126 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 0202 HMA 76880 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 0202 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 0202 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 240 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 240 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 9 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017561 QF06007-003 06/04/2015 1126 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 RSK - 175 10 06/12/2015 2013 JJG 77223 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 3800 2ug/L100 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 10 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017562 QF06007-004 06/04/2015 1033 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 0222 HMA 76880 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 0222 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 0222 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 96 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 96 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 11 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017562 QF06007-004 06/04/2015 1033 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 2101 JJG 77131 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 49 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 12 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017563 QF06007-005 06/04/2015 1402 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 0227 HMA 76880 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 0227 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 0227 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 13 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017563 QF06007-005 06/04/2015 1402 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 2113 JJG 77131 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 14 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017564 QF06007-006 06/04/2015 1302 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 0231 HMA 76880 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 0231 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 0231 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 15 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017564 QF06007-006 06/04/2015 1302 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 2128 JJG 77131 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 16 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017565 QF06007-007 06/04/2015 1219 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 1248 HMA 76942 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 1248 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 1248 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 170 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 160 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 17 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017565 QF06007-007 06/04/2015 1219 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 2144 JJG 77131 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 11 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 18 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017566 QF06007-008 06/04/2015 1506 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 1305 HMA 76942 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 1305 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 1305 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 19 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017566 QF06007-008 06/04/2015 1506 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 2154 JJG 77131 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 20 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017567 QF06007-009 06/04/2015 1605 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 1311 HMA 76942 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 1311 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 1311 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 43 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 43 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 21 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017567 QF06007-009 06/04/2015 1605 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 2210 JJG 77131 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 22 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017568 QF06007-010 06/04/2015 1555 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 1320 HMA 76942 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 1320 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 1320 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 410 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 400 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 23 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017568 QF06007-010 06/04/2015 1555 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 2235 JJG 77131 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 130 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 24 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017569 QF06007-011 06/04/2015 1735 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 1325 HMA 76942 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 1325 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 1325 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 90 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 90 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 25 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017569 QF06007-011 06/04/2015 1735 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 RSK - 175 5 06/12/2015 2024 JJG 77223 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 830 2ug/L50 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 26 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017570 QF06007-012 06/04/2015 1704 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 1329 HMA 76942 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 1329 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 1329 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 24 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 23 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 27 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017570 QF06007-012 06/04/2015 1704 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 2302 JJG 77131 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 28 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017575 QF06007-016 06/04/2015 1410 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 1336 HMA 76942 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 1336 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 1336 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 29 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017575 QF06007-016 06/04/2015 1410 06/06/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060200 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/12/2015 0955 DCS 77176 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 30 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 QC Summary QC Data for Lot Number: QF06007 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MB Batch: Sample ID:QQ76880-001 76880 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Alkalinity ND 06/09/2015 234610mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF06007 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - LCS Batch: Sample ID:QQ76880-002 76880 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Alkalinity 97 06/09/2015 23529710090-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF06007 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MS Batch: Sample ID:QF06007-006MS 76880 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Alkalinity 96 06/10/2015 02379610070-130ND1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF06007 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MSD Batch: Sample ID:QF06007-006MD 76880 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Alkalinity 96 06/10/2015 02449610070-1300.021 20ND1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF06007 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MB Batch: Sample ID:QQ76942-001 76942 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Alkalinity ND 06/10/2015 123510mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF06007 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - LCS Batch: Sample ID:QQ76942-002 76942 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Alkalinity 96 06/10/2015 12419610090-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF06007 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MS Batch: Sample ID:QF06007-007MS 76942 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Alkalinity 250 06/10/2015 12548710070-1301701 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF06007 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MSD Batch: Sample ID:QF06007-007MD 76942 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Alkalinity 250 06/10/2015 13018810070-1300.37 201701 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF06007 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - MB Batch: Sample ID:QQ77131-001 77131 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 06/11/2015 165510ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF06007 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCS Batch: Sample ID:QQ77131-002 77131 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 45 06/11/2015 1627895070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF06007 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCSD Batch: Sample ID:QQ77131-003 77131 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 44 06/11/2015 1641875070-1302.7 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF06007 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - MB Batch: Sample ID:QQ77176-001 77176 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 06/12/2015 093810ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF06007 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCS Batch: Sample ID:QQ77176-002 77176 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 46 06/12/2015 0911915070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF06007 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCSD Batch: Sample ID:QQ77176-003 77176 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 46 06/12/2015 0924925070-1300.65 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF06007 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - MB Batch: Sample ID:QQ77223-001 77223 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 06/12/2015 172010ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF06007 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCS Batch: Sample ID:QQ77223-002 77223 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 45 06/12/2015 1626885070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF06007 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCSD Batch: Sample ID:QQ77223-003 77223 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 49 06/12/2015 1659965070-1308.8 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF06007 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 June 12, 2015 Mrs. Mary Ann Ogle Duke Energy Analytical Laboratory 13339 Hagers Ferry Road Mail Code: MGO3A2 Huntersville, North Carolina 28078 Re: AB GW Assessment Water Work Order: 374588 SDG: J15000200 Dear Mrs. : GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received on June 08, 2015. This original data report has been prepared and reviewed in accordance with GEL’s standard operating procedures. Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time. We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at (843) 556-8171, ext. 4443. Sincerely, PM_SIGN_HERE Lindsay Fabra Project Manager Purchase Order: 1142110 Enclosures Page 1 of 12 Analytical Lab Page 97 of 109 Reviewed by USER_SIGN_HERE GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Certificate of Analysis Report DUPO002 Duke Energy Client SDG: J15000200 GEL Work Order: 374588 Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the Certificate of Analysis. The designation ND, if present, appears in the result column when the analyte concentration is not detected above the limit as defined in the ’U’ qualifier above. This data report has been prepared and reviewed in accordance with GEL Laboratories LLC standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra. The Qualifiers in this report are defined as follows: * A quality control analyte recovery is outside of specified acceptance criteria ** Analyte is a Tracer compound ** Analyte is a surrogate compound U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD. for Page 2 of 12 Analytical Lab Page 98 of 109 Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: June 12, 2015 Metals Analysis-ICP-MS Rad Gas Flow Proportional Counting Rad Radium-226 Parameter Result UnitsQualifier Analyst Date Time 1484159 1484159 1484168 1484245 0812 0944 1054 0805 ug/mL ug/mL ug/mL ug/mL pCi/L pCi/L 06/11/15 06/11/15 06/12/15 06/12/15 SKJ SKJ AXM6 CXP3 0.0002 0.00005 0.00005 0.00005 3.00 1.00 DF 1 1 1 1 Mrs. Mary Ann Ogle Contact: Duke Energy Analytical Laboratory Company : 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Address : AB GW Assessment WaterProject: 374588001 Ground Water 04-JUN-15 17:54 08-JUN-15 2015017571 DUKE00225Project: DUPO002Client ID: Client Mail Code: MGO3A2 Surrogate/Tracer Recovery Recovery%Test Acceptable Limits Sample ID: Receive Date: Client Sample ID: Matrix: Collect Date: Collector: Batch Barium-133 Tracer GFPC, Ra228, Liquid "As Received"93.0 (15%-125%) 0.000067 0.00001 0.00001 0.00001 1.36 0.580 The following Prep Methods were performed: SW846 3010A SW 846 3010 Acid Digestion 06/09/15 14841580730JXM5 Method Description Analyst Date Time Prep Batch Method The following Analytical Methods were performed: 1 2 3 4 Method Description 1 2 3 4 SW846 3010A/6020A SW846 3010A/6020A EPA 904.0/SW846 9320 Modified EPA 903.1 Modified Analyst Comments U U U U U Uranium-238 Uranium-233 Uranium-234 Uranium-236 Radium-228 Radium-226 SW846 3010A/6020A Liquid "As Received" GFPC, Ra228, Liquid "As Received" Lucas Cell, Ra226, liquid "As Received" 0.0000456 0.00 0.00 1.00E-06 0.312 1.01 NominalResult RLDL Notes: Page 3 of 12 Analytical Lab Page 99 of 109 Certificate of Analysis GEL LABORATORIES LLC 2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com Report Date: June 12, 2015 Metals Analysis-ICP-MS Rad Gas Flow Proportional Counting Rad Radium-226 Parameter Result UnitsQualifier Analyst Date Time 1484159 1484159 1484168 1484245 0819 0950 1054 0805 ug/mL ug/mL ug/mL ug/mL pCi/L pCi/L 06/11/15 06/11/15 06/12/15 06/12/15 SKJ SKJ AXM6 CXP3 0.0002 0.00005 0.00005 0.00005 3.00 1.00 DF 1 1 1 1 Mrs. Mary Ann Ogle Contact: Duke Energy Analytical Laboratory Company : 13339 Hagers Ferry Road Huntersville, North Carolina 28078 Address : AB GW Assessment WaterProject: 374588002 Ground Water 04-JUN-15 18:16 08-JUN-15 2015017572 DUKE00225Project: DUPO002Client ID: Client Mail Code: MGO3A2 Surrogate/Tracer Recovery Recovery%Test Acceptable Limits Sample ID: Receive Date: Client Sample ID: Matrix: Collect Date: Collector: Batch Barium-133 Tracer GFPC, Ra228, Liquid "As Received"105 (15%-125%) 0.000067 0.00001 0.00001 0.00001 1.59 0.597 The following Prep Methods were performed: SW846 3010A SW 846 3010 Acid Digestion 06/09/15 14841580730JXM5 Method Description Analyst Date Time Prep Batch Method The following Analytical Methods were performed: 1 2 3 4 Method Description 1 2 3 4 SW846 3010A/6020A SW846 3010A/6020A EPA 904.0/SW846 9320 Modified EPA 903.1 Modified Analyst Comments U U U U Uranium-238 Uranium-233 Uranium-234 Uranium-236 Radium-228 Radium-226 SW846 3010A/6020A Liquid "As Received" GFPC, Ra228, Liquid "As Received" Lucas Cell, Ra226, liquid "As Received" 0.0000335 0.00 0.00 1.00E-06 1.60 0.739 NominalResult RLDL Notes: Page 4 of 12 Analytical Lab Page 100 of 109 QC Summary GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com Metals Analysis - ICPMS 1484159Batch Uranium-233 Uranium-234 Uranium-236 Uranium-238 Uranium-238 Uranium-233 Uranium-234 Uranium-236 Uranium-233 Uranium-234 Uranium-236 Uranium-238 Uranium-238 Uranium-233 Uranium-234 Uranium-236 Uranium-233 Parmname Mrs. Mary Ann Ogle Contact: Duke Energy Analytical Laboratory 13339 Hagers Ferry Road Huntersville, North Carolina June 12, 2015Report Date: Units ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/mL ug/L Anlst Date Time SKJ 06/11/15 09:46 06/11/15 08:13 06/11/15 08:10 06/11/15 09:40 06/11/15 09:39 06/11/15 08:09 06/11/15 08:14 06/11/15 09:47 06/11/15 09:49 QC ND ND ND ND 0.0502 0.000514 0.000546 0.00579 ND ND ND ND 0.0514 0.000503 0.000529 0.00571 ND NOM Sample ND ND ND ND ND ND ND ND ND Range (80%-120%) (80%-120%) (80%-120%) (80%-120%) (75%-125%) (75%-125%) (75%-125%) (75%-125%) Qual U U U U U U U U U QC1203333195 374588001 QC1203333194 QC1203333402 QC1203333193 QC1203333196 374588001 QC1203333403 374588001 QC1203333197 374588001 N/A N/A N/A N/A N/A REC% 101 103 99.3 116 103 101 96.2 114 0.0496 0.0005 0.00055 0.005 0.0496 0.0005 0.00055 0.005 DUP LCS LCS MB MS MS SDILT 374588Workorder: Mail Code: MGO3A2 U U U U U U U U U RPD% Page 1 of 3 Page 5 of 12 Analytical Lab Page 101 of 109 QC Summary GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com Metals Analysis - ICPMS Rad Gas Flow Rad Ra-226 1484159 1484168 1484245 Batch Batch Batch Uranium-234 Uranium-236 Uranium-238 Radium-228 Radium-228 Radium-228 Radium-226 Radium-226 Radium-226 Radium-226 Parmname Units ug/L ug/L ug/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L pCi/L Anlst Date Time SKJ AXM6 CXP3 06/11/15 09:49 06/11/15 08:15 06/12/15 10:55 06/12/15 10:55 06/12/15 10:55 06/12/15 08:35 06/12/15 09:10 06/12/15 08:35 06/12/15 09:10 QC ND ND ND 0.226 26.9 -0.26 0.528 26.9 0.515 109 NOM Sample ND ND ND 1.60 1.01 1.01 Range (0%-10%) (0%-10%) (0% - 100%) (75%-125%) (0% - 100%) (75%-125%) (75%-125%) Qual U U U U U U U QC1203333221 374588002 QC1203333222 QC1203333220 QC1203333426 374588001 QC1203333428 QC1203333425 QC1203333427 374588001 The Qualifiers in this report are defined as follows: N/A N/A N/A 151 62.3 REC% 87.3 109 87.5 30.8 24.7 124 DUP LCS MB DUP LCS MB MS 374588Workorder: ** < > BD E FA FB H Analyte is a Tracer compound Result is less than value reported Result is greater than value reported Results are either below the MDC or tracer recovery is low %difference of sample and SD is >10%. Sample concentration must meet flagging criteria Failed analysis. Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed invalid for reporting to regulatory agencies Analytical holding time was exceeded U U U * RPD% Notes: Page 2 of 3 Page 6 of 12 Analytical Lab Page 102 of 109 QC Summary GEL LABORATORIES LLC 2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com Parmname Page 3 of 3 Units Anlst Date TimeQCNOMSampleRangeQualREC% 374588Workorder: J K L M M N N/A N1 ND NJ Q R U UI UJ UL X Y ^ h Value is estimated Analyte present. Reported value may be biased high. Actual value is expected to be lower. Analyte present. Reported value may be biased low. Actual value is expected to be higher. M if above MDC and less than LLD REMP Result > MDC/CL and < RDL Metals--The Matrix spike sample recovery is not within specified control limits RPD or %Recovery limits do not apply. See case narrative Analyte concentration is not detected above the detection limit Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier One or more quality control criteria have not been met. Refer to the applicable narrative or DER. Sample results are rejected Analyte was analyzed for, but not detected above the MDL, MDA, or LOD. Gamma Spectroscopy--Uncertain identification Gamma Spectroscopy--Uncertain identification Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias. Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier Other specific qualifiers were required to properly define the results. Consult case narrative. RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry. Preparation or preservation holding time was exceeded N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable. ^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the RL is used to evaluate the DUP result. * Indicates that a Quality Control parameter was not within specifications. For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations. Where the analytical method has been performed under NELAP certification, the analysis has met all of the requirements of the NELAC standard unless qualified on the QC Summary. RPD% Page 7 of 12 Analytical Lab Page 103 of 109 Page 8 of 12 Analytical Lab Page 104 of 109 Page 9 of 12 Analytical Lab Page 105 of 109 Page 10 of 12 Analytical Lab Page 106 of 109 State Certification Alaska Arkansas CLIA California Colorado Connecticut Delaware DoD ELAP/ ISO17025 A2LA Florida NELAP Foreign Soils Permit Georgia Georgia SDWA Hawaii Idaho Chemistry Idaho Radiochemistry Illinois NELAP Indiana Kansas NELAP Kentucky SDWA Kentucky Wastewater Louisiana NELAP Louisiana SDWA Maryland Massachusetts Michigan Mississippi Nebraska Nevada New Hampshire NELAP New Jersey NELAP New Mexico New York NELAP North Carolina North Carolina SDWA Oklahoma Pennsylvania NELAP Plant Material Permit S.Carolina Radchem South Carolina Chemistry Tennessee Texas NELAP Utah NELAP Vermont Virginia NELAP Washington West Virginia UST-110 88-0651 42D0904046 2940 Interim SC00012 PH-0169 SC000122013-10 2567.01 E87156 P330-12-00283, P330-12-00284 SC00012 967 SC000122013-10 SC00012 SC00012 200029 C-SC-01 E-10332 90129 90129 03046 (AI33904) LA150001 270 M-SC012 9976 SC000122013-10 NE-OS-26-13 SC000122014-1 2054 SC002 SC00012 11501 233 45709 9904 68-00485 PDEP-12-00260 10120002 10120001 TN 02934 T104704235-15-10 SC000122015-17 VT87156 460202 C780 997404 List of current GEL Certifications as of 12 June 2015 Page 11 of 12 Analytical Lab Page 107 of 109 There are no "Data Exception Reports" associated with this analytical report. 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