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Home My WebLink AboutNC0001422_ATT 5 - Water - J15060170report_2015080513339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number: J15060170 Project Name:SUTTON - AB GW ASSESSMENT WATER Lab Contact:Mary Ann Ogle Date:6/23/2015 Customer Address: Customer Name(s): Perry Waldrep, Tim Hunsucker, Kathy Webb, John Toepfer Phone: 980-875-5274 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Mary Ann Ogle Analytical Lab Page 1 of 129 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015017431 Sutton 03-Jun-15 10:26 AM Richard Jacobs AW-5B 2015017433 Sutton 03-Jun-15 11:26 AM Richard Jacobs AW-5C 2015017434 Sutton 03-Jun-15 4:12 PM Richard Jacobs AW-5E 2015017435 Sutton 03-Jun-15 10:06 AM Richard Jacobs AW-2B 2015017436 Sutton 03-Jun-15 2:26 PM Richard Jacobs AW-2C 2015017437 Sutton 03-Jun-15 1:50 PM Richard Jacobs AW-2D 2015017438 Sutton 02-Jun-15 8:00 PM Richard Jacobs AW-1B 2015017439 Sutton 02-Jun-15 5:33 PM Richard Jacobs AW-1C 2015017440 Sutton 02-Jun-15 1:55 PM Richard Jacobs AW-8B 2015017441 Sutton 02-Jun-15 3:10 PM Richard Jacobs AW-8C 2015017442 Sutton 03-Jun-15 10:05 AM Richard Jacobs MW-23B 2015017443 Sutton 03-Jun-15 11:44 AM Richard Jacobs MW-23E 2015017444 Sutton 03-Jun-15 4:20 PM Richard Jacobs SMW-6D 2015017445 Sutton 03-Jun-15 4:40 PM Richard Jacobs SMW-6B 2015017446 Sutton 03-Jun-15 9:20 AM Richard Jacobs Filter Blank 2015017447 Sutton 03-Jun-15 9:20 AM Richard Jacobs Equipment Blank 2015017448 Sutton 03-Jun-15 3:52 PM Richard Jacobs AW-6B 2015017449 Sutton 03-Jun-15 6:37 PM Richard Jacobs AW-6D 2015017450 Sutton 02-Jun-15 12:51 PM Unknown MW-27B 19 Total Samples Analytical Lab Page 2 of 129 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:Mary Ann Ogle Date:6/23/2015 Electronic Data Deliverable (EDD) Sent Separately Analytical Lab Page 3 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017431 Collection Date: 03-Jun-15 10:26 AM Site: AW-5B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.011 mg-N/L EPA 353.2 06/09/2015 11:03 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 1.6 mg/L EPA 300.0 06/09/2015 21:38 BGN90340.1 1 Sulfate 8.7 mg/L EPA 300.0 06/09/2015 21:38 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 14:39 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 11:05 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.043 mg/L EPA 200.7 06/05/2015 11:55 MHALL30.005 1 Barium (Ba)0.021 mg/L EPA 200.7 06/05/2015 11:55 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/05/2015 11:55 MHALL30.05 1 Iron (Fe)0.033 mg/L EPA 200.7 06/05/2015 11:55 MHALL30.01 1 Manganese (Mn)0.017 mg/L EPA 200.7 06/05/2015 11:55 MHALL30.005 1 Strontium (Sr)0.024 mg/L EPA 200.7 06/05/2015 11:55 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/05/2015 11:55 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)6.14 mg/L EPA 200.7 06/10/2015 11:13 MHALL30.01 1 Magnesium (Mg)0.066 mg/L EPA 200.7 06/10/2015 11:13 MHALL30.005 1 Potassium (K)5.74 mg/L EPA 200.7 06/10/2015 11:13 MHALL30.1 1 Sodium (Na)6.53 mg/L EPA 200.7 06/10/2015 11:13 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.045 mg/L EPA 200.7 06/08/2015 13:07 MHALL30.005 1 Barium (Ba)0.025 mg/L EPA 200.7 06/08/2015 13:07 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/08/2015 13:07 MHALL30.05 1 Iron (Fe)0.281 mg/L EPA 200.7 06/08/2015 13:07 MHALL30.01 1 Manganese (Mn)0.026 mg/L EPA 200.7 06/08/2015 13:07 MHALL30.005 1 Strontium (Sr)0.026 mg/L EPA 200.7 06/08/2015 13:07 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/08/2015 13:07 MHALL30.005 1 Analytical Lab Page 4 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017431 Collection Date: 03-Jun-15 10:26 AM Site: AW-5B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 21:19 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 21:19 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 21:19 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 21:19 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 21:19 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 21:19 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 21:19 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 21:19 SLS256011 Molybdenum (Mo)8.12 ug/L EPA 200.8 06/21/2015 21:19 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 21:19 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 21:19 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 21:19 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 21:19 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 14:55 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/20/2015 14:55 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 14:55 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 14:55 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 14:55 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/20/2015 14:55 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 14:55 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 14:55 SLS256011 Molybdenum (Mo)8.54 ug/L EPA 200.8 06/20/2015 14:55 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 14:55 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 14:55 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 14:55 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 14:55 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 50 mg/L SM2540C 06/09/2015 11:22 AGIBBS5251 Total Carbon TOC 1.8 mg/L SM5310C/EPA9060A 06/08/2015 14:18 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/08/2015 11:45 AGIBBS551 Analytical Lab Page 5 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017433 Collection Date: 03-Jun-15 11:26 AM Site: AW-5C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.409 mg-N/L EPA 353.2 06/09/2015 11:07 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 4.0 mg/L EPA 300.0 06/09/2015 21:54 BGN90340.1 1 Sulfate 23 mg/L EPA 300.0 06/09/2015 21:54 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 14:41 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 11:12 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.220 mg/L EPA 200.7 06/05/2015 12:14 MHALL30.005 1 Barium (Ba)0.032 mg/L EPA 200.7 06/05/2015 12:14 MHALL30.005 1 Boron (B)0.065 mg/L EPA 200.7 06/05/2015 12:14 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 06/05/2015 12:14 MHALL30.01 1 Manganese (Mn)0.020 mg/L EPA 200.7 06/05/2015 12:14 MHALL30.005 1 Strontium (Sr)0.024 mg/L EPA 200.7 06/05/2015 12:14 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/05/2015 12:14 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)6.20 mg/L EPA 200.7 06/10/2015 12:00 MHALL30.01 1 Magnesium (Mg)0.520 mg/L EPA 200.7 06/10/2015 12:00 MHALL30.005 1 Potassium (K)0.879 mg/L EPA 200.7 06/10/2015 12:00 MHALL30.1 1 Sodium (Na)2.53 mg/L EPA 200.7 06/10/2015 12:00 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.256 mg/L EPA 200.7 06/08/2015 13:19 MHALL30.005 1 Barium (Ba)0.036 mg/L EPA 200.7 06/08/2015 13:19 MHALL30.005 1 Boron (B)0.069 mg/L EPA 200.7 06/08/2015 13:19 MHALL30.05 1 Iron (Fe)0.128 mg/L EPA 200.7 06/08/2015 13:19 MHALL30.01 1 Manganese (Mn)0.021 mg/L EPA 200.7 06/08/2015 13:19 MHALL30.005 1 Strontium (Sr)0.025 mg/L EPA 200.7 06/08/2015 13:19 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/08/2015 13:19 MHALL30.005 1 Analytical Lab Page 6 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017433 Collection Date: 03-Jun-15 11:26 AM Site: AW-5C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 21:26 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 21:26 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 21:26 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 21:26 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 21:26 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 21:26 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 21:26 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 21:26 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 21:26 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 21:26 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 21:26 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 21:26 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 21:26 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 14:34 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/20/2015 14:34 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 14:34 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 14:34 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 14:34 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/20/2015 14:34 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 14:34 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 14:34 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/20/2015 14:34 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 14:34 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 14:34 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 14:34 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 14:34 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 40 mg/L SM2540C 06/09/2015 11:22 AGIBBS5251 Total Carbon TOC 0.500 mg/L SM5310C/EPA9060A 06/08/2015 14:18 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/08/2015 11:45 AGIBBS551 Analytical Lab Page 7 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017434 Collection Date: 03-Jun-15 4:12 PM Site: AW-5E Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/09/2015 11:08 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 540 mg/L EPA 300.0 06/10/2015 09:09 BGN903410100 Sulfate 120 mg/L EPA 300.0 06/10/2015 09:09 BGN90342.5 25 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 14:44 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 11:19 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.018 mg/L EPA 200.7 06/05/2015 12:25 MHALL30.005 1 Barium (Ba)0.009 mg/L EPA 200.7 06/05/2015 12:25 MHALL30.005 1 Boron (B)1.92 mg/L EPA 200.7 06/05/2015 12:25 MHALL30.05 1 Iron (Fe)0.066 mg/L EPA 200.7 06/05/2015 12:25 MHALL30.01 1 Manganese (Mn)0.007 mg/L EPA 200.7 06/05/2015 12:25 MHALL30.005 1 Strontium (Sr)0.203 mg/L EPA 200.7 06/05/2015 12:25 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/05/2015 12:25 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)12.6 mg/L EPA 200.7 06/10/2015 11:16 MHALL30.01 1 Magnesium (Mg)13.0 mg/L EPA 200.7 06/10/2015 11:16 MHALL30.005 1 Potassium (K)30.0 mg/L EPA 200.7 06/10/2015 11:16 MHALL3110 Sodium (Na)540 mg/L EPA 200.7 06/10/2015 11:16 MHALL30.5 10 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.097 mg/L EPA 200.7 06/08/2015 13:23 MHALL30.005 1 Barium (Ba)0.008 mg/L EPA 200.7 06/08/2015 13:23 MHALL30.005 1 Boron (B)1.95 mg/L EPA 200.7 06/08/2015 13:23 MHALL30.05 1 Iron (Fe)0.276 mg/L EPA 200.7 06/08/2015 13:23 MHALL30.01 1 Manganese (Mn)0.009 mg/L EPA 200.7 06/08/2015 13:23 MHALL30.005 1 Strontium (Sr)0.211 mg/L EPA 200.7 06/08/2015 13:23 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/08/2015 13:23 MHALL30.005 1 Analytical Lab Page 8 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017434 Collection Date: 03-Jun-15 4:12 PM Site: AW-5E Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 21:33 SLS256011 Arsenic (As)1.24 ug/L EPA 200.8 06/21/2015 21:33 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 21:33 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 21:33 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 21:33 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 21:33 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 21:33 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 21:33 SLS256011 Molybdenum (Mo)20.7 ug/L EPA 200.8 06/21/2015 21:33 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 21:33 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 21:33 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 21:33 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 21:33 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 15:02 SLS256011 Arsenic (As)1.37 ug/L EPA 200.8 06/20/2015 15:02 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 15:02 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 15:02 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 15:02 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/20/2015 15:02 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 15:02 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 15:02 SLS256011 Molybdenum (Mo)21.3 ug/L EPA 200.8 06/20/2015 15:02 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 15:02 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 15:02 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 15:02 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 15:02 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 1500 mg/L SM2540C 06/09/2015 11:22 AGIBBS5251 Total Carbon TOC 5.0 mg/L SM5310C/EPA9060A 06/08/2015 14:18 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS 10 mg/L SM2540D 06/08/2015 11:45 AGIBBS551 Analytical Lab Page 9 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017435 Collection Date: 03-Jun-15 10:06 AM Site: AW-2B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.014 mg-N/L EPA 353.2 06/09/2015 11:09 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 1.3 mg/L EPA 300.0 06/09/2015 18:06 BGN90340.1 1 Sulfate 2.9 mg/L EPA 300.0 06/09/2015 18:06 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 14:46 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 11:21 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.026 mg/L EPA 200.7 06/05/2015 12:29 MHALL30.005 1 Barium (Ba)0.015 mg/L EPA 200.7 06/05/2015 12:29 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/05/2015 12:29 MHALL30.05 1 Iron (Fe)1.63 mg/L EPA 200.7 06/05/2015 12:29 MHALL30.01 1 Manganese (Mn)0.202 mg/L EPA 200.7 06/05/2015 12:29 MHALL30.005 1 Strontium (Sr)0.010 mg/L EPA 200.7 06/05/2015 12:29 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/05/2015 12:29 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)1.60 mg/L EPA 200.7 06/10/2015 11:20 MHALL30.01 1 Magnesium (Mg)0.285 mg/L EPA 200.7 06/10/2015 11:20 MHALL30.005 1 Potassium (K)0.864 mg/L EPA 200.7 06/10/2015 11:20 MHALL30.1 1 Sodium (Na)0.867 mg/L EPA 200.7 06/10/2015 11:20 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.035 mg/L EPA 200.7 06/08/2015 13:26 MHALL30.005 1 Barium (Ba)0.016 mg/L EPA 200.7 06/08/2015 13:26 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/08/2015 13:26 MHALL30.05 1 Iron (Fe)1.32 mg/L EPA 200.7 06/08/2015 13:26 MHALL30.01 1 Manganese (Mn)0.204 mg/L EPA 200.7 06/08/2015 13:26 MHALL30.005 1 Strontium (Sr)0.010 mg/L EPA 200.7 06/08/2015 13:26 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/08/2015 13:26 MHALL30.005 1 Analytical Lab Page 10 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017435 Collection Date: 03-Jun-15 10:06 AM Site: AW-2B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 21:51 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 21:51 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 21:51 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 21:51 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 21:51 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 21:51 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 21:51 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 21:51 SLS256011 Molybdenum (Mo)1.43 ug/L EPA 200.8 06/21/2015 21:51 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 21:51 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 21:51 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 21:51 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 21:51 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 15:10 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/20/2015 15:10 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 15:10 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 15:10 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 15:10 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/20/2015 15:10 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 15:10 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 15:10 SLS256011 Molybdenum (Mo)1.40 ug/L EPA 200.8 06/20/2015 15:10 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 15:10 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 15:10 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 15:10 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 15:10 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 06/09/2015 11:22 AGIBBS5251 Total Carbon TOC 0.723 mg/L SM5310C/EPA9060A 06/08/2015 14:18 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/08/2015 11:45 AGIBBS551 Analytical Lab Page 11 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017436 Collection Date: 03-Jun-15 2:26 PM Site: AW-2C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.031 mg-N/L EPA 353.2 06/09/2015 11:10 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 4.7 mg/L EPA 300.0 06/09/2015 18:23 BGN90340.1 1 Sulfate 3.0 mg/L EPA 300.0 06/09/2015 18:23 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 14:49 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 11:24 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.021 mg/L EPA 200.7 06/05/2015 12:33 MHALL30.005 1 Barium (Ba)0.049 mg/L EPA 200.7 06/05/2015 12:33 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/05/2015 12:33 MHALL30.05 1 Iron (Fe)6.84 mg/L EPA 200.7 06/05/2015 12:33 MHALL30.01 1 Manganese (Mn)0.054 mg/L EPA 200.7 06/05/2015 12:33 MHALL30.005 1 Strontium (Sr)0.012 mg/L EPA 200.7 06/05/2015 12:33 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/05/2015 12:33 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)1.96 mg/L EPA 200.7 06/10/2015 11:24 MHALL30.01 1 Magnesium (Mg)0.567 mg/L EPA 200.7 06/10/2015 11:24 MHALL30.005 1 Potassium (K)1.17 mg/L EPA 200.7 06/10/2015 11:24 MHALL30.1 1 Sodium (Na)2.78 mg/L EPA 200.7 06/10/2015 11:24 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.117 mg/L EPA 200.7 06/08/2015 13:30 MHALL30.005 1 Barium (Ba)0.055 mg/L EPA 200.7 06/08/2015 13:30 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/08/2015 13:30 MHALL30.05 1 Iron (Fe)7.61 mg/L EPA 200.7 06/08/2015 13:30 MHALL30.01 1 Manganese (Mn)0.057 mg/L EPA 200.7 06/08/2015 13:30 MHALL30.005 1 Strontium (Sr)0.012 mg/L EPA 200.7 06/08/2015 13:30 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/08/2015 13:30 MHALL30.005 1 Analytical Lab Page 12 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017436 Collection Date: 03-Jun-15 2:26 PM Site: AW-2C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 22:25 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 22:25 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 22:25 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 22:25 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 22:25 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 22:25 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 22:25 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 22:25 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 22:25 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 22:25 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 22:25 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 22:25 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 22:25 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 15:17 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/20/2015 15:17 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 15:17 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 15:17 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 15:17 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/20/2015 15:17 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 15:17 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 15:17 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/20/2015 15:17 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 15:17 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 15:17 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 15:17 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 15:17 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 38 mg/L SM2540C 06/09/2015 11:22 AGIBBS5251 Total Carbon TOC 1.2 mg/L SM5310C/EPA9060A 06/08/2015 14:18 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/08/2015 11:45 AGIBBS551 Analytical Lab Page 13 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017437 Collection Date: 03-Jun-15 1:50 PM Site: AW-2D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/09/2015 11:11 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 160 mg/L EPA 300.0 06/10/2015 08:59 BGN9034550 Sulfate 35 mg/L EPA 300.0 06/10/2015 08:59 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 14:51 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 11:26 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.017 mg/L EPA 200.7 06/05/2015 12:37 MHALL30.005 1 Barium (Ba)0.011 mg/L EPA 200.7 06/05/2015 12:37 MHALL30.005 1 Boron (B)0.652 mg/L EPA 200.7 06/05/2015 12:37 MHALL30.05 1 Iron (Fe)0.174 mg/L EPA 200.7 06/05/2015 12:37 MHALL30.01 1 Manganese (Mn)0.056 mg/L EPA 200.7 06/05/2015 12:37 MHALL30.005 1 Strontium (Sr)0.103 mg/L EPA 200.7 06/05/2015 12:37 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/05/2015 12:37 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)13.3 mg/L EPA 200.7 06/10/2015 11:28 MHALL30.01 1 Magnesium (Mg)7.58 mg/L EPA 200.7 06/10/2015 11:28 MHALL30.005 1 Potassium (K)8.25 mg/L EPA 200.7 06/10/2015 11:28 MHALL30.1 1 Sodium (Na)172 mg/L EPA 200.7 06/10/2015 11:28 MHALL30.5 10 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.104 mg/L EPA 200.7 06/08/2015 13:34 MHALL30.005 1 Barium (Ba)0.012 mg/L EPA 200.7 06/08/2015 13:34 MHALL30.005 1 Boron (B)0.666 mg/L EPA 200.7 06/08/2015 13:34 MHALL30.05 1 Iron (Fe)0.438 mg/L EPA 200.7 06/08/2015 13:34 MHALL30.01 1 Manganese (Mn)0.059 mg/L EPA 200.7 06/08/2015 13:34 MHALL30.005 1 Strontium (Sr)0.107 mg/L EPA 200.7 06/08/2015 13:34 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/08/2015 13:34 MHALL30.005 1 Analytical Lab Page 14 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017437 Collection Date: 03-Jun-15 1:50 PM Site: AW-2D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 22:32 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 22:32 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 22:32 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 22:32 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 22:32 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 22:32 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 22:32 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 22:32 SLS256011 Molybdenum (Mo)2.58 ug/L EPA 200.8 06/21/2015 22:32 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 22:32 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 22:32 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 22:32 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 22:32 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 15:46 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/20/2015 15:46 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 15:46 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 15:46 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 15:46 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/20/2015 15:46 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 15:46 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 15:46 SLS256011 Molybdenum (Mo)3.15 ug/L EPA 200.8 06/20/2015 15:46 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 15:46 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 15:46 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 15:46 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 15:46 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 510 mg/L SM2540C 06/09/2015 11:22 AGIBBS5251 Total Carbon TOC 3.5 mg/L SM5310C/EPA9060A 06/08/2015 14:18 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS 6.0 mg/L SM2540D 06/08/2015 11:45 AGIBBS551 Analytical Lab Page 15 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017438 Collection Date: 02-Jun-15 8:00 PM Site: AW-1B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.044 mg-N/L EPA 353.2 06/09/2015 11:13 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 2.3 mg/L EPA 300.0 06/10/2015 15:24 BGN90340.1 1 Sulfate 4.5 mg/L EPA 300.0 06/10/2015 15:24 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 14:53 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 11:28 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.042 mg/L EPA 200.7 06/05/2015 12:40 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 06/05/2015 12:40 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/05/2015 12:40 MHALL30.05 1 Iron (Fe)2.16 mg/L EPA 200.7 06/05/2015 12:40 MHALL30.01 1 Manganese (Mn)0.089 mg/L EPA 200.7 06/05/2015 12:40 MHALL30.005 1 Strontium (Sr)0.007 mg/L EPA 200.7 06/05/2015 12:40 MHALL30.005 1 Zinc (Zn)0.015 mg/L EPA 200.7 06/05/2015 12:40 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)1.01 mg/L EPA 200.7 06/10/2015 12:11 MHALL30.01 1 Magnesium (Mg)0.237 mg/L EPA 200.7 06/10/2015 12:11 MHALL30.005 1 Potassium (K)0.365 mg/L EPA 200.7 06/10/2015 12:11 MHALL30.1 1 Sodium (Na)4.91 mg/L EPA 200.7 06/10/2015 12:11 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.522 mg/L EPA 200.7 06/08/2015 13:38 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 06/08/2015 13:38 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/08/2015 13:38 MHALL30.05 1 Iron (Fe)2.68 mg/L EPA 200.7 06/08/2015 13:38 MHALL30.01 1 Manganese (Mn)0.105 mg/L EPA 200.7 06/08/2015 13:38 MHALL30.005 1 Strontium (Sr)0.008 mg/L EPA 200.7 06/08/2015 13:38 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/08/2015 13:38 MHALL30.005 1 Analytical Lab Page 16 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017438 Collection Date: 02-Jun-15 8:00 PM Site: AW-1B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 22:39 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 22:39 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 22:39 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 22:39 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 22:39 SLS256011 Cobalt (Co)1.24 ug/L EPA 200.8 06/21/2015 22:39 SLS256011 Copper (Cu)1.31 ug/L EPA 200.8 06/21/2015 22:39 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 22:39 SLS256011 Molybdenum (Mo)1.44 ug/L EPA 200.8 06/21/2015 22:39 SLS256011 Nickel (Ni)1.07 ug/L EPA 200.8 06/21/2015 22:39 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 22:39 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 22:39 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 22:39 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 15:53 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/20/2015 15:53 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 15:53 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 15:53 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 15:53 SLS256011 Cobalt (Co)1.44 ug/L EPA 200.8 06/20/2015 15:53 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 15:53 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 15:53 SLS256011 Molybdenum (Mo)1.37 ug/L EPA 200.8 06/20/2015 15:53 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 15:53 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 15:53 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 15:53 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 15:53 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 44 mg/L SM2540C 06/08/2015 14:28 AGIBBS5251 Total Carbon TOC 0.580 mg/L SM5310C/EPA9060A 06/08/2015 14:18 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS 12 mg/L SM2540D 06/08/2015 09:02 AGIBBS551 Analytical Lab Page 17 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017439 Collection Date: 02-Jun-15 5:33 PM Site: AW-1C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.445 mg-N/L EPA 353.2 06/09/2015 11:14 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 29 mg/L EPA 300.0 06/10/2015 12:08 BGN9034110 Sulfate 32 mg/L EPA 300.0 06/10/2015 12:08 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 14:56 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 11:31 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.115 mg/L EPA 200.7 06/05/2015 12:44 MHALL30.005 1 Barium (Ba)0.136 mg/L EPA 200.7 06/05/2015 12:44 MHALL30.005 1 Boron (B)0.111 mg/L EPA 200.7 06/05/2015 12:44 MHALL30.05 1 Iron (Fe)0.067 mg/L EPA 200.7 06/05/2015 12:44 MHALL30.01 1 Manganese (Mn)0.171 mg/L EPA 200.7 06/05/2015 12:44 MHALL30.005 1 Strontium (Sr)0.066 mg/L EPA 200.7 06/05/2015 12:44 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/05/2015 12:44 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)5.24 mg/L EPA 200.7 06/10/2015 12:15 MHALL30.01 1 Magnesium (Mg)2.25 mg/L EPA 200.7 06/10/2015 12:15 MHALL30.005 1 Potassium (K)2.24 mg/L EPA 200.7 06/10/2015 12:15 MHALL30.1 1 Sodium (Na)16.4 mg/L EPA 200.7 06/10/2015 12:15 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.472 mg/L EPA 200.7 06/08/2015 13:42 MHALL30.005 1 Barium (Ba)0.141 mg/L EPA 200.7 06/08/2015 13:42 MHALL30.005 1 Boron (B)0.098 mg/L EPA 200.7 06/08/2015 13:42 MHALL30.05 1 Iron (Fe)0.470 mg/L EPA 200.7 06/08/2015 13:42 MHALL30.01 1 Manganese (Mn)0.179 mg/L EPA 200.7 06/08/2015 13:42 MHALL30.005 1 Strontium (Sr)0.062 mg/L EPA 200.7 06/08/2015 13:42 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/08/2015 13:42 MHALL30.005 1 Analytical Lab Page 18 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017439 Collection Date: 02-Jun-15 5:33 PM Site: AW-1C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 23:08 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 23:08 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 23:08 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 23:08 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 23:08 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/21/2015 23:08 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 23:08 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 23:08 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 23:08 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 23:08 SLS256011 Selenium (Se)2.78 ug/L EPA 200.8 06/21/2015 23:08 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 23:08 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 23:08 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 16:00 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/20/2015 16:00 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 16:00 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 16:00 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 16:00 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/20/2015 16:00 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 16:00 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 16:00 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/20/2015 16:00 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 16:00 SLS256011 Selenium (Se)2.60 ug/L EPA 200.8 06/20/2015 16:00 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 16:00 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 16:00 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 84 mg/L SM2540C 06/08/2015 14:28 AGIBBS5251 Total Carbon TOC 0.549 mg/L SM5310C/EPA9060A 06/08/2015 14:18 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS 7.0 mg/L SM2540D 06/08/2015 09:02 AGIBBS551 Analytical Lab Page 19 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017440 Collection Date: 02-Jun-15 1:55 PM Site: AW-8B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.022 mg-N/L EPA 353.2 06/09/2015 11:15 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 2.3 mg/L EPA 300.0 06/10/2015 15:57 BGN90340.1 1 Sulfate 16 mg/L EPA 300.0 06/10/2015 15:57 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 14:58 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 11:33 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.198 mg/L EPA 200.7 06/05/2015 12:48 MHALL30.005 1 Barium (Ba)0.025 mg/L EPA 200.7 06/05/2015 12:48 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/05/2015 12:48 MHALL30.05 1 Iron (Fe)4.16 mg/L EPA 200.7 06/05/2015 12:48 MHALL30.01 1 Manganese (Mn)0.028 mg/L EPA 200.7 06/05/2015 12:48 MHALL30.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 06/05/2015 12:48 MHALL30.005 1 Zinc (Zn)0.008 mg/L EPA 200.7 06/05/2015 12:48 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)0.503 mg/L EPA 200.7 06/10/2015 12:53 MHALL30.01 1 Magnesium (Mg)0.357 mg/L EPA 200.7 06/10/2015 12:53 MHALL30.005 1 Potassium (K)1.01 mg/L EPA 200.7 06/10/2015 12:53 MHALL30.1 1 Sodium (Na)1.15 mg/L EPA 200.7 06/10/2015 12:53 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.276 mg/L EPA 200.7 06/08/2015 13:45 MHALL30.005 1 Barium (Ba)0.025 mg/L EPA 200.7 06/08/2015 13:45 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/08/2015 13:45 MHALL30.05 1 Iron (Fe)4.45 mg/L EPA 200.7 06/08/2015 13:45 MHALL30.01 1 Manganese (Mn)0.029 mg/L EPA 200.7 06/08/2015 13:45 MHALL30.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 06/08/2015 13:45 MHALL30.005 1 Zinc (Zn)0.013 mg/L EPA 200.7 06/08/2015 13:45 MHALL30.005 1 Analytical Lab Page 20 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017440 Collection Date: 02-Jun-15 1:55 PM Site: AW-8B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 23:30 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 23:30 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 23:30 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 23:30 SLS256011 Chromium (Cr)1.03 ug/L EPA 200.8 06/21/2015 23:30 SLS256011 Cobalt (Co)2.55 ug/L EPA 200.8 06/21/2015 23:30 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 23:30 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 23:30 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 23:30 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/21/2015 23:30 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 23:30 SLS256011 Thallium (Tl) Low Level 0.258 ug/L EPA 200.8 06/21/2015 23:30 SLS25600.2 1 Vanadium (V) Low Level 0.346 ug/L EPA 200.8 06/21/2015 23:30 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 16:08 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/20/2015 16:08 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 16:08 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 16:08 SLS256011 Chromium (Cr)1.65 ug/L EPA 200.8 06/20/2015 16:08 SLS256011 Cobalt (Co)2.53 ug/L EPA 200.8 06/20/2015 16:08 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 16:08 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 16:08 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/20/2015 16:08 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 16:08 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 16:08 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 16:08 SLS25600.2 1 Vanadium (V) Low Level 0.335 ug/L EPA 200.8 06/20/2015 16:08 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 26 mg/L SM2540C 06/08/2015 14:28 AGIBBS5251 Total Carbon TOC 1.2 mg/L SM5310C/EPA9060A 06/08/2015 14:18 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/08/2015 09:02 AGIBBS551 Analytical Lab Page 21 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017441 Collection Date: 02-Jun-15 3:10 PM Site: AW-8C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.449 mg-N/L EPA 353.2 06/09/2015 11:16 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 6.5 mg/L EPA 300.0 06/10/2015 16:13 BGN90340.1 1 Sulfate 21 mg/L EPA 300.0 06/10/2015 16:13 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 15:19 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 11:35 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.297 mg/L EPA 200.7 06/05/2015 12:52 MHALL30.005 1 Barium (Ba)0.037 mg/L EPA 200.7 06/05/2015 12:52 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/05/2015 12:52 MHALL30.05 1 Iron (Fe)0.061 mg/L EPA 200.7 06/05/2015 12:52 MHALL30.01 1 Manganese (Mn)0.022 mg/L EPA 200.7 06/05/2015 12:52 MHALL30.005 1 Strontium (Sr)0.023 mg/L EPA 200.7 06/05/2015 12:52 MHALL30.005 1 Zinc (Zn)0.015 mg/L EPA 200.7 06/05/2015 12:52 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)1.94 mg/L EPA 200.7 06/10/2015 14:07 MHALL30.01 1 Magnesium (Mg)1.05 mg/L EPA 200.7 06/10/2015 14:07 MHALL30.005 1 Potassium (K)1.05 mg/L EPA 200.7 06/10/2015 14:07 MHALL30.1 1 Sodium (Na)4.29 mg/L EPA 200.7 06/10/2015 14:07 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.339 mg/L EPA 200.7 06/08/2015 13:49 MHALL30.005 1 Barium (Ba)0.040 mg/L EPA 200.7 06/08/2015 13:49 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/08/2015 13:49 MHALL30.05 1 Iron (Fe)0.061 mg/L EPA 200.7 06/08/2015 13:49 MHALL30.01 1 Manganese (Mn)0.023 mg/L EPA 200.7 06/08/2015 13:49 MHALL30.005 1 Strontium (Sr)0.023 mg/L EPA 200.7 06/08/2015 13:49 MHALL30.005 1 Zinc (Zn)0.010 mg/L EPA 200.7 06/08/2015 13:49 MHALL30.005 1 Analytical Lab Page 22 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017441 Collection Date: 02-Jun-15 3:10 PM Site: AW-8C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/21/2015 23:59 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/21/2015 23:59 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/21/2015 23:59 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/21/2015 23:59 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/21/2015 23:59 SLS256011 Cobalt (Co)1.07 ug/L EPA 200.8 06/21/2015 23:59 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/21/2015 23:59 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/21/2015 23:59 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/21/2015 23:59 SLS256011 Nickel (Ni)1.31 ug/L EPA 200.8 06/21/2015 23:59 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/21/2015 23:59 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/21/2015 23:59 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/21/2015 23:59 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 16:15 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/20/2015 16:15 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 16:15 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 16:15 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 16:15 SLS256011 Cobalt (Co)1.19 ug/L EPA 200.8 06/20/2015 16:15 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 16:15 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 16:15 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/20/2015 16:15 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 16:15 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 16:15 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 16:15 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 16:15 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 30 mg/L SM2540C 06/08/2015 14:28 AGIBBS5251 Total Carbon TOC 0.214 mg/L SM5310C/EPA9060A 06/08/2015 14:18 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/08/2015 09:02 AGIBBS551 Analytical Lab Page 23 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017442 Collection Date: 03-Jun-15 10:05 AM Site: MW-23B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.123 mg-N/L EPA 353.2 06/09/2015 11:21 LSTARL10.01 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 15:26 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 11:38 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 06/05/2015 12:56 MHALL30.005 1 Barium (Ba)0.038 mg/L EPA 200.7 06/05/2015 12:56 MHALL30.005 1 Boron (B)0.144 mg/L EPA 200.7 06/05/2015 12:56 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 06/05/2015 12:56 MHALL30.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 06/05/2015 12:56 MHALL30.005 1 Strontium (Sr)0.355 mg/L EPA 200.7 06/05/2015 12:56 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/05/2015 12:56 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)11.8 mg/L EPA 200.7 06/10/2015 12:23 MHALL30.01 1 Magnesium (Mg)1.90 mg/L EPA 200.7 06/10/2015 12:23 MHALL30.005 1 Potassium (K)2.86 mg/L EPA 200.7 06/10/2015 12:23 MHALL30.1 1 Sodium (Na)1.52 mg/L EPA 200.7 06/10/2015 12:23 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.029 mg/L EPA 200.7 06/08/2015 14:01 MHALL30.005 1 Barium (Ba)0.039 mg/L EPA 200.7 06/08/2015 14:01 MHALL30.005 1 Boron (B)0.137 mg/L EPA 200.7 06/08/2015 14:01 MHALL30.05 1 Iron (Fe)0.020 mg/L EPA 200.7 06/08/2015 14:01 MHALL30.01 1 Manganese (Mn)0.009 mg/L EPA 200.7 06/08/2015 14:01 MHALL30.005 1 Strontium (Sr)0.365 mg/L EPA 200.7 06/08/2015 14:01 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/08/2015 14:01 MHALL30.005 1 Analytical Lab Page 24 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017442 Collection Date: 03-Jun-15 10:05 AM Site: MW-23B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/22/2015 00:06 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/22/2015 00:06 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/22/2015 00:06 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/22/2015 00:06 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/22/2015 00:06 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/22/2015 00:06 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/22/2015 00:06 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/22/2015 00:06 SLS256011 Molybdenum (Mo)130 ug/L EPA 200.8 06/22/2015 00:06 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/22/2015 00:06 SLS256011 Selenium (Se)4.77 ug/L EPA 200.8 06/22/2015 00:06 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/22/2015 00:06 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/22/2015 00:06 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 16:44 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/20/2015 16:44 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 16:44 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 16:44 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 16:44 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/20/2015 16:44 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 16:44 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 16:44 SLS256011 Molybdenum (Mo)129 ug/L EPA 200.8 06/20/2015 16:44 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 16:44 SLS256011 Selenium (Se)4.88 ug/L EPA 200.8 06/20/2015 16:44 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 16:44 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 16:44 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 Total Carbon TOC 1.0 mg/L SM5310C/EPA9060A 06/08/2015 14:18 GHUTCHI0.1 1 Analytical Lab Page 25 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017443 Collection Date: 03-Jun-15 11:44 AM Site: MW-23E Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/09/2015 11:25 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 500 mg/L EPA 300.0 06/11/2015 09:33 BGN903410100 Sulfate 110 mg/L EPA 300.0 06/11/2015 09:33 BGN90342.5 25 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 15:28 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 11:59 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.014 mg/L EPA 200.7 06/05/2015 13:07 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 06/05/2015 13:07 MHALL30.005 1 Boron (B)2.42 mg/L EPA 200.7 06/05/2015 13:07 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 06/05/2015 13:07 MHALL30.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 06/05/2015 13:07 MHALL30.005 1 Strontium (Sr)0.082 mg/L EPA 200.7 06/05/2015 13:07 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/05/2015 13:07 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)4.96 mg/L EPA 200.7 06/10/2015 09:51 MHALL30.01 1 Magnesium (Mg)9.04 mg/L EPA 200.7 06/10/2015 09:51 MHALL30.005 1 Potassium (K)88.2 mg/L EPA 200.7 06/10/2015 09:51 MHALL3110 Sodium (Na)519 mg/L EPA 200.7 06/10/2015 09:51 MHALL30.5 10 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.041 mg/L EPA 200.7 06/08/2015 14:12 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 06/08/2015 14:12 MHALL30.005 1 Boron (B)2.50 mg/L EPA 200.7 06/08/2015 14:12 MHALL30.05 1 Iron (Fe)0.048 mg/L EPA 200.7 06/08/2015 14:12 MHALL30.01 1 Manganese (Mn)0.005 mg/L EPA 200.7 06/08/2015 14:12 MHALL30.005 1 Strontium (Sr)0.092 mg/L EPA 200.7 06/08/2015 14:12 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/08/2015 14:12 MHALL30.005 1 Analytical Lab Page 26 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017443 Collection Date: 03-Jun-15 11:44 AM Site: MW-23E Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/22/2015 00:13 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/22/2015 00:13 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/22/2015 00:13 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/22/2015 00:13 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/22/2015 00:13 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/22/2015 00:13 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/22/2015 00:13 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/22/2015 00:13 SLS256011 Molybdenum (Mo)16.2 ug/L EPA 200.8 06/22/2015 00:13 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/22/2015 00:13 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/22/2015 00:13 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/22/2015 00:13 SLS25600.2 1 Vanadium (V) Low Level 1.16 ug/L EPA 200.8 06/22/2015 00:13 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 16:22 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/20/2015 16:22 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 16:22 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 16:22 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 16:22 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/20/2015 16:22 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 16:22 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 16:22 SLS256011 Molybdenum (Mo)15.6 ug/L EPA 200.8 06/20/2015 16:22 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 16:22 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 16:22 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 16:22 SLS25600.2 1 Vanadium (V) Low Level 0.993 ug/L EPA 200.8 06/20/2015 16:22 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 1500 mg/L SM2540C 06/09/2015 11:22 AGIBBS5251 Total Carbon TOC 4.0 mg/L SM5310C/EPA9060A 06/08/2015 14:18 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS 8.0 mg/L SM2540D 06/08/2015 11:45 AGIBBS551 Analytical Lab Page 27 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017444 Collection Date: 03-Jun-15 4:20 PM Site: SMW-6D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/09/2015 11:26 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 190 mg/L EPA 300.0 06/11/2015 09:49 BGN9034550 Sulfate 26 mg/L EPA 300.0 06/11/2015 09:49 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 15:30 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 12:06 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.050 mg/L EPA 200.7 06/05/2015 13:18 MHALL30.005 1 Barium (Ba)0.014 mg/L EPA 200.7 06/05/2015 13:18 MHALL30.005 1 Boron (B)0.987 mg/L EPA 200.7 06/05/2015 13:18 MHALL30.05 1 Iron (Fe)0.058 mg/L EPA 200.7 06/05/2015 13:18 MHALL30.01 1 Manganese (Mn)0.031 mg/L EPA 200.7 06/05/2015 13:18 MHALL30.005 1 Strontium (Sr)0.078 mg/L EPA 200.7 06/05/2015 13:18 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/05/2015 13:18 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)6.79 mg/L EPA 200.7 06/10/2015 10:12 MHALL30.01 1 Magnesium (Mg)2.95 mg/L EPA 200.7 06/10/2015 10:12 MHALL30.005 1 Potassium (K)6.38 mg/L EPA 200.7 06/10/2015 10:12 MHALL30.1 1 Sodium (Na)260 mg/L EPA 200.7 06/10/2015 10:12 MHALL30.5 10 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.221 mg/L EPA 200.7 06/08/2015 14:16 MHALL30.005 1 Barium (Ba)0.015 mg/L EPA 200.7 06/08/2015 14:16 MHALL30.005 1 Boron (B)0.990 mg/L EPA 200.7 06/08/2015 14:16 MHALL30.05 1 Iron (Fe)0.300 mg/L EPA 200.7 06/08/2015 14:16 MHALL30.01 1 Manganese (Mn)0.037 mg/L EPA 200.7 06/08/2015 14:16 MHALL30.005 1 Strontium (Sr)0.085 mg/L EPA 200.7 06/08/2015 14:16 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/08/2015 14:16 MHALL30.005 1 Analytical Lab Page 28 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017444 Collection Date: 03-Jun-15 4:20 PM Site: SMW-6D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/22/2015 00:20 SLS256011 Arsenic (As)3.82 ug/L EPA 200.8 06/22/2015 00:20 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/22/2015 00:20 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/22/2015 00:20 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/22/2015 00:20 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/22/2015 00:20 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/22/2015 00:20 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/22/2015 00:20 SLS256011 Molybdenum (Mo)122 ug/L EPA 200.8 06/22/2015 00:20 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/22/2015 00:20 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/22/2015 00:20 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/22/2015 00:20 SLS25600.2 1 Vanadium (V) Low Level 1.19 ug/L EPA 200.8 06/22/2015 00:20 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 16:51 SLS256011 Arsenic (As)3.76 ug/L EPA 200.8 06/20/2015 16:51 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 16:51 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 16:51 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 16:51 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/20/2015 16:51 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 16:51 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 16:51 SLS256011 Molybdenum (Mo)110 ug/L EPA 200.8 06/20/2015 16:51 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 16:51 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 16:51 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 16:51 SLS25600.2 1 Vanadium (V) Low Level 1.61 ug/L EPA 200.8 06/20/2015 16:51 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 670 mg/L SM2540C 06/09/2015 11:22 AGIBBS5251 Total Carbon TOC 19 mg/L SM5310C/EPA9060A 06/08/2015 14:18 GHUTCHI110 TOTAL SUSPENDED SOLIDS TSS 8.0 mg/L SM2540D 06/08/2015 11:45 AGIBBS551 Analytical Lab Page 29 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017445 Collection Date: 03-Jun-15 4:40 PM Site: SMW-6B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.800 mg-N/L EPA 353.2 06/09/2015 11:27 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 5.8 mg/L EPA 300.0 06/10/2015 17:03 BGN90340.1 1 Sulfate 42 mg/L EPA 300.0 06/10/2015 17:03 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 15:33 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 12:08 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.070 mg/L EPA 200.7 06/05/2015 13:22 MHALL30.005 1 Barium (Ba)0.043 mg/L EPA 200.7 06/05/2015 13:22 MHALL30.005 1 Boron (B)0.059 mg/L EPA 200.7 06/05/2015 13:22 MHALL30.05 1 Iron (Fe)0.016 mg/L EPA 200.7 06/05/2015 13:22 MHALL30.01 1 Manganese (Mn)0.030 mg/L EPA 200.7 06/05/2015 13:22 MHALL30.005 1 Strontium (Sr)0.028 mg/L EPA 200.7 06/05/2015 13:22 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/05/2015 13:22 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)5.36 mg/L EPA 200.7 06/10/2015 12:34 MHALL30.01 1 Magnesium (Mg)0.759 mg/L EPA 200.7 06/10/2015 12:34 MHALL30.005 1 Potassium (K)8.92 mg/L EPA 200.7 06/10/2015 12:34 MHALL30.1 1 Sodium (Na)10.6 mg/L EPA 200.7 06/10/2015 12:34 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.073 mg/L EPA 200.7 06/08/2015 14:20 MHALL30.005 1 Barium (Ba)0.048 mg/L EPA 200.7 06/08/2015 14:20 MHALL30.005 1 Boron (B)0.060 mg/L EPA 200.7 06/08/2015 14:20 MHALL30.05 1 Iron (Fe)0.022 mg/L EPA 200.7 06/08/2015 14:20 MHALL30.01 1 Manganese (Mn)0.030 mg/L EPA 200.7 06/08/2015 14:20 MHALL30.005 1 Strontium (Sr)0.029 mg/L EPA 200.7 06/08/2015 14:20 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/08/2015 14:20 MHALL30.005 1 Analytical Lab Page 30 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017445 Collection Date: 03-Jun-15 4:40 PM Site: SMW-6B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/22/2015 00:28 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/22/2015 00:28 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/22/2015 00:28 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/22/2015 00:28 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/22/2015 00:28 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/22/2015 00:28 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/22/2015 00:28 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/22/2015 00:28 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/22/2015 00:28 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/22/2015 00:28 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/22/2015 00:28 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/22/2015 00:28 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/22/2015 00:28 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 17:20 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/20/2015 17:20 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 17:20 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 17:20 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 17:20 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/20/2015 17:20 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 17:20 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 17:20 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/20/2015 17:20 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 17:20 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 17:20 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 17:20 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 17:20 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 83 mg/L SM2540C 06/09/2015 11:22 AGIBBS5251 Total Carbon TOC 0.830 mg/L SM5310C/EPA9060A 06/08/2015 14:18 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/08/2015 11:45 AGIBBS551 Analytical Lab Page 31 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017446 Collection Date: 03-Jun-15 9:20 AM Site: Filter Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 12:10 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 06/05/2015 13:26 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 06/05/2015 13:26 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/05/2015 13:26 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 06/05/2015 13:26 MHALL30.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 06/05/2015 13:26 MHALL30.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 06/05/2015 13:26 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/05/2015 13:26 MHALL30.005 1 TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/22/2015 00:35 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/22/2015 00:35 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/22/2015 00:35 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/22/2015 00:35 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/22/2015 00:35 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/22/2015 00:35 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/22/2015 00:35 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/22/2015 00:35 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/22/2015 00:35 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/22/2015 00:35 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/22/2015 00:35 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/22/2015 00:35 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/22/2015 00:35 SLS25600.3 1 Analytical Lab Page 32 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017447 Collection Date: 03-Jun-15 9:20 AM Site: Equipment Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/09/2015 11:28 LSTARL10.01 1 INORGANIC IONS BY IC Chloride < 0.1 mg/L EPA 300.0 06/10/2015 18:08 BGN90340.1 1 Sulfate < 0.1 mg/L EPA 300.0 06/10/2015 18:08 BGN90340.1 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 06/09/2015 11:22 AGIBBS5251 Total Carbon TOC 0.117 mg/L SM5310C/EPA9060A 06/08/2015 14:18 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/08/2015 11:45 AGIBBS551 Analytical Lab Page 33 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017448 Collection Date: 03-Jun-15 3:52 PM Site: AW-6B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.050 mg-N/L EPA 353.2 06/09/2015 11:29 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 3.6 mg/L EPA 300.0 06/10/2015 21:25 BGN90340.1 1 Sulfate 14 mg/L EPA 300.0 06/10/2015 21:25 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 15:35 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 12:13 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.764 mg/L EPA 200.7 06/05/2015 13:30 MHALL30.005 1 Barium (Ba)0.030 mg/L EPA 200.7 06/05/2015 13:30 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/05/2015 13:30 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 06/05/2015 13:30 MHALL30.01 1 Manganese (Mn)0.017 mg/L EPA 200.7 06/05/2015 13:30 MHALL30.005 1 Strontium (Sr)0.023 mg/L EPA 200.7 06/05/2015 13:30 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/05/2015 13:30 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)1.71 mg/L EPA 200.7 06/10/2015 12:38 MHALL30.01 1 Magnesium (Mg)0.395 mg/L EPA 200.7 06/10/2015 12:38 MHALL30.005 1 Potassium (K)0.849 mg/L EPA 200.7 06/10/2015 12:38 MHALL30.1 1 Sodium (Na)1.54 mg/L EPA 200.7 06/10/2015 12:38 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.890 mg/L EPA 200.7 06/08/2015 14:23 MHALL30.005 1 Barium (Ba)0.032 mg/L EPA 200.7 06/08/2015 14:23 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 06/08/2015 14:23 MHALL30.05 1 Iron (Fe)0.071 mg/L EPA 200.7 06/08/2015 14:23 MHALL30.01 1 Manganese (Mn)0.017 mg/L EPA 200.7 06/08/2015 14:23 MHALL30.005 1 Strontium (Sr)0.025 mg/L EPA 200.7 06/08/2015 14:23 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/08/2015 14:23 MHALL30.005 1 Analytical Lab Page 34 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017448 Collection Date: 03-Jun-15 3:52 PM Site: AW-6B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/22/2015 00:42 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/22/2015 00:42 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/22/2015 00:42 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/22/2015 00:42 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/22/2015 00:42 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/22/2015 00:42 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/22/2015 00:42 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/22/2015 00:42 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/22/2015 00:42 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/22/2015 00:42 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/22/2015 00:42 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/22/2015 00:42 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/22/2015 00:42 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 17:27 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/20/2015 17:27 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 17:27 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 17:27 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 17:27 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/20/2015 17:27 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 17:27 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 17:27 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/20/2015 17:27 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 17:27 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 17:27 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 17:27 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 17:27 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 06/09/2015 11:22 AGIBBS5251 Total Carbon TOC 0.454 mg/L SM5310C/EPA9060A 06/08/2015 14:18 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/08/2015 11:45 AGIBBS551 Analytical Lab Page 35 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017449 Collection Date: 03-Jun-15 6:37 PM Site: AW-6D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/09/2015 11:31 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 190 mg/L EPA 300.0 06/11/2015 10:22 BGN90342.5 25 Sulfate 15 mg/L EPA 300.0 06/11/2015 10:22 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 15:38 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 12:15 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.019 mg/L EPA 200.7 06/05/2015 13:34 MHALL30.005 1 Barium (Ba)0.015 mg/L EPA 200.7 06/05/2015 13:34 MHALL30.005 1 Boron (B)0.934 mg/L EPA 200.7 06/05/2015 13:34 MHALL30.05 1 Iron (Fe)0.013 mg/L EPA 200.7 06/05/2015 13:34 MHALL30.01 1 Manganese (Mn)0.016 mg/L EPA 200.7 06/05/2015 13:34 MHALL30.005 1 Strontium (Sr)0.080 mg/L EPA 200.7 06/05/2015 13:34 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/05/2015 13:34 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)7.33 mg/L EPA 200.7 06/10/2015 12:42 MHALL30.01 1 Magnesium (Mg)3.45 mg/L EPA 200.7 06/10/2015 12:42 MHALL30.005 1 Potassium (K)7.90 mg/L EPA 200.7 06/10/2015 12:42 MHALL30.1 1 Sodium (Na)239 mg/L EPA 200.7 06/10/2015 12:42 MHALL30.5 10 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.043 mg/L EPA 200.7 06/08/2015 14:27 MHALL30.005 1 Barium (Ba)0.016 mg/L EPA 200.7 06/08/2015 14:27 MHALL30.005 1 Boron (B)0.980 mg/L EPA 200.7 06/08/2015 14:27 MHALL30.05 1 Iron (Fe)0.102 mg/L EPA 200.7 06/08/2015 14:27 MHALL30.01 1 Manganese (Mn)0.018 mg/L EPA 200.7 06/08/2015 14:27 MHALL30.005 1 Strontium (Sr)0.082 mg/L EPA 200.7 06/08/2015 14:27 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/08/2015 14:27 MHALL30.005 1 Analytical Lab Page 36 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017449 Collection Date: 03-Jun-15 6:37 PM Site: AW-6D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/22/2015 00:49 SLS256011 Arsenic (As)2.14 ug/L EPA 200.8 06/22/2015 00:49 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/22/2015 00:49 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/22/2015 00:49 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/22/2015 00:49 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/22/2015 00:49 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/22/2015 00:49 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/22/2015 00:49 SLS256011 Molybdenum (Mo)11.7 ug/L EPA 200.8 06/22/2015 00:49 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/22/2015 00:49 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/22/2015 00:49 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/22/2015 00:49 SLS25600.2 1 Vanadium (V) Low Level 0.380 ug/L EPA 200.8 06/22/2015 00:49 SLS25600.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 17:34 SLS256011 Arsenic (As)1.57 ug/L EPA 200.8 06/20/2015 17:34 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 17:34 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 17:34 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 17:34 SLS256011 Cobalt (Co)< 1 ug/L EPA 200.8 06/20/2015 17:34 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 17:34 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 17:34 SLS256011 Molybdenum (Mo)18.1 ug/L EPA 200.8 06/20/2015 17:34 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 17:34 SLS256011 Selenium (Se)< 1 ug/L EPA 200.8 06/20/2015 17:34 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 17:34 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 17:34 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 720 mg/L SM2540C 06/09/2015 11:22 AGIBBS5251 Total Carbon TOC 32 mg/L SM5310C/EPA9060A 06/08/2015 14:18 GHUTCHI110 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 06/08/2015 11:45 AGIBBS551 Analytical Lab Page 37 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017450 Collection Date: 02-Jun-15 12:51 PM Site: MW-27B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)1.3 mg-N/L EPA 353.2 06/09/2015 11:32 LSTARL10.01 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 15:40 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 12:17 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.235 mg/L EPA 200.7 06/05/2015 13:38 MHALL30.005 1 Barium (Ba)0.039 mg/L EPA 200.7 06/05/2015 13:38 MHALL30.005 1 Boron (B)0.193 mg/L EPA 200.7 06/05/2015 13:38 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 06/05/2015 13:38 MHALL30.01 1 Manganese (Mn)0.054 mg/L EPA 200.7 06/05/2015 13:38 MHALL30.005 1 Strontium (Sr)0.120 mg/L EPA 200.7 06/05/2015 13:38 MHALL30.005 1 Zinc (Zn)0.006 mg/L EPA 200.7 06/05/2015 13:38 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)12.6 mg/L EPA 200.7 06/10/2015 13:04 MHALL30.01 1 Magnesium (Mg)2.57 mg/L EPA 200.7 06/10/2015 13:04 MHALL30.005 1 Potassium (K)3.88 mg/L EPA 200.7 06/10/2015 13:04 MHALL30.1 1 Sodium (Na)12.8 mg/L EPA 200.7 06/10/2015 13:04 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.240 mg/L EPA 200.7 06/08/2015 15:00 MHALL30.005 1 Barium (Ba)0.042 mg/L EPA 200.7 06/08/2015 15:00 MHALL30.005 1 Boron (B)0.195 mg/L EPA 200.7 06/08/2015 15:00 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 06/08/2015 15:00 MHALL30.01 1 Manganese (Mn)0.055 mg/L EPA 200.7 06/08/2015 15:00 MHALL30.005 1 Strontium (Sr)0.124 mg/L EPA 200.7 06/08/2015 15:00 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 06/08/2015 15:00 MHALL30.005 1 Analytical Lab Page 38 of 129 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060170 2015017450 Collection Date: 02-Jun-15 12:51 PM Site: MW-27B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) Antimony (Sb)< 1 ug/L EPA 200.8 06/18/2015 23:09 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 06/18/2015 23:09 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 06/18/2015 23:09 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 06/18/2015 23:09 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 06/18/2015 23:09 JAHERMA11 Cobalt (Co)1.79 ug/L EPA 200.8 06/18/2015 23:09 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 06/18/2015 23:09 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 06/18/2015 23:09 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/18/2015 23:09 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 06/18/2015 23:09 JAHERMA11 Selenium (Se)26.7 ug/L EPA 200.8 06/18/2015 23:09 JAHERMA11 Thallium (Tl) Low Level 0.291 ug/L EPA 200.8 06/18/2015 23:09 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/18/2015 23:09 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 06/20/2015 17:41 SLS256011 Arsenic (As)< 1 ug/L EPA 200.8 06/20/2015 17:41 SLS256011 Beryllium (Be)< 1 ug/L EPA 200.8 06/20/2015 17:41 SLS256011 Cadmium (Cd)< 1 ug/L EPA 200.8 06/20/2015 17:41 SLS256011 Chromium (Cr)< 1 ug/L EPA 200.8 06/20/2015 17:41 SLS256011 Cobalt (Co)1.65 ug/L EPA 200.8 06/20/2015 17:41 SLS256011 Copper (Cu)< 1 ug/L EPA 200.8 06/20/2015 17:41 SLS256011 Lead (Pb)< 1 ug/L EPA 200.8 06/20/2015 17:41 SLS256011 Molybdenum (Mo)< 1 ug/L EPA 200.8 06/20/2015 17:41 SLS256011 Nickel (Ni)< 1 ug/L EPA 200.8 06/20/2015 17:41 SLS256011 Selenium (Se)28.4 ug/L EPA 200.8 06/20/2015 17:41 SLS256011 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/20/2015 17:41 SLS25600.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/20/2015 17:41 SLS25600.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 Total Carbon TOC 0.450 mg/L SM5310C/EPA9060A 06/08/2015 14:18 GHUTCHI0.1 1 Analytical Lab Page 39 of 129 Analytical Lab Page 40 of 129 Analytical Lab Page 41 of 129 Analytical Lab Page 42 of 129 Analytical Lab Page 43 of 129 Analytical Lab Page 44 of 129 Analytical Lab Page 45 of 129 Analytical Lab Page 46 of 129 Analytical Lab Page 47 of 129 Analytical Lab Page 48 of 129 Analytical Lab Page 49 of 129 Analytical Lab Page 50 of 129 Analytical Lab Page 51 of 129 Analytical Lab Page 52 of 129 Analytical Lab Page 53 of 129 Analytical Lab Page 54 of 129 Analytical Lab Page 55 of 129 SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle QF05013Lot Number: J15060170Project Number: AB GW Assessment Water - SuttonProject Name: 06/15/2015 06/16/2015 Date Completed: Date Revised: Grant Wilton Project Manager *QF05013* This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. Page: 1 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Case Narrative Duke Energy Lot Number: QF05013 SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329 Project Name: AB GW Assessment Water - Sutton Project Number: J15060170 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. Page: 2 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: QF05013 Project Name: AB GW Assessment Water - Sutton Project Number: J15060170 Sample Number Sample ID Matrix Date Sampled Date Received 001 06/03/2015 10262015017431Aqueous 06/05/2015 002 06/03/2015 11262015017433Aqueous 06/05/2015 003 06/03/2015 16122015017434Aqueous 06/05/2015 004 06/03/2015 10062015017435Aqueous 06/05/2015 005 06/03/2015 14262015017436Aqueous 06/05/2015 006 06/03/2015 13502015017437Aqueous 06/05/2015 007 06/02/2015 20002015017438Aqueous 06/05/2015 008 06/02/2015 17332015017439Aqueous 06/05/2015 009 06/02/2015 13552015017440Aqueous 06/05/2015 010 06/02/2015 15102015017441Aqueous 06/05/2015 011 06/03/2015 12052015017442Aqueous 06/05/2015 012 06/03/2015 11442015017443Aqueous 06/05/2015 013 06/03/2015 16202015017444Aqueous 06/05/2015 014 06/03/2015 16402015017445Aqueous 06/05/2015 015 06/03/2015 09202015017447Aqueous 06/05/2015 (15 samples) Page: 3 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: QF05013 Project Name: AB GW Assessment Water - Sutton Project Number: J15060170 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2015017431 Aqueous Alkalinity SM 2320B-28 mg/L 5 001 2015017431 Aqueous Bicarbonate Alkalinity SM 2320B-27 mg/L 5 003 2015017434 Aqueous Alkalinity SM 2320B-360 mg/L 9 003 2015017434 Aqueous Bicarbonate Alkalinity SM 2320B-340 mg/L 9 003 2015017434 Aqueous Carbonate Alkalinity SM 2320B-12 mg/L 9 005 2015017436 Aqueous Alkalinity SM 2320B-14 mg/L 13 005 2015017436 Aqueous Bicarbonate Alkalinity SM 2320B-14 mg/L 13 006 2015017437 Aqueous Alkalinity SM 2320B-180 mg/L 15 006 2015017437 Aqueous Bicarbonate Alkalinity SM 2320B-180 mg/L 15 007 2015017438 Aqueous Methane RSK - 175 25 ug/L 18 009 2015017440 Aqueous Methane RSK - 175 34 ug/L 22 012 2015017443 Aqueous Alkalinity SM 2320B-450 mg/L 26 012 2015017443 Aqueous Bicarbonate Alkalinity SM 2320B-370 mg/L 26 012 2015017443 Aqueous Carbonate Alkalinity SM 2320B-80 mg/L 26 013 2015017444 Aqueous Alkalinity SM 2320B-290 mg/L 28 013 2015017444 Aqueous Bicarbonate Alkalinity SM 2320B-290 mg/L 28 (16 detections) Page: 4 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017431 QF05013-001 06/03/2015 1026 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/09/2015 2317 HMA 76879 1 (Bicarbonate ) SM 2320B-2011 1 06/09/2015 2317 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/09/2015 2317 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 28 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 27 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 5 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017431 QF05013-001 06/03/2015 1026 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 1059 DCS 77071 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 6 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017433 QF05013-002 06/03/2015 1126 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/09/2015 2321 HMA 76879 1 (Bicarbonate ) SM 2320B-2011 1 06/09/2015 2321 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/09/2015 2321 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 7 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017433 QF05013-002 06/03/2015 1126 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 1111 DCS 77071 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 8 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017434 QF05013-003 06/03/2015 1612 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 0000 HMA 76880 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 0000 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 0000 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 360 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 340 1mg/L10 Carbonate Alkalinity SM 2320B-20 12 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 9 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017434 QF05013-003 06/03/2015 1612 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 1121 DCS 77071 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 10 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017435 QF05013-004 06/03/2015 1006 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 0023 HMA 76880 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 0009 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 0009 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 11 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017435 QF05013-004 06/03/2015 1006 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 1134 DCS 77071 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 12 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017436 QF05013-005 06/03/2015 1426 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 0028 HMA 76880 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 0017 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 0017 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 14 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 14 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 13 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017436 QF05013-005 06/03/2015 1426 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 1144 DCS 77071 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 14 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017437 QF05013-006 06/03/2015 1350 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 0035 HMA 76880 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 0023 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 0023 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 180 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 180 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 15 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017437 QF05013-006 06/03/2015 1350 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 1354 DCS 77071 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 16 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017438 QF05013-007 06/02/2015 2000 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 0039 HMA 76880 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 0028 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 0028 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 17 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017438 QF05013-007 06/02/2015 2000 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 1407 DCS 77071 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 25 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 18 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017439 QF05013-008 06/02/2015 1733 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 0043 HMA 76880 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 0035 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 0035 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 19 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017439 QF05013-008 06/02/2015 1733 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 1418 DCS 77071 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 20 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017440 QF05013-009 06/02/2015 1355 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 0048 HMA 76880 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 0039 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 0039 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 21 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017440 QF05013-009 06/02/2015 1355 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 1429 DCS 77071 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 34 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 22 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017441 QF05013-010 06/02/2015 1510 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 0105 HMA 76880 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 0105 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 0105 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 23 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017441 QF05013-010 06/02/2015 1510 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 1441 DCS 77071 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 24 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017442 QF05013-011 06/03/2015 1205 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 1800 JJG 77131 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 25 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017443 QF05013-012 06/03/2015 1144 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 0114 HMA 76880 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 0114 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 0114 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 450 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 370 1mg/L10 Carbonate Alkalinity SM 2320B-20 80 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 26 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017443 QF05013-012 06/03/2015 1144 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 1815 JJG 77131 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 27 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017444 QF05013-013 06/03/2015 1620 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 0121 HMA 76880 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 0121 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 0121 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 290 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 290 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 28 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017444 QF05013-013 06/03/2015 1620 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 1840 JJG 77131 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 29 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017445 QF05013-014 06/03/2015 1640 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 0126 HMA 76880 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 0126 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 0126 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 30 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017445 QF05013-014 06/03/2015 1640 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 1851 JJG 77131 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 31 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017447 QF05013-015 06/03/2015 0920 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 0132 HMA 76880 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 0132 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 0132 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 32 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017447 QF05013-015 06/03/2015 0920 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 1916 JJG 77131 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 33 of 33 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 QC Summary QC Data for Lot Number: QF05013 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MB Batch: Sample ID:QQ76879-001 76879 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Alkalinity ND 06/09/2015 204510mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF05013 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - LCS Batch: Sample ID:QQ76879-002 76879 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Alkalinity 99 06/09/2015 20519910090-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF05013 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MS Batch: Sample ID:QF05013-002MS 76879 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Alkalinity 93 06/09/2015 23279310070-130ND1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF05013 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MSD Batch: Sample ID:QF05013-002MD 76879 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Alkalinity 94 06/09/2015 23339410070-1301.5 20ND1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF05013 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MB Batch: Sample ID:QQ76880-001 76880 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Alkalinity ND 06/09/2015 234610mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF05013 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - LCS Batch: Sample ID:QQ76880-002 76880 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Alkalinity 97 06/09/2015 23529710090-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF05013 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MS Batch: Sample ID:QF05013-003MS 76880 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Alkalinity 430 06/10/2015 00097410070-1303601 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF05013 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MSD Batch: Sample ID:QF05013-003MD 76880 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Alkalinity 420 06/10/2015 0017N6810070-1301.4 203601 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF05013 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - MB Batch: Sample ID:QQ77071-001 77071 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 06/11/2015 094210ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF05013 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCS Batch: Sample ID:QQ77071-002 77071 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 46 06/11/2015 0905925070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF05013 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCSD Batch: Sample ID:QQ77071-003 77071 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 46 06/11/2015 0920915070-1301.2 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF05013 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - MB Batch: Sample ID:QQ77131-001 77131 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 06/11/2015 165510ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF05013 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCS Batch: Sample ID:QQ77131-002 77131 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 45 06/11/2015 1627895070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF05013 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCSD Batch: Sample ID:QQ77131-003 77131 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 44 06/11/2015 1641875070-1302.7 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF05013 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle QF05014Lot Number: J15060170Project Number: AB GW Assessment Water - SuttonProject Name: 06/16/2015Date Completed: Grant Wilton Project Manager *QF05014* This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. Page: 1 of 9 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Case Narrative Duke Energy Lot Number: QF05014 SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329 Project Name: AB GW Assessment Water - Sutton Project Number: J15060170 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. Page: 2 of 9 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: QF05014 Project Name: AB GW Assessment Water - Sutton Project Number: J15060170 Sample Number Sample ID Matrix Date Sampled Date Received 001 06/03/2015 15522015017448Aqueous 06/05/2015 002 06/03/2015 18372015017449Aqueous 06/05/2015 003 06/02/2015 12512015017450Aqueous 06/05/2015 (3 samples) Page: 3 of 9 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: QF05014 Project Name: AB GW Assessment Water - Sutton Project Number: J15060170 Sample Sample ID Matrix Parameter Method Result Q Units Page 002 2015017449 Aqueous Alkalinity SM 2320B-260 mg/L 7 002 2015017449 Aqueous Bicarbonate Alkalinity SM 2320B-250 mg/L 7 002 2015017449 Aqueous Methane RSK - 175 690 ug/L 8 (3 detections) Page: 4 of 9 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017448 QF05014-001 06/03/2015 1552 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 0136 HMA 76880 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 0136 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 0136 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 5 of 9 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017448 QF05014-001 06/03/2015 1552 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 1927 JJG 77131 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 6 of 9 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017449 QF05014-002 06/03/2015 1837 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 06/10/2015 0143 HMA 76880 1 (Bicarbonate ) SM 2320B-2011 1 06/10/2015 0143 HMA 1 (Carbonate Al) SM 2320B-2011 1 06/10/2015 0143 HMA AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 260 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 250 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 7 of 9 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017449 QF05014-002 06/03/2015 1837 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 RSK - 175 2 06/12/2015 1931 JJG 77223 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 690 2ug/L20 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 8 of 9 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015017450 QF05014-003 06/02/2015 1251 06/05/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15060170 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 06/11/2015 1949 JJG 77131 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 9 of 9 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 QC Summary QC Data for Lot Number: QF05014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MB Batch: Sample ID:QQ76880-001 76880 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Alkalinity ND 06/09/2015 234610mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF05014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - LCS Batch: Sample ID:QQ76880-002 76880 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Alkalinity 97 06/09/2015 23529710090-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF05014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - MB Batch: Sample ID:QQ77131-001 77131 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 06/11/2015 165510ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF05014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCS Batch: Sample ID:QQ77131-002 77131 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 45 06/11/2015 1627895070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF05014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCSD Batch: Sample ID:QQ77131-003 77131 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 44 06/11/2015 1641875070-1302.7 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF05014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - MB Batch: Sample ID:QQ77223-001 77223 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 06/12/2015 172010ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF05014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCS Batch: Sample ID:QQ77223-002 77223 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 45 06/12/2015 1626885070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF05014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCSD Batch: Sample ID:QQ77223-003 77223 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 49 06/12/2015 1659965070-1308.8 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QF05014 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Analytical Lab Page 126 of 129 Analytical Lab Page 127 of 129 Analytical Lab Page 128 of 129 Analytical Lab Page 129 of 129