NC0001422_ATT 5 - Water - J15060095report_20150805

13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Analytical Laboratory
Order Number: J15060095
Project Name:SUTTON - AB GW ASSESSMENT WATER
Lab Contact:Mary Ann Ogle
Date:6/22/2015
Customer Address:
Customer Name(s): Perry Waldrep, Tim Hunsucker, Kathy Webb, John Toepfer
Phone: [phone]
Report Authorized By:
(Signature)
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.
Mary Ann Ogle
Analytical Lab
Page 1 of 76
Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By Sample Description
2015017116 Sutton 02-Jun-15 2:38 PM ILLEGIBLE MW-7A
2015017117 Sutton 02-Jun-15 2:56 PM ILLEGIBLE MW-7B
2015017118 Sutton 02-Jun-15 1:45 PM ILLEGIBLE MW-7C
2015017119 Sutton 02-Jun-15 10:12 AM ILLEGIBLE MW-37B
2015017120 Sutton 02-Jun-15 11:58 AM ILLEGIBLE MW-37C
2015017121 Sutton 02-Jun-15 11:44 AM ILLEGIBLE MW-31C
2015017122 Sutton 02-Jun-15 9:46 AM ILLEGIBLE MW-12
2015017123 Sutton 02-Jun-15 2:26 PM ILLEGIBLE MW-23C
2015017124 Sutton 02-Jun-15 11:23 AM ILLEGIBLE MW-24C
2015017125 Sutton 02-Jun-15 9:50 AM ILLEGIBLE MW-24B
2015017126 Sutton 02-Jun-15 1:55 PM ILLEGIBLE AW-8B
2015017129 Sutton 02-Jun-15 3:11 PM ILLEGIBLE AW-8C
12 Total Samples
Analytical Lab
Page 2 of 76
COC and .pdf report are in agreement with sample totals
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits.
All laboratory QA/QC requirements are acceptable.
Yes No
Technical Validation Review
Checklist:
Yes No
Yes No
Report Sections Included:
Job Summary Report Sub-contracted Laboratory Results
Sample Identification Customer Specific Data Sheets, Reports, & Documentation
Technical Validation of Data Package Customer Database Entries
Analytical Laboratory Certificate of Analysis
Analytical Laboratory QC Report
Chain of Custody
Reviewed By:Mary Ann Ogle Date:6/22/2015
Electronic Data Deliverable (EDD) Sent Separately
Analytical Lab
Page 3 of 76
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060095
2015017116
Collection Date: 02-Jun-15 2:38 PM
Site: MW-7A
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.710 mg-N/L EPA 353.2 06/08/2015 12:05 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 1.1 mg/L EPA 300.0 06/08/2015 17:48 BGN90340.1 1
Sulfate 14 mg/L EPA 300.0 06/08/2015 17:48 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 10:36 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 16:04 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.919 mg/L EPA 200.7 06/04/2015 13:28 MHALL30.005 1
Barium (Ba)0.006 mg/L EPA 200.7 06/04/2015 13:28 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/04/2015 13:28 MHALL30.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 06/04/2015 13:28 MHALL30.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 06/04/2015 13:28 MHALL30.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 06/04/2015 13:28 MHALL30.005 1
Zinc (Zn)0.015 mg/L EPA 200.7 06/04/2015 13:28 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.794 mg/L EPA 200.7 06/05/2015 13:38 MHALL30.01 1
Magnesium (Mg)0.113 mg/L EPA 200.7 06/05/2015 13:38 MHALL30.005 1
Potassium (K)0.170 mg/L EPA 200.7 06/05/2015 13:38 MHALL30.1 1
Sodium (Na)0.452 mg/L EPA 200.7 06/05/2015 13:38 MHALL30.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)1.13 mg/L EPA 200.7 06/09/2015 10:55 MHH71310.005 1
Barium (Ba)0.006 mg/L EPA 200.7 06/09/2015 10:55 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/09/2015 10:55 MHH71310.05 1
Iron (Fe)0.093 mg/L EPA 200.7 06/09/2015 10:55 MHH71310.01 1
Manganese (Mn)< 0.005 mg/L EPA 200.7 06/09/2015 10:55 MHH71310.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 06/09/2015 10:55 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 10:55 MHH71310.005 1
Analytical Lab
Page 4 of 76
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060095
2015017116
Collection Date: 02-Jun-15 2:38 PM
Site: MW-7A
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/17/2015 19:16 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 06/17/2015 19:16 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 06/17/2015 19:16 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 06/17/2015 19:16 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 06/17/2015 19:16 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 06/17/2015 19:16 JAHERMA11
Copper (Cu)13.1 ug/L EPA 200.8 06/17/2015 19:16 JAHERMA11
Lead (Pb)1.27 ug/L EPA 200.8 06/17/2015 19:16 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/17/2015 19:16 JAHERMA11
Nickel (Ni)1.57 ug/L EPA 200.8 06/17/2015 19:16 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 06/17/2015 19:16 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/17/2015 19:16 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/17/2015 19:16 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/10/2015 14:46 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 06/10/2015 14:46 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 06/10/2015 14:46 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 06/10/2015 14:46 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 06/10/2015 14:46 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 06/10/2015 14:46 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 06/10/2015 14:46 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 06/10/2015 14:46 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/10/2015 14:46 JAHERMA11
Nickel (Ni)1.34 ug/L EPA 200.8 06/10/2015 14:46 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 06/10/2015 14:46 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/10/2015 14:46 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/10/2015 14:46 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 06/08/2015 10:13 AGIBBS5251
Total Carbon
TOC 0.518 mg/L SM5310C/EPA9060A 06/08/2015 10:08 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 06/06/2015 08:41 AGIBBS551
Analytical Lab
Page 5 of 76
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060095
2015017117
Collection Date: 02-Jun-15 2:56 PM
Site: MW-7B
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.530 mg-N/L EPA 353.2 06/08/2015 12:07 LSTARL10.01 1
INORGANIC IONS BY IC
Chloride 2.0 mg/L EPA 300.0 06/08/2015 18:04 BGN90340.1 1
Sulfate 17 mg/L EPA 300.0 06/08/2015 18:04 BGN9034110
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 11:24 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 16:06 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.540 mg/L EPA 200.7 06/04/2015 13:52 MHALL30.005 1
Barium (Ba)0.022 mg/L EPA 200.7 06/04/2015 13:52 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/04/2015 13:52 MHALL30.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 06/04/2015 13:52 MHALL30.01 1
Manganese (Mn)0.007 mg/L EPA 200.7 06/04/2015 13:52 MHALL30.005 1
Strontium (Sr)0.015 mg/L EPA 200.7 06/04/2015 13:52 MHALL30.005 1
Zinc (Zn)0.015 mg/L EPA 200.7 06/04/2015 13:52 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)2.29 mg/L EPA 200.7 06/05/2015 11:56 MHALL30.01 1
Magnesium (Mg)0.249 mg/L EPA 200.7 06/05/2015 11:56 MHALL30.005 1
Potassium (K)1.22 mg/L EPA 200.7 06/05/2015 11:56 MHALL30.1 1
Sodium (Na)1.06 mg/L EPA 200.7 06/05/2015 11:56 MHALL30.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.590 mg/L EPA 200.7 06/09/2015 11:07 MHH71310.005 1
Barium (Ba)0.022 mg/L EPA 200.7 06/09/2015 11:07 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/09/2015 11:07 MHH71310.05 1
Iron (Fe)0.015 mg/L EPA 200.7 06/09/2015 11:07 MHH71310.01 1
Manganese (Mn)0.009 mg/L EPA 200.7 06/09/2015 11:07 MHH71310.005 1
Strontium (Sr)0.015 mg/L EPA 200.7 06/09/2015 11:07 MHH71310.005 1
Zinc (Zn)0.006 mg/L EPA 200.7 06/09/2015 11:07 MHH71310.005 1
Analytical Lab
Page 6 of 76
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060095
2015017117
Collection Date: 02-Jun-15 2:56 PM
Site: MW-7B
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/17/2015 19:23 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 06/17/2015 19:23 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 06/17/2015 19:23 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 06/17/2015 19:23 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 06/17/2015 19:23 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 06/17/2015 19:23 JAHERMA11
Copper (Cu)12.3 ug/L EPA 200.8 06/17/2015 19:23 JAHERMA11
Lead (Pb)1.16 ug/L EPA 200.8 06/17/2015 19:23 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/17/2015 19:23 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 06/17/2015 19:23 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 06/17/2015 19:23 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/17/2015 19:23 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/17/2015 19:23 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/10/2015 14:31 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 06/10/2015 14:31 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 06/10/2015 14:31 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 06/10/2015 14:31 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 06/10/2015 14:31 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 06/10/2015 14:31 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 06/10/2015 14:31 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 06/10/2015 14:31 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/10/2015 14:31 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 06/10/2015 14:31 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 06/10/2015 14:31 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/10/2015 14:31 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/10/2015 14:31 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L SM2540C 06/08/2015 10:13 AGIBBS5251
Total Carbon
TOC 0.415 mg/L SM5310C/EPA9060A 06/08/2015 10:08 GHUTCHI0.1 1
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L SM2540D 06/06/2015 08:41 AGIBBS551
Analytical Lab
Page 7 of 76
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060095
2015017118
Collection Date: 02-Jun-15 1:45 PM
Site: MW-7C
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.457 mg-N/L EPA 353.2 06/08/2015 12:08 LSTARL10.01 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 11:22 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 16:08 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.107 mg/L EPA 200.7 06/04/2015 14:04 MHALL30.005 1
Barium (Ba)0.076 mg/L EPA 200.7 06/04/2015 14:04 MHALL30.005 1
Boron (B)0.571 mg/L EPA 200.7 06/04/2015 14:04 MHALL30.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 06/04/2015 14:04 MHALL30.01 1
Manganese (Mn)0.343 mg/L EPA 200.7 06/04/2015 14:04 MHALL30.005 1
Strontium (Sr)0.251 mg/L EPA 200.7 06/04/2015 14:04 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/04/2015 14:04 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)19.7 mg/L EPA 200.7 06/05/2015 13:42 MHALL30.01 1
Magnesium (Mg)4.78 mg/L EPA 200.7 06/05/2015 13:42 MHALL30.005 1
Potassium (K)4.26 mg/L EPA 200.7 06/05/2015 13:42 MHALL30.1 1
Sodium (Na)29.7 mg/L EPA 200.7 06/05/2015 13:42 MHALL30.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.111 mg/L EPA 200.7 06/09/2015 11:11 MHH71310.005 1
Barium (Ba)0.072 mg/L EPA 200.7 06/09/2015 11:11 MHH71310.005 1
Boron (B)0.546 mg/L EPA 200.7 06/09/2015 11:11 MHH71310.05 1
Iron (Fe)0.073 mg/L EPA 200.7 06/09/2015 11:11 MHH71310.01 1
Manganese (Mn)0.333 mg/L EPA 200.7 06/09/2015 11:11 MHH71310.005 1
Strontium (Sr)0.242 mg/L EPA 200.7 06/09/2015 11:11 MHH71310.005 1
Zinc (Zn)0.018 mg/L EPA 200.7 06/09/2015 11:11 MHH71310.005 1
Analytical Lab
Page 8 of 76
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060095
2015017118
Collection Date: 02-Jun-15 1:45 PM
Site: MW-7C
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/17/2015 19:30 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 06/17/2015 19:30 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 06/17/2015 19:30 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 06/17/2015 19:30 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 06/17/2015 19:30 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 06/17/2015 19:30 JAHERMA11
Copper (Cu)1.08 ug/L EPA 200.8 06/17/2015 19:30 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 06/17/2015 19:30 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/17/2015 19:30 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 06/17/2015 19:30 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 06/17/2015 19:30 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/17/2015 19:30 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/17/2015 19:30 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/10/2015 14:50 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 06/10/2015 14:50 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 06/10/2015 14:50 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 06/10/2015 14:50 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 06/10/2015 14:50 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 06/10/2015 14:50 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 06/10/2015 14:50 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 06/10/2015 14:50 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/10/2015 14:50 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 06/10/2015 14:50 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 06/10/2015 14:50 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/10/2015 14:50 JAHERMA0.2 1
Vanadium (V) Low Level 0.573 ug/L EPA 200.8 06/10/2015 14:50 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
Total Carbon
TOC 0.748 mg/L SM5310C/EPA9060A 06/08/2015 10:08 GHUTCHI0.1 1
Analytical Lab
Page 9 of 76
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060095
2015017119
Collection Date: 02-Jun-15 10:12 AM
Site: MW-37B
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.096 mg-N/L EPA 353.2 06/08/2015 12:09 LSTARL10.01 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 11:15 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 16:11 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.601 mg/L EPA 200.7 06/04/2015 14:07 MHALL30.005 1
Barium (Ba)0.008 mg/L EPA 200.7 06/04/2015 14:07 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/04/2015 14:07 MHALL30.05 1
Iron (Fe)0.022 mg/L EPA 200.7 06/04/2015 14:07 MHALL30.01 1
Manganese (Mn)0.008 mg/L EPA 200.7 06/04/2015 14:07 MHALL30.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 06/04/2015 14:07 MHALL30.005 1
Zinc (Zn)0.012 mg/L EPA 200.7 06/04/2015 14:07 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)0.482 mg/L EPA 200.7 06/05/2015 13:11 MHALL30.01 1
Magnesium (Mg)0.130 mg/L EPA 200.7 06/05/2015 13:11 MHALL30.005 1
Potassium (K)0.204 mg/L EPA 200.7 06/05/2015 13:11 MHALL30.1 1
Sodium (Na)2.31 mg/L EPA 200.7 06/05/2015 13:11 MHALL30.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.697 mg/L EPA 200.7 06/09/2015 11:15 MHH71310.005 1
Barium (Ba)0.008 mg/L EPA 200.7 06/09/2015 11:15 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/09/2015 11:15 MHH71310.05 1
Iron (Fe)0.031 mg/L EPA 200.7 06/09/2015 11:15 MHH71310.01 1
Manganese (Mn)0.007 mg/L EPA 200.7 06/09/2015 11:15 MHH71310.005 1
Strontium (Sr)< 0.005 mg/L EPA 200.7 06/09/2015 11:15 MHH71310.005 1
Zinc (Zn)0.010 mg/L EPA 200.7 06/09/2015 11:15 MHH71310.005 1
Analytical Lab
Page 10 of 76
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060095
2015017119
Collection Date: 02-Jun-15 10:12 AM
Site: MW-37B
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/17/2015 19:37 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 06/17/2015 19:37 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 06/17/2015 19:37 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 06/17/2015 19:37 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 06/17/2015 19:37 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 06/17/2015 19:37 JAHERMA11
Copper (Cu)10.8 ug/L EPA 200.8 06/17/2015 19:37 JAHERMA11
Lead (Pb)1.03 ug/L EPA 200.8 06/17/2015 19:37 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/17/2015 19:37 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 06/17/2015 19:37 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 06/17/2015 19:37 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/17/2015 19:37 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/17/2015 19:37 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/10/2015 14:55 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 06/10/2015 14:55 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 06/10/2015 14:55 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 06/10/2015 14:55 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 06/10/2015 14:55 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 06/10/2015 14:55 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 06/10/2015 14:55 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 06/10/2015 14:55 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/10/2015 14:55 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 06/10/2015 14:55 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 06/10/2015 14:55 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/10/2015 14:55 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/10/2015 14:55 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
Total Carbon
TOC 0.514 mg/L SM5310C/EPA9060A 06/08/2015 10:08 GHUTCHI0.1 1
Analytical Lab
Page 11 of 76
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060095
2015017120
Collection Date: 02-Jun-15 11:58 AM
Site: MW-37C
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.368 mg-N/L EPA 353.2 06/08/2015 12:13 LSTARL10.01 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 11:27 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 16:13 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.020 mg/L EPA 200.7 06/04/2015 14:11 MHALL30.005 1
Barium (Ba)0.039 mg/L EPA 200.7 06/04/2015 14:11 MHALL30.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/04/2015 14:11 MHALL30.05 1
Iron (Fe)8.55 mg/L EPA 200.7 06/04/2015 14:11 MHALL30.01 1
Manganese (Mn)0.249 mg/L EPA 200.7 06/04/2015 14:11 MHALL30.005 1
Strontium (Sr)0.019 mg/L EPA 200.7 06/04/2015 14:11 MHALL30.005 1
Zinc (Zn)0.015 mg/L EPA 200.7 06/04/2015 14:11 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)8.48 mg/L EPA 200.7 06/05/2015 14:24 MHALL30.01 1
Magnesium (Mg)1.75 mg/L EPA 200.7 06/05/2015 14:24 MHALL30.005 1
Potassium (K)4.73 mg/L EPA 200.7 06/05/2015 14:24 MHALL30.1 1
Sodium (Na)2.64 mg/L EPA 200.7 06/05/2015 14:24 MHALL30.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.052 mg/L EPA 200.7 06/09/2015 11:20 MHH71310.005 1
Barium (Ba)0.038 mg/L EPA 200.7 06/09/2015 11:20 MHH71310.005 1
Boron (B)< 0.05 mg/L EPA 200.7 06/09/2015 11:20 MHH71310.05 1
Iron (Fe)9.58 mg/L EPA 200.7 06/09/2015 11:20 MHH71310.01 1
Manganese (Mn)0.244 mg/L EPA 200.7 06/09/2015 11:20 MHH71310.005 1
Strontium (Sr)0.018 mg/L EPA 200.7 06/09/2015 11:20 MHH71310.005 1
Zinc (Zn)0.015 mg/L EPA 200.7 06/09/2015 11:20 MHH71310.005 1
Analytical Lab
Page 12 of 76
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060095
2015017120
Collection Date: 02-Jun-15 11:58 AM
Site: MW-37C
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/17/2015 19:44 JAHERMA11
Arsenic (As)2.56 ug/L EPA 200.8 06/17/2015 19:44 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 06/17/2015 19:44 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 06/17/2015 19:44 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 06/17/2015 19:44 JAHERMA11
Cobalt (Co)2.35 ug/L EPA 200.8 06/17/2015 19:44 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 06/17/2015 19:44 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 06/17/2015 19:44 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/17/2015 19:44 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 06/17/2015 19:44 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 06/17/2015 19:44 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/17/2015 19:44 JAHERMA0.2 1
Vanadium (V) Low Level 0.795 ug/L EPA 200.8 06/17/2015 19:44 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/10/2015 15:00 JAHERMA11
Arsenic (As)3.30 ug/L EPA 200.8 06/10/2015 15:00 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 06/10/2015 15:00 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 06/10/2015 15:00 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 06/10/2015 15:00 JAHERMA11
Cobalt (Co)2.73 ug/L EPA 200.8 06/10/2015 15:00 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 06/10/2015 15:00 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 06/10/2015 15:00 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/10/2015 15:00 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 06/10/2015 15:00 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 06/10/2015 15:00 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/10/2015 15:00 JAHERMA0.2 1
Vanadium (V) Low Level 1.22 ug/L EPA 200.8 06/10/2015 15:00 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
Total Carbon
TOC 5.6 mg/L SM5310C/EPA9060A 06/08/2015 10:08 GHUTCHI0.1 1
Analytical Lab
Page 13 of 76
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060095
2015017121
Collection Date: 02-Jun-15 11:44 AM
Site: MW-31C
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.016 mg-N/L EPA 353.2 06/08/2015 12:14 LSTARL10.01 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 11:29 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 16:15 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.083 mg/L EPA 200.7 06/04/2015 14:15 MHALL30.005 1
Barium (Ba)0.057 mg/L EPA 200.7 06/04/2015 14:15 MHALL30.005 1
Boron (B)1.18 mg/L EPA 200.7 06/04/2015 14:15 MHALL30.05 1
Iron (Fe)2.78 mg/L EPA 200.7 06/04/2015 14:15 MHALL30.01 1
Manganese (Mn)1.70 mg/L EPA 200.7 06/04/2015 14:15 MHALL30.005 1
Strontium (Sr)0.686 mg/L EPA 200.7 06/04/2015 14:15 MHALL30.005 1
Zinc (Zn)0.047 mg/L EPA 200.7 06/04/2015 14:15 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)53.1 mg/L EPA 200.7 06/05/2015 13:46 MHALL30.01 1
Magnesium (Mg)14.1 mg/L EPA 200.7 06/05/2015 13:46 MHALL30.005 1
Potassium (K)6.37 mg/L EPA 200.7 06/05/2015 13:46 MHALL30.1 1
Sodium (Na)77.9 mg/L EPA 200.7 06/05/2015 13:46 MHALL30.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.031 mg/L EPA 200.7 06/09/2015 11:24 MHH71310.005 1
Barium (Ba)0.054 mg/L EPA 200.7 06/09/2015 11:24 MHH71310.005 1
Boron (B)1.13 mg/L EPA 200.7 06/09/2015 11:24 MHH71310.05 1
Iron (Fe)2.96 mg/L EPA 200.7 06/09/2015 11:24 MHH71310.01 1
Manganese (Mn)1.64 mg/L EPA 200.7 06/09/2015 11:24 MHH71310.005 1
Strontium (Sr)0.648 mg/L EPA 200.7 06/09/2015 11:24 MHH71310.005 1
Zinc (Zn)0.048 mg/L EPA 200.7 06/09/2015 11:24 MHH71310.005 1
Analytical Lab
Page 14 of 76
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060095
2015017121
Collection Date: 02-Jun-15 11:44 AM
Site: MW-31C
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/17/2015 19:51 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 06/17/2015 19:51 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 06/17/2015 19:51 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 06/17/2015 19:51 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 06/17/2015 19:51 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 06/17/2015 19:51 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 06/17/2015 19:51 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 06/17/2015 19:51 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/17/2015 19:51 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 06/17/2015 19:51 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 06/17/2015 19:51 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/17/2015 19:51 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/17/2015 19:51 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/10/2015 15:04 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 06/10/2015 15:04 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 06/10/2015 15:04 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 06/10/2015 15:04 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 06/10/2015 15:04 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 06/10/2015 15:04 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 06/10/2015 15:04 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 06/10/2015 15:04 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/10/2015 15:04 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 06/10/2015 15:04 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 06/10/2015 15:04 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/10/2015 15:04 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/10/2015 15:04 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
Total Carbon
TOC 0.668 mg/L SM5310C/EPA9060A 06/08/2015 10:08 GHUTCHI0.1 1
Analytical Lab
Page 15 of 76
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060095
2015017122
Collection Date: 02-Jun-15 9:46 AM
Site: MW-12
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.018 mg-N/L EPA 353.2 06/08/2015 12:15 LSTARL10.01 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 11:31 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 16:18 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.072 mg/L EPA 200.7 06/04/2015 14:19 MHALL30.005 1
Barium (Ba)0.030 mg/L EPA 200.7 06/04/2015 14:19 MHALL30.005 1
Boron (B)1.49 mg/L EPA 200.7 06/04/2015 14:19 MHALL30.05 1
Iron (Fe)5.66 mg/L EPA 200.7 06/04/2015 14:19 MHALL30.01 1
Manganese (Mn)0.677 mg/L EPA 200.7 06/04/2015 14:19 MHALL30.005 1
Strontium (Sr)1.27 mg/L EPA 200.7 06/04/2015 14:19 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/04/2015 14:19 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)52.4 mg/L EPA 200.7 06/05/2015 13:50 MHALL30.01 1
Magnesium (Mg)10.2 mg/L EPA 200.7 06/05/2015 13:50 MHALL30.005 1
Potassium (K)9.09 mg/L EPA 200.7 06/05/2015 13:50 MHALL30.1 1
Sodium (Na)59.1 mg/L EPA 200.7 06/05/2015 13:50 MHALL30.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.015 mg/L EPA 200.7 06/09/2015 11:28 MHH71310.005 1
Barium (Ba)0.028 mg/L EPA 200.7 06/09/2015 11:28 MHH71310.005 1
Boron (B)1.45 mg/L EPA 200.7 06/09/2015 11:28 MHH71310.05 1
Iron (Fe)5.79 mg/L EPA 200.7 06/09/2015 11:28 MHH71310.01 1
Manganese (Mn)0.683 mg/L EPA 200.7 06/09/2015 11:28 MHH71310.005 1
Strontium (Sr)1.31 mg/L EPA 200.7 06/09/2015 11:28 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 11:28 MHH71310.005 1
Analytical Lab
Page 16 of 76
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060095
2015017122
Collection Date: 02-Jun-15 9:46 AM
Site: MW-12
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/17/2015 18:55 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 06/17/2015 18:55 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 06/17/2015 18:55 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 06/17/2015 18:55 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 06/17/2015 18:55 JAHERMA11
Cobalt (Co)1.21 ug/L EPA 200.8 06/17/2015 18:55 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 06/17/2015 18:55 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 06/17/2015 18:55 JAHERMA11
Molybdenum (Mo)15.9 ug/L EPA 200.8 06/17/2015 18:55 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 06/17/2015 18:55 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 06/17/2015 18:55 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/17/2015 18:55 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/17/2015 18:55 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/10/2015 15:09 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 06/10/2015 15:09 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 06/10/2015 15:09 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 06/10/2015 15:09 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 06/10/2015 15:09 JAHERMA11
Cobalt (Co)1.26 ug/L EPA 200.8 06/10/2015 15:09 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 06/10/2015 15:09 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 06/10/2015 15:09 JAHERMA11
Molybdenum (Mo)15.8 ug/L EPA 200.8 06/10/2015 15:09 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 06/10/2015 15:09 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 06/10/2015 15:09 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/10/2015 15:09 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/10/2015 15:09 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
Total Carbon
TOC 2.5 mg/L SM5310C/EPA9060A 06/08/2015 10:08 GHUTCHI0.1 1
Analytical Lab
Page 17 of 76
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060095
2015017123
Collection Date: 02-Jun-15 2:26 PM
Site: MW-23C
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 06/08/2015 12:20 LSTARL10.01 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 11:34 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 16:20 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.073 mg/L EPA 200.7 06/04/2015 14:22 MHALL30.005 1
Barium (Ba)0.035 mg/L EPA 200.7 06/04/2015 14:22 MHALL30.005 1
Boron (B)1.98 mg/L EPA 200.7 06/04/2015 14:22 MHALL30.05 1
Iron (Fe)0.031 mg/L EPA 200.7 06/04/2015 14:22 MHALL30.01 1
Manganese (Mn)0.280 mg/L EPA 200.7 06/04/2015 14:22 MHALL30.005 1
Strontium (Sr)1.47 mg/L EPA 200.7 06/04/2015 14:22 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/04/2015 14:22 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)46.3 mg/L EPA 200.7 06/05/2015 13:54 MHALL30.01 1
Magnesium (Mg)9.78 mg/L EPA 200.7 06/05/2015 13:54 MHALL30.005 1
Potassium (K)12.8 mg/L EPA 200.7 06/05/2015 13:54 MHALL30.1 1
Sodium (Na)22.1 mg/L EPA 200.7 06/05/2015 13:54 MHALL30.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.012 mg/L EPA 200.7 06/09/2015 11:32 MHH71310.005 1
Barium (Ba)0.034 mg/L EPA 200.7 06/09/2015 11:32 MHH71310.005 1
Boron (B)1.94 mg/L EPA 200.7 06/09/2015 11:32 MHH71310.05 1
Iron (Fe)0.076 mg/L EPA 200.7 06/09/2015 11:32 MHH71310.01 1
Manganese (Mn)0.287 mg/L EPA 200.7 06/09/2015 11:32 MHH71310.005 1
Strontium (Sr)1.52 mg/L EPA 200.7 06/09/2015 11:32 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 11:32 MHH71310.005 1
Analytical Lab
Page 18 of 76
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060095
2015017123
Collection Date: 02-Jun-15 2:26 PM
Site: MW-23C
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/17/2015 19:58 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 06/17/2015 19:58 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 06/17/2015 19:58 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 06/17/2015 19:58 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 06/17/2015 19:58 JAHERMA11
Cobalt (Co)3.79 ug/L EPA 200.8 06/17/2015 19:58 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 06/17/2015 19:58 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 06/17/2015 19:58 JAHERMA11
Molybdenum (Mo)368 ug/L EPA 200.8 06/17/2015 19:58 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 06/17/2015 19:58 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 06/17/2015 19:58 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/17/2015 19:58 JAHERMA0.2 1
Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 06/17/2015 19:58 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/10/2015 15:14 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 06/10/2015 15:14 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 06/10/2015 15:14 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 06/10/2015 15:14 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 06/10/2015 15:14 JAHERMA11
Cobalt (Co)4.83 ug/L EPA 200.8 06/10/2015 15:14 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 06/10/2015 15:14 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 06/10/2015 15:14 JAHERMA11
Molybdenum (Mo)371 ug/L EPA 200.8 06/10/2015 15:14 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 06/10/2015 15:14 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 06/10/2015 15:14 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/10/2015 15:14 JAHERMA0.2 1
Vanadium (V) Low Level 0.323 ug/L EPA 200.8 06/10/2015 15:14 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
Total Carbon
TOC 2.7 mg/L SM5310C/EPA9060A 06/08/2015 10:08 GHUTCHI0.1 1
Analytical Lab
Page 19 of 76
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060095
2015017124
Collection Date: 02-Jun-15 11:23 AM
Site: MW-24C
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.066 mg-N/L EPA 353.2 06/08/2015 12:23 LSTARL10.01 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 11:36 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/11/2015 12:25 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.037 mg/L EPA 200.7 06/04/2015 14:26 MHALL30.005 1
Barium (Ba)0.046 mg/L EPA 200.7 06/04/2015 14:26 MHALL30.005 1
Boron (B)0.415 mg/L EPA 200.7 06/04/2015 14:26 MHALL30.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 06/04/2015 14:26 MHALL30.01 1
Manganese (Mn)0.037 mg/L EPA 200.7 06/04/2015 14:26 MHALL30.005 1
Strontium (Sr)0.563 mg/L EPA 200.7 06/04/2015 14:26 MHALL30.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/04/2015 14:26 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)23.0 mg/L EPA 200.7 06/05/2015 13:58 MHALL30.01 1
Magnesium (Mg)6.11 mg/L EPA 200.7 06/05/2015 13:58 MHALL30.005 1
Potassium (K)3.84 mg/L EPA 200.7 06/05/2015 13:58 MHALL30.1 1
Sodium (Na)10.9 mg/L EPA 200.7 06/05/2015 13:58 MHALL30.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.005 mg/L EPA 200.7 06/09/2015 11:36 MHH71310.005 1
Barium (Ba)0.043 mg/L EPA 200.7 06/09/2015 11:36 MHH71310.005 1
Boron (B)0.405 mg/L EPA 200.7 06/09/2015 11:36 MHH71310.05 1
Iron (Fe)< 0.01 mg/L EPA 200.7 06/09/2015 11:36 MHH71310.01 1
Manganese (Mn)0.046 mg/L EPA 200.7 06/09/2015 11:36 MHH71310.005 1
Strontium (Sr)0.534 mg/L EPA 200.7 06/09/2015 11:36 MHH71310.005 1
Zinc (Zn)< 0.005 mg/L EPA 200.7 06/09/2015 11:36 MHH71310.005 1
Analytical Lab
Page 20 of 76
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060095
2015017124
Collection Date: 02-Jun-15 11:23 AM
Site: MW-24C
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)1.05 ug/L EPA 200.8 06/17/2015 20:05 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 06/17/2015 20:05 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 06/17/2015 20:05 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 06/17/2015 20:05 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 06/17/2015 20:05 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 06/17/2015 20:05 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 06/17/2015 20:05 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 06/17/2015 20:05 JAHERMA11
Molybdenum (Mo)92.5 ug/L EPA 200.8 06/17/2015 20:05 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 06/17/2015 20:05 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 06/17/2015 20:05 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/17/2015 20:05 JAHERMA0.2 1
Vanadium (V) Low Level 0.366 ug/L EPA 200.8 06/17/2015 20:05 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/10/2015 15:18 JAHERMA11
Arsenic (As)< 1 ug/L EPA 200.8 06/10/2015 15:18 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 06/10/2015 15:18 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 06/10/2015 15:18 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 06/10/2015 15:18 JAHERMA11
Cobalt (Co)< 1 ug/L EPA 200.8 06/10/2015 15:18 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 06/10/2015 15:18 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 06/10/2015 15:18 JAHERMA11
Molybdenum (Mo)94.3 ug/L EPA 200.8 06/10/2015 15:18 JAHERMA11
Nickel (Ni)< 1 ug/L EPA 200.8 06/10/2015 15:18 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 06/10/2015 15:18 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/10/2015 15:18 JAHERMA0.2 1
Vanadium (V) Low Level 0.543 ug/L EPA 200.8 06/10/2015 15:18 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
Total Carbon
TOC 1.7 mg/L SM5310C/EPA9060A 06/08/2015 10:08 GHUTCHI0.1 1
Analytical Lab
Page 21 of 76
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060095
2015017125
Collection Date: 02-Jun-15 9:50 AM
Site: MW-24B
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)0.015 mg-N/L EPA 353.2 06/08/2015 12:25 LSTARL10.01 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/05/2015 11:38 ACPAYNE0.05 1
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)< 0.05 ug/L EPA 245.1 06/10/2015 16:22 ACPAYNE0.05 1
DISSOLVED METALS BY ICP
Aluminum (Al)0.083 mg/L EPA 200.7 06/04/2015 14:30 MHALL30.005 1
Barium (Ba)0.040 mg/L EPA 200.7 06/04/2015 14:30 MHALL30.005 1
Boron (B)1.08 mg/L EPA 200.7 06/04/2015 14:30 MHALL30.05 1
Iron (Fe)2.83 mg/L EPA 200.7 06/04/2015 14:30 MHALL30.01 1
Manganese (Mn)0.868 mg/L EPA 200.7 06/04/2015 14:30 MHALL30.005 1
Strontium (Sr)0.599 mg/L EPA 200.7 06/04/2015 14:30 MHALL30.005 1
Zinc (Zn)0.055 mg/L EPA 200.7 06/04/2015 14:30 MHALL30.005 1
UNDIGESTED METALS BY ICP
Calcium (Ca)50.9 mg/L EPA 200.7 06/05/2015 14:02 MHALL30.01 1
Magnesium (Mg)13.2 mg/L EPA 200.7 06/05/2015 14:02 MHALL30.005 1
Potassium (K)6.03 mg/L EPA 200.7 06/05/2015 14:02 MHALL30.1 1
Sodium (Na)79.6 mg/L EPA 200.7 06/05/2015 14:02 MHALL30.05 1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)0.024 mg/L EPA 200.7 06/09/2015 11:40 MHH71310.005 1
Barium (Ba)0.038 mg/L EPA 200.7 06/09/2015 11:40 MHH71310.005 1
Boron (B)1.03 mg/L EPA 200.7 06/09/2015 11:40 MHH71310.05 1
Iron (Fe)3.56 mg/L EPA 200.7 06/09/2015 11:40 MHH71310.01 1
Manganese (Mn)1.04 mg/L EPA 200.7 06/09/2015 11:40 MHH71310.005 1
Strontium (Sr)0.568 mg/L EPA 200.7 06/09/2015 11:40 MHH71310.005 1
Zinc (Zn)0.058 mg/L EPA 200.7 06/09/2015 11:40 MHH71310.005 1
Analytical Lab
Page 22 of 76
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060095
2015017125
Collection Date: 02-Jun-15 9:50 AM
Site: MW-24B
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Antimony (Sb)< 1 ug/L EPA 200.8 06/17/2015 20:12 JAHERMA11
Arsenic (As)2.91 ug/L EPA 200.8 06/17/2015 20:12 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 06/17/2015 20:12 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 06/17/2015 20:12 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 06/17/2015 20:12 JAHERMA11
Cobalt (Co)14.0 ug/L EPA 200.8 06/17/2015 20:12 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 06/17/2015 20:12 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 06/17/2015 20:12 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/17/2015 20:12 JAHERMA11
Nickel (Ni)4.09 ug/L EPA 200.8 06/17/2015 20:12 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 06/17/2015 20:12 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/17/2015 20:12 JAHERMA0.2 1
Vanadium (V) Low Level 0.318 ug/L EPA 200.8 06/17/2015 20:12 JAHERMA0.3 1
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)< 1 ug/L EPA 200.8 06/10/2015 15:23 JAHERMA11
Arsenic (As)3.26 ug/L EPA 200.8 06/10/2015 15:23 JAHERMA11
Beryllium (Be)< 1 ug/L EPA 200.8 06/10/2015 15:23 JAHERMA11
Cadmium (Cd)< 1 ug/L EPA 200.8 06/10/2015 15:23 JAHERMA11
Chromium (Cr)< 1 ug/L EPA 200.8 06/10/2015 15:23 JAHERMA11
Cobalt (Co)17.9 ug/L EPA 200.8 06/10/2015 15:23 JAHERMA11
Copper (Cu)< 1 ug/L EPA 200.8 06/10/2015 15:23 JAHERMA11
Lead (Pb)< 1 ug/L EPA 200.8 06/10/2015 15:23 JAHERMA11
Molybdenum (Mo)< 1 ug/L EPA 200.8 06/10/2015 15:23 JAHERMA11
Nickel (Ni)4.65 ug/L EPA 200.8 06/10/2015 15:23 JAHERMA11
Selenium (Se)< 1 ug/L EPA 200.8 06/10/2015 15:23 JAHERMA11
Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 06/10/2015 15:23 JAHERMA0.2 1
Vanadium (V) Low Level 0.555 ug/L EPA 200.8 06/10/2015 15:23 JAHERMA0.3 1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4)Complete Vendor Method V_SHEALY
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete Vendor Method V_ELE1
Total Carbon
TOC 1.2 mg/L SM5310C/EPA9060A 06/08/2015 10:08 GHUTCHI0.1 1
Analytical Lab
Page 23 of 76
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060095
2015017126
Collection Date: 02-Jun-15 1:55 PM
Site: AW-8B
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
Analytical Lab
Page 24 of 76
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15060095
2015017129
Collection Date: 02-Jun-15 3:11 PM
Site: AW-8C
Matrix: GW_WW
Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult
Sample #:
AnalystDF
RADIOLOGICAL - (Analysis Performed by GEL)
Vendor Parameter Complete Vendor Method v_GEL
Analytical Lab
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Page 36 of 76

June 15, 2015

Mrs. Mary Ann Ogle
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Mail Code: MGO3A2
Huntersville, North Carolina 28078

Re: AB GW Assessment Water
Work Order: 374527
SDG: J15060095

Dear Mrs. :
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on June 05, 2015. This revised data report has been prepared and reviewed in accordance
with GEL’s standard operating procedures. Rev01: This data package is revised to include the correct Duke Job
number.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at [phone], ext. 4443.

Sincerely,

PM_SIGN_HERE
Lindsay Fabra
Project Manager

Purchase Order: 1142110
Enclosures
Page 1 of 12
Analytical Lab
Page 37 of 76
Reviewed by USER_SIGN_HERE
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Certificate of Analysis Report
DUPO002 Duke Energy
Client SDG: J15060095 GEL Work Order: 374527
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the ’U’ qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Lindsay Fabra.
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a Tracer compound
** Analyte is a surrogate compound
U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
for
Page 2 of 12
Analytical Lab
Page 38 of 76
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: June 15, 2015
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1483666
1483666
1483789
1483816
1001
0847
1610
0845
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
06/10/15
06/11/15
06/10/15
06/08/15
SKJ
SKJ
AXM6
CXP3
0.0002
0.00005
0.00005
0.00005
3.00
1.00
DF
1
1
1
1
Mrs. Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
374527001
Ground Water
02-JUN-15 13:55
05-JUN-15
2015017126 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"77.5 (15%-125%)
0.000067
0.00001
0.00001
0.00001
1.56
0.919
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 06/08/15 14836651545JP1
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.0000588
0.00
0.00
2.00E-06
0.872
1.65
NominalResult
RLDL
Notes:
Page 3 of 12
Analytical Lab
Page 39 of 76
Certificate of Analysis
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - [phone] - www.gel.com
Report Date: June 15, 2015
Metals Analysis-ICP-MS
Rad Gas Flow Proportional Counting
Rad Radium-226
Parameter Result UnitsQualifier Analyst Date Time
1483666
1483666
1483789
1483816
1002
0848
1610
0845
ug/mL
ug/mL
ug/mL
ug/mL
pCi/L
pCi/L
06/10/15
06/11/15
06/10/15
06/08/15
SKJ
SKJ
AXM6
CXP3
0.0002
0.00005
0.00005
0.00005
3.00
1.00
DF
1
1
1
1
Mrs. Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory Company :
13339 Hagers Ferry Road
Huntersville, North Carolina 28078
Address :
AB GW Assessment WaterProject:
374527002
Ground Water
02-JUN-15 15:11
05-JUN-15
2015017129 DUKE00225Project:
DUPO002Client ID:
Client
Mail Code: MGO3A2
Surrogate/Tracer Recovery Recovery%Test Acceptable Limits
Sample ID:
Receive Date:
Client Sample ID:
Matrix:
Collect Date:
Collector:
Batch
Barium-133 Tracer GFPC, Ra228, Liquid "As Received"80.7 (15%-125%)
0.000067
0.00001
0.00001
0.00001
1.59
0.695
The following Prep Methods were performed:
SW846 3010A SW 846 3010 Acid Digestion 06/08/15 14836651545JP1
Method Description Analyst Date Time Prep Batch
Method
The following Analytical Methods were performed:
1
2
3
4
Method Description
1
2
3
4
SW846 3010A/6020A
SW846 3010A/6020A
EPA 904.0/SW846 9320 Modified
EPA 903.1 Modified
Analyst Comments
U
U
U
U
U
U
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Radium-228
Radium-226
SW846 3010A/6020A Liquid "As Received"
GFPC, Ra228, Liquid "As Received"
Lucas Cell, Ra226, liquid "As Received"
0.0000513
0.00
0.00
1.00E-06
0.00531
0.301
NominalResult
RLDL
Notes:
Page 4 of 12
Analytical Lab
Page 40 of 76
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
1483666Batch
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Uranium-234
Uranium-236
Uranium-238
Uranium-238
Uranium-233
Uranium-234
Uranium-236
Uranium-233
Parmname
Mrs. Mary Ann Ogle Contact:
Duke Energy Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, North Carolina
June 15, 2015Report Date:
Units
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/mL
ug/L
Anlst Date Time
SKJ 06/11/15 10:01
06/11/15 07:39
06/11/15 07:37
06/11/15 08:45
06/11/15 08:44
06/11/15 07:36
06/11/15 07:41
06/11/15 10:02
06/11/15 10:03
QC
ND
ND
ND
ND
0.0528
0.000502
0.000529
0.0056
ND
ND
ND
ND
0.0529
0.000395
0.000415
0.0044
ND
NOM Sample
ND
ND
ND
ND
ND
ND
ND
ND
ND
Range
(80%-120%)
(80%-120%)
(80%-120%)
(80%-120%)
(75%-125%)
(75%-125%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
U
U
U
QC1203331839 374139001
QC1203331838
QC1203333067
QC1203331837
QC1203331840 374139001
QC1203333068 374139001
QC1203331841 374139001
N/A
N/A
N/A
N/A
N/A
REC%
106
100
96.2
112
106
79
75.5
87.9
0.0496
0.0005
0.00055
0.005
0.0496
0.0005
0.00055
0.005
DUP
LCS
LCS
MB
MS
MS
SDILT
374527Workorder:
Mail Code: MGO3A2
U
U
U
U
U
U
U
U
U
RPD%
Page 1 of 3
Page 5 of 12
Analytical Lab
Page 41 of 76
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Metals Analysis - ICPMS
Rad Gas Flow
Rad Ra-226
1483666
1483789
1483816
Batch
Batch
Batch
Uranium-234
Uranium-236
Uranium-238
Radium-228
Radium-228
Radium-228
Radium-226
Radium-226
Radium-226
Radium-226
Parmname Units
ug/L
ug/L
ug/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
pCi/L
Anlst Date Time
SKJ
AXM6
CXP3
06/11/15 10:03
06/11/15 07:42
06/10/15 16:10
06/10/15 16:10
06/10/15 16:10
06/08/15 09:25
06/11/15 11:20
06/11/15 11:20
06/08/15 09:25
QC
ND
ND
ND
0.824
24.9
0.530
1.33
29.5
0.574
23.8
NOM Sample
ND
ND
ND
0.538
1.65
1.65
Range
(0%-10%)
(0%-10%)
N/A
(75%-125%)
(0% - 100%)
(75%-125%)
(75%-125%)
Qual
U
U
U
U
U
U
QC1203332161 374528001
QC1203332162
QC1203332160
QC1203332252 374527001
QC1203332254
QC1203332251
QC1203332253 374527001
The Qualifiers in this report are defined as follows:
N/A
N/A
N/A
N/A
21.2
REC%
80.7
119
89.8
30.9
24.7
24.7
DUP
LCS
MB
DUP
LCS
MB
MS
374527Workorder:
**
<
>
BD
E
FA
FB
H
Analyte is a Tracer compound
Result is less than value reported
Result is greater than value reported
Results are either below the MDC or tracer recovery is low
%difference of sample and SD is >10%. Sample concentration must meet flagging criteria
Failed analysis.
Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
Analytical holding time was exceeded
U
U
U
U
RPD%
Notes:
Page 2 of 3
Page 6 of 12
Analytical Lab
Page 42 of 76
QC Summary
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - [phone] - www.gel.com
Parmname
Page 3 of 3
Units Anlst Date TimeQCNOMSampleRangeQualREC%
374527Workorder:
J
K
L
M
M
N
N/A
N1
ND
NJ
Q
R
U
UI
UJ
UL
X
Y
^
h
Value is estimated
Analyte present. Reported value may be biased high. Actual value is expected to be lower.
Analyte present. Reported value may be biased low. Actual value is expected to be higher.
M if above MDC and less than LLD
REMP Result > MDC/CL and < RDL
Metals--The Matrix spike sample recovery is not within specified control limits
RPD or %Recovery limits do not apply.
See case narrative
Analyte concentration is not detected above the detection limit
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
Sample results are rejected
Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
Gamma Spectroscopy--Uncertain identification
Gamma Spectroscopy--Uncertain identification
Not considered detected. The associated number is the reported concentration, which may be inaccurate due to a low bias.
Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Other specific qualifiers were required to properly define the results. Consult case narrative.
RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more or %RPD not applicable.
^ The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
RPD%
Page 7 of 12
Analytical Lab
Page 43 of 76
Page 8 of 12
Analytical Lab
Page 44 of 76
Page 9 of 12
Analytical Lab
Page 45 of 76
Page 10 of 12
Analytical Lab
Page 46 of 76
State Certification
Alaska
Arkansas
CLIA
California
Colorado
Connecticut
Delaware
DoD ELAP/ ISO17025 A2LA
Florida NELAP
Foreign Soils Permit
Georgia
Georgia SDWA
Hawaii
Idaho Chemistry
Idaho Radiochemistry
Illinois NELAP
Indiana
Kansas NELAP
Kentucky SDWA
Kentucky Wastewater
Louisiana NELAP
Louisiana SDWA
Maryland
Massachusetts
Michigan
Mississippi
Nebraska
Nevada
New Hampshire NELAP
New Jersey NELAP
New Mexico
New York NELAP
North Carolina
North Carolina SDWA
Oklahoma
Pennsylvania NELAP
Plant Material Permit
S.Carolina Radchem
South Carolina Chemistry
Tennessee
Texas NELAP
Utah NELAP
Vermont
Virginia NELAP
Washington
West Virginia
UST-110
88-0651
42D0904046
2940 Interim
SC00012
PH-0169
SC000122013-10
2567.01
E87156
P330-12-00283, P330-12-00284
SC00012
967
SC000122013-10
SC00012
SC00012
200029
C-SC-01
E-10332
90129
90129
03046 (AI33904)
LA150001
270
M-SC012
9976
SC000122013-10
NE-OS-26-13
SC000122014-1
2054
SC002
SC00012
11501
233
45709
9904
68-00485
PDEP-12-00260
10120002
10120001
TN 02934
T104704235-15-10
SC000122015-17
VT87156
460202
C780
997404
List of current GEL Certifications as of 15 June 2015
Page 11 of 12
Analytical Lab
Page 47 of 76
There are no "Data Exception Reports" associated with this analytical report.
Page 12 of 12
Analytical Lab
Page 48 of 76
SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
QF04085Lot Number:
J15060095Project Number:
AB GW Assessment Water - SuttonProject Name:
06/15/2015Date Completed:
Grant Wilton
Project Manager
*QF04085*

This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
Page: 1 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
Case Narrative
Duke Energy
Lot Number: QF04085
SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page.
Page: 2 of 16
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Shealy Environmental Services, Inc.
Level 1 Report v2.1
SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QF04085

Sample Number Sample ID Matrix Date Sampled Date Received
001 06/02/2015 14382015017116Aqueous 06/04/2015
002 06/02/2015 14562015017117Aqueous 06/04/2015
003 06/02/2015 13452015017118Aqueous 06/04/2015
004 06/02/2015 10122015017119Aqueous 06/04/2015
005 06/02/2015 11582015017120Aqueous 06/04/2015
006 06/02/2015 11442015017121Aqueous 06/04/2015
007 06/02/2015 09462015017122Aqueous 06/04/2015
008 06/02/2015 14262015017123Aqueous 06/04/2015
009 06/02/2015 11232015017124Aqueous 06/04/2015
010 06/02/2015 09502015017125Aqueous 06/04/2015
(10 samples)
Page: 3 of 16
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Shealy Environmental Services, Inc.
Level 1 Report v2.1
SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QF04085

Sample Sample ID Matrix Parameter Method Result Q Units Page
005 2015017120 Aqueous Methane RSK - 175 29 ug/L 11
006 2015017121 Aqueous Methane RSK - 175 17 ug/L 12
007 2015017122 Aqueous Methane RSK - 175 13 ug/L 13
009 2015017124 Aqueous Methane RSK - 175 26 ug/L 15
(4 detections)
Page: 4 of 16
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Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015017116
QF04085-001
06/02/2015 1438
06/04/2015
Aqueous
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 06/09/2015 2205 HMA 76879
1 (Bicarbonate ) SM 2320B-2011 1 06/09/2015 2205 HMA
1 (Carbonate Al) SM 2320B-2011 1 06/09/2015 2205 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 ND 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 5 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015017116
QF04085-001
06/02/2015 1438
06/04/2015
Aqueous
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/10/2015 2112 JJG 77026
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 6 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015017117
QF04085-002
06/02/2015 1456
06/04/2015
Aqueous
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 06/09/2015 2209 HMA 76879
1 (Bicarbonate ) SM 2320B-2011 1 06/09/2015 2209 HMA
1 (Carbonate Al) SM 2320B-2011 1 06/09/2015 2209 HMA
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Alkalinity SM 2320B-20 ND 1mg/L10
Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10
Carbonate Alkalinity SM 2320B-20 ND 1mg/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 7 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015017117
QF04085-002
06/02/2015 1456
06/04/2015
Aqueous
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/10/2015 2136 JJG 77026
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 8 of 16
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Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015017118
QF04085-003
06/02/2015 1345
06/04/2015
Aqueous
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/10/2015 2200 JJG 77026
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 9 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015017119
QF04085-004
06/02/2015 1012
06/04/2015
Aqueous
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/10/2015 2212 JJG 77026
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 10 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015017120
QF04085-005
06/02/2015 1158
06/04/2015
Aqueous
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/10/2015 2226 JJG 77026
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 29 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 11 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015017121
QF04085-006
06/02/2015 1144
06/04/2015
Aqueous
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/10/2015 2244 JJG 77026
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 17 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 12 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015017122
QF04085-007
06/02/2015 0946
06/04/2015
Aqueous
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/10/2015 2308 JJG 77026
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 13 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 13 of 16
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Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015017123
QF04085-008
06/02/2015 1426
06/04/2015
Aqueous
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/10/2015 2321 JJG 77026
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 14 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015017124
QF04085-009
06/02/2015 1123
06/04/2015
Aqueous
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/11/2015 0954 DCS 77071
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 26 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 15 of 16
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Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane
Description:Matrix:
Date Received:
Client:Laboratory ID:
Date Sampled:
Duke Energy
2015017125
QF04085-010
06/02/2015 0950
06/04/2015
Aqueous
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/11/2015 1004 DCS 77071
AnalyticalCAS
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 1ug/L10
J = Estimated result < PQL and > MDL
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria_
H = Out of holding time
Page: 16 of 16
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Shealy Environmental Services, Inc.
Level 1 Report v2.1
QC Summary
QC Data for Lot Number: QF04085
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Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals - MB
Batch:
Sample ID:QQ76879-001
76879
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Alkalinity ND 06/09/2015 204510mg/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF04085
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Shealy Environmental Services, Inc.
Level 1 Report v2.1
Inorganic non-metals - LCS
Batch:
Sample ID:QQ76879-002
76879
Analytical Method:SM 2320B-2011
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(mg/L)(mg/L)
Alkalinity 99 06/09/2015 20519910090-1101
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF04085
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Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - MB
Batch:
Sample ID:QQ77026-001
77026
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Methane ND 06/10/2015 191310ug/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF04085
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - LCS
Batch:
Sample ID:QQ77026-002
77026
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
Methane 47 06/10/2015 1705945070-1301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF04085
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - LCSD
Batch:
Sample ID:QQ77026-003
77026
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
LimitDil(ug/L)(ug/L)
Methane 39 06/10/2015 1717765070-13021 301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF04085
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Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - MB
Batch:
Sample ID:QQ77071-001
77071
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter Result Q PQL Units Analysis DateDil
Methane ND 06/11/2015 094210ug/L1
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF04085
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - LCS
Batch:
Sample ID:QQ77071-002
77071
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date
% Rec
LimitDil(ug/L)(ug/L)
Methane 46 06/11/2015 0905925070-1301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF04085
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Methane - LCSD
Batch:
Sample ID:QQ77071-003
77071
Analytical Method:RSK - 175
Matrix:Aqueous
Parameter
Result
Q % Rec
Spike
Amount
Analysis Date% RPD
% Rec
Limit
% RPD
LimitDil(ug/L)(ug/L)
Methane 46 06/11/2015 0920915070-1301.2 301
Note:Calculations are performed before rounding to avoid round-off errors in calculated results
PQL = Practical quantitation limit
ND = Not detected at or above the PQL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
J = Estimated result < PQL and > MDL
N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40%
+ = RPD is out of criteria_
QC Data for Lot Number: QF04085
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
SHEALY ENVIRONMENTAL SERVICES, INC.

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
SHEALY ENVIRONMENTAL SERVICES, INC.

106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Shealy Environmental Services, Inc.
Level 1 Report v2.1
Analytical Lab
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