Loading...
HomeMy WebLinkAboutNC0001422_ATT 5 - Water - J15040754report_2015080513339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number: J15040754 Project Name:SUTTON - AB GW ASSESSMENT WATER Lab Contact:Mary Ann Ogle Date:5/20/2015 Customer Address: Customer Name(s): Perry Waldrep, Tim Hunsucker, Kathy Webb, John Toepfer Phone: 980-875-5274 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Mary Ann Ogle Analytical Lab Page 1 of 86 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015012746 Sutton 28-Apr-15 8:55 AM ILLEGIBLE SMW-4B 2015012747 Sutton 28-Apr-15 9:42 AM ILLEGIBLE SMW-4C 2015012748 Sutton 28-Apr-15 12:55 PM ILLEGIBLE SMW-5B 2015012749 Sutton 28-Apr-15 11:08 AM ILLEGIBLE Smw-5C 2015012750 Sutton 28-Apr-15 4:48 PM ILLEGIBLE ABMW-1S 2015012751 Sutton 28-Apr-15 3:35 PM ILLEGIBLE ABMW-1D 2015012752 Sutton 29-Apr-15 11:26 AM ILLEGIBLE SMW-6B 2015012753 Sutton 29-Apr-15 1:25 PM ILLEGIBLE SMW-6C 2015012754 Sutton 29-Apr-15 12:20 PM ILLEGIBLE SMW-6D 2015012755 Sutton 29-Apr-15 3:05 PM ILLEGIBLE AW-7B/MW-31B 2015012756 Sutton 29-Apr-15 4:28 PM ILLEGIBLE ABMW-2S 2015012757 Sutton 28-Apr-15 8:25 AM ILLEGIBLE Filter Blank 2015012758 Sutton 28-Apr-15 8:25 AM ILLEGIBLE Equipment Blank 2015012759 Sutton 29-Apr-15 1:45 PM ILLEGIBLE Filter Blank 2015012760 Sutton 29-Apr-15 1:45 PM ILLEGIBLE Equipment Blank 2015012761 Sutton 29-Apr-15 12:00 PM ILLEGIBLE SMW-6B DUP 16 Total Samples Analytical Lab Page 2 of 86 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:Peggy Kendall Date:5/20/2015 Electronic Data Deliverable (EDD) Sent Separately Analytical Lab Page 3 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012746 Collection Date: 28-Apr-15 8:55 AM Site: SMW-4B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/30/2015 13:26 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 4.9 mg/L EPA 300.0 05/04/2015 13:53 BGN90340.1 1 Sulfate 14 mg/L EPA 300.0 05/04/2015 13:53 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 12:26 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 14:42 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.016 mg/L EPA 200.7 04/30/2015 14:35 MHALL30.005 1 Barium (Ba)0.021 mg/L EPA 200.7 04/30/2015 14:35 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 04/30/2015 14:35 MHALL30.05 1 Iron (Fe)0.945 mg/L EPA 200.7 04/30/2015 14:35 MHALL30.01 1 Manganese (Mn)0.059 mg/L EPA 200.7 04/30/2015 14:35 MHALL30.005 1 Strontium (Sr)0.025 mg/L EPA 200.7 04/30/2015 14:35 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 04/30/2015 14:35 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)11.0 mg/L EPA 200.7 04/30/2015 14:35 MHALL30.01 1 Magnesium (Mg)0.811 mg/L EPA 200.7 04/30/2015 14:35 MHALL30.005 1 Potassium (K)0.996 mg/L EPA 200.7 04/30/2015 14:35 MHALL30.1 1 Sodium (Na)7.64 mg/L EPA 200.7 04/30/2015 14:35 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.281 mg/L EPA 200.7 05/04/2015 11:51 MHALL30.005 1 Barium (Ba)0.028 mg/L EPA 200.7 05/04/2015 11:51 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 05/04/2015 11:51 MHALL30.05 1 Iron (Fe)1.31 mg/L EPA 200.7 05/04/2015 11:51 MHALL30.01 1 Manganese (Mn)0.073 mg/L EPA 200.7 05/04/2015 11:51 MHALL30.005 1 Strontium (Sr)0.033 mg/L EPA 200.7 05/04/2015 11:51 MHALL30.005 1 Zinc (Zn)0.005 mg/L EPA 200.7 05/04/2015 11:51 MHALL30.005 1 Analytical Lab Page 4 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012746 Collection Date: 28-Apr-15 8:55 AM Site: SMW-4B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/13/2015 14:51 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 05/13/2015 14:51 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/13/2015 14:51 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/13/2015 14:51 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/13/2015 14:51 JAHERMA11 Cobalt (Co)1.04 ug/L EPA 200.8 05/13/2015 14:51 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/13/2015 14:51 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/13/2015 14:51 JAHERMA11 Molybdenum (Mo)7.00 ug/L EPA 200.8 05/13/2015 14:51 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/13/2015 14:51 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/13/2015 14:51 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/13/2015 14:51 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 05/13/2015 14:51 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/08/2015 12:59 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 05/08/2015 12:59 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/08/2015 12:59 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/08/2015 12:59 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/08/2015 12:59 JAHERMA11 Cobalt (Co)1.17 ug/L EPA 200.8 05/08/2015 12:59 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/08/2015 12:59 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/08/2015 12:59 JAHERMA11 Molybdenum (Mo)8.74 ug/L EPA 200.8 05/08/2015 12:59 JAHERMA11 Nickel (Ni)1.14 ug/L EPA 200.8 05/08/2015 12:59 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/08/2015 12:59 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/08/2015 12:59 JAHERMA0.2 1 Vanadium (V) Low Level 0.466 ug/L EPA 200.8 05/08/2015 12:59 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 64 mg/L SM2540C 05/04/2015 15:01 AGIBBS5251 Total Carbon TOC 1.2 mg/L SM5310C/EPA9060A 05/05/2015 13:25 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS 16 mg/L SM2540D 05/04/2015 10:05 AGIBBS551 Analytical Lab Page 5 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012747 Collection Date: 28-Apr-15 9:42 AM Site: SMW-4C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.017 mg-N/L EPA 353.2 04/30/2015 13:27 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 18 mg/L EPA 300.0 05/04/2015 12:23 BGN9034110 Sulfate 30 mg/L EPA 300.0 05/04/2015 12:23 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 12:29 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 14:44 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.014 mg/L EPA 200.7 04/30/2015 14:50 MHALL30.005 1 Barium (Ba)0.011 mg/L EPA 200.7 04/30/2015 14:50 MHALL30.005 1 Boron (B)0.096 mg/L EPA 200.7 04/30/2015 14:50 MHALL30.05 1 Iron (Fe)3.43 mg/L EPA 200.7 04/30/2015 14:50 MHALL30.01 1 Manganese (Mn)0.184 mg/L EPA 200.7 04/30/2015 14:50 MHALL30.005 1 Strontium (Sr)0.045 mg/L EPA 200.7 04/30/2015 14:50 MHALL30.005 1 Zinc (Zn)0.014 mg/L EPA 200.7 04/30/2015 14:50 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)9.00 mg/L EPA 200.7 04/30/2015 14:50 MHALL30.01 1 Magnesium (Mg)3.17 mg/L EPA 200.7 04/30/2015 14:50 MHALL30.005 1 Potassium (K)0.775 mg/L EPA 200.7 04/30/2015 14:50 MHALL30.1 1 Sodium (Na)39.4 mg/L EPA 200.7 04/30/2015 14:50 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)1.31 mg/L EPA 200.7 05/04/2015 11:55 MHALL30.005 1 Barium (Ba)0.019 mg/L EPA 200.7 05/04/2015 11:55 MHALL30.005 1 Boron (B)0.103 mg/L EPA 200.7 05/04/2015 11:55 MHALL30.05 1 Iron (Fe)4.99 mg/L EPA 200.7 05/04/2015 11:55 MHALL30.01 1 Manganese (Mn)0.220 mg/L EPA 200.7 05/04/2015 11:55 MHALL30.005 1 Strontium (Sr)0.056 mg/L EPA 200.7 05/04/2015 11:55 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 05/04/2015 11:55 MHALL30.005 1 Analytical Lab Page 6 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012747 Collection Date: 28-Apr-15 9:42 AM Site: SMW-4C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/13/2015 14:56 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 05/13/2015 14:56 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/13/2015 14:56 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/13/2015 14:56 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/13/2015 14:56 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/13/2015 14:56 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/13/2015 14:56 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/13/2015 14:56 JAHERMA11 Molybdenum (Mo)7.07 ug/L EPA 200.8 05/13/2015 14:56 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/13/2015 14:56 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/13/2015 14:56 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/13/2015 14:56 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 05/13/2015 14:56 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/08/2015 13:03 JAHERMA11 Arsenic (As)1.09 ug/L EPA 200.8 05/08/2015 13:03 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/08/2015 13:03 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/08/2015 13:03 JAHERMA11 Chromium (Cr)1.03 ug/L EPA 200.8 05/08/2015 13:03 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/08/2015 13:03 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/08/2015 13:03 JAHERMA11 Lead (Pb)1.29 ug/L EPA 200.8 05/08/2015 13:03 JAHERMA11 Molybdenum (Mo)6.23 ug/L EPA 200.8 05/08/2015 13:03 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/08/2015 13:03 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/08/2015 13:03 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/08/2015 13:03 JAHERMA0.2 1 Vanadium (V) Low Level 0.825 ug/L EPA 200.8 05/08/2015 13:03 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 210 mg/L SM2540C 05/04/2015 15:01 AGIBBS51001 Total Carbon TOC 3.2 mg/L SM5310C/EPA9060A 05/05/2015 13:25 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS 72 mg/L SM2540D 05/04/2015 10:05 AGIBBS591 Analytical Lab Page 7 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012748 Collection Date: 28-Apr-15 12:55 PM Site: SMW-5B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.036 mg-N/L EPA 353.2 04/30/2015 13:36 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 12 mg/L EPA 300.0 05/04/2015 12:41 BGN9034110 Sulfate 41 mg/L EPA 300.0 05/04/2015 12:41 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 12:31 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 14:46 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.057 mg/L EPA 200.7 04/30/2015 14:46 MHALL30.005 1 Barium (Ba)0.036 mg/L EPA 200.7 04/30/2015 14:46 MHALL30.005 1 Boron (B)0.095 mg/L EPA 200.7 04/30/2015 14:46 MHALL30.05 1 Iron (Fe)20.7 mg/L EPA 200.7 04/30/2015 14:46 MHALL30.01 1 Manganese (Mn)0.236 mg/L EPA 200.7 04/30/2015 14:46 MHALL30.005 1 Strontium (Sr)0.078 mg/L EPA 200.7 04/30/2015 14:46 MHALL30.005 1 Zinc (Zn)0.015 mg/L EPA 200.7 04/30/2015 14:46 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)17.8 mg/L EPA 200.7 04/30/2015 14:46 MHALL30.01 1 Magnesium (Mg)2.30 mg/L EPA 200.7 04/30/2015 14:46 MHALL30.005 1 Potassium (K)3.44 mg/L EPA 200.7 04/30/2015 14:46 MHALL30.1 1 Sodium (Na)6.40 mg/L EPA 200.7 04/30/2015 14:46 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.066 mg/L EPA 200.7 05/04/2015 11:59 MHALL30.005 1 Barium (Ba)0.036 mg/L EPA 200.7 05/04/2015 11:59 MHALL30.005 1 Boron (B)0.087 mg/L EPA 200.7 05/04/2015 11:59 MHALL30.05 1 Iron (Fe)19.7 mg/L EPA 200.7 05/04/2015 11:59 MHALL30.01 1 Manganese (Mn)0.222 mg/L EPA 200.7 05/04/2015 11:59 MHALL30.005 1 Strontium (Sr)0.075 mg/L EPA 200.7 05/04/2015 11:59 MHALL30.005 1 Zinc (Zn)0.013 mg/L EPA 200.7 05/04/2015 11:59 MHALL30.005 1 Analytical Lab Page 8 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012748 Collection Date: 28-Apr-15 12:55 PM Site: SMW-5B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/13/2015 15:00 JAHERMA11 Arsenic (As)1.54 ug/L EPA 200.8 05/13/2015 15:00 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/13/2015 15:00 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/13/2015 15:00 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/13/2015 15:00 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/13/2015 15:00 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/13/2015 15:00 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/13/2015 15:00 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 05/13/2015 15:00 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/13/2015 15:00 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/13/2015 15:00 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/13/2015 15:00 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 05/13/2015 15:00 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/08/2015 13:08 JAHERMA11 Arsenic (As)1.70 ug/L EPA 200.8 05/08/2015 13:08 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/08/2015 13:08 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/08/2015 13:08 JAHERMA11 Chromium (Cr)1.01 ug/L EPA 200.8 05/08/2015 13:08 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/08/2015 13:08 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/08/2015 13:08 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/08/2015 13:08 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 05/08/2015 13:08 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/08/2015 13:08 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/08/2015 13:08 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/08/2015 13:08 JAHERMA0.2 1 Vanadium (V) Low Level 0.629 ug/L EPA 200.8 05/08/2015 13:08 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 140 mg/L SM2540C 05/04/2015 15:01 AGIBBS5251 Total Carbon TOC 7.9 mg/L SM5310C/EPA9060A 05/05/2015 13:25 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS 9.0 mg/L SM2540D 05/04/2015 10:05 AGIBBS551 Analytical Lab Page 9 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012749 Collection Date: 28-Apr-15 11:08 AM Site: Smw-5C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.010 mg-N/L EPA 353.2 04/30/2015 13:37 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 28 mg/L EPA 300.0 05/05/2015 17:27 BGN9034110 Sulfate 46 mg/L EPA 300.0 05/05/2015 17:27 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 12:33 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 14:49 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.009 mg/L EPA 200.7 04/30/2015 14:42 MHALL30.005 1 Barium (Ba)0.081 mg/L EPA 200.7 04/30/2015 14:42 MHALL30.005 1 Boron (B)0.347 mg/L EPA 200.7 04/30/2015 14:42 MHALL30.05 1 Iron (Fe)1.88 mg/L EPA 200.7 04/30/2015 14:42 MHALL30.01 1 Manganese (Mn)0.367 mg/L EPA 200.7 04/30/2015 14:42 MHALL30.005 1 Strontium (Sr)0.245 mg/L EPA 200.7 04/30/2015 14:42 MHALL30.005 1 Zinc (Zn)0.014 mg/L EPA 200.7 04/30/2015 14:42 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)15.3 mg/L EPA 200.7 04/30/2015 14:42 MHALL30.01 1 Magnesium (Mg)3.39 mg/L EPA 200.7 04/30/2015 14:42 MHALL30.005 1 Potassium (K)2.50 mg/L EPA 200.7 04/30/2015 14:42 MHALL30.1 1 Sodium (Na)16.4 mg/L EPA 200.7 04/30/2015 14:42 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.023 mg/L EPA 200.7 05/04/2015 12:03 MHALL30.005 1 Barium (Ba)0.082 mg/L EPA 200.7 05/04/2015 12:03 MHALL30.005 1 Boron (B)0.347 mg/L EPA 200.7 05/04/2015 12:03 MHALL30.05 1 Iron (Fe)1.89 mg/L EPA 200.7 05/04/2015 12:03 MHALL30.01 1 Manganese (Mn)0.350 mg/L EPA 200.7 05/04/2015 12:03 MHALL30.005 1 Strontium (Sr)0.240 mg/L EPA 200.7 05/04/2015 12:03 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 05/04/2015 12:03 MHALL30.005 1 Analytical Lab Page 10 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012749 Collection Date: 28-Apr-15 11:08 AM Site: Smw-5C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/13/2015 15:05 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 05/13/2015 15:05 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/13/2015 15:05 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/13/2015 15:05 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/13/2015 15:05 JAHERMA11 Cobalt (Co)11.2 ug/L EPA 200.8 05/13/2015 15:05 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/13/2015 15:05 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/13/2015 15:05 JAHERMA11 Molybdenum (Mo)1.42 ug/L EPA 200.8 05/13/2015 15:05 JAHERMA11 Nickel (Ni)2.97 ug/L EPA 200.8 05/13/2015 15:05 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/13/2015 15:05 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/13/2015 15:05 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 05/13/2015 15:05 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/08/2015 13:13 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 05/08/2015 13:13 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/08/2015 13:13 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/08/2015 13:13 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/08/2015 13:13 JAHERMA11 Cobalt (Co)11.4 ug/L EPA 200.8 05/08/2015 13:13 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/08/2015 13:13 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/08/2015 13:13 JAHERMA11 Molybdenum (Mo)1.27 ug/L EPA 200.8 05/08/2015 13:13 JAHERMA11 Nickel (Ni)2.89 ug/L EPA 200.8 05/08/2015 13:13 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/08/2015 13:13 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/08/2015 13:13 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 05/08/2015 13:13 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 130 mg/L SM2540C 05/04/2015 15:01 AGIBBS5251 Total Carbon TOC 0.435 mg/L SM5310C/EPA9060A 05/05/2015 13:25 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 05/04/2015 10:05 AGIBBS551 Analytical Lab Page 11 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012750 Collection Date: 28-Apr-15 4:48 PM Site: ABMW-1S Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/30/2015 13:32 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 81 mg/L EPA 300.0 05/05/2015 17:46 BGN9034110 Sulfate 99 mg/L EPA 300.0 05/05/2015 17:46 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 12:36 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 14:51 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.070 mg/L EPA 200.7 04/30/2015 13:45 MHALL30.005 1 Barium (Ba)0.578 mg/L EPA 200.7 04/30/2015 13:45 MHALL30.005 1 Boron (B)3.87 mg/L EPA 200.7 04/30/2015 13:45 MHALL30.05 1 Iron (Fe)0.162 mg/L EPA 200.7 04/30/2015 13:45 MHALL30.01 1 Manganese (Mn)0.107 mg/L EPA 200.7 04/30/2015 13:45 MHALL30.005 1 Strontium (Sr)6.10 mg/L EPA 200.7 04/30/2015 13:45 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 04/30/2015 13:45 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)122 mg/L EPA 200.7 04/30/2015 13:45 MHALL30.1 10 Magnesium (Mg)49.1 mg/L EPA 200.7 04/30/2015 13:45 MHALL30.05 10 Potassium (K)14.7 mg/L EPA 200.7 04/30/2015 13:45 MHALL30.1 1 Sodium (Na)55.7 mg/L EPA 200.7 04/30/2015 13:45 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.225 mg/L EPA 200.7 05/04/2015 12:14 MHALL30.005 1 Barium (Ba)0.597 mg/L EPA 200.7 05/04/2015 12:14 MHALL30.005 1 Boron (B)3.96 mg/L EPA 200.7 05/04/2015 12:14 MHALL30.05 1 Iron (Fe)0.277 mg/L EPA 200.7 05/04/2015 12:14 MHALL30.01 1 Manganese (Mn)0.108 mg/L EPA 200.7 05/04/2015 12:14 MHALL30.005 1 Strontium (Sr)6.18 mg/L EPA 200.7 05/04/2015 12:14 MHALL30.005 1 Zinc (Zn)0.037 mg/L EPA 200.7 05/04/2015 12:14 MHALL30.005 1 Analytical Lab Page 12 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012750 Collection Date: 28-Apr-15 4:48 PM Site: ABMW-1S Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/13/2015 18:53 JAHERMA11 Arsenic (As)737 ug/L EPA 200.8 05/13/2015 18:53 JAHERMA55 Beryllium (Be)< 1 ug/L EPA 200.8 05/13/2015 18:53 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/13/2015 18:53 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/13/2015 18:53 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/13/2015 18:53 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/13/2015 18:53 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/13/2015 18:53 JAHERMA11 Molybdenum (Mo)179 ug/L EPA 200.8 05/13/2015 18:53 JAHERMA11 Nickel (Ni)1.24 ug/L EPA 200.8 05/13/2015 18:53 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/13/2015 18:53 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/13/2015 18:53 JAHERMA0.2 1 Vanadium (V) Low Level 6.95 ug/L EPA 200.8 05/13/2015 18:53 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/08/2015 13:17 JAHERMA11 Arsenic (As)858 ug/L EPA 200.8 05/08/2015 13:17 JAHERMA55 Beryllium (Be)< 1 ug/L EPA 200.8 05/08/2015 13:17 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/08/2015 13:17 JAHERMA11 Chromium (Cr)1.71 ug/L EPA 200.8 05/08/2015 13:17 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/08/2015 13:17 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/08/2015 13:17 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/08/2015 13:17 JAHERMA11 Molybdenum (Mo)190 ug/L EPA 200.8 05/08/2015 13:17 JAHERMA11 Nickel (Ni)1.69 ug/L EPA 200.8 05/08/2015 13:17 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/08/2015 13:17 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/08/2015 13:17 JAHERMA0.2 1 Vanadium (V) Low Level 8.72 ug/L EPA 200.8 05/08/2015 13:17 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 760 mg/L SM2540C 05/04/2015 15:01 AGIBBS55001 Total Carbon TOC 3.1 mg/L SM5310C/EPA9060A 05/05/2015 13:25 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS 6.0 mg/L SM2540D 05/04/2015 10:05 AGIBBS551 Analytical Lab Page 13 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012751 Collection Date: 28-Apr-15 3:35 PM Site: ABMW-1D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/30/2015 13:38 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 51 mg/L EPA 300.0 05/05/2015 18:05 BGN9034110 Sulfate 33 mg/L EPA 300.0 05/05/2015 18:05 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 12:38 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 14:53 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.014 mg/L EPA 200.7 04/30/2015 14:01 MHALL30.005 1 Barium (Ba)0.014 mg/L EPA 200.7 04/30/2015 14:01 MHALL30.005 1 Boron (B)0.158 mg/L EPA 200.7 04/30/2015 14:01 MHALL30.05 1 Iron (Fe)0.097 mg/L EPA 200.7 04/30/2015 14:01 MHALL30.01 1 Manganese (Mn)0.039 mg/L EPA 200.7 04/30/2015 14:01 MHALL30.005 1 Strontium (Sr)0.153 mg/L EPA 200.7 04/30/2015 14:01 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 04/30/2015 14:01 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)26.0 mg/L EPA 200.7 04/30/2015 14:01 MHALL30.01 1 Magnesium (Mg)8.38 mg/L EPA 200.7 04/30/2015 14:01 MHALL30.005 1 Potassium (K)5.76 mg/L EPA 200.7 04/30/2015 14:01 MHALL30.1 1 Sodium (Na)54.9 mg/L EPA 200.7 04/30/2015 14:01 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.071 mg/L EPA 200.7 05/04/2015 12:25 MHALL30.005 1 Barium (Ba)0.016 mg/L EPA 200.7 05/04/2015 12:25 MHALL30.005 1 Boron (B)0.166 mg/L EPA 200.7 05/04/2015 12:25 MHALL30.05 1 Iron (Fe)0.227 mg/L EPA 200.7 05/04/2015 12:25 MHALL30.01 1 Manganese (Mn)0.040 mg/L EPA 200.7 05/04/2015 12:25 MHALL30.005 1 Strontium (Sr)0.155 mg/L EPA 200.7 05/04/2015 12:25 MHALL30.005 1 Zinc (Zn)0.029 mg/L EPA 200.7 05/04/2015 12:25 MHALL30.005 1 Analytical Lab Page 14 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012751 Collection Date: 28-Apr-15 3:35 PM Site: ABMW-1D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/13/2015 15:32 JAHERMA11 Arsenic (As)2.57 ug/L EPA 200.8 05/13/2015 15:32 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/13/2015 15:32 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/13/2015 15:32 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/13/2015 15:32 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/13/2015 15:32 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/13/2015 15:32 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/13/2015 15:32 JAHERMA11 Molybdenum (Mo)15.4 ug/L EPA 200.8 05/13/2015 15:32 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/13/2015 15:32 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/13/2015 15:32 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/13/2015 15:32 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 05/13/2015 15:32 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/08/2015 13:35 JAHERMA11 Arsenic (As)2.57 ug/L EPA 200.8 05/08/2015 13:35 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/08/2015 13:35 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/08/2015 13:35 JAHERMA11 Chromium (Cr)1.18 ug/L EPA 200.8 05/08/2015 13:35 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/08/2015 13:35 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/08/2015 13:35 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/08/2015 13:35 JAHERMA11 Molybdenum (Mo)15.5 ug/L EPA 200.8 05/08/2015 13:35 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/08/2015 13:35 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/08/2015 13:35 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/08/2015 13:35 JAHERMA0.2 1 Vanadium (V) Low Level 0.676 ug/L EPA 200.8 05/08/2015 13:35 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 320 mg/L SM2540C 05/04/2015 15:01 AGIBBS51001 Total Carbon TOC 8.6 mg/L SM5310C/EPA9060A 05/05/2015 13:25 GHUTCHI110 TOTAL SUSPENDED SOLIDS TSS 7.0 mg/L SM2540D 05/04/2015 10:05 AGIBBS551 Analytical Lab Page 15 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012752 Collection Date: 29-Apr-15 11:26 AM Site: SMW-6B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.513 mg-N/L EPA 353.2 04/30/2015 13:39 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 4.8 mg/L EPA 300.0 05/05/2015 21:33 BGN90340.1 1 Sulfate 32 mg/L EPA 300.0 05/05/2015 21:33 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 12:40 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 14:56 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.034 mg/L EPA 200.7 04/30/2015 14:04 MHALL30.005 1 Barium (Ba)0.039 mg/L EPA 200.7 04/30/2015 14:04 MHALL30.005 1 Boron (B)0.059 mg/L EPA 200.7 04/30/2015 14:04 MHALL30.05 1 Iron (Fe)0.540 mg/L EPA 200.7 04/30/2015 14:04 MHALL30.01 1 Manganese (Mn)0.042 mg/L EPA 200.7 04/30/2015 14:04 MHALL30.005 1 Strontium (Sr)0.029 mg/L EPA 200.7 04/30/2015 14:04 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 04/30/2015 14:04 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)5.58 mg/L EPA 200.7 04/30/2015 14:04 MHALL30.01 1 Magnesium (Mg)0.758 mg/L EPA 200.7 04/30/2015 14:04 MHALL30.005 1 Potassium (K)9.42 mg/L EPA 200.7 04/30/2015 14:04 MHALL30.1 1 Sodium (Na)8.33 mg/L EPA 200.7 04/30/2015 14:04 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.097 mg/L EPA 200.7 05/04/2015 12:29 MHALL30.005 1 Barium (Ba)0.045 mg/L EPA 200.7 05/04/2015 12:29 MHALL30.005 1 Boron (B)0.068 mg/L EPA 200.7 05/04/2015 12:29 MHALL30.05 1 Iron (Fe)0.638 mg/L EPA 200.7 05/04/2015 12:29 MHALL30.01 1 Manganese (Mn)0.044 mg/L EPA 200.7 05/04/2015 12:29 MHALL30.005 1 Strontium (Sr)0.029 mg/L EPA 200.7 05/04/2015 12:29 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 05/04/2015 12:29 MHALL30.005 1 Analytical Lab Page 16 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012752 Collection Date: 29-Apr-15 11:26 AM Site: SMW-6B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/13/2015 15:46 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 05/13/2015 15:46 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/13/2015 15:46 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/13/2015 15:46 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/13/2015 15:46 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/13/2015 15:46 JAHERMA11 Copper (Cu)1.03 ug/L EPA 200.8 05/13/2015 15:46 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/13/2015 15:46 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 05/13/2015 15:46 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/13/2015 15:46 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/13/2015 15:46 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/13/2015 15:46 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 05/13/2015 15:46 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/08/2015 13:49 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 05/08/2015 13:49 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/08/2015 13:49 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/08/2015 13:49 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/08/2015 13:49 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/08/2015 13:49 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/08/2015 13:49 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/08/2015 13:49 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 05/08/2015 13:49 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/08/2015 13:49 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/08/2015 13:49 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/08/2015 13:49 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 05/08/2015 13:49 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 82 mg/L SM2540C 05/04/2015 15:01 AGIBBS5251 Total Carbon TOC 1.1 mg/L SM5310C/EPA9060A 05/05/2015 13:25 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 05/04/2015 10:05 AGIBBS551 Analytical Lab Page 17 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012753 Collection Date: 29-Apr-15 1:25 PM Site: SMW-6C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.020 mg-N/L EPA 353.2 04/30/2015 13:41 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 19 mg/L EPA 300.0 05/06/2015 16:15 BGN9034110 Sulfate 43 mg/L EPA 300.0 05/06/2015 16:15 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 12:43 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 15:08 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.025 mg/L EPA 200.7 04/30/2015 13:56 MHALL30.005 1 Barium (Ba)0.054 mg/L EPA 200.7 04/30/2015 13:56 MHALL30.005 1 Boron (B)0.184 mg/L EPA 200.7 04/30/2015 13:56 MHALL30.05 1 Iron (Fe)4.49 mg/L EPA 200.7 04/30/2015 13:56 MHALL30.01 1 Manganese (Mn)0.313 mg/L EPA 200.7 04/30/2015 13:56 MHALL30.005 1 Strontium (Sr)0.133 mg/L EPA 200.7 04/30/2015 13:56 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 04/30/2015 13:56 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)17.7 mg/L EPA 200.7 04/30/2015 13:56 MHALL30.01 1 Magnesium (Mg)3.02 mg/L EPA 200.7 04/30/2015 13:56 MHALL30.005 1 Potassium (K)2.29 mg/L EPA 200.7 04/30/2015 13:56 MHALL30.1 1 Sodium (Na)11.7 mg/L EPA 200.7 04/30/2015 13:56 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.147 mg/L EPA 200.7 05/04/2015 12:33 MHALL30.005 1 Barium (Ba)0.058 mg/L EPA 200.7 05/04/2015 12:33 MHALL30.005 1 Boron (B)0.192 mg/L EPA 200.7 05/04/2015 12:33 MHALL30.05 1 Iron (Fe)4.48 mg/L EPA 200.7 05/04/2015 12:33 MHALL30.01 1 Manganese (Mn)0.322 mg/L EPA 200.7 05/04/2015 12:33 MHALL30.005 1 Strontium (Sr)0.134 mg/L EPA 200.7 05/04/2015 12:33 MHALL30.005 1 Zinc (Zn)0.008 mg/L EPA 200.7 05/04/2015 12:33 MHALL30.005 1 Analytical Lab Page 18 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012753 Collection Date: 29-Apr-15 1:25 PM Site: SMW-6C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/13/2015 15:50 JAHERMA11 Arsenic (As)3.62 ug/L EPA 200.8 05/13/2015 15:50 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/13/2015 15:50 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/13/2015 15:50 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/13/2015 15:50 JAHERMA11 Cobalt (Co)7.23 ug/L EPA 200.8 05/13/2015 15:50 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/13/2015 15:50 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/13/2015 15:50 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 05/13/2015 15:50 JAHERMA11 Nickel (Ni)2.44 ug/L EPA 200.8 05/13/2015 15:50 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/13/2015 15:50 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/13/2015 15:50 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 05/13/2015 15:50 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/08/2015 13:53 JAHERMA11 Arsenic (As)4.28 ug/L EPA 200.8 05/08/2015 13:53 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/08/2015 13:53 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/08/2015 13:53 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/08/2015 13:53 JAHERMA11 Cobalt (Co)7.92 ug/L EPA 200.8 05/08/2015 13:53 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/08/2015 13:53 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/08/2015 13:53 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 05/08/2015 13:53 JAHERMA11 Nickel (Ni)2.67 ug/L EPA 200.8 05/08/2015 13:53 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/08/2015 13:53 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/08/2015 13:53 JAHERMA0.2 1 Vanadium (V) Low Level 0.388 ug/L EPA 200.8 05/08/2015 13:53 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 130 mg/L SM2540C 05/04/2015 15:01 AGIBBS5251 Total Carbon TOC 1.0 mg/L SM5310C/EPA9060A 05/05/2015 13:25 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 05/04/2015 10:05 AGIBBS551 Analytical Lab Page 19 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012754 Collection Date: 29-Apr-15 12:20 PM Site: SMW-6D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/30/2015 13:42 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 180 mg/L EPA 300.0 05/07/2015 08:54 BGN90342.5 25 Sulfate 68 mg/L EPA 300.0 05/07/2015 08:54 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 12:50 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 15:15 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.038 mg/L EPA 200.7 05/04/2015 10:40 MHALL30.005 1 Barium (Ba)0.010 mg/L EPA 200.7 05/04/2015 10:40 MHALL30.005 1 Boron (B)0.982 mg/L EPA 200.7 05/04/2015 10:40 MHALL30.05 1 Iron (Fe)0.026 mg/L EPA 200.7 05/04/2015 10:40 MHALL30.01 1 Manganese (Mn)0.017 mg/L EPA 200.7 05/04/2015 10:40 MHALL30.005 1 Strontium (Sr)0.071 mg/L EPA 200.7 05/04/2015 10:40 MHALL30.005 1 Zinc (Zn)0.013 mg/L EPA 200.7 05/04/2015 10:40 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)7.32 mg/L EPA 200.7 04/30/2015 13:52 MHALL30.01 1 Magnesium (Mg)3.54 mg/L EPA 200.7 04/30/2015 13:52 MHALL30.005 1 Potassium (K)6.73 mg/L EPA 200.7 04/30/2015 13:52 MHALL30.1 1 Sodium (Na)243 mg/L EPA 200.7 04/30/2015 13:52 MHALL3120 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.666 mg/L EPA 200.7 05/04/2015 12:37 MHALL30.005 1 Barium (Ba)0.015 mg/L EPA 200.7 05/04/2015 12:37 MHALL30.005 1 Boron (B)0.982 mg/L EPA 200.7 05/04/2015 12:37 MHALL30.05 1 Iron (Fe)0.836 mg/L EPA 200.7 05/04/2015 12:37 MHALL30.01 1 Manganese (Mn)0.024 mg/L EPA 200.7 05/04/2015 12:37 MHALL30.005 1 Strontium (Sr)0.079 mg/L EPA 200.7 05/04/2015 12:37 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 05/04/2015 12:37 MHALL30.005 1 Analytical Lab Page 20 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012754 Collection Date: 29-Apr-15 12:20 PM Site: SMW-6D Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP-MS Antimony (Sb)1.19 ug/L EPA 200.8 05/13/2015 15:55 JAHERMA11 Arsenic (As)3.75 ug/L EPA 200.8 05/13/2015 15:55 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/13/2015 15:55 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/13/2015 15:55 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/13/2015 15:55 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/13/2015 15:55 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/13/2015 15:55 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/13/2015 15:55 JAHERMA11 Molybdenum (Mo)87.0 ug/L EPA 200.8 05/13/2015 15:55 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/13/2015 15:55 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/13/2015 15:55 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/13/2015 15:55 JAHERMA0.2 1 Vanadium (V) Low Level 0.702 ug/L EPA 200.8 05/13/2015 15:55 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)1.37 ug/L EPA 200.8 05/08/2015 13:58 JAHERMA11 Arsenic (As)3.90 ug/L EPA 200.8 05/08/2015 13:58 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/08/2015 13:58 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/08/2015 13:58 JAHERMA11 Chromium (Cr)2.44 ug/L EPA 200.8 05/08/2015 13:58 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/08/2015 13:58 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/08/2015 13:58 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/08/2015 13:58 JAHERMA11 Molybdenum (Mo)87.2 ug/L EPA 200.8 05/08/2015 13:58 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/08/2015 13:58 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/08/2015 13:58 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/08/2015 13:58 JAHERMA0.2 1 Vanadium (V) Low Level 1.96 ug/L EPA 200.8 05/08/2015 13:58 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 710 mg/L SM2540C 05/04/2015 15:01 AGIBBS5251 Total Carbon TOC 7.1 mg/L SM5310C/EPA9060A 05/05/2015 13:25 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS 34 mg/L SM2540D 05/04/2015 10:05 AGIBBS561 Analytical Lab Page 21 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012755 Collection Date: 29-Apr-15 3:05 PM Site: AW-7B/MW-31B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.014 mg-N/L EPA 353.2 04/30/2015 13:43 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 4.7 mg/L EPA 300.0 05/06/2015 18:08 BGN90340.1 1 Sulfate 9.8 mg/L EPA 300.0 05/06/2015 18:08 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 12:57 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 15:17 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.017 mg/L EPA 200.7 04/30/2015 14:23 MHALL30.005 1 Barium (Ba)0.036 mg/L EPA 200.7 04/30/2015 14:23 MHALL30.005 1 Boron (B)0.074 mg/L EPA 200.7 04/30/2015 14:23 MHALL30.05 1 Iron (Fe)0.453 mg/L EPA 200.7 04/30/2015 14:23 MHALL30.01 1 Manganese (Mn)0.034 mg/L EPA 200.7 04/30/2015 14:23 MHALL30.005 1 Strontium (Sr)0.135 mg/L EPA 200.7 04/30/2015 14:23 MHALL30.005 1 Zinc (Zn)0.008 mg/L EPA 200.7 04/30/2015 14:23 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)6.85 mg/L EPA 200.7 04/30/2015 14:23 MHALL30.01 1 Magnesium (Mg)1.33 mg/L EPA 200.7 04/30/2015 14:23 MHALL30.005 1 Potassium (K)1.19 mg/L EPA 200.7 04/30/2015 14:23 MHALL30.1 1 Sodium (Na)2.98 mg/L EPA 200.7 04/30/2015 14:23 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.391 mg/L EPA 200.7 05/04/2015 12:41 MHALL30.005 1 Barium (Ba)0.042 mg/L EPA 200.7 05/04/2015 12:41 MHALL30.005 1 Boron (B)0.071 mg/L EPA 200.7 05/04/2015 12:41 MHALL30.05 1 Iron (Fe)0.902 mg/L EPA 200.7 05/04/2015 12:41 MHALL30.01 1 Manganese (Mn)0.049 mg/L EPA 200.7 05/04/2015 12:41 MHALL30.005 1 Strontium (Sr)0.139 mg/L EPA 200.7 05/04/2015 12:41 MHALL30.005 1 Zinc (Zn)0.006 mg/L EPA 200.7 05/04/2015 12:41 MHALL30.005 1 Analytical Lab Page 22 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012755 Collection Date: 29-Apr-15 3:05 PM Site: AW-7B/MW-31B Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/13/2015 16:00 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 05/13/2015 16:00 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/13/2015 16:00 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/13/2015 16:00 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/13/2015 16:00 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/13/2015 16:00 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/13/2015 16:00 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/13/2015 16:00 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 05/13/2015 16:00 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/13/2015 16:00 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/13/2015 16:00 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/13/2015 16:00 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 05/13/2015 16:00 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/08/2015 14:02 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 05/08/2015 14:02 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/08/2015 14:02 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/08/2015 14:02 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/08/2015 14:02 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/08/2015 14:02 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/08/2015 14:02 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/08/2015 14:02 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 05/08/2015 14:02 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/08/2015 14:02 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/08/2015 14:02 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/08/2015 14:02 JAHERMA0.2 1 Vanadium (V) Low Level 0.742 ug/L EPA 200.8 05/08/2015 14:02 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 48 mg/L SM2540C 05/04/2015 15:01 AGIBBS5251 Total Carbon TOC 2.5 mg/L SM5310C/EPA9060A 05/05/2015 13:25 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS 8.0 mg/L SM2540D 05/04/2015 10:05 AGIBBS551 Analytical Lab Page 23 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012756 Collection Date: 29-Apr-15 4:28 PM Site: ABMW-2S Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 12:59 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 15:19 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.043 mg/L EPA 200.7 04/30/2015 14:08 MHALL30.005 1 Barium (Ba)1.43 mg/L EPA 200.7 04/30/2015 14:08 MHALL30.005 1 Boron (B)0.212 mg/L EPA 200.7 04/30/2015 14:08 MHALL30.05 1 Iron (Fe)22.2 mg/L EPA 200.7 04/30/2015 14:08 MHALL30.01 1 Manganese (Mn)0.725 mg/L EPA 200.7 04/30/2015 14:08 MHALL30.005 1 Strontium (Sr)1.60 mg/L EPA 200.7 04/30/2015 14:08 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 04/30/2015 14:08 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)62.9 mg/L EPA 200.7 04/30/2015 14:08 MHALL30.01 1 Magnesium (Mg)7.67 mg/L EPA 200.7 04/30/2015 14:08 MHALL30.005 1 Potassium (K)7.29 mg/L EPA 200.7 04/30/2015 14:08 MHALL30.1 1 Sodium (Na)19.7 mg/L EPA 200.7 04/30/2015 14:08 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.321 mg/L EPA 200.7 05/04/2015 12:44 MHALL30.005 1 Barium (Ba)1.47 mg/L EPA 200.7 05/04/2015 12:44 MHALL30.005 1 Boron (B)0.222 mg/L EPA 200.7 05/04/2015 12:44 MHALL30.05 1 Iron (Fe)22.7 mg/L EPA 200.7 05/04/2015 12:44 MHALL30.01 1 Manganese (Mn)0.741 mg/L EPA 200.7 05/04/2015 12:44 MHALL30.005 1 Strontium (Sr)1.63 mg/L EPA 200.7 05/04/2015 12:44 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 05/04/2015 12:44 MHALL30.005 1 DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/13/2015 16:04 JAHERMA11 Arsenic (As)39.2 ug/L EPA 200.8 05/13/2015 16:04 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/13/2015 16:04 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/13/2015 16:04 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/13/2015 16:04 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/13/2015 16:04 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/13/2015 16:04 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/13/2015 16:04 JAHERMA11 Molybdenum (Mo)10.8 ug/L EPA 200.8 05/13/2015 16:04 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/13/2015 16:04 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/13/2015 16:04 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/13/2015 16:04 JAHERMA0.2 1 Vanadium (V) Low Level 1.26 ug/L EPA 200.8 05/13/2015 16:04 JAHERMA0.3 1 Analytical Lab Page 24 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012756 Collection Date: 29-Apr-15 4:28 PM Site: ABMW-2S Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/08/2015 14:07 JAHERMA11 Arsenic (As)38.6 ug/L EPA 200.8 05/08/2015 14:07 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/08/2015 14:07 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/08/2015 14:07 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/08/2015 14:07 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/08/2015 14:07 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/08/2015 14:07 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/08/2015 14:07 JAHERMA11 Molybdenum (Mo)10.9 ug/L EPA 200.8 05/08/2015 14:07 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/08/2015 14:07 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/08/2015 14:07 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/08/2015 14:07 JAHERMA0.2 1 Vanadium (V) Low Level 2.24 ug/L EPA 200.8 05/08/2015 14:07 JAHERMA0.3 1 Analytical Lab Page 25 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012757 Collection Date: 28-Apr-15 8:25 AM Site: Filter Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 15:22 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 04/30/2015 11:31 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 04/30/2015 11:31 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 04/30/2015 11:31 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 04/30/2015 11:31 MHALL30.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 04/30/2015 11:31 MHALL30.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 04/30/2015 11:31 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 04/30/2015 11:31 MHALL30.005 1 DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/13/2015 16:09 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 05/13/2015 16:09 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/13/2015 16:09 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/13/2015 16:09 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/13/2015 16:09 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/13/2015 16:09 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/13/2015 16:09 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/13/2015 16:09 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 05/13/2015 16:09 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/13/2015 16:09 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/13/2015 16:09 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/13/2015 16:09 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 05/13/2015 16:09 JAHERMA0.3 1 Analytical Lab Page 26 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012758 Collection Date: 28-Apr-15 8:25 AM Site: Equipment Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/30/2015 13:44 LSTARL10.01 1 INORGANIC IONS BY IC Chloride < 0.1 mg/L EPA 300.0 05/06/2015 12:28 BGN90340.1 1 Sulfate < 0.1 mg/L EPA 300.0 05/06/2015 12:28 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 13:02 ACPAYNE0.05 1 UNDIGESTED METALS BY ICP Calcium (Ca)0.013 mg/L EPA 200.7 04/30/2015 14:12 MHALL30.01 1 Magnesium (Mg)< 0.005 mg/L EPA 200.7 04/30/2015 14:12 MHALL30.005 1 Potassium (K)< 0.1 mg/L EPA 200.7 04/30/2015 14:12 MHALL30.1 1 Sodium (Na)< 0.05 mg/L EPA 200.7 04/30/2015 14:12 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 05/04/2015 12:48 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 05/04/2015 12:48 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 05/04/2015 12:48 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 05/04/2015 12:48 MHALL30.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 05/04/2015 12:48 MHALL30.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 05/04/2015 12:48 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 05/04/2015 12:48 MHALL30.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/08/2015 14:12 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 05/08/2015 14:12 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/08/2015 14:12 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/08/2015 14:12 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/08/2015 14:12 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/08/2015 14:12 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/08/2015 14:12 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/08/2015 14:12 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 05/08/2015 14:12 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/08/2015 14:12 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/08/2015 14:12 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/08/2015 14:12 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 05/08/2015 14:12 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY Analytical Lab Page 27 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012758 Collection Date: 28-Apr-15 8:25 AM Site: Equipment Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 05/04/2015 15:01 AGIBBS5251 Total Carbon TOC 0.162 mg/L SM5310C/EPA9060A 05/05/2015 13:25 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 05/04/2015 10:05 AGIBBS551 Analytical Lab Page 28 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012759 Collection Date: 29-Apr-15 1:45 PM Site: Filter Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 15:24 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 04/30/2015 12:01 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 04/30/2015 12:01 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 04/30/2015 12:01 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 04/30/2015 12:01 MHALL30.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 04/30/2015 12:01 MHALL30.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 04/30/2015 12:01 MHALL30.005 1 Zinc (Zn)0.006 mg/L EPA 200.7 04/30/2015 12:01 MHALL30.005 1 DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/13/2015 16:13 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 05/13/2015 16:13 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/13/2015 16:13 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/13/2015 16:13 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/13/2015 16:13 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/13/2015 16:13 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/13/2015 16:13 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/13/2015 16:13 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 05/13/2015 16:13 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/13/2015 16:13 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/13/2015 16:13 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/13/2015 16:13 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 05/13/2015 16:13 JAHERMA0.3 1 Analytical Lab Page 29 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012760 Collection Date: 29-Apr-15 1:45 PM Site: Equipment Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.033 mg-N/L EPA 353.2 04/30/2015 13:45 LSTARL10.01 1 INORGANIC IONS BY IC Chloride < 0.1 mg/L EPA 300.0 05/06/2015 12:47 BGN90340.1 1 Sulfate < 0.1 mg/L EPA 300.0 05/06/2015 12:47 BGN90340.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 13:04 ACPAYNE0.05 1 UNDIGESTED METALS BY ICP Calcium (Ca)0.013 mg/L EPA 200.7 04/30/2015 14:39 MHALL30.01 1 Magnesium (Mg)< 0.005 mg/L EPA 200.7 04/30/2015 14:39 MHALL30.005 1 Potassium (K)< 0.1 mg/L EPA 200.7 04/30/2015 14:39 MHALL30.1 1 Sodium (Na)< 0.05 mg/L EPA 200.7 04/30/2015 14:39 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 05/04/2015 12:56 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 05/04/2015 12:56 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 05/04/2015 12:56 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 05/04/2015 12:56 MHALL30.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 05/04/2015 12:56 MHALL30.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 05/04/2015 12:56 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 05/04/2015 12:56 MHALL30.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/08/2015 14:16 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 05/08/2015 14:16 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/08/2015 14:16 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/08/2015 14:16 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/08/2015 14:16 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/08/2015 14:16 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/08/2015 14:16 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/08/2015 14:16 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 05/08/2015 14:16 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/08/2015 14:16 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/08/2015 14:16 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/08/2015 14:16 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 05/08/2015 14:16 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY Analytical Lab Page 30 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012760 Collection Date: 29-Apr-15 1:45 PM Site: Equipment Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 05/04/2015 15:01 AGIBBS5251 Total Carbon TOC < 0.1 mg/L SM5310C/EPA9060A 05/05/2015 13:25 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 05/04/2015 10:05 AGIBBS551 Analytical Lab Page 31 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012761 Collection Date: 29-Apr-15 12:00 PM Site: SMW-6B DUP Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.530 mg-N/L EPA 353.2 04/30/2015 14:00 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 5.0 mg/L EPA 300.0 05/06/2015 18:27 BGN90340.1 1 Sulfate 35 mg/L EPA 300.0 05/06/2015 18:27 BGN9034110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 13:06 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 05/01/2015 15:26 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.036 mg/L EPA 200.7 04/30/2015 13:30 MHALL30.005 1 Barium (Ba)0.042 mg/L EPA 200.7 04/30/2015 13:30 MHALL30.005 1 Boron (B)0.065 mg/L EPA 200.7 04/30/2015 13:30 MHALL30.05 1 Iron (Fe)0.575 mg/L EPA 200.7 04/30/2015 13:30 MHALL30.01 1 Manganese (Mn)0.043 mg/L EPA 200.7 04/30/2015 13:30 MHALL30.005 1 Strontium (Sr)0.029 mg/L EPA 200.7 04/30/2015 13:30 MHALL30.005 1 Zinc (Zn)0.005 mg/L EPA 200.7 04/30/2015 13:30 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)5.43 mg/L EPA 200.7 04/30/2015 13:30 MHALL30.01 1 Magnesium (Mg)0.780 mg/L EPA 200.7 04/30/2015 13:30 MHALL30.005 1 Potassium (K)9.12 mg/L EPA 200.7 04/30/2015 13:30 MHALL30.1 1 Sodium (Na)8.62 mg/L EPA 200.7 04/30/2015 13:30 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.078 mg/L EPA 200.7 05/04/2015 12:52 MHALL30.005 1 Barium (Ba)0.044 mg/L EPA 200.7 05/04/2015 12:52 MHALL30.005 1 Boron (B)0.061 mg/L EPA 200.7 05/04/2015 12:52 MHALL30.05 1 Iron (Fe)0.587 mg/L EPA 200.7 05/04/2015 12:52 MHALL30.01 1 Manganese (Mn)0.043 mg/L EPA 200.7 05/04/2015 12:52 MHALL30.005 1 Strontium (Sr)0.029 mg/L EPA 200.7 05/04/2015 12:52 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 05/04/2015 12:52 MHALL30.005 1 Analytical Lab Page 32 of 86 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040754 2015012761 Collection Date: 29-Apr-15 12:00 PM Site: SMW-6B DUP Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/13/2015 16:18 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 05/13/2015 16:18 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/13/2015 16:18 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/13/2015 16:18 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/13/2015 16:18 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/13/2015 16:18 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/13/2015 16:18 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/13/2015 16:18 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 05/13/2015 16:18 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/13/2015 16:18 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/13/2015 16:18 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/13/2015 16:18 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 05/13/2015 16:18 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/08/2015 14:21 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 05/08/2015 14:21 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/08/2015 14:21 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/08/2015 14:21 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/08/2015 14:21 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/08/2015 14:21 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/08/2015 14:21 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/08/2015 14:21 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 05/08/2015 14:21 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/08/2015 14:21 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/08/2015 14:21 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/08/2015 14:21 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 05/08/2015 14:21 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 72 mg/L SM2540C 05/04/2015 15:01 AGIBBS5251 Total Carbon TOC 0.863 mg/L SM5310C/EPA9060A 05/05/2015 13:25 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 05/04/2015 10:05 AGIBBS551 Analytical Lab Page 33 of 86 SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle QD30038Lot Number: J15040754Project Number: AB GW Assessment Water - SuttonProject Name: 05/07/2015Date Completed: Grant Wilton Project Manager *QD30038* This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. Page: 1 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Case Narrative Duke Energy Lot Number: QD30038 SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329 Project Name: AB GW Assessment Water - Sutton Project Number: J15040754 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. Page: 2 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: QD30038 Project Name: AB GW Assessment Water - Sutton Project Number: J15040754 Sample Number Sample ID Matrix Date Sampled Date Received 001 04/28/2015 08552015012746Aqueous 04/30/2015 002 04/28/2015 09422015012747Aqueous 04/30/2015 003 04/28/2015 12552015012748Aqueous 04/30/2015 004 04/28/2015 11082015012749Aqueous 04/30/2015 005 04/28/2015 16482015012750Aqueous 04/30/2015 006 04/28/2015 15352015012751Aqueous 04/30/2015 007 04/29/2015 11262015012752Aqueous 04/30/2015 008 04/29/2015 13252015012753Aqueous 04/30/2015 009 04/29/2015 12202015012754Aqueous 04/30/2015 010 04/29/2015 15052015012755Aqueous 04/30/2015 011 04/28/2015 08252015012758Aqueous 04/30/2015 012 04/29/2015 13452015012760Aqueous 04/30/2015 013 04/29/2015 12002015012761Aqueous 04/30/2015 (13 samples) Page: 3 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: QD30038 Project Name: AB GW Assessment Water - Sutton Project Number: J15040754 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2015012746 Aqueous Alkalinity SM 2320B-23 mg/L 5 001 2015012746 Aqueous Bicarbonate Alkalinity SM 2320B-23 mg/L 5 001 2015012746 Aqueous Methane RSK - 175 11 ug/L 6 002 2015012747 Aqueous Alkalinity SM 2320B-52 mg/L 7 002 2015012747 Aqueous Bicarbonate Alkalinity SM 2320B-52 mg/L 7 003 2015012748 Aqueous Alkalinity SM 2320B-40 mg/L 9 003 2015012748 Aqueous Bicarbonate Alkalinity SM 2320B-40 mg/L 9 003 2015012748 Aqueous Methane RSK - 175 140 ug/L 10 005 2015012750 Aqueous Alkalinity SM 2320B-380 mg/L 13 005 2015012750 Aqueous Bicarbonate Alkalinity SM 2320B-380 mg/L 13 005 2015012750 Aqueous Methane RSK - 175 87 ug/L 14 006 2015012751 Aqueous Alkalinity SM 2320B-110 mg/L 15 006 2015012751 Aqueous Bicarbonate Alkalinity SM 2320B-110 mg/L 15 006 2015012751 Aqueous Methane RSK - 175 130 ug/L 16 008 2015012753 Aqueous Alkalinity SM 2320B-17 mg/L 19 008 2015012753 Aqueous Bicarbonate Alkalinity SM 2320B-17 mg/L 19 009 2015012754 Aqueous Alkalinity SM 2320B-250 mg/L 21 009 2015012754 Aqueous Bicarbonate Alkalinity SM 2320B-240 mg/L 21 010 2015012755 Aqueous Alkalinity SM 2320B-11 mg/L 23 010 2015012755 Aqueous Bicarbonate Alkalinity SM 2320B-11 mg/L 23 010 2015012755 Aqueous Methane RSK - 175 33 ug/L 24 (21 detections) Page: 4 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012746 QD30038-001 04/28/2015 0855 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/02/2015 1646 HMA 73874 1 (Bicarbonate ) SM 2320B-2011 1 05/02/2015 1646 BWS 1 (Carbonate Al) SM 2320B-2011 1 05/02/2015 1646 BWS AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 23 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 23 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 5 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012746 QD30038-001 04/28/2015 0855 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/05/2015 2059 JJG 74109 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 11 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 6 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012747 QD30038-002 04/28/2015 0942 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/02/2015 1722 HMA 73875 1 (Bicarbonate ) SM 2320B-2011 1 05/02/2015 1722 BWS 1 (Carbonate Al) SM 2320B-2011 1 05/02/2015 1722 BWS AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 52 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 52 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 7 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012747 QD30038-002 04/28/2015 0942 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/05/2015 2127 JJG 74109 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 8 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012748 QD30038-003 04/28/2015 1255 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/02/2015 1726 HMA 73875 1 (Bicarbonate ) SM 2320B-2011 1 05/02/2015 1726 BWS 1 (Carbonate Al) SM 2320B-2011 1 05/02/2015 1726 BWS AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 40 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 40 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 9 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012748 QD30038-003 04/28/2015 1255 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/05/2015 2138 JJG 74109 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 140 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 10 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012749 QD30038-004 04/28/2015 1108 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/02/2015 1732 HMA 73875 1 (Bicarbonate ) SM 2320B-2011 1 05/02/2015 1732 BWS 1 (Carbonate Al) SM 2320B-2011 1 05/02/2015 1732 BWS AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 11 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012749 QD30038-004 04/28/2015 1108 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/05/2015 2158 JJG 74109 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 12 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012750 QD30038-005 04/28/2015 1648 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/02/2015 1742 HMA 73875 1 (Bicarbonate ) SM 2320B-2011 1 05/02/2015 1742 BWS 1 (Carbonate Al) SM 2320B-2011 1 05/02/2015 1742 BWS AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 380 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 380 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 13 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012750 QD30038-005 04/28/2015 1648 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/06/2015 1042 DCS 74169 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 87 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 14 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012751 QD30038-006 04/28/2015 1535 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/02/2015 1747 HMA 73875 1 (Bicarbonate ) SM 2320B-2011 1 05/02/2015 1747 BWS 1 (Carbonate Al) SM 2320B-2011 1 05/02/2015 1747 BWS AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 110 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 110 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 15 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012751 QD30038-006 04/28/2015 1535 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/06/2015 1313 DCS 74169 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 130 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 16 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012752 QD30038-007 04/29/2015 1126 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/02/2015 1818 HMA 73875 1 (Bicarbonate ) SM 2320B-2011 1 05/02/2015 1818 BWS 1 (Carbonate Al) SM 2320B-2011 1 05/02/2015 1818 BWS AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 17 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012752 QD30038-007 04/29/2015 1126 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/06/2015 1100 DCS 74169 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 18 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012753 QD30038-008 04/29/2015 1325 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/02/2015 1822 HMA 73875 1 (Bicarbonate ) SM 2320B-2011 1 05/02/2015 1822 BWS 1 (Carbonate Al) SM 2320B-2011 1 05/02/2015 1822 BWS AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 17 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 17 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 19 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012753 QD30038-008 04/29/2015 1325 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/06/2015 1125 DCS 74169 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 20 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012754 QD30038-009 04/29/2015 1220 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/02/2015 1830 HMA 73875 1 (Bicarbonate ) SM 2320B-2011 1 05/02/2015 1830 BWS 1 (Carbonate Al) SM 2320B-2011 1 05/02/2015 1830 BWS AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 250 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 240 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 21 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012754 QD30038-009 04/29/2015 1220 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/06/2015 1142 DCS 74169 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 22 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012755 QD30038-010 04/29/2015 1505 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/02/2015 1834 HMA 73875 1 (Bicarbonate ) SM 2320B-2011 1 05/02/2015 1834 BWS 1 (Carbonate Al) SM 2320B-2011 1 05/02/2015 1834 BWS AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 11 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 11 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 23 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012755 QD30038-010 04/29/2015 1505 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/06/2015 1205 DCS 74169 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 33 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 24 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012758 QD30038-011 04/28/2015 0825 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/02/2015 1839 HMA 73875 1 (Bicarbonate ) SM 2320B-2011 1 05/02/2015 1839 BWS 1 (Carbonate Al) SM 2320B-2011 1 05/02/2015 1839 BWS AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 25 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012758 QD30038-011 04/28/2015 0825 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/06/2015 1002 DCS 74169 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 26 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012760 QD30038-012 04/29/2015 1345 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/02/2015 1844 HMA 73875 1 (Bicarbonate ) SM 2320B-2011 1 05/02/2015 1844 BWS 1 (Carbonate Al) SM 2320B-2011 1 05/02/2015 1844 BWS AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 27 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012760 QD30038-012 04/29/2015 1345 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/06/2015 1025 DCS 74169 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 28 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012761 QD30038-013 04/29/2015 1200 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/02/2015 1849 HMA 73875 1 (Bicarbonate ) SM 2320B-2011 1 05/02/2015 1849 BWS 1 (Carbonate Al) SM 2320B-2011 1 05/02/2015 1849 BWS AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 29 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012761 QD30038-013 04/29/2015 1200 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040754 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/06/2015 1216 DCS 74169 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 30 of 30 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 QC Summary QC Data for Lot Number: QD30038 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MB Batch: Sample ID:QQ73874-001 73874 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Alkalinity ND 05/02/2015 141410mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD30038 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - LCS Batch: Sample ID:QQ73874-002 73874 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Alkalinity 92 05/02/2015 14219210090-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD30038 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MB Batch: Sample ID:QQ73875-001 73875 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Alkalinity ND 05/02/2015 171110mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD30038 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - LCS Batch: Sample ID:QQ73875-002 73875 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Alkalinity 93 05/02/2015 17179310090-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD30038 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MS Batch: Sample ID:QD30038-006MS 73875 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Alkalinity 180 05/02/2015 17537210070-1301101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD30038 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MSD Batch: Sample ID:QD30038-006MD 73875 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Alkalinity 180 05/02/2015 18007010070-1301.2 201101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD30038 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - MB Batch: Sample ID:QQ74109-001 74109 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 05/05/2015 185910ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD30038 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCS Batch: Sample ID:QQ74109-002 74109 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 110 05/05/2015 17427115070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD30038 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCSD Batch: Sample ID:QQ74109-003 74109 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 120 05/05/2015 17537715070-1307.7 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD30038 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - MB Batch: Sample ID:QQ74169-001 74169 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 05/06/2015 094010ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD30038 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCS Batch: Sample ID:QQ74169-002 74169 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 120 05/06/2015 08598115070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD30038 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCSD Batch: Sample ID:QQ74169-003 74169 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 110 05/06/2015 09117515070-1307.2 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD30038 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Analytical Lab Page 79 of 86 Analytical Lab Page 80 of 86 Analytical Lab Page 81 of 86 Analytical Lab Page 82 of 86 Analytical Lab Page 83 of 86 Analytical Lab Page 84 of 86 Analytical Lab Page 85 of 86 Analytical Lab Page 86 of 86