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Home My WebLink AboutNC0001422_ATT 5 - Water - J15040753report_2015080513339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number: J15040753 Project Name:SUTTON - AB GW ASSESSMENT WATER Lab Contact:Mary Ann Ogle Date:5/20/2015 Customer Address: Customer Name(s):Perry Waldrep, Tim Hunsucker, Kathy Webb, John Toepfer Phone: 980-875-5274 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Mary Ann Ogle Analytical Lab Page 1 of 63 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015012738 Sutton 28-Apr-15 2:00 PM ILLEGIBLE SW-CFP 2015012739 Sutton 28-Apr-15 4:55 PM ILLEGIBLE SW-CF001 2015012740 Sutton 28-Apr-15 3:35 PM ILLEGIBLE SW-1C 2015012741 Sutton 28-Apr-15 3:45 PM ILLEGIBLE SW-1C Dup 2015012742 Sutton 29-Apr-15 9:50 AM Equipment Blank 2015012743 Sutton FIELD BLANK 2015012744 Sutton Trip Blank 2015012745 Sutton Filter Blank 8 Total Samples Analytical Lab Page 2 of 63 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:Peggy Kendall Date:5/20/2015 Electronic Data Deliverable (EDD) Sent Separately Analytical Lab Page 3 of 63 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040753 2015012738 Collection Date: 28-Apr-15 2:00 PM Site:SW-CFP Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.427 mg-N/L EPA 353.2 04/30/2015 13:20 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 28 mg/L EPA 300.0 05/04/2015 13:17 BGN9034110 Sulfate 8.6 mg/L EPA 300.0 05/04/2015 13:17 BGN90340.1 1 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY DISSOLVED METALS BY ICP Aluminum (Al)0.456 mg/L EPA 200.7 04/30/2015 10:06 MHALL30.005 1 Barium (Ba)0.024 mg/L EPA 200.7 04/30/2015 10:06 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 04/30/2015 10:06 MHALL30.05 1 Iron (Fe)0.857 mg/L EPA 200.7 04/30/2015 10:06 MHALL30.01 1 Manganese (Mn)0.044 mg/L EPA 200.7 04/30/2015 10:06 MHALL30.005 1 Strontium (Sr)0.038 mg/L EPA 200.7 04/30/2015 10:06 MHALL30.005 1 Zinc (Zn)0.043 mg/L EPA 200.7 04/30/2015 10:06 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)5.37 mg/L EPA 200.7 04/30/2015 12:55 MHALL30.01 1 Magnesium (Mg)2.19 mg/L EPA 200.7 04/30/2015 12:55 MHALL30.005 1 Potassium (K)3.44 mg/L EPA 200.7 04/30/2015 12:55 MHALL30.1 1 Sodium (Na)20.3 mg/L EPA 200.7 04/30/2015 12:55 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.977 mg/L EPA 200.7 05/04/2015 11:25 MHALL30.005 1 Barium (Ba)0.033 mg/L EPA 200.7 05/04/2015 11:25 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 05/04/2015 11:25 MHALL30.05 1 Iron (Fe)1.83 mg/L EPA 200.7 05/04/2015 11:25 MHALL30.01 1 Manganese (Mn)0.079 mg/L EPA 200.7 05/04/2015 11:25 MHALL30.005 1 Strontium (Sr)0.039 mg/L EPA 200.7 05/04/2015 11:25 MHALL30.005 1 Zinc (Zn)0.048 mg/L EPA 200.7 05/04/2015 11:25 MHALL30.005 1 Analytical Lab Page 4 of 63 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040753 2015012738 Collection Date: 28-Apr-15 2:00 PM Site:SW-CFP Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/13/2015 14:19 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 05/13/2015 14:19 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/13/2015 14:19 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/13/2015 14:19 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/13/2015 14:19 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/13/2015 14:19 JAHERMA11 Copper (Cu)2.61 ug/L EPA 200.8 05/13/2015 14:19 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/13/2015 14:19 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 05/13/2015 14:19 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/13/2015 14:19 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/13/2015 14:19 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/13/2015 14:19 JAHERMA0.2 1 Vanadium (V) Low Level 1.25 ug/L EPA 200.8 05/13/2015 14:19 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/08/2015 12:41 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 05/08/2015 12:41 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/08/2015 12:41 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/08/2015 12:41 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/08/2015 12:41 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/08/2015 12:41 JAHERMA11 Copper (Cu)4.60 ug/L EPA 200.8 05/08/2015 12:41 JAHERMA11 Lead (Pb)4.44 ug/L EPA 200.8 05/08/2015 12:41 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 05/08/2015 12:41 JAHERMA11 Nickel (Ni)1.02 ug/L EPA 200.8 05/08/2015 12:41 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/08/2015 12:41 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/08/2015 12:41 JAHERMA0.2 1 Vanadium (V) Low Level 2.45 ug/L EPA 200.8 05/08/2015 12:41 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 110 mg/L SM2540C 04/30/2015 14:23 AGIBBS5251 Total Carbon TOC 14 mg/L SM5310C/EPA9060A 05/05/2015 13:25 GHUTCHI0.5 5 TOTAL SUSPENDED SOLIDS TSS 18 mg/L SM2540D 05/01/2015 08:50 AGIBBS551 Analytical Lab Page 5 of 63 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040753 2015012738 Collection Date: 28-Apr-15 2:00 PM Site:SW-CFP Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF Analytical Lab Page 6 of 63 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040753 2015012739 Collection Date: 28-Apr-15 4:55 PM Site:SW-CF001 Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.525 mg-N/L EPA 353.2 04/30/2015 13:21 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 11 mg/L EPA 300.0 05/04/2015 11:12 BGN9034110 Sulfate 10.0 mg/L EPA 300.0 05/04/2015 11:12 BGN9034110 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY DISSOLVED METALS BY ICP Aluminum (Al)0.383 mg/L EPA 200.7 04/30/2015 10:52 MHALL30.005 1 Barium (Ba)0.025 mg/L EPA 200.7 04/30/2015 10:52 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 04/30/2015 10:52 MHALL30.05 1 Iron (Fe)0.730 mg/L EPA 200.7 04/30/2015 10:52 MHALL30.01 1 Manganese (Mn)0.042 mg/L EPA 200.7 04/30/2015 10:52 MHALL30.005 1 Strontium (Sr)0.043 mg/L EPA 200.7 04/30/2015 10:52 MHALL30.005 1 Zinc (Zn)0.018 mg/L EPA 200.7 04/30/2015 10:52 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)5.94 mg/L EPA 200.7 04/30/2015 13:09 MHALL30.01 1 Magnesium (Mg)2.32 mg/L EPA 200.7 04/30/2015 13:09 MHALL30.005 1 Potassium (K)3.12 mg/L EPA 200.7 04/30/2015 13:09 MHALL30.1 1 Sodium (Na)10.2 mg/L EPA 200.7 04/30/2015 13:09 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.599 mg/L EPA 200.7 05/04/2015 11:36 MHALL30.005 1 Barium (Ba)0.030 mg/L EPA 200.7 05/04/2015 11:36 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 05/04/2015 11:36 MHALL30.05 1 Iron (Fe)1.31 mg/L EPA 200.7 05/04/2015 11:36 MHALL30.01 1 Manganese (Mn)0.052 mg/L EPA 200.7 05/04/2015 11:36 MHALL30.005 1 Strontium (Sr)0.044 mg/L EPA 200.7 05/04/2015 11:36 MHALL30.005 1 Zinc (Zn)0.009 mg/L EPA 200.7 05/04/2015 11:36 MHALL30.005 1 Analytical Lab Page 7 of 63 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040753 2015012739 Collection Date: 28-Apr-15 4:55 PM Site:SW-CF001 Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/13/2015 14:33 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 05/13/2015 14:33 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/13/2015 14:33 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/13/2015 14:33 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/13/2015 14:33 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/13/2015 14:33 JAHERMA11 Copper (Cu)2.24 ug/L EPA 200.8 05/13/2015 14:33 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/13/2015 14:33 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 05/13/2015 14:33 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/13/2015 14:33 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/13/2015 14:33 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/13/2015 14:33 JAHERMA0.2 1 Vanadium (V) Low Level 1.29 ug/L EPA 200.8 05/13/2015 14:33 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/08/2015 12:27 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 05/08/2015 12:27 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/08/2015 12:27 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/08/2015 12:27 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/08/2015 12:27 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/08/2015 12:27 JAHERMA11 Copper (Cu)2.10 ug/L EPA 200.8 05/08/2015 12:27 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/08/2015 12:27 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 05/08/2015 12:27 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/08/2015 12:27 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/08/2015 12:27 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/08/2015 12:27 JAHERMA0.2 1 Vanadium (V) Low Level 2.15 ug/L EPA 200.8 05/08/2015 12:27 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 89 mg/L SM2540C 04/30/2015 14:23 AGIBBS5251 Total Carbon TOC 13 mg/L SM5310C/EPA9060A 05/05/2015 13:25 GHUTCHI0.5 5 TOTAL SUSPENDED SOLIDS TSS 13 mg/L SM2540D 05/01/2015 08:50 AGIBBS551 Analytical Lab Page 8 of 63 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040753 2015012739 Collection Date: 28-Apr-15 4:55 PM Site:SW-CF001 Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF Analytical Lab Page 9 of 63 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040753 2015012740 Collection Date: 28-Apr-15 3:35 PM Site:SW-1C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.145 mg-N/L EPA 353.2 04/30/2015 13:23 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 30 mg/L EPA 300.0 05/04/2015 11:30 BGN9034110 Sulfate 35 mg/L EPA 300.0 05/04/2015 11:30 BGN9034110 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY DISSOLVED METALS BY ICP Aluminum (Al)0.049 mg/L EPA 200.7 04/30/2015 10:14 MHALL30.005 1 Barium (Ba)0.046 mg/L EPA 200.7 04/30/2015 10:14 MHALL30.005 1 Boron (B)0.204 mg/L EPA 200.7 04/30/2015 10:14 MHALL30.05 1 Iron (Fe)0.057 mg/L EPA 200.7 04/30/2015 10:14 MHALL30.01 1 Manganese (Mn)0.007 mg/L EPA 200.7 04/30/2015 10:14 MHALL30.005 1 Strontium (Sr)0.199 mg/L EPA 200.7 04/30/2015 10:14 MHALL30.005 1 Zinc (Zn)0.058 mg/L EPA 200.7 04/30/2015 10:14 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)10.8 mg/L EPA 200.7 04/30/2015 12:43 MHALL30.01 1 Magnesium (Mg)5.02 mg/L EPA 200.7 04/30/2015 12:43 MHALL30.005 1 Potassium (K)5.81 mg/L EPA 200.7 04/30/2015 12:43 MHALL30.1 1 Sodium (Na)27.5 mg/L EPA 200.7 04/30/2015 12:43 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.101 mg/L EPA 200.7 05/04/2015 11:40 MHALL30.005 1 Barium (Ba)0.051 mg/L EPA 200.7 05/04/2015 11:40 MHALL30.005 1 Boron (B)0.210 mg/L EPA 200.7 05/04/2015 11:40 MHALL30.05 1 Iron (Fe)0.127 mg/L EPA 200.7 05/04/2015 11:40 MHALL30.01 1 Manganese (Mn)0.012 mg/L EPA 200.7 05/04/2015 11:40 MHALL30.005 1 Strontium (Sr)0.201 mg/L EPA 200.7 05/04/2015 11:40 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 05/04/2015 11:40 MHALL30.005 1 Analytical Lab Page 10 of 63 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040753 2015012740 Collection Date: 28-Apr-15 3:35 PM Site:SW-1C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/13/2015 14:37 JAHERMA11 Arsenic (As)2.38 ug/L EPA 200.8 05/13/2015 14:37 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/13/2015 14:37 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/13/2015 14:37 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/13/2015 14:37 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/13/2015 14:37 JAHERMA11 Copper (Cu)9.13 ug/L EPA 200.8 05/13/2015 14:37 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/13/2015 14:37 JAHERMA11 Molybdenum (Mo)13.3 ug/L EPA 200.8 05/13/2015 14:37 JAHERMA11 Nickel (Ni)1.30 ug/L EPA 200.8 05/13/2015 14:37 JAHERMA11 Selenium (Se)1.90 ug/L EPA 200.8 05/13/2015 14:37 JAHERMA11 Thallium (Tl) Low Level 0.209 ug/L EPA 200.8 05/13/2015 14:37 JAHERMA0.2 1 Vanadium (V) Low Level 3.29 ug/L EPA 200.8 05/13/2015 14:37 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/08/2015 12:45 JAHERMA11 Arsenic (As)2.77 ug/L EPA 200.8 05/08/2015 12:45 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/08/2015 12:45 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/08/2015 12:45 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/08/2015 12:45 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/08/2015 12:45 JAHERMA11 Copper (Cu)9.88 ug/L EPA 200.8 05/08/2015 12:45 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/08/2015 12:45 JAHERMA11 Molybdenum (Mo)13.6 ug/L EPA 200.8 05/08/2015 12:45 JAHERMA11 Nickel (Ni)1.41 ug/L EPA 200.8 05/08/2015 12:45 JAHERMA11 Selenium (Se)1.85 ug/L EPA 200.8 05/08/2015 12:45 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/08/2015 12:45 JAHERMA0.2 1 Vanadium (V) Low Level 4.05 ug/L EPA 200.8 05/08/2015 12:45 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 150 mg/L SM2540C 04/30/2015 14:23 AGIBBS5251 Total Carbon TOC 5.9 mg/L SM5310C/EPA9060A 05/05/2015 13:25 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 05/01/2015 08:50 AGIBBS551 Analytical Lab Page 11 of 63 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040753 2015012740 Collection Date: 28-Apr-15 3:35 PM Site:SW-1C Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF Analytical Lab Page 12 of 63 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040753 2015012741 Collection Date: 28-Apr-15 3:45 PM Site:SW-1C Dup Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.143 mg-N/L EPA 353.2 04/30/2015 13:24 LSTARL10.01 1 INORGANIC IONS BY IC Chloride 30 mg/L EPA 300.0 05/04/2015 11:48 BGN9034110 Sulfate 35 mg/L EPA 300.0 05/04/2015 11:48 BGN9034110 MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY DISSOLVED METALS BY ICP Aluminum (Al)0.047 mg/L EPA 200.7 04/30/2015 10:18 MHALL30.005 1 Barium (Ba)0.046 mg/L EPA 200.7 04/30/2015 10:18 MHALL30.005 1 Boron (B)0.204 mg/L EPA 200.7 04/30/2015 10:18 MHALL30.05 1 Iron (Fe)0.052 mg/L EPA 200.7 04/30/2015 10:18 MHALL30.01 1 Manganese (Mn)0.007 mg/L EPA 200.7 04/30/2015 10:18 MHALL30.005 1 Strontium (Sr)0.200 mg/L EPA 200.7 04/30/2015 10:18 MHALL30.005 1 Zinc (Zn)0.039 mg/L EPA 200.7 04/30/2015 10:18 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)10.8 mg/L EPA 200.7 04/30/2015 12:47 MHALL30.01 1 Magnesium (Mg)5.00 mg/L EPA 200.7 04/30/2015 12:47 MHALL30.005 1 Potassium (K)5.82 mg/L EPA 200.7 04/30/2015 12:47 MHALL30.1 1 Sodium (Na)27.5 mg/L EPA 200.7 04/30/2015 12:47 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.123 mg/L EPA 200.7 05/04/2015 11:44 MHALL30.005 1 Barium (Ba)0.052 mg/L EPA 200.7 05/04/2015 11:44 MHALL30.005 1 Boron (B)0.211 mg/L EPA 200.7 05/04/2015 11:44 MHALL30.05 1 Iron (Fe)0.144 mg/L EPA 200.7 05/04/2015 11:44 MHALL30.01 1 Manganese (Mn)0.013 mg/L EPA 200.7 05/04/2015 11:44 MHALL30.005 1 Strontium (Sr)0.203 mg/L EPA 200.7 05/04/2015 11:44 MHALL30.005 1 Zinc (Zn)0.006 mg/L EPA 200.7 05/04/2015 11:44 MHALL30.005 1 Analytical Lab Page 13 of 63 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040753 2015012741 Collection Date: 28-Apr-15 3:45 PM Site:SW-1C Dup Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/13/2015 14:42 JAHERMA11 Arsenic (As)2.38 ug/L EPA 200.8 05/13/2015 14:42 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/13/2015 14:42 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/13/2015 14:42 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/13/2015 14:42 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/13/2015 14:42 JAHERMA11 Copper (Cu)8.54 ug/L EPA 200.8 05/13/2015 14:42 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/13/2015 14:42 JAHERMA11 Molybdenum (Mo)13.2 ug/L EPA 200.8 05/13/2015 14:42 JAHERMA11 Nickel (Ni)1.23 ug/L EPA 200.8 05/13/2015 14:42 JAHERMA11 Selenium (Se)1.69 ug/L EPA 200.8 05/13/2015 14:42 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/13/2015 14:42 JAHERMA0.2 1 Vanadium (V) Low Level 3.04 ug/L EPA 200.8 05/13/2015 14:42 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)1.08 ug/L EPA 200.8 05/08/2015 12:50 JAHERMA11 Arsenic (As)2.87 ug/L EPA 200.8 05/08/2015 12:50 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/08/2015 12:50 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/08/2015 12:50 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/08/2015 12:50 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/08/2015 12:50 JAHERMA11 Copper (Cu)9.99 ug/L EPA 200.8 05/08/2015 12:50 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/08/2015 12:50 JAHERMA11 Molybdenum (Mo)13.0 ug/L EPA 200.8 05/08/2015 12:50 JAHERMA11 Nickel (Ni)1.59 ug/L EPA 200.8 05/08/2015 12:50 JAHERMA11 Selenium (Se)1.82 ug/L EPA 200.8 05/08/2015 12:50 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/08/2015 12:50 JAHERMA0.2 1 Vanadium (V) Low Level 4.08 ug/L EPA 200.8 05/08/2015 12:50 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 150 mg/L SM2540C 04/30/2015 14:23 AGIBBS5251 Total Carbon TOC 5.9 mg/L SM5310C/EPA9060A 05/05/2015 13:25 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 05/01/2015 08:50 AGIBBS551 Analytical Lab Page 14 of 63 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040753 2015012741 Collection Date: 28-Apr-15 3:45 PM Site:SW-1C Dup Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF Analytical Lab Page 15 of 63 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040753 2015012742 Collection Date: 29-Apr-15 9:50 AM Site:Equipment Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.015 mg-N/L EPA 353.2 04/30/2015 13:25 LSTARL10.01 1 INORGANIC IONS BY IC Chloride < 0.1 mg/L EPA 300.0 05/04/2015 09:42 BGN90340.1 1 Sulfate < 0.1 mg/L EPA 300.0 05/04/2015 09:42 BGN90340.1 1 UNDIGESTED METALS BY ICP Calcium (Ca)0.025 mg/L EPA 200.7 04/30/2015 12:59 MHALL30.01 1 Magnesium (Mg)< 0.005 mg/L EPA 200.7 04/30/2015 12:59 MHALL30.005 1 Potassium (K)< 0.1 mg/L EPA 200.7 04/30/2015 12:59 MHALL30.1 1 Sodium (Na)0.062 mg/L EPA 200.7 04/30/2015 12:59 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.020 mg/L EPA 200.7 05/04/2015 11:47 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 05/04/2015 11:47 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 05/04/2015 11:47 MHALL30.05 1 Iron (Fe)0.012 mg/L EPA 200.7 05/04/2015 11:47 MHALL30.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 05/04/2015 11:47 MHALL30.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 05/04/2015 11:47 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 05/04/2015 11:47 MHALL30.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/08/2015 12:54 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 05/08/2015 12:54 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/08/2015 12:54 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/08/2015 12:54 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/08/2015 12:54 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/08/2015 12:54 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/08/2015 12:54 JAHERMA11 Lead (Pb)1.01 ug/L EPA 200.8 05/08/2015 12:54 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 05/08/2015 12:54 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/08/2015 12:54 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/08/2015 12:54 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/08/2015 12:54 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 05/08/2015 12:54 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 Analytical Lab Page 16 of 63 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040753 2015012742 Collection Date: 29-Apr-15 9:50 AM Site:Equipment Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 04/30/2015 14:23 AGIBBS5251 Total Carbon TOC 0.155 mg/L SM5310C/EPA9060A 05/05/2015 13:25 GHUTCHI0.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 05/01/2015 08:50 AGIBBS551 Analytical Lab Page 17 of 63 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040753 2015012743 Collection Date: Site:FIELD BLANK Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY Analytical Lab Page 18 of 63 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040753 2015012744 Collection Date: Site:Trip Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF MERCURY IN WATER - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY Analytical Lab Page 19 of 63 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040753 2015012745 Collection Date: Site:Filter Blank Matrix: GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 04/30/2015 10:22 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 04/30/2015 10:22 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 04/30/2015 10:22 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 04/30/2015 10:22 MHALL30.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 04/30/2015 10:22 MHALL30.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 04/30/2015 10:22 MHALL30.005 1 Zinc (Zn)0.013 mg/L EPA 200.7 04/30/2015 10:22 MHALL30.005 1 DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 05/13/2015 14:46 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 05/13/2015 14:46 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 05/13/2015 14:46 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 05/13/2015 14:46 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 05/13/2015 14:46 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 05/13/2015 14:46 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 05/13/2015 14:46 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 05/13/2015 14:46 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 05/13/2015 14:46 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 05/13/2015 14:46 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 05/13/2015 14:46 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 05/13/2015 14:46 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 05/13/2015 14:46 JAHERMA0.3 1 Analytical Lab Page 20 of 63 1 Ogle, Mary A From:Ogle, Mary A Sent:Thursday, April 30, 2015 1:55 PM To:'mmcdade@synterracorp.com'; 'hsmith@synterracorp.com' Subject:Sutton Surface water Attachments:FullSizeRender.jpg; ATT00001.txt; COCf.jpg Hi Mark and Heather. This COC had a couple of issues I wanted to bring to your attention. An equipment blank was sent in , but not included on the COC. I thought we were not going to receive equipment blanks for surface water samples? The TDS/TSS bottle for was received with the label not completed -by process of elimination we are assuming this to be SW-CF001 (see attached photo). Thanks Mary Ann Ogle Duke Energy Analytical Lab Office 980-875-5274 Cell 704-280-7956 -----Original Message----- From: Mary Ann Ogle [mailto:mogle@carolina.rr.com] Sent: Thursday, April 30, 2015 1:39 PM To: Ogle, Mary A Subject: *** Exercise caution. This is an EXTERNAL email. DO NOT open attachments or click links from unknown senders or unexpected email. *** Analytical Lab Page 21 of 63 Analytical Lab Page 22 of 63 SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle QD30036Lot Number: J15040753Project Number: AB GW Assessment Water - SuttonProject Name: 05/07/2015Date Completed: Grant Wilton Project Manager *QD30036* This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. Page: 1 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Case Narrative Duke Energy Lot Number: QD30036 SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329 Project Name: AB GW Assessment Water - Sutton Project Number: J15040753 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. Page: 2 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: QD30036 Project Name: AB GW Assessment Water - Sutton Project Number: J15040753 Sample Number Sample ID Matrix Date Sampled Date Received 001 04/28/2015 14002015012738Aqueous 04/30/2015 002 04/28/2015 16552015012739Aqueous 04/30/2015 003 04/28/2015 15352015012740Aqueous 04/30/2015 004 04/28/2015 15452015012741Aqueous 04/30/2015 005 04/28/2015 09502015012742Aqueous 04/30/2015 006 04/28/2015 14002015012743Aqueous 04/30/2015 007 04/28/2015 14002015012744Aqueous 04/30/2015 (7 samples) Page: 3 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: QD30036 Project Name: AB GW Assessment Water - Sutton Project Number: J15040753 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2015012738 Aqueous Alkalinity SM 2320B-15 mg/L 5 001 2015012738 Aqueous Bicarbonate Alkalinity SM 2320B-15 mg/L 5 001 2015012738 Aqueous Methane RSK - 175 13 ug/L 6 001 2015012738 Aqueous Mercury (CVAFS)1631E 4.99 ng/L 7 002 2015012739 Aqueous Alkalinity SM 2320B-17 mg/L 8 002 2015012739 Aqueous Bicarbonate Alkalinity SM 2320B-17 mg/L 8 002 2015012739 Aqueous Methane RSK - 175 11 ug/L 9 002 2015012739 Aqueous Mercury (CVAFS)1631E 2.17 ng/L 10 003 2015012740 Aqueous Alkalinity SM 2320B-29 mg/L 11 003 2015012740 Aqueous Bicarbonate Alkalinity SM 2320B-29 mg/L 11 003 2015012740 Aqueous Mercury (CVAFS)1631E 0.717 ng/L 13 004 2015012741 Aqueous Alkalinity SM 2320B-30 mg/L 14 004 2015012741 Aqueous Bicarbonate Alkalinity SM 2320B-30 mg/L 14 004 2015012741 Aqueous Mercury (CVAFS)1631E 0.672 ng/L 16 (14 detections) Page: 4 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012738 QD30036-001 04/28/2015 1400 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040753 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/02/2015 1542 HMA 73874 1 (Bicarbonate ) SM 2320B-2011 1 05/02/2015 1542 BWS 1 (Carbonate Al) SM 2320B-2011 1 05/02/2015 1542 BWS AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 15 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 15 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 5 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012738 QD30036-001 04/28/2015 1400 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040753 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 RSK - 175 1 05/05/2015 1436 DCS 74077 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 13 2ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 6 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Mercury (CVAFS) Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012738 QD30036-001 04/28/2015 1400 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040753 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631E 1 05/04/2015 1502 COH 05/01/2015 2030 73796 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Mercury (CVAFS)7439-97-6 1631E 4.99 1ng/L0.500 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 7 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012739 QD30036-002 04/28/2015 1655 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040753 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/02/2015 1546 HMA 73874 1 (Bicarbonate ) SM 2320B-2011 1 05/02/2015 1546 BWS 1 (Carbonate Al) SM 2320B-2011 1 05/02/2015 1546 BWS AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 17 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 17 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 8 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012739 QD30036-002 04/28/2015 1655 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040753 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 RSK - 175 1 05/05/2015 1451 DCS 74077 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 11 2ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 9 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Mercury (CVAFS) Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012739 QD30036-002 04/28/2015 1655 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040753 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631E 1 05/04/2015 1516 COH 05/01/2015 2030 73796 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Mercury (CVAFS)7439-97-6 1631E 2.17 1ng/L0.500 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 10 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012740 QD30036-003 04/28/2015 1535 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040753 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/02/2015 1552 HMA 73874 1 (Bicarbonate ) SM 2320B-2011 1 05/02/2015 1552 BWS 1 (Carbonate Al) SM 2320B-2011 1 05/02/2015 1552 BWS AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 29 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 29 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 11 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012740 QD30036-003 04/28/2015 1535 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040753 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 RSK - 175 1 05/05/2015 1634 DCS 74077 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 2ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 12 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Mercury (CVAFS) Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012740 QD30036-003 04/28/2015 1535 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040753 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631E 1 05/04/2015 1520 COH 05/01/2015 2030 73796 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Mercury (CVAFS)7439-97-6 1631E 0.717 1ng/L0.500 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 13 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012741 QD30036-004 04/28/2015 1545 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040753 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/02/2015 1610 HMA 73874 1 (Bicarbonate ) SM 2320B-2011 1 05/02/2015 1610 BWS 1 (Carbonate Al) SM 2320B-2011 1 05/02/2015 1610 BWS AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 30 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 30 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 14 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012741 QD30036-004 04/28/2015 1545 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040753 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 RSK - 175 1 05/05/2015 1647 DCS 74077 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 2ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 15 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Mercury (CVAFS) Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012741 QD30036-004 04/28/2015 1545 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040753 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631E 1 05/04/2015 1525 COH 05/01/2015 2030 73796 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Mercury (CVAFS)7439-97-6 1631E 0.672 1ng/L0.500 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 16 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012742 QD30036-005 04/28/2015 0950 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040753 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/02/2015 1615 HMA 73874 1 (Bicarbonate ) SM 2320B-2011 1 05/02/2015 1615 BWS 1 (Carbonate Al) SM 2320B-2011 1 05/02/2015 1615 BWS AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 17 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012742 QD30036-005 04/28/2015 0950 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040753 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 RSK - 175 1 05/05/2015 1701 DCS 74077 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 2ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 18 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Mercury (CVAFS) Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012743 QD30036-006 04/28/2015 1400 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040753 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631E 1 05/04/2015 1529 COH 05/01/2015 2030 73796 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Mercury (CVAFS)7439-97-6 1631E ND 1ng/L0.500 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 19 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Mercury (CVAFS) Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015012744 QD30036-007 04/28/2015 1400 04/30/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040753 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631E 1 05/04/2015 1534 COH 05/01/2015 2030 73796 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Mercury (CVAFS)7439-97-6 1631E ND 1ng/L0.500 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 20 of 20 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 QC Summary QC Data for Lot Number: QD30036 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MB Batch: Sample ID:QQ73874-001 73874 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Alkalinity ND 05/02/2015 141410mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD30036 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - LCS Batch: Sample ID:QQ73874-002 73874 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Alkalinity 92 05/02/2015 14219210090-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD30036 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MS Batch: Sample ID:QD30036-003MS 73874 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Alkalinity 120 05/02/2015 15589310070-130291 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD30036 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MSD Batch: Sample ID:QD30036-003MD 73874 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD Limit Sample Amount Dil(mg/L)(mg/L)(mg/L) Alkalinity 120 05/02/2015 16048910070-1303.0 20291 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD30036 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - MB Batch: Sample ID:QQ74077-001 74077 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 05/05/2015 100410ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD30036 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCS Batch: Sample ID:QQ74077-002 74077 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 120 05/05/2015 09348115070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD30036 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCSD Batch: Sample ID:QQ74077-003 74077 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 130 05/05/2015 09218415070-1302.9 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD30036 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Mercury (CVAFS) - MB Batch:Prep Method: Prep Date: Sample ID:QQ73796-001 73796 1631E 05/01/2015 2030Analytical Method:1631E Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Mercury (CVAFS)ND 05/04/2015 14520.500 ng/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD30036 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Mercury (CVAFS) - LCS Batch:Prep Method: Prep Date: Sample ID:QQ73796-002 73796 1631E 05/01/2015 2030Analytical Method:1631E Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ng/L)(ng/L) Mercury (CVAFS)5.47 05/04/2015 14571095.00 75-1251 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD30036 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Mercury (CVAFS) - MS Batch:Prep Method: Prep Date: Sample ID:QD30036-001MS 73796 1631E 05/01/2015 2030Analytical Method:1631E Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec Limit Sample Amount Dil(ng/L)(ng/L)(ng/L) Mercury (CVAFS)6.89 05/04/2015 1506N385.00 71-1254.99 1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD30036 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Mercury (CVAFS) - MSD Batch:Prep Method: Prep Date: Sample ID:QD30036-001MD 73796 1631E 05/01/2015 2030Analytical Method:1631E Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD Limit Sample Amount Dil(ng/L)(ng/L)(ng/L) Mercury (CVAFS)4.88 05/04/2015 1511N,+-2.25.00 71-12534 244.99 1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD30036 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 cy SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Analytical Lab Page 57 of 63 Analytical Lab Page 58 of 63 Analytical Lab Page 59 of 63 Analytical Lab Page 60 of 63 Analytical Lab Page 61 of 63 Analytical Lab Page 62 of 63 Analytical Lab Page 63 of 63