NC0001422_ATT 5 - Water - J15040670report_20150805

{ DUKE Analytical Laboratory
' ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J15040670
Project Name: SUTTON - AB GW ASSESSMENT WATER
Customer Name(s): Perry Waldrep, Tim Hunsucker, Kathy Webb, John Toepfer
Customer Address:
Lab Contact: Mary Ann Ogle Phone: [phone]
Mary Ann Ogle
'7 1 2015.05,11 15:08:52
Report Authorized By: Date:
(Signature) {� 04'OQ_
Mary Ann Ogle
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
5/11/2015
Page 1 of 51
Any analytical tests or individual analyses within a test flagged with a Qualifier Indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
Included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative, An estimation of
the uncertainty of measurement for the results In the report is available upon request. This report shall not be reproduced, except
In full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Reporl, Sarnple identificalion, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Sample ID
2015012311
2015012312
2015012313
2015012314
2015012315
2015012316
2015012317
2015012318
8 Total Samples
Page 2 of 51
Collection
Plant/Station
Date and Time
Collected By
Sample Description
Sutton
27-Apr-15 2:25 PM
Richard Jacobs
SMW-1B
Sutton
27-Apr-15 2:21 PM
Richard Jacobs
SMW-IC p7s
Sutton
27-Apr-15 12:28 PM
Richard Jacobs
SW,8
Sutton
27-Apr-15 12:30 PM
Richard Jacobs
SW-3C
Sutton
27-Apr-15 9:50 AM
Richard Jacobs
ABMW-2S
Sutton
27-Apr-15 9:23 AM
Richard Jacobs
ABMW-2D
Sutton
27-Apr-15 9:15 AM
Richard Jacobs
Filter Blank
Sutton
27-Apr-15 9:15 AM
Richard Jacobs
Equipment Blank

Page 3 of 51
Technical Validation Review
Checklist:
CQC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. Yes �, No
All laboratory QA/QC requirements are acceptable. Yes No
Report Sections Included:
VI Job Summary Report
di Sample Identification
e Technical Validation of Data Package
Analytical Laboratory Certificate of Analysis
1 Analytical Laboratory QC Report
V] Sub -contracted Laboratory Results
Customer Specific Data Sheets, Reports, & Documentation
] Customer Database Entries
Chain of Custody
IV', Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: DBA Account Date: 5/11/2015

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040670
Site: SMW-16
Collection Date: 27-Apr-15 2:25 PM
Analyte Result
Units Qualifiers
RDL
DF
ALKALINITY • (Analysis Performed by Shealy Labs
Vendor Parameter Complete
NITRITE +NITRATE (COLOR IMETRIC
Nitrite + Nitrate (Colorimetric) 0.385
mg-N/L
0.01
1
INORGANIC IONS BY IC
Chloride 12
mg/L
I
10
Sulfate 40
mg/L
1
10
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg) < 0.05
ug/L
0.05
1
Mercury Dissolved cold vaporvaporl in Water Filtered
Mercury (Hg) < 0.05
ug/L
0.05
1
DISSOLVED METALS BY ICP
Aluminum (Al) 0.237
mg/L
0.005
1
Barium (Ba) 0.083
mg/L
0.005
1
Boron (B) 0.131
mg/L
0.05
1
Iron (Fe) 0.403
mg/L
0.01
1
Manganese (Mn) 0.011
mg/L
0.005
1
Strontium (Sr) 0.040
mg/L
0.005
.1
Zinc (Zn) 0.007
mg/L
0.005
1
UNDIGESTED METALS BY ICP
Calcium (Ca) 14.4
mg/L
0.01
1
Magnesium (Mg) 1.18
mg/L
0.005
1
Potassium (K) 1.85
mg/L
0.1
1
Sodium (Na) 8.56
mg/L
0.05
1
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI) 0.301
mg/L
0.005
1
Barium (Be) 0.082
mg/L
0.005
1
Boron (B) 0.138
mg/L
0.05
1
Iron (Fe) 0.591
mg/L
0.01
1
Manganese (Mn) 0.012
mg/L
0.005
1
Strontium (Sr) 0.040
mg/L
0.005
1
Zinc (Zn) < 0.005
mg/L
0.005
I
Sample #: 2015012311
Matrix: GW W W
Page 4 of 51
Method
Analysis Date/Time
Analyst
Vendor Method
V_SHEALY
EPA 353.2
04/30/2015 09:56
LSTARL1
EPA 300.0
05/04/2015 11:45
BGN9034
EPA 300.0
05/04/2015 11:45
BGN9034
EPA 245.1
04/29/2015 15:03
ACPAYNE
EPA 245.1
04/29/2015 15:41
ACPAYNE
EPA 200Y
04/29/2015 10:49
MHALL3
EPA 200.7
04/29/2015 10:49
MHALL3
EPA 200.7
04/29/2015 10:49
MHALL3
EPA 200.7
04/29/2015 10:49
MHALL3
EPA 200.7
04/29/2015 10:49
MHALL3
EPA 200.7
04/29/2015 10:49
MHALL3
EPA 200.7
04/29/2015 10:49
MHALL3
EPA 200.7
04/29/2015 12:49
MHALL3
EPA 200.7
04/29/2015 12:49
MHALL3
EPA 200.7
04/29/2015 12:49
MHALL3
EPA 200.7
04/29/2015 12:49
MHALL3
EPA 200.7
05/01/2015 12:44
MHALL3
EPA 200.7
05/01/2015 12:44
MHALL3
EPA 200.7
05/01/2015 12:44
MHALL3
EPA 200.7
05/01/2015 12:44
MHALL3
EPA 200.7
05/01/2015 12:44
MHALL3
EPA 200.7
05/01/2015 12:44
MHALL3
EPA 200.7
05/01/2015 12:44
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # A 5040670
Site: SMW-16
Collection Date: 27-Apr-15 2:25 PM
Analyte
Result
DISSOLVED METALS BY ICP-MS
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
< 1
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
TOTAL RECOVERABLE METALS BY ICP-MI5
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper(Cu)
<1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
< 1
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
METHANE • Anal sls Performed b
Sheal Labs
Methane (CH4)
Complete
SULFIDE (Analysis Performed by
Element One
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
90
Total Carbon
TOC
0.948
TOTAL' SUSPENDED SOLID
TSS
< 5
Sample #: 2015012311
Matrix: GW WW
Page 5 of 51
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
ug/L
1
1
EPA 200.8
04/30/2015 15:33
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 15:33
JAHERMA
ug/L
1
I
EPA 200.8
04/30/2015 15:33
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 15:33
JAHERMA
ug/L
1
t
EPA 200.8
04/30/2015 15:33
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 15:33
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 15:33
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 15:33
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 15:33
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 15:33
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 15:33
JAHERMA
ug/L
0.2
1
EPA 200.8
04/30/2015 15:33
JAHERMA
ug/L
0.3
1
EPA 200.8
04/30/2015 15:33
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:41
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:41
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:41
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:41
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:41
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:41
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:41
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:41
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:41
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:41
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:41
JAHERMA
ug/L
0.2
1
EPA 200.8
05/07/2015 14:41
JAHERMA
ug/L
0.3
1
EPA 200.8
05/07/2015 14:41
JAHERMA
Vendor Method V_SHEALY
Vendor Method V_ELE1
mg/L
25
1 SM2540C
04/28/201514:19
AGIBBS5
mg/L
0.1
1 SM5310C/EPA9060A
05/04/201512:15
GHUTCHI
mg/L
5
1 SM2540D
04/29/201511:24
AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # A 5040670
Site: SMW-1 C
Collection Date: 27-Apr-I5 2:21 PM
Analyte
Result
Units Qualifiers
ROL
ALKALINITY • (Analysis Performed
by Shealy La".
Vendor Parameter
Complete
NITRITE + NITRATE ICQLORINiETRIC
Nitrite + Nitrate (Colorimetric)
0.015
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
60
mg/L
1
Sulfate
140
mg/L
2
MERCURY COLD VAPOR IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved cold vapor In Water Filtered
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (Al)
0.034
mg/L
0.005
Barium (Ba)
0.038
mg/L
0.005
Boron (B)
0.781
mg/L
0.05
Iron (Fe)
8.95
mg/L
0.01
Manganese (Mn)
0.845
mg/L
0.005
Strontium (Sr)
0.462
mg/L
0.005
Zinc (Zn)
0.011
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
38.1
mg/L
0.01
Magnesium (Mg)
8.47
mg/L
0.005
Potassium (K)
5.77
mg/L
0.1
Sodium (Na)
42.4
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)
0.154
mg/L
0.005
Barium (Ba)
0.038
mg/L
0.005
Boron (B)
0.783
mg/L
0.05
Iron (Fe)
9.17
mg/L
0.01
Manganese (Mn)
0.852
mg/L
0.005
Strontium (Sr)
0.467
mg/L
0.005
Zinc (Zn)
0.006
mg/L
0.005
Sample #: 2015012312
Matrix: GW WW
Page 6 of 51
OF Method Analysis Date/Time Analyst
Vendor Method V__SHEALY
1
EPA 353.2
04/30/2015 09:57
LSTARL1
10
EPA 300.0
05/04/2015 13:50
BGN9034
20
EPA 300.0
05/04/2015 13:50
BGN9034
1
EPA 245.1
04/29/2015 14:56
ACPAYNE
1
EPA 245.1
04/29/2015 15:43
ACPAYNE
I
EPA 200.7
04/29/2015 10:45
MHALL3
1
EPA 200.7
04/29/2015 10:45
MHALL3
I
EPA 200.7
04/29/2015 10:45
MHALL3
I
EPA 200.7
04/29/2015 10:45
MHALL3
1
EPA 200.7
04/29/2015 10:45
MHALL3
1
EPA 200.7
04/29/2015 10:45
MHALL3
1
EPA 200.7
04/29/2015 10:45
MHALL3
1
EPA 200.7
04/29/2015 12:53
MHALL3
1
EPA 200.7
04/29/2015 12:53
MHALL3
1
EPA 200.7
04/29/2015 12:53
MHALL3
1
EPA 200.7
04/29/2015 12:53
MHALL3
1
EPA 200.7
05/01/2015 12:48
MHALL3
1
EPA 200.7
05/01/2015 12:48
MHALL3
1
EPA 200.7
05/01/2015 12:48
MHALL3
1
EPA 200.7
05/01/2015 12:48
MHALL3
1
EPA 200.7
05/01/2015 12:48
MHALL3
1
EPA 200.7
05/01/2015 12:48
MHALL3
1
EPA 200.7
05/01/2015 12:48
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040670
Site: SMW-IC
Collection Date: 27-Apr-15 2:21 PM
Analyte
Result
DISSOLVED METALS BY ICP-MS
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
4.88
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
1.73
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
TOTAL RECOVERABLE METALS BY 1CP-MS
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
5.33
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
2.54
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
0.337
METHANE - (Analysis Performed by
Sheal Labs
Methane (CH4)
Complete
SULFIDE - (Analysis Pe armed by
Element One
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
330
Total Carbon
TOC
0.708
TOTAL SUSPENDED SOLIDS
TSS
< 5
Sample #: 2015012312
Matrix: GW WW
Page 7 of 51
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
ug/L
1
i
EPA 200.8
04/30/2015 15:55
JAHERMA
ug/L
1
EPA 200.8
04/30/2015 15:55
JAHERMA
ug/L
p
1
EPA 200.8
04/30/2015 15:55
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 15:55
JAHERMA
ug/L
1
i
EPA 200.8
04/30/2015 15:55
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 15:55
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 15:55
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 15:55
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 15:55
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 15:55
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 15:55
JAHERMA
ug/L
0.2
1
EPA 200.8
04/30/2015 15:55
JAHERMA
ug/L
0.3
1
EPA 200.8
04/30/2015 15:55
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:54
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:54
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:54
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:54
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:54
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:54
JAHERMA
ug/L
1
➢
EPA 200.8
05/07/2016 14:54
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:54
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:54
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:54
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:54
JAHERMA
ug/L
0.2
1
EPA 200.8
05/07/2015 14:54
JAHERMA
ug/L
0.3
1
EPA 200.8
05/07/2015 14:54
JAHERMA
Vendor Method
V_SHEALY
mg/L
mg/L
mg/L
Vendor Method V__ELE1
25 1 SM2540C 04/28/201514:19 AGIBBS5
0.1 1 SM5310C/EPA9060A 05/04/201512:15 GHUTCHI
5 1 SM2540D 04/29/201511:24 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # A 5040670
Site: SW-3, WS
Collection Date: 27-Apr-15 12:28 PM
Analyte
Result
Units Qualifiers
RDL
ALKALINITY - Anal sis Performed b Sheal Labs
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
14
mg-N/L
0.5
INORGANIC IONS BY IC
Chloride
6.3
mg/L
0.1
Sulfate
27
mg/L
t
!gERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved cold va or in Water Filtered
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (AI)
0.011
mg/L
0.005
Barium (Ba)
0.044
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.214
mg/L
0.01
Manganese (Mn)
0.056
mg/L
0.005
Strontium (Sr)
0.062
mg/L
0.005
Zinc (Zn)
0.010
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
35.1
mg/L
0.01
Magnesium (Mg)
4.80
mg/L
0.005
Potassium (K)
4.64
mg/L
0.1
Sodium (Na)
5.59
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.055
mg/L
0.005
Barium (Ba)
0.046
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
1.35
mg/L
0.01
Manganese (Mn)
0.057
mg/L
0.005
Strontium (Sr)
0.066
mg/L
0.005
Zinc (Zn)
0.007
mg/L
0.005
Sample #: 2015012313
Matrix: GW W W
Page 8 of 51
DF Method Analysis Date/Time Analyst
Vendor Method V._SHEALY
50 EPA 353.2 04/30/2015 10:04 LSTARL1
1 EPA 300.0 05/04/2015 14:08 BGN9034
10 EPA 300.0 05/04/2015 14:08 BGN9034
1 EPA 245.1 04/29/2015 15:05 ACPAYNE
t EPA 245.1 04/29/2015 15:46 ACPAYNE
1 EPA 200.7
04/29/2015 10:34
MHALL3
1 EPA 200.7
04/29/2015 10:34
MHALL3
1 EPA 200.7
04/29/2015 10:34
MHALL3
1 EPA 200.7
04/29/2015 10:34
MHALL3
t EPA 200.7
04/29/2015 10:34
MHALL3
7 EPA 200.7
04/29/2015 10:34
MHALL3
1 EPA 200.7
04/29/2015 10:34
MHALL3
I EPA 200.7
04/29/2015 13:25
MHALL3
EPA 200.7
04/29/2015 13:25
MHALL3
k EPA 200,7
04/29/2015 13:25
MHALL3
EPA 200.7
04/29/2015 13:25
MHALL3
1 EPA 200.7
05/01/2015 12:51
MHALL3
1 EPA 200.7
05/01/2015 12:51
MHALL3
i EPA 200.7
05/01/2015 12:51
MHALL3
I EPA 200.7
05/01/2015 12:51
MHALL3
1 EPA 200.7
05/01/2015 12:51
MHALL3
t EPA 200.7
05/01/2015 12:51
MHALL3
1 EPA 200.7
05/01/2015 12:51
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # A 5040670
Site: SW-3Vo
Collection Date: 27-Apr-15 12:28 PM
Analyte
Result
DISSOLVED METALS BY 1CP-MS
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
1.19
Copper(Cu)
<1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
2.03
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
TOTAL RECOVERABLE METALS BY_ICP-MS
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
1.42
Copper(Cu)
1.03
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
3.13
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
0.324
METHANE - (AnafZsis Performed by
Shealy Labs
Methane (CH4)
Complete
SULFIDE (Analysis Performed by
Element One
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
200
Total Carbon
TOC
2.5
TOTAL SUSPENDED SOLIDS
TSS
< 5
Sample #: 2015012313
Matrix: GW W W
Page 9 of 51
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
ug/L
1
1
EPA 200.8
04/30/2015 16:09
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 16:09
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 16:09
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 16:09
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 16:09
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 16:09
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 16:09
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 16:09
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 16:09
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 16:09
JAHERMA
ug/L
1
1
EPA 200.8
04/30/2015 16:09
JAHERMA
ug/L
0.2
1
EPA 200.8
04/30/2015 16:09
JAHERMA
ug/L
0.3
1
EPA 200.8
04/30/2015 16:09
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:59
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:59
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:59
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:59
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:59
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:59
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:59
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:59
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:59
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:59
JAHERMA
ug/L
1
1
EPA 200.8
05/07/2015 14:59
JAHERMA
ug/L
0.2
l
EPA 200.8
05/07/2015 14:59
JAHERMA
ug/L
0.3
!
EPA 200.8
05/07/2015 14:59
JAHERMA
Vendor Method
V_SHEALY
mg/L
mg/L
mg/L
Vendor Method V ELE1
25 1 SM2540C 04/28/201514:19 AGIBBS5
0.1 1 SM5310C/EPA9060A 05/04/201512:15 GHUTCHI
5 1 SM2540D 04/29/201511:24 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # A 5040670
Site: SW-3C
Collection Date: 27-Apr-15 12:30 PM
Analyte Result
Units Qualifiers
RDL
ALKALINITY - (Analysis Performed by Shealy Labs
Vendor Parameter Complete
NITRITE + NITRATE COLORIMETRIC
Nitrite + Nitrate (Colorimetric) < 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride 39
mg/L
I
Sulfate 94
mg/L
I
MERCURY (COLD VAPORI Ih1 WATER
Mercury (Hg) < 0.05
ug/L
0.05
Mercury Dis Wvad (cold vapor) in Water (filtered)
Mercury (Hg) < 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
Aluminum (Al) 0.097
mg/L
0.005
Barium (Ba) 0.086
mg/L
0.005
Boron (B) 0.444
mg/L
0.05
Iron (Fe) 2.01
mg/L
0.01
Manganese (Mn) 0.682
mg/L
0.005
Strontium (Sr) 0.227
mg/L
0.005
Zinc (Zn) 0.009
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca) 28.1
mg/L
0.01
Magnesium (Mg) 5.48
mg/L
0.005
Potassium (K) 3.67
mg/L
0.1
Sodium (Na) 25.6
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI) 0.139
mg/L
0.005
Barium (Ba) 0.088
mg/L
0.005
Boron (B) 0.465
mg/L
0.05
Iron (Fe) 2.42
mg/L
0.01
Manganese (Mn) 0.719
mg/L
0.005
Strontium (Sr) 0.235
mg/L
0.005
Zinc (Zn) 0.006
mg/L
0.005
Sample #: 2015012314
Matrix: GW WW
Page 10 of 51
DF Method Analysis DatelTime Analyst
Vendor Method V_SHEALY
1 EPA 353.2
04/30/2015 10:03
LSTARL1
10 EPA 300.0
05/04/2015 12:39
BGN9034
10 EPA 300.0
05/04/2015 12:39
BGN9034
1 EPA 245.1
04/29/2015 15:08
ACPAYNE
1 EPA 245.1
04/29/2015 15:48
ACPAYNE
[ EPA 200.7
04/29/2015 10:53
MHALL3
1 EPA 200.7
04/29/2015 10:53
MHALL3
1 EPA 200.7
04/29/2015 10:53
MHALL3
1 EPA 200.7
04/29/2015 10:53
MHALL3
1 EPA 200.7
04/29/2015 10:53
MHALL3
1 EPA 200.7
04/29/2015 10:53
MHALL3
1 EPA 200.7
04/29/2015 10:53
MHALL3
i EPA 200.7
04/29/2015 13:36
MHALL3
1 EPA 200.7
04/29/2015 13:36
MHALL3
1 EPA 200.7
04/29/2015 13:36
MHALL3
1 EPA 200.7
04/29/2015 13:36
MHALL3
l EPA 200.7
05/01/2015 12:55
MHALL3
1 EPA 200.7
05/01/2015 12:55
MHALL3
1 EPA 200.7
05/01/2015 12:55
MHALL3
1 EPA 200.7
05/01/2015 12:55
MHALL3
1 EPA 200.7
05/01/2015 12:55
MHALL3
1 EPA 200.7
05/01/2015 12:55
MHALL3
EPA 200.7
05/01/2015 12:55
MHALL3

Certificate of Laboratory Analysis Page 11 of 51
This report shall not be reproduced, except in full.
Order # J15040670
Site: SW-3C
Sample #: 2015012314
Collection Date: 27-Apr-15 12:30 PM
Matrix: GW__WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
DISSOLVED METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
04/30/2015 16:14
JAHERMA
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
04/30/2015 16:14
JAHERMA
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
04/30/2015 16:14
JAHERMA
Cadmium (Cd)
< 1
ug/L
1
P
EPA 200.8
04/30/2015 16:14
JAHERMA
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
04/30/2015 16:14
JAHERMA
Cobalt (Co)
13.9
ug/L
1
1
EPA 200.8
04/30/2015 16:14
JAHERMA
Copper (Cu)
< 1
uglL
1
1
EPA 200.8
04/30/2015 16:14
JAHERMA
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
04/30/2015 16:14
JAHERMA
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
04/30/2015 16:14
JAHERMA
Nickel (Ni)
< 1
ug/L
1
t
EPA 200.8
04/30/2015 16:14
JAHERMA
Selenium (Se)
< 1
ug/L
1
i
EPA 200.8
04/30/2015 16:14
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
04/30/2015 16:14
JAHERMA
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
04/30/2015 16:14
JAHERMA
TOTAL RECOVERABLE METALS BY ICP•MS
Antimony (Sb)
< 1
ug/L
1
i
EPA 200.8
05/07/2015 15:03
JAHERMA
Arsenic (As)
< 1
ug/L
1
i
EPA 200.8
05/07/2015 15:03
JAHERMA
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
05/07/2015 15:03
JAHERMA
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
05/07/2015 15:03
JAHERMA
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
05/07/2015 15:03
JAHERMA
Cobalt (Co)
15.4
ug/L
1
1
EPA 200.8
05/07/2015 15:03
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
05/07/2015 15:03
JAHERMA
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
05/07/2015 15:03
JAHERMA
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
05/07/2015 15:03
JAHERMA
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
05/07/2015 15:03
JAHERMA
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
05/07/2015 15:03
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
05/07/2015 15:03
JAHERMA
Vanadium (V) Low Level
0.632
ug/L
0.3
1
EPA 200.8
05/07/2015 15:03
JAHERMA
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V _SHEALY
SULFIDE --(Analysis Performed by
Element 09j
Vendor Parameter
Complete
Vendor Method
V ELE1
TOTAL DISSOLVED SOLIDS
TDS
220
mg/L
25
1
SM2540C
04/28/201514:19
AGIBBS5
Total Carbon
TOC
0.567
mg/L
0.1
1
SM5310C/EPA9060A
05/04/201512:15
GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
1
SM2540D
04/29/2015 11:24
AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040670
Site: ABMW-2S
Collection Date: 27-Apr-15 9:50 AM
Analyse Result
Units Qualifiers
RDL
DF
ALKALINITY - (Analysis Performed U Shealy Labs
Vendor Parameter Complete
NITRITE + N ITRATF f COLORIMETRIC
Nitrite + Nitrate (Colorimetric) 0.020
mg-N/L
0.01
1
INORGANIC IONS BY IC
Chloride 18
mg/L
1
10
Sulfate 2.6
mg/L
0.1
1
MERCURYLCOLa VAPOR) IN WATER
Mercury (Hg) < 0.05
ug/L
0.05
1
Mercury Dissolved (cold vaporrl In Water (Filtered)
Mercury (Hg) < 0.05
ug/L
0.05
1
DISSOLVES} METALS BY ICP
Aluminum (Al) < 0.005
mg/L
0.005
1
Barium (Ba) 1.23
mg/L
0.005
1
Boron (B) 0.223
mg/L
0.05
I
Iron (Fe) 1.16
mg/L
0.01
1
Manganese (Mn) 0.857
mg/L
0.005
1
Strontium (Sr) 1.61
mg/L
0.005
1
Zinc (Zn) < 0.005
mg/L
0.005
1
UNDIGESTED METAO BY ICP
Calcium (Ca) 61.6
mg/L
0.01
'1
Magnesium (Mg) 8.24
mg/L
0.005
1
Potassium (K) 7.54
mg/L
0.1
1
Sodium (Na) 39.6
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI) 0.076
mg/L
0.005
i
Barium (Ba) 1.57
mg/L
0.005
1
Boron (B) 0.229
mg/L
0.05
1
Iron (Fe) 29.2
mg/L
0.01
1
Manganese (Mn) 0.970
mg/L
0.005
1
Strontium (Sr) 1.70
mg/L
0.005
1
Zinc (Zn) < 0.005
mg/L
0.005
1
Sample #: 2015012315
Matrix: GW WW
Page 12 of 51
Method
Analysis Date/Time
Analyst
Vendor Method
V SHEALY
EPA 353.2
04/30/2015 10:05
LSTARL1
EPA 300.0
05/04/2015 14:44
BGN9034
EPA 300.0
05/04/2015 14:44
BGN9034
EPA 245.1
04/29/2015 15:10
ACPAYNE
EPA 245.1 04/29/2015 15:50 ACPAYNE
EPA 200.7
04/29/2015 11:41
MHALL3
EPA 200.7
04/29/2015 11:41
MHALL3
EPA 200.7
04/29/2015 11:41
MHALL3
EPA 200.7
04/29/2015 11:41
MHALL3
EPA 200.7
04/29/2015 11:41
MHALL3
EPA 200.7
04/29/2015 11:41
MHALL3
EPA 200.7
04/29/2015 11:41
MHALL3
EPA 200.7
04/29/2015 12:57
MHALL3
EPA 200.7
04/29/2015 12:57
MHALL3
EPA 200.7
04/29/2015 12:57
MHALL3
EPA 200.7
04/29/2015 12:57
MHALL3
EPA 200.7
05/01/2015 13:26
MHALL3
EPA 200.7
05/01/2015 13:26
MHALL3
EPA 200.7
05/01/2015 13:26
MHALL3
EPA 200.7
05/01/2015 13:26
MHALL3
EPA 200.7
05/01/2015 13:26
MHALL3
EPA 200.7
05/01/2015 13:26
MHALL3
EPA 200.7
05/01/2015 13:26
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # A 5040670
Page 13 of 51
Site: ABMW-2S
Sample #: 2015012315
Collection Date: 27-Apr-I5 9:50 AM
Matrix: GW,_WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
DISSOLVED METALS BYJCP-MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
04/30/2015 16:18
JAHERMA
Arsenic (As)
6.79
ug/L
[
1
EPA 200.8
04/30/2015 16:18
JAHERMA
Beryllium (Be)
< 1
ug/L
i
1
EPA 200.8
04/30/2015 16:18
JAHERMA
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
04/30/2015 16:18
JAHERMA
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
04/30/2015 16:18
JAHERMA
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
04/30/2015 16:18
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
04/30/2015 16:18
JAHERMA
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
04/30/2015 16:18
JAHERMA
Molybdenum (Mo)
18.6
ug/L
1
1
EPA 200.8
04/30/2015 16:18
JAHERMA
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
04/30/2015 16:18
JAHERMA
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
04/30/2015 16:18
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
'1
EPA 200.8
04/30/2015 16:18
JAHERMA
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
04/30/2015 16:18
JAHERMA
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
05/07/2015 15:08
JAHERMA
Arsenic (As)
57.8
ug/L
1
1
EPA 200.8
05/07/2015 15:08
JAHERMA
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
05/07/2015 15:08
JAHERMA
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
05/07/2015 15:08
JAHERMA
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
05/07/2015 15:08
JAHERMA
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
05/07/2015 15:08
JAHERMA
Copper (Cu)
< 1
ug/L
I
1
EPA 200.8
05/07/2015 15:08
JAHERMA
Lead (Pb)
< 1
ug/L
[
1
EPA 200.8
05/07/2015 15:08
JAHERMA
Molybdenum (Mo)
30.1
ug/L
1
1
EPA 200.8
05/07/2015 15:08
JAHERMA
Nickel (Ni)
< 1
ug/L
I
1
EPA 200.8
05/07/2015 15:08
JAHERMA
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
05/07/2015 15:08
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
05/07/2015 15:08
JAHERMA
Vanadium (V) Low Level
2.21
ug/L
0.3
1
EPA 200.8
05/07/2015 15:08
JAHERMA
METHANE . (Analysis Performed by
5heal Labs
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - Anal sls Performed by
Elament On
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
330
mg/L
25
1
SM2540C
04/28/201514:19
AGIBBS5
Total Carbon
TOC
15
mg/L
0.5
5
SM5310C/EPA9060A
05/04/201512:15
GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS
59
mg/L
5
1
SM2540D
04/29/201511:24
AGIBBS5