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Home My WebLink AboutNC0001422_ATT 5 - Water - J15040006report_2015080513339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number:J15040006 Project Name:AB GW ASSESSMENT WATER Lab Contact:Mary Ann Ogle Date:4/21/2015 Customer Address: Customer Name(s):Perry Waldrep, Tim Hunsucker, Kathy Webb, John Toepfer Phone: 980-875-5274 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Mary Ann Ogle Page 1 of 37 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015009207 Sutton 27-Mar-15 1:10 PM ILLEGIBLE MW 37B 2015009208 Sutton 27-Mar-15 3:15 PM ILLEGIBLE MW 37C 2015009209 Sutton 27-Mar-15 11:30 AM ILLEGIBLE Filter Blank 2015009210 Sutton 27-Mar-15 11:30 AM ILLEGIBLE Equipment Blank 4 Total Samples Page 2 of 37 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:DBA Account Date:4/21/2015 Electronic Data Deliverable (EDD) Sent Separately Page 3 of 37 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040006 2015009207 Collection Date:27-Mar-15 1:10 PM Site:MW 37B Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.102 mg-N/L EPA 353.2 04/07/2015 11:51 BGN90340.01 1 INORGANIC IONS BY IC Chloride 5.0 mg/L EPA 300.0 04/06/2015 20:05 JAHERMA220 Sulfate 4.6 mg/L EPA 300.0 04/06/2015 20:05 JAHERMA220 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 04/02/2015 12:36 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 04/08/2015 11:51 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.528 mg/L EPA 200.7 04/01/2015 14:13 MHALL30.005 1 Barium (Ba)0.010 mg/L EPA 200.7 04/01/2015 14:13 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 04/01/2015 14:13 MHALL30.05 1 Iron (Fe)0.702 mg/L EPA 200.7 04/01/2015 14:13 MHALL30.01 1 Manganese (Mn)0.040 mg/L EPA 200.7 04/01/2015 14:13 MHALL30.005 1 Strontium (Sr)0.006 mg/L EPA 200.7 04/01/2015 14:13 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 04/01/2015 14:13 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)0.634 mg/L EPA 200.7 04/01/2015 15:20 MHALL30.01 1 Magnesium (Mg)0.127 mg/L EPA 200.7 04/01/2015 15:20 MHALL30.005 1 Potassium (K)0.263 mg/L EPA 200.7 04/01/2015 15:20 MHALL30.1 1 Sodium (Na)3.08 mg/L EPA 200.7 04/01/2015 15:20 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.557 mg/L EPA 200.7 04/07/2015 08:42 MHH71310.005 1 Barium (Ba)0.010 mg/L EPA 200.7 04/07/2015 08:42 MHH71310.005 1 Boron (B)< 0.05 mg/L EPA 200.7 04/07/2015 08:42 MHH71310.05 1 Iron (Fe)0.687 mg/L EPA 200.7 04/07/2015 08:42 MHH71310.01 1 Manganese (Mn)0.038 mg/L EPA 200.7 04/07/2015 08:42 MHH71310.005 1 Strontium (Sr)0.006 mg/L EPA 200.7 04/07/2015 08:42 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 04/07/2015 08:42 MHH71310.005 1 Page 4 of 37 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040006 2015009207 Collection Date:27-Mar-15 1:10 PM Site:MW 37B Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/17/2015 11:58 DJSULL111 Arsenic (As)< 1 ug/L EPA 200.8 04/17/2015 11:58 DJSULL111 Beryllium (Be)< 1 ug/L EPA 200.8 04/17/2015 11:58 DJSULL111 Cadmium (Cd)< 1 ug/L EPA 200.8 04/17/2015 11:58 DJSULL111 Chromium (Cr)< 1 ug/L EPA 200.8 04/17/2015 11:58 DJSULL111 Cobalt (Co)< 1 ug/L EPA 200.8 04/17/2015 11:58 DJSULL111 Copper (Cu)< 1 ug/L EPA 200.8 04/17/2015 11:58 DJSULL111 Lead (Pb)< 1 ug/L EPA 200.8 04/17/2015 11:58 DJSULL111 Molybdenum (Mo)< 1 ug/L EPA 200.8 04/17/2015 11:58 DJSULL111 Nickel (Ni)< 1 ug/L EPA 200.8 04/17/2015 11:58 DJSULL111 Selenium (Se)< 1 ug/L EPA 200.8 04/17/2015 11:58 DJSULL111 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/17/2015 11:58 DJSULL10.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/17/2015 11:58 DJSULL10.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/16/2015 13:11 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 04/16/2015 13:11 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 04/16/2015 13:11 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 04/16/2015 13:11 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 04/16/2015 13:11 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 04/16/2015 13:11 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 04/16/2015 13:11 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 04/16/2015 13:11 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 04/16/2015 13:11 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 04/16/2015 13:11 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 04/16/2015 13:11 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/16/2015 13:11 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/16/2015 13:11 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 04/02/2015 11:49 AGIBBS5251 Total Carbon TOC 0.663 mg/L SM5310C/EPA9060A 04/08/2015 12:53 TJA70670.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 04/02/2015 11:00 AGIBBS551 Page 5 of 37 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040006 2015009208 Collection Date:27-Mar-15 3:15 PM Site:MW 37C Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/07/2015 11:52 BGN90340.01 1 INORGANIC IONS BY IC Chloride 4.2 mg/L EPA 300.0 04/06/2015 20:54 JAHERMA220 Sulfate 10 mg/L EPA 300.0 04/06/2015 20:54 JAHERMA220 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 04/02/2015 12:16 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 04/08/2015 10:58 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.023 mg/L EPA 200.7 04/01/2015 14:24 MHALL30.005 1 Barium (Ba)0.043 mg/L EPA 200.7 04/01/2015 14:24 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 04/01/2015 14:24 MHALL30.05 1 Iron (Fe)9.32 mg/L EPA 200.7 04/01/2015 14:24 MHALL30.01 1 Manganese (Mn)0.238 mg/L EPA 200.7 04/01/2015 14:24 MHALL30.005 1 Strontium (Sr)0.020 mg/L EPA 200.7 04/01/2015 14:24 MHALL30.005 1 Zinc (Zn)0.011 mg/L EPA 200.7 04/01/2015 14:24 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)8.77 mg/L EPA 200.7 04/01/2015 15:43 MHALL30.01 1 Magnesium (Mg)1.81 mg/L EPA 200.7 04/01/2015 15:43 MHALL30.005 1 Potassium (K)4.98 mg/L EPA 200.7 04/01/2015 15:43 MHALL30.1 1 Sodium (Na)3.16 mg/L EPA 200.7 04/01/2015 15:43 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.171 mg/L EPA 200.7 04/07/2015 08:54 MHH71310.005 1 Barium (Ba)0.043 mg/L EPA 200.7 04/07/2015 08:54 MHH71310.005 1 Boron (B)< 0.05 mg/L EPA 200.7 04/07/2015 08:54 MHH71310.05 1 Iron (Fe)9.50 mg/L EPA 200.7 04/07/2015 08:54 MHH71310.01 1 Manganese (Mn)0.233 mg/L EPA 200.7 04/07/2015 08:54 MHH71310.005 1 Strontium (Sr)0.020 mg/L EPA 200.7 04/07/2015 08:54 MHH71310.005 1 Zinc (Zn)0.011 mg/L EPA 200.7 04/07/2015 08:54 MHH71310.005 1 Page 6 of 37 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040006 2015009208 Collection Date:27-Mar-15 3:15 PM Site:MW 37C Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/17/2015 12:02 DJSULL111 Arsenic (As)2.62 ug/L EPA 200.8 04/17/2015 12:02 DJSULL111 Beryllium (Be)< 1 ug/L EPA 200.8 04/17/2015 12:02 DJSULL111 Cadmium (Cd)< 1 ug/L EPA 200.8 04/17/2015 12:02 DJSULL111 Chromium (Cr)< 1 ug/L EPA 200.8 04/17/2015 12:02 DJSULL111 Cobalt (Co)2.72 ug/L EPA 200.8 04/17/2015 12:02 DJSULL111 Copper (Cu)< 1 ug/L EPA 200.8 04/17/2015 12:02 DJSULL111 Lead (Pb)< 1 ug/L EPA 200.8 04/17/2015 12:02 DJSULL111 Molybdenum (Mo)< 1 ug/L EPA 200.8 04/17/2015 12:02 DJSULL111 Nickel (Ni)< 1 ug/L EPA 200.8 04/17/2015 12:02 DJSULL111 Selenium (Se)< 1 ug/L EPA 200.8 04/17/2015 12:02 DJSULL111 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/17/2015 12:02 DJSULL10.2 1 Vanadium (V) Low Level 0.517 ug/L EPA 200.8 04/17/2015 12:02 DJSULL10.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/16/2015 13:25 JAHERMA11 Arsenic (As)2.93 ug/L EPA 200.8 04/16/2015 13:25 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 04/16/2015 13:25 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 04/16/2015 13:25 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 04/16/2015 13:25 JAHERMA11 Cobalt (Co)2.99 ug/L EPA 200.8 04/16/2015 13:25 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 04/16/2015 13:25 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 04/16/2015 13:25 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 04/16/2015 13:25 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 04/16/2015 13:25 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 04/16/2015 13:25 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/16/2015 13:25 JAHERMA0.2 1 Vanadium (V) Low Level 1.15 ug/L EPA 200.8 04/16/2015 13:25 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 78 mg/L SM2540C 04/02/2015 11:49 AGIBBS5251 Total Carbon TOC 5.4 mg/L SM5310C/EPA9060A 04/08/2015 12:53 TJA70670.1 1 TOTAL SUSPENDED SOLIDS TSS 5.0 mg/L SM2540D 04/02/2015 11:00 AGIBBS551 Page 7 of 37 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040006 2015009209 Collection Date:27-Mar-15 11:30 AM Site:Filter Blank Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 04/08/2015 11:00 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 04/01/2015 14:48 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 04/01/2015 14:48 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 04/01/2015 14:48 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 04/01/2015 14:48 MHALL30.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 04/01/2015 14:48 MHALL30.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 04/01/2015 14:48 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 04/01/2015 14:48 MHALL30.005 1 DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/17/2015 11:44 DJSULL111 Arsenic (As)< 1 ug/L EPA 200.8 04/17/2015 11:44 DJSULL111 Beryllium (Be)< 1 ug/L EPA 200.8 04/17/2015 11:44 DJSULL111 Cadmium (Cd)< 1 ug/L EPA 200.8 04/17/2015 11:44 DJSULL111 Chromium (Cr)< 1 ug/L EPA 200.8 04/17/2015 11:44 DJSULL111 Cobalt (Co)< 1 ug/L EPA 200.8 04/17/2015 11:44 DJSULL111 Copper (Cu)< 1 ug/L EPA 200.8 04/17/2015 11:44 DJSULL111 Lead (Pb)< 1 ug/L EPA 200.8 04/17/2015 11:44 DJSULL111 Molybdenum (Mo)< 1 ug/L EPA 200.8 04/17/2015 11:44 DJSULL111 Nickel (Ni)< 1 ug/L EPA 200.8 04/17/2015 11:44 DJSULL111 Selenium (Se)< 1 ug/L EPA 200.8 04/17/2015 11:44 DJSULL111 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/17/2015 11:44 DJSULL10.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/17/2015 11:44 DJSULL10.3 1 Page 8 of 37 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040006 2015009210 Collection Date:27-Mar-15 11:30 AM Site:Equipment Blank Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/07/2015 11:54 BGN90340.01 1 INORGANIC IONS BY IC Chloride < 0.1 mg/L EPA 300.0 04/06/2015 22:06 JAHERMA0.1 1 Sulfate 0.29 mg/L EPA 300.0 04/06/2015 22:06 JAHERMA0.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 04/02/2015 12:19 ACPAYNE0.05 1 UNDIGESTED METALS BY ICP Calcium (Ca)0.165 mg/L EPA 200.7 04/01/2015 15:54 MHALL30.01 1 Magnesium (Mg)0.038 mg/L EPA 200.7 04/01/2015 15:54 MHALL30.005 1 Potassium (K)< 0.1 mg/L EPA 200.7 04/01/2015 15:54 MHALL30.1 1 Sodium (Na)< 0.05 mg/L EPA 200.7 04/01/2015 15:54 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)1.05 mg/L EPA 200.7 04/07/2015 10:19 MHH71310.005 1 Barium (Ba)0.018 mg/L EPA 200.7 04/07/2015 10:19 MHH71310.005 1 Boron (B)< 0.05 mg/L EPA 200.7 04/07/2015 10:19 MHH71310.05 1 Iron (Fe)0.605 mg/L EPA 200.7 04/07/2015 10:19 MHH71310.01 1 Manganese (Mn)0.009 mg/L EPA 200.7 04/07/2015 10:19 MHH71310.005 1 Strontium (Sr)0.012 mg/L EPA 200.7 04/07/2015 10:19 MHH71310.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 04/07/2015 10:19 MHH71310.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/16/2015 13:29 JAHERMA11 Arsenic (As)5.00 ug/L EPA 200.8 04/16/2015 13:29 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 04/16/2015 13:29 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 04/16/2015 13:29 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 04/16/2015 13:29 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 04/16/2015 13:29 JAHERMA11 Copper (Cu)1.72 ug/L EPA 200.8 04/16/2015 13:29 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 04/16/2015 13:29 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 04/16/2015 13:29 JAHERMA11 Nickel (Ni)1.11 ug/L EPA 200.8 04/16/2015 13:29 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 04/16/2015 13:29 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/16/2015 13:29 JAHERMA0.2 1 Vanadium (V) Low Level 4.03 ug/L EPA 200.8 04/16/2015 13:29 JAHERMA0.3 1 Page 9 of 37 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040006 2015009210 Collection Date:27-Mar-15 11:30 AM Site:Equipment Blank Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 04/02/2015 11:49 AGIBBS5251 Total Carbon TOC 0.157 mg/L SM5310C/EPA9060A 04/08/2015 12:53 TJA70670.1 1 TOTAL SUSPENDED SOLIDS TSS 13 mg/L SM2540D 04/02/2015 11:00 AGIBBS551 Page 10 of 37 Page 11 of 37 Page 12 of 37 Page 13 of 37 Page 14 of 37 Page 15 of 37 SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle QD01092Lot Number: J15040006Project Number: AB GW Assessment Water - SuttonProject Name: 04/08/2015Date Completed: Grant Wilton Project Manager *QD01092* This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. Page: 1 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Case Narrative Duke Energy Lot Number: QD01092 SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329 Project Name: AB GW Assessment Water - Sutton Project Number: J15040006 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. Page: 2 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: QD01092 Project Name: AB GW Assessment Water - Sutton Project Number: J15040006 Sample Number Sample ID Matrix Date Sampled Date Received 001 03/27/2015 13102015009207Aqueous 04/01/2015 002 03/27/2015 15152015009208Aqueous 04/01/2015 003 03/27/2015 11302015009210Aqueous 04/01/2015 (3 samples) Page: 3 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: QD01092 Project Name: AB GW Assessment Water - Sutton Project Number: J15040006 Sample Sample ID Matrix Parameter Method Result Q Units Page 002 2015009208 Aqueous Alkalinity SM 2320B-31 mg/L 7 002 2015009208 Aqueous Bicarbonate Alkalinity SM 2320B-31 mg/L 7 002 2015009208 Aqueous Methane RSK - 175 26 ug/L 8 (3 detections) Page: 4 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015009207 QD01092-001 03/27/2015 1310 04/01/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040006 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/04/2015 2139 HMA 71830 1 (Bicarbonate ) SM 2320B-2011 1 04/04/2015 2139 HMA 04/04/2015 2139 1 (Carbonate Al) SM 2320B-2011 1 04/04/2015 2139 HMA 04/04/2015 2139 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 5 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015009207 QD01092-001 03/27/2015 1310 04/01/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040006 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 04/08/2015 0959 DCS 72088 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 6 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015009208 QD01092-002 03/27/2015 1515 04/01/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040006 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/04/2015 2144 HMA 71830 1 (Bicarbonate ) SM 2320B-2011 1 04/04/2015 2144 HMA 04/04/2015 2144 1 (Carbonate Al) SM 2320B-2011 1 04/04/2015 2144 HMA 04/04/2015 2144 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 31 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 31 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 7 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015009208 QD01092-002 03/27/2015 1515 04/01/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040006 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 04/08/2015 1009 DCS 72088 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 26 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 8 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015009210 QD01092-003 03/27/2015 1130 04/01/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040006 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/04/2015 2148 HMA 71830 1 (Bicarbonate ) SM 2320B-2011 1 04/04/2015 2148 HMA 04/04/2015 2148 1 (Carbonate Al) SM 2320B-2011 1 04/04/2015 2148 HMA 04/04/2015 2148 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 9 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015009210 QD01092-003 03/27/2015 1130 04/01/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15040006 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 04/07/2015 1331 DCS 72066 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 10 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 QC Summary QC Data for Lot Number: QD01092 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MB Batch: Sample ID:QQ71830-001 71830 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Alkalinity ND 04/04/2015 205010mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD01092 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - LCS Batch: Sample ID:QQ71830-002 71830 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Alkalinity 96 04/04/2015 20579610090-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD01092 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - MB Batch: Sample ID:QQ72066-001 72066 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 04/07/2015 094810ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD01092 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCS Batch: Sample ID:QQ72066-002 72066 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 160 04/07/2015 090310815070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD01092 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCSD Batch: Sample ID:QQ72066-003 72066 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 160 04/07/2015 091910415070-1303.6 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD01092 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - MB Batch: Sample ID:QQ72088-001 72088 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 04/08/2015 094310ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD01092 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCS Batch: Sample ID:QQ72088-002 72088 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 150 04/08/2015 09209715070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD01092 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCSD Batch: Sample ID:QQ72088-003 72088 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 150 04/08/2015 09329815070-1300.84 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QD01092 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. I�I U4i w! i1J i J!P J I I Y [e 7� Ui I �I U LL 0 Xxf 0! -A A ! S _I }#*^140i10 I■q Non) -11514" WHIRS �' r I Iw'Ar'I4 F Punwewr+4P�13dP { ' 4t � � r 41 AIPiUR A, C914 4L. rn i ['J 7 , - IN a- w F I ! I 0 g rc I` ^ I? 1 P�..y m a6? u➢ 3 I � Y �I I wwo I r P I Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Page 37 of 37