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Home My WebLink AboutNC0001422_ATT 5 - Water - J15030697report_2015080513339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number:J15030697 Project Name:AB GW ASSESSMENT WATER Lab Contact:Mary Ann Ogle Date:4/16/2015 Customer Address: Customer Name(s):Perry Waldrep, Tim Hunsucker, Kathy Webb, John Toepfer Phone: 980-875-5274 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Mary Ann Ogle Page 1 of 33 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015008663 Sutton 26-Mar-15 4:55 PM ILLEGIBLE SW-2B 2015008664 Sutton 26-Mar-15 3:30 PM ILLEGIBLE SW-2C 2015008665 Sutton 26-Mar-15 1:05 PM ILLEGIBLE Filter Blank 2015008666 Sutton 26-Mar-15 1:05 PM ILLEGIBLE Equipment Blank 4 Total Samples Page 2 of 33 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:DBA Account Date:4/16/2015 Electronic Data Deliverable (EDD) Sent Separately Page 3 of 33 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030697 2015008663 Collection Date:26-Mar-15 4:55 PM Site:SW-2B Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.241 mg-N/L EPA 353.2 04/07/2015 11:30N1 BGN90340.01 1 INORGANIC IONS BY IC Chloride 9.9 mg/L EPA 300.0 03/30/2015 19:27N1 JAHERMA110 Sulfate 27 mg/L EPA 300.0 03/30/2015 19:27N1 JAHERMA110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 04/02/2015 11:15 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 04/07/2015 17:05 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.048 mg/L EPA 200.7 03/30/2015 12:17 MHALL30.005 1 Barium (Ba)0.029 mg/L EPA 200.7 03/30/2015 12:17 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 03/30/2015 12:17 MHALL30.05 1 Iron (Fe)10.1 mg/L EPA 200.7 03/30/2015 12:17 MHALL30.01 1 Manganese (Mn)0.209 mg/L EPA 200.7 03/30/2015 12:17 MHALL30.005 1 Strontium (Sr)0.060 mg/L EPA 200.7 03/30/2015 12:17 MHALL30.005 1 Zinc (Zn)0.010 mg/L EPA 200.7 03/30/2015 12:17 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)23.7 mg/L EPA 200.7 03/30/2015 15:51 MHALL30.01 1 Magnesium (Mg)1.68 mg/L EPA 200.7 03/30/2015 15:51 MHALL30.005 1 Potassium (K)2.00 mg/L EPA 200.7 03/30/2015 15:51 MHALL30.1 1 Sodium (Na)12.2 mg/L EPA 200.7 03/30/2015 15:51 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.081 mg/L EPA 200.7 03/31/2015 11:01 MHALL30.005 1 Barium (Ba)0.030 mg/L EPA 200.7 03/31/2015 11:01 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 03/31/2015 11:01 MHALL30.05 1 Iron (Fe)11.4 mg/L EPA 200.7 03/31/2015 11:01 MHALL30.01 1 Manganese (Mn)0.235 mg/L EPA 200.7 03/31/2015 11:01 MHALL30.005 1 Strontium (Sr)0.061 mg/L EPA 200.7 03/31/2015 11:01 MHALL30.005 1 Zinc (Zn)0.006 mg/L EPA 200.7 03/31/2015 11:01 MHALL30.005 1 Page 4 of 33 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030697 2015008663 Collection Date:26-Mar-15 4:55 PM Site:SW-2B Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/14/2015 17:48 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 04/14/2015 17:48 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 04/14/2015 17:48 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2015 17:48 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 04/14/2015 17:48 JAHERMA11 Cobalt (Co)1.64 ug/L EPA 200.8 04/14/2015 17:48 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 04/14/2015 17:48 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 04/14/2015 17:48 JAHERMA11 Molybdenum (Mo)4.64 ug/L EPA 200.8 04/14/2015 17:48 JAHERMA11 Nickel (Ni)1.39 ug/L EPA 200.8 04/14/2015 17:48 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 04/14/2015 17:48 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/14/2015 17:48 JAHERMA0.2 1 Vanadium (V) Low Level 1.55 ug/L EPA 200.8 04/14/2015 17:48 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/13/2015 19:05 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 04/13/2015 19:05 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 04/13/2015 19:05 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 04/13/2015 19:05 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 04/13/2015 19:05 JAHERMA11 Cobalt (Co)1.77 ug/L EPA 200.8 04/13/2015 19:05 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 04/13/2015 19:05 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 04/13/2015 19:05 JAHERMA11 Molybdenum (Mo)4.18 ug/L EPA 200.8 04/13/2015 19:05 JAHERMA11 Nickel (Ni)1.47 ug/L EPA 200.8 04/13/2015 19:05 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 04/13/2015 19:05 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/13/2015 19:05 JAHERMA0.2 1 Vanadium (V) Low Level 2.35 ug/L EPA 200.8 04/13/2015 19:05 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 130 mg/L SM2540C 03/31/2015 11:21N1 AGIBBS5251 Total Carbon TOC 4.5 mg/L SM5310C/EPA9060A 04/02/2015 14:21N1 TJA70670.1 1 TOTAL SUSPENDED SOLIDS TSS 15 mg/L SM2540D 03/27/2015 11:04N1 GHUTCHI51 Page 5 of 33 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030697 2015008664 Collection Date:26-Mar-15 3:30 PM Site:SW-2C Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.033 mg-N/L EPA 353.2 04/07/2015 11:31N1 BGN90340.01 1 INORGANIC IONS BY IC Chloride 28 mg/L EPA 300.0 03/30/2015 19:45N1 JAHERMA110 Sulfate 72 mg/L EPA 300.0 03/30/2015 19:45N1 JAHERMA110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 04/02/2015 11:22 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 04/07/2015 17:07 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.030 mg/L EPA 200.7 03/30/2015 12:21 MHALL30.005 1 Barium (Ba)0.033 mg/L EPA 200.7 03/30/2015 12:21 MHALL30.005 1 Boron (B)0.326 mg/L EPA 200.7 03/30/2015 12:21 MHALL30.05 1 Iron (Fe)20.4 mg/L EPA 200.7 03/30/2015 12:21 MHALL30.01 1 Manganese (Mn)1.92 mg/L EPA 200.7 03/30/2015 12:21 MHALL30.005 1 Strontium (Sr)0.211 mg/L EPA 200.7 03/30/2015 12:21 MHALL30.005 1 Zinc (Zn)0.007 mg/L EPA 200.7 03/30/2015 12:21 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)22.3 mg/L EPA 200.7 03/30/2015 15:14 MHALL30.01 1 Magnesium (Mg)3.84 mg/L EPA 200.7 03/30/2015 15:14 MHALL30.005 1 Potassium (K)3.68 mg/L EPA 200.7 03/30/2015 15:14 MHALL30.1 1 Sodium (Na)18.6 mg/L EPA 200.7 03/30/2015 15:14 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.325 mg/L EPA 200.7 03/31/2015 11:13 MHALL30.005 1 Barium (Ba)0.036 mg/L EPA 200.7 03/31/2015 11:13 MHALL30.005 1 Boron (B)0.338 mg/L EPA 200.7 03/31/2015 11:13 MHALL30.05 1 Iron (Fe)19.2 mg/L EPA 200.7 03/31/2015 11:13 MHALL30.01 1 Manganese (Mn)1.97 mg/L EPA 200.7 03/31/2015 11:13 MHALL30.005 1 Strontium (Sr)0.220 mg/L EPA 200.7 03/31/2015 11:13 MHALL30.005 1 Zinc (Zn)0.007 mg/L EPA 200.7 03/31/2015 11:13 MHALL30.005 1 Page 6 of 33 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030697 2015008664 Collection Date:26-Mar-15 3:30 PM Site:SW-2C Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/14/2015 18:09 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 04/14/2015 18:09 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 04/14/2015 18:09 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2015 18:09 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 04/14/2015 18:09 JAHERMA11 Cobalt (Co)92.0 ug/L EPA 200.8 04/14/2015 18:09 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 04/14/2015 18:09 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 04/14/2015 18:09 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 04/14/2015 18:09 JAHERMA11 Nickel (Ni)1.75 ug/L EPA 200.8 04/14/2015 18:09 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 04/14/2015 18:09 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/14/2015 18:09 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/14/2015 18:09 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/13/2015 19:21 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 04/13/2015 19:21 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 04/13/2015 19:21 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 04/13/2015 19:21 JAHERMA11 Chromium (Cr)1.08 ug/L EPA 200.8 04/13/2015 19:21 JAHERMA11 Cobalt (Co)93.1 ug/L EPA 200.8 04/13/2015 19:21 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 04/13/2015 19:21 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 04/13/2015 19:21 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 04/13/2015 19:21 JAHERMA11 Nickel (Ni)2.13 ug/L EPA 200.8 04/13/2015 19:21 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 04/13/2015 19:21 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/13/2015 19:21 JAHERMA0.2 1 Vanadium (V) Low Level 0.828 ug/L EPA 200.8 04/13/2015 19:21 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 180 mg/L SM2540C 03/31/2015 11:21N1 AGIBBS5251 Total Carbon TOC 1.1 mg/L SM5310C/EPA9060A 04/02/2015 14:21N1 TJA70670.1 1 TOTAL SUSPENDED SOLIDS TSS 17 mg/L SM2540D 03/27/2015 11:04N1 GHUTCHI51 Page 7 of 33 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030697 2015008665 Collection Date:26-Mar-15 1:05 PM Site:Filter Blank Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 04/07/2015 17:21 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 03/30/2015 12:44 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 03/30/2015 12:44 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 03/30/2015 12:44 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 03/30/2015 12:44 MHALL30.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 03/30/2015 12:44 MHALL30.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 03/30/2015 12:44 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 03/30/2015 12:44 MHALL30.005 1 DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/14/2015 18:14 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 04/14/2015 18:14 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 04/14/2015 18:14 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2015 18:14 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 04/14/2015 18:14 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 04/14/2015 18:14 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 04/14/2015 18:14 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 04/14/2015 18:14 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 04/14/2015 18:14 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 04/14/2015 18:14 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 04/14/2015 18:14 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/14/2015 18:14 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/14/2015 18:14 JAHERMA0.3 1 Page 8 of 33 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030697 2015008666 Collection Date:26-Mar-15 1:05 PM Site:Equipment Blank Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/07/2015 11:32N1 BGN90340.01 1 INORGANIC IONS BY IC Chloride < 0.1 mg/L EPA 300.0 03/30/2015 20:21N1 JAHERMA0.1 1 Sulfate < 0.1 mg/L EPA 300.0 03/30/2015 20:21N1 JAHERMA0.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 04/02/2015 11:29 ACPAYNE0.05 1 UNDIGESTED METALS BY ICP Calcium (Ca)< 0.01 mg/L EPA 200.7 03/30/2015 16:02 MHALL30.01 1 Magnesium (Mg)< 0.005 mg/L EPA 200.7 03/30/2015 16:02 MHALL30.005 1 Potassium (K)< 0.1 mg/L EPA 200.7 03/30/2015 16:02 MHALL30.1 1 Sodium (Na)< 0.05 mg/L EPA 200.7 03/30/2015 16:02 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 03/31/2015 11:16 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 03/31/2015 11:16 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 03/31/2015 11:16 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 03/31/2015 11:16 MHALL30.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 03/31/2015 11:16 MHALL30.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 03/31/2015 11:16 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 03/31/2015 11:16 MHALL30.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/13/2015 19:26 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 04/13/2015 19:26 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 04/13/2015 19:26 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 04/13/2015 19:26 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 04/13/2015 19:26 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 04/13/2015 19:26 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 04/13/2015 19:26 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 04/13/2015 19:26 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 04/13/2015 19:26 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 04/13/2015 19:26 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 04/13/2015 19:26 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/13/2015 19:26 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/13/2015 19:26 JAHERMA0.3 1 Page 9 of 33 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030697 2015008666 Collection Date:26-Mar-15 1:05 PM Site:Equipment Blank Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 03/31/2015 11:21N1 AGIBBS5251 Total Carbon TOC 0.212 mg/L SM5310C/EPA9060A 04/02/2015 14:21N1 TJA70670.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 03/27/2015 11:04N1 GHUTCHI51 These sample were stored in a refrigerator that malfunctioned causing the sample to freeze. The state was notified and the results may be reported for compliance purposes as long as the data is flagged. Any parameter requriing preservation at < 6C and that was tested after 3/25/2015 at 15:45 when the refrigerator was documented to be in compliance are flagged with N1. -- Additional Information -- Qualifiers: N1 See additional information listed below. Page 10 of 33 SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle QC31013Lot Number: J15030697Project Number: AB GW Assessment Water - SuttonProject Name: 04/08/2015Date Completed: Grant Wilton Project Manager *QC31013* This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. Page: 1 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Case Narrative Duke Energy Lot Number: QC31013 SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329 Project Name: AB GW Assessment Water - Sutton Project Number: J15030697 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. Page: 2 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: QC31013 Project Name: AB GW Assessment Water - Sutton Project Number: J15030697 Sample Number Sample ID Matrix Date Sampled Date Received 001 03/26/2015 16552015008663Aqueous 03/31/2015 002 03/26/2015 15302015008664Aqueous 03/31/2015 003 03/26/2015 13052015008666Aqueous 03/31/2015 (3 samples) Page: 3 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: QC31013 Project Name: AB GW Assessment Water - Sutton Project Number: J15030697 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2015008663 Aqueous Alkalinity SM 2320B-52 mg/L 5 001 2015008663 Aqueous Bicarbonate Alkalinity SM 2320B-52 mg/L 5 001 2015008663 Aqueous Methane RSK - 175 170 ug/L 6 002 2015008664 Aqueous Alkalinity SM 2320B-15 mg/L 7 002 2015008664 Aqueous Bicarbonate Alkalinity SM 2320B-15 mg/L 7 002 2015008664 Aqueous Methane RSK - 175 14 ug/L 8 003 2015008666 Aqueous Methane RSK - 175 10 ug/L 10 (7 detections) Page: 4 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015008663 QC31013-001 03/26/2015 1655 03/31/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15030697 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/02/2015 1411 HMA 71557 1 (Bicarbonate ) SM 2320B-2011 1 04/02/2015 1411 HMA 04/02/2015 1411 1 (Carbonate Al) SM 2320B-2011 1 04/02/2015 1411 HMA 04/02/2015 1411 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 52 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 52 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 5 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015008663 QC31013-001 03/26/2015 1655 03/31/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15030697 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 04/04/2015 0244 JJG 71805 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 170 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 6 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015008664 QC31013-002 03/26/2015 1530 03/31/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15030697 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/02/2015 1429 HMA 71557 1 (Bicarbonate ) SM 2320B-2011 1 04/02/2015 1429 HMA 04/02/2015 1429 1 (Carbonate Al) SM 2320B-2011 1 04/02/2015 1429 HMA 04/02/2015 1429 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 15 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 15 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 7 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015008664 QC31013-002 03/26/2015 1530 03/31/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15030697 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 04/04/2015 0255 JJG 71805 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 14 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 8 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015008666 QC31013-003 03/26/2015 1305 03/31/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15030697 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/02/2015 1433 HMA 71557 1 (Bicarbonate ) SM 2320B-2011 1 04/02/2015 1433 HMA 04/02/2015 1433 1 (Carbonate Al) SM 2320B-2011 1 04/02/2015 1433 HMA 04/02/2015 1433 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 9 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015008666 QC31013-003 03/26/2015 1305 03/31/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15030697 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 04/04/2015 0307 JJG 71805 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 10 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 10 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 QC Summary QC Data for Lot Number: QC31013 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MB Batch: Sample ID:QQ71557-001 71557 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Alkalinity ND 04/02/2015 115710mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QC31013 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - LCS Batch: Sample ID:QQ71557-002 71557 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Alkalinity 96 04/02/2015 12039610090-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QC31013 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - MB Batch: Sample ID:QQ71805-001 71805 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 04/04/2015 004110ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QC31013 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCS Batch: Sample ID:QQ71805-002 71805 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 150 04/04/2015 00049715070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QC31013 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCSD Batch: Sample ID:QQ71805-003 71805 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 170 04/04/2015 001511215070-13015 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QC31013 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Page 29 of 33 Page 30 of 33 Page 31 of 33 Page 32 of 33 Page 33 of 33