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Home My WebLink AboutNC0001422_ATT 5 - Water - J15030669report_2015080513339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number:J15030669 Project Name:AB GW ASSESSMENT WATER Lab Contact:Mary Ann Ogle Date:4/16/2015 Customer Address: Customer Name(s):Perry Waldrep, Tim Hunsucker, Kathy Webb, John Toepfer Phone: 980-875-5274 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Mary Ann Ogle Page 1 of 33 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015008528 Sutton 24-Mar-15 1:05 PM ILLEGIBLE AW-6D 2015008529 Sutton 24-Mar-15 5:00 PM ILLEGIBLE AW-5B 2015008530 Sutton 24-Mar-15 5:15 PM ILLEGIBLE Equipment Blank 2015008531 Sutton 24-Mar-15 5:15 PM ILLEGIBLE Filter Blank 4 Total Samples Page 2 of 33 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:DBA Account Date:4/16/2015 Electronic Data Deliverable (EDD) Sent Separately Page 3 of 33 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030669 2015008528 Collection Date:24-Mar-15 1:05 PM Site:AW-6D Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)0.032 mg-N/L EPA 353.2 04/01/2015 14:02N1 BGN90340.01 1 INORGANIC IONS BY IC Chloride 200 mg/L EPA 300.0 03/30/2015 15:57N1 JAHERMA550 Sulfate 24 mg/L EPA 300.0 03/30/2015 15:57N1 JAHERMA0.5 5 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 04/02/2015 11:00 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 04/07/2015 16:50 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.036 mg/L EPA 200.7 03/30/2015 12:29 MHALL30.005 1 Barium (Ba)0.015 mg/L EPA 200.7 03/30/2015 12:29 MHALL30.005 1 Boron (B)0.975 mg/L EPA 200.7 03/30/2015 12:29 MHALL30.05 1 Iron (Fe)0.025 mg/L EPA 200.7 03/30/2015 12:29 MHALL30.01 1 Manganese (Mn)0.015 mg/L EPA 200.7 03/30/2015 12:29 MHALL30.005 1 Strontium (Sr)0.074 mg/L EPA 200.7 03/30/2015 12:29 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 03/30/2015 12:29 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)7.41 mg/L EPA 200.7 03/30/2015 14:43 MHALL30.01 1 Magnesium (Mg)3.28 mg/L EPA 200.7 03/30/2015 14:43 MHALL30.005 1 Potassium (K)7.79 mg/L EPA 200.7 03/30/2015 14:43 MHALL30.1 1 Sodium (Na)251 mg/L EPA 200.7 03/30/2015 14:43 MHALL32.5 50 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.160 mg/L EPA 200.7 03/27/2015 10:40 MHALL30.005 1 Barium (Ba)0.015 mg/L EPA 200.7 03/27/2015 10:40 MHALL30.005 1 Boron (B)0.976 mg/L EPA 200.7 03/27/2015 10:40 MHALL30.05 1 Iron (Fe)0.250 mg/L EPA 200.7 03/27/2015 10:40 MHALL30.01 1 Manganese (Mn)0.016 mg/L EPA 200.7 03/27/2015 10:40 MHALL30.005 1 Strontium (Sr)0.075 mg/L EPA 200.7 03/27/2015 10:40 MHALL30.005 1 Zinc (Zn)0.008 mg/L EPA 200.7 03/27/2015 10:40 MHALL30.005 1 Page 4 of 33 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030669 2015008528 Collection Date:24-Mar-15 1:05 PM Site:AW-6D Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/14/2015 15:53 JAHERMA11 Arsenic (As)1.96 ug/L EPA 200.8 04/14/2015 15:53 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 04/14/2015 15:53 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2015 15:53 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 04/14/2015 15:53 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 04/14/2015 15:53 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 04/14/2015 15:53 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 04/14/2015 15:53 JAHERMA11 Molybdenum (Mo)13.2 ug/L EPA 200.8 04/14/2015 15:53 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 04/14/2015 15:53 JAHERMA11 Selenium (Se)26.1 ug/L EPA 200.8 04/14/2015 15:53 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/14/2015 15:53 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/14/2015 15:53 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/01/2015 16:03 DJSULL111 Arsenic (As)2.02 ug/L EPA 200.8 04/01/2015 16:03 DJSULL111 Beryllium (Be)< 1 ug/L EPA 200.8 04/01/2015 16:03 DJSULL111 Cadmium (Cd)< 1 ug/L EPA 200.8 04/01/2015 16:03 DJSULL111 Chromium (Cr)< 1 ug/L EPA 200.8 04/01/2015 16:03 DJSULL111 Cobalt (Co)< 1 ug/L EPA 200.8 04/01/2015 16:03 DJSULL111 Copper (Cu)< 1 ug/L EPA 200.8 04/01/2015 16:03 DJSULL111 Lead (Pb)< 1 ug/L EPA 200.8 04/01/2015 16:03 DJSULL111 Molybdenum (Mo)13.4 ug/L EPA 200.8 04/01/2015 16:03 DJSULL111 Nickel (Ni)< 1 ug/L EPA 200.8 04/01/2015 16:03 DJSULL111 Selenium (Se)< 1 ug/L EPA 200.8 04/01/2015 16:03M2 DJSULL111 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/01/2015 16:03 DJSULL10.2 1 Vanadium (V) Low Level 0.588 ug/L EPA 200.8 04/01/2015 16:03 DJSULL10.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 600 mg/L SM2540C 03/31/2015 11:21N1 AGIBBS52501 Total Carbon TOC 34 mg/L SM5310C/EPA9060A 04/02/2015 14:21N1 TJA7067220 TOTAL SUSPENDED SOLIDS TSS 8.0 mg/L SM2540D 03/26/2015 13:48N1 AGIBBS551 Page 5 of 33 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030669 2015008529 Collection Date:24-Mar-15 5:00 PM Site:AW-5B Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/01/2015 14:03N1 BGN90340.01 1 INORGANIC IONS BY IC Chloride 6.2 mg/L EPA 300.0 03/31/2015 11:44N1 JAHERMA110 Sulfate 15 mg/L EPA 300.0 03/31/2015 11:44N1 JAHERMA110 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 04/02/2015 11:03 ACPAYNE0.05 1 Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 04/07/2015 16:53 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)0.027 mg/L EPA 200.7 03/30/2015 12:25 MHALL30.005 1 Barium (Ba)0.063 mg/L EPA 200.7 03/30/2015 12:25 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 03/30/2015 12:25 MHALL30.05 1 Iron (Fe)5.80 mg/L EPA 200.7 03/30/2015 12:25 MHALL30.01 1 Manganese (Mn)0.385 mg/L EPA 200.7 03/30/2015 12:25 MHALL30.005 1 Strontium (Sr)0.082 mg/L EPA 200.7 03/30/2015 12:25 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 03/30/2015 12:25 MHALL30.005 1 UNDIGESTED METALS BY ICP Calcium (Ca)15.5 mg/L EPA 200.7 03/30/2015 14:39 MHALL30.01 1 Magnesium (Mg)0.457 mg/L EPA 200.7 03/30/2015 14:39 MHALL30.005 1 Potassium (K)6.79 mg/L EPA 200.7 03/30/2015 14:39 MHALL30.1 1 Sodium (Na)14.3 mg/L EPA 200.7 03/30/2015 14:39 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)0.046 mg/L EPA 200.7 03/31/2015 13:49 MHALL30.005 1 Barium (Ba)0.066 mg/L EPA 200.7 03/31/2015 13:49 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 03/31/2015 13:49 MHALL30.05 1 Iron (Fe)6.79 mg/L EPA 200.7 03/31/2015 13:49 MHALL30.01 1 Manganese (Mn)0.391 mg/L EPA 200.7 03/31/2015 13:49 MHALL30.005 1 Strontium (Sr)0.085 mg/L EPA 200.7 03/31/2015 13:49 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 03/31/2015 13:49 MHALL30.005 1 Page 6 of 33 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030669 2015008529 Collection Date:24-Mar-15 5:00 PM Site:AW-5B Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/14/2015 15:59 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 04/14/2015 15:59 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 04/14/2015 15:59 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2015 15:59 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 04/14/2015 15:59 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 04/14/2015 15:59 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 04/14/2015 15:59 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 04/14/2015 15:59 JAHERMA11 Molybdenum (Mo)6.73 ug/L EPA 200.8 04/14/2015 15:59 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 04/14/2015 15:59 JAHERMA11 Selenium (Se)1.26 ug/L EPA 200.8 04/14/2015 15:59 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/14/2015 15:59 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/14/2015 15:59 JAHERMA0.3 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/13/2015 18:00 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 04/13/2015 18:00 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 04/13/2015 18:00 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 04/13/2015 18:00 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 04/13/2015 18:00 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 04/13/2015 18:00 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 04/13/2015 18:00 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 04/13/2015 18:00 JAHERMA11 Molybdenum (Mo)6.50 ug/L EPA 200.8 04/13/2015 18:00 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 04/13/2015 18:00 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 04/13/2015 18:00 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/13/2015 18:00 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/13/2015 18:00 JAHERMA0.3 1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 130 mg/L SM2540C 03/31/2015 11:21N1 AGIBBS5251 Total Carbon TOC 40 mg/L SM5310C/EPA9060A 04/02/2015 14:21N1 TJA7067220 TOTAL SUSPENDED SOLIDS TSS 14 mg/L SM2540D 03/26/2015 13:48N1 AGIBBS551 Page 7 of 33 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030669 2015008530 Collection Date:24-Mar-15 5:15 PM Site:Equipment Blank Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF ALKALINITY - (Analysis Performed by Shealy Labs) Vendor Parameter Complete Vendor Method V_SHEALY NITRITE + NITRATE (COLORIMETRIC) Nitrite + Nitrate (Colorimetric)< 0.01 mg-N/L EPA 353.2 04/01/2015 14:04N1 BGN90340.01 1 INORGANIC IONS BY IC Chloride < 0.1 mg/L EPA 300.0 03/30/2015 16:33N1 JAHERMA0.1 1 Sulfate < 0.1 mg/L EPA 300.0 03/30/2015 16:33N1 JAHERMA0.1 1 MERCURY (COLD VAPOR) IN WATER Mercury (Hg)< 0.05 ug/L EPA 245.1 04/02/2015 11:05 ACPAYNE0.05 1 UNDIGESTED METALS BY ICP Calcium (Ca)< 0.01 mg/L EPA 200.7 03/30/2015 15:58 MHALL30.01 1 Magnesium (Mg)< 0.005 mg/L EPA 200.7 03/30/2015 15:58 MHALL30.005 1 Potassium (K)< 0.1 mg/L EPA 200.7 03/30/2015 15:58 MHALL30.1 1 Sodium (Na)< 0.05 mg/L EPA 200.7 03/30/2015 15:58 MHALL30.05 1 TOTAL RECOVERABLE METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 03/31/2015 13:57 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 03/31/2015 13:57 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 03/31/2015 13:57 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 03/31/2015 13:57 MHALL30.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 03/31/2015 13:57 MHALL30.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 03/31/2015 13:57 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 03/31/2015 13:57 MHALL30.005 1 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/13/2015 18:05 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 04/13/2015 18:05 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 04/13/2015 18:05 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 04/13/2015 18:05 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 04/13/2015 18:05 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 04/13/2015 18:05 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 04/13/2015 18:05 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 04/13/2015 18:05 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 04/13/2015 18:05 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 04/13/2015 18:05 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 04/13/2015 18:05 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/13/2015 18:05 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/13/2015 18:05 JAHERMA0.3 1 Page 8 of 33 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030669 2015008530 Collection Date:24-Mar-15 5:15 PM Site:Equipment Blank Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METHANE - (Analysis Performed by Shealy Labs) Methane (CH4)Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L SM2540C 03/31/2015 11:21N1 AGIBBS5251 Total Carbon TOC 0.132 mg/L SM5310C/EPA9060A 04/02/2015 14:21N1 TJA70670.1 1 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L SM2540D 03/26/2015 13:48N1 AGIBBS551 Page 9 of 33 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030669 2015008531 Collection Date:24-Mar-15 5:15 PM Site:Filter Blank Matrix:GW_WW Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF Mercury Dissolved (cold vapor) in Water (Filtered) Mercury (Hg)< 0.05 ug/L EPA 245.1 04/07/2015 16:55 ACPAYNE0.05 1 DISSOLVED METALS BY ICP Aluminum (Al)< 0.005 mg/L EPA 200.7 03/30/2015 13:18 MHALL30.005 1 Barium (Ba)< 0.005 mg/L EPA 200.7 03/30/2015 13:18 MHALL30.005 1 Boron (B)< 0.05 mg/L EPA 200.7 03/30/2015 13:18 MHALL30.05 1 Iron (Fe)< 0.01 mg/L EPA 200.7 03/30/2015 13:18 MHALL30.01 1 Manganese (Mn)< 0.005 mg/L EPA 200.7 03/30/2015 13:18 MHALL30.005 1 Strontium (Sr)< 0.005 mg/L EPA 200.7 03/30/2015 13:18 MHALL30.005 1 Zinc (Zn)< 0.005 mg/L EPA 200.7 03/30/2015 13:18 MHALL30.005 1 DISSOLVED METALS BY ICP-MS Antimony (Sb)< 1 ug/L EPA 200.8 04/14/2015 16:04 JAHERMA11 Arsenic (As)< 1 ug/L EPA 200.8 04/14/2015 16:04 JAHERMA11 Beryllium (Be)< 1 ug/L EPA 200.8 04/14/2015 16:04 JAHERMA11 Cadmium (Cd)< 1 ug/L EPA 200.8 04/14/2015 16:04 JAHERMA11 Chromium (Cr)< 1 ug/L EPA 200.8 04/14/2015 16:04 JAHERMA11 Cobalt (Co)< 1 ug/L EPA 200.8 04/14/2015 16:04 JAHERMA11 Copper (Cu)< 1 ug/L EPA 200.8 04/14/2015 16:04 JAHERMA11 Lead (Pb)< 1 ug/L EPA 200.8 04/14/2015 16:04 JAHERMA11 Molybdenum (Mo)< 1 ug/L EPA 200.8 04/14/2015 16:04 JAHERMA11 Nickel (Ni)< 1 ug/L EPA 200.8 04/14/2015 16:04 JAHERMA11 Selenium (Se)< 1 ug/L EPA 200.8 04/14/2015 16:04 JAHERMA11 Thallium (Tl) Low Level < 0.2 ug/L EPA 200.8 04/14/2015 16:04 JAHERMA0.2 1 Vanadium (V) Low Level < 0.3 ug/L EPA 200.8 04/14/2015 16:04 JAHERMA0.3 1 These sample were stored in a refrigerator that malfunctioned causing the sample to freeze. The state was notified and the results may be reported for compliance purposes as long as the data is flagged. Any parameter requriing preservation at < 6C and that was tested after 3/25/2015 at 15:45 when the refrigerator was documented to be in compliance are flagged with N1. -- Additional Information -- Qualifiers: M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable. N1 See additional information listed below. Page 10 of 33 SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle QC27018Lot Number: J15030669Project Number: AB GW Assessment Water - SuttonProject Name: 04/08/2015Date Completed: Grant Wilton Project Manager *QC27018* This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non-paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. Page: 1 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Case Narrative Duke Energy Lot Number: QC27018 SC DHEC No: 32010 NC Field Parameters No: 5639 NELAC No: E87653 NC DENR No: 329 Project Name: AB GW Assessment Water - Sutton Project Number: J15030669 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. Page: 2 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: QC27018 Project Name: AB GW Assessment Water - Sutton Project Number: J15030669 Sample Number Sample ID Matrix Date Sampled Date Received 001 03/24/2015 13052015008528Aqueous 03/27/2015 002 03/24/2015 17002015008529Aqueous 03/27/2015 003 03/24/2015 17152015008530Aqueous 03/27/2015 (3 samples) Page: 3 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: QC27018 Project Name: AB GW Assessment Water - Sutton Project Number: J15030669 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2015008528 Aqueous Alkalinity SM 2320B-230 mg/L 5 001 2015008528 Aqueous Bicarbonate Alkalinity SM 2320B-230 mg/L 5 001 2015008528 Aqueous Methane RSK - 175 16 ug/L 6 002 2015008529 Aqueous Alkalinity SM 2320B-39 mg/L 7 002 2015008529 Aqueous Bicarbonate Alkalinity SM 2320B-39 mg/L 7 002 2015008529 Aqueous Methane RSK - 175 17 ug/L 8 (6 detections) Page: 4 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015008528 QC27018-001 03/24/2015 1305 03/27/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15030669 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/04/2015 1737 HMA 71829 1 (Bicarbonate ) SM 2320B-2011 1 04/04/2015 1737 HMA 04/04/2015 1737 1 (Carbonate Al) SM 2320B-2011 1 04/04/2015 1737 HMA 04/04/2015 1737 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 230 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 230 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 5 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015008528 QC27018-001 03/24/2015 1305 03/27/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15030669 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 04/04/2015 0125 JJG 71805 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 16 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 6 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015008529 QC27018-002 03/24/2015 1700 03/27/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15030669 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/04/2015 1742 HMA 71829 1 (Bicarbonate ) SM 2320B-2011 1 04/04/2015 1742 HMA 04/04/2015 1742 1 (Carbonate Al) SM 2320B-2011 1 04/04/2015 1742 HMA 04/04/2015 1742 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 39 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 39 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 7 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015008529 QC27018-002 03/24/2015 1700 03/27/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15030669 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 04/04/2015 0137 JJG 71805 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 17 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 8 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015008530 QC27018-003 03/24/2015 1715 03/27/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15030669 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/04/2015 1747 HMA 71829 1 (Bicarbonate ) SM 2320B-2011 1 04/04/2015 1747 HMA 04/04/2015 1747 1 (Carbonate Al) SM 2320B-2011 1 04/04/2015 1747 HMA 04/04/2015 1747 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 1mg/L10 Bicarbonate Alkalinity SM 2320B-20 ND 1mg/L10 Carbonate Alkalinity SM 2320B-20 ND 1mg/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 9 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: Duke Energy 2015008530 QC27018-003 03/24/2015 1715 03/27/2015 Aqueous Project Name: AB GW Assessment Water - Project Number: J15030669 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 04/04/2015 0147 JJG 71805 AnalyticalCAS Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 1ug/L10 J = Estimated result < PQL and > MDL PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" N = Recovery is out of criteria_ H = Out of holding time Page: 10 of 10 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 QC Summary QC Data for Lot Number: QC27018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - MB Batch: Sample ID:QQ71829-001 71829 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Alkalinity ND 04/04/2015 170210mg/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QC27018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Inorganic non-metals - LCS Batch: Sample ID:QQ71829-002 71829 Analytical Method:SM 2320B-2011 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(mg/L)(mg/L) Alkalinity 94 04/04/2015 17089410090-1101 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QC27018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - MB Batch: Sample ID:QQ71805-001 71805 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q PQL Units Analysis DateDil Methane ND 04/04/2015 004110ug/L1 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QC27018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCS Batch: Sample ID:QQ71805-002 71805 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date % Rec LimitDil(ug/L)(ug/L) Methane 150 04/04/2015 00049715070-1301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QC27018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Methane - LCSD Batch: Sample ID:QQ71805-003 71805 Analytical Method:RSK - 175 Matrix:Aqueous Parameter Result Q % Rec Spike Amount Analysis Date% RPD % Rec Limit % RPD LimitDil(ug/L)(ug/L) Methane 170 04/04/2015 001511215070-13015 301 Note:Calculations are performed before rounding to avoid round-off errors in calculated results PQL = Practical quantitation limit ND = Not detected at or above the PQL Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" J = Estimated result < PQL and > MDL N = Recovery is out of criteriaP = The RPD between two GC columns exceeds 40% + = RPD is out of criteria_ QC Data for Lot Number: QC27018 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Level 1 Report v2.1 Page 29 of 33 Page 30 of 33 Page 31 of 33 Page 32 of 33 Page 33 of 33