The URL can be used to link to this page

Home My WebLink AboutNC0001422_ATT 5 - Soil - J15050747 Report_2015080513339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number: J15050747 Project Name:SUTTON - AB GW ASSESSMENT SOIL Lab Contact:Margaret Galvin-Karr Date:6/16/2015 Customer Address: Customer Name(s):Perry Waldrep, Tim Hunsucker, Kathy Webb, John Toepfer Phone: 980-875-5219 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Margaret Galvin-Karr) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Margaret Galvin-Karr 1 of 59 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015016332 Sutton 26-May-15 5:50 PM ILLEGIBLE SW-CFUP 2015016333 Sutton 26-May-15 2:10 PM ILLEGIBLE SW-6A 2015016334 Sutton 26-May-15 2:50 PM ILLEGIBLE SW-8A 2015016335 Sutton 26-May-15 3:30 PM ILLEGIBLE SW-004 4 Total Samples 2 of 59 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By: Date: Electronic Data Deliverable (EDD) Sent Separately 3 of 59 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050747 2015016332 Collection Date: 26-May-15 5:50 PM Site:SW-CFUP Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 4 of 59 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050747 2015016333 Collection Date: 26-May-15 2:10 PM Site:SW-6A Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete Vendor Method V_A.Analytical TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 5 of 59 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050747 2015016334 Collection Date: 26-May-15 2:50 PM Site:SW-8A Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete Vendor Method V_A.Analytical TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 6 of 59 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050747 2015016335 Collection Date: 26-May-15 3:30 PM Site:SW-004 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete Vendor Method V_A.Analytical TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 7 of 59 #=CL# June 15, 2015 LIMS USE: FR - PROGRAM MANAGER LIMS OBJECT ID: 92251877 92251877 Project: Pace Project No.: RE: Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 J15050747 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on May 28, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc:Marge Galvin-Karr, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Rodney Wike, Duke Energy REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 38 8 of 59 #=CP# CERTIFICATIONS Pace Project No.: Project: 92251877 J15050747 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 38 9 of 59 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92251877 J15050747 Lab ID Sample ID Matrix Date Collected Date Received 92251877001 2015016332 Solid 05/20/15 17:50 05/28/15 16:40 92251877002 2015016333 Solid 05/20/15 14:10 05/28/15 16:40 92251877003 2015016334 Solid 05/20/15 14:50 05/28/15 16:40 92251877004 2015016335 Solid 05/20/15 15:30 05/28/15 16:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 38 10 of 59 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92251877 J15050747 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92251877001 2015016332 EPA 6010 16 PASI-OCKJ, TAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OCRT ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMAB EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92251877002 2015016333 EPA 6010 16 PASI-OCKJ, TAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OCRT ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMAB EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92251877003 2015016334 EPA 6010 16 PASI-OCKJ, TAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OCRT ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMAB EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92251877004 2015016335 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OCRT ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMAB EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 38 11 of 59 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92251877 J15050747 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92251877001 2015016332 Aluminum 302 mg/kg 06/05/15 13:126.5EPA 6010 Barium 2.8 mg/kg 06/05/15 13:120.65EPA 6010 Beryllium 0.076 mg/kg 06/05/15 13:120.065EPA 6010 Calcium 44.3 mg/kg 06/05/15 13:1232.3EPA 6010 Chromium 0.56 mg/kg 06/05/15 13:120.32EPA 6010 Copper 0.26J mg/kg 06/05/15 13:120.32EPA 6010 Iron 1180 mg/kg 06/05/15 13:122.6EPA 6010 Manganese 17.4 mg/kg 06/05/15 13:120.32EPA 6010 Nickel 0.66 mg/kg 06/05/15 13:120.32EPA 6010 Strontium 0.46J mg/kg 06/05/15 13:120.65EPA 6010 Zinc 4.8 mg/kg 06/05/15 13:121.3EPA 6010 Percent Moisture 23.2 %06/04/15 09:170.10ASTM D2974-87 pH at 25 Degrees C 6.5 Std. Units 06/05/15 14:550.10EPA 9045 Total Organic Carbon 784 mg/kg 06/12/15 10:22774EPA 9060 Total Organic Carbon 787 mg/kg 06/12/15 10:28780EPA 9060 Total Organic Carbon 753J mg/kg 06/12/15 10:34785EPA 9060 Total Organic Carbon 764J mg/kg 06/12/15 10:41774EPA 9060 Mean Total Organic Carbon 772J mg/kg 06/12/15 10:22778EPA 9060 RSD%2.1 %06/12/15 10:22EPA 9060 92251877002 2015016333 Aluminum 328 mg/kg 06/05/15 13:296.8EPA 6010 Barium 61.0 mg/kg 06/05/15 13:290.68EPA 6010 Beryllium 0.073 mg/kg 06/05/15 13:290.068EPA 6010 Boron 1.7J mg/kg 06/05/15 13:293.4EPA 6010 Calcium 43400 mg/kg 06/06/15 15:57 D4170EPA 6010 Chromium 0.79 mg/kg 06/05/15 13:290.34EPA 6010 Copper 15.8 mg/kg 06/06/15 15:57 D31.7EPA 6010 Iron 1070 mg/kg 06/05/15 13:292.7EPA 6010 Magnesium 88.6 mg/kg 06/05/15 13:2934.0EPA 6010 Manganese 161 mg/kg 06/05/15 13:290.34EPA 6010 Molybdenum 0.70 mg/kg 06/05/15 13:290.68EPA 6010 Nickel 3.6 mg/kg 06/05/15 13:290.34EPA 6010 Sodium 201J mg/kg 06/06/15 15:57 D3340EPA 6010 Strontium 252 mg/kg 06/06/15 15:57 D33.4EPA 6010 Zinc 4.6 mg/kg 06/05/15 13:291.4EPA 6010 Arsenic 4.6J mg/kg 06/05/15 10:446.8EPA 6020 Vanadium 5.8J mg/kg 06/05/15 10:446.8EPA 6020 Mercury 0.0053J mg/kg 06/05/15 13:170.011EPA 7471 Percent Moisture 28.1 %06/04/15 09:170.10ASTM D2974-87 pH at 25 Degrees C 6.6 Std. Units 06/05/15 14:550.10EPA 9045 Total Organic Carbon 7130 mg/kg 06/12/15 11:34836EPA 9060 Total Organic Carbon 3490 mg/kg 06/12/15 11:39831EPA 9060 Total Organic Carbon 3020 mg/kg 06/12/15 11:45836EPA 9060 Total Organic Carbon 2390 mg/kg 06/12/15 11:50832EPA 9060 Mean Total Organic Carbon 4010 mg/kg 06/12/15 11:34834EPA 9060 RSD%53.2 %06/12/15 11:34 1gEPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 38 12 of 59 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92251877 J15050747 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92251877003 2015016334 Aluminum 312 mg/kg 06/05/15 13:337.2EPA 6010 Barium 90.4 mg/kg 06/05/15 13:330.72EPA 6010 Beryllium 0.047J mg/kg 06/05/15 13:330.072EPA 6010 Calcium 145000 mg/kg 06/06/15 16:01 D4179EPA 6010 Chromium 0.82 mg/kg 06/05/15 13:330.36EPA 6010 Copper 11.6 mg/kg 06/06/15 16:01 D41.8EPA 6010 Iron 992 mg/kg 06/05/15 13:332.9EPA 6010 Magnesium 47.4 mg/kg 06/05/15 13:3335.8EPA 6010 Manganese 111 mg/kg 06/05/15 13:330.36EPA 6010 Molybdenum 0.42J mg/kg 06/05/15 13:330.72EPA 6010 Nickel 2.2 mg/kg 06/05/15 13:330.36EPA 6010 Sodium 790 mg/kg 06/06/15 16:01 D3358EPA 6010 Strontium 862 mg/kg 06/06/15 16:01 D43.6EPA 6010 Zinc 4.5 mg/kg 06/05/15 13:331.4EPA 6010 Vanadium 4.3J mg/kg 06/05/15 10:577.2EPA 6020 Percent Moisture 27.9 %06/04/15 09:170.10ASTM D2974-87 pH at 25 Degrees C 6.9 Std. Units 06/05/15 14:550.10EPA 9045 Total Organic Carbon 1430 mg/kg 06/12/15 11:56827EPA 9060 Total Organic Carbon 1520 mg/kg 06/12/15 12:01832EPA 9060 Total Organic Carbon 1700 mg/kg 06/12/15 12:06840EPA 9060 Total Organic Carbon 1840 mg/kg 06/12/15 12:12832EPA 9060 Mean Total Organic Carbon 1630 mg/kg 06/12/15 11:56833EPA 9060 RSD%11.4 %06/12/15 11:56EPA 9060 92251877004 2015016335 Aluminum 591 mg/kg 06/05/15 16:556.4EPA 6010 Barium 6.9 mg/kg 06/05/15 16:550.64EPA 6010 Beryllium 0.45 mg/kg 06/05/15 16:550.064EPA 6010 Calcium 15700 mg/kg 06/05/15 16:5531.9EPA 6010 Chromium 4.2 mg/kg 06/05/15 16:550.32EPA 6010 Copper 8.1 mg/kg 06/05/15 16:550.32EPA 6010 Iron 949 mg/kg 06/05/15 16:552.6EPA 6010 Magnesium 27.2J mg/kg 06/05/15 16:5531.9EPA 6010 Manganese 5.1 mg/kg 06/05/15 16:550.32EPA 6010 Molybdenum 3.4 mg/kg 06/05/15 16:550.64EPA 6010 Nickel 1.3 mg/kg 06/05/15 16:550.32EPA 6010 Potassium 68.5 mg/kg 06/05/15 16:5563.8EPA 6010 Sodium 154 mg/kg 06/05/15 16:5563.8EPA 6010 Strontium 64.4 mg/kg 06/05/15 16:550.64EPA 6010 Zinc 4.9 mg/kg 06/05/15 16:551.3EPA 6010 Vanadium 12.5 mg/kg 06/05/15 10:596.4EPA 6020 Percent Moisture 24.6 %06/04/15 09:170.10ASTM D2974-87 pH at 25 Degrees C 6.9 Std. Units 06/05/15 14:550.10EPA 9045 Total Organic Carbon 1410 mg/kg 06/12/15 12:31794EPA 9060 Total Organic Carbon 1390 mg/kg 06/12/15 12:37797EPA 9060 Total Organic Carbon 1500 mg/kg 06/12/15 12:43796EPA 9060 Total Organic Carbon 1390 mg/kg 06/12/15 12:50791EPA 9060 Mean Total Organic Carbon 1420 mg/kg 06/12/15 12:31794EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 38 13 of 59 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92251877 J15050747 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92251877004 2015016335 RSD%3.8 %06/12/15 12:31EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 38 14 of 59 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92251877 J15050747 Method: Client:Duke Energy EPA 6010 Date:June 15, 2015 Description:6010 MET ICP General Information: 4 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24521 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35190409001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1231984) • Aluminum • Iron • MSD (Lab ID: 1231985) • Aluminum Additional Comments: Analyte Comments: QC Batch: MPRP/24521 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015016332 (Lab ID: 92251877001) • Potassium • 2015016333 (Lab ID: 92251877002) • Copper • Potassium • Sodium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 38 15 of 59 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92251877 J15050747 Method: Client:Duke Energy EPA 6010 Date:June 15, 2015 Description:6010 MET ICP Analyte Comments: QC Batch: MPRP/24521 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015016333 (Lab ID: 92251877002) • Strontium • 2015016334 (Lab ID: 92251877003) • Potassium • Sodium D4: Sample was diluted due to the presence of high levels of target analytes. • 2015016333 (Lab ID: 92251877002) • Calcium • 2015016334 (Lab ID: 92251877003) • Calcium • Copper • Strontium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 38 16 of 59 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92251877 J15050747 Method: Client:Duke Energy EPA 6020 Date:June 15, 2015 Description:6020 MET ICPMS General Information: 4 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24522 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92251877001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1231988) • Selenium • MSD (Lab ID: 1231989) • Selenium Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • QC Batch: ICPM / 9927 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 38 17 of 59 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92251877 J15050747 Method: Client:Duke Energy EPA 6020 Date:June 15, 2015 Description:6020 MET ICPMS Analyte Comments: QC Batch: MPRP/24522 N2: The lab does not hold TNI accreditation for this parameter. • 2015016332 (Lab ID: 92251877001) • Antimony • 2015016333 (Lab ID: 92251877002) • Antimony • 2015016334 (Lab ID: 92251877003) • Antimony • 2015016335 (Lab ID: 92251877004) • Antimony • BLANK (Lab ID: 1231986) • Antimony • LCS (Lab ID: 1231987) • Antimony • MS (Lab ID: 1231988) • Antimony • MSD (Lab ID: 1231989) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 38 18 of 59 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92251877 J15050747 Method: Client:Duke Energy EPA 7471 Date:June 15, 2015 Description:7471 Mercury General Information: 4 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MERP/5819 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35189952001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1232529) • Mercury Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 38 19 of 59 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92251877 J15050747 Method: Client:Duke Energy EPA 9045 Date:June 15, 2015 Description:9045 pH Soil General Information: 4 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 38 20 of 59 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92251877 J15050747 Method: Client:Duke Energy EPA 9056 Date:June 15, 2015 Description:9056 IC Anions General Information: 4 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/46862 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015016332 (Lab ID: 92251877001) • Chloride • Sulfate • 2015016333 (Lab ID: 92251877002) • Chloride • Sulfate • 2015016334 (Lab ID: 92251877003) • Chloride • Sulfate • 2015016335 (Lab ID: 92251877004) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 38 21 of 59 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92251877 J15050747 Method: Client:Duke Energy EPA 9056 Date:June 15, 2015 Description:9056 IC Anions 48hr General Information: 4 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H3: Sample was received or analysis requested beyond the recognized method holding time. • 2015016332 (Lab ID: 92251877001) • 2015016333 (Lab ID: 92251877002) • 2015016334 (Lab ID: 92251877003) • 2015016335 (Lab ID: 92251877004) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/46861 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015016332 (Lab ID: 92251877001) • Nitrate as N • 2015016333 (Lab ID: 92251877002) • Nitrate as N • 2015016334 (Lab ID: 92251877003) • Nitrate as N • 2015016335 (Lab ID: 92251877004) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 38 22 of 59 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92251877 J15050747 Method: Client:Duke Energy EPA 9060 Date:June 15, 2015 Description:Total Organic Carbon Quad General Information: 4 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/28987 1g: % RSD > 40 • 2015016333 (Lab ID: 92251877002) • RSD% This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 38 23 of 59 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92251877 J15050747 Sample:2015016332 Lab ID:92251877001 Collected:05/20/15 17:50 Received:05/28/15 16:40 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 302 mg/kg 06/05/15 13:12 7429-90-506/04/15 15:506.5 3.2 1 Barium 2.8 mg/kg 06/05/15 13:12 7440-39-306/04/15 15:500.65 0.32 1 Beryllium 0.076 mg/kg 06/05/15 13:12 7440-41-706/04/15 15:500.065 0.032 1 Boron ND mg/kg 06/05/15 13:12 7440-42-806/04/15 15:503.2 1.6 1 Calcium 44.3 mg/kg 06/05/15 13:12 7440-70-206/04/15 15:5032.3 16.2 1 Chromium 0.56 mg/kg 06/05/15 13:12 7440-47-306/04/15 15:500.32 0.16 1 Copper 0.26J mg/kg 06/05/15 13:12 7440-50-806/04/15 15:500.32 0.16 1 Iron 1180 mg/kg 06/05/15 13:12 7439-89-606/04/15 15:502.6 1.3 1 Magnesium ND mg/kg 06/05/15 13:12 7439-95-406/04/15 15:5032.3 16.2 1 Manganese 17.4 mg/kg 06/05/15 13:12 7439-96-506/04/15 15:500.32 0.16 1 Molybdenum ND mg/kg 06/05/15 13:12 7439-98-706/04/15 15:500.65 0.32 1 Nickel 0.66 mg/kg 06/05/15 13:12 7440-02-006/04/15 15:500.32 0.16 1 Potassium ND mg/kg 06/06/15 15:53 7440-09-7 D306/04/15 15:503231625 Sodium ND mg/kg 06/05/15 13:12 7440-23-506/04/15 15:5064.7 32.3 1 Strontium 0.46J mg/kg 06/05/15 13:12 7440-24-606/04/15 15:500.65 0.32 1 Zinc 4.8 mg/kg 06/05/15 13:12 7440-66-606/04/15 15:501.3 0.65 1 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 06/05/15 10:36 7440-36-0 N206/04/15 15:506.5 3.2 100 Arsenic ND mg/kg 06/05/15 10:36 7440-38-206/04/15 15:506.5 3.2 100 Cadmium ND mg/kg 06/05/15 10:36 7440-43-906/04/15 15:500.78 0.39 100 Cobalt ND mg/kg 06/05/15 10:36 7440-48-406/04/15 15:506.5 3.2 100 Lead ND mg/kg 06/05/15 10:36 7439-92-106/04/15 15:506.5 3.2 100 Selenium ND mg/kg 06/05/15 10:36 7782-49-2 M606/04/15 15:506.5 3.2 100 Thallium ND mg/kg 06/05/15 10:36 7440-28-006/04/15 15:506.5 3.2 100 Vanadium ND mg/kg 06/05/15 10:36 7440-62-206/04/15 15:506.5 3.2 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 06/05/15 13:14 7439-97-606/04/15 16:000.011 0.0053 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 23.2 %06/04/15 09:170.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.5 Std. Units 06/05/15 14:550.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 05/31/15 23:52 16887-00-6 D33201605 Sulfate ND mg/kg 05/31/15 23:52 14808-79-8 D33201605 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 05/31/15 23:52 14797-55-8 D3,H332.0 16.0 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 11:30 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 38 24 of 59 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92251877 J15050747 Sample:2015016332 Lab ID:92251877001 Collected:05/20/15 17:50 Received:05/28/15 16:40 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 784 mg/kg 06/12/15 10:22 7440-44-07743871 Total Organic Carbon 787 mg/kg 06/12/15 10:28 7440-44-07803901 Total Organic Carbon 753J mg/kg 06/12/15 10:34 7440-44-07853921 Total Organic Carbon 764J mg/kg 06/12/15 10:41 7440-44-07743871 Mean Total Organic Carbon 772J mg/kg 06/12/15 10:22 7440-44-07783891 Surrogates RSD%2.1 %06/12/15 10:221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 11:30 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 38 25 of 59 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92251877 J15050747 Sample:2015016333 Lab ID:92251877002 Collected:05/20/15 14:10 Received:05/28/15 16:40 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 328 mg/kg 06/05/15 13:29 7429-90-506/04/15 15:506.8 3.4 1 Barium 61.0 mg/kg 06/05/15 13:29 7440-39-306/04/15 15:500.68 0.34 1 Beryllium 0.073 mg/kg 06/05/15 13:29 7440-41-706/04/15 15:500.068 0.034 1 Boron 1.7J mg/kg 06/05/15 13:29 7440-42-806/04/15 15:503.4 1.7 1 Calcium 43400 mg/kg 06/06/15 15:57 7440-70-2 D406/04/15 15:5017085.0 5 Chromium 0.79 mg/kg 06/05/15 13:29 7440-47-306/04/15 15:500.34 0.17 1 Copper 15.8 mg/kg 06/06/15 15:57 7440-50-8 D306/04/15 15:501.7 0.85 5 Iron 1070 mg/kg 06/05/15 13:29 7439-89-606/04/15 15:502.7 1.4 1 Magnesium 88.6 mg/kg 06/05/15 13:29 7439-95-406/04/15 15:5034.0 17.0 1 Manganese 161 mg/kg 06/05/15 13:29 7439-96-506/04/15 15:500.34 0.17 1 Molybdenum 0.70 mg/kg 06/05/15 13:29 7439-98-706/04/15 15:500.68 0.34 1 Nickel 3.6 mg/kg 06/05/15 13:29 7440-02-006/04/15 15:500.34 0.17 1 Potassium ND mg/kg 06/06/15 15:57 7440-09-7 D306/04/15 15:503401705 Sodium 201J mg/kg 06/06/15 15:57 7440-23-5 D306/04/15 15:503401705 Strontium 252 mg/kg 06/06/15 15:57 7440-24-6 D306/04/15 15:503.4 1.7 5 Zinc 4.6 mg/kg 06/05/15 13:29 7440-66-606/04/15 15:501.4 0.68 1 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 06/05/15 10:44 7440-36-0 N206/04/15 15:506.8 3.4 100 Arsenic 4.6J mg/kg 06/05/15 10:44 7440-38-206/04/15 15:506.8 3.4 100 Cadmium ND mg/kg 06/05/15 10:44 7440-43-906/04/15 15:500.82 0.41 100 Cobalt ND mg/kg 06/05/15 10:44 7440-48-406/04/15 15:506.8 3.4 100 Lead ND mg/kg 06/05/15 10:44 7439-92-106/04/15 15:506.8 3.4 100 Selenium ND mg/kg 06/05/15 10:44 7782-49-206/04/15 15:506.8 3.4 100 Thallium ND mg/kg 06/05/15 10:44 7440-28-006/04/15 15:506.8 3.4 100 Vanadium 5.8J mg/kg 06/05/15 10:44 7440-62-206/04/15 15:506.8 3.4 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.0053J mg/kg 06/05/15 13:17 7439-97-606/04/15 16:000.011 0.0053 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 28.1 %06/04/15 09:170.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.6 Std. Units 06/05/15 14:550.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 06/01/15 00:56 16887-00-6 D33441725 Sulfate ND mg/kg 06/01/15 00:56 14808-79-8 D33441725 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 06/01/15 00:56 14797-55-8 D3,H334.4 17.2 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 11:30 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 38 26 of 59 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92251877 J15050747 Sample:2015016333 Lab ID:92251877002 Collected:05/20/15 14:10 Received:05/28/15 16:40 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 7130 mg/kg 06/12/15 11:34 7440-44-08364181 Total Organic Carbon 3490 mg/kg 06/12/15 11:39 7440-44-08314151 Total Organic Carbon 3020 mg/kg 06/12/15 11:45 7440-44-08364181 Total Organic Carbon 2390 mg/kg 06/12/15 11:50 7440-44-08324161 Mean Total Organic Carbon 4010 mg/kg 06/12/15 11:34 7440-44-08344171 Surrogates RSD%53.2 %06/12/15 11:34 1g1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 11:30 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 38 27 of 59 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92251877 J15050747 Sample:2015016334 Lab ID:92251877003 Collected:05/20/15 14:50 Received:05/28/15 16:40 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 312 mg/kg 06/05/15 13:33 7429-90-506/04/15 15:507.2 3.6 1 Barium 90.4 mg/kg 06/05/15 13:33 7440-39-306/04/15 15:500.72 0.36 1 Beryllium 0.047J mg/kg 06/05/15 13:33 7440-41-706/04/15 15:500.072 0.036 1 Boron ND mg/kg 06/05/15 13:33 7440-42-806/04/15 15:503.6 1.8 1 Calcium 145000 mg/kg 06/06/15 16:01 7440-70-2 D406/04/15 15:5017989.6 5 Chromium 0.82 mg/kg 06/05/15 13:33 7440-47-306/04/15 15:500.36 0.18 1 Copper 11.6 mg/kg 06/06/15 16:01 7440-50-8 D406/04/15 15:501.8 0.90 5 Iron 992 mg/kg 06/05/15 13:33 7439-89-606/04/15 15:502.9 1.4 1 Magnesium 47.4 mg/kg 06/05/15 13:33 7439-95-406/04/15 15:5035.8 17.9 1 Manganese 111 mg/kg 06/05/15 13:33 7439-96-506/04/15 15:500.36 0.18 1 Molybdenum 0.42J mg/kg 06/05/15 13:33 7439-98-706/04/15 15:500.72 0.36 1 Nickel 2.2 mg/kg 06/05/15 13:33 7440-02-006/04/15 15:500.36 0.18 1 Potassium ND mg/kg 06/06/15 16:01 7440-09-7 D306/04/15 15:503581795 Sodium 790 mg/kg 06/06/15 16:01 7440-23-5 D306/04/15 15:503581795 Strontium 862 mg/kg 06/06/15 16:01 7440-24-6 D406/04/15 15:503.6 1.8 5 Zinc 4.5 mg/kg 06/05/15 13:33 7440-66-606/04/15 15:501.4 0.72 1 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 06/05/15 10:57 7440-36-0 N206/04/15 15:507.2 3.6 100 Arsenic ND mg/kg 06/05/15 10:57 7440-38-206/04/15 15:507.2 3.6 100 Cadmium ND mg/kg 06/05/15 10:57 7440-43-906/04/15 15:500.86 0.43 100 Cobalt ND mg/kg 06/05/15 10:57 7440-48-406/04/15 15:507.2 3.6 100 Lead ND mg/kg 06/05/15 10:57 7439-92-106/04/15 15:507.2 3.6 100 Selenium ND mg/kg 06/05/15 10:57 7782-49-206/04/15 15:507.2 3.6 100 Thallium ND mg/kg 06/05/15 10:57 7440-28-006/04/15 15:507.2 3.6 100 Vanadium 4.3J mg/kg 06/05/15 10:57 7440-62-206/04/15 15:507.2 3.6 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 06/05/15 13:23 7439-97-606/04/15 16:000.011 0.0056 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 27.9 %06/04/15 09:170.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.9 Std. Units 06/05/15 14:550.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 06/01/15 01:18 16887-00-6 D33471735 Sulfate ND mg/kg 06/01/15 01:18 14808-79-8 D33471735 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 06/01/15 01:18 14797-55-8 D3,H334.7 17.3 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 11:30 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 38 28 of 59 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92251877 J15050747 Sample:2015016334 Lab ID:92251877003 Collected:05/20/15 14:50 Received:05/28/15 16:40 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 1430 mg/kg 06/12/15 11:56 7440-44-08274141 Total Organic Carbon 1520 mg/kg 06/12/15 12:01 7440-44-08324161 Total Organic Carbon 1700 mg/kg 06/12/15 12:06 7440-44-08404201 Total Organic Carbon 1840 mg/kg 06/12/15 12:12 7440-44-08324161 Mean Total Organic Carbon 1630 mg/kg 06/12/15 11:56 7440-44-08334161 Surrogates RSD%11.4 %06/12/15 11:561 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 11:30 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 38 29 of 59 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92251877 J15050747 Sample:2015016335 Lab ID:92251877004 Collected:05/20/15 15:30 Received:05/28/15 16:40 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 591 mg/kg 06/05/15 16:55 7429-90-506/04/15 15:506.4 3.2 1 Barium 6.9 mg/kg 06/05/15 16:55 7440-39-306/04/15 15:500.64 0.32 1 Beryllium 0.45 mg/kg 06/05/15 16:55 7440-41-706/04/15 15:500.064 0.032 1 Boron ND mg/kg 06/05/15 16:55 7440-42-806/04/15 15:503.2 1.6 1 Calcium 15700 mg/kg 06/05/15 16:55 7440-70-206/04/15 15:5031.9 15.9 1 Chromium 4.2 mg/kg 06/05/15 16:55 7440-47-306/04/15 15:500.32 0.16 1 Copper 8.1 mg/kg 06/05/15 16:55 7440-50-806/04/15 15:500.32 0.16 1 Iron 949 mg/kg 06/05/15 16:55 7439-89-606/04/15 15:502.6 1.3 1 Magnesium 27.2J mg/kg 06/05/15 16:55 7439-95-406/04/15 15:5031.9 15.9 1 Manganese 5.1 mg/kg 06/05/15 16:55 7439-96-506/04/15 15:500.32 0.16 1 Molybdenum 3.4 mg/kg 06/05/15 16:55 7439-98-706/04/15 15:500.64 0.32 1 Nickel 1.3 mg/kg 06/05/15 16:55 7440-02-006/04/15 15:500.32 0.16 1 Potassium 68.5 mg/kg 06/05/15 16:55 7440-09-706/04/15 15:5063.8 31.9 1 Sodium 154 mg/kg 06/05/15 16:55 7440-23-506/04/15 15:5063.8 31.9 1 Strontium 64.4 mg/kg 06/05/15 16:55 7440-24-606/04/15 15:500.64 0.32 1 Zinc 4.9 mg/kg 06/05/15 16:55 7440-66-606/04/15 15:501.3 0.64 1 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 06/05/15 10:59 7440-36-0 N206/04/15 15:506.4 3.2 100 Arsenic ND mg/kg 06/05/15 10:59 7440-38-206/04/15 15:506.4 3.2 100 Cadmium ND mg/kg 06/05/15 10:59 7440-43-906/04/15 15:500.77 0.38 100 Cobalt ND mg/kg 06/05/15 10:59 7440-48-406/04/15 15:506.4 3.2 100 Lead ND mg/kg 06/05/15 10:59 7439-92-106/04/15 15:506.4 3.2 100 Selenium ND mg/kg 06/05/15 10:59 7782-49-206/04/15 15:506.4 3.2 100 Thallium ND mg/kg 06/05/15 10:59 7440-28-006/04/15 15:506.4 3.2 100 Vanadium 12.5 mg/kg 06/05/15 10:59 7440-62-206/04/15 15:506.4 3.2 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 06/05/15 13:25 7439-97-606/04/15 16:000.010 0.0052 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 24.6 %06/04/15 09:170.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.9 Std. Units 06/05/15 14:550.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 06/01/15 01:39 16887-00-6 D33321665 Sulfate ND mg/kg 06/01/15 01:39 14808-79-8 D33321665 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 06/01/15 01:39 14797-55-8 D3,H333.2 16.6 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 11:30 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 38 30 of 59 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92251877 J15050747 Sample:2015016335 Lab ID:92251877004 Collected:05/20/15 15:30 Received:05/28/15 16:40 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 1410 mg/kg 06/12/15 12:31 7440-44-07943971 Total Organic Carbon 1390 mg/kg 06/12/15 12:37 7440-44-07973981 Total Organic Carbon 1500 mg/kg 06/12/15 12:43 7440-44-07963981 Total Organic Carbon 1390 mg/kg 06/12/15 12:50 7440-44-07913951 Mean Total Organic Carbon 1420 mg/kg 06/12/15 12:31 7440-44-07943971 Surrogates RSD%3.8 %06/12/15 12:311 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 11:30 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 38 31 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251877 J15050747 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/5819 EPA 7471 EPA 7471 7471 Mercury Associated Lab Samples:92251877001, 92251877002, 92251877003, 92251877004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1232527 Associated Lab Samples:92251877001, 92251877002, 92251877003, 92251877004 Matrix:Solid Analyzed Mercury mg/kg ND 0.0078 06/05/15 12:52 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1232528LABORATORY CONTROL SAMPLE: LCSSpike Mercury mg/kg 0.078.081 96 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1232529MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 35189952001 1232530 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury mg/kg M11.14 129 80-120111 12 201.070.53 2.0 1.7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 11:30 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 38 32 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251877 J15050747 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/24521 EPA 3050 EPA 6010 6010 MET Solid Associated Lab Samples:92251877001, 92251877002, 92251877003, 92251877004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1231982 Associated Lab Samples:92251877001, 92251877002, 92251877003, 92251877004 Matrix:Solid Analyzed Aluminum mg/kg ND 5.2 06/05/15 11:46 Barium mg/kg ND 0.52 06/05/15 11:46 Beryllium mg/kg ND 0.052 06/05/15 11:46 Boron mg/kg ND 2.6 06/05/15 11:46 Calcium mg/kg ND 26.2 06/05/15 11:46 Chromium mg/kg ND 0.26 06/05/15 11:46 Copper mg/kg ND 0.26 06/05/15 11:46 Iron mg/kg 1.9J 2.1 06/05/15 11:46 Magnesium mg/kg ND 26.2 06/05/15 11:46 Manganese mg/kg ND 0.26 06/05/15 11:46 Molybdenum mg/kg ND 0.52 06/05/15 11:46 Nickel mg/kg ND 0.26 06/05/15 11:46 Potassium mg/kg ND 52.4 06/05/15 11:46 Sodium mg/kg ND 52.4 06/05/15 11:46 Strontium mg/kg ND 0.52 06/05/15 11:46 Zinc mg/kg ND 1.0 06/05/15 11:46 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1231983LABORATORY CONTROL SAMPLE: LCSSpike Aluminum mg/kg 172188 91 80-120 Barium mg/kg 17.318.8 92 80-120 Beryllium mg/kg 1.71.9 90 80-120 Boron mg/kg 167188 89 80-120 Calcium mg/kg 867939 92 80-120 Chromium mg/kg 16.918.8 90 80-120 Copper mg/kg 16.518.8 88 80-120 Iron mg/kg 171188 91 80-120 Magnesium mg/kg 858939 91 80-120 Manganese mg/kg 16.918.8 90 80-120 Molybdenum mg/kg 16.618.8 88 80-120 Nickel mg/kg 16.818.8 89 80-120 Potassium mg/kg 838939 89 80-120 Sodium mg/kg 876939 93 80-120 Strontium mg/kg 17.118.8 91 80-120 Zinc mg/kg 83.593.9 89 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 11:30 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 38 33 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251877 J15050747 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1231984MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 35190409001 1231985 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum mg/kg M170712975-125127 1 20740170026102640 Barium mg/kg 70.7 95 75-12591 0 2074100167168 Beryllium mg/kg 7.14 87 75-12585 2 207.520.098U 6.2 6.3 Boron mg/kg 707 88 75-12586 3 2074036.6 657 677 Calcium mg/kg 3540 84 75-12583 0 203700116001460014700 Chromium mg/kg 70.7 85 75-12584 3 207411.6 71.8 73.8 Copper mg/kg 70.7 88 75-12583 0 2074195257256 Iron mg/kg M17077475-12575 1 20740503055505580 Magnesium mg/kg 3540 87 75-12587 3 20370083439004040 Manganese mg/kg 70.7 84 75-12576 2 2074142202198 Molybdenum mg/kg 70.7 79 75-12579 4 20744.0 59.9 62.2 Nickel mg/kg 70.7 85 75-12585 3 20747.5 67.9 70.2 Potassium mg/kg 3540 87 75-12587 4 20370069537803920 Sodium mg/kg 3540 89 75-12590 4 20370087140304210 Strontium mg/kg 70.7 91 75-12587 0 2074139203203 Zinc mg/kg 354 84 75-12582 1 20370492790796 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 11:30 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 38 34 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251877 J15050747 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/24522 EPA 3050 EPA 6020 6020 MET SOLID Associated Lab Samples:92251877001, 92251877002, 92251877003, 92251877004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1231986 Associated Lab Samples:92251877001, 92251877002, 92251877003, 92251877004 Matrix:Solid Analyzed Antimony mg/kg ND 0.051 N206/05/15 10:31 Arsenic mg/kg ND 0.051 06/05/15 10:31 Cadmium mg/kg ND 0.0061 06/05/15 10:31 Cobalt mg/kg ND 0.051 06/05/15 10:31 Lead mg/kg ND 0.051 06/05/15 10:31 Selenium mg/kg ND 0.051 06/05/15 10:31 Thallium mg/kg ND 0.051 06/05/15 10:31 Vanadium mg/kg ND 0.051 06/05/15 10:31 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1231987LABORATORY CONTROL SAMPLE: LCSSpike Antimony mg/kg 2.4 N22.5 97 80-120 Arsenic mg/kg 2.42.5 98 80-120 Cadmium mg/kg 0.25.25 99 80-120 Cobalt mg/kg 2.52.5 103 80-120 Lead mg/kg 2.52.5 102 80-120 Selenium mg/kg 2.42.5 98 80-120 Thallium mg/kg 2.62.5 105 80-120 Vanadium mg/kg 2.52.5 100 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1231988MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92251877001 1231989 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony mg/kg N23.13 87 75-12595 203.39ND ND 3.4J Arsenic mg/kg 3.13 83 75-12584 203.39ND ND ND Cadmium mg/kg .313 78 75-125100 20.339ND ND ND Cobalt mg/kg 3.13 100 75-125101 203.39ND 3.9J 4.2J Lead mg/kg 3.13 101 75-12594 203.39ND 3.6J 3.6J Selenium mg/kg M63.13 71 75-12556 203.39ND 3.4J ND Thallium mg/kg 3.13 90 75-12587 203.39ND ND ND Vanadium mg/kg 3.13 86 75-12588 203.39ND 3.4J 3.6J REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 11:30 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 38 35 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251877 J15050747 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: PMST/3614 ASTM D2974-87 ASTM D2974-87 Dry Weight/Percent Moisture Associated Lab Samples:92251877001, 92251877002, 92251877003, 92251877004 Parameter Units Dup Result Max RPD QualifiersRPDResult 35189331001 1231890SAMPLE DUPLICATE: Percent Moisture %99.6 0 1099.6 Parameter Units Dup Result Max RPD QualifiersRPDResult 35190463012 1231891SAMPLE DUPLICATE: Percent Moisture %21.0 6 10 Parameter Units Dup Result Max RPD QualifiersRPDResult 35190901003 1231892SAMPLE DUPLICATE: Percent Moisture %5.5 1 105.5 Parameter Units Dup Result Max RPD QualifiersRPDResult 35190901012 1231893SAMPLE DUPLICATE: Percent Moisture %4.5 8 104.9 Parameter Units Dup Result Max RPD QualifiersRPDResult 35191012008 1231894SAMPLE DUPLICATE: Percent Moisture %25.3 7 1023.7 Parameter Units Dup Result Max RPD QualifiersRPDResult 35191012017 1231895SAMPLE DUPLICATE: Percent Moisture %19.4 2 1019.0 Parameter Units Dup Result Max RPD QualifiersRPDResult 35191012026 1231896SAMPLE DUPLICATE: Percent Moisture %20.9 D6211016.9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 11:30 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 38 36 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251877 J15050747 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 35191012035 1231897SAMPLE DUPLICATE: Percent Moisture %8.3 1 108.2 Parameter Units Dup Result Max RPD QualifiersRPDResult 35191079001 1231902SAMPLE DUPLICATE: Percent Moisture %2.5 7 102.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 11:30 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 38 37 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251877 J15050747 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/37840 EPA 9045 EPA 9045 9045 pH Associated Lab Samples:92251877001, 92251877002, 92251877003, 92251877004 Parameter Units Dup Result Max RPD QualifiersRPDResult 92250905001 1473429SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 7.9 0 107.9 Parameter Units Dup Result Max RPD QualifiersRPDResult 92251844002 1473430SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 7.6 0 107.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 11:30 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 38 38 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251877 J15050747 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/46862 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92251877001, 92251877002, 92251877003, 92251877004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1228361 Associated Lab Samples: Matrix:Solid Analyzed Chloride mg/kg ND 49.9 05/31/15 23:09 Sulfate mg/kg ND 49.9 05/31/15 23:09 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1228362LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/kg 474497 95 80-120 Sulfate mg/kg 458497 92 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1228364MATRIX SPIKE SAMPLE: MSSpike Result 92251877001 Chloride mg/kg 604638 95 80-120ND Sulfate mg/kg 632638 99 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92251877001 1228363SAMPLE DUPLICATE: Chloride mg/kg ND 20ND Sulfate mg/kg ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 11:30 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 38 39 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251877 J15050747 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/46861 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92251877001, 92251877002, 92251877003, 92251877004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1228357 Associated Lab Samples: Matrix:Solid Analyzed Nitrate as N mg/kg ND 5.0 05/31/15 23:09 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1228358LABORATORY CONTROL SAMPLE: LCSSpike Nitrate as N mg/kg 46.849.7 94 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1228360MATRIX SPIKE SAMPLE: MSSpike Result 92251877001 Nitrate as N mg/kg 60.8 H363.8 95 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92251877001 1228359SAMPLE DUPLICATE: Nitrate as N mg/kg ND H320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 11:30 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 38 40 of 59 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92251877 J15050747 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/28987 EPA 9060 EPA 9060 9060 TOC Average Associated Lab Samples:92251877001, 92251877002, 92251877003, 92251877004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1173951 Associated Lab Samples: Matrix:Solid Analyzed Mean Total Organic Carbon mg/kg ND 600 06/12/15 08:04 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1173952LABORATORY CONTROL SAMPLE: LCSSpike Mean Total Organic Carbon mg/kg 105000120000 87 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1173953MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92251236003 1173954 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 7920 83 50-15095 12 307920ND68907800 Parameter Units MS Result % Rec Limits Qual% RecConc. 1173955MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92251877001 1173956 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 7830 88 50-15088 1 307800772J76607620 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 11:30 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 38 41 of 59 #=QL# QUALIFIERS Pace Project No.: Project: 92251877 J15050747 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - Green BayPASI-G Pace Analytical Services - Ormond BeachPASI-O BATCH QUALIFIERS Batch: ICPM/9927 Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.[1] ANALYTE QUALIFIERS % RSD > 401g Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3 Sample was diluted due to the presence of high levels of target analytes.D4 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6 Sample was received or analysis requested beyond the recognized method holding time.H3 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6 The lab does not hold TNI accreditation for this parameter.N2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 11:30 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 38 42 of 59 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92251877 J15050747 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92251877001 MPRP/24521 ICP/149772015016332EPA 3050 EPA 6010 92251877002 MPRP/24521 ICP/149772015016333EPA 3050 EPA 6010 92251877003 MPRP/24521 ICP/149772015016334EPA 3050 EPA 6010 92251877004 MPRP/24521 ICP/149772015016335EPA 3050 EPA 6010 92251877001 MPRP/24522 ICPM/99272015016332EPA 3050 EPA 6020 92251877002 MPRP/24522 ICPM/99272015016333EPA 3050 EPA 6020 92251877003 MPRP/24522 ICPM/99272015016334EPA 3050 EPA 6020 92251877004 MPRP/24522 ICPM/99272015016335EPA 3050 EPA 6020 92251877001 MERP/5819 MERC/58012015016332EPA 7471 EPA 7471 92251877002 MERP/5819 MERC/58012015016333EPA 7471 EPA 7471 92251877003 MERP/5819 MERC/58012015016334EPA 7471 EPA 7471 92251877004 MERP/5819 MERC/58012015016335EPA 7471 EPA 7471 92251877001 PMST/36142015016332ASTM D2974-87 92251877002 PMST/36142015016333ASTM D2974-87 92251877003 PMST/36142015016334ASTM D2974-87 92251877004 PMST/36142015016335ASTM D2974-87 92251877001 WET/378402015016332EPA 9045 92251877002 WET/378402015016333EPA 9045 92251877003 WET/378402015016334EPA 9045 92251877004 WET/378402015016335EPA 9045 92251877001 WETA/468622015016332EPA 9056 92251877002 WETA/468622015016333EPA 9056 92251877003 WETA/468622015016334EPA 9056 92251877004 WETA/468622015016335EPA 9056 92251877001 WETA/468612015016332EPA 9056 92251877002 WETA/468612015016333EPA 9056 92251877003 WETA/468612015016334EPA 9056 92251877004 WETA/468612015016335EPA 9056 92251877001 WETA/289872015016332EPA 9060 92251877001 WETA/289882015016332EPA 9060 92251877002 WETA/289872015016333EPA 9060 92251877002 WETA/289882015016333EPA 9060 92251877003 WETA/289872015016334EPA 9060 92251877003 WETA/289882015016334EPA 9060 92251877004 WETA/289872015016335EPA 9060 92251877004 WETA/289882015016335EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/15/2015 11:30 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 36 of 38 43 of 59 Page 37 of 38 44 of 59 Page 38 of 38 45 of 59 June 15, 2015 LABORATORY REPORT NUMBER PROJECT ID Primary Data Review By Project Manager, AES 1506007 Marge Galvin-Karr Duke Energy 13339 Hagers Ferry Rd. Huntersville NC 28078 J15050747 Chantelle Kanhai Project Manager, Access Analytical aamick@axs-inc.com Ashley Amick PLEASE NOTE: -Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. -AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Secondary Data Review By ATTENTION DATE CLIENT ANALYTICAL REPORT Page 1 of 8 46 of 59 P a g e 2 o f 8 4 7 o f 5 9 15-Jun-15Date:Analytical Environmental Services, Inc Client: Case NarrativeJ15050747 Duke Energy Lab ID: Project: 1506007 REDOX POTENTIAL 1506007-001 229.2 mV 197.7 mV 96.9 mV 1506007-002 84.1 mV 51.5 mV 21.8 mV 1506007-003 246.7 mV 201.6 mV 192.8 mV Page 3 of 8 48 of 59 1506007-001 15-Jun-15Date:Analytical Environmental Services, Inc Analyses Date AnalyzedDilution FactorBatchIDUnitsQualReporting LimitResult Client: Sediment 5/26/2015 2:10:00 PM SW-6A Matrix: Collection Date: Client Sample ID: J15050747 Duke Energy Lab ID: Project Name: Analyst (SW9081)CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity 2.7 1.0 meq/100g 208358 1 06/09/2015 00:28 TA Qualifiers: * Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value > Greater than Result value J Estimated value detected below Reporting Limit Page 4 of 8 49 of 59 1506007-002 15-Jun-15Date:Analytical Environmental Services, Inc Analyses Date AnalyzedDilution FactorBatchIDUnitsQualReporting LimitResult Client: Sediment 5/26/2015 2:50:00 PM SW-8A Matrix: Collection Date: Client Sample ID: J15050747 Duke Energy Lab ID: Project Name: Analyst (SW9081)CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity 1.8 1.0 meq/100g 208358 1 06/09/2015 00:31 TA Qualifiers: * Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value > Greater than Result value J Estimated value detected below Reporting Limit Page 5 of 8 50 of 59 1506007-003 15-Jun-15Date:Analytical Environmental Services, Inc Analyses Date AnalyzedDilution FactorBatchIDUnitsQualReporting LimitResult Client: Sediment 5/26/2015 3:30:00 PM SW-004 Matrix: Collection Date: Client Sample ID: J15050747 Duke Energy Lab ID: Project Name: Analyst (SW9081)CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity 3.6 1.0 meq/100g 208358 1 06/09/2015 00:34 TA Qualifiers: * Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value > Greater than Result value J Estimated value detected below Reporting Limit Page 6 of 8 51 of 59 P a g e 7 o f 8 5 2 o f 5 9 15-Jun-15Date:Analytical Environmental Services, Inc Client: BatchID:Workorder: Project Name: ANALYTICAL QC SUMMARY REPORTJ15050747 1506007 Duke Energy 208358 RPT Limit QualAnalyteResultSPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit SampleType:BatchID:Analysis Date:Seq No:TestCode:208358DUP 06/09/2015CEC of Soils (Na Saturation) SW9081 Units:Prep Date:Sample ID:Client ID:Run No:meq/100g 06/04/2015 2934411506006-001ADUP 6252194 Cation Exchange Capacity 1.018.00 2011.90 R40.8 Qualifiers: J Estimated value detected below Reporting Limit BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix < Less than Result value> Greater than Result value R RPD outside limits due to matrix Rpt Lim Reporting Limit Page 8 of 8 53 of 59 Terracon Consultants, Inc. 521 Clemson Road Columbia, South Carolina 29229 P [803] 741 9000 F [803] 741 9900 terracon.com June 11, 2015 Access Analytical 7478 Carlisle Street Irmo, South Carolina 29063 Attn: Mr. Ashley Amick Re: Summary of Laboratory Testing AB Groundwater Assessment Terracon Project No. 73075016 (WOJ15050747) Dear Mr. Amick: Terracon has performed the requested laboratory testing program indicated by your Chain of Custody Record, dated 06/01/15. The correspondence indicated hydrometer testing for Samples SW-6A, SW-8A, and SW-004. The results have been electronically forwarded to you in PDF format at aamick@accessanalyticalinc.com, as instructed. If there are any questions regarding the results or if we can be of additional service, please contact us. Sincerely, Terracon Consultants, Inc. Rebecca Simms, CET Phillip A. Morrison, P.E. Laboratory Manager Geotechnical Department Manager Attachments Copies: 1xc: Above (PDF via email) 1xc: File RS/PM 54 of 59 55 of 59 56 of 59 57 of 59 58 of 59 59 of 59