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Home My WebLink AboutNC0001422_ATT 5 - Soil - J15040323 Report_2015080513339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number: J15040323 Project Name:SUTTON - AB GW ASSESSMENT SOIL Lab Contact:Margaret Galvin-Karr Date:6/3/2015 Customer Address: Customer Name(s):Perry Waldrep, Tim Hunsucker, Kathy Webb, John Toepfer Phone: 980-875-5219 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Margaret Galvin-Karr) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Margaret Galvin-Karr 1 of 109 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015010704 Sutton 13-Apr-15 4:50 PM ILLEGIBLE SMW-4C 4-6 2015010719 Sutton 13-Apr-15 4:45 PM ILLEGIBLE SMW-4C 0-2 2015010720 Sutton 08-Apr-15 11:45 AM ILLEGIBLE SMW-6D 103 2015010721 Sutton 08-Apr-15 11:45 AM ILLEGIBLE SMW-6D 103 Dup 2015010722 Sutton 13-Apr-15 8:45 AM ILLEGIBLE SMW-5C 0-2 2015010723 Sutton 13-Apr-15 9:10 AM ILLEGIBLE SMW-5C 6-8 2015010724 Sutton 13-Apr-15 11:00 AM ILLEGIBLE SMW-5C 41-43 2015010725 Sutton 13-Apr-15 6:00 PM ILLEGIBLE SMW-4C 43-45 2015010726 Sutton 06-Apr-15 5:45 PM ILLEGIBLE SMW-6D 6-8 2015010727 Sutton 06-Apr-15 5:30 PM ILLEGIBLE SMW-6D 0-2 2015010728 Sutton 14-Apr-15 1:40 PM ILLEGIBLE SMW-1C 0-2 2015010729 Sutton 14-Apr-15 2:30 PM ILLEGIBLE SMW-1C 8-10 2015010730 Sutton 14-Apr-15 4:00 PM ILLEGIBLE SMW-1C 42-44 2015010731 Sutton 14-Apr-15 1:30 PM ILLEGIBLE Equipment Blank SMW-1C 2015010732 Sutton 13-Apr-15 8:30 AM ILLEGIBLE Equipment Blank SMW-5C 2015010733 Sutton 13-Apr-15 4:40 PM ILLEGIBLE Equipment Blank SMw-04C 2015010734 Sutton 06-Apr-15 5:00 PM ILLEGIBLE Equipment Blank(1 per day) 17 Total Samples 2 of 109 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By: Date: Electronic Data Deliverable (EDD) Sent Separately 3 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040323 2015010704 Collection Date: 13-Apr-15 4:50 PM Site:SMW-4C 4-6 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 4 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040323 2015010719 Collection Date: 13-Apr-15 4:45 PM Site:SMW-4C 0-2 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 5 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040323 2015010720 Collection Date: 08-Apr-15 11:45 AM Site:SMW-6D 103 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 6 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040323 2015010721 Collection Date: 08-Apr-15 11:45 AM Site:SMW-6D 103 Dup Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 7 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040323 2015010722 Collection Date: 13-Apr-15 8:45 AM Site: SMW-5C 0-2 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 8 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040323 2015010723 Collection Date: 13-Apr-15 9:10 AM Site:SMW-5C 6-8 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 9 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040323 2015010724 Collection Date: 13-Apr-15 11:00 AM Site:SMW-5C 41-43 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 10 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040323 2015010725 Collection Date: 13-Apr-15 6:00 PM Site:SMW-4C 43-45 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 11 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040323 2015010726 Collection Date: 06-Apr-15 5:45 PM Site:SMW-6D 6-8 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 12 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040323 2015010727 Collection Date: 06-Apr-15 5:30 PM Site:SMW-6D 0-2 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 13 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040323 2015010728 Collection Date: 14-Apr-15 1:40 PM Site:SMW-1C 0-2 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 14 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040323 2015010729 Collection Date: 14-Apr-15 2:30 PM Site:SMW-1C 8-10 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 15 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040323 2015010730 Collection Date: 14-Apr-15 4:00 PM Site:SMW-1C 42-44 Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 16 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040323 2015010731 Collection Date: 14-Apr-15 1:30 PM Site:Equipment Blank SMW-1C Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 17 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040323 2015010732 Collection Date: 13-Apr-15 8:30 AM Site:Equipment Blank SMW-5C Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 18 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040323 2015010733 Collection Date: 13-Apr-15 4:40 PM Site:Equipment Blank SMw-04C Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 19 of 109 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040323 2015010734 Collection Date: 06-Apr-15 5:00 PM Site:Equipment Blank(1 per day) Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 20 of 109 #=CL# May 12, 2015 LIMS USE: FR - PROGRAM MANAGER LIMS OBJECT ID: 92245618 92245618 Project: Pace Project No.: RE: Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 J15040323 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on April 15, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc:Marge Galvin-Karr, Duke Energy Program Manager, Duke Energy Rodney Wike, Duke Energy REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 88 21 of 109 #=CP# CERTIFICATIONS Pace Project No.: Project: 92245618 J15040323 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A2LA Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA #: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 88 22 of 109 #=CP# CERTIFICATIONS Pace Project No.: Project: 92245618 J15040323 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 88 23 of 109 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92245618 J15040323 Lab ID Sample ID Matrix Date Collected Date Received 92245618001 2015010704 Solid 04/13/15 16:50 04/15/15 15:30 92245618002 2015010719 Solid 04/13/15 16:45 04/15/15 15:30 92245618003 2015010720 Solid 04/08/15 11:45 04/15/15 15:30 92245618004 2015010721 Solid 04/08/15 11:45 04/15/15 15:30 92245618005 2015010722 Solid 04/13/15 08:45 04/15/15 15:30 92245618006 2015010723 Solid 04/13/15 09:10 04/15/15 15:30 92245618007 2015010724 Solid 04/13/15 11:00 04/15/15 15:30 92245618008 2015010725 Solid 04/13/15 18:00 04/15/15 15:30 92245618009 2015010726 Solid 04/06/15 17:45 04/15/15 15:30 92245618010 2015010727 Solid 04/06/15 17:30 04/15/15 15:30 92245618011 2015010728 Solid 04/14/15 13:40 04/15/15 15:30 92245618012 2015010729 Solid 04/14/15 14:30 04/15/15 15:30 92245618013 2015010730 Solid 04/14/15 16:00 04/15/15 15:30 92245618014 2015010731 Water 04/14/15 13:30 04/15/15 15:30 92245618015 2015010732 Water 04/13/15 08:30 04/15/15 15:30 92245618016 2015010733 Water 04/13/15 16:40 04/15/15 15:30 92245618017 2015010734 Water 04/06/15 17:00 04/15/15 15:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 88 24 of 109 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92245618 J15040323 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92245618001 2015010704 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCRT ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92245618002 2015010719 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCRT ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92245618003 2015010720 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCRT ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-ATEP EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92245618004 2015010721 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCRT ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-ATEP EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92245618005 2015010722 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCRT ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 88 25 of 109 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92245618 J15040323 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92245618006 2015010723 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCRT ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92245618007 2015010724 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCRT ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92245618008 2015010725 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCRT ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92245618009 2015010726 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCRT ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-ATEP EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92245618010 2015010727 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-ODRS REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 88 26 of 109 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92245618 J15040323 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts EPA 7471 1 PASI-OCRT ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-ATEP EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92245618011 2015010728 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCRT ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92245618012 2015010729 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCRT ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92245618013 2015010730 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-ODRS EPA 7471 1 PASI-OCRT ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92245618014 2015010731 EPA 6020A 24 PASI-MRJS EPA 7470 1 PASI-MJDD 92245618015 2015010732 EPA 6020A 24 PASI-MRJS EPA 7470 1 PASI-MJDD 92245618016 2015010733 EPA 6020A 24 PASI-MRJS EPA 7470 1 PASI-MJDD 92245618017 2015010734 EPA 6020A 24 PASI-MRJS REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 88 27 of 109 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92245618 J15040323 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts EPA 7470 1 PASI-MJDD REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 88 28 of 109 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92245618 J15040323 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92245618001 2015010704 Aluminum 334 mg/kg 04/26/15 00:4330.3EPA 6010 Iron 177 mg/kg 04/26/15 00:4312.1EPA 6010 Percent Moisture 19.5 %04/23/15 13:180.10ASTM D2974-87 pH at 25 Degrees C 4.9 Std. Units 04/20/15 21:250.10EPA 9045 RSD%5.4 %04/30/15 07:14EPA 9060 92245618002 2015010719 Aluminum 1800 mg/kg 04/26/15 00:4735.5EPA 6010 Barium 1.8J mg/kg 04/26/15 00:473.6EPA 6010 Iron 160 mg/kg 04/26/15 00:4714.2EPA 6010 Mercury 0.0062J mg/kg 04/23/15 17:060.011EPA 7471 Percent Moisture 27.3 %04/23/15 13:180.10ASTM D2974-87 pH at 25 Degrees C 5.0 Std. Units 04/20/15 21:250.10EPA 9045 Total Organic Carbon 2940 mg/kg 04/30/15 08:26821EPA 9060 Total Organic Carbon 3820 mg/kg 04/30/15 08:32828EPA 9060 Total Organic Carbon 2880 mg/kg 04/30/15 08:39828EPA 9060 Total Organic Carbon 3320 mg/kg 04/30/15 08:45830EPA 9060 Mean Total Organic Carbon 3240 mg/kg 04/30/15 08:26827EPA 9060 RSD%13.3 %04/30/15 08:26EPA 9060 92245618003 2015010720 Aluminum 2810 mg/kg 04/26/15 00:5236.1EPA 6010 Barium 5.5 mg/kg 04/26/15 00:523.6EPA 6010 Beryllium 0.39 mg/kg 04/26/15 00:520.36EPA 6010 Boron 23.0 mg/kg 04/26/15 00:5218.0EPA 6010 Calcium 24100 mg/kg 04/26/15 00:52180EPA 6010 Chromium 19.4 mg/kg 04/26/15 00:521.8EPA 6010 Copper 1.6J mg/kg 04/26/15 00:521.8EPA 6010 Iron 9000 mg/kg 04/26/15 00:5214.4EPA 6010 Magnesium 11800 mg/kg 04/26/15 00:52180EPA 6010 Manganese 58.6 mg/kg 04/26/15 00:521.8EPA 6010 Nickel 5.1 mg/kg 04/26/15 00:521.8EPA 6010 Potassium 1780 mg/kg 04/26/15 00:52361EPA 6010 Sodium 399 mg/kg 04/26/15 00:52361EPA 6010 Strontium 34.0 mg/kg 04/26/15 00:523.6EPA 6010 Zinc 25.3 mg/kg 04/26/15 00:527.2EPA 6010 Percent Moisture 28.4 %04/23/15 13:180.10ASTM D2974-87 pH at 25 Degrees C 8.5 Std. Units 04/17/15 10:50 H30.10EPA 9045 Sulfate 198J mg/kg 04/20/15 03:28 D3346EPA 9056 Total Organic Carbon 3020 mg/kg 04/30/15 17:141230EPA 9060 Total Organic Carbon 2930 mg/kg 04/30/15 17:201220EPA 9060 Total Organic Carbon 3720 mg/kg 04/30/15 17:271230EPA 9060 Total Organic Carbon 3330 mg/kg 04/30/15 17:321220EPA 9060 Mean Total Organic Carbon 3250 mg/kg 04/30/15 17:141220EPA 9060 RSD%11.1 %04/30/15 17:14EPA 9060 92245618004 2015010721 Aluminum 3610 mg/kg 04/26/15 01:2839.2EPA 6010 Barium 5.8 mg/kg 04/26/15 01:283.9EPA 6010 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 88 29 of 109 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92245618 J15040323 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92245618004 2015010721 Beryllium 0.46 mg/kg 04/26/15 01:280.39EPA 6010 Calcium 26300 mg/kg 04/26/15 01:28196EPA 6010 Chromium 23.5 mg/kg 04/26/15 01:282.0EPA 6010 Copper 1.4J mg/kg 04/26/15 01:282.0EPA 6010 Iron 9900 mg/kg 04/26/15 01:2815.7EPA 6010 Magnesium 12900 mg/kg 04/26/15 01:28196EPA 6010 Manganese 68.4 mg/kg 04/26/15 01:282.0EPA 6010 Nickel 4.6 mg/kg 04/26/15 01:282.0EPA 6010 Potassium 2180 mg/kg 04/26/15 01:28392EPA 6010 Sodium 380J mg/kg 04/26/15 01:28392EPA 6010 Strontium 36.9 mg/kg 04/26/15 01:283.9EPA 6010 Zinc 23.9 mg/kg 04/26/15 01:287.8EPA 6010 Vanadium 12.8 mg/kg 04/26/15 11:557.8EPA 6020 Percent Moisture 35.5 %04/21/15 10:520.10ASTM D2974-87 pH at 25 Degrees C 8.7 Std. Units 04/17/15 10:50 H30.10EPA 9045 Total Organic Carbon 3350 mg/kg 04/30/15 17:38936EPA 9060 Total Organic Carbon 3600 mg/kg 04/30/15 17:43927EPA 9060 Total Organic Carbon 3300 mg/kg 04/30/15 17:50927EPA 9060 Total Organic Carbon 3350 mg/kg 04/30/15 17:55932EPA 9060 Mean Total Organic Carbon 3400 mg/kg 04/30/15 17:38931EPA 9060 RSD%4.1 %04/30/15 17:38EPA 9060 92245618005 2015010722 Aluminum 39.1 mg/kg 04/26/15 01:4135.8EPA 6010 Iron 43.8 mg/kg 04/26/15 01:4114.3EPA 6010 Percent Moisture 27.6 %04/21/15 10:530.10ASTM D2974-87 pH at 25 Degrees C 6.0 Std. Units 04/20/15 21:250.10EPA 9045 Total Organic Carbon 992 mg/kg 04/30/15 09:13826EPA 9060 Total Organic Carbon 1240 mg/kg 04/30/15 09:19824EPA 9060 Total Organic Carbon 855 mg/kg 04/30/15 09:25836EPA 9060 Total Organic Carbon 785J mg/kg 04/30/15 09:32836EPA 9060 Mean Total Organic Carbon 968 mg/kg 04/30/15 09:13831EPA 9060 RSD%20.8 %04/30/15 09:13EPA 9060 92245618006 2015010723 Aluminum 115 mg/kg 04/26/15 01:4530.7EPA 6010 Iron 54.6 mg/kg 04/26/15 01:4512.3EPA 6010 Percent Moisture 19.6 %04/21/15 10:530.10ASTM D2974-87 pH at 25 Degrees C 5.9 Std. Units 04/20/15 21:250.10EPA 9045 Total Organic Carbon 384J mg/kg 05/07/15 13:36746EPA 9060 Total Organic Carbon 387J mg/kg 05/07/15 13:42741EPA 9060 Total Organic Carbon 375J mg/kg 05/07/15 13:52743EPA 9060 Mean Total Organic Carbon 375J mg/kg 05/07/15 13:36744EPA 9060 RSD%3.8 %05/07/15 13:36EPA 9060 92245618007 2015010724 Aluminum 101 mg/kg 04/26/15 01:4929.1EPA 6010 Iron 124 mg/kg 04/26/15 01:4911.7EPA 6010 Manganese 4.3 mg/kg 04/26/15 01:491.5EPA 6010 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 88 30 of 109 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92245618 J15040323 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92245618007 2015010724 Percent Moisture 18.0 %04/21/15 10:540.10ASTM D2974-87 pH at 25 Degrees C 5.9 Std. Units 04/20/15 21:250.10EPA 9045 RSD%3.4 %05/07/15 13:58EPA 9060 92245618008 2015010725 Aluminum 294 mg/kg 04/26/15 02:0532.3EPA 6010 Barium 1.6J mg/kg 04/26/15 02:053.2EPA 6010 Iron 412 mg/kg 04/26/15 02:0512.9EPA 6010 Manganese 6.2 mg/kg 04/26/15 02:051.6EPA 6010 Percent Moisture 23.4 %04/21/15 10:550.10ASTM D2974-87 pH at 25 Degrees C 6.0 Std. Units 04/20/15 21:250.10EPA 9045 RSD%3.9 %05/07/15 14:23EPA 9060 92245618009 2015010726 Aluminum 587 mg/kg 04/26/15 02:1031.0EPA 6010 Iron 422 mg/kg 04/26/15 02:1012.4EPA 6010 Percent Moisture 19.6 %04/21/15 10:550.10ASTM D2974-87 pH at 25 Degrees C 5.0 Std. Units 04/17/15 10:50 H30.10EPA 9045 Total Organic Carbon 404J mg/kg 04/28/15 15:43746EPA 9060 Total Organic Carbon 434J mg/kg 04/28/15 15:49749EPA 9060 Total Organic Carbon 432J mg/kg 04/28/15 15:55743EPA 9060 Total Organic Carbon 413J mg/kg 04/28/15 16:01746EPA 9060 Mean Total Organic Carbon 421J mg/kg 04/28/15 15:43746EPA 9060 RSD%3.5 %04/28/15 15:43EPA 9060 92245618010 2015010727 Aluminum 144 mg/kg 04/26/15 02:1433.9EPA 6010 Iron 55.1 mg/kg 04/26/15 02:1413.5EPA 6010 Percent Moisture 23.0 %04/21/15 10:560.10ASTM D2974-87 pH at 25 Degrees C 4.6 Std. Units 04/17/15 10:50 H30.10EPA 9045 Total Organic Carbon 5770 mg/kg 04/28/15 16:07772EPA 9060 Total Organic Carbon 4840 mg/kg 04/28/15 16:14785EPA 9060 Total Organic Carbon 4190 mg/kg 04/28/15 16:20780EPA 9060 Total Organic Carbon 4430 mg/kg 04/28/15 16:25780EPA 9060 Mean Total Organic Carbon 4810 mg/kg 04/28/15 16:07779EPA 9060 RSD%14.5 %04/28/15 16:07EPA 9060 92245618011 2015010728 Aluminum 800 mg/kg 04/26/15 02:1834.4EPA 6010 Calcium 138J mg/kg 04/26/15 02:18172EPA 6010 Iron 609 mg/kg 04/26/15 02:1813.8EPA 6010 Manganese 2.1 mg/kg 04/26/15 02:181.7EPA 6010 Percent Moisture 26.2 %04/21/15 10:570.10ASTM D2974-87 pH at 25 Degrees C 8.4 Std. Units 04/20/15 21:250.10EPA 9045 Total Organic Carbon 1220 mg/kg 05/07/15 14:46808EPA 9060 Total Organic Carbon 1070 mg/kg 05/07/15 14:52810EPA 9060 Total Organic Carbon 1080 mg/kg 05/07/15 14:57810EPA 9060 Total Organic Carbon 1690 mg/kg 05/07/15 15:03811EPA 9060 Mean Total Organic Carbon 1260 mg/kg 05/07/15 14:46810EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 88 31 of 109 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92245618 J15040323 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92245618011 2015010728 RSD%23.0 %05/07/15 14:46EPA 9060 92245618012 2015010729 Aluminum 302 mg/kg 04/26/15 02:2230.5EPA 6010 Iron 82.3 mg/kg 04/26/15 02:2212.2EPA 6010 Percent Moisture 19.5 %04/21/15 10:580.10ASTM D2974-87 pH at 25 Degrees C 6.8 Std. Units 04/20/15 21:250.10EPA 9045 Total Organic Carbon 400J mg/kg 05/07/15 15:14744EPA 9060 Total Organic Carbon 384J mg/kg 05/07/15 15:20742EPA 9060 Total Organic Carbon 417J mg/kg 05/07/15 15:25750EPA 9060 Mean Total Organic Carbon 386J mg/kg 05/07/15 15:09744EPA 9060 RSD%8.2 %05/07/15 15:09EPA 9060 92245618013 2015010730 Aluminum 1310 mg/kg 04/26/15 02:2630.8EPA 6010 Barium 3.3 mg/kg 04/26/15 02:263.1EPA 6010 Calcium 93.6J mg/kg 04/26/15 02:26154EPA 6010 Chromium 1.9 mg/kg 04/26/15 02:261.5EPA 6010 Iron 1870 mg/kg 04/26/15 02:2612.3EPA 6010 Magnesium 97.9J mg/kg 04/26/15 02:26154EPA 6010 Manganese 7.5 mg/kg 04/26/15 02:261.5EPA 6010 Nickel 0.98J mg/kg 04/26/15 02:261.5EPA 6010 Strontium 1.8J mg/kg 04/26/15 02:263.1EPA 6010 Percent Moisture 22.3 %04/21/15 11:000.10ASTM D2974-87 pH at 25 Degrees C 5.8 Std. Units 04/20/15 21:250.10EPA 9045 RSD%6.0 %05/11/15 14:00EPA 9060 92245618014 2015010731 Aluminum 57.5 ug/L 04/21/15 05:1310.0EPA 6020A Barium 0.91 ug/L 04/21/15 05:130.30EPA 6020A Calcium 938 ug/L 04/23/15 01:4940.0EPA 6020A Chromium 2.0 ug/L 04/21/15 05:130.50EPA 6020A Copper 1.0 ug/L 04/21/15 05:131.0EPA 6020A Iron 364 ug/L 04/21/15 05:1350.0EPA 6020A Lead 0.15 ug/L 04/21/15 05:130.10EPA 6020A Magnesium 39.4 ug/L 04/21/15 05:1310.0EPA 6020A Manganese 4.5 ug/L 04/21/15 05:130.50EPA 6020A Molybdenum 0.76 ug/L 04/21/15 05:130.50EPA 6020A Nickel 0.26J ug/L 04/21/15 05:130.50EPA 6020A Potassium 131 ug/L 04/21/15 05:1350.0EPA 6020A Sodium 308 ug/L 04/21/15 05:1350.0EPA 6020A Strontium 1.8 ug/L 04/21/15 05:130.50EPA 6020A Zinc 9.9 ug/L 04/21/15 05:135.0EPA 6020A 92245618015 2015010732 Aluminum 14.3 ug/L 04/21/15 05:1810.0EPA 6020A Barium 4.2 ug/L 04/21/15 05:180.30EPA 6020A Boron 14.2 ug/L 04/21/15 05:185.0EPA 6020A Calcium 144 ug/L 04/23/15 01:5340.0EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 88 32 of 109 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92245618 J15040323 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92245618015 2015010732 Chromium 4.6 ug/L 04/21/15 05:180.50EPA 6020A Cobalt 1.8 ug/L 04/21/15 05:180.50EPA 6020A Copper 18.2 ug/L 04/21/15 05:181.0EPA 6020A Iron 337 ug/L 04/21/15 05:1850.0EPA 6020A Lead 19.1 ug/L 04/21/15 05:180.10EPA 6020A Magnesium 10.9 ug/L 04/21/15 05:1810.0EPA 6020A Manganese 31.3 ug/L 04/21/15 05:180.50EPA 6020A Molybdenum 0.69 ug/L 04/21/15 05:180.50EPA 6020A Nickel 1.0 ug/L 04/21/15 05:180.50EPA 6020A Sodium 23.9J ug/L 04/21/15 05:1850.0EPA 6020A Strontium 0.59 ug/L 04/21/15 05:180.50EPA 6020A Zinc 59.6 ug/L 04/21/15 05:185.0EPA 6020A 92245618016 2015010733 Aluminum 9.1J ug/L 04/21/15 05:2310.0EPA 6020A Barium 0.22J ug/L 04/21/15 05:230.30EPA 6020A Calcium 177 ug/L 04/23/15 01:5840.0EPA 6020A Chromium 0.34J ug/L 04/21/15 05:230.50EPA 6020A Cobalt 0.23J ug/L 04/21/15 05:230.50EPA 6020A Copper 0.29J ug/L 04/21/15 05:231.0EPA 6020A Iron 68.1 ug/L 04/21/15 05:2350.0EPA 6020A Lead 0.049J ug/L 04/21/15 05:230.10EPA 6020A Magnesium 11.6 ug/L 04/21/15 05:2310.0EPA 6020A Manganese 0.81 ug/L 04/21/15 05:230.50EPA 6020A Molybdenum 0.16J ug/L 04/21/15 05:230.50EPA 6020A Potassium 22.1J ug/L 04/21/15 05:2350.0EPA 6020A Sodium 104 ug/L 04/21/15 05:2350.0EPA 6020A Strontium 0.36J ug/L 04/21/15 05:230.50EPA 6020A 92245618017 2015010734 Aluminum 590 ug/L 04/21/15 05:2710.0EPA 6020A Antimony 0.51 ug/L 04/21/15 05:270.50EPA 6020A Arsenic 1.0 ug/L 04/21/15 05:270.50EPA 6020A Barium 11.2 ug/L 04/21/15 05:270.30EPA 6020A Beryllium 0.17J ug/L 04/21/15 05:270.20EPA 6020A Boron 4.0J ug/L 04/21/15 05:275.0EPA 6020A Cadmium 0.040J ug/L 04/21/15 05:270.080EPA 6020A Calcium 13300 ug/L 04/23/15 02:03200EPA 6020A Chromium 8.6 ug/L 04/21/15 05:270.50EPA 6020A Cobalt 3.1 ug/L 04/21/15 05:270.50EPA 6020A Copper 3.5 ug/L 04/21/15 05:271.0EPA 6020A Iron 2900 ug/L 04/21/15 05:2750.0EPA 6020A Lead 0.73 ug/L 04/21/15 05:270.10EPA 6020A Magnesium 4580 ug/L 04/21/15 05:2710.0EPA 6020A Manganese 40.2 ug/L 04/21/15 05:270.50EPA 6020A Molybdenum 1.3 ug/L 04/21/15 05:270.50EPA 6020A Nickel 2.1 ug/L 04/21/15 05:270.50EPA 6020A Potassium 501 ug/L 04/21/15 05:2750.0EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 88 33 of 109 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92245618 J15040323 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92245618017 2015010734 Selenium 0.40J ug/L 04/21/15 05:270.50EPA 6020A Sodium 586 ug/L 04/21/15 05:2750.0EPA 6020A Strontium 23.6 ug/L 04/21/15 05:270.50EPA 6020A Thallium 0.016J ug/L 04/21/15 05:270.10EPA 6020A Vanadium 3.2 ug/L 04/21/15 05:271.0EPA 6020A Zinc 17.4 ug/L 04/21/15 05:275.0EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 88 34 of 109 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245618 J15040323 Method: Client:Duke Energy EPA 6010 Date:May 12, 2015 Description:6010 MET ICP General Information: 13 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23716 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245627003 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1188469) • Aluminum • Barium • Iron • Potassium • Strontium • MSD (Lab ID: 1188470) • Aluminum • Barium • Beryllium • Calcium • Copper • Potassium • Strontium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 88 35 of 109 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245618 J15040323 Method: Client:Duke Energy EPA 6010 Date:May 12, 2015 Description:6010 MET ICP QC Batch: MPRP/23746 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245637001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1190237) • Aluminum • Barium • Chromium • Iron • Manganese • Potassium • Strontium • MSD (Lab ID: 1190238) • Aluminum • Barium • Iron • Magnesium • Manganese • Potassium • Strontium R1: RPD value was outside control limits. • MSD (Lab ID: 1190238) • Chromium Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • QC Batch: ICP / 14506 • QC Batch: ICP / 14514 Analyte Comments: QC Batch: MPRP/23716 P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. • BLANK (Lab ID: 1188467) • Iron QC Batch: MPRP/23746 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015010721 (Lab ID: 92245618004) • Boron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 88 36 of 109 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245618 J15040323 Method: Client:Duke Energy EPA 6020 Date:May 12, 2015 Description:6020 MET ICPMS General Information: 13 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23717 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245627003 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1188475) • Antimony • Arsenic • Cadmium • Cobalt • Lead • Selenium • Thallium • Vanadium • MSD (Lab ID: 1188476) • Antimony • Arsenic • Cadmium • Cobalt REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 88 37 of 109 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245618 J15040323 Method: Client:Duke Energy EPA 6020 Date:May 12, 2015 Description:6020 MET ICPMS QC Batch: MPRP/23717 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245627003 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • Lead • Selenium • Thallium • Vanadium QC Batch: MPRP/23747 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245637001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1190235) • Antimony • Arsenic • Cadmium • Cobalt • Lead • Selenium • Thallium • Vanadium • MSD (Lab ID: 1190236) • Antimony • Arsenic • Cadmium • Cobalt • Lead • Selenium • Thallium • Vanadium Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • QC Batch: ICPM / 9649 Analyte Comments: QC Batch: MPRP/23717 N2: The lab does not hold TNI accreditation for this parameter. • 2015010704 (Lab ID: 92245618001) • Antimony • 2015010719 (Lab ID: 92245618002) • Antimony • 2015010720 (Lab ID: 92245618003) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 88 38 of 109 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245618 J15040323 Method: Client:Duke Energy EPA 6020 Date:May 12, 2015 Description:6020 MET ICPMS Analyte Comments: QC Batch: MPRP/23717 N2: The lab does not hold TNI accreditation for this parameter. • BLANK (Lab ID: 1188473) • Antimony • LCS (Lab ID: 1188474) • Antimony • MS (Lab ID: 1188475) • Antimony • MSD (Lab ID: 1188476) • Antimony QC Batch: MPRP/23747 N2: The lab does not hold TNI accreditation for this parameter. • 2015010721 (Lab ID: 92245618004) • Antimony • 2015010722 (Lab ID: 92245618005) • Antimony • 2015010723 (Lab ID: 92245618006) • Antimony • 2015010724 (Lab ID: 92245618007) • Antimony • 2015010725 (Lab ID: 92245618008) • Antimony • 2015010726 (Lab ID: 92245618009) • Antimony • 2015010727 (Lab ID: 92245618010) • Antimony • 2015010728 (Lab ID: 92245618011) • Antimony • 2015010729 (Lab ID: 92245618012) • Antimony • 2015010730 (Lab ID: 92245618013) • Antimony • BLANK (Lab ID: 1190231) • Antimony • LCS (Lab ID: 1190232) • Antimony • MS (Lab ID: 1190235) • Antimony • MSD (Lab ID: 1190236) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 88 39 of 109 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245618 J15040323 Method: Client:Duke Energy EPA 6020A Date:May 12, 2015 Description:6020A MET ICPMS General Information: 4 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/53712 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245612006 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1943026) • Copper • Zinc R1: RPD value was outside control limits. • MSD (Lab ID: 1943027) • Copper • Zinc Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 88 40 of 109 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245618 J15040323 Method: Client:Duke Energy EPA 7470 Date:May 12, 2015 Description:7470 Mercury General Information: 4 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 88 41 of 109 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245618 J15040323 Method: Client:Duke Energy EPA 7471 Date:May 12, 2015 Description:7471 Mercury General Information: 13 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 88 42 of 109 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245618 J15040323 Method: Client:Duke Energy EPA 9045 Date:May 12, 2015 Description:9045 pH Soil General Information: 13 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H3: Sample was received or analysis requested beyond the recognized method holding time. • 2015010720 (Lab ID: 92245618003) • 2015010721 (Lab ID: 92245618004) • 2015010726 (Lab ID: 92245618009) • 2015010727 (Lab ID: 92245618010) Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 88 43 of 109 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245618 J15040323 Method: Client:Duke Energy EPA 9056 Date:May 12, 2015 Description:9056 IC Anions General Information: 13 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/45554 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015010704 (Lab ID: 92245618001) • Chloride • Sulfate • 2015010719 (Lab ID: 92245618002) • Chloride • Sulfate • 2015010720 (Lab ID: 92245618003) • Chloride • Sulfate • 2015010721 (Lab ID: 92245618004) • Chloride • Sulfate QC Batch: WETA/45556 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015010722 (Lab ID: 92245618005) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 88 44 of 109 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245618 J15040323 Method: Client:Duke Energy EPA 9056 Date:May 12, 2015 Description:9056 IC Anions Analyte Comments: QC Batch: WETA/45556 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015010723 (Lab ID: 92245618006) • Chloride • Sulfate • 2015010724 (Lab ID: 92245618007) • Chloride • Sulfate • 2015010725 (Lab ID: 92245618008) • Chloride • Sulfate • 2015010726 (Lab ID: 92245618009) • Chloride • Sulfate • 2015010727 (Lab ID: 92245618010) • Chloride • Sulfate • 2015010728 (Lab ID: 92245618011) • Chloride • Sulfate • 2015010729 (Lab ID: 92245618012) • Chloride • Sulfate • 2015010730 (Lab ID: 92245618013) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 88 45 of 109 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245618 J15040323 Method: Client:Duke Energy EPA 9056 Date:May 12, 2015 Description:9056 IC Anions 48hr General Information: 13 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H3: Sample was received or analysis requested beyond the recognized method holding time. • 2015010704 (Lab ID: 92245618001) • 2015010719 (Lab ID: 92245618002) • 2015010720 (Lab ID: 92245618003) • 2015010721 (Lab ID: 92245618004) • 2015010722 (Lab ID: 92245618005) • 2015010723 (Lab ID: 92245618006) • 2015010724 (Lab ID: 92245618007) • 2015010725 (Lab ID: 92245618008) • 2015010726 (Lab ID: 92245618009) • 2015010727 (Lab ID: 92245618010) • 2015010728 (Lab ID: 92245618011) • 2015010729 (Lab ID: 92245618012) • 2015010730 (Lab ID: 92245618013) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 88 46 of 109 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92245618 J15040323 Method: Client:Duke Energy EPA 9060 Date:May 12, 2015 Description:Total Organic Carbon Quad General Information: 13 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 88 47 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010704 Lab ID:92245618001 Collected:04/13/15 16:50 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 334 mg/kg 04/26/15 00:43 7429-90-504/21/15 14:4030.3 15.1 5 Barium ND mg/kg 04/26/15 00:43 7440-39-304/21/15 14:403.0 1.5 5 Beryllium ND mg/kg 04/26/15 00:43 7440-41-704/21/15 14:400.30 0.15 5 Boron ND mg/kg 04/26/15 00:43 7440-42-804/21/15 14:4015.1 7.6 5 Calcium ND mg/kg 04/26/15 00:43 7440-70-204/21/15 14:4015175.6 5 Chromium ND mg/kg 04/26/15 00:43 7440-47-304/21/15 14:401.5 0.76 5 Copper ND mg/kg 04/26/15 00:43 7440-50-804/21/15 14:401.5 0.76 5 Iron 177 mg/kg 04/26/15 00:43 7439-89-604/21/15 14:4012.1 6.1 5 Magnesium ND mg/kg 04/26/15 00:43 7439-95-404/21/15 14:4015175.6 5 Manganese ND mg/kg 04/26/15 00:43 7439-96-504/21/15 14:401.5 0.76 5 Molybdenum ND mg/kg 04/26/15 00:43 7439-98-704/21/15 14:403.0 1.5 5 Nickel ND mg/kg 04/26/15 00:43 7440-02-004/21/15 14:401.5 0.76 5 Potassium ND mg/kg 04/26/15 00:43 7440-09-704/21/15 14:403031515 Sodium ND mg/kg 04/26/15 00:43 7440-23-504/21/15 14:403031515 Strontium ND mg/kg 04/26/15 00:43 7440-24-604/21/15 14:403.0 1.5 5 Zinc ND mg/kg 04/26/15 00:43 7440-66-604/21/15 14:406.1 3.0 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/26/15 11:30 7440-36-0 N204/21/15 14:406.1 3.0 100 Arsenic ND mg/kg 04/26/15 11:30 7440-38-204/21/15 14:406.1 3.0 100 Cadmium ND mg/kg 04/26/15 11:30 7440-43-904/21/15 14:400.73 0.36 100 Cobalt ND mg/kg 04/26/15 11:30 7440-48-404/21/15 14:406.1 3.0 100 Lead ND mg/kg 04/26/15 11:30 7439-92-104/21/15 14:406.1 3.0 100 Selenium ND mg/kg 04/26/15 11:30 7782-49-204/21/15 14:406.1 3.0 100 Thallium ND mg/kg 04/26/15 11:30 7440-28-004/21/15 14:406.1 3.0 100 Vanadium ND mg/kg 04/26/15 11:30 7440-62-204/21/15 14:406.1 3.0 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/23/15 18:40 7439-97-604/23/15 08:300.010 0.0051 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 19.5 %04/23/15 13:180.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 4.9 Std. Units 04/20/15 21:250.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/20/15 02:45 16887-00-6 D33051535 Sulfate ND mg/kg 04/20/15 02:45 14808-79-8 D33051535 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/20/15 02:45 14797-55-8 H330.5 15.3 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 88 48 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010704 Lab ID:92245618001 Collected:04/13/15 16:50 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 04/30/15 07:14 7440-44-07433711 Total Organic Carbon ND mg/kg 04/30/15 07:21 7440-44-07433721 Total Organic Carbon ND mg/kg 04/30/15 07:27 7440-44-07463731 Total Organic Carbon ND mg/kg 04/30/15 07:33 7440-44-07403701 Mean Total Organic Carbon ND mg/kg 04/30/15 07:14 7440-44-07433711 Surrogates RSD%5.4 %04/30/15 07:141 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 88 49 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010719 Lab ID:92245618002 Collected:04/13/15 16:45 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 1800 mg/kg 04/26/15 00:47 7429-90-504/21/15 14:4035.5 17.8 5 Barium 1.8J mg/kg 04/26/15 00:47 7440-39-304/21/15 14:403.6 1.8 5 Beryllium ND mg/kg 04/26/15 00:47 7440-41-704/21/15 14:400.36 0.18 5 Boron ND mg/kg 04/26/15 00:47 7440-42-804/21/15 14:4017.8 8.9 5 Calcium ND mg/kg 04/26/15 00:47 7440-70-204/21/15 14:4017888.9 5 Chromium ND mg/kg 04/26/15 00:47 7440-47-304/21/15 14:401.8 0.89 5 Copper ND mg/kg 04/26/15 00:47 7440-50-804/21/15 14:401.8 0.89 5 Iron 160 mg/kg 04/26/15 00:47 7439-89-604/21/15 14:4014.2 7.1 5 Magnesium ND mg/kg 04/26/15 00:47 7439-95-404/21/15 14:4017888.9 5 Manganese ND mg/kg 04/26/15 00:47 7439-96-504/21/15 14:401.8 0.89 5 Molybdenum ND mg/kg 04/26/15 00:47 7439-98-704/21/15 14:403.6 1.8 5 Nickel ND mg/kg 04/26/15 00:47 7440-02-004/21/15 14:401.8 0.89 5 Potassium ND mg/kg 04/26/15 00:47 7440-09-704/21/15 14:403551785 Sodium ND mg/kg 04/26/15 00:47 7440-23-504/21/15 14:403551785 Strontium ND mg/kg 04/26/15 00:47 7440-24-604/21/15 14:403.6 1.8 5 Zinc ND mg/kg 04/26/15 00:47 7440-66-604/21/15 14:407.1 3.6 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/26/15 11:33 7440-36-0 N204/21/15 14:407.1 3.6 100 Arsenic ND mg/kg 04/26/15 11:33 7440-38-204/21/15 14:407.1 3.6 100 Cadmium ND mg/kg 04/26/15 11:33 7440-43-904/21/15 14:400.85 0.43 100 Cobalt ND mg/kg 04/26/15 11:33 7440-48-404/21/15 14:407.1 3.6 100 Lead ND mg/kg 04/26/15 11:33 7439-92-104/21/15 14:407.1 3.6 100 Selenium ND mg/kg 04/26/15 11:33 7782-49-204/21/15 14:407.1 3.6 100 Thallium ND mg/kg 04/26/15 11:33 7440-28-004/21/15 14:407.1 3.6 100 Vanadium ND mg/kg 04/26/15 11:33 7440-62-204/21/15 14:407.1 3.6 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.0062J mg/kg 04/23/15 17:06 7439-97-604/22/15 14:550.011 0.0056 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 27.3 %04/23/15 13:180.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 5.0 Std. Units 04/20/15 21:250.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/20/15 03:06 16887-00-6 D33371695 Sulfate ND mg/kg 04/20/15 03:06 14808-79-8 D33371695 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/20/15 03:06 14797-55-8 H333.7 16.9 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 88 50 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010719 Lab ID:92245618002 Collected:04/13/15 16:45 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 2940 mg/kg 04/30/15 08:26 7440-44-08214101 Total Organic Carbon 3820 mg/kg 04/30/15 08:32 7440-44-08284141 Total Organic Carbon 2880 mg/kg 04/30/15 08:39 7440-44-08284141 Total Organic Carbon 3320 mg/kg 04/30/15 08:45 7440-44-08304151 Mean Total Organic Carbon 3240 mg/kg 04/30/15 08:26 7440-44-08274131 Surrogates RSD%13.3 %04/30/15 08:261 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 88 51 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010720 Lab ID:92245618003 Collected:04/08/15 11:45 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 2810 mg/kg 04/26/15 00:52 7429-90-504/21/15 14:4036.1 18.0 5 Barium 5.5 mg/kg 04/26/15 00:52 7440-39-304/21/15 14:403.6 1.8 5 Beryllium 0.39 mg/kg 04/26/15 00:52 7440-41-704/21/15 14:400.36 0.18 5 Boron 23.0 mg/kg 04/26/15 00:52 7440-42-804/21/15 14:4018.0 9.0 5 Calcium 24100 mg/kg 04/26/15 00:52 7440-70-204/21/15 14:4018090.2 5 Chromium 19.4 mg/kg 04/26/15 00:52 7440-47-304/21/15 14:401.8 0.90 5 Copper 1.6J mg/kg 04/26/15 00:52 7440-50-804/21/15 14:401.8 0.90 5 Iron 9000 mg/kg 04/26/15 00:52 7439-89-604/21/15 14:4014.4 7.2 5 Magnesium 11800 mg/kg 04/26/15 00:52 7439-95-404/21/15 14:4018090.2 5 Manganese 58.6 mg/kg 04/26/15 00:52 7439-96-504/21/15 14:401.8 0.90 5 Molybdenum ND mg/kg 04/26/15 00:52 7439-98-704/21/15 14:403.6 1.8 5 Nickel 5.1 mg/kg 04/26/15 00:52 7440-02-004/21/15 14:401.8 0.90 5 Potassium 1780 mg/kg 04/26/15 00:52 7440-09-704/21/15 14:403611805 Sodium 399 mg/kg 04/26/15 00:52 7440-23-504/21/15 14:403611805 Strontium 34.0 mg/kg 04/26/15 00:52 7440-24-604/21/15 14:403.6 1.8 5 Zinc 25.3 mg/kg 04/26/15 00:52 7440-66-604/21/15 14:407.2 3.6 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/26/15 11:35 7440-36-0 N204/21/15 14:407.2 3.6 100 Arsenic ND mg/kg 04/26/15 11:35 7440-38-204/21/15 14:407.2 3.6 100 Cadmium ND mg/kg 04/26/15 11:35 7440-43-904/21/15 14:400.87 0.43 100 Cobalt ND mg/kg 04/26/15 11:35 7440-48-404/21/15 14:407.2 3.6 100 Lead ND mg/kg 04/26/15 11:35 7439-92-104/21/15 14:407.2 3.6 100 Selenium ND mg/kg 04/26/15 11:35 7782-49-204/21/15 14:407.2 3.6 100 Thallium ND mg/kg 04/26/15 11:35 7440-28-004/21/15 14:407.2 3.6 100 Vanadium ND mg/kg 04/26/15 11:35 7440-62-204/21/15 14:407.2 3.6 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/23/15 17:17 7439-97-604/22/15 14:550.011 0.0054 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 28.4 %04/23/15 13:180.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 8.5 Std. Units 04/17/15 10:50 H30.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/20/15 03:28 16887-00-6 D33461735 Sulfate 198J mg/kg 04/20/15 03:28 14808-79-8 D33461735 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/20/15 03:28 14797-55-8 H334.6 17.3 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 88 52 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010720 Lab ID:92245618003 Collected:04/08/15 11:45 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 3020 mg/kg 04/30/15 17:14 7440-44-012306131 Total Organic Carbon 2930 mg/kg 04/30/15 17:20 7440-44-012206101 Total Organic Carbon 3720 mg/kg 04/30/15 17:27 7440-44-012306131 Total Organic Carbon 3330 mg/kg 04/30/15 17:32 7440-44-012206101 Mean Total Organic Carbon 3250 mg/kg 04/30/15 17:14 7440-44-012206121 Surrogates RSD%11.1 %04/30/15 17:141 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 88 53 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010721 Lab ID:92245618004 Collected:04/08/15 11:45 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 3610 mg/kg 04/26/15 01:28 7429-90-504/22/15 14:5039.2 19.6 5 Barium 5.8 mg/kg 04/26/15 01:28 7440-39-304/22/15 14:503.9 2.0 5 Beryllium 0.46 mg/kg 04/26/15 01:28 7440-41-704/22/15 14:500.39 0.20 5 Boron ND mg/kg 04/26/15 01:32 7440-42-8 D304/22/15 14:5097.9 49.0 25 Calcium 26300 mg/kg 04/26/15 01:28 7440-70-204/22/15 14:5019697.9 5 Chromium 23.5 mg/kg 04/26/15 01:28 7440-47-304/22/15 14:502.0 0.98 5 Copper 1.4J mg/kg 04/26/15 01:28 7440-50-804/22/15 14:502.0 0.98 5 Iron 9900 mg/kg 04/26/15 01:28 7439-89-604/22/15 14:5015.7 7.8 5 Magnesium 12900 mg/kg 04/26/15 01:28 7439-95-404/22/15 14:5019697.9 5 Manganese 68.4 mg/kg 04/26/15 01:28 7439-96-504/22/15 14:502.0 0.98 5 Molybdenum ND mg/kg 04/26/15 01:28 7439-98-704/22/15 14:503.9 2.0 5 Nickel 4.6 mg/kg 04/26/15 01:28 7440-02-004/22/15 14:502.0 0.98 5 Potassium 2180 mg/kg 04/26/15 01:28 7440-09-704/22/15 14:503921965 Sodium 380J mg/kg 04/26/15 01:28 7440-23-504/22/15 14:503921965 Strontium 36.9 mg/kg 04/26/15 01:28 7440-24-604/22/15 14:503.9 2.0 5 Zinc 23.9 mg/kg 04/26/15 01:28 7440-66-604/22/15 14:507.8 3.9 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/26/15 11:55 7440-36-0 N204/22/15 14:507.8 3.9 100 Arsenic ND mg/kg 04/26/15 11:55 7440-38-204/22/15 14:507.8 3.9 100 Cadmium ND mg/kg 04/26/15 11:55 7440-43-904/22/15 14:500.94 0.47 100 Cobalt ND mg/kg 04/26/15 11:55 7440-48-404/22/15 14:507.8 3.9 100 Lead ND mg/kg 04/26/15 11:55 7439-92-104/22/15 14:507.8 3.9 100 Selenium ND mg/kg 04/26/15 11:55 7782-49-204/22/15 14:507.8 3.9 100 Thallium ND mg/kg 04/26/15 11:55 7440-28-004/22/15 14:507.8 3.9 100 Vanadium 12.8 mg/kg 04/26/15 11:55 7440-62-204/22/15 14:507.8 3.9 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/23/15 17:22 7439-97-604/22/15 14:550.013 0.0063 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 35.5 %04/21/15 10:520.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 8.7 Std. Units 04/17/15 10:50 H30.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/20/15 03:49 16887-00-6 D33821915 Sulfate ND mg/kg 04/20/15 03:49 14808-79-8 D33821915 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/20/15 03:49 14797-55-8 H338.2 19.1 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 88 54 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010721 Lab ID:92245618004 Collected:04/08/15 11:45 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 3350 mg/kg 04/30/15 17:38 7440-44-09364681 Total Organic Carbon 3600 mg/kg 04/30/15 17:43 7440-44-09274631 Total Organic Carbon 3300 mg/kg 04/30/15 17:50 7440-44-09274631 Total Organic Carbon 3350 mg/kg 04/30/15 17:55 7440-44-09324661 Mean Total Organic Carbon 3400 mg/kg 04/30/15 17:38 7440-44-09314651 Surrogates RSD%4.1 %04/30/15 17:381 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 88 55 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010722 Lab ID:92245618005 Collected:04/13/15 08:45 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 39.1 mg/kg 04/26/15 01:41 7429-90-504/22/15 14:5035.8 17.9 5 Barium ND mg/kg 04/26/15 01:41 7440-39-304/22/15 14:503.6 1.8 5 Beryllium ND mg/kg 04/26/15 01:41 7440-41-704/22/15 14:500.36 0.18 5 Boron ND mg/kg 04/26/15 01:41 7440-42-804/22/15 14:5017.9 8.9 5 Calcium ND mg/kg 04/26/15 01:41 7440-70-204/22/15 14:5017989.4 5 Chromium ND mg/kg 04/26/15 01:41 7440-47-304/22/15 14:501.8 0.89 5 Copper ND mg/kg 04/26/15 01:41 7440-50-804/22/15 14:501.8 0.89 5 Iron 43.8 mg/kg 04/26/15 01:41 7439-89-604/22/15 14:5014.3 7.2 5 Magnesium ND mg/kg 04/26/15 01:41 7439-95-404/22/15 14:5017989.4 5 Manganese ND mg/kg 04/26/15 01:41 7439-96-504/22/15 14:501.8 0.89 5 Molybdenum ND mg/kg 04/26/15 01:41 7439-98-704/22/15 14:503.6 1.8 5 Nickel ND mg/kg 04/26/15 01:41 7440-02-004/22/15 14:501.8 0.89 5 Potassium ND mg/kg 04/26/15 01:41 7440-09-704/22/15 14:503581795 Sodium ND mg/kg 04/26/15 01:41 7440-23-504/22/15 14:503581795 Strontium ND mg/kg 04/26/15 01:41 7440-24-604/22/15 14:503.6 1.8 5 Zinc ND mg/kg 04/26/15 01:41 7440-66-604/22/15 14:507.2 3.6 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/26/15 12:00 7440-36-0 N204/22/15 14:507.2 3.6 100 Arsenic ND mg/kg 04/26/15 12:00 7440-38-204/22/15 14:507.2 3.6 100 Cadmium ND mg/kg 04/26/15 12:00 7440-43-904/22/15 14:500.86 0.43 100 Cobalt ND mg/kg 04/26/15 12:00 7440-48-404/22/15 14:507.2 3.6 100 Lead ND mg/kg 04/26/15 12:00 7439-92-104/22/15 14:507.2 3.6 100 Selenium ND mg/kg 04/26/15 12:00 7782-49-204/22/15 14:507.2 3.6 100 Thallium ND mg/kg 04/26/15 12:00 7440-28-004/22/15 14:507.2 3.6 100 Vanadium ND mg/kg 04/26/15 12:00 7440-62-204/22/15 14:507.2 3.6 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/23/15 17:24 7439-97-604/22/15 14:550.012 0.0058 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 27.6 %04/21/15 10:530.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.0 Std. Units 04/20/15 21:250.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/20/15 05:36 16887-00-6 D33341675 Sulfate ND mg/kg 04/20/15 05:36 14808-79-8 D33341675 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/20/15 05:36 14797-55-8 H333.4 16.7 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 36 of 88 56 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010722 Lab ID:92245618005 Collected:04/13/15 08:45 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 992 mg/kg 04/30/15 09:13 7440-44-08264131 Total Organic Carbon 1240 mg/kg 04/30/15 09:19 7440-44-08244121 Total Organic Carbon 855 mg/kg 04/30/15 09:25 7440-44-08364181 Total Organic Carbon 785J mg/kg 04/30/15 09:32 7440-44-08364181 Mean Total Organic Carbon 968 mg/kg 04/30/15 09:13 7440-44-08314151 Surrogates RSD%20.8 %04/30/15 09:131 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 37 of 88 57 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010723 Lab ID:92245618006 Collected:04/13/15 09:10 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 115 mg/kg 04/26/15 01:45 7429-90-504/22/15 14:5030.7 15.3 5 Barium ND mg/kg 04/26/15 01:45 7440-39-304/22/15 14:503.1 1.5 5 Beryllium ND mg/kg 04/26/15 01:45 7440-41-704/22/15 14:500.31 0.15 5 Boron ND mg/kg 04/26/15 01:45 7440-42-804/22/15 14:5015.3 7.7 5 Calcium ND mg/kg 04/26/15 01:45 7440-70-204/22/15 14:5015376.6 5 Chromium ND mg/kg 04/26/15 01:45 7440-47-304/22/15 14:501.5 0.77 5 Copper ND mg/kg 04/26/15 01:45 7440-50-804/22/15 14:501.5 0.77 5 Iron 54.6 mg/kg 04/26/15 01:45 7439-89-604/22/15 14:5012.3 6.1 5 Magnesium ND mg/kg 04/26/15 01:45 7439-95-404/22/15 14:5015376.6 5 Manganese ND mg/kg 04/26/15 01:45 7439-96-504/22/15 14:501.5 0.77 5 Molybdenum ND mg/kg 04/26/15 01:45 7439-98-704/22/15 14:503.1 1.5 5 Nickel ND mg/kg 04/26/15 01:45 7440-02-004/22/15 14:501.5 0.77 5 Potassium ND mg/kg 04/26/15 01:45 7440-09-704/22/15 14:503071535 Sodium ND mg/kg 04/26/15 01:45 7440-23-504/22/15 14:503071535 Strontium ND mg/kg 04/26/15 01:45 7440-24-604/22/15 14:503.1 1.5 5 Zinc ND mg/kg 04/26/15 01:45 7440-66-604/22/15 14:506.1 3.1 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/26/15 12:02 7440-36-0 N204/22/15 14:506.1 3.1 100 Arsenic ND mg/kg 04/26/15 12:02 7440-38-204/22/15 14:506.1 3.1 100 Cadmium ND mg/kg 04/26/15 12:02 7440-43-904/22/15 14:500.74 0.37 100 Cobalt ND mg/kg 04/26/15 12:02 7440-48-404/22/15 14:506.1 3.1 100 Lead ND mg/kg 04/26/15 12:02 7439-92-104/22/15 14:506.1 3.1 100 Selenium ND mg/kg 04/26/15 12:02 7782-49-204/22/15 14:506.1 3.1 100 Thallium ND mg/kg 04/26/15 12:02 7440-28-004/22/15 14:506.1 3.1 100 Vanadium ND mg/kg 04/26/15 12:02 7440-62-204/22/15 14:506.1 3.1 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/23/15 17:26 7439-97-604/22/15 14:550.0097 0.0048 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 19.6 %04/21/15 10:530.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 5.9 Std. Units 04/20/15 21:250.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/20/15 08:27 16887-00-6 D33121565 Sulfate ND mg/kg 04/20/15 08:27 14808-79-8 D33121565 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/20/15 08:27 14797-55-8 H331.2 15.6 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 38 of 88 58 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010723 Lab ID:92245618006 Collected:04/13/15 09:10 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 384J mg/kg 05/07/15 13:36 7440-44-07463731 Total Organic Carbon 387J mg/kg 05/07/15 13:42 7440-44-07413711 Total Organic Carbon ND mg/kg 05/07/15 13:47 7440-44-07463731 Total Organic Carbon 375J mg/kg 05/07/15 13:52 7440-44-07433721 Mean Total Organic Carbon 375J mg/kg 05/07/15 13:36 7440-44-07443721 Surrogates RSD%3.8 %05/07/15 13:361 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 39 of 88 59 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010724 Lab ID:92245618007 Collected:04/13/15 11:00 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 101 mg/kg 04/26/15 01:49 7429-90-504/22/15 14:5029.1 14.6 5 Barium ND mg/kg 04/26/15 01:49 7440-39-304/22/15 14:502.9 1.5 5 Beryllium ND mg/kg 04/26/15 01:49 7440-41-704/22/15 14:500.29 0.15 5 Boron ND mg/kg 04/26/15 01:49 7440-42-804/22/15 14:5014.6 7.3 5 Calcium ND mg/kg 04/26/15 01:49 7440-70-204/22/15 14:5014672.8 5 Chromium ND mg/kg 04/26/15 01:49 7440-47-304/22/15 14:501.5 0.73 5 Copper ND mg/kg 04/26/15 01:49 7440-50-804/22/15 14:501.5 0.73 5 Iron 124 mg/kg 04/26/15 01:49 7439-89-604/22/15 14:5011.7 5.8 5 Magnesium ND mg/kg 04/26/15 01:49 7439-95-404/22/15 14:5014672.8 5 Manganese 4.3 mg/kg 04/26/15 01:49 7439-96-504/22/15 14:501.5 0.73 5 Molybdenum ND mg/kg 04/26/15 01:49 7439-98-704/22/15 14:502.9 1.5 5 Nickel ND mg/kg 04/26/15 01:49 7440-02-004/22/15 14:501.5 0.73 5 Potassium ND mg/kg 04/26/15 01:49 7440-09-704/22/15 14:502911465 Sodium ND mg/kg 04/26/15 01:49 7440-23-504/22/15 14:502911465 Strontium ND mg/kg 04/26/15 01:49 7440-24-604/22/15 14:502.9 1.5 5 Zinc ND mg/kg 04/26/15 01:49 7440-66-604/22/15 14:505.8 2.9 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/26/15 12:04 7440-36-0 N204/22/15 14:505.8 2.9 100 Arsenic ND mg/kg 04/26/15 12:04 7440-38-204/22/15 14:505.8 2.9 100 Cadmium ND mg/kg 04/26/15 12:04 7440-43-904/22/15 14:500.70 0.35 100 Cobalt ND mg/kg 04/26/15 12:04 7440-48-404/22/15 14:505.8 2.9 100 Lead ND mg/kg 04/26/15 12:04 7439-92-104/22/15 14:505.8 2.9 100 Selenium ND mg/kg 04/26/15 12:04 7782-49-204/22/15 14:505.8 2.9 100 Thallium ND mg/kg 04/26/15 12:04 7440-28-004/22/15 14:505.8 2.9 100 Vanadium ND mg/kg 04/26/15 12:04 7440-62-204/22/15 14:505.8 2.9 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/23/15 18:46 7439-97-604/22/15 14:550.0093 0.0047 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 18.0 %04/21/15 10:540.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 5.9 Std. Units 04/20/15 21:250.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/20/15 08:49 16887-00-6 D33051535 Sulfate ND mg/kg 04/20/15 08:49 14808-79-8 D33051535 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/20/15 08:49 14797-55-8 H330.5 15.3 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 40 of 88 60 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010724 Lab ID:92245618007 Collected:04/13/15 11:00 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 05/07/15 13:58 7440-44-07383691 Total Organic Carbon ND mg/kg 05/07/15 14:04 7440-44-07353681 Total Organic Carbon ND mg/kg 05/07/15 14:10 7440-44-07293651 Total Organic Carbon ND mg/kg 05/07/15 14:16 7440-44-07313661 Mean Total Organic Carbon ND mg/kg 05/07/15 13:58 7440-44-07333671 Surrogates RSD%3.4 %05/07/15 13:581 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 41 of 88 61 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010725 Lab ID:92245618008 Collected:04/13/15 18:00 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 294 mg/kg 04/26/15 02:05 7429-90-504/22/15 14:5032.3 16.1 5 Barium 1.6J mg/kg 04/26/15 02:05 7440-39-304/22/15 14:503.2 1.6 5 Beryllium ND mg/kg 04/26/15 02:05 7440-41-704/22/15 14:500.32 0.16 5 Boron ND mg/kg 04/26/15 02:05 7440-42-804/22/15 14:5016.1 8.1 5 Calcium ND mg/kg 04/26/15 02:05 7440-70-204/22/15 14:5016180.7 5 Chromium ND mg/kg 04/26/15 02:05 7440-47-304/22/15 14:501.6 0.81 5 Copper ND mg/kg 04/26/15 02:05 7440-50-804/22/15 14:501.6 0.81 5 Iron 412 mg/kg 04/26/15 02:05 7439-89-604/22/15 14:5012.9 6.5 5 Magnesium ND mg/kg 04/26/15 02:05 7439-95-404/22/15 14:5016180.7 5 Manganese 6.2 mg/kg 04/26/15 02:05 7439-96-504/22/15 14:501.6 0.81 5 Molybdenum ND mg/kg 04/26/15 02:05 7439-98-704/22/15 14:503.2 1.6 5 Nickel ND mg/kg 04/26/15 02:05 7440-02-004/22/15 14:501.6 0.81 5 Potassium ND mg/kg 04/26/15 02:05 7440-09-704/22/15 14:503231615 Sodium ND mg/kg 04/26/15 02:05 7440-23-504/22/15 14:503231615 Strontium ND mg/kg 04/26/15 02:05 7440-24-604/22/15 14:503.2 1.6 5 Zinc ND mg/kg 04/26/15 02:05 7440-66-604/22/15 14:506.5 3.2 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/26/15 12:07 7440-36-0 N204/22/15 14:506.5 3.2 100 Arsenic ND mg/kg 04/26/15 12:07 7440-38-204/22/15 14:506.5 3.2 100 Cadmium ND mg/kg 04/26/15 12:07 7440-43-904/22/15 14:500.77 0.39 100 Cobalt ND mg/kg 04/26/15 12:07 7440-48-404/22/15 14:506.5 3.2 100 Lead ND mg/kg 04/26/15 12:07 7439-92-104/22/15 14:506.5 3.2 100 Selenium ND mg/kg 04/26/15 12:07 7782-49-204/22/15 14:506.5 3.2 100 Thallium ND mg/kg 04/26/15 12:07 7440-28-004/22/15 14:506.5 3.2 100 Vanadium ND mg/kg 04/26/15 12:07 7440-62-204/22/15 14:506.5 3.2 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/23/15 18:48 7439-97-604/22/15 14:550.010 0.0051 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 23.4 %04/21/15 10:550.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.0 Std. Units 04/20/15 21:250.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/20/15 09:10 16887-00-6 D33271635 Sulfate ND mg/kg 04/20/15 09:10 14808-79-8 D33271635 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/20/15 09:10 14797-55-8 H332.7 16.3 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 42 of 88 62 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010725 Lab ID:92245618008 Collected:04/13/15 18:00 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 05/07/15 14:23 7440-44-07883941 Total Organic Carbon ND mg/kg 05/07/15 14:28 7440-44-07883941 Total Organic Carbon ND mg/kg 05/07/15 14:34 7440-44-07903951 Total Organic Carbon ND mg/kg 05/07/15 14:39 7440-44-07803901 Mean Total Organic Carbon ND mg/kg 05/07/15 14:23 7440-44-07863931 Surrogates RSD%3.9 %05/07/15 14:231 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 43 of 88 63 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010726 Lab ID:92245618009 Collected:04/06/15 17:45 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 587 mg/kg 04/26/15 02:10 7429-90-504/22/15 14:5031.0 15.5 5 Barium ND mg/kg 04/26/15 02:10 7440-39-304/22/15 14:503.1 1.6 5 Beryllium ND mg/kg 04/26/15 02:10 7440-41-704/22/15 14:500.31 0.16 5 Boron ND mg/kg 04/26/15 02:10 7440-42-804/22/15 14:5015.5 7.8 5 Calcium ND mg/kg 04/26/15 02:10 7440-70-204/22/15 14:5015577.6 5 Chromium ND mg/kg 04/26/15 02:10 7440-47-304/22/15 14:501.6 0.78 5 Copper ND mg/kg 04/26/15 02:10 7440-50-804/22/15 14:501.6 0.78 5 Iron 422 mg/kg 04/26/15 02:10 7439-89-604/22/15 14:5012.4 6.2 5 Magnesium ND mg/kg 04/26/15 02:10 7439-95-404/22/15 14:5015577.6 5 Manganese ND mg/kg 04/26/15 02:10 7439-96-504/22/15 14:501.6 0.78 5 Molybdenum ND mg/kg 04/26/15 02:10 7439-98-704/22/15 14:503.1 1.6 5 Nickel ND mg/kg 04/26/15 02:10 7440-02-004/22/15 14:501.6 0.78 5 Potassium ND mg/kg 04/26/15 02:10 7440-09-704/22/15 14:503101555 Sodium ND mg/kg 04/26/15 02:10 7440-23-504/22/15 14:503101555 Strontium ND mg/kg 04/26/15 02:10 7440-24-604/22/15 14:503.1 1.6 5 Zinc ND mg/kg 04/26/15 02:10 7440-66-604/22/15 14:506.2 3.1 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/26/15 12:09 7440-36-0 N204/22/15 14:506.2 3.1 100 Arsenic ND mg/kg 04/26/15 12:09 7440-38-204/22/15 14:506.2 3.1 100 Cadmium ND mg/kg 04/26/15 12:09 7440-43-904/22/15 14:500.75 0.37 100 Cobalt ND mg/kg 04/26/15 12:09 7440-48-404/22/15 14:506.2 3.1 100 Lead ND mg/kg 04/26/15 12:09 7439-92-104/22/15 14:506.2 3.1 100 Selenium ND mg/kg 04/26/15 12:09 7782-49-204/22/15 14:506.2 3.1 100 Thallium ND mg/kg 04/26/15 12:09 7440-28-004/22/15 14:506.2 3.1 100 Vanadium ND mg/kg 04/26/15 12:09 7440-62-204/22/15 14:506.2 3.1 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/23/15 18:50 7439-97-604/22/15 14:550.010 0.0051 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 19.6 %04/21/15 10:550.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 5.0 Std. Units 04/17/15 10:50 H30.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/20/15 09:32 16887-00-6 D33081545 Sulfate ND mg/kg 04/20/15 09:32 14808-79-8 D33081545 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/20/15 09:32 14797-55-8 H330.8 15.4 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 44 of 88 64 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010726 Lab ID:92245618009 Collected:04/06/15 17:45 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 404J mg/kg 04/28/15 15:43 7440-44-07463731 Total Organic Carbon 434J mg/kg 04/28/15 15:49 7440-44-07493741 Total Organic Carbon 432J mg/kg 04/28/15 15:55 7440-44-07433711 Total Organic Carbon 413J mg/kg 04/28/15 16:01 7440-44-07463731 Mean Total Organic Carbon 421J mg/kg 04/28/15 15:43 7440-44-07463731 Surrogates RSD%3.5 %04/28/15 15:431 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 45 of 88 65 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010727 Lab ID:92245618010 Collected:04/06/15 17:30 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 144 mg/kg 04/26/15 02:14 7429-90-504/22/15 14:5033.9 16.9 5 Barium ND mg/kg 04/26/15 02:14 7440-39-304/22/15 14:503.4 1.7 5 Beryllium ND mg/kg 04/26/15 02:14 7440-41-704/22/15 14:500.34 0.17 5 Boron ND mg/kg 04/26/15 02:14 7440-42-804/22/15 14:5016.9 8.5 5 Calcium ND mg/kg 04/26/15 02:14 7440-70-204/22/15 14:5016984.6 5 Chromium ND mg/kg 04/26/15 02:14 7440-47-304/22/15 14:501.7 0.85 5 Copper ND mg/kg 04/26/15 02:14 7440-50-804/22/15 14:501.7 0.85 5 Iron 55.1 mg/kg 04/26/15 02:14 7439-89-604/22/15 14:5013.5 6.8 5 Magnesium ND mg/kg 04/26/15 02:14 7439-95-404/22/15 14:5016984.6 5 Manganese ND mg/kg 04/26/15 02:14 7439-96-504/22/15 14:501.7 0.85 5 Molybdenum ND mg/kg 04/26/15 02:14 7439-98-704/22/15 14:503.4 1.7 5 Nickel ND mg/kg 04/26/15 02:14 7440-02-004/22/15 14:501.7 0.85 5 Potassium ND mg/kg 04/26/15 02:14 7440-09-704/22/15 14:503391695 Sodium ND mg/kg 04/26/15 02:14 7440-23-504/22/15 14:503391695 Strontium ND mg/kg 04/26/15 02:14 7440-24-604/22/15 14:503.4 1.7 5 Zinc ND mg/kg 04/26/15 02:14 7440-66-604/22/15 14:506.8 3.4 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/26/15 12:18 7440-36-0 N204/22/15 14:506.8 3.4 100 Arsenic ND mg/kg 04/26/15 12:18 7440-38-204/22/15 14:506.8 3.4 100 Cadmium ND mg/kg 04/26/15 12:18 7440-43-904/22/15 14:500.81 0.41 100 Cobalt ND mg/kg 04/26/15 12:18 7440-48-404/22/15 14:506.8 3.4 100 Lead ND mg/kg 04/26/15 12:18 7439-92-104/22/15 14:506.8 3.4 100 Selenium ND mg/kg 04/26/15 12:18 7782-49-204/22/15 14:506.8 3.4 100 Thallium ND mg/kg 04/26/15 12:18 7440-28-004/22/15 14:506.8 3.4 100 Vanadium ND mg/kg 04/26/15 12:18 7440-62-204/22/15 14:506.8 3.4 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/23/15 18:57 7439-97-604/22/15 14:550.010 0.0051 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 23.0 %04/21/15 10:560.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 4.6 Std. Units 04/17/15 10:50 H30.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/20/15 09:53 16887-00-6 D33231625 Sulfate ND mg/kg 04/20/15 09:53 14808-79-8 D33231625 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/20/15 09:53 14797-55-8 H332.3 16.2 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 46 of 88 66 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010727 Lab ID:92245618010 Collected:04/06/15 17:30 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 5770 mg/kg 04/28/15 16:07 7440-44-07723861 Total Organic Carbon 4840 mg/kg 04/28/15 16:14 7440-44-07853921 Total Organic Carbon 4190 mg/kg 04/28/15 16:20 7440-44-07803901 Total Organic Carbon 4430 mg/kg 04/28/15 16:25 7440-44-07803901 Mean Total Organic Carbon 4810 mg/kg 04/28/15 16:07 7440-44-07793901 Surrogates RSD%14.5 %04/28/15 16:071 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 47 of 88 67 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010728 Lab ID:92245618011 Collected:04/14/15 13:40 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 800 mg/kg 04/26/15 02:18 7429-90-504/22/15 14:5034.4 17.2 5 Barium ND mg/kg 04/26/15 02:18 7440-39-304/22/15 14:503.4 1.7 5 Beryllium ND mg/kg 04/26/15 02:18 7440-41-704/22/15 14:500.34 0.17 5 Boron ND mg/kg 04/26/15 02:18 7440-42-804/22/15 14:5017.2 8.6 5 Calcium 138J mg/kg 04/26/15 02:18 7440-70-204/22/15 14:5017286.1 5 Chromium ND mg/kg 04/26/15 02:18 7440-47-304/22/15 14:501.7 0.86 5 Copper ND mg/kg 04/26/15 02:18 7440-50-804/22/15 14:501.7 0.86 5 Iron 609 mg/kg 04/26/15 02:18 7439-89-604/22/15 14:5013.8 6.9 5 Magnesium ND mg/kg 04/26/15 02:18 7439-95-404/22/15 14:5017286.1 5 Manganese 2.1 mg/kg 04/26/15 02:18 7439-96-504/22/15 14:501.7 0.86 5 Molybdenum ND mg/kg 04/26/15 02:18 7439-98-704/22/15 14:503.4 1.7 5 Nickel ND mg/kg 04/26/15 02:18 7440-02-004/22/15 14:501.7 0.86 5 Potassium ND mg/kg 04/26/15 02:18 7440-09-704/22/15 14:503441725 Sodium ND mg/kg 04/26/15 02:18 7440-23-504/22/15 14:503441725 Strontium ND mg/kg 04/26/15 02:18 7440-24-604/22/15 14:503.4 1.7 5 Zinc ND mg/kg 04/26/15 02:18 7440-66-604/22/15 14:506.9 3.4 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/26/15 12:20 7440-36-0 N204/22/15 14:506.9 3.4 100 Arsenic ND mg/kg 04/26/15 12:20 7440-38-204/22/15 14:506.9 3.4 100 Cadmium ND mg/kg 04/26/15 12:20 7440-43-904/22/15 14:500.83 0.41 100 Cobalt ND mg/kg 04/26/15 12:20 7440-48-404/22/15 14:506.9 3.4 100 Lead ND mg/kg 04/26/15 12:20 7439-92-104/22/15 14:506.9 3.4 100 Selenium ND mg/kg 04/26/15 12:20 7782-49-204/22/15 14:506.9 3.4 100 Thallium ND mg/kg 04/26/15 12:20 7440-28-004/22/15 14:506.9 3.4 100 Vanadium ND mg/kg 04/26/15 12:20 7440-62-204/22/15 14:506.9 3.4 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/23/15 18:59 7439-97-604/22/15 14:550.011 0.0057 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 26.2 %04/21/15 10:570.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 8.4 Std. Units 04/20/15 21:250.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/20/15 10:14 16887-00-6 D33351685 Sulfate ND mg/kg 04/20/15 10:14 14808-79-8 D33351685 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/20/15 10:14 14797-55-8 H333.5 16.8 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 48 of 88 68 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010728 Lab ID:92245618011 Collected:04/14/15 13:40 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 1220 mg/kg 05/07/15 14:46 7440-44-08084041 Total Organic Carbon 1070 mg/kg 05/07/15 14:52 7440-44-08104051 Total Organic Carbon 1080 mg/kg 05/07/15 14:57 7440-44-08104051 Total Organic Carbon 1690 mg/kg 05/07/15 15:03 7440-44-08114051 Mean Total Organic Carbon 1260 mg/kg 05/07/15 14:46 7440-44-08104051 Surrogates RSD%23.0 %05/07/15 14:461 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 49 of 88 69 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010729 Lab ID:92245618012 Collected:04/14/15 14:30 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 302 mg/kg 04/26/15 02:22 7429-90-504/22/15 14:5030.5 15.3 5 Barium ND mg/kg 04/26/15 02:22 7440-39-304/22/15 14:503.1 1.5 5 Beryllium ND mg/kg 04/26/15 02:22 7440-41-704/22/15 14:500.31 0.15 5 Boron ND mg/kg 04/26/15 02:22 7440-42-804/22/15 14:5015.3 7.6 5 Calcium ND mg/kg 04/26/15 02:22 7440-70-204/22/15 14:5015376.3 5 Chromium ND mg/kg 04/26/15 02:22 7440-47-304/22/15 14:501.5 0.76 5 Copper ND mg/kg 04/26/15 02:22 7440-50-804/22/15 14:501.5 0.76 5 Iron 82.3 mg/kg 04/26/15 02:22 7439-89-604/22/15 14:5012.2 6.1 5 Magnesium ND mg/kg 04/26/15 02:22 7439-95-404/22/15 14:5015376.3 5 Manganese ND mg/kg 04/26/15 02:22 7439-96-504/22/15 14:501.5 0.76 5 Molybdenum ND mg/kg 04/26/15 02:22 7439-98-704/22/15 14:503.1 1.5 5 Nickel ND mg/kg 04/26/15 02:22 7440-02-004/22/15 14:501.5 0.76 5 Potassium ND mg/kg 04/26/15 02:22 7440-09-704/22/15 14:503051535 Sodium ND mg/kg 04/26/15 02:22 7440-23-504/22/15 14:503051535 Strontium ND mg/kg 04/26/15 02:22 7440-24-604/22/15 14:503.1 1.5 5 Zinc ND mg/kg 04/26/15 02:22 7440-66-604/22/15 14:506.1 3.1 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/26/15 12:23 7440-36-0 N204/22/15 14:506.1 3.1 100 Arsenic ND mg/kg 04/26/15 12:23 7440-38-204/22/15 14:506.1 3.1 100 Cadmium ND mg/kg 04/26/15 12:23 7440-43-904/22/15 14:500.73 0.37 100 Cobalt ND mg/kg 04/26/15 12:23 7440-48-404/22/15 14:506.1 3.1 100 Lead ND mg/kg 04/26/15 12:23 7439-92-104/22/15 14:506.1 3.1 100 Selenium ND mg/kg 04/26/15 12:23 7782-49-204/22/15 14:506.1 3.1 100 Thallium ND mg/kg 04/26/15 12:23 7440-28-004/22/15 14:506.1 3.1 100 Vanadium ND mg/kg 04/26/15 12:23 7440-62-204/22/15 14:506.1 3.1 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/23/15 19:01 7439-97-604/22/15 14:550.010 0.0052 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 19.5 %04/21/15 10:580.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.8 Std. Units 04/20/15 21:250.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/20/15 10:36 16887-00-6 D33101555 Sulfate ND mg/kg 04/20/15 10:36 14808-79-8 D33101555 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/20/15 10:36 14797-55-8 H331.0 15.5 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 50 of 88 70 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010729 Lab ID:92245618012 Collected:04/14/15 14:30 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 05/07/15 15:09 7440-44-07393701 Total Organic Carbon 400J mg/kg 05/07/15 15:14 7440-44-07443721 Total Organic Carbon 384J mg/kg 05/07/15 15:20 7440-44-07423711 Total Organic Carbon 417J mg/kg 05/07/15 15:25 7440-44-07503751 Mean Total Organic Carbon 386J mg/kg 05/07/15 15:09 7440-44-07443721 Surrogates RSD%8.2 %05/07/15 15:091 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 51 of 88 71 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010730 Lab ID:92245618013 Collected:04/14/15 16:00 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 1310 mg/kg 04/26/15 02:26 7429-90-504/22/15 14:5030.8 15.4 5 Barium 3.3 mg/kg 04/26/15 02:26 7440-39-304/22/15 14:503.1 1.5 5 Beryllium ND mg/kg 04/26/15 02:26 7440-41-704/22/15 14:500.31 0.15 5 Boron ND mg/kg 04/26/15 02:26 7440-42-804/22/15 14:5015.4 7.7 5 Calcium 93.6J mg/kg 04/26/15 02:26 7440-70-204/22/15 14:5015477.0 5 Chromium 1.9 mg/kg 04/26/15 02:26 7440-47-304/22/15 14:501.5 0.77 5 Copper ND mg/kg 04/26/15 02:26 7440-50-804/22/15 14:501.5 0.77 5 Iron 1870 mg/kg 04/26/15 02:26 7439-89-604/22/15 14:5012.3 6.2 5 Magnesium 97.9J mg/kg 04/26/15 02:26 7439-95-404/22/15 14:5015477.0 5 Manganese 7.5 mg/kg 04/26/15 02:26 7439-96-504/22/15 14:501.5 0.77 5 Molybdenum ND mg/kg 04/26/15 02:26 7439-98-704/22/15 14:503.1 1.5 5 Nickel 0.98J mg/kg 04/26/15 02:26 7440-02-004/22/15 14:501.5 0.77 5 Potassium ND mg/kg 04/26/15 02:26 7440-09-704/22/15 14:503081545 Sodium ND mg/kg 04/26/15 02:26 7440-23-504/22/15 14:503081545 Strontium 1.8J mg/kg 04/26/15 02:26 7440-24-604/22/15 14:503.1 1.5 5 Zinc ND mg/kg 04/26/15 02:26 7440-66-604/22/15 14:506.2 3.1 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/26/15 12:25 7440-36-0 N204/22/15 14:506.2 3.1 100 Arsenic ND mg/kg 04/26/15 12:25 7440-38-204/22/15 14:506.2 3.1 100 Cadmium ND mg/kg 04/26/15 12:25 7440-43-904/22/15 14:500.74 0.37 100 Cobalt ND mg/kg 04/26/15 12:25 7440-48-404/22/15 14:506.2 3.1 100 Lead ND mg/kg 04/26/15 12:25 7439-92-104/22/15 14:506.2 3.1 100 Selenium ND mg/kg 04/26/15 12:25 7782-49-204/22/15 14:506.2 3.1 100 Thallium ND mg/kg 04/26/15 12:25 7440-28-004/22/15 14:506.2 3.1 100 Vanadium ND mg/kg 04/26/15 12:25 7440-62-204/22/15 14:506.2 3.1 100 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/23/15 19:03 7439-97-604/22/15 14:550.010 0.0052 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 22.3 %04/21/15 11:000.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 5.8 Std. Units 04/20/15 21:250.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/20/15 10:57 16887-00-6 D33201605 Sulfate ND mg/kg 04/20/15 10:57 14808-79-8 D33201605 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/20/15 10:57 14797-55-8 H332.0 16.0 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 52 of 88 72 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010730 Lab ID:92245618013 Collected:04/14/15 16:00 Received:04/15/15 15:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 05/11/15 14:00 7440-44-07703851 Total Organic Carbon ND mg/kg 05/11/15 14:06 7440-44-07693841 Total Organic Carbon ND mg/kg 05/11/15 14:11 7440-44-07713861 Total Organic Carbon ND mg/kg 05/11/15 14:17 7440-44-07733871 Mean Total Organic Carbon ND mg/kg 05/11/15 14:00 7440-44-07713851 Surrogates RSD%6.0 %05/11/15 14:001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 53 of 88 73 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010731 Lab ID:92245618014 Collected:04/14/15 13:30 Received:04/15/15 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 57.5 ug/L 04/21/15 05:13 7429-90-504/20/15 06:3310.0 3.0 1 Antimony ND ug/L 04/21/15 05:13 7440-36-004/20/15 06:330.50 0.15 1 Arsenic ND ug/L 04/21/15 05:13 7440-38-204/20/15 06:330.50 0.11 1 Barium 0.91 ug/L 04/21/15 05:13 7440-39-304/20/15 06:330.30 0.081 1 Beryllium ND ug/L 04/21/15 05:13 7440-41-704/20/15 06:330.20 0.067 1 Boron ND ug/L 04/21/15 05:13 7440-42-804/20/15 06:335.0 1.1 1 Cadmium ND ug/L 04/21/15 05:13 7440-43-904/20/15 06:330.080 0.024 1 Calcium 938 ug/L 04/23/15 01:49 7440-70-204/20/15 06:3340.0 16.0 1 Chromium 2.0 ug/L 04/21/15 05:13 7440-47-304/20/15 06:330.50 0.17 1 Cobalt ND ug/L 04/21/15 05:13 7440-48-404/20/15 06:330.50 0.13 1 Copper 1.0 ug/L 04/21/15 05:13 7440-50-804/20/15 06:331.0 0.21 1 Iron 364 ug/L 04/21/15 05:13 7439-89-604/20/15 06:3350.0 13.7 1 Lead 0.15 ug/L 04/21/15 05:13 7439-92-104/20/15 06:330.10 0.046 1 Magnesium 39.4 ug/L 04/21/15 05:13 7439-95-404/20/15 06:3310.0 3.2 1 Manganese 4.5 ug/L 04/21/15 05:13 7439-96-504/20/15 06:330.50 0.24 1 Molybdenum 0.76 ug/L 04/21/15 05:13 7439-98-704/20/15 06:330.50 0.094 1 Nickel 0.26J ug/L 04/21/15 05:13 7440-02-004/20/15 06:330.50 0.16 1 Potassium 131 ug/L 04/21/15 05:13 7440-09-704/20/15 06:3350.0 11.7 1 Selenium ND ug/L 04/21/15 05:13 7782-49-204/20/15 06:330.50 0.20 1 Sodium 308 ug/L 04/21/15 05:13 7440-23-504/20/15 06:3350.0 16.3 1 Strontium 1.8 ug/L 04/21/15 05:13 7440-24-604/20/15 06:330.50 0.13 1 Thallium ND ug/L 04/21/15 05:13 7440-28-004/20/15 06:330.10 0.015 1 Vanadium ND ug/L 04/21/15 05:13 7440-62-204/20/15 06:331.0 0.28 1 Zinc 9.9 ug/L 04/21/15 05:13 7440-66-604/20/15 06:335.0 2.4 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 04/20/15 20:16 7439-97-604/20/15 11:150.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 54 of 88 74 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010732 Lab ID:92245618015 Collected:04/13/15 08:30 Received:04/15/15 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 14.3 ug/L 04/21/15 05:18 7429-90-504/20/15 06:3310.0 3.0 1 Antimony ND ug/L 04/21/15 05:18 7440-36-004/20/15 06:330.50 0.15 1 Arsenic ND ug/L 04/21/15 05:18 7440-38-204/20/15 06:330.50 0.11 1 Barium 4.2 ug/L 04/21/15 05:18 7440-39-304/20/15 06:330.30 0.081 1 Beryllium ND ug/L 04/21/15 05:18 7440-41-704/20/15 06:330.20 0.067 1 Boron 14.2 ug/L 04/21/15 05:18 7440-42-804/20/15 06:335.0 1.1 1 Cadmium ND ug/L 04/21/15 05:18 7440-43-904/20/15 06:330.080 0.024 1 Calcium 144 ug/L 04/23/15 01:53 7440-70-204/20/15 06:3340.0 16.0 1 Chromium 4.6 ug/L 04/21/15 05:18 7440-47-304/20/15 06:330.50 0.17 1 Cobalt 1.8 ug/L 04/21/15 05:18 7440-48-404/20/15 06:330.50 0.13 1 Copper 18.2 ug/L 04/21/15 05:18 7440-50-804/20/15 06:331.0 0.21 1 Iron 337 ug/L 04/21/15 05:18 7439-89-604/20/15 06:3350.0 13.7 1 Lead 19.1 ug/L 04/21/15 05:18 7439-92-104/20/15 06:330.10 0.046 1 Magnesium 10.9 ug/L 04/21/15 05:18 7439-95-404/20/15 06:3310.0 3.2 1 Manganese 31.3 ug/L 04/21/15 05:18 7439-96-504/20/15 06:330.50 0.24 1 Molybdenum 0.69 ug/L 04/21/15 05:18 7439-98-704/20/15 06:330.50 0.094 1 Nickel 1.0 ug/L 04/21/15 05:18 7440-02-004/20/15 06:330.50 0.16 1 Potassium ND ug/L 04/21/15 05:18 7440-09-704/20/15 06:3350.0 11.7 1 Selenium ND ug/L 04/21/15 05:18 7782-49-204/20/15 06:330.50 0.20 1 Sodium 23.9J ug/L 04/21/15 05:18 7440-23-504/20/15 06:3350.0 16.3 1 Strontium 0.59 ug/L 04/21/15 05:18 7440-24-604/20/15 06:330.50 0.13 1 Thallium ND ug/L 04/21/15 05:18 7440-28-004/20/15 06:330.10 0.015 1 Vanadium ND ug/L 04/21/15 05:18 7440-62-204/20/15 06:331.0 0.28 1 Zinc 59.6 ug/L 04/21/15 05:18 7440-66-604/20/15 06:335.0 2.4 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 04/20/15 20:18 7439-97-604/20/15 11:150.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 55 of 88 75 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010733 Lab ID:92245618016 Collected:04/13/15 16:40 Received:04/15/15 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 9.1J ug/L 04/21/15 05:23 7429-90-504/20/15 06:3310.0 3.0 1 Antimony ND ug/L 04/21/15 05:23 7440-36-004/20/15 06:330.50 0.15 1 Arsenic ND ug/L 04/21/15 05:23 7440-38-204/20/15 06:330.50 0.11 1 Barium 0.22J ug/L 04/21/15 05:23 7440-39-304/20/15 06:330.30 0.081 1 Beryllium ND ug/L 04/21/15 05:23 7440-41-704/20/15 06:330.20 0.067 1 Boron ND ug/L 04/21/15 05:23 7440-42-804/20/15 06:335.0 1.1 1 Cadmium ND ug/L 04/21/15 05:23 7440-43-904/20/15 06:330.080 0.024 1 Calcium 177 ug/L 04/23/15 01:58 7440-70-204/20/15 06:3340.0 16.0 1 Chromium 0.34J ug/L 04/21/15 05:23 7440-47-304/20/15 06:330.50 0.17 1 Cobalt 0.23J ug/L 04/21/15 05:23 7440-48-404/20/15 06:330.50 0.13 1 Copper 0.29J ug/L 04/21/15 05:23 7440-50-804/20/15 06:331.0 0.21 1 Iron 68.1 ug/L 04/21/15 05:23 7439-89-604/20/15 06:3350.0 13.7 1 Lead 0.049J ug/L 04/21/15 05:23 7439-92-104/20/15 06:330.10 0.046 1 Magnesium 11.6 ug/L 04/21/15 05:23 7439-95-404/20/15 06:3310.0 3.2 1 Manganese 0.81 ug/L 04/21/15 05:23 7439-96-504/20/15 06:330.50 0.24 1 Molybdenum 0.16J ug/L 04/21/15 05:23 7439-98-704/20/15 06:330.50 0.094 1 Nickel ND ug/L 04/21/15 05:23 7440-02-004/20/15 06:330.50 0.16 1 Potassium 22.1J ug/L 04/21/15 05:23 7440-09-704/20/15 06:3350.0 11.7 1 Selenium ND ug/L 04/21/15 05:23 7782-49-204/20/15 06:330.50 0.20 1 Sodium 104 ug/L 04/21/15 05:23 7440-23-504/20/15 06:3350.0 16.3 1 Strontium 0.36J ug/L 04/21/15 05:23 7440-24-604/20/15 06:330.50 0.13 1 Thallium ND ug/L 04/21/15 05:23 7440-28-004/20/15 06:330.10 0.015 1 Vanadium ND ug/L 04/21/15 05:23 7440-62-204/20/15 06:331.0 0.28 1 Zinc ND ug/L 04/21/15 05:23 7440-66-604/20/15 06:335.0 2.4 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 04/20/15 20:21 7439-97-604/20/15 11:150.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 56 of 88 76 of 109 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92245618 J15040323 Sample:2015010734 Lab ID:92245618017 Collected:04/06/15 17:00 Received:04/15/15 15:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 590 ug/L 04/21/15 05:27 7429-90-504/20/15 06:3310.0 3.0 1 Antimony 0.51 ug/L 04/21/15 05:27 7440-36-004/20/15 06:330.50 0.15 1 Arsenic 1.0 ug/L 04/21/15 05:27 7440-38-204/20/15 06:330.50 0.11 1 Barium 11.2 ug/L 04/21/15 05:27 7440-39-304/20/15 06:330.30 0.081 1 Beryllium 0.17J ug/L 04/21/15 05:27 7440-41-704/20/15 06:330.20 0.067 1 Boron 4.0J ug/L 04/21/15 05:27 7440-42-804/20/15 06:335.0 1.1 1 Cadmium 0.040J ug/L 04/21/15 05:27 7440-43-904/20/15 06:330.080 0.024 1 Calcium 13300 ug/L 04/23/15 02:03 7440-70-204/20/15 06:3320080.0 5 Chromium 8.6 ug/L 04/21/15 05:27 7440-47-304/20/15 06:330.50 0.17 1 Cobalt 3.1 ug/L 04/21/15 05:27 7440-48-404/20/15 06:330.50 0.13 1 Copper 3.5 ug/L 04/21/15 05:27 7440-50-804/20/15 06:331.0 0.21 1 Iron 2900 ug/L 04/21/15 05:27 7439-89-604/20/15 06:3350.0 13.7 1 Lead 0.73 ug/L 04/21/15 05:27 7439-92-104/20/15 06:330.10 0.046 1 Magnesium 4580 ug/L 04/21/15 05:27 7439-95-404/20/15 06:3310.0 3.2 1 Manganese 40.2 ug/L 04/21/15 05:27 7439-96-504/20/15 06:330.50 0.24 1 Molybdenum 1.3 ug/L 04/21/15 05:27 7439-98-704/20/15 06:330.50 0.094 1 Nickel 2.1 ug/L 04/21/15 05:27 7440-02-004/20/15 06:330.50 0.16 1 Potassium 501 ug/L 04/21/15 05:27 7440-09-704/20/15 06:3350.0 11.7 1 Selenium 0.40J ug/L 04/21/15 05:27 7782-49-204/20/15 06:330.50 0.20 1 Sodium 586 ug/L 04/21/15 05:27 7440-23-504/20/15 06:3350.0 16.3 1 Strontium 23.6 ug/L 04/21/15 05:27 7440-24-604/20/15 06:330.50 0.13 1 Thallium 0.016J ug/L 04/21/15 05:27 7440-28-004/20/15 06:330.10 0.015 1 Vanadium 3.2 ug/L 04/21/15 05:27 7440-62-204/20/15 06:331.0 0.28 1 Zinc 17.4 ug/L 04/21/15 05:27 7440-66-604/20/15 06:335.0 2.4 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 04/20/15 20:23 7439-97-604/20/15 11:150.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 57 of 88 77 of 109 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245618 J15040323 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/13265 EPA 7470 EPA 7470 7470 Mercury Associated Lab Samples:92245618014, 92245618015, 92245618016, 92245618017 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1942361 Associated Lab Samples:92245618014, 92245618015, 92245618016, 92245618017 Matrix:Water Analyzed Mercury ug/L ND 0.20 04/20/15 19:41 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1942362LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 5.15 102 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1942363MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243757012 1942364 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 103 75-125100 3 205ND5.2 5.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 58 of 88 78 of 109 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245618 J15040323 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/5615 EPA 7471 EPA 7471 7471 Mercury Associated Lab Samples:92245618002, 92245618003, 92245618004, 92245618005, 92245618006, 92245618007, 92245618008, 92245618009, 92245618010, 92245618011, 92245618012, 92245618013 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1190223 Associated Lab Samples:92245618002, 92245618003, 92245618004, 92245618005, 92245618006, 92245618007, 92245618008, 92245618009, 92245618010, 92245618011, 92245618012, 92245618013 Matrix:Solid Analyzed Mercury mg/kg ND 0.0082 04/23/15 17:01 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1190224LABORATORY CONTROL SAMPLE: LCSSpike Mercury mg/kg 0.071.081 88 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1190225MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245618002 1190226 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury mg/kg .109 91 80-12094 6 20.1110.0062J 0.10 0.11 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 59 of 88 79 of 109 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245618 J15040323 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/5618 EPA 7471 EPA 7471 7471 Mercury Associated Lab Samples:92245618001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1190449 Associated Lab Samples:92245618001 Matrix:Solid Analyzed Mercury mg/kg ND 0.0079 04/23/15 17:44 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1190450LABORATORY CONTROL SAMPLE: LCSSpike Mercury mg/kg 0.070.078 90 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1191846MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245637003 1191847 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury mg/kg .0845 86 80-12085 3 20.0824ND 0.072 0.070 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 60 of 88 80 of 109 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245618 J15040323 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/23716 EPA 3050 EPA 6010 6010 MET Solid Associated Lab Samples:92245618001, 92245618002, 92245618003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1188467 Associated Lab Samples:92245618001, 92245618002, 92245618003 Matrix:Solid Analyzed Aluminum mg/kg ND 5.2 04/25/15 22:53 Barium mg/kg ND 0.52 04/25/15 22:53 Beryllium mg/kg ND 0.052 04/25/15 22:53 Boron mg/kg ND 2.6 04/25/15 22:53 Calcium mg/kg ND 25.9 04/25/15 22:53 Chromium mg/kg ND 0.26 04/25/15 22:53 Copper mg/kg ND 0.26 04/25/15 22:53 Iron mg/kg 1.8J 2.1 P804/25/15 22:53 Magnesium mg/kg ND 25.9 04/25/15 22:53 Manganese mg/kg ND 0.26 04/25/15 22:53 Molybdenum mg/kg ND 0.52 04/25/15 22:53 Nickel mg/kg ND 0.26 04/25/15 22:53 Potassium mg/kg ND 51.8 04/25/15 22:53 Sodium mg/kg ND 51.8 04/25/15 22:53 Strontium mg/kg ND 0.52 04/25/15 22:53 Zinc mg/kg ND 1.0 04/25/15 22:53 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1188468LABORATORY CONTROL SAMPLE: LCSSpike Aluminum mg/kg 131129 102 80-120 Barium mg/kg 13.212.9 103 80-120 Beryllium mg/kg 1.31.3 101 80-120 Boron mg/kg 126129 98 80-120 Calcium mg/kg 665645 103 80-120 Chromium mg/kg 12.512.9 97 80-120 Copper mg/kg 12.512.9 97 80-120 Iron mg/kg 131129 101 80-120 Magnesium mg/kg 646645 100 80-120 Manganese mg/kg 12.812.9 99 80-120 Molybdenum mg/kg 12.712.9 98 80-120 Nickel mg/kg 13.112.9 102 80-120 Potassium mg/kg 646645 100 80-120 Sodium mg/kg 673645 104 80-120 Strontium mg/kg 13.112.9 101 80-120 Zinc mg/kg 65.164.5 101 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 61 of 88 81 of 109 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245618 J15040323 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1188469MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245627003 1188470 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum mg/kg M1224147075-1252170 16 20220520084809980 Barium mg/kg M122.4 340 75-125615 10 2022482558617 Beryllium mg/kg M12.25 112 75-125135 12 202.251.1 3.6 4.1 Boron mg/kg 224 83 75-12589 6 20220ND189200 Calcium mg/kg M1111012575-125152 10 201100139027903070 Chromium mg/kg 22.4 86 75-125104 11 202210.5 29.7 33.3 Copper mg/kg M122.4 115 75-125145 13 202219.3 44.9 51.1 Iron mg/kg M1224-1110 75-12584 14 20220205001800020700 Magnesium mg/kg 1110 106 75-125121 9 20110044716301780 Manganese mg/kg 22.4 102 75-125121 5 202256.2 79.0 82.8 Molybdenum mg/kg 22.4 84 75-12591 6 2022ND20.3 21.7 Nickel mg/kg 22.4 99 75-125119 11 202213.0 35.1 39.2 Potassium mg/kg M1111015175-125181 11 20110085325402840 Sodium mg/kg 1110 99 75-125106 5 201100ND11701230 Strontium mg/kg M122.4 276 75-125395 15 202297.4 159 184 Zinc mg/kg 111 92 75-125101 7 201109.7 113 121 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 62 of 88 82 of 109 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245618 J15040323 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/23746 EPA 3050 EPA 6010 6010 MET Solid Associated Lab Samples:92245618004, 92245618005, 92245618006, 92245618007, 92245618008, 92245618009, 92245618010, 92245618011, 92245618012, 92245618013 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1190227 Associated Lab Samples:92245618004, 92245618005, 92245618006, 92245618007, 92245618008, 92245618009, 92245618010, 92245618011, 92245618012, 92245618013 Matrix:Solid Analyzed Aluminum mg/kg ND 4.9 04/26/15 00:56 Barium mg/kg ND 0.49 04/26/15 00:56 Beryllium mg/kg ND 0.049 04/26/15 00:56 Boron mg/kg ND 2.4 04/26/15 00:56 Calcium mg/kg ND 24.3 04/26/15 00:56 Chromium mg/kg ND 0.24 04/26/15 00:56 Copper mg/kg ND 0.24 04/26/15 00:56 Iron mg/kg ND 1.9 04/26/15 00:56 Magnesium mg/kg ND 24.3 04/26/15 00:56 Manganese mg/kg ND 0.24 04/26/15 00:56 Molybdenum mg/kg ND 0.49 04/26/15 00:56 Nickel mg/kg ND 0.24 04/26/15 00:56 Potassium mg/kg ND 48.7 04/26/15 00:56 Sodium mg/kg ND 48.7 04/26/15 00:56 Strontium mg/kg ND 0.49 04/26/15 00:56 Zinc mg/kg ND 0.97 04/26/15 00:56 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1190228LABORATORY CONTROL SAMPLE: LCSSpike Aluminum mg/kg 124122 102 80-120 Barium mg/kg 12.612.2 103 80-120 Beryllium mg/kg 1.21.2 102 80-120 Boron mg/kg 121122 99 80-120 Calcium mg/kg 626610 103 80-120 Chromium mg/kg 11.912.2 98 80-120 Copper mg/kg 11.912.2 98 80-120 Iron mg/kg 123122 101 80-120 Magnesium mg/kg 611610 100 80-120 Manganese mg/kg 12.212.2 100 80-120 Molybdenum mg/kg 12.012.2 99 80-120 Nickel mg/kg 12.512.2 102 80-120 Potassium mg/kg 614610 101 80-120 Sodium mg/kg 640610 105 80-120 Strontium mg/kg 12.412.2 101 80-120 Zinc mg/kg 62.061 102 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 63 of 88 83 of 109 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245618 J15040323 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1190237MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245637001 1190238 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum mg/kg M1196295075-1252040 7 20194207002650024700 Barium mg/kg M119.6 -202 75-125-73 6 2019.4462 422 447 Beryllium mg/kg 1.94 89 75-12589 0 201.942.7 4.5 4.5 Boron mg/kg 196 78 75-12583 5 20194ND159167 Calcium mg/kg 976 83 75-12583 0 20970201028202810 Chromium mg/kg M1,R119.6 148 75-12582 24 2019.431.7 60.7 47.7 Copper mg/kg 19.6 81 75-12575 3 2019.440.4 56.3 54.9 Iron mg/kg M1196111075-125-434 10 20194296003180028800 Magnesium mg/kg M197611075-125177 18 20970210031703810 Manganese mg/kg M119.6 221 75-125483 14 2019.4281 324 375 Molybdenum mg/kg 19.6 83 75-12588 4 2019.46.8 23.0 23.9 Nickel mg/kg 19.6 107 75-12598 4 2019.424.1 45.0 43.2 Potassium mg/kg M197612675-125162 8 20970269039204260 Sodium mg/kg 976 94 75-12597 2 20970224J11401160 Strontium mg/kg M119.6 71 75-12544 3 2019.4148 162 157 Zinc mg/kg 97.6 91 75-125103 8 209749.1 138 149 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 64 of 88 84 of 109 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245618 J15040323 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/23717 EPA 3050 EPA 6020 6020 MET SOLID Associated Lab Samples:92245618001, 92245618002, 92245618003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1188473 Associated Lab Samples:92245618001, 92245618002, 92245618003 Matrix:Solid Analyzed Antimony mg/kg ND 0.051 N204/26/15 10:31 Arsenic mg/kg ND 0.051 04/26/15 10:31 Cadmium mg/kg ND 0.0062 04/26/15 10:31 Cobalt mg/kg ND 0.051 04/26/15 10:31 Lead mg/kg ND 0.051 04/26/15 10:31 Selenium mg/kg ND 0.051 04/26/15 10:31 Thallium mg/kg ND 0.051 04/26/15 10:31 Vanadium mg/kg ND 0.051 04/26/15 10:31 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1188474LABORATORY CONTROL SAMPLE: LCSSpike Antimony mg/kg 2.6 N22.6 99 80-120 Arsenic mg/kg 2.72.6 103 80-120 Cadmium mg/kg 0.26.26 99 80-120 Cobalt mg/kg 2.72.6 104 80-120 Lead mg/kg 2.62.6 100 80-120 Selenium mg/kg 2.62.6 99 80-120 Thallium mg/kg 2.62.6 101 80-120 Vanadium mg/kg 2.72.6 103 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1188475MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245627003 1188476 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony mg/kg M6,N24.51 381 75-125351 15 204.16ND 17.2 14.8 Arsenic mg/kg M64.51 661 75-125816 8 204.1621.8 51.2 55.5 Cadmium mg/kg M6.451 411 75-125397 8 20.4160.59J 2.4 2.2 Cobalt mg/kg M64.51 500 75-125567 4 204.166.9J 29.1 30.3 Lead mg/kg M64.51 525 75-125594 4 204.16ND 27.4 28.6 Selenium mg/kg M64.51 507 75-125533 2 204.166.9J 29.5 29.0 Thallium mg/kg M64.51 444 75-125450 6 204.16ND 20.6 19.4 Vanadium mg/kg M64.51 650 75-125816 9 204.1620.4 49.4 54.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 65 of 88 85 of 109 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245618 J15040323 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/23747 EPA 3050 EPA 6020 6020 MET SOLID Associated Lab Samples:92245618004, 92245618005, 92245618006, 92245618007, 92245618008, 92245618009, 92245618010, 92245618011, 92245618012, 92245618013 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1190231 Associated Lab Samples:92245618004, 92245618005, 92245618006, 92245618007, 92245618008, 92245618009, 92245618010, 92245618011, 92245618012, 92245618013 Matrix:Solid Analyzed Antimony mg/kg ND 0.050 N204/27/15 14:25 Arsenic mg/kg ND 0.050 04/27/15 14:25 Cadmium mg/kg ND 0.0060 04/27/15 14:25 Cobalt mg/kg ND 0.050 04/27/15 14:25 Lead mg/kg ND 0.050 04/27/15 14:25 Selenium mg/kg ND 0.050 04/27/15 14:25 Thallium mg/kg ND 0.050 04/27/15 14:25 Vanadium mg/kg ND 0.050 04/27/15 14:25 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1190232LABORATORY CONTROL SAMPLE: LCSSpike Antimony mg/kg 2.6 N22.5 103 80-120 Arsenic mg/kg 2.72.5 107 80-120 Cadmium mg/kg 0.26.25 103 80-120 Cobalt mg/kg 2.72.5 105 80-120 Lead mg/kg 2.62.5 102 80-120 Selenium mg/kg 2.72.5 104 80-120 Thallium mg/kg 2.62.5 103 80-120 Vanadium mg/kg 2.72.5 105 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1190235MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245637001 1190236 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony mg/kg M6,N23.88 281 75-125294 4 203.58ND 12.1 11.6 Arsenic mg/kg M63.88 -219 75-125-247 0 203.5871.4 62.9 62.6 Cadmium mg/kg M6.388 379 75-125419 1 20.358ND 1.8 1.8 Cobalt mg/kg M63.88 438 75-125423 6 203.5818.7 35.7 33.8 Lead mg/kg M63.88 439 75-125437 5 203.5816.1 33.1 31.7 Selenium mg/kg M63.88 380 75-125384 4 203.5811.8 26.5 25.4 Thallium mg/kg M63.88 403 75-125419 4 203.58ND 16.5 15.8 Vanadium mg/kg M63.88 410 75-125381 3 203.5854.9 70.8 68.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 66 of 88 86 of 109 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245618 J15040323 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/53712 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92245618014, 92245618015, 92245618016, 92245618017 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1942408 Associated Lab Samples:92245618014, 92245618015, 92245618016, 92245618017 Matrix:Water Analyzed Aluminum ug/L ND 10.0 04/21/15 03:54 Antimony ug/L ND 0.50 04/21/15 03:54 Arsenic ug/L ND 0.50 04/21/15 03:54 Barium ug/L ND 0.30 04/21/15 03:54 Beryllium ug/L ND 0.20 04/21/15 03:54 Boron ug/L ND 5.0 04/21/15 03:54 Cadmium ug/L ND 0.080 04/21/15 03:54 Calcium ug/L ND 40.0 04/21/15 03:54 Chromium ug/L ND 0.50 04/21/15 03:54 Cobalt ug/L ND 0.50 04/21/15 03:54 Copper ug/L ND 1.0 04/21/15 03:54 Iron ug/L ND 50.0 04/21/15 03:54 Lead ug/L ND 0.10 04/21/15 03:54 Magnesium ug/L ND 10.0 04/21/15 03:54 Manganese ug/L ND 0.50 04/21/15 03:54 Molybdenum ug/L ND 0.50 04/21/15 03:54 Nickel ug/L ND 0.50 04/21/15 03:54 Potassium ug/L ND 50.0 04/21/15 03:54 Selenium ug/L ND 0.50 04/21/15 03:54 Sodium ug/L ND 50.0 04/21/15 03:54 Strontium ug/L ND 0.50 04/21/15 03:54 Thallium ug/L ND 0.10 04/21/15 03:54 Vanadium ug/L ND 1.0 04/21/15 03:54 Zinc ug/L ND 5.0 04/21/15 03:54 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1942409LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 75.180 94 80-120 Antimony ug/L 79.880 100 80-120 Arsenic ug/L 78.980 99 80-120 Barium ug/L 78.980 99 80-120 Beryllium ug/L 76.680 96 80-120 Boron ug/L 78.180 98 80-120 Cadmium ug/L 78.480 98 80-120 Calcium ug/L 9081000 91 80-120 Chromium ug/L 78.780 98 80-120 Cobalt ug/L 77.480 97 80-120 Copper ug/L 76.880 96 80-120 Iron ug/L 9831000 98 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 67 of 88 87 of 109 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245618 J15040323 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1942409LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 79.180 99 80-120 Magnesium ug/L 9601000 96 80-120 Manganese ug/L 78.680 98 80-120 Molybdenum ug/L 75.680 95 80-120 Nickel ug/L 80.380 100 80-120 Potassium ug/L 9851000 98 80-120 Selenium ug/L 79.280 99 80-120 Sodium ug/L 9581000 96 80-120 Strontium ug/L 77.480 97 80-120 Thallium ug/L 77.380 97 80-120 Vanadium ug/L 78.880 99 80-120 Zinc ug/L 79.980 100 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1943026MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245612006 1943027 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L 80 105 75-12595 9 2080ND83.9 76.5 Antimony ug/L 80 100 75-125100 0 2080ND79.9 79.8 Arsenic ug/L 80 99 75-125101 2 2080ND78.9 80.7 Barium ug/L 80 100 75-12597 2 2080ND79.7 77.8 Beryllium ug/L 80 95 75-12595 0 2080ND75.7 75.9 Boron ug/L 80 98 75-12594 4 2080ND78.4 75.1 Cadmium ug/L 80 98 75-12598 0 2080ND78.2 78.2 Calcium ug/L 1000 95 75-125104 9 201000ND9561050 Chromium ug/L 80 98 75-12598 1 2080ND78.6 78.1 Cobalt ug/L 80 98 75-12598 0 2080ND78.4 78.3 Copper ug/L M1,R18016275-12598 49 2080ND13078.9 Iron ug/L 1000 97 75-12599 2 201000ND970987 Lead ug/L 80 103 75-12599 4 2080ND82.6 79.2 Magnesium ug/L 1000 96 75-12598 1 201000ND966977 Manganese ug/L 80 99 75-12598 0 2080ND79.1 78.8 Molybdenum ug/L 80 95 75-12594 1 2080ND76.2 75.6 Nickel ug/L 80 102 75-125101 1 2080ND81.8 81.0 Potassium ug/L 1000 97 75-12597 0 201000ND973975 Selenium ug/L 80 101 75-12599 2 2080ND80.5 79.0 Sodium ug/L 1000 98 75-12595 3 201000ND980951 Strontium ug/L 80 97 75-12597 0 2080ND77.5 77.4 Thallium ug/L 80 99 75-12599 0 2080ND79.4 79.1 Vanadium ug/L 80 99 75-12599 1 2080ND79.0 79.6 Zinc ug/L M1,R18014675-12598 39 2080ND11879.7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 68 of 88 88 of 109 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245618 J15040323 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: PMST/3460 ASTM D2974-87 ASTM D2974-87 Dry Weight/Percent Moisture Associated Lab Samples:92245618004, 92245618005, 92245618006, 92245618007, 92245618008, 92245618009, 92245618010, 92245618011, 92245618012, 92245618013 Parameter Units Dup Result Max RPD QualifiersRPDResult 35184153001 1189490SAMPLE DUPLICATE: Percent Moisture %12.6 2 1012.9 Parameter Units Dup Result Max RPD QualifiersRPDResult 92245618011 1189494SAMPLE DUPLICATE: Percent Moisture %24.5 7 1026.2 Parameter Units Dup Result Max RPD QualifiersRPDResult 92245612008 1189495SAMPLE DUPLICATE: Percent Moisture %39.0 0 1039.2 Parameter Units Dup Result Max RPD QualifiersRPDResult 92245612019 1189496SAMPLE DUPLICATE: Percent Moisture %36.7 5 1038.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 69 of 88 89 of 109 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245618 J15040323 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: PMST/3479 ASTM D2974-87 ASTM D2974-87 Dry Weight/Percent Moisture Associated Lab Samples:92245618001, 92245618002, 92245618003 Parameter Units Dup Result Max RPD QualifiersRPDResult 92245394016 1192377SAMPLE DUPLICATE: Percent Moisture %20.4 5 1019.3 Parameter Units Dup Result Max RPD QualifiersRPDResult 35184321009 1192394SAMPLE DUPLICATE: Percent Moisture %2.8 D619102.3 Parameter Units Dup Result Max RPD QualifiersRPDResult 92245627011 1192395SAMPLE DUPLICATE: Percent Moisture %42.5 6 1040.1 Parameter Units Dup Result Max RPD QualifiersRPDResult 35184455005 1192396SAMPLE DUPLICATE: Percent Moisture %6.7 8 106.2 Parameter Units Dup Result Max RPD QualifiersRPDResult 35184857004 1192397SAMPLE DUPLICATE: Percent Moisture %20.8 3 1021.5 Parameter Units Dup Result Max RPD QualifiersRPDResult 35184857008 1192398SAMPLE DUPLICATE: Percent Moisture %19.9 5 1019.0 Parameter Units Dup Result Max RPD QualifiersRPDResult 35184308001 1192399SAMPLE DUPLICATE: Percent Moisture %75.8 2 1074.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 70 of 88 90 of 109 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245618 J15040323 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/36878 EPA 9045 EPA 9045 9045 pH Associated Lab Samples:92245618003, 92245618004, 92245618009, 92245618010 Parameter Units Dup Result Max RPD QualifiersRPDResult 92245618009 1436453SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 4.9 H31105.0 Parameter Units Dup Result Max RPD QualifiersRPDResult 92245612008 1436454SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 5.8 H32105.7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 71 of 88 91 of 109 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245618 J15040323 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/36942 EPA 9045 EPA 9045 9045 pH Associated Lab Samples:92245618001, 92245618002, 92245618005, 92245618006, 92245618007, 92245618008, 92245618011, 92245618012, 92245618013 Parameter Units Dup Result Max RPD QualifiersRPDResult 92245612013 1438600SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 6.6 0 106.6 Parameter Units Dup Result Max RPD QualifiersRPDResult 92245627004 1438601SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 6.6 0 106.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 72 of 88 92 of 109 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245618 J15040323 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/45554 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92245618001, 92245618002, 92245618003, 92245618004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1188148 Associated Lab Samples: Matrix:Solid Analyzed Chloride mg/kg ND 49.3 04/19/15 18:54 Sulfate mg/kg ND 49.3 04/19/15 18:54 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1188149LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/kg 488501 97 80-120 Sulfate mg/kg 487501 97 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1188151MATRIX SPIKE SAMPLE: MSSpike Result 92245612001 Chloride mg/kg 620655 95 80-120ND Sulfate mg/kg 639655 85 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92245612001 1188150SAMPLE DUPLICATE: Chloride mg/kg ND 20ND Sulfate mg/kg ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 73 of 88 93 of 109 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245618 J15040323 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/45556 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92245618005, 92245618006, 92245618007, 92245618008, 92245618009, 92245618010, 92245618011, 92245618012, 92245618013 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1188156 Associated Lab Samples: Matrix:Solid Analyzed Chloride mg/kg ND 49.6 04/20/15 04:53 Sulfate mg/kg ND 49.6 04/20/15 04:53 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1188157LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/kg 470496 95 80-120 Sulfate mg/kg 469496 95 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1188159MATRIX SPIKE SAMPLE: MSSpike Result 92245618005 Chloride mg/kg 657689 95 80-120ND Sulfate mg/kg 688689 100 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92245618005 1188158SAMPLE DUPLICATE: Chloride mg/kg ND 20ND Sulfate mg/kg ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 74 of 88 94 of 109 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245618 J15040323 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/45553 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92245618001, 92245618002, 92245618003, 92245618004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1188144 Associated Lab Samples: Matrix:Solid Analyzed Nitrate as N mg/kg ND 4.9 04/19/15 18:54 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1188145LABORATORY CONTROL SAMPLE: LCSSpike Nitrate as N mg/kg 51.550.1 103 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1188147MATRIX SPIKE SAMPLE: MSSpike Result 92245612001 Nitrate as N mg/kg 65.2 H365.5 100 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92245612001 1188146SAMPLE DUPLICATE: Nitrate as N mg/kg ND H320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 75 of 88 95 of 109 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245618 J15040323 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/45555 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92245618005, 92245618006, 92245618007, 92245618008, 92245618009, 92245618010, 92245618011, 92245618012, 92245618013 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1188152 Associated Lab Samples: Matrix:Solid Analyzed Nitrate as N mg/kg ND 5.0 04/20/15 04:53 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1188153LABORATORY CONTROL SAMPLE: LCSSpike Nitrate as N mg/kg 48.649.6 98 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1188155MATRIX SPIKE SAMPLE: MSSpike Result 92245618005 Nitrate as N mg/kg 66.2 H368.9 96 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92245618005 1188154SAMPLE DUPLICATE: Nitrate as N mg/kg ND H320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 76 of 88 96 of 109 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245618 J15040323 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/28220 EPA 9060 EPA 9060 9060 TOC Average Associated Lab Samples:92245618009, 92245618010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1147912 Associated Lab Samples: Matrix:Solid Analyzed Mean Total Organic Carbon mg/kg ND 600 04/28/15 08:25 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1147913LABORATORY CONTROL SAMPLE: LCSSpike Mean Total Organic Carbon mg/kg 127000120000 105 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1147914MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245084005 1147915 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 65000 102 50-15078 11 306480087800154000138000 Parameter Units MS Result % Rec Limits Qual% RecConc. 1147916MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245128004 1147917 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 6660 114 50-150119 3 30667037801140011800 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 77 of 88 97 of 109 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245618 J15040323 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/28242 EPA 9060 EPA 9060 9060 TOC Average Associated Lab Samples:92245618001, 92245618002, 92245618003, 92245618004, 92245618005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1148472 Associated Lab Samples: Matrix:Solid Analyzed Mean Total Organic Carbon mg/kg ND 600 04/30/15 06:14 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1148473LABORATORY CONTROL SAMPLE: LCSSpike Mean Total Organic Carbon mg/kg 113000120000 94 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1148474MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245618001 1148475 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 7440 82 50-15086 6 307480ND64106770 Parameter Units MS Result % Rec Limits Qual% RecConc. 1148476MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245394008 1148477 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 102000 81 50-150103 13 3010500098600181000207000 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 78 of 88 98 of 109 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245618 J15040323 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/28320 EPA 9060 EPA 9060 9060 TOC Average Associated Lab Samples:92245618006, 92245618007, 92245618008, 92245618011, 92245618012 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1151702 Associated Lab Samples: Matrix:Solid Analyzed Mean Total Organic Carbon mg/kg ND 600 05/06/15 13:21 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1151703LABORATORY CONTROL SAMPLE: LCSSpike Mean Total Organic Carbon mg/kg 125000120000 104 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1151704MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245627003 1151705 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 91000 114 50-150111 1 3091700104000208000206000 Parameter Units MS Result % Rec Limits Qual% RecConc. 1151706MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245627004 1151707 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 65500 118 50-15090 13 306440082900160000141000 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 79 of 88 99 of 109 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92245618 J15040323 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/28413 EPA 9060 EPA 9060 9060 TOC Average Associated Lab Samples:92245618013 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1154316 Associated Lab Samples: Matrix:Solid Analyzed Mean Total Organic Carbon mg/kg ND 600 05/11/15 09:53 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1154317LABORATORY CONTROL SAMPLE: LCSSpike Mean Total Organic Carbon mg/kg 118000120000 99 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1154318MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245627013 1154319 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 74100 79 50-150118 12 3074500175000234000263000 Parameter Units MS Result % Rec Limits Qual% RecConc. 1154320MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92247019006 1154321 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 6950 81 50-15080 1 306920524J61306060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 80 of 88 100 of 109 #=QL# QUALIFIERS Pace Project No.: Project: 92245618 J15040323 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - Green BayPASI-G Pace Analytical Services - MinneapolisPASI-M Pace Analytical Services - Ormond BeachPASI-O BATCH QUALIFIERS Batch: ICP/14506 Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.[1] Batch: ICPM/9649 Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.[1] Batch: ICP/14514 Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.[1] ANALYTE QUALIFIERS Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6 Sample was received or analysis requested beyond the recognized method holding time.H3 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 81 of 88 101 of 109 #=QL# QUALIFIERS Pace Project No.: Project: 92245618 J15040323 ANALYTE QUALIFIERS Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6 The lab does not hold TNI accreditation for this parameter.N2 Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit.P8 RPD value was outside control limits.R1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 82 of 88 102 of 109 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92245618 J15040323 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92245618001 MPRP/23716 ICP/145062015010704EPA 3050 EPA 6010 92245618002 MPRP/23716 ICP/145062015010719EPA 3050 EPA 6010 92245618003 MPRP/23716 ICP/145062015010720EPA 3050 EPA 6010 92245618004 MPRP/23746 ICP/145142015010721EPA 3050 EPA 6010 92245618005 MPRP/23746 ICP/145142015010722EPA 3050 EPA 6010 92245618006 MPRP/23746 ICP/145142015010723EPA 3050 EPA 6010 92245618007 MPRP/23746 ICP/145142015010724EPA 3050 EPA 6010 92245618008 MPRP/23746 ICP/145142015010725EPA 3050 EPA 6010 92245618009 MPRP/23746 ICP/145142015010726EPA 3050 EPA 6010 92245618010 MPRP/23746 ICP/145142015010727EPA 3050 EPA 6010 92245618011 MPRP/23746 ICP/145142015010728EPA 3050 EPA 6010 92245618012 MPRP/23746 ICP/145142015010729EPA 3050 EPA 6010 92245618013 MPRP/23746 ICP/145142015010730EPA 3050 EPA 6010 92245618001 MPRP/23717 ICPM/96492015010704EPA 3050 EPA 6020 92245618002 MPRP/23717 ICPM/96492015010719EPA 3050 EPA 6020 92245618003 MPRP/23717 ICPM/96492015010720EPA 3050 EPA 6020 92245618004 MPRP/23747 ICPM/96542015010721EPA 3050 EPA 6020 92245618005 MPRP/23747 ICPM/96542015010722EPA 3050 EPA 6020 92245618006 MPRP/23747 ICPM/96542015010723EPA 3050 EPA 6020 92245618007 MPRP/23747 ICPM/96542015010724EPA 3050 EPA 6020 92245618008 MPRP/23747 ICPM/96542015010725EPA 3050 EPA 6020 92245618009 MPRP/23747 ICPM/96542015010726EPA 3050 EPA 6020 92245618010 MPRP/23747 ICPM/96542015010727EPA 3050 EPA 6020 92245618011 MPRP/23747 ICPM/96542015010728EPA 3050 EPA 6020 92245618012 MPRP/23747 ICPM/96542015010729EPA 3050 EPA 6020 92245618013 MPRP/23747 ICPM/96542015010730EPA 3050 EPA 6020 92245618014 MPRP/53712 ICPM/238552015010731EPA 3020 EPA 6020A 92245618015 MPRP/53712 ICPM/238552015010732EPA 3020 EPA 6020A 92245618016 MPRP/53712 ICPM/238552015010733EPA 3020 EPA 6020A 92245618017 MPRP/53712 ICPM/238552015010734EPA 3020 EPA 6020A 92245618014 MERP/13265 MERC/154392015010731EPA 7470 EPA 7470 92245618015 MERP/13265 MERC/154392015010732EPA 7470 EPA 7470 92245618016 MERP/13265 MERC/154392015010733EPA 7470 EPA 7470 92245618017 MERP/13265 MERC/154392015010734EPA 7470 EPA 7470 92245618001 MERP/5618 MERC/56152015010704EPA 7471 EPA 7471 92245618002 MERP/5615 MERC/56112015010719EPA 7471 EPA 7471 92245618003 MERP/5615 MERC/56112015010720EPA 7471 EPA 7471 92245618004 MERP/5615 MERC/56112015010721EPA 7471 EPA 7471 92245618005 MERP/5615 MERC/56112015010722EPA 7471 EPA 7471 92245618006 MERP/5615 MERC/56112015010723EPA 7471 EPA 7471 92245618007 MERP/5615 MERC/56112015010724EPA 7471 EPA 7471 92245618008 MERP/5615 MERC/56112015010725EPA 7471 EPA 7471 92245618009 MERP/5615 MERC/56112015010726EPA 7471 EPA 7471 92245618010 MERP/5615 MERC/56112015010727EPA 7471 EPA 7471 92245618011 MERP/5615 MERC/56112015010728EPA 7471 EPA 7471 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 83 of 88 103 of 109 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92245618 J15040323 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92245618012 MERP/5615 MERC/56112015010729EPA 7471 EPA 7471 92245618013 MERP/5615 MERC/56112015010730EPA 7471 EPA 7471 92245618001 PMST/34792015010704ASTM D2974-87 92245618002 PMST/34792015010719ASTM D2974-87 92245618003 PMST/34792015010720ASTM D2974-87 92245618004 PMST/34602015010721ASTM D2974-87 92245618005 PMST/34602015010722ASTM D2974-87 92245618006 PMST/34602015010723ASTM D2974-87 92245618007 PMST/34602015010724ASTM D2974-87 92245618008 PMST/34602015010725ASTM D2974-87 92245618009 PMST/34602015010726ASTM D2974-87 92245618010 PMST/34602015010727ASTM D2974-87 92245618011 PMST/34602015010728ASTM D2974-87 92245618012 PMST/34602015010729ASTM D2974-87 92245618013 PMST/34602015010730ASTM D2974-87 92245618001 WET/369422015010704EPA 9045 92245618002 WET/369422015010719EPA 9045 92245618003 WET/368782015010720EPA 9045 92245618004 WET/368782015010721EPA 9045 92245618005 WET/369422015010722EPA 9045 92245618006 WET/369422015010723EPA 9045 92245618007 WET/369422015010724EPA 9045 92245618008 WET/369422015010725EPA 9045 92245618009 WET/368782015010726EPA 9045 92245618010 WET/368782015010727EPA 9045 92245618011 WET/369422015010728EPA 9045 92245618012 WET/369422015010729EPA 9045 92245618013 WET/369422015010730EPA 9045 92245618001 WETA/455542015010704EPA 9056 92245618002 WETA/455542015010719EPA 9056 92245618003 WETA/455542015010720EPA 9056 92245618004 WETA/455542015010721EPA 9056 92245618005 WETA/455562015010722EPA 9056 92245618006 WETA/455562015010723EPA 9056 92245618007 WETA/455562015010724EPA 9056 92245618008 WETA/455562015010725EPA 9056 92245618009 WETA/455562015010726EPA 9056 92245618010 WETA/455562015010727EPA 9056 92245618011 WETA/455562015010728EPA 9056 92245618012 WETA/455562015010729EPA 9056 92245618013 WETA/455562015010730EPA 9056 92245618001 WETA/455532015010704EPA 9056 92245618002 WETA/455532015010719EPA 9056 92245618003 WETA/455532015010720EPA 9056 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 84 of 88 104 of 109 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92245618 J15040323 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92245618004 WETA/455532015010721EPA 9056 92245618005 WETA/455552015010722EPA 9056 92245618006 WETA/455552015010723EPA 9056 92245618007 WETA/455552015010724EPA 9056 92245618008 WETA/455552015010725EPA 9056 92245618009 WETA/455552015010726EPA 9056 92245618010 WETA/455552015010727EPA 9056 92245618011 WETA/455552015010728EPA 9056 92245618012 WETA/455552015010729EPA 9056 92245618013 WETA/455552015010730EPA 9056 92245618001 WETA/282422015010704EPA 9060 92245618001 WETA/282432015010704EPA 9060 92245618002 WETA/282422015010719EPA 9060 92245618002 WETA/282432015010719EPA 9060 92245618003 WETA/282422015010720EPA 9060 92245618003 WETA/282432015010720EPA 9060 92245618004 WETA/282422015010721EPA 9060 92245618004 WETA/282432015010721EPA 9060 92245618005 WETA/282422015010722EPA 9060 92245618005 WETA/282432015010722EPA 9060 92245618006 WETA/283202015010723EPA 9060 92245618006 WETA/283212015010723EPA 9060 92245618007 WETA/283202015010724EPA 9060 92245618007 WETA/283212015010724EPA 9060 92245618008 WETA/283202015010725EPA 9060 92245618008 WETA/283212015010725EPA 9060 92245618009 WETA/282202015010726EPA 9060 92245618009 WETA/282212015010726EPA 9060 92245618010 WETA/282202015010727EPA 9060 92245618010 WETA/282212015010727EPA 9060 92245618011 WETA/283202015010728EPA 9060 92245618011 WETA/283212015010728EPA 9060 92245618012 WETA/283202015010729EPA 9060 92245618012 WETA/283212015010729EPA 9060 92245618013 WETA/284132015010730EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 85 of 88 105 of 109 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92245618 J15040323 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92245618013 WETA/284142015010730EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 05/12/2015 06:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 86 of 88 106 of 109 Page 87 of 88 107 of 109 Page 88 of 88 108 of 109 109 of 109