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HomeMy WebLinkAboutNC0001422_ATT 5 - Soil - J15040002 Report_2015080513339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number: J15040002 Project Name:SUTTON - AB GW ASSESSMENT SOIL Lab Contact:Margaret Galvin-Karr Date:6/17/2015 Customer Address: Customer Name(s):Perry Waldrep, Tim Hunsucker, Kathy Webb, John Toepfer Phone: 980-875-5219 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Margaret Galvin-Karr) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Margaret Galvin-Karr 1 of 82 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015009196 Sutton 28-Mar-15 10:00 AM ILLEGIBLE Well AB-2 53-55' 2015009197 Sutton 28-Mar-15 4:00 PM ILLEGIBLE Well AB-1 3-5' 2015009198 Sutton 28-Mar-15 7:00 PM ILLEGIBLE Well AB-1 82-84' 2015009199 Sutton 28-Mar-15 6:45 PM ILLEGIBLE Well AB-1 78-80' 2015009200 Sutton 28-Mar-15 6:00 PM ILLEGIBLE Well AB-1 43-45' 2015009201 Sutton 29-Mar-15 6:30 PM ILLEGIBLE Well AB-1 96-98' 2015009202 Sutton 27-Mar-15 2:50 PM ILLEGIBLE Well AB-2 Minisonic 7 Total Samples 2 of 82 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By: Date: Electronic Data Deliverable (EDD) Sent Separately 3 of 82 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040002 2015009196 Collection Date: 28-Mar-15 10:00 AM Site:Well AB-2 53-55' Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 4 of 82 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040002 2015009197 Collection Date: 28-Mar-15 4:00 PM Site:Well AB-1 3-5' Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 5 of 82 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040002 2015009198 Collection Date: 28-Mar-15 7:00 PM Site:Well AB-1 82-84' Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 6 of 82 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040002 2015009199 Collection Date: 28-Mar-15 6:45 PM Site:Well AB-1 78-80' Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 7 of 82 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040002 2015009200 Collection Date: 28-Mar-15 6:00 PM Site:Well AB-1 43-45' Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 8 of 82 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040002 2015009201 Collection Date: 29-Mar-15 6:30 PM Site:Well AB-1 96-98' Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE 9 of 82 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040002 2015009202 Collection Date: 27-Mar-15 2:50 PM Site:Well AB-2 Minisonic Matrix: SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP sulfate blank shows 2.8 mg/L. Associated samples are less than 10 times thae concentration in the blank so results may be suspect. RPD for % moisture for 2015009199 is19% RPD outside the acceptance range of 10%. SPLP mercury for 2015009200 run outside of hold time. MG-K 6/17/15 -- Additional Information -- 10 of 82 #=CL# June 16, 2015 LIMS USE: FR - PROGRAM MANAGER LIMS OBJECT ID: 92243759 92243759 Project: Pace Project No.: RE: Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 J15040002 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on April 01, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc:Marge Galvin-Karr, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Rodney Wike, Duke Energy REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 71 11 of 82 #=CP# CERTIFICATIONS Pace Project No.: Project: 92243759 J15040002 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A2LA Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA #: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 71 12 of 82 #=CP# CERTIFICATIONS Pace Project No.: Project: 92243759 J15040002 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 71 13 of 82 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92243759 J15040002 Lab ID Sample ID Matrix Date Collected Date Received 92243759001 2015009196 Solid 03/28/15 10:00 04/01/15 17:34 92243759002 2015009198 Solid 03/28/15 19:00 04/01/15 17:34 92243759003 2015009197 Solid 03/28/15 16:00 04/01/15 17:34 92243759004 2015009199 Solid 03/28/15 18:45 04/01/15 17:34 92243759005 2015009201 Solid 03/29/15 18:30 04/01/15 17:34 92243759006 2015009200 Solid 03/28/15 18:00 04/01/15 17:34 92243759007 2015009202 Water 03/27/15 14:50 04/01/15 17:34 92243759008 2015009196 SPLP Water 03/28/15 10:00 04/01/15 17:34 92243759009 2015009198 SPLP Water 03/28/15 19:00 04/01/15 17:34 92243759010 2015009200 Water 03/28/15 18:00 04/01/15 17:34 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 71 14 of 82 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92243759 J15040002 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92243759001 2015009196 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OTAP ASTM D2974-87 1 PASI-OAEM EPA 9045 1 PASI-AMAB EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92243759002 2015009198 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OTAP ASTM D2974-87 1 PASI-OAEM EPA 9045 1 PASI-AMAB EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92243759003 2015009197 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OTAP ASTM D2974-87 1 PASI-OAEM EPA 9045 1 PASI-AMAB EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92243759004 2015009199 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OTAP ASTM D2974-87 1 PASI-OMLO EPA 9045 1 PASI-AMAB EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 71 15 of 82 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92243759 J15040002 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts EPA 9060 6 PASI-GTJJ 92243759005 2015009201 EPA 6010 16 PASI-OCKJ EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OTAP ASTM D2974-87 1 PASI-OAEM EPA 9045 1 PASI-AMAB EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92243759006 2015009200 EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER 92243759007 2015009202 EPA 6020A 24 PASI-MRJS EPA 7470 1 PASI-MDM 92243759008 2015009196 SPLP EPA 6020A 24 PASI-MRJS EPA 7470A 1 PASI-MDM 92243759009 2015009198 SPLP EPA 6020A 24 PASI-MRJS EPA 7470A 1 PASI-MDM 92243759010 2015009200 EPA 6020A 24 PASI-MRJS EPA 7470A 1 PASI-MLMW REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 71 16 of 82 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92243759 J15040002 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92243759001 2015009196 Aluminum 1590 mg/kg 04/11/15 22:02 D334.1EPA 6010 Barium 7.1 mg/kg 04/11/15 22:02 D33.4EPA 6010 Beryllium 0.34J mg/kg 04/11/15 22:02 D30.34EPA 6010 Boron 11.0J mg/kg 04/11/15 22:02 D317.1EPA 6010 Calcium 27300 mg/kg 04/11/15 22:02 D3171EPA 6010 Chromium 12.9 mg/kg 04/11/15 22:02 D31.7EPA 6010 Copper 2.0 mg/kg 04/11/15 22:02 D31.7EPA 6010 Iron 5640 mg/kg 04/11/15 22:02 D313.6EPA 6010 Magnesium 6310 mg/kg 04/11/15 22:02 D3171EPA 6010 Manganese 42.8 mg/kg 04/11/15 22:02 D31.7EPA 6010 Nickel 2.8 mg/kg 04/11/15 22:02 D31.7EPA 6010 Potassium 1160 mg/kg 04/11/15 22:02 D3341EPA 6010 Strontium 60.9 mg/kg 04/11/15 22:02 D33.4EPA 6010 Zinc 16.5 mg/kg 04/11/15 22:02 D36.8EPA 6010 Arsenic 2.0J mg/kg 04/10/15 14:573.4EPA 6020 Lead 1.9J mg/kg 04/10/15 14:573.4EPA 6020 Vanadium 8.3 mg/kg 04/10/15 14:573.4EPA 6020 Percent Moisture 24.2 %04/15/15 14:320.10ASTM D2974-87 pH at 25 Degrees C 8.2 Std. Units 04/08/15 13:150.10EPA 9045 Sulfate 11.7 mg/L 04/15/15 15:35 B2.6EPA 300.0 Chloride 20.7 mg/L 04/15/15 04:156.6SM 4500-Cl-E Total Organic Carbon 1410 mg/kg 04/20/15 17:38794EPA 9060 Total Organic Carbon 1060 mg/kg 04/20/15 17:43787EPA 9060 Total Organic Carbon 1290 mg/kg 04/20/15 17:50784EPA 9060 Total Organic Carbon 1240 mg/kg 04/20/15 17:57800EPA 9060 Mean Total Organic Carbon 1250 mg/kg 04/20/15 17:38791EPA 9060 RSD%11.8 %04/20/15 17:38EPA 9060 92243759002 2015009198 Aluminum 1400 mg/kg 04/11/15 22:06 D334.4EPA 6010 Barium 8.2 mg/kg 04/11/15 22:06 D33.4EPA 6010 Beryllium 0.34J mg/kg 04/11/15 22:06 D30.34EPA 6010 Boron 12.6J mg/kg 04/11/15 22:06 D317.2EPA 6010 Calcium 1950 mg/kg 04/11/15 22:06 D3172EPA 6010 Chromium 11.7 mg/kg 04/11/15 22:06 D31.7EPA 6010 Copper 0.99J mg/kg 04/11/15 22:06 D31.7EPA 6010 Iron 6500 mg/kg 04/11/15 22:06 D313.8EPA 6010 Magnesium 920 mg/kg 04/11/15 22:06 D3172EPA 6010 Manganese 28.9 mg/kg 04/11/15 22:06 D31.7EPA 6010 Nickel 2.5 mg/kg 04/11/15 22:06 D31.7EPA 6010 Potassium 1230 mg/kg 04/11/15 22:06 D3344EPA 6010 Strontium 21.3 mg/kg 04/11/15 22:06 D33.4EPA 6010 Zinc 15.7 mg/kg 04/11/15 22:06 D36.9EPA 6010 Arsenic 3.3J mg/kg 04/10/15 15:003.4EPA 6020 Lead 2.0J mg/kg 04/10/15 15:003.4EPA 6020 Vanadium 7.9 mg/kg 04/10/15 15:003.4EPA 6020 Percent Moisture 26.4 %04/15/15 14:330.10ASTM D2974-87 pH at 25 Degrees C 8.0 Std. Units 04/08/15 13:150.10EPA 9045 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 71 17 of 82 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92243759 J15040002 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92243759002 2015009198 Sulfate 14.0 mg/L 04/15/15 15:48 B2.7EPA 300.0 Chloride 9.6 mg/L 04/15/15 04:176.8SM 4500-Cl-E Total Organic Carbon 1070 mg/kg 04/20/15 18:52815EPA 9060 Total Organic Carbon 1000 mg/kg 04/20/15 18:58818EPA 9060 Total Organic Carbon 1110 mg/kg 04/20/15 19:03816EPA 9060 Total Organic Carbon 1110 mg/kg 04/20/15 19:09810EPA 9060 Mean Total Organic Carbon 1070 mg/kg 04/20/15 18:52815EPA 9060 RSD%4.8 %04/20/15 18:52EPA 9060 92243759003 2015009197 Aluminum 4460 mg/kg 04/11/15 22:10 D333.5EPA 6010 Barium 148 mg/kg 04/11/15 22:10 D33.4EPA 6010 Beryllium 2.1 mg/kg 04/11/15 22:10 D30.34EPA 6010 Boron 8.7J mg/kg 04/11/15 22:10 D316.8EPA 6010 Calcium 997 mg/kg 04/11/15 22:10 D3168EPA 6010 Chromium 11.8 mg/kg 04/11/15 22:10 D31.7EPA 6010 Copper 25.3 mg/kg 04/11/15 22:10 D31.7EPA 6010 Iron 9590 mg/kg 04/11/15 22:10 D313.4EPA 6010 Magnesium 383 mg/kg 04/11/15 22:10 D3168EPA 6010 Manganese 35.2 mg/kg 04/11/15 22:10 D31.7EPA 6010 Molybdenum 4.0 mg/kg 04/11/15 22:10 D33.4EPA 6010 Nickel 13.0 mg/kg 04/11/15 22:10 D31.7EPA 6010 Potassium 826 mg/kg 04/11/15 22:10 D3335EPA 6010 Strontium 66.7 mg/kg 04/11/15 22:10 D33.4EPA 6010 Zinc 13.2 mg/kg 04/11/15 22:10 D36.7EPA 6010 Arsenic 22.1 mg/kg 04/10/15 15:023.4EPA 6020 Cobalt 6.7 mg/kg 04/10/15 15:023.4EPA 6020 Lead 8.6 mg/kg 04/10/15 15:023.4EPA 6020 Selenium 10.1 mg/kg 04/10/15 15:023.4EPA 6020 Vanadium 34.4 mg/kg 04/10/15 15:023.4EPA 6020 Mercury 0.16 mg/kg 04/09/15 10:430.011EPA 7471 Percent Moisture 26.6 %04/15/15 14:350.10ASTM D2974-87 pH at 25 Degrees C 6.6 Std. Units 04/08/15 13:150.10EPA 9045 Total Organic Carbon 142000 mg/kg 04/20/15 08:4212100EPA 9060 Total Organic Carbon 148000 mg/kg 04/20/15 08:4911300EPA 9060 Total Organic Carbon 152000 mg/kg 04/20/15 08:5511600EPA 9060 Total Organic Carbon 139000 mg/kg 04/20/15 09:0110900EPA 9060 Mean Total Organic Carbon 145000 mg/kg 04/20/15 08:4211500EPA 9060 RSD%3.9 %04/20/15 08:42EPA 9060 92243759004 2015009199 Aluminum 3370 mg/kg 04/11/15 22:14 D327.7EPA 6010 Barium 92.9 mg/kg 04/11/15 22:14 D32.8EPA 6010 Beryllium 0.62 mg/kg 04/11/15 22:14 D30.28EPA 6010 Boron 7.2J mg/kg 04/11/15 22:14 D313.9EPA 6010 Calcium 722 mg/kg 04/11/15 22:14 D3139EPA 6010 Chromium 7.1 mg/kg 04/11/15 22:14 D31.4EPA 6010 Copper 8.4 mg/kg 04/11/15 22:14 D31.4EPA 6010 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 71 18 of 82 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92243759 J15040002 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92243759004 2015009199 Iron 5110 mg/kg 04/11/15 22:14 D311.1EPA 6010 Magnesium 285 mg/kg 04/11/15 22:14 D3139EPA 6010 Manganese 24.2 mg/kg 04/11/15 22:14 D31.4EPA 6010 Molybdenum 3.2 mg/kg 04/11/15 22:14 D32.8EPA 6010 Nickel 5.0 mg/kg 04/11/15 22:14 D31.4EPA 6010 Potassium 469 mg/kg 04/11/15 22:14 D3277EPA 6010 Strontium 57.9 mg/kg 04/11/15 22:14 D32.8EPA 6010 Zinc 8.2 mg/kg 04/11/15 22:14 D35.5EPA 6010 Arsenic 16.8 mg/kg 04/10/15 15:042.8EPA 6020 Cobalt 2.5J mg/kg 04/10/15 15:042.8EPA 6020 Lead 3.6 mg/kg 04/10/15 15:042.8EPA 6020 Vanadium 15.7 mg/kg 04/10/15 15:042.8EPA 6020 Mercury 0.015 mg/kg 04/09/15 10:450.0086EPA 7471 Percent Moisture 9.9 %04/16/15 10:51 D60.10ASTM D2974-87 pH at 25 Degrees C 8.3 Std. Units 04/08/15 13:150.10EPA 9045 Total Organic Carbon 8080 mg/kg 04/20/15 09:085710EPA 9060 Total Organic Carbon 6680 mg/kg 04/20/15 09:135490EPA 9060 Total Organic Carbon 7670 mg/kg 04/20/15 09:205430EPA 9060 Total Organic Carbon 6070 mg/kg 04/20/15 09:255410EPA 9060 Mean Total Organic Carbon 7130 mg/kg 04/20/15 09:085510EPA 9060 RSD%12.9 %04/20/15 09:08EPA 9060 92243759005 2015009201 Aluminum 1640 mg/kg 04/11/15 22:18 D333.4EPA 6010 Barium 5.7 mg/kg 04/11/15 22:18 D33.3EPA 6010 Beryllium 0.34 mg/kg 04/11/15 22:18 D30.33EPA 6010 Boron 12.5J mg/kg 04/11/15 22:18 D316.7EPA 6010 Calcium 18800 mg/kg 04/11/15 22:18 D3167EPA 6010 Chromium 14.1 mg/kg 04/11/15 22:18 D31.7EPA 6010 Copper 1.2J mg/kg 04/11/15 22:18 D31.7EPA 6010 Iron 6050 mg/kg 04/11/15 22:18 D313.4EPA 6010 Magnesium 6020 mg/kg 04/11/15 22:18 D3167EPA 6010 Manganese 39.3 mg/kg 04/11/15 22:18 D31.7EPA 6010 Nickel 2.9 mg/kg 04/11/15 22:18 D31.7EPA 6010 Potassium 1240 mg/kg 04/11/15 22:18 D3334EPA 6010 Sodium 174J mg/kg 04/11/15 22:18 D3334EPA 6010 Strontium 36.3 mg/kg 04/11/15 22:18 D33.3EPA 6010 Zinc 18.0 mg/kg 04/11/15 22:18 D36.7EPA 6010 Arsenic 2.1J mg/kg 04/10/15 15:063.3EPA 6020 Lead 2.1J mg/kg 04/10/15 15:063.3EPA 6020 Vanadium 8.8 mg/kg 04/10/15 15:063.3EPA 6020 Percent Moisture 25.9 %04/15/15 14:380.10ASTM D2974-87 pH at 25 Degrees C 7.7 Std. Units 04/08/15 13:150.10EPA 9045 Total Organic Carbon 1520 mg/kg 04/21/15 10:47816EPA 9060 Total Organic Carbon 1470 mg/kg 04/21/15 10:53812EPA 9060 Total Organic Carbon 1580 mg/kg 04/21/15 10:58811EPA 9060 Total Organic Carbon 1640 mg/kg 04/21/15 11:05813EPA 9060 Mean Total Organic Carbon 1550 mg/kg 04/21/15 10:47813EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 71 19 of 82 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92243759 J15040002 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92243759005 2015009201 RSD%4.7 %04/21/15 10:47EPA 9060 92243759006 2015009200 Sulfate 17.2 mg/L 04/15/15 16:02 B2.0EPA 300.0 92243759007 2015009202 Calcium 134 ug/L 04/08/15 16:2540.0EPA 6020A Magnesium 11.0 ug/L 04/08/15 16:2510.0EPA 6020A Sodium 62.9 ug/L 04/08/15 16:2550.0EPA 6020A Zinc 5.5 ug/L 04/08/15 16:255.0EPA 6020A 92243759008 2015009196 SPLP Aluminum 687 ug/L 04/24/15 20:4210.0EPA 6020A Arsenic 0.61 ug/L 04/24/15 20:420.50EPA 6020A Barium 123 ug/L 04/24/15 20:420.30EPA 6020A Beryllium 0.096J ug/L 04/24/15 20:420.20EPA 6020A Boron 50.6 ug/L 04/27/15 14:25 B25.0EPA 6020A Cadmium 0.088 ug/L 04/24/15 20:420.080EPA 6020A Calcium 20200 ug/L 04/24/15 20:4240.0EPA 6020A Chromium 4.0 ug/L 04/24/15 20:420.50EPA 6020A Cobalt 0.18J ug/L 04/24/15 20:420.50EPA 6020A Copper 0.27J ug/L 04/24/15 20:421.0EPA 6020A Iron 550 ug/L 04/24/15 20:4250.0EPA 6020A Lead 0.29 ug/L 04/24/15 20:420.10EPA 6020A Magnesium 1100 ug/L 04/24/15 20:4210.0EPA 6020A Manganese 7.2 ug/L 04/24/15 20:420.50EPA 6020A Molybdenum 3.3 ug/L 04/24/15 20:420.50EPA 6020A Nickel 0.98 ug/L 04/24/15 20:420.50EPA 6020A Potassium 831 ug/L 04/24/15 20:4250.0EPA 6020A Selenium 0.28J ug/L 04/24/15 20:420.50EPA 6020A Sodium 2270 ug/L 04/24/15 20:4250.0EPA 6020A Strontium 60.6 ug/L 04/24/15 20:420.50EPA 6020A Thallium 0.078J ug/L 04/24/15 20:42 B0.10EPA 6020A Vanadium 2.1 ug/L 04/24/15 20:421.0EPA 6020A Zinc 20.5 ug/L 04/24/15 20:425.0EPA 6020A 92243759009 2015009198 SPLP Aluminum 3970 ug/L 04/24/15 21:1110.0EPA 6020A Arsenic 7.2 ug/L 04/24/15 21:110.50EPA 6020A Barium 153 ug/L 04/24/15 21:110.30EPA 6020A Beryllium 0.57 ug/L 04/27/15 13:570.40EPA 6020A Boron 120 ug/L 04/27/15 13:5710.0EPA 6020A Cadmium 0.33 ug/L 04/24/15 21:110.080EPA 6020A Calcium 12000 ug/L 04/24/15 21:1140.0EPA 6020A Chromium 25.4 ug/L 04/24/15 21:110.50EPA 6020A Cobalt 0.84 ug/L 04/24/15 21:110.50EPA 6020A Copper 0.79J ug/L 04/24/15 21:111.0EPA 6020A Iron 5670 ug/L 04/24/15 21:1150.0EPA 6020A Lead 0.86 ug/L 04/24/15 21:110.10EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 71 20 of 82 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92243759 J15040002 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92243759009 2015009198 SPLP Magnesium 2470 ug/L 04/24/15 21:1110.0EPA 6020A Manganese 33.6 ug/L 04/24/15 21:110.50EPA 6020A Molybdenum 6.9 ug/L 04/24/15 21:110.50EPA 6020A Nickel 3.4 ug/L 04/24/15 21:110.50EPA 6020A Potassium 2660 ug/L 04/24/15 21:1150.0EPA 6020A Selenium 2.3 ug/L 04/24/15 21:110.50EPA 6020A Sodium 1810 ug/L 04/24/15 21:1150.0EPA 6020A Strontium 262 ug/L 04/24/15 21:110.50EPA 6020A Thallium 0.037J ug/L 04/24/15 21:11 B0.10EPA 6020A Vanadium 14.3 ug/L 04/24/15 21:111.0EPA 6020A Zinc 79.2 ug/L 04/24/15 21:115.0EPA 6020A 92243759010 2015009200 Aluminum 7.8J ug/L 06/04/15 12:0810.0EPA 6020A Antimony 0.47J ug/L 06/04/15 12:080.50EPA 6020A Arsenic 3.6 ug/L 06/04/15 12:080.50EPA 6020A Barium 190 ug/L 06/04/15 12:080.30EPA 6020A Boron 36.4 ug/L 06/04/15 12:085.0EPA 6020A Calcium 6510 ug/L 06/04/15 12:0840.0EPA 6020A Chromium 0.59 ug/L 06/04/15 12:080.50EPA 6020A Copper 0.48J ug/L 06/04/15 12:081.0EPA 6020A Magnesium 894 ug/L 06/04/15 12:0810.0EPA 6020A Manganese 27.6 ug/L 06/04/15 12:080.50EPA 6020A Molybdenum 3.6 ug/L 06/04/15 12:080.50EPA 6020A Nickel 1.0 ug/L 06/04/15 12:080.50EPA 6020A Potassium 858 ug/L 06/04/15 12:0850.0EPA 6020A Selenium 1.9 ug/L 06/04/15 12:080.50EPA 6020A Sodium 1400 ug/L 06/04/15 12:0850.0EPA 6020A Strontium 98.2 ug/L 06/04/15 12:080.50EPA 6020A Zinc 27.0 ug/L 06/04/15 12:085.0EPA 6020A Mercury 0.20 ug/L 06/02/15 17:50 B,H30.20EPA 7470A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 71 21 of 82 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243759 J15040002 Method: Client:Duke Energy EPA 6010 Date:June 16, 2015 Description:6010 MET ICP General Information: 5 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23485 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92243393007 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1176764) • Aluminum • Iron • MSD (Lab ID: 1176765) • Aluminum • Iron Additional Comments: Analyte Comments: QC Batch: MPRP/23485 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015009196 (Lab ID: 92243759001) • Aluminum • Boron • Barium • Beryllium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 71 22 of 82 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243759 J15040002 Method: Client:Duke Energy EPA 6010 Date:June 16, 2015 Description:6010 MET ICP Analyte Comments: QC Batch: MPRP/23485 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015009196 (Lab ID: 92243759001) • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc • 2015009197 (Lab ID: 92243759003) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc • 2015009198 (Lab ID: 92243759002) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 71 23 of 82 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243759 J15040002 Method: Client:Duke Energy EPA 6010 Date:June 16, 2015 Description:6010 MET ICP Analyte Comments: QC Batch: MPRP/23485 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015009198 (Lab ID: 92243759002) • Sodium • Nickel • Strontium • Zinc • 2015009199 (Lab ID: 92243759004) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc • 2015009201 (Lab ID: 92243759005) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc • MS (Lab ID: 1176764) • Aluminum • Boron • Barium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 71 24 of 82 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243759 J15040002 Method: Client:Duke Energy EPA 6010 Date:June 16, 2015 Description:6010 MET ICP Analyte Comments: QC Batch: MPRP/23485 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • MS (Lab ID: 1176764) • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc • MSD (Lab ID: 1176765) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. • BLANK (Lab ID: 1176762) • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 71 25 of 82 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243759 J15040002 Method: Client:Duke Energy EPA 6020 Date:June 16, 2015 Description:6020 MET ICPMS General Information: 5 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23486 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92243393008 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1176768) • Antimony • Vanadium • MSD (Lab ID: 1176769) • Antimony • Lead • Selenium • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 71 26 of 82 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243759 J15040002 Method: Client:Duke Energy EPA 6020 Date:June 16, 2015 Description:6020 MET ICPMS Analyte Comments: QC Batch: MPRP/23486 N2: The lab does not hold TNI accreditation for this parameter. • 2015009196 (Lab ID: 92243759001) • Antimony • 2015009197 (Lab ID: 92243759003) • Antimony • 2015009198 (Lab ID: 92243759002) • Antimony • 2015009199 (Lab ID: 92243759004) • Antimony • 2015009201 (Lab ID: 92243759005) • Antimony • BLANK (Lab ID: 1176766) • Antimony • LCS (Lab ID: 1176767) • Antimony • MS (Lab ID: 1176768) • Antimony • MSD (Lab ID: 1176769) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 71 27 of 82 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243759 J15040002 Method: Client:Duke Energy EPA 6020A Date:June 16, 2015 Description:6020A MET ICPMS General Information: 4 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: MPRP/53878 B: Analyte was detected in the associated method blank. • BLANK for HBN 351124 [MPRP/538 (Lab ID: 1946943) • Boron • Thallium Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/53405 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10301430001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1932878) • Calcium • Magnesium • Manganese • Sodium • MSD (Lab ID: 1932879) • Aluminum • Calcium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 71 28 of 82 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243759 J15040002 Method: Client:Duke Energy EPA 6020A Date:June 16, 2015 Description:6020A MET ICPMS QC Batch: MPRP/53405 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10301430001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • Magnesium • Manganese • Potassium • Sodium QC Batch: MPRP/53878 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92244129009 R1: RPD value was outside control limits. • MSD (Lab ID: 1946946) • Magnesium Additional Comments: Analyte Comments: QC Batch: MPRP/53405 E: Analyte concentration exceeded the calibration range. The reported result is estimated. • MS (Lab ID: 1932878) • Calcium • MSD (Lab ID: 1932879) • Calcium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 71 29 of 82 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243759 J15040002 Method: Client:Duke Energy EPA 7470 Date:June 16, 2015 Description:7470 Mercury General Information: 1 sample was analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 71 30 of 82 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243759 J15040002 Method: Client:Duke Energy EPA 7470A Date:June 16, 2015 Description:7470A Mercury General Information: 3 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H3: Sample was received or analysis requested beyond the recognized method holding time. • 2015009200 (Lab ID: 92243759010) Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: MERP/13740 B: Analyte was detected in the associated method blank. • BLANK for HBN 357872 [MERP/137 (Lab ID: 1982127) • Mercury Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 71 31 of 82 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243759 J15040002 Method: Client:Duke Energy EPA 7471 Date:June 16, 2015 Description:7471 Mercury General Information: 5 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MERP/5566 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92243393005 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1178140) • Mercury • MSD (Lab ID: 1178141) • Mercury Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 71 32 of 82 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243759 J15040002 Method: Client:Duke Energy EPA 9045 Date:June 16, 2015 Description:9045 pH Soil General Information: 5 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/36682 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1428910) • pH at 25 Degrees C Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 71 33 of 82 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243759 J15040002 Method: Client:Duke Energy EPA 300.0 Date:June 16, 2015 Description:300.0 IC Anions, SPLP General Information: 3 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/22570 B: Analyte was detected in the associated method blank. • BLANK for HBN 259622 [WETA/225 (Lab ID: 1434821) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 71 34 of 82 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243759 J15040002 Method: Client:Duke Energy EPA 353.2 Date:June 16, 2015 Description:353.2 Nitrogen, NO2/NO3, SPLP General Information: 3 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H1: Analysis conducted outside the EPA method holding time. • 2015009196 (Lab ID: 92243759001) • 2015009198 (Lab ID: 92243759002) • 2015009200 (Lab ID: 92243759006) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 71 35 of 82 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243759 J15040002 Method: Client:Duke Energy SM 4500-Cl-E Date:June 16, 2015 Description:4500 Chloride, SPLP General Information: 3 samples were analyzed for SM 4500-Cl-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 71 36 of 82 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243759 J15040002 Method: Client:Duke Energy EPA 9056 Date:June 16, 2015 Description:9056 IC Anions General Information: 5 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/45122 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015009196 (Lab ID: 92243759001) • Chloride • Sulfate • 2015009197 (Lab ID: 92243759003) • Chloride • Sulfate • 2015009198 (Lab ID: 92243759002) • Chloride • Sulfate • 2015009199 (Lab ID: 92243759004) • Chloride • Sulfate • 2015009201 (Lab ID: 92243759005) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 71 37 of 82 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243759 J15040002 Method: Client:Duke Energy EPA 9056 Date:June 16, 2015 Description:9056 IC Anions 48hr General Information: 5 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H3: Sample was received or analysis requested beyond the recognized method holding time. • 2015009196 (Lab ID: 92243759001) • 2015009197 (Lab ID: 92243759003) • 2015009198 (Lab ID: 92243759002) • 2015009199 (Lab ID: 92243759004) • 2015009201 (Lab ID: 92243759005) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 71 38 of 82 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243759 J15040002 Method: Client:Duke Energy EPA 9060 Date:June 16, 2015 Description:Total Organic Carbon Quad General Information: 5 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 71 39 of 82 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243759 J15040002 Sample:2015009196 Lab ID:92243759001 Collected:03/28/15 10:00 Received:04/01/15 17:34 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 1590 mg/kg 04/11/15 22:02 7429-90-5 D304/09/15 05:3034.1 17.1 5 Barium 7.1 mg/kg 04/11/15 22:02 7440-39-3 D304/09/15 05:303.4 1.7 5 Beryllium 0.34J mg/kg 04/11/15 22:02 7440-41-7 D304/09/15 05:300.34 0.17 5 Boron 11.0J mg/kg 04/11/15 22:02 7440-42-8 D304/09/15 05:3017.1 8.5 5 Calcium 27300 mg/kg 04/11/15 22:02 7440-70-2 D304/09/15 05:3017185.3 5 Chromium 12.9 mg/kg 04/11/15 22:02 7440-47-3 D304/09/15 05:301.7 0.85 5 Copper 2.0 mg/kg 04/11/15 22:02 7440-50-8 D304/09/15 05:301.7 0.85 5 Iron 5640 mg/kg 04/11/15 22:02 7439-89-6 D304/09/15 05:3013.6 6.8 5 Magnesium 6310 mg/kg 04/11/15 22:02 7439-95-4 D304/09/15 05:3017185.3 5 Manganese 42.8 mg/kg 04/11/15 22:02 7439-96-5 D304/09/15 05:301.7 0.85 5 Molybdenum ND mg/kg 04/11/15 22:02 7439-98-7 D304/09/15 05:303.4 1.7 5 Nickel 2.8 mg/kg 04/11/15 22:02 7440-02-0 D304/09/15 05:301.7 0.85 5 Potassium 1160 mg/kg 04/11/15 22:02 7440-09-7 D304/09/15 05:303411715 Sodium ND mg/kg 04/11/15 22:02 7440-23-5 D304/09/15 05:303411715 Strontium 60.9 mg/kg 04/11/15 22:02 7440-24-6 D304/09/15 05:303.4 1.7 5 Zinc 16.5 mg/kg 04/11/15 22:02 7440-66-6 D304/09/15 05:306.8 3.4 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/10/15 14:57 7440-36-0 N204/09/15 05:303.4 1.7 50 Arsenic 2.0J mg/kg 04/10/15 14:57 7440-38-204/09/15 05:303.4 1.7 50 Cadmium ND mg/kg 04/10/15 14:57 7440-43-904/09/15 05:300.41 0.20 50 Cobalt ND mg/kg 04/10/15 14:57 7440-48-404/09/15 05:303.4 1.7 50 Lead 1.9J mg/kg 04/10/15 14:57 7439-92-104/09/15 05:303.4 1.7 50 Selenium ND mg/kg 04/10/15 14:57 7782-49-204/09/15 05:303.4 1.7 50 Thallium ND mg/kg 04/10/15 14:57 7440-28-004/09/15 05:303.4 1.7 50 Vanadium 8.3 mg/kg 04/10/15 14:57 7440-62-204/09/15 05:303.4 1.7 50 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/09/15 10:38 7439-97-604/08/15 20:180.010 0.0052 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 24.2 %04/15/15 14:320.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 8.2 Std. Units 04/08/15 13:150.10 0.10 1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/10/15 17:20300.0 IC Anions, SPLP Sulfate 11.7 mg/L 04/15/15 15:35 14808-79-8 B2.6 1.3 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/10/15 17:20353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate ND mg/L 04/15/15 17:09 H10.26 0.26 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 04/10/15 17:204500 Chloride, SPLP Chloride 20.7 mg/L 04/15/15 04:15 16887-00-66.6 3.3 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 71 40 of 82 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243759 J15040002 Sample:2015009196 Lab ID:92243759001 Collected:03/28/15 10:00 Received:04/01/15 17:34 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/05/15 10:22 16887-00-6 D33301655 Sulfate ND mg/kg 04/05/15 10:22 14808-79-8 D33301655 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/05/15 10:22 14797-55-8 H333.0 16.5 5 Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 1410 mg/kg 04/20/15 17:38 7440-44-07943971 Total Organic Carbon 1060 mg/kg 04/20/15 17:43 7440-44-07873941 Total Organic Carbon 1290 mg/kg 04/20/15 17:50 7440-44-07843921 Total Organic Carbon 1240 mg/kg 04/20/15 17:57 7440-44-08004001 Mean Total Organic Carbon 1250 mg/kg 04/20/15 17:38 7440-44-07913961 Surrogates RSD%11.8 %04/20/15 17:381 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 71 41 of 82 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243759 J15040002 Sample:2015009198 Lab ID:92243759002 Collected:03/28/15 19:00 Received:04/01/15 17:34 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 1400 mg/kg 04/11/15 22:06 7429-90-5 D304/09/15 05:3034.4 17.2 5 Barium 8.2 mg/kg 04/11/15 22:06 7440-39-3 D304/09/15 05:303.4 1.7 5 Beryllium 0.34J mg/kg 04/11/15 22:06 7440-41-7 D304/09/15 05:300.34 0.17 5 Boron 12.6J mg/kg 04/11/15 22:06 7440-42-8 D304/09/15 05:3017.2 8.6 5 Calcium 1950 mg/kg 04/11/15 22:06 7440-70-2 D304/09/15 05:3017286.0 5 Chromium 11.7 mg/kg 04/11/15 22:06 7440-47-3 D304/09/15 05:301.7 0.86 5 Copper 0.99J mg/kg 04/11/15 22:06 7440-50-8 D304/09/15 05:301.7 0.86 5 Iron 6500 mg/kg 04/11/15 22:06 7439-89-6 D304/09/15 05:3013.8 6.9 5 Magnesium 920 mg/kg 04/11/15 22:06 7439-95-4 D304/09/15 05:3017286.0 5 Manganese 28.9 mg/kg 04/11/15 22:06 7439-96-5 D304/09/15 05:301.7 0.86 5 Molybdenum ND mg/kg 04/11/15 22:06 7439-98-7 D304/09/15 05:303.4 1.7 5 Nickel 2.5 mg/kg 04/11/15 22:06 7440-02-0 D304/09/15 05:301.7 0.86 5 Potassium 1230 mg/kg 04/11/15 22:06 7440-09-7 D304/09/15 05:303441725 Sodium ND mg/kg 04/11/15 22:06 7440-23-5 D304/09/15 05:303441725 Strontium 21.3 mg/kg 04/11/15 22:06 7440-24-6 D304/09/15 05:303.4 1.7 5 Zinc 15.7 mg/kg 04/11/15 22:06 7440-66-6 D304/09/15 05:306.9 3.4 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/10/15 15:00 7440-36-0 N204/09/15 05:303.4 1.7 50 Arsenic 3.3J mg/kg 04/10/15 15:00 7440-38-204/09/15 05:303.4 1.7 50 Cadmium ND mg/kg 04/10/15 15:00 7440-43-904/09/15 05:300.41 0.21 50 Cobalt ND mg/kg 04/10/15 15:00 7440-48-404/09/15 05:303.4 1.7 50 Lead 2.0J mg/kg 04/10/15 15:00 7439-92-104/09/15 05:303.4 1.7 50 Selenium ND mg/kg 04/10/15 15:00 7782-49-204/09/15 05:303.4 1.7 50 Thallium ND mg/kg 04/10/15 15:00 7440-28-004/09/15 05:303.4 1.7 50 Vanadium 7.9 mg/kg 04/10/15 15:00 7440-62-204/09/15 05:303.4 1.7 50 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/09/15 10:40 7439-97-604/08/15 20:180.011 0.0053 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 26.4 %04/15/15 14:330.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 8.0 Std. Units 04/08/15 13:150.10 0.10 1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/10/15 17:20300.0 IC Anions, SPLP Sulfate 14.0 mg/L 04/15/15 15:48 14808-79-8 B2.7 1.4 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/10/15 17:20353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate ND mg/L 04/15/15 17:17 H10.27 0.27 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 04/10/15 17:204500 Chloride, SPLP Chloride 9.6 mg/L 04/15/15 04:17 16887-00-66.8 3.4 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 71 42 of 82 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243759 J15040002 Sample:2015009198 Lab ID:92243759002 Collected:03/28/15 19:00 Received:04/01/15 17:34 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/05/15 10:43 16887-00-6 D33381695 Sulfate ND mg/kg 04/05/15 10:43 14808-79-8 D33381695 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/05/15 10:43 14797-55-8 H333.8 16.9 5 Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 1070 mg/kg 04/20/15 18:52 7440-44-08154071 Total Organic Carbon 1000 mg/kg 04/20/15 18:58 7440-44-08184091 Total Organic Carbon 1110 mg/kg 04/20/15 19:03 7440-44-08164081 Total Organic Carbon 1110 mg/kg 04/20/15 19:09 7440-44-08104051 Mean Total Organic Carbon 1070 mg/kg 04/20/15 18:52 7440-44-08154071 Surrogates RSD%4.8 %04/20/15 18:521 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 71 43 of 82 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243759 J15040002 Sample:2015009197 Lab ID:92243759003 Collected:03/28/15 16:00 Received:04/01/15 17:34 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 4460 mg/kg 04/11/15 22:10 7429-90-5 D304/09/15 05:3033.5 16.8 5 Barium 148 mg/kg 04/11/15 22:10 7440-39-3 D304/09/15 05:303.4 1.7 5 Beryllium 2.1 mg/kg 04/11/15 22:10 7440-41-7 D304/09/15 05:300.34 0.17 5 Boron 8.7J mg/kg 04/11/15 22:10 7440-42-8 D304/09/15 05:3016.8 8.4 5 Calcium 997 mg/kg 04/11/15 22:10 7440-70-2 D304/09/15 05:3016883.8 5 Chromium 11.8 mg/kg 04/11/15 22:10 7440-47-3 D304/09/15 05:301.7 0.84 5 Copper 25.3 mg/kg 04/11/15 22:10 7440-50-8 D304/09/15 05:301.7 0.84 5 Iron 9590 mg/kg 04/11/15 22:10 7439-89-6 D304/09/15 05:3013.4 6.7 5 Magnesium 383 mg/kg 04/11/15 22:10 7439-95-4 D304/09/15 05:3016883.8 5 Manganese 35.2 mg/kg 04/11/15 22:10 7439-96-5 D304/09/15 05:301.7 0.84 5 Molybdenum 4.0 mg/kg 04/11/15 22:10 7439-98-7 D304/09/15 05:303.4 1.7 5 Nickel 13.0 mg/kg 04/11/15 22:10 7440-02-0 D304/09/15 05:301.7 0.84 5 Potassium 826 mg/kg 04/11/15 22:10 7440-09-7 D304/09/15 05:303351685 Sodium ND mg/kg 04/11/15 22:10 7440-23-5 D304/09/15 05:303351685 Strontium 66.7 mg/kg 04/11/15 22:10 7440-24-6 D304/09/15 05:303.4 1.7 5 Zinc 13.2 mg/kg 04/11/15 22:10 7440-66-6 D304/09/15 05:306.7 3.4 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/10/15 15:02 7440-36-0 N204/09/15 05:303.4 1.7 50 Arsenic 22.1 mg/kg 04/10/15 15:02 7440-38-204/09/15 05:303.4 1.7 50 Cadmium ND mg/kg 04/10/15 15:02 7440-43-904/09/15 05:300.40 0.20 50 Cobalt 6.7 mg/kg 04/10/15 15:02 7440-48-404/09/15 05:303.4 1.7 50 Lead 8.6 mg/kg 04/10/15 15:02 7439-92-104/09/15 05:303.4 1.7 50 Selenium 10.1 mg/kg 04/10/15 15:02 7782-49-204/09/15 05:303.4 1.7 50 Thallium ND mg/kg 04/10/15 15:02 7440-28-004/09/15 05:303.4 1.7 50 Vanadium 34.4 mg/kg 04/10/15 15:02 7440-62-204/09/15 05:303.4 1.7 50 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.16 mg/kg 04/09/15 10:43 7439-97-604/08/15 20:180.011 0.0056 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 26.6 %04/15/15 14:350.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.6 Std. Units 04/08/15 13:150.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/05/15 11:04 16887-00-6 D33381695 Sulfate ND mg/kg 04/05/15 11:04 14808-79-8 D33381695 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/05/15 11:04 14797-55-8 H333.8 16.9 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 71 44 of 82 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243759 J15040002 Sample:2015009197 Lab ID:92243759003 Collected:03/28/15 16:00 Received:04/01/15 17:34 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 142000 mg/kg 04/20/15 08:42 7440-44-01210060601 Total Organic Carbon 148000 mg/kg 04/20/15 08:49 7440-44-01130056601 Total Organic Carbon 152000 mg/kg 04/20/15 08:55 7440-44-01160057901 Total Organic Carbon 139000 mg/kg 04/20/15 09:01 7440-44-01090054301 Mean Total Organic Carbon 145000 mg/kg 04/20/15 08:42 7440-44-01150057401 Surrogates RSD%3.9 %04/20/15 08:421 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 71 45 of 82 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243759 J15040002 Sample:2015009199 Lab ID:92243759004 Collected:03/28/15 18:45 Received:04/01/15 17:34 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 3370 mg/kg 04/11/15 22:14 7429-90-5 D304/09/15 05:3027.7 13.9 5 Barium 92.9 mg/kg 04/11/15 22:14 7440-39-3 D304/09/15 05:302.8 1.4 5 Beryllium 0.62 mg/kg 04/11/15 22:14 7440-41-7 D304/09/15 05:300.28 0.14 5 Boron 7.2J mg/kg 04/11/15 22:14 7440-42-8 D304/09/15 05:3013.9 6.9 5 Calcium 722 mg/kg 04/11/15 22:14 7440-70-2 D304/09/15 05:3013969.3 5 Chromium 7.1 mg/kg 04/11/15 22:14 7440-47-3 D304/09/15 05:301.4 0.69 5 Copper 8.4 mg/kg 04/11/15 22:14 7440-50-8 D304/09/15 05:301.4 0.69 5 Iron 5110 mg/kg 04/11/15 22:14 7439-89-6 D304/09/15 05:3011.1 5.5 5 Magnesium 285 mg/kg 04/11/15 22:14 7439-95-4 D304/09/15 05:3013969.3 5 Manganese 24.2 mg/kg 04/11/15 22:14 7439-96-5 D304/09/15 05:301.4 0.69 5 Molybdenum 3.2 mg/kg 04/11/15 22:14 7439-98-7 D304/09/15 05:302.8 1.4 5 Nickel 5.0 mg/kg 04/11/15 22:14 7440-02-0 D304/09/15 05:301.4 0.69 5 Potassium 469 mg/kg 04/11/15 22:14 7440-09-7 D304/09/15 05:302771395 Sodium ND mg/kg 04/11/15 22:14 7440-23-5 D304/09/15 05:302771395 Strontium 57.9 mg/kg 04/11/15 22:14 7440-24-6 D304/09/15 05:302.8 1.4 5 Zinc 8.2 mg/kg 04/11/15 22:14 7440-66-6 D304/09/15 05:305.5 2.8 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/10/15 15:04 7440-36-0 N204/09/15 05:302.8 1.4 50 Arsenic 16.8 mg/kg 04/10/15 15:04 7440-38-204/09/15 05:302.8 1.4 50 Cadmium ND mg/kg 04/10/15 15:04 7440-43-904/09/15 05:300.33 0.17 50 Cobalt 2.5J mg/kg 04/10/15 15:04 7440-48-404/09/15 05:302.8 1.4 50 Lead 3.6 mg/kg 04/10/15 15:04 7439-92-104/09/15 05:302.8 1.4 50 Selenium ND mg/kg 04/10/15 15:04 7782-49-204/09/15 05:302.8 1.4 50 Thallium ND mg/kg 04/10/15 15:04 7440-28-004/09/15 05:302.8 1.4 50 Vanadium 15.7 mg/kg 04/10/15 15:04 7440-62-204/09/15 05:302.8 1.4 50 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.015 mg/kg 04/09/15 10:45 7439-97-604/08/15 20:180.0086 0.0043 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 9.9 %04/16/15 10:51 D60.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 8.3 Std. Units 04/08/15 13:150.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/05/15 12:09 16887-00-6 D32761385 Sulfate ND mg/kg 04/05/15 12:09 14808-79-8 D32761385 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/05/15 12:09 14797-55-8 H327.6 13.8 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 36 of 71 46 of 82 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243759 J15040002 Sample:2015009199 Lab ID:92243759004 Collected:03/28/15 18:45 Received:04/01/15 17:34 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 8080 mg/kg 04/20/15 09:08 7440-44-0571028601 Total Organic Carbon 6680 mg/kg 04/20/15 09:13 7440-44-0549027401 Total Organic Carbon 7670 mg/kg 04/20/15 09:20 7440-44-0543027101 Total Organic Carbon 6070 mg/kg 04/20/15 09:25 7440-44-0541027101 Mean Total Organic Carbon 7130 mg/kg 04/20/15 09:08 7440-44-0551027601 Surrogates RSD%12.9 %04/20/15 09:081 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 37 of 71 47 of 82 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243759 J15040002 Sample:2015009201 Lab ID:92243759005 Collected:03/29/15 18:30 Received:04/01/15 17:34 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 1640 mg/kg 04/11/15 22:18 7429-90-5 D304/09/15 05:3033.4 16.7 5 Barium 5.7 mg/kg 04/11/15 22:18 7440-39-3 D304/09/15 05:303.3 1.7 5 Beryllium 0.34 mg/kg 04/11/15 22:18 7440-41-7 D304/09/15 05:300.33 0.17 5 Boron 12.5J mg/kg 04/11/15 22:18 7440-42-8 D304/09/15 05:3016.7 8.3 5 Calcium 18800 mg/kg 04/11/15 22:18 7440-70-2 D304/09/15 05:3016783.5 5 Chromium 14.1 mg/kg 04/11/15 22:18 7440-47-3 D304/09/15 05:301.7 0.83 5 Copper 1.2J mg/kg 04/11/15 22:18 7440-50-8 D304/09/15 05:301.7 0.83 5 Iron 6050 mg/kg 04/11/15 22:18 7439-89-6 D304/09/15 05:3013.4 6.7 5 Magnesium 6020 mg/kg 04/11/15 22:18 7439-95-4 D304/09/15 05:3016783.5 5 Manganese 39.3 mg/kg 04/11/15 22:18 7439-96-5 D304/09/15 05:301.7 0.83 5 Molybdenum ND mg/kg 04/11/15 22:18 7439-98-7 D304/09/15 05:303.3 1.7 5 Nickel 2.9 mg/kg 04/11/15 22:18 7440-02-0 D304/09/15 05:301.7 0.83 5 Potassium 1240 mg/kg 04/11/15 22:18 7440-09-7 D304/09/15 05:303341675 Sodium 174J mg/kg 04/11/15 22:18 7440-23-5 D304/09/15 05:303341675 Strontium 36.3 mg/kg 04/11/15 22:18 7440-24-6 D304/09/15 05:303.3 1.7 5 Zinc 18.0 mg/kg 04/11/15 22:18 7440-66-6 D304/09/15 05:306.7 3.3 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/10/15 15:06 7440-36-0 N204/09/15 05:303.3 1.7 50 Arsenic 2.1J mg/kg 04/10/15 15:06 7440-38-204/09/15 05:303.3 1.7 50 Cadmium ND mg/kg 04/10/15 15:06 7440-43-904/09/15 05:300.40 0.20 50 Cobalt ND mg/kg 04/10/15 15:06 7440-48-404/09/15 05:303.3 1.7 50 Lead 2.1J mg/kg 04/10/15 15:06 7439-92-104/09/15 05:303.3 1.7 50 Selenium ND mg/kg 04/10/15 15:06 7782-49-204/09/15 05:303.3 1.7 50 Thallium ND mg/kg 04/10/15 15:06 7440-28-004/09/15 05:303.3 1.7 50 Vanadium 8.8 mg/kg 04/10/15 15:06 7440-62-204/09/15 05:303.3 1.7 50 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/09/15 10:47 7439-97-604/08/15 20:180.011 0.0053 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 25.9 %04/15/15 14:380.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 7.7 Std. Units 04/08/15 13:150.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/05/15 11:32 16887-00-6 D33371695 Sulfate ND mg/kg 04/05/15 11:32 14808-79-8 D33371695 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/05/15 11:32 14797-55-8 H333.7 16.9 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 38 of 71 48 of 82 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243759 J15040002 Sample:2015009201 Lab ID:92243759005 Collected:03/29/15 18:30 Received:04/01/15 17:34 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 1520 mg/kg 04/21/15 10:47 7440-44-08164081 Total Organic Carbon 1470 mg/kg 04/21/15 10:53 7440-44-08124061 Total Organic Carbon 1580 mg/kg 04/21/15 10:58 7440-44-08114051 Total Organic Carbon 1640 mg/kg 04/21/15 11:05 7440-44-08134061 Mean Total Organic Carbon 1550 mg/kg 04/21/15 10:47 7440-44-08134061 Surrogates RSD%4.7 %04/21/15 10:471 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 39 of 71 49 of 82 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243759 J15040002 Sample:2015009200 Lab ID:92243759006 Collected:03/28/15 18:00 Received:04/01/15 17:34 Matrix:Solid Results reported on a "wet-weight" basis Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/10/15 17:20300.0 IC Anions, SPLP Sulfate 17.2 mg/L 04/15/15 16:02 14808-79-8 B2.0 1.0 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/10/15 17:20353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate ND mg/L 04/15/15 17:18 H10.20 0.20 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 04/10/15 17:204500 Chloride, SPLP Chloride ND mg/L 04/15/15 04:18 16887-00-65.0 2.5 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 40 of 71 50 of 82 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243759 J15040002 Sample:2015009202 Lab ID:92243759007 Collected:03/27/15 14:50 Received:04/01/15 17:34 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum ND ug/L 04/08/15 16:25 7429-90-504/05/15 20:4810.0 3.0 1 Antimony ND ug/L 04/08/15 16:25 7440-36-004/05/15 20:480.50 0.15 1 Arsenic ND ug/L 04/08/15 16:25 7440-38-204/05/15 20:480.50 0.11 1 Barium ND ug/L 04/08/15 16:25 7440-39-304/05/15 20:480.30 0.081 1 Beryllium ND ug/L 04/08/15 16:25 7440-41-704/05/15 20:480.20 0.067 1 Boron ND ug/L 04/08/15 16:25 7440-42-804/05/15 20:485.0 1.1 1 Cadmium ND ug/L 04/08/15 16:25 7440-43-904/05/15 20:480.080 0.024 1 Calcium 134 ug/L 04/08/15 16:25 7440-70-204/05/15 20:4840.0 16.0 1 Chromium ND ug/L 04/08/15 16:25 7440-47-304/05/15 20:480.50 0.17 1 Cobalt ND ug/L 04/08/15 16:25 7440-48-404/05/15 20:480.50 0.13 1 Copper ND ug/L 04/08/15 16:25 7440-50-804/05/15 20:481.0 0.21 1 Iron ND ug/L 04/08/15 16:25 7439-89-604/05/15 20:4850.0 13.7 1 Lead ND ug/L 04/08/15 16:25 7439-92-104/05/15 20:480.10 0.046 1 Magnesium 11.0 ug/L 04/08/15 16:25 7439-95-404/05/15 20:4810.0 3.2 1 Manganese ND ug/L 04/08/15 16:25 7439-96-504/05/15 20:480.50 0.24 1 Molybdenum ND ug/L 04/08/15 16:25 7439-98-704/05/15 20:480.50 0.094 1 Nickel ND ug/L 04/08/15 16:25 7440-02-004/05/15 20:480.50 0.16 1 Potassium ND ug/L 04/08/15 16:25 7440-09-704/05/15 20:4850.0 11.7 1 Selenium ND ug/L 04/08/15 16:25 7782-49-204/05/15 20:480.50 0.20 1 Sodium 62.9 ug/L 04/08/15 16:25 7440-23-504/05/15 20:4850.0 16.3 1 Strontium ND ug/L 04/08/15 16:25 7440-24-604/05/15 20:480.50 0.13 1 Thallium ND ug/L 04/08/15 16:25 7440-28-004/05/15 20:480.10 0.015 1 Vanadium ND ug/L 04/08/15 16:25 7440-62-204/05/15 20:481.0 0.28 1 Zinc 5.5 ug/L 04/08/15 16:25 7440-66-604/05/15 20:485.0 2.4 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 04/10/15 13:12 7439-97-604/09/15 12:230.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 41 of 71 51 of 82 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243759 J15040002 Sample:2015009196 SPLP Lab ID:92243759008 Collected:03/28/15 10:00 Received:04/01/15 17:34 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 687 ug/L 04/24/15 20:42 7429-90-504/23/15 21:5310.0 3.0 1 Antimony ND ug/L 04/24/15 20:42 7440-36-004/23/15 21:530.50 0.15 1 Arsenic 0.61 ug/L 04/24/15 20:42 7440-38-204/23/15 21:530.50 0.11 1 Barium 123 ug/L 04/24/15 20:42 7440-39-304/23/15 21:530.30 0.081 1 Beryllium 0.096J ug/L 04/24/15 20:42 7440-41-704/23/15 21:530.20 0.067 1 Boron 50.6 ug/L 04/27/15 14:25 7440-42-8 B04/23/15 21:5325.0 5.6 5 Cadmium 0.088 ug/L 04/24/15 20:42 7440-43-904/23/15 21:530.080 0.024 1 Calcium 20200 ug/L 04/24/15 20:42 7440-70-204/23/15 21:5340.0 16.0 1 Chromium 4.0 ug/L 04/24/15 20:42 7440-47-304/23/15 21:530.50 0.17 1 Cobalt 0.18J ug/L 04/24/15 20:42 7440-48-404/23/15 21:530.50 0.13 1 Copper 0.27J ug/L 04/24/15 20:42 7440-50-804/23/15 21:531.0 0.21 1 Iron 550 ug/L 04/24/15 20:42 7439-89-604/23/15 21:5350.0 13.7 1 Lead 0.29 ug/L 04/24/15 20:42 7439-92-104/23/15 21:530.10 0.046 1 Magnesium 1100 ug/L 04/24/15 20:42 7439-95-404/23/15 21:5310.0 3.2 1 Manganese 7.2 ug/L 04/24/15 20:42 7439-96-504/23/15 21:530.50 0.24 1 Molybdenum 3.3 ug/L 04/24/15 20:42 7439-98-704/23/15 21:530.50 0.094 1 Nickel 0.98 ug/L 04/24/15 20:42 7440-02-004/23/15 21:530.50 0.16 1 Potassium 831 ug/L 04/24/15 20:42 7440-09-704/23/15 21:5350.0 11.7 1 Selenium 0.28J ug/L 04/24/15 20:42 7782-49-204/23/15 21:530.50 0.20 1 Sodium 2270 ug/L 04/24/15 20:42 7440-23-504/23/15 21:5350.0 16.3 1 Strontium 60.6 ug/L 04/24/15 20:42 7440-24-604/23/15 21:530.50 0.13 1 Thallium 0.078J ug/L 04/24/15 20:42 7440-28-0 B04/23/15 21:530.10 0.015 1 Vanadium 2.1 ug/L 04/24/15 20:42 7440-62-204/23/15 21:531.0 0.28 1 Zinc 20.5 ug/L 04/24/15 20:42 7440-66-604/23/15 21:535.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 04/24/15 11:03 7439-97-604/23/15 21:300.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 42 of 71 52 of 82 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243759 J15040002 Sample:2015009198 SPLP Lab ID:92243759009 Collected:03/28/15 19:00 Received:04/01/15 17:34 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 3970 ug/L 04/24/15 21:11 7429-90-504/23/15 21:5310.0 3.0 1 Antimony ND ug/L 04/24/15 21:11 7440-36-004/23/15 21:530.50 0.15 1 Arsenic 7.2 ug/L 04/24/15 21:11 7440-38-204/23/15 21:530.50 0.11 1 Barium 153 ug/L 04/24/15 21:11 7440-39-304/23/15 21:530.30 0.081 1 Beryllium 0.57 ug/L 04/27/15 13:57 7440-41-704/23/15 21:530.40 0.13 2 Boron 120 ug/L 04/27/15 13:57 7440-42-804/23/15 21:5310.0 2.2 2 Cadmium 0.33 ug/L 04/24/15 21:11 7440-43-904/23/15 21:530.080 0.024 1 Calcium 12000 ug/L 04/24/15 21:11 7440-70-204/23/15 21:5340.0 16.0 1 Chromium 25.4 ug/L 04/24/15 21:11 7440-47-304/23/15 21:530.50 0.17 1 Cobalt 0.84 ug/L 04/24/15 21:11 7440-48-404/23/15 21:530.50 0.13 1 Copper 0.79J ug/L 04/24/15 21:11 7440-50-804/23/15 21:531.0 0.21 1 Iron 5670 ug/L 04/24/15 21:11 7439-89-604/23/15 21:5350.0 13.7 1 Lead 0.86 ug/L 04/24/15 21:11 7439-92-104/23/15 21:530.10 0.046 1 Magnesium 2470 ug/L 04/24/15 21:11 7439-95-404/23/15 21:5310.0 3.2 1 Manganese 33.6 ug/L 04/24/15 21:11 7439-96-504/23/15 21:530.50 0.24 1 Molybdenum 6.9 ug/L 04/24/15 21:11 7439-98-704/23/15 21:530.50 0.094 1 Nickel 3.4 ug/L 04/24/15 21:11 7440-02-004/23/15 21:530.50 0.16 1 Potassium 2660 ug/L 04/24/15 21:11 7440-09-704/23/15 21:5350.0 11.7 1 Selenium 2.3 ug/L 04/24/15 21:11 7782-49-204/23/15 21:530.50 0.20 1 Sodium 1810 ug/L 04/24/15 21:11 7440-23-504/23/15 21:5350.0 16.3 1 Strontium 262 ug/L 04/24/15 21:11 7440-24-604/23/15 21:530.50 0.13 1 Thallium 0.037J ug/L 04/24/15 21:11 7440-28-0 B04/23/15 21:530.10 0.015 1 Vanadium 14.3 ug/L 04/24/15 21:11 7440-62-204/23/15 21:531.0 0.28 1 Zinc 79.2 ug/L 04/24/15 21:11 7440-66-604/23/15 21:535.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury ND ug/L 04/24/15 11:05 7439-97-604/23/15 21:300.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 43 of 71 53 of 82 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243759 J15040002 Sample:2015009200 Lab ID:92243759010 Collected:03/28/15 18:00 Received:04/01/15 17:34 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 7.8J ug/L 06/04/15 12:08 7429-90-506/04/15 10:1010.0 3.0 1 Antimony 0.47J ug/L 06/04/15 12:08 7440-36-006/04/15 10:100.50 0.15 1 Arsenic 3.6 ug/L 06/04/15 12:08 7440-38-206/04/15 10:100.50 0.11 1 Barium 190 ug/L 06/04/15 12:08 7440-39-306/04/15 10:100.30 0.081 1 Beryllium ND ug/L 06/04/15 12:08 7440-41-706/04/15 10:100.20 0.067 1 Boron 36.4 ug/L 06/04/15 12:08 7440-42-806/04/15 10:105.0 1.1 1 Cadmium ND ug/L 06/04/15 12:08 7440-43-906/04/15 10:100.080 0.024 1 Calcium 6510 ug/L 06/04/15 12:08 7440-70-206/04/15 10:1040.0 16.0 1 Chromium 0.59 ug/L 06/04/15 12:08 7440-47-306/04/15 10:100.50 0.17 1 Cobalt ND ug/L 06/04/15 12:08 7440-48-406/04/15 10:100.50 0.13 1 Copper 0.48J ug/L 06/04/15 12:08 7440-50-806/04/15 10:101.0 0.21 1 Iron ND ug/L 06/04/15 12:08 7439-89-606/04/15 10:1050.0 13.7 1 Lead ND ug/L 06/04/15 12:08 7439-92-106/04/15 10:100.10 0.046 1 Magnesium 894 ug/L 06/04/15 12:08 7439-95-406/04/15 10:1010.0 3.2 1 Manganese 27.6 ug/L 06/04/15 12:08 7439-96-506/04/15 10:100.50 0.24 1 Molybdenum 3.6 ug/L 06/04/15 12:08 7439-98-706/04/15 10:100.50 0.094 1 Nickel 1.0 ug/L 06/04/15 12:08 7440-02-006/04/15 10:100.50 0.16 1 Potassium 858 ug/L 06/04/15 12:08 7440-09-706/04/15 10:1050.0 11.7 1 Selenium 1.9 ug/L 06/04/15 12:08 7782-49-206/04/15 10:100.50 0.20 1 Sodium 1400 ug/L 06/04/15 12:08 7440-23-506/04/15 10:1050.0 16.3 1 Strontium 98.2 ug/L 06/04/15 12:08 7440-24-606/04/15 10:100.50 0.13 1 Thallium ND ug/L 06/04/15 12:08 7440-28-006/04/15 10:100.10 0.015 1 Vanadium ND ug/L 06/04/15 12:08 7440-62-206/04/15 10:101.0 0.28 1 Zinc 27.0 ug/L 06/04/15 12:08 7440-66-606/04/15 10:105.0 2.4 1 Analytical Method: EPA 7470A Preparation Method: EPA 7470A7470A Mercury Mercury 0.20 ug/L 06/02/15 17:50 7439-97-6 B,H306/02/15 09:050.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 44 of 71 54 of 82 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243759 J15040002 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/13171 EPA 7470 EPA 7470 7470 Mercury Associated Lab Samples:92243759007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1934785 Associated Lab Samples:92243759007 Matrix:Water Analyzed Mercury ug/L ND 0.20 04/10/15 11:49 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1934786LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 5.45 108 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1935455MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243388026 1935456 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 104 75-125105 1 205ND5.2 5.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 45 of 71 55 of 82 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243759 J15040002 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/13333 EPA 7470A EPA 7470A 7470A Mercury Water Associated Lab Samples:92243759008, 92243759009 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1946983 Associated Lab Samples:92243759008, 92243759009 Matrix:Water Analyzed Mercury ug/L ND 0.20 04/24/15 10:51 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1946984LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 5.15 103 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1946985MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243757010 1946986 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L H3510380-120102 1 205ND5.2 5.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 46 of 71 56 of 82 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243759 J15040002 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/13740 EPA 7470A EPA 7470A 7470A Mercury Water Associated Lab Samples:92243759010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1982127 Associated Lab Samples:92243759010 Matrix:Water Analyzed Mercury ug/L 0.067J 0.20 06/02/15 17:45 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1982128LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 5.55 110 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1982129MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 10307127009 1982130 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 102 80-120104 1 205ND5.2 5.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 47 of 71 57 of 82 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243759 J15040002 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/5566 EPA 7471 EPA 7471 7471 Mercury Associated Lab Samples:92243759001, 92243759002, 92243759003, 92243759004, 92243759005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1178138 Associated Lab Samples:92243759001, 92243759002, 92243759003, 92243759004, 92243759005 Matrix:Solid Analyzed Mercury mg/kg ND 0.0082 04/09/15 10:13 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1178139LABORATORY CONTROL SAMPLE: LCSSpike Mercury mg/kg 0.086.082 106 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1178140MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243393005 1178141 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury mg/kg M1.0929 73 80-12077 7 20.09890.028 0.096 0.10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 48 of 71 58 of 82 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243759 J15040002 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/23485 EPA 3050 EPA 6010 6010 MET Solid Associated Lab Samples:92243759001, 92243759002, 92243759003, 92243759004, 92243759005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1176762 Associated Lab Samples:92243759001, 92243759002, 92243759003, 92243759004, 92243759005 Matrix:Solid Analyzed Aluminum mg/kg ND 5.0 04/11/15 21:17 Barium mg/kg ND 0.50 04/11/15 21:17 Beryllium mg/kg ND 0.050 04/11/15 21:17 Boron mg/kg ND 2.5 04/11/15 21:17 Calcium mg/kg ND 25.0 04/11/15 21:17 Chromium mg/kg ND 0.25 04/11/15 21:17 Copper mg/kg ND 0.25 04/11/15 21:17 Iron mg/kg 1.1J 2.0 P804/11/15 21:17 Magnesium mg/kg ND 25.0 04/11/15 21:17 Manganese mg/kg ND 0.25 04/11/15 21:17 Molybdenum mg/kg ND 0.50 04/11/15 21:17 Nickel mg/kg ND 0.25 04/11/15 21:17 Potassium mg/kg ND 49.9 04/11/15 21:17 Sodium mg/kg ND 49.9 04/11/15 21:17 Strontium mg/kg ND 0.50 04/11/15 21:17 Zinc mg/kg ND 1.0 04/11/15 21:17 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1176763LABORATORY CONTROL SAMPLE: LCSSpike Aluminum mg/kg 125123 101 80-120 Barium mg/kg 12.912.3 105 80-120 Beryllium mg/kg 1.21.2 101 80-120 Boron mg/kg 123123 100 80-120 Calcium mg/kg 626615 102 80-120 Chromium mg/kg 12.212.3 100 80-120 Copper mg/kg 12.112.3 99 80-120 Iron mg/kg 119123 97 80-120 Magnesium mg/kg 608615 99 80-120 Manganese mg/kg 12.412.3 101 80-120 Molybdenum mg/kg 12.112.3 98 80-120 Nickel mg/kg 12.512.3 102 80-120 Potassium mg/kg 655615 107 80-120 Sodium mg/kg 670615 109 80-120 Strontium mg/kg 12.512.3 102 80-120 Zinc mg/kg 63.061.5 103 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 49 of 71 59 of 82 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243759 J15040002 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1176764MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243393007 1176765 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum mg/kg D3,M1163165075-1251330 11 20170127039703550 Barium mg/kg D316.3 116 75-125108 2 20176.8 25.8 25.2 Beryllium mg/kg D31.68 103 75-125100 1 201.68ND 1.8 1.8 Boron mg/kg D31639775-12595 3 20170ND160164 Calcium mg/kg D381510475-125102 3 20851ND891918 Chromium mg/kg D316.3 106 75-125103 1 20172.4 19.7 20.0 Copper mg/kg D316.3 100 75-12596 1 20171.6 17.8 18.0 Iron mg/kg D3,M116327675-125280 2 2017082912801310 Magnesium mg/kg D381510875-125104 1 20851ND942948 Manganese mg/kg D316.3 108 75-125100 2 20175.0 22.6 22.1 Molybdenum mg/kg D316.3 92 75-12589 2 2017ND15.3 15.5 Nickel mg/kg D316.3 107 75-125106 3 20171.0J 18.5 19.1 Potassium mg/kg D381511175-125106 0 20851ND965965 Sodium mg/kg D381511075-125110 4 20851ND907948 Strontium mg/kg D316.3 105 75-125103 2 2017ND17.9 18.2 Zinc mg/kg D381.5 105 75-125103 3 2085.13.5J 89.0 91.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 50 of 71 60 of 82 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243759 J15040002 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/23486 EPA 3050 EPA 6020 6020 MET SOLID Associated Lab Samples:92243759001, 92243759002, 92243759003, 92243759004, 92243759005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1176766 Associated Lab Samples:92243759001, 92243759002, 92243759003, 92243759004, 92243759005 Matrix:Solid Analyzed Antimony mg/kg ND 0.051 N204/10/15 14:28 Arsenic mg/kg ND 0.051 04/10/15 14:28 Cadmium mg/kg ND 0.0061 04/10/15 14:28 Cobalt mg/kg ND 0.051 04/10/15 14:28 Lead mg/kg ND 0.051 04/10/15 14:28 Selenium mg/kg ND 0.051 04/10/15 14:28 Thallium mg/kg ND 0.051 04/10/15 14:28 Vanadium mg/kg ND 0.051 04/10/15 14:28 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1176767LABORATORY CONTROL SAMPLE: LCSSpike Antimony mg/kg 2.6 N22.5 105 80-120 Arsenic mg/kg 2.62.5 106 80-120 Cadmium mg/kg 0.25.25 100 80-120 Cobalt mg/kg 2.62.5 107 80-120 Lead mg/kg 2.62.5 107 80-120 Selenium mg/kg 2.72.5 110 80-120 Thallium mg/kg 2.42.5 98 80-120 Vanadium mg/kg 2.72.5 107 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1176768MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243393008 1176769 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony mg/kg M6,N23.27 71 75-12570 203.15ND 2.6J 2.4J Arsenic mg/kg 3.27 86 75-12591 1 203.15ND 3.9 3.9 Cadmium mg/kg .327 101 75-12587 20.315ND 0.33J 0.27J Cobalt mg/kg 3.27 112 75-125122 4 203.15ND 4.5 4.6 Lead mg/kg M63.27 116 75-125141 6 203.155.5 9.3 9.9 Selenium mg/kg M63.27 75 75-12574 203.15ND 2.7J 2.6J Thallium mg/kg 3.27 90 75-12597 203.15ND 3.1J 3.2 Vanadium mg/kg M63.27 133 75-125238 14 203.1516.1 20.4 23.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 51 of 71 61 of 82 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243759 J15040002 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/53405 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92243759007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1932876 Associated Lab Samples:92243759007 Matrix:Water Analyzed Aluminum ug/L ND 10.0 04/08/15 14:02 Antimony ug/L ND 0.50 04/08/15 14:02 Arsenic ug/L ND 0.50 04/08/15 14:02 Barium ug/L ND 0.30 04/08/15 14:02 Beryllium ug/L ND 0.20 04/08/15 14:02 Boron ug/L ND 5.0 04/09/15 09:54 Cadmium ug/L ND 0.080 04/08/15 14:02 Calcium ug/L ND 40.0 04/08/15 14:02 Chromium ug/L ND 0.50 04/08/15 14:02 Cobalt ug/L ND 0.50 04/08/15 14:02 Copper ug/L ND 1.0 04/08/15 14:02 Iron ug/L ND 50.0 04/08/15 14:02 Lead ug/L ND 0.10 04/08/15 14:02 Magnesium ug/L ND 10.0 04/08/15 14:02 Manganese ug/L ND 0.50 04/08/15 14:02 Molybdenum ug/L ND 0.50 04/08/15 14:02 Nickel ug/L ND 0.50 04/08/15 14:02 Potassium ug/L ND 50.0 04/08/15 14:02 Selenium ug/L ND 0.50 04/08/15 14:02 Sodium ug/L ND 50.0 04/08/15 14:02 Strontium ug/L ND 0.50 04/08/15 14:02 Thallium ug/L ND 0.10 04/08/15 14:02 Vanadium ug/L ND 1.0 04/08/15 14:02 Zinc ug/L ND 5.0 04/08/15 14:02 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1932877LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 75.980 95 80-120 Antimony ug/L 79.880 100 80-120 Arsenic ug/L 78.780 98 80-120 Barium ug/L 77.980 97 80-120 Beryllium ug/L 75.680 94 80-120 Boron ug/L 76.280 95 80-120 Cadmium ug/L 77.580 97 80-120 Calcium ug/L 8901000 89 80-120 Chromium ug/L 76.880 96 80-120 Cobalt ug/L 74.980 94 80-120 Copper ug/L 74.980 94 80-120 Iron ug/L 9671000 97 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 52 of 71 62 of 82 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243759 J15040002 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1932877LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 78.380 98 80-120 Magnesium ug/L 9561000 96 80-120 Manganese ug/L 77.780 97 80-120 Molybdenum ug/L 75.180 94 80-120 Nickel ug/L 78.180 98 80-120 Potassium ug/L 9751000 98 80-120 Selenium ug/L 79.680 99 80-120 Sodium ug/L 9431000 94 80-120 Strontium ug/L 75.480 94 80-120 Thallium ug/L 76.680 96 80-120 Vanadium ug/L 79.380 99 80-120 Zinc ug/L 79.080 99 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1932878MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 10301430001 1932879 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L M18012175-125144 17 2080ND100119 Antimony ug/L 80 100 75-125100 0 2080ND80.2 80.2 Arsenic ug/L 80 99 75-125100 0 2080183262263 Barium ug/L 80 94 75-12598 2 2080113188192 Beryllium ug/L 80 85 75-12591 7 2080ND68.2 72.9 Boron ug/L 80 111 75-125119 1 2080500589596 Cadmium ug/L 80 97 75-12597 0 2080ND77.5 77.4 Calcium ug/L E,M11000-262 75-125-158 1 201000943009160092700 Chromium ug/L 80 95 75-12597 1 20800.53 76.8 78.0 Cobalt ug/L 80 93 75-12593 0 2080ND74.7 74.6 Copper ug/L 80 92 75-12593 1 20801.1 75.0 75.9 Iron ug/L 1000 99 75-125115 1 20100094901050010600 Lead ug/L 80 96 75-12598 1 2080ND77.3 78.1 Magnesium ug/L M11000-92 75-125-72 0 201000467004580046000 Manganese ug/L M1803075-12548 1 2080150015201540 Molybdenum ug/L 80 95 75-12596 1 20800.91 77.0 77.6 Nickel ug/L 80 96 75-12595 2 20801.2 78.4 77.1 Potassium ug/L M1100011675-125128 1 20100099401110011200 Selenium ug/L 80 102 75-125100 2 2080ND81.8 80.3 Sodium ug/L M11000-222 75-125-190 0 201000787007650076800 Strontium ug/L 80 81 75-12591 1 2080604669677 Thallium ug/L 80 99 75-125100 2 2080ND78.9 80.2 Vanadium ug/L 80 99 75-12598 0 2080ND79.4 79.2 Zinc ug/L 80 101 75-125104 3 20805.7 86.5 89.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 53 of 71 63 of 82 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243759 J15040002 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/53878 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92243759008, 92243759009 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1946943 Associated Lab Samples:92243759008, 92243759009 Matrix:Water Analyzed Aluminum ug/L ND 10.0 04/24/15 20:32 Antimony ug/L ND 0.50 04/24/15 20:32 Arsenic ug/L ND 0.50 04/24/15 20:32 Barium ug/L ND 0.30 04/24/15 20:32 Beryllium ug/L ND 0.20 04/24/15 20:32 Boron ug/L 1.8J 5.0 04/24/15 20:32 Cadmium ug/L ND 0.080 04/24/15 20:32 Calcium ug/L ND 40.0 04/24/15 20:32 Chromium ug/L ND 0.50 04/24/15 20:32 Cobalt ug/L ND 0.50 04/24/15 20:32 Copper ug/L ND 1.0 04/24/15 20:32 Iron ug/L ND 50.0 04/24/15 20:32 Lead ug/L ND 0.10 04/24/15 20:32 Magnesium ug/L 3.6J 10.0 04/24/15 20:32 Manganese ug/L ND 0.50 04/24/15 20:32 Molybdenum ug/L ND 0.50 04/24/15 20:32 Nickel ug/L ND 0.50 04/24/15 20:32 Potassium ug/L ND 50.0 04/24/15 20:32 Selenium ug/L ND 0.50 04/24/15 20:32 Sodium ug/L ND 50.0 04/24/15 20:32 Strontium ug/L ND 0.50 04/24/15 20:32 Thallium ug/L 0.026J 0.10 04/24/15 20:32 Vanadium ug/L ND 1.0 04/24/15 20:32 Zinc ug/L ND 5.0 04/24/15 20:32 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1946944LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 75.580 94 80-120 Antimony ug/L 77.980 97 80-120 Arsenic ug/L 77.180 96 80-120 Barium ug/L 77.480 97 80-120 Beryllium ug/L 75.980 95 80-120 Boron ug/L 77.480 97 80-120 Cadmium ug/L 76.380 95 80-120 Calcium ug/L 8901000 89 80-120 Chromium ug/L 75.280 94 80-120 Cobalt ug/L 76.380 95 80-120 Copper ug/L 75.680 94 80-120 Iron ug/L 9571000 96 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 54 of 71 64 of 82 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243759 J15040002 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1946944LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 78.380 98 80-120 Magnesium ug/L 9561000 96 80-120 Manganese ug/L 76.780 96 80-120 Molybdenum ug/L 74.180 93 80-120 Nickel ug/L 78.380 98 80-120 Potassium ug/L 9631000 96 80-120 Selenium ug/L 77.680 97 80-120 Sodium ug/L 9621000 96 80-120 Strontium ug/L 76.880 96 80-120 Thallium ug/L 74.880 94 80-120 Vanadium ug/L 75.080 94 80-120 Zinc ug/L 77.880 97 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1946945MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92244129009 1946946 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L 400 91 75-12591 1 2040064.4 430 427 Antimony ug/L 400 99 75-12597 2 20400ND396390 Arsenic ug/L 400 96 75-12596 0 204004.0 386 386 Barium ug/L 400 93 75-12595 1 20400260633639 Beryllium ug/L 400 95 75-12597 2 20400ND379387 Boron ug/L 400 101 75-125103 1 2040086.5 491 497 Cadmium ug/L 400 97 75-12597 0 204000.86 387 388 Calcium ug/L 5000 89 75-12597 6 205000209065206920 Chromium ug/L 400 93 75-12594 0 20400ND374375 Cobalt ug/L 400 94 75-12595 1 204009.1 387 391 Copper ug/L 400 94 75-12594 0 204009.0 384 386 Iron ug/L 5000 96 75-12596 0 205000ND48104790 Lead ug/L 400 98 75-12597 0 20400ND391390 Magnesium ug/L R150009775-125124 22 20500059054406790 Manganese ug/L 400 93 75-12595 1 20400227600607 Molybdenum ug/L 400 92 75-12593 1 20400ND369371 Nickel ug/L 400 97 75-12597 1 204009.8 396 399 Potassium ug/L 5000 93 75-12595 2 205000242J48904980 Selenium ug/L 400 97 75-12596 2 204003.9 392 386 Sodium ug/L 5000 93 75-125117 18 205000147061007310 Strontium ug/L 400 96 75-125105 8 2040027.4 411 446 Thallium ug/L 400 100 75-125100 0 20400ND402400 Vanadium ug/L 400 94 75-12594 0 20400ND374376 Zinc ug/L 400 92 75-12594 2 20400139508517 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 55 of 71 65 of 82 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243759 J15040002 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/54926 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92243759010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1984434 Associated Lab Samples:92243759010 Matrix:Water Analyzed Aluminum ug/L ND 10.0 06/04/15 12:04 Antimony ug/L ND 0.50 06/04/15 12:04 Arsenic ug/L ND 0.50 06/04/15 12:04 Barium ug/L ND 0.30 06/04/15 12:04 Beryllium ug/L ND 0.20 06/04/15 12:04 Boron ug/L ND 5.0 06/04/15 12:04 Cadmium ug/L ND 0.080 06/04/15 12:04 Calcium ug/L ND 40.0 06/04/15 12:04 Chromium ug/L ND 0.50 06/04/15 12:04 Cobalt ug/L ND 0.50 06/04/15 12:04 Copper ug/L ND 1.0 06/04/15 12:04 Iron ug/L ND 50.0 06/04/15 12:04 Lead ug/L ND 0.10 06/04/15 12:04 Magnesium ug/L ND 10.0 06/04/15 12:04 Manganese ug/L ND 0.50 06/04/15 12:04 Molybdenum ug/L ND 0.50 06/04/15 12:04 Nickel ug/L ND 0.50 06/04/15 12:04 Potassium ug/L ND 50.0 06/04/15 12:04 Selenium ug/L ND 0.50 06/04/15 12:04 Sodium ug/L ND 50.0 06/04/15 12:04 Strontium ug/L ND 0.50 06/04/15 12:04 Thallium ug/L ND 0.10 06/04/15 12:04 Vanadium ug/L ND 1.0 06/04/15 12:04 Zinc ug/L ND 5.0 06/04/15 12:04 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1984435LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 79.080 99 80-120 Antimony ug/L 79.480 99 80-120 Arsenic ug/L 78.480 98 80-120 Barium ug/L 77.680 97 80-120 Beryllium ug/L 80.580 101 80-120 Boron ug/L 80.880 101 80-120 Cadmium ug/L 80.480 100 80-120 Calcium ug/L 9561000 96 80-120 Chromium ug/L 79.580 99 80-120 Cobalt ug/L 79.080 99 80-120 Copper ug/L 78.780 98 80-120 Iron ug/L 9771000 98 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 56 of 71 66 of 82 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243759 J15040002 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1984435LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 78.680 98 80-120 Magnesium ug/L 9621000 96 80-120 Manganese ug/L 78.480 98 80-120 Molybdenum ug/L 77.280 96 80-120 Nickel ug/L 77.880 97 80-120 Potassium ug/L 9771000 98 80-120 Selenium ug/L 79.680 100 80-120 Sodium ug/L 9721000 97 80-120 Strontium ug/L 77.580 97 80-120 Thallium ug/L 82.080 103 80-120 Vanadium ug/L 78.180 98 80-120 Zinc ug/L 79.280 99 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1984437MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92252107001 1984438 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L 80 102 75-125103 2 2080ND83.6 84.9 Antimony ug/L 80 99 75-125100 2 2080ND79.0 80.4 Arsenic ug/L 80 96 75-12598 2 2080ND77.0 78.7 Barium ug/L 80 96 75-12597 1 20801.5 78.3 79.1 Beryllium ug/L 80 98 75-125100 2 2080ND78.2 79.6 Boron ug/L 80 110 75-125106 3 2080ND88.2 85.5 Cadmium ug/L 80 101 75-125102 1 2080ND80.9 81.5 Calcium ug/L 1000 95 75-12598 3 20100012410801110 Chromium ug/L 80 99 75-125102 3 2080ND79.0 81.4 Cobalt ug/L 80 99 75-125101 2 2080ND79.2 80.6 Copper ug/L 80 99 75-12599 1 2080ND79.1 79.6 Iron ug/L 1000 96 75-12599 3 201000ND963990 Lead ug/L 80 98 75-12599 1 2080ND78.8 79.3 Magnesium ug/L 1000 99 75-125101 2 20100012.9 1000 1020 Manganese ug/L 80 98 75-125100 2 20800.37J 78.9 80.7 Molybdenum ug/L 80 96 75-12597 1 2080ND76.6 77.7 Nickel ug/L 80 98 75-125100 2 2080ND78.4 80.4 Potassium ug/L 1000 96 75-12599 3 201000ND966996 Selenium ug/L 80 96 75-125102 5 2080ND77.2 81.4 Sodium ug/L 1000 95 75-12599 4 20100021.5J 971 1010 Strontium ug/L 80 95 75-12597 1 20800.84 77.2 78.0 Thallium ug/L 80 102 75-125104 1 2080ND81.9 82.9 Vanadium ug/L 80 98 75-12598 0 2080ND78.7 78.5 Zinc ug/L 80 99 75-12599 0 20803.0J 82.4 82.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 57 of 71 67 of 82 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243759 J15040002 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: PMST/3444 ASTM D2974-87 ASTM D2974-87 Dry Weight/Percent Moisture Associated Lab Samples:92243759001, 92243759002, 92243759003, 92243759005 Parameter Units Dup Result Max RPD QualifiersRPDResult 35182170002 1184039SAMPLE DUPLICATE: Percent Moisture %5.8 2 105.9 Parameter Units Dup Result Max RPD QualifiersRPDResult 35182775094 1184040SAMPLE DUPLICATE: Percent Moisture %5.3 D611105.9 Parameter Units Dup Result Max RPD QualifiersRPDResult 35182775103 1184041SAMPLE DUPLICATE: Percent Moisture %20.1 5 1019.2 Parameter Units Dup Result Max RPD QualifiersRPDResult 35182955001 1184042SAMPLE DUPLICATE: Percent Moisture %7.3 D620108.9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 58 of 71 68 of 82 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243759 J15040002 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: PMST/3446 ASTM D2974-87 ASTM D2974-87 Dry Weight/Percent Moisture Associated Lab Samples:92243759004 Parameter Units Dup Result Max RPD QualifiersRPDResult 92243759004 1185152SAMPLE DUPLICATE: Percent Moisture %12.0 D619109.9 Parameter Units Dup Result Max RPD QualifiersRPDResult 35183451003 1185153SAMPLE DUPLICATE: Percent Moisture %20.8 5 1019.9 Parameter Units Dup Result Max RPD QualifiersRPDResult 35183626002 1185154SAMPLE DUPLICATE: Percent Moisture %11.6 D6521019.8 Parameter Units Dup Result Max RPD QualifiersRPDResult 35183572001 1185155SAMPLE DUPLICATE: Percent Moisture %39.8 D6211049.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 59 of 71 69 of 82 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243759 J15040002 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/36682 EPA 9045 EPA 9045 9045 pH Associated Lab Samples:92243759001, 92243759002, 92243759003, 92243759004, 92243759005 Parameter Units Dup Result Max RPD QualifiersRPDResult 92243916001 1428909SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 6.3 0 106.3 Parameter Units Dup Result Max RPD QualifiersRPDResult 92243757006 1428910SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 6.2 D62106.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 60 of 71 70 of 82 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243759 J15040002 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22570 EPA 300.0 EPA 300.0 300.0 IC Anions Associated Lab Samples:92243759001, 92243759002, 92243759006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1434821 Associated Lab Samples:92243759001, 92243759002, 92243759006 Matrix:Water Analyzed Sulfate mg/L 2.8 2.0 04/15/15 14:27 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1434822LABORATORY CONTROL SAMPLE: LCSSpike Sulfate mg/L 19.420 97 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1434823MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243757005 1434824 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate mg/L 33.3 90 90 033.34.0 33.9 34.0 Parameter Units MS Result % Rec Limits Qual% RecConc. 1434825MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243920005 1434826 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate mg/L 26.2 89 90 126.25.3 28.7 28.9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 61 of 71 71 of 82 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243759 J15040002 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22576 EPA 353.2 EPA 353.2 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples:92243759001, 92243759002, 92243759006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1435291 Associated Lab Samples:92243759001, 92243759002, 92243759006 Matrix:Water Analyzed Nitrogen, Nitrate mg/L 0.16 0.020 Z204/15/15 17:00 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1435292LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Nitrate mg/L 2.52.5 100 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1435293MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243757005 1435294 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L H14.2 91 90-11092 1 104.2ND 4.0 4.1 Parameter Units MS Result % Rec Limits Qual% RecConc. 1435295MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243759001 1435296 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L H13.3 95 90-11095 0 103.3ND 3.3 3.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 62 of 71 72 of 82 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243759 J15040002 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22563 SM 4500-Cl-E SM 4500-Cl-E 4500 Chloride Associated Lab Samples:92243759001, 92243759002, 92243759006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1434670 Associated Lab Samples:92243759001, 92243759002, 92243759006 Matrix:Water Analyzed Chloride mg/L ND 1.0 04/15/15 04:12 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1434671LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/L 21.320 106 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1434672MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243757005 1434673 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L 33.3 104 90-110103 1 1033.3ND 36.4 36.0 Parameter Units MS Result % Rec Limits Qual% RecConc. 1434674MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243920005 1434675 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L 26.2 103 90-110102 1 1026.2ND 28.2 28.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 63 of 71 73 of 82 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243759 J15040002 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/45122 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92243759001, 92243759002, 92243759003, 92243759004, 92243759005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1174929 Associated Lab Samples: Matrix:Solid Analyzed Chloride mg/kg ND 49.4 04/05/15 03:35 Sulfate mg/kg ND 49.4 04/05/15 03:35 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1174930LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/kg 469496 94 80-120 Sulfate mg/kg 469496 94 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1174932MATRIX SPIKE SAMPLE: MSSpike Result 92243393005 Chloride mg/kg 855J M66027380-120ND Sulfate mg/kg 781J M660213080-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92243393005 1174931SAMPLE DUPLICATE: Chloride mg/kg ND D320ND Sulfate mg/kg ND D320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 64 of 71 74 of 82 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243759 J15040002 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/45121 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92243759001, 92243759002, 92243759003, 92243759004, 92243759005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1174925 Associated Lab Samples: Matrix:Solid Analyzed Nitrate as N mg/kg ND 4.9 04/05/15 03:35 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1174926LABORATORY CONTROL SAMPLE: LCSSpike Nitrate as N mg/kg 48.949.6 99 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1174928MATRIX SPIKE SAMPLE: MSSpike Result 92243393005 Nitrate as N mg/kg ND H360.2 96 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92243393005 1174927SAMPLE DUPLICATE: Nitrate as N mg/kg ND H320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 65 of 71 75 of 82 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243759 J15040002 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/28061 EPA 9060 EPA 9060 9060 TOC Average Associated Lab Samples:92243759001, 92243759002, 92243759003, 92243759004, 92243759005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1142189 Associated Lab Samples: Matrix:Solid Analyzed Mean Total Organic Carbon mg/kg ND 600 04/20/15 07:09 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1142190LABORATORY CONTROL SAMPLE: LCSSpike Mean Total Organic Carbon mg/kg 119000120000 99 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1142191MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243759001 1142192 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 7920 90 50-15086 4 307940125083908090 Parameter Units MS Result % Rec Limits Qual% RecConc. 1142193MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243757002 1142194 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 109000 88 50-15084 2 3010900083300179000175000 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 66 of 71 76 of 82 #=QL# QUALIFIERS Pace Project No.: Project: 92243759 J15040002 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - Green BayPASI-G Pace Analytical Services - MinneapolisPASI-M Pace Analytical Services - Ormond BeachPASI-O ANALYTE QUALIFIERS Analyte was detected in the associated method blank.B Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6 Analyte concentration exceeded the calibration range. The reported result is estimated.E Analysis conducted outside the EPA method holding time.H1 Sample was received or analysis requested beyond the recognized method holding time.H3 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6 The lab does not hold TNI accreditation for this parameter.N2 Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit.P8 RPD value was outside control limits.R1 Analyte present in the associated method blank above the detection limit.Z2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 67 of 71 77 of 82 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92243759 J15040002 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92243759001 MPRP/23485 ICP/143642015009196EPA 3050 EPA 6010 92243759002 MPRP/23485 ICP/143642015009198EPA 3050 EPA 6010 92243759003 MPRP/23485 ICP/143642015009197EPA 3050 EPA 6010 92243759004 MPRP/23485 ICP/143642015009199EPA 3050 EPA 6010 92243759005 MPRP/23485 ICP/143642015009201EPA 3050 EPA 6010 92243759001 MPRP/23486 ICPM/95682015009196EPA 3050 EPA 6020 92243759002 MPRP/23486 ICPM/95682015009198EPA 3050 EPA 6020 92243759003 MPRP/23486 ICPM/95682015009197EPA 3050 EPA 6020 92243759004 MPRP/23486 ICPM/95682015009199EPA 3050 EPA 6020 92243759005 MPRP/23486 ICPM/95682015009201EPA 3050 EPA 6020 92243759007 MPRP/53405 ICPM/236672015009202EPA 3020 EPA 6020A 92243759008 MPRP/53878 ICPM/239382015009196 SPLP EPA 3020 EPA 6020A 92243759009 MPRP/53878 ICPM/239382015009198 SPLP EPA 3020 EPA 6020A 92243759010 MPRP/54926 ICPM/246472015009200EPA 3020 EPA 6020A 92243759007 MERP/13171 MERC/153162015009202EPA 7470 EPA 7470 92243759008 MERP/13333 MERC/154972015009196 SPLP EPA 7470A EPA 7470A 92243759009 MERP/13333 MERC/154972015009198 SPLP EPA 7470A EPA 7470A 92243759010 MERP/13740 MERC/159682015009200EPA 7470A EPA 7470A 92243759001 MERP/5566 MERC/55542015009196EPA 7471 EPA 7471 92243759002 MERP/5566 MERC/55542015009198EPA 7471 EPA 7471 92243759003 MERP/5566 MERC/55542015009197EPA 7471 EPA 7471 92243759004 MERP/5566 MERC/55542015009199EPA 7471 EPA 7471 92243759005 MERP/5566 MERC/55542015009201EPA 7471 EPA 7471 92243759001 PMST/34442015009196ASTM D2974-87 92243759002 PMST/34442015009198ASTM D2974-87 92243759003 PMST/34442015009197ASTM D2974-87 92243759004 PMST/34462015009199ASTM D2974-87 92243759005 PMST/34442015009201ASTM D2974-87 92243759001 WET/366822015009196EPA 9045 92243759002 WET/366822015009198EPA 9045 92243759003 WET/366822015009197EPA 9045 92243759004 WET/366822015009199EPA 9045 92243759005 WET/366822015009201EPA 9045 92243759001 WETA/225702015009196EPA 300.0 92243759002 WETA/225702015009198EPA 300.0 92243759006 WETA/225702015009200EPA 300.0 92243759001 WETA/225762015009196EPA 353.2 92243759002 WETA/225762015009198EPA 353.2 92243759006 WETA/225762015009200EPA 353.2 92243759001 WETA/225632015009196SM 4500-Cl-E 92243759002 WETA/225632015009198SM 4500-Cl-E REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 68 of 71 78 of 82 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92243759 J15040002 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92243759006 WETA/225632015009200SM 4500-Cl-E 92243759001 WETA/451222015009196EPA 9056 92243759002 WETA/451222015009198EPA 9056 92243759003 WETA/451222015009197EPA 9056 92243759004 WETA/451222015009199EPA 9056 92243759005 WETA/451222015009201EPA 9056 92243759001 WETA/451212015009196EPA 9056 92243759002 WETA/451212015009198EPA 9056 92243759003 WETA/451212015009197EPA 9056 92243759004 WETA/451212015009199EPA 9056 92243759005 WETA/451212015009201EPA 9056 92243759001 WETA/280612015009196EPA 9060 92243759001 WETA/280642015009196EPA 9060 92243759002 WETA/280612015009198EPA 9060 92243759002 WETA/280642015009198EPA 9060 92243759003 WETA/280612015009197EPA 9060 92243759003 WETA/280642015009197EPA 9060 92243759004 WETA/280612015009199EPA 9060 92243759004 WETA/280642015009199EPA 9060 92243759005 WETA/280612015009201EPA 9060 92243759005 WETA/280642015009201EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 06/16/2015 08:32 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 69 of 71 79 of 82 Page 70 of 71 80 of 82 Page 71 of 71 81 of 82 82 of 82