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Home My WebLink AboutNC0001422_ATT 5 - Soil - J15030746 Report_2015080513339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number:J15030746 Project Name:SUTTON - AB GW ASSESSMENT SOIL Lab Contact:Margaret Galvin-Karr Date:5/5/2015 Customer Address: Customer Name(s):Perry Waldrep, Tim Hunsucker, Kathy Webb, John Toepfer Phone: 980-875-5219 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Margaret Galvin-Karr) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Margaret Galvin-Karr Page 1 of 72 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015008932 Sutton 26-Mar-15 11:00 AM ILLEGIBLE Well AB-2 3'-5' 2015008933 Sutton 26-Mar-15 12:15 PM ILLEGIBLE Well AB-2 10'-12' 2015008934 Sutton 26-Mar-15 12:15 PM ILLEGIBLE Well AB-2 DUPLICATE 2015008935 Sutton 26-Mar-15 12:00 PM ILLEGIBLE Well AB-2 6'-8' 2015008936 Sutton 26-Mar-15 12:00 PM ILLEGIBLE Well AB-2 DUPLICATE 2015008937 Sutton 26-Mar-15 12:40 PM ILLEGIBLE Well AB-2 10'-12' 2015008938 Sutton 26-Mar-15 10:25 AM ILLEGIBLE Well AB-2 MINISONIC 7 Total Samples Page 2 of 72 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:DBA Account Date:5/5/2015 Electronic Data Deliverable (EDD) Sent Separately Page 3 of 72 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030746 2015008932 Collection Date:26-Mar-15 11:00 AM Site:Well AB-2 3'-5' Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 4 of 72 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030746 2015008933 Collection Date:26-Mar-15 12:15 PM Site:Well AB-2 10'-12' Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 5 of 72 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030746 2015008934 Collection Date:26-Mar-15 12:15 PM Site:Well AB-2 DUPLICATE Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 6 of 72 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030746 2015008935 Collection Date:26-Mar-15 12:00 PM Site:Well AB-2 6'-8' Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 7 of 72 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030746 2015008936 Collection Date:26-Mar-15 12:00 PM Site:Well AB-2 DUPLICATE Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 8 of 72 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030746 2015008937 Collection Date:26-Mar-15 12:40 PM Site:Well AB-2 10'-12' Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 9 of 72 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030746 2015008938 Collection Date:26-Mar-15 10:25 AM Site:Well AB-2 MINISONIC Matrix:OTHER Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 10 of 72 #=CL# April 27, 2015 LIMS USE: FR - PROGRAM MANAGER LIMS OBJECT ID: 92243245 92243245 Project: Pace Project No.: RE: Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 J15030746 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on March 30, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc:Marge Galvin-Karr, Duke Energy Program Manager, Duke Energy Rodney Wike, Duke Energy REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 60 Page 11 of 72 #=CP# CERTIFICATIONS Pace Project No.: Project: 92243245 J15030746 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A2LA Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA #: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 60 Page 12 of 72 #=CP# CERTIFICATIONS Pace Project No.: Project: 92243245 J15030746 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 60 Page 13 of 72 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92243245 J15030746 Lab ID Sample ID Matrix Date Collected Date Received 92243245001 2015008932 Solid 03/26/15 11:00 03/30/15 15:10 92243245002 2015008933 Solid 03/26/15 12:15 03/30/15 15:10 92243245003 2015008934 Solid 03/26/15 12:15 03/30/15 15:10 92243245004 2015008935 Solid 03/26/15 12:00 03/30/15 15:10 92243245005 2015008936 Solid 03/26/15 12:00 03/30/15 15:10 92243245006 2015008937 Solid 03/26/15 12:40 03/30/15 15:10 92243245007 2015008938 Water 03/26/15 10:25 03/30/15 15:10 92243245008 2015008935 SPLP Water 03/26/15 12:00 03/30/15 15:10 92243245009 2015008936 SPLP Water 03/26/15 12:00 03/30/15 15:10 92243245010 2015008937 SPLP Water 03/26/15 12:40 03/30/15 15:10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 60 Page 14 of 72 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92243245 J15030746 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92243245001 2015008932 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OCRT EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92243245002 2015008933 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OCRT EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92243245003 2015008934 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OCRT EPA 9045 1 PASI-AMLS EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92243245004 2015008935 EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER 92243245005 2015008936 EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER 92243245006 2015008937 EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER 92243245007 2015008938 EPA 6020A 24 PASI-MRJS EPA 7470 1 PASI-MJDD 92243245008 2015008935 SPLP EPA 6020A 24 PASI-MRJS EPA 7470 1 PASI-MJDD REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 60 Page 15 of 72 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92243245 J15030746 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92243245009 2015008936 SPLP EPA 6020A 24 PASI-MRJS EPA 7470 1 PASI-MJDD 92243245010 2015008937 SPLP EPA 6020A 24 PASI-MRJS EPA 7470 1 PASI-MJDD REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 60 Page 16 of 72 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92243245 J15030746 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92243245001 2015008932 Aluminum 19600 mg/kg 04/09/15 07:1147.0EPA 6010 Barium 603 mg/kg 04/09/15 07:114.7EPA 6010 Beryllium 7.4 mg/kg 04/09/15 07:110.47EPA 6010 Boron 21.9J mg/kg 04/09/15 07:1123.5EPA 6010 Calcium 3970 mg/kg 04/09/15 07:11235EPA 6010 Chromium 23.4 mg/kg 04/09/15 07:112.3EPA 6010 Copper 67.8 mg/kg 04/09/15 07:112.3EPA 6010 Iron 9860 mg/kg 04/09/15 07:1118.8EPA 6010 Magnesium 1410 mg/kg 04/09/15 07:11235EPA 6010 Manganese 79.5 mg/kg 04/09/15 07:112.3EPA 6010 Molybdenum 3.8J mg/kg 04/09/15 07:114.7EPA 6010 Nickel 33.8 mg/kg 04/09/15 07:112.3EPA 6010 Potassium 2480 mg/kg 04/09/15 07:11470EPA 6010 Sodium 592 mg/kg 04/09/15 07:11470EPA 6010 Strontium 394 mg/kg 04/09/15 07:114.7EPA 6010 Zinc 33.9 mg/kg 04/09/15 07:119.4EPA 6010 Arsenic 51.4 mg/kg 04/07/15 12:574.7EPA 6020 Cadmium 0.32J mg/kg 04/07/15 12:570.56EPA 6020 Cobalt 19.5 mg/kg 04/07/15 12:574.7EPA 6020 Lead 25.5 mg/kg 04/07/15 12:574.7EPA 6020 Selenium 12.2 mg/kg 04/07/15 12:574.7EPA 6020 Vanadium 84.2 mg/kg 04/07/15 12:574.7EPA 6020 Mercury 0.14 mg/kg 04/08/15 17:550.015EPA 7471 Percent Moisture 45.0 %04/07/15 21:250.10ASTM D2974-87 pH at 25 Degrees C 6.5 Std. Units 04/08/15 22:000.10EPA 9045 Total Organic Carbon 89800 mg/kg 04/17/15 06:5911600EPA 9060 Total Organic Carbon 88600 mg/kg 04/17/15 07:0511700EPA 9060 Total Organic Carbon 91700 mg/kg 04/17/15 07:1111100EPA 9060 Total Organic Carbon 94000 mg/kg 04/17/15 07:1711800EPA 9060 Mean Total Organic Carbon 91000 mg/kg 04/17/15 06:5911600EPA 9060 RSD%2.6 %04/17/15 06:59EPA 9060 92243245002 2015008933 Aluminum 385 mg/kg 04/09/15 07:1628.3EPA 6010 Iron 211 mg/kg 04/09/15 07:1611.3EPA 6010 Percent Moisture 14.9 %04/07/15 21:250.10ASTM D2974-87 pH at 25 Degrees C 6.7 Std. Units 04/08/15 22:000.10EPA 9045 RSD%3.4 %04/17/15 08:09EPA 9060 92243245003 2015008934 Aluminum 351 mg/kg 04/09/15 07:2030.9EPA 6010 Iron 252 mg/kg 04/09/15 07:2012.4EPA 6010 Percent Moisture 16.1 %04/07/15 21:250.10ASTM D2974-87 pH at 25 Degrees C 6.7 Std. Units 04/08/15 22:000.10EPA 9045 Total Organic Carbon 362J mg/kg 04/17/15 08:45717EPA 9060 Total Organic Carbon 390J mg/kg 04/17/15 08:50720EPA 9060 Mean Total Organic Carbon 360J mg/kg 04/17/15 08:34718EPA 9060 RSD%6.4 %04/17/15 08:34EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 60 Page 17 of 72 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92243245 J15030746 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92243245004 2015008935 Sulfate 3.8 mg/L 04/09/15 18:44 B2.0EPA 300.0 92243245005 2015008936 Sulfate 2.9 mg/L 04/09/15 19:25 B2.0EPA 300.0 92243245006 2015008937 Sulfate 3.4 mg/L 04/09/15 19:39 B2.0EPA 300.0 Nitrogen, Nitrate 0.23 mg/L 04/09/15 20:06 H10.20EPA 353.2 92243245007 2015008938 Aluminum 38.0 ug/L 04/06/15 08:0910.0EPA 6020A Barium 0.82 ug/L 04/06/15 08:090.30EPA 6020A Calcium 1560 ug/L 04/06/15 08:0940.0EPA 6020A Chromium 1.8 ug/L 04/06/15 08:090.50EPA 6020A Cobalt 0.54 ug/L 04/06/15 08:090.50EPA 6020A Copper 1.3 ug/L 04/06/15 08:091.0EPA 6020A Iron 478 ug/L 04/06/15 08:0950.0EPA 6020A Lead 0.20 ug/L 04/06/15 08:090.10EPA 6020A Magnesium 35.4 ug/L 04/06/15 08:0910.0EPA 6020A Manganese 7.5 ug/L 04/06/15 08:090.50EPA 6020A Molybdenum 0.60 ug/L 04/06/15 08:090.50EPA 6020A Strontium 2.3 ug/L 04/06/15 08:090.50EPA 6020A Zinc 8.7 ug/L 04/06/15 08:095.0EPA 6020A 92243245008 2015008935 SPLP Aluminum 2080 ug/L 04/17/15 19:0910.0EPA 6020A Antimony 2.8 ug/L 04/17/15 19:090.50EPA 6020A Arsenic 24.5 ug/L 04/17/15 19:090.50EPA 6020A Barium 285 ug/L 04/17/15 19:090.30EPA 6020A Beryllium 0.54 ug/L 04/17/15 19:090.20EPA 6020A Boron 160 ug/L 04/20/15 15:3225.0EPA 6020A Calcium 1720 ug/L 04/17/15 19:0940.0EPA 6020A Chromium 4.2 ug/L 04/17/15 19:090.50EPA 6020A Cobalt 1.2 ug/L 04/17/15 19:090.50EPA 6020A Copper 11.4 ug/L 04/17/15 19:091.0EPA 6020A Iron 737 ug/L 04/17/15 19:0950.0EPA 6020A Lead 2.3 ug/L 04/17/15 19:090.10EPA 6020A Magnesium 198 ug/L 04/17/15 19:0910.0EPA 6020A Manganese 9.7 ug/L 04/17/15 19:090.50EPA 6020A Molybdenum 24.0 ug/L 04/17/15 19:090.50EPA 6020A Nickel 2.5 ug/L 04/17/15 19:090.50EPA 6020A Potassium 98.8 ug/L 04/17/15 19:0950.0EPA 6020A Selenium 2.1 ug/L 04/17/15 19:090.50EPA 6020A Sodium 1340 ug/L 04/17/15 19:0950.0EPA 6020A Strontium 56.0 ug/L 04/17/15 19:090.50EPA 6020A Thallium 0.10 ug/L 04/17/15 19:090.10EPA 6020A Vanadium 23.7 ug/L 04/20/15 15:325.0EPA 6020A Zinc 46.1 ug/L 04/17/15 19:095.0EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 60 Page 18 of 72 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92243245 J15030746 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92243245009 2015008936 SPLP Aluminum 1480 ug/L 04/17/15 19:1310.0EPA 6020A Antimony 4.0 ug/L 04/17/15 19:130.50EPA 6020A Arsenic 22.6 ug/L 04/17/15 19:130.50EPA 6020A Barium 282 ug/L 04/17/15 19:130.30EPA 6020A Beryllium 0.38 ug/L 04/17/15 19:130.20EPA 6020A Boron 47.5 ug/L 04/20/15 15:3725.0EPA 6020A Calcium 1780 ug/L 04/17/15 19:1340.0EPA 6020A Chromium 3.5 ug/L 04/17/15 19:130.50EPA 6020A Cobalt 0.96 ug/L 04/17/15 19:130.50EPA 6020A Copper 8.9 ug/L 04/17/15 19:131.0EPA 6020A Iron 574 ug/L 04/17/15 19:1350.0EPA 6020A Lead 1.7 ug/L 04/17/15 19:130.10EPA 6020A Magnesium 174 ug/L 04/17/15 19:1310.0EPA 6020A Manganese 9.2 ug/L 04/17/15 19:130.50EPA 6020A Molybdenum 27.1 ug/L 04/17/15 19:130.50EPA 6020A Nickel 2.1 ug/L 04/17/15 19:130.50EPA 6020A Potassium 259 ug/L 04/17/15 19:1350.0EPA 6020A Selenium 4.2 ug/L 04/17/15 19:130.50EPA 6020A Sodium 321 ug/L 04/17/15 19:1350.0EPA 6020A Strontium 56.5 ug/L 04/17/15 19:130.50EPA 6020A Vanadium 22.6 ug/L 04/20/15 15:375.0EPA 6020A Zinc 66.1 ug/L 04/17/15 19:135.0EPA 6020A 92243245010 2015008937 SPLP Aluminum 1470 ug/L 04/17/15 19:1810.0EPA 6020A Arsenic 0.71 ug/L 04/17/15 19:180.50EPA 6020A Barium 70.0 ug/L 04/17/15 19:180.30EPA 6020A Boron 38.9 ug/L 04/20/15 15:425.0EPA 6020A Calcium 580 ug/L 04/17/15 19:1840.0EPA 6020A Chromium 1.1 ug/L 04/17/15 19:180.50EPA 6020A Iron 365 ug/L 04/17/15 19:1850.0EPA 6020A Lead 0.42 ug/L 04/17/15 19:180.10EPA 6020A Magnesium 70.5 ug/L 04/17/15 19:1810.0EPA 6020A Manganese 3.1 ug/L 04/17/15 19:180.50EPA 6020A Molybdenum 0.69 ug/L 04/17/15 19:180.50EPA 6020A Nickel 0.56 ug/L 04/17/15 19:180.50EPA 6020A Sodium 713 ug/L 04/17/15 19:1850.0EPA 6020A Strontium 10.4 ug/L 04/17/15 19:180.50EPA 6020A Vanadium 1.9 ug/L 04/20/15 15:421.0EPA 6020A Zinc 35.0 ug/L 04/17/15 19:185.0EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 60 Page 19 of 72 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243245 J15030746 Method: Client:Duke Energy EPA 6010 Date:April 27, 2015 Description:6010 MET ICP General Information: 3 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23429 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242920018 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1174971) • Aluminum • Barium • Chromium • Copper • Iron • Manganese • Strontium • MSD (Lab ID: 1174972) • Aluminum • Barium • Iron • Magnesium • Manganese • Potassium • Strontium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 60 Page 20 of 72 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243245 J15030746 Method: Client:Duke Energy EPA 6010 Date:April 27, 2015 Description:6010 MET ICP QC Batch: MPRP/23429 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242920018 R1: RPD value was outside control limits. • MSD (Lab ID: 1174972) • Barium • Beryllium • Potassium • Strontium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 60 Page 21 of 72 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243245 J15030746 Method: Client:Duke Energy EPA 6020 Date:April 27, 2015 Description:6020 MET ICPMS General Information: 3 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23430 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242920019 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1174975) • Antimony • Arsenic • Lead • Selenium • Thallium • Vanadium • MSD (Lab ID: 1174976) • Antimony • Arsenic • Selenium • Thallium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 60 Page 22 of 72 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243245 J15030746 Method: Client:Duke Energy EPA 6020 Date:April 27, 2015 Description:6020 MET ICPMS Analyte Comments: QC Batch: MPRP/23430 N2: The lab does not hold TNI accreditation for this parameter. • 2015008932 (Lab ID: 92243245001) • Antimony • 2015008933 (Lab ID: 92243245002) • Antimony • 2015008934 (Lab ID: 92243245003) • Antimony • BLANK (Lab ID: 1174973) • Antimony • LCS (Lab ID: 1174974) • Antimony • MS (Lab ID: 1174975) • Antimony • MSD (Lab ID: 1174976) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 60 Page 23 of 72 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243245 J15030746 Method: Client:Duke Energy EPA 6020A Date:April 27, 2015 Description:6020A MET ICPMS General Information: 4 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 60 Page 24 of 72 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243245 J15030746 Method: Client:Duke Energy EPA 7470 Date:April 27, 2015 Description:7470 Mercury General Information: 4 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 60 Page 25 of 72 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243245 J15030746 Method: Client:Duke Energy EPA 7471 Date:April 27, 2015 Description:7471 Mercury General Information: 3 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 60 Page 26 of 72 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243245 J15030746 Method: Client:Duke Energy EPA 9045 Date:April 27, 2015 Description:9045 pH Soil General Information: 3 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WET/36660 • DUP (Lab ID: 1427812) • pH at 25 Degrees C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 60 Page 27 of 72 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243245 J15030746 Method: Client:Duke Energy EPA 300.0 Date:April 27, 2015 Description:300.0 IC Anions, SPLP General Information: 3 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/22495 B: Analyte was detected in the associated method blank. • BLANK for HBN 258853 [WETA/224 (Lab ID: 1430392) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 60 Page 28 of 72 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243245 J15030746 Method: Client:Duke Energy EPA 353.2 Date:April 27, 2015 Description:353.2 Nitrogen, NO2/NO3, SPLP General Information: 3 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H1: Analysis conducted outside the EPA method holding time. • 2015008935 (Lab ID: 92243245004) • 2015008936 (Lab ID: 92243245005) • 2015008937 (Lab ID: 92243245006) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 60 Page 29 of 72 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243245 J15030746 Method: Client:Duke Energy SM 4500-Cl-E Date:April 27, 2015 Description:4500 Chloride, SPLP General Information: 3 samples were analyzed for SM 4500-Cl-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: WETA/22491 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92243096002,92243393001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MSD (Lab ID: 1430200) • Chloride Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 60 Page 30 of 72 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243245 J15030746 Method: Client:Duke Energy EPA 9056 Date:April 27, 2015 Description:9056 IC Anions General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/45049 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015008932 (Lab ID: 92243245001) • Chloride • Sulfate • 2015008933 (Lab ID: 92243245002) • Chloride • Sulfate • 2015008934 (Lab ID: 92243245003) • Chloride REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 60 Page 31 of 72 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243245 J15030746 Method: Client:Duke Energy EPA 9056 Date:April 27, 2015 Description:9056 IC Anions 48hr General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H3: Sample was received or analysis requested beyond the recognized method holding time. • 2015008932 (Lab ID: 92243245001) • 2015008933 (Lab ID: 92243245002) • 2015008934 (Lab ID: 92243245003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 60 Page 32 of 72 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92243245 J15030746 Method: Client:Duke Energy EPA 9060 Date:April 27, 2015 Description:Total Organic Carbon Quad General Information: 3 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 60 Page 33 of 72 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243245 J15030746 Sample:2015008932 Lab ID:92243245001 Collected:03/26/15 11:00 Received:03/30/15 15:10 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 19600 mg/kg 04/09/15 07:11 7429-90-504/04/15 18:3747.0 23.5 5 Barium 603 mg/kg 04/09/15 07:11 7440-39-304/04/15 18:374.7 2.3 5 Beryllium 7.4 mg/kg 04/09/15 07:11 7440-41-704/04/15 18:370.47 0.23 5 Boron 21.9J mg/kg 04/09/15 07:11 7440-42-804/04/15 18:3723.5 11.7 5 Calcium 3970 mg/kg 04/09/15 07:11 7440-70-204/04/15 18:372351175 Chromium 23.4 mg/kg 04/09/15 07:11 7440-47-304/04/15 18:372.3 1.2 5 Copper 67.8 mg/kg 04/09/15 07:11 7440-50-804/04/15 18:372.3 1.2 5 Iron 9860 mg/kg 04/09/15 07:11 7439-89-604/04/15 18:3718.8 9.4 5 Magnesium 1410 mg/kg 04/09/15 07:11 7439-95-404/04/15 18:372351175 Manganese 79.5 mg/kg 04/09/15 07:11 7439-96-504/04/15 18:372.3 1.2 5 Molybdenum 3.8J mg/kg 04/09/15 07:11 7439-98-704/04/15 18:374.7 2.3 5 Nickel 33.8 mg/kg 04/09/15 07:11 7440-02-004/04/15 18:372.3 1.2 5 Potassium 2480 mg/kg 04/09/15 07:11 7440-09-704/04/15 18:374702355 Sodium 592 mg/kg 04/09/15 07:11 7440-23-504/04/15 18:374702355 Strontium 394 mg/kg 04/09/15 07:11 7440-24-604/04/15 18:374.7 2.3 5 Zinc 33.9 mg/kg 04/09/15 07:11 7440-66-604/04/15 18:379.4 4.7 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/07/15 12:57 7440-36-0 N204/04/15 18:374.7 2.3 50 Arsenic 51.4 mg/kg 04/07/15 12:57 7440-38-204/04/15 18:374.7 2.3 50 Cadmium 0.32J mg/kg 04/07/15 12:57 7440-43-904/04/15 18:370.56 0.28 50 Cobalt 19.5 mg/kg 04/07/15 12:57 7440-48-404/04/15 18:374.7 2.3 50 Lead 25.5 mg/kg 04/07/15 12:57 7439-92-104/04/15 18:374.7 2.3 50 Selenium 12.2 mg/kg 04/07/15 12:57 7782-49-204/04/15 18:374.7 2.3 50 Thallium ND mg/kg 04/07/15 12:57 7440-28-004/04/15 18:374.7 2.3 50 Vanadium 84.2 mg/kg 04/07/15 12:57 7440-62-204/04/15 18:374.7 2.3 50 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury 0.14 mg/kg 04/08/15 17:55 7439-97-604/08/15 07:420.015 0.0076 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 45.0 %04/07/15 21:250.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.5 Std. Units 04/08/15 22:000.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/03/15 08:09 16887-00-6 D34572285 Sulfate ND mg/kg 04/03/15 08:09 14808-79-8 D34572285 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/03/15 08:09 14797-55-8 H345.7 22.8 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 60 Page 34 of 72 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243245 J15030746 Sample:2015008932 Lab ID:92243245001 Collected:03/26/15 11:00 Received:03/30/15 15:10 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 89800 mg/kg 04/17/15 06:59 7440-44-01160058201 Total Organic Carbon 88600 mg/kg 04/17/15 07:05 7440-44-01170058701 Total Organic Carbon 91700 mg/kg 04/17/15 07:11 7440-44-01110055701 Total Organic Carbon 94000 mg/kg 04/17/15 07:17 7440-44-01180058801 Mean Total Organic Carbon 91000 mg/kg 04/17/15 06:59 7440-44-01160057901 Surrogates RSD%2.6 %04/17/15 06:591 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 60 Page 35 of 72 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243245 J15030746 Sample:2015008933 Lab ID:92243245002 Collected:03/26/15 12:15 Received:03/30/15 15:10 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 385 mg/kg 04/09/15 07:16 7429-90-504/04/15 18:3728.3 14.1 5 Barium ND mg/kg 04/09/15 07:16 7440-39-304/04/15 18:372.8 1.4 5 Beryllium ND mg/kg 04/09/15 07:16 7440-41-704/04/15 18:370.28 0.14 5 Boron ND mg/kg 04/09/15 07:16 7440-42-804/04/15 18:3714.1 7.1 5 Calcium ND mg/kg 04/09/15 07:16 7440-70-204/04/15 18:3714170.7 5 Chromium ND mg/kg 04/09/15 07:16 7440-47-304/04/15 18:371.4 0.71 5 Copper ND mg/kg 04/09/15 07:16 7440-50-804/04/15 18:371.4 0.71 5 Iron 211 mg/kg 04/09/15 07:16 7439-89-604/04/15 18:3711.3 5.7 5 Magnesium ND mg/kg 04/09/15 07:16 7439-95-404/04/15 18:3714170.7 5 Manganese ND mg/kg 04/09/15 07:16 7439-96-504/04/15 18:371.4 0.71 5 Molybdenum ND mg/kg 04/09/15 07:16 7439-98-704/04/15 18:372.8 1.4 5 Nickel ND mg/kg 04/09/15 07:16 7440-02-004/04/15 18:371.4 0.71 5 Potassium ND mg/kg 04/09/15 07:16 7440-09-704/04/15 18:372831415 Sodium ND mg/kg 04/09/15 07:16 7440-23-504/04/15 18:372831415 Strontium ND mg/kg 04/09/15 07:16 7440-24-604/04/15 18:372.8 1.4 5 Zinc ND mg/kg 04/09/15 07:16 7440-66-604/04/15 18:375.7 2.8 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/07/15 12:59 7440-36-0 N204/04/15 18:372.8 1.4 50 Arsenic ND mg/kg 04/07/15 12:59 7440-38-204/04/15 18:372.8 1.4 50 Cadmium ND mg/kg 04/07/15 12:59 7440-43-904/04/15 18:370.34 0.17 50 Cobalt ND mg/kg 04/07/15 12:59 7440-48-404/04/15 18:372.8 1.4 50 Lead ND mg/kg 04/07/15 12:59 7439-92-104/04/15 18:372.8 1.4 50 Selenium ND mg/kg 04/07/15 12:59 7782-49-204/04/15 18:372.8 1.4 50 Thallium ND mg/kg 04/07/15 12:59 7440-28-004/04/15 18:372.8 1.4 50 Vanadium ND mg/kg 04/07/15 12:59 7440-62-204/04/15 18:372.8 1.4 50 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/08/15 17:59 7439-97-604/08/15 07:420.0097 0.0049 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 14.9 %04/07/15 21:250.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.7 Std. Units 04/08/15 22:000.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/03/15 08:31 16887-00-6 D32881445 Sulfate ND mg/kg 04/03/15 08:31 14808-79-8 D32881445 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/03/15 08:31 14797-55-8 H328.8 14.4 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 60 Page 36 of 72 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243245 J15030746 Sample:2015008933 Lab ID:92243245002 Collected:03/26/15 12:15 Received:03/30/15 15:10 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 04/17/15 08:09 7440-44-07053531 Total Organic Carbon ND mg/kg 04/17/15 08:15 7440-44-07043521 Total Organic Carbon ND mg/kg 04/17/15 08:22 7440-44-07073531 Total Organic Carbon ND mg/kg 04/17/15 08:27 7440-44-07113551 Mean Total Organic Carbon ND mg/kg 04/17/15 08:09 7440-44-07073531 Surrogates RSD%3.4 %04/17/15 08:091 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 60 Page 37 of 72 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243245 J15030746 Sample:2015008934 Lab ID:92243245003 Collected:03/26/15 12:15 Received:03/30/15 15:10 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 351 mg/kg 04/09/15 07:20 7429-90-504/04/15 18:3730.9 15.4 5 Barium ND mg/kg 04/09/15 07:20 7440-39-304/04/15 18:373.1 1.5 5 Beryllium ND mg/kg 04/09/15 07:20 7440-41-704/04/15 18:370.31 0.15 5 Boron ND mg/kg 04/09/15 07:20 7440-42-804/04/15 18:3715.4 7.7 5 Calcium ND mg/kg 04/09/15 07:20 7440-70-204/04/15 18:3715477.2 5 Chromium ND mg/kg 04/09/15 07:20 7440-47-304/04/15 18:371.5 0.77 5 Copper ND mg/kg 04/09/15 07:20 7440-50-804/04/15 18:371.5 0.77 5 Iron 252 mg/kg 04/09/15 07:20 7439-89-604/04/15 18:3712.4 6.2 5 Magnesium ND mg/kg 04/09/15 07:20 7439-95-404/04/15 18:3715477.2 5 Manganese ND mg/kg 04/09/15 07:20 7439-96-504/04/15 18:371.5 0.77 5 Molybdenum ND mg/kg 04/09/15 07:20 7439-98-704/04/15 18:373.1 1.5 5 Nickel ND mg/kg 04/09/15 07:20 7440-02-004/04/15 18:371.5 0.77 5 Potassium ND mg/kg 04/09/15 07:20 7440-09-704/04/15 18:373091545 Sodium ND mg/kg 04/09/15 07:20 7440-23-504/04/15 18:373091545 Strontium ND mg/kg 04/09/15 07:20 7440-24-604/04/15 18:373.1 1.5 5 Zinc ND mg/kg 04/09/15 07:20 7440-66-604/04/15 18:376.2 3.1 5 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/07/15 13:02 7440-36-0 N204/04/15 18:373.1 1.5 50 Arsenic ND mg/kg 04/07/15 13:02 7440-38-204/04/15 18:373.1 1.5 50 Cadmium ND mg/kg 04/07/15 13:02 7440-43-904/04/15 18:370.37 0.19 50 Cobalt ND mg/kg 04/07/15 13:02 7440-48-404/04/15 18:373.1 1.5 50 Lead ND mg/kg 04/07/15 13:02 7439-92-104/04/15 18:373.1 1.5 50 Selenium ND mg/kg 04/07/15 13:02 7782-49-204/04/15 18:373.1 1.5 50 Thallium ND mg/kg 04/07/15 13:02 7440-28-004/04/15 18:373.1 1.5 50 Vanadium ND mg/kg 04/07/15 13:02 7440-62-204/04/15 18:373.1 1.5 50 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/08/15 18:02 7439-97-604/08/15 07:420.0093 0.0047 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 16.1 %04/07/15 21:250.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.7 Std. Units 04/08/15 22:000.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/03/15 08:52 16887-00-6 D3,M02951475 Sulfate ND mg/kg 04/03/15 08:52 14808-79-82951475 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/03/15 08:52 14797-55-8 H329.5 14.7 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 60 Page 38 of 72 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243245 J15030746 Sample:2015008934 Lab ID:92243245003 Collected:03/26/15 12:15 Received:03/30/15 15:10 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 04/17/15 08:34 7440-44-07193601 Total Organic Carbon ND mg/kg 04/17/15 08:40 7440-44-07173591 Total Organic Carbon 362J mg/kg 04/17/15 08:45 7440-44-07173581 Total Organic Carbon 390J mg/kg 04/17/15 08:50 7440-44-07203601 Mean Total Organic Carbon 360J mg/kg 04/17/15 08:34 7440-44-07183591 Surrogates RSD%6.4 %04/17/15 08:341 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 60 Page 39 of 72 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243245 J15030746 Sample:2015008935 Lab ID:92243245004 Collected:03/26/15 12:00 Received:03/30/15 15:10 Matrix:Solid Results reported on a "wet-weight" basis Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/06/15 18:30300.0 IC Anions, SPLP Sulfate 3.8 mg/L 04/09/15 18:44 14808-79-8 B2.0 1.0 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/06/15 18:30353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate ND mg/L 04/09/15 19:52 H10.20 0.20 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 04/06/15 18:304500 Chloride, SPLP Chloride ND mg/L 04/09/15 05:01 16887-00-65.0 2.5 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 60 Page 40 of 72 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243245 J15030746 Sample:2015008936 Lab ID:92243245005 Collected:03/26/15 12:00 Received:03/30/15 15:10 Matrix:Solid Results reported on a "wet-weight" basis Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/06/15 18:30300.0 IC Anions, SPLP Sulfate 2.9 mg/L 04/09/15 19:25 14808-79-8 B2.0 1.0 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/06/15 18:30353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate ND mg/L 04/09/15 20:01 H10.20 0.20 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 04/06/15 18:304500 Chloride, SPLP Chloride ND mg/L 04/09/15 05:02 16887-00-65.0 2.5 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 60 Page 41 of 72 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243245 J15030746 Sample:2015008937 Lab ID:92243245006 Collected:03/26/15 12:40 Received:03/30/15 15:10 Matrix:Solid Results reported on a "wet-weight" basis Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/06/15 18:30300.0 IC Anions, SPLP Sulfate 3.4 mg/L 04/09/15 19:39 14808-79-8 B2.0 1.0 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/06/15 18:30353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 0.23 mg/L 04/09/15 20:06 H10.20 0.20 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 04/06/15 18:304500 Chloride, SPLP Chloride ND mg/L 04/09/15 05:03 16887-00-65.0 2.5 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 60 Page 42 of 72 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243245 J15030746 Sample:2015008938 Lab ID:92243245007 Collected:03/26/15 10:25 Received:03/30/15 15:10 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 38.0 ug/L 04/06/15 08:09 7429-90-504/03/15 12:5210.0 3.0 1 Antimony ND ug/L 04/06/15 08:09 7440-36-004/03/15 12:520.50 0.15 1 Arsenic ND ug/L 04/06/15 08:09 7440-38-204/03/15 12:520.50 0.11 1 Barium 0.82 ug/L 04/06/15 08:09 7440-39-304/03/15 12:520.30 0.081 1 Beryllium ND ug/L 04/06/15 08:09 7440-41-704/03/15 12:520.20 0.067 1 Boron ND ug/L 04/06/15 08:09 7440-42-804/03/15 12:525.0 1.1 1 Cadmium ND ug/L 04/06/15 08:09 7440-43-904/03/15 12:520.080 0.024 1 Calcium 1560 ug/L 04/06/15 08:09 7440-70-204/03/15 12:5240.0 16.0 1 Chromium 1.8 ug/L 04/06/15 08:09 7440-47-304/03/15 12:520.50 0.17 1 Cobalt 0.54 ug/L 04/06/15 08:09 7440-48-404/03/15 12:520.50 0.13 1 Copper 1.3 ug/L 04/06/15 08:09 7440-50-804/03/15 12:521.0 0.21 1 Iron 478 ug/L 04/06/15 08:09 7439-89-604/03/15 12:5250.0 13.7 1 Lead 0.20 ug/L 04/06/15 08:09 7439-92-104/03/15 12:520.10 0.046 1 Magnesium 35.4 ug/L 04/06/15 08:09 7439-95-404/03/15 12:5210.0 3.2 1 Manganese 7.5 ug/L 04/06/15 08:09 7439-96-504/03/15 12:520.50 0.24 1 Molybdenum 0.60 ug/L 04/06/15 08:09 7439-98-704/03/15 12:520.50 0.094 1 Nickel ND ug/L 04/06/15 08:09 7440-02-004/03/15 12:520.50 0.16 1 Potassium ND ug/L 04/06/15 08:09 7440-09-704/03/15 12:5250.0 11.7 1 Selenium ND ug/L 04/06/15 08:09 7782-49-204/03/15 12:520.50 0.20 1 Sodium ND ug/L 04/06/15 08:09 7440-23-504/03/15 12:5250.0 16.3 1 Strontium 2.3 ug/L 04/06/15 08:09 7440-24-604/03/15 12:520.50 0.13 1 Thallium ND ug/L 04/06/15 08:09 7440-28-004/03/15 12:520.10 0.015 1 Vanadium ND ug/L 04/06/15 08:09 7440-62-204/03/15 12:521.0 0.28 1 Zinc 8.7 ug/L 04/06/15 08:09 7440-66-604/03/15 12:525.0 2.4 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 04/06/15 18:45 7439-97-604/04/15 17:200.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 60 Page 43 of 72 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243245 J15030746 Sample:2015008935 SPLP Lab ID:92243245008 Collected:03/26/15 12:00 Received:03/30/15 15:10 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 2080 ug/L 04/17/15 19:09 7429-90-504/15/15 22:1910.0 3.0 1 Antimony 2.8 ug/L 04/17/15 19:09 7440-36-004/15/15 22:190.50 0.15 1 Arsenic 24.5 ug/L 04/17/15 19:09 7440-38-204/15/15 22:190.50 0.11 1 Barium 285 ug/L 04/17/15 19:09 7440-39-304/15/15 22:190.30 0.081 1 Beryllium 0.54 ug/L 04/17/15 19:09 7440-41-704/15/15 22:190.20 0.067 1 Boron 160 ug/L 04/20/15 15:32 7440-42-804/15/15 22:1925.0 5.6 5 Cadmium ND ug/L 04/17/15 19:09 7440-43-904/15/15 22:190.080 0.024 1 Calcium 1720 ug/L 04/17/15 19:09 7440-70-204/15/15 22:1940.0 16.0 1 Chromium 4.2 ug/L 04/17/15 19:09 7440-47-304/15/15 22:190.50 0.17 1 Cobalt 1.2 ug/L 04/17/15 19:09 7440-48-404/15/15 22:190.50 0.13 1 Copper 11.4 ug/L 04/17/15 19:09 7440-50-804/15/15 22:191.0 0.21 1 Iron 737 ug/L 04/17/15 19:09 7439-89-604/15/15 22:1950.0 13.7 1 Lead 2.3 ug/L 04/17/15 19:09 7439-92-104/15/15 22:190.10 0.046 1 Magnesium 198 ug/L 04/17/15 19:09 7439-95-404/15/15 22:1910.0 3.2 1 Manganese 9.7 ug/L 04/17/15 19:09 7439-96-504/15/15 22:190.50 0.24 1 Molybdenum 24.0 ug/L 04/17/15 19:09 7439-98-704/15/15 22:190.50 0.094 1 Nickel 2.5 ug/L 04/17/15 19:09 7440-02-004/15/15 22:190.50 0.16 1 Potassium 98.8 ug/L 04/17/15 19:09 7440-09-704/15/15 22:1950.0 11.7 1 Selenium 2.1 ug/L 04/17/15 19:09 7782-49-204/15/15 22:190.50 0.20 1 Sodium 1340 ug/L 04/17/15 19:09 7440-23-504/15/15 22:1950.0 16.3 1 Strontium 56.0 ug/L 04/17/15 19:09 7440-24-604/15/15 22:190.50 0.13 1 Thallium 0.10 ug/L 04/17/15 19:09 7440-28-004/15/15 22:190.10 0.015 1 Vanadium 23.7 ug/L 04/20/15 15:32 7440-62-204/15/15 22:195.0 1.4 5 Zinc 46.1 ug/L 04/17/15 19:09 7440-66-604/15/15 22:195.0 2.4 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 04/16/15 20:15 7439-97-604/16/15 08:580.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 60 Page 44 of 72 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243245 J15030746 Sample:2015008936 SPLP Lab ID:92243245009 Collected:03/26/15 12:00 Received:03/30/15 15:10 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 1480 ug/L 04/17/15 19:13 7429-90-504/15/15 22:1910.0 3.0 1 Antimony 4.0 ug/L 04/17/15 19:13 7440-36-004/15/15 22:190.50 0.15 1 Arsenic 22.6 ug/L 04/17/15 19:13 7440-38-204/15/15 22:190.50 0.11 1 Barium 282 ug/L 04/17/15 19:13 7440-39-304/15/15 22:190.30 0.081 1 Beryllium 0.38 ug/L 04/17/15 19:13 7440-41-704/15/15 22:190.20 0.067 1 Boron 47.5 ug/L 04/20/15 15:37 7440-42-804/15/15 22:1925.0 5.6 5 Cadmium ND ug/L 04/17/15 19:13 7440-43-904/15/15 22:190.080 0.024 1 Calcium 1780 ug/L 04/17/15 19:13 7440-70-204/15/15 22:1940.0 16.0 1 Chromium 3.5 ug/L 04/17/15 19:13 7440-47-304/15/15 22:190.50 0.17 1 Cobalt 0.96 ug/L 04/17/15 19:13 7440-48-404/15/15 22:190.50 0.13 1 Copper 8.9 ug/L 04/17/15 19:13 7440-50-804/15/15 22:191.0 0.21 1 Iron 574 ug/L 04/17/15 19:13 7439-89-604/15/15 22:1950.0 13.7 1 Lead 1.7 ug/L 04/17/15 19:13 7439-92-104/15/15 22:190.10 0.046 1 Magnesium 174 ug/L 04/17/15 19:13 7439-95-404/15/15 22:1910.0 3.2 1 Manganese 9.2 ug/L 04/17/15 19:13 7439-96-504/15/15 22:190.50 0.24 1 Molybdenum 27.1 ug/L 04/17/15 19:13 7439-98-704/15/15 22:190.50 0.094 1 Nickel 2.1 ug/L 04/17/15 19:13 7440-02-004/15/15 22:190.50 0.16 1 Potassium 259 ug/L 04/17/15 19:13 7440-09-704/15/15 22:1950.0 11.7 1 Selenium 4.2 ug/L 04/17/15 19:13 7782-49-204/15/15 22:190.50 0.20 1 Sodium 321 ug/L 04/17/15 19:13 7440-23-504/15/15 22:1950.0 16.3 1 Strontium 56.5 ug/L 04/17/15 19:13 7440-24-604/15/15 22:190.50 0.13 1 Thallium ND ug/L 04/17/15 19:13 7440-28-004/15/15 22:190.10 0.015 1 Vanadium 22.6 ug/L 04/20/15 15:37 7440-62-204/15/15 22:195.0 1.4 5 Zinc 66.1 ug/L 04/17/15 19:13 7440-66-604/15/15 22:195.0 2.4 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 04/16/15 20:18 7439-97-604/16/15 08:580.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 60 Page 45 of 72 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92243245 J15030746 Sample:2015008937 SPLP Lab ID:92243245010 Collected:03/26/15 12:40 Received:03/30/15 15:10 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 1470 ug/L 04/17/15 19:18 7429-90-504/15/15 22:1910.0 3.0 1 Antimony ND ug/L 04/17/15 19:18 7440-36-004/15/15 22:190.50 0.15 1 Arsenic 0.71 ug/L 04/17/15 19:18 7440-38-204/15/15 22:190.50 0.11 1 Barium 70.0 ug/L 04/17/15 19:18 7440-39-304/15/15 22:190.30 0.081 1 Beryllium ND ug/L 04/17/15 19:18 7440-41-704/15/15 22:190.20 0.067 1 Boron 38.9 ug/L 04/20/15 15:42 7440-42-804/15/15 22:195.0 1.1 1 Cadmium ND ug/L 04/17/15 19:18 7440-43-904/15/15 22:190.080 0.024 1 Calcium 580 ug/L 04/17/15 19:18 7440-70-204/15/15 22:1940.0 16.0 1 Chromium 1.1 ug/L 04/17/15 19:18 7440-47-304/15/15 22:190.50 0.17 1 Cobalt ND ug/L 04/17/15 19:18 7440-48-404/15/15 22:190.50 0.13 1 Copper ND ug/L 04/17/15 19:18 7440-50-804/15/15 22:191.0 0.21 1 Iron 365 ug/L 04/17/15 19:18 7439-89-604/15/15 22:1950.0 13.7 1 Lead 0.42 ug/L 04/17/15 19:18 7439-92-104/15/15 22:190.10 0.046 1 Magnesium 70.5 ug/L 04/17/15 19:18 7439-95-404/15/15 22:1910.0 3.2 1 Manganese 3.1 ug/L 04/17/15 19:18 7439-96-504/15/15 22:190.50 0.24 1 Molybdenum 0.69 ug/L 04/17/15 19:18 7439-98-704/15/15 22:190.50 0.094 1 Nickel 0.56 ug/L 04/17/15 19:18 7440-02-004/15/15 22:190.50 0.16 1 Potassium ND ug/L 04/17/15 19:18 7440-09-704/15/15 22:1950.0 11.7 1 Selenium ND ug/L 04/17/15 19:18 7782-49-204/15/15 22:190.50 0.20 1 Sodium 713 ug/L 04/17/15 19:18 7440-23-504/15/15 22:1950.0 16.3 1 Strontium 10.4 ug/L 04/17/15 19:18 7440-24-604/15/15 22:190.50 0.13 1 Thallium ND ug/L 04/17/15 19:18 7440-28-004/15/15 22:190.10 0.015 1 Vanadium 1.9 ug/L 04/20/15 15:42 7440-62-204/15/15 22:191.0 0.28 1 Zinc 35.0 ug/L 04/17/15 19:18 7440-66-604/15/15 22:195.0 2.4 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 04/16/15 20:20 7439-97-604/16/15 08:580.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 36 of 60 Page 46 of 72 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243245 J15030746 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/13139 EPA 7470 EPA 7470 7470 Mercury Associated Lab Samples:92243245007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1932636 Associated Lab Samples:92243245007 Matrix:Water Analyzed Mercury ug/L ND 0.20 04/06/15 18:28 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1932637LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 5.85 116 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1932638MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92239540007 1932639 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L H31510775-125106 1 2015ND16.1 16.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 37 of 60 Page 47 of 72 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243245 J15030746 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/13232 EPA 7470 EPA 7470 7470 Mercury Associated Lab Samples:92243245008, 92243245009, 92243245010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1939457 Associated Lab Samples:92243245008, 92243245009, 92243245010 Matrix:Water Analyzed Mercury ug/L ND 0.20 04/16/15 19:16 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1939458LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 4.75 94 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1939459MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245092001 1939460 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 95 75-12596 2 205ND4.7 4.8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 38 of 60 Page 48 of 72 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243245 J15030746 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/5560 EPA 7471 EPA 7471 7471 Mercury Associated Lab Samples:92243245001, 92243245002, 92243245003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1176776 Associated Lab Samples:92243245001, 92243245002, 92243245003 Matrix:Solid Analyzed Mercury mg/kg ND 0.0083 04/08/15 17:40 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1176777LABORATORY CONTROL SAMPLE: LCSSpike Mercury mg/kg 0.077.079 98 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1176778MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 35181733001 1176779 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury mg/kg 1.14 82 80-12085 5 201.140.056U 0.94 0.99 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 39 of 60 Page 49 of 72 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243245 J15030746 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/23429 EPA 3050 EPA 6010 6010 MET Solid Associated Lab Samples:92243245001, 92243245002, 92243245003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1174969 Associated Lab Samples:92243245001, 92243245002, 92243245003 Matrix:Solid Analyzed Aluminum mg/kg ND 5.1 04/09/15 06:25 Barium mg/kg ND 0.51 04/09/15 06:25 Beryllium mg/kg ND 0.051 04/09/15 06:25 Boron mg/kg ND 2.6 04/09/15 06:25 Calcium mg/kg ND 25.7 04/09/15 06:25 Chromium mg/kg ND 0.26 04/09/15 06:25 Copper mg/kg ND 0.26 04/09/15 06:25 Iron mg/kg ND 2.1 04/09/15 06:25 Magnesium mg/kg ND 25.7 04/09/15 06:25 Manganese mg/kg ND 0.26 04/09/15 06:25 Molybdenum mg/kg ND 0.51 04/09/15 06:25 Nickel mg/kg ND 0.26 04/09/15 06:25 Potassium mg/kg ND 51.4 04/09/15 06:25 Sodium mg/kg ND 51.4 04/09/15 06:25 Strontium mg/kg ND 0.51 04/09/15 06:25 Zinc mg/kg ND 1.0 04/09/15 06:25 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1174970LABORATORY CONTROL SAMPLE: LCSSpike Aluminum mg/kg 123126 98 80-120 Barium mg/kg 12.512.6 99 80-120 Beryllium mg/kg 1.21.3 98 80-120 Boron mg/kg 123126 98 80-120 Calcium mg/kg 621629 99 80-120 Chromium mg/kg 12.312.6 98 80-120 Copper mg/kg 12.212.6 97 80-120 Iron mg/kg 120126 96 80-120 Magnesium mg/kg 612629 97 80-120 Manganese mg/kg 12.412.6 98 80-120 Molybdenum mg/kg 11.912.6 95 80-120 Nickel mg/kg 12.212.6 97 80-120 Potassium mg/kg 603629 96 80-120 Sodium mg/kg 626629 100 80-120 Strontium mg/kg 12.312.6 98 80-120 Zinc mg/kg 61.962.9 98 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 40 of 60 Page 50 of 72 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243245 J15030746 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1174971MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92242920018 1174972 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum mg/kg M1166166075-1252220 11 2018380601080012100 Barium mg/kg M1,R116.6 -660 75-125388 22 2018.3833 723 904 Beryllium mg/kg R11.7 84 75-125125 26 201.841.5 2.9 3.8 Boron mg/kg 166 97 75-12598 9 2018314.7J 176 193 Calcium mg/kg 829 88 75-125120 16 20913134020702440 Chromium mg/kg M116.6 129 75-125109 5 2018.310.6 32.0 30.5 Copper mg/kg M116.6 74 75-125101 14 2018.328.0 40.3 46.5 Iron mg/kg M1166103075-1251120 3 2018393801110011400 Magnesium mg/kg M182911175-125138 17 2091391818402170 Manganese mg/kg M116.6 129 75-125133 5 2018.340.4 61.9 64.8 Molybdenum mg/kg 16.6 88 75-12589 10 2018.3ND 15.9 17.5 Nickel mg/kg 16.6 105 75-125114 12 2018.38.6 26.1 29.5 Potassium mg/kg M1,R182910275-125207 32 20913187027203750 Sodium mg/kg 829 105 75-125114 14 20913251J11201290 Strontium mg/kg M1,R116.6 24 75-125218 36 2018.377.1 81.2 117 Zinc mg/kg 82.9 100 75-125103 11 2091.312.3 94.9 106 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 41 of 60 Page 51 of 72 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243245 J15030746 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/23430 EPA 3050 EPA 6020 6020 MET SOLID Associated Lab Samples:92243245001, 92243245002, 92243245003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1174973 Associated Lab Samples:92243245001, 92243245002, 92243245003 Matrix:Solid Analyzed Antimony mg/kg ND 0.052 N204/07/15 12:23 Arsenic mg/kg ND 0.052 04/07/15 12:23 Cadmium mg/kg ND 0.0063 04/07/15 12:23 Cobalt mg/kg ND 0.052 04/07/15 12:23 Lead mg/kg ND 0.052 04/07/15 12:23 Selenium mg/kg ND 0.052 04/07/15 12:23 Thallium mg/kg ND 0.052 04/07/15 12:23 Vanadium mg/kg ND 0.052 04/07/15 12:23 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1174974LABORATORY CONTROL SAMPLE: LCSSpike Antimony mg/kg 2.5 N22.6 96 80-120 Arsenic mg/kg 2.72.6 106 80-120 Cadmium mg/kg 0.27.26 104 80-120 Cobalt mg/kg 2.72.6 106 80-120 Lead mg/kg 2.62.6 100 80-120 Selenium mg/kg 2.72.6 103 80-120 Thallium mg/kg 2.62.6 99 80-120 Vanadium mg/kg 2.72.6 104 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1174975MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92242920019 1174976 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony mg/kg M6,N23.38 49 75-12544 203.52ND 2.8J 2.6J Arsenic mg/kg M63.38 -97 75-125197 13 203.5274.5 71.3 81.3 Cadmium mg/kg .338 110 75-12582 15 20.3520.24J 0.61 0.52 Cobalt mg/kg 3.38 107 75-125111 2 203.525.6 9.2 9.5 Lead mg/kg M63.38 141 75-12585 12 203.5211.7 16.4 14.6 Selenium mg/kg M63.38 60 75-12557 1 203.523.9 5.9 5.9 Thallium mg/kg M63.38 74 75-12572 0 203.52ND 3.6 3.6 Vanadium mg/kg M63.38 327 75-125112 15 203.5239.4 50.4 43.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 42 of 60 Page 52 of 72 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243245 J15030746 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/53349 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92243245007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1931408 Associated Lab Samples:92243245007 Matrix:Water Analyzed Aluminum ug/L ND 10.0 04/06/15 07:50 Antimony ug/L ND 0.50 04/06/15 07:50 Arsenic ug/L ND 0.50 04/06/15 07:50 Barium ug/L ND 0.30 04/06/15 07:50 Beryllium ug/L ND 0.20 04/06/15 07:50 Boron ug/L ND 5.0 04/06/15 07:50 Cadmium ug/L ND 0.080 04/06/15 07:50 Calcium ug/L ND 40.0 04/06/15 07:50 Chromium ug/L ND 0.50 04/06/15 07:50 Cobalt ug/L ND 0.50 04/06/15 07:50 Copper ug/L ND 1.0 04/06/15 07:50 Iron ug/L ND 50.0 04/06/15 07:50 Lead ug/L ND 0.10 04/06/15 07:50 Magnesium ug/L ND 10.0 04/06/15 07:50 Manganese ug/L ND 0.50 04/06/15 07:50 Molybdenum ug/L ND 0.50 04/06/15 07:50 Nickel ug/L ND 0.50 04/06/15 07:50 Potassium ug/L ND 50.0 04/06/15 07:50 Selenium ug/L ND 0.50 04/06/15 07:50 Sodium ug/L ND 50.0 04/06/15 07:50 Strontium ug/L ND 0.50 04/06/15 07:50 Thallium ug/L ND 0.10 04/06/15 07:50 Vanadium ug/L ND 1.0 04/06/15 07:50 Zinc ug/L ND 5.0 04/06/15 07:50 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1931409LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 85.580 107 80-120 Antimony ug/L 80.180 100 80-120 Arsenic ug/L 80.580 101 80-120 Barium ug/L 80.480 101 80-120 Beryllium ug/L 80.580 101 80-120 Boron ug/L 82.680 103 80-120 Cadmium ug/L 81.680 102 80-120 Calcium ug/L 9551000 96 80-120 Chromium ug/L 82.780 103 80-120 Cobalt ug/L 79.780 100 80-120 Copper ug/L 78.780 98 80-120 Iron ug/L 10401000 104 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 43 of 60 Page 53 of 72 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243245 J15030746 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1931409LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 82.280 103 80-120 Magnesium ug/L 9781000 98 80-120 Manganese ug/L 81.380 102 80-120 Molybdenum ug/L 79.280 99 80-120 Nickel ug/L 80.280 100 80-120 Potassium ug/L 10201000 102 80-120 Selenium ug/L 80.180 100 80-120 Sodium ug/L 10001000 100 80-120 Strontium ug/L 79.980 100 80-120 Thallium ug/L 80.480 101 80-120 Vanadium ug/L 80.080 100 80-120 Zinc ug/L 84.480 106 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1931410MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243088001 1931411 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L 80 113 75-125108 4 2080ND94.2 90.2 Antimony ug/L 80 98 75-125101 3 2080ND78.6 81.2 Arsenic ug/L 80 100 75-125103 3 2080ND80.0 82.5 Barium ug/L 80 100 75-125100 1 2080ND79.8 80.3 Beryllium ug/L 80 103 75-125101 2 2080ND82.4 80.6 Boron ug/L 80 104 75-125100 4 2080ND83.9 81.0 Cadmium ug/L 80 101 75-125102 0 2080ND81.0 81.3 Calcium ug/L 1000 88 75-12595 8 201000ND882953 Chromium ug/L 80 102 75-125104 1 2080ND81.8 82.8 Cobalt ug/L 80 100 75-12599 0 2080ND79.9 79.6 Copper ug/L 80 99 75-12599 0 2080ND79.3 79.0 Iron ug/L 1000 103 75-125104 1 201000ND10301040 Lead ug/L 80 102 75-125103 2 2080ND81.4 82.8 Magnesium ug/L 1000 96 75-12598 2 201000ND959978 Manganese ug/L 80 101 75-125103 1 2080ND81.1 82.1 Molybdenum ug/L 80 99 75-12599 0 2080ND79.0 78.9 Nickel ug/L 80 101 75-125100 1 2080ND80.5 79.6 Potassium ug/L 1000 103 75-125103 0 201000ND10301030 Selenium ug/L 80 102 75-125101 1 2080ND81.5 80.8 Sodium ug/L 1000 101 75-125100 1 201000ND10101000 Strontium ug/L 80 100 75-125100 0 2080ND79.9 79.8 Thallium ug/L 80 103 75-125105 2 2080ND82.6 83.8 Vanadium ug/L 80 100 75-125100 0 2080ND79.7 80.0 Zinc ug/L 80 105 75-125104 1 2080ND85.3 84.7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 44 of 60 Page 54 of 72 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243245 J15030746 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/53628 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92243245008, 92243245009, 92243245010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1939436 Associated Lab Samples:92243245008, 92243245009, 92243245010 Matrix:Water Analyzed Aluminum ug/L ND 10.0 04/17/15 17:03 Antimony ug/L ND 0.50 04/17/15 17:03 Arsenic ug/L ND 0.50 04/17/15 17:03 Barium ug/L ND 0.30 04/17/15 17:03 Beryllium ug/L ND 0.20 04/17/15 17:03 Boron ug/L ND 5.0 04/17/15 17:03 Cadmium ug/L ND 0.080 04/17/15 17:03 Calcium ug/L ND 40.0 04/20/15 14:02 Chromium ug/L ND 0.50 04/17/15 17:03 Cobalt ug/L ND 0.50 04/17/15 17:03 Copper ug/L ND 1.0 04/17/15 17:03 Iron ug/L ND 50.0 04/17/15 17:03 Lead ug/L ND 0.10 04/17/15 17:03 Magnesium ug/L ND 10.0 04/17/15 17:03 Manganese ug/L ND 0.50 04/17/15 17:03 Molybdenum ug/L ND 0.50 04/17/15 17:03 Nickel ug/L ND 0.50 04/17/15 17:03 Potassium ug/L ND 50.0 04/17/15 17:03 Selenium ug/L ND 0.50 04/17/15 17:03 Sodium ug/L ND 50.0 04/17/15 17:03 Strontium ug/L ND 0.50 04/17/15 17:03 Thallium ug/L ND 0.10 04/17/15 17:03 Vanadium ug/L ND 1.0 04/17/15 17:03 Zinc ug/L ND 5.0 04/17/15 17:03 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1939437LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 78.080 98 80-120 Antimony ug/L 76.980 96 80-120 Arsenic ug/L 78.280 98 80-120 Barium ug/L 76.580 96 80-120 Beryllium ug/L 68.980 86 80-120 Boron ug/L 79.480 99 80-120 Cadmium ug/L 76.680 96 80-120 Calcium ug/L 10601000 106 80-120 Chromium ug/L 77.180 96 80-120 Cobalt ug/L 77.980 97 80-120 Copper ug/L 80.480 101 80-120 Iron ug/L 9771000 98 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 45 of 60 Page 55 of 72 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243245 J15030746 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1939437LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 76.980 96 80-120 Magnesium ug/L 9511000 95 80-120 Manganese ug/L 77.180 96 80-120 Molybdenum ug/L 77.880 97 80-120 Nickel ug/L 80.180 100 80-120 Potassium ug/L 9911000 99 80-120 Selenium ug/L 79.480 99 80-120 Sodium ug/L 9511000 95 80-120 Strontium ug/L 77.180 96 80-120 Thallium ug/L 77.380 97 80-120 Vanadium ug/L 81.380 102 80-120 Zinc ug/L 79.280 99 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1939446MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245087005 1939447 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L 80 120 75-125102 16 2080ND98.4 83.9 Antimony ug/L 80 96 75-12597 1 2080ND76.9 77.7 Arsenic ug/L 80 97 75-12597 1 2080ND77.2 78.0 Barium ug/L 80 95 75-12596 1 2080ND76.5 77.2 Beryllium ug/L 80 85 75-12586 1 2080ND68.0 68.6 Boron ug/L 80 97 75-12595 1 2080ND79.4 78.5 Cadmium ug/L 80 94 75-12597 2 2080ND75.6 77.2 Calcium ug/L 1000 106 75-125100 5 20100066.3 1130 1070 Chromium ug/L 80 97 75-12599 2 20800.50 78.2 79.8 Cobalt ug/L 80 96 75-12598 2 2080ND76.9 78.1 Copper ug/L 80 100 75-125101 1 2080ND80.2 80.9 Iron ug/L 1000 98 75-12599 1 201000ND9931010 Lead ug/L 80 96 75-12598 2 2080ND76.7 78.3 Magnesium ug/L 1000 95 75-12597 2 20100011.0 961 983 Manganese ug/L 80 96 75-12597 1 20800.78 77.4 78.5 Molybdenum ug/L 80 96 75-12597 1 2080ND76.8 77.4 Nickel ug/L 80 100 75-125102 2 20801.1 80.8 82.4 Potassium ug/L 1000 97 75-12598 1 201000ND984994 Selenium ug/L 80 98 75-12599 1 2080ND78.8 79.4 Sodium ug/L 1000 94 75-12593 1 20100056.3 999 985 Strontium ug/L 80 96 75-12598 2 2080ND76.8 78.4 Thallium ug/L 80 99 75-125101 2 2080ND79.6 80.8 Vanadium ug/L 80 101 75-125101 0 2080ND81.2 80.8 Zinc ug/L 80 96 75-12597 1 2080ND80.7 81.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 46 of 60 Page 56 of 72 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243245 J15030746 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: PMST/3420 ASTM D2974-87 ASTM D2974-87 Dry Weight/Percent Moisture Associated Lab Samples:92243245001, 92243245002, 92243245003 Parameter Units Dup Result Max RPD QualifiersRPDResult 35181339021 1176728SAMPLE DUPLICATE: Percent Moisture %5.3 D624106.7 Parameter Units Dup Result Max RPD QualifiersRPDResult 35181841005 1176729SAMPLE DUPLICATE: Percent Moisture %17.1 8 1018.5 Parameter Units Dup Result Max RPD QualifiersRPDResult 35181980001 1176730SAMPLE DUPLICATE: Percent Moisture %1.0 D62410 Parameter Units Dup Result Max RPD QualifiersRPDResult 35181986001 1176731SAMPLE DUPLICATE: Percent Moisture %ND 100.10U Parameter Units Dup Result Max RPD QualifiersRPDResult 35182043001 1176732SAMPLE DUPLICATE: Percent Moisture %ND 100.10U Parameter Units Dup Result Max RPD QualifiersRPDResult 35182053001 1176733SAMPLE DUPLICATE: Percent Moisture %ND 100.51 Parameter Units Dup Result Max RPD QualifiersRPDResult 35182064001 1176734SAMPLE DUPLICATE: Percent Moisture %ND 100.78 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 47 of 60 Page 57 of 72 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243245 J15030746 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 35182075001 1176735SAMPLE DUPLICATE: Percent Moisture %0.66 100.10U Parameter Units Dup Result Max RPD QualifiersRPDResult 35182085001 1176736SAMPLE DUPLICATE: Percent Moisture %1.7 D620101.4 Parameter Units Dup Result Max RPD QualifiersRPDResult 35182211003 1176737SAMPLE DUPLICATE: Percent Moisture %2.2 D643101.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 48 of 60 Page 58 of 72 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243245 J15030746 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/36660 EPA 9045 EPA 9045 9045 pH Associated Lab Samples:92243245001, 92243245002, 92243245003 Parameter Units Dup Result Max RPD QualifiersRPDResult 92243088009 1427812SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 7.0 1 106.9 Parameter Units Dup Result Max RPD QualifiersRPDResult 92243096004 1427813SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 4.8 0 104.8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 49 of 60 Page 59 of 72 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243245 J15030746 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22495 EPA 300.0 EPA 300.0 300.0 IC Anions Associated Lab Samples:92243245004, 92243245005, 92243245006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1430392 Associated Lab Samples:92243245004, 92243245005, 92243245006 Matrix:Water Analyzed Sulfate mg/L 3.4 2.0 04/09/15 16:42 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1430393LABORATORY CONTROL SAMPLE: LCSSpike Sulfate mg/L 19.320 96 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1430394MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243096002 1430395 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate mg/L 20.6 90 89 120.63.9 22.4 22.3 Parameter Units MS Result % Rec Limits Qual% RecConc. 1430396MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243393001 1430397 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate mg/L 37.9 93 94 137.911.3 46.4 46.7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 50 of 60 Page 60 of 72 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243245 J15030746 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22501 EPA 353.2 EPA 353.2 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples:92243245004, 92243245005, 92243245006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1431026 Associated Lab Samples:92243245004, 92243245005, 92243245006 Matrix:Water Analyzed Nitrogen, Nitrate mg/L 0.16 0.020 Z204/09/15 19:46 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1431027LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Nitrate mg/L 2.42.5 97 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1431028MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243245004 1431029 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L H12.5 102 90-110102 0 102.5ND 2.7 2.7 Parameter Units MS Result % Rec Limits Qual% RecConc. 1431030MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243245005 1431031 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L H12.5 92 90-11092 0 102.5ND 2.5 2.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 51 of 60 Page 61 of 72 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243245 J15030746 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22491 SM 4500-Cl-E SM 4500-Cl-E 4500 Chloride Associated Lab Samples:92243245004, 92243245005, 92243245006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1430197 Associated Lab Samples:92243245004, 92243245005, 92243245006 Matrix:Water Analyzed Chloride mg/L ND 1.0 04/09/15 04:54 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1430198LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/L 21.220 106 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1430199MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243096002 1430200 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L M120.6 110 90-110111 1 1020.63.9J 26.6 26.7 Parameter Units MS Result % Rec Limits Qual% RecConc. 1430201MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243393001 1430202 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L 37.9 102 90-110101 1 1037.9ND 40.2 39.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 52 of 60 Page 62 of 72 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243245 J15030746 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/45049 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92243245001, 92243245002, 92243245003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1172374 Associated Lab Samples: Matrix:Solid Analyzed Chloride mg/kg ND 49.5 04/03/15 00:40 Sulfate mg/kg ND 49.5 04/03/15 00:40 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1172376LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/kg 524497 105 80-120 Sulfate mg/kg 513497 103 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1172378MATRIX SPIKE SAMPLE: MSSpike Result 92243245003 Chloride mg/kg 1010 M011907780-120ND Sulfate mg/kg 10401190 88 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92243245003 1172377SAMPLE DUPLICATE: Chloride mg/kg ND 20ND Sulfate mg/kg ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 53 of 60 Page 63 of 72 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243245 J15030746 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/45063 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92243245001, 92243245002, 92243245003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1172585 Associated Lab Samples: Matrix:Solid Analyzed Nitrate as N mg/kg ND 5.0 04/03/15 00:40 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1172586LABORATORY CONTROL SAMPLE: LCSSpike Nitrate as N mg/kg 52.649.7 106 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1172588MATRIX SPIKE SAMPLE: MSSpike Result 92243245003 Nitrate as N mg/kg 107 H31199180-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92243245003 1172587SAMPLE DUPLICATE: Nitrate as N mg/kg ND H320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 54 of 60 Page 64 of 72 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92243245 J15030746 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/28037 EPA 9060 EPA 9060 9060 TOC Average Associated Lab Samples:92243245001, 92243245002, 92243245003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1141398 Associated Lab Samples: Matrix:Solid Analyzed Mean Total Organic Carbon mg/kg ND 600 04/17/15 05:46 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1141399LABORATORY CONTROL SAMPLE: LCSSpike Mean Total Organic Carbon mg/kg 114000120000 95 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1141400MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243245001 1141401 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 114000 89 50-150101 6 3011300091000193000205000 Parameter Units MS Result % Rec Limits Qual% RecConc. 1141402MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243090001 1141403 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 6640 99 50-15087 12 306650334J69106120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 55 of 60 Page 65 of 72 #=QL# QUALIFIERS Pace Project No.: Project: 92243245 J15030746 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - Green BayPASI-G Pace Analytical Services - MinneapolisPASI-M Pace Analytical Services - Ormond BeachPASI-O ANALYTE QUALIFIERS Analyte was detected in the associated method blank.B Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6 Analysis conducted outside the EPA method holding time.H1 Sample was received or analysis requested beyond the recognized method holding time.H3 Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6 The lab does not hold TNI accreditation for this parameter.N2 RPD value was outside control limits.R1 Analyte present in the associated method blank above the detection limit.Z2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 56 of 60 Page 66 of 72 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92243245 J15030746 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92243245001 MPRP/23429 ICP/143302015008932EPA 3050 EPA 6010 92243245002 MPRP/23429 ICP/143302015008933EPA 3050 EPA 6010 92243245003 MPRP/23429 ICP/143302015008934EPA 3050 EPA 6010 92243245001 MPRP/23430 ICPM/95412015008932EPA 3050 EPA 6020 92243245002 MPRP/23430 ICPM/95412015008933EPA 3050 EPA 6020 92243245003 MPRP/23430 ICPM/95412015008934EPA 3050 EPA 6020 92243245007 MPRP/53349 ICPM/236722015008938EPA 3020 EPA 6020A 92243245008 MPRP/53628 ICPM/238392015008935 SPLP EPA 3020 EPA 6020A 92243245009 MPRP/53628 ICPM/238392015008936 SPLP EPA 3020 EPA 6020A 92243245010 MPRP/53628 ICPM/238392015008937 SPLP EPA 3020 EPA 6020A 92243245007 MERP/13139 MERC/152542015008938EPA 7470 EPA 7470 92243245008 MERP/13232 MERC/153872015008935 SPLP EPA 7470 EPA 7470 92243245009 MERP/13232 MERC/153872015008936 SPLP EPA 7470 EPA 7470 92243245010 MERP/13232 MERC/153872015008937 SPLP EPA 7470 EPA 7470 92243245001 MERP/5560 MERC/55492015008932EPA 7471 EPA 7471 92243245002 MERP/5560 MERC/55492015008933EPA 7471 EPA 7471 92243245003 MERP/5560 MERC/55492015008934EPA 7471 EPA 7471 92243245001 PMST/34202015008932ASTM D2974-87 92243245002 PMST/34202015008933ASTM D2974-87 92243245003 PMST/34202015008934ASTM D2974-87 92243245001 WET/366602015008932EPA 9045 92243245002 WET/366602015008933EPA 9045 92243245003 WET/366602015008934EPA 9045 92243245004 WETA/224952015008935EPA 300.0 92243245005 WETA/224952015008936EPA 300.0 92243245006 WETA/224952015008937EPA 300.0 92243245004 WETA/225012015008935EPA 353.2 92243245005 WETA/225012015008936EPA 353.2 92243245006 WETA/225012015008937EPA 353.2 92243245004 WETA/224912015008935SM 4500-Cl-E 92243245005 WETA/224912015008936SM 4500-Cl-E 92243245006 WETA/224912015008937SM 4500-Cl-E 92243245001 WETA/450492015008932EPA 9056 92243245002 WETA/450492015008933EPA 9056 92243245003 WETA/450492015008934EPA 9056 92243245001 WETA/450632015008932EPA 9056 92243245002 WETA/450632015008933EPA 9056 92243245003 WETA/450632015008934EPA 9056 92243245001 WETA/280372015008932EPA 9060 92243245001 WETA/280382015008932EPA 9060 92243245002 WETA/280372015008933EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 57 of 60 Page 67 of 72 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92243245 J15030746 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92243245002 WETA/280382015008933EPA 9060 92243245003 WETA/280372015008934EPA 9060 92243245003 WETA/280382015008934EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/27/2015 01:46 PM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 58 of 60 Page 68 of 72 Page 59 of 60 Page 69 of 72 Page 60 of 60 Page 70 of 72 Page 71 of 72 Page 72 of 72