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HomeMy WebLinkAboutNC0001422_ATT 5 - Soil - J15030673 Report_2015080513339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Analytical Laboratory Order Number:J15030673 Project Name:AB GW ASSESSMENT SOIL Lab Contact:Margaret Galvin-Karr Date:4/22/2015 Customer Address: Customer Name(s):Perry Waldrep, Tim Hunsucker, Kathy Webb, John Toepfer Phone: 980-875-5219 Report Authorized By: (Signature) Program Comments: Please contact the Program Manager (Margaret Galvin-Karr) with any questions regarding this report. Data Flags & Calculations: Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Margaret Galvin-Karr Page 1 of 80 Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015008539 Sutton 24-Mar-15 8:00 AM ILLEGIBLE Well SW-2C 0-2' 2015008540 Sutton 24-Mar-15 9:15 AM ILLEGIBLE Well SW-2C 8-10' 2015008541 Sutton 24-Mar-15 11:15 AM ILLEGIBLE Well SW-2C 43-45' 2015008542 Sutton 24-Mar-15 4:00 PM ILLEGIBLE Well SW-3C 0-2' 2015008543 Sutton 24-Mar-15 4:30 PM ILLEGIBLE Well SW-3C 10-12' 2015008544 Sutton 24-Mar-15 5:00 PM ILLEGIBLE Well SW-3C 41-43' 2015008545 Sutton 24-Mar-15 4:05 PM ILLEGIBLE Well SW-3 Equip Blank 2015008546 Sutton 24-Mar-15 8:15 AM ILLEGIBLE Well SW-2 Mini-Sonic 8 Total Samples Page 2 of 80 COC and .pdf report are in agreement with sample totals and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. All laboratory QA/QC requirements are acceptable. Yes No Technical Validation Review Checklist: Yes No Yes No Report Sections Included: Job Summary Report Sub-contracted Laboratory Results Sample Identification Customer Specific Data Sheets, Reports, & Documentation Technical Validation of Data Package Customer Database Entries Analytical Laboratory Certificate of Analysis Analytical Laboratory QC Report Chain of Custody Reviewed By:DBA Account Date:4/22/2015 Electronic Data Deliverable (EDD) Sent Separately Page 3 of 80 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030673 2015008539 Collection Date:24-Mar-15 8:00 AM Site:Well SW-2C 0-2' Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 4 of 80 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030673 2015008540 Collection Date:24-Mar-15 9:15 AM Site:Well SW-2C 8-10' Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 5 of 80 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030673 2015008541 Collection Date:24-Mar-15 11:15 AM Site:Well SW-2C 43-45' Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 6 of 80 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030673 2015008542 Collection Date:24-Mar-15 4:00 PM Site:Well SW-3C 0-2' Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 7 of 80 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030673 2015008543 Collection Date:24-Mar-15 4:30 PM Site:Well SW-3C 10-12' Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 8 of 80 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030673 2015008544 Collection Date:24-Mar-15 5:00 PM Site:Well SW-3C 41-43' Matrix:SOIL Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 9 of 80 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030673 2015008545 Collection Date:24-Mar-15 4:05 PM Site:Well SW-3 Equip Blank Matrix:OTHER Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 10 of 80 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15030673 2015008546 Collection Date:24-Mar-15 8:15 AM Site:Well SW-2 Mini-Sonic Matrix:OTHER Analyte Analysis Date/TimeMethodUnits Qualifiers RDLResult Sample #: AnalystDF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE Page 11 of 80 #=CL# April 21, 2015 LIMS USE: FR - PROGRAM MANAGER LIMS OBJECT ID: 92242955 92242955 Project: Pace Project No.: RE: Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 J15030673 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on March 26, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc:Marge Galvin-Karr, Duke Energy Program Manager, Duke Energy Rodney Wike, Duke Energy REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 68 Page 12 of 80 #=CP# CERTIFICATIONS Pace Project No.: Project: 92242955 J15030673 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A2LA Certification #: 2926.01 Alaska Certification #: UST-078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ-0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH-0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. Protection - WW #:90062 Louisiana DEQ Certification #: 3086 Louisiana DHH #: LA140001 Maine Certification #: 2013011 Maryland Certification #: 322 Michigan DEPH Certification #: 9909 Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN-002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA #: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification #: PH-0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Montana Certification #: Cert 0074 Nebraska Certification: NE-OS-28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FL01264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 68 Page 13 of 80 #=CP# CERTIFICATIONS Pace Project No.: Project: 92242955 J15030673 Charlotte Certification IDs South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 West Virginia Certification #: 357 Virginia/VELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 68 Page 14 of 80 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92242955 J15030673 Lab ID Sample ID Matrix Date Collected Date Received 92242955001 2015008539 Solid 03/24/15 08:00 03/26/15 14:45 92242955002 2015008540 Solid 03/24/15 09:15 03/26/15 14:45 92242955003 2015008541 Solid 03/24/15 11:15 03/26/15 14:45 92242955004 2015008542 Solid 03/24/15 16:00 03/26/15 14:45 92242955005 2015008543 Solid 03/24/15 16:30 03/26/15 14:45 92242955006 2015008544 Solid 03/24/15 17:00 03/26/15 14:45 92242955007 2015008543 SPLP Water 03/24/15 16:30 03/26/15 14:45 92242955008 2015008544 SPLP Water 03/24/15 17:00 03/26/15 14:45 92242955009 2015008545 Water 03/24/15 16:05 03/26/15 14:45 92242955010 2015008546 Water 03/24/15 08:45 03/26/15 14:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 68 Page 15 of 80 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92242955 J15030673 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92242955001 2015008539 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OCRT EPA 9045 1 PASI-AMAB EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92242955002 2015008540 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OCRT EPA 9045 1 PASI-AMAB EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92242955003 2015008541 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OCRT EPA 9045 1 PASI-AMAB EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92242955004 2015008542 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OCRT EPA 9045 1 PASI-AMAB EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92242955005 2015008543 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OCRT EPA 9045 1 PASI-AMAB REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 68 Page 16 of 80 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92242955 J15030673 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92242955006 2015008544 EPA 6010 16 PASI-OTAP EPA 6020 8 PASI-OCRT EPA 7471 1 PASI-OCKJ ASTM D2974-87 1 PASI-OCRT EPA 9045 1 PASI-AMAB EPA 300.0 1 PASI-AAES2 EPA 353.2 1 PASI-ADMN SM 4500-Cl-E 1 PASI-ASER EPA 9056 2 PASI-OAIS EPA 9056 1 PASI-OAIS EPA 9060 6 PASI-GTJJ 92242955007 2015008543 SPLP EPA 6020A 24 PASI-MRJS EPA 7470 1 PASI-MBT 92242955008 2015008544 SPLP EPA 6020A 24 PASI-MRJS EPA 7470 1 PASI-MBT 92242955009 2015008545 EPA 6020A 24 PASI-MTT3 EPA 7470 1 PASI-MLMW 92242955010 2015008546 EPA 6020A 24 PASI-MTT3 EPA 7470 1 PASI-MLMW REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 68 Page 17 of 80 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92242955 J15030673 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92242955001 2015008539 Aluminum 702 mg/kg 04/07/15 09:085.9EPA 6010 Barium 0.97 mg/kg 04/07/15 09:080.59EPA 6010 Calcium 82.7 mg/kg 04/07/15 09:0829.7EPA 6010 Chromium 0.60 mg/kg 04/07/15 09:080.30EPA 6010 Copper 0.24J mg/kg 04/07/15 09:080.30EPA 6010 Iron 510 mg/kg 04/07/15 09:082.4EPA 6010 Magnesium 16.7J mg/kg 04/07/15 09:0829.7EPA 6010 Manganese 0.99 mg/kg 04/07/15 09:080.30EPA 6010 Nickel 0.43 mg/kg 04/07/15 09:080.30EPA 6010 Zinc 0.76J mg/kg 04/07/15 09:081.2EPA 6010 Percent Moisture 17.6 %04/04/15 20:040.10ASTM D2974-87 pH at 25 Degrees C 6.8 Std. Units 04/01/15 13:550.10EPA 9045 Total Organic Carbon 452J mg/kg 04/08/15 07:30729EPA 9060 Total Organic Carbon 679J mg/kg 04/08/15 07:35724EPA 9060 Total Organic Carbon 604J mg/kg 04/08/15 07:41731EPA 9060 Total Organic Carbon 519J mg/kg 04/08/15 07:46725EPA 9060 Mean Total Organic Carbon 564J mg/kg 04/08/15 07:30727EPA 9060 RSD%17.5 %04/08/15 07:30EPA 9060 92242955002 2015008540 Aluminum 364 mg/kg 04/07/15 09:126.3EPA 6010 Barium 1.2 mg/kg 04/07/15 09:120.63EPA 6010 Calcium 26.2J mg/kg 04/07/15 09:1231.7EPA 6010 Chromium 0.44 mg/kg 04/07/15 09:120.32EPA 6010 Copper 0.42 mg/kg 04/07/15 09:120.32EPA 6010 Iron 190 mg/kg 04/07/15 09:122.5EPA 6010 Manganese 0.40 mg/kg 04/07/15 09:120.32EPA 6010 Nickel 0.39 mg/kg 04/07/15 09:120.32EPA 6010 Percent Moisture 19.8 %04/04/15 20:040.10ASTM D2974-87 pH at 25 Degrees C 7.2 Std. Units 04/01/15 13:550.10EPA 9045 RSD%8.5 %04/08/15 08:39EPA 9060 92242955003 2015008541 Aluminum 261 mg/kg 04/07/15 09:166.8EPA 6010 Barium 1.4 mg/kg 04/07/15 09:160.68EPA 6010 Calcium 20.6J mg/kg 04/07/15 09:1634.2EPA 6010 Chromium 0.36 mg/kg 04/07/15 09:160.34EPA 6010 Copper 0.27J mg/kg 04/07/15 09:160.34EPA 6010 Iron 465 mg/kg 04/07/15 09:162.7EPA 6010 Manganese 20.1 mg/kg 04/07/15 09:160.34EPA 6010 Strontium 0.48J mg/kg 04/07/15 09:160.68EPA 6010 Percent Moisture 30.0 %04/04/15 20:040.10ASTM D2974-87 pH at 25 Degrees C 5.4 Std. Units 04/01/15 13:550.10EPA 9045 RSD%8.5 %04/08/15 09:01EPA 9060 92242955004 2015008542 Aluminum 23.8 mg/kg 04/09/15 05:375.0EPA 6010 Barium 0.36J mg/kg 04/09/15 05:370.50EPA 6010 Calcium 43.7 mg/kg 04/09/15 05:3724.9EPA 6010 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 68 Page 18 of 80 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92242955 J15030673 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92242955004 2015008542 Iron 11.3 mg/kg 04/09/15 05:372.0EPA 6010 Nickel 0.22J mg/kg 04/09/15 05:370.25EPA 6010 Percent Moisture 2.6 %04/04/15 20:040.10ASTM D2974-87 pH at 25 Degrees C 6.8 Std. Units 04/01/15 13:550.10EPA 9045 Total Organic Carbon 533J mg/kg 04/08/15 09:24613EPA 9060 Total Organic Carbon 734 mg/kg 04/08/15 09:30617EPA 9060 Total Organic Carbon 478J mg/kg 04/08/15 09:35614EPA 9060 Total Organic Carbon 490J mg/kg 04/08/15 09:42620EPA 9060 Mean Total Organic Carbon 559J mg/kg 04/08/15 09:24616EPA 9060 RSD%21.3 %04/08/15 09:24EPA 9060 92242955005 2015008543 Aluminum 1350 mg/kg 04/09/15 05:555.5EPA 6010 Barium 2.1 mg/kg 04/09/15 05:550.55EPA 6010 Calcium 51.8 mg/kg 04/09/15 05:5527.3EPA 6010 Chromium 1.5 mg/kg 04/09/15 05:550.27EPA 6010 Copper 1.0 mg/kg 04/09/15 05:550.27EPA 6010 Iron 230 mg/kg 04/09/15 05:552.2EPA 6010 Magnesium 20.9J mg/kg 04/09/15 05:5527.3EPA 6010 Manganese 1.0 mg/kg 04/09/15 05:550.27EPA 6010 Nickel 0.65 mg/kg 04/09/15 05:550.27EPA 6010 Potassium 43.5J mg/kg 04/09/15 05:5554.7EPA 6010 Strontium 0.32J mg/kg 04/09/15 05:550.55EPA 6010 Zinc 0.94J mg/kg 04/09/15 05:55 B1.1EPA 6010 Percent Moisture 4.1 %04/04/15 20:040.10ASTM D2974-87 pH at 25 Degrees C 6.5 Std. Units 04/01/15 13:550.10EPA 9045 Sulfate 3.5 mg/L 04/07/15 17:51 B2.1EPA 300.0 Nitrogen, Nitrate 0.29 mg/L 04/09/15 19:26 H10.21EPA 353.2 Total Organic Carbon 515J mg/kg 04/08/15 09:48624EPA 9060 Total Organic Carbon 476J mg/kg 04/08/15 09:55632EPA 9060 Total Organic Carbon 465J mg/kg 04/08/15 10:01625EPA 9060 Total Organic Carbon 498J mg/kg 04/08/15 10:06630EPA 9060 Mean Total Organic Carbon 488J mg/kg 04/08/15 09:48628EPA 9060 RSD%4.6 %04/08/15 09:48EPA 9060 92242955006 2015008544 Aluminum 51.8 mg/kg 04/09/15 05:595.7EPA 6010 Barium 0.52J mg/kg 04/09/15 05:590.57EPA 6010 Iron 57.5 mg/kg 04/09/15 05:592.3EPA 6010 Manganese 0.96 mg/kg 04/09/15 05:590.28EPA 6010 Percent Moisture 13.2 %04/04/15 20:050.10ASTM D2974-87 pH at 25 Degrees C 5.8 Std. Units 04/01/15 13:550.10EPA 9045 Sulfate 3.5 mg/L 04/07/15 18:05 B2.3EPA 300.0 RSD%0.75 %04/17/15 06:35EPA 9060 92242955007 2015008543 SPLP Aluminum 7660 ug/L 04/17/15 16:3510.0EPA 6020A Arsenic 0.56 ug/L 04/17/15 16:350.50EPA 6020A Barium 116 ug/L 04/17/15 16:350.30EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 68 Page 19 of 80 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92242955 J15030673 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92242955007 2015008543 SPLP Boron 34.0 ug/L 04/17/15 16:355.0EPA 6020A Calcium 1730 ug/L 04/20/15 13:3840.0EPA 6020A Chromium 5.1 ug/L 04/17/15 16:350.50EPA 6020A Cobalt 0.64 ug/L 04/17/15 16:350.50EPA 6020A Copper 3.6 ug/L 04/17/15 16:351.0EPA 6020A Iron 862 ug/L 04/17/15 16:3550.0EPA 6020A Lead 1.2 ug/L 04/17/15 16:350.10EPA 6020A Magnesium 103 ug/L 04/17/15 16:3510.0EPA 6020A Manganese 1.3 ug/L 04/17/15 16:350.50EPA 6020A Nickel 1.5 ug/L 04/17/15 16:350.50EPA 6020A Potassium 252 ug/L 04/17/15 16:3550.0EPA 6020A Sodium 1340 ug/L 04/17/15 16:3550.0EPA 6020A Strontium 6.4 ug/L 04/17/15 16:350.50EPA 6020A Vanadium 1.4 ug/L 04/17/15 16:351.0EPA 6020A Zinc 60.6 ug/L 04/17/15 16:355.0EPA 6020A 92242955008 2015008544 SPLP Aluminum 28.5 ug/L 04/17/15 16:3910.0EPA 6020A Barium 72.1 ug/L 04/17/15 16:390.30EPA 6020A Boron 32.0 ug/L 04/17/15 16:395.0EPA 6020A Calcium 506 ug/L 04/20/15 13:4340.0EPA 6020A Cobalt 1.1 ug/L 04/17/15 16:390.50EPA 6020A Magnesium 85.0 ug/L 04/17/15 16:3910.0EPA 6020A Manganese 22.1 ug/L 04/17/15 16:390.50EPA 6020A Nickel 1.6 ug/L 04/17/15 16:390.50EPA 6020A Sodium 1160 ug/L 04/17/15 16:3950.0EPA 6020A Strontium 5.1 ug/L 04/17/15 16:390.50EPA 6020A Zinc 23.6 ug/L 04/17/15 16:395.0EPA 6020A 92242955009 2015008545 Aluminum 257 ug/L 04/02/15 16:2210.0EPA 6020A Barium 1.9 ug/L 04/02/15 16:220.30EPA 6020A Calcium 14500 ug/L 04/02/15 16:2240.0EPA 6020A Chromium 1.6 ug/L 04/02/15 16:220.50EPA 6020A Cobalt 1.4 ug/L 04/02/15 16:220.50EPA 6020A Iron 481 ug/L 04/02/15 16:2250.0EPA 6020A Lead 0.43 ug/L 04/02/15 16:220.10EPA 6020A Magnesium 286 ug/L 04/02/15 16:2210.0EPA 6020A Manganese 11.0 ug/L 04/02/15 16:220.50EPA 6020A Potassium 146 ug/L 04/02/15 16:2250.0EPA 6020A Strontium 16.2 ug/L 04/02/15 16:220.50EPA 6020A Vanadium 1.5 ug/L 04/02/15 16:221.0EPA 6020A 92242955010 2015008546 Aluminum 209 ug/L 04/02/15 19:0010.0EPA 6020A Barium 1.9 ug/L 04/02/15 19:000.30EPA 6020A Calcium 405 ug/L 04/02/15 19:0040.0EPA 6020A Chromium 3.5 ug/L 04/02/15 19:000.50EPA 6020A Cobalt 1.5 ug/L 04/02/15 19:000.50EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 68 Page 20 of 80 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92242955 J15030673 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92242955010 2015008546 Copper 1.6 ug/L 04/02/15 19:001.0EPA 6020A Iron 983 ug/L 04/02/15 19:0050.0EPA 6020A Lead 0.25 ug/L 04/02/15 19:000.10EPA 6020A Magnesium 29.2 ug/L 04/02/15 19:0010.0EPA 6020A Manganese 8.8 ug/L 04/02/15 19:000.50EPA 6020A Molybdenum 0.64 ug/L 04/02/15 19:000.50EPA 6020A Nickel 0.66 ug/L 04/02/15 19:000.50EPA 6020A Potassium 53.5 ug/L 04/02/15 19:0050.0EPA 6020A Sodium 71.0 ug/L 04/02/15 19:0050.0EPA 6020A Strontium 1.6 ug/L 04/02/15 19:000.50EPA 6020A Zinc 6.6 ug/L 04/02/15 19:005.0EPA 6020A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 68 Page 21 of 80 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92242955 J15030673 Method: Client:Duke Energy EPA 6010 Date:April 21, 2015 Description:6010 MET ICP General Information: 6 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: MPRP/23407 B: Analyte was detected in the associated method blank. • BLANK for HBN 225655 [MPRP/234 (Lab ID: 1173242) • Zinc Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23407 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242976001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1173244) • Aluminum • Copper • Iron • Strontium • MSD (Lab ID: 1173245) • Aluminum • Barium • Beryllium • Calcium • Copper • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 68 Page 22 of 80 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92242955 J15030673 Method: Client:Duke Energy EPA 6010 Date:April 21, 2015 Description:6010 MET ICP QC Batch: MPRP/23407 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242976001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • Strontium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 68 Page 23 of 80 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92242955 J15030673 Method: Client:Duke Energy EPA 6020 Date:April 21, 2015 Description:6020 MET ICPMS General Information: 6 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23408 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242976002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1173248) • Antimony • Arsenic • Cobalt • Lead • Selenium • Thallium • Vanadium • MSD (Lab ID: 1173249) • Antimony • Arsenic • Cobalt • Lead • Selenium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 68 Page 24 of 80 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92242955 J15030673 Method: Client:Duke Energy EPA 6020 Date:April 21, 2015 Description:6020 MET ICPMS QC Batch: MPRP/23408 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92242976002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • Thallium • Vanadium Additional Comments: Analyte Comments: QC Batch: MPRP/23408 N2: The lab does not hold TNI accreditation for this parameter. • 2015008539 (Lab ID: 92242955001) • Antimony • 2015008540 (Lab ID: 92242955002) • Antimony • 2015008541 (Lab ID: 92242955003) • Antimony • 2015008542 (Lab ID: 92242955004) • Antimony • 2015008543 (Lab ID: 92242955005) • Antimony • 2015008544 (Lab ID: 92242955006) • Antimony • BLANK (Lab ID: 1173246) • Antimony • LCS (Lab ID: 1173247) • Antimony • MS (Lab ID: 1173248) • Antimony • MSD (Lab ID: 1173249) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 68 Page 25 of 80 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92242955 J15030673 Method: Client:Duke Energy EPA 6020A Date:April 21, 2015 Description:6020A MET ICPMS General Information: 4 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/53629 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245086001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1939444) • Aluminum • MSD (Lab ID: 1939445) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 68 Page 26 of 80 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92242955 J15030673 Method: Client:Duke Energy EPA 7470 Date:April 21, 2015 Description:7470 Mercury General Information: 4 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 68 Page 27 of 80 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92242955 J15030673 Method: Client:Duke Energy EPA 7471 Date:April 21, 2015 Description:7471 Mercury General Information: 6 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 68 Page 28 of 80 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92242955 J15030673 Method: Client:Duke Energy EPA 9045 Date:April 21, 2015 Description:9045 pH Soil General Information: 6 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 68 Page 29 of 80 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92242955 J15030673 Method: Client:Duke Energy EPA 300.0 Date:April 21, 2015 Description:300.0 IC Anions, SPLP General Information: 2 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/22469 B: Analyte was detected in the associated method blank. • BLANK for HBN 258521 [WETA/224 (Lab ID: 1428206) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 68 Page 30 of 80 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92242955 J15030673 Method: Client:Duke Energy EPA 353.2 Date:April 21, 2015 Description:353.2 Nitrogen, NO2/NO3, SPLP General Information: 2 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H1: Analysis conducted outside the EPA method holding time. • 2015008543 (Lab ID: 92242955005) • 2015008544 (Lab ID: 92242955006) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 68 Page 31 of 80 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92242955 J15030673 Method: Client:Duke Energy SM 4500-Cl-E Date:April 21, 2015 Description:4500 Chloride, SPLP General Information: 2 samples were analyzed for SM 4500-Cl-E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 68 Page 32 of 80 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92242955 J15030673 Method: Client:Duke Energy EPA 9056 Date:April 21, 2015 Description:9056 IC Anions General Information: 6 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/45008 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015008539 (Lab ID: 92242955001) • Chloride • Sulfate • 2015008540 (Lab ID: 92242955002) • Chloride • Sulfate • 2015008541 (Lab ID: 92242955003) • Chloride • Sulfate QC Batch: WETA/45010 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015008542 (Lab ID: 92242955004) • Chloride • Sulfate • 2015008543 (Lab ID: 92242955005) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 68 Page 33 of 80 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92242955 J15030673 Method: Client:Duke Energy EPA 9056 Date:April 21, 2015 Description:9056 IC Anions Analyte Comments: QC Batch: WETA/45010 D3: Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference. • 2015008544 (Lab ID: 92242955006) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 68 Page 34 of 80 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92242955 J15030673 Method: Client:Duke Energy EPA 9056 Date:April 21, 2015 Description:9056 IC Anions 48hr General Information: 6 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. H3: Sample was received or analysis requested beyond the recognized method holding time. • 2015008539 (Lab ID: 92242955001) • 2015008540 (Lab ID: 92242955002) • 2015008541 (Lab ID: 92242955003) • 2015008542 (Lab ID: 92242955004) • 2015008543 (Lab ID: 92242955005) • 2015008544 (Lab ID: 92242955006) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 68 Page 35 of 80 #=NA# PROJECT NARRATIVE Pace Project No.: Project: 92242955 J15030673 Method: Client:Duke Energy EPA 9060 Date:April 21, 2015 Description:Total Organic Carbon Quad General Information: 6 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 68 Page 36 of 80 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92242955 J15030673 Sample:2015008539 Lab ID:92242955001 Collected:03/24/15 08:00 Received:03/26/15 14:45 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 702 mg/kg 04/07/15 09:08 7429-90-504/04/15 13:505.9 3.0 1 Barium 0.97 mg/kg 04/07/15 09:08 7440-39-304/04/15 13:500.59 0.30 1 Beryllium ND mg/kg 04/07/15 09:08 7440-41-704/04/15 13:500.059 0.030 1 Boron ND mg/kg 04/07/15 09:08 7440-42-804/04/15 13:503.0 1.5 1 Calcium 82.7 mg/kg 04/07/15 09:08 7440-70-204/04/15 13:5029.7 14.8 1 Chromium 0.60 mg/kg 04/07/15 09:08 7440-47-304/04/15 13:500.30 0.15 1 Copper 0.24J mg/kg 04/07/15 09:08 7440-50-804/04/15 13:500.30 0.15 1 Iron 510 mg/kg 04/07/15 09:08 7439-89-604/04/15 13:502.4 1.2 1 Magnesium 16.7J mg/kg 04/07/15 09:08 7439-95-404/04/15 13:5029.7 14.8 1 Manganese 0.99 mg/kg 04/07/15 09:08 7439-96-504/04/15 13:500.30 0.15 1 Molybdenum ND mg/kg 04/07/15 09:08 7439-98-704/04/15 13:500.59 0.30 1 Nickel 0.43 mg/kg 04/07/15 09:08 7440-02-004/04/15 13:500.30 0.15 1 Potassium ND mg/kg 04/07/15 09:08 7440-09-704/04/15 13:5059.3 29.7 1 Sodium ND mg/kg 04/07/15 09:08 7440-23-504/04/15 13:5059.3 29.7 1 Strontium ND mg/kg 04/07/15 09:08 7440-24-604/04/15 13:500.59 0.30 1 Zinc 0.76J mg/kg 04/07/15 09:08 7440-66-604/04/15 13:501.2 0.59 1 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/06/15 11:32 7440-36-0 N204/04/15 13:503.0 1.5 50 Arsenic ND mg/kg 04/06/15 11:32 7440-38-204/04/15 13:503.0 1.5 50 Cadmium ND mg/kg 04/06/15 11:32 7440-43-904/04/15 13:500.36 0.18 50 Cobalt ND mg/kg 04/06/15 11:32 7440-48-404/04/15 13:503.0 1.5 50 Lead ND mg/kg 04/06/15 11:32 7439-92-104/04/15 13:503.0 1.5 50 Selenium ND mg/kg 04/06/15 11:32 7782-49-204/04/15 13:503.0 1.5 50 Thallium ND mg/kg 04/06/15 11:32 7440-28-004/04/15 13:503.0 1.5 50 Vanadium ND mg/kg 04/06/15 11:32 7440-62-204/04/15 13:503.0 1.5 50 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/04/15 20:49 7439-97-604/04/15 14:550.0099 0.0049 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 17.6 %04/04/15 20:040.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.8 Std. Units 04/01/15 13:550.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/01/15 21:00 16887-00-6 D33001505 Sulfate ND mg/kg 04/01/15 21:00 14808-79-8 D33001505 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/01/15 21:00 14797-55-8 H330.0 15.0 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 68 Page 37 of 80 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92242955 J15030673 Sample:2015008539 Lab ID:92242955001 Collected:03/24/15 08:00 Received:03/26/15 14:45 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 452J mg/kg 04/08/15 07:30 7440-44-07293651 Total Organic Carbon 679J mg/kg 04/08/15 07:35 7440-44-07243621 Total Organic Carbon 604J mg/kg 04/08/15 07:41 7440-44-07313661 Total Organic Carbon 519J mg/kg 04/08/15 07:46 7440-44-07253621 Mean Total Organic Carbon 564J mg/kg 04/08/15 07:30 7440-44-07273641 Surrogates RSD%17.5 %04/08/15 07:301 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 68 Page 38 of 80 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92242955 J15030673 Sample:2015008540 Lab ID:92242955002 Collected:03/24/15 09:15 Received:03/26/15 14:45 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 364 mg/kg 04/07/15 09:12 7429-90-504/04/15 13:506.3 3.2 1 Barium 1.2 mg/kg 04/07/15 09:12 7440-39-304/04/15 13:500.63 0.32 1 Beryllium ND mg/kg 04/07/15 09:12 7440-41-704/04/15 13:500.063 0.032 1 Boron ND mg/kg 04/07/15 09:12 7440-42-804/04/15 13:503.2 1.6 1 Calcium 26.2J mg/kg 04/07/15 09:12 7440-70-204/04/15 13:5031.7 15.9 1 Chromium 0.44 mg/kg 04/07/15 09:12 7440-47-304/04/15 13:500.32 0.16 1 Copper 0.42 mg/kg 04/07/15 09:12 7440-50-804/04/15 13:500.32 0.16 1 Iron 190 mg/kg 04/07/15 09:12 7439-89-604/04/15 13:502.5 1.3 1 Magnesium ND mg/kg 04/07/15 09:12 7439-95-404/04/15 13:5031.7 15.9 1 Manganese 0.40 mg/kg 04/07/15 09:12 7439-96-504/04/15 13:500.32 0.16 1 Molybdenum ND mg/kg 04/07/15 09:12 7439-98-704/04/15 13:500.63 0.32 1 Nickel 0.39 mg/kg 04/07/15 09:12 7440-02-004/04/15 13:500.32 0.16 1 Potassium ND mg/kg 04/07/15 09:12 7440-09-704/04/15 13:5063.5 31.7 1 Sodium ND mg/kg 04/07/15 09:12 7440-23-504/04/15 13:5063.5 31.7 1 Strontium ND mg/kg 04/07/15 09:12 7440-24-604/04/15 13:500.63 0.32 1 Zinc ND mg/kg 04/07/15 09:12 7440-66-604/04/15 13:501.3 0.63 1 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/06/15 11:34 7440-36-0 N204/04/15 13:503.2 1.6 50 Arsenic ND mg/kg 04/06/15 11:34 7440-38-204/04/15 13:503.2 1.6 50 Cadmium ND mg/kg 04/06/15 11:34 7440-43-904/04/15 13:500.38 0.19 50 Cobalt ND mg/kg 04/06/15 11:34 7440-48-404/04/15 13:503.2 1.6 50 Lead ND mg/kg 04/06/15 11:34 7439-92-104/04/15 13:503.2 1.6 50 Selenium ND mg/kg 04/06/15 11:34 7782-49-204/04/15 13:503.2 1.6 50 Thallium ND mg/kg 04/06/15 11:34 7440-28-004/04/15 13:503.2 1.6 50 Vanadium ND mg/kg 04/06/15 11:34 7440-62-204/04/15 13:503.2 1.6 50 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/04/15 20:51 7439-97-604/04/15 14:550.010 0.0051 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 19.8 %04/04/15 20:040.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 7.2 Std. Units 04/01/15 13:550.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/01/15 21:22 16887-00-6 D33131575 Sulfate ND mg/kg 04/01/15 21:22 14808-79-8 D33131575 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/01/15 21:22 14797-55-8 H331.3 15.7 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 68 Page 39 of 80 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92242955 J15030673 Sample:2015008540 Lab ID:92242955002 Collected:03/24/15 09:15 Received:03/26/15 14:45 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 04/08/15 08:39 7440-44-07553771 Total Organic Carbon ND mg/kg 04/08/15 08:44 7440-44-07473741 Total Organic Carbon ND mg/kg 04/08/15 08:51 7440-44-07523761 Total Organic Carbon ND mg/kg 04/08/15 08:56 7440-44-07443721 Mean Total Organic Carbon ND mg/kg 04/08/15 08:39 7440-44-07503751 Surrogates RSD%8.5 %04/08/15 08:391 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 68 Page 40 of 80 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92242955 J15030673 Sample:2015008541 Lab ID:92242955003 Collected:03/24/15 11:15 Received:03/26/15 14:45 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 261 mg/kg 04/07/15 09:16 7429-90-504/04/15 13:506.8 3.4 1 Barium 1.4 mg/kg 04/07/15 09:16 7440-39-304/04/15 13:500.68 0.34 1 Beryllium ND mg/kg 04/07/15 09:16 7440-41-704/04/15 13:500.068 0.034 1 Boron ND mg/kg 04/07/15 09:16 7440-42-804/04/15 13:503.4 1.7 1 Calcium 20.6J mg/kg 04/07/15 09:16 7440-70-204/04/15 13:5034.2 17.1 1 Chromium 0.36 mg/kg 04/07/15 09:16 7440-47-304/04/15 13:500.34 0.17 1 Copper 0.27J mg/kg 04/07/15 09:16 7440-50-804/04/15 13:500.34 0.17 1 Iron 465 mg/kg 04/07/15 09:16 7439-89-604/04/15 13:502.7 1.4 1 Magnesium ND mg/kg 04/07/15 09:16 7439-95-404/04/15 13:5034.2 17.1 1 Manganese 20.1 mg/kg 04/07/15 09:16 7439-96-504/04/15 13:500.34 0.17 1 Molybdenum ND mg/kg 04/07/15 09:16 7439-98-704/04/15 13:500.68 0.34 1 Nickel ND mg/kg 04/07/15 09:16 7440-02-004/04/15 13:500.34 0.17 1 Potassium ND mg/kg 04/07/15 09:16 7440-09-704/04/15 13:5068.4 34.2 1 Sodium ND mg/kg 04/07/15 09:16 7440-23-504/04/15 13:5068.4 34.2 1 Strontium 0.48J mg/kg 04/07/15 09:16 7440-24-604/04/15 13:500.68 0.34 1 Zinc ND mg/kg 04/07/15 09:16 7440-66-604/04/15 13:501.4 0.68 1 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/06/15 11:37 7440-36-0 N204/04/15 13:503.4 1.7 50 Arsenic ND mg/kg 04/06/15 11:37 7440-38-204/04/15 13:503.4 1.7 50 Cadmium ND mg/kg 04/06/15 11:37 7440-43-904/04/15 13:500.41 0.21 50 Cobalt ND mg/kg 04/06/15 11:37 7440-48-404/04/15 13:503.4 1.7 50 Lead ND mg/kg 04/06/15 11:37 7439-92-104/04/15 13:503.4 1.7 50 Selenium ND mg/kg 04/06/15 11:37 7782-49-204/04/15 13:503.4 1.7 50 Thallium ND mg/kg 04/06/15 11:37 7440-28-004/04/15 13:503.4 1.7 50 Vanadium ND mg/kg 04/06/15 11:37 7440-62-204/04/15 13:503.4 1.7 50 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/04/15 20:53 7439-97-604/04/15 14:550.011 0.0055 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 30.0 %04/04/15 20:040.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 5.4 Std. Units 04/01/15 13:550.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/01/15 21:43 16887-00-6 D33531775 Sulfate ND mg/kg 04/01/15 21:43 14808-79-8 D33531775 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/01/15 21:43 14797-55-8 H335.3 17.7 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 68 Page 41 of 80 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92242955 J15030673 Sample:2015008541 Lab ID:92242955003 Collected:03/24/15 11:15 Received:03/26/15 14:45 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 04/08/15 09:01 7440-44-08654321 Total Organic Carbon ND mg/kg 04/08/15 09:07 7440-44-08534271 Total Organic Carbon ND mg/kg 04/08/15 09:12 7440-44-08524261 Total Organic Carbon ND mg/kg 04/08/15 09:19 7440-44-08604301 Mean Total Organic Carbon ND mg/kg 04/08/15 09:01 7440-44-08574291 Surrogates RSD%8.5 %04/08/15 09:011 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 68 Page 42 of 80 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92242955 J15030673 Sample:2015008542 Lab ID:92242955004 Collected:03/24/15 16:00 Received:03/26/15 14:45 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 23.8 mg/kg 04/09/15 05:37 7429-90-504/04/15 13:505.0 2.5 1 Barium 0.36J mg/kg 04/09/15 05:37 7440-39-304/04/15 13:500.50 0.25 1 Beryllium ND mg/kg 04/09/15 05:37 7440-41-704/04/15 13:500.050 0.025 1 Boron ND mg/kg 04/09/15 05:37 7440-42-804/04/15 13:502.5 1.2 1 Calcium 43.7 mg/kg 04/09/15 05:37 7440-70-204/04/15 13:5024.9 12.4 1 Chromium ND mg/kg 04/09/15 05:37 7440-47-304/04/15 13:500.25 0.12 1 Copper ND mg/kg 04/09/15 05:37 7440-50-804/04/15 13:500.25 0.12 1 Iron 11.3 mg/kg 04/09/15 05:37 7439-89-604/04/15 13:502.0 0.99 1 Magnesium ND mg/kg 04/09/15 05:37 7439-95-404/04/15 13:5024.9 12.4 1 Manganese ND mg/kg 04/09/15 05:37 7439-96-504/04/15 13:500.25 0.12 1 Molybdenum ND mg/kg 04/09/15 05:37 7439-98-704/04/15 13:500.50 0.25 1 Nickel 0.22J mg/kg 04/09/15 05:37 7440-02-004/04/15 13:500.25 0.12 1 Potassium ND mg/kg 04/09/15 05:37 7440-09-704/04/15 13:5049.7 24.9 1 Sodium ND mg/kg 04/09/15 05:37 7440-23-504/04/15 13:5049.7 24.9 1 Strontium ND mg/kg 04/09/15 05:37 7440-24-604/04/15 13:500.50 0.25 1 Zinc ND mg/kg 04/09/15 05:37 7440-66-604/04/15 13:500.99 0.50 1 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/06/15 11:39 7440-36-0 N204/04/15 13:502.5 1.2 50 Arsenic ND mg/kg 04/06/15 11:39 7440-38-204/04/15 13:502.5 1.2 50 Cadmium ND mg/kg 04/06/15 11:39 7440-43-904/04/15 13:500.30 0.15 50 Cobalt ND mg/kg 04/06/15 11:39 7440-48-404/04/15 13:502.5 1.2 50 Lead ND mg/kg 04/06/15 11:39 7439-92-104/04/15 13:502.5 1.2 50 Selenium ND mg/kg 04/06/15 11:39 7782-49-204/04/15 13:502.5 1.2 50 Thallium ND mg/kg 04/06/15 11:39 7440-28-004/04/15 13:502.5 1.2 50 Vanadium ND mg/kg 04/06/15 11:39 7440-62-204/04/15 13:502.5 1.2 50 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/04/15 20:55 7439-97-604/04/15 14:550.0084 0.0042 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 2.6 %04/04/15 20:040.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.8 Std. Units 04/01/15 13:550.10 0.10 1 Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/01/15 23:30 16887-00-6 D32511265 Sulfate ND mg/kg 04/01/15 23:30 14808-79-8 D32511265 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/01/15 23:30 14797-55-8 H325.1 12.6 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 68 Page 43 of 80 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92242955 J15030673 Sample:2015008542 Lab ID:92242955004 Collected:03/24/15 16:00 Received:03/26/15 14:45 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 533J mg/kg 04/08/15 09:24 7440-44-06133061 Total Organic Carbon 734 mg/kg 04/08/15 09:30 7440-44-06173091 Total Organic Carbon 478J mg/kg 04/08/15 09:35 7440-44-06143071 Total Organic Carbon 490J mg/kg 04/08/15 09:42 7440-44-06203101 Mean Total Organic Carbon 559J mg/kg 04/08/15 09:24 7440-44-06163081 Surrogates RSD%21.3 %04/08/15 09:241 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 68 Page 44 of 80 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92242955 J15030673 Sample:2015008543 Lab ID:92242955005 Collected:03/24/15 16:30 Received:03/26/15 14:45 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 1350 mg/kg 04/09/15 05:55 7429-90-504/04/15 13:505.5 2.7 1 Barium 2.1 mg/kg 04/09/15 05:55 7440-39-304/04/15 13:500.55 0.27 1 Beryllium ND mg/kg 04/09/15 05:55 7440-41-704/04/15 13:500.055 0.027 1 Boron ND mg/kg 04/09/15 05:55 7440-42-804/04/15 13:502.7 1.4 1 Calcium 51.8 mg/kg 04/09/15 05:55 7440-70-204/04/15 13:5027.3 13.7 1 Chromium 1.5 mg/kg 04/09/15 05:55 7440-47-304/04/15 13:500.27 0.14 1 Copper 1.0 mg/kg 04/09/15 05:55 7440-50-804/04/15 13:500.27 0.14 1 Iron 230 mg/kg 04/09/15 05:55 7439-89-604/04/15 13:502.2 1.1 1 Magnesium 20.9J mg/kg 04/09/15 05:55 7439-95-404/04/15 13:5027.3 13.7 1 Manganese 1.0 mg/kg 04/09/15 05:55 7439-96-504/04/15 13:500.27 0.14 1 Molybdenum ND mg/kg 04/09/15 05:55 7439-98-704/04/15 13:500.55 0.27 1 Nickel 0.65 mg/kg 04/09/15 05:55 7440-02-004/04/15 13:500.27 0.14 1 Potassium 43.5J mg/kg 04/09/15 05:55 7440-09-704/04/15 13:5054.7 27.3 1 Sodium ND mg/kg 04/09/15 05:55 7440-23-504/04/15 13:5054.7 27.3 1 Strontium 0.32J mg/kg 04/09/15 05:55 7440-24-604/04/15 13:500.55 0.27 1 Zinc 0.94J mg/kg 04/09/15 05:55 7440-66-6 B04/04/15 13:501.1 0.55 1 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/06/15 11:41 7440-36-0 N204/04/15 13:502.7 1.4 50 Arsenic ND mg/kg 04/06/15 11:41 7440-38-204/04/15 13:502.7 1.4 50 Cadmium ND mg/kg 04/06/15 11:41 7440-43-904/04/15 13:500.33 0.16 50 Cobalt ND mg/kg 04/06/15 11:41 7440-48-404/04/15 13:502.7 1.4 50 Lead ND mg/kg 04/06/15 11:41 7439-92-104/04/15 13:502.7 1.4 50 Selenium ND mg/kg 04/06/15 11:41 7782-49-204/04/15 13:502.7 1.4 50 Thallium ND mg/kg 04/06/15 11:41 7440-28-004/04/15 13:502.7 1.4 50 Vanadium ND mg/kg 04/06/15 11:41 7440-62-204/04/15 13:502.7 1.4 50 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/04/15 20:57 7439-97-604/04/15 14:550.0087 0.0043 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 4.1 %04/04/15 20:040.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 6.5 Std. Units 04/01/15 13:550.10 0.10 1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/02/15 18:00300.0 IC Anions, SPLP Sulfate 3.5 mg/L 04/07/15 17:51 14808-79-8 B2.1 1.0 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/02/15 18:00353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 0.29 mg/L 04/09/15 19:26 H10.21 0.21 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 04/02/15 18:004500 Chloride, SPLP Chloride ND mg/L 04/08/15 02:29 16887-00-65.2 2.6 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 68 Page 45 of 80 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92242955 J15030673 Sample:2015008543 Lab ID:92242955005 Collected:03/24/15 16:30 Received:03/26/15 14:45 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/02/15 00:35 16887-00-6 D32601305 Sulfate ND mg/kg 04/02/15 00:35 14808-79-8 D32601305 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/02/15 00:35 14797-55-8 H326.0 13.0 5 Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon 515J mg/kg 04/08/15 09:48 7440-44-06243121 Total Organic Carbon 476J mg/kg 04/08/15 09:55 7440-44-06323161 Total Organic Carbon 465J mg/kg 04/08/15 10:01 7440-44-06253121 Total Organic Carbon 498J mg/kg 04/08/15 10:06 7440-44-06303151 Mean Total Organic Carbon 488J mg/kg 04/08/15 09:48 7440-44-06283141 Surrogates RSD%4.6 %04/08/15 09:481 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 68 Page 46 of 80 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92242955 J15030673 Sample:2015008544 Lab ID:92242955006 Collected:03/24/15 17:00 Received:03/26/15 14:45 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Aluminum 51.8 mg/kg 04/09/15 05:59 7429-90-504/04/15 13:505.7 2.8 1 Barium 0.52J mg/kg 04/09/15 05:59 7440-39-304/04/15 13:500.57 0.28 1 Beryllium ND mg/kg 04/09/15 05:59 7440-41-704/04/15 13:500.057 0.028 1 Boron ND mg/kg 04/09/15 05:59 7440-42-804/04/15 13:502.8 1.4 1 Calcium ND mg/kg 04/09/15 05:59 7440-70-204/04/15 13:5028.3 14.1 1 Chromium ND mg/kg 04/09/15 05:59 7440-47-304/04/15 13:500.28 0.14 1 Copper ND mg/kg 04/09/15 05:59 7440-50-804/04/15 13:500.28 0.14 1 Iron 57.5 mg/kg 04/09/15 05:59 7439-89-604/04/15 13:502.3 1.1 1 Magnesium ND mg/kg 04/09/15 05:59 7439-95-404/04/15 13:5028.3 14.1 1 Manganese 0.96 mg/kg 04/09/15 05:59 7439-96-504/04/15 13:500.28 0.14 1 Molybdenum ND mg/kg 04/09/15 05:59 7439-98-704/04/15 13:500.57 0.28 1 Nickel ND mg/kg 04/09/15 05:59 7440-02-004/04/15 13:500.28 0.14 1 Potassium ND mg/kg 04/09/15 05:59 7440-09-704/04/15 13:5056.6 28.3 1 Sodium ND mg/kg 04/09/15 05:59 7440-23-504/04/15 13:5056.6 28.3 1 Strontium ND mg/kg 04/09/15 05:59 7440-24-604/04/15 13:500.57 0.28 1 Zinc ND mg/kg 04/09/15 05:59 7440-66-604/04/15 13:501.1 0.57 1 Analytical Method: EPA 6020 Preparation Method: EPA 30506020 MET ICPMS Antimony ND mg/kg 04/06/15 11:43 7440-36-0 N204/04/15 13:502.8 1.4 50 Arsenic ND mg/kg 04/06/15 11:43 7440-38-204/04/15 13:502.8 1.4 50 Cadmium ND mg/kg 04/06/15 11:43 7440-43-904/04/15 13:500.34 0.17 50 Cobalt ND mg/kg 04/06/15 11:43 7440-48-404/04/15 13:502.8 1.4 50 Lead ND mg/kg 04/06/15 11:43 7439-92-104/04/15 13:502.8 1.4 50 Selenium ND mg/kg 04/06/15 11:43 7782-49-204/04/15 13:502.8 1.4 50 Thallium ND mg/kg 04/06/15 11:43 7440-28-004/04/15 13:502.8 1.4 50 Vanadium ND mg/kg 04/06/15 11:43 7440-62-204/04/15 13:502.8 1.4 50 Analytical Method: EPA 7471 Preparation Method: EPA 74717471 Mercury Mercury ND mg/kg 04/04/15 20:59 7439-97-604/04/15 14:550.0096 0.0048 1 Analytical Method: ASTM D2974-87Percent Moisture Percent Moisture 13.2 %04/04/15 20:050.10 0.10 1 Analytical Method: EPA 90459045 pH Soil pH at 25 Degrees C 5.8 Std. Units 04/01/15 13:550.10 0.10 1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/02/15 18:00300.0 IC Anions, SPLP Sulfate 3.5 mg/L 04/07/15 18:05 14808-79-8 B2.3 1.2 1 Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/02/15 18:00353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate ND mg/L 04/09/15 19:27 H10.23 0.23 1 Analytical Method: SM 4500-Cl-E Leachate Method/Date: EPA 1312; 04/02/15 18:004500 Chloride, SPLP Chloride ND mg/L 04/08/15 02:30 16887-00-65.8 2.9 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 36 of 68 Page 47 of 80 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92242955 J15030673 Sample:2015008544 Lab ID:92242955006 Collected:03/24/15 17:00 Received:03/26/15 14:45 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 90569056 IC Anions Chloride ND mg/kg 04/02/15 00:56 16887-00-6 D32841425 Sulfate ND mg/kg 04/02/15 00:56 14808-79-8 D32841425 Analytical Method: EPA 90569056 IC Anions 48hr Nitrate as N ND mg/kg 04/02/15 00:56 14797-55-8 H328.4 14.2 5 Analytical Method: EPA 9060Total Organic Carbon Quad Total Organic Carbon ND mg/kg 04/17/15 06:35 7440-44-06853431 Total Organic Carbon ND mg/kg 04/17/15 06:42 7440-44-06933461 Total Organic Carbon ND mg/kg 04/17/15 06:47 7440-44-06973491 Total Organic Carbon ND mg/kg 04/17/15 06:54 7440-44-06963481 Mean Total Organic Carbon ND mg/kg 04/17/15 06:35 7440-44-06933461 Surrogates RSD%0.75 %04/17/15 06:351 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 37 of 68 Page 48 of 80 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92242955 J15030673 Sample:2015008543 SPLP Lab ID:92242955007 Collected:03/24/15 16:30 Received:03/26/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 7660 ug/L 04/17/15 16:35 7429-90-504/15/15 22:2210.0 3.0 1 Antimony ND ug/L 04/17/15 16:35 7440-36-004/15/15 22:220.50 0.15 1 Arsenic 0.56 ug/L 04/17/15 16:35 7440-38-204/15/15 22:220.50 0.11 1 Barium 116 ug/L 04/17/15 16:35 7440-39-304/15/15 22:220.30 0.081 1 Beryllium ND ug/L 04/17/15 16:35 7440-41-704/15/15 22:220.20 0.067 1 Boron 34.0 ug/L 04/17/15 16:35 7440-42-804/15/15 22:225.0 1.1 1 Cadmium ND ug/L 04/17/15 16:35 7440-43-904/15/15 22:220.080 0.024 1 Calcium 1730 ug/L 04/20/15 13:38 7440-70-204/15/15 22:2240.0 16.0 1 Chromium 5.1 ug/L 04/17/15 16:35 7440-47-304/15/15 22:220.50 0.17 1 Cobalt 0.64 ug/L 04/17/15 16:35 7440-48-404/15/15 22:220.50 0.13 1 Copper 3.6 ug/L 04/17/15 16:35 7440-50-804/15/15 22:221.0 0.21 1 Iron 862 ug/L 04/17/15 16:35 7439-89-604/15/15 22:2250.0 13.7 1 Lead 1.2 ug/L 04/17/15 16:35 7439-92-104/15/15 22:220.10 0.046 1 Magnesium 103 ug/L 04/17/15 16:35 7439-95-404/15/15 22:2210.0 3.2 1 Manganese 1.3 ug/L 04/17/15 16:35 7439-96-504/15/15 22:220.50 0.24 1 Molybdenum ND ug/L 04/17/15 16:35 7439-98-704/15/15 22:220.50 0.094 1 Nickel 1.5 ug/L 04/17/15 16:35 7440-02-004/15/15 22:220.50 0.16 1 Potassium 252 ug/L 04/17/15 16:35 7440-09-704/15/15 22:2250.0 11.7 1 Selenium ND ug/L 04/17/15 16:35 7782-49-204/15/15 22:220.50 0.20 1 Sodium 1340 ug/L 04/17/15 16:35 7440-23-504/15/15 22:2250.0 16.3 1 Strontium 6.4 ug/L 04/17/15 16:35 7440-24-604/15/15 22:220.50 0.13 1 Thallium ND ug/L 04/17/15 16:35 7440-28-004/15/15 22:220.10 0.015 1 Vanadium 1.4 ug/L 04/17/15 16:35 7440-62-204/15/15 22:221.0 0.28 1 Zinc 60.6 ug/L 04/17/15 16:35 7440-66-604/15/15 22:225.0 2.4 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 04/17/15 07:51 7439-97-604/16/15 08:580.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 38 of 68 Page 49 of 80 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92242955 J15030673 Sample:2015008544 SPLP Lab ID:92242955008 Collected:03/24/15 17:00 Received:03/26/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 28.5 ug/L 04/17/15 16:39 7429-90-504/15/15 22:2210.0 3.0 1 Antimony ND ug/L 04/17/15 16:39 7440-36-004/15/15 22:220.50 0.15 1 Arsenic ND ug/L 04/17/15 16:39 7440-38-204/15/15 22:220.50 0.11 1 Barium 72.1 ug/L 04/17/15 16:39 7440-39-304/15/15 22:220.30 0.081 1 Beryllium ND ug/L 04/17/15 16:39 7440-41-704/15/15 22:220.20 0.067 1 Boron 32.0 ug/L 04/17/15 16:39 7440-42-804/15/15 22:225.0 1.1 1 Cadmium ND ug/L 04/17/15 16:39 7440-43-904/15/15 22:220.080 0.024 1 Calcium 506 ug/L 04/20/15 13:43 7440-70-204/15/15 22:2240.0 16.0 1 Chromium ND ug/L 04/17/15 16:39 7440-47-304/15/15 22:220.50 0.17 1 Cobalt 1.1 ug/L 04/17/15 16:39 7440-48-404/15/15 22:220.50 0.13 1 Copper ND ug/L 04/17/15 16:39 7440-50-804/15/15 22:221.0 0.21 1 Iron ND ug/L 04/17/15 16:39 7439-89-604/15/15 22:2250.0 13.7 1 Lead ND ug/L 04/17/15 16:39 7439-92-104/15/15 22:220.10 0.046 1 Magnesium 85.0 ug/L 04/17/15 16:39 7439-95-404/15/15 22:2210.0 3.2 1 Manganese 22.1 ug/L 04/17/15 16:39 7439-96-504/15/15 22:220.50 0.24 1 Molybdenum ND ug/L 04/17/15 16:39 7439-98-704/15/15 22:220.50 0.094 1 Nickel 1.6 ug/L 04/17/15 16:39 7440-02-004/15/15 22:220.50 0.16 1 Potassium ND ug/L 04/17/15 16:39 7440-09-704/15/15 22:2250.0 11.7 1 Selenium ND ug/L 04/17/15 16:39 7782-49-204/15/15 22:220.50 0.20 1 Sodium 1160 ug/L 04/17/15 16:39 7440-23-504/15/15 22:2250.0 16.3 1 Strontium 5.1 ug/L 04/17/15 16:39 7440-24-604/15/15 22:220.50 0.13 1 Thallium ND ug/L 04/17/15 16:39 7440-28-004/15/15 22:220.10 0.015 1 Vanadium ND ug/L 04/17/15 16:39 7440-62-204/15/15 22:221.0 0.28 1 Zinc 23.6 ug/L 04/17/15 16:39 7440-66-604/15/15 22:225.0 2.4 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 04/17/15 07:53 7439-97-604/16/15 08:580.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 39 of 68 Page 50 of 80 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92242955 J15030673 Sample:2015008545 Lab ID:92242955009 Collected:03/24/15 16:05 Received:03/26/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 257 ug/L 04/02/15 16:22 7429-90-504/02/15 07:3010.0 3.0 1 Antimony ND ug/L 04/02/15 16:22 7440-36-004/02/15 07:300.50 0.15 1 Arsenic ND ug/L 04/02/15 16:22 7440-38-204/02/15 07:300.50 0.11 1 Barium 1.9 ug/L 04/02/15 16:22 7440-39-304/02/15 07:300.30 0.081 1 Beryllium ND ug/L 04/02/15 16:22 7440-41-704/02/15 07:300.20 0.067 1 Boron ND ug/L 04/02/15 16:22 7440-42-804/02/15 07:305.0 1.1 1 Cadmium ND ug/L 04/02/15 16:22 7440-43-904/02/15 07:300.080 0.024 1 Calcium 14500 ug/L 04/02/15 16:22 7440-70-204/02/15 07:3040.0 16.0 1 Chromium 1.6 ug/L 04/02/15 16:22 7440-47-304/02/15 07:300.50 0.17 1 Cobalt 1.4 ug/L 04/02/15 16:22 7440-48-404/02/15 07:300.50 0.13 1 Copper ND ug/L 04/02/15 16:22 7440-50-804/02/15 07:301.0 0.21 1 Iron 481 ug/L 04/02/15 16:22 7439-89-604/02/15 07:3050.0 13.7 1 Lead 0.43 ug/L 04/02/15 16:22 7439-92-104/02/15 07:300.10 0.046 1 Magnesium 286 ug/L 04/02/15 16:22 7439-95-404/02/15 07:3010.0 3.2 1 Manganese 11.0 ug/L 04/02/15 16:22 7439-96-504/02/15 07:300.50 0.24 1 Molybdenum ND ug/L 04/02/15 16:22 7439-98-704/02/15 07:300.50 0.094 1 Nickel ND ug/L 04/02/15 16:22 7440-02-004/02/15 07:300.50 0.16 1 Potassium 146 ug/L 04/02/15 16:22 7440-09-704/02/15 07:3050.0 11.7 1 Selenium ND ug/L 04/02/15 16:22 7782-49-204/02/15 07:300.50 0.20 1 Sodium ND ug/L 04/02/15 16:22 7440-23-504/02/15 07:3050.0 16.3 1 Strontium 16.2 ug/L 04/02/15 16:22 7440-24-604/02/15 07:300.50 0.13 1 Thallium ND ug/L 04/02/15 16:22 7440-28-004/02/15 07:300.10 0.015 1 Vanadium 1.5 ug/L 04/02/15 16:22 7440-62-204/02/15 07:301.0 0.28 1 Zinc ND ug/L 04/02/15 16:22 7440-66-604/02/15 07:305.0 2.4 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 04/01/15 13:23 7439-97-604/01/15 09:200.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 40 of 68 Page 51 of 80 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92242955 J15030673 Sample:2015008546 Lab ID:92242955010 Collected:03/24/15 08:45 Received:03/26/15 14:45 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6020A Preparation Method: EPA 30206020A MET ICPMS Aluminum 209 ug/L 04/02/15 19:00 7429-90-504/02/15 07:3010.0 3.0 1 Antimony ND ug/L 04/02/15 19:00 7440-36-004/02/15 07:300.50 0.15 1 Arsenic ND ug/L 04/02/15 19:00 7440-38-204/02/15 07:300.50 0.11 1 Barium 1.9 ug/L 04/02/15 19:00 7440-39-304/02/15 07:300.30 0.081 1 Beryllium ND ug/L 04/02/15 19:00 7440-41-704/02/15 07:300.20 0.067 1 Boron ND ug/L 04/02/15 19:00 7440-42-804/02/15 07:305.0 1.1 1 Cadmium ND ug/L 04/02/15 19:00 7440-43-904/02/15 07:300.080 0.024 1 Calcium 405 ug/L 04/02/15 19:00 7440-70-204/02/15 07:3040.0 16.0 1 Chromium 3.5 ug/L 04/02/15 19:00 7440-47-304/02/15 07:300.50 0.17 1 Cobalt 1.5 ug/L 04/02/15 19:00 7440-48-404/02/15 07:300.50 0.13 1 Copper 1.6 ug/L 04/02/15 19:00 7440-50-804/02/15 07:301.0 0.21 1 Iron 983 ug/L 04/02/15 19:00 7439-89-604/02/15 07:3050.0 13.7 1 Lead 0.25 ug/L 04/02/15 19:00 7439-92-104/02/15 07:300.10 0.046 1 Magnesium 29.2 ug/L 04/02/15 19:00 7439-95-404/02/15 07:3010.0 3.2 1 Manganese 8.8 ug/L 04/02/15 19:00 7439-96-504/02/15 07:300.50 0.24 1 Molybdenum 0.64 ug/L 04/02/15 19:00 7439-98-704/02/15 07:300.50 0.094 1 Nickel 0.66 ug/L 04/02/15 19:00 7440-02-004/02/15 07:300.50 0.16 1 Potassium 53.5 ug/L 04/02/15 19:00 7440-09-704/02/15 07:3050.0 11.7 1 Selenium ND ug/L 04/02/15 19:00 7782-49-204/02/15 07:300.50 0.20 1 Sodium 71.0 ug/L 04/02/15 19:00 7440-23-504/02/15 07:3050.0 16.3 1 Strontium 1.6 ug/L 04/02/15 19:00 7440-24-604/02/15 07:300.50 0.13 1 Thallium ND ug/L 04/02/15 19:00 7440-28-004/02/15 07:300.10 0.015 1 Vanadium ND ug/L 04/02/15 19:00 7440-62-204/02/15 07:301.0 0.28 1 Zinc 6.6 ug/L 04/02/15 19:00 7440-66-604/02/15 07:305.0 2.4 1 Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury Mercury ND ug/L 04/01/15 13:26 7439-97-604/01/15 09:200.20 0.022 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 41 of 68 Page 52 of 80 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92242955 J15030673 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/13104 EPA 7470 EPA 7470 7470 Mercury Associated Lab Samples:92242955009, 92242955010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1929182 Associated Lab Samples:92242955009, 92242955010 Matrix:Water Analyzed Mercury ug/L ND 0.20 04/01/15 13:03 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1929183LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 5.45 108 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1929376MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92242976005 1929377 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 106 75-125110 4 205ND5.3 5.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 42 of 68 Page 53 of 80 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92242955 J15030673 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/13233 EPA 7470 EPA 7470 7470 Mercury Associated Lab Samples:92242955007, 92242955008 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1939461 Associated Lab Samples:92242955007, 92242955008 Matrix:Water Analyzed Mercury ug/L ND 0.20 04/17/15 06:43 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1939462LABORATORY CONTROL SAMPLE: LCSSpike Mercury ug/L 5.05 100 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1939463MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245086002 1939464 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury ug/L 5 102 75-125102 0 205ND5.1 5.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 43 of 68 Page 54 of 80 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92242955 J15030673 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MERP/5551 EPA 7471 EPA 7471 7471 Mercury Associated Lab Samples:92242955001, 92242955002, 92242955003, 92242955004, 92242955005, 92242955006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1174890 Associated Lab Samples:92242955001, 92242955002, 92242955003, 92242955004, 92242955005, 92242955006 Matrix:Solid Analyzed Mercury mg/kg ND 0.0081 04/04/15 20:07 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1174891LABORATORY CONTROL SAMPLE: LCSSpike Mercury mg/kg 0.077.081 94 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1174892MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92242976001 1174893 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mercury mg/kg .083 101 80-12088 3 20.0830.25 0.33 0.32 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 44 of 68 Page 55 of 80 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92242955 J15030673 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/23407 EPA 3050 EPA 6010 6010 MET Solid Associated Lab Samples:92242955001, 92242955002, 92242955003, 92242955004, 92242955005, 92242955006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1173242 Associated Lab Samples:92242955001, 92242955002, 92242955003, 92242955004, 92242955005, 92242955006 Matrix:Solid Analyzed Aluminum mg/kg ND 5.1 04/07/15 07:49 Barium mg/kg ND 0.51 04/07/15 07:49 Beryllium mg/kg ND 0.051 04/07/15 07:49 Boron mg/kg ND 2.5 04/07/15 07:49 Calcium mg/kg ND 25.3 04/07/15 07:49 Chromium mg/kg ND 0.25 04/07/15 07:49 Copper mg/kg ND 0.25 04/07/15 07:49 Iron mg/kg ND 2.0 04/07/15 07:49 Magnesium mg/kg ND 25.3 04/07/15 07:49 Manganese mg/kg ND 0.25 04/07/15 07:49 Molybdenum mg/kg ND 0.51 04/07/15 07:49 Nickel mg/kg ND 0.25 04/07/15 07:49 Potassium mg/kg ND 50.5 04/07/15 07:49 Sodium mg/kg ND 50.5 04/07/15 07:49 Strontium mg/kg ND 0.51 04/07/15 07:49 Zinc mg/kg 0.56J 1.0 04/07/15 07:49 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1173243LABORATORY CONTROL SAMPLE: LCSSpike Aluminum mg/kg 136126 108 80-120 Barium mg/kg 13.512.6 107 80-120 Beryllium mg/kg 1.41.3 112 80-120 Boron mg/kg 137126 109 80-120 Calcium mg/kg 687628 109 80-120 Chromium mg/kg 13.312.6 106 80-120 Copper mg/kg 13.512.6 108 80-120 Iron mg/kg 136126 108 80-120 Magnesium mg/kg 658628 105 80-120 Manganese mg/kg 13.812.6 110 80-120 Molybdenum mg/kg 13.212.6 105 80-120 Nickel mg/kg 13.412.6 107 80-120 Potassium mg/kg 659628 105 80-120 Sodium mg/kg 692628 110 80-120 Strontium mg/kg 13.512.6 108 80-120 Zinc mg/kg 67.962.8 108 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 45 of 68 Page 56 of 80 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92242955 J15030673 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1173244MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92242976001 1173245 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum mg/kg M112422675-125209 0 20127127001300012900 Barium mg/kg M112.4 106 75-125145 2 2012.7218 231 236 Beryllium mg/kg M11.2 79 75-12570 2 201.35.0 5.9 5.8 Boron mg/kg 124 88 75-12586 0 2012760.9 169 170 Calcium mg/kg M16207575-12547 4 20635325037203550 Chromium mg/kg 12.4 77 75-12581 2 2012.720.3 29.9 30.6 Copper mg/kg M112.4 58 75-12559 0 2012.755.1 62.4 62.6 Iron mg/kg M1124-562 75-125-462 2 20127624055405650 Magnesium mg/kg 620 92 75-12592 1 2063579313601380 Manganese mg/kg 12.4 76 75-12577 1 2012.746.8 56.2 56.6 Molybdenum mg/kg 12.4 88 75-12590 4 2012.72.2J 13.2 13.7 Nickel mg/kg 12.4 90 75-12597 3 2012.730.4 41.6 42.8 Potassium mg/kg 620 113 75-125115 1 20635153022302260 Sodium mg/kg 620 98 75-12599 3 20635333938963 Strontium mg/kg M112.4 -128 75-125-165 3 2012.7222 206 201 Zinc mg/kg 62 93 75-12596 3 2063.542.7 100 104 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 46 of 68 Page 57 of 80 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92242955 J15030673 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/23408 EPA 3050 EPA 6020 6020 MET SOLID Associated Lab Samples:92242955001, 92242955002, 92242955003, 92242955004, 92242955005, 92242955006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1173246 Associated Lab Samples:92242955001, 92242955002, 92242955003, 92242955004, 92242955005, 92242955006 Matrix:Solid Analyzed Antimony mg/kg 0.026J 0.050 N204/06/15 10:43 Arsenic mg/kg ND 0.050 04/06/15 10:43 Cadmium mg/kg ND 0.0060 04/06/15 10:43 Cobalt mg/kg ND 0.050 04/06/15 10:43 Lead mg/kg ND 0.050 04/06/15 10:43 Selenium mg/kg ND 0.050 04/06/15 10:43 Thallium mg/kg ND 0.050 04/06/15 10:43 Vanadium mg/kg ND 0.050 04/06/15 10:43 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1173247LABORATORY CONTROL SAMPLE: LCSSpike Antimony mg/kg 2.6 N22.5 103 80-120 Arsenic mg/kg 2.62.5 105 80-120 Cadmium mg/kg 0.25.25 100 80-120 Cobalt mg/kg 2.62.5 103 80-120 Lead mg/kg 2.52.5 101 80-120 Selenium mg/kg 2.62.5 104 80-120 Thallium mg/kg 2.62.5 103 80-120 Vanadium mg/kg 2.52.5 101 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1173248MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92242976002 1173249 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony mg/kg M6,N22.6 56 75-12543 15 202.41.4J 2.9 2.5 Arsenic mg/kg M62.6 272 75-125178 12 202.417.1 24.2 21.5 Cadmium mg/kg .26 109 75-12599 12 20.24ND 0.36 0.31 Cobalt mg/kg M62.6 153 75-125152 3 202.45.0 8.9 8.7 Lead mg/kg M62.6 203 75-125191 5 202.47.3 12.6 11.9 Selenium mg/kg M62.6 243 75-125137 17 202.412.6 18.9 15.9 Thallium mg/kg M62.6 66 75-12562 202.4ND 2.2J 2.0J Vanadium mg/kg M62.6 293 75-125270 3 202.430.9 38.5 37.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 47 of 68 Page 58 of 80 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92242955 J15030673 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/53294 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92242955009, 92242955010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1929140 Associated Lab Samples:92242955009, 92242955010 Matrix:Water Analyzed Aluminum ug/L ND 10.0 04/02/15 15:57 Antimony ug/L ND 0.50 04/02/15 15:57 Arsenic ug/L ND 0.50 04/02/15 15:57 Barium ug/L ND 0.30 04/02/15 15:57 Beryllium ug/L ND 0.20 04/02/15 15:57 Boron ug/L ND 5.0 04/02/15 15:57 Cadmium ug/L ND 0.080 04/02/15 15:57 Calcium ug/L ND 40.0 04/02/15 15:57 Chromium ug/L ND 0.50 04/02/15 15:57 Cobalt ug/L ND 0.50 04/02/15 15:57 Copper ug/L ND 1.0 04/02/15 15:57 Iron ug/L ND 50.0 04/02/15 15:57 Lead ug/L ND 0.10 04/02/15 15:57 Magnesium ug/L ND 10.0 04/02/15 15:57 Manganese ug/L ND 0.50 04/02/15 15:57 Molybdenum ug/L ND 0.50 04/02/15 15:57 Nickel ug/L ND 0.50 04/02/15 15:57 Potassium ug/L ND 50.0 04/02/15 15:57 Selenium ug/L ND 0.50 04/02/15 15:57 Sodium ug/L ND 50.0 04/02/15 15:57 Strontium ug/L ND 0.50 04/02/15 15:57 Thallium ug/L ND 0.10 04/02/15 15:57 Vanadium ug/L ND 1.0 04/02/15 15:57 Zinc ug/L ND 5.0 04/02/15 15:57 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1929141LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 84.180 105 80-120 Antimony ug/L 83.280 104 80-120 Arsenic ug/L 84.580 106 80-120 Barium ug/L 81.880 102 80-120 Beryllium ug/L 84.680 106 80-120 Boron ug/L 83.980 105 80-120 Cadmium ug/L 81.880 102 80-120 Calcium ug/L 9811000 98 80-120 Chromium ug/L 83.480 104 80-120 Cobalt ug/L 81.880 102 80-120 Copper ug/L 77.680 97 80-120 Iron ug/L 10601000 106 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 48 of 68 Page 59 of 80 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92242955 J15030673 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1929141LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 86.580 108 80-120 Magnesium ug/L 10201000 102 80-120 Manganese ug/L 86.180 108 80-120 Molybdenum ug/L 79.280 99 80-120 Nickel ug/L 81.280 101 80-120 Potassium ug/L 10601000 106 80-120 Selenium ug/L 83.280 104 80-120 Sodium ug/L 10301000 103 80-120 Strontium ug/L 83.180 104 80-120 Thallium ug/L 85.480 107 80-120 Vanadium ug/L 83.280 104 80-120 Zinc ug/L 84.980 106 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1929142MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92242959001 1929143 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L 80 113 75-125107 5 208011.6 102 97.4 Antimony ug/L 80 105 75-125104 1 2080ND83.7 83.2 Arsenic ug/L 80 107 75-125107 0 2080ND85.5 85.6 Barium ug/L 80 104 75-125103 0 2080ND83.5 83.1 Beryllium ug/L 80 107 75-125107 1 2080ND85.8 85.2 Boron ug/L 80 107 75-125106 1 2080ND86.4 85.8 Cadmium ug/L 80 103 75-125104 1 2080ND82.2 82.9 Calcium ug/L 1000 102 75-12596 5 201000ND10501000 Chromium ug/L 80 106 75-125106 0 2080ND85.2 85.3 Cobalt ug/L 80 105 75-125104 1 2080ND83.6 82.9 Copper ug/L 80 99 75-12598 1 20801.5 80.3 79.9 Iron ug/L 1000 107 75-125106 1 201000ND10901080 Lead ug/L 80 108 75-125109 1 20800.24 87.0 87.8 Magnesium ug/L 1000 105 75-125104 1 20100012.9 1070 1050 Manganese ug/L 80 109 75-125109 0 20801.1 87.9 87.9 Molybdenum ug/L 80 100 75-125100 0 2080ND79.8 80.1 Nickel ug/L 80 104 75-125103 1 2080ND83.3 82.5 Potassium ug/L 1000 110 75-125110 1 201000ND11201130 Selenium ug/L 80 105 75-125105 0 2080ND84.0 84.0 Sodium ug/L 1000 105 75-125105 0 201000ND10901090 Strontium ug/L 80 105 75-125105 1 2080ND83.8 84.3 Thallium ug/L 80 105 75-125105 1 2080ND83.7 84.3 Vanadium ug/L 80 104 75-125105 0 2080ND83.4 83.7 Zinc ug/L 80 106 75-125105 1 2080ND87.3 86.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 49 of 68 Page 60 of 80 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92242955 J15030673 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: MPRP/53629 EPA 3020 EPA 6020A 6020A Water UPD4 Associated Lab Samples:92242955007, 92242955008 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1939440 Associated Lab Samples:92242955007, 92242955008 Matrix:Water Analyzed Aluminum ug/L ND 10.0 04/17/15 14:19 Antimony ug/L ND 0.50 04/17/15 14:19 Arsenic ug/L ND 0.50 04/17/15 14:19 Barium ug/L ND 0.30 04/17/15 14:19 Beryllium ug/L ND 0.20 04/17/15 14:19 Boron ug/L ND 5.0 04/17/15 14:19 Cadmium ug/L ND 0.080 04/17/15 14:19 Calcium ug/L ND 40.0 04/17/15 14:19 Chromium ug/L ND 0.50 04/17/15 14:19 Cobalt ug/L ND 0.50 04/17/15 14:19 Copper ug/L ND 1.0 04/17/15 14:19 Iron ug/L ND 50.0 04/17/15 14:19 Lead ug/L ND 0.10 04/17/15 14:19 Magnesium ug/L ND 10.0 04/17/15 14:19 Manganese ug/L ND 0.50 04/17/15 14:19 Molybdenum ug/L ND 0.50 04/17/15 14:19 Nickel ug/L ND 0.50 04/17/15 14:19 Potassium ug/L ND 50.0 04/17/15 14:19 Selenium ug/L ND 0.50 04/17/15 14:19 Sodium ug/L ND 50.0 04/17/15 14:19 Strontium ug/L ND 0.50 04/17/15 14:19 Thallium ug/L ND 0.10 04/17/15 14:19 Vanadium ug/L ND 1.0 04/17/15 14:19 Zinc ug/L ND 5.0 04/17/15 14:19 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1939441LABORATORY CONTROL SAMPLE: LCSSpike Aluminum ug/L 80.580 101 80-120 Antimony ug/L 78.680 98 80-120 Arsenic ug/L 78.280 98 80-120 Barium ug/L 78.980 99 80-120 Beryllium ug/L 69.680 87 80-120 Boron ug/L 73.980 92 80-120 Cadmium ug/L 78.280 98 80-120 Calcium ug/L 9581000 96 80-120 Chromium ug/L 78.780 98 80-120 Cobalt ug/L 78.380 98 80-120 Copper ug/L 80.980 101 80-120 Iron ug/L 10101000 101 80-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 50 of 68 Page 61 of 80 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92242955 J15030673 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1939441LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 78.980 99 80-120 Magnesium ug/L 9801000 98 80-120 Manganese ug/L 78.680 98 80-120 Molybdenum ug/L 79.280 99 80-120 Nickel ug/L 80.680 101 80-120 Potassium ug/L 10001000 100 80-120 Selenium ug/L 78.880 99 80-120 Sodium ug/L 9701000 97 80-120 Strontium ug/L 78.580 98 80-120 Thallium ug/L 79.580 99 80-120 Vanadium ug/L 82.480 103 80-120 Zinc ug/L 78.980 99 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1939444MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92245086001 1939445 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Aluminum ug/L M18013975-125165 13 208045.6 157 178 Antimony ug/L 80 98 75-12596 1 2080ND78.2 77.2 Arsenic ug/L 80 98 75-12598 0 2080ND78.6 78.4 Barium ug/L 80 96 75-12597 1 20801.1 78.2 79.0 Beryllium ug/L 80 85 75-12583 2 2080ND67.9 66.3 Boron ug/L 80 102 75-125100 2 2080ND83.0 81.1 Cadmium ug/L 80 97 75-12598 0 2080ND77.8 78.1 Calcium ug/L 1000 95 75-12599 3 20100012910801120 Chromium ug/L 80 98 75-12598 1 2080ND78.2 78.6 Cobalt ug/L 80 99 75-12598 1 2080ND79.0 78.3 Copper ug/L 80 102 75-125101 0 2080ND81.6 81.4 Iron ug/L 1000 103 75-125103 0 20100060.0 1090 1090 Lead ug/L 80 98 75-12597 1 2080ND78.2 77.7 Magnesium ug/L 1000 96 75-12597 1 20100030.0 990 1000 Manganese ug/L 80 99 75-12598 1 20803.5 82.8 81.7 Molybdenum ug/L 80 97 75-12598 1 2080ND77.9 78.6 Nickel ug/L 80 102 75-125101 1 2080ND81.4 80.6 Potassium ug/L 1000 102 75-125101 0 201000ND10601060 Selenium ug/L 80 101 75-125100 0 2080ND80.5 80.3 Sodium ug/L 1000 97 75-12597 1 20100050.2 1020 1020 Strontium ug/L 80 97 75-12597 0 20800.89 78.6 78.3 Thallium ug/L 80 101 75-125101 0 2080ND80.8 80.5 Vanadium ug/L 80 102 75-125101 1 2080ND81.8 80.8 Zinc ug/L 80 98 75-125100 2 2080ND80.2 81.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 51 of 68 Page 62 of 80 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92242955 J15030673 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: PMST/3411 ASTM D2974-87 ASTM D2974-87 Dry Weight/Percent Moisture Associated Lab Samples:92242955001, 92242955002, 92242955003, 92242955004, 92242955005, 92242955006 Parameter Units Dup Result Max RPD QualifiersRPDResult 35181405002 1174882SAMPLE DUPLICATE: Percent Moisture %15.5 1 1015.7 Parameter Units Dup Result Max RPD QualifiersRPDResult 92243188001 1174883SAMPLE DUPLICATE: Percent Moisture %18.7 1 10 Parameter Units Dup Result Max RPD QualifiersRPDResult 92243093008 1174884SAMPLE DUPLICATE: Percent Moisture %4.6 D635106.6 Parameter Units Dup Result Max RPD QualifiersRPDResult 92243093018 1174885SAMPLE DUPLICATE: Percent Moisture %23.9 5 1022.8 Parameter Units Dup Result Max RPD QualifiersRPDResult 92242955005 1174886SAMPLE DUPLICATE: Percent Moisture %4.2 3 104.1 Parameter Units Dup Result Max RPD QualifiersRPDResult 92243087002 1174887SAMPLE DUPLICATE: Percent Moisture %18.8 2 1019.2 Parameter Units Dup Result Max RPD QualifiersRPDResult 92242920003 1174888SAMPLE DUPLICATE: Percent Moisture %25.9 2 1025.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 52 of 68 Page 63 of 80 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92242955 J15030673 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 92242920016 1174889SAMPLE DUPLICATE: Percent Moisture %20.3 5 1019.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 53 of 68 Page 64 of 80 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92242955 J15030673 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WET/36525 EPA 9045 EPA 9045 9045 pH Associated Lab Samples:92242955001, 92242955002, 92242955003, 92242955004, 92242955005, 92242955006 Parameter Units Dup Result Max RPD QualifiersRPDResult 92242920012 1422956SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 6.6 0 106.6 Parameter Units Dup Result Max RPD QualifiersRPDResult 92242920014 1422957SAMPLE DUPLICATE: pH at 25 Degrees C Std. Units 8.0 0 108.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 54 of 68 Page 65 of 80 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92242955 J15030673 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22469 EPA 300.0 EPA 300.0 300.0 IC Anions Associated Lab Samples:92242955005, 92242955006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1428206 Associated Lab Samples:92242955005, 92242955006 Matrix:Water Analyzed Sulfate mg/L 2.0J 2.0 04/07/15 14:55 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1428207LABORATORY CONTROL SAMPLE: LCSSpike Sulfate mg/L 19.620 98 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1428208MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92240170029 1428209 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate mg/L H124.8 94 94 024.82.0J 25.3 25.4 Parameter Units MS Result % Rec Limits Qual% RecConc. 1428210MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92242976002 1428211 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Sulfate mg/L 41 100 100 04112.7 53.8 53.7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 55 of 68 Page 66 of 80 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92242955 J15030673 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22500 EPA 353.2 EPA 353.2 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples:92242955005, 92242955006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1431018 Associated Lab Samples:92242955005, 92242955006 Matrix:Water Analyzed Nitrogen, Nitrate mg/L 0.11 0.020 Z204/09/15 19:03 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1431019LABORATORY CONTROL SAMPLE: LCSSpike Nitrogen, Nitrate mg/L 2.42.5 97 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1431020MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92242504018 1431021 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L H149990-11099 0 104ND4.1 4.1 Parameter Units MS Result % Rec Limits Qual% RecConc. 1431022MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92242504019 1431023 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Nitrogen, Nitrate mg/L H12.5 92 90-11092 0 102.5ND 2.4 2.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 56 of 68 Page 67 of 80 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92242955 J15030673 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/22478 SM 4500-Cl-E SM 4500-Cl-E 4500 Chloride Associated Lab Samples:92242955005, 92242955006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1428876 Associated Lab Samples:92242955005, 92242955006 Matrix:Water Analyzed Chloride mg/L ND 1.0 04/08/15 02:24 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1428877LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/L 20.220 101 90-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1428878MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92242504017 1428879 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L 26.3 103 90-110102 1 1026.3ND 28.3 28.1 Parameter Units MS Result % Rec Limits Qual% RecConc. 1428880MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243093009 1428881 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chloride mg/L 31.8 100 90-11098 2 1031.8ND 32.7 32.0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 57 of 68 Page 68 of 80 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92242955 J15030673 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/45008 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92242955001, 92242955002, 92242955003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1171004 Associated Lab Samples: Matrix:Solid Analyzed Chloride mg/kg ND 49.5 04/01/15 12:48 Sulfate mg/kg ND 49.5 04/01/15 12:48 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1171005LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/kg 465500 93 80-120 Sulfate mg/kg 465500 93 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1171007MATRIX SPIKE SAMPLE: MSSpike Result 92242920001 Chloride mg/kg 707 M17867380-120ND Sulfate mg/kg 1140786 87 80-120464 Parameter Units Dup Result Max RPD QualifiersRPDResult 92242920001 1171006SAMPLE DUPLICATE: Chloride mg/kg ND 20ND Sulfate mg/kg 483 4 20464 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 58 of 68 Page 69 of 80 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92242955 J15030673 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/45010 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92242955004, 92242955005, 92242955006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1171012 Associated Lab Samples: Matrix:Solid Analyzed Chloride mg/kg ND 50.0 04/01/15 22:48 Sulfate mg/kg ND 50.0 04/01/15 22:48 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1171013LABORATORY CONTROL SAMPLE: LCSSpike Chloride mg/kg 466490 95 80-120 Sulfate mg/kg 462490 94 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1171015MATRIX SPIKE SAMPLE: MSSpike Result 92242955004 Chloride mg/kg 457508 90 80-120ND Sulfate mg/kg 471508 93 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92242955004 1171014SAMPLE DUPLICATE: Chloride mg/kg ND 20ND Sulfate mg/kg ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 59 of 68 Page 70 of 80 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92242955 J15030673 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/45006 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92242955001, 92242955002, 92242955003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1170996 Associated Lab Samples: Matrix:Solid Analyzed Nitrate as N mg/kg ND 5.0 04/01/15 12:48 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1170997LABORATORY CONTROL SAMPLE: LCSSpike Nitrate as N mg/kg 48.550 97 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1170999MATRIX SPIKE SAMPLE: MSSpike Result 92242920001 Nitrate as N mg/kg 70.0 H378.6 89 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92242920001 1170998SAMPLE DUPLICATE: Nitrate as N mg/kg ND H320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 60 of 68 Page 71 of 80 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92242955 J15030673 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/45009 EPA 9056 EPA 9056 9056 IC Anions Associated Lab Samples:92242955004, 92242955005, 92242955006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1171008 Associated Lab Samples: Matrix:Solid Analyzed Nitrate as N mg/kg ND 5.0 04/01/15 22:48 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1171009LABORATORY CONTROL SAMPLE: LCSSpike Nitrate as N mg/kg 48.749 99 80-120 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1171011MATRIX SPIKE SAMPLE: MSSpike Result 92242955004 Nitrate as N mg/kg 46.0 H350.8 91 80-120ND Parameter Units Dup Result Max RPD QualifiersRPDResult 92242955004 1171010SAMPLE DUPLICATE: Nitrate as N mg/kg ND H320ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 61 of 68 Page 72 of 80 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92242955 J15030673 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/27904 EPA 9060 EPA 9060 9060 TOC Average Associated Lab Samples:92242955001, 92242955002, 92242955003, 92242955004, 92242955005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1137566 Associated Lab Samples: Matrix:Solid Analyzed Mean Total Organic Carbon mg/kg ND 600 04/08/15 06:45 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1137567LABORATORY CONTROL SAMPLE: LCSSpike Mean Total Organic Carbon mg/kg 120000120000 100 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1137568MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92242955001 1137569 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 7270 95 50-15098 3 307280564J74607700 Parameter Units MS Result % Rec Limits Qual% RecConc. 1137570MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92242959006 1137571 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 94900 89 50-150114 11 3095000130000214000238000 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 62 of 68 Page 73 of 80 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92242955 J15030673 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: WETA/28037 EPA 9060 EPA 9060 9060 TOC Average Associated Lab Samples:92242955006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1141398 Associated Lab Samples: Matrix:Solid Analyzed Mean Total Organic Carbon mg/kg ND 600 04/17/15 05:46 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1141399LABORATORY CONTROL SAMPLE: LCSSpike Mean Total Organic Carbon mg/kg 114000120000 95 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1141400MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243245001 1141401 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 114000 89 50-150101 6 3011300091000193000205000 Parameter Units MS Result % Rec Limits Qual% RecConc. 1141402MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92243090001 1141403 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Mean Total Organic Carbon mg/kg 6640 99 50-15087 12 306650334J69106120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 63 of 68 Page 74 of 80 #=QL# QUALIFIERS Pace Project No.: Project: 92242955 J15030673 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C Pace Analytical Services - Green BayPASI-G Pace Analytical Services - MinneapolisPASI-M Pace Analytical Services - Ormond BeachPASI-O ANALYTE QUALIFIERS Analyte was detected in the associated method blank.B Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6 Analysis conducted outside the EPA method holding time.H1 Sample was received or analysis requested beyond the recognized method holding time.H3 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6 The lab does not hold TNI accreditation for this parameter.N2 RPD value was outside control limits.R1 Analyte present in the associated method blank above the detection limit.Z2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 64 of 68 Page 75 of 80 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92242955 J15030673 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92242955001 MPRP/23407 ICP/143312015008539EPA 3050 EPA 6010 92242955002 MPRP/23407 ICP/143312015008540EPA 3050 EPA 6010 92242955003 MPRP/23407 ICP/143312015008541EPA 3050 EPA 6010 92242955004 MPRP/23407 ICP/143312015008542EPA 3050 EPA 6010 92242955005 MPRP/23407 ICP/143312015008543EPA 3050 EPA 6010 92242955006 MPRP/23407 ICP/143312015008544EPA 3050 EPA 6010 92242955001 MPRP/23408 ICPM/95422015008539EPA 3050 EPA 6020 92242955002 MPRP/23408 ICPM/95422015008540EPA 3050 EPA 6020 92242955003 MPRP/23408 ICPM/95422015008541EPA 3050 EPA 6020 92242955004 MPRP/23408 ICPM/95422015008542EPA 3050 EPA 6020 92242955005 MPRP/23408 ICPM/95422015008543EPA 3050 EPA 6020 92242955006 MPRP/23408 ICPM/95422015008544EPA 3050 EPA 6020 92242955007 MPRP/53629 ICPM/238112015008543 SPLP EPA 3020 EPA 6020A 92242955008 MPRP/53629 ICPM/238112015008544 SPLP EPA 3020 EPA 6020A 92242955009 MPRP/53294 ICPM/236392015008545EPA 3020 EPA 6020A 92242955010 MPRP/53294 ICPM/236392015008546EPA 3020 EPA 6020A 92242955007 MERP/13233 MERC/153882015008543 SPLP EPA 7470 EPA 7470 92242955008 MERP/13233 MERC/153882015008544 SPLP EPA 7470 EPA 7470 92242955009 MERP/13104 MERC/152202015008545EPA 7470 EPA 7470 92242955010 MERP/13104 MERC/152202015008546EPA 7470 EPA 7470 92242955001 MERP/5551 MERC/55392015008539EPA 7471 EPA 7471 92242955002 MERP/5551 MERC/55392015008540EPA 7471 EPA 7471 92242955003 MERP/5551 MERC/55392015008541EPA 7471 EPA 7471 92242955004 MERP/5551 MERC/55392015008542EPA 7471 EPA 7471 92242955005 MERP/5551 MERC/55392015008543EPA 7471 EPA 7471 92242955006 MERP/5551 MERC/55392015008544EPA 7471 EPA 7471 92242955001 PMST/34112015008539ASTM D2974-87 92242955002 PMST/34112015008540ASTM D2974-87 92242955003 PMST/34112015008541ASTM D2974-87 92242955004 PMST/34112015008542ASTM D2974-87 92242955005 PMST/34112015008543ASTM D2974-87 92242955006 PMST/34112015008544ASTM D2974-87 92242955001 WET/365252015008539EPA 9045 92242955002 WET/365252015008540EPA 9045 92242955003 WET/365252015008541EPA 9045 92242955004 WET/365252015008542EPA 9045 92242955005 WET/365252015008543EPA 9045 92242955006 WET/365252015008544EPA 9045 92242955005 WETA/224692015008543EPA 300.0 92242955006 WETA/224692015008544EPA 300.0 92242955005 WETA/225002015008543EPA 353.2 92242955006 WETA/225002015008544EPA 353.2 92242955005 WETA/224782015008543SM 4500-Cl-E REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 65 of 68 Page 76 of 80 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92242955 J15030673 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92242955006 WETA/224782015008544SM 4500-Cl-E 92242955001 WETA/450082015008539EPA 9056 92242955002 WETA/450082015008540EPA 9056 92242955003 WETA/450082015008541EPA 9056 92242955004 WETA/450102015008542EPA 9056 92242955005 WETA/450102015008543EPA 9056 92242955006 WETA/450102015008544EPA 9056 92242955001 WETA/450062015008539EPA 9056 92242955002 WETA/450062015008540EPA 9056 92242955003 WETA/450062015008541EPA 9056 92242955004 WETA/450092015008542EPA 9056 92242955005 WETA/450092015008543EPA 9056 92242955006 WETA/450092015008544EPA 9056 92242955001 WETA/279042015008539EPA 9060 92242955001 WETA/279052015008539EPA 9060 92242955002 WETA/279042015008540EPA 9060 92242955002 WETA/279052015008540EPA 9060 92242955003 WETA/279042015008541EPA 9060 92242955003 WETA/279052015008541EPA 9060 92242955004 WETA/279042015008542EPA 9060 92242955004 WETA/279052015008542EPA 9060 92242955005 WETA/279042015008543EPA 9060 92242955005 WETA/279052015008543EPA 9060 92242955006 WETA/280372015008544EPA 9060 92242955006 WETA/280382015008544EPA 9060 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 04/21/2015 07:42 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 66 of 68 Page 77 of 80 Page 67 of 68 Page 78 of 80 Page 68 of 68 Page 79 of 80 Page 80 of 80