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HomeMy WebLinkAboutNC0001422_Well Water Lab Results_20150805 (3)Environmental Chemists, Inc. envirochem 6602 Windmill Way • Wilmington, NC 25405 (910) 392-0223 (Lab) • (910) 392-4424 (Fax) SM 710 Bowsertown Road • Manteo, NC 27954 (252)473-5702 ANALYTICAL & CONSULTING CHEMISTS NCDENR: DWQ CERTIFICATE #94. DL$ CERTIFICATE #37729 Duke Energy -Laboratory Date of Report: Apr 20, 2015 1339 Hagers Ferry Road/Bld 7405 MG03A2 Customer PO #: Huntersville NC 28078 Customer ID: 15030001 Attention: Peggy Kendall Report #: 2015-02737 Project ID: Ash Pond Investigation Lab ID Sample ID: Collect Date/Time Matrix Sampled by 15-06244 Site: Reg # 4055 Well # 2 3/5/2015 10:45 AM DW Ray Porter/Cindy McDonald Test Method Results Date Analyzed Bicarbonate as CaCO3 Bicarbonate as CaCO3 1 mg/L 03/19/2015 Carbonate as CaCO3 Carbonate as CaCO3 <1 mg/L 03/19/2015 Aluminum EPA 200.7 0.070 mg/L 03/11/2015 Boron EPA 200.7 0.25 mg/L 03/11/2015 Calcium EPA 200.7 9.50 mg/L 03/12/2015 Iron EPA 200.7 0.120 mg/L 03/11/2015 Magnesium EPA 200.7 2.19 mg/L 03/12/2015 Potassium EPA 200.7 1.79 mg/L 03/12/2015 Sodium EPA 200.7 11.8 mg/L 03/12/2015 Strontium EPA 200.7 0.133 mg/L 03/11/2015 Zinc EPA 200.7 0.015 mg/L 03/11/2015 Antimony EPA 200.8 <0.000099mg/L 03/10/2015 Arsenic EPA 200.8 0.000293J mg/L 03/10/2015 J: Estimated. Between Method Detection Limit and Reporting Limit. Barium EPA 200.8 0.045 mg/L 03/10/2015 Beryllium EPA 200.8 <0.000146mg/L 03/10/2015 Cadmium EPA 200.8 <0.0000827mg/L 03/10/2015 Chromium EPA 200.8 <0.000148mg/L 03/10/2015 Cobalt EPA 200.8 0.004 mg/L 03/11/2015 Copper EPA 200.8 0.008 mg/L 03/10/2015 Lead EPA 200.8 0.000520 J mg/L 03/10/2015 J: Estimated. Between Method Detection Limit and Reporting Limit. Manganese EPA 200.8 0.142 mg/L 03/11/2015 Molybdenum EPA 200.8 <0.0001 15 mg/L 03/10/2015 Nickel EPA 200.3 < 0.100 mg/L 03/10/2015 Selenium EPA 200.8 0.00059408 J mg/L 03/27/2015 J: Estimated. Between Method Detection Limit and Reporting Limit. Report #:: 2015-02737 Page 1 of 2 00 7 1 gn:v7irochem' ANALYTICAL & CONSULTING CHEMISTS Environmental Chemists, Inc. Duke Energy -Laboratory 1339 Hagers Ferry Road/Bid 7405 MG03A2 Huntersville NC 28078 Attention: Peggy Kendall 6602 Windmill Way • Wilmington, NC 28405 (910)392-0223 (Lab) • (910) 392-4424 (Fax) 710 Bowsertown Road • Manteo, NC 27954 (252)473-5702 NCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE #37729 Date of Report: Apr 20, 2015 Customer PO #: Customer ID: 15030001 Report #: 2015-02737 Project ID: Ash Pond Investigation Thallium EPA 200.8 <0.0001 mg/L 03/10/2015 Vanadium EPA 200.8 0.000236 J mg/L 03/11/2015 J: Estimated. Between Method Detection Limit and Reporting Limit. SM 2540 C 85 mg/L Hexavalent Chromium EPA 218-7 <0.02 pg/L 03/09/2015 Mercury EPA 245.1 <0.0004 mg/L 03/09/2015 Sulfate EPA 300.0 33mg/L 03/11/2015 Turbidity SM2130B 0.2NTU 03/06/2015 Field Turbidity 0.2 NTU. Dissolved Oxygen SM 4500 o G 4.10 mg/L Alkalinity SM 2320B 1 mg/L 03/13/2015 Conductivity SM 2510 B 156 umho/cm 03/12/2015 Total Dissolved Solids (TDS) SM 2540 C 85 mg/L 03/06/2015 Residue Suspended (TSS) SM2540D <2.5 mg/L 03/09/2015 Temperature SM 2550 B 18.7 C 03/05/2015 Chloride SM 4500 CI B 19 mg/L 03/12/2015 pH SM4500H8 5.21 units 03/05/2015 Dissolved Oxygen SM 4500 o G 4.10 mg/L 03/05/2015 Comment: Turbidity, temperature, pH and dissolved oxygen measured in field at sample collection. All non - detects for metals reported to MDL. Reviewed by Report #:: 2015-02737 Page 2 of 2 Environmental Chemists, Inc. envirochem 6602 Windmill Way • Wilmington, NC 28405 (910)392-0223 (Lab) • (910) 392-4424 (Fax) SM 710 Bowsertown Road • Manteo, NC 27954 (252)473-5702 ANALYTICAL & CONSULTING CHEMISTS NCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE #37729 QC for Duke Energy - 2015-02737 LCS Parameter True Value m 2 Result m %True Value Limits Alkalinity 12.5 13 104 90-110 Aluminum 0.05 0.05 100 90-110 Antimony 0.01 0.01 100 90-110 Arsenic 0.01 0.01 100 90-110 Barium 0.01 0.01 100 90-110 Beryllium 0.01 0.01 100 90-110 Boron 0.05 0.05 100 90-110 Cadmium 0.01 0.01 100 90-110 Calcium 0.5 0.5 100 90-110 Chloride 50 48 96 90-110 Chromium 0.01 0.01 100 90-110 Cobalt 0.01 0.01 100 90-110 Conductivity 10000 99900 99.9 90/110 Copper 0.01 0.01 100 90-110 Iron 0.05 0.05 100 90-110 Lead 0.01 0.01 100 90-110 Magnesium 0.5 0.5 100 90-110 Manganese 0.01 0.01 100 90-110 Mercury 0.0040 0.0037 92 90-110 Molybdenum 0.01 0.01 100 90-110 Nickel 0.0050 0.0048 96 90-110 Potassium 0.5 0.5 100 90-110 TSS 248.8 274.4 110 90-110 Selenium 0.01 0.01 100 90-110 Sodium 0.5 0.5 100 90-110 Strontium 0.05 0.05 100 90-110 Sulfate 50 50 100 90-110 Thallium 0.0050 0.0048 96 90-110 TDS 600 601 100 f 10 Turbidity N/A N/A N/A N/A Vanadium 0.01 0.01 100 90-110 Zinc 0.05 0.05 100 90-110 1/M. XYM Parameter True Value mg/L Result mg/L % Recovery % Difference Limits % Recovery Limits % Difference Alkalinity N/A N/A N/A N/A N/A N/A Aluminum 0.100 0.099/0.100 99/100 1 80-120 <20 Antimony 0.025 0.028/0.028 112/112 0 80-120 <_ 20 Arsenic 0.025 0.030/0.030 120/120 0 80-120 <20 Barium 0.025 0.025/0.025 100/100 0 80-120 <_ 20 Beryllium 0.025 0.029/0.029 116/116 0 80-120 <20 Boron 0.100 0.097/0.095 97/95 2 80-120 <20 Cadmium 0.025 0.028/0.028 112/112 0 80-120 <20 Calcium 1.0 0.98/0.99 98/99 1 80-120 <20 Chloride N/A N/A N/A N/A N/A N/A Chromium 0.025 0.024/0.025 96/100 4 80-120 <_ 20 Cobalt 0.025 0.024/0.025 96/100 4 80-120 <20 Conductivity N/A N/A N/A N/A N/A N/A Copper 0.025 0.027/0.028 108/112 4 80-120 <_ 20 Iron 0.100 0.098/100 98/100 2 80-120 <20 Lead 0.025 0.023/0.023 92/92 0 80-120 <_ 20 Magnesium 1.0 0.98/1.0 98/100 2 80-120 <20 Manganese 0.025 0.024/0.025 96/100 4 80-120 <_ 20 Mercury 0.0020 0.0022/0.0019 110/95 15 80-120 <20 Molybdenum 0.025 0.028/0.028 112/112 0 80-120 <20 Nickel 0.0100 0.0099/0.0103 99/103 4 80-120 <_ 20 Potassium 1.0 1.0/1.0 100/100 0 80-120 <20 TSS N/A N/A N/A N/A N/A N/A Selenium 0.025 0.030/0.030 120/120 0 80-120 <20 Sodium 1.0 1.0/1.0 100/100 0 80-120 <_ 20 Strontium 0.100 0.098/0.105 98/105 7 80-120 <_ 20 71TTVT WA'TV 4ZA1% PT.Ti.0 Parameter 10.0 10.5/10.6 105/106 1 80-120 <_ 20 0 0.0100 0.0102/0.0105 102/105 3 80-120 <_ 20 Antimony N/A N/A N/A N/A N/A N/A MVanadium N/A N/A N/A N/A N/A N/A N/A 0.025 0.024/0.025 96/100 4 80-120 <_20 N/A 0.100 0.099/0.102 99/102 3 80-120 20 71TTVT WA'TV 4ZA1% PT.Ti.0 Parameter Results mg/L % Difference Limits Alkalinity 36 36 0 <_ 10 Aluminum N/A N/A N/A N/A Antimony N/A N/A N/A N/A Arsenic N/A N/A N/A N/A Barium N/A N/A N/A N/A Beryllium N/A N/A N/A N/A Boron N/A N/A N/A N/A Cadmium N/A N/A N/A N/A Calcium N/A N/A N/A N/A Chloride 467 462 1 <10 Chromium N/A N/A N/A N/A Cobalt N/A N/A N/A N/A Conductivity 156 156 0 <_ 10 Copper N/A N/A N/A N/A Iron N/A N/A N/A N/A Lead N/A N/A N/A N/A Magnesium N/A N/A N/A N/A Manganese N/A N/A N/A N/A Mercury N/A N/A N/A N/A Molybdenum N/A N/A N/A N/A NickelN/A N/A N/A N/A Potassium N/A N/A N/A N/A TSS 313.3 303.3 3 <_ 10 Selenium N/A N/A N/A N/A Sodium N/A N/A N/A N/A Strontium N/A N/A N/A N/A Sulfate 28 29 4 <10 Thallium N/A N/A N/A N/A TDs 403 404 0 :510 Turbidity 0.37 0.37 0 <10 Vanadium N/A N/A N/A N/A Zinc N/A N/A N/A N/A BLANKS Parameter Rmg�' Limit, mg/L Alkalinity 1 1 Aluminum <0.005 0.005 Antimony <0.0005 0.0005 Arsenic <0.0005 0.0005 Barium <0.0005 0.0005 Beryllium <0.0005 0.0005 Boron <0.005 0.005 Cadmium <0.0005 0.0005 Calcium <0.5 0.5 Chloride <2.5 2.5 Chromium <0.0005 0.0005 Cobalt <0.0005 0.0005 Conductivity <5 5 Copper <0.0005 0.0005 Iron <0.005 0.005 Lead <0.0005 0.0005 Magnesium <0.5 0.5 Manganese <0.0005 0.0005 Mercury <0.0002 0.0002 Molybdenum <0.0005 0.0005 Nickel <0.00005 0.00005 Potassium <0.5 0.5 TSS <2.5 2.5 Selenium <0.0005 0.0005 Sodium <0.5 0.5 Strontium <0.005 0.005 Sulfate <2.5 2.5 Thallium <0.00005 0.00005 TDS <2.5 2.5 Turbidity N/A N/A Vanadium <0.0005 0.0005 Zinc <0.005 0.005 A v v v v v v v v a tD Ln 00 N O -t^ LC) tD tD O N M^ 0) M d 00 a Ln ^ O N O N O MY tD ~^ M N N M O 0) N V^ O Ol 00 1f1 M O) M N N lD W00 O) N M^ 00 O N W 00 N O) 00 N O N Ir, N ^ V M v M O c'' O tD M M M V V lf1 41 O) O) O N O O D7 lfl N m lD a v Z Ln N 0) O O 0) 0) 000 00 O O O O O O O M 0) 0) O N O O m O M V A^ M^^ 00 10 N H N N V V' M M � V It V� V V -IT -It M M M V 00 cl' V' M Ln M C^ c -I Ln 00 N^00aavvv cvvvvavvvvvvvvvL.cvL^v^^ 00 L oN .000 LD ^ Q M ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ O ^ ^ ^ `MM ^ U Ln M O M U O M U U m 9 Ln U m m y M y ^ ^ ^ ^ ^ ^ ^ ^ ^ 00 00 00 00 00 00 00 00 W W W 00 00 00 00 ^ c -I O m CO CO U m U S O O� 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 00 Ifl 0 0 0 0 0 0 0 0 0 0 C O O O O O O O O O O O O O O O O O O O O O O O O N d' OM N -Q O N N N N N N N N N N N N N N N N N N N N N N N N N N M M m NLnLn Ln to V [0 Q O_ Q 0. 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Wilmington, NC 28412 Phone: 910 793-0128 Fax: 910 792-6853 ellab@ellab.com FINAL REPORT OF ANALYSES March 09, 2015 Client Project Name: Client Project Number: E1 Project Number e24189 Sample ID 15-06244 Sample Type Date Received 03/06/2015 Time Sampled 1045 Time Received 0810 Sampler Received by KMS E1 Sample # 24189-5 Result Unit Dilution DL Method Date < 0.02 pg/L 1 0.02 EPA 218.7 03/09/2015 Ken mith, Laboratory Director 24189 Envirochem Cr6+Report Compiled by �'w NC Certifications: DW 37788 and DWQ DENR 604 d {/\ / �5E } 7 , ) � }k(\ » )\{{ �7J ; ) Ln g a \\ a JZ E \ o fa 2 Ir\ E . ƒ� � \ ?iTwm ILL Jc;�rA fe Facility Name: Environmental Chemists, Inc Permit# 94' PLEASE CIRCLE METER USED FOR IDENTIFICATION PURPOSES Meter Id: 11277 Meter Id: 11250 Meter Id: 09996 - Meter Id: NYI-11373 --- Facility/Sample location Time Sampled* Time Analyzed+• Temp (°C) ■ I pH Result Buffer Check value Comment Sample Temperature Cp- G 9. <S-2,1 L/ �iV6 �f.� 10;'K G 0 +If sample is measured in directly in the stream only time analyzed would be recorded. ►Indicates a recommended drift check (Use Buffer 7.0) Should be within 0.1 units of the buffeNs true value) a Document the temperature of the sample at the time of analysis. Note: This temperature is not to be used for reporting on the monthly monitoring report Calibration drift check is recommended when performing analysis at multiple sampling locations, *All pH results in pH units (i.e., s.u.). check standard's obtained true value) Dissolved OMen (DO) Reference Method: SM 4500 O G, 20th Edition, —YSI DO 550 A Model—YSI PRO 20 Temperature °C Adjusted Au Calibration♦ (mg/L) Saturation % Calibration Time Facility/Sample Location DO reading mg/L `Time Analyze&Time Sampled Sample Temperature Cp- G ,tic 0 , L/ �iV6 �f.� 10;'K G 0 �zasea on appropriate alnmae adjustment - - - -- ♦ When performing analysis at multiple sampling locations, re-calibration(s) should he performed every four hours.. *Analysis time and sampling time the same. (Ideally the sample should be analyzed m -situ):. "Temperature Sewer Annual Check Date (550 A): INPROCESS Tempentnre Season Annual Check Date (PR020):IN PROCESS Temperature '=--. --- Reference Method: SM 2550 B 201h Edition Facility/Sample Location Tem/pent. C `Tim. Analyzern me Sampled .— Comments -Amlysts tlme and sampnng time the same.(Ideally the sample should be analyzed in -atlas). - --_- O ZN -'w,- wWLu " J 2� W O U z W V, Z z F Q' L w OW z i x a 1'` O m J w C U U O R n C1 o 0co N a❑ a 0 C E 3 is C m O � U F �j> 3 a a co E 5 = r H E Q W W iE- �m� L G a Z z O I -- p o LU Q z A w O t6 Y U Y U F Ury 3 U a w M U m a� � >,.a) x� oS oCD m. O Ci a LL] J U C > v c O F -0 Q tm m x o Mn d Z z Q a L (a w n� p 2 Q c a N 2 a li ;g `O m n J h m ❑ y CO N � > U @ c 2 Z � w 1== M d C M Y Y 7 y O U � v F- W C a7 ' a z a = W p c' aaHlo U Q Q co Z U c U U n o o 0co N a❑ a 0 m�2 E o -6W is m � U F �j> 3 a co E 5 = H E w iE- �m� L G a p o C o)t-o E A w O t6 Y U Y U F m 3 U) O o In U m a� � >,.a) x� oS oCD m. Ci a J U C > v c O F -0 Q m Cl) x o d Z z Q a L (a w n� p 2 Q c a N 2 U ;g `O m ❑ m C Z � > @ I� ui w rL U v d aaHlo y =m Z O OM1 0 d F HOVN .e o d U % CONN Q W E W90SZH y O 13H e m 3NON d L H88W N u ai sv, `o c E E 1/6w N o aUP0143 a C A (E) JO d) d (D d C9 a (D a (D d 0 d C7 a_ C7 a 0 o lauluj000 d e, d a d jo U CD U CD U C7 U C7 U C7 U C9 U CD U C7 allsodwoo E R adAj. aldwuS m c d m CL C v C a) Z a C H O U A c 0 E R � ¢ O `o M a C HO A o v Q L c a c -O el o 1- a as U V) 0 z r fV