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Home My WebLink AboutNC0001422_Well Water Lab Results_20150805 (2)Environmental Chemists, Inc. envirochem 6602 Windmill Way • Wilmington, NC 28405 (910) 392-0223 (Lab) • (910) 392-4424 (Fax) $M 710 Bowsertown Road • Manteo, NC 27954 (252)473-5702 ANALYTICAL & CONSULTING CHEMISTS NCDENR: DWQ CERTIFICATE 494. DLS CERTIFICATE #37729 Duke Energy -Laboratory Date of Report: Apr 20, 2015 1339 Hagers Ferry Road/Bld 7405 MG03A2 Customer PO #: Huntersville NC 28078 Customer ID: 15030001 Attention: Peggy Kendall Report #: 2015-02736 Project ID: Ash Pond Investigation Lab ID Sample ID: Collect Date/Time Matrix Sampled by 15-06243 Site: Ferg # 2485 3/5/2015 10:30 AM DW Ray Porter/Cindy McDonald Test Method Results Date Analyzed Bicarbonate as CaCO3 Bicarbonate as CaCO3 7.00 mg/L 03/19/2015 Carbonate as CaCO3 Carbonate as CaCO3 <1 mg/L 03/19/2015 Aluminum EPA 200.7 0.021 mg/L 03/11/2015 Baron EPA 200.7 0.02 mg/L 03/11/2015 Calcium EPA 200.7 4.17 mg/L 03/12/2015 Iron EPA 200.7 1.94 mg/L 03/20/2015 Magnesium EPA 200.7 0.48 mg/L 03/18/2015 Potassium EPA 200.7 0.54 mg/L 03/18/2015 Sodium EPA 200.7 2.82 mg/L 03/12/2015 Strontium EPA 200.7 0.016 mg/L 03/11/2015 Zinc EPA 200.7 0.016 mg/L 03/11/2015 Antimony EPA 200.8 <0.000099 mg/L 03/10/2015 Arsenic EPA 200.8 0.002 mg/L 03/10/2015 Barium EPA 200.8 0.024 mg/L 03/10/2015 Beryllium EPA 200.8 <0.000146 mg/L 03/10/2015 Cadmium EPA 200.8 <0.0000827mg/L 03/10/2015 Chromium EPA 200.8 <0.000 148 mg/L 03/10/2015 Cobalt EPA 200.8 0.003 mg/L 03/11/2015 Copper EPA 200.8 0.005 mg/L 03/10/2015 Lead EPA 200.8 0.000791 J mg/L 03/10/2015 J: Estimated. Between Method Detection Limit and Reporting Limit. Manganese EPA 200.8 0.074 mg/L 03/11/2015 Molybdenum EPA 200.8 <0.0001 15 mg/L 03/10/2015 Nickel EPA 200.8 < 0.100 mg/L 03/10/2015 Selenium EPA 200.8 0.00016426 J mg/L 03/27/2015 J: Estimated. Between Method Detection Limit and Reporting Limit. Thallium EPA 200.8 <0.0001 mg/L 03/10/2015 Report #:: 2015-02736 Page 1 of 2 Environmental Chemists, Inc. 6602 Windmill Way • Wilmington, NC 28405 (910) 392-0223 (Lab) • (910) 392-4424 (Fax) SM 710 Bowsertown Road • Manteo, NC 27954 (252)473-5702 ANALYTICAL & CONSULTING CHEMISTS NCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE #37729 Duke Energy -Laboratory Date of Report: Apr 20, 2015 1339 Hagers Ferry Road/Bid 7405 MG03A2 Customer PO #: Huntersville NC 28078 Customer ID: 15030001 Attention: Peggy Kendall Report #: 2015-02736 Project ID: Ash Pond Investigation Vanadium EPA 200.8 0.000271 J mg/L 03/11/2015 J: Estimated. Between Method Detection Limit and Reporting Limit. Hexavalent Chromium EPA 218.7 <0.02 pg/L 03/09/2015 Mercury EPA 245.1 <0.0004mg/L 03/09/2015 Sulfate EPA 300.0 <15 mg/L 03/11/2015 Turbidity SM 2130 B 0.6 NTU 03/06/2015 Field Turbidity 0.3 NTU. Alkalinity SM 2320B 7 mg/L 03/13/2015 Conductivity SM2510B 54umho/cm 03/12/2015 Total Dissolved Solids (TDS) SM 2540 C 30 mg/L 03/06/2015 Residue Suspended (TSS) SM 2540 D <2.5 mg/L 03/09/2015 Temperature SM 2550 B 21.8 C 03/05/2015 Chloride SM 4500 CI B <5 mg/L 03/12/2015 pH SM 4500 H B 5.90 units 03/05/2015 Dissolved Oxygen SM45000G 5.80 mg/L 03/05/2015 Comment: Turbidity, temperature, pH and dissolved oxygen measured in field at sample collection. All non - detects for metals reported to MDL. Reviewed by: Report #:: 2015-02736 Page 2 of 2 Environmental Chemists, Inc. renviroChem 6602 Windmill Way • Wilmington, NC 28405 (910) 392-0223 (Lab) • (910) 392-4424 (Fax) sm 710 Bowsertown Road • Manteo, NC 27954 (252)473-5702 ANALYTICAL & CONSULTING CHEMISTS NCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE #37729 QC for Duke Energy - 2015-02736 LCS Parameter True Value m 1E Result m %True Value Limits Alkalinity 12.5 13.0 104 90-110 Aluminum 0.05 0.05 100 90-110 Antimony 0.01 0.01 100 90-110 Arsenic 0.01 0.01 100 90-110 Barium 0.01 0.01 100 90-110 Beryllium 0.01 0.01 100 90-110 Boron 0.05 0.05 100 90-110 Cadmium 0.01 0.01 100 90-110 Calcium 0.5 0.5 100 90-110 Chloride 50 48 96 90-110 Chromium 0.01 0.01 100 90-110 Cobalt 0.01 0.01 100 90-110 Conductivity 10000 99900 99.9 90/110 Copper 0.01 0.01 100 90-110 Iron 0.05 0.05 100 90-110 Lead 0.01 0.01 100 90-110 Magnesium 0.5 0.5 100 90-110 Manganese 0.01 0.01 100 90-110 Mercury 0.0040 0.0037 92 90-110 Molybdenum 0.01 0.01 100 90-110 Nickel 0.0050 0.0048 96 90-110 Potassium 0.5 0.5 100 90-110 TSS 248.8 274.4 110 90-110 Selenium 0.01 0.01 100 90-110 Sodium 0.5 0.5 100 90-110 Strontium 0.05 0.05 100 90-110 Sulfate 50 50 100 90-110 Thallium 0.0050 0.0048 96 90-110 TDs 600 601 100 f 10 Turbidity N/A N/A N/A N/A Vanadium 0.01 0.01 100 90-110 Zinc 0.05 0.05 100 90-110 MS/MSD Parameter True Value M91L Result M91L % Recovery % Difference Limits % Recovery Limits % Difference Alkalinity N/A N/A N/A N/A N/A N/A Aluminum 0.100 0.099/0.100 99/100 1 80-120 <_ 20 Antimony 0.025 0.028/0.028 112/112 0 80-120 <20 Arsenic 0.025 0.030/0.030 120/120 0 80-120 <20 Barium 0.025 0.025/0.025 100/100 0 80-120 <20 Beryllium 0.025 0.029/0.029 116/116 0 80-120 <20 Boron 0.100 0.097/0.095 97/95 2 80-120 <20 Cadmium 0.025 0.028/0.028 112/112 0 80-120 <20 Calcium 1.0 0.98/0.99 98/99 1 80-120 <_ 20 Chloride N/A N/A N/A N/A N/A N/A Chromium 0.025 0.024/0.025 96/100 4 80-120 :520 Cobalt 0.025 0.024/0.025 96/100 4 80-120 :5 20 Conductivity N/A N/A N/A N/A N/A N/A Copper 0.025 0.027/0.028 108/112 4 80-120 <20 Iron 0.100 0.085/0.93 85/93 9 80-120 <20 Lead 0.025 0.023/0.023 92/92 0 80-120 <_ 20 Magnesium 1.0 1.03/1.04 103/104 1 80-120 < 20 Manganese 0.025 0.024/0.025 96/100 4 80-120 <20 Mercury 0.0020 0.0022/0.0019 110/95 15 80-120 :5 20 Molybdenum 0.025 0.028/0.028 112/112 0 80-120<_ 20 Nickel 0.0100 0.0099/0.0103 99/103 4 80-120 <20 Potassium 1.0 1.03/1.02 103/102 1 80-120 <20 TSS N/A N/A N/A N/A N/A N/A Selenium 0.025 0.030/0.030 120/120 0 80-120 <20 Sodium 1.0 1.0/1.0 100/100 0 80-120 <20 Strontium 0.100 0.098/0.105 98/105 7 80-120 <20 Sulfate 10.0 10.6/10.6 106/106 0 80-120 <20 Thallium 0.0100 0.0102/0.0105 102/105 3 80-120 <_20 TDS N/A N/A N/A N/A N/A N/A Turbidity N/A N/A N/A N/A N/A N/A Vanadium 0.025 0.024/0.025 96/100 4 80-120 :520 Zinc 0.100 0.099/0.102 99/102 3 80-120 <20 DUPLICATE SAMPLES Parameter Results mg/L % Difference Limits Alkalinity 4 4 0 <10 Aluminum N/A N/A N/A N/A Antimony N/A N/A N/A N/A Arsenic N/A N/A N/A N/A Barium N/A N/A N/A N/A Beryllium N/A N/A N/A N/A Boron N/A N/A N/A N/A Cadmium N/A N/A N/A N/A Calcium N/A N/A N/A N/A Chloride 467 462 1 <10 Chromium N/A N/A N/A N/A Cobalt N/A N/A N/A N/A Conductivity 156 156 0 <10 Copper N/A N/A N/A N/A Iron N/A N/A N/A N/A Lead N/A N/A N/A N/A Magnesium N/A N/A N/A N/A Manganese N/A N/A N/A N/A Mercury N/A N/A N/A N/A Molybdenum N/A N/A N/A N/A Nickel N/A N/A N/A N/A Potassium N/A N/A N/A N/A TSS 313.3 303.3 3 <_ 10 Selenium N/A N/A N/A N/A Sodium N/A N/A N/A N/A Strontium N/A N/A N/A N/A Sulfate <15 <15 0 <10 Thallium N/A N/A N/A N/A TDS 403 404 0 < 10 Turbidity 0.37 0.37 0 <10 Vanadium N/A N/A N/A N/A Zinc N/A N/A N/A N/A BLANKS Parameter Rmg�' Limit, mg/L Alkalinity 2 1 Aluminum <0.005 0.005 Antimony <0.0005 0.0005 Arsenic <0.0005 0.0005 Barium <0.0005 0.0005 Beryllium <0.0005 0.0005 Boron <0.005 0.005 Cadmium <0.0005 0.0005 Calcium <0.5 0.5 Chloride <2.5 2.5 Chromium <0.0005 0.0005 Cobalt <0.0005 0.0005 Conductivity <5 5 Copper <0.0005 0.0005 Iron <0.005 0.005 Lead <0.0005 0.0005 Magnesium <0.5 0.5 Manganese <0.0005 0.0005 Mercury <0.0002 0.0002 Molybdenum <0.0005 0.0005 Nickel <0.00005 0,00005 Potassium <0.5 0.5 TSS <2.5 2.5 Selenium <0.005 0.005 Sodium <0.5 0.5 Strontium <0.005 0.005 Sulfate <2.5 2.5 Thallium <0.00005 0.00005 TDS <2.5 2.5 Turbidity NSA NSA Vanadium <0.0005 0.0005 Zinc <0.005 0.005 A L a lD Ln 00 N LO -;t n N l0 W O NM n m M d' W N M n O N O N M W M Y O1 O �„� M" N N M O D7 N 0 n Q7 00 MQl M O m N d' N l0 W LID00 m N m I� W O N W 00 N m00 N w N I, N n d' O M M O `~ V O M M M V d' V V M M M M O o"OoC V N M Ln Moo 2 N N N� IT M M CT d' d' V V 'q' V d' V V V M M M 'c1 00 a V� M 00 M M r, N Vf 00 W 00 r, n n M n n n N N n n n n n n n N n n N n N r N N n n 00 n W a ^ W M n uti N N ti M O M V O U U G U = @ m m U � �.,,��n�nnn000000 00 00 00 00 00 000000a0000000�.-+ommmuo mu=O a 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 o ao vi 0 0 0 0 0 0 0 0 0 0 Or -0000 000 0 0 O M N N l!1 0 0 0 O N N N N N N N N N N N N N N N N N N N N N N N N N N m N N N N N N V V Cts' ;saaaQaQaQaaaaaaaaaaaaaaaaaaa m V W W W W W W W W W W W W W W W W W W W W W W W W W W W (/� V) o o VI IA o H o y o o N o N IA o N Ln LnM O �_ v m M O U E O CU c v� U 'Oc W c N N E U T> N- d X °.3 E E E d n m 3 E CO E E a°c E >>> v ° C c E v E 'y. 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I Facility Name: Meter Id: 11277 Meter Id: 11280 Meter Id: 09996 - Meter Id: NY1-11373-- Analyst: pHAoslysis .... ._..^ cnn a m cxA xnu Cal. Time Calbraation Buffer 4.0 1 Calibration Buffer 10.0 *Check Buffer 7.0 Comments - %� Comment qK 0 Slope: gb / *pH buffer checks are to be within+ 0.1 pH units of the standards true value Facility/Sample location I Time Sampled• I Time Analyzed♦ I Temp(°C)■ I pHResult 1 0-1 Buffer Check value Comment qK 16,-30 1630 ♦If sample is measured in directly in the stream only time analyzed would be recomea. )-Indicates a recommended drift check (Use Buffer 7.0) Should be within* 0.1 units of the buffer's true value) is Document the temperature of the sample at the time of analysis. Nott This temperature is not to be used for reporting on the monthly monitoring report Calibmtkm drift check is recommended when performing analysis at multiple sampling lo=tions, *All pH results in pH units (i.e., s.u.). - - - - . _Total Residual Chlorine (TR exxn Facility/Sample Location Time Sampled Time Analyzed TRC Result ug/L Daily check standard Comment obtained value uelL. 9. &) -A, Z916-6- 1 V30 TRC check standard obtained true value 210 (acceptance range 190-220 ug/L) (Should recover withm i1(1% 01 the check standard's obtained true value) Dissolved Oxygen (DO) Reference Method: SM 4500 O G, 206 Edition, —YSI DO 550 A Model—YSI PRO 20 Temperance °C Adjtuted Au Calibmtionk (mglL) Saturatio¢ % Calibration Facility/Sample Location Time DO reading *Time Sample Temperature mg(L Analyzed/Time Sampled 9. &) -A, Z916-6- 1 V30 LBased on appropriate altitude adjustment -- - When perfdrmmg analysis at multiple sampling locations, re-calibration(s) should be performed every four bohis: *Analysis time add sampling time the same. (Ideally the sample should be analyzed bi:situ)......... - " Temperature Sensor Annual CbeckDate (550 A): IN PROCESS Temperature Sensor Annual Check Date (PRO 20):IN PROCESS Temnemnam - . . . . ` ._..— ..__..__. _- Element One Inc. 6319-D Carolina Beach Rd, el 1 Wilmington, NC 28412 Phone: 910 793-0128 Fax: 910 792-6853 allab@eilab.com FINAL REPORT OF ANALYSES Ray Porter March 09, 2015 Environmental Chemists, Inc. Client Project Name: 66002 Windmill Way Client Project Number: Wilmington, NC 28405 E1 Project Number e24189 Sample # Sample ID 15-06243 Sample Matrix DW Sample Type Date Received 03/06/2015 Date Sampled 03/05/2015 Time Sampled 1030 Time Received 0810 Delivered by Client Sampler Received by KMS E1 Sample # 24189-4 Parameter Result Unit Dilution DL Method Date Chromium VI < 0.02 Ng/L 1 0.02 EPA 218.7 03/09/2015 i Ken Sm th, Laboratory Director 24189 Envirochem Cr6+Report Compiled by�� NC Certifications: DW 37788 and DWQ DENR 604 s fD 3 n "O 3 -Op m o n O " n •J O O Z n N Q x C V d n J £- xw". FF— g � m 3 � N 557 O w S 0 8 3 — d 7 � N G n G d. m. �•m m 's3 m 3 v� V .e N d fD d (p d •* n 01, pnn y� Lr\ N o O O (D N (D N � CA v C A Q Z w m 0 l7 y i N co 4 to N N r r crC (A 1 m C W CL A 0 N 3 0 CA 1 o 0 -1 n mm o D D 3 M 3 !i1 J 0 O CL � 7 .Ni .di.. 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