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HomeMy WebLinkAboutNC0001422_Well Water Lab Results_20150805Environmental Chemists, Inc. envirochem 6602 Windmill Way • Wilmington, NC 28405 (910) 392-0223 (Lab) • (910) 392-4424 (Fax) SM 710 Bowsertown Road • Manteo, NC 27954 (252) 473-5702 ANALYTICAL & CONSULTING CHEMISTS NCDENR: DWQ CERTIFICATE 094. DLS CERTIFICATE #37729 Duke Energy -Laboratory Date of Report: Apr 20, 2015 1339 Hagers Ferry Road/Bld 7405 MG03A2 Customer PO #: Huntersville NC 28078 Customer ID: 15030001 Attention: Peggy Kendall Report #: 2015-02734 Project ID: Ash Pond Investigation Lab ID Sample ID: St. Wooten - Combo Collect Date/Time Matrix Sampled by 15-06241 Site: Well 1 & 2 Combined 3/5/2015 11:45 AM DW Ray Porter/Cindy McDonald Test Method Results Date Analyzed J: Estimated. Between Method Detection Limit and Reporting Limit. Bicarbonate as CaCO3 Bicarbonate as CaCC3 36.0 mg/L 03/19/2015 Carbonate asCaCO3 Carbonate asCaCO3 <1mg/L 03/19/2015 Aluminum EPA 200.7 0.045 mg/L 03/11/2015 Boron EPA 200.7 0.16 mg/L 03/11/2015 Calcium EPA 200.7 60.7 mg/L 03/12/2015 Iron EPA 200.7 0.635 mg/L 03/11/2015 Magnesium EPA 200.7 5.46 mg/L 03/12/2015 Potassium EPA 200.7 9.98 mg/L 03/12/2015 Sodium EPA 200.7 24.1 mg/L 03/12/2015 Strontium EPA 200.7 0.287 mg/L 03/11/2015 Zinc EPA 200.7 0.015 mg/L 03/11/2015 Antimony EPA 2006. <0.000099mg/L 03/10/2015 Arsenic EPA 200.8 0.000575Jmg/L 03/10/2015 J: Estimated. Between Method Detection Limit and Reporting Limit. Barium EPA 200.8 Beryllium EPA 200.8 Cadmium EPA 200.8 Chromium EPA 200.8 J: Estimated. Between Method Detection Limit and Reporting Limit. Cobalt EPA 200.8 Copper EPA 200.8 Lead EPA 200.8 Manganese EPA 200.8 Molybdenum EPA 200.8 J: Estimated. Between Method Detection Limit and Reporting Limit. Nickel EPA 200.8 Selenium EPA 200.8 0.047 mg/L 03/10/2015 <0.000146 mg/L 03/10/2015 <0.0000827 mg/L 03/10/2015 0.000176 J mg/L 03/10/2015 0.002 mg/L 03/11/2015 0.004 mg/L 03/10/2015 <0.000126 mg/L 03/10/2015 0.278 mg/L 03/11/2015 0.000758 J mg/L 03/10/2015 < 0.100 mg/L 03/10/2015 0.001 mg/L 03/27/2015 Report #:: 2015-02734 Pagel of 2 Environmental Chemists, Inc. envirochem 6602 Windmill Way • Wilmington, NC 28405 (910) 392-0223 (Lab) • (910) 392-4424 (Fax) $M 710 Bowsertown Road • Manteo, NC 27954 (252) 473-5702 ANALYTICAL & CONSULTING CHEMISTS NCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE #37729 Duke Energy -Laboratory 1339 Hagers Ferry Road/Bld 7405 MG03A2 Huntersville NC 28078 Attention: Peggy Kendall Date of Report: Apr 20, 2015 Customer PO #: Customer ID: 15030001 Report M 2015-02734 Project ID: Ash Pond Investigation Thallium EPA 200.8 <0.0001 mg/L 03/10/2015 Vanadium EPA 200.8 0.000386 J mg/L 03/11/2015 J: Estimated. Between Method Detection Limit and Reporting Limit. Hexavalent Chromium EPA 218.7 <0.02 pg/L 03/09/2015 Mercury EPA 245.1 <0.0004 mg/L 03/09/2015 Sulfate EPA 300.0 160 mg/L 03/11/2015 Turbidity SM 2130 B 5.3 NTU 03/06/2015 Field Turbidity 4.1 NTU. Alkalinity SM 2320B 36mg/L 03/13/2015 Conductivity SM 2510 B 506 umho/cm 03/12/2015 Total Dissolved Solids (TDS) SM 2,540 C 326 mg/L 03/06/2015 Residue Suspended (TSS) SM 2540 D <2.5 mg/L 03/09/2015 Temperature SM 2550 B 18.7 C 03/05/2015 Chloride SM 4500 CI B 25 mg/L 03/12/2015 pH SM 4500 H B 6.02 units 03/05/2015 Dissolved Oxygen SM 4500 o c 6.60 mg/L 03/05/2015 Comment: Turbidity, temperature, pH and dissolved oxygen measured in field at sample collection. All non - detects for metals reported to MDL. Reviewed by: Report #:: 2015-02734 Page 2 of 2 Environmental Chemists, Inc. 6602 Windmill Way • Wilmington, NC 28405 (910)392-0223 (Lab) • (910)392-4424 (Fax) sm 710 Bowsertown Road • Manteo, NC 27954 (252)473-5702 ANALYTICAL & CONSULTING CHEMISTS NCDENR: DWQ CERTIFICATE #94. DLS CERTIFICATE #37729 QC for Duke Energy - 2015-02734 LCS Parameter True Value Rest % True Value Limits Alkalinity 50 52 104 90-110 Aluminum 0.05 0.05 100 90-110 Antimony 0.01 0.01 100 90-110 Arsenic 0.01 0.01 100 90-110 Barium 0.01 0.01 100 90-110 Beryllium 0.01 0.01 100 90-110 Boron 0.05 0.05 100 90-110 Cadmium 0.01 0.01 100 90-110 Calcium 0.5 0.5 100 90-110 Chloride 50 48 96 90-110 Chromium 0.01 0.01 100 90-110 Cobalt 0.01 0.01 100 90-110 Conductivity 10000 99900 99.9 90/110 Copper 0.01 0.01 100 90-110 Iron 0.05 0.05 100 90-110 Lead 0.01 0.01 100 90-110 Magnesium 0.5 0.5 100 90-110 Manganese 0.01 0.01 100 90-110 Mercury 0.0040 0.0037 92 90-110 Molybdenum 0.01 0.01 100 90-110 Nickel 0.0050 0.0048 96 90-110 Potassium 0.5 0.5 100 90-110 TSS 248.8 274.4 110 90-110 Selenium 0.01 0.01 100 90-110 Sodium 0.5 0.5 100 90-110 Strontium 0.05 0.05 100 90-110 Sulfate 50 50 100 90-110 Thallium 0.0050 0.0048 96 90-110 TDS 600 601 100 :1: 10 Turbidity N/A N/A N/A N/A Vanadium 0.01 0.01 100 90-110 Zinc 0.05 0.05 100 1 90-110 MS/MSD Parameter True Value mg/L Result mg/L % Recovery % Difference Limits % Recovery Limits % Difference Alkalinity N/A N/A N/A N/A N/A N/A Aluminum 0.100 0.099/0.100 99/100 1 80-120 <20 Antimony 0.025 0.028/0.028 112/112 0 80-120 :520 Arsenic 0.025 0.030/0.030 120/120 0 80-120 <20 Barium 0.025 0.025/0.025 100/100 0 80-120 <20 Beryllium 0.025 0.029/0.029 116/116 0 80-120 <_ 20 Boron 0.100 0.097/0.095 97/95 2 80-120 <20 Cadmium 0.025 0.028/0.028 112/112 0 80-120 <_ 20 Calcium 1.0 0.98/0.99 98/99 1 80-120 <20 Chloride N/A N/A N/A N/A N/A N/A Chromium 0.025 0.024/0.025 96/100 4 80-120 <20 Cobalt 0.025 0.024/0.025 96/100 4 80-120 <_ 20 Conductivity N/A N/A N/A N/A N/A N/A Copper 0.025 0.027/0.028 108/112 4 80-120 <_ 20 Iron 0.100 0.098/0.100 98/100 2 80-120 <20 Lead 0.025 0.023/0.023 92/92 0 80-120 <_ 20 Magnesium 1.0 0.98/1.0 98/100 2 80-120 <20 Manganese 0.025 0.024/0.025 96/100 4 80-120 <20 Mercury 0.0020 0.0022/0.0019 110/95 15 80-120 <20 Molybdenum 0.025 0.028/0.028 112/112 0 80-120 5 20 Nickel 0.0100 0.0099/0.0103 99/103 4 80-120 <20 Potassium 1.0 1.0/1.0 100/100 0 80-120 <20 TSS N/A N/A N/A N/A N/A N/A Selenium 0.025 0.030/0.030 120/120 0 80-120 <20 Sodium 1.0 1.0/1.0 100/100 0 80-120 <20 Strontium 0.100 0.098/0.105 98/105 7 80-120 <20 Sulfate 10.0 10.5/10.6 105/106 1 80-120 5 20 Thallium 0.0100 0.0102/0.0105 102/105 3 80-120 <_ 20 TDs N/A N/A N/A N/A N/A N/A Turbidity N/A N/A N/A N/A N/A N/A Vanadium 0.025 0.024/0.025 96/100 4 80-120 <_ 20 Zinc 0.100 0.099/0.102 99/102 3 80-120 <_ 20 DUPLICATE SAMPLES Parameter Results mg/L % Difference Limits Alkalinity 36 36 0 < 10 Aluminum N/A N/A N/A N/A Antimony N/A N/A N/A NIA Arsenic N/A N/A N/A N/A Barium N/A N/A N/A N/A Beryllium N/A N/A N/A N/A Boron N/A N/A N/A N/A Cadmium N/A N/A N/A N/A Calcium N/A N/A N/A N/A Chloride 467 462 1 <10 Chromium N/A N/A N/A N/A Cobalt N/A N/A N/A N/A Conductivity 156 156 0 <10 Copper N/A N/A N/A N/A Iron N/A N/A N/A N/A Lead N/A N/A N/A N/A Magnesium N/A N/A N/A N/A Manganese N/A N/A N/A N/A Mercury N/A N/A N/A N/A Molybdenum N/A N/A N/A N/A Nickel N/A N/A N/A N/A Potassium N/A N/A N/A N/A TSS 313.3 303.3 3 :510 Selenium N/A N/A N/A N/A Sodium N/A N/A N/A N/A Strontium N/A N/A N/A N/A Sulfate 28 29 4 < 10 Thallium N/A N/A N/A N/A TDs 403 404 0 <10 Turbidity 0.37 0.37 0 <_ 10 Vanadium N/A N/A N/A N/A Zinc N/A N/A N/A N/A BLANKS Parameter Results, Limit, mg/L Alkalinity 1 1 Aluminum <0.005 0.005 Antimony <0.0005 0.0005 Arsenic <0.0005 0.0005 Barium <0.0005 0.0005 Beryllium <0.0005 0.0005 Boron <0.005 0.005 Cadmium <0.0005 0.0005 Calcium <0.5 0.5 Chloride 2,5 2.5 Chromium <0.0005 0.0005 Cobalt <0.0005 0.0005 Conductivity <5 5 Copper <0.0005 0.0005 Iron <0.005 0.005 Lead <0.0005 0.0005 Magnesium <0.5 0.5 Manganese <0.0005 0.0005 Mercury <0.0002 0.0002 Molybdenum <0.0005 0.0005 Nickel <0.00005 0.00005 Potassium <0.5 0.5 TSS <2.5 2.5 Selenium <0.0005 0.0005 Sodium <0.5 0.5 Strontium <0.005 0.005 Sulfate <2.5 2.5 Thallium <0.00005 0.00005 TDS <2.5 2.5 Turbidity N/A N/A Vanadium <0.0005 0.0005 Zinc <0.005 0.005 Element One Inc. 6319-D Carolina Beach Rd. eI 1 Wilmington, NC 28412 Phone: 910 793-0128 Fax: 910 792-6853 ellab@ellab.com e�ementOne FINAL REPORT OF ANALYSES Ray Porter March 09, 2015 Environmental Chemists, Inc. Client Project Name: 66002 Windmill Way Client Project Number: Wilmington, NC 28405 E1 Project Number e24189 Sample # Sample ID 15-06241 Sample Matrix DW Sample Type Date Received 03/06/2015 Date Sampled 03/05/2015 Time Sampled 1145 Time Received 0810 Delivered by Client Sampler Received by KMS E1 Sample # 24189-3 Parameter Result Unit Dilution DL Method Date Chromium VI < 0.02 pg/L 1 0.02 EPA 218.7 03/09/2015 Ken Smith, Laboratory Director 24189 Envirochem Cr6+Report Compiled by—Lk - NC Certifications: DW 37788 and DWO DENR 604 ". Chent ID. - sT c� Facility Name: lErrvhronmental Chemists,Inc Permit4 94' Meter Id: 11277 Meter Id: 11280. . Meter Id: 09996 Meter Id: NY1-11373-- Analyst: Facility/Sample location 7 Time Sampled♦ I Time Analyzed Temp (°C) ■ pH Result heckvalue Comment X041 b0 132 q;OD IMOX I;z I 1..tdIl.bv fl:s� b'.3'1. 1, 5 �f5 .02 - +If sample is measured in directly in the stream only time analyzed woula ne recornea. ►Iudicates a. recommended dr'if't check. (Use Buffer 7.0) Should be withiu 0.1 units of the buffer's true value) • Document the temperature of the sample at the time of analysis. Note This temperature is not to be used for reporting on the monthly monitoring report. Calibration drift check is recommended when performing analysis at multiple samplrog locations, *All pH results in pH units (r.e., s.u.). -- - - - ..Total Residual Chlorine (TRC) Facility/Sampie Location Time Sampled Time Analyzed I TRC Result Daily check standard uOL obtained value ug/L Comment Ob% q;OD IMOX I;z I 1..tdIl.bv fl:s� b'.3'1. 'LRC check standard obtained true value 210 (acceptance range 19U -22U ug/L) (Jlaould recover wtmm Gaze i at me check standard's obtained true value) Dissolved Oxygen (DO) Refereace Method: SM 4500 O G, 201h Edition, —YSI DO 550 A Model—YSIPRO 20 Temperature °C Adjusted Air Calibration♦ (mg/L) Saturation % Cahbration Facility/Sample Location DO reading °Time Sample Temperature Time mg/L Analyzed/Ilme I Sampled Ob% q;OD IMOX I;z I 1..tdIl.bv fl:s� b'.3'1. ♦Based on appropriate attitude adjustment -- -- 4 Whea performing analysis at multiple sampling locations, re-calibration(s) should be performed every four hoots:" - .. *Analysis time and sampling time the same. (Ideally the sample should be analywrl fit:ktn):..........z. - " Temperature Sensor AnnualChecltDate(550 A): IN PROCESS Temre peratuSensor Annual Cheek Date (PRO 20):IN PROCESS -- .._._ — Referenm Method. 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