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HomeMy WebLinkAboutNC0001422_GW S18 24736_20150805 Duke Energy Laboratory Services 13339 Hagers Ferry Road Bld. MG03A Huntersville, NC 28078 Project ID: Ash Basin GW Assessment – S18 Metals, Mercury, Hexavalent Chromium, Chloride, Sulfate, Sodium, Alkalinity, Bicarbonate, Carbonate, Turbidity, Total Dissolved Solids, Total Suspended Solids, Dissolved Oxygen, pH, Temperature and Conductivity Analytical Report 24736 Element One, Inc. 6319-D Carolina Beach Rd., Wilmington, NC 28412 910-793-0128 FAX: 910-792-6853 e1lab@e1lab.com el1 The following data for Analytical Report 24736 has been reviewed for completeness, accuracy, adherence to method protocol, and compliance with quality assurance guidelines. Review by: i i Katie Strickland, B.S. Chemist June 3, 2015 Report Reviewed and Finalized By: l Ken Smith, Laboratory Director June 3, 2015 elementOne 24736 Duke Report Packet Page 2 of 49 elementOne 24736 Duke Report Packet Page 3 of 49 SUMMARY OF RESULTS elementOne 24736 Duke Report Packet Page 4 of 49 Summary of Analysis Summary of Method 200.8 Metals Analysis S18 136 Roymac Dr S18 136 Roymac Dr 24736-1 24736-1 dup Element mg/L mg/L ----------------- --------------- --------------- Aluminum 0.024 0.022 Antimony < 0.001 < 0.001 Arsenic < 0.005 < 0.005 Barium 0.020 0.020 Beryllium < 0.001 < 0.001 Boron 0.026 0.025 Cadmium < 0.002 < 0.002 Calcium 12.7 14.5 Chromium < 0.005 < 0.005 Cobalt < 0.001 < 0.001 Copper < 0.003 < 0.003 Iron 0.030 0.030 Lead < 0.003 < 0.003 Magnesium 0.724 0.727 Manganese 0.018 0.018 Molybdenum < 0.005 < 0.005 Nickel < 0.005 < 0.005 Potassium 1.22 1.230 Selenium < 0.005 < 0.005 Strontium 0.029 0.029 Thallium < 0.0002 < 0.0002 Vanadium 0.0012 0.0011 Zinc < 0.005 < 0.005 Summary of Method 245.1 Mercury Analysis S18 136 Roymac Dr S18 136 Roymac Dr 24736-1 24736-1 dup Element mg/L mg/L ----------------- ------ --------------- --------------- Mercury #1 < 0.0002 < 0.0002 #2 < 0.0002 < 0.0002 elementOne 24736 Duke Report Packet Page 5 of 49 Summary of Analysis Summary of Method 218.7 Hexavalent Chromium Analysis S18 136 Roymac Dr S18 136 Roymac Dr 24736-1 24736-1 dup Element µg/L µg/L ----------------- --------------- --------------- Chromium (VI) < 0.02 < 0.02 Summary of Method 300.0 Anions Analysis S18 136 Roymac Dr 24736-1 Element mg/L ----------------- --------------- Chloride 4.05 Sulfate 16.1 Summary of Method ASTM D6919-03 Sodium Analysis S18 136 Roymac Dr S18 136 Roymac Dr 24736-1 24736-1 dup Element mg/L mg/L ----------------- --------------- --------------- Sodium 3.03 3.05 elementOne 24736 Duke Report Packet Page 6 of 49 Summary of Analysis Summary of Standard Method 2320B Alkalinity Analysis S18 136 Roymac Dr S18 136 Roymac Dr 24736-1 24736-1 dup Assay mg/L mg/L ----------------- --------------- --------------- Alkalinity as CaCO3 15.9 15.9 Summary of Standard Method 4500 CO2 E Analysis S18 136 Roymac Dr S18 136 Roymac Dr 24736-1 24736-1 dup Assay mg/L mg/L ----------------- --------------- --------------- Bicarbonate (HCO32- as CaCO3) 15.9 15.9 Carbonate (CO32- as CaCO3) < 1 < 1 Summary of Standard Method 2130 B Turbidity Analysis S18 136 Roymac Dr S18 136 Roymac Dr 24736-1 24736-1 dup Assay NTU NTU ----------------- --------------- --------------- Turbidity < 1 < 1 Summary of Standard Method 2540 C TDS Analysis S18 136 Roymac Dr S18 136 Roymac Dr 24736-1 24736-1 dup Assay mg/L mg/L ----------------- --------------- --------------- Total Dissolved Solids 59.5 61.0 Summary of Standard Method 2540 D TSS Analysis S18 136 Roymac Dr 24736-1 Assay mg/L ----------------- --------------- Total Suspended Solids < 2.5 elementOne 24736 Duke Report Packet Page 7 of 49 Summary of Analysis Summary of Standard Method 4500O G DO Analysis S18 136 Roymac Dr 24736-1 Assay mg/L ----------------- --------------- Dissolved Oxygen 6.60 Summary of Standard Method 4500H+ pH Analysis S18 136 Roymac Dr 24736-1 Assay SU ----------------- --------------- pH 6.27 Summary of Standard Method 2500 B Temperature Analysis S18 136 Roymac Dr 24736-1 Assay °C ----------------- --------------- Temperature 24.0 Summary of Standard Method 2510 B Conductivity Analysis S18 136 Roymac Dr 24736-1 Assay µmhos/cm ----------------- --------------- Conductivity 99.9 elementOne 24736 Duke Report Packet Page 8 of 49 ANALYTICAL NARRATIVE elementOne 24736 Duke Report Packet Page 9 of 49 Element One Analytical Narrative Client: Duke Energy Element One #: 24736 Client ID: Ash Basin GW Assessment –S18 Analyst: DBW, DAM, KLS, LAW, PQT, DMR Method: See table below Dates Received: 05/19/2015 Analytes: See table below Dates Analyzed: 05/19-28/15 Summary of Analysis The samples were collected by Element One, Inc. on 05/19/2015 and were analyzed for pH, temperature, conductivity and dissolved oxygen in the field immediately following sampling. Samples were returned to Element One, Inc., prepared and analyzed for the other parameters following method protocol. The samples were analyzed for metals according to EPA Method 200.8 protocol on a PerkinElmer ELAN 6100 ICP-MS. The samples were analyzed for mercury according to EPA method 245.1 on a PerkinElmer FIMS-100 CVAA mercury analyzer. Samples were prepared and analyzed for chromium (VI) according to SW-846 Method 218.7 protocol on a Shimadzu 2010 HPLC unit and a Timberline RDR-1 Reaction Module. Samples were analyzed for chloride, sulfate by EPA 300.0 and sodium by ATSM D6919-03 on Metrohm 861/788 and 761/788 ion chromatograph system. Detection Limits The following is a list of parameters, methods used and the associated reporting limit for each: Parameter DL, mg/L Method Parameter DL, mg/L Method Beryllium 0.001 EPA 200.8 Antimony *0.001 EPA 200.8 Boron 0.005 EPA 200.8 Barium 0.005 EPA 200.8 Magnesium 0.02 EPA 200.8 Thallium *0.0002 EPA 200.8 Aluminum 0.005 EPA 200.8 Lead 0.003 EPA 200.8 Potassium 0.02 EPA 200.8 Mercury 0.0002 EPA 245.1 Calcium 0.05 EPA 200.8 Hexavalent Chromium 0.02 µg/L EPA 218.7 Vanadium *0.0003 EPA 200.8 Chloride 0.1 EPA 300.0 Chromium 0.005 EPA 200.8 Sulfate 0.1 EPA 300.0 Manganese 0.005 EPA 200.8 Sodium 0.05 ASTM D6919-03 Iron 0.02 EPA 200.8 Alkalinity 1 SM 2320 B Cobalt *0.001 EPA 200.8 Bicarbonate 1 SM 4500 CO2 D Nickel 0.005 EPA 200.8 Carbonate 1 SM 4500 CO2 D Copper 0.003 EPA 200.8 Turbidity 1.0 NTU SM 2130 B Zinc 0.005 EPA 200.8 TDS 10 SM 2540 C Arsenic 0.005 EPA 200.8 TSS 2.5 SM 2540 D Selenium 0.005 EPA 200.8 Dissolved Oxygen SM 4500O G Strontium 0.005 EPA 200.8 pH 1.0 SU SM 4500-H+ Molybdenum 0.005 EPA 200.8 Temperature SM 2500 B Cadmium 0.002 EPA 200.8 Conductivity 10µmhos/cm SM2510B *Detection Limit based on client request. elementOne 24736 Duke Report Packet Page 10 of 49 Element One Analytical Narrative Analysis QA/QC Duplicate analyses relative percent difference (RPD), sample spike recovery and second source calibration verification data are summarized in the Quality Control Section. All QA/QC data was within the criteria of the method. Additional Comments The reported results have not been corrected for any blank values or spike recovery values. The reported results relate only to the items tested or calibrated. elementOne 24736 Duke Report Packet Page 11 of 49 QUALITY CONTROL SUMMARY elementOne 24736 Duke Report Packet Page 12 of 49 Summary of Quality Control Data 200.8 Duplicate Analysis RPD (QC limits: < 20% for RPD.) S18 136 Roymac Dr Element RPD ----------------- --------------- Aluminum 6.4% Antimony NA Arsenic NA Barium 0.1% Beryllium NA Boron 3.6% Cadmium NA Calcium 12.8% Chromium NA Cobalt NA Copper NA Iron 1.4% Lead NA Magnesium 0.3% Manganese 0.8% Molybdenum NA Nickel NA Potassium 0.7% Selenium NA Strontium 0.8% Thallium NA Vanadium 6.5% Zinc NA *See Analytical Narrative page 10. elementOne 24736 Duke Report Packet Page 13 of 49 Summary of Quality Control Data Metals Second Source Calibration Check Recoveries (QC limits: ±10% for Second Source Continuing Check Standard*) Element 1 ppb 50 ppb 100 ppb* 250 ppb ----------------- ----------------- ----------------- ----------------- ----------------- Aluminum 125% 96% 92% 93% Antimony 92% 99% 99% 100% Arsenic 106% 101% 101% 102% Barium 104% 98% 99% 99% Beryllium 106% 105% 106% 104% Cadmium 105% 98% 98% 100% Chromium 100% 99% 97% 104% Cobalt 105% 100% 98% 103% Copper 110% 103% 100% 103% Lead 106% 99% 100% 99% Manganese 102% 98% 97% 101% Molybdenum 124% 96% 95% 95% Nickel 110% 103% 103% 103% Selenium 108% 100% 101% 101% Strontium 96% ---- 99% 100% Zinc 114% 104% 102% 102% Element 21 ppb 250 ppb 1100 ppb* 2500 ppb ----------------- ----------------- ----------------- ----------------- ----------------- Calcium 79% 99% 101% 100% Iron 109% 102% 101% 101% Magnesium 102% 100% 104% 102% Potassium 109% 106% 103% 101% Element 5 ppb 50 ppb 100 ppb* 250 ppb ----------------- ----------------- ----------------- ----------------- ----------------- Boron 127% 119% 99% 98% Element 0.3 ppb 1 ppb 10 ppb* 25 ppb ----------------- ----------------- ----------------- ----------------- ----------------- Thallium 101% 102% 101% 101% Vanadium 119% 102% 102% 114% elementOne 24736 Duke Report Packet Page 14 of 49 Summary of Quality Control Data Mercury 245.1 Duplicate Analysis RPD (QC limits: < 20% for RPD) S18 136 Roymac Dr Element RPD ----------------- --------------- Mercury NA Chromium (VI) 218.7 Duplicate Analysis RPD (QC limits: <1 10% for RPD) S18 136 Roymac Dr Element RPD ----------------- --------------- Chromium (VI) NA Chromium (VI) 218.7 Sample Spike Recovery (QC limits: 90-110% for Recovery) S18 136 Roymac Dr Element Recovery ----------------- --------------- Chromium (VI) 100% Sodium ASTM D6919-03 Duplicate Analysis RPD (QC limits: < 10% for RPD) S18 136 Roymac Dr Element RPD ----------------- --------------- Sodium 0.6% Sodium ASTM D6919-03 Sample Spike Recovery (QC limits: 90-110% for Recovery) S18 136 Roymac Dr Element Recovery ----------------- --------------- Sodium 103% elementOne 24736 Duke Report Packet Page 15 of 49 Summary of Quality Control Data Alkalinity SM 2320B Duplicate Analysis RPD (QC limits: < 10% for RPD) S18 136 Roymac Dr Element RPD ----------------- --------------- Alkalinity 0.0% SM 4500 CO2 E Duplicate Analysis RPD (QC limits: < 10% for RPD) S18 136 Roymac Dr Element RPD ----------------- --------------- Bicarbonate 0.6% Carbonate NA Turbidity SM 2130 B Duplicate Analysis RPD (QC limits: < 10% for RPD) S18 136 Roymac Dr Element RPD ----------------- --------------- Turbidity NA TTD SM 2540 C Duplicate Analysis RPD (QC limits: < 10% for RPD) S18 136 Roymac Dr Element RPD ----------------- --------------- TDS 2.5% elementOne 24736 Duke Report Packet Page 16 of 49 SAMPLE CUSTODY elementOne 24736 Duke Report Packet Page 17 of 49 elementOne 24736 Duke Report Packet Page 18 of 49 ANALYTICAL DATA elementOne 24736 Duke Report Packet Page 19 of 49 Analytical Calculations Metals, Mercury- Metals (mg/L) = ICP Results (µg/L)*Dilution 1000 Where- ICP-Hg Results = Raw sample concentration (ppb)—ICP-Hg -Data Sheet Dilution= Diluted Volume--ICP-MS Run Sheet/ Hg Run Sheet Aliquot Chromium (VI)- Chromium (VI) (µg/L) = HPLC Results (µg/L)*Dilution Where- HPLC Results = Raw sample concentration (ppb)—HPLC -Data Sheet Dilution= Diluted Volume--HPLC Run Sheet Aliquot Anions- Anions (mg/L) = IC Results (mg/L)*Dilution Where- IC Results = Raw sample concentration (ppm)—IC-Data Sheet Dilution= Diluted Volume-- IC-Data Sheet Aliquot elementOne 24736 Duke Report Packet Page 20 of 49 Analytical Calculations Spike Recovery- Spike (%) = (Spiked Result (µg/L) – Sample Result (µg/L)) X100 Spike Amount (µg/L) Where- Spike Result = Raw sample concentration (ppb)--ICP-Data Sheet Sample Result = Raw sample concentration (ppb)--ICP-Data Sheet Spike Amount--ICP-MS Spike Table Duplicate Analysis RPD- RPD (%) = (Duplicate Result (µg/L) - Sample Result (µg/L)) X100 Average (µg/L) Where- Sample Result and Duplicate Results=Raw sample concentration (ppb)--ICP-Data Sheet Average= (Duplicate + Sample Results) 2 elementOne 24736 Duke Report Packet Page 21 of 49 elementOne 24736 Duke Report Packet Page 22 of 49 elementOne 24736 Duke Report Packet Page 23 of 49 elementOne 24736 Duke Report Packet Page 24 of 49 elementOne 24736 Duke Report Packet Page 25 of 49 elementOne 24736 Duke Report Packet Page 26 of 49 elementOne 24736 Duke Report Packet Page 27 of 49 elementOne 24736 Duke Report Packet Page 28 of 49 elementOne 24736 Duke Report Packet Page 29 of 49 elementOne 24736 Duke Report Packet Page 30 of 49 elementOne 24736 Duke Report Packet Page 31 of 49 elementOne 24736 Duke Report Packet Page 32 of 49 elementOne 24736 Duke Report Packet Page 33 of 49 elementOne 24736 Duke Report Packet Page 34 of 49 elementOne 24736 Duke Report Packet Page 35 of 49 elementOne 24736 Duke Report Packet Page 36 of 49 elementOne 24736 Duke Report Packet Page 37 of 49 elementOne 24736 Duke Report Packet Page 38 of 49 elementOne 24736 Duke Report Packet Page 39 of 49 elementOne 24736 Duke Report Packet Page 40 of 49 elementOne 24736 Duke Report Packet Page 41 of 49 elementOne 24736 Duke Report Packet Page 42 of 49 elementOne 24736 Duke Report Packet Page 43 of 49 elementOne 24736 Duke Report Packet Page 44 of 49 elementOne 24736 Duke Report Packet Page 45 of 49 elementOne 24736 Duke Report Packet Page 46 of 49 elementOne 24736 Duke Report Packet Page 47 of 49 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: Blank Sample DatThursday, May 21, 2015 12:37:46 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 80548.7 ppb |- Be 9 2.3 ppb |- B 10 713.7 ppb | B 11 3100.9 ppb | Mg 24 479.7 ppb | Mg 25 63.3 ppb | K 39 253638.6 ppb | Ca 44 9898.7 ppb | Sc 45 230066.4 ppb | Cr 52 6907 ppb | Cr 53 7536.6 ppb | Fe 54 27914.5 ppb | Mn 55 414.7 ppb | Fe 57 4496.8 ppb | Co 59 40.7 ppb | Ni 60 81 ppb | Cu 63 1365.8 ppb | Cu 65 695.4 ppb | Zn 66 599.4 ppb | Zn 67 1582.1 ppb | Zn 68 899.7 ppb | As 75 -172.6 ppb | Se 77 313.7 ppb | Se 82 6.7 ppb | Sr 88 130.3 ppb | Mo 95 274.3 ppb | Mo 97 179.7 ppb | Mo 98 442.8 ppb |> Rh 103 458868.2 ppb | Cd 111 1.3 ppb |- Cd 114 7.3 ppb |- Sb 121 1480.8 ppb | Sb 123 1135.2 ppb | Ba 135 138 ppb | Ba 137 239.7 ppb |> Ho 165 993209.2 ppb | Pb 206 128 ppb | Pb 207 106 ppb |- Pb 208 479.7 ppb Kr 83 35.4 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 1 Sample DatThursday, May 21, 2015 12:41:04 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 79754.2 ppb |- Be 9 481 1 ppb |- B 10 1381.4 1 ppb | B 11 5988.3 1 ppb | Mg 24 87060.2 21 ppb | Mg 25 12248.9 21 ppb | K 39 447857.6 21 ppb | Ca 44 16446.5 21 ppb | Sc 45 232600.3 ppb | Cr 52 15037.8 1 ppb | Cr 53 5404.3 1 ppb | Fe 54 43928.9 21 ppb | Mn 55 13921 1 ppb | Fe 57 10879.8 21 ppb | Co 59 11662.8 1 ppb | Ni 60 2738.1 1 ppb | Cu 63 7178.2 1 ppb | Cu 65 3477.3 1 ppb | Zn 66 2733.7 1 ppb | Zn 67 1381.8 1 ppb | Zn 68 2373.3 1 ppb | As 75 1460.6 1 ppb | Se 77 368.3 1 ppb | Se 82 203.4 1 ppb | Sr 88 22115.9 1 ppb | Mo 95 3438.3 1 ppb | Mo 97 2143.3 1 ppb | Mo 98 5677 1 ppb |> Rh 103 454566.9 ppb | Cd 111 2526.6 1 ppb |- Cd 114 5817.7 1 ppb |- Sb 121 8643.8 1 ppb | Sb 123 6636.4 1 ppb | Ba 135 2497 1 ppb | Ba 137 4339.4 1 ppb |> Ho 165 985214.7 ppb | Pb 206 11297 1 ppb | Pb 207 9829.3 1 ppb |- Pb 208 45378.3 1 ppb Kr 83 -119 ppb ICP-Data 1 of 18 elementOne e 24736-Metals 48.1 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 2 Sample DatThursday, May 21, 2015 12:44:23 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 82473.4 ppb |- Be 9 50149 100.0001 ppb |- B 10 14983.7 99.96043 ppb | B 11 64840.2 99.96046 ppb | Mg 24 4591849.3 1099.986 ppb | Mg 25 629440.4 1099.975 ppb | K 39 9988102.8 1099.956 ppb | Ca 44 347447.9 1099.968 ppb | Sc 45 243119.9 ppb | Cr 52 862504.2 99.99997 ppb | Cr 53 105152 100.0322 ppb | Fe 54 831533.4 1099.955 ppb | Mn 55 1369073.9 99.99966 ppb | Fe 57 327042.3 1099.963 ppb | Co 59 1166035.9 99.99956 ppb | Ni 60 255848.9 99.99912 ppb | Cu 63 569798.9 99.99927 ppb | Cu 65 272919.8 99.99927 ppb | Zn 66 171799.9 99.99691 ppb | Zn 67 28592.9 100.0172 ppb | Zn 68 123178.7 99.99731 ppb | As 75 178478.5 100.0004 ppb | Se 77 15882.5 100.0061 ppb | Se 82 20903.1 100.0001 ppb | Sr 88 2312651.6 100 ppb | Mo 95 330993 99.99997 ppb | Mo 97 210156.4 100.0002 ppb | Mo 98 542834.8 99.99989 ppb |> Rh 103 475958.8 ppb | Cd 111 256738.3 99.9997 ppb |- Cd 114 599062.4 99.99984 ppb |- Sb 121 777060.8 100.0002 ppb | Sb 123 590826.9 100.0001 ppb | Ba 135 239521.5 99.99958 ppb | Ba 137 419699.3 99.99967 ppb |> Ho 165 1041000 ppb | Pb 206 1132058.6 99.99957 ppb | Pb 207 996688.2 99.99969 ppb |- Pb 208 4562953 99.9996 ppb Kr 83 -15640.1 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 3 Sample DatThursday, May 21, 2015 12:47:41 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 79792.3 ppb |- Be 9 239091.2 499.7203 ppb |- B 10 76097.9 500.6801 ppb | B 11 330423.6 500.7442 ppb | Mg 24 22925998 5495.386 ppb | Mg 25 3254552.1 5502.808 ppb | K 39 49546925 5498.54 ppb | Ca 44 1711173.6 5497.561 ppb | Sc 45 251831.6 ppb | Cr 52 4486819.1 500.4963 ppb | Cr 53 511285.2 500.2611 ppb | Fe 54 4223748.9 5504.996 ppb | Mn 55 7163546 500.4829 ppb | Fe 57 1621138.7 5496.277 ppb | Co 59 5983764.1 500.1104 ppb | Ni 60 1245756.1 499.0863 ppb | Cu 63 2890178.2 499.9234 ppb | Cu 65 1334968.5 499.2149 ppb | Zn 66 842288.7 499.2762 ppb | Zn 67 138171.9 499.8612 ppb | Zn 68 602826.2 499.3037 ppb | As 75 899495.2 499.7452 ppb | Se 77 79868.8 500.0392 ppb | Se 82 105804.2 499.8509 ppb | Sr 88 12338339 500.844 ppb | Mo 95 1733832.5 500.5142 ppb | Mo 97 1095067.4 500.4158 ppb | Mo 98 2981504.4 501.3836 ppb |> Rh 103 485641 ppb | Cd 111 1310654.5 500.0117 ppb |- Cd 114 3167335.2 500.6742 ppb |- Sb 121 4192520 500.6325 ppb | Sb 123 3188713.9 500.6383 ppb | Ba 135 1258804.6 500.1162 ppb | Ba 137 2281333.4 500.7508 ppb |> Ho 165 1088010.4 ppb | Pb 206 5843598 499.7638 ppb | Pb 207 5099068.1 499.5891 ppb |- Pb 208 23362279 499.6041 ppb Kr 83 -83603.6 ppb ICP-Data 2 of 18 elementOne e 24736-Metals 48.2 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatThursday, May 21, 2015 12:51:00 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 82841.7 ppb |- Be 9 23 0.0415 ppb |- B 10 1723.2 6.33224 ppb | B 11 7718.6 6.69057 ppb | Mg 24 2136.7 0.38554 ppb | Mg 25 285 0.36387 ppb | K 39 278190.4 0.85596 ppb | Ca 44 8719.2 -5.8939 ppb | Sc 45 246431.3 ppb | Cr 52 7336.3 -0.00386 ppb | Cr 53 3008.2 -4.96439 ppb | Fe 54 32834.4 3.94862 ppb | Mn 55 3844.5 0.23222 ppb | Fe 57 5802.6 3.3576 ppb | Co 59 2233.3 0.1788 ppb | Ni 60 521.4 0.1702 ppb | Cu 63 2463.1 0.17059 ppb | Cu 65 1183.1 0.16183 ppb | Zn 66 837 0.11491 ppb | Zn 67 763 -3.36106 ppb | Zn 68 1060.4 0.08187 ppb | As 75 -42.4 0.07628 ppb | Se 77 200.3 -0.83928 ppb | Se 82 48 0.19001 ppb | Sr 88 1212.8 0.04273 ppb | Mo 95 8179.1 2.24866 ppb | Mo 97 5159.3 2.242 ppb | Mo 98 13422.1 2.1515 ppb |> Rh 103 489334 ppb | Cd 111 85.4 0.03151 ppb |- Cd 114 219.4 0.03286 ppb |- Sb 121 986.7 -0.07113 ppb | Sb 123 734 -0.07535 ppb | Ba 135 262.7 0.04852 ppb | Ba 137 482 0.05243 ppb |> Ho 165 1043034.8 ppb | Pb 206 882.7 0.06641 ppb | Pb 207 781.7 0.06816 ppb |- Pb 208 3475.4 0.06595 ppb Kr 83 25.4 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 2 Sample DatThursday, May 21, 2015 12:54:19 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 80846 ppb |- Be 9 514.3 1.05619 ppb |- B 10 2109.6 9.46908 ppb | B 11 9317.8 9.71831 ppb | Mg 24 87207.6 21.49063 ppb | Mg 25 12330.7 21.44155 ppb | K 39 458882.8 22.97833 ppb | Ca 44 15095.9 16.58036 ppb | Sc 45 241213.9 ppb | Cr 52 15709.9 0.99785 ppb | Cr 53 3664.7 -4.16349 ppb | Fe 54 45278.2 22.6578 ppb | Mn 55 14509.6 1.01732 ppb | Fe 57 11130.5 22.93986 ppb | Co 59 12136.1 1.04495 ppb | Ni 60 2730.1 1.09651 ppb | Cu 63 7535.1 1.09792 ppb | Cu 65 3681.1 1.14859 ppb | Zn 66 2547.4 1.186 ppb | Zn 67 973.7 -2.44528 ppb | Zn 68 2280.6 1.16572 ppb | As 75 1668.3 1.0593 ppb | Se 77 329.7 0.05519 ppb | Se 82 228.7 1.08362 ppb | Sr 88 23014.1 0.96015 ppb | Mo 95 5613.4 1.59081 ppb | Mo 97 3587.4 1.60734 ppb | Mo 98 9149.8 1.51136 ppb |> Rh 103 469814.8 ppb | Cd 111 2666.1 1.05096 ppb |- Cd 114 6019.6 0.98233 ppb |- Sb 121 8494 0.90893 ppb | Sb 123 6522.1 0.91806 ppb | Ba 135 2603 1.06402 ppb | Ba 137 4599.2 1.03947 ppb |> Ho 165 1001142.8 ppb | Pb 206 11437.5 1.05103 ppb | Pb 207 10085.3 1.06243 ppb |- Pb 208 45900.8 1.05551 ppb Kr 83 -121.4 ppb ICP-Data 3 of 18 elementOne e 24736-Metals 48.3 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 3 Sample DatThursday, May 21, 2015 12:57:38 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 80001.7 ppb |- Be 9 124491.7 259.5081 ppb |- B 10 36944.9 243.2991 ppb | B 11 162171.6 246.0549 ppb | Mg 24 10487915 2542.416 ppb | Mg 25 1415691.1 2420.927 ppb | K 39 22572739 2517.527 ppb | Ca 44 775744.8 2502.569 ppb | Sc 45 251930.6 ppb | Cr 52 2305880.6 259.7399 ppb | Cr 53 263383.3 256.869 ppb | Fe 54 1843497.3 2408.613 ppb | Mn 55 3571458.7 252.3447 ppb | Fe 57 737183.4 2519.264 ppb | Co 59 3050266 257.839 ppb | Ni 60 633945.3 256.8763 ppb | Cu 63 1475561.3 258.0588 ppb | Cu 65 710792.5 268.7265 ppb | Zn 66 425515 254.923 ppb | Zn 67 70031.4 253.2542 ppb | Zn 68 307528.7 257.2378 ppb | As 75 451409.9 253.7233 ppb | Se 77 39722.9 250.5068 ppb | Se 82 52621.4 251.445 ppb | Sr 88 6070743.2 249.2264 ppb | Mo 95 851350.9 248.525 ppb | Mo 97 534271.8 246.876 ppb | Mo 98 1395839.1 237.3576 ppb |> Rh 103 480169.6 ppb | Cd 111 645298.2 248.9831 ppb |- Cd 114 1504045.8 240.47 ppb |- Sb 121 2023159.6 250.1974 ppb | Sb 123 1537425.7 250.0147 ppb | Ba 135 612261.8 251.9892 ppb | Ba 137 1082657.7 246.1971 ppb |> Ho 165 1050170.8 ppb | Pb 206 2792451.1 247.43 ppb | Pb 207 2445821.2 248.2801 ppb |- Pb 208 11199072 248.1421 ppb Kr 83 -41116.7 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatThursday, May 21, 2015 13:00:57 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 83613.9 ppb |- Be 9 53150.6 106.0065 ppb |- B 10 16685.3 99.29041 ppb | B 11 72147.5 98.86865 ppb | Mg 24 5082731.4 1146.088 ppb | Mg 25 685216.6 1089.87 ppb | K 39 11093726 1134.579 ppb | Ca 44 375057.9 1106.692 ppb | Sc 45 261517.7 ppb | Cr 52 934360 97.39238 ppb | Cr 53 112911.9 97.64934 ppb | Fe 54 894173.5 1065.305 ppb | Mn 55 1474523.3 96.89034 ppb | Fe 57 353204.9 1113.663 ppb | Co 59 1247881.7 98.11108 ppb | Ni 60 274149.1 103.296 ppb | Cu 63 615338 99.93348 ppb | Cu 65 294309.3 103.3194 ppb | Zn 66 183709.2 102.1413 ppb | Zn 67 30728.2 99.72742 ppb | Zn 68 133080.1 103.0689 ppb | As 75 193049.8 100.9794 ppb | Se 77 17339.5 100.4683 ppb | Se 82 22673.7 100.7448 ppb | Sr 88 2593519.9 99.03519 ppb | Mo 95 364055 98.80008 ppb | Mo 97 230303.4 98.93618 ppb | Mo 98 598161.5 94.5664 ppb |> Rh 103 516251.5 ppb | Cd 111 272907.5 97.94252 ppb |- Cd 114 639717.2 95.13255 ppb |- Sb 121 829423.9 98.18583 ppb | Sb 123 635116.2 98.85321 ppb | Ba 135 259200.6 102.1959 ppb | Ba 137 455264.9 99.17508 ppb |> Ho 165 1095881.1 ppb | Pb 206 1166213.6 99.01197 ppb | Pb 207 1013897.2 98.61678 ppb |- Pb 208 4726677.2 100.3455 ppb Kr 83 -17546.3 ppb ICP-Data 4 of 18 elementOne e 24736-Metals 48.4 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 5 Sample DatThursday, May 21, 2015 13:04:16 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 83037.1 ppb |- Be 9 26154.2 52.52305 ppb |- B 10 9798.9 58.04543 ppb | B 11 43543.7 59.53364 ppb | Mg 24 1081661.7 251.0279 ppb | Mg 25 152500.1 249.6367 ppb | K 39 2247508 212.9337 ppb | Ca 44 89655.3 246.8079 ppb | Sc 45 256610.9 ppb | Cr 52 465186.9 49.52731 ppb | Cr 53 57076.3 47.01733 ppb | Fe 54 232049 256.2067 ppb | Mn 55 724053.7 48.96599 ppb | Fe 57 82487.5 255.4844 ppb | Co 59 615769.9 49.84156 ppb | Ni 60 133026.2 51.58605 ppb | Cu 63 309767.9 51.67391 ppb | Cu 65 147594.5 53.21107 ppb | Zn 66 91378 52.12567 ppb | Zn 67 15428.7 48.58875 ppb | Zn 68 66557.1 52.68544 ppb | As 75 93898.7 50.61527 ppb | Se 77 8304.5 48.48357 ppb | Se 82 10966.7 50.14915 ppb | Sr 88 869 0.02857 ppb | Mo 95 179464.5 50.09879 ppb | Mo 97 113390.5 50.10567 ppb | Mo 98 293946.5 47.80365 ppb |> Rh 103 501469.5 ppb | Cd 111 132489.4 48.95246 ppb |- Cd 114 311533.8 47.69534 ppb |- Sb 121 406677.8 49.59244 ppb | Sb 123 309701.9 49.65511 ppb | Ba 135 123301.6 50.14507 ppb | Ba 137 218679.6 49.13822 ppb |> Ho 165 1061760.2 ppb | Pb 206 566972.6 49.67548 ppb | Pb 207 492343.4 49.41964 ppb |- Pb 208 2255189.6 49.40845 ppb Kr 83 32.4 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 9 Sample DatThursday, May 21, 2015 13:07:36 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 73495.5 ppb |- Be 9 5.3 0.00737 ppb |- B 10 1404.1 5.33758 ppb | B 11 6075.4 5.29898 ppb | Mg 24 7607.4 1.89786 ppb | Mg 25 1311.8 2.34087 ppb | K 39 340240.6 12.1709 ppb | Ca 44 15200.4 20.65212 ppb | Sc 45 225094.8 ppb | Cr 52 8447.3 0.23012 ppb | Cr 53 2224.9 -5.47403 ppb | Fe 54 43042.3 23.9107 ppb | Mn 55 1832.9 0.1113 ppb | Fe 57 5506 4.59166 ppb | Co 59 988.1 0.08791 ppb | Ni 60 257.7 0.08006 ppb | Cu 63 2591.4 0.24743 ppb | Cu 65 1272.8 0.25319 ppb | Zn 66 8354.5 5.12286 ppb | Zn 67 1767.8 1.0515 ppb | Zn 68 6306.5 5.01566 ppb | As 75 -148.6 0.00975 ppb | Se 77 147 -1.06094 ppb | Se 82 12.7 0.03295 ppb | Sr 88 798 0.03032 ppb | Mo 95 2223.3 0.62956 ppb | Mo 97 1416.1 0.6324 ppb | Mo 98 3591 0.59249 ppb |> Rh 103 437694.6 ppb | Cd 111 26.4 0.01065 ppb |- Cd 114 57.1 0.00882 ppb |- Sb 121 563.7 -0.11565 ppb | Sb 123 433.1 -0.11639 ppb | Ba 135 187 0.02615 ppb | Ba 137 286 0.01524 ppb |> Ho 165 937231.3 ppb | Pb 206 350 0.02274 ppb | Pb 207 293.7 0.02201 ppb |- Pb 208 1363.7 0.0226 ppb Kr 83 27.9 ppb ICP-Data 5 of 18 elementOne e 24736-Metals 48.5 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 10 Sample DatThursday, May 21, 2015 13:10:54 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 82769.9 ppb |- Be 9 25061.2 50.49555 ppb |- B 10 1159.4 2.59496 ppb | B 11 5063.7 2.63684 ppb | Mg 24 2473886 586.1059 ppb | Mg 25 337215.4 563.54 ppb | K 39 5020054.3 523.7889 ppb | Ca 44 185286 558.2177 ppb | Sc 45 254031.8 ppb | Cr 52 469754.5 51.06655 ppb | Cr 53 56620.8 47.70262 ppb | Fe 54 468747 569.4174 ppb | Mn 55 728610.1 50.29329 ppb | Fe 57 176017.2 575.4817 ppb | Co 59 621118.7 51.31256 ppb | Ni 60 134209.5 53.12027 ppb | Cu 63 311315.5 53.0099 ppb | Cu 65 148622.4 54.69636 ppb | Zn 66 84537.3 49.19468 ppb | Zn 67 14476.9 46.27244 ppb | Zn 68 61444.6 49.59795 ppb | As 75 88146.8 48.49997 ppb | Se 77 7481.4 44.40926 ppb | Se 82 9616.2 44.87774 ppb | Sr 88 687 0.02197 ppb | Mo 95 178048.1 50.7319 ppb | Mo 97 111975.8 50.50423 ppb | Mo 98 289380 48.03308 ppb |> Rh 103 491320.2 ppb | Cd 111 127534.9 48.09481 ppb |- Cd 114 296258.7 46.2914 ppb |- Sb 121 395004.9 48.37897 ppb | Sb 123 303098.5 48.81111 ppb | Ba 135 125304.3 51.19211 ppb | Ba 137 220101.4 49.67843 ppb |> Ho 165 1057066.1 ppb | Pb 206 585703.4 51.54758 ppb | Pb 207 513348.5 51.76115 ppb |- Pb 208 2354801.7 51.82408 ppb Kr 83 27.3 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC STD 2 Sample DatThursday, May 21, 2015 13:14:14 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 81597.9 ppb |- Be 9 519.3 1.05682 ppb |- B 10 1719.8 6.38269 ppb | B 11 7441.7 6.34464 ppb | Mg 24 89851.5 21.37039 ppb | Mg 25 12741.3 21.38355 ppb | K 39 470305.7 22.41188 ppb | Ca 44 14877.2 14.12353 ppb | Sc 45 246198.2 ppb | Cr 52 16423.5 1.01433 ppb | Cr 53 3165.6 -4.78847 ppb | Fe 54 46406.1 22.00501 ppb | Mn 55 14889.2 1.00736 ppb | Fe 57 11439.2 22.63317 ppb | Co 59 12506.6 1.03937 ppb | Ni 60 2727.7 1.05624 ppb | Cu 63 7631.5 1.06771 ppb | Cu 65 3699.1 1.10568 ppb | Zn 66 2558.7 1.13858 ppb | Zn 67 873 -2.94179 ppb | Zn 68 2287.3 1.10379 ppb | As 75 1670.6 1.02719 ppb | Se 77 314.7 -0.11368 ppb | Se 82 225 1.02718 ppb | Sr 88 23427.5 0.94343 ppb | Mo 95 4801.3 1.30007 ppb | Mo 97 3001.8 1.28294 ppb | Mo 98 7841 1.23776 ppb |> Rh 103 486740.3 ppb | Cd 111 2712.3 1.0319 ppb |- Cd 114 6303.7 0.99293 ppb |- Sb 121 8600.4 0.89637 ppb | Sb 123 6646.5 0.91244 ppb | Ba 135 2624.7 1.04647 ppb | Ba 137 4756.9 1.05041 ppb |> Ho 165 1025455.6 ppb | Pb 206 11509.9 1.03248 ppb | Pb 207 10146 1.04335 ppb |- Pb 208 46134.5 1.03557 ppb Kr 83 -122.5 ppb ICP-Data 6 of 18 elementOne e 24736-Metals 48.6 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: 24736-1.1 Sample DatThursday, May 21, 2015 13:17:34 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 84549.2 ppb |- Be 9 21 0.03657 ppb |- B 10 4737.9 24.78441 ppb | B 11 21065.4 25.50189 ppb | Mg 24 3192924.1 724.3138 ppb | Mg 25 433138.9 693.0787 ppb | K 39 11849947 1221.401 ppb | Ca 44 4111245.2 12543.12 ppb | Sc 45 273242.8 ppb | Cr 52 9344.1 0.17108 ppb | Cr 53 2219.9 -5.84114 ppb | Fe 54 69070.9 47.02444 ppb | Mn 55 267708.4 17.67299 ppb | Fe 57 14371.4 30.06773 ppb | Co 59 2602.7 0.20221 ppb | Ni 60 2386 0.87037 ppb | Cu 63 7768.3 1.02259 ppb | Cu 65 3785.5 1.06553 ppb | Zn 66 6169.4 3.08725 ppb | Zn 67 1633.1 -0.47304 ppb | Zn 68 5572 3.58464 ppb | As 75 -44.9 0.07804 ppb | Se 77 213 -0.81833 ppb | Se 82 89.4 0.36618 ppb | Sr 88 752546.1 28.90956 ppb | Mo 95 2750.7 0.66811 ppb | Mo 97 1729.5 0.66181 ppb | Mo 98 4514.3 0.64013 ppb |> Rh 103 513066.7 ppb | Cd 111 79.5 0.02816 ppb |- Cd 114 175 0.02496 ppb |- Sb 121 1148.7 -0.05852 ppb | Sb 123 849.9 -0.06371 ppb | Ba 135 53750.6 20.98333 ppb | Ba 137 94923.6 20.47683 ppb |> Ho 165 1104122.8 ppb | Pb 206 838.4 0.05873 ppb | Pb 207 709.4 0.05711 ppb |- Pb 208 3291.9 0.0582 ppb Kr 83 -5070 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: 24736-1.1 Sample DatThursday, May 21, 2015 13:20:53 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 86837.9 ppb |- Be 9 23 0.03936 ppb |- B 10 4796.9 23.84868 ppb | B 11 21374.8 24.60776 ppb | Mg 24 3348237.2 726.8007 ppb | Mg 25 454037.5 695.1973 ppb | K 39 12464287 1229.665 ppb | Ca 44 4340075 12672.05 ppb | Sc 45 287100.8 ppb | Cr 52 9531.7 0.14761 ppb | Cr 53 2316.6 -5.84301 ppb | Fe 54 72431.4 47.32943 ppb | Mn 55 281889.9 17.80754 ppb | Fe 57 14882.5 29.64923 ppb | Co 59 2735.7 0.20348 ppb | Ni 60 2291.3 0.79711 ppb | Cu 63 8478.3 1.07884 ppb | Cu 65 4060.9 1.10076 ppb | Zn 66 3664.4 1.59224 ppb | Zn 67 1293.4 -1.84236 ppb | Zn 68 3903.8 2.14333 ppb | As 75 -172.6 0.01449 ppb | Se 77 227.3 -0.79259 ppb | Se 82 81.7 0.31608 ppb | Sr 88 792772.2 29.1394 ppb | Mo 95 2542.4 0.58101 ppb | Mo 97 1564.8 0.56083 ppb | Mo 98 4049.6 0.53812 ppb |> Rh 103 536263.8 ppb | Cd 111 81.4 0.02758 ppb |- Cd 114 164.4 0.02232 ppb |- Sb 121 1056.7 -0.07413 ppb | Sb 123 801.5 -0.07601 ppb | Ba 135 55987.6 21.02452 ppb | Ba 137 98747.1 20.48896 ppb |> Ho 165 1147955.6 ppb | Pb 206 711 0.04564 ppb | Pb 207 606.7 0.04496 ppb |- Pb 208 2755.8 0.04462 ppb Kr 83 -5344.5 ppb ICP-Data 7 of 18 elementOne e 24736-Metals 48.7 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatThursday, May 21, 2015 13:47:23 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 81905.8 ppb |- Be 9 1.7 -0.00143 ppb |- B 10 931 1.1449 ppb | B 11 4253.7 1.46293 ppb | Mg 24 1117.8 0.14389 ppb | Mg 25 193.3 0.21066 ppb | K 39 292936.3 2.61905 ppb | Ca 44 10732 0.70332 ppb | Sc 45 252814.8 ppb | Cr 52 7660.2 0.03639 ppb | Cr 53 2073.6 -5.87374 ppb | Fe 54 32617.4 3.89937 ppb | Mn 55 547.4 0.0074 ppb | Fe 57 5471 2.36408 ppb | Co 59 36 -0.00061 ppb | Ni 60 91.3 0.00214 ppb | Cu 63 2578.4 0.19438 ppb | Cu 65 1272.1 0.19885 ppb | Zn 66 903 0.15663 ppb | Zn 67 491.7 -4.33768 ppb | Zn 68 1097.1 0.11656 ppb | As 75 -229.9 -0.02564 ppb | Se 77 156.3 -1.10775 ppb | Se 82 15.4 0.03904 ppb | Sr 88 319.3 0.00732 ppb | Mo 95 212.7 -0.02261 ppb | Mo 97 126.3 -0.02932 ppb | Mo 98 325.1 -0.02432 ppb |> Rh 103 487127.3 ppb | Cd 111 4 0.00101 ppb |- Cd 114 4.4 -0.00053 ppb |- Sb 121 125 -0.17754 ppb | Sb 123 94.6 -0.17918 ppb | Ba 135 179.3 0.01748 ppb | Ba 137 289 0.01151 ppb |> Ho 165 998961.6 ppb | Pb 206 128.7 -0.00002 ppb | Pb 207 130.3 0.00251 ppb |- Pb 208 571.7 0.00206 ppb Kr 83 28.2 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatThursday, May 21, 2015 13:50:42 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 80264.2 ppb |- Be 9 47379.2 98.44439 ppb |- B 10 13708.3 91.06559 ppb | B 11 59731.6 91.42001 ppb | Mg 24 4360383.7 1102.222 ppb | Mg 25 580871.6 1035.766 ppb | K 39 10550092 1211.775 ppb | Ca 44 353683.2 1171.918 ppb | Sc 45 244484.2 ppb | Cr 52 863680.9 100.9442 ppb | Cr 53 103384.7 100.4334 ppb | Fe 54 850379.7 1138.435 ppb | Mn 55 1416782 104.3714 ppb | Fe 57 335659.2 1187.627 ppb | Co 59 1158758.4 102.1378 ppb | Ni 60 251858.1 106.3815 ppb | Cu 63 563655 102.627 ppb | Cu 65 266129.5 104.7302 ppb | Zn 66 169778.5 105.8337 ppb | Zn 67 28054.2 102.2166 ppb | Zn 68 121397.6 105.4237 ppb | As 75 175904.5 103.1416 ppb | Se 77 15994.7 103.9483 ppb | Se 82 20850.9 103.8552 ppb | Sr 88 2439794.4 104.4378 ppb | Mo 95 322975 98.25849 ppb | Mo 97 203212.9 97.86481 ppb | Mo 98 526833.4 93.372 ppb |> Rh 103 460545.8 ppb | Cd 111 243520.4 97.9647 ppb |- Cd 114 565676.4 94.29633 ppb |- Sb 121 745681.7 100.6668 ppb | Sb 123 570055.1 101.189 ppb | Ba 135 229708.8 103.2785 ppb | Ba 137 404739.1 100.5557 ppb |> Ho 165 960946.7 ppb | Pb 206 1074642.4 104.0478 ppb | Pb 207 945815.1 104.9201 ppb |- Pb 208 4408244.8 106.7423 ppb Kr 83 -16500.9 ppb ICP-Data 8 of 18 elementOne e 24736-Metals 48.8 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatThursday, May 21, 2015 14:17:15 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 11196 ppb |- Be 9 11 0.15444 ppb |- B 10 1605.5 101.7778 ppb | B 11 7034.8 102.831 ppb | Mg 24 441339.9 1018.849 ppb | Mg 25 62302.2 1010.827 ppb | K 39 9382270.5 10117.95 ppb | Ca 44 128726.9 3972.187 ppb | Sc 45 15218.6 ppb | Cr 52 30062 31.6555 ppb | Cr 53 3942.9 30.36767 ppb | Fe 54 34078.5 400.3247 ppb | Mn 55 26865.7 17.95099 ppb | Fe 57 9176.9 285.2844 ppb | Co 59 3650.1 2.92011 ppb | Ni 60 783 2.96695 ppb | Cu 63 53343.9 88.13307 ppb | Cu 65 25492.7 91.1885 ppb | Zn 66 17948.6 102.204 ppb | Zn 67 2861.5 95.3545 ppb | Zn 68 13173.1 104.9263 ppb | As 75 325.3 1.7444 ppb | Se 77 75 2.66741 ppb | Se 82 110.2 4.90638 ppb | Sr 88 49405 19.19577 ppb | Mo 95 1974.6 5.48943 ppb | Mo 97 1218.1 5.31988 ppb | Mo 98 2986.2 4.86163 ppb |> Rh 103 50426.5 ppb | Cd 111 19 0.07362 ppb |- Cd 114 41.2 0.05826 ppb |- Sb 121 242447.4 254.8573 ppb | Sb 123 189427.2 262.1778 ppb | Ba 135 6797.7 23.73919 ppb | Ba 137 11741.8 22.61211 ppb |> Ho 165 122631.5 ppb | Pb 206 8731.1 6.57514 ppb | Pb 207 7024.2 6.05107 ppb |- Pb 208 33153.1 6.24202 ppb Kr 83 -314 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatThursday, May 21, 2015 14:20:34 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 38308.1 ppb |- Be 9 19910.5 83.80161 ppb |- B 10 5793.3 88.19361 ppb | B 11 25725.5 90.73206 ppb | Mg 24 1782735.9 1003.629 ppb | Mg 25 236979.4 951.8848 ppb | K 39 4033334.2 1043.915 ppb | Ca 44 131780.7 980.9943 ppb | Sc 45 87282 ppb | Cr 52 325852.2 85.8428 ppb | Cr 53 39123.3 85.06432 ppb | Fe 54 314889.3 949.7065 ppb | Mn 55 528248.1 87.7241 ppb | Fe 57 120712.7 963.1326 ppb | Co 59 417316.7 83.01017 ppb | Ni 60 89764.3 85.51714 ppb | Cu 63 209769.3 86.29252 ppb | Cu 65 100645 89.4816 ppb | Zn 66 71464.5 100.6088 ppb | Zn 67 11536.1 94.47902 ppb | Zn 68 52402.4 102.5957 ppb | As 75 73371.4 97.07048 ppb | Se 77 6865.9 100.8702 ppb | Se 82 9157.9 102.9144 ppb | Sr 88 962941.2 92.61722 ppb | Mo 95 128513.9 88.05969 ppb | Mo 97 80659.1 87.27614 ppb | Mo 98 210748.3 84.00637 ppb |> Rh 103 198654.6 ppb | Cd 111 104021.5 94.65836 ppb |- Cd 114 245782.8 92.69968 ppb |- Sb 121 345024.3 94.37983 ppb | Sb 123 266855.6 96.05922 ppb | Ba 135 105271.8 95.95801 ppb | Ba 137 184196.9 92.71522 ppb |> Ho 165 463297.4 ppb | Pb 206 497670.9 97.55668 ppb | Pb 207 435417.1 98.00755 ppb |- Pb 208 1988456.9 97.64876 ppb Kr 83 -6507 ppb ICP-Data 9 of 18 elementOne e 24736-Metals 48.9 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC STD 2 Sample DatThursday, May 21, 2015 14:28:23 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 71138.1 ppb |- Be 9 431 1.00345 ppb |- B 10 2162.9 12.67674 ppb | B 11 9534.3 12.94523 ppb | Mg 24 70989.1 20.83193 ppb | Mg 25 10165 21.04996 ppb | K 39 399696.9 24.94625 ppb | Ca 44 15341.1 27.42199 ppb | Sc 45 202651.6 ppb | Cr 52 13968.7 1.10478 ppb | Cr 53 2234.9 -5.19209 ppb | Fe 54 40145.5 26.11397 ppb | Mn 55 13029.3 1.09021 ppb | Fe 57 9572.7 23.88583 ppb | Co 59 10112.3 1.03666 ppb | Ni 60 2549.7 1.22627 ppb | Cu 63 24823.1 5.14406 ppb | Cu 65 12169.7 5.44324 ppb | Zn 66 3112.9 1.91408 ppb | Zn 67 703 -2.94725 ppb | Zn 68 2540.7 1.82055 ppb | As 75 1394.3 1.05469 ppb | Se 77 274.7 0.03847 ppb | Se 82 190.4 1.07203 ppb | Sr 88 20853.6 1.03679 ppb | Mo 95 3787.5 1.26556 ppb | Mo 97 2444.3 1.29085 ppb | Mo 98 6119.7 1.19058 ppb |> Rh 103 394646.5 ppb | Cd 111 2215 1.03919 ppb |- Cd 114 5186.5 1.00772 ppb |- Sb 121 8201.4 1.02806 ppb | Sb 123 6306 1.03972 ppb | Ba 135 2841.5 1.35249 ppb | Ba 137 4984.5 1.31101 ppb |> Ho 165 873320.4 ppb | Pb 206 10522.1 1.1097 ppb | Pb 207 9194.3 1.11161 ppb |- Pb 208 42386 1.11873 ppb Kr 83 -112.1 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatThursday, May 21, 2015 14:35:42 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 78266.9 ppb |- Be 9 1.3 -0.00198 ppb |- B 10 1040.7 3.06454 ppb | B 11 4464.4 2.96469 ppb | Mg 24 444 0.00263 ppb | Mg 25 71.3 0.02756 ppb | K 39 236891.8 0.93588 ppb | Ca 44 7077.8 -7.13012 ppb | Sc 45 209640.2 ppb | Cr 52 6002.6 -0.03301 ppb | Cr 53 1259.8 -6.46515 ppb | Fe 54 27085.3 2.76939 ppb | Mn 55 394.7 0.00156 ppb | Fe 57 4493.1 1.66974 ppb | Co 59 23 -0.00135 ppb | Ni 60 72 -0.00065 ppb | Cu 63 1267.4 0.00617 ppb | Cu 65 615.7 -0.00617 ppb | Zn 66 585.4 0.02953 ppb | Zn 67 325.3 -4.73973 ppb | Zn 68 794 -0.02009 ppb | As 75 -213.7 -0.03729 ppb | Se 77 113.7 -1.25176 ppb | Se 82 11.8 0.03186 ppb | Sr 88 140 0.00104 ppb | Mo 95 191.7 -0.01916 ppb | Mo 97 112.7 -0.02673 ppb | Mo 98 320.2 -0.01586 ppb |> Rh 103 415593.1 ppb | Cd 111 0.5 -0.00032 ppb |- Cd 114 10 0.00063 ppb |- Sb 121 191 -0.16638 ppb | Sb 123 149.5 -0.16713 ppb | Ba 135 118 -0.0037 ppb | Ba 137 220 0.00045 ppb |> Ho 165 905038.9 ppb | Pb 206 124.7 0.00082 ppb | Pb 207 104.3 0.0009 ppb |- Pb 208 467.7 0.00078 ppb Kr 83 21.4 ppb ICP-Data 10 of 18 elementOne e 24736-Metals 48.10 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatThursday, May 21, 2015 14:39:01 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 80007.8 ppb |- Be 9 45547.5 94.92986 ppb |- B 10 13608.5 97.96695 ppb | B 11 58936.2 97.70815 ppb | Mg 24 4194643.1 1144.976 ppb | Mg 25 553542.4 1065.718 ppb | K 39 9830781.6 1219.217 ppb | Ca 44 325411.2 1163.948 ppb | Sc 45 224376.3 ppb | Cr 52 790132.1 99.70917 ppb | Cr 53 94564.1 99.09804 ppb | Fe 54 780041.4 1127.062 ppb | Mn 55 1314589.6 104.5606 ppb | Fe 57 314532.6 1201.699 ppb | Co 59 1074308.8 102.2418 ppb | Ni 60 234413 106.9157 ppb | Cu 63 519978.3 102.2265 ppb | Cu 65 247339.1 105.1071 ppb | Zn 66 158626 106.7773 ppb | Zn 67 26266.2 103.3992 ppb | Zn 68 113174.1 106.1215 ppb | As 75 161574 102.3004 ppb | Se 77 14629.4 102.6453 ppb | Se 82 19428.2 104.4917 ppb | Sr 88 2218893.8 102.5646 ppb | Mo 95 295705.7 97.13725 ppb | Mo 97 186237 96.83883 ppb | Mo 98 483566.2 92.53647 ppb |> Rh 103 426512.1 ppb | Cd 111 228682.5 99.34104 ppb |- Cd 114 530382.4 95.46773 ppb |- Sb 121 687147.2 94.58264 ppb | Sb 123 528234.1 95.59553 ppb | Ba 135 210808.1 96.64216 ppb | Ba 137 373217.3 94.53552 ppb |> Ho 165 942422.1 ppb | Pb 206 1089973.4 107.6064 ppb | Pb 207 952886.6 107.7792 ppb |- Pb 208 4434279.7 109.4756 ppb Kr 83 -15016.3 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: 24736-1.1 Sample DatThursday, May 21, 2015 15:05:32 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 81071.7 ppb |- Be 9 3 0.00137 ppb |- B 10 2190.3 11.50575 ppb | B 11 9462.6 11.42716 ppb | Mg 24 277212.8 75.37633 ppb | Mg 25 39084.2 74.98136 ppb | K 39 1255232.5 129.1567 ppb | Ca 44 355963.5 1273.307 ppb | Sc 45 227419.3 ppb | Cr 52 10895.9 0.56609 ppb | Cr 53 20631.7 15.39243 ppb | Fe 54 34324.1 12.39124 ppb | Mn 55 24164.1 1.88718 ppb | Fe 57 5509.3 5.09932 ppb | Co 59 249 0.02004 ppb | Ni 60 254.3 0.08137 ppb | Cu 63 2641.4 0.26896 ppb | Cu 65 1301.4 0.27736 ppb | Zn 66 906 0.23418 ppb | Zn 67 746.4 -3.0145 ppb | Zn 68 1094.1 0.24124 ppb | As 75 -783.8 -0.39496 ppb | Se 77 3363.3 21.94589 ppb | Se 82 54.1 0.25394 ppb | Sr 88 64135 2.95132 ppb | Mo 95 439.7 0.06029 ppb | Mo 97 256.7 0.04627 ppb | Mo 98 720.2 0.05867 ppb |> Rh 103 427490.2 ppb | Cd 111 10 0.00379 ppb |- Cd 114 29.3 0.004 ppb |- Sb 121 4416.8 0.40127 ppb | Sb 123 3360.5 0.40004 ppb | Ba 135 4545.8 1.98662 ppb | Ba 137 7905.1 1.90909 ppb |> Ho 165 959904.4 ppb | Pb 206 178.7 0.00532 ppb | Pb 207 150 0.00528 ppb |- Pb 208 728.3 0.00641 ppb Kr 83 -403.6 ppb ICP-Data 11 of 18 elementOne e 24736-Metals 48.11 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: 24736-1.1 Sample DatThursday, May 21, 2015 15:08:51 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 71950.6 ppb |- Be 9 2.7 0.00135 ppb |- B 10 1858.2 11.0753 ppb | B 11 8160.3 11.25718 ppb | Mg 24 275858.7 86.06951 ppb | Mg 25 38574 84.90123 ppb | K 39 1222512.9 147.8467 ppb | Ca 44 351428.7 1446.806 ppb | Sc 45 198386.2 ppb | Cr 52 10918.9 0.77334 ppb | Cr 53 24101 23.29509 ppb | Fe 54 33330.3 18.24212 ppb | Mn 55 23501.3 2.10957 ppb | Fe 57 5496.7 8.17797 ppb | Co 59 269.3 0.02574 ppb | Ni 60 250.3 0.09639 ppb | Cu 63 2497.7 0.31325 ppb | Cu 65 1191.7 0.30583 ppb | Zn 66 1342.8 0.66189 ppb | Zn 67 1419.4 0.64303 ppb | Zn 68 1448.4 0.77621 ppb | As 75 -975.3 -0.60459 ppb | Se 77 3500 26.59393 ppb | Se 82 27.5 0.13578 ppb | Sr 88 62662.6 3.30984 ppb | Mo 95 337.7 0.04324 ppb | Mo 97 213.3 0.04018 ppb | Mo 98 550.6 0.04187 ppb |> Rh 103 372610.8 ppb | Cd 111 9.4 0.00416 ppb |- Cd 114 25.1 0.00394 ppb |- Sb 121 1457.8 0.03243 ppb | Sb 123 1097.3 0.02853 ppb | Ba 135 4429.1 2.22593 ppb | Ba 137 7763.6 2.15635 ppb |> Ho 165 837607.8 ppb | Pb 206 144.3 0.00404 ppb | Pb 207 133.3 0.0056 ppb |- Pb 208 599.7 0.00542 ppb Kr 83 -403.2 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatThursday, May 21, 2015 15:12:11 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 83715.7 ppb |- Be 9 0.7 -0.00349 ppb |- B 10 1274.1 4.08034 ppb | B 11 5598.4 4.18495 ppb | Mg 24 901.7 0.11054 ppb | Mg 25 111.3 0.08888 ppb | K 39 256418.2 0.78453 ppb | Ca 44 9217 -1.85051 ppb | Sc 45 231502.5 ppb | Cr 52 6662.4 -0.01697 ppb | Cr 53 4238.7 -3.39807 ppb | Fe 54 28349.1 1.19743 ppb | Mn 55 585.7 0.01329 ppb | Fe 57 4721.9 1.0688 ppb | Co 59 32.3 -0.0007 ppb | Ni 60 99.3 0.00839 ppb | Cu 63 1400.8 0.01034 ppb | Cu 65 674.4 -0.00423 ppb | Zn 66 768 0.11323 ppb | Zn 67 895.7 -2.60597 ppb | Zn 68 988.4 0.09087 ppb | As 75 -169.9 0.0003 ppb | Se 77 222.3 -0.58465 ppb | Se 82 8.1 0.00794 ppb | Sr 88 195 0.00291 ppb | Mo 95 158 -0.03483 ppb | Mo 97 90.7 -0.04241 ppb | Mo 98 249 -0.03383 ppb |> Rh 103 452058.2 ppb | Cd 111 6.2 0.00202 ppb |- Cd 114 14.7 0.00126 ppb |- Sb 121 423 -0.13852 ppb | Sb 123 346.8 -0.13578 ppb | Ba 135 141 0.00118 ppb | Ba 137 245.7 0.00133 ppb |> Ho 165 995142.8 ppb | Pb 206 224 0.00896 ppb | Pb 207 172.7 0.00712 ppb |- Pb 208 880.7 0.00936 ppb Kr 83 26 ppb ICP-Data 12 of 18 elementOne e 24736-Metals 48.12 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatThursday, May 21, 2015 15:15:30 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 83389.6 ppb |- Be 9 47985.3 95.95496 ppb |- B 10 14617.7 97.2633 ppb | B 11 63200 96.8372 ppb | Mg 24 4793957.4 1209.897 ppb | Mg 25 619271.2 1102.468 ppb | K 39 10533328 1207.681 ppb | Ca 44 347319.9 1148.361 ppb | Sc 45 242374 ppb | Cr 52 845396.9 98.64433 ppb | Cr 53 101924.5 98.74625 ppb | Fe 54 823173.4 1098.943 ppb | Mn 55 1379475 101.4569 ppb | Fe 57 329729.1 1164.409 ppb | Co 59 1132001.9 99.619 ppb | Ni 60 246026 103.7572 ppb | Cu 63 546769.5 99.39349 ppb | Cu 65 260263 102.2572 ppb | Zn 66 170111.2 105.8822 ppb | Zn 67 28277.2 102.9097 ppb | Zn 68 121455 105.3021 ppb | As 75 174366.4 102.0949 ppb | Se 77 15590.7 101.1347 ppb | Se 82 20853 103.7261 ppb | Sr 88 2403990.7 102.749 ppb | Mo 95 322664.9 98.01429 ppb | Mo 97 201834.8 97.04573 ppb | Mo 98 525703.4 93.02619 ppb |> Rh 103 461235.9 ppb | Cd 111 250220.1 100.5151 ppb |- Cd 114 586674.3 97.65497 ppb |- Sb 121 757819.2 96.61687 ppb | Sb 123 578907.9 97.04334 ppb | Ba 135 231682.9 98.3758 ppb | Ba 137 405824.9 95.21054 ppb |> Ho 165 1017512.9 ppb | Pb 206 1114244.8 101.8874 ppb | Pb 207 990454.5 103.758 ppb |- Pb 208 4608661.6 105.3786 ppb Kr 83 -16264.1 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: Blank Sample DatFriday, May 22, 2015 10:11:27 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 68377.9 ppb |- Sc 45 277589.8 ppb | V-1 51 6191.4 ppb | V 51 8590.5 ppb |> Rh 103 528338.8 ppb |> Ho 165 960678.6 ppb |- Tl 205 71.7 ppb Kr 83 36.4 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 1 Sample DatFriday, May 22, 2015 10:12:45 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 70852.2 ppb |- Sc 45 290888.3 ppb | V-1 51 18923.7 0.93038 ppb | V 51 34693.5 0.96347 ppb |> Rh 103 549254.1 ppb |> Ho 165 1001212.1 ppb |- Tl 205 27528.6 0.97146 ppb Kr 83 45.6 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 2 Sample DatFriday, May 22, 2015 10:14:03 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 75333.5 ppb |- Sc 45 308624.2 ppb | V-1 51 148036.3 9.91497 ppb | V 51 293079.4 9.99554 ppb |> Rh 103 582875.8 ppb |> Ho 165 1079147.5 ppb |- Tl 205 301399.8 9.89021 ppb Kr 83 44.7 mg/L ICP-Data 13 of 18 elementOne e 24736-Metals 48.13 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 3 Sample DatFriday, May 22, 2015 10:15:21 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 71885.8 ppb |- Sc 45 287111.1 ppb | V-1 51 401820.4 30.03067 ppb | V 51 795998.5 30.0027 ppb |> Rh 103 538936.6 ppb |> Ho 165 1004057.7 ppb |- Tl 205 851295.7 30.03755 ppb Kr 83 44.2 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatFriday, May 22, 2015 10:16:39 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 73868.7 ppb |- Sc 45 296224.3 ppb | V-1 51 12299.9 ppb | V 51 14798 ppb |> Rh 103 548367.1 ppb |> Ho 165 1007097.1 ppb |- Tl 205 398.3 ppb Kr 83 48.5 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 2 Sample DatFriday, May 22, 2015 10:17:57 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 72080.2 ppb |- Sc 45 287453.9 ppb | V-1 51 18237.8 0.49064 ppb | V 51 24545 0.39632 ppb |> Rh 103 531885.1 ppb |> Ho 165 970850.1 ppb |- Tl 205 8667.8 0.30235 ppb Kr 83 43.8 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 3 Sample DatFriday, May 22, 2015 10:19:15 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 71898.7 ppb |- Sc 45 283654.5 ppb | V-1 51 28505.1 1.28804 ppb | V 51 43533.9 1.13525 ppb |> Rh 103 530021.3 ppb |> Ho 165 966558 ppb |- Tl 205 27791.1 1.0048 ppb Kr 83 45.6 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatFriday, May 22, 2015 10:20:33 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 74347.8 ppb |- Sc 45 293448.8 ppb | V-1 51 150151.1 10.33322 ppb | V 51 285523.4 10.18249 ppb |> Rh 103 546790.1 ppb |> Ho 165 993683 ppb |- Tl 205 284656.9 10.13371 ppb Kr 83 40.5 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 5 Sample DatFriday, May 22, 2015 10:21:52 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 68914.7 ppb |- Sc 45 271907.4 ppb | V-1 51 331848.6 25.60251 ppb | V 51 647638.6 25.42367 ppb |> Rh 103 511982.7 ppb |> Ho 165 936223.2 ppb |- Tl 205 671313.2 25.38647 ppb Kr 83 50.9 mg/L ICP-Data 14 of 18 elementOne e 24736-Metals 48.14 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 9 Sample DatFriday, May 22, 2015 10:23:11 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 61988.6 ppb |- Sc 45 279091 ppb | V-1 51 142063.8 14.72799 ppb | V 51 234684.4 12.41884 ppb |> Rh 103 371572.6 ppb |> Ho 165 737390.5 ppb |- Tl 205 873 0.02791 ppb Kr 83 -77514.2 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 10 Sample DatFriday, May 22, 2015 10:24:29 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 63133.9 ppb |- Sc 45 279873.5 ppb | V-1 51 201262.8 21.20242 ppb | V 51 288513.6 15.36169 ppb |> Rh 103 372266.7 ppb |> Ho 165 722969.7 ppb |- Tl 205 737.4 0.02214 ppb Kr 83 -77470.2 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC STD 2 Sample DatFriday, May 22, 2015 10:25:48 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 62224.8 ppb |- Sc 45 297121.1 ppb | V-1 51 39535.3 2.08519 ppb | V 51 45636 1.18507 ppb |> Rh 103 539881.4 ppb |> Ho 165 936651.6 ppb |- Tl 205 8011.9 0.28893 ppb Kr 83 39.7 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: 24736-1.1 Sample DatFriday, May 22, 2015 10:27:08 Sample DesDuke Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 66395.9 ppb |- Sc 45 320683.9 ppb | V-1 51 36242.1 1.82002 ppb | V 51 45309.2 1.16307 ppb |> Rh 103 543404.6 ppb |> Ho 165 987412.2 ppb |- Tl 205 588.7 0.00714 ppb Kr 83 -5528.6 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: 24736-1.1 Sample DatFriday, May 22, 2015 10:28:25 Sample DesDuke Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 70306.8 ppb |- Sc 45 320217.6 ppb | V-1 51 34468.5 1.69088 ppb | V 51 43320 1.09027 ppb |> Rh 103 542685.2 ppb |> Ho 165 995238.6 ppb |- Tl 205 548.3 0.00554 ppb Kr 83 -5603.9 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatFriday, May 22, 2015 10:29:45 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 70400.7 ppb |- Sc 45 301460.3 ppb | V-1 51 26492.1 1.05249 ppb | V 51 28880.5 0.52359 ppb |> Rh 103 551418.8 ppb |> Ho 165 977547.4 ppb |- Tl 205 92.3 -0.01066 ppb Kr 83 43.5 mg/L ICP-Data 15 of 18 elementOne e 24736-Metals 48.15 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatFriday, May 22, 2015 10:31:03 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 70892.1 ppb |- Sc 45 296604.8 ppb | V-1 51 164465.9 11.29885 ppb | V 51 305284.1 10.82731 ppb |> Rh 103 550886.9 ppb |> Ho 165 975688.9 ppb |- Tl 205 273349.9 9.90865 ppb Kr 83 41 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: Blank Sample DatFriday, May 22, 2015 10:39:38 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 82641.9 ppb |- Al 27 1786.8 ppb | Sc 45 280034 ppb |> Rh 103 525228.1 ppb Ho 165 959729.9 ppb Kr 83 49.6 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 1 Sample DatFriday, May 22, 2015 10:40:43 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 83883 ppb |- Al 27 10633.9 1.05779 ppb | Sc 45 292386.8 ppb |> Rh 103 537935.9 ppb Ho 165 980870.5 ppb Kr 83 -135.4 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 2 Sample DatFriday, May 22, 2015 10:41:49 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 78913.8 ppb |- Al 27 789522.6 94.86932 ppb | Sc 45 293683.3 ppb |> Rh 103 536821.1 ppb Ho 165 989117.6 ppb Kr 83 -20064 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 3 Sample DatFriday, May 22, 2015 10:42:54 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 76872.9 ppb |- Al 27 4105538.4 501.026 ppb | Sc 45 300923.4 ppb |> Rh 103 529586.9 ppb Ho 165 991848.7 ppb Kr 83 -98606.6 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatFriday, May 22, 2015 10:44:00 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 77664.2 ppb |- Al 27 2751.4 0.10793 ppb | Sc 45 285649.4 ppb |> Rh 103 544035.9 ppb Ho 165 989942 ppb Kr 83 51 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 2 Sample DatFriday, May 22, 2015 10:45:06 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 76849.4 ppb |- Al 27 12081.7 1.24986 ppb | Sc 45 288580.6 ppb |> Rh 103 531446.1 ppb Ho 165 974050.3 ppb Kr 83 -127.4 ppb ICP-Data 16 of 18 elementOne e 24736-Metals 48.16 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 3 Sample DatFriday, May 22, 2015 10:46:11 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 73459.7 ppb |- Al 27 1849407.2 232.6615 ppb | Sc 45 292812.8 ppb |> Rh 103 513765.3 ppb Ho 165 949976.9 ppb Kr 83 -48118.8 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatFriday, May 22, 2015 10:47:18 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 75910.2 ppb |- Al 27 761567.6 92.32841 ppb | Sc 45 284031.1 ppb |> Rh 103 532099.1 ppb Ho 165 971640 ppb Kr 83 -19836.1 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 5 Sample DatFriday, May 22, 2015 10:48:24 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 78897 ppb |- Al 27 404141.5 48.15996 ppb | Sc 45 293325 ppb |> Rh 103 540114.3 ppb Ho 165 991243.3 ppb Kr 83 63.3 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 9 Sample DatFriday, May 22, 2015 10:49:30 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 64352.8 ppb |- Al 27 16635.2 1.91825 ppb | Sc 45 273930.1 ppb |> Rh 103 502794.6 ppb Ho 165 874936.5 ppb Kr 83 54.5 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 10 Sample DatFriday, May 22, 2015 10:50:36 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 71579 ppb |- Al 27 433613.4 50.87808 ppb | Sc 45 307743.3 ppb |> Rh 103 548539.4 ppb Ho 165 973240.5 ppb Kr 83 54.8 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC STD 2 Sample DatFriday, May 22, 2015 10:51:43 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 76450.5 ppb |- Al 27 12515.3 1.32775 ppb | Sc 45 283853.8 ppb |> Rh 103 522385.9 ppb Ho 165 965616.8 ppb Kr 83 -126.7 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: 24736-1.1 Sample DatFriday, May 22, 2015 10:52:50 Sample DesDuke Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 73970.2 ppb |- Al 27 208129.1 23.83794 ppb | Sc 45 319884 ppb |> Rh 103 558817.5 ppb Ho 165 1008756.5 ppb Kr 83 -5826 ppb ICP-Data 17 of 18 elementOne e 24736-Metals 48.17 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: 24736-1.1 Sample DatFriday, May 22, 2015 10:53:55 Sample DesDuke Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 77771.7 ppb |- Al 27 197794.4 22.36305 ppb | Sc 45 324750 ppb |> Rh 103 566294.6 ppb Ho 165 1028377.7 ppb Kr 83 -5938.1 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatFriday, May 22, 2015 10:55:02 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 81503.2 ppb |- Al 27 2252.9 0.04776 ppb | Sc 45 281696 ppb |> Rh 103 544052.6 ppb Ho 165 999826.3 ppb Kr 83 56.3 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatFriday, May 22, 2015 10:56:08 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 81019.4 ppb |- Al 27 761951.6 91.15847 ppb | Sc 45 291453.3 ppb |> Rh 103 538928.1 ppb Ho 165 1005476.7 ppb Kr 83 -20166.7 ppb ICP-Data 18 of 18 elementOne e 24736-Metals 48.18 PerkinElmer FIMS-100 CVAA Mercury Analyzer Sample_ID Date Time Mean_Sig Mean_Rd Mean_Rt Units Alq.Vol. Sig 1 Reading-1 Result-1 Sig 2 Reading-2 Result-2 Calib Blank 5/20/2015 9:17:07 AM 5.92E-06 µg -3.30E-05 4.48E-05 STD1 = .004ug 5/20/2015 9:18:47 AM 0.0011752 µg 0.0011589 0.0011916 STD2 = .04ug 5/20/2015 9:20:29 AM 0.0117725 µg 0.011685 0.01186 STD3 = .08ug 5/20/2015 9:22:22 AM 0.0235638 µg 0.0235728 0.0235547 STD4 = .16ug 5/20/2015 9:24:17 AM 0.0465987 µg 0.046712 0.0464855 STD5 = .2ug 5/20/2015 9:26:12 AM 0.0579255 µg 0.0579836 0.0578674 Reagent Blank 5/20/2015 9:28:05 AM 6.57E-05 0.0002261 0.0002261 µg 7.59E-05 0.000261 0.000261 5.56E-05 0.0001912 0.0001912 0.004ug = DL 5/20/2015 9:29:46 AM 0.0012042 0.0041421 0.0041421 µg 0.0012024 0.004136 0.004136 0.001206 0.0041483 0.0041483 0.080ug = QC STD 2 5/20/2015 9:31:28 AM 0.0240916 0.0828666 0.0828666 µg 0.0240752 0.0828103 0.0828103 0.024108 0.0829229 0.0829229 0.080ug = QC STD 3 5/20/2015 9:33:25 AM 0.023655 0.0813648 0.0813648 µg 0.0235575 0.0810294 0.0810294 0.0237525 0.0817001 0.0817001 Reagent Blank 5/20/2015 9:35:19 AM 1.05E-05 3.62E-05 3.62E-05 µg 4.45E-05 0.000153 0.000153 -2.34E-05 -8.06E-05 -8.06E-05 0.004ug = DL 5/20/2015 12:10:34 PM 0.0012171 0.0041863 0.0041863 µg 0.0011938 0.0041062 0.0041062 0.0012403 0.0042663 0.0042663 0.080ug = QC STD 2 5/20/2015 12:12:17 PM 0.0235349 0.0809519 0.0809519 µg 0.0234041 0.0805019 0.0805019 0.0236657 0.0814018 0.0814018 Reagent Blank 5/20/2015 12:14:11 PM 7.01E-05 0.0002413 0.0002413 µg 7.91E-05 0.000272 0.000272 6.12E-05 0.0002105 0.0002105 24736- 1.1 5/20/2015 12:25:59 PM 0.0001372 0.0002457 6.14E-06 µg 40 1 0.0001222 0.0001944 4.86E-06 0.0001521 0.0002971 7.43E-06 24736- 1.1 DUP 5/20/2015 12:27:41 PM 0.0001377 0.0002476 6.19E-06 µg 40 1 0.0001264 0.0002087 5.22E-06 0.000149 0.0002865 7.16E-06 0.004ug = DL 5/20/2015 12:32:57 PM 0.0011885 0.0040881 0.0040881 µg 0.0011685 0.0040193 0.0040193 0.0012085 0.004157 0.004157 0.080ug = QC STD 2 5/20/2015 12:34:40 PM 0.0232096 0.079833 0.079833 µg 0.0231075 0.0794817 0.0794817 0.0233118 0.0801843 0.0801843 Reagent Blank 5/20/2015 12:36:33 PM 7.17E-05 0.0002467 0.0002467 µg 7.68E-05 0.0002641 0.0002641 6.67E-05 0.0002293 0.0002293 Hg-Data 1 of 1 elementOne e 24736-Hg 49.1