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HomeMy WebLinkAboutNC0001422_GW S12 25269_20150805 Duke Energy Laboratory Services 13339 Hagers Ferry Road Bld. MG03A Huntersville, NC 28078 Project ID: Ash Basin GW Assessment – S12 Metals, Mercury, Hexavalent Chromium, Chloride, Sulfate, Sodium, Alkalinity, Bicarbonate, Carbonate, Turbidity, Total Dissolved Solids, Total Suspended Solids, Dissolved Oxygen, pH, Temperature and Conductivity Analytical Report 24269 Element One, Inc. 6319-D Carolina Beach Rd., Wilmington, NC 28412 910-793-0128 FAX: 910-792-6853 e1lab@e1lab.com el1 The following data for Analytical Report 24269 has been reviewed for completeness, accuracy, adherence to method protocol, and compliance with quality assurance guidelines. Review by: atie Strickland, B.S. Chemist March 31, 2015 Report Reviewed and Finalized By: Ke Smith, aboratory Director March 31, 2015 elementOne 24269 Duke Report Packet Page 2 of 51 elementOne 24269 Duke Report Packet Page 3 of 51 SUMMARY OF RESULTS elementOne 24269 Duke Report Packet Page 4 of 51 Summary of Analysis Summary of Method 200.8 Metals Analysis S12 Mastec S12 Mastec 24269-1 24269-1 Element mg/L mg/L ----------------- --------------- --------------- Aluminum 0.109 0.110 Antimony < 0.001 < 0.001 Arsenic < 0.005 < 0.005 Barium 0.053 0.054 Beryllium < 0.001 < 0.001 Boron 0.034 0.035 Cadmium < 0.002 < 0.002 Calcium 27.4 26.4 Chromium < 0.005 < 0.005 Cobalt < 0.001 < 0.001 Copper < 0.003 < 0.003 Iron 0.258 0.254 Lead < 0.003 < 0.003 Magnesium 1.80 1.97 Manganese 0.066 0.073 Molybdenum < 0.005 < 0.005 Nickel < 0.005 < 0.005 Potassium 1.20 1.27 Selenium < 0.005 < 0.005 Strontium 0.070 0.076 Thallium < 0.0002 < 0.0002 Vanadium < 0.0003 < 0.0003 Zinc < 0.005 0.005 Summary of Method 245.1 Mercury Analysis S12 Mastec S12 Mastec 24269-1 24269-1 dup Element mg/L mg/L ----------------- ------ --------------- --------------- Mercury #1 < 0.0002 < 0.0002 #2 < 0.0002 < 0.0002 elementOne 24269 Duke Report Packet Page 5 of 51 Summary of Analysis Summary of Method 218.6 Hexavalent Chromium Analysis S12 Mastec 24269-1 Element µg/L ----------------- --------------- Chromium (VI) < 0.1 Summary of Method 300.0 Anions Analysis S12 Mastec S12 Mastec 24269-1 24269-1 dup Element mg/L mg/L ----------------- --------------- --------------- Chloride 5.29 5.30 Sulfate 28.9 28.0 Summary of Method ASTM D6919-03 Sodium Analysis S12 Mastec 24269-1 Element mg/L ----------------- --------------- Sodium 3.08 Summary of Standard Method 2320B Alkalinity Analysis S12 Mastec 24269-1 Assay mg/L ----------------- --------------- Alkalinity as CaCO3 42.8 Summary of Standard Method 4500 CO2 E Analysis S12 Mastec 24269-1 Assay mg/L ----------------- --------------- Bicarbonate (HCO32- as CaCO3) 42.8 Carbonate (CO32- as CaCO3) < 1 Summary of Standard Method 2130 B Turbidity Analysis S12 Mastec 24269-1 Assay NTU ----------------- --------------- Turbidity 1.37 elementOne 24269 Duke Report Packet Page 6 of 51 Summary of Analysis Summary of Standard Method 2540 C TDS Analysis S12 Mastec 24269-1 Assay mg/L ----------------- --------------- Total Dissolved Solids 104 Summary of Standard Method 2540 D TSS Analysis S12 Mastec 24269-1 Assay mg/L ----------------- --------------- Total Suspended Solids < 2.5 Summary of Standard Method 4500O G DO Analysis S12 Mastec 24269-1 Assay mg/L ----------------- --------------- Dissolved Oxygen 8.45 Summary of Standard Method 4500H+ pH Analysis S12 Mastec 24269-1 Assay SU ----------------- --------------- pH 6.85 Summary of Standard Method 2500 B Temperature Analysis S12 Mastec 24269-1 Assay °C ----------------- --------------- Temperature 16.6 Summary of Standard Method 2510 B Conductivity Analysis S12 Mastec 24269-1 Assay µmhos/cm ----------------- --------------- Conductivity 178 elementOne 24269 Duke Report Packet Page 7 of 51 ANALYTICAL NARRATIVE elementOne 24269 Duke Report Packet Page 8 of 51 Element One Analytical Narrative Client: Duke Energy Element One #: 24269 Client ID: Ash Basin GW Assessment –S12 Analyst: DBW, DAM, KLS, LAW, PQT, DMR Method: See table below Dates Received: 03/18/2015 Analytes: See table below Dates Analyzed: 03/18-20/15 Summary of Analysis The samples were collected by Element One, Inc. on 03/18/2015 and were analyzed for pH, temperature, conductivity and dissolved oxygen in the field immediately following sampling. Samples were returned to Element One, Inc., prepared and analyzed for the other parameters following method protocol. The samples were analyzed for metals according to EPA Method 200.8 protocol on a PerkinElmer ELAN 6100 ICP-MS. The samples were analyzed for mercury according to EPA method 245.1 on a PerkinElmer FIMS-100 CVAA mercury analyzer. Samples were prepared and analyzed for chromium (VI) according to SW-846 Method 0061 protocol on a Shimadzu 2010 HPLC unit and a Timberline RDR-1 Reaction Module. Samples were analyzed for chloride, sulfate by EPA 300.0 and sodium by ATSM D6919-03 on Metrohm 861/788 and 761/788 ion chromatograph system. Detection Limits The following is a list of parameters, methods used and the associated reporting limit for each: Parameter DL, mg/L Method Parameter DL, mg/L Method Beryllium 0.001 EPA 200.8 Antimony *0.001 EPA 200.8 Boron 0.005 EPA 200.8 Barium 0.005 EPA 200.8 Magnesium 0.02 EPA 200.8 Thallium *0.0002 EPA 200.8 Aluminum 0.005 EPA 200.8 Lead 0.003 EPA 200.8 Potassium 0.02 EPA 200.8 Mercury 0.0002 EPA 245.1 Calcium 0.05 EPA 200.8 Chloride 0.1 EPA 300.0 Vanadium *0.0003 EPA 200.8 Sulfate 0.1 EPA 300.0 Chromium 0.005 EPA 200.8 Sodium 0.05 ASTM D6919-03 Manganese 0.005 EPA 200.8 Alkalinity 1 SM 2320 B Iron 0.02 EPA 200.8 Bicarbonate 1 SM 4500 CO2 D Cobalt *0.001 EPA 200.8 Carbonate 1 SM 4500 CO2 D Nickel 0.005 EPA 200.8 Turbidity 1.0 NTU SM 2130 B Copper 0.003 EPA 200.8 TDS 10 SM 2540 C Zinc 0.005 EPA 200.8 TSS 2.5 SM 2540 D Arsenic 0.005 EPA 200.8 Dissolved Oxygen SM 4500O G Selenium 0.005 EPA 200.8 pH 1.0 SU SM 4500-H+ Strontium 0.005 EPA 200.8 Temperature SM 2500 B Molybdenum 0.005 EPA 200.8 Conductivity 10µmhos/cm SM2510B Cadmium 0.002 EPA 200.8 *Detection Limit based on client request. elementOne 24269 Duke Report Packet Page 9 of 51 Element One Analytical Narrative Analysis QA/QC Duplicate analyses relative percent difference (RPD), sample spike recovery and second source calibration verification data are summarized in the Quality Control Section. All QA/QC data was within the criteria of the method. Additional Comments The reported results have not been corrected for any blank values or spike recovery values. The reported results relate only to the items tested or calibrated. elementOne 24269 Duke Report Packet Page 10 of 51 QUALITY CONTROL SUMMARY elementOne 24269 Duke Report Packet Page 11 of 51 Summary of Quality Control Data 200.8 Duplicate Analysis RPD (QC limits: <20% for RPD.) S12 Mastec Element RPD ----------------- --------------- Aluminum 1.0% Antimony NA Arsenic NA Barium 1.0% Beryllium NA Boron 5.1% Cadmium NA Calcium 3.9% Chromium NA Cobalt NA Copper NA Iron 1.8% Lead NA Magnesium 8.9% Manganese 9.8% Molybdenum NA Nickel NA Potassium 6.2% Selenium NA Strontium 8.7% Thallium NA Vanadium NA Zinc 16.1% elementOne 24269 Duke Report Packet Page 12 of 51 Summary of Quality Control Data Metals Second Source Calibration Check Recoveries (QC limits: ±10% for Second Source Continuing Check Standard*) Element 1 ppb 50 ppb 100 ppb* 250 ppb ----------------- ----------------- ----------------- ----------------- ----------------- Aluminum 108% 101% 99% 102% Antimony 96% 94% 94% 101% Arsenic 125% 105% 103% 107% Barium 96% 92% 94% 93% Beryllium 101% 99% 100% 99% Cadmium 107% 103% 104% 105% Chromium 89% 97% 94% 107% Cobalt 101% 95% 96% 107% Copper 102% 98% 96% 102% Lead 99% 96% 101% 103% Manganese 96% 96% 96% 106% Molybdenum 196% 93% 92% 100% Nickel 109% 102% 104% 106% Selenium 103% 105% 106% 108% Strontium 88% 94% 102% 104% Thallium 98% 92% 105% 104% Zinc 95% 106% 107% 110% Element 21 ppb 250 ppb 1100 ppb* 2500 ppb ----------------- ----------------- ----------------- ----------------- ----------------- Calcium ----- 100% 101% 103% Iron 85% 101% 96% 99% Magnesium 67% 93% 102% 105% Potassium 109% 98% 102% 102% Element 5 ppb 50 ppb 100 ppb* 250 ppb ----------------- ----------------- ----------------- ----------------- ----------------- Boron 81% 110% 99% 109% Element 0.3 ppb 1 ppb 10 ppb* 25 ppb ----------------- ----------------- ----------------- ----------------- ----------------- Vanadium 104% 101% 99% 101% elementOne 24269 Duke Report Packet Page 13 of 51 Summary of Quality Control Data Mercury 245.1 Duplicate Analysis RPD (QC limits: < 20% for RPD) Sample ID RPD ------------------------- ------------- S12 Mastec NA Mercury 245.1 Sample Spike Recovery (QC limits: 75-125% for Recovery) Sample ID Recovery ------------------------- ------------- S12 Mastec 80% 218.6 Sample Spike Recovery (QC limits: 90-110% for Recovery) S12 Mastec Element Recovery ----------------- --------------- Chromium (VI) 104% 300.0 Sample Duplicate Analysis RPD (QC limits: < 10% for RPD) S12 Mastec Element RPD ----------------- --------------- Chloride 0.1% Sulfate 2.9% Sodium ASTM D6919-03 Spike Recovery (QC limits: 90-110% for Recovery) Sample ID Recovery ------------------------- ------------- S12 Mastec 104% elementOne 24269 Duke Report Packet Page 14 of 51 SAMPLE CUSTODY elementOne 24269 Duke Report Packet Page 15 of 51 elementOne 24269 Duke Report Packet Page 16 of 51 ANALYTICAL DATA elementOne 24269 Duke Report Packet Page 17 of 51 Analytical Calculations Metals, Mercury- Metals (mg/L) = ICP Results (µg/L)*Dilution 1000 Where- ICP-Hg Results = Raw sample concentration (ppb)—ICP-Hg -Data Sheet Dilution= Diluted Volume--ICP-MS Run Sheet/ Hg Run Sheet Aliquot Chromium (VI)- Chromium (VI) (µg/L) = HPLC Results (µg/L)*Dilution Where- HPLC Results = Raw sample concentration (ppb)—HPLC -Data Sheet Dilution= Diluted Volume--HPLC Run Sheet Aliquot Anions- Anions (mg/L) = IC Results (mg/L)*Dilution Where- IC Results = Raw sample concentration (ppm)—IC-Data Sheet Dilution= Diluted Volume-- IC-Data Sheet Aliquot elementOne 24269 Duke Report Packet Page 18 of 51 Analytical Calculations Spike Recovery- Spike (%) = (Spiked Result (µg/L) – Sample Result (µg/L)) X100 Spike Amount (µg/L) Where- Spike Result = Raw sample concentration (ppb)--ICP-Data Sheet Sample Result = Raw sample concentration (ppb)--ICP-Data Sheet Spike Amount--ICP-MS Spike Table Duplicate Analysis RPD- RPD (%) = (Duplicate Result (µg/L) - Sample Result (µg/L)) X100 Average (µg/L) Where- Sample Result and Duplicate Results=Raw sample concentration (ppb)--ICP-Data Sheet Average= (Duplicate + Sample Results) 2 elementOne 24269 Duke Report Packet Page 19 of 51 elementOne 24269 Duke Report Packet Page 20 of 51 elementOne 24269 Duke Report Packet Page 21 of 51 elementOne 24269 Duke Report Packet Page 22 of 51 elementOne 24269 Duke Report Packet Page 23 of 51 elementOne 24269 Duke Report Packet Page 24 of 51 elementOne 24269 Duke Report Packet Page 25 of 51 elementOne 24269 Duke Report Packet Page 26 of 51 elementOne 24269 Duke Report Packet Page 27 of 51 elementOne 24269 Duke Report Packet Page 28 of 51 elementOne 24269 Duke Report Packet Page 29 of 51 elementOne 24269 Duke Report Packet Page 30 of 51 elementOne 24269 Duke Report Packet Page 31 of 51 elementOne 24269 Duke Report Packet Page 32 of 51 elementOne 24269 Duke Report Packet Page 33 of 51 elementOne 24269 Duke Report Packet Page 34 of 51 elementOne 24269 Duke Report Packet Page 35 of 51 elementOne 24269 Duke Report Packet Page 36 of 51 elementOne 24269 Duke Report Packet Page 37 of 51 elementOne 24269 Duke Report Packet Page 38 of 51 elementOne 24269 Duke Report Packet Page 39 of 51 elementOne 24269 Duke Report Packet Page 40 of 51 elementOne 24269 Duke Report Packet Page 41 of 51 elementOne 24269 Duke Report Packet Page 42 of 51 elementOne 24269 Duke Report Packet Page 43 of 51 elementOne 24269 Duke Report Packet Page 44 of 51 elementOne 24269 Duke Report Packet Page 45 of 51 elementOne 24269 Duke Report Packet Page 46 of 51 elementOne 24269 Duke Report Packet Page 47 of 51 elementOne 24269 Duke Report Packet Page 48 of 51 elementOne 24269 Duke Report Packet Page 49 of 51 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: Blank Sample DatThursday, March 19, 2015 12:31:35 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 62460.4 ppb | Be 9 1 ppb | B 10 218.7 ppb |- B 11 952.1 ppb |- Na 23 72845.9 ppb | Mg 24 25621.7 ppb | Mg 25 3621.7 ppb | Al 27 817.7 ppb | P 31 2306 ppb | K 39 292014.9 ppb | Ca 44 24375 ppb | Sc 45 235530.9 ppb | Cr 52 11300.4 ppb | Cr 53 44013 ppb | Fe 54 33780.3 ppb | Mn 55 1114.4 ppb | Fe 57 5667.1 ppb | Co 59 53 ppb | Ni 60 47 ppb | Cu 63 901.4 ppb | Cu 65 455.7 ppb | Zn 66 1448.1 ppb | Zn 67 4184.3 ppb | Zn 68 2471.3 ppb | As 75 -1599.7 ppb | Se 77 5079.8 ppb | Se 82 6 ppb | Sr 88 4915.7 ppb | Mo 95 193 ppb | Mo 97 133 ppb | Mo 98 329 ppb |> Rh 103 632245.7 ppb | Ag 107 229.7 ppb | Ag 109 234 ppb | Cd 111 7.2 ppb |- Cd 114 18 ppb |- Sb 121 198 ppb | Sb 123 150.5 ppb | Ba 135 66 ppb | Ba 137 110.3 ppb |> Ho 165 1118820.4 ppb | Tl 205 161 ppb | Pb 206 136 ppb | Pb 207 124.7 ppb |- Pb 208 555 ppb Kr 83 8.7 ppb ICP-Data 1 of 30 elementOne e 24269-Metals 50.1 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 1 Sample DatThursday, March 19, 2015 12:35:03 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 57297.9 ppb | Be 9 345.3 1 ppb | B 10 642.7 5 ppb |- B 11 2863.8 5 ppb |- Na 23 140839.1 21 ppb | Mg 24 71004.3 21 ppb | Mg 25 10058.9 21 ppb | Al 27 5821.5 1 ppb | P 31 8299.5 20 ppb | K 39 483544.9 21 ppb | Ca 44 25522.8 21 ppb | Sc 45 225430.2 ppb | Cr 52 19276.4 1 ppb | Cr 53 45440.3 1 ppb | Fe 54 46243.3 21 ppb | Mn 55 15548.6 1 ppb | Fe 57 11411.5 21 ppb | Co 59 11610.4 1 ppb | Ni 60 2526.7 1 ppb | Cu 63 6450 1 ppb | Cu 65 3207.6 1 ppb | Zn 66 2738.1 1 ppb | Zn 67 4430.7 1 ppb | Zn 68 3345.6 1 ppb | As 75 902.9 1 ppb | Se 77 4843.3 1 ppb | Se 82 243 1 ppb | Sr 88 32263.5 1 ppb | Mo 95 4611.8 1 ppb | Mo 97 2908.1 1 ppb | Mo 98 7501.3 1 ppb |> Rh 103 606929.8 ppb | Ag 107 13250.7 1 ppb | Ag 109 12587.7 1 ppb | Cd 111 3099.8 1 ppb |- Cd 114 7513.9 1 ppb |- Sb 121 10662.3 1 ppb | Sb 123 8213 1 ppb | Ba 135 3147.2 1 ppb | Ba 137 5478.7 1 ppb |> Ho 165 1085649.2 ppb | Tl 205 32114.3 1 ppb | Pb 206 10817.8 1 ppb | Pb 207 9546.7 1 ppb |- Pb 208 43353.8 1 ppb Kr 83 -177.1 ppb ICP-Data 2 of 30 elementOne e 24269-Metals 50.2 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 2 Sample DatThursday, March 19, 2015 12:38:31 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 52082 ppb | Be 9 30732.2 99.99982 ppb | B 10 7951.8 99.99152 ppb |- B 11 36600.2 99.99738 ppb |- Na 23 5394929 1100.141 ppb | Mg 24 3402902.2 1100.132 ppb | Mg 25 463597.5 1100.121 ppb | Al 27 456241.6 99.9997 ppb | P 31 296481.6 1000.015 ppb | K 39 9254382.5 1099.959 ppb | Ca 44 313173.9 1100.258 ppb | Sc 45 209618 ppb | Cr 52 816250 100.0003 ppb | Cr 53 139342.5 99.98016 ppb | Fe 54 786283.9 1100.043 ppb | Mn 55 1360783.7 100.0001 ppb | Fe 57 307219 1100.014 ppb | Co 59 1059413.1 99.99983 ppb | Ni 60 226161.3 99.99977 ppb | Cu 63 526661.7 100.0001 ppb | Cu 65 262448 100.0002 ppb | Zn 66 159847 100.0021 ppb | Zn 67 30775.3 99.99569 ppb | Zn 68 121841.1 100.0024 ppb | As 75 198439.4 99.99866 ppb | Se 77 20673.8 100.0119 ppb | Se 82 22373.9 100.0001 ppb | Sr 88 3145854.6 100.0018 ppb | Mo 95 422659.9 100.0002 ppb | Mo 97 266372.4 100.0003 ppb | Mo 98 687216.4 100.0003 ppb |> Rh 103 565568.7 ppb | Ag 107 1208468.5 99.99995 ppb | Ag 109 1173366.5 100.0002 ppb | Cd 111 290084.9 100.0001 ppb |- Cd 114 680412.7 99.99973 ppb |- Sb 121 996795.8 100 ppb | Sb 123 759373.7 99.99993 ppb | Ba 135 289753 99.99991 ppb | Ba 137 504878 99.99991 ppb |> Ho 165 1029287.6 ppb | Tl 205 3233469 100.0006 ppb | Pb 206 1007023.9 99.99994 ppb | Pb 207 882359 99.99987 ppb |- Pb 208 4160203.6 100.0002 ppb Kr 83 -21282 ppb ICP-Data 3 of 30 elementOne e 24269-Metals 50.3 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 3 Sample DatThursday, March 19, 2015 12:41:59 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 49153.8 ppb | Be 9 144960.1 499.9927 ppb | B 10 35420.2 499.2258 ppb |- B 11 163163.2 499.2241 ppb |- Na 23 25492803 5500.881 ppb | Mg 24 15878524 5497.281 ppb | Mg 25 2283113.7 5508.613 ppb | Al 27 2233946.8 500.5927 ppb | P 31 1350148.9 4992.745 ppb | K 39 43252263 5501.307 ppb | Ca 44 1407487.8 5500.343 ppb | Sc 45 201892.9 ppb | Cr 52 4055417 501.0242 ppb | Cr 53 487858.2 498.9462 ppb | Fe 54 3791032.4 5509.566 ppb | Mn 55 6820734.3 501.0119 ppb | Fe 57 1423581.2 5497.433 ppb | Co 59 5350864.5 501.1402 ppb | Ni 60 1048722.8 499.5261 ppb | Cu 63 2634279.8 500.9861 ppb | Cu 65 1213737.4 499.4959 ppb | Zn 66 715016.1 498.9365 ppb | Zn 67 124467 498.8026 ppb | Zn 68 545881.1 499.1302 ppb | As 75 933212.5 499.6879 ppb | Se 77 80640.5 499.9207 ppb | Se 82 104679.1 499.7002 ppb | Sr 88 15149862 500.2757 ppb | Mo 95 2151696.1 501.2842 ppb | Mo 97 1284186.8 500.2817 ppb | Mo 98 3564468.7 501.6244 ppb |> Rh 103 537487.3 ppb | Ag 107 5531628.5 499.2625 ppb | Ag 109 5299545.5 498.9935 ppb | Cd 111 1338511.4 499.4259 ppb |- Cd 114 3472954.5 501.3316 ppb |- Sb 121 5237863.6 501.3143 ppb | Sb 123 3976411.2 501.2495 ppb | Ba 135 1404857.9 499.8064 ppb | Ba 137 2643617.6 501.2472 ppb |> Ho 165 1008193.8 ppb | Tl 205 15597736 499.7061 ppb | Pb 206 5181371 500.9282 ppb | Pb 207 4510352.1 500.8071 ppb |- Pb 208 20547463 500.1623 ppb Kr 83 -102657.2 ppb ICP-Data 4 of 30 elementOne e 24269-Metals 50.4 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatThursday, March 19, 2015 12:45:27 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 49911.8 ppb | Be 9 3.3 0.00886 ppb | B 10 812.7 8.93288 ppb |- B 11 3735.8 9.0431 ppb |- Na 23 35535.7 -5.5783 ppb | Mg 24 21147.6 -0.15133 ppb | Mg 25 3019.5 -0.07346 ppb | Al 27 757.4 0.01596 ppb | P 31 2002.9 0.2313 ppb | K 39 303738.5 7.48669 ppb | Ca 44 25715 20.82873 ppb | Sc 45 191757.1 ppb | Cr 52 8171 -0.16801 ppb | Cr 53 42404.7 5.98123 ppb | Fe 54 25989.1 -3.64434 ppb | Mn 55 1176.7 0.01785 ppb | Fe 57 4586.8 -0.72711 ppb | Co 59 172.7 0.01229 ppb | Ni 60 74.7 0.01712 ppb | Cu 63 1121.1 0.06994 ppb | Cu 65 578.7 0.08127 ppb | Zn 66 1176.4 -0.03051 ppb | Zn 67 4154.6 2.62641 ppb | Zn 68 2095.2 0.01294 ppb | As 75 -1001.1 0.18934 ppb | Se 77 3775.5 -3.33002 ppb | Se 82 25.6 0.09985 ppb | Sr 88 4491.8 0.01188 ppb | Mo 95 1696.8 0.3616 ppb | Mo 97 1062.4 0.37428 ppb | Mo 98 2722.1 0.34796 ppb |> Rh 103 532499.9 ppb | Ag 107 173134.1 15.72593 ppb | Ag 109 164474.9 15.58439 ppb | Cd 111 54.4 0.0184 ppb |- Cd 114 135.4 0.01771 ppb |- Sb 121 312.7 0.01441 ppb | Sb 123 223.7 0.01253 ppb | Ba 135 88.7 0.012 ppb | Ba 137 152.3 0.01156 ppb |> Ho 165 963864.1 ppb | Tl 205 815.7 0.02281 ppb | Pb 206 331.7 0.02188 ppb | Pb 207 293.7 0.02181 ppb |- Pb 208 1279 0.02056 ppb Kr 83 13.9 ppb ICP-Data 5 of 30 elementOne e 24269-Metals 50.5 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 2 Sample DatThursday, March 19, 2015 12:48:55 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 58908.9 ppb | Be 9 351.7 1.00661 ppb | B 10 1160.4 11.27721 ppb |- B 11 5383.6 11.52303 ppb |- Na 23 130953.1 12.03866 ppb | Mg 24 68393.9 13.66879 ppb | Mg 25 9802 13.75155 ppb | Al 27 6001.3 1.04775 ppb | P 31 8343.5 20.38179 ppb | K 39 477676.2 22.94663 ppb | Ca 44 23781.1 2.29287 ppb | Sc 45 225769.7 ppb | Cr 52 18397.3 0.84813 ppb | Cr 53 40944.7 -0.83295 ppb | Fe 54 45611.3 17.7194 ppb | Mn 55 15661.2 0.9599 ppb | Fe 57 11372.1 20.76249 ppb | Co 59 12107.4 1.01027 ppb | Ni 60 2611.4 1.09374 ppb | Cu 63 6823.2 1.01561 ppb | Cu 65 3382 1.08616 ppb | Zn 66 2888.5 0.94596 ppb | Zn 67 4225.3 0.93809 ppb | Zn 68 3475.7 0.92677 ppb | As 75 1172.1 1.29104 ppb | Se 77 4350.4 -2.78488 ppb | Se 82 267.3 1.1174 ppb | Sr 88 34542.2 0.88295 ppb | Mo 95 9848 2.01566 ppb | Mo 97 6154.1 2.10178 ppb | Mo 98 15971.9 1.97232 ppb |> Rh 103 600520.3 ppb | Ag 107 32757.4 2.62532 ppb | Ag 109 31877.2 2.66493 ppb | Cd 111 3208.1 1.06927 ppb |- Cd 114 7525.1 0.97032 ppb |- Sb 121 11097.8 0.96546 ppb | Sb 123 8371.9 0.95932 ppb | Ba 135 3212.2 1.03594 ppb | Ba 137 5586.4 0.9608 ppb |> Ho 165 1090441 ppb | Tl 205 33313.3 0.98241 ppb | Pb 206 11200.9 0.99019 ppb | Pb 207 9716.5 0.98553 ppb |- Pb 208 44343.9 0.98624 ppb Kr 83 -192.6 ppb ICP-Data 6 of 30 elementOne e 24269-Metals 50.6 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 3 Sample DatThursday, March 19, 2015 12:52:23 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 62324.4 ppb | Be 9 90583.7 246.4558 ppb | B 10 25320.9 280.3701 ppb |- B 11 117131.2 281.6378 ppb |- Na 23 13719109 2564.878 ppb | Mg 24 8737043.7 2623.724 ppb | Mg 25 1159352.7 2426.185 ppb | Al 27 1282962.9 249.6558 ppb | P 31 804857.4 2581.644 ppb | K 39 23172754 2543.808 ppb | Ca 44 771265.6 2575.648 ppb | Sc 45 236064.7 ppb | Cr 52 2496835.5 267.4794 ppb | Cr 53 307908.9 254.8923 ppb | Fe 54 1977078.5 2473.602 ppb | Mn 55 4150027.2 264.8831 ppb | Fe 57 795022.3 2658.285 ppb | Co 59 3279567.3 266.8989 ppb | Ni 60 641198.6 265.302 ppb | Cu 63 1545780.5 255.2887 ppb | Cu 65 769121.5 274.8792 ppb | Zn 66 453697.6 274.6279 ppb | Zn 67 81016.6 275.6782 ppb | Zn 68 346235.5 274.1563 ppb | As 75 572288.6 266.5757 ppb | Se 77 52700 271.6485 ppb | Se 82 65005.4 269.6026 ppb | Sr 88 9072405 260.2472 ppb | Mo 95 2589365.1 524.3536 ppb | Mo 97 1479022 500.5908 ppb | Mo 98 4093659.8 500.5242 ppb |> Rh 103 618677.2 ppb | Ag 107 3710330.1 290.8945 ppb | Ag 109 3539695.9 289.4771 ppb | Cd 111 809007.8 262.2692 ppb |- Cd 114 1942235.3 243.5157 ppb |- Sb 121 3002697.8 252.8169 ppb | Sb 123 2266774.2 251.3609 ppb | Ba 135 807709.8 252.7197 ppb | Ba 137 1399416 233.355 ppb |> Ho 165 1146276.5 ppb | Tl 205 9196844.2 259.2008 ppb | Pb 206 3030128.9 257.7042 ppb | Pb 207 2636841.6 257.599 ppb |- Pb 208 12030284 257.6192 ppb Kr 83 -61462 ppb ICP-Data 7 of 30 elementOne e 24269-Metals 50.7 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatThursday, March 19, 2015 12:55:52 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 56378.5 ppb | Be 9 33161.4 99.71258 ppb | B 10 9729.9 117.6968 ppb |- B 11 44104.4 115.8867 ppb |- Na 23 5675068.4 1111.314 ppb | Mg 24 3571160.7 1126.692 ppb | Mg 25 480034.1 1055.005 ppb | Al 27 478929.4 98.18719 ppb | P 31 308967.1 1040.857 ppb | K 39 9861436.6 1123.719 ppb | Ca 44 326977.8 1105.835 ppb | Sc 45 217401.8 ppb | Cr 52 842359 94.37231 ppb | Cr 53 138800.9 99.40913 ppb | Fe 54 817315.6 1054.547 ppb | Mn 55 1421239.5 95.58175 ppb | Fe 57 328556 1147.829 ppb | Co 59 1117476.4 95.85688 ppb | Ni 60 237718.3 103.7087 ppb | Cu 63 553610.3 96.32507 ppb | Cu 65 274385.4 103.3101 ppb | Zn 66 167944.7 106.6725 ppb | Zn 67 32068.1 106.5194 ppb | Zn 68 128842.4 106.4158 ppb | As 75 208903.5 103.0582 ppb | Se 77 21903 103.1165 ppb | Se 82 24191.9 105.7794 ppb | Sr 88 3358019.4 101.4681 ppb | Mo 95 441228.2 94.15351 ppb | Mo 97 277110.7 98.86314 ppb | Mo 98 714410.1 92.05903 ppb |> Rh 103 586798.4 ppb | Ag 107 1289488.3 106.6288 ppb | Ag 109 1253894 108.1824 ppb | Cd 111 302677.7 103.4512 ppb |- Cd 114 713602 94.35687 ppb |- Sb 121 1023275.3 93.05505 ppb | Sb 123 780790.8 93.52128 ppb | Ba 135 300465.1 101.5714 ppb | Ba 137 521806.3 94.00411 ppb |> Ho 165 1060878.3 ppb | Tl 205 3461786.6 105.3963 ppb | Pb 206 1050642.7 96.52623 ppb | Pb 207 909441.9 95.96344 ppb |- Pb 208 4384136.9 101.417 ppb Kr 83 -22725.7 ppb ICP-Data 8 of 30 elementOne e 24269-Metals 50.8 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 5 Sample DatThursday, March 19, 2015 12:59:20 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 54769.6 ppb | Be 9 15955.7 49.38884 ppb | B 10 5237.8 64.13752 ppb |- B 11 23661.4 62.96628 ppb |- Na 23 1132811.7 219.6366 ppb | Mg 24 730427.7 233.2634 ppb | Mg 25 103525.5 230.4187 ppb | Al 27 231263.8 49.14196 ppb | P 31 58658.7 199.3248 ppb | K 39 1871211.8 195.877 ppb | Ca 44 87855.5 249.2134 ppb | Sc 45 211683.5 ppb | Cr 52 420112.9 48.28795 ppb | Cr 53 89006 52.31545 ppb | Fe 54 210969.9 251.7581 ppb | Mn 55 690652.9 48.18486 ppb | Fe 57 74745 256.7951 ppb | Co 59 531213.3 47.3123 ppb | Ni 60 112391.9 50.89756 ppb | Cu 63 270932.5 48.87029 ppb | Cu 65 135634.8 52.94015 ppb | Zn 66 81210.8 53.12415 ppb | Zn 67 17393 53.56216 ppb | Zn 68 62071.9 52.2545 ppb | As 75 101337 52.25698 ppb | Se 77 12182.8 47.60673 ppb | Se 82 11594.4 52.62214 ppb | Sr 88 1495129.8 46.83017 ppb | Mo 95 213622.1 47.30855 ppb | Mo 97 134961.9 49.96083 ppb | Mo 98 346679.5 46.35996 ppb |> Rh 103 565174.3 ppb | Ag 107 623828 53.54805 ppb | Ag 109 599271.2 53.66642 ppb | Cd 111 145695.3 51.70101 ppb |- Cd 114 342434.1 47.00836 ppb |- Sb 121 501500.5 46.68664 ppb | Sb 123 382849.3 46.94142 ppb | Ba 135 144511.3 50.00552 ppb | Ba 137 250343.1 46.16569 ppb |> Ho 165 1036161.2 ppb | Tl 205 1468066.7 45.7572 ppb | Pb 206 511130.5 48.07222 ppb | Pb 207 445495.8 48.12498 ppb |- Pb 208 2033960.7 48.16666 ppb Kr 83 -10090.5 ppb ICP-Data 9 of 30 elementOne e 24269-Metals 50.9 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 9 Sample DatThursday, March 19, 2015 13:02:49 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 51951.5 ppb | Be 9 5.7 0.01591 ppb | B 10 636 6.09043 ppb |- B 11 3020.8 6.48132 ppb |- Na 23 60960 0.29167 ppb | Mg 24 3988.5 -6.11338 ppb | Mg 25 584 -5.97146 ppb | Al 27 8111.3 1.73462 ppb | P 31 2355.3 1.80855 ppb | K 39 308268.2 9.24256 ppb | Ca 44 23392.7 14.28925 ppb | Sc 45 190395.4 ppb | Cr 52 12226.6 0.38497 ppb | Cr 53 86146.8 57.8263 ppb | Fe 54 34528.5 10.52195 ppb | Mn 55 1054.1 0.01092 ppb | Fe 57 4783.6 0.60252 ppb | Co 59 66 0.0022 ppb | Ni 60 60 0.01066 ppb | Cu 63 1119.4 0.07561 ppb | Cu 65 550.7 0.07621 ppb | Zn 66 4849 2.66353 ppb | Zn 67 10135.4 28.83057 ppb | Zn 68 5101.8 2.9403 ppb | As 75 -2437.4 -0.63033 ppb | Se 77 9139.9 33.9697 ppb | Se 82 12.6 0.03782 ppb | Sr 88 622.7 -0.11667 ppb | Mo 95 636.7 0.11604 ppb | Mo 97 412.7 0.12313 ppb | Mo 98 1075 0.11794 ppb |> Rh 103 516995.7 ppb | Ag 107 14537 1.34589 ppb | Ag 109 13827.2 1.33441 ppb | Cd 111 20.4 0.00558 ppb |- Cd 114 51.9 0.00556 ppb |- Sb 121 1559.8 0.14313 ppb | Sb 123 1159.3 0.13971 ppb | Ba 135 86.3 0.0118 ppb | Ba 137 131.3 0.00788 ppb |> Ho 165 939274.3 ppb | Tl 205 237.3 0.00351 ppb | Pb 206 275 0.01669 ppb | Pb 207 246.3 0.01689 ppb |- Pb 208 1113 0.01691 ppb Kr 83 43.1 ppb ICP-Data 10 of 30 elementOne e 24269-Metals 50.10 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 10 Sample DatThursday, March 19, 2015 13:06:17 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 49824.9 ppb | Be 9 14801.4 50.36258 ppb | B 10 4298 57.61146 ppb |- B 11 19531.3 56.92869 ppb |- Na 23 2434191.1 536.6048 ppb | Mg 24 1427406.2 509.3373 ppb | Mg 25 203406.7 505.8591 ppb | Al 27 203826.7 47.56628 ppb | P 31 123306.8 469.7264 ppb | K 39 4014216.6 504.6177 ppb | Ca 44 155897.7 563.7343 ppb | Sc 45 187696.6 ppb | Cr 52 379738.8 47.93087 ppb | Cr 53 138950 119.3163 ppb | Fe 54 379930.6 539.0933 ppb | Mn 55 620993.7 47.58529 ppb | Fe 57 143587.5 562.5605 ppb | Co 59 493272.4 48.25454 ppb | Ni 60 105441.3 52.44728 ppb | Cu 63 249470.3 49.4286 ppb | Cu 65 124968.9 53.57981 ppb | Zn 66 74822.7 53.77231 ppb | Zn 67 23203.2 85.31105 ppb | Zn 68 57754.9 53.44699 ppb | As 75 89239.2 50.56894 ppb | Se 77 16658.9 85.69725 ppb | Se 82 9846.9 49.08412 ppb | Sr 88 1379074.1 47.44543 ppb | Mo 95 199835.6 48.6101 ppb | Mo 97 126385.8 51.39014 ppb | Mo 98 323890.4 47.57395 ppb |> Rh 103 514552.3 ppb | Ag 107 558390.9 52.6465 ppb | Ag 109 540841.7 53.19794 ppb | Cd 111 128666 50.14768 ppb |- Cd 114 303460.5 45.75605 ppb |- Sb 121 463191.5 47.53556 ppb | Sb 123 354418 47.90674 ppb | Ba 135 132526.7 50.55517 ppb | Ba 137 231988.5 47.16777 ppb |> Ho 165 940077.5 ppb | Tl 205 1375515.8 47.267 ppb | Pb 206 476190.3 49.36942 ppb | Pb 207 412366 49.10682 ppb |- Pb 208 1895109.8 49.47314 ppb Kr 83 -9291.2 ppb ICP-Data 11 of 30 elementOne e 24269-Metals 50.11 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC STD2 Sample DatThursday, March 19, 2015 13:09:46 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 57236.1 ppb | Be 9 324.7 0.95749 ppb | B 10 979.7 9.4843 ppb |- B 11 4369.4 9.23524 ppb |- Na 23 121003.5 10.96005 ppb | Mg 24 65040.1 13.38095 ppb | Mg 25 9331.1 13.48946 ppb | Al 27 5711.1 1.03221 ppb | P 31 7945.8 20.06453 ppb | K 39 462821.5 23.22876 ppb | Ca 44 23781.1 5.45201 ppb | Sc 45 215924 ppb | Cr 52 18099.3 0.89154 ppb | Cr 53 48690.2 8.71874 ppb | Fe 54 43487.6 17.06543 ppb | Mn 55 14927.9 0.9484 ppb | Fe 57 10996 20.89663 ppb | Co 59 11322.4 0.98052 ppb | Ni 60 2515.3 1.09407 ppb | Cu 63 6300.9 0.96739 ppb | Cu 65 3189.9 1.05944 ppb | Zn 66 2743.1 0.9194 ppb | Zn 67 5281.5 5.5926 ppb | Zn 68 3373.3 0.94679 ppb | As 75 1061.9 1.25295 ppb | Se 77 4457.1 -1.16425 ppb | Se 82 237 1.02638 ppb | Sr 88 33053.7 0.87585 ppb | Mo 95 9401.9 1.99593 ppb | Mo 97 6012 2.13005 ppb | Mo 98 15275.4 1.956 ppb |> Rh 103 578820.6 ppb | Ag 107 13667.6 1.12828 ppb | Ag 109 13323.4 1.14658 ppb | Cd 111 3053.9 1.05554 ppb |- Cd 114 7219.3 0.96551 ppb |- Sb 121 10709.6 0.96342 ppb | Sb 123 8131.1 0.96363 ppb | Ba 135 3093.9 1.03187 ppb | Ba 137 5364.9 0.95445 ppb |> Ho 165 1054327.5 ppb | Tl 205 32354.2 0.98681 ppb | Pb 206 10787.4 0.98547 ppb | Pb 207 9317.4 0.97698 ppb |- Pb 208 42742.7 0.98293 ppb Kr 83 -180.8 ppb ICP-Data 12 of 30 elementOne e 24269-Metals 50.12 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatThursday, March 19, 2015 13:44:27 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 51541.8 ppb | Be 9 1 0.00058 ppb | B 10 241 0.81885 ppb |- B 11 1149.4 1.0672 ppb |- Na 23 54516.6 -2.34035 ppb | Mg 24 22923.5 -0.07865 ppb | Mg 25 3179.6 -0.21592 ppb | Al 27 739.4 0.00003 ppb | P 31 1951.5 -0.46077 ppb | K 39 302771.8 4.66733 ppb | Ca 44 27789.8 21.4576 ppb | Sc 45 209061.2 ppb | Cr 52 12865.1 0.30842 ppb | Cr 53 63143 24.32024 ppb | Fe 54 30856 0.43062 ppb | Mn 55 1151.4 0.00994 ppb | Fe 57 4827.9 -1.07312 ppb | Co 59 63 0.00136 ppb | Ni 60 51.3 0.00396 ppb | Cu 63 873 0.01033 ppb | Cu 65 413.7 0.00071 ppb | Zn 66 1354.8 0.03019 ppb | Zn 67 5700.5 7.43146 ppb | Zn 68 2307.6 0.06329 ppb | As 75 -1463.1 -0.00921 ppb | Se 77 7166.8 15.87288 ppb | Se 82 -6.1 -0.05183 ppb | Sr 88 4489.1 0.00137 ppb | Mo 95 104.7 -0.01526 ppb | Mo 97 72 -0.01759 ppb | Mo 98 141.4 -0.02064 ppb |> Rh 103 571637.9 ppb | Ag 107 256 0.0041 ppb | Ag 109 231.7 0.00177 ppb | Cd 111 12.8 0.00219 ppb |- Cd 114 23.6 0.00099 ppb |- Sb 121 175.3 -0.00067 ppb | Sb 123 118.3 -0.00249 ppb | Ba 135 56.3 -0.00156 ppb | Ba 137 97.7 -0.00077 ppb |> Ho 165 1030432.8 ppb | Tl 205 105.7 -0.00134 ppb | Pb 206 106 -0.00182 ppb | Pb 207 100 -0.00161 ppb |- Pb 208 414.3 -0.00231 ppb Kr 83 17.2 ppb ICP-Data 13 of 30 elementOne e 24269-Metals 50.13 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatThursday, March 19, 2015 13:47:55 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 49031.6 ppb | Be 9 28804.6 99.59203 ppb | B 10 7597.5 105.4299 ppb |- B 11 34567.6 104.2048 ppb |- Na 23 5235651 1084.131 ppb | Mg 24 3296392.5 1099.866 ppb | Mg 25 435416.7 1011.944 ppb | Al 27 427384.1 92.67894 ppb | P 31 278292.5 991.4566 ppb | K 39 9161207.7 1103.905 ppb | Ca 44 305137.5 1090.6 ppb | Sc 45 202263.5 ppb | Cr 52 789261.6 93.52407 ppb | Cr 53 147692.9 117.0805 ppb | Fe 54 759359.6 1035.494 ppb | Mn 55 1317141.6 93.69586 ppb | Fe 57 300673 1110.44 ppb | Co 59 1027739.1 93.27257 ppb | Ni 60 218385.9 100.7902 ppb | Cu 63 507239.9 93.36177 ppb | Cu 65 250585.9 99.80523 ppb | Zn 66 150990.7 101.4122 ppb | Zn 67 30296.7 106.4301 ppb | Zn 68 116373.3 101.5732 ppb | As 75 192648 100.5465 ppb | Se 77 22060.4 111.7217 ppb | Se 82 21539.8 99.63606 ppb | Sr 88 3151471.3 100.7432 ppb | Mo 95 414307 93.52516 ppb | Mo 97 258261.6 97.46947 ppb | Mo 98 674065.8 91.89239 ppb |> Rh 103 554661.5 ppb | Ag 107 1168522.8 102.2266 ppb | Ag 109 1125137.3 102.6866 ppb | Cd 111 279964.7 101.2261 ppb |- Cd 114 658612.9 92.11983 ppb |- Sb 121 979790.7 94.64535 ppb | Sb 123 749820.7 95.39577 ppb | Ba 135 285521.6 102.518 ppb | Ba 137 491640.2 94.07601 ppb |> Ho 165 998754.1 ppb | Tl 205 3214552.8 103.9571 ppb | Pb 206 980003 95.62951 ppb | Pb 207 853596.3 95.67313 ppb |- Pb 208 4124502.7 101.3425 ppb Kr 83 -21314.1 ppb ICP-Data 14 of 30 elementOne e 24269-Metals 50.14 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: 24269-1.1 Sample DatThursday, March 19, 2015 14:12:12 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 50417.5 ppb | Be 9 23 0.07715 ppb | B 10 3606.7 47.30403 ppb |- B 11 16466.8 47.02678 ppb |- Na 23 12216641 2771.306 ppb | Mg 24 4947777.1 1799.791 ppb | Mg 25 651441.9 1648.356 ppb | Al 27 440930.2 103.976 ppb | P 31 3236.6 5.53786 ppb | K 39 9130594.5 1198.122 ppb | Ca 44 6774646.1 28157.99 ppb | Sc 45 194225.1 ppb | Cr 52 31586.6 2.9235 ppb | Cr 53 148795.7 130.8642 ppb | Fe 54 194487.3 258.4984 ppb | Mn 55 853059.7 66.00068 ppb | Fe 57 74851 287.5475 ppb | Co 59 3158.9 0.3077 ppb | Ni 60 1525.8 0.74993 ppb | Cu 63 3306.6 0.51682 ppb | Cu 65 1611.8 0.54084 ppb | Zn 66 15305.4 10.42302 ppb | Zn 67 13956 45.61138 ppb | Zn 68 14796.5 12.42238 ppb | As 75 -3931.5 -1.57722 ppb | Se 77 24449.3 139.3835 ppb | Se 82 24.4 0.0958 ppb | Sr 88 2015697.1 69.76909 ppb | Mo 95 231.7 0.01895 ppb | Mo 97 146 0.01676 ppb | Mo 98 336.8 0.01079 ppb |> Rh 103 507027.5 ppb | Ag 107 176.3 -0.00025 ppb | Ag 109 131 -0.00538 ppb | Cd 111 242.3 0.09292 ppb |- Cd 114 318 0.04658 ppb |- Sb 121 395.3 0.02327 ppb | Sb 123 324.8 0.02635 ppb | Ba 135 152054.2 57.27796 ppb | Ba 137 263480.5 52.98128 ppb |> Ho 165 950761.6 ppb | Tl 205 789 0.02224 ppb | Pb 206 1184.7 0.11018 ppb | Pb 207 1011.1 0.10649 ppb |- Pb 208 4662.8 0.10828 ppb Kr 83 -13602.1 ppb ICP-Data 15 of 30 elementOne e 24269-Metals 50.15 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: 24269-1.1 Sample DatThursday, March 19, 2015 14:15:40 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 62447.8 ppb | Be 9 30.3 0.07984 ppb | B 10 4423.4 46.86268 ppb |- B 11 20257.6 46.69851 ppb |- Na 23 14906078 3033.136 ppb | Mg 24 6027418.9 1966.886 ppb | Mg 25 795508.7 1808.75 ppb | Al 27 551607.3 116.6894 ppb | P 31 2257.9 0.63794 ppb | K 39 10806343 1274.205 ppb | Ca 44 8125803.3 30371.53 ppb | Sc 45 225981.9 ppb | Cr 52 31145.4 2.45105 ppb | Cr 53 153435.8 119.0093 ppb | Fe 54 213950.6 253.9833 ppb | Mn 55 1049914.5 72.80735 ppb | Fe 57 89852.7 310.309 ppb | Co 59 3784.5 0.33064 ppb | Ni 60 1660.5 0.72853 ppb | Cu 63 3166.2 0.42351 ppb | Cu 65 1673.5 0.49149 ppb | Zn 66 9333.1 5.30447 ppb | Zn 67 14936.9 43.60353 ppb | Zn 68 10744.3 7.39065 ppb | As 75 -4123.5 -1.34743 ppb | Se 77 25474.6 129.1216 ppb | Se 82 27.4 0.09796 ppb | Sr 88 2443900.6 76.12123 ppb | Mo 95 187 0.00302 ppb | Mo 97 123 0.00122 ppb | Mo 98 271.2 -0.00331 ppb |> Rh 103 568949.3 ppb | Ag 107 127.7 -0.00672 ppb | Ag 109 105.3 -0.00936 ppb | Cd 111 163.3 0.05515 ppb |- Cd 114 351.5 0.04572 ppb |- Sb 121 342 0.01295 ppb | Sb 123 304.5 0.01816 ppb | Ba 135 177151.1 57.81728 ppb | Ba 137 307705.6 53.52808 ppb |> Ho 165 1098588.4 ppb | Tl 205 663.4 0.01484 ppb | Pb 206 1164.7 0.09151 ppb | Pb 207 982.7 0.08768 ppb |- Pb 208 4554.4 0.08959 ppb Kr 83 -16503.8 ppb ICP-Data 16 of 30 elementOne e 24269-Metals 50.16 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: 24269-1.1 Sample DatThursday, March 19, 2015 14:19:08 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 60021.6 ppb | Be 9 2 0.00294 ppb | B 10 643 5.02027 ppb |- B 11 2848.8 4.86864 ppb |- Na 23 325791.5 56.58351 ppb | Mg 24 109340.7 30.09119 ppb | Mg 25 15591.4 29.96851 ppb | Al 27 11660.8 2.44029 ppb | P 31 1767.8 -0.75772 ppb | K 39 491433 30.67543 ppb | Ca 44 160201.1 548.8324 ppb | Sc 45 194957.3 ppb | Cr 52 14076.6 0.54135 ppb | Cr 53 69685.6 35.20114 ppb | Fe 54 33539.8 6.72077 ppb | Mn 55 19790.2 1.37425 ppb | Fe 57 6297.8 5.56677 ppb | Co 59 114.3 0.00641 ppb | Ni 60 86.3 0.02181 ppb | Cu 63 558.7 -0.04023 ppb | Cu 65 268.3 -0.0498 ppb | Zn 66 11389.8 7.04576 ppb | Zn 67 7123.5 14.50692 ppb | Zn 68 9837.7 7.03827 ppb | As 75 -1436 -0.03341 ppb | Se 77 9419.2 32.98736 ppb | Se 82 8 0.01373 ppb | Sr 88 42020.2 1.24033 ppb | Mo 95 53 -0.02597 ppb | Mo 97 39.7 -0.02869 ppb | Mo 98 89.6 -0.02683 ppb |> Rh 103 541224.8 ppb | Ag 107 38 -0.01423 ppb | Ag 109 46.7 -0.01437 ppb | Cd 111 7.3 0.0004 ppb |- Cd 114 25.5 0.00145 ppb |- Sb 121 104 -0.00735 ppb | Sb 123 74.5 -0.00791 ppb | Ba 135 3481.7 1.18794 ppb | Ba 137 6015.7 1.09449 ppb |> Ho 165 1032761.5 ppb | Tl 205 101.3 -0.00148 ppb | Pb 206 286.3 0.01517 ppb | Pb 207 246.7 0.01425 ppb |- Pb 208 1147.4 0.01508 ppb Kr 83 -249.9 ppb ICP-Data 17 of 30 elementOne e 24269-Metals 50.17 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: 24269-1.1 Sample DatThursday, March 19, 2015 14:22:36 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 55607.5 ppb | Be 9 0.7 -0.00068 ppb | B 10 521.3 4.09057 ppb |- B 11 2307.6 3.96784 ppb |- Na 23 270766.3 45.88167 ppb | Mg 24 104407.5 29.08166 ppb | Mg 25 15074.8 29.42063 ppb | Al 27 12204.9 2.61275 ppb | P 31 1747.2 -0.71116 ppb | K 39 442770.7 25.56863 ppb | Ca 44 151914.1 527.6685 ppb | Sc 45 186018.6 ppb | Cr 52 13176.5 0.46186 ppb | Cr 53 65651.9 32.1569 ppb | Fe 54 31168 4.14013 ppb | Mn 55 18679.2 1.31926 ppb | Fe 57 5792.5 4.04947 ppb | Co 59 128 0.00791 ppb | Ni 60 110.7 0.03432 ppb | Cu 63 588.4 -0.0325 ppb | Cu 65 316.3 -0.02764 ppb | Zn 66 5144.8 2.77916 ppb | Zn 67 5577 8.61118 ppb | Zn 68 5264.5 2.96212 ppb | As 75 -1868.2 -0.28393 ppb | Se 77 9304.8 33.39938 ppb | Se 82 7.4 0.0114 ppb | Sr 88 40312.2 1.20966 ppb | Mo 95 68 -0.0222 ppb | Mo 97 51 -0.02394 ppb | Mo 98 106.9 -0.02413 ppb |> Rh 103 531058.1 ppb | Ag 107 66.7 -0.01153 ppb | Ag 109 61.7 -0.01286 ppb | Cd 111 13.5 0.0028 ppb |- Cd 114 26.2 0.00163 ppb |- Sb 121 153.7 -0.0022 ppb | Sb 123 134.2 -0.00002 ppb | Ba 135 3373.6 1.19078 ppb | Ba 137 5826.9 1.09641 ppb |> Ho 165 998864.2 ppb | Tl 205 85 -0.0019 ppb | Pb 206 327.3 0.02008 ppb | Pb 207 277 0.01856 ppb |- Pb 208 1254.4 0.01864 ppb Kr 83 -237 ppb ICP-Data 18 of 30 elementOne e 24269-Metals 50.18 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatThursday, March 19, 2015 14:26:06 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 55899.1 ppb | Be 9 2.7 0.0054 ppb | B 10 368.3 2.151 ppb |- B 11 1726.5 2.36258 ppb |- Na 23 17939 -9.55155 ppb | Mg 24 19158.5 -0.9594 ppb | Mg 25 2706.7 -0.94723 ppb | Al 27 666 -0.00767 ppb | P 31 1612.8 -1.33318 ppb | K 39 263224.7 1.66528 ppb | Ca 44 25113.3 16.6854 ppb | Sc 45 187775.3 ppb | Cr 52 12464.2 0.34216 ppb | Cr 53 65955.7 31.06651 ppb | Fe 54 27302.9 -2.37086 ppb | Mn 55 1081.4 0.00927 ppb | Fe 57 4379.7 -1.82561 ppb | Co 59 31.7 -0.00127 ppb | Ni 60 37.7 -0.00122 ppb | Cu 63 672.4 -0.01882 ppb | Cu 65 344.7 -0.01873 ppb | Zn 66 1217.1 -0.01607 ppb | Zn 67 4888 5.33917 ppb | Zn 68 2116.9 0 ppb | As 75 -1868.8 -0.26656 ppb | Se 77 9104.2 30.90516 ppb | Se 82 -2.7 -0.03683 ppb | Sr 88 4142.3 -0.00225 ppb | Mo 95 40.7 -0.02881 ppb | Mo 97 30 -0.03246 ppb | Mo 98 57.2 -0.03136 ppb |> Rh 103 541607.7 ppb | Ag 107 151.3 -0.00407 ppb | Ag 109 151.3 -0.00459 ppb | Cd 111 11.9 0.00211 ppb |- Cd 114 22.9 0.00107 ppb |- Sb 121 73.7 -0.01003 ppb | Sb 123 59.5 -0.0096 ppb | Ba 135 53.7 -0.00209 ppb | Ba 137 97.7 -0.00035 ppb |> Ho 165 1009351.1 ppb | Tl 205 84 -0.00196 ppb | Pb 206 100.7 -0.00213 ppb | Pb 207 87.3 -0.00279 ppb |- Pb 208 382.7 -0.00287 ppb Kr 83 11.6 ppb ICP-Data 19 of 30 elementOne e 24269-Metals 50.19 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatThursday, March 19, 2015 14:29:34 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 52547.1 ppb | Be 9 29628.9 95.58739 ppb | B 10 7559.5 97.6976 ppb |- B 11 34236 96.11863 ppb |- Na 23 4513518.1 1021.256 ppb | Mg 24 2830790.1 1032.379 ppb | Mg 25 374998.4 952.5685 ppb | Al 27 367551.6 87.14422 ppb | P 31 234907.4 914.6092 ppb | K 39 7849489.2 1032.339 ppb | Ca 44 268957.3 1048.3 ppb | Sc 45 180488.3 ppb | Cr 52 699322.5 90.57043 ppb | Cr 53 137026.9 119.3458 ppb | Fe 54 670524 998.218 ppb | Mn 55 1169407.8 90.95332 ppb | Fe 57 269604.5 1088.365 ppb | Co 59 939771.4 93.27022 ppb | Ni 60 202625.3 102.2633 ppb | Cu 63 469710.5 94.54104 ppb | Cu 65 234529.3 102.1448 ppb | Zn 66 139545.3 102.4934 ppb | Zn 67 27780.4 106.759 ppb | Zn 68 108464.4 103.5428 ppb | As 75 179358.4 102.3252 ppb | Se 77 21680.9 122.1392 ppb | Se 82 20053 101.4031 ppb | Sr 88 2885766.6 100.8563 ppb | Mo 95 380020.9 93.7995 ppb | Mo 97 238915.5 98.58286 ppb | Mo 98 620116.9 92.42558 ppb |> Rh 103 507309.1 ppb | Ag 107 1074897.1 102.7973 ppb | Ag 109 1038828.6 103.6685 ppb | Cd 111 261025.7 103.1926 ppb |- Cd 114 618127.2 94.51863 ppb |- Sb 121 918847.9 90.62548 ppb | Sb 123 693153.3 90.05087 ppb | Ba 135 268010.1 98.26825 ppb | Ba 137 465440.8 90.947 ppb |> Ho 165 978114.1 ppb | Tl 205 3142070.8 103.7613 ppb | Pb 206 963428.3 95.99539 ppb | Pb 207 846275.4 96.85464 ppb |- Pb 208 4026775.9 101.0286 ppb Kr 83 -19508.4 ppb ICP-Data 20 of 30 elementOne e 24269-Metals 50.20 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: Blank Sample DatFriday, March 20, 2015 09:19:11 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 51518.2 ppb |- Sc 45 205083.8 ppb | V-1 51 15722.6 ppb | V 51 17747.7 ppb |> Rh 103 598204.8 ppb Ho 165 1031344.9 ppb Kr 83 52.1 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 1 Sample DatFriday, March 20, 2015 09:20:23 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 49395.7 ppb |- Sc 45 213211.3 ppb | V-1 51 24766.8 1 ppb | V 51 36887.1 1 ppb |> Rh 103 585278.5 ppb Ho 165 998938.7 ppb Kr 83 -154.3 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 2 Sample DatFriday, March 20, 2015 09:21:35 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 48516.6 ppb |- Sc 45 204645.7 ppb | V-1 51 112843.1 10.00973 ppb | V 51 211013.2 10.00515 ppb |> Rh 103 553465.2 ppb Ho 165 958498.8 ppb Kr 83 -1913.8 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 3 Sample DatFriday, March 20, 2015 09:22:46 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 46366.8 ppb |- Sc 45 202100.2 ppb | V-1 51 290905.9 29.95663 ppb | V 51 563135.1 29.94985 ppb |> Rh 103 527988 ppb Ho 165 916347.7 ppb Kr 83 -5529.7 mg/L ICP-Data 21 of 30 elementOne e 24269-Metals 50.21 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatFriday, March 20, 2015 09:23:58 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 48562.1 ppb |- Sc 45 193303.8 ppb | V-1 51 15218.7 0.06315 ppb | V 51 16865.4 0.01985 ppb |> Rh 103 556441.2 ppb Ho 165 965817.2 ppb Kr 83 41.2 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 2 Sample DatFriday, March 20, 2015 09:25:10 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 47588.3 ppb |- Sc 45 189569.3 ppb | V-1 51 18044.2 0.37544 ppb | V 51 22246.4 0.31303 ppb |> Rh 103 550025.9 ppb Ho 165 946963.6 ppb Kr 83 46.1 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 3 Sample DatFriday, March 20, 2015 09:26:21 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 48294.6 ppb |- Sc 45 201657.1 ppb | V-1 51 24759.3 1.02624 ppb | V 51 36123.4 1.00693 ppb |> Rh 103 560401 ppb Ho 165 970313.4 ppb Kr 83 42.7 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatFriday, March 20, 2015 09:27:34 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 48082.5 ppb |- Sc 45 208093.9 ppb | V-1 51 110151.5 9.83939 ppb | V 51 206311.6 9.88832 ppb |> Rh 103 555121.1 ppb Ho 165 947895.7 ppb Kr 83 -1912.4 mg/L ICP-Data 22 of 30 elementOne e 24269-Metals 50.22 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 5 Sample DatFriday, March 20, 2015 09:28:46 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 51252.2 ppb |- Sc 45 220310.8 ppb | V-1 51 270139.9 25.08818 ppb | V 51 525798.2 25.32323 ppb |> Rh 103 579960.6 ppb Ho 165 992631.7 ppb Kr 83 40.9 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 9 Sample DatFriday, March 20, 2015 09:29:59 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 57308 ppb |- Sc 45 233378 ppb | V-1 51 11890.8 -0.4579 ppb | V 51 14743 -0.20312 ppb |> Rh 103 652451.9 ppb Ho 165 1105409.3 ppb Kr 83 32.7 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 10 Sample DatFriday, March 20, 2015 09:31:11 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 57978.9 ppb |- Sc 45 242230.6 ppb | V-1 51 591439.8 49.95893 ppb | V 51 1173989.8 50.82185 ppb |> Rh 103 656359.1 ppb Ho 165 1107765.2 ppb Kr 83 40.7 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC STD2 Sample DatFriday, March 20, 2015 09:32:24 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 57293.5 ppb |- Sc 45 224391.3 ppb | V-1 51 11528.3 -0.47585 ppb | V 51 13695.3 -0.24063 ppb |> Rh 103 643326.2 ppb Ho 165 1089625.8 ppb Kr 83 40.8 mg/L ICP-Data 23 of 30 elementOne e 24269-Metals 50.23 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: 24269-1.1 Sample DatFriday, March 20, 2015 09:33:37 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 56515 ppb |- Sc 45 241392.2 ppb | V-1 51 14812.7 -0.16779 ppb | V 51 20025.1 0.05398 ppb |> Rh 103 636131.8 ppb Ho 165 1110708.2 ppb Kr 83 -16988.8 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: 24269-1.1 Sample DatFriday, March 20, 2015 09:34:48 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 56489.1 ppb |- Sc 45 232730 ppb | V-1 51 14479.9 -0.16639 ppb | V 51 19421.9 0.04828 ppb |> Rh 103 620416.4 ppb Ho 165 1102766.7 ppb Kr 83 -16279.3 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatFriday, March 20, 2015 09:38:26 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 49906.9 ppb |- Sc 45 204997.9 ppb | V-1 51 13057 -0.26485 ppb | V 51 15027.3 -0.13785 ppb |> Rh 103 603813.3 ppb Ho 165 1038228.1 ppb Kr 83 39.9 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatFriday, March 20, 2015 09:39:38 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 46381.4 ppb |- Sc 45 209522 ppb | V-1 51 111696 9.70007 ppb | V 51 210583.4 9.82634 ppb |> Rh 103 569268.3 ppb Ho 165 976102.7 ppb Kr 83 -1952.5 mg/L ICP-Data 24 of 30 elementOne e 24269-Metals 50.24 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: Blank Sample DatFriday, March 20, 2015 09:44:03 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 52152.4 ppb | B 10 216.3 ppb |- B 11 960.7 ppb |- Al 27 797.4 ppb | Sc 45 180971.4 ppb | Zn 66 908.4 ppb | Zn 67 1279.8 ppb | Zn 68 1760.8 ppb |> Rh 103 531462.9 ppb Ho 165 947211.6 ppb Kr 83 37.6 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 1 Sample DatFriday, March 20, 2015 09:45:24 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 49925.1 ppb | B 10 551.4 5 ppb |- B 11 2531 5 ppb |- Al 27 8200.4 1 ppb | Sc 45 180521.7 ppb | Zn 66 5858.9 1 ppb | Zn 67 2866.1 1 ppb | Zn 68 5462.6 1 ppb |> Rh 103 524385.4 ppb Ho 165 928647.1 ppb Kr 83 -145.2 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 2 Sample DatFriday, March 20, 2015 09:46:45 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 50158.1 ppb | B 10 6694.1 99.98322 ppb |- B 11 31243.7 99.98303 ppb |- Al 27 396553.9 99.99104 ppb | Sc 45 183855 ppb | Zn 66 145409.3 99.97525 ppb | Zn 67 27208.4 99.94752 ppb | Zn 68 111935.4 99.97581 ppb |> Rh 103 530687.1 ppb Ho 165 948682 ppb Kr 83 -20286.1 ppb ICP-Data 25 of 30 elementOne e 24269-Metals 50.25 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 3 Sample DatFriday, March 20, 2015 09:48:06 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 56634.5 ppb | B 10 40617 501.7911 ppb |- B 11 188725.2 501.6911 ppb |- Al 27 2300658.2 501.4058 ppb | Sc 45 209364.3 ppb | Zn 66 788685.3 500.2304 ppb | Zn 67 138251.2 499.5839 ppb | Zn 68 603910.3 500.2667 ppb |> Rh 103 571628.5 ppb Ho 165 1047909.5 ppb Kr 83 -110006.9 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatFriday, March 20, 2015 09:49:27 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 64941.7 ppb | B 10 787 ppb |- B 11 3600 ppb |- Al 27 1572.8 ppb | Sc 45 232339.9 ppb | Zn 66 1678.2 ppb | Zn 67 3259.3 ppb | Zn 68 2575.7 ppb |> Rh 103 645065.9 ppb Ho 165 1132700.9 ppb Kr 83 25.1 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 2 Sample DatFriday, March 20, 2015 09:50:48 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 72490.9 ppb | B 10 1266.8 3.77428 ppb |- B 11 5955.6 4.05337 ppb |- Al 27 7957.5 1.13652 ppb | Sc 45 260046.1 ppb | Zn 66 4471.4 1.41215 ppb | Zn 67 4088.6 1.85936 ppb | Zn 68 4852 1.45287 ppb |> Rh 103 688463.7 ppb Ho 165 1199562.1 ppb Kr 83 -233.4 ppb ICP-Data 26 of 30 elementOne e 24269-Metals 50.26 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 3 Sample DatFriday, March 20, 2015 09:52:09 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 60315.7 ppb | B 10 24540.8 278.07 ppb |- B 11 111610.4 271.915 ppb |- Al 27 1211559.9 253.6305 ppb | Sc 45 221753.3 ppb | Zn 66 437573.2 266.1943 ppb | Zn 67 78264.8 264.1722 ppb | Zn 68 341156.4 270.5374 ppb |> Rh 103 594786 ppb Ho 165 1060649.3 ppb Kr 83 -59645.6 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatFriday, March 20, 2015 09:53:31 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 60892.3 ppb | B 10 9449.9 100.8023 ppb |- B 11 43002.5 98.62222 ppb |- Al 27 488587.3 99.23161 ppb | Sc 45 216144.7 ppb | Zn 66 180679 106.2506 ppb | Zn 67 34200.6 106.0817 ppb | Zn 68 138475.7 105.5636 ppb |> Rh 103 611872.5 ppb Ho 165 1084015.6 ppb Kr 83 -24022.2 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 5 Sample DatFriday, March 20, 2015 09:54:53 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 56735 ppb | B 10 5153.8 55.41966 ppb |- B 11 23795.5 55.14874 ppb |- Al 27 239074 50.62308 ppb | Sc 45 206543.6 ppb | Zn 66 85934.7 52.36946 ppb | Zn 67 18310.1 54.77221 ppb | Zn 68 67334.6 52.76485 ppb |> Rh 103 585002.7 ppb Ho 165 1027742.5 ppb Kr 83 34.7 ppb ICP-Data 27 of 30 elementOne e 24269-Metals 50.27 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 9 Sample DatFriday, March 20, 2015 09:56:14 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 56540.4 ppb | B 10 529 -1.94495 ppb |- B 11 2484 -1.7365 ppb |- Al 27 8660.1 1.62731 ppb | Sc 45 199023.9 ppb | Zn 66 5531.7 2.64696 ppb | Zn 67 8394.6 20.73937 ppb | Zn 68 5597.7 2.85991 ppb |> Rh 103 558886 ppb Ho 165 990514.4 ppb Kr 83 43.7 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 10 Sample DatFriday, March 20, 2015 09:57:35 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 55813.1 ppb | B 10 4705.2 50.91042 ppb |- B 11 22098.5 51.63372 ppb |- Al 27 222245 49.75019 ppb | Sc 45 199785 ppb | Zn 66 81028.1 52.20581 ppb | Zn 67 22481.8 74.22032 ppb | Zn 68 63106.8 52.25739 ppb |> Rh 103 553320.5 ppb Ho 165 992366.5 ppb Kr 83 -10249.9 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 2 Sample DatFriday, March 20, 2015 09:58:57 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 55352.4 ppb | B 10 815.7 1.86382 ppb |- B 11 3776.8 1.95069 ppb |- Al 27 6384.9 1.08386 ppb | Sc 45 202784.5 ppb | Zn 66 3619.1 1.34701 ppb | Zn 67 5458 9.33699 ppb | Zn 68 4103.6 1.50418 ppb |> Rh 103 573276.8 ppb Ho 165 995599.4 ppb Kr 83 -168.3 ppb ICP-Data 28 of 30 elementOne e 24269-Metals 50.28 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: 24269-1.1 Sample DatFriday, March 20, 2015 10:00:19 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 55396.3 ppb | B 10 3343.9 33.97587 ppb |- B 11 15362 33.6134 ppb |- Al 27 476151.6 108.5994 ppb | Sc 45 209816 ppb | Zn 66 15832.8 9.60111 ppb | Zn 67 11913.2 35.0555 ppb | Zn 68 14923.2 11.10802 ppb |> Rh 103 545040.1 ppb Ho 165 1013209.4 ppb Kr 83 -14730.7 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: 24269-1.1 Sample DatFriday, March 20, 2015 10:01:40 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 51668.2 ppb | B 10 3092.5 33.6597 ppb |- B 11 14927.3 35.36576 ppb |- Al 27 451713.2 109.6579 ppb | Sc 45 191466.9 ppb | Zn 66 7701.9 4.51541 ppb | Zn 67 11205.6 35.10678 ppb | Zn 68 8883 6.34488 ppb |> Rh 103 511851.3 ppb Ho 165 947404.9 ppb Kr 83 -13091.2 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatFriday, March 20, 2015 10:08:27 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 55586.9 ppb | B 10 364.3 -3.90926 ppb |- B 11 1673.5 -3.83501 ppb |- Al 27 2010.6 0.15304 ppb | Sc 45 197951.4 ppb | Zn 66 1381.4 -0.03761 ppb | Zn 67 5256.5 9.30915 ppb | Zn 68 2259.3 0.04392 ppb |> Rh 103 553634.5 ppb Ho 165 993471.7 ppb Kr 83 44.9 ppb ICP-Data 29 of 30 elementOne e 24269-Metals 50.29 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatFriday, March 20, 2015 10:09:48 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 62942.2 ppb | B 10 9681.2 99.82199 ppb |- B 11 44791.7 99.34744 ppb |- Al 27 506281.6 101.499 ppb | Sc 45 227202.6 ppb | Zn 66 186858.2 108.4985 ppb | Zn 67 36609.1 112.731 ppb | Zn 68 144855.5 109.131 ppb |> Rh 103 619554 ppb Ho 165 1105483 ppb Kr 83 -24399.5 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 2 Sample DatFriday, March 20, 2015 10:21:19 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 55423.4 ppb | B 10 275 -5.04073 ppb |- B 11 1236.1 -5.01941 ppb |- Al 27 5797.2 1.01655 ppb | Sc 45 197774.3 ppb | Zn 66 3050.2 1.07894 ppb | Zn 67 5029.1 8.63693 ppb | Zn 68 3645.1 1.26662 ppb |> Rh 103 547256.4 ppb Ho 165 975128.7 ppb Kr 83 -168.6 ppb ICP-Data 30 of 30 elementOne e 24269-Metals 50.30 PerkinElmer FIMS-100 CVAA Mercury Analyzer Sample_ID Date Time Mean_Sig Mean_Rd Mean_Rt Units Alq.Vol. Sig 1 Reading-1 Result-1 Sig 2 Reading-2 Result-2 Calib Blank 3/19/2015 10:14:51 AM 0.00018269 µg 0.00016879 0.00019658 STD 1= .004 ug 3/19/2015 10:16:31 AM 0.00137162 µg 0.00139061 0.00135264 STD 2= .04 ug 3/19/2015 10:18:13 AM 0.01459709 µg 0.01466346 0.01453071 STD 3= .08 ug 3/19/2015 10:20:06 AM 0.02897143 µg 0.02890999 0.02903287 STD 4= .16 ug 3/19/2015 10:22:01 AM 0.06032927 µg 0.0606153 0.06004323 STD 5= .20 ug 3/19/2015 10:23:56 AM 0.07091303 µg 0.07094749 0.07087857 Reagent Blank 3/19/2015 10:25:49 AM -0.0001505 -0.0004141 -0.0004141 µg -0.0001584 -0.0004356 -0.0004356 -0.0001427 -0.0003925 -0.0003925 0.004ug = DL 3/19/2015 10:27:30 AM 0.00136241 0.00374738 0.00374738 µg 0.00137173 0.00377299 0.00377299 0.0013531 0.00372176 0.00372176 0.080ug = QC STD 2 3/19/2015 10:29:13 AM 0.03086209 0.08488752 0.08488752 µg 0.03107762 0.08548034 0.08548034 0.03064656 0.08429469 0.08429469 0.080ug = QC STD 3 3/19/2015 10:31:10 AM 0.02914807 0.08017302 0.08017302 µg 0.02927349 0.08051799 0.08051799 0.02902265 0.07982805 0.07982805 Reagent Blank 3/19/2015 10:33:04 AM -0.0001063 -0.0002923 -0.0002923 µg -0.0001201 -0.0003303 -0.0003303 -9.24E-05 -0.0002542 -0.0002542 0.004ug = DL 3/19/2015 10:52:35 AM 0.00135315 0.0037219 0.0037219 µg 0.00138323 0.00380464 0.00380464 0.00132307 0.00363916 0.00363916 0.080ug = QC STD 2 3/19/2015 10:54:18 AM 0.0308233 0.08478082 0.08478082 µg 0.03093375 0.08508463 0.08508463 0.03071285 0.08447701 0.08447701 Reagent Blank 3/19/2015 10:56:12 AM -0.0001189 -0.000327 -0.000327 µg -0.0001438 -0.0003955 -0.0003955 -9.40E-05 -0.0002585 -0.0002585 24269- 1.1 3/19/2015 11:03:07 AM -8.25E-05 0.00018713 4.68E-06 µg 40 1 -9.21E-05 0.00016062 4.02E-06 -7.29E-05 0.00021364 5.34E-06 24269- 1.1 DUP 3/19/2015 11:04:49 AM -3.49E-05 0.00031795 7.95E-06 µg 40 1 -1.57E-05 0.00037081 9.27E-06 -5.42E-05 0.00026509 6.63E-06 24269- 1.1 SPK 3/19/2015 11:06:31 AM 0.02307714 0.06388874 0.00159722 µg 40 1 0.02325342 0.06437358 0.00160934 0.02290087 0.06340389 0.0015851 0.004ug = DL 3/19/2015 11:13:46 AM 0.00139102 0.00382606 0.00382606 µg 0.00143361 0.00394319 0.00394319 0.00134844 0.00370893 0.00370893 0.080ug = QC STD 3 3/19/2015 11:15:30 AM 0.02805468 0.07716562 0.07716562 µg 0.02806559 0.07719562 0.07719562 0.02804377 0.07713561 0.07713561 Reagent Blank 3/19/2015 11:17:24 AM -8.23E-05 -0.0002264 -0.0002264 µg -7.04E-05 -0.0001938 -0.0001938 -9.42E-05 -0.000259 -0.000259 Hg-Data 1 of 1 elementOne e 24269-Hg 51.1