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HomeMy WebLinkAboutNC0001422_Ele1FR-S1NewandOld_20150805 Duke Energy Laboratory Services 13339 Hagers Ferry Road Bld. MG03A Huntersville, NC 28078 Project ID: Ash Basin GW Assessment - Invista Metals, Mercury, Chloride, Sulfate, Sodium, Alkalinity, Bicarbonate, Carbonate, Turbidity, Total Dissolved Solids, Total Suspended Solids, Dissolved Oxygen, pH, Temperature and Conductivity Analytical Report 23952 Element One, Inc. 6319-D Carolina Beach Rd., Wilmington, NC 28412 910-793-0128 FAX: 910-792-6853 e1lab@e1lab.com el1 The following data for Analytical Report 23952 has been reviewed for completeness, accuracy, adherence to method protocol, and compliance with quality assurance guidelines. Review by: Katie Strickland, B.S. Chemist February 24, 2015 Report Reviewed and Finalized By: Ken Smith, Laboratory Director February 24, 2015 ellementOne 23952 Duke Invista Report Packet Page 2 of 48 elementOne 23952 Duke Invista Report Packet Page 3 of 48 SUMMARY OF RESULTS elementOne 23952 Duke Invista Report Packet Page 4 of 48 Summary of Analysis Summary of Method 200.8 Metals Analysis Invista/S1/OH2 – DW1 Invista/S1/OH2 – DW1 Invista/S1/OG2 – DW3 23952-1 23952-1 dup 23952-2 Element mg/L mg/L mg/L ----------------- --------------- --------------- --------------- Aluminum 0.253 0.266 0.142 Antimony < 0.001 < 0.001 < 0.001 Arsenic < 0.005 < 0.005 < 0.005 Barium 0.037 0.038 0.048 Beryllium < 0.001 < 0.001 < 0.001 Boron 0.015 0.014 0.024 Cadmium < 0.002 < 0.002 < 0.002 Calcium 3.72 3.94 4.28 Chromium < 0.005 < 0.005 < 0.005 Cobalt < 0.001 < 0.001 < 0.001 Copper 0.003 0.003 < 0.003 Iron 0.058 0.057 0.070 Lead < 0.003 < 0.003 0.004 Magnesium 0.602 0.631 1.038 Manganese 0.025 0.026 0.023 Molybdenum < 0.005 < 0.005 < 0.005 Nickel < 0.005 < 0.005 < 0.005 Potassium 0.716 0.731 0.993 Selenium < 0.005 < 0.005 < 0.005 Strontium 0.016 0.017 0.025 Thallium < 0.0002 < 0.0002 < 0.0002 Vanadium 0.0003 < 0.0003 < 0.0003 Zinc 0.015 0.015 0.011 Summary of Method 245.1 Mercury Analysis Invista/S1/OH2 – DW1 Invista/S1/OG2 – DW3 Invista/S1/OG2 – DW3 23952-1 23952-2 23952-2 dup Element mg/L mg/L mg/L ----------------- ------ --------------- --------------- --------------- Mercury #1 < 0.0002 < 0.0002 < 0.0002 #2 < 0.0002 < 0.0002 < 0.0002 elementOne 23952 Duke Invista Report Packet Page 5 of 48 Summary of Analysis Summary of Method 300.0 Anions Analysis Invista/S1/OH2 – DW1 Invista/S1/OG2 – DW3 23952-1 23952-2 Element mg/L mg/L ----------------- --------------- --------------- Chloride 4.87 8.02 Sulfate 9.67 10.1 Summary of Method ASTM D6919-03 Sodium Analysis Invista/S1/OH2 – DW1 Invista/S1/OG2 – DW3 Invista/S1/OG2 – DW3 23952-1 23952-2 23952-2 dup Element mg/L mg/L mg/L ----------------- --------------- --------------- --------------- Sodium 2.90 4.51 4.49 Summary of Standard Method 2320B Alkalinity Analysis Invista/S1/OH2 – DW1 Invista/S1/OG2 – DW3 23952-1 23952-2 Assay mg/L mg/L ----------------- --------------- --------------- Alkalinity as CaCO3 2.59 1.99 Summary of Standard Method 4500 CO2 E Analysis Invista/S1/OH2 – DW1 Invista/S1/OG2 – DW3 23952-1 23952-2 Assay mg/L mg/L ----------------- --------------- --------------- Bicarbonate (HCO32- as CaCO3) 2.59 1.99 Carbonate (CO32- as CaCO3) < 1 < 1 Summary of Standard Method 2130 B Turbidity Analysis Invista/S1/OH2 – DW1 Invista/S1/OG2 – DW3 23952-1 23952-2 Assay NTU NTU ----------------- --------------- --------------- Turbidity < 1 < 1 elementOne 23952 Duke Invista Report Packet Page 6 of 48 Summary of Analysis Summary of Standard Method 2540 C TDS Analysis Invista/S1/OH2 – DW1 Invista/S1/OG2 – DW3 23952-1 23952-2 Assay mg/L mg/L ----------------- --------------- --------------- Total Dissolved Solids 32.0 37.5 Summary of Standard Method 2540 D TSS Analysis Invista/S1/OH2 – DW1 Invista/S1/OG2 – DW3 23952-1 23952-2 Assay mg/L mg/L ----------------- --------------- --------------- Total Suspended Solids < 2.5 < 2.5 Summary of Standard Method 4500O G DO Analysis Invista/S1/OH2 – DW1 Invista/S1/OG2 – DW3 23952-1 23952-2 Assay mg/L mg/L ----------------- --------------- --------------- Dissolved Oxygen 6.24 9.22 Summary of Standard Method 4500H+ pH Analysis Invista/S1/OH2 – DW1 Invista/S1/OG2 – DW 3 23952-1 23952-2 Assay SU SU ----------------- --------------- --------------- pH 5.58 6.75 Summary of Standard Method 2500 B Temperature Analysis Invista/S1/OH2 – DW1 Invista/S1/OG2 – DW3 23952-1 23952-2 Assay °C °C ----------------- --------------- --------------- Temperature 18.8 16.6 Summary of Standard Method 2510 B Conductivity Analysis Invista/S1/OH2 – DW1 Invista/S1/OG2 – DW3 23952-1 23952-2 Assay µmhos/cm µmhos/cm ----------------- --------------- --------------- Conductivity 53.0 62.5 elementOne 23952 Duke Invista Report Packet Page 7 of 48 ANALYTICAL NARRATIVE elementOne 23952 Duke Invista Report Packet Page 8 of 48 Element One Analytical Narrative Client: Duke Energy Element One #: 23952 Client ID: Ash Basin GW Assessment - Invista Analyst: DBW, DAM, KLS, PQT, KAM Method: See table below Dates Received: 02/04/2015 Analytes: See table below Dates Analyzed: 02/04-23/15 Summary of Analysis The samples were collected by Element One, Inc. on 02/04/2015. The samples were analyzed for pH, temperature, conductivity and dissolved oxygen in the field immediately following sampling. Samples were returned to Element One, Inc., prepared and analyzed for the other parameters following method protocol. The samples analyzed for metals according to EPA Method 200.8 protocol on a PerkinElmer ELAN 6100 ICP-MS. The samples were analyzed for mercury according to EPA method 245.1 on a PerkinElmer FIMS-100 CVAA mercury analyzer. Samples were analyzed for chloride, sulfate by EPA 300.0 and sodium by ATSM D6919-03 on Metrohm 861/788 and 761/788 ion chromatograph system. Detection Limits The following is a list of parameters, methods used and the associated reporting limit for each: Parameter DL, mg/L Method Parameter DL, mg/L Method Beryllium 0.001 EPA 200.8 Antimony *0.001 EPA 200.8 Boron 0.005 EPA 200.8 Barium 0.005 EPA 200.8 Magnesium 0.02 EPA 200.8 Thallium *0.0002 EPA 200.8 Aluminum 0.005 EPA 200.8 Lead 0.003 EPA 200.8 Potassium 0.02 EPA 200.8 Mercury 0.0002 EPA 245.1 Calcium 0.05 EPA 200.8 Chloride 0.1 EPA 300.0 Vanadium *0.0003 EPA 200.8 Sulfate 0.1 EPA 300.0 Chromium 0.005 EPA 200.8 Sodium 0.05 ASTM D6919-03 Manganese 0.005 EPA 200.8 Alkalinity 1 SM 2320 B Iron 0.02 EPA 200.8 Bicarbonate 1 SM 4500 CO2 D Cobalt *0.001 EPA 200.8 Carbonate 1 SM 4500 CO2 D Nickel 0.005 EPA 200.8 Turbidity 1.0 NTU SM 2130 B Copper 0.003 EPA 200.8 TDS 10 SM 2540 C Zinc 0.005 EPA 200.8 TSS 2.5 SM 2540 D Arsenic 0.005 EPA 200.8 Dissolved Oxygen SM 4500O G Selenium 0.005 EPA 200.8 pH 1.0 SU SM 4500-H+ Strontium 0.005 EPA 200.8 Temperature SM 2500 B Molybdenum 0.005 EPA 200.8 Conductivity 10µmhos/cm SM2510B Cadmium 0.002 EPA 200.8 *Detection Limit based on client request. elementOne 23952 Duke Invista Report Packet Page 9 of 48 Element One Analytical Narrative Analysis QA/QC Duplicate analyses relative percent difference (RPD), sample spike recovery and second source calibration verification data are summarized in the Quality Control Section. *Ref. page 11; sample Invista/S1/OH2 – DW1 duplicate analysis RPD was outside of laboratory guidelines for vanadium with 67.6% RPD. Sample results were at the detection limit for vanadium and should have no significant impact on the results. All other QA/QC data was within the criteria of the method. Additional Comments The reported results have not been corrected for any blank values or spike recovery values. The reported results relate only to the items tested or calibrated. elementOne 23952 Duke Invista Report Packet Page 10 of 48 QUALITY CONTROL SUMMARY elementOne 23952 Duke Invista Report Packet Page 11 of 48 Summary of Quality Control Data 200.8 Duplicate Analysis RPD (QC limits: <20% for RPD.) Invista/S1/OH2 – DW1 23952-1 Element RPD ----------------- --------------- Aluminum 5.0% Antimony NA Arsenic NA Barium 2.9% Beryllium NA Boron 2.8% Cadmium NA Calcium 5.8% Chromium NA Cobalt NA Copper 0.7% Iron 0.1% Lead NA Magnesium 4.6% Manganese 3.0% Molybdenum NA Nickel NA Potassium 2.1% Selenium NA Strontium 1.9% Thallium NA Vanadium 67.6%* Zinc 3.2% *See Analytical Narrative page 9. elementOne 23952 Duke Invista Report Packet Page 12 of 48 Summary of Quality Control Data Second Source Calibration Check Recoveries (QC limits: ±10% for Second Source Continuing Check Standard*) Element 1 ppb 50 ppb 100 ppb* 250 ppb ----------------- ----------------- ----------------- ----------------- ----------------- Aluminum 117% 110% 104% 102% Antimony 110% 103% 106% 106% Arsenic 109% 96% 98% 101% Barium 109% 99% 103% 103% Beryllium 107% 95% 100% 101% Cadmium 104% 95% 100% 100% Chromium 114% 96% 98% 100% Cobalt 104% 94% 98% 99% Copper 110% 98% 100% 104% Lead 106% 100% 105% 104% Manganese 105% 95% 100% 99% Molybdenum 112% 106% 105% 103% Nickel 100% 96% 99% 101% Selenium 97% 90% 95% 96% Strontium 103% 95% 100% 101% Thallium 108% 95% 106% 103% Zinc 108% 92% 97% 96% Element 21 ppb 250 ppb 1100 ppb* 2500 ppb ----------------- ----------------- ----------------- ----------------- ----------------- Calcium 94% 109% 103% 102% Iron 88% 98% 97% 99% Magnesium 99% 103% 102% 100% Potassium 77% 100% 100% 97% Element 5 ppb 50 ppb 100 ppb* 250 ppb ----------------- ----------------- ----------------- ----------------- ----------------- Boron 119% 120% 96% 96% Element 0.3 ppb 1 ppb 10 ppb* 25 ppb ----------------- ----------------- ----------------- ----------------- ----------------- Vanadium 123% 102% 105% 111% elementOne 23952 Duke Invista Report Packet Page 13 of 48 Summary of Quality Control Data Mercury 245.1 Duplicate Analysis RPD (QC limits: <10 % for RPD) Sample ID RPD ------------------------- ------------- Invista/S1/OH2 – DW1 NA Invista/S1/OG2 – DW 3 NA Sodium ASTM D6919-03 Duplicate Analysis RPD (QC limits: <10 % for RPD) Sample ID RPD ------------------------- ------------- Invista/S1/OG2 – DW3 0.4% elementOne 23952 Duke Invista Report Packet Page 14 of 48 SAMPLE CUSTODY elementOne 23952 Duke Invista Report Packet Page 15 of 48 elementOne 23952 Duke Invista Report Packet Page 16 of 48 elementOne 23952 Duke Invista Report Packet Page 17 of 48 ANALYTICAL DATA elementOne 23952 Duke Invista Report Packet Page 18 of 48 Analytical Calculations Metals, Mercury- Metals (mg/L) = ICP Results (µg/L)*Dilution 1000 Where- ICP-Hg Results = Raw sample concentration (ppb)—ICP-Hg -Data Sheet Dilution= Diluted Volume--ICP-MS Run Sheet/ Hg Run Sheet Aliquot Anions- Anions (mg/L) = IC Results (mg/L)*Dilution Where- IC Results = Raw sample concentration (ppm)—IC-Data Sheet Dilution= Diluted Volume-- IC-Data Sheet Aliquot elementOne 23952 Duke Invista Report Packet Page 19 of 48 Analytical Calculations Spike Recovery- Spike (%) = (Spiked Result (µg/L) – Sample Result (µg/L)) X100 Spike Amount (µg/L) Where- Spike Result = Raw sample concentration (ppb)--ICP-Data Sheet Sample Result = Raw sample concentration (ppb)--ICP-Data Sheet Spike Amount--ICP-MS Spike Table Duplicate Analysis RPD- RPD (%) = (Duplicate Result (µg/L) - Sample Result (µg/L)) X100 Average (µg/L) Where- Sample Result and Duplicate Results=Raw sample concentration (ppb)--ICP-Data Sheet Average= (Duplicate + Sample Results) 2 elementOne 23952 Duke Invista Report Packet Page 20 of 48 elementOne 23952 Duke Invista Report Packet Page 21 of 48 elementOne 23952 Duke Invista Report Packet Page 22 of 48 elementOne 23952 Duke Invista Report Packet Page 23 of 48 elementOne 23952 Duke Invista Report Packet Page 24 of 48 elementOne 23952 Duke Invista Report Packet Page 25 of 48 elementOne 23952 Duke Invista Report Packet Page 26 of 48 elementOne 23952 Duke Invista Report Packet Page 27 of 48 elementOne 23952 Duke Invista Report Packet Page 28 of 48 elementOne 23952 Duke Invista Report Packet Page 29 of 48 elementOne 23952 Duke Invista Report Packet Page 30 of 48 elementOne 23952 Duke Invista Report Packet Page 31 of 48 elementOne 23952 Duke Invista Report Packet Page 32 of 48 elementOne 23952 Duke Invista Report Packet Page 33 of 48 elementOne 23952 Duke Invista Report Packet Page 34 of 48 elementOne 23952 Duke Invista Report Packet Page 35 of 48 elementOne 23952 Duke Invista Report Packet Page 36 of 48 elementOne 23952 Duke Invista Report Packet Page 37 of 48 elementOne 23952 Duke Invista Report Packet Page 38 of 48 elementOne 23952 Duke Invista Report Packet Page 39 of 48 elementOne 23952 Duke Invista Report Packet Page 40 of 48 elementOne 23952 Duke Invista Report Packet Page 41 of 48 elementOne 23952 Duke Invista Report Packet Page 42 of 48 elementOne 23952 Duke Invista Report Packet Page 43 of 48 elementOne 23952 Duke Invista Report Packet Page 44 of 48 elementOne 23952 Duke Invista Report Packet Page 45 of 48 elementOne 23952 Duke Invista Report Packet Page 46 of 48 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: Blank Sample DatThursday, February 05, 2015 17:19:52 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 55551.9 ppb | Be 9 2.3 ppb | B 10 652 ppb | B 11 2876.1 ppb | Mg 24 701.4 ppb | Mg 25 89 ppb | Al 27 909.7 ppb | Ca 44 16289.6 ppb | Sc 45 186851.1 ppb | Cr 52 6768.2 ppb | Cr 53 17429 ppb | Fe 54 29335.3 ppb | Mn 55 452.7 ppb | Fe 57 5244.5 ppb |- Co 59 70.7 ppb |- Ni 60 204.3 ppb | Cu 63 196.3 ppb | Cu 65 123.7 ppb | Zn 66 1007.4 ppb | Zn 67 1872.2 ppb | Zn 68 1819.5 ppb | As 75 -400.1 ppb | Se 77 1807.5 ppb | Se 82 55.6 ppb | Sr 88 208 ppb | Mo 95 3945.4 ppb | Mo 97 2470.1 ppb | Mo 98 6395.7 ppb |> Rh 103 500865.1 ppb | Cd 111 12.8 ppb |- Cd 114 37.1 ppb |- Sb 121 267.3 ppb | Sb 123 221.2 ppb | Ba 135 105.3 ppb | Ba 137 174 ppb |> Ho 165 990665 ppb | Tl 205 202.3 ppb | Pb 206 284 ppb | Pb 207 219.3 ppb |- Pb 208 1055.4 ppb Kr 83 44.9 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 1 Sample DatThursday, February 05, 2015 17:23:20 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 54870.4 ppb | Be 9 371.3 1.09017 ppb | B 10 1074.1 4.5845 ppb | B 11 4915.3 4.7848 ppb | Mg 24 64019 19.82755 ppb | Mg 25 9200.3 19.79721 ppb | Al 27 6573.7 1.09677 ppb | Ca 44 22321.4 21.87443 ppb | Sc 45 221344.3 ppb | Cr 52 15650.5 0.99161 ppb | Cr 53 19224.6 2.01325 ppb | Fe 54 40728.7 15.91686 ppb | Mn 55 15030.4 0.99704 ppb | Fe 57 10143.7 18.33401 ppb |- Co 59 11912.5 0.99471 ppb |- Ni 60 2683.1 1.04796 ppb | Cu 63 5938.9 0.94916 ppb | Cu 65 3066.9 1.0774 ppb | Zn 66 2341.3 0.80878 ppb | Zn 67 2165.6 1.08277 ppb | Zn 68 2810.8 0.81566 ppb | As 75 1759 1.11382 ppb | Se 77 1861.5 0.37913 ppb | Se 82 241.2 0.83005 ppb | Sr 88 27585.5 0.92517 ppb | Mo 95 5083.4 0.32589 ppb | Mo 97 3190.2 0.32746 ppb | Mo 98 8124.9 0.27704 ppb |> Rh 103 498490.4 ppb | Cd 111 2734.7 1.04182 ppb |- Cd 114 6438.4 0.93135 ppb |- Sb 121 9548.3 1.0179 ppb | Sb 123 7149.7 0.99634 ppb | Ba 135 2897.5 1.09293 ppb | Ba 137 5115.1 0.99915 ppb |> Ho 165 986205.8 ppb | Tl 205 32982.4 0.95756 ppb | Pb 206 10956.9 0.94644 ppb | Pb 207 9553.7 0.94063 ppb |- Pb 208 43259.4 0.9359 ppb Kr 83 -134.1 ppb ICP-Data 1 of 17 elementOne e 23952-Metals 47.1 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 2 Sample DatThursday, February 05, 2015 17:26:48 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 54401.9 ppb | Be 9 34011 101.4055 ppb | B 10 9361.2 93.6393 ppb | B 11 42823.2 92.84988 ppb | Mg 24 3383829.3 1067.74 ppb | Mg 25 469178.9 1027.362 ppb | Al 27 481232.4 93.62816 ppb | Ca 44 328976.4 1109.03 ppb | Sc 45 216892.4 ppb | Cr 52 878681.4 97.26604 ppb | Cr 53 120275 104.2546 ppb | Fe 54 795953.6 1047.302 ppb | Mn 55 1388733.8 95.77545 ppb | Fe 57 308637.2 1131.225 ppb |- Co 59 1123449.3 95.23123 ppb |- Ni 60 238978.9 99.29261 ppb | Cu 63 558131.5 90.71885 ppb | Cu 65 276512.9 99.47389 ppb | Zn 66 167202.7 98.72411 ppb | Zn 67 29891.8 98.54483 ppb | Zn 68 125171.9 98.95742 ppb | As 75 194683.9 99.10529 ppb | Se 77 18058.9 95.64624 ppb | Se 82 21728.3 95.26074 ppb | Sr 88 2891857.5 96.10505 ppb | Mo 95 356009.1 97.86996 ppb | Mo 97 225052.6 98.25356 ppb | Mo 98 583342.8 89.68456 ppb |> Rh 103 506582.2 ppb | Cd 111 262160.9 98.6832 ppb |- Cd 114 617474.9 88.35998 ppb |- Sb 121 894589.5 93.58827 ppb | Sb 123 685921.7 94.09518 ppb | Ba 135 272002.6 101.5609 ppb | Ba 137 473570 91.35508 ppb |> Ho 165 1033204.9 ppb | Tl 205 3544153.6 98.79699 ppb | Pb 206 1077059.1 91.12052 ppb | Pb 207 945666 90.92921 ppb |- Pb 208 4530745.3 95.85482 ppb Kr 83 -19561 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 3 Sample DatThursday, February 05, 2015 17:30:15 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 61064 ppb | Be 9 188308.2 499.7187 ppb | B 10 53248.9 501.265 ppb | B 11 245919.3 501.4225 ppb | Mg 24 19598012 5506.457 ppb | Mg 25 2827003.5 5514.532 ppb | Al 27 2887141 501.2742 ppb | Ca 44 1760398.8 5498.191 ppb | Sc 45 263540.8 ppb | Cr 52 5045587.7 500.5468 ppb | Cr 53 573828.7 499.1471 ppb | Fe 54 4566491.5 5510.559 ppb | Mn 55 8147632.3 500.8449 ppb | Fe 57 1659370 5493.765 ppb |- Co 59 6635993.3 500.9538 ppb |- Ni 60 1266251.1 500.1414 ppb | Cu 63 3249512.8 501.8563 ppb | Cu 65 1462551.3 500.1051 ppb | Zn 66 887335.7 500.2556 ppb | Zn 67 151573 500.2909 ppb | Zn 68 658147.7 500.2089 ppb | As 75 1035919.1 500.1787 ppb | Se 77 91407.4 500.872 ppb | Se 82 120053.6 500.9482 ppb | Sr 88 15860592 500.7791 ppb | Mo 95 1898994.6 500.4274 ppb | Mo 97 1195632.5 500.3506 ppb | Mo 98 3407137.3 502.0645 ppb |> Rh 103 533245.2 ppb | Cd 111 1398385.9 500.2633 ppb |- Cd 114 3694136.3 502.3281 ppb |- Sb 121 5210745.2 501.2823 ppb | Sb 123 3973058.5 501.181 ppb | Ba 135 1455553.6 499.6876 ppb | Ba 137 2829711.8 501.729 ppb |> Ho 165 1124198.7 ppb | Tl 205 19523405 500.2407 ppb | Pb 206 6452990.7 501.776 ppb | Pb 207 5677774 501.8143 ppb |- Pb 208 25752853 500.8292 ppb Kr 83 -107471 ppb ICP-Data 2 of 17 elementOne e 23952-Metals 47.2 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatThursday, February 05, 2015 17:33:44 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 62646.4 ppb | Be 9 18.7 0.04092 ppb | B 10 1647.5 8.47297 ppb | B 11 7398.7 8.35156 ppb | Mg 24 2619.5 0.49437 ppb | Mg 25 386 0.53636 ppb | Al 27 1220.1 0.0323 ppb | Ca 44 15345.3 -9.26932 ppb | Sc 45 208208.1 ppb | Cr 52 8542 0.08806 ppb | Cr 53 18794.8 -0.73583 ppb | Fe 54 44464.7 13.62297 ppb | Mn 55 1280.8 0.04548 ppb | Fe 57 10665.3 15.52194 ppb |- Co 59 634.7 0.04026 ppb |- Ni 60 299.3 0.03174 ppb | Cu 63 789.4 0.08908 ppb | Cu 65 391 0.08802 ppb | Zn 66 1198.1 0.06718 ppb | Zn 67 2188.6 0.61293 ppb | Zn 68 2105.9 0.11989 ppb | As 75 91.8 0.24986 ppb | Se 77 2256.6 1.79066 ppb | Se 82 290.6 0.95929 ppb | Sr 88 1264.1 0.03276 ppb | Mo 95 67595.6 16.62 ppb | Mo 97 41993.1 16.38791 ppb | Mo 98 107576.8 14.77342 ppb |> Rh 103 536209 ppb | Cd 111 147.1 0.04752 ppb |- Cd 114 438.4 0.05398 ppb |- Sb 121 577 0.02837 ppb | Sb 123 431 0.02471 ppb | Ba 135 224.7 0.03893 ppb | Ba 137 425.3 0.04318 ppb |> Ho 165 1082645.9 ppb | Tl 205 1929.9 0.04533 ppb | Pb 206 1639.5 0.10733 ppb | Pb 207 1439.8 0.11012 ppb |- Pb 208 6541.3 0.10883 ppb Kr 83 37.4 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 2 Sample DatThursday, February 05, 2015 17:37:12 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 57891.6 ppb | Be 9 382.7 1.06478 ppb | B 10 1567.5 8.97202 ppb | B 11 7092.8 8.94626 ppb | Mg 24 64894.7 19.02987 ppb | Mg 25 9214 18.7684 ppb | Al 27 6828.6 1.07724 ppb | Ca 44 22885.4 19.65397 ppb | Sc 45 228482.9 ppb | Cr 52 17129.5 1.05611 ppb | Cr 53 21267.2 2.94547 ppb | Fe 54 44437 17.77116 ppb | Mn 55 15403.7 0.96745 ppb | Fe 57 10743 18.46734 ppb |- Co 59 12082.7 0.95577 ppb |- Ni 60 2651.4 1.0003 ppb | Cu 63 6632.1 1.03032 ppb | Cu 65 3203.9 1.09121 ppb | Zn 66 2881.5 1.08121 ppb | Zn 67 2528.7 2.10032 ppb | Zn 68 3303.3 1.13479 ppb | As 75 1771.4 1.09143 ppb | Se 77 2210.9 2.06324 ppb | Se 82 280.6 0.96649 ppb | Sr 88 28434.4 0.92423 ppb | Mo 95 12279.7 2.23542 ppb | Mo 97 7727.9 2.23979 ppb | Mo 98 19881 2.02199 ppb |> Rh 103 514442.6 ppb | Cd 111 2814.5 1.03897 ppb |- Cd 114 6613.1 0.92706 ppb |- Sb 121 9827.3 1.00231 ppb | Sb 123 7464.3 0.99559 ppb | Ba 135 2991.5 1.07968 ppb | Ba 137 5282.5 0.98726 ppb |> Ho 165 1030220.7 ppb | Tl 205 34710.5 0.96476 ppb | Pb 206 11314.7 0.93527 ppb | Pb 207 10086.9 0.95096 ppb |- Pb 208 45701.4 0.94674 ppb Kr 83 -141.8 ppb ICP-Data 3 of 17 elementOne e 23952-Metals 47.3 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 3 Sample DatThursday, February 05, 2015 17:40:40 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 51791 ppb | Be 9 80268.4 251.4103 ppb | B 10 22271.6 244.5445 ppb | B 11 100432.8 238.9064 ppb | Mg 24 7494525 2489.734 ppb | Mg 25 1007404.4 2321.829 ppb | Al 27 1146088.8 234.964 ppb | Ca 44 697980.2 2540.757 ppb | Sc 45 225506.8 ppb | Cr 52 2304083.5 269.4136 ppb | Cr 53 268736.9 267.8448 ppb | Fe 54 1730369.7 2441.952 ppb | Mn 55 3656230.7 265.087 ppb | Fe 57 683258.4 2657.395 ppb |- Co 59 2975435.4 264.9876 ppb |- Ni 60 578311.3 251.3334 ppb | Cu 63 1383496.3 235.1126 ppb | Cu 65 674939.8 253.9014 ppb | Zn 66 386947.6 239.6909 ppb | Zn 67 67978 243.4823 ppb | Zn 68 296258.6 246.9935 ppb | As 75 474474.4 252.174 ppb | Se 77 40607.2 239.4393 ppb | Se 82 52097.7 239.0969 ppb | Sr 88 7252706.5 252.0537 ppb | Mo 95 893708.7 258.3381 ppb | Mo 97 560554 257.303 ppb | Mo 98 1436739.8 232.1882 ppb |> Rh 103 484808.8 ppb | Cd 111 636827.6 250.6152 ppb |- Cd 114 1505739 225.3052 ppb |- Sb 121 2492090.1 267.921 ppb | Sb 123 1694301.2 238.8307 ppb | Ba 135 669134.6 256.7403 ppb | Ba 137 1174844.8 232.8665 ppb |> Ho 165 1005695.3 ppb | Tl 205 9014691.1 258.2388 ppb | Pb 206 2996041.6 260.4951 ppb | Pb 207 2616600.7 258.5497 ppb |- Pb 208 11947784 259.7777 ppb Kr 83 -49128.6 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatThursday, February 05, 2015 17:44:08 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 51374.5 ppb | Be 9 31689.5 99.99156 ppb | B 10 8919.4 94.59819 ppb | B 11 41613 95.84628 ppb | Mg 24 3359615.9 1122.885 ppb | Mg 25 450544.4 1044.806 ppb | Al 27 465252.3 95.85799 ppb | Ca 44 315903.3 1127.083 ppb | Sc 45 199672.4 ppb | Cr 52 851207.3 99.74595 ppb | Cr 53 120293.8 111.2738 ppb | Fe 54 779491.7 1086.09 ppb | Mn 55 1373027.8 100.205 ppb | Fe 57 304158.1 1180.308 ppb |- Co 59 1090367.2 97.77982 ppb |- Ni 60 233065 99.03635 ppb | Cu 63 541993.9 90.10941 ppb | Cu 65 264873.1 97.45628 ppb | Zn 66 160239.4 96.76141 ppb | Zn 67 29098.8 98.10337 ppb | Zn 68 120297.8 97.25087 ppb | As 75 188526.7 98.16858 ppb | Se 77 17640.8 95.56405 ppb | Se 82 21153.2 94.83799 ppb | Sr 88 2948271.3 100.2153 ppb | Mo 95 378379.7 106.3705 ppb | Mo 97 234882.7 104.8572 ppb | Mo 98 604897.8 95.09303 ppb |> Rh 103 495431 ppb | Cd 111 260753.3 100.3958 ppb |- Cd 114 619014.7 90.60651 ppb |- Sb 121 896379.3 96.12787 ppb | Sb 123 682541.6 95.96788 ppb | Ba 135 268204.7 102.6462 ppb | Ba 137 469618.2 92.84657 ppb |> Ho 165 1008037.2 ppb | Tl 205 3693655.3 105.5518 ppb | Pb 206 1074917.5 93.21443 ppb | Pb 207 938001.5 92.44695 ppb |- Pb 208 4599942.3 99.76207 ppb Kr 83 -19939.2 ppb ICP-Data 4 of 17 elementOne e 23952-Metals 47.4 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 5 Sample DatThursday, February 05, 2015 17:47:37 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 50390.1 ppb | Be 9 14732.6 47.4078 ppb | B 10 5679.4 59.01805 ppb | B 11 26416 59.7585 ppb | Mg 24 699800 238.3407 ppb | Mg 25 98751.8 233.3922 ppb | Al 27 240968.9 50.55142 ppb | Ca 44 85814.3 271.3549 ppb | Sc 45 202393.3 ppb | Cr 52 409202.1 48.51816 ppb | Cr 53 67815.7 56.6471 ppb | Fe 54 202853.9 259.3873 ppb | Mn 55 641750.1 47.74797 ppb | Fe 57 71734 269.2662 ppb |- Co 59 515601.7 47.13775 ppb |- Ni 60 110455.8 47.83611 ppb | Cu 63 260461.7 44.15352 ppb | Cu 65 128172.8 48.09064 ppb | Zn 66 74956.1 45.86109 ppb | Zn 67 14850.8 47.88086 ppb | Zn 68 57171.6 46.38653 ppb | As 75 90032.2 47.93654 ppb | Se 77 9094.2 45.14923 ppb | Se 82 9849.9 44.93215 ppb | Sr 88 1234611.2 42.81904 ppb | Mo 95 187909.7 53.35138 ppb | Mo 97 117569.5 53.00407 ppb | Mo 98 300694.9 47.71936 ppb |> Rh 103 485633.8 ppb | Cd 111 120856.4 47.47757 ppb |- Cd 114 287471.1 42.93213 ppb |- Sb 121 427640.3 46.34278 ppb | Sb 123 325970.9 46.31182 ppb | Ba 135 126755.6 49.01641 ppb | Ba 137 224642.7 44.87587 ppb |> Ho 165 997338.3 ppb | Tl 205 1466550.8 42.36181 ppb | Pb 206 511477.4 44.82409 ppb | Pb 207 444551.8 44.27902 ppb |- Pb 208 2036941 44.64436 ppb Kr 83 -8321.2 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 8 Sample DatThursday, February 05, 2015 17:51:05 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 57162.1 ppb | Be 9 78.7 0.21723 ppb | B 10 1005.1 3.43716 ppb | B 11 4888 4.31611 ppb | Mg 24 1055.1 0.10096 ppb | Mg 25 153 0.12999 ppb | Al 27 1834.9 0.1677 ppb | Ca 44 15217.7 -4.86835 ppb | Sc 45 209637.4 ppb | Cr 52 9464.9 0.26685 ppb | Cr 53 21041 3.04468 ppb | Fe 54 29450.2 -0.9481 ppb | Mn 55 3443.7 0.19624 ppb | Fe 57 5057.8 -1.22405 ppb |- Co 59 2521.7 0.19804 ppb |- Ni 60 563.7 0.14597 ppb | Cu 63 1553.5 0.2176 ppb | Cu 65 761.4 0.22648 ppb | Zn 66 696 -0.19721 ppb | Zn 67 2280 1.27248 ppb | Zn 68 1691.2 -0.13359 ppb | As 75 -7.8 0.20629 ppb | Se 77 2046.9 1.14082 ppb | Se 82 108.9 0.22665 ppb | Sr 88 5892.6 0.18669 ppb | Mo 95 6859 0.74959 ppb | Mo 97 4226.5 0.71493 ppb | Mo 98 10934.2 0.65116 ppb |> Rh 103 512645.2 ppb | Cd 111 584.2 0.21241 ppb |- Cd 114 1408.1 0.19414 ppb |- Sb 121 2262.3 0.20689 ppb | Sb 123 1648.3 0.19385 ppb | Ba 135 723.4 0.2286 ppb | Ba 137 1225.1 0.20085 ppb |> Ho 165 1035275.4 ppb | Tl 205 7180.2 0.194 ppb | Pb 206 2864.5 0.21679 ppb | Pb 207 2507.3 0.21856 ppb |- Pb 208 11386.5 0.21712 ppb Kr 83 13.4 ppb ICP-Data 5 of 17 elementOne e 23952-Metals 47.5 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 9 Sample DatThursday, February 05, 2015 17:54:33 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 68357.8 ppb | Be 9 1.3 -0.00366 ppb | B 10 1200.4 3.41325 ppb | B 11 5465 3.57569 ppb | Mg 24 4444.8 0.90007 ppb | Mg 25 622.4 0.89446 ppb | Al 27 13542.8 1.92708 ppb | Ca 44 17447.7 -7.32508 ppb | Sc 45 251559.3 ppb | Cr 52 14430.5 0.5407 ppb | Cr 53 65577.1 35.31882 ppb | Fe 54 43565.9 8.0955 ppb | Mn 55 1395.8 0.04601 ppb | Fe 57 5681.4 -2.28814 ppb |- Co 59 2007.2 0.1294 ppb |- Ni 60 89.7 -0.04996 ppb | Cu 63 1029.4 0.12946 ppb | Cu 65 506.3 0.13102 ppb | Zn 66 9457.9 4.82199 ppb | Zn 67 9130.4 24.26718 ppb | Zn 68 8267.1 4.92663 ppb | As 75 -2007 -0.78198 ppb | Se 77 8532.7 37.76924 ppb | Se 82 80.3 0.09316 ppb | Sr 88 489 0.00869 ppb | Mo 95 2637.8 -0.40744 ppb | Mo 97 1654.9 -0.40393 ppb | Mo 98 4303.1 -0.36543 ppb |> Rh 103 524778.6 ppb | Cd 111 10.6 -0.00101 ppb |- Cd 114 31.6 -0.00101 ppb |- Sb 121 2267.3 0.20024 ppb | Sb 123 1702.4 0.19422 ppb | Ba 135 304.3 0.06888 ppb | Ba 137 553.4 0.06823 ppb |> Ho 165 1068506.4 ppb | Tl 205 280 0.00167 ppb | Pb 206 529.7 0.01825 ppb | Pb 207 450.7 0.01989 ppb |- Pb 208 2035.1 0.01833 ppb Kr 83 35.4 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 10 Sample DatThursday, February 05, 2015 17:58:01 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 62502 ppb | Be 9 18706.2 48.52212 ppb | B 10 7745 65.54608 ppb | B 11 34832.6 63.92035 ppb | Mg 24 1870143.2 513.7096 ppb | Mg 25 268488 511.8147 ppb | Al 27 298699.8 50.51767 ppb | Ca 44 197843.7 553.047 ppb | Sc 45 248733.5 ppb | Cr 52 473178.9 45.18048 ppb | Cr 53 135124.3 101.3987 ppb | Fe 54 460473 507.2931 ppb | Mn 55 727504 43.6301 ppb | Fe 57 173254.1 542.522 ppb |- Co 59 601308.4 44.32929 ppb |- Ni 60 129075.2 53.29563 ppb | Cu 63 305147.8 49.31209 ppb | Cu 65 149542.3 53.48862 ppb | Zn 66 90224.2 52.70697 ppb | Zn 67 26278 85.32387 ppb | Zn 68 67489.3 52.38333 ppb | As 75 93483.9 47.43833 ppb | Se 77 16668.9 86.93498 ppb | Se 82 10371.8 45.08875 ppb | Sr 88 1378439.4 45.56422 ppb | Mo 95 197943.1 53.57042 ppb | Mo 97 124350.1 53.44767 ppb | Mo 98 320891.8 48.567 ppb |> Rh 103 509475 ppb | Cd 111 130286.9 48.7803 ppb |- Cd 114 308177.6 43.86641 ppb |- Sb 121 443100.5 45.61931 ppb | Sb 123 338190.5 45.64913 ppb | Ba 135 138062.8 50.72217 ppb | Ba 137 242678.5 46.05848 ppb |> Ho 165 1049684 ppb | Tl 205 1630816.1 44.75134 ppb | Pb 206 567506.8 47.24831 ppb | Pb 207 490537.7 46.41615 ppb |- Pb 208 2253131.1 46.91299 ppb Kr 83 -9290.5 ppb ICP-Data 6 of 17 elementOne e 23952-Metals 47.6 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC STD2 Sample DatThursday, February 05, 2015 18:01:30 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 55582.5 ppb | Be 9 361.7 1.0478 ppb | B 10 1206.1 5.83321 ppb | B 11 5471.3 5.92745 ppb | Mg 24 63091.9 19.29006 ppb | Mg 25 9039.8 19.19888 ppb | Al 27 6574.4 1.08155 ppb | Ca 44 24064.8 26.98098 ppb | Sc 45 216981.7 ppb | Cr 52 18186.8 1.247 ppb | Cr 53 32948.6 15.40794 ppb | Fe 54 43130.1 18.43541 ppb | Mn 55 15287.2 1.00159 ppb | Fe 57 10161 17.92995 ppb |- Co 59 11733.6 0.96723 ppb |- Ni 60 2562.7 0.97499 ppb | Cu 63 6337.2 0.99367 ppb | Cu 65 3096.2 1.06485 ppb | Zn 66 2793.1 1.04663 ppb | Zn 67 4312.7 8.46569 ppb | Zn 68 3427 1.26154 ppb | As 75 1627 1.02748 ppb | Se 77 2429.3 3.4798 ppb | Se 82 266.9 0.9196 ppb | Sr 88 28017.1 0.92031 ppb | Mo 95 6207.8 0.60485 ppb | Mo 97 3900.5 0.60697 ppb | Mo 98 9970.3 0.53381 ppb |> Rh 103 508986.4 ppb | Cd 111 2772 1.03414 ppb |- Cd 114 6463 0.91569 ppb |- Sb 121 10022.5 1.03865 ppb | Sb 123 7661.8 1.03859 ppb | Ba 135 2954.8 1.08265 ppb | Ba 137 5230.5 0.99242 ppb |> Ho 165 1014891.6 ppb | Tl 205 33879.7 0.95588 ppb | Pb 206 11200.2 0.93993 ppb | Pb 207 9862.7 0.9438 ppb |- Pb 208 44904.1 0.94423 ppb Kr 83 -140.7 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatThursday, February 05, 2015 19:17:50 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 64186.9 ppb | Be 9 2.3 -0.00087 ppb | B 10 1991.2 11.23975 ppb | B 11 9317.2 11.7723 ppb | Mg 24 2555.7 0.46637 ppb | Mg 25 373.7 0.50227 ppb | Al 27 4823.3 0.62313 ppb | Ca 44 30762.3 35.82727 ppb | Sc 45 202309.8 ppb | Cr 52 15037.8 0.68203 ppb | Cr 53 64319.9 37.76339 ppb | Fe 54 35940 2.36841 ppb | Mn 55 1948.9 0.08326 ppb | Fe 57 5932.6 -0.39898 ppb |- Co 59 75 -0.00047 ppb |- Ni 60 725 0.15295 ppb | Cu 63 694.7 0.05718 ppb | Cu 65 394 0.06733 ppb | Zn 66 11719.2 4.90964 ppb | Zn 67 8270.4 16.38373 ppb | Zn 68 10416.6 5.14389 ppb | As 75 -1090.9 -0.23365 ppb | Se 77 6389.2 19.04839 ppb | Se 82 16.2 -0.19067 ppb | Sr 88 1128.4 0.02272 ppb | Mo 95 236.7 -1.05628 ppb | Mo 97 151 -1.04918 ppb | Mo 98 342.6 -0.96261 ppb |> Rh 103 639574.5 ppb | Cd 111 26.8 0.00311 ppb |- Cd 114 36.3 -0.00125 ppb |- Sb 121 2966.5 0.21974 ppb | Sb 123 2296.2 0.22108 ppb | Ba 135 299.3 0.04828 ppb | Ba 137 516.3 0.04445 ppb |> Ho 165 1294983.3 ppb | Tl 205 176.7 -0.00196 ppb | Pb 206 485.3 0.0077 ppb | Pb 207 426.7 0.01074 ppb |- Pb 208 1984.4 0.01021 ppb Kr 83 41 ppb ICP-Data 7 of 17 elementOne e 23952-Metals 47.7 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatThursday, February 05, 2015 19:21:18 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 56752.6 ppb | Be 9 34050 97.33415 ppb | B 10 10459.7 100.8775 ppb | B 11 50418.8 105.7703 ppb | Mg 24 3669380.3 1110.8 ppb | Mg 25 466598.6 980.0281 ppb | Al 27 505785.8 94.2686 ppb | Ca 44 355984 1151.435 ppb | Sc 45 236515.4 ppb | Cr 52 972850.8 103.2502 ppb | Cr 53 162392.8 139.8204 ppb | Fe 54 891235.6 1125.564 ppb | Mn 55 1589136.8 105.0111 ppb | Fe 57 352307.7 1238.569 ppb |- Co 59 1249499.9 101.4529 ppb |- Ni 60 262342.4 92.52654 ppb | Cu 63 610549.3 84.25077 ppb | Cu 65 304218.7 92.92333 ppb | Zn 66 184180.2 92.28273 ppb | Zn 67 35881.1 100.5534 ppb | Zn 68 140784.8 94.41071 ppb | As 75 226618.1 97.94565 ppb | Se 77 23623 107.3978 ppb | Se 82 25930.9 96.49074 ppb | Sr 88 3674134.5 103.6867 ppb | Mo 95 433217.7 101.0088 ppb | Mo 97 272703.8 100.9828 ppb | Mo 98 705306.5 91.96625 ppb |> Rh 103 596835.6 ppb | Cd 111 314378.4 100.4786 ppb |- Cd 114 745110.5 90.52423 ppb |- Sb 121 1063509.6 94.14358 ppb | Sb 123 816494.6 94.76349 ppb | Ba 135 326813.9 103.2469 ppb | Ba 137 571786.8 93.31725 ppb |> Ho 165 1221174.1 ppb | Tl 205 4562969.8 107.6428 ppb | Pb 206 1294499 92.66072 ppb | Pb 207 1130276.3 91.9486 ppb |- Pb 208 5617395.8 100.5614 ppb Kr 83 -24845 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: 23952-1.1 Sample DatThursday, February 05, 2015 19:45:35 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 58676.6 ppb | Be 9 20.3 0.04939 ppb | B 10 2110.9 14.16531 ppb | B 11 9826.6 14.6274 ppb | Mg 24 1904915 557.3494 ppb | Mg 25 272906.1 554.0281 ppb | Al 27 1291190.2 233.1939 ppb | Ca 44 1149854.4 3715.697 ppb | Sc 45 296600.9 ppb | Cr 52 38766.5 3.26777 ppb | Cr 53 183900.8 154.7434 ppb | Fe 54 115534.7 106.8607 ppb | Mn 55 423774 27.05331 ppb | Fe 57 25717.3 69.65664 ppb |- Co 59 5201.8 0.40256 ppb |- Ni 60 1155.4 0.31993 ppb | Cu 63 20934.4 2.84304 ppb | Cu 65 10397.6 3.11605 ppb | Zn 66 31941.7 15.42302 ppb | Zn 67 23671.2 63.69715 ppb | Zn 68 27334 17.05045 ppb | As 75 -3753.4 -1.40598 ppb | Se 77 24477.3 111.0383 ppb | Se 82 114.1 0.1764 ppb | Sr 88 526012.7 14.76227 ppb | Mo 95 1610.5 -0.73167 ppb | Mo 97 1043.1 -0.71446 ppb | Mo 98 2646.3 -0.65864 ppb |> Rh 103 599856.3 ppb | Cd 111 164 0.04734 ppb |- Cd 114 324.2 0.03386 ppb |- Sb 121 3888.5 0.30897 ppb | Sb 123 3045.6 0.31551 ppb | Ba 135 118919.1 36.94618 ppb | Ba 137 208897.2 33.52739 ppb |> Ho 165 1241059.4 ppb | Tl 205 594.4 0.00796 ppb | Pb 206 10146 0.6899 ppb | Pb 207 8585.7 0.66574 ppb |- Pb 208 39887 0.67965 ppb Kr 83 -3503.6 ppb ICP-Data 8 of 17 elementOne e 23952-Metals 47.8 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: 23952-1.1 Sample DatThursday, February 05, 2015 19:49:03 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 52477.8 ppb | Be 9 24.3 0.06838 ppb | B 10 1784.8 13.02425 ppb | B 11 8621.1 14.23033 ppb | Mg 24 1784377.2 583.8747 ppb | Mg 25 254768 578.3298 ppb | Al 27 1213667.4 245.1031 ppb | Ca 44 1088758.6 3937.261 ppb | Sc 45 265182.3 ppb | Cr 52 37999.6 3.65334 ppb | Cr 53 197713.7 189.549 ppb | Fe 54 109975.3 116.2895 ppb | Mn 55 409952 29.26355 ppb | Fe 57 24122 74.01164 ppb |- Co 59 4991.7 0.4324 ppb |- Ni 60 1203.7 0.36449 ppb | Cu 63 19787.2 2.86297 ppb | Cu 65 9918.4 3.16771 ppb | Zn 66 29082.4 14.94293 ppb | Zn 67 23811.2 68.76496 ppb | Zn 68 25228 16.73981 ppb | As 75 -2907.5 -1.12408 ppb | Se 77 26121.8 127.7571 ppb | Se 82 71.7 0.03597 ppb | Sr 88 503079.3 15.0412 ppb | Mo 95 583.7 -0.96267 ppb | Mo 97 390.3 -0.94712 ppb | Mo 98 921.8 -0.8761 ppb |> Rh 103 563059.2 ppb | Cd 111 185.6 0.05803 ppb |- Cd 114 263.4 0.02855 ppb |- Sb 121 2669.7 0.22417 ppb | Sb 123 2020.1 0.21967 ppb | Ba 135 113834 38.50592 ppb | Ba 137 197437 34.50217 ppb |> Ho 165 1139733.7 ppb | Tl 205 439 0.00521 ppb | Pb 206 9604.4 0.71178 ppb | Pb 207 8221 0.69481 ppb |- Pb 208 37487.4 0.69595 ppb Kr 83 -3334.7 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: 23952-2.1 Sample DatThursday, February 05, 2015 19:52:31 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 52869.8 ppb | Be 9 22 0.06051 ppb | B 10 2697.1 22.96031 ppb | B 11 12728.2 23.8928 ppb | Mg 24 3195165.3 1037.719 ppb | Mg 25 405353.8 913.4477 ppb | Al 27 651712.5 130.5716 ppb | Ca 44 1192169.1 4284.932 ppb | Sc 45 252318.4 ppb | Cr 52 36395.4 3.43529 ppb | Cr 53 200733.8 191.0756 ppb | Fe 54 120417.3 129.772 ppb | Mn 55 364874.2 25.84938 ppb | Fe 57 29125.9 92.47732 ppb |- Co 59 3857.2 0.33029 ppb |- Ni 60 6815.2 2.38649 ppb | Cu 63 11492.3 1.59756 ppb | Cu 65 5627.1 1.722 ppb | Zn 66 21936.4 10.76463 ppb | Zn 67 23035.9 64.06605 ppb | Zn 68 20205.4 12.66851 ppb | As 75 -2934.3 -1.0964 ppb | Se 77 26374.9 124.8093 ppb | Se 82 86.7 0.0855 ppb | Sr 88 784054.8 22.7289 ppb | Mo 95 388.7 -1.01467 ppb | Mo 97 261 -1.00202 ppb | Mo 98 609.2 -0.92263 ppb |> Rh 103 580771.1 ppb | Cd 111 142.2 0.04182 ppb |- Cd 114 329.2 0.03573 ppb |- Sb 121 2034.2 0.15705 ppb | Sb 123 1638.1 0.16495 ppb | Ba 135 146021.5 47.71646 ppb | Ba 137 258540.4 43.64069 ppb |> Ho 165 1180201.4 ppb | Tl 205 573.4 0.00811 ppb | Pb 206 48196.8 3.54585 ppb | Pb 207 40282.4 3.36996 ppb |- Pb 208 187155.6 3.44458 ppb Kr 83 -5245.3 ppb ICP-Data 9 of 17 elementOne e 23952-Metals 47.9 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: 23952-3.1 Sample DatThursday, February 05, 2015 19:55:59 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 58599.2 ppb | Be 9 58 0.154 ppb | B 10 1863.9 11.72122 ppb | B 11 8518.7 11.83748 ppb | Mg 24 2044495.5 597.8557 ppb | Mg 25 279610.9 568.6862 ppb | Al 27 1424163.8 257.682 ppb | Ca 44 815786.9 2627.629 ppb | Sc 45 269055.5 ppb | Cr 52 37697.8 3.17099 ppb | Cr 53 198449.8 169.2323 ppb | Fe 54 87112.5 71.35266 ppb | Mn 55 470140.1 30.10414 ppb | Fe 57 12717.6 24.9044 ppb |- Co 59 2204.9 0.16805 ppb |- Ni 60 716.4 0.16362 ppb | Cu 63 12136.8 1.62284 ppb | Cu 65 6033 1.77777 ppb | Zn 66 21470.7 10.09345 ppb | Zn 67 23286.2 62.07339 ppb | Zn 68 20875.3 12.57262 ppb | As 75 -2798.2 -0.99448 ppb | Se 77 26572.5 120.7131 ppb | Se 82 72 0.01808 ppb | Sr 88 632642.6 17.64087 ppb | Mo 95 344.3 -1.02905 ppb | Mo 97 211.7 -1.02474 ppb | Mo 98 482.7 -0.94271 ppb |> Rh 103 603785 ppb | Cd 111 245.8 0.07285 ppb |- Cd 114 441.3 0.04761 ppb |- Sb 121 1802.8 0.12608 ppb | Sb 123 1430.8 0.12987 ppb | Ba 135 232871.7 71.66843 ppb | Ba 137 407212.7 64.74198 ppb |> Ho 165 1253242.4 ppb | Tl 205 679.7 0.00973 ppb | Pb 206 12608.7 0.85442 ppb | Pb 207 11063.7 0.85516 ppb |- Pb 208 50539.2 0.8584 ppb Kr 83 -4217.6 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatThursday, February 05, 2015 19:59:29 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 64829.7 ppb | Be 9 3.3 0.00146 ppb | B 10 562 -1.78317 ppb | B 11 2638.4 -1.39299 ppb | Mg 24 2393.3 0.41875 ppb | Mg 25 340.3 0.43709 ppb | Al 27 4966.7 0.63953 ppb | Ca 44 30163.3 33.26451 ppb | Sc 45 204230.3 ppb | Cr 52 15273.5 0.69136 ppb | Cr 53 66396.8 39.13482 ppb | Fe 54 36258.2 2.33083 ppb | Mn 55 1951.2 0.08235 ppb | Fe 57 5933.6 -0.58391 ppb |- Co 59 72 -0.00074 ppb |- Ni 60 753.4 0.16215 ppb | Cu 63 657 0.05224 ppb | Cu 65 374 0.06157 ppb | Zn 66 11718.2 4.90376 ppb | Zn 67 8271.4 16.42293 ppb | Zn 68 10427.3 5.14537 ppb | As 75 -857.3 -0.13707 ppb | Se 77 6383.9 19.03287 ppb | Se 82 15.6 -0.19226 ppb | Sr 88 1190.4 0.02438 ppb | Mo 95 191 -1.06685 ppb | Mo 97 129.3 -1.05728 ppb | Mo 98 292.6 -0.96919 ppb |> Rh 103 640141.4 ppb | Cd 111 18.2 0.00055 ppb |- Cd 114 45.3 -0.00025 ppb |- Sb 121 327 -0.00266 ppb | Sb 123 264.2 -0.00355 ppb | Ba 135 330.3 0.05482 ppb | Ba 137 578.7 0.05179 ppb |> Ho 165 1329995.6 ppb | Tl 205 177.7 -0.00204 ppb | Pb 206 507 0.00826 ppb | Pb 207 438 0.01074 ppb |- Pb 208 2009.8 0.00974 ppb Kr 83 38.3 ppb ICP-Data 10 of 17 elementOne e 23952-Metals 47.10 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatThursday, February 05, 2015 20:02:57 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit |> Li 6 59708.8 ppb | Be 9 35022.3 95.12493 ppb | B 10 10442.7 95.3712 ppb | B 11 49156.6 97.55895 ppb | Mg 24 3798564.1 1092.796 ppb | Mg 25 480940.1 959.864 ppb | Al 27 501923.4 88.99219 ppb | Ca 44 367398 1128.389 ppb | Sc 45 247315.1 ppb | Cr 52 1009599 101.8296 ppb | Cr 53 167992.3 137.2025 ppb | Fe 54 937008.5 1124.792 ppb | Mn 55 1647443.3 103.4566 ppb | Fe 57 368656.8 1231.782 ppb |- Co 59 1298082.8 100.1872 ppb |- Ni 60 274081.6 93.79031 ppb | Cu 63 633584.1 84.81305 ppb | Cu 65 315605.8 93.49752 ppb | Zn 66 192980.5 93.80016 ppb | Zn 67 37648.5 102.4698 ppb | Zn 68 147647.9 96.08677 ppb | As 75 234669.6 98.38865 ppb | Se 77 25158.1 111.3232 ppb | Se 82 27201.9 98.21874 ppb | Sr 88 3850844.9 105.4086 ppb | Mo 95 454704.1 102.8896 ppb | Mo 97 283698.7 101.9308 ppb | Mo 98 730984 92.49501 ppb |> Rh 103 615314.6 ppb | Cd 111 332610.8 103.1398 ppb |- Cd 114 785988.1 92.64646 ppb |- Sb 121 1101259.4 92.7952 ppb | Sb 123 843229.4 93.15526 ppb | Ba 135 339513.6 102.0957 ppb | Ba 137 592930.4 92.10503 ppb |> Ho 165 1282953.2 ppb | Tl 205 4845158.8 108.7928 ppb | Pb 206 1367977.7 93.20754 ppb | Pb 207 1202726.8 93.13513 ppb |- Pb 208 5971492.8 101.7567 ppb Kr 83 -26044.2 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: Blank Sample DatFriday, February 06, 2015 09:32:17 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 46947.6 ppb |- K 39 446633.6 ppb | Sc 45 270730.3 ppb |> Rh 103 633653.8 ppb Ho 165 1186121.5 ppb Kr 83 51.8 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 1 Sample DatFriday, February 06, 2015 09:34:00 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 50889.9 ppb |- K 39 668093.3 16.45046 ppb | Sc 45 295282.3 ppb |> Rh 103 646138.8 ppb Ho 165 1208572.9 ppb Kr 83 -196.4 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 2 Sample DatFriday, February 06, 2015 09:35:42 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 51851.1 ppb |- K 39 15193404 1096.806 ppb | Sc 45 296947.5 ppb |> Rh 103 669729.4 ppb Ho 165 1263149.7 ppb Kr 83 -28093 ppb ICP-Data 11 of 17 elementOne e 23952-Metals 47.11 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 3 Sample DatFriday, February 06, 2015 09:37:25 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 50105.6 ppb |- K 39 71539287 5500.656 ppb | Sc 45 304249.2 ppb |> Rh 103 644599.5 ppb Ho 165 1248889.5 ppb Kr 83 -137662.6 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatFriday, February 06, 2015 09:39:08 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 48858.5 ppb |- K 39 431900 -3.10391 ppb | Sc 45 277075.3 ppb |> Rh 103 672568.1 ppb Ho 165 1237993.3 ppb Kr 83 22.6 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 2 Sample DatFriday, February 06, 2015 09:40:51 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 47334.5 ppb |- K 39 665845.3 14.78399 ppb | Sc 45 293376.3 ppb |> Rh 103 665493.7 ppb Ho 165 1212240.1 ppb Kr 83 -197.1 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 3 Sample DatFriday, February 06, 2015 09:42:34 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 41165.8 ppb |- K 39 28473134 2429.608 ppb | Sc 45 270016.3 ppb |> Rh 103 576350.8 ppb Ho 165 1085011.1 ppb Kr 83 -59894.7 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatFriday, February 06, 2015 09:44:17 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 43870.8 ppb |- K 39 14196448 1098.396 ppb | Sc 45 257746.5 ppb |> Rh 103 624794.8 ppb Ho 165 1161668.8 ppb Kr 83 -26736 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 5 Sample DatFriday, February 06, 2015 09:46:00 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 44377 ppb |- K 39 3071682 203.85 ppb | Sc 45 276299.5 ppb |> Rh 103 641386.6 ppb Ho 165 1185280.2 ppb Kr 83 56.9 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 9 Sample DatFriday, February 06, 2015 09:47:43 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 46132.5 ppb |- K 39 442310.6 0.96627 ppb | Sc 45 275450.5 ppb |> Rh 103 611046.4 ppb Ho 165 1117853.8 ppb Kr 83 69.9 ppb ICP-Data 12 of 17 elementOne e 23952-Metals 47.12 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 10 Sample DatFriday, February 06, 2015 09:49:26 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 45428.1 ppb |- K 39 6737079.3 519.2547 ppb | Sc 45 277203.6 ppb |> Rh 103 606304.8 ppb Ho 165 1135602.1 ppb Kr 83 -11397.7 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC STD2 Sample DatFriday, February 06, 2015 09:51:10 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 42445.4 ppb |- K 39 661626.3 20.15483 ppb | Sc 45 256509.3 ppb |> Rh 103 596826.8 ppb Ho 165 1099865.2 ppb Kr 83 -167.6 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: 23952-1.1 Sample DatFriday, February 06, 2015 10:06:37 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 53848.5 ppb |- K 39 8799997.1 718.3664 ppb | Sc 45 315832.4 ppb |> Rh 103 582574.5 ppb Ho 165 1176655.6 ppb Kr 83 -3464.7 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: 23952-1.1 Sample DatFriday, February 06, 2015 10:08:19 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 50049.3 ppb |- K 39 8444600.9 733.8359 ppb | Sc 45 283993.4 ppb |> Rh 103 547812.5 ppb Ho 165 1095356.8 ppb Kr 83 -3331.4 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatFriday, February 06, 2015 10:10:03 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 47479.5 ppb |- K 39 417017.2 0.17293 ppb | Sc 45 239045.5 ppb |> Rh 103 589269.2 ppb Ho 165 1124597.8 ppb Kr 83 66.5 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatFriday, February 06, 2015 10:11:46 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 44759.1 ppb |- K 39 12936347 1088.839 ppb | Sc 45 248574.4 ppb |> Rh 103 574363.7 ppb Ho 165 1101631.6 ppb Kr 83 -24609.3 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: 23952-2.1 Sample DatFriday, February 06, 2015 10:13:30 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 49578.3 ppb |- K 39 11497902 995.8497 ppb | Sc 45 276451.9 ppb |> Rh 103 556435.9 ppb Ho 165 1116317.9 ppb Kr 83 -5200.8 ppb ICP-Data 13 of 17 elementOne e 23952-Metals 47.13 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: 23952-3.1 Sample DatFriday, February 06, 2015 10:15:13 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 49657 ppb |- K 39 12216911 1056.82 ppb | Sc 45 268511.9 ppb |> Rh 103 558076.9 ppb Ho 165 1130225.3 ppb Kr 83 -3956.6 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatFriday, February 06, 2015 10:22:19 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 59874.8 ppb |- K 39 373361 -4.704 ppb | Sc 45 268966.1 ppb |> Rh 103 612190.2 ppb Ho 165 1225742.3 ppb Kr 83 54.1 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatFriday, February 06, 2015 10:24:02 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 60257.3 ppb |- K 39 13859446 1101.629 ppb | Sc 45 279173.8 ppb |> Rh 103 608189.8 ppb Ho 165 1231587.3 ppb Kr 83 -26694.7 ppb Method 6020 & 200.8 Metals Summary Report Sample ID: Blank Sample DatMonday, February 23, 2015 14:42:08 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 42656.3 ppb |- Sc 45 197567.2 ppb | V-1 51 50517.3 ppb | V 51 51441.2 ppb |> Rh 103 485687 ppb Ho 165 921580.8 ppb Kr 83 50.8 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 1 Sample DatMonday, February 23, 2015 14:43:19 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 44153.2 ppb |- Sc 45 200987.5 ppb | V-1 51 51943.9 1 ppb | V 51 62315.4 1 ppb |> Rh 103 494876.2 ppb Ho 165 928689.1 ppb Kr 83 46.3 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 2 Sample DatMonday, February 23, 2015 14:44:31 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 45435.5 ppb |- Sc 45 208166.2 ppb | V-1 51 134984.1 10.09005 ppb | V 51 232415.2 10.04179 ppb |> Rh 103 502468.7 ppb Ho 165 954074.4 ppb Kr 83 39 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: Standard 3 Sample DatMonday, February 23, 2015 14:45:43 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 42865.2 ppb |- Sc 45 199255.3 ppb | V-1 51 313518.8 30.32035 ppb | V 51 589053.5 30.13919 ppb |> Rh 103 482057.9 ppb Ho 165 913625 ppb Kr 83 33.9 mg/L ICP-Data 14 of 17 elementOne e 23952-Metals 47.14 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatMonday, February 23, 2015 14:46:54 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 41979.7 ppb |- Sc 45 195446.4 ppb | V-1 51 38422.4 ppb | V 51 39005.8 ppb |> Rh 103 472214 ppb Ho 165 883997 ppb Kr 83 37.5 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 2 Sample DatMonday, February 23, 2015 14:48:06 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 40184.9 ppb |- Sc 45 186434.6 ppb | V-1 51 40778.6 0.44168 ppb | V 51 43953.8 0.36785 ppb |> Rh 103 459223.7 ppb Ho 165 865634.3 ppb Kr 83 43.7 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 3 Sample DatMonday, February 23, 2015 14:49:18 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 39678 ppb |- Sc 45 187291.7 ppb | V-1 51 46632.3 1.2349 ppb | V 51 55726.6 1.10947 ppb |> Rh 103 452507.3 ppb Ho 165 858184.3 ppb Kr 83 51.5 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatMonday, February 23, 2015 14:50:30 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 39010.1 ppb |- Sc 45 183088.8 ppb | V-1 51 123900.4 10.84304 ppb | V 51 210755.3 10.47744 ppb |> Rh 103 448116.9 ppb Ho 165 838962.2 ppb Kr 83 51.3 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 5 Sample DatMonday, February 23, 2015 14:51:42 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 37966.9 ppb |- Sc 45 176961.3 ppb | V-1 51 243359.3 26.48663 ppb | V 51 449020.2 25.59769 ppb |> Rh 103 435985 ppb Ho 165 814923.7 ppb Kr 83 39.8 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 9 Sample DatMonday, February 23, 2015 14:52:56 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 39255 ppb |- Sc 45 175424.8 ppb | V-1 51 38352.5 0.25546 ppb | V 51 39203.5 0.14416 ppb |> Rh 103 448798.2 ppb Ho 165 836247.6 ppb Kr 83 30.2 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 10 Sample DatMonday, February 23, 2015 14:54:07 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 38607 ppb |- Sc 45 193326.5 ppb | V-1 51 82659.1 5.9827 ppb | V 51 127029.6 5.61422 ppb |> Rh 103 438383.1 ppb Ho 165 826999 ppb Kr 83 -797.9 mg/L ICP-Data 15 of 17 elementOne e 23952-Metals 47.15 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatMonday, February 23, 2015 14:55:21 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 36725.8 ppb |- Sc 45 172514.7 ppb | V-1 51 38608.6 0.5431 ppb | V 51 39207.5 0.26892 ppb |> Rh 103 426541.9 ppb Ho 165 801244.8 ppb Kr 83 48 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatMonday, February 23, 2015 14:56:33 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 36441.2 ppb |- Sc 45 174521.3 ppb | V-1 51 38899.4 0.58142 ppb | V 51 39718.3 0.29917 ppb |> Rh 103 426932.6 ppb Ho 165 795337.1 ppb Kr 83 43.1 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 2 Sample DatMonday, February 23, 2015 14:57:45 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 35867.1 ppb |- Sc 45 171053.5 ppb | V-1 51 41134.1 1.00185 ppb | V 51 44229 0.65377 ppb |> Rh 103 416488.7 ppb Ho 165 769354.2 ppb Kr 83 45.2 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatMonday, February 23, 2015 14:58:58 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 35681.6 ppb |- Sc 45 171710.5 ppb | V-1 51 39001.5 0.69621 ppb | V 51 39385.1 0.33022 ppb |> Rh 103 417223.5 ppb Ho 165 777542.2 ppb Kr 83 41.5 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatMonday, February 23, 2015 15:00:10 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 35742.8 ppb |- Sc 45 168287.6 ppb | V-1 51 116599.6 11.14537 ppb | V 51 195129 10.51363 ppb |> Rh 103 413670.3 ppb Ho 165 772306.1 ppb Kr 83 45.7 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: 23952-1 Sample DatMonday, February 23, 2015 15:01:53 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 41229.2 ppb |- Sc 45 199370.4 ppb | V-1 51 40948 0.45292 ppb | V 51 43013 0.30766 ppb |> Rh 103 460727.4 ppb Ho 165 888083.1 ppb Kr 83 -2586.8 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: 23952-1 Sample DatMonday, February 23, 2015 15:03:05 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 41605.8 ppb |- Sc 45 196279.4 ppb | V-1 51 37989.8 0.18975 ppb | V 51 39550.8 0.15222 ppb |> Rh 103 451752.8 ppb Ho 165 871809 ppb Kr 83 -2607.1 mg/L ICP-Data 16 of 17 elementOne e 23952-Metals 47.16 PerkinElmer ELAN 6100 ICP-MS Method 6020 & 200.8 Metals Summary Report Sample ID: 23952-2 Sample DatMonday, February 23, 2015 15:04:16 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 44552.5 ppb |- Sc 45 206193.1 ppb | V-1 51 35842.3 -0.27534 ppb | V 51 38522 -0.01426 ppb |> Rh 103 472404.2 ppb Ho 165 923502.3 ppb Kr 83 -4256.8 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: 23952-2 Sample DatMonday, February 23, 2015 15:05:28 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 46632.1 ppb |- Sc 45 226013.8 ppb | V-1 51 84633.2 5.05338 ppb | V 51 137454.4 5.32337 ppb |> Rh 103 492328.3 ppb Ho 165 960579.2 ppb Kr 83 -5369.2 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: 23952-3 Sample DatMonday, February 23, 2015 15:06:40 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 48770.5 ppb |- Sc 45 218692.5 ppb | V-1 51 32535.3 -0.91831 ppb | V 51 35242.9 -0.33587 ppb |> Rh 103 505565.5 ppb Ho 165 980005.3 ppb Kr 83 -3447.4 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 1 Sample DatMonday, February 23, 2015 15:07:54 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 45547.4 ppb |- Sc 45 200962.9 ppb | V-1 51 32236.3 -0.80398 ppb | V 51 33416.4 -0.36073 ppb |> Rh 103 486718.8 ppb Ho 165 921651.7 ppb Kr 83 41 mg/L Method 6020 & 200.8 Metals Summary Report Sample ID: QC Std 4 Sample DatMonday, February 23, 2015 15:09:06 Sample Description: Concentration Results Analyte Mass Meas. IntensConc. MeanReport Unit Li 6 43466.3 ppb |- Sc 45 194959.5 ppb | V-1 51 122530.3 9.98654 ppb | V 51 212888.6 10.02008 ppb |> Rh 103 469551.6 ppb Ho 165 887915.5 ppb Kr 83 35.6 mg/L ICP-Data 17 of 17 elementOne e 23952-Metals 47.17 PerkinElmer FIMS-100 CVAA Mercury Analyzer Sample_ID Date Time Mean_Sig Mean_Rd Mean_Rt Units Alq.Vol. Sig 1 Reading-1 Result-1 Sig 2 Reading-2 Result-2 Calib Blank 2/6/2015 10:19:23 AM 0.0002182 µg 0.0002859 0.0001504 STD1 = .004ug 2/6/2015 10:21:03 AM 0.0012732 µg 0.0012426 0.0013037 STD2 = .04ug 2/6/2015 10:22:45 AM 0.0129182 µg 0.0129063 0.0129301 STD3 = .08ug 2/6/2015 10:24:38 AM 0.0266981 µg 0.0267065 0.0266897 STD4 = .16ug 2/6/2015 10:26:32 AM 0.0528853 µg 0.0530862 0.0526844 STD5 = .2ug 2/6/2015 10:28:27 AM 0.0667245 µg 0.0669915 0.0664574 Reagent Blank 2/6/2015 10:30:20 AM -3.30E-07 -9.94E-07 -9.94E-07 µg 3.35E-05 0.0001007 0.0001007 -3.41E-05 -0.0001027 -0.0001027 0.004ug = DL 2/6/2015 10:32:00 AM 0.001369 0.0041193 0.0041193 µg 0.0013369 0.0040229 0.0040229 0.001401 0.0042157 0.0042157 0.080ug = QC STD 2 2/6/2015 10:33:44 AM 0.0271411 0.0816679 0.0816679 µg 0.0271352 0.0816502 0.0816502 0.0271469 0.0816856 0.0816856 0.080ug = QC STD 3 2/6/2015 10:35:41 AM 0.0267248 0.0804154 0.0804154 µg 0.0270516 0.0813987 0.0813987 0.026398 0.0794321 0.0794321 Reagent Blank 2/6/2015 10:37:35 AM 7.39E-05 0.0002224 0.0002224 µg 0.0001243 0.0003741 0.0003741 2.35E-05 7.07E-05 7.07E-05 0.004ug = DL 2/6/2015 10:58:12 AM 0.0013404 0.0040332 0.0040332 µg 0.0013467 0.0040523 0.0040523 0.001334 0.004014 0.004014 0.080ug = QC STD 2 2/6/2015 10:59:55 AM 0.0285981 0.0860523 0.0860523 µg 0.0286084 0.0860831 0.0860831 0.0285879 0.0860215 0.0860215 Reagent Blank 2/6/2015 11:01:49 AM 1.54E-05 4.64E-05 4.64E-05 µg 2.72E-05 8.17E-05 8.17E-05 3.69E-06 1.11E-05 1.11E-05 23952- 1.1 2/6/2015 11:10:36 AM 2.50E-06 8.52E-06 2.13E-07 µg 40 1 -2.32E-05 -6.87E-05 -1.72E-06 2.82E-05 8.57E-05 2.14E-06 23952- 2.1 2/6/2015 11:12:18 AM 5.55E-05 0.000168 4.20E-06 µg 40 1 5.01E-05 0.0001517 3.79E-06 6.09E-05 0.0001843 4.61E-06 23952- 2.1 DUP 2/6/2015 11:14:02 AM 0.0001185 0.0003575 8.94E-06 µg 40 1 0.0001235 0.0003726 9.31E-06 0.0001135 0.0003424 8.56E-06 23952- 3.1 2/6/2015 11:15:45 AM 6.31E-05 0.0001908 4.77E-06 µg 40 1 4.71E-05 0.0001428 3.57E-06 7.90E-05 0.0002388 5.97E-06 23952- 3.1 SPK 2/6/2015 11:17:28 AM 0.0292799 0.0881047 0.0022026 µg 40 1 0.0293077 0.0881882 0.0022047 0.0292521 0.0880211 0.0022005 0.004ug = DL 2/6/2015 11:21:06 AM 0.0013553 0.0040782 0.0040782 µg 0.001369 0.0041194 0.0041194 0.0013416 0.0040369 0.0040369 0.080ug = QC STD 2 2/6/2015 11:22:49 AM 0.0274498 0.0825968 0.0825968 µg 0.0274568 0.0826181 0.0826181 0.0274427 0.0825755 0.0825755 Reagent Blank 2/6/2015 11:24:43 AM -3.52E-05 -0.000106 -0.000106 µg -2.04E-05 -6.15E-05 -6.15E-05 -5.00E-05 -0.0001505 -0.0001505 Hg-Data 1 of 1 elementOne e 23952-Hg 48.1