NC0000396_J15070251report_20150823

DUE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Order Number: J15070251
Project Name: ASHEVILLE - AB GW ASSESSMENT WATER
Customer Name(s): Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker
Customer Address: 200 CP and L Drive
Arden,NC 28704
Lab Contact: Mary Ann Ogle mary.ogle@duke-
Phone: [phone]
a (� energy.com
Report Authorized By: 2015.07.16 16:28:19 Date:
(Signature) -0400'
Mary Ann Ogle
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
7/16/2015
Analytical Lab
Page 1 of 26
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Sample ID Plant/Station
2015022704 ASHEVILLE
2015022705 ASHEVILLE
2 Total Samples
Collection
Date and Time Collected By
Sample Description
07 -Jul -15 9:49 AM illegible CB -02
07 -Jul -15 2:25 PM illegible C13-413
Analytical Lab
Page 2 of 26

Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals 0 Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable. 0 Yes F-] No
Report Sections Included:
E%-'] Job Summary Report
❑� Sample Identification
Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Analytical Lab
Page 3 of 26
❑d Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Mary Ann Ogle Date: 7/16/2015

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070251
Site: CB -02
Collection Date: 07 -Jul -15 9:49 AM
Analyte Result Units Qualifiers RDL DF
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 2.2 mg-N/L 0.02 2
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg) < 0.05 ug/L
Analytical Lab
Page 4 of 26
Sample #: 2015022704
Matrix: GW WW
Method Analysis Date/Time Analyst
EPA 353.2 07/13/2015 11:40 LSTARL1
0.05 1 EPA 245.1 07/10/2015 13:39 ACPAYNE
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
1
EPA 245.1
07/14/2015 11:35
ACPAYNE
DISSOLVED METALS BY ICP
Aluminum (AI)
0.009
mg/L
0.005
1
EPA 200.7
07/09/2015 09:38
FCJORDA
Barium (Ba)
0.030
mg/L
0.005
1
EPA 200.7
07/09/2015 09:38
FCJORDA
Boron (B)
0.153
mg/L
0.05
1
EPA 200.7
07/09/2015 09:38
FCJORDA
Iron (Fe)
< 0.01
mg/L
0.01
1
EPA 200.7
07/09/2015 09:38
FCJORDA
Manganese (Mn)
2.93
mg/L
0.005
1
EPA 200.7
07/09/2015 09:38
FCJORDA
Strontium (Sr)
0.014
mg/L
0.005
1
EPA 200.7
07/09/2015 09:38
FCJORDA
Zinc (Zn)
0.020
mg/L
0.005
1
EPA 200.7
07/09/2015 09:38
FCJORDA
UNDIGESTED METALS BY ICP
Calcium (Ca)
9.34
mg/L
0.01
1
EPA 200.7
07/14/2015 11:59
FCJORDA
Magnesium (Mg)
3.36
mg/L
0.005
1
EPA 200.7
07/14/2015 11:59
FCJORDA
Potassium (K)
0.828
mg/L
0.1
1
EPA 200.7
07/14/2015 11:59
FCJORDA
Sodium (Na)
9.94
mg/L
0.05
1
EPA 200.7
07/14/2015 11:59
FCJORDA
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.158
mg/L
B1 0.005
1
EPA 200.7
07/14/2015 10:34
FCJORDA
Barium (Ba)
0.031
mg/L
0.005
1
EPA 200.7
07/14/2015 10:34
FCJORDA
Boron (B)
0.158
mg/L
0.05
1
EPA 200.7
07/14/2015 10:34
FCJORDA
Iron (Fe)
0.144
mg/L
0.01
1
EPA 200.7
07/14/2015 10:34
FCJORDA
Manganese (Mn)
2.94
mg/L
0.005
1
EPA 200.7
07/14/2015 10:34
FCJORDA
Strontium (Sr)
0.013
mg/L
0.005
1
EPA 200.7
07/14/2015 10:34
FCJORDA
Zinc (Zn)
0.008
mg/L
0.005
1
EPA 200.7
07/14/2015 10:34
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070251
Site: CB -02
Collection Date: 07 -Jul -15 9:49 AM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #: 2015022704
Matrix: GW WW
Analytical Lab
Page 5 of 26
RDL DF Method Analysis Date/Time Analyst
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 16:14
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 16:14
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 16:14
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 16:14
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 16:14
MHALL3
Cobalt (Co)
4.00
ug/L
1
1
EPA 200.8
07/13/2015 16:14
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 16:14
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 16:14
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 16:14
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 16:14
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 16:14
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
07/13/2015 16:14
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
07/13/2015 16:14
MHALL3
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
07/15/2015 16:13
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
07/15/2015 16:13
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
07/15/2015 16:13
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
07/15/2015 16:13
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
07/15/2015 16:13
JAHERMA
Cobalt (Co)
4.11
ug/L
1
1
EPA 200.8
07/15/2015 16:13
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
07/15/2015 16:13
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
07/15/2015 16:13
JAHERMA
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
07/15/2015 16:13
JAHERMA
Nickel (Ni)
<1
ug/L
1
1
EPA 200.8
07/15/2015 16:13
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
07/15/2015 16:13
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
07/15/2015 16:13
JAHERMA
Vanadium (V) Low Level
0.429
ug/L
0.3
1
EPA 200.8
07/15/2015 16:13
JAHERMA
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
Total Carbon
TOC 0.281 mg/L 0.1 1 SM5310C/EPA9060A 07/09/201514:22 GHUTCHI

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070251
Site: CB -4B
Collection Date: 07 -Jul -15 2:25 PM
Analyte Result Units Qualifiers RDL DF
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.032 mg-N/L 0.01 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg) < 0.05 ug/L
Analytical Lab
Page 6 of 26
Sample #: 2015022705
Matrix: GW WW
Method Analysis Date/Time Analyst
EPA 353.2 07/13/2015 11:17 LSTARL1
0.05 1 EPA 245.1 07/10/2015 13:51 ACPAYNE
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
1
EPA 245.1
07/14/2015 11:37
ACPAYNE
DISSOLVED METALS BY ICP
Aluminum (AI)
< 0.005
mg/L
0.005
1
EPA 200.7
07/09/2015 09:42
FCJORDA
Barium (Ba)
0.019
mg/L
0.005
1
EPA 200.7
07/09/2015 09:42
FCJORDA
Boron (B)
< 0.05
mg/L
0.05
1
EPA 200.7
07/09/2015 09:42
FCJORDA
Iron (Fe)
0.020
mg/L
0.01
1
EPA 200.7
07/09/2015 09:42
FCJORDA
Manganese (Mn)
0.034
mg/L
0.005
1
EPA 200.7
07/09/2015 09:42
FCJORDA
Strontium (Sr)
0.141
mg/L
0.005
1
EPA 200.7
07/09/2015 09:42
FCJORDA
Zinc (Zn)
0.113
mg/L
0.005
1
EPA 200.7
07/09/2015 09:42
FCJORDA
UNDIGESTED METALS BY ICP
Calcium (Ca)
18.7
mg/L
0.01
1
EPA 200.7
07/14/2015 12:02
FCJORDA
Magnesium (Mg)
4.43
mg/L
0.005
1
EPA 200.7
07/14/2015 12:02
FCJORDA
Potassium (K)
5.85
mg/L
0.1
1
EPA 200.7
07/14/2015 12:02
FCJORDA
Sodium (Na)
18.4
mg/L
0.05
1
EPA 200.7
07/14/2015 12:02
FCJORDA
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.043
mg/L
B 0.005
1
EPA 200.7
07/14/2015 10:38
FCJORDA
Barium (Ba)
0.020
mg/L
0.005
1
EPA 200.7
07/14/2015 10:38
FCJORDA
Boron (B)
< 0.05
mg/L
0.05
1
EPA 200.7
07/14/2015 10:38
FCJORDA
Iron (Fe)
0.313
mg/L
0.01
1
EPA 200.7
07/14/2015 10:38
FCJORDA
Manganese (Mn)
0.040
mg/L
0.005
1
EPA 200.7
07/14/2015 10:38
FCJORDA
Strontium (Sr)
0.144
mg/L
0.005
1
EPA 200.7
07/14/2015 10:38
FCJORDA
Zinc (Zn)
0.007
mg/L
0.005
1
EPA 200.7
07/14/2015 10:38
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070251
Site: C13-413
Collection Date: 07 -Jul -15 2:25 PM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #: 2015022705
Matrix: GW WW
Analytical Lab
Page 7 of 26
RDL DF Method Analysis Date/Time Analyst
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:15
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:15
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:15
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:15
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:15
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:15
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:15
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:15
MHALL3
Molybdenum (Mo)
7.78
ug/L
1
1
EPA 200.8
07/13/2015 15:15
MHALL3
Nickel (Ni)
2.06
ug/L
1
1
EPA 200.8
07/13/2015 15:15
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:15
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
07/13/2015 15:15
MHALL3
Vanadium (V) Low Level
0.421
ug/L
0.3
1
EPA 200.8
07/13/2015 15:15
MHALL3
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
07/15/2015 16:20
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
07/15/2015 16:20
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
07/15/2015 16:20
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
07/15/2015 16:20
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
07/15/2015 16:20
JAHERMA
Cobalt (Co)
<1
ug/L
1
1
EPA 200.8
07/15/2015 16:20
JAHERMA
Copper (Cu)
2.31
ug/L
1
1
EPA 200.8
07/15/2015 16:20
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
07/15/2015 16:20
JAHERMA
Molybdenum (Mo)
6.65
ug/L
1
1
EPA 200.8
07/15/2015 16:20
JAHERMA
Nickel (Ni)
1.75
ug/L
1
1
EPA 200.8
07/15/2015 16:20
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
07/15/2015 16:20
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
07/15/2015 16:20
JAHERMA
Vanadium (V) Low Level
0.798
ug/L
0.3
1
EPA 200.8
07/15/2015 16:20
JAHERMA
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
Total Carbon
TOC 0.428 mg/L 0.1 1 SM5310C/EPA9060A 07/09/201514:22 GHUTCHI
Qualifiers:
B Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in
sample is less than 10X the concentration in the method blank. Analyte concentration in sample could be due

Analytical Lab
Certificate of Laboratory Analysis Page 8 of 26
This report shall not be reproduced, except in full.
Order # J15070251
to contamination.
B1 Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in
sample was greater than 10X the concentration of the target analyte detected in the method blank. Analyte
concentration in sample is not affected by contamination.

Analytical Lab
Page 9 of 26
EIeirnenit One Inc.
6319-D Carolina Beach Rd.
Wilmington, IAC 28412
Rhone: 910 793-0128
Fax: [phone]
[e-mail]
REPORT OF ANALYSES
Duke Energy July 13, 2015
Laboratory Services Client Project Name AB GW Assessment water Asheville
13339 Hagers Ferry Road Bld. MG03A Client Project Number J15070251
Huntersville, NC 28078 PO Number
Sample Matrix GW WW Sample Type Grab Date Received 07/09/2015
Date Analyzed 07/10/2015 Method SM 4500 S2_ D Time Received 1145
Delivered by FedEx
eOne ID Duke Energy ID Parameter Result Unit Dil
25284-1 CB -02
25284-2 CB -413
Sulfide < 0.1 mg/L 1
Received by LLB
DL Date Time
Sampled Sampled
0.1 07/07/15 0949
Sulfide < 0.1 mg/L 1 0.1 07/07/15 1425
� � �Zfo W�
Ken Smith, Laboratory Director
25284 Duke Report Packet Compiled by �VS
NC Certifications: DW 37788 and DWQ DENR 604

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elemen One SAMPLE SUBMISSION FORM
TAT 5 BD
Hold Time Expiration 07.14.15 @ 0949
Client: Duke Energy
LIMS No J15070251
Project ID Asheville
Analytical Lab
Lab I15ge'1gi84
Analysis Due Date
07.13.15
Report Due Date
07.14.15
Date Rec:
07.09.15
Time Rec:
1145
Rec By
LLB
H >g eo� No Temp:5 6°C a No Ref. Method:
If No, Record If No, Record d SM4500 S2 D
sam ie Identitication & Collection Information
Lab ID Client ID Collection Date Collection Time Analysis Requested
1 CB -02 07.07.15 0949 ulfi
2 CB -4B 07.07.15 1425 Sul
NOTE for Sulfide The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected
at 100 pg/L spike the sample to render the final spike concentration at — 500 pg/L
Prep By / Date , I U IS
Labeled By / Date -7
ID Verification By /Date

METHOD:
SM 4500 S2- D
ELEMENT ASSAY:
Sulfide
CLIENT:
Duke
LabID#
25284
Date:
107/10/15
Time Analysis Begun
18-100
Time Analysis Ended
110:00
X
y
ug STD
STD
SOLUTION
ABS
0.00
-TO -00
11.00
0.097
2.50
0.234
5.00
0.442
7.50
0.637
10.00
0.856
QC Std Lot: SD -19-2
10
Analytical Lab
Page 12 of 26
9
D
SAMPLE
1. D.
ELEMENT ONE
ALI in mL
ANALYZED
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/M
DETECTION LIMIT _WM
1.000
SPK LEVELca
5
Na2S-9H2O Lot #
40721
10
MAX ALIQUOT
10.00
STANDARD conc(ppm)
x
ICal Std Lot: SD -19-1
10
QC Std Lot: SD -19-2
10
ISTD ABSORPTION
Y
10
<
0200
9
D
SAMPLE
1. D.
SAMP ug PER
ABS ALIQUOT
ALI in mL
ANALYZED
0 0.955
Slope
ALI in mL
TAKEN
0.08452967
RESULTS
ug/nnL
Correlation
LESS THAN
% SPK REC
0.999638418
SPIKE
LEVEL
0900
0.000
7
10
0.500
10
<
V
0.400
Std. B. 1.00
442
0.9244
0
10
10
<
0200
1.0
Std. B. 2.50
0.230
0100
10
10
10
0 000
am
101.85%
2.5
Std. B. 5.00
9
D
SAMPLE
1. D.
SAMP ug PER
ABS ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
Slope
ALI in mL
TAKEN
0.08452967
RESULTS
ug/nnL
Correlation
LESS THAN
% SPK REC
0.999638418
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.0
Std. B. 1.00
0.096
0.9244
10
10
10
<
92.44%
1.0
Std. B. 2.50
0.230
2.5462
10
10
10
0.255
101.85%
2.5
Std. B. 5.00
0.439
1 5.0756
10
10
10
0.508
101.51%
5.0
Std. B. 7.50
0.629
7.3751
10
10
10
0.738
98.34%
7.5
Std. B. 10.00
0.854
10.0983
10
10
10
1.010
100.98%
10.0
LRB
0.000
0.0000
10
10
10
<
0.0
LRB SPK
0.450
5.2088
10
10
10
0.521
104%
5.0
QC
0.446
5.1604
10
10
10
0.516
103%
5.0
25284-1
0,003
-0.2011
10
10
10
25284-1 s
0.430
4.9667
10
10
10
0.497
99%
5.0
25284-2
0.001
-0.2253
10
10
10
-7-7777F
1
25284-2 dup
0.004
-0,1890
10
10
10
< 0.1
25284-2 s
0.452
5.2330
10
10
10
0.523
105%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.446
5.1604
10
10
10
0.516
103%
5.0
Submitted for QA/QC-
Date: 07/10/15
By: (Print)
KAM
1(sign):

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
Project Name: AB GW Assessment Water - Asheville
Project Number:J15070251
Lot Number:QG09085
Date Completed:07/14/2015
Grant Wilton
Project Manager
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
Shealy Environmental Services, Inc. Page: 1 of 6
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: QG09085
Project Name: AB GW Assessment Water - Asheville
Project Number: J15070251
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page
Sample Receiving
The samples were received at 26.7 degrees C. The client was notified on 7/10/2015 and instructed the lab to proceed with the analysis.
Shealy Environmental Services, Inc. Page: 2 of 6
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QG09085
Project Name: AB GW Assessment Water - Asheville
Project Number: J15070251
Sample Number Sample ID Matrix Date Sampled Date Received
001 2015022704 Aqueous 07/07/2015 0949 07/09/2015
002 2015022705 Aqueous 07/07/20151425 07/09/2015
(2 samples)
Shealy Environmental Services, Inc. Page: 3 of 6
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QG09085
Project Name: AB GW Assessment Water - Asheville
Project Number: J15070251
Sample Sample ID Matrix Parameter Method Result Q Units Page
(0 detections)
Shealy Environmental Services, Inc. Page: 4 of 6
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID: QG09085-001
Description: 2015022704 Matrix: Aqueous
Date Sampled:07/07/2015 0949 Project Name: AB GW Assessment Water -
Date Received: 07/09/2015 Project Number: J15070251
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 07/13/2015 1752 DCS 79485
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 5 of 6
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID: QG09085-002
Description: 2015022705 Matrix: Aqueous
Date Sampled:07/07/2015 1425 Project Name: AB GW Assessment Water -
Date Received: 07/09/2015 Project Number: J15070251
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 07/13/2015 1842 DCS 79485
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 6 of 6
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: QG09085
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane - MB
Sample ID: QQ79485-001 Matrix: Aqueous
Batch:79485
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 07/13/20151508
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QG09085
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane - LCS
Sample ID: QQ79485-002 Matrix: Aqueous
Batch:79485
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 150 110 1 72 70-130 07/13/20151445
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QG09085
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane - LCSD
Sample ID: QQ79485-003 Matrix: Aqueous
Batch:79485
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 150 120 1 77 6.4 70-130 30 07/13/20151456
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QG09085
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

w!
SHEALY ENVIRONMENTAL SERVICES, INC.
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

SHEALY ENVIRONMENTAL SERVICES, INC.
Shea Ip Euoito-u erml Scrwicci, tna.
D-%�Iumenl Number F -A11416
Revision NufAu-- 13
Page i
R eplzzcs Dale: 16J NI.4
EM*dVr DaU: 01+'3{1+] S
Sample Receipt Checkltgt (SRC)
Client: ! ri r T Conley inspecicd by?date= A2,' i 'I
Means ofTmeipt:
SPS] ❑ Clileut ❑ UPS ❑ FedEx ❑ Airb a Exp ❑ 01her
-Yes NoE
I 1. V4'ere cust2k seals presmit on the cnoler7
Yes Ll I No
IATA . Cf stocly seals were emwit, v ere th tntael and nnl7roiC[a7
Cooler IDOriginal tempentum upon rec:eipuq)cTived (col7ected) tantpe'i)1urc upon receipt;
rr
Method: ❑ Ternperawrc Blank aAgaiml Bottles IR Gun ID:IRG Cicm Factor; °C
_,.j
McLbod of coolant: ❑ Wet ke ❑ Blue ice ❑ Dry Ice N®ne
3. If temperarure cooler exoecdcd 6.0 °C.3 was Piuicct Marfager notified?
Yes 140 ❑
NA ❑ IPM notifiedSR ph -one, note (uircic one:), other:
(Fur carolers received via commercial imurier, RMs are to be pati Fieri
itnxnedial+e,l .
Yes-7NA
4, Is the ceirEmarcial c o.ui ier's acicin sli attached to this fcrm,?
YesNo ❑
j, Were ro er cu.Rtndrocedures (reli uir-heallreceived) followed?
Yes ❑
NA 5a Were sam lea rclinqu.ished b, client to
commercial courier?
Ye -so Q
6_ Wert sample IN listed [en the Co c7
es
Yo
7. Were sample IN listed on all sample containers?
Yes No ❑
S. Was collection dare cki. time listed 4an the COC?
-'e€ No ❑
9, Was collection date c c lime listed on all s€�msylc container%"
yt:� 10 ❑
10. Did MI co ntai= label information (ID, date, tinea with dkc CC}(:''
Yes c ❑
11, Were tests to be erformcd iisted on the COC?
Yes No ❑
1
12, d rill samples arrive i,s Ihr proper containers for each test?
Yes o El7
3.1 did all cantaioers arrive i11 ucxl aot�ditirm "unl}rc�laect, lids cm, etc)?
Yes No ❑
IC Was adequatearrl sle volume available?
Ye* E:1N'?15.
Were all samples reczived within L/3 the holding time or 4K hours, whichever
Cilm-s first'?
Y" ❑ No
16. Were any gam , les ccm ainm mrssm ?
Yrs :'No
17. Wem thew M excess SUM lcs not listed on C�{ C ?
Yes No
NA ❑ 18. Were bubbles uscnt �' ca -side" !,V or -6mm in diameter i❑ fm iV0A visls'1
Yes No ElNA
9_ Were all metal€+CiBsG+HQ+J!?nuteietti> st+am les received ata 13 of<2? I
Ye s ❑ No L]
NA M V4err all s aside alnd?or 6ulfidc les hived ata H >129
Yes ❑ No ]
N. 1 Were all appheable NMITKNJcyanidOphenol (�U_2mag/L) samples c vF
residual chlorine?
Yes ❑ No
NA 22, Werc csollcction tern atm -es documented an the COC for NC- samples?
Yes ❑ Na ❑
+q 23 Werc clicat remadWr+equW& (i. c. requested dilutiorm, MSINISD dcsignations,
elt... carrccily transcribed from the COC urtp the conimen, section in LIMS?
Yes ❑ No
24 Was the quate awnber ureal taken from the container label?
Simple Preserratiun (Must be completed for any samples) inenmactly preservW or with hmdspace)
Sample(s)
were reethrod iuorrectly pitse ved and were adjustE:d
accat'rdinAly in samnlc rcrr-ivin with 1.4SO4,ff N0.,,HC1,1N€EO)rl using SR #
Salta le(s)
were ruuQivcd with bubb[es ->6 thin in diameter_
Swm lc(s)
were received with TRC >0.2 raWl f #21 is Ne
SU, Drinking Walter Projmt Samples) pH verified to be r 3 by Date:
Barn lc(s)
were noE received at a pH of and were adjusted a000rLigly using SR#
a1n 1e labels applilyd by; 'Verified h : bate: -
Cnmrncnts
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Analytical Lab
Page 25 of 26
Ogle, Mary A
From: Pifer, Anne H.
Sent: Friday, July 10, 2015 1:54 PM
To: [e-mail]; Ogle, Mary A
Cc: Mace, Dale Morgan
Subject: Asheville- J15070283 and J15070251
Mark -
As we discussed, the 6 methane samples from Asheville (115070283 and J15070251) were received at the vendor lab at
an elevated temperature. Coolers containing LL Hg were picked up from the Duke Lab at the same time, and the cooler
with the methane samples failed to get the ice required before shipment. I apologize for the oversight on our part. As
we discussed, I will tell the vendor lab to continue with the analysis and flag the data. If you have any further questions
please let me know.
Best wishes.
Anne
Anne Pifer
Supervising Scientist- Analytical Laboratory
Duke Energy, Environmental Services
Office: 980-875-3583
Cell: 704-224-5406
Email: anne.pifcrC duke-erici�gN,,.com
DUKE
EMERY

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