NC0000396_J15070191report_20150823

Lab
DUI E Analytical Laboratory APagel1aof34
ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
J15070191
ASHEVILLE - AB GW ASSESSMENT WATER
Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker
200 CP and L Drive
Arden,NC 28704
Mary Ann Ogle ma ry.og I e@d u ke- Phone: [phone]
""(/] ✓✓✓ 2015.07.1516:44:06 Date:
-04'00'
Mary Ann Ogle
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
7/15/2015
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
2015022429
2015022430
2015022431
2015022432
2015022433
2015022434
6 Total Samples
Collected By
Sample Description
ASHEVILLE
06 -Jul -15 1:00 PM
illegible
GW -01
ASHEVILLE
06 -Jul -15 11:12 AM
illegible
CB -01
ASHEVILLE
06 -Jul -15 9:43 AM
illegible
CB -08
ASHEVILLE
06 -Jul -15 2:57 PM
illegible
CB -09
ASHEVILLE
06 -Jul -15 3:30 PM
illegible
Filter Blank
ASHEVILLE
06 -Jul -15 3:30 PM
illegible
Equipment Blank
Analytical Lab
Page 2 of 34

Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals 0 Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable. 0 Yes F-] No
Report Sections Included:
E%-'] Job Summary Report
❑� Sample Identification
Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Analytical Lab
Page 3 of 34
❑d Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Mary Ann Ogle Date: 7/15/2015

Analytical Lab
Certificate of Laboratory Analysis Page 4 of 34
This report shall not be reproduced, except in full.
Order # J15070191
Site: GW -01
Sample #:
2015022429
Collection Date: 06 -Jul -15
1:00 PM
Matrix:
GW WW
Analyte
Result
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
3.0
mg-N/L
0.05
5
EPA 353.2
07/13/2015 11:12
LSTARL1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
0.15
ug/L
0.05
1
EPA 245.1
07/09/2015 13:33
ACPAYNE
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
1
EPA 245.1
07/09/2015 15:17
ACPAYNE
DISSOLVED METALS BY ICP
Aluminum (AI)
0.138
mg/L
0.005
1
EPA 200.7
07/09/2015 09:11
FCJORDA
Barium (Ba)
0.055
mg/L
0.005
1
EPA 200.7
07/09/2015 09:11
FCJORDA
Boron (B)
< 0.05
mg/L
0.05
1
EPA 200.7
07/09/2015 09:11
FCJORDA
Iron (Fe)
< 0.01
mg/L
0.01
1
EPA 200.7
07/09/2015 09:11
FCJORDA
Manganese (Mn)
0.564
mg/L
0.005
1
EPA 200.7
07/09/2015 09:11
FCJORDA
Strontium (Sr)
< 0.005
mg/L
0.005
1
EPA 200.7
07/09/2015 09:11
FCJORDA
Zinc (Zn)
0.013
mg/L
0.005
1
EPA 200.7
07/09/2015 09:11
FCJORDA
UNDIGESTED METALS BY ICP
Calcium (Ca)
8.29
mg/L
0.01
1
EPA 200.7
07/09/2015 10:10
FCJORDA
Magnesium (Mg)
7.52
mg/L
0.005
1
EPA 200.7
07/09/2015 10:10
FCJORDA
Potassium (K)
0.640
mg/L
0.1
1
EPA 200.7
07/09/2015 10:10
FCJORDA
Sodium (Na)
1.04
mg/L
0.05
1
EPA 200.7
07/09/2015 10:10
FCJORDA
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.251
mg/L
0.005
1
EPA 200.7
07/09/2015 11:05
FCJORDA
Barium (Ba)
0.057
mg/L
0.005
1
EPA 200.7
07/09/2015 11:05
FCJORDA
Boron (B)
< 0.05
mg/L
0.05
1
EPA 200.7
07/09/2015 11:05
FCJORDA
Iron (Fe)
0.101
mg/L
0.01
1
EPA 200.7
07/09/2015 11:05
FCJORDA
Manganese (Mn)
0.551
mg/L
0.005
1
EPA 200.7
07/09/2015 11:05
FCJORDA
Strontium (Sr)
< 0.005
mg/L
0.005
1
EPA 200.7
07/09/2015 11:05
FCJORDA
Zinc (Zn)
0.012
mg/L
0.005
1
EPA 200.7
07/09/2015 11:05
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070191
Site: GW -01
Collection Date: 06 -Jul -15 1:00 PM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #: 2015022429
Matrix: GW WW
Analytical Lab
Page 5 of 34
RDL DF Method Analysis Date/Time Analyst
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:37
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:37
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:37
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:37
MHALL3
Chromium (Cr)
1.31
ug/L
1
1
EPA 200.8
07/13/2015 15:37
MHALL3
Cobalt (Co)
4.54
ug/L
1
1
EPA 200.8
07/13/2015 15:37
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:37
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:37
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:37
MHALL3
Nickel (Ni)
2.28
ug/L
1
1
EPA 200.8
07/13/2015 15:37
MHALL3
Selenium (Se)
1.38
ug/L
1
1
EPA 200.8
07/13/2015 15:37
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
07/13/2015 15:37
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
07/13/2015 15:37
MHALL3
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
07/09/2015 16:46
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
07/09/2015 16:46
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
07/09/2015 16:46
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
07/09/2015 16:46
JAHERMA
Chromium (Cr)
1.14
ug/L
1
1
EPA 200.8
07/09/2015 16:46
JAHERMA
Cobalt (Co)
4.76
ug/L
1
1
EPA 200.8
07/09/2015 16:46
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
07/09/2015 16:46
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
07/09/2015 16:46
JAHERMA
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
07/09/2015 16:46
JAHERMA
Nickel (Ni)
2.68
ug/L
1
1
EPA 200.8
07/09/2015 16:46
JAHERMA
Selenium (Se)
1.78
ug/L
1
1
EPA 200.8
07/09/2015 16:46
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
07/09/2015 16:46
JAHERMA
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
07/09/2015 16:46
JAHERMA
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
Total Carbon
TOC 0.560 mg/L 0.1 1 SM5310C/EPA9060A 07/09/201514:22 GHUTCHI

Analytical Lab
Certificate of Laboratory Analysis Page 6 of 34
This report shall not be reproduced, except in full.
Order # J15070191
Site: CB -01
Sample #:
2015022430
Collection Date: 06 -Jul -15
11:12 AM
Matrix:
GW WW
Analyte
Result
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
0.423
mg-N/L
0.01
1
EPA 353.2
07/13/2015 11:08
LSTARL1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
1
EPA 245.1
07/09/2015 13:36
ACPAYNE
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
1
EPA 245.1
07/09/2015 15:24
ACPAYNE
DISSOLVED METALS BY ICP
Aluminum (AI)
0.050
mg/L
0.005
1
EPA 200.7
07/09/2015 09:23
FCJORDA
Barium (Ba)
0.020
mg/L
0.005
1
EPA 200.7
07/09/2015 09:23
FCJORDA
Boron (B)
< 0.05
mg/L
0.05
1
EPA 200.7
07/09/2015 09:23
FCJORDA
Iron (Fe)
< 0.01
mg/L
0.01
1
EPA 200.7
07/09/2015 09:23
FCJORDA
Manganese (Mn)
0.025
mg/L
0.005
1
EPA 200.7
07/09/2015 09:23
FCJORDA
Strontium (Sr)
< 0.005
mg/L
0.005
1
EPA 200.7
07/09/2015 09:23
FCJORDA
Zinc (Zn)
0.082
mg/L
0.005
1
EPA 200.7
07/09/2015 09:23
FCJORDA
UNDIGESTED METALS BY ICP
Calcium (Ca)
0.170
mg/L
0.01
1
EPA 200.7
07/09/2015 10:22
FCJORDA
Magnesium (Mg)
0.433
mg/L
0.005
1
EPA 200.7
07/09/2015 10:22
FCJORDA
Potassium (K)
0.398
mg/L
0.1
1
EPA 200.7
07/09/2015 10:22
FCJORDA
Sodium (Na)
0.994
mg/L
0.05
1
EPA 200.7
07/09/2015 10:22
FCJORDA
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.150
mg/L
0.005
1
EPA 200.7
07/09/2015 11:16
FCJORDA
Barium (Ba)
0.021
mg/L
0.005
1
EPA 200.7
07/09/2015 11:16
FCJORDA
Boron (B)
< 0.05
mg/L
0.05
1
EPA 200.7
07/09/2015 11:16
FCJORDA
Iron (Fe)
0.086
mg/L
0.01
1
EPA 200.7
07/09/2015 11:16
FCJORDA
Manganese (Mn)
0.025
mg/L
0.005
1
EPA 200.7
07/09/2015 11:16
FCJORDA
Strontium (Sr)
< 0.005
mg/L
0.005
1
EPA 200.7
07/09/2015 11:16
FCJORDA
Zinc (Zn)
0.077
mg/L
0.005
1
EPA 200.7
07/09/2015 11:16
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070191
Site: CB -01
Collection Date: 06 -Jul -15 11:12 AM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #: 2015022430
Matrix: GW WW
Analytical Lab
Page 7 of 34
RDL DF Method Analysis Date/Time Analyst
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:44
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:44
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:44
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:44
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:44
MHALL3
Cobalt (Co)
2.02
ug/L
1
1
EPA 200.8
07/13/2015 15:44
MHALL3
Copper (Cu)
7.90
ug/L
1
1
EPA 200.8
07/13/2015 15:44
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:44
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:44
MHALL3
Nickel (Ni)
1.13
ug/L
1
1
EPA 200.8
07/13/2015 15:44
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:44
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
07/13/2015 15:44
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
07/13/2015 15:44
MHALL3
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
07/09/2015 16:25
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
07/09/2015 16:25
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
07/09/2015 16:25
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
07/09/2015 16:25
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
07/09/2015 16:25
JAHERMA
Cobalt (Co)
1.95
ug/L
1
1
EPA 200.8
07/09/2015 16:25
JAHERMA
Copper (Cu)
12.2
ug/L
1
1
EPA 200.8
07/09/2015 16:25
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
07/09/2015 16:25
JAHERMA
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
07/09/2015 16:25
JAHERMA
Nickel (Ni)
1.02
ug/L
1
1
EPA 200.8
07/09/2015 16:25
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
07/09/2015 16:25
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
07/09/2015 16:25
JAHERMA
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
07/09/2015 16:25
JAHERMA
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
Total Carbon
TOC 0.106 mg/L 0.1 1 SM5310C/EPA9060A 07/09/201514:22 GHUTCHI

Analytical Lab
Certificate of Laboratory Analysis Page 8 of 34
This report shall not be reproduced, except in full.
Order # J15070191
Site: CB -08
Sample #:
2015022431
Collection Date: 06 -Jul -15 9:43 AM
Matrix:
GW WW
Analyte
Result
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
1.8
mg-N/L
0.01
1
EPA 353.2
07/13/2015 11:09
LSTARL1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
0.13
ug/L
0.05
1
EPA 245.1
07/09/2015 13:38
ACPAYNE
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
1
EPA 245.1
07/09/2015 15:27
ACPAYNE
DISSOLVED METALS BY ICP
Aluminum (AI)
0.134
mg/L
0.005
1
EPA 200.7
07/09/2015 09:26
FCJORDA
Barium (Ba)
0.169
mg/L
0.005
1
EPA 200.7
07/09/2015 09:26
FCJORDA
Boron (B)
2.35
mg/L
0.05
1
EPA 200.7
07/09/2015 09:26
FCJORDA
Iron (Fe)
0.014
mg/L
0.01
1
EPA 200.7
07/09/2015 09:26
FCJORDA
Manganese (Mn)
1.09
mg/L
0.005
1
EPA 200.7
07/09/2015 09:26
FCJORDA
Strontium (Sr)
0.659
mg/L
0.005
1
EPA 200.7
07/09/2015 09:26
FCJORDA
Zinc (Zn)
0.126
mg/L
0.005
1
EPA 200.7
07/09/2015 09:26
FCJORDA
UNDIGESTED METALS BY ICP
Calcium (Ca)
106
mg/L
0.01
1
EPA 200.7
07/09/2015 10:25
FCJORDA
Magnesium (Mg)
37.4
mg/L
0.005
1
EPA 200.7
07/09/2015 10:25
FCJORDA
Potassium (K)
2.64
mg/L
0.1
1
EPA 200.7
07/09/2015 10:25
FCJORDA
Sodium (Na)
8.05
mg/L
0.05
1
EPA 200.7
07/09/2015 10:25
FCJORDA
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.175
mg/L
0.005
1
EPA 200.7
07/09/2015 11:20
FCJORDA
Barium (Ba)
0.180
mg/L
0.005
1
EPA 200.7
07/09/2015 11:20
FCJORDA
Boron (B)
2.31
mg/L
0.05
1
EPA 200.7
07/09/2015 11:20
FCJORDA
Iron (Fe)
0.046
mg/L
0.01
1
EPA 200.7
07/09/2015 11:20
FCJORDA
Manganese (Mn)
1.08
mg/L
0.005
1
EPA 200.7
07/09/2015 11:20
FCJORDA
Strontium (Sr)
0.655
mg/L
0.005
1
EPA 200.7
07/09/2015 11:20
FCJORDA
Zinc (Zn)
0.112
mg/L
0.005
1
EPA 200.7
07/09/2015 11:20
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070191
Site: CB -08
Collection Date: 06 -Jul -15 9:43 AM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #: 2015022431
Matrix: GW WW
Analytical Lab
Page 9 of 34
RDL DF Method Analysis Date/Time Analyst
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:52
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:52
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:52
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:52
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:52
MHALL3
Cobalt (Co)
2.89
ug/L
1
1
EPA 200.8
07/13/2015 15:52
MHALL3
Copper (Cu)
14.5
ug/L
1
1
EPA 200.8
07/13/2015 15:52
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:52
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:52
MHALL3
Nickel (Ni)
2.67
ug/L
1
1
EPA 200.8
07/13/2015 15:52
MHALL3
Selenium (Se)
19.2
ug/L
1
1
EPA 200.8
07/13/2015 15:52
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
07/13/2015 15:52
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
07/13/2015 15:52
MHALL3
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
07/09/2015 17:14
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
07/09/2015 17:14
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
07/09/2015 17:14
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
07/09/2015 17:14
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
07/09/2015 17:14
JAHERMA
Cobalt (Co)
2.68
ug/L
1
1
EPA 200.8
07/09/2015 17:14
JAHERMA
Copper (Cu)
22.8
ug/L
1
1
EPA 200.8
07/09/2015 17:14
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
07/09/2015 17:14
JAHERMA
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
07/09/2015 17:14
JAHERMA
Nickel (Ni)
2.36
ug/L
1
1
EPA 200.8
07/09/2015 17:14
JAHERMA
Selenium (Se)
19.5
ug/L
1
1
EPA 200.8
07/09/2015 17:14
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
07/09/2015 17:14
JAHERMA
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
07/09/2015 17:14
JAHERMA
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
Total Carbon
TOC 0.362 mg/L 0.1 1 SM5310C/EPA9060A 07/09/201514:22 GHUTCHI

Analytical Lab
Certificate of Laboratory Analysis Page 10 of 34
This report shall not be reproduced, except in full.
Order # J15070191
Site: CB -09
Sample #:
2015022432
Collection Date: 06 -Jul -15 2:57 PM
Matrix:
GW WW
Analyte
Result
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
1
EPA 353.2
07/13/2015 11:10
LSTARL1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
0.05
1
EPA 245.1
07/09/2015 13:40
ACPAYNE
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
1
EPA 245.1
07/09/2015 15:29
ACPAYNE
DISSOLVED METALS BY ICP
Aluminum (AI)
0.021
mg/L
0.005
1
EPA 200.7
07/09/2015 09:30
FCJORDA
Barium (Ba)
0.026
mg/L
0.005
1
EPA 200.7
07/09/2015 09:30
FCJORDA
Boron (B)
< 0.05
mg/L
0.05
1
EPA 200.7
07/09/2015 09:30
FCJORDA
Iron (Fe)
< 0.01
mg/L
0.01
1
EPA 200.7
07/09/2015 09:30
FCJORDA
Manganese (Mn)
0.035
mg/L
0.005
1
EPA 200.7
07/09/2015 09:30
FCJORDA
Strontium (Sr)
0.008
mg/L
0.005
1
EPA 200.7
07/09/2015 09:30
FCJORDA
Zinc (Zn)
0.038
mg/L
0.005
1
EPA 200.7
07/09/2015 09:30
FCJORDA
UNDIGESTED METALS BY ICP
Calcium (Ca)
0.542
mg/L
0.01
1
EPA 200.7
07/09/2015 10:33
FCJORDA
Magnesium (Mg)
0.956
mg/L
0.005
1
EPA 200.7
07/09/2015 10:33
FCJORDA
Potassium (K)
0.696
mg/L
0.1
1
EPA 200.7
07/09/2015 10:33
FCJORDA
Sodium (Na)
4.03
mg/L
0.05
1
EPA 200.7
07/09/2015 10:33
FCJORDA
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.103
mg/L
0.005
1
EPA 200.7
07/09/2015 11:24
FCJORDA
Barium (Ba)
0.029
mg/L
0.005
1
EPA 200.7
07/09/2015 11:24
FCJORDA
Boron (B)
< 0.05
mg/L
0.05
1
EPA 200.7
07/09/2015 11:24
FCJORDA
Iron (Fe)
0.158
mg/L
0.01
1
EPA 200.7
07/09/2015 11:24
FCJORDA
Manganese (Mn)
0.040
mg/L
0.005
1
EPA 200.7
07/09/2015 11:24
FCJORDA
Strontium (Sr)
0.008
mg/L
0.005
1
EPA 200.7
07/09/2015 11:24
FCJORDA
Zinc (Zn)
0.037
mg/L
0.005
1
EPA 200.7
07/09/2015 11:24
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070191
Site: CB -09
Collection Date: 06 -Jul -15 2:57 PM
Analyte Result Units Qualifiers
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #: 2015022432
Matrix: GW WW
Analytical Lab
Page 11 of 34
RDL DF Method Analysis Date/Time Analyst
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:59
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:59
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:59
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:59
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:59
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:59
MHALL3
Copper (Cu)
1.78
ug/L
1
1
EPA 200.8
07/13/2015 15:59
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:59
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:59
MHALL3
Nickel (Ni)
1.10
ug/L
1
1
EPA 200.8
07/13/2015 15:59
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
07/13/2015 15:59
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
07/13/2015 15:59
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
07/13/2015 15:59
MHALL3
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
07/09/2015 16:53
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
07/09/2015 16:53
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
07/09/2015 16:53
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
07/09/2015 16:53
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
07/09/2015 16:53
JAHERMA
Cobalt (Co)
<1
ug/L
1
1
EPA 200.8
07/09/2015 16:53
JAHERMA
Copper (Cu)
5.03
ug/L
1
1
EPA 200.8
07/09/2015 16:53
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
07/09/2015 16:53
JAHERMA
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
07/09/2015 16:53
JAHERMA
Nickel (Ni)
1.28
ug/L
1
1
EPA 200.8
07/09/2015 16:53
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
07/09/2015 16:53
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
07/09/2015 16:53
JAHERMA
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
07/09/2015 16:53
JAHERMA
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
Total Carbon
TOC 0.158 mg/L 0.1 1 SM5310C/EPA9060A 07/09/201514:22 GHUTCHI

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070191
Site: Filter Blank
Collection Date: 06 -Jul -15 3:30 PM
Analyte
Result
Units
Qualifiers RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
EPA 245.1
07/09/2015 15:31
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
1
EPA 200.7
07/09/2015 09:34
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
1
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2015022433
Matrix: GW WW
Analytical Lab
Page 12 of 34
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
07/09/2015 15:31
ACPAYNE
1
EPA 200.7
07/09/2015 09:34
FCJORDA
1
EPA 200.7
07/09/2015 09:34
FCJORDA
1
EPA 200.7
07/09/2015 09:34
FCJORDA
1
EPA 200.7
07/09/2015 09:34
FCJORDA
1
EPA 200.7
07/09/2015 09:34
FCJORDA
1
EPA 200.7
07/09/2015 09:34
FCJORDA
1
EPA 200.7
07/09/2015 09:34
FCJORDA
1
EPA 200.8
07/13/2015 16:06
MHALL3
1
EPA 200.8
07/13/2015 16:06
MHALL3
1
EPA 200.8
07/13/2015 16:06
MHALL3
1
EPA 200.8
07/13/2015 16:06
MHALL3
1
EPA 200.8
07/13/2015 16:06
MHALL3
1
EPA 200.8
07/13/2015 16:06
MHALL3
1
EPA 200.8
07/13/2015 16:06
MHALL3
1
EPA 200.8
07/13/2015 16:06
MHALL3
1
EPA 200.8
07/13/2015 16:06
MHALL3
1
EPA 200.8
07/13/2015 16:06
MHALL3
1
EPA 200.8
07/13/2015 16:06
MHALL3
1
EPA 200.8
07/13/2015 16:06
MHALL3
1
EPA 200.8
07/13/2015 16:06
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15070191
Site: Equipment Blank
Collection Date: 06 -Jul -15 3:30 PM
Analyte Result Units Qualifiers RDL DF
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.286 mg-N/L 0.01 1
MERCURY (COLD VAPOR) IN WATER
Mercury (Hg)
< 0.05
ug/L
UNDIGESTED METALS BY ICP
ACPAYNE
0.01
Calcium (Ca)
< 0.01
mg/L
Magnesium (Mg)
< 0.005
mg/L
Potassium (K)
< 0.1
mg/L
Sodium (Na)
< 0.05
mg/L
TOTAL RECOVERABLE METALS BY ICP
FCJORDA
Aluminum (AI)
< 0.005
mg/L
Barium (Ba)
< 0.005
mg/L
Boron (B)
< 0.05
mg/L
Iron (Fe)
< 0.01
mg/L
Manganese (Mn)
< 0.005
mg/L
Strontium (Sr)
< 0.005
mg/L
Zinc (Zn)
< 0.005
mg/L
TOTAL RECOVERABLE METALS BY ICP -MS
EPA 200.7
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
METHANE - (Analysis Performed by
Shealy Labs)
JAHERMA
Methane (CH4)
Complete
EPA 200.8
SULFIDE - (Analysis Performed by
Element One)
1
Vendor Parameter
Complete
07/09/2015 17:07
Total Carbon
1
1
TOC
0.386
mg/L
Analytical Lab
Page 13 of 34
Sample #: 2015022434
Matrix: GW WW
Method Analysis Date/Time Analyst
EPA 353.2 07/13/2015 11:11 LSTARL1
0.05
1
EPA 245.1
07/09/2015 13:45
ACPAYNE
0.01
1
EPA 200.7
07/09/2015 10:37
FCJORDA
0.005
1
EPA 200.7
07/09/2015 10:37
FCJORDA
0.1
1
EPA 200.7
07/09/2015 10:37
FCJORDA
0.05
1
EPA 200.7
07/09/2015 10:37
FCJORDA
0.005
1
EPA 200.7
07/09/2015 11:28
FCJORDA
0.005
1
EPA 200.7
07/09/2015 11:28
FCJORDA
0.05
1
EPA 200.7
07/09/2015 11:28
FCJORDA
0.01
1
EPA 200.7
07/09/2015 11:28
FCJORDA
0.005
1
EPA 200.7
07/09/2015 11:28
FCJORDA
0.005
1
EPA 200.7
07/09/2015 11:28
FCJORDA
0.005
1
EPA 200.7
07/09/2015 11:28
FCJORDA
1
1
EPA 200.8
07/09/2015 17:07
JAHERMA
1
1
EPA 200.8
07/09/2015 17:07
JAHERMA
1
1
EPA 200.8
07/09/2015 17:07
JAHERMA
1
1
EPA 200.8
07/09/2015 17:07
JAHERMA
1
1
EPA 200.8
07/09/2015 17:07
JAHERMA
1
1
EPA 200.8
07/09/2015 17:07
JAHERMA
1
1
EPA 200.8
07/09/2015 17:07
JAHERMA
1
1
EPA 200.8
07/09/2015 17:07
JAHERMA
1
1
EPA 200.8
07/09/2015 17:07
JAHERMA
1
1
EPA 200.8
07/09/2015 17:07
JAHERMA
1
1
EPA 200.8
07/09/2015 17:07
JAHERMA
0.2
1
EPA 200.8
07/09/2015 17:07
JAHERMA
0.3
1
EPA 200.8
07/09/2015 17:07
JAHERMA
Vendor Method V_SHEALY
Vendor Method V_ELE1
0.1 1 SM5310C/EPA9060A 07/09/201514:22 GHUTCHI

to
REPORT OF ANALYSES
Analytical Lab
Page 14 of 34
EBernent One lnc.
6319-D Carolina Beach Rd.
Wilmington, NC 28412
Phone: [phone]
Fax: [phone]
[e-mail]
Duke Energy
July 13, 2015
Laboratory Services
Client Project Name AB
GW Assessment water Asheville
13339 Hagers
Ferry Road Bld. MG03A
Client Project Number
J15070191
Huntersville, NC 28078
PO Number
Sample Matrix
GW WW
Sample Type Grab
Date Received
07/10/2015
Date Analyzed
07/10/2015
Method
SM 4500 SZ- D
Time Received
1350
Delivered by
FedEx
Received by
LLB
eOne ID
Duke Energy ID
Parameter
Result Unit
Dil
DL Date
Time
Sampled
Sampled
25295-1
GW -01
Sulfide
< 0.1 mg/L
1
0.1 07/06/15
1300
25295-2
CB -01
Sulfide
< 0.1 mg/L
1
0.1 07/06/15
1112
25295-3
CB -08
Sulfide
< 0.1 mg/L
1
0.1 07/06/15
0943
25295-4*
CB -09
Sulfide
< 0.2 mg/L
2
0.1 07/06115
1457
25295-5
Equipment Blank
Sulfide
< 0.1 mg/L
1
0.1 07/06/15
1530
*Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits.
Ken Smith, Laboratory Director
25295 Duke Report Packet Compiled by i.`
NC Certifications: DW 37788 and DWQ DENR 604

00
O
0
Analytical Lab
Page 15 of 34
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Analytical Lab
Page 15 of 34
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elementOne SAMPLE SUBMISSION FORM
TAT 5 BD
Hold Time Expiration 07.13.15 @ 0943
Client: Duke Ener
LIMS No J15070191
Project ID Asheville
Analytical Lab
Lab IIyge L,q2J5
Analysis Due Date 07.10.15
Report Due Date 07.15.15
IH >9 No
Date Rec:
07.10.15
If No, Record
Time Rec:
1350
Rec By
LLB
IH >9 No
Tem <_ 6°C Si No
Ref. Method:
SM4500 S2 D
If No, Record
If No, Record
sampie Iaentnication & collection Intormatiion
Lab ID Client ID Collection Date Collection Time Analysis Requested
1 GW -01 07.06.15 1300ulfid
2 CB -01
7.06.15 1112 Sulfid
3 CB -08 07.06.15 � 0943
id
4 CB -09 07.06.15 1457ul i
5 Equipment Blank 07.06.15 1530
NOTE for Sulfide The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected
at 100 pg/L spike the sample to render the final spike concentration at — 500 pg/L
Lab Communications
_.. _ ............ .... _.- .. --- I
All AB Groundwater Assessment jobs need a RL of 0.1
Per MaryAnn via,email, 5 Day TAT.
SS Page 1 Prep By / Date VA A,\ 7 ` (11 1S
SS by Labeled By / Date X/3
7/10/201 2:27:46 PM ID Verification By /Date M `7<<d rS

Analytical Lab
Page 17 of 34
METHOD:
SM4500` S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT: Duke
SPK LEVELLuM
5'
Lab ID#
25295 / 296 / 297
Na2S•9H2O Lot #
40721
MAX ALIQUOT
10.00
Date: 07/10/15
STANDARD conc(ppm)
X
Time Analysis Begun 15:30
Cal Std Lot: SD -19-1
10
Time Analysis Ended 17:00
lQC Std Lot: SD -19-2
10
Analyst: KAM
STD ABSORPTION
Y
X
0.900
ug STD
SOLUTION
rAB
0600
°
0'0°
--------
e '
-000
0.00
1.00
2.50
5.00
7.500.637
10.00
0.234
0.442
1 0.856
0.600
0500
-2%
0dW
-2so
oz�
230
0.100
°°°°
000
1
2A0
600
6.00
X
800
1000 12.00
4
SAMPLE SAMP ug PER ALI in mL
I.D. ABS ALIQUOT ANALYZED
PREP
VOL in mL
Sloe
ALI in mL
TAKEN
0.08452967
RESULTS
ug/mL
Correlation
LESS THAN
% SPK REC
0.999638418
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.0
Std. B. 1.00
0.096
0.9244
10
10
10
<
92.44%
1.0
Std. B. 2.50
0.230
2.5462
10
10
10
0.255
101.85%
2.5
Std. B. 5.00
0.439
5.0756
10
10
10
0.508
101.51%
5.0
Std. B. 7.50
0.629
7.3751
10
10
10
0.738
98.34%
7.5
Std. B. 10.00
0.854
10.0983
10
10
10
1.010
100.98%
10.0
LRB
0.000
0.0000
10
10
10
<
0.0
LRB SPK
0.456
5.2814
10
10
10
0.528
106%
5.0
QC
0.440
5.0877
10
10
10
0.509
102%
5.0
25295-1
0.000
0.0000
10
10
10
"1< 0.1
25295-1 s k
0.395
4.5431
10
10
10
0.454
91%
5.0
25295-2
0.008
-0.1406
10
10
10
25295-2 dup
0.004
-0.1890
10
10
10
< 0.1
25295-2 s k
0.443
5.1240
10
10
10
0.512
102%
5.0
25295-3
-0.001
0.0000
10
10
10
<
25295-3 s k
0.362
4.1437
10
10
10
0.414
83%
5.0
25295-4
0.000
0.0000
10
10
10
wom
25295-4 s k
0.433
5.0030
10
10
10
0.500
100%
5.0
25295-5
0.001
-0.2253
10
10
10
25295-5 s k
0.440
5.0877
10
10
10
0.509
102%
5.0
25296-1
0.025
0.0651
10
10
10
<
25296-1 s k
0.307
3.4781
10
10
10
0.348
70%
5.0
25296-2
0.004
-0.1890
10
10
10
< 0.1�
25296-2 spk
0.391
4.4947
10
10
10
0.449
90%
5.0
25296-3
0.003
-0.2011
10
10
10
<i
25296-3 s k
0.395
4.5431
10
10
10
0.454
91%
5.0
25296-4
-0.001
0.0000
10
10
10
25296-4 s k
0.437
5.0514
10
10
10
0.505
101%
5.0
Blank
0.001
0.0000
10
10
10
<
QC
0.442
1 5.1119
10
10
10
0.511
102%
5.0
Submitted fOf QA/QC-
Date: 07/10/15
By: (Print)
KAM
(sign): 77��
�d
Page 1 of 2

Analytical Lab
Page 18 of 34
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT:
Duke
SPK LEVEL (uq)
5
Lab ID#
25295 / 296 / 297
Na2S•9H2O Lot #
40721
MAX ALIQUOT
10.00
Date:
07/10/15
STANDARD conc(ppm)
X
Time Analysis Begun
15:30
Cal Std Lot: SD -19-1
10
Time Analysis Ended
17:00
1 QC Std Lot: SD -19-2
10
Analyst:
KAM
ISTID ABSORPTION
Y
X
Y
0900
ug STD
SOLUTION
STD
ABS
6eoo
08W
070017
-
I
--
0.00
1,00
2.50
5.00
0.0: 0
0.000
0.097
0.234
0.442
0.637
0.856
0840
o soo
0400
°d2
sao
0.200
zoa
=;oma
0100
n0oo 00 -
2.06
4,W
800
x
8,w8,w1060
1z12M100
SAMPLE
I.D.
„b
SAMP ug PER
ABS ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
Slope
ALI in mL
TAKEN
0.08452967
RESULTS
ug/mL
Correlation
LESS THAN
% SPK REC
0.999638418=
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.0
Std. B. 1.00
0.096
0.9244
10
10
10
<
92.44%
1.0
Std. B. 2.50
0.230
2.5462
10
10
10
0.255
101.85%
2.5
Std. B. 5.00
0.439
5.0756
10
10
10
0.508
101.51%
5.0
Std. B. 7.50
0.629
7.3751
10
10
10
0.738
98.34%
7.5
Std. B. 10.00
0.854
10.0983
10
10
10
1.010
100.98%
10.0
LRB
0.000
0.0000
10
10
10
<
0.0
LRB SPK
0.456
5.2814
10
10
10
0.528
106%
5.0
QC
0.440
5.0877
10
10
10
0.509
102%
5.0
25297
0.042
0.2709
10
10
10
;< 0, t
25297 s k
0.452
5.2330
10
10
10
0.523
105%
5.0
25295-3
-0.001
0.0000
10
10
5
< ��
25295-3 spk
0.391
4.4947
10
10
5
0.899
90%
5.0
25296-1
0.024
0.0530
10
10
5
<
25296-1 s k
0.337
3.8412
10
10
5
0.768
77%
5.0
25296-1
0.025
0.0651
10
10
2
F
25296-1 s k
0.406
4.6762
10
10
2
2.338
94%
5.0
Blank
-0.001
0.0000
10
10
10
<
QC
0.442
5.1119
10
10
10
0.511
102%
5.0
JUpm/ifed for LIA/QC- Date: 07/10/15 By: (Print) KAM (sign):
Page 2 of 2

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
Project Name: AB GW Assessment Water - Asheville
Project Number:J15070191
Lot Number:QG08106
Date Completed:07/14/2015
Grant Wilton
Project Manager
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
Shealy Environmental Services, Inc. Page: 1 of 9
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SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: QG08106
Project Name: AB GW Assessment Water - Asheville
Project Number: J15070191
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page
Shealy Environmental Services, Inc. Page: 2 of 9
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SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QG08106
Project Name: AB GW Assessment Water - Asheville
Project Number: J15070191
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
2015022429
Aqueous
07/06/20151300
07/08/2015
002
2015022430
Aqueous
07/06/20151112
07/08/2015
003
2015022431
Aqueous
07/06/2015 0943
07/08/2015
004
2015022432
Aqueous
07/06/20151457
07/08/2015
005
2015022434
Aqueous
07/06/20151530
07/08/2015
(5 samples)
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SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QG08106
Project Name: AB GW Assessment Water - Asheville
Project Number: J15070191
Sample Sample ID Matrix Parameter Method Result Q Units Page
(0 detections)
Shealy Environmental Services, Inc. Page: 4 of 9
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Methane
Client: Duke Energy Laboratory ID: QG08106-001
Description: 2015022429 Matrix: Aqueous
Date Sampled:07/06/2015 1300 Project Name: AB GW Assessment Water -
Date Received: 07/08/2015 Project Number: J15070191
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 07/13/2015 1522 DCS 79485
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 5 of 9
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Methane
Client: Duke Energy Laboratory ID: QG08106-002
Description: 2015022430 Matrix: Aqueous
Date Sampled:07/06/2015 1112 Project Name: AB GW Assessment Water -
Date Received: 07/08/2015 Project Number: J15070191
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 07/13/2015 1533 DCS 79485
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QG08106-003
Description: 2015022431 Matrix: Aqueous
Date Sampled:07/06/2015 0943 Project Name: AB GW Assessment Water -
Date Received: 07/08/2015 Project Number: J15070191
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 07/13/2015 1546 DCS 79485
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QG08106-004
Description: 2015022432 Matrix: Aqueous
Date Sampled:07/06/2015 1457 Project Name: AB GW Assessment Water -
Date Received: 07/08/2015 Project Number: J15070191
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 07/13/2015 1601 DCS 79485
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QG08106-005
Description: 2015022434 Matrix: Aqueous
Date Sampled:07/06/2015 1530 Project Name: AB GW Assessment Water -
Date Received: 07/08/2015 Project Number: J15070191
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 07/13/2015 1629 DCS 79485
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: QG08106
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane - MB
Sample ID: QQ79485-001 Matrix: Aqueous
Batch:79485
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 07/13/20151508
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QG08106
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane - LCS
Sample ID: QQ79485-002 Matrix: Aqueous
Batch:79485
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 150 110 1 72 70-130 07/13/20151445
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QG08106
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane - LCSD
Sample ID: QQ79485-003 Matrix: Aqueous
Batch:79485
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 150 120 1 77 6.4 70-130 30 07/13/20151456
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QG08106
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

SHEALY ENVIRONMENTAL SERVICES, INC.
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
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SHEALY ENVIRONMENTAL SERVICES, INC.
shv; y sffvi[#. Im.
t7c wrmtNumber.F-ADJD16
Revisirm. Kurdxr. 17
Pap 1of1
ReplacesC13tr- 11.10 A 4
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Sample Receipt Checklist (SR
Client: ['};A.! c- Cnc r j CoolerImperted hyidate; - ` 1 7 9 Lot #; 4
Means ofrcceipt_
❑ SE -91 ❑ Chmt ❑ UPS ❑ FodEx ❑ Airbomes Fxp 6thtr
Yes No
1,Wm- vustody seals pEsent on the cocwlet°A
Yes El I Na LJ
I NA Zr L2. If Custody seals were gresent. were thc.y intacl and tmbrokea?
Cooler IDPOrigilwl temperature upor1 rec:cipi, Dcdved (corrected) temporature UP011 receipt;
f 3` k; 3,'711[ 1 I CC I 1 QC _ f 1 �€
Method:- ❑ Temperattu'e Bunk Against Bottles IR [run ID_ lR Gun C.arrection Factor: `C
Method of coolant: Wet Ice ❑ Blinn Ice Ice ❑ None
Ycs ❑ No ❑
3, If temp e lum of Hny,. taulcrcxeccdcd 6,[1°C, was Project Manager rwfi Led?
NA PM noE icd by SkC, phcnte, note (circle one:), outer,
(For coolers received via coMnXTeial courier, PMs arty to be ratified
ir>�diat
Yes ® NQ ❑
NA 4. is the mmmereial ccrtmrier's packing slip anached to this forth?
Yes Pia ❑
5. Fere proper eustvd pTi'vedures rcUg uished/mxi ud) fol lo wod?
Yes ❑ LNo J
Nle Sri W= samples rolintui4iled Cliont tocomme=i,ftl couricr?
Yes MNo ❑
6, Wcie part le Itis listod on the CY)(;? _.
YCS 0 ❑
7. Were sm le Ips huW vn all sem le containers?
Ye, 0 ❑
R. Was c,3llecfi n date &. time listed can dit COC?
Y o L19.
Was collection date & time JiAod tan all les containers?
Yes No ❑
m
10. Did all conlaincr label information Q2, (late, fifne) a wilh the COC?
Y� No
11, Were tats to be formed lisped on the COC?
Yes a ❑
12. Did all lea a� e in the: c4ntaincrs for each test?
Yes o ❑
13. Did all containers arrive in good c�onditian wibrokcrn lids on, etc-)? _
Yes No ❑
1. Was ad nt
uo sample volume available" —
Yes ❑ No
_
15.'d4�ere all samples received within'/4 the MIdingtilneord8 bcmn, Wlei,�, L—mr—
cnn-kes first
Yes ❑ No
16. W'�-Tty arly :earn les containen Inissin ?
Yes ❑ No
17. Wcre there ally exce*s sarin les not listed on COOT
Yes Ll 1140 0
ItiA ❑ i a.Wcm huhhles prffzrd ?" size" '/a"or f imn in dial ter) in any VOA vials?
Yes ElNp []
AA Z 19, Were all meUlP,+0&GeHEN1eiLu1Ticnl wnWlrs rcccivcd ata 2H of <2^
Yeti El No [Q
TSA 24, Were all autde ltndr`or s�ullide s�tru les fclot�ytiull at a pH>12?
Yes ❑ Nu ❑
NA Y 21. Were all aPphctable NH1'l'XNe'cyaniddp1eno1 (=Ca_2,InWL) saxnples fire of
residual chlorine?
Yeb No Ll
NA Z 22, W= collection tcm critlirEKs documMed on the COC for NC s les?
Yes ❑ No ❑
.NA 23. Worc client rcmarks?requests (i -e- irepested dillufions, MVMSD drns g io ,
etc_ c�,v're tly transcribed the COC into the coni +tien�t�sl�ection in LIM S?
��T}
Yes ❑ 1M
�.1. � �ffr_o,8m
24- Y'N U [Ile i UE 01.0 TLSIXJJbtf used lAktn the c*ntainer label?
Sample (Preservation ( Must be c vmpit,tc ,l for any samplc(s) Inc t TTw- lye preserved or with hea&pace)
accor&n ins
were received incoi-ectly preseivW and wm-- djusl.cd
le receiving -W it'll W0Jl,HNO3,HCLNa014i using SR 0
Barn lc(s)
v,'ere received with bubbles �-6 rnm in di ameter.
Samplc(c)
vu ere reo�ivcd with TRC 1-0.2 w&l (If #21 is No)
SC Drinking Water Project Sample(s) pi l veflfied to be - .2 by Date;
S le 's were not received ata H c& -2 and were ad jwvwd aconrditl ly using SRA
Sample labels applied
b Verified by: Date;
Comments,
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

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