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Home My WebLink AboutNC0000396_J15060830 Report_20150823+ DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Order Number: J15060830 Project Name: ASHEVILLE - AB GW ASSESSMENT SOIL Customer Name(s): Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker Customer Address: 200 CP and L Drive Arden, NC 28704 Lab Contact: Margaret Galvin -Karr Phone: 980-875-5219 MXG4644 (101161) 2015.07.14 08:02:54 Date: Report Authorized By: �RGYw -04'00' (Signature) Margaret Galvin -Karr Program Comments: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 7/14/2015 1 of 76 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: 2 of 76 Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015020935 ASHEVILLE 23 -Jun -15 9:15 AM illegible MW -22(1-2) 2015020936 ASHEVILLE 23 -Jun -15 10:15 AM illegible MW -22(7-8) 2015020937 ASHEVILLE 23 -Jun -15 10:25 AM illegible MW -22(1 0-11) 2015020938 ASHEVILLE 23 -Jun -15 9:48 AM illegible MW-21SB(2-3) 2015020939 ASHEVILLE 23 -Jun -15 12:20 PM illegible MW-21SB(7-8) 2015020940 ASHEVILLE 23 -Jun -15 8:20 AM illegible Equipment Blank 6 Total Samples Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes F./] No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report 3 of 76 Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 66 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Reviewed By: Margaret Galvin -Karr Date: 7/14/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060830 Site: MW -22(1-2) Collection Date: 23 -Jun -15 9:15 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 4 of 76 Sample #: 2015020935 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060830 Site: MW -22(7-8) Collection Date: 23 -Jun -15 10:15 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 5 of 76 Sample #: 2015020936 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060830 Site: MW -22(10-11) Collection Date: 23 -Jun -15 10:25 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6 of 76 Sample #: 2015020937 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060830 Site: MW -21 SB(2-3) Collection Date: 23 -Jun -15 9:48 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 7 of 76 Sample #: 2015020938 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060830 Site: MW -21 SB(7-8) Collection Date: 23 -Jun -15 12:20 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 8 of 76 Sample #: 2015020939 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis 9 of 76 This report shall not be reproduced, except in full. Order # J15060830 Site: Equipment Blank Collection Date: 23 -Jun -15 8:20 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015020940 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE aceAnaiXical www.pacelabs.com July 13, 2015 Marge Galvin -Karr RE: Project: J15060830 REV Pace Project No.: 92256104 Dear Marge Galvin -Karr: Pace Analytical Services, Inc. 9800 )i6g8y fte. Suite 100 Huntersville, INC 28078 (704)875-9092 Enclosed are the analytical results for sample(s) received by the laboratory on June 25, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. This report was revised 7/13/15 to add Al & Fe to the SPLP list. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Rodney Wilke, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy pie PIC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 1 of 66 9eORAT�O lacmnalyfica( www.pacelabs.com Project: J15060830 REV Pace Project No.: 92256104 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21 -A Certification #: 2926.01 Alaska Certification #: UST -078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ -0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH -0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. 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Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN -002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE -OS -28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 North Carolina Certification #: 12710 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 North Carolina Drinking Water Certification #: 37712 Florida/NELAP Certification #: E87648 North Carolina Wastewater Certification #: 40 Massachusetts Certification #: M-NC030 South Carolina Certification #: 99030001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 66 aceAnaiXical www.pacelabs.com CERTIFICATIONS Project: J15060830 REV Pace Project No.: 92256104 Asheville Certification IDs West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 f iQ'8y fte. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 66 aceAnaiXical www.pacelabs.com SAMPLE SUMMARY Project: J15060830 REV Pace Project No.: 92256104 Lab ID Sample ID Matrix Date Collected Date Received 92256104001 2015020935 Solid 06/23/15 09:15 06/25/15 14:45 92256104002 2015020936 Solid 06/23/1510:15 06/25/1514:45 92256104003 2015020937 Solid 06/23/1510:25 06/25/1514:45 92256104004 2015020938 Solid 06/23/15 09:48 06/25/15 14:45 92256104005 2015020939 Solid 06/23/1512:20 06/25/1514:45 92256104006 2015020940 Water 06/23/15 08:20 06/25/15 14:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 f ig'8y fte. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 66 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 9800 ffli '8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15060830 REV 92256104 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92256104001 2015020935 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 Modified TJJ 4 PASI-G 92256104002 2015020936 EPA 6010 CKJ, TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 6020A RAG 24 PASI-M EPA 7470A LMW 1 PASI-M EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E SER 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 Modified TJJ 4 PASI-G 92256104003 2015020937 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 Modified TJJ 4 PASI-G 92256104004 2015020938 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 TEP 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 Modified TJJ 4 PASI-G REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 66 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Project: J15060830 REV Pace Project No.: 92256104 Pace Analytical Services, Inc. 9800 f ig'8y fte. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92256104005 2015020939 EPA 6010 CKJ, TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 6020A RAG 24 PASI-M EPA 7470A LMW 1 PASI-M EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 TEP 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E SER 1 PASI-A EPA 9056 CMB 2 PASI-O EPA 9056 CMB 1 PASI-O EPA 9060 Modified TJJ 4 PASI-G 92256104006 2015020940 EPA 6020A AJM, RAG 24 PASI-M EPA 7470A LMW 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 66 aceAnaiXical www.pacelabs.com SUMMARY OF DETECTION Pace Analytical Services, Inc. 9800 ffli '8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15060830 REV 92256104 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92256104001 2015020935 EPA 6010 Aluminum 15100 mg/kg 29.4 07/08/15 16:47 M1 EPA 6010 Barium 112 mg/kg 2.9 07/08/1516:47 M1,R1 EPA 6010 Beryllium 0.92 mg/kg 0.29 07/08/15 16:47 EPA 6010 Calcium 330 mg/kg 147 07/08/15 16:47 EPA 6010 Chromium 17.7 mg/kg 1.5 07/08/15 16:47 EPA 6010 Copper 9.4 mg/kg 1.5 07/08/15 16:47 EPA 6010 Iron 17600 mg/kg 11.8 07/08/15 16:47 M1 EPA 6010 Magnesium 1740 mg/kg 147 07/08/1516:47 M1,R1 EPA 6010 Manganese 716 mg/kg 1.5 07/08/1516:47 M1,R1 EPA 6010 Nickel 9.6 mg/kg 1.5 07/08/15 16:47 EPA 6010 Potassium 1330 mg/kg 294 07/08/1516:47 M1,R1 EPA 6010 Strontium 3.4 mg/kg 2.9 07/08/15 16:47 EPA 6010 Zinc 33.3 mg/kg 5.9 07/08/15 16:47 EPA 6020 Arsenic 3.OJ mg/kg 5.9 07/10/15 12:30 EPA 6020 Cobalt 9.7 mg/kg 5.9 07/10/15 12:30 M6 EPA 6020 Lead 11.8 mg/kg 5.9 07/10/15 12:30 M6 EPA 6020 Vanadium 25.6 mg/kg 5.9 07/10/15 12:30 M6 EPA 7471 Mercury 0.035 mg/kg 0.0094 07/08/15 11:06 ASTM D2974-87 Percent Moisture 16.5 % 0.10 07/09/15 08:03 EPA 9045 pH at 25 Degrees C 5.7 Std. Units 0.10 06/30/15 16:05 EPA 9060 Modified RPD% 16.0 % 0.10 07/09/15 16:26 EPA 9060 Modified Total Organic Carbon 4010 mg/kg 713 07/09/15 16:26 EPA 9060 Modified Total Organic Carbon 4710 mg/kg 718 07/09/15 16:33 EPA 9060 Modified Mean Total Organic Carbon 4360 mg/kg 716 07/09/15 16:26 92256104002 2015020936 EPA 6010 Aluminum 49600 mg/kg 189 07/09/15 09:27 EPA 6010 Barium 197 mg/kg 3.8 07/08/15 17:12 EPA 6010 Beryllium 1.7 mg/kg 0.38 07/08/15 17:12 EPA 6010 Calcium 244 mg/kg 189 07/08/15 17:12 EPA 6010 Chromium 47.8 mg/kg 1.9 07/08/15 17:12 EPA 6010 Copper 23.3 mg/kg 1.9 07/08/15 17:12 EPA 6010 Iron 58500 mg/kg 75.6 07/09/15 09:27 EPA 6010 Magnesium 6810 mg/kg 189 07/08/15 17:12 EPA 6010 Manganese 110 mg/kg 9.4 07/09/15 09:27 EPA 6010 Nickel 30.3 mg/kg 1.9 07/08/15 17:12 EPA 6010 Potassium 3740 mg/kg 378 07/08/15 17:12 EPA 6010 Sodium 241J mg/kg 378 07/08/1517:12 EPA 6010 Strontium 3.OJ mg/kg 3.8 07/08/15 17:12 EPA 6010 Zinc 76.5 mg/kg 7.6 07/08/15 17:12 EPA 6020 Cobalt 13.5 mg/kg 7.6 07/10/15 12:33 EPA 6020 Lead 20.2 mg/kg 7.6 07/10/15 12:33 EPA 6020 Vanadium 43.2 mg/kg 7.6 07/10/15 12:33 EPA 6020A Aluminum 38AJ ug/L 100 07/05/15 17:14 EPA 6020A Barium 3.7J ug/L 100 07/05/1517:14 1g EPA 6020A Calcium 487 ug/L 400 07/05/1517:14 1g EPA 6020A Lead 37.2 ug/L 1.0 07/06/1514:12 1g EPA 6020A Magnesium 95.3J ug/L 100 07/06/15 14:12 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 66 aceAnaiXical www.pacelabs.com Project: J15060830 REV Pace Project No.: 92256104 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 9800 ffli .8yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92256104002 2015020936 EPA 6020A Molybdenum 1 AJ ug/L 5.0 07/05/15 17:14 EPA 6020A Potassium 205J ug/L 500 07/05/15 17:14 EPA 6020A Sodium 7650 ug/L 500 07/05/15 17:14 EPA 7471 Mercury 0.068 mg/kg 0.012 07/08/15 11:17 ASTM D2974-87 Percent Moisture 31.9 % 0.10 07/09/15 08:03 EPA 9045 pH at 25 Degrees C 6.0 Std. Units 0.10 06/30/15 16:05 EPA 300.0 Sulfate 15.7 mg/L 2.9 07/02/15 15:04 EPA 353.2 Nitrogen, Nitrate 0.44 mg/L 0.29 07/06/15 15:55 EPA 9060 Modified RPD% 9.3 % 0.10 07/09/15 16:38 EPA 9060 Modified Total Organic Carbon 1660 mg/kg 884 07/09/15 16:38 EPA 9060 Modified Total Organic Carbon 1510 mg/kg 885 07/09/15 16:45 EPA 9060 Modified Mean Total Organic Carbon 1580 mg/kg 885 07/09/15 16:38 92256104003 2015020937 EPA 6010 Aluminum 17200 mg/kg 31.5 07/08/15 17:28 EPA 6010 Barium 74.8 mg/kg 3.1 07/08/15 17:28 EPA 6010 Beryllium 0.69 mg/kg 0.31 07/08/15 17:28 EPA 6010 Calcium 384 mg/kg 157 07/08/15 17:28 EPA 6010 Chromium 17.8 mg/kg 1.6 07/08/15 17:28 EPA 6010 Copper 78.6 mg/kg 1.6 07/08/15 17:28 EPA 6010 Iron 41800 mg/kg 12.6 07/08/15 17:28 EPA 6010 Magnesium 7320 mg/kg 157 07/08/15 17:28 EPA 6010 Manganese 158 mg/kg 1.6 07/08/15 17:28 EPA 6010 Nickel 14.1 mg/kg 1.6 07/08/15 17:28 EPA 6010 Potassium 6250 mg/kg 315 07/08/15 17:28 EPA 6010 Strontium 3.OJ mg/kg 3.1 07/08/15 17:28 EPA 6010 Zinc 71.6 mg/kg 6.3 07/08/15 17:28 EPA 6020 Cobalt 14.0 mg/kg 6.3 07/10/15 12:35 EPA 6020 Lead 4.9J mg/kg 6.3 07/10/15 12:35 EPA 6020 Vanadium 16.6 mg/kg 6.3 07/10/15 12:35 ASTM D2974-87 Percent Moisture 19.9 % 0.10 07/09/15 08:03 EPA 9045 pH at 25 Degrees C 5.8 Std. Units 0.10 06/30/15 16:05 EPA 9056 Sulfate 182J mg/kg 307 07/06/15 21:06 EPA 9060 Modified RPD% 12.5 % 0.10 07/08/15 19:07 EPA 9060 Modified Total Organic Carbon 3540 mg/kg 747 07/08/15 19:07 EPA 9060 Modified Total Organic Carbon 4010 mg/kg 745 07/08/15 19:14 EPA 9060 Modified Mean Total Organic Carbon 3780 mg/kg 746 07/08/15 19:07 92256104004 2015020938 EPA 6010 Aluminum 13300 mg/kg 33.3 07/08/15 17:32 EPA 6010 Barium 62.7 mg/kg 3.3 07/08/15 17:32 EPA 6010 Beryllium 0.51 mg/kg 0.33 07/08/15 17:32 EPA 6010 Calcium 317 mg/kg 166 07/08/15 17:32 EPA 6010 Chromium 12.1 mg/kg 1.7 07/08/15 17:32 EPA 6010 Copper 16.0 mg/kg 1.7 07/08/15 17:32 EPA 6010 Iron 11800 mg/kg 13.3 07/08/15 17:32 EPA 6010 Magnesium 4090 mg/kg 166 07/08/15 17:32 EPA 6010 Manganese 70.2 mg/kg 1.7 07/08/15 17:32 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 1g B H1 D3 Qualifiers Page 8 of 66 aceAnaiXical www.pacelabs.com Project: J15060830 REV Pace Project No.: 92256104 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 9800 ffli%c&ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92256104004 2015020938 EPA 6010 Nickel 8.7 mg/kg 1.7 07/08/15 17:32 EPA 6010 Potassium 975 mg/kg 333 07/08/15 17:32 EPA 6010 Strontium 11.4 mg/kg 3.3 07/08/15 17:32 EPA 6010 Zinc 47.7 mg/kg 6.7 07/08/15 17:32 EPA 6020 Cobalt 4.5J mg/kg 6.7 07/10/15 12:38 EPA 6020 Lead 3.7J mg/kg 6.7 07/10/15 12:38 EPA 6020 Vanadium 16.9 mg/kg 6.7 07/10/15 12:38 EPA 7471 Mercury 0.024 mg/kg 0.010 07/08/15 11:24 ASTM D2974-87 Percent Moisture 23.6 % 0.10 07/09/15 08:03 EPA 9045 pH at 25 Degrees C 5.0 Std. Units 0.10 07/03/15 15:20 EPA 9060 Modified RPD% 15.6 % 0.10 07/08/15 19:21 EPA 9060 Modified Total Organic Carbon 2800 mg/kg 783 07/08/15 19:21 EPA 9060 Modified Total Organic Carbon 2400 mg/kg 785 07/08/15 19:27 EPA 9060 Modified Mean Total Organic Carbon 2600 mg/kg 784 07/08/15 19:21 92256104005 2015020939 EPA 6010 Aluminum 41500 mg/kg 32.8 07/08/15 17:36 EPA 6010 Barium 195 mg/kg 3.3 07/08/15 17:36 EPA 6010 Beryllium 2.2 mg/kg 0.66 07/09/15 09:49 EPA 6010 Calcium 427 mg/kg 164 07/08/15 17:36 EPA 6010 Chromium 96.2 mg/kg 3.3 07/09/15 09:49 EPA 6010 Copper 42.7 mg/kg 3.3 07/09/15 09:49 EPA 6010 Iron 79300 mg/kg 13.1 07/08/15 17:36 EPA 6010 Magnesium 10500 mg/kg 164 07/08/15 17:36 EPA 6010 Manganese 4350 mg/kg 3.3 07/09/15 09:49 EPA 6010 Nickel 43.7 mg/kg 1.6 07/08/15 17:36 EPA 6010 Potassium 6200 mg/kg 328 07/08/15 17:36 EPA 6010 Strontium 7.9 mg/kg 3.3 07/08/15 17:36 EPA 6010 Zinc 159 mg/kg 6.6 07/08/15 17:36 EPA 6020 Arsenic 4.2J mg/kg 6.6 07/10/15 12:40 EPA 6020 Cobalt 223 mg/kg 6.6 07/10/15 12:40 EPA 6020 Lead 23.6 mg/kg 6.6 07/10/15 12:40 EPA 6020 Selenium 7.4 mg/kg 6.6 07/10/15 12:40 EPA 6020 Vanadium 82.9 mg/kg 6.6 07/10/15 12:40 EPA 6020A Aluminum 4790 ug/L 100 07/05/15 17:16 EPA 6020A Barium 36.OJ ug/L 100 07/05/15 17:16 EPA 6020A Boron 141 ug/L 50.0 07/05/15 17:16 EPA 6020A Calcium 367J ug/L 400 07/05/15 17:16 EPA 6020A Chromium 7.8 ug/L 5.0 07/05/15 17:16 EPA 6020A Cobalt 121 ug/L 5.0 07/05/15 17:16 EPA 6020A Copper 6.7J ug/L 10.0 07/05/15 17:16 EPA 6020A Iron 14300 ug/L 500 07/05/15 17:16 EPA 6020A Lead 5.4 ug/L 1.0 07/06/15 14:15 EPA 6020A Magnesium 545 ug/L 100 07/06/15 14:15 EPA 6020A Manganese 3080 ug/L 50.0 07/06/15 14:17 EPA 6020A Nickel 5.9 ug/L 5.0 07/05/15 17:16 EPA 6020A Potassium 245J ug/L 500 07/05/15 17:16 EPA 6020A Sodium 17300 ug/L 500 07/05/15 17:16 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. H1 1g 1g Qualifiers Page 9 of 66 aceAnaiXical www.pacelabs.com Project: J15060830 REV Pace Project No.: 92256104 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 9800 ffli ,8yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92256104005 2015020939 EPA 6020A Strontium 2.6J ug/L 5.0 07/05/15 17:16 EPA 6020A Thallium 1.0 ug/L 1.0 07/05/15 17:16 EPA 6020A Vanadium 6.6J ug/L 10.0 07/05/15 17:16 EPA 7471 Mercury 0.014 mg/kg 0.010 07/08/15 11:26 ASTM D2974-87 Percent Moisture 22.4 % 0.10 07/09/15 08:03 EPA 9045 pH at 25 Degrees C 5.3 Std. Units 0.10 07/03/15 15:20 H1 EPA 300.0 Sulfate 8.4 mg/L 2.6 07/02/15 15:17 B EPA 353.2 Nitrogen, Nitrate 0.39 mg/L 0.26 07/06/1515:57 H1 EPA 9060 Modified RPD% 13.5 % 0.10 07/08/15 21:28 EPA 9060 Modified Total Organic Carbon 1640 mg/kg 777 07/08/15 21:28 EPA 9060 Modified Total Organic Carbon 1430 mg/kg 780 07/08/15 21:35 EPA 9060 Modified Mean Total Organic Carbon 1530 mg/kg 778 07/08/15 21:28 92256104006 2015020940 EPA 6020A Aluminum 3820 ug/L 10.0 06/29/15 17:43 EPA 6020A Antimony 0.27J ug/L 0.50 06/28/15 20:12 EPA 6020A Arsenic 1.5 ug/L 0.50 06/28/15 20:12 EPA 6020A Barium 23.0 ug/L 0.30 06/28/15 20:12 EPA 6020A Beryllium 0.10J ug/L 0.20 06/28/15 20:12 EPA 6020A Boron 3.6J ug/L 5.0 06/29/15 17:43 EPA 6020A Calcium 367 ug/L 40.0 06/29/15 17:43 EPA 6020A Chromium 11.8 ug/L 0.50 06/28/15 20:12 EPA 6020A Cobalt 1.2 ug/L 0.50 06/28/15 20:12 EPA 6020A Copper 3.2 ug/L 1.0 06/28/15 20:12 EPA 6020A Iron 6210 ug/L 50.0 06/29/15 17:43 EPA 6020A Lead 4.0 ug/L 0.10 06/28/15 20:12 EPA 6020A Magnesium 299 ug/L 10.0 06/28/15 20:12 EPA 6020A Manganese 51.1 ug/L 0.50 06/28/15 20:12 EPA 6020A Molybdenum 0.20J ug/L 0.50 06/28/15 20:12 EPA 6020A Nickel 129 ug/L 0.50 06/28/15 20:12 EPA 6020A Potassium 370 ug/L 50.0 06/28/15 20:12 EPA 6020A Sodium 77.4 ug/L 50.0 06/29/15 17:43 EPA 6020A Strontium 3.2 ug/L 0.50 06/28/15 20:12 EPA 6020A Thallium 0.052J ug/L 0.10 06/28/15 20:12 EPA 6020A Vanadium 14.2 ug/L 1.0 06/28/15 20:12 EPA 6020A Zinc 47.0 ug/L 5.0 06/28/15 20:12 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 66 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060830 REV Pace Project No.: 92256104 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: July 13, 2015 Pace Analytical Services, Inc. 9800 KPi '8fft.. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 5 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/25106 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92256104001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1262233) • Aluminum • Barium • Iron • Magnesium • Manganese • Molybdenum • Potassium • MSD (Lab ID: 1262234) • Aluminum • Barium • Iron • Magnesium • Manganese • Potassium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 66 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 tf�T'8y fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060830 REV Pace Project No.: 92256104 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: July 13, 2015 QC Batch: MPRP/25106 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92256104001 R1: RPD value was outside control limits. • MSD (Lab ID: 1262234) • Barium • Magnesium • Manganese • Potassium Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICP / 15292 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 66 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060830 REV Pace Project No.: 92256104 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: July 13, 2015 Pace Analytical Services, Inc. 9800 KQ'igy ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 5 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/25107 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92256104001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1262240) • Antimony • Cobalt • Selenium • Vanadium • MSD (Lab ID: 1262241) • Antimony • Cobalt • Lead • Selenium • Vanadium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 66 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KS'8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060830 REV Pace Project No.: 92256104 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: July 13, 2015 Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICPM / 10191 Analyte Comments: QC Batch: MPRP/25107 N2: The lab does not hold TNI accreditation for this parameter. •2015020935 (Lab ID:92256104001) • Antimony •2015020936 (Lab ID:92256104002) • Antimony •2015020937 (Lab ID:92256104003) • Antimony •2015020938 (Lab ID:92256104004) • Antimony •2015020939 (Lab ID:92256104005) • Antimony • BLANK (Lab ID: 1262238) • Antimony • LCS (Lab ID: 1262239) • Antimony • MS (Lab ID: 1262240) • Antimony • MSD (Lab ID: 1262241) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 66 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060830 REV Pace Project No.: 92256104 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: July 13, 2015 Pace Analytical Services, Inc. 9800 K4'8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 1 sample was analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/55604 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92256087001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 2008901) • Aluminum • Iron • Manganese • MSD (Lab ID: 2008902) • Aluminum • Iron Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 66 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060830 REV Pace Project No.: 92256104 Method: EPA 6020A Description: 6020A MET ICPMS, SPLP Client: Duke Energy Date: July 13, 2015 Pace Analytical Services, Inc. 9800 KPi '8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 2 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: MPRP/55752 1g: Analyte was detected in the associated leachate blank. •2015020936 (Lab ID: 92256104002) • Barium • Calcium • Sodium • Lead •2015020939 (Lab ID: 92256104005) • Calcium • Lead REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 66 aceAnaiXical www.pacelabs.com Project: J15060830 REV Pace Project No.: 92256104 Method: EPA 6020A Description: 6020A MET ICPMS, SPLP Client: Duke Energy Date: July 13, 2015 Analyte Comments: QC Batch: MPRP/55752 •2015020939 (Lab ID: 92256104005) • Sodium Pace Analytical Services, Inc. 9800 tf� '8fftie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 66 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060830 REV Pace Project No.: 92256104 Method: EPA 7470A Description: 7470A Mercury, SPLP Client: Duke Energy Date: July 13, 2015 Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 2 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 66 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060830 REV Pace Project No.: 92256104 Method: EPA 7470A Description: 7470A Mercury Client: Duke Energy Date: July 13, 2015 Pace Analytical Services, Inc. 9800 KPi '8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 1 sample was analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 66 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060830 REV Pace Project No.: 92256104 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: July 13, 2015 Pace Analytical Services, Inc. 9800 %'8fftie. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 5 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 66 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060830 REV Pace Project No.: 92256104 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: July 13, 2015 Pace Analytical Services, Inc. 9800 tri '8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 5 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015020938 (Lab ID: 92256104004) •2015020939 (Lab ID: 92256104005) Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 66 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060830 REV Pace Project No.: 92256104 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: July 13, 2015 Pace Analytical Services, Inc. 9800 �nlc&)rfte. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 2 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/23569 B: Analyte was detected in the associated method blank. • BLANK for HBN 270836 [WETA/235 (Lab ID: 1500538) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 66 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060830 REV Pace Project No.: 92256104 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: July 13, 2015 Pace Analytical Services, Inc. 9800 �2c8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 2 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015020936 (Lab ID: 92256104002) •2015020939 (Lab ID: 92256104005) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 66 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060830 REV Pace Project No.: 92256104 Method: SM 4500 -CI -E Description: 4500 Chloride, SPLP Client: Duke Energy Date: July 13, 2015 Pace Analytical Services, Inc. 9800 t S'8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 2 samples were analyzed for SM 4500 -CI -E. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 66 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060830 REV Pace Project No.: 92256104 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: July 13, 2015 Pace Analytical Services, Inc. 9800 t 4'8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 5 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/47925 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015020935 (Lab ID:92256104001) • Chloride • Sulfate •2015020936 (Lab ID:92256104002) • Chloride • Sulfate •2015020937 (Lab ID:92256104003) • Chloride • Sulfate •2015020938 (Lab ID:92256104004) • Chloride • Sulfate •2015020939 (Lab ID:92256104005) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 66 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060830 REV Pace Project No.: 92256104 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: July 13, 2015 Pace Analytical Services, Inc. 9800 tri '8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 5 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015020935 (Lab ID: 92256104001) •2015020936 (Lab ID: 92256104002) •2015020937 (Lab ID: 92256104003) •2015020938 (Lab ID: 92256104004) •2015020939 (Lab ID: 92256104005) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/47924 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015020935 (Lab ID: 92256104001) • Nitrate as N •2015020936 (Lab ID: 92256104002) • Nitrate as N •2015020937 (Lab ID: 92256104003) • Nitrate as N •2015020938 (Lab ID: 92256104004) • Nitrate as N •2015020939 (Lab ID: 92256104005) • Nitrate as N REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 66 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060830 REV Pace Project No.: 92256104 Method: EPA 9060 Modified Description: Total Organic Carbon Client: Duke Energy Date: July 13, 2015 Pace Analytical Services, Inc. 9800 %'8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 5 samples were analyzed for EPA 9060 Modified. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 66 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060830 REV Pace Project No.: 92256104 Sample: 2015020935 Lab ID: 92256104001 Collected: 06/23/15 09:15 Received: 06/25/15 14:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 15100 mg/kg 29.4 14.7 5 07/07/1516:14 07/08/1516:47 7429-90-5 M1 Barium 112 mg/kg 2.9 1.5 5 07/07/1516:14 07/08/1516:47 7440-39-3 M1,R1 Beryllium 0.92 mg/kg 0.29 0.15 5 07/07/1516:14 07/08/1516:47 7440-41-7 Boron ND mg/kg 14.7 7.4 5 07/07/1516:14 07/08/1516:47 7440-42-8 Calcium 330 mg/kg 147 73.6 5 07/07/1516:14 07/08/1516:47 7440-70-2 Chromium 17.7 mg/kg 1.5 0.74 5 07/07/1516:14 07/08/1516:47 7440-47-3 Copper 9.4 mg/kg 1.5 0.74 5 07/07/1516:14 07/08/1516:47 7440-50-8 Iron 17600 mg/kg 11.8 5.9 5 07/07/1516:14 07/08/1516:47 7439-89-6 M1 Magnesium 1740 mg/kg 147 73.6 5 07/07/1516:14 07/08/1516:47 7439-95-4 M1,R1 Manganese 716 mg/kg 1.5 0.74 5 07/07/1516:14 07/08/1516:47 7439-96-5 M1,R1 Molybdenum ND mg/kg 2.9 1.5 5 07/07/1516:14 07/08/1516:47 7439-98-7 M1 Nickel 9.6 mg/kg 1.5 0.74 5 07/07/1516:14 07/08/1516:47 7440-02-0 Potassium 1330 mg/kg 294 147 5 07/07/1516:14 07/08/1516:47 7440-09-7 M1,R1 Sodium ND mg/kg 294 147 5 07/07/1516:14 07/08/1516:47 7440-23-5 Strontium 3.4 mg/kg 2.9 1.5 5 07/07/1516:14 07/08/1516:47 7440-24-6 Zinc 33.3 mg/kg 5.9 2.9 5 07/07/1516:14 07/08/1516:47 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 5.9 2.9 100 07/07/1516:14 07/10/1512:30 7440-36-0 M6, N2 Arsenic 3.OJ mg/kg 5.9 2.9 100 07/07/1516:14 07/10/1512:30 7440-38-2 Cadmium ND mg/kg 0.71 0.35 100 07/07/1516:14 07/10/1512:30 7440-43-9 Cobalt 9.7 mg/kg 5.9 2.9 100 07/07/1516:14 07/10/1512:30 7440-48-4 M6 Lead 11.8 mg/kg 5.9 2.9 100 07/07/1516:14 07/10/1512:30 7439-92-1 M6 Selenium ND mg/kg 5.9 2.9 100 07/07/1516:14 07/10/1512:30 7782-49-2 M6 Thallium ND mg/kg 5.9 2.9 100 07/07/1516:14 07/10/1512:30 7440-28-0 Vanadium 25.6 mg/kg 5.9 2.9 100 07/07/1516:14 07/10/1512:30 7440-62-2 M6 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.035 mg/kg 0.0094 0.0047 1 07/07/1516:31 07/08/1511:06 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 16.5 % 0.10 0.10 1 07/09/15 08:03 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.7 Std. Units 0.10 0.10 1 06/30/15 16:05 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 297 148 5 07/06/1519:37 16887-00-6 D3,M1 Sulfate ND mg/kg 297 148 5 07/06/1519:37 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 29.7 14.8 5 07/06/15 19:37 14797-55-8 D3,H3 Date: 07/13/2015 05:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 66 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060830 REV Pace Project No.: 92256104 Pace Analytical Services, Inc. 9800 %'8fft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015020935 Lab ID: 92256104001 Collected: 06/23/15 09:15 Received: 06/25/15 14:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Analytical Method: EPA 9060 Modified Surrogates RPD% 16.0 % 0.10 0.10 1 07/09/1516:26 Total Organic Carbon 4010 mg/kg 713 357 1 07/09/15 16:26 7440-44-0 Total Organic Carbon 4710 mg/kg 718 359 1 07/09/15 16:33 7440-44-0 Mean Total Organic Carbon 4360 mg/kg 716 358 1 07/09/15 16:26 7440-44-0 Date: 07/13/2015 05:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 66 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060830 REV Pace Project No.: 92256104 Pace Analytical Services, Inc. 9800 Kai '8fft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015020936 Lab ID: 92256104002 Collected: 06/23/15 10:15 Received: 06/25/15 14:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 49600 mg/kg 189 94.5 25 07/07/15 16:14 07/09/15 09:27 7429-90-5 Barium 197 mg/kg 3.8 1.9 5 07/07/1516:14 07/08/1517:12 7440-39-3 Beryllium 1.7 mg/kg 0.38 0.19 5 07/07/1516:14 07/08/1517:12 7440-41-7 Boron ND mg/kg 18.9 9.4 5 07/07/1516:14 07/08/1517:12 7440-42-8 Calcium 244 mg/kg 189 94.5 5 07/07/1516:14 07/08/1517:12 7440-70-2 Chromium 47.8 mg/kg 1.9 0.94 5 07/07/1516:14 07/08/1517:12 7440-47-3 Copper 23.3 mg/kg 1.9 0.94 5 07/07/1516:14 07/08/1517:12 7440-50-8 Iron 58500 mg/kg 75.6 37.8 25 07/07/15 16:14 07/09/15 09:27 7439-89-6 Magnesium 6810 mg/kg 189 94.5 5 07/07/1516:14 07/08/1517:12 7439-95-4 Manganese 110 mg/kg 9.4 4.7 25 07/07/15 16:14 07/09/15 09:27 7439-96-5 Molybdenum ND mg/kg 3.8 1.9 5 07/07/1516:14 07/08/1517:12 7439-98-7 Nickel 30.3 mg/kg 1.9 0.94 5 07/07/1516:14 07/08/1517:12 7440-02-0 Potassium 3740 mg/kg 378 189 5 07/07/1516:14 07/08/1517:12 7440-09-7 Sodium 241J mg/kg 378 189 5 07/07/1516:14 07/08/1517:12 7440-23-5 Strontium 3.OJ mg/kg 3.8 1.9 5 07/07/1516:14 07/08/1517:12 7440-24-6 Zinc 76.5 mg/kg 7.6 3.8 5 07/07/1516:14 07/08/1517:12 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 7.6 3.8 100 07/07/1516:14 07/10/1512:33 7440-36-0 Arsenic ND mg/kg 7.6 3.8 100 07/07/1516:14 07/10/1512:33 7440-38-2 Cadmium ND mg/kg 0.91 0.45 100 07/07/1516:14 07/10/1512:33 7440-43-9 Cobalt 13.5 mg/kg 7.6 3.8 100 07/07/1516:14 07/10/1512:33 7440-48-4 Lead 20.2 mg/kg 7.6 3.8 100 07/07/1516:14 07/10/1512:33 7439-92-1 Selenium ND mg/kg 7.6 3.8 100 07/07/1516:14 07/10/1512:33 7782-49-2 Thallium ND mg/kg 7.6 3.8 100 07/07/1516:14 07/10/1512:33 7440-28-0 Vanadium 43.2 mg/kg 7.6 3.8 100 07/07/1516:14 07/10/1512:33 7440-62-2 6020A MET ICPMS, SPLP Analytical Method: EPA 6020A Preparation Method: EPA 3020 Leachate Method/Date: EPA 1312; 07/01/15 15:08 Aluminum 38AJ ug/L 100 29.8 1 07/01/1517:33 07/05/1517:14 7429-90-5 Antimony ND ug/L 5.0 1.5 1 07/01/1517:33 07/05/1517:14 7440-36-0 Arsenic ND ug/L 5.0 1.1 1 07/01/1517:33 07/05/1517:14 7440-38-2 Barium 3.7J ug/L 100 0.81 1 07/01/1517:33 07/05/1517:14 7440-39-3 Beryllium ND ug/L 2.0 0.67 1 07/01/1517:33 07/05/1517:14 7440-41-7 Boron ND ug/L 50.0 11.1 1 07/01/1517:33 07/05/1517:14 7440-42-8 Cadmium ND ug/L 0.80 0.24 1 07/01/1517:33 07/05/1517:14 7440-43-9 Calcium 487 ug/L 400 160 1 07/01/1517:33 07/05/1517:14 7440-70-2 Chromium ND ug/L 5.0 1.7 1 07/01/1517:33 07/05/1517:14 7440-47-3 Cobalt ND ug/L 5.0 1.3 1 07/01/1517:33 07/05/1517:14 7440-48-4 Copper ND ug/L 10.0 2.1 1 07/01/1517:33 07/05/1517:14 7440-50-8 Iron ND ug/L 500 137 1 07/01/1517:33 07/05/1517:14 7439-89-6 Lead 37.2 ug/L 1.0 0.46 1 07/01/1517:33 07/06/1514:12 7439-92-1 Magnesium 95.3J ug/L 100 31.7 1 07/01/1517:33 07/06/1514:12 7439-95-4 Manganese ND ug/L 5.0 2.4 1 07/01/1517:33 07/05/1517:14 7439-96-5 Molybdenum 1AJ ug/L 5.0 0.94 1 07/01/1517:33 07/05/1517:14 7439-98-7 REPORT OF LABORATORY ANALYSIS N2 iE This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 30 of 66 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060830 REV Pace Project No.: 92256104 Pace Analytical Services, Inc. 9800 %'8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015020936 Lab ID: 92256104002 Collected: 06/23/15 10:15 Received: 06/25/15 14:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020A MET ICPMS, SPLP Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury, SPLP Mercury 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, N021NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Total Organic Carbon Surrogates RPD% Total Organic Carbon Total Organic Carbon Date: 07/13/2015 05:15 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 Leachate Method/Date: EPA 1312; 07/01/15 15:08 ND ug/L 5.0 1.6 1 07/01/1517:33 07/05/1517:14 7440-02-0 205J ug/L 500 117 1 07/01/1517:33 07/05/1517:14 7440-09-7 ND ug/L 5.0 2.0 1 07/01/1517:33 07/05/1517:14 7782-49-2 7650 ug/L 500 163 1 07/01/1517:33 07/05/1517:14 7440-23-5 1g ND ug/L 5.0 1.3 1 07/01/1517:33 07/05/1517:14 7440-24-6 ND ug/L 1.0 0.15 1 07/01/1517:33 07/05/1517:14 7440-28-0 ND ug/L 10.0 2.8 1 07/01/1517:33 07/05/1517:14 7440-62-2 ND ug/L 50.0 24.1 1 07/01/1517:33 07/06/1514:12 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A Leachate Method/Date: EPA 1312; 07/01/15 15:08 ND ug/L 0.20 0.022 1 07/01/1518:53 07/02/1513:56 7439-97-6 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.068 mg/kg 0.012 0.0060 1 07/07/1516:31 07/08/1511:17 7439-97-6 Analytical Method: ASTM D2974-87 31.9 % 0.10 0.10 1 07/09/15 08:03 Analytical Method: EPA 9045 6.0 Std. Units 0.10 0.10 1 06/30/15 16:05 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 06/28/15 20:20 15.7 mg/L 2.9 1.5 1 07/02/1515:04 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 06/28/15 20:20 0.44 mg/L 0.29 0.29 1 07/06/1515:55 H1 Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 06/28/15 20:20 ND mg/L 7.3 3.7 1 06/30/15 03:38 16887-00-6 Analytical Method: EPA 9056 ND mg/kg 352 176 5 07/06/15 20:44 16887-00-6 D3 ND mg/kg 352 176 5 07/06/15 20:44 14808-79-8 D3 Analytical Method: EPA 9056 ND mg/kg 35.2 17.6 5 07/06/15 20:44 14797-55-8 D3,H3 Analytical Method: EPA 9060 Modified 9.3 % 0.10 0.10 1 07/09/1516:38 1660 mg/kg 884 442 1 07/09/1516:38 7440-44-0 1510 mg/kg 885 443 1 07/09/1516:45 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 31 of 66 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060830 REV Pace Project No.: 92256104 Pace Analytical Services, Inc. 9800 1in�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015020936 Lab ID: 92256104002 Collected: 06/23/15 10:15 Received: 06/25/15 14:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Analytical Method: EPA 9060 Modified Mean Total Organic Carbon 1580 mg/kg 885 442 1 07/09/15 16:38 7440-44-0 Date: 07/13/2015 05:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 32 of 66 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060830 REV Pace Project No.: 92256104 Sample: 2015020937 Lab ID: 92256104003 Collected: 06/23/15 10:25 Received: 06/25/15 14:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 17200 mg/kg 31.5 15.7 5 07/07/1516:14 07/08/1517:28 7429-90-5 Barium 74.8 mg/kg 3.1 1.6 5 07/07/1516:14 07/08/1517:28 7440-39-3 Beryllium 0.69 mg/kg 0.31 0.16 5 07/07/1516:14 07/08/1517:28 7440-41-7 Boron ND mg/kg 15.7 7.9 5 07/07/1516:14 07/08/1517:28 7440-42-8 Calcium 384 mg/kg 157 78.6 5 07/07/1516:14 07/08/1517:28 7440-70-2 Chromium 17.8 mg/kg 1.6 0.79 5 07/07/1516:14 07/08/1517:28 7440-47-3 Copper 78.6 mg/kg 1.6 0.79 5 07/07/1516:14 07/08/1517:28 7440-50-8 Iron 41800 mg/kg 12.6 6.3 5 07/07/1516:14 07/08/1517:28 7439-89-6 Magnesium 7320 mg/kg 157 78.6 5 07/07/1516:14 07/08/1517:28 7439-95-4 Manganese 158 mg/kg 1.6 0.79 5 07/07/1516:14 07/08/1517:28 7439-96-5 Molybdenum ND mg/kg 3.1 1.6 5 07/07/1516:14 07/08/1517:28 7439-98-7 Nickel 14.1 mg/kg 1.6 0.79 5 07/07/1516:14 07/08/1517:28 7440-02-0 Potassium 6250 mg/kg 315 157 5 07/07/1516:14 07/08/1517:28 7440-09-7 Sodium ND mg/kg 315 157 5 07/07/1516:14 07/08/1517:28 7440-23-5 Strontium 3.OJ mg/kg 3.1 1.6 5 07/07/1516:14 07/08/1517:28 7440-24-6 Zinc 71.6 mg/kg 6.3 3.1 5 07/07/1516:14 07/08/1517:28 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 6.3 3.1 100 07/07/1516:14 07/10/1512:35 7440-36-0 N2 Arsenic ND mg/kg 6.3 3.1 100 07/07/1516:14 07/10/1512:35 7440-38-2 Cadmium ND mg/kg 0.75 0.38 100 07/07/1516:14 07/10/1512:35 7440-43-9 Cobalt 14.0 mg/kg 6.3 3.1 100 07/07/1516:14 07/10/1512:35 7440-48-4 Lead 4.9J mg/kg 6.3 3.1 100 07/07/1516:14 07/10/1512:35 7439-92-1 Selenium ND mg/kg 6.3 3.1 100 07/07/1516:14 07/10/1512:35 7782-49-2 Thallium ND mg/kg 6.3 3.1 100 07/07/1516:14 07/10/1512:35 7440-28-0 Vanadium 16.6 mg/kg 6.3 3.1 100 07/07/1516:14 07/10/1512:35 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0096 0.0048 1 07/07/1516:31 07/08/1511:21 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 19.9 % 0.10 0.10 1 07/09/15 08:03 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.8 Std. Units 0.10 0.10 1 06/30/15 16:05 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 307 153 5 07/06/15 21:06 16887-00-6 D3 Sulfate 182J mg/kg 307 153 5 07/06/15 21:06 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 30.7 15.3 5 07/06/15 21:06 14797-55-8 D3,H3 Date: 07/13/2015 05:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 33 of 66 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060830 REV Pace Project No.: 92256104 Pace Analytical Services, Inc. 9800 %'8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015020937 Lab ID: 92256104003 Collected: 06/23/15 10:25 Received: 06/25/15 14:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Analytical Method: EPA 9060 Modified Surrogates RPD% 12.5 % 0.10 0.10 1 07/08/1519:07 Total Organic Carbon 3540 mg/kg 747 374 1 07/08/15 19:07 7440-44-0 Total Organic Carbon 4010 mg/kg 745 373 1 07/08/15 19:14 7440-44-0 Mean Total Organic Carbon 3780 mg/kg 746 373 1 07/08/15 19:07 7440-44-0 Date: 07/13/2015 05:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 34 of 66 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060830 REV Pace Project No.: 92256104 Pace Analytical Services, Inc. 9800 %'8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015020938 Lab ID: 92256104004 Collected: 06/23/15 09:48 Received: 06/25/15 14:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 07/13/2015 05:15 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 13300 mg/kg 33.3 16.6 5 07/07/1516:14 07/08/1517:32 7429-90-5 62.7 mg/kg 3.3 1.7 5 07/07/1516:14 07/08/1517:32 7440-39-3 0.51 mg/kg 0.33 0.17 5 07/07/1516:14 07/08/1517:32 7440-41-7 ND mg/kg 16.6 8.3 5 07/07/1516:14 07/08/1517:32 7440-42-8 317 mg/kg 166 83.2 5 07/07/1516:14 07/08/1517:32 7440-70-2 12.1 mg/kg 1.7 0.83 5 07/07/1516:14 07/08/1517:32 7440-47-3 16.0 mg/kg 1.7 0.83 5 07/07/1516:14 07/08/1517:32 7440-50-8 11800 mg/kg 13.3 6.7 5 07/07/1516:14 07/08/1517:32 7439-89-6 4090 mg/kg 166 83.2 5 07/07/1516:14 07/08/1517:32 7439-95-4 70.2 mg/kg 1.7 0.83 5 07/07/1516:14 07/08/1517:32 7439-96-5 ND mg/kg 3.3 1.7 5 07/07/1516:14 07/08/1517:32 7439-98-7 8.7 mg/kg 1.7 0.83 5 07/07/1516:14 07/08/1517:32 7440-02-0 975 mg/kg 333 166 5 07/07/1516:14 07/08/1517:32 7440-09-7 ND mg/kg 333 166 5 07/07/1516:14 07/08/1517:32 7440-23-5 11.4 mg/kg 3.3 1.7 5 07/07/1516:14 07/08/1517:32 7440-24-6 47.7 mg/kg 6.7 3.3 5 07/07/1516:14 07/08/1517:32 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 6.7 3.3 100 07/07/1516:14 07/10/1512:38 7440-36-0 ND mg/kg 6.7 3.3 100 07/07/1516:14 07/10/1512:38 7440-38-2 ND mg/kg 0.80 0.40 100 07/07/1516:14 07/10/1512:38 7440-43-9 4.5J mg/kg 6.7 3.3 100 07/07/1516:14 07/10/1512:38 7440-48-4 3.7J mg/kg 6.7 3.3 100 07/07/1516:14 07/10/1512:38 7439-92-1 ND mg/kg 6.7 3.3 100 07/07/1516:14 07/10/1512:38 7782-49-2 ND mg/kg 6.7 3.3 100 07/07/1516:14 07/10/1512:38 7440-28-0 16.9 mg/kg 6.7 3.3 100 07/07/1516:14 07/10/1512:38 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.024 mg/kg 0.010 0.0052 1 07/07/1516:31 07/08/1511:24 7439-97-6 Analytical Method: ASTM D2974-87 23.6 % 0.10 0.10 1 07/09/15 08:03 Analytical Method: EPA 9045 5.0 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 329 165 5 ND mg/kg 329 165 5 Analytical Method: EPA 9056 ND mg/kg 32.9 16.5 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. [t'1FAIX7f6 SIMP ; N2 I:fl 07/06/15 21:28 16887-00-6 D3 07/06/15 21:28 14808-79-8 D3 07/06/15 21:28 14797-55-8 D3,H3 Page 35 of 66 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060830 REV Pace Project No.: 92256104 Pace Analytical Services, Inc. 9800 %'8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015020938 Lab ID: 92256104004 Collected: 06/23/15 09:48 Received: 06/25/15 14:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Analytical Method: EPA 9060 Modified Surrogates RPD% 15.6 % 0.10 0.10 1 07/08/1519:21 Total Organic Carbon 2800 mg/kg 783 391 1 07/08/15 19:21 7440-44-0 Total Organic Carbon 2400 mg/kg 785 392 1 07/08/15 19:27 7440-44-0 Mean Total Organic Carbon 2600 mg/kg 784 392 1 07/08/15 19:21 7440-44-0 Date: 07/13/2015 05:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 36 of 66 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060830 REV Pace Project No.: 92256104 Pace Analytical Services, Inc. 9800 %'8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015020939 Lab ID: 92256104005 Collected: 06/23/15 12:20 Received: 06/25/15 14:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 41500 mg/kg 32.8 16.4 5 07/07/1516:14 07/08/1517:36 7429-90-5 Barium 195 mg/kg 3.3 1.6 5 07/07/1516:14 07/08/1517:36 7440-39-3 Beryllium 2.2 mg/kg 0.66 0.33 10 07/07/15 16:14 07/09/15 09:49 7440-41-7 Boron ND mg/kg 32.8 16.4 10 07/07/15 16:14 07/09/15 09:49 7440-42-8 Calcium 427 mg/kg 164 82.0 5 07/07/1516:14 07/08/1517:36 7440-70-2 Chromium 96.2 mg/kg 3.3 1.6 10 07/07/15 16:14 07/09/15 09:49 7440-47-3 Copper 42.7 mg/kg 3.3 1.6 10 07/07/15 16:14 07/09/15 09:49 7440-50-8 Iron 79300 mg/kg 13.1 6.6 5 07/07/1516:14 07/08/1517:36 7439-89-6 Magnesium 10500 mg/kg 164 82.0 5 07/07/1516:14 07/08/1517:36 7439-95-4 Manganese 4350 mg/kg 3.3 1.6 10 07/07/15 16:14 07/09/15 09:49 7439-96-5 Molybdenum ND mg/kg 3.3 1.6 5 07/07/1516:14 07/08/1517:36 7439-98-7 Nickel 43.7 mg/kg 1.6 0.82 5 07/07/1516:14 07/08/1517:36 7440-02-0 Potassium 6200 mg/kg 328 164 5 07/07/1516:14 07/08/1517:36 7440-09-7 Sodium ND mg/kg 328 164 5 07/07/1516:14 07/08/1517:36 7440-23-5 Strontium 7.9 mg/kg 3.3 1.6 5 07/07/1516:14 07/08/1517:36 7440-24-6 Zinc 159 mg/kg 6.6 3.3 5 07/07/1516:14 07/08/1517:36 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 6.6 3.3 100 07/07/1516:14 07/10/1512:40 7440-36-0 Arsenic 4.2J mg/kg 6.6 3.3 100 07/07/1516:14 07/10/1512:40 7440-38-2 Cadmium ND mg/kg 0.80 0.40 100 07/07/1516:14 07/10/1512:40 7440-43-9 Cobalt 223 mg/kg 6.6 3.3 100 07/07/1516:14 07/10/1512:40 7440-48-4 Lead 23.6 mg/kg 6.6 3.3 100 07/07/1516:14 07/10/1512:40 7439-92-1 Selenium 7.4 mg/kg 6.6 3.3 100 07/07/1516:14 07/10/1512:40 7782-49-2 Thallium ND mg/kg 6.6 3.3 100 07/07/1516:14 07/10/1512:40 7440-28-0 Vanadium 82.9 mg/kg 6.6 3.3 100 07/07/1516:14 07/10/1512:40 7440-62-2 6020A MET ICPMS, SPLP Analytical Method: EPA 6020A Preparation Method: EPA 3020 Leachate Method/Date: EPA 1312; 07/01/15 15:08 Aluminum 4790 ug/L 100 29.8 1 07/01/1517:33 07/05/1517:16 7429-90-5 Antimony ND ug/L 5.0 1.5 1 07/01/1517:33 07/05/1517:16 7440-36-0 Arsenic ND ug/L 5.0 1.1 1 07/01/1517:33 07/05/1517:16 7440-38-2 Barium 36.OJ ug/L 100 0.81 1 07/01/1517:33 07/05/1517:16 7440-39-3 Beryllium ND ug/L 2.0 0.67 1 07/01/1517:33 07/05/1517:16 7440-41-7 Boron 141 ug/L 50.0 11.1 1 07/01/1517:33 07/05/1517:16 7440-42-8 Cadmium ND ug/L 0.80 0.24 1 07/01/1517:33 07/05/1517:16 7440-43-9 Calcium 367J ug/L 400 160 1 07/01/1517:33 07/05/1517:16 7440-70-2 Chromium 7.8 ug/L 5.0 1.7 1 07/01/1517:33 07/05/1517:16 7440-47-3 Cobalt 121 ug/L 5.0 1.3 1 07/01/1517:33 07/05/1517:16 7440-48-4 Copper 6.7J ug/L 10.0 2.1 1 07/01/1517:33 07/05/1517:16 7440-50-8 Iron 14300 ug/L 500 137 1 07/01/1517:33 07/05/1517:16 7439-89-6 Lead 5.4 ug/L 1.0 0.46 1 07/01/1517:33 07/06/1514:15 7439-92-1 Magnesium 545 ug/L 100 31.7 1 07/01/1517:33 07/06/1514:15 7439-95-4 Manganese 3080 ug/L 50.0 23.8 10 07/01/1517:33 07/06/1514:17 7439-96-5 Molybdenum ND ug/L 5.0 0.94 1 07/01/1517:33 07/05/1517:16 7439-98-7 REPORT OF LABORATORY ANALYSIS N2 iE This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 37 of 66 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060830 REV Pace Project No.: 92256104 Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015020939 Lab ID: 92256104005 Collected: 06/23/15 12:20 Received: 06/25/15 14:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020A MET ICPMS, SPLP Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury, SPLP Mercury 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, N021NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Total Organic Carbon Surrogates RPD% Total Organic Carbon Total Organic Carbon Date: 07/13/2015 05:15 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 Leachate Method/Date: EPA 1312; 07/01/15 15:08 5.9 ug/L 5.0 1.6 1 07/01/1517:33 07/05/1517:16 7440-02-0 245J ug/L 500 117 1 07/01/1517:33 07/05/1517:16 7440-09-7 ND ug/L 5.0 2.0 1 07/01/1517:33 07/05/1517:16 7782-49-2 17300 ug/L 500 163 1 07/01/1517:33 07/05/1517:16 7440-23-5 2.6J ug/L 5.0 1.3 1 07/01/1517:33 07/05/1517:16 7440-24-6 1.0 ug/L 1.0 0.15 1 07/01/1517:33 07/05/1517:16 7440-28-0 6.6J ug/L 10.0 2.8 1 07/01/1517:33 07/05/1517:16 7440-62-2 ND ug/L 50.0 24.1 1 07/01/1517:33 07/06/1514:15 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A Leachate Method/Date: EPA 1312; 07/01/15 15:08 ND ug/L 0.20 0.022 1 07/01/1518:53 07/02/1513:58 7439-97-6 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.014 mg/kg 0.010 0.0051 1 07/07/1516:31 07/08/1511:26 7439-97-6 Analytical Method: ASTM D2974-87 22.4 % 0.10 0.10 1 07/09/15 08:03 Analytical Method: EPA 9045 5.3 Std. Units 0.10 0.10 1 07/03/15 15:20 H1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 06/28/15 20:20 8.4 mg/L 2.6 1.3 1 07/02/1515:17 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 06/28/15 20:20 0.39 mg/L 0.26 0.26 1 07/06/1515:57 H1 Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 06/28/15 20:20 ND mg/L 6.4 3.2 1 06/30/15 03:42 16887-00-6 Analytical Method: EPA 9056 ND mg/kg 307 153 5 07/06/15 21:50 16887-00-6 D3 ND mg/kg 307 153 5 07/06/15 21:50 14808-79-8 D3 Analytical Method: EPA 9056 ND mg/kg 30.7 15.3 5 07/06/15 21:50 14797-55-8 D3,H3 Analytical Method: EPA 9060 Modified 13.5 % 0.10 0.10 1 07/08/15 21:28 1640 mg/kg 777 388 1 07/08/15 21:28 7440-44-0 1430 mg/kg 780 390 1 07/08/15 21:35 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 38 of 66 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060830 REV Pace Project No.: 92256104 Pace Analytical Services, Inc. 9800 %'8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015020939 Lab ID: 92256104005 Collected: 06/23/15 12:20 Received: 06/25/15 14:45 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Analytical Method: EPA 9060 Modified Mean Total Organic Carbon 1530 mg/kg 778 389 1 07/08/15 21:28 7440-44-0 Date: 07/13/2015 05:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 39 of 66 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060830 REV Pace Project No.: 92256104 Pace Analytical Services, Inc. 9800 %'8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015020940 Lab ID: 92256104006 Collected: 06/23/15 08:20 Received: 06/25/15 14:45 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢ZI7c\�i,I=11 l[99�� 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 07/13/2015 05:15 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 3820 ug/L 10.0 3.0 1 06/28/1511:41 06/29/1517:43 7429-90-5 0.27J ug/L 0.50 0.15 1 06/28/15 11:41 06/28/15 20:12 7440-36-0 1.5 ug/L 0.50 0.11 1 06/28/15 11:41 06/28/15 20:12 7440-38-2 23.0 ug/L 0.30 0.081 1 06/28/15 11:41 06/28/15 20:12 7440-39-3 0.10J ug/L 0.20 0.067 1 06/28/15 11:41 06/28/15 20:12 7440-41-7 3.6J ug/L 5.0 1.1 1 06/28/1511:41 06/29/1517:43 7440-42-8 ND ug/L 0.080 0.024 1 06/28/15 11:41 06/28/15 20:12 7440-43-9 367 ug/L 40.0 16.0 1 06/28/1511:41 06/29/1517:43 7440-70-2 11.8 ug/L 0.50 0.17 1 06/28/15 11:41 06/28/15 20:12 7440-47-3 1.2 ug/L 0.50 0.13 1 06/28/15 11:41 06/28/15 20:12 7440-48-4 3.2 ug/L 1.0 0.21 1 06/28/15 11:41 06/28/15 20:12 7440-50-8 6210 ug/L 50.0 13.7 1 06/28/1511:41 06/29/1517:43 7439-89-6 4.0 ug/L 0.10 0.046 1 06/28/15 11:41 06/28/15 20:12 7439-92-1 299 ug/L 10.0 3.2 1 06/28/15 11:41 06/28/15 20:12 7439-95-4 51.1 ug/L 0.50 0.24 1 06/28/15 11:41 06/28/15 20:12 7439-96-5 0.20J ug/L 0.50 0.094 1 06/28/15 11:41 06/28/15 20:12 7439-98-7 129 ug/L 0.50 0.16 1 06/28/15 11:41 06/28/15 20:12 7440-02-0 370 ug/L 50.0 11.7 1 06/28/15 11:41 06/28/15 20:12 7440-09-7 ND ug/L 0.50 0.20 1 06/28/15 11:41 06/28/15 20:12 7782-49-2 77.4 ug/L 50.0 16.3 1 06/28/1511:41 06/29/1517:43 7440-23-5 3.2 ug/L 0.50 0.13 1 06/28/15 11:41 06/28/15 20:12 7440-24-6 0.052J ug/L 0.10 0.015 1 06/28/15 11:41 06/28/15 20:12 7440-28-0 14.2 ug/L 1.0 0.28 1 06/28/15 11:41 06/28/15 20:12 7440-62-2 47.0 ug/L 5.0 2.4 1 06/28/15 11:41 06/28/15 20:12 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 07/01/1514:20 07/01/1519:19 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 40 of 66 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060830 REV Pace Project No.: 92256104 QC Batch: MERP/14093 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury SPLP Associated Lab Samples: 92256104002, 92256104005 METHOD BLANK: 2012382 Matrix: Water Associated Lab Samples: 92256104002, 92256104005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 07/02/1513:33 METHOD BLANK: 2009309 Matrix: Solid Associated Lab Samples: 92256104002, 92256104005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 07/02/1514:00 LABORATORY CONTROL SAMPLE: 2012383 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.6 92 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2012384 2012385 MS MSD 92255787001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Mercury ug/L ND 5 5 4.5 4.5 91 90 80-120 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 41 of 66 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 1jiT igy fre. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060830 REV Pace Project No.: 92256104 QC Batch: MERP/14076 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92256104006 METHOD BLANK: 2011122 Matrix: Water Associated Lab Samples: 92256104006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 07/01/1518:45 LABORATORY CONTROL SAMPLE: 2011123 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.0 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2011564 2011565 MS MSD 92256087002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.2 5.3 105 106 80-120 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 42 of 66 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 IjiQ%yft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060830 REV Pace Project No.: 92256104 QC Batch: MERP/5952 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92256104001, 92256104002, 92256104003, 92256104004, 92256104005 METHOD BLANK: 1262242 Matrix: Solid Associated Lab Samples: 92256104001, 92256104002, 92256104003, 92256104004, 92256104005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0081 07/08/1511:02 LABORATORY CONTROL SAMPLE: 1262243 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .082 0.088 108 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1262244 1262245 MS MSD 92256104001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.035 .097 .0982 0.13 0.13 102 98 80-120 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 43 of 66 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15060830 REV Pace Project No.: 92256104 QC Batch: MPRP/25106 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92256104001, 92256104002, 92256104003, 92256104004, 92256104005 METHOD BLANK: 1262231 Matrix: Solid Associated Lab Samples: 92256104001, 92256104002, 92256104003, 92256104004, 92256104005 Blank Reporting Parameter Units Result Limit Analyzed Aluminum mg/kg ND 5.0 07/08/1516:39 Barium mg/kg ND 0.50 07/08/1516:39 Beryllium mg/kg ND 0.050 07/08/1516:39 Boron mg/kg ND 2.5 07/08/1516:39 Calcium mg/kg ND 25.2 07/08/1516:39 Chromium mg/kg ND 0.25 07/08/1516:39 Copper mg/kg ND 0.25 07/08/1516:39 Iron mg/kg ND 2.0 07/08/1516:39 Magnesium mg/kg ND 25.2 07/08/1516:39 Manganese mg/kg ND 0.25 07/08/1516:39 Molybdenum mg/kg ND 0.50 07/08/1516:39 Nickel mg/kg ND 0.25 07/08/1516:39 Potassium mg/kg ND 50.4 07/08/1516:39 Sodium mg/kg ND 50.4 07/08/1516:39 Strontium mg/kg ND 0.50 07/08/1516:39 Zinc mg/kg ND 1.0 07/08/1516:39 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1262232 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 162 159 98 80-120 Barium mg/kg 16.2 15.7 97 80-120 Beryllium mg/kg 1.6 1.6 97 80-120 Boron mg/kg 162 155 96 80-120 Calcium mg/kg 811 805 99 80-120 Chromium mg/kg 16.2 15.4 95 80-120 Copper mg/kg 16.2 14.9 92 80-120 Iron mg/kg 162 156 96 80-120 Magnesium mg/kg 811 773 95 80-120 Manganese mg/kg 16.2 15.4 95 80-120 Molybdenum mg/kg 16.2 14.8 91 80-120 Nickel mg/kg 16.2 15.7 97 80-120 Potassium mg/kg 811 780 96 80-120 Sodium mg/kg 811 791 98 80-120 Strontium mg/kg 16.2 15.6 96 80-120 Zinc mg/kg 81.1 78.9 97 80-120 Pace Analytical Services, Inc. 9800 I S igy ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 44 of 66 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 14,8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15060830 REV 92256104 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1262233 1262234 MS MSD 92256104001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Aluminum mg/kg 15100 198 193 18600 17500 1740 1240 75-125 6 20 M1 Barium mg/kg 112 19.8 19.3 124 156 60 225 75-125 22 20 M1,R1 Beryllium mg/kg 0.92 1.92 1.92 2.6 2.9 87 105 75-125 11 20 Boron mg/kg ND 198 193 159 165 78 84 75-125 4 20 Calcium mg/kg 330 987 963 1220 1340 91 105 75-125 9 20 Chromium mg/kg 17.7 19.8 19.3 33.0 37.9 78 105 75-125 14 20 Copper mg/kg 9.4 19.8 19.3 29.7 25.4 103 83 75-125 16 20 Iron mg/kg 17600 198 193 18500 16900 448 -381 75-125 9 20 M1 Magnesium mg/kg 1740 987 963 3120 2340 140 62 75-125 28 20 M1,R1 Manganese mg/kg 716 19.8 19.3 653 924 -319 1080 75-125 34 20 M1,R1 Molybdenum mg/kg ND 19.8 19.3 13.9 15.4 69 78 75-125 10 20 M1 Nickel mg/kg 9.6 19.8 19.3 28.2 29.1 94 102 75-125 3 20 Potassium mg/kg 1330 987 963 2730 1850 142 54 75-125 39 20 M1,R1 Sodium mg/kg ND 987 963 993 1030 92 98 75-125 3 20 Strontium mg/kg 3.4 19.8 19.3 23.5 23.3 102 103 75-125 1 20 Zinc mg/kg 33.3 98.7 96.3 131 127 99 97 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 45 of 66 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15060830 REV Pace Project No.: 92256104 QC Batch: MPRP/25107 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92256104001, 92256104002, 92256104003, 92256104004, 92256104005 METHOD BLANK: 1262238 Matrix: Solid Associated Lab Samples: 92256104001, 92256104002, 92256104003, 92256104004, 92256104005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.050 07/10/1512:20 N2 Arsenic mg/kg ND 0.050 07/10/1512:20 Cadmium mg/kg ND 0.0060 07/10/1512:20 Cobalt mg/kg ND 0.050 07/10/1512:20 Lead mg/kg ND 0.050 07/10/1512:20 Selenium mg/kg ND 0.050 07/10/1512:20 Thallium mg/kg ND 0.050 07/10/1512:20 Vanadium mg/kg ND 0.050 07/10/1512:20 Pace Analytical Services, Inc. 9800 Ijigc&y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1262239 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony mg/kg 2.6 2.5 98 80-120 N2 Arsenic mg/kg 2.6 2.7 105 80-120 Cadmium mg/kg .26 0.26 101 80-120 Cobalt mg/kg 2.6 2.7 103 80-120 Lead mg/kg 2.6 2.6 101 80-120 Selenium mg/kg 2.6 2.6 101 80-120 Thallium mg/kg 2.6 2.6 100 80-120 Vanadium mg/kg 2.6 2.6 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1262240 1262241 MS MSD 92256104001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 2.99 2.99 ND ND 44 28 75-125 20 M6, N2 Arsenic mg/kg 3.OJ 2.99 2.99 5.8J 5.6J 93 87 75-125 20 Cadmium mg/kg ND .299 .299 ND ND 110 110 75-125 20 Cobalt mg/kg 9.7 2.99 2.99 11.7 10.5 65 27 75-125 11 20 M6 Lead mg/kg 11.8 2.99 2.99 14.1 13.9 76 71 75-125 1 20 M6 Selenium mg/kg ND 2.99 2.99 4.1J 4AJ 51 61 75-125 20 M6 Thallium mg/kg ND 2.99 2.99 3.2J ND 99 89 75-125 20 Vanadium mg/kg 25.6 2.99 2.99 25.5 26.7 -3 36 75-125 5 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 46 of 66 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15060830 REV Pace Project No.: 92256104 QC Batch: MPRP/55604 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92256104006 METHOD BLANK: 2007813 Associated Lab Samples: 92256104006 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed Qualifiers Aluminum ug/L ND 10.0 06/29/1517:08 Antimony ug/L ND 0.50 06/28/1519:37 Arsenic ug/L ND 0.50 06/28/1519:37 Barium ug/L ND 0.30 06/28/1519:37 Beryllium ug/L ND 0.20 06/28/1519:37 Boron ug/L ND 5.0 06/29/1517:08 Cadmium ug/L ND 0.080 06/28/1519:37 Calcium ug/L ND 40.0 06/29/1517:08 Chromium ug/L ND 0.50 06/28/1519:37 Cobalt ug/L ND 0.50 06/28/1519:37 Copper ug/L ND 1.0 06/28/1519:37 Iron ug/L ND 50.0 06/29/1517:08 Lead ug/L ND 0.10 06/28/1519:37 Magnesium ug/L ND 10.0 06/28/1519:37 Manganese ug/L 0.24J 0.50 06/29/1517:08 Molybdenum ug/L ND 0.50 06/28/1519:37 Nickel ug/L ND 0.50 06/28/1519:37 Potassium ug/L ND 50.0 06/28/1519:37 Selenium ug/L ND 0.50 06/28/1519:37 Sodium ug/L ND 50.0 06/29/1517:08 Strontium ug/L ND 0.50 06/28/1519:37 Thallium ug/L ND 0.10 06/28/1519:37 Vanadium ug/L ND 1.0 06/28/1519:37 Zinc ug/L ND 5.0 06/28/1519:37 Pace Analytical Services, Inc. 9800 16,8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 2007814 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 80.5 101 80-120 Antimony ug/L 80 79.3 99 80-120 Arsenic ug/L 80 82.1 103 80-120 Barium ug/L 80 86.4 108 80-120 Beryllium ug/L 80 81.6 102 80-120 Boron ug/L 80 82.0 103 80-120 Cadmium ug/L 80 84.3 105 80-120 Calcium ug/L 1000 995 99 80-120 Chromium ug/L 80 86.1 108 80-120 Cobalt ug/L 80 88.0 110 80-120 Copper ug/L 80 86.0 107 80-120 Iron ug/L 1000 1050 105 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 47 of 66 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Ijc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060830 REV Pace Project No.: 92256104 LABORATORY CONTROL SAMPLE: 2007814 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 89.3 112 80-120 Magnesium ug/L 1000 1050 105 80-120 Manganese ug/L 80 84.7 106 80-120 Molybdenum ug/L 80 82.0 102 80-120 Nickel ug/L 80 82.8 103 80-120 Potassium ug/L 1000 1020 102 80-120 Selenium ug/L 80 82.8 103 80-120 Sodium ug/L 1000 1050 105 80-120 Strontium ug/L 80 79.4 99 80-120 Thallium ug/L 80 90.8 113 80-120 Vanadium ug/L 80 83.1 104 80-120 Zinc ug/L 80 84.8 106 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2008901 2008902 MS MSD 92256087001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 1500 80 80 1910 1920 515 525 75-125 0 20 M1 Antimony ug/L 0.32J 80 80 78.6 79.3 98 99 75-125 1 20 Arsenic ug/L 1.4 80 80 81.7 80.9 100 99 75-125 1 20 Barium ug/L 17.0 80 80 105 103 110 107 75-125 2 20 Beryllium ug/L 0.078J 80 80 78.0 79.6 97 99 75-125 2 20 Boron ug/L 8.1 80 80 88.2 87.7 100 100 75-125 1 20 Cadmium ug/L 0.13 80 80 82.1 79.3 103 99 75-125 4 20 Calcium ug/L 1960 1000 1000 2980 2950 102 99 75-125 1 20 Chromium ug/L 175 80 80 255 245 100 88 75-125 4 20 Cobalt ug/L 2.0 80 80 89.9 88.7 110 108 75-125 1 20 Copper ug/L 39.2 80 80 129 129 113 112 75-125 1 20 Iron ug/L 21300 1000 1000 21100 21000 -15 -28 75-125 1 20 M1 Lead ug/L 0.80 80 80 89.2 84.5 110 105 75-125 5 20 Magnesium ug/L 450 1000 1000 1510 1480 106 103 75-125 2 20 Manganese ug/L 115 80 80 216 193 126 97 75-125 11 20 M1 Molybdenum ug/L 26.0 80 80 107 105 102 99 75-125 2 20 Nickel ug/L 12.5 80 80 94.5 95.2 102 103 75-125 1 20 Potassium ug/L 755 1000 1000 1910 1690 115 94 75-125 12 20 Selenium ug/L 1.6 80 80 81.9 81.4 100 100 75-125 1 20 Sodium ug/L 968 1000 1000 2040 2050 107 109 75-125 1 20 Strontium ug/L 14.5 80 80 94.8 91.8 100 97 75-125 3 20 Thallium ug/L 0.048J 80 80 90.1 83.5 113 104 75-125 8 20 Vanadium ug/L 13.6 80 80 94.3 91.7 101 98 75-125 3 20 Zinc ug/L 28.3 80 80 110 108 102 100 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 48 of 66 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15060830 REV Pace Project No.: 92256104 QC Batch: MPRP/55752 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A SPLP UPD4 Associated Lab Samples: 92256104002, 92256104005 METHOD BLANK: 2012394 Associated Lab Samples: 92256104002, 92256104005 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 100 07/05/1516:33 ND 5.0 07/05/1516:33 ND 5.0 07/05/1516:33 ND 100 07/05/1516:33 ND 2.0 07/05/1516:33 ND 50.0 07/05/1516:33 ND 0.80 07/05/1516:33 ND 400 07/05/1516:33 ND 5.0 07/05/1516:33 ND 5.0 07/05/1516:33 ND 10.0 07/05/1516:33 ND 500 07/05/1516:33 ND 1.0 07/06/1513:37 ND 100 07/06/1513:37 ND 5.0 07/05/1516:33 ND 5.0 07/05/1516:33 ND 5.0 07/05/1516:33 ND 500 07/05/1516:33 ND 5.0 07/05/1516:33 ND 500 07/05/1516:33 ND 5.0 07/05/1516:33 ND 1.0 07/05/1516:33 ND 10.0 07/05/1516:33 ND 50.0 07/06/1513:37 METHOD BLANK: 2009309 Associated Lab Samples: 92256104002, 92256104005 Parameter Units Matrix: Blank Result Solid Reporting Limit Analyzed Aluminum ug/L ND 100 07/05/1517:19 Antimony ug/L ND 5.0 07/05/1517:19 Arsenic ug/L ND 5.0 07/05/1517:19 Barium ug/L 2.5J 100 07/05/1517:19 Beryllium ug/L ND 2.0 07/05/1517:19 Boron ug/L ND 50.0 07/05/1517:19 Cadmium ug/L ND 0.80 07/05/1517:19 Calcium ug/L 229J 400 07/05/1517:19 Chromium ug/L ND 5.0 07/05/1517:19 Cobalt ug/L ND 5.0 07/05/1517:19 Qualifiers Qualifiers Pace Analytical Services, Inc. 9800 Ijgc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 49 of 66 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15060830 REV Pace Project No.: 92256104 METHOD BLANK: 2009309 Associated Lab Samples: 92256104002, 92256104005 Parameter Units Matrix: Blank Result Solid Reporting Limit Analyzed Copper ug/L ND 10.0 07/05/1517:19 Iron ug/L ND 500 07/05/1517:19 Lead ug/L 6.6 1.0 07/06/1514:20 Magnesium ug/L ND 100 07/06/1514:20 Manganese ug/L ND 5.0 07/05/1517:19 Molybdenum ug/L ND 5.0 07/05/1517:19 Nickel ug/L ND 5.0 07/05/1517:19 Potassium ug/L ND 500 07/05/1517:19 Selenium ug/L ND 5.0 07/05/1517:19 Sodium ug/L 3000 500 07/05/1517:19 Strontium ug/L ND 5.0 07/05/1517:19 Thallium ug/L ND 1.0 07/05/1517:19 Vanadium ug/L ND 10.0 07/05/1517:19 Zinc ug/L ND 50.0 07/06/1514:20 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2012395 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum ug/L 80 84.OJ 105 80-120 Antimony ug/L 80 79.9 100 80-120 Arsenic ug/L 80 82.4 103 80-120 Barium ug/L 80 86.5J 108 80-120 Beryllium ug/L 80 85.3 107 80-120 Boron ug/L 80 82.1 103 80-120 Cadmium ug/L 80 81.0 101 80-120 Calcium ug/L 1000 1020 102 80-120 Chromium ug/L 80 83.7 105 80-120 Cobalt ug/L 80 88.3 110 80-120 Copper ug/L 80 89.1 111 80-120 Iron ug/L 1000 1070 107 80-120 Lead ug/L 80 84.1 105 80-120 Magnesium ug/L 1000 998 100 80-120 Manganese ug/L 80 82.1 103 80-120 Molybdenum ug/L 80 80.3 100 80-120 Nickel ug/L 80 84.2 105 80-120 Potassium ug/L 1000 1020 102 80-120 Selenium ug/L 80 79.3 99 80-120 Sodium ug/L 1000 1100 110 80-120 Strontium ug/L 80 78.0 97 80-120 Thallium ug/L 80 88.3 110 80-120 Vanadium ug/L 80 81.6 102 80-120 Zinc ug/L 80 73.8 92 80-120 Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 50 of 66 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 t 6,8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060830 REV Pace Project No.: 92256104 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2012396 2012397 MS MSD 92255787001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 1120 80 80 1400 1420 339 372 75-125 2 20 Antimony ug/L 3.9J 80 80 81.7 79.9 97 95 75-125 2 20 Arsenic ug/L 138 80 80 209 211 89 92 75-125 1 20 Barium ug/L 136 80 80 211 219 94 104 75-125 4 20 Beryllium ug/L ND 80 80 82.3 85.0 102 106 75-125 3 20 Boron ug/L 47.8J 80 80 126 131 98 104 75-125 4 20 Cadmium ug/L ND 80 80 76.3 78.1 95 98 75-125 2 20 Calcium ug/L 6260 1000 1000 6910 7110 66 86 75-125 3 20 Chromium ug/L 7.2 80 80 88.8 90.4 102 104 75-125 2 20 Cobalt ug/L ND 80 80 83.6 85.0 103 105 75-125 2 20 Copper ug/L 14.6 80 80 93.1 95.8 98 102 75-125 3 20 Iron ug/L 669 1000 1000 1740 1770 107 110 75-125 2 20 Lead ug/L 3.9 80 80 87.0 91.5 104 110 75-125 5 20 Magnesium ug/L 649 1000 1000 1760 1780 111 113 75-125 1 20 Manganese ug/L 10.8 80 80 91.3 93.5 101 103 75-125 2 20 Molybdenum ug/L 5.0 80 80 79.2 81.2 93 95 75-125 2 20 Nickel ug/L 2.5J 80 80 78.0 79.7 94 97 75-125 2 20 Potassium ug/L 315J 1000 1000 1300 1330 98 102 75-125 3 20 Selenium ug/L 38.1 80 80 113 116 93 97 75-125 3 20 Sodium ug/L 9690 1000 1000 10200 10600 47 89 75-125 4 20 Strontium ug/L 122 80 80 208 215 108 116 75-125 3 20 Thallium ug/L 0.17J 80 80 88.3 88.7 110 111 75-125 0 20 Vanadium ug/L 88.2 80 80 178 181 112 116 75-125 2 20 Zinc ug/L ND 80 80 74.1 75.6 89 91 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 51 of 66 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 �T igy fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060830 REV Pace Project No.: 92256104 QC Batch: PMST/3710 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92256104001, 92256104002, 92256104003, 92256104004, 92256104005 SAMPLE DUPLICATE: 1264548 35195416001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 13.6 13.6 0 10 SAMPLE DUPLICATE: 1264549 92256907004 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 28.5 31.7 11 10 D6 SAMPLE DUPLICATE: 1264550 92256918002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 32.6 32.2 1 10 SAMPLE DUPLICATE: 1264551 92256918012 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 27.0 31.8 17 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 52 of 66 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15060830 REV Pace Project No.: 92256104 QC Batch: WET/38480 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92256104001, 92256104002, 92256104003 Pace Analytical Services, Inc. 9800 t Q igy ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE DUPLICATE: 1498162 92256013001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 8.6 8.6 0 10 SAMPLE DUPLICATE: 1498163 92255839003 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 7.2 7.2 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 53 of 66 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15060830 REV Pace Project No.: 92256104 QC Batch: WET/38515 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92256104004, 92256104005 Pace Analytical Services, Inc. 9800 t S igy ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE DUPLICATE: 1499053 92256693008 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.1 6.1 0 10 H3 SAMPLE DUPLICATE: 1499054 92256693004 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 3.8 3.8 1 10 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 54 of 66 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 t 4,8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060830 REV Pace Project No.: 92256104 QC Batch: WETA/23569 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92256104002, 92256104005 METHOD BLANK: 1500538 Matrix: Water Associated Lab Samples: 92256104002, 92256104005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L 1.6J 2.0 07/02/1512:07 LABORATORY CONTROL SAMPLE: 1500539 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 20.2 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1500540 1500541 MS MSD 92255296001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 10.4 20 20 28.4 28.3 90 90 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 55 of 66 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 �gc&y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060830 REV Pace Project No.: 92256104 QC Batch: WETA/23607 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92256104002, 92256104005 METHOD BLANK: 1502287 Matrix: Water Associated Lab Samples: 92256104002, 92256104005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.11 0.020 07/06/15 15:37 Z2 LABORATORY CONTROL SAMPLE: 1502288 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.4 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1502289 1502290 MS MSD 92255305004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 0.43 3.1 3.1 3.5 3.5 97 97 90-110 0 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 56 of 66 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 t 6,8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060830 REV Pace Project No.: 92256104 QC Batch: WETA/23529 Analysis Method: SM 4500 -CI -E QC Batch Method: SM 4500 -CI -E Analysis Description: 4500 Chloride Associated Lab Samples: 92256104002, 92256104005 METHOD BLANK: 1497717 Matrix: Water Associated Lab Samples: 92256104002, 92256104005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 06/30/15 03:30 LABORATORY CONTROL SAMPLE: 1497718 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.9 104 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1497719 1497720 MS MSD 92255755014 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 29.2 29.2 34.3 34.3 110 110 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 57 of 66 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15060830 REV Pace Project No.: 92256104 QC Batch: WETA/47925 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92256104001, 92256104002, 92256104003, 92256104004, 92256104005 METHOD BLANK: 1261655 1261656 Matrix: Solid Units Associated Lab Samples: mg/kg Sulfate mg/kg Blank Reporting 1261658 Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.0 07/06/1518:53 Sulfate mg/kg ND 49.0 07/06/1518:53 LABORATORY CONTROL SAMPLE: 1261656 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1261658 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1261657 Parameter Chloride Sulfate Pace Analytical Services, Inc. 9800 ",8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 504 503 100 80-120 504 518 103 80-120 92256104001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 603 563 75 80-120 M1 ND 603 651 90 80-120 92256104001 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 58 of 66 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 �gc&y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060830 REV Pace Project No.: 92256104 QC Batch: WETA/47924 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92256104001, 92256104002, 92256104003, 92256104004, 92256104005 METHOD BLANK: 1261651 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 4.9 07/06/15 18:53 F5 LABORATORY CONTROL SAMPLE: 1261652 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 50.4 51.8 103 80-120 MATRIX SPIKE SAMPLE: 1261654 92256104001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 60.3 57.5 93 80-120 H3 SAMPLE DUPLICATE: 1261653 92256104001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 59 of 66 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060830 REV Pace Project No.: 92256104 QC Batch: WETA/29386 Analysis Method: EPA 9060 Modified QC Batch Method: EPA 9060 Modified Analysis Description: 9060 TOC Average Associated Lab Samples: 92256104001, 92256104002, 92256104003, 92256104004, 92256104005 METHOD BLANK: 1188414 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 07/08/15 14:19 LABORATORY CONTROL SAMPLE: 1188415 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 125000 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1188416 1188417 MS MSD 92255972013 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 66500 85500 85000 154000 162000 102 113 50-150 5 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1188418 1188419 MS MSD 60197109009 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 1480 8000 8000 10100 9990 108 106 50-150 1 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 60 of 66 aceAnaiXical www.pacelabs.com QUALIFIERS Project: J15060830 REV Pace Project No.: 92256104 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. Pace Analytical Services, Inc. 9800 t 6'8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICP/15292 [1] Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. Batch: ICPM/10191 [1j Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS 1g Analyte was detected in the associated leachate blank. B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. F5 The recovery of the analyte in the CRDL standard (also known as the reporting limit verification) did not meet the acceptance criteria. H1 Analysis conducted outside the EPA method holding time. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 61 of 66 Pace Analytical Services, Inc aceAnalXical Hu ® 9800 t c&rrfte. Suite 100 ntersville, INC 28078 www.pacelabs.com (704)875-9092 QUALIFIERS Project: J15060830 REV Pace Project No.: 92256104 ANALYTE QUALIFIERS H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TNI accreditation for this parameter. R1 RPD value was outside control limits. Z2 Analyte present in the associated method blank above the detection limit. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 62 of 66 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, Inc. 9800 t 2'8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15060830 REV 92256104 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92256104001 2015020935 EPA 3050 MPRP/25106 EPA 6010 ICP/15292 92256104002 2015020936 EPA 3050 MPRP/25106 EPA 6010 ICP/15292 92256104003 2015020937 EPA 3050 MPRP/25106 EPA 6010 1CP/15292 92256104004 2015020938 EPA 3050 MPRP/25106 EPA 6010 ICP/15292 92256104005 2015020939 EPA 3050 MPRP/25106 EPA 6010 ICP/15292 92256104001 2015020935 EPA 3050 MPRP/25107 EPA 6020 ICPM/10191 92256104002 2015020936 EPA 3050 MPRP/25107 EPA 6020 ICPM/10191 92256104003 2015020937 EPA 3050 MPRP/25107 EPA 6020 ICPM/10191 92256104004 2015020938 EPA 3050 MPRP/25107 EPA 6020 ICPM/10191 92256104005 2015020939 EPA 3050 MPRP/25107 EPA 6020 ICPM/10191 92256104006 2015020940 EPA 3020 MPRP/55604 EPA 6020A ICPM/25056 92256104002 2015020936 EPA 3020 MPRP/55752 EPA 6020A ICPM/25183 92256104005 2015020939 EPA 3020 MPRP/55752 EPA 6020A ICPM/25183 92256104002 2015020936 EPA 7470A MERP/14093 EPA 7470A MERC/16411 92256104005 2015020939 EPA 7470A MERP/14093 EPA 7470A MERC/16411 92256104006 2015020940 EPA 7470A MERP/14076 EPA 7470A MERC/16397 92256104001 2015020935 EPA 7471 MERP/5952 EPA 7471 MERC/5934 92256104002 2015020936 EPA 7471 MERP/5952 EPA 7471 MERC/5934 92256104003 2015020937 EPA 7471 MERP/5952 EPA 7471 MERC/5934 92256104004 2015020938 EPA 7471 MERP/5952 EPA 7471 MERC/5934 92256104005 2015020939 EPA 7471 MERP/5952 EPA 7471 MERC/5934 92256104001 2015020935 ASTM D2974-87 PMST/3710 92256104002 2015020936 ASTM D2974-87 PMST/3710 92256104003 2015020937 ASTM D2974-87 PMST/3710 92256104004 2015020938 ASTM D2974-87 PMST/3710 92256104005 2015020939 ASTM D2974-87 PMST/3710 92256104001 2015020935 EPA 9045 WET/38480 92256104002 2015020936 EPA 9045 WET/38480 92256104003 2015020937 EPA 9045 WET/38480 92256104004 2015020938 EPA 9045 WET/38515 92256104005 2015020939 EPA 9045 WET/38515 92256104002 2015020936 EPA 300.0 WETA/23569 92256104005 2015020939 EPA 300.0 WETA/23569 92256104002 2015020936 EPA 353.2 WETA/23607 92256104005 2015020939 EPA 353.2 WETA/23607 92256104002 2015020936 SM 4500 -CI -E WETA/23529 92256104005 2015020939 SM 4500 -CI -E WETA/23529 92256104001 2015020935 EPA 9056 WETA/47925 92256104002 2015020936 EPA 9056 WETA/47925 92256104003 2015020937 EPA 9056 WETA/47925 92256104004 2015020938 EPA 9056 WETA/47925 92256104005 2015020939 EPA 9056 WETA/47925 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/13/2015 05:15 PM without the written consent of Pace Analytical Services, Inc.. Page 63 of 66 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15060830 REV Pace Project No.: 92256104 Lab ID Sample ID QC Batch Method QC Batch 92256104001 2015020935 EPA 9056 WETA/47924 92256104002 2015020936 EPA 9056 WETA/47924 92256104003 2015020937 EPA 9056 WETA/47924 92256104004 2015020938 EPA 9056 WETA/47924 92256104005 2015020939 EPA 9056 WETA/47924 92256104001 2015020935 EPA 9060 Modified WETA/29386 92256104001 2015020935 EPA 9060 Modified WETA/29387 92256104002 2015020936 EPA 9060 Modified WETA/29386 92256104002 2015020936 EPA 9060 Modified WETA/29387 92256104003 2015020937 EPA 9060 Modified WETA/29386 92256104003 2015020937 EPA 9060 Modified WETA/29387 92256104004 2015020938 EPA 9060 Modified WETA/29386 92256104004 2015020938 EPA 9060 Modified WETA/29387 92256104005 2015020939 EPA 9060 Modified WETA/29386 92256104005 2015020939 EPA 9060 Modified WETA/29387 Date: 07/13/2015 05:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 t S'8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Analytical Method Analytical Batch Page 64 of 66 ��17CO*NXica( Client Name: D" i4k-' Document Name: Sample Condition Upon Receil Document Number: F-CHR-CS-003-rev.16 Document Revised: May 18, 2015 Page 1 of 2* Issuing Authority: 74 of 76 Pace Huntersville Qualitv Office * Page 2 of 2 is for Internal Use Only Courier: ® Fed Ex Q UPS[] USPS❑ Client❑ commercial❑ Cace)Other Custody Seal on CoolerlBox Present: ❑ yes [9 no Seals intact: ❑ yes ❑ no Packing Material: ❑ Bubble V[3p ❑ Bubble Bags one ❑. Other Thermometer Used: IR Gun T1401 Type of Ice:Wet Blue None E Samples on ice, cooling process has begun Temp Correction Factor T1401 No Correction Corrected Cooler Tem °C Temp.: Temp should be above freezing to 6°C Biological Tissue is Frozen: Yes N NIA g� Comments:, Date and Initlals f p rso rni in % contents: �. >> Chain of Custody Present: V es No ❑NIA 1. Chairs of Custody Filled Out: a ❑No L1 NIA 2. Chain of Custody Relinquished: 11es ❑No 11 N/A 3. Sampler Name & Signature on COC: DYe5,[]No */A 4. Samples Arrived within Hold Time: 134es ❑No ❑NIA 5. Short Hold Time Analysis (<72hr): Dyes AlNo ❑NIA 6. Rush Turn Around Time Requested: ❑Yes No ❑NIA 7. Sufficient Volume: Yes�es ❑No ❑NIA 8. Correct Containers Used: -Pace Containers Used: t}rYes No es ❑No ❑NIA ❑NIA 9. Containers Intact: es ❑No 11N1A 10. Filtered volume received for Dissolved tests ❑Ne IA 11. Sample Labels match COC: -Includes date/timellD/Analysis Matrix: �❑Yes L14, ❑ o ❑N/A ,1 f�6 t 12. All containers needing preservation have been checked. All containers needing preservation are found to be in compliance with EPA recommendation. exceptions: VOA, coliform, TOC, O&G, VVI -DRO (water) �yye❑No Yes ❑No ❑Ye No ❑N!A ❑NIA 13. Samples checked for dechlorination: es El No ❑NIA 14. Headspace in VOA Vials ( >6mm): ❑Yes ❑No NIA 15. Trip Blank Present: Trip Blank Custody Seals Present Pace Trip Blank Lot # (if purchased): ❑Yes []No�NNIA ❑Yes ❑No IA 16. Client Notification/ Resolution: Field Data Required? Y / N Person Contacted: Date/Time: Comments/ Resolution: SCURF Review: avu Date: I &12,5'11S-j SRF Review: Date: /S Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( Le out of hold, incorrect preservative, out of temp, incorrect containers) WOp:92256104 1111111111111111111111 Page 65 of 66 f O I ;Iil► !ii I�dl1 mom! � � i l i ► i i I I�j1 3 �! I I p I I ! 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(PACE) ( ) _ O� I i " I i •, F,�< PLP - Total Metals 0 and Anions ; 2- 8 oz jars (PACE) i _ a Sediment specific tests 2 - 8 ozar , I ' (ACCESS m ANALYTICAL) 5 I ! I Page 66 of 66 z N Mitnln i I ,>« I z I V I o m ! j i t I �--� 0 h Z Ino Z 0.1 p r� 0 _- m m o p z r°Total # of Containers Page 66 of 66 76 of 76 Cep to mer m6•d Comp+etc .. O M 3 f" n IZ7 a yN, � p CLCL t m m t^ QG N 0 0 rr i3 j rD N . 1 - 10 co o t cc b cT Z n STI Cus-omer ,rComp. 16AOalysits to c,mMlote ar propriate D a colurns 7C ?G )G to tight m I i N c m a °IU z; � a m e 9.. W x Total Metals , Anions, D fD I t wI I X pH 1 - 8 oz jar (PACE) __ u+ IQ N t m d 1 o/t, S611J_�, TOC 1 - 4 oz jar C o m a �I0 (PACE) s I� m •! G •G 1 oa `+ i y 63 -4 (AZ 01 �!0 SPLP - Total Metals F! in �C and Anions ! I !o I C J 2 - 8 oz jars (PACE) 10 � 6 i O a I M M c g IM In { o i/� t CO fo a Q +L 1 —..l qqy G/1 i irN� 1 l ■ v I> J& o f 3 IZ fi = GIN 1 s�0 m f'Y yr ? 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