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Home My WebLink AboutNC0000396_J15060148 Report_20150823+ DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Order Number: J15060148 Project Name: ASHEVILLE - AB GW ASSESSMENT SOIL Customer Name(s): Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker Customer Address: 200 CP and L Drive Arden, NC 28704 Lab Contact: Margaret Galvin -Karr Phone: 980-875-5219 MXG4644 (101161) Report Authorized By: °GY 2015.06.29 08:16:16 Date: (Signature) -04'00' Margaret Galvin -Karr Program Comments: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 6/29/2015 1 of 55 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: 2 of 55 Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015017322 ASHEVILLE 02 -Jun -15 10:40 AM illegible Well FB -1 2015017323 ASHEVILLE 02 -Jun -15 10:55 AM illegible Well FB -1 Dup 2015017324 ASHEVILLE 02 -Jun -15 12:00 PM illegible Well FB -2 3 Total Samples Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes F./] No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report 3 of 55 Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 66 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Reviewed By: Margaret Galvin -Karr Date: 6/29/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060148 Site: Well FB -1 Collection Date: 02 -Jun -15 10:40 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 4 of 55 Sample #: 2015017322 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060148 Site: Well FB -1 Dup Collection Date: 02 -Jun -15 10:55 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 5 of 55 Sample #: 2015017323 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15060148 Site: Well FB -2 Collection Date: 02 -Jun -15 12:00 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6 of 55 Sample #: 2015017324 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE aceAnaiXical www.pacelabs.com June 26, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 RE: Project: J15060148 Pace Project No.: 92253135 Pace Analytical Services, Inc. 9800 Ki,�c8y&&e. Suite 100 Huntersville, INC 28078 (704)875-9092 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on June 04, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Mary Ann Ogle, Duke Energy Rodney Wilke, Duke Energy HiQ p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 35 aceAnaiXical www.pacelabs.com Project: J15060148 Pace Project No.: 92253135 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification M PH -0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate M 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification M E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 Pace Analytical Services, Inc. 9800 Kigg8y&&e. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Montana Certification #: Cert 0074 Nebraska Certification: NE -OS -28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification M FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification M 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 35 aceAnaiXical www.pacelabs.com SAMPLE SUMMARY Project: J15060148 Pace Project No.: 92253135 Lab ID Sample ID Matrix Date Collected Date Received 92253135001 2015017322 Solid 06/02/1510:40 06/04/1516:35 92253135002 2015017323 Solid 06/02/1510:55 06/04/1516:35 92253135003 2015017324 Solid 06/02/1512:00 06/04/1516:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kigc&y&ie. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 35 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15060148 92253135 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92253135001 2015017322 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 Modified TJJ 4 PASI-G 92253135002 2015017323 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 Modified TJJ 4 PASI-G 92253135003 2015017324 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 TAP 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 Modified TJJ 4 PASI-G REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 35 aceAnaiXical www.pacelabs.com Project: J15060148 Pace Project No.: 92253135 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 9800 fflin� c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92253135001 2015017322 EPA 6010 Aluminum 4660 mg/kg 35.4 06/17/15 12:05 EPA 6010 Barium 41.4 mg/kg 3.5 06/17/15 12:05 EPA 6010 Beryllium 0.47 mg/kg 0.35 06/17/15 12:05 EPA 6010 Calcium 552 mg/kg 177 06/17/15 12:05 EPA 6010 Chromium 4.4 mg/kg 1.8 06/17/15 12:05 EPA 6010 Copper 3.8 mg/kg 1.8 06/17/15 12:05 EPA 6010 Iron 6190 mg/kg 14.2 06/17/15 12:05 EPA 6010 Magnesium 1030 mg/kg 177 06/17/15 12:05 EPA 6010 Manganese 324 mg/kg 1.8 06/17/15 12:05 EPA 6010 Nickel 3.0 mg/kg 1.8 06/17/15 12:05 EPA 6010 Potassium 870 mg/kg 354 06/17/15 12:05 EPA 6010 Strontium 5.1 mg/kg 3.5 06/17/15 12:05 EPA 6010 Zinc 27.0 mg/kg 7.1 06/17/15 12:05 EPA 6020 Lead 4.5J mg/kg 6.9 06/16/15 11:54 M6 EPA 6020 Vanadium 7.9 mg/kg 6.9 06/16/15 11:54 EPA 7471 Mercury 0.021 mg/kg 0.011 06/16/15 11:31 ASTM D2974-87 Percent Moisture 30.2 % 0.10 06/15/15 09:59 EPA 9045 pH at 25 Degrees C 6.0 Std. Units 0.10 06/10/15 12:30 EPA 9060 Modified RPD% 21.9 % 0.10 06/26/15 09:44 EPA 9060 Modified Total Organic Carbon 1980 mg/kg 860 06/26/15 09:44 EPA 9060 Modified Total Organic Carbon 2460 mg/kg 860 06/26/15 09:50 EPA 9060 Modified Mean Total Organic Carbon 2220 mg/kg 860 06/26/15 09:44 92253135002 2015017323 EPA 6010 Aluminum 2500 mg/kg 34.9 06/17/15 12:10 EPA 6010 Barium 17.5 mg/kg 3.5 06/17/15 12:10 EPA 6010 Beryllium 0.21J mg/kg 0.35 06/17/1512:10 EPA 6010 Calcium 121J mg/kg 174 06/17/1512:10 EPA 6010 Chromium 3.6 mg/kg 1.7 06/17/15 12:10 EPA 6010 Copper 2.2 mg/kg 1.7 06/17/15 12:10 EPA 6010 Iron 3320 mg/kg 13.9 06/17/15 12:10 EPA 6010 Magnesium 539 mg/kg 174 06/17/15 12:10 EPA 6010 Manganese 110 mg/kg 1.7 06/17/15 12:10 EPA 6010 Nickel 1.7J mg/kg 1.7 06/17/15 12:10 EPA 6010 Potassium 490 mg/kg 349 06/17/15 12:10 EPA 6010 Zinc 18.6 mg/kg 7.0 06/17/15 12:10 EPA 6020 Vanadium 6.1J mg/kg 7.2 06/16/1512:14 EPA 7471 Mercury 0.014 mg/kg 0.011 06/16/15 11:37 ASTM D2974-87 Percent Moisture 29.8 % 0.10 06/15/15 09:59 EPA 9045 pH at 25 Degrees C 5.9 Std. Units 0.10 06/10/15 12:30 EPA 9060 Modified RPD% 4.7 % 0.10 06/26/15 09:55 EPA 9060 Modified Total Organic Carbon 1510 mg/kg 856 06/26/15 09:55 EPA 9060 Modified Total Organic Carbon 1440 mg/kg 854 06/26/15 10:00 EPA 9060 Modified Mean Total Organic Carbon 1470 mg/kg 855 06/26/15 09:55 92253135003 2015017324 EPA 6010 Aluminum 1720 mg/kg 34.5 06/17/15 12:14 EPA 6010 Barium 13.6 mg/kg 3.4 06/17/15 12:14 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Qualifiers Page 5 of 35 aceAnaiXical www.pacelabs.com SUMMARY OF DETECTION Project: J15060148 Pace Project No.: 92253135 Lab Sample ID Client Sample ID 1.7 06/17/1512:14 Method Parameters Result Units 92253135003 2015017324 1.7 06/17/1512:14 EPA 6010 Calcium 124J mg/kg EPA 6010 Chromium 2.6 mg/kg EPA 6010 Copper 1.5J mg/kg EPA 6010 Iron 2500 mg/kg EPA 6010 Magnesium 319 mg/kg EPA 6010 Manganese 179 mg/kg EPA 6010 Nickel 1.2J mg/kg EPA 6010 Potassium 327J mg/kg EPA 6010 Zinc 11.7 mg/kg EPA 6020 Vanadium 5.1J mg/kg EPA 7471 Mercury 0.018 mg/kg ASTM D2974-87 Percent Moisture 25.7 % EPA 9045 pH at 25 Degrees C 6.1 Std. Units EPA 9060 Modified RPD% 8.5 % EPA 9060 Modified Total Organic Carbon 1130 mg/kg EPA 9060 Modified Total Organic Carbon 1040 mg/kg EPA 9060 Modified Mean Total Organic Carbon 1080 mg/kg REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Report Limit Analyzed Qualifiers 172 06/17/1512:14 1.7 06/17/1512:14 1.7 06/17/1512:14 13.8 06/17/1512:14 172 06/17/1512:14 1.7 06/17/1512:14 1.7 06/17/1512:14 345 06/17/1512:14 6.9 06/17/1512:14 6.6 06/16/1512:21 0.011 06/16/15 11:41 0.10 06/15/15 09:59 0.10 06/10/1512:30 0.10 06/26/1510:06 812 06/26/1510:06 804 06/26/1510:11 808 06/26/1510:06 Page 6 of 35 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060148 Pace Project No.: 92253135 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: June 26, 2015 Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 3 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24725 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92253144001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1242945) • Aluminum • Boron • Iron • Manganese • MSD (Lab ID: 1242946) • Aluminum • Copper • Iron • Manganese Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICP / 15086 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 35 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ff�ic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060148 Pace Project No.: 92253135 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: June 26, 2015 Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICP / 15087 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 35 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060148 Pace Project No.: 92253135 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: June 26, 2015 Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 3 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/24676 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92253135001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1240575) • Lead • MSD (Lab ID: 1240576) • Lead • Selenium Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICPM / 10012 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 35 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffii�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15060148 Pace Project No.: 92253135 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: June 26, 2015 Analyte Comments: QC Batch: MPRP/24676 N2: The lab does not hold TNI accreditation for this parameter. •2015017322 (Lab ID:92253135001) • Antimony •2015017323 (Lab ID:92253135002) • Antimony •2015017324 (Lab ID:92253135003) • Antimony • BLANK (Lab ID: 1240573) • Antimony • LCS (Lab ID: 1240574) • Antimony • MS (Lab ID: 1240575) • Antimony • MSD (Lab ID: 1240576) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 35 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060148 Pace Project No.: 92253135 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: June 26, 2015 Pace Analytical Services, Inc. 9800 fflic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 3 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 35 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060148 Pace Project No.: 92253135 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: June 26, 2015 Pace Analytical Services, Inc. 9800 ffligc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 3 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 35 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060148 Pace Project No.: 92253135 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: June 26, 2015 Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/47186 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015017322 (Lab ID: 92253135001) • Chloride • Sulfate •2015017323 (Lab ID: 92253135002) • Chloride • Sulfate •2015017324 (Lab ID: 92253135003) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 35 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060148 Pace Project No.: 92253135 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: June 26, 2015 Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015017322 (Lab ID: 92253135001) •2015017323 (Lab ID: 92253135002) •2015017324 (Lab ID: 92253135003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 35 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15060148 Pace Project No.: 92253135 Method: EPA 9060 Modified Description: Total Organic Carbon Client: Duke Energy Date: June 26, 2015 Pace Analytical Services, Inc. 9800 K�nic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 3 samples were analyzed for EPA 9060 Modified. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 35 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060148 Pace Project No.: 92253135 Sample: 2015017322 Lab ID: 92253135001 Collected: 06/02/15 10:40 Received: 06/04/15 16:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 4660 mg/kg 35.4 17.7 5 06/16/15 20:35 06/17/15 12:05 7429-90-5 Barium 41.4 mg/kg 3.5 1.8 5 06/16/15 20:35 06/17/15 12:05 7440-39-3 Beryllium 0.47 mg/kg 0.35 0.18 5 06/16/15 20:35 06/17/15 12:05 7440-41-7 Boron ND mg/kg 17.7 8.9 5 06/16/15 20:35 06/17/15 12:05 7440-42-8 Calcium 552 mg/kg 177 88.6 5 06/16/15 20:35 06/17/15 12:05 7440-70-2 Chromium 4.4 mg/kg 1.8 0.89 5 06/16/15 20:35 06/17/15 12:05 7440-47-3 Copper 3.8 mg/kg 1.8 0.89 5 06/16/15 20:35 06/17/15 12:05 7440-50-8 Iron 6190 mg/kg 14.2 7.1 5 06/16/15 20:35 06/17/15 12:05 7439-89-6 Magnesium 1030 mg/kg 177 88.6 5 06/16/15 20:35 06/17/15 12:05 7439-95-4 Manganese 324 mg/kg 1.8 0.89 5 06/16/15 20:35 06/17/15 12:05 7439-96-5 Molybdenum ND mg/kg 3.5 1.8 5 06/16/15 20:35 06/17/15 12:05 7439-98-7 Nickel 3.0 mg/kg 1.8 0.89 5 06/16/15 20:35 06/17/15 12:05 7440-02-0 Potassium 870 mg/kg 354 177 5 06/16/15 20:35 06/17/15 12:05 7440-09-7 Sodium ND mg/kg 354 177 5 06/16/15 20:35 06/17/15 12:05 7440-23-5 Strontium 5.1 mg/kg 3.5 1.8 5 06/16/15 20:35 06/17/15 12:05 7440-24-6 Zinc 27.0 mg/kg 7.1 3.5 5 06/16/15 20:35 06/17/15 12:05 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 6.9 3.5 100 06/12/1516:16 06/16/1511:54 7440-36-0 N2 Arsenic ND mg/kg 6.9 3.5 100 06/12/1516:16 06/16/1511:54 7440-38-2 Cadmium ND mg/kg 0.83 0.42 100 06/12/1516:16 06/16/1511:54 7440-43-9 Cobalt ND mg/kg 6.9 3.5 100 06/12/1516:16 06/16/1511:54 7440-48-4 Lead 4.5J mg/kg 6.9 3.5 100 06/12/1516:16 06/16/1511:54 7439-92-1 M6 Selenium ND mg/kg 6.9 3.5 100 06/12/1516:16 06/16/1511:54 7782-49-2 M6 Thallium ND mg/kg 6.9 3.5 100 06/12/1516:16 06/16/1511:54 7440-28-0 Vanadium 7.9 mg/kg 6.9 3.5 100 06/12/1516:16 06/16/1511:54 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.021 mg/kg 0.011 0.0056 1 06/12/1516:30 06/16/1511:31 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 30.2 % 0.10 0.10 1 06/15/15 09:59 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.0 Std. Units 0.10 0.10 1 06/10/15 12:30 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 358 179 5 06/10/1511:35 16887-00-6 D3 Sulfate ND mg/kg 358 179 5 06/10/1511:35 14808-79-8 D3,M1 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 35.5 17.7 5 06/10/15 11:35 14797-55-8 H3 Date: 06/26/2015 04:01 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 35 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060148 Pace Project No.: 92253135 Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015017322 Lab ID: 92253135001 Collected: 06/02/15 10:40 Received: 06/04/15 16:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Analytical Method: EPA 9060 Modified Surrogates RPD% 21.9 % 0.10 0.10 1 06/26/15 09:44 Total Organic Carbon 1980 mg/kg 860 430 1 06/26/15 09:44 7440-44-0 Total Organic Carbon 2460 mg/kg 860 430 1 06/26/15 09:50 7440-44-0 Mean Total Organic Carbon 2220 mg/kg 860 430 1 06/26/15 09:44 7440-44-0 Date: 06/26/2015 04:01 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 35 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 KPc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060148 Pace Project No.: 92253135 Sample: 2015017323 Lab ID: 92253135002 Collected: 06/02/15 10:55 Received: 06/04/15 16:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 2500 mg/kg 34.9 17.4 5 06/16/15 20:35 06/17/15 12:10 7429-90-5 Barium 17.5 mg/kg 3.5 1.7 5 06/16/15 20:35 06/17/15 12:10 7440-39-3 Beryllium 0.21J mg/kg 0.35 0.17 5 06/16/15 20:35 06/17/15 12:10 7440-41-7 Boron ND mg/kg 17.4 8.7 5 06/16/15 20:35 06/17/15 12:10 7440-42-8 Calcium 121J mg/kg 174 87.1 5 06/16/15 20:35 06/17/15 12:10 7440-70-2 Chromium 3.6 mg/kg 1.7 0.87 5 06/16/15 20:35 06/17/15 12:10 7440-47-3 Copper 2.2 mg/kg 1.7 0.87 5 06/16/15 20:35 06/17/15 12:10 7440-50-8 Iron 3320 mg/kg 13.9 7.0 5 06/16/15 20:35 06/17/15 12:10 7439-89-6 Magnesium 539 mg/kg 174 87.1 5 06/16/15 20:35 06/17/15 12:10 7439-95-4 Manganese 110 mg/kg 1.7 0.87 5 06/16/15 20:35 06/17/15 12:10 7439-96-5 Molybdenum ND mg/kg 3.5 1.7 5 06/16/15 20:35 06/17/15 12:10 7439-98-7 Nickel 1.7J mg/kg 1.7 0.87 5 06/16/15 20:35 06/17/15 12:10 7440-02-0 Potassium 490 mg/kg 349 174 5 06/16/15 20:35 06/17/15 12:10 7440-09-7 Sodium ND mg/kg 349 174 5 06/16/15 20:35 06/17/15 12:10 7440-23-5 Strontium ND mg/kg 3.5 1.7 5 06/16/15 20:35 06/17/15 12:10 7440-24-6 Zinc 18.6 mg/kg 7.0 3.5 5 06/16/15 20:35 06/17/15 12:10 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 7.2 3.6 100 06/12/1516:16 06/16/1512:14 7440-36-0 N2 Arsenic ND mg/kg 7.2 3.6 100 06/12/1516:16 06/16/1512:14 7440-38-2 Cadmium ND mg/kg 0.87 0.43 100 06/12/1516:16 06/16/1512:14 7440-43-9 Cobalt ND mg/kg 7.2 3.6 100 06/12/1516:16 06/16/1512:14 7440-48-4 Lead ND mg/kg 7.2 3.6 100 06/12/1516:16 06/16/1512:14 7439-92-1 Selenium ND mg/kg 7.2 3.6 100 06/12/1516:16 06/16/1512:14 7782-49-2 Thallium ND mg/kg 7.2 3.6 100 06/12/1516:16 06/16/1512:14 7440-28-0 Vanadium 6.1J mg/kg 7.2 3.6 100 06/12/1516:16 06/16/1512:14 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.014 mg/kg 0.011 0.0057 1 06/12/1516:30 06/16/1511:37 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 29.8 % 0.10 0.10 1 06/15/15 09:59 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.9 Std. Units 0.10 0.10 1 06/10/15 12:30 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 356 178 5 06/10/1512:39 16887-00-6 D3 Sulfate ND mg/kg 356 178 5 06/10/1512:39 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 35.5 17.8 5 06/10/15 12:39 14797-55-8 H3 Date: 06/26/2015 04:01 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 35 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060148 Pace Project No.: 92253135 Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015017323 Lab ID: 92253135002 Collected: 06/02/15 10:55 Received: 06/04/15 16:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Analytical Method: EPA 9060 Modified Surrogates RPD% 4.7 % 0.10 0.10 1 06/26/15 09:55 Total Organic Carbon 1510 mg/kg 856 428 1 06/26/15 09:55 7440-44-0 Total Organic Carbon 1440 mg/kg 854 427 1 06/26/15 10:00 7440-44-0 Mean Total Organic Carbon 1470 mg/kg 855 428 1 06/26/15 09:55 7440-44-0 Date: 06/26/2015 04:01 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 35 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060148 Pace Project No.: 92253135 Sample: 2015017324 Lab ID: 92253135003 Collected: 06/02/15 12:00 Received: 06/04/15 16:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 1720 mg/kg 34.5 17.2 5 06/16/15 20:35 06/17/15 12:14 7429-90-5 Barium 13.6 mg/kg 3.4 1.7 5 06/16/15 20:35 06/17/15 12:14 7440-39-3 Beryllium ND mg/kg 0.34 0.17 5 06/16/15 20:35 06/17/15 12:14 7440-41-7 Boron ND mg/kg 17.2 8.6 5 06/16/15 20:35 06/17/15 12:14 7440-42-8 Calcium 124J mg/kg 172 86.2 5 06/16/15 20:35 06/17/15 12:14 7440-70-2 Chromium 2.6 mg/kg 1.7 0.86 5 06/16/15 20:35 06/17/15 12:14 7440-47-3 Copper 1.51 mg/kg 1.7 0.86 5 06/16/15 20:35 06/17/15 12:14 7440-50-8 Iron 2500 mg/kg 13.8 6.9 5 06/16/15 20:35 06/17/15 12:14 7439-89-6 Magnesium 319 mg/kg 172 86.2 5 06/16/15 20:35 06/17/15 12:14 7439-95-4 Manganese 179 mg/kg 1.7 0.86 5 06/16/15 20:35 06/17/15 12:14 7439-96-5 Molybdenum ND mg/kg 3.4 1.7 5 06/16/15 20:35 06/17/15 12:14 7439-98-7 Nickel 1.2J mg/kg 1.7 0.86 5 06/16/15 20:35 06/17/15 12:14 7440-02-0 Potassium 327J mg/kg 345 172 5 06/16/15 20:35 06/17/15 12:14 7440-09-7 Sodium ND mg/kg 345 172 5 06/16/15 20:35 06/17/15 12:14 7440-23-5 Strontium ND mg/kg 3.4 1.7 5 06/16/15 20:35 06/17/15 12:14 7440-24-6 Zinc 11.7 mg/kg 6.9 3.4 5 06/16/15 20:35 06/17/15 12:14 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 6.6 3.3 100 06/12/1516:16 06/16/1512:21 7440-36-0 N2 Arsenic ND mg/kg 6.6 3.3 100 06/12/1516:16 06/16/1512:21 7440-38-2 Cadmium ND mg/kg 0.79 0.40 100 06/12/1516:16 06/16/1512:21 7440-43-9 Cobalt ND mg/kg 6.6 3.3 100 06/12/1516:16 06/16/1512:21 7440-48-4 Lead ND mg/kg 6.6 3.3 100 06/12/1516:16 06/16/1512:21 7439-92-1 Selenium ND mg/kg 6.6 3.3 100 06/12/1516:16 06/16/1512:21 7782-49-2 Thallium ND mg/kg 6.6 3.3 100 06/12/1516:16 06/16/1512:21 7440-28-0 Vanadium 5.1J mg/kg 6.6 3.3 100 06/12/1516:16 06/16/1512:21 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.018 mg/kg 0.011 0.0057 1 06/12/1516:30 06/16/1511:41 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 25.7 % 0.10 0.10 1 06/15/15 09:59 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.1 Std. Units 0.10 0.10 1 06/10/15 12:30 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 336 168 5 06/10/1513:01 16887-00-6 D3 Sulfate ND mg/kg 336 168 5 06/10/1513:01 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 33.3 16.7 5 06/10/15 13:01 14797-55-8 H3 Date: 06/26/2015 04:01 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 35 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15060148 Pace Project No.: 92253135 Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015017324 Lab ID: 92253135003 Collected: 06/02/15 12:00 Received: 06/04/15 16:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Analytical Method: EPA 9060 Modified Surrogates RPD% 8.5 % 0.10 0.10 1 06/26/1510:06 Total Organic Carbon 1130 mg/kg 812 406 1 06/26/15 10:06 7440-44-0 Total Organic Carbon 1040 mg/kg 804 402 1 06/26/15 10:11 7440-44-0 Mean Total Organic Carbon 1080 mg/kg 808 404 1 06/26/15 10:06 7440-44-0 Date: 06/26/2015 04:01 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 35 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 KPgc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060148 Pace Project No.: 92253135 QC Batch: MERP/5850 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92253135001, 92253135002, 92253135003 METHOD BLANK: 1240667 Matrix: Solid Associated Lab Samples: 92253135001, 92253135002, 92253135003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0081 06/16/1511:26 LABORATORY CONTROL SAMPLE: 1240668 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .08 0.085 106 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1240669 1240670 MS MSD 92253135001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.021 .119 .113 0.14 0.14 103 103 80-120 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/26/2015 04:01 PM without the written consent of Pace Analytical Services, Inc.. Page 22 of 35 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15060148 Pace Project No.: 92253135 QC Batch: MPRP/24725 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92253135001, 92253135002, 92253135003 METHOD BLANK: 1242943 Matrix: Associated Lab Samples: 92253135001, 92253135002, 92253135003 Blank Parameter Units Result Solid Reporting Limit Analyzed Aluminum mg/kg ND 4.8 06/17/1511:10 Barium mg/kg ND 0.48 06/17/1511:10 Beryllium mg/kg ND 0.048 06/17/1511:10 Boron mg/kg ND 2.4 06/17/1511:10 Calcium mg/kg ND 24.2 06/17/1511:10 Chromium mg/kg ND 0.24 06/17/1511:10 Copper mg/kg ND 0.24 06/16/1515:45 Iron mg/kg ND 1.9 06/17/1511:10 Magnesium mg/kg ND 24.2 06/17/1511:10 Manganese mg/kg ND 0.24 06/17/1511:10 Molybdenum mg/kg ND 0.48 06/17/1511:10 Nickel mg/kg ND 0.24 06/17/1511:10 Potassium mg/kg ND 48.4 06/17/1511:10 Sodium mg/kg ND 48.4 06/17/1511:10 Strontium mg/kg ND 0.48 06/17/1511:10 Zinc mg/kg ND 0.97 06/17/1511:10 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1242944 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 127 127 100 80-120 Barium mg/kg 12.7 13.0 102 80-120 Beryllium mg/kg 1.3 1.3 102 80-120 Boron mg/kg 127 126 99 80-120 Calcium mg/kg 635 650 102 80-120 Chromium mg/kg 12.7 12.9 102 80-120 Copper mg/kg 12.7 12.3 97 80-120 Iron mg/kg 127 129 102 80-120 Magnesium mg/kg 635 639 101 80-120 Manganese mg/kg 12.7 12.8 101 80-120 Molybdenum mg/kg 12.7 12.7 100 80-120 Nickel mg/kg 12.7 12.9 102 80-120 Potassium mg/kg 635 625 99 80-120 Sodium mg/kg 635 647 102 80-120 Strontium mg/kg 12.7 12.7 100 80-120 Zinc mg/kg 63.5 64.3 101 80-120 Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/26/2015 04:01 PM without the written consent of Pace Analytical Services, Inc.. Page 23 of 35 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060148 Pace Project No.: 92253135 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1242945 1242946 MS MSD 92253144001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 16600 130 128 28900 25700 9500 7130 75-125 12 20 M1 Barium mg/kg 35.5 13 12.8 48.9 49.6 103 110 75-125 1 20 Beryllium mg/kg 0.29 1.3 1.3 1.5 1.5 93 97 75-125 2 20 Boron mg/kg ND 130 128 92.3 98.1 71 77 75-125 6 20 M1 Calcium mg/kg 502 650 639 1110 1160 93 102 75-125 4 20 Chromium mg/kg 12.6 13 12.8 25.3 24.5 98 93 75-125 3 20 Copper mg/kg 10.8 13 12.8 20.6 20.2 75 74 75-125 2 20 M1 Iron mg/kg 24400 130 128 22400 21600 -1580 -2200 75-125 3 20 M1 Magnesium mg/kg 619 650 639 1300 1340 105 113 75-125 3 20 Manganese mg/kg 90.3 13 12.8 96.6 96.1 48 46 75-125 0 20 M1 Molybdenum mg/kg ND 13 12.8 11.7 11.1 83 80 75-125 6 20 Nickel mg/kg 4.1 13 12.8 17.7 17.3 105 104 75-125 2 20 Potassium mg/kg 894 650 639 1560 1610 102 112 75-125 3 20 Sodium mg/kg ND 650 639 673 665 103 103 75-125 1 20 Strontium mg/kg 6.0 13 12.8 18.2 18.7 94 99 75-125 2 20 Zinc mg/kg 16.1 65 63.9 81.0 81.1 100 102 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/26/2015 04:01 PM without the written consent of Pace Analytical Services, Inc.. Page 24 of 35 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15060148 Pace Project No.: 92253135 QC Batch: MPRP/24676 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92253135001, 92253135002, 92253135003 METHOD BLANK: 1240573 Matrix: Solid LCS Result Associated Lab Samples: 92253135001, 92253135002, 92253135003 mg/kg 2.6 2.4 94 Blank Reporting mg/kg Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.049 06/16/1511:47 N2 Arsenic mg/kg ND 0.049 06/16/1511:47 Cadmium mg/kg ND 0.0059 06/16/1511:47 Cobalt mg/kg ND 0.049 06/16/1511:47 Lead mg/kg ND 0.049 06/16/1511:47 Selenium mg/kg ND 0.049 06/16/1511:47 Thallium mg/kg ND 0.049 06/16/1511:47 Vanadium mg/kg ND 0.049 06/16/1511:47 Pace Analytical Services, Inc. 9800 K�nlc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1240574 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.6 2.4 94 80-120 N2 Arsenic mg/kg 2.6 2.6 99 80-120 Cadmium mg/kg .26 0.25 95 80-120 Cobalt mg/kg 2.6 2.6 102 80-120 Lead mg/kg 2.6 2.6 101 80-120 Selenium mg/kg 2.6 2.5 96 80-120 Thallium mg/kg 2.6 2.6 100 80-120 Vanadium mg/kg 2.6 2.6 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1240575 1240576 MS MSD 92253135001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 3.73 3.73 ND ND 77 77 75-125 20 N2 Arsenic mg/kg ND 3.73 3.73 3.9J 3.9J 80 80 75-125 20 Cadmium mg/kg ND .373 .373 ND ND 112 98 75-125 20 Cobalt mg/kg ND 3.73 3.73 6.1J 6.7J 90 107 75-125 20 Lead mg/kg 4.5J 3.73 3.73 6.7J 6.9J 58 65 75-125 20 M6 Selenium mg/kg ND 3.73 3.73 5.5J ND 117 55 75-125 20 M6 Thallium mg/kg ND 3.73 3.73 ND ND 90 91 75-125 20 Vanadium mg/kg 7.9 3.73 3.73 11.0 10.8 83 80 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/26/2015 04:01 PM without the written consent of Pace Analytical Services, Inc.. Page 25 of 35 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060148 Pace Project No.: 92253135 QC Batch: PMST/3643 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92253135001, 92253135002, 92253135003 SAMPLE DUPLICATE: 1242327 35190839001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 98.9 99.0 0 10 SAMPLE DUPLICATE: 1242328 35192012004 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 8.0 8.4 5 10 SAMPLE DUPLICATE: 1242329 35192419015 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 9.9 8.0 21 10 D6 SAMPLE DUPLICATE: 1242330 35192773005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 5.1 4.4 15 10 D6 SAMPLE DUPLICATE: 1242331 35192649006 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 18.2 16.1 12 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/26/2015 04:01 PM without the written consent of Pace Analytical Services, Inc.. Page 26 of 35 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15060148 Pace Project No.: 92253135 QC Batch: WET/37953 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92253135001, 92253135002, 92253135003 Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE DUPLICATE: 1478381 92253145001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 5.9 5.8 0 10 SAMPLE DUPLICATE: 1478382 92252534003 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 7.4 7.4 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/26/2015 04:01 PM without the written consent of Pace Analytical Services, Inc.. Page 27 of 35 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15060148 Pace Project No.: 92253135 QC Batch: WETA/47186 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92253135001, 92253135002, 92253135003 METHOD BLANK: 1238020 1238021 Matrix: Solid Units Associated Lab Samples: mg/kg Sulfate mg/kg Blank Reporting 1238023 Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 50.8 06/10/1510:52 Sulfate mg/kg ND 50.8 06/10/1510:52 LABORATORY CONTROL SAMPLE: 1238021 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1238023 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1238022 Parameter Chloride Sulfate Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 491 467 95 80-120 491 475 97 80-120 92253135001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 711 619 87 80-120 ND 711 657 78 80-120 M1 92253135001 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/26/2015 04:01 PM without the written consent of Pace Analytical Services, Inc.. Page 28 of 35 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060148 Pace Project No.: 92253135 QC Batch: WETA/47187 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92253135001, 92253135002, 92253135003 METHOD BLANK: 1238024 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.1 06/10/15 10:52 LABORATORY CONTROL SAMPLE: 1238025 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.1 48.8 99 80-120 MATRIX SPIKE SAMPLE: 1238027 92253135001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 71.1 63.8 90 80-120 H3 SAMPLE DUPLICATE: 1238026 92253135001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/26/2015 04:01 PM without the written consent of Pace Analytical Services, Inc.. Page 29 of 35 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15060148 Pace Project No.: 92253135 QC Batch: WETA/29200 Analysis Method: EPA 9060 Modified QC Batch Method: EPA 9060 Modified Analysis Description: 9060 TOC Average Associated Lab Samples: 92253135001, 92253135002, 92253135003 METHOD BLANK: 1182186 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 06/25/15 15:17 LABORATORY CONTROL SAMPLE: 1182187 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 131000 109 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1182188 1182189 MS MSD 92252541001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 4790 7040 7030 12400 11900 108 100 50-150 4 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1182190 1182191 MS MSD 92253161001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg ND 10200 10200 9530 9550 90 90 50-150 0 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/26/2015 04:01 PM without the written consent of Pace Analytical Services, Inc.. Page 30 of 35 aceAnaiXical www.pacelabs.com QUALIFIERS Project: J15060148 Pace Project No.: 92253135 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICPM/10012 [1] Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. Batch: ICP/15086 [1] Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. Batch: ICP/15087 [1] Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/26/2015 04:01 PM without the written consent of Pace Analytical Services, Inc.. Page 31 of 35 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�gc&fie. Suite 100 Huntersville, INC 28078 (704)875-9092 QUALIFIERS Project: J15060148 Pace Project No.: 92253135 ANALYTE QUALIFIERS N2 The lab does not hold TNI accreditation for this parameter. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/26/2015 04:01 PM without the written consent of Pace Analytical Services, Inc.. Page 32 of 35 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15060148 Pace Project No.: 92253135 Pace Analytical Services, Inc. 9800 K3�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92253135001 2015017322 EPA 3050 MPRP/24724 EPA 6010 92253135001 2015017322 EPA 3050 MPRP/24725 EPA 6010 92253135002 2015017323 EPA 3050 MPRP/24725 EPA 6010 92253135003 2015017324 EPA 3050 MPRP/24725 EPA 6010 92253135001 2015017322 EPA 3050 MPRP/24676 EPA 6020 92253135002 2015017323 EPA 3050 MPRP/24676 EPA 6020 92253135003 2015017324 EPA 3050 MPRP/24676 EPA 6020 92253135001 2015017322 EPA 7471 MERP/5850 EPA 7471 92253135002 2015017323 EPA 7471 MERP/5850 EPA 7471 92253135003 2015017324 EPA 7471 MERP/5850 EPA 7471 92253135001 2015017322 ASTM D2974-87 PMST/3643 92253135002 2015017323 ASTM D2974-87 PMST/3643 92253135003 2015017324 ASTM D2974-87 PMST/3643 92253135001 2015017322 EPA 9045 WET/37953 92253135002 2015017323 EPA 9045 WET/37953 92253135003 2015017324 EPA 9045 WET/37953 92253135001 2015017322 EPA 9056 WETA/47186 92253135002 2015017323 EPA 9056 WETA/47186 92253135003 2015017324 EPA 9056 WETA/47186 92253135001 2015017322 EPA 9056 WETA/47187 92253135002 2015017323 EPA 9056 WETA/47187 92253135003 2015017324 EPA 9056 WETA/47187 92253135001 2015017322 EPA 9060 Modified WETA/29200 92253135001 2015017322 EPA 9060 Modified WETA/29201 92253135002 2015017323 EPA 9060 Modified WETA/29200 92253135002 2015017323 EPA 9060 Modified WETA/29201 92253135003 2015017324 EPA 9060 Modified WETA/29200 92253135003 2015017324 EPA 9060 Modified WETA/29201 Date: 06/26/2015 04:01 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP/15086 ICP/15087 ICP/15087 ICP/15087 ICPM/10012 ICPM/10012 ICPM/10012 MERC/5837 MERC/5837 MERC/5837 Page 33 of 35 Document Name: _. t�ceAwlylia?l' Sample Condition Upon Receii Document Number: F-CHR-CS-063-rev.16 Client Name: P,+Ye- rAelyy Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client❑ Co ercial❑ P(9 Other Custody Seal on GooferlBox Present: El yes-' no Seals intact; ❑yes Document Revised: may 16, Lul0 Page 1 of 2* Issuing Authority: 40 of 55 Pace Huntersville Quality Office * Page 2 of 2 is for Internal Use Only ❑ no Packing Material: ❑ Bubble 11Dp -]IA,u ble Bags ❑ None ❑ Other Thermometer Used: IR Gun 140 Type of Ice: } et lue !done ampies on ice, cooling process has begun Lf Tn.r,n f`nrrnnFinn 1:9n#nr T'i fly Nn f`.nrrPrtinn °C Biological Tissue is Frozen; Yes No A Date and Initials of ersoyaexaminina f 3 Corrected Cooler Temp.: contents: Temp should be above freezing to 6*C Comments: Chaiin of Cust6dy Present: L64, ON/A 1. Chain of Custody Filled Out:es No ❑NIA 2. Chain of Custody Relinquished: &Irl o 11 NIA 3. Sampler Name & Signature on COC: ON, s No 171 NIA 4. Samples Arrived within Hold Time: es ON, IA 5. Short Hold Time Analysis (<72hr): Dyes W6 IA 6. Rush Turn Around Time Requested: ❑Yes glo ❑N1A 7. Sufficient Volume: es o 0N1A $. Correct Containers Used: 134111,❑Na NIA 9. -Pace Containers Used: ❑Yes ❑NIA Containers Intact: ❑ es ONO ❑NIA 10. Filtered volume received for Dissolved tests ❑Yes ❑ o ❑ 11. Sample Labels match COG: No ❑NIA 12. -Includes datellime/ID/Analysis Matrix:_ 5 1,— _ All containers needing preservation have been checked. ❑Yes ❑No% ❑ A 13 All containers needing preservation are found to be in Dyes ❑NOAA compliance with EPA recommendation. exceptions: VOA, coliform, TOC. O&G, WI -DRO (water) ❑Yes El Samples checked for dechlorination: ❑Yes ONO EWIA, Headspace in VOA Vials (>Smm): ❑Yes ONO EQ1 . Trip Blank Present: ❑Yes ❑NoNI 16. Trip Blank Custody Seals Present [:]Yes ONO NIA Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: Field Data Required? Y 1 N Person Contacted: Date/Time: Comments/ Resolution: SRF Review: I W jDate: j( WWW ' vLLvv 1.JJ Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR IIIIIIIIIIIII fl Certification Office ( Le out of hold, Incorrect preservative, out of temp, 82233138 incorrect containers) Page 34 of 35 I I v lD �l> rlU) 91 j a ;CJ o iD tM'^ 4 f1 ----- C C R o is V -u z In C+ C7 I m 3 0 � C n O Ip �f N i i i I � f 1 � nD�ezQ j 0 © 7 _ of 111ppp -f C Iz oo C O A � W I n �a m n_ N f A rli O � m o `q N V! obi 'a° N .. z. .._ ._- J .._ V •• 7 O s+ .._ Customer ._. f a C, m _. _..L.. appfalfrialc .._ y° _.. ............. to right _.. .l L 0 on] (: 6 S fD N i u '0 N s 0 M tl f1 2 cy a o M Onrl,pt o� C 9 s b qe ry n� 3 V Y � p dN `.� E. CL I rA X M M BMW cn m 3 Q Customer �,.�si c��wpiE N I v lD �l> rlU) 91 j a ;CJ o iD tM'^ 4 f1 ----- _. i 0 �i R o is V -u In C+ C7 I m Cr ra N C n O Ip I y N i i i I I N f 1 � � � o j 0 © 7 _ 1 111ppp -f C Iz o C mt I 7 m o `q N 'a° N .. z. .._ ._- _.. .._ ._. _... .. .._ Customer ._. _.- to ..-.. complete _. _..L.. appfalfrialc .._ .._. columns _.. ............. to right _.. .l csc 0 on] (: 6 S 7 i u '0 s 0 M tl f1 2 a o a 9 s b qe ry 3 rA X M M BMW cn m 3 Q Customer �,.�si c��wpiE N I v lD �l> rlU) 91 j a ;CJ o iD tM'^ 4 f1 ----- _. i 0 �i R o is V -u In C+ C7 I m Cr ra N C n O Ip I y N i i i I I N f 1 � � � o j 0 © 7 _ 1 111ppp -f C Iz o C mt 7 m o `q N 'a° N N d 3 o T vi ry + csc 0 on] (: 6 S 7 i u '0 $ p @ tl f1 2 a o a b qe ry "Comp. t6A i '4, "Grab -- Re4 Total Metals , Anic pH 1 - 8 oz jar (PACE:) I v 54 �l> rlU) 91 j a ;CJ o iD tM'^ _.. _.._.._.. n f1 ----- _. i 0 �i R o is V -u In C+ C7 I m Cr ra N g n O Ip I a i i i I I N f 1 � j 0 © n O O N 00 _ 1 111ppp -f n Iz "Comp. t6A i '4, "Grab -- Re4 Total Metals , Anic pH 1 - 8 oz jar (PACE:) 5 TOC 1 - 4 oz jar 4 (PACE) S otal M and Ani oz jars (PAC 5 Sediment specific iv tests 2 - 8 oz jar i I ANALYTICAL) 5 f l 2°Total # of Containers I v x cn �l> rlU) 91 j a ;CJ o iD tM'^ _.. _.._.._.. n ._.$ ----- _. i 0 O � R m i V In C7 I m Cr ra N g C IQ-yry� I a i i i I I N f 1 tA 3 j j At- 1 n Iz 5 TOC 1 - 4 oz jar 4 (PACE) S otal M and Ani oz jars (PAC 5 Sediment specific iv tests 2 - 8 oz jar i I ANALYTICAL) 5 f l 2°Total # of Containers Page 35 of 35 I v x cn �l> rlU) 91 j a ;CJ o iD tM'^ 3 3 m a 0! i i i i I m I^ i z =lair i i I Page 35 of 35 Acass ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Duke Energy 13339 Hagers Ferry Rd. Huntersville NC 28078 ATTENTION Marge Galvin -Karr PROJECT ID J15060148 LABORATORY REPORT NUMBER 1506882 DATE June 16, 2015 Primary Data Review By Secondary Data Review By Ashley Amick Chantelle Kanhai Project Manager, Access Analytical Project Manager, AES aamick@axs-inc.com PLEASE NOTE: 42 of 55 - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL -E87582, NELAP certified laboratory # E87582 - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 1 of 8 CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM( SY11tel'M EDD 21)Relinquktced By �,.� DatelTime f , $_ /00 YF Analytical Laboratory Services - i i - - - - - - - - - -----..-Anal ical Laborato Use Only DUKE Mail Code MG03A2 (Building 7406) 93339 Nagata Ferry Rd 1 I I ,L SQ _ samples OriginatingFrom �! I DISTRIBUTION 1 ORIGINAL LAB, work order I G l r f Matrix: SOIL ed oat/s a Tlma 4 L E NERGY� g Huntereviile, N. C. 2807$ to {980) 876.5245 1 i � ' ) 24)commems Metals: Al, Sb, As, Ba, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, NI, IC, Se, Na, Sr, TI, V, in, Mercury, pI4 COPY to CLIENT — — — _ — — _FaxLLIMls75,4349--._•_...__--i G 3'�1 '�` P � SAMPLE PROGRAM Grund Water NPDES' Other_ Plant_ 1jPmjeeeHame AB Groundwater Assessment -Soil 2)PhomNo: iVendar 1.7 ' ;Access Analytical Cooler Tem c n 3lctiem 41Fax No: i PO !Number 1.142057 =r�.:,� vi� AB GW 1f 8 t one In ... . .. V in Unit: )x) eet 10 Mi l Code: Pace a 0 , t2j8i pperalin9DH: D: 71ProessIP PO 1142081a � 'c to �. v w, a s tt used Ip)Igt be s " Q R N ar, _ i1 ca Q N ri I o IM22EMj: When specific accounting has been established and is not indicated above wa need the following: 9) Enter correct accounting in all 5 accounting fields above, or added Wlgtin,l5 mfrs of salrtple w° ap U 2 Provide correct accounting for Operating Unit and Process ID. '; Cp)jpn., �- i m =. �� 'N - , ,.. O •� 'N N .................._ , I• LABU5EONlY i Matrix ''Collection information E V. rJ c E LIJ ,a U a 'rlsn ID {Sall, Sediment, Ash) "Sam le Descri tion or I[} Date Time —Signature ~ O. r D. !n i� Q ' t2i115� _ �T37x: i . L My� a'. f I 17 " I i 3z �E _2 i o 1 Fm R 1 I m it a {l V 1 1"� 1 im E FU 1 I I i 1 I I I f 1 WATER EQUIPMENT BLANK 7 PER DAY 21)Relinquktced By �,.� DatelTime f , $_ /00 YF �Re{luested Turnarl }tl'Id Relln4utshcd BY Datefrime d ateft3me l 14 Days ( �Cf~ Relinquish By Daterrlme iaepted By: Oa"ITlme is C. '7 Days Sealed/Locked By Date 8aawn ack ned By Oatemme • 48 Hr 24)commems Metals: Al, Sb, As, Ba, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, NI, IC, Se, Na, Sr, TI, V, in, Mercury, pI4 Actions: Cl, Nitrate -N, SO4 Sediment Specific Parameters: %Solids CEC Particle Size Distribution Redox Potential Analytical Environmental Services, Inc Date: 19 -Jun -1544 of 55 Client: Duke Energy Project: J15060148 Case Narrative Lab ID: 1506882 Four containers per sample were indicated on the Chain of Custody. Only one container per sample was received. The laboratory proceeded with analysis. REDOX POTENTIAL 1506882-001A 214.1 mV 223.9 mV 209.2 mV 1506882-002A 194.0 mV 217.7 mV 233.1 mV 1506882-003A 206.7 mV 197.2 mV 193.3 mV Page 3 of 8 Analytical Environmental Services, Inc Date: 19 -Jun -15 45 of 55 Client: Duke Energy Client Sample ID: F13-1 Project Name: J15060148 Collection Date: 6/2/2015 10:40:00 AM Lab ID: 1506882-001 Matrix: Sediment Reporting Dilution Analyses Result Qual Units BatchID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity Qualifiers: r Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value (SW9081) 4.2 1.0 meq/100g 208603 1 06/13/2015 03:49 TA E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Nan See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 4 of 8 Analytical Environmental Services, Inc Date: 19 -Jun -15 46 of 55 Client: Duke Energy Client Sample ID: 1713-1 DUP Project Name: J15060148 Collection Date: 6/2/2015 10:55:00 AM Lab ID: 1506882-002 Matrix: Sediment Reporting Dilution Analyses Result Qual Units BatcbID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity Qualifiers: r Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value (SW9081) 5.1 1.0 meq/100g 208603 1 06/13/2015 03:52 TA E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Nan See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 5 of 8 Analytical Environmental Services, Inc Date: 19 -Jun -15 47 of 55 Client: Duke Energy Client Sample ID: 1713-2 Project Name: J15060148 Collection Date: 6/2/2015 12:00:00 PM Lab ID: 1506882-003 Matrix: Sediment Reporting Dilution Analyses Result Qual Units BatcbID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity Qualifiers: r Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value (SW9081) 1.9 1.0 meq/100g 208603 1 06/13/2015 03:58 TA E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Nan See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 6 of 8 48 of 55 Analylticlal Environmental Survicus, Inc. 8amp la/Coo lar Racuipt ChaclkL s1 Clienit c�c�.G� �y� l% %L W arA C rc er N urrib er 1�O AP� Checklist carnpletec Hy Signature Da( Yes ✓ Nc _ Carriem names: Fec Ex _VIJA S _ Caurier _ Clien" _ U9 Mail _ O"Iher Shippting in iiian? Yes containerrlcaaler gaud cam Yes ✓ N a Cus" ady seals intact an sl illpin€I cam ainerrlcoaler? Yes No Cusilocy seals in"lauil an sample battles? Yes _ No _ ` Conitainern emp Blank temfleratt me ini comflliance? i1C'° PC' *Yes No _ Y es Na _ Nat Present _ Nail F resen" N of Present Caaler Alit Caaler 41:1 Caaler 43 Caoler #4 CaalerAl-I j ar c iffusive samples ar A 11H.4 lead) Is ai knawni Hlan k incluc ec? Yeis gee Case .N'anrative fcir resolu ilicini oif ilbei 1\ eini-Cor foirmanae. Nct P pplicaflle Nc Nca AFIFllicatila Na Cooler #( ' 9 aMple9 da not t ave to comply �,ith the given ;iano( fon canain parameter. Pes- 3etl=er,l\SamptleReceirtAlyJacumews\CCCs,rd pHAdjustment SH eet'Sample_Caalan Recipt Checklisl_Re.,l.rf Page 7 of 8 Chain afcusilacy presenit? Yes ✓ Nc _ Chaim cif cuslocy sign(d wllen reliriqu ishec and receivec? Yes No — Chaim of ct stud) agilees wiilh satmplle laHeils? Y ( s Nc ✓ _ `- am plleis in proper conolaineu lboti la? Y es Na _ S aariptlei cantainers in" acs? Yes No Sufficienr sample valumei fan indicated teis'll Yes ✓ No ^ All samples receivec will in holcinig time? Yes Na _ Was TAT markec an "he CCC? Yei ✓ Nc Prace(c w ith f tamd arc TA 11 as l ler plraject 1 is" ary? Yes _ N a ^ / Water - VC N ials 1 av( zera fluadspace`. Na YCA vials suHmitlac ✓ Yes _ Water- pH accept" able uponreceipt? Yes _ N a /" Acjusted? CHecltec by Saimple Candi" ian: Gaac " CtHen(Exr join j ar c iffusive samples ar A 11H.4 lead) Is ai knawni Hlan k incluc ec? Yeis gee Case .N'anrative fcir resolu ilicini oif ilbei 1\ eini-Cor foirmanae. Nct P pplicaflle Nc Nca AFIFllicatila Na Cooler #( ' 9 aMple9 da not t ave to comply �,ith the given ;iano( fon canain parameter. Pes- 3etl=er,l\SamptleReceirtAlyJacumews\CCCs,rd pHAdjustment SH eet'Sample_Caalan Recipt Checklisl_Re.,l.rf Page 7 of 8 Analytical Environmental Services, Inc Client: Duke Energy Project Name: J15060148 Workorder: 1506882 49 of 55 Date: 16 -Jun -15 ANALYTICAL QC SUMMARY REPORT BatchID: 208603 Sample ID: 1506882-002ADUP Client ID: FB -1 DUP Units: meq/100g Prep Date: 06/10/2015 Run No: 293817 SampleType: DUP TestCode: CEC of Soils (Na Saturation) SW9081 BatchID: 208603 Analysis Date: 06/13/2015 Seq No: 6261687 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual Cation Exchange Capacity 7.200 1.0 5.100 34.1 20 R Qualifiers: > Greater than Result value < Less than Result value B Analyte detected in the associated method blank BRL Below reporting limit E Estimated (value above quantitation range) H Holding times for preparation or analysis exceeded J Estimated value detected below Reporting Limit N Analyte not NELAC certified R RPD outside limits due to matrix Page 8 of 8 Rpt Lim Reporting Limit S Spike Recovery outside limits due to matrix June 17, 2015 Access Analytical 7478 Carlisle Street Irmo, South Carolina 29063 Attn: Mr. Ashley Amick Re: Summary of Laboratory Testing AB Groundwater Assessment Terracon Project No. 73075016 (WOJ15060148) Dear Mr. Amick: 50 of 55 Irerracon Terracon has performed the requested laboratory testing program indicated by your Chain of Custody Record, dated 06/09/15. The correspondence indicated hydrometer testing for Samples FB -1, FB -1 DUP, and FB -2. The results have been electronically forwarded to you in PDF format at aamick@accessanalyticalinc.com, as instructed. If there are any questions regarding the results or if we can be of additional service, please contact us. Sincerely, Terracon Consultants, Inc. Rebecca Simms, CET Laboratory Manager Attachments Copies: 1xc: Above (PDF via email) 1xc: File RS/PM Philli A. M riso , P.E. Ge echnic partment Manager Terracon Consultants, Inc. 521 Clemson Road Columbia, South Carolina 29229 P [803] 741 9000 F [803] 741 9900 terracon.com GRAIN SIZE DISTRIBUTION 51 of 55 ASTM D422 U.S. SIEVE OPENING IN INCHES U.S. SIEVE NUMBERS I HYDROMETER 6 4 3 2 1.5 1 3/4 1/23/8 3 4 6 810 1416 20 30 40 50 60 100 140 200 100 95 080 90--- 8 -0 75 70 65 w 60 >- 55 m Z 50 LL I- 45 z LU 40 w CL 35--- 30 25 20 15 10 5 0 100 10 1 0.1 0.01 0.001 GRAIN SIZE IN MILLIMETERS COBBLES GRAVEL SAND SILT OR CLAY coarse fine coarse medium fine Boring ID Depth AASHTO Classification LL PL PI Cc Cu • FB -1 0 1.10 4.17 Boring ID Depth D,00 Doo D30 Dto %Gravel %Sand %Silt %Clay 0 FB -1 0 2 0.655 0.337 0.157 0.0 94.7 2.2 3.2 PROJECT: AB GW Assessment - Asheville Irerracon PROJECT NUMBER: 73075016 SITE: Asheville, North Carolina CLIENT: Access Analytical 521 Clemson Road Columbia, South Carolina 95 90 85 80 75 70 65 w 60 >- 55 m w Z 50 LL I- 45 z LU 40 w CL 35 30 25 20 15 10 5 0 GRAIN SIZE DISTRIBUTION 52 of 55 ASTM D422 U.S. SIEVE OPENING IN INCHES I U.S. SIEVE NUMBERS I HYDROMETER / 1 1 1 1. 1 11 1 11 ■IIIIIIIY®IYIIIimq1�1111YII111Y1�lllll 100 10 1 0.1 GRAIN SIZE IN MILLIMETERS 0.01 0.001 I COBBLES GRAVEL SAND SILT OR CLAY coarse fine coarse I medium fine Boring ID Depth AASHTO Classification LL PL PI Cc Cu • 1`13-1 DUP 0 1.27 3.91 Boring ID Depth D100 D60 D. D,0 %Gravel -/.Sand -/.Slit -/.Clay • FB -1 DUP 0 9.5 0.453 0.259 0.116 2.1 91.3 3.5 3.1 PROJECT: AB GW Assessment - Asheville PROJECT NUMBER: 73075016 SITE: Asheville, North Carolina Irerracon CLIENT: Access Analytical 521 Clemson Road Columbia, South Carolina 95 90 85 80 75 70 65 w 60 >- 55 m w Z 50 LL I— 45 z LU 40 w CL 35 30 25 20 15 10 5 0 GRAIN SIZE DISTRIBUTION 53 of 55 ASTM D422 U.S. SIEVE OPENING IN INCHES I U.S. SIEVE NUMBERS I HYDROMETER fa �IIIr18 100 10 1 0.1 GRAIN SIZE IN MILLIMETERS 0.01 0.001 I COBBLES GRAVEL SAND SILT OR CLAY coarse fine coarse I medium fine Boring ID Depth AASHTO Classification LL PL PI Cc Cu • FB -2 0 1.27 5.90 Boring ID Depth D100 D60 D. D,0 %Gravel -/.Sand -/.Slit -/.Clay 97 FB -2 0 9.5 1.068 0.496 0.181 0.2 96.3 2.4 1.1 PROJECT: AB GW Assessment - Asheville PROJECT NUMBER: 73075016 SITE: Asheville, North Carolina Irerracon CLIENT: Access Analytical 521 Clemson Road Columbia, South Carolina z 0 w ar m a J Q S[ Q Q C'1{ G p.x 1 o 0d i Ip ct n Q R u �y a I I— eL W � a � N M , � o L) IL:Hl AK z 0 w ar m a J s rs UB r �V�eue s!a3� - 11" ase sysAtette �.r�� Ir,�,rI�r v n m m N T3 Co v Q S[ Q Q C'1{ �i 0d i Ip ct 7r+, �y a I eL W � a s rs UB r �V�eue s!a3� - 11" ase sysAtette �.r�� Ir,�,rI�r v n m m N T3 Co v --�y Q S[ Q Q C'1{ Imo. gl �°" 0d i Ip ct �y a I W � a � N U cx U z� z� z� --�y y C C'1{ Imo. gl �°" 0d o o ct �y H ODUKE °� ENERGYa. _ CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM - ------ Laboratory Services : i-----_._-----i--.----_-_-_-----_--Analytical Laboratory Use Only._._._._._._._._._._._._._._._._._.i ytical Work Order NC_x_ Page t9fil 55 Mail Code MG03A2 (Building 7465) I ; h Mattis: SOIL Sc— I DISTRIBUTION 13339 Hagers Ferry Rd j I V i -1 Samples Originating From OH_ j Huntersville, N. C. 28978 j ILoggedBy Date aTime ORIGINAL L LAB, (980)875-5245 l j i I COPY to CLIENT SAMPLE PROGRAM Ground Water_ NPDESj 2)Phone No: ;Vendor �j � Other _ Plant � j i ).'7 t REV DATE 2!10!2015 I )Project Name AB Groundwater Assessment Soil Matrix (Soil, Sediment, Ash) 3JGIISM ��tVl � AS GW 4)Fax No: S)Buslness Unit: e)Project 10: T)Mall Code: 8) Operating Unit: fiKe vtty ID: 19)Pracess ID :a e �e ilk: when specific accounting has bean established and is not indicated above we need the following- 1) Enter correct accounting In all 5 accounting fields above, Or 2 Provide correct accountingfor Operating Unit and Process ID.. I LAB USE ONLY I "LabID �2aISb073ZZ ji .. 3Z3 j R� 3Z r Matrix (Soil, Sediment, Ash) /�t a N J O L fa �o up Q O � J :a e �e mea 2-H s04 ' '& lcda 0 I __. E = one Iw I IU of 1 I 1 t I i I t=tl�tOmer to [Om Dlete all ; I I I aorarooriateareas ¢ WATER EQUIPMENT BLANK (1 PER DA !Poo u A a a N J O L fa = N up Q O � J mea 2-H s04 3-H •� I __. 4=1G8 = one U1 of t=tl�tOmer to [Om Dlete all aorarooriateareas ¢ e U a a Preservatives when used must be added within 15 minutes of sample e� Collection 1V "Collection Information c Q 0O = a0o ' Date Time .06 Signature ~ r r 0/11V71 Y I 12W Nr N O un I u7 a u A a a N J O L fa = N Q=i N1l1� E W Q O � J mea to Q IR 21)Relinqulshed By Datefrlme a 22Re costed Turnaround 14 Days x "7 Days 48 Hr Relinquished 6y Datel7imepte Relinquished By Daletlhne _ • _ ! d {�fi 1^ i Accepted By: DoWTiTime SealedlLock Opened By DateiTlme SeeiedlLocked By Date/Time 24)Commertt3 Metals: Al,. Sb, As, Ba, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg., Mn, Mo, Ni, K, Se, Na, Sr, TI, V, Zn, Mercury, pH Anions: Cl, Nitrate -N, SO4 Sediment $ ecific Parameters: %Solids, CEC, Particle Size Distribution. Redox Potential