NC0000396_J15050770report_20150823

DUE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Order Number: J15050770
Project Name: ASHEVILLE - AB GW ASSESSMENT WATER
Customer Name(s): Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker
Customer Address: 200 CP and L Drive
Arden,NC 28704
Lab Contact: Mary Ann Oale Phone: [phone]
Mary Ann Ogle
2015.06.17
Report Authorized By: NF' GY 13:12:27 -04'00' Date:
(Signature)
Mary Ann Ogle
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
6/17/2015
Analytical Lab
Page 1 of 71
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By
Sample Description
2015016462
ASHEVILLE
28 -May -15 9:24 AM
GW -01 D
2015016463
ASHEVILLE
28 -May -15 10:42 AM
MW -16A
2015016464
ASHEVILLE
28 -May -15 9:21 AM
MW-05BR
2015016465
ASHEVILLE
28 -May -15 1:32 PM
CB-09BR
2015016466
ASHEVILLE
28 -May -15 11:11 AM
CB-09SL
2015016467
ASHEVILLE
28 -May -15 12:31 PM
MW-16BR
2015016468
ASHEVILLE
28 -May -15 2:15 PM
MW-18BR
2015016469
ASHEVILLE
28 -May -15 1:36 PM
MW -18D
2015016470
ASHEVILLE
28 -May -15 8:26 AM
Filter Blank
2015016471
ASHEVILLE
28 -May -15 8:26 AM
Equipment Blank
10 Total Samples
Analytical Lab
Page 2 of 71

Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals 0 Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable. 0 Yes F-] No
Report Sections Included:
E%-'] Job Summary Report
❑� Sample Identification
Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Analytical Lab
Page 3 of 71
❑d Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Mary Ann Ogle Date: 6/17/2015

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050770
Site: GW -01D
Collection Date: 28 -May -15 9:24 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
BGN9034
1 EPA 300.0
Vendor Parameter
Complete
1 EPA 245.1
06/01/2015 10:31
NITRITE + NITRATE (COLORIMETRIC)
1 EPA 245.1
06/03/2015 15:27
Nitrite + Nitrate (Colorimetric)
0.542
mg-N/L
0.01
INORGANIC IONS BY IC
06/01/2015 13:36
MHALL3
1 EPA 200.7
Chloride
5.3
mg/L
0.1
Sulfate
2.9
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
06/01/2015 13:36
MHALL3
Mercury (Hg)
0.14
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
MHH7131
1 EPA 200.7
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
1 EPA 200.7
06/04/2015 12:17
MHH7131
Aluminum (AI)
0.034
mg/L
0.005
Barium (Ba)
0.038
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.160
mg/L
0.01
Manganese (Mn)
0.239
mg/L
0.005
Strontium (Sr)
0.028
mg/L
0.005
Zinc (Zn)
0.010
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
2.51
mg/L
0.01
Magnesium (Mg)
2.41
mg/L
0.005
Potassium (K)
1.31
mg/L
0.1
Sodium (Na)
2.52
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.139
mg/L
0.005
Barium (Ba)
0.041
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.295
mg/L
0.01
Manganese (Mn)
0.240
mg/L
0.005
Strontium (Sr)
0.029
mg/L
0.005
Zinc (Zn)
0.017
mg/L
0.005
Sample #: 2015016462
Matrix: GW -WW
Analytical Lab
Page 4 of 71
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1 EPA 353.2
06/01/2015 14:39
LSTARLI
1 EPA 300.0
06/03/2015 00:10
BGN9034
1 EPA 300.0
06/03/2015 00:10
BGN9034
1 EPA 245.1
06/01/2015 10:31
ACPAYNE
1 EPA 245.1
06/03/2015 15:27
ACPAYNE
1 EPA 200.7
06/01/2015 13:36
MHALL3
1 EPA 200.7
06/01/2015 13:36
MHALL3
1 EPA 200.7
06/01/2015 13:36
MHALL3
1 EPA 200.7
06/01/2015 13:36
MHALL3
1 EPA 200.7
06/01/2015 13:36
MHALL3
1 EPA 200.7
06/01/2015 13:36
MHALL3
1 EPA 200.7
06/01/2015 13:36
MHALL3
1 EPA 200.7
06/04/2015 12:17
MHH7131
1 EPA 200.7
06/04/2015 12:17
MHH7131
1 EPA 200.7
06/04/2015 12:17
MHH7131
1 EPA 200.7
06/04/2015 12:17
MHH7131
1 EPA 200.7
06/02/2015 10:43
MHALL3
1 EPA 200.7
06/02/2015 10:43
MHALL3
1 EPA 200.7
06/02/2015 10:43
MHALL3
1 EPA 200.7
06/02/2015 10:43
MHALL3
1 EPA 200.7
06/02/2015 10:43
MHALL3
1 EPA 200.7
06/02/2015 10:43
MHALL3
1 EPA 200.7
06/02/2015 10:43
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050770
Site: GW -01D
Collection Date: 28 -May -15 9:24 AM
Analyte
Result
Units Qualifiers
RDL
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
EPA 200.8
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
3.90
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
1.19
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP -MS
SLS2560
1
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
4.02
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
1.44
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
41
mg/L
25
Total Carbon
TOC
0.311
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
11
mg/L
5
Sample #: 2015016462
Matrix: GW -WW
Analytical Lab
Page 5 of 71
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/15/2015 20:30
JAHERMA
1
EPA 200.8
06/15/2015 20:30
JAHERMA
1
EPA 200.8
06/15/2015 20:30
JAHERMA
1
EPA 200.8
06/15/2015 20:30
JAHERMA
1
EPA 200.8
06/15/2015 20:30
JAHERMA
1
EPA 200.8
06/15/2015 20:30
JAHERMA
1
EPA 200.8
06/15/2015 20:30
JAHERMA
1
EPA 200.8
06/15/2015 20:30
JAHERMA
1
EPA 200.8
06/15/2015 20:30
JAHERMA
1
EPA 200.8
06/15/2015 20:30
JAHERMA
1
EPA 200.8
06/15/2015 20:30
JAHERMA
1
EPA 200.8
06/15/2015 20:30
JAHERMA
1
EPA 200.8
06/15/2015 20:30
JAHERMA
1
EPA 200.8
06/07/2015 02:38
SLS2560
1
EPA 200.8
06/07/2015 02:38
SLS2560
1
EPA 200.8
06/07/2015 02:38
SLS2560
1
EPA 200.8
06/07/2015 02:38
SLS2560
1
EPA 200.8
06/07/2015 02:38
SLS2560
1
EPA 200.8
06/07/2015 02:38
SLS2560
1
EPA 200.8
06/07/2015 02:38
SLS2560
1
EPA 200.8
06/07/2015 02:38
SLS2560
1
EPA 200.8
06/07/2015 02:38
SLS2560
1
EPA 200.8
06/07/2015 02:38
SLS2560
1
EPA 200.8
06/07/2015 02:38
SLS2560
1
EPA 200.8
06/07/2015 02:38
SLS2560
1
EPA 200.8
06/07/2015 02:38
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/02/201511:59 AGIBBS5
1 SM5310C/EPA9060A 06/05/201511:47 TJA7067
1 SM2540D 06/03/2015 09:00 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050770
Site: MW -16A
Collection Date: 28 -May -15 10:42 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
06/02/2015 21:29
Vendor Parameter
Complete
EPA 300.0
06/02/2015 21:29
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
0.022
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
97
mg/L
1
Sulfate
33
mg/L
1
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
06/01/2015 13:40
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
06/01/2015 13:40
MHALL3
Aluminum (AI)
0.213
mg/L
0.005
Barium (Ba)
0.117
mg/L
0.005
Boron (B)
0.358
mg/L
0.05
Iron (Fe)
0.185
mg/L
0.01
Manganese (Mn)
1.96
mg/L
0.005
Strontium (Sr)
0.204
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
06/02/2015 10:47
MHALL3
Calcium (Ca)
35.4
mg/L
0.01
Magnesium (Mg)
12.6
mg/L
0.005
Potassium (K)
2.57
mg/L
0.1
Sodium (Na)
17.5
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.226
mg/L
0.005
Barium (Ba)
0.118
mg/L
0.005
Boron (B)
0.354
mg/L
0.05
Iron (Fe)
0.248
mg/L
0.01
Manganese (Mn)
1.94
mg/L
0.005
Strontium (Sr)
0.203
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015016463
Matrix: GW -WW
Analytical Lab
Page 6 of 71
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/01/2015 14:40
LSTARLI
10
EPA 300.0
06/02/2015 21:29
BGN9034
10
EPA 300.0
06/02/2015 21:29
BGN9034
1
EPA 245.1
06/01/2015 10:42
ACPAYNE
1
EPA 245.1
06/03/2015 15:29
ACPAYNE
1
EPA 200.7
06/01/2015 13:40
MHALL3
1
EPA 200.7
06/01/2015 13:40
MHALL3
1
EPA 200.7
06/01/2015 13:40
MHALL3
1
EPA 200.7
06/01/2015 13:40
MHALL3
1
EPA 200.7
06/01/2015 13:40
MHALL3
1
EPA 200.7
06/01/2015 13:40
MHALL3
1
EPA 200.7
06/01/2015 13:40
MHALL3
1
EPA 200.7
06/04/2015 12:21
MHH7131
1
EPA 200.7
06/04/2015 12:21
MHH7131
1
EPA 200.7
06/04/2015 12:21
MHH7131
1
EPA 200.7
06/04/2015 12:21
MHH7131
1
EPA 200.7
06/02/2015 10:47
MHALL3
1
EPA 200.7
06/02/2015 10:47
MHALL3
1
EPA 200.7
06/02/2015 10:47
MHALL3
1
EPA 200.7
06/02/2015 10:47
MHALL3
1
EPA 200.7
06/02/2015 10:47
MHALL3
1
EPA 200.7
06/02/2015 10:47
MHALL3
1
EPA 200.7
06/02/2015 10:47
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050770
Site: MW -16A
Collection Date: 28 -May -15 10:42 AM
Analyte
Result
Units Qualifiers
RDL
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
EPA 200.8
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
1.32
ug/L
1
Copper (Cu)
1.97
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP -MS
SLS2560
1
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
1.35
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
350
mg/L
25
Total Carbon
TOC
0.725
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Sample #: 2015016463
Matrix: GW -WW
Analytical Lab
Page 7 of 71
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/15/2015 20:58
JAHERMA
1
EPA 200.8
06/15/2015 20:58
JAHERMA
1
EPA 200.8
06/15/2015 20:58
JAHERMA
1
EPA 200.8
06/15/2015 20:58
JAHERMA
1
EPA 200.8
06/15/2015 20:58
JAHERMA
1
EPA 200.8
06/15/2015 20:58
JAHERMA
1
EPA 200.8
06/15/2015 20:58
JAHERMA
1
EPA 200.8
06/15/2015 20:58
JAHERMA
1
EPA 200.8
06/15/2015 20:58
JAHERMA
1
EPA 200.8
06/15/2015 20:58
JAHERMA
1
EPA 200.8
06/15/2015 20:58
JAHERMA
1
EPA 200.8
06/15/2015 20:58
JAHERMA
1
EPA 200.8
06/15/2015 20:58
JAHERMA
1
EPA 200.8
06/07/2015 02:56
SLS2560
1
EPA 200.8
06/07/2015 02:56
SLS2560
1
EPA 200.8
06/07/2015 02:56
SLS2560
1
EPA 200.8
06/07/2015 02:56
SLS2560
1
EPA 200.8
06/07/2015 02:56
SLS2560
1
EPA 200.8
06/07/2015 02:56
SLS2560
1
EPA 200.8
06/07/2015 02:56
SLS2560
1
EPA 200.8
06/07/2015 02:56
SLS2560
1
EPA 200.8
06/07/2015 02:56
SLS2560
1
EPA 200.8
06/07/2015 02:56
SLS2560
1
EPA 200.8
06/07/2015 02:56
SLS2560
1
EPA 200.8
06/07/2015 02:56
SLS2560
1
EPA 200.8
06/07/2015 02:56
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/02/201511:59 AGIBBS5
1 SM5310C/EPA9060A 06/05/201511:47 TJA7067
1 SM2540D 06/03/2015 09:00 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050770
Site: MW-05BR
Collection Date: 28 -May -15 9:21 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
06/03/2015 02:21
Vendor Parameter
Complete
EPA 300.0
06/03/2015 02:21
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
0.027
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
8.4
mg/L
0.1
Sulfate
140
mg/L
2.5
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
06/01/2015 13:44
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
06/01/2015 13:44
MHALL3
Aluminum (AI)
0.045
mg/L
0.005
Barium (Ba)
0.019
mg/L
0.005
Boron (B)
0.464
mg/L
0.05
Iron (Fe)
28.9
mg/L
0.01
Manganese (Mn)
0.254
mg/L
0.005
Strontium (Sr)
0.329
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
06/02/2015 10:59
MHALL3
Calcium (Ca)
36.1
mg/L
0.01
Magnesium (Mg)
6.13
mg/L
0.005
Potassium (K)
3.72
mg/L
0.1
Sodium (Na)
18.1
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.071
mg/L
0.005
Barium (Ba)
0.023
mg/L
0.005
Boron (B)
0.454
mg/L
0.05
Iron (Fe)
27.9
mg/L
0.01
Manganese (Mn)
0.244
mg/L
0.005
Strontium (Sr)
0.328
mg/L
0.005
Zinc (Zn)
0.005
mg/L
0.005
Sample #: 2015016464
Matrix: GW -WW
Analytical Lab
Page 8 of 71
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/01/2015 14:41
LSTARLI
1
EPA 300.0
06/03/2015 02:21
BGN9034
25
EPA 300.0
06/03/2015 02:21
BGN9034
1
EPA 245.1
06/01/2015 10:50
ACPAYNE
1
EPA 245.1
06/03/2015 15:31
ACPAYNE
1
EPA 200.7
06/01/2015 13:44
MHALL3
1
EPA 200.7
06/01/2015 13:44
MHALL3
1
EPA 200.7
06/01/2015 13:44
MHALL3
1
EPA 200.7
06/01/2015 13:44
MHALL3
1
EPA 200.7
06/01/2015 13:44
MHALL3
1
EPA 200.7
06/01/2015 13:44
MHALL3
1
EPA 200.7
06/01/2015 13:44
MHALL3
1
EPA 200.7
06/04/2015 12:25
MHH7131
1
EPA 200.7
06/04/2015 12:25
MHH7131
1
EPA 200.7
06/04/2015 12:25
MHH7131
1
EPA 200.7
06/04/2015 12:25
MHH7131
1
EPA 200.7
06/02/2015 10:59
MHALL3
1
EPA 200.7
06/02/2015 10:59
MHALL3
1
EPA 200.7
06/02/2015 10:59
MHALL3
1
EPA 200.7
06/02/2015 10:59
MHALL3
1
EPA 200.7
06/02/2015 10:59
MHALL3
1
EPA 200.7
06/02/2015 10:59
MHALL3
1
EPA 200.7
06/02/2015 10:59
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050770
Site: MW-05BR
Collection Date: 28 -May -15 9:21 AM
Analyte
Result
Units Qualifiers
RDL
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
EPA 200.8
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.05
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP -MS
SLS2560
1
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.21
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
0.287
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
260
mg/L
25
Total Carbon
TOC
0.239
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
29
mg/L
5
Sample #: 2015016464
Matrix: GW -WW
Analytical Lab
Page 9 of 71
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/15/2015 21:05
JAHERMA
1
EPA 200.8
06/15/2015 21:05
JAHERMA
1
EPA 200.8
06/15/2015 21:05
JAHERMA
1
EPA 200.8
06/15/2015 21:05
JAHERMA
1
EPA 200.8
06/15/2015 21:05
JAHERMA
1
EPA 200.8
06/15/2015 21:05
JAHERMA
1
EPA 200.8
06/15/2015 21:05
JAHERMA
1
EPA 200.8
06/15/2015 21:05
JAHERMA
1
EPA 200.8
06/15/2015 21:05
JAHERMA
1
EPA 200.8
06/15/2015 21:05
JAHERMA
1
EPA 200.8
06/15/2015 21:05
JAHERMA
1
EPA 200.8
06/15/2015 21:05
JAHERMA
1
EPA 200.8
06/15/2015 21:05
JAHERMA
1
EPA 200.8
06/07/2015 03:10
SLS2560
1
EPA 200.8
06/07/2015 03:10
SLS2560
1
EPA 200.8
06/07/2015 03:10
SLS2560
1
EPA 200.8
06/07/2015 03:10
SLS2560
1
EPA 200.8
06/07/2015 03:10
SLS2560
1
EPA 200.8
06/07/2015 03:10
SLS2560
1
EPA 200.8
06/07/2015 03:10
SLS2560
1
EPA 200.8
06/07/2015 03:10
SLS2560
1
EPA 200.8
06/07/2015 03:10
SLS2560
1
EPA 200.8
06/07/2015 03:10
SLS2560
1
EPA 200.8
06/07/2015 03:10
SLS2560
1
EPA 200.8
06/07/2015 03:10
SLS2560
1
EPA 200.8
06/07/2015 03:10
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/02/201511:59 AGIBBS5
1 SM5310C/EPA9060A 06/05/201511:47 TJA7067
1 SM2540D 06/03/2015 09:00 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050770
Site: CB-09BR
Collection Date: 28 -May -15 1:32 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
BGN9034
1 EPA 300.0
Vendor Parameter
Complete
1 EPA 245.1
06/01/2015 10:52
NITRITE + NITRATE (COLORIMETRIC)
1 EPA 245.1
06/03/2015 15:34
Nitrite + Nitrate (Colorimetric)
0.069
mg-N/L
0.01
INORGANIC IONS BY IC
06/01/2015 13:47
MHALL3
1 EPA 200.7
Chloride
6.4
mg/L
0.1
Sulfate
1.8
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
06/01/2015 13:47
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
MHH7131
1 EPA 200.7
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
1 EPA 200.7
06/04/2015 12:44
MHH7131
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.018
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.232
mg/L
0.01
Manganese (Mn)
0.065
mg/L
0.005
Strontium (Sr)
0.088
mg/L
0.005
Zinc (Zn)
0.011
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
16.1
mg/L
0.01
Magnesium (Mg)
3.20
mg/L
0.005
Potassium (K)
3.41
mg/L
0.1
Sodium (Na)
4.76
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.160
mg/L
0.005
Barium (Ba)
0.033
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.402
mg/L
0.01
Manganese (Mn)
0.076
mg/L
0.005
Strontium (Sr)
0.098
mg/L
0.005
Zinc (Zn)
0.021
mg/L
0.005
Sample #: 2015016465
Matrix: GW -WW
Analytical Lab
Page 10 of 71
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1 EPA 353.2
06/01/2015 14:42
LSTARLI
1 EPA 300.0
06/03/2015 02:37
BGN9034
1 EPA 300.0
06/03/2015 02:37
BGN9034
1 EPA 245.1
06/01/2015 10:52
ACPAYNE
1 EPA 245.1
06/03/2015 15:34
ACPAYNE
1 EPA 200.7
06/01/2015 13:47
MHALL3
1 EPA 200.7
06/01/2015 13:47
MHALL3
1 EPA 200.7
06/01/2015 13:47
MHALL3
1 EPA 200.7
06/01/2015 13:47
MHALL3
1 EPA 200.7
06/01/2015 13:47
MHALL3
1 EPA 200.7
06/01/2015 13:47
MHALL3
1 EPA 200.7
06/01/2015 13:47
MHALL3
1 EPA 200.7
06/04/2015 12:44
MHH7131
1 EPA 200.7
06/04/2015 12:44
MHH7131
1 EPA 200.7
06/04/2015 12:44
MHH7131
1 EPA 200.7
06/04/2015 12:44
MHH7131
1 EPA 200.7
06/02/2015 11:10
MHALL3
1 EPA 200.7
06/02/2015 11:10
MHALL3
1 EPA 200.7
06/02/2015 11:10
MHALL3
1 EPA 200.7
06/02/2015 11:10
MHALL3
1 EPA 200.7
06/02/2015 11:10
MHALL3
1 EPA 200.7
06/02/2015 11:10
MHALL3
1 EPA 200.7
06/02/2015 11:10
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050770
Site: CB-09BR
Collection Date: 28 -May -15 1:32 PM
Analyte
Result
Units Qualifiers
RDL
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
EPA 200.8
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.14
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP -MS
SLS2560
1
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.17
ug/L
1
Nickel (Ni)
1.36
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
0.499
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
96
mg/L
25
Total Carbon
TOC
0.204
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
8.0
mg/L
5
Sample #: 2015016465
Matrix: GW -WW
Analytical Lab
Page 11 of 71
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/15/2015 21:12
JAHERMA
1
EPA 200.8
06/15/2015 21:12
JAHERMA
1
EPA 200.8
06/15/2015 21:12
JAHERMA
1
EPA 200.8
06/15/2015 21:12
JAHERMA
1
EPA 200.8
06/15/2015 21:12
JAHERMA
1
EPA 200.8
06/15/2015 21:12
JAHERMA
1
EPA 200.8
06/15/2015 21:12
JAHERMA
1
EPA 200.8
06/15/2015 21:12
JAHERMA
1
EPA 200.8
06/15/2015 21:12
JAHERMA
1
EPA 200.8
06/15/2015 21:12
JAHERMA
1
EPA 200.8
06/15/2015 21:12
JAHERMA
1
EPA 200.8
06/15/2015 21:12
JAHERMA
1
EPA 200.8
06/15/2015 21:12
JAHERMA
1
EPA 200.8
06/07/2015 03:14
SLS2560
1
EPA 200.8
06/07/2015 03:14
SLS2560
1
EPA 200.8
06/07/2015 03:14
SLS2560
1
EPA 200.8
06/07/2015 03:14
SLS2560
1
EPA 200.8
06/07/2015 03:14
SLS2560
1
EPA 200.8
06/07/2015 03:14
SLS2560
1
EPA 200.8
06/07/2015 03:14
SLS2560
1
EPA 200.8
06/07/2015 03:14
SLS2560
1
EPA 200.8
06/07/2015 03:14
SLS2560
1
EPA 200.8
06/07/2015 03:14
SLS2560
1
EPA 200.8
06/07/2015 03:14
SLS2560
1
EPA 200.8
06/07/2015 03:14
SLS2560
1
EPA 200.8
06/07/2015 03:14
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/02/201511:59 AGIBBS5
1 SM5310C/EPA9060A 06/05/201511:47 TJA7067
1 SM2540D 06/03/2015 09:00 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050770
Site: CB-09SL
Collection Date: 28 -May -15 11:11 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
BGN9034
1 EPA 300.0
Vendor Parameter
Complete
1 EPA 245.1
06/01/2015 10:54
NITRITE + NITRATE (COLORIMETRIC)
1 EPA 245.1
06/03/2015 15:36
Nitrite + Nitrate (Colorimetric)
0.206
mg-N/L
0.01
INORGANIC IONS BY IC
06/01/2015 13:51
MHALL3
1 EPA 200.7
Chloride
6.6
mg/L
0.1
Sulfate
0.57
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
06/01/2015 13:51
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
MHH7131
1 EPA 200.7
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
1 EPA 200.7
06/04/2015 12:57
MHH7131
Aluminum (AI)
0.011
mg/L
0.005
Barium (Ba)
0.027
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.029
mg/L
0.01
Manganese (Mn)
0.069
mg/L
0.005
Strontium (Sr)
0.026
mg/L
0.005
Zinc (Zn)
0.016
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
3.38
mg/L
0.01
Magnesium (Mg)
1.77
mg/L
0.005
Potassium (K)
1.28
mg/L
0.1
Sodium (Na)
4.15
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.119
mg/L
0.005
Barium (Ba)
0.032
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.073
mg/L
0.01
Manganese (Mn)
0.071
mg/L
0.005
Strontium (Sr)
0.028
mg/L
0.005
Zinc (Zn)
0.012
mg/L
0.005
Sample #: 2015016466
Matrix: GW -WW
Analytical Lab
Page 12 of 71
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1 EPA 353.2
06/01/2015 14:43
LSTARLI
1 EPA 300.0
06/03/2015 02:54
BGN9034
1 EPA 300.0
06/03/2015 02:54
BGN9034
1 EPA 245.1
06/01/2015 10:54
ACPAYNE
1 EPA 245.1
06/03/2015 15:36
ACPAYNE
1 EPA 200.7
06/01/2015 13:51
MHALL3
1 EPA 200.7
06/01/2015 13:51
MHALL3
1 EPA 200.7
06/01/2015 13:51
MHALL3
1 EPA 200.7
06/01/2015 13:51
MHALL3
1 EPA 200.7
06/01/2015 13:51
MHALL3
1 EPA 200.7
06/01/2015 13:51
MHALL3
1 EPA 200.7
06/01/2015 13:51
MHALL3
1 EPA 200.7
06/04/2015 12:57
MHH7131
1 EPA 200.7
06/04/2015 12:57
MHH7131
1 EPA 200.7
06/04/2015 12:57
MHH7131
1 EPA 200.7
06/04/2015 12:57
MHH7131
1 EPA 200.7
06/02/2015 11:14
MHALL3
1 EPA 200.7
06/02/2015 11:14
MHALL3
1 EPA 200.7
06/02/2015 11:14
MHALL3
1 EPA 200.7
06/02/2015 11:14
MHALL3
1 EPA 200.7
06/02/2015 11:14
MHALL3
1 EPA 200.7
06/02/2015 11:14
MHALL3
1 EPA 200.7
06/02/2015 11:14
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050770
Site: CB-09SL
Collection Date: 28 -May -15 11:11 AM
Analyte
Result
Units Qualifiers
RDL
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
EPA 200.8
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.24
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP -MS
SLS2560
1
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.25
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
43
mg/L
25
Total Carbon
TOC
0.209
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
6.0
mg/L
5
Sample #: 2015016466
Matrix: GW -WW
Analytical Lab
Page 13 of 71
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/15/2015 21:19
JAHERMA
1
EPA 200.8
06/15/2015 21:19
JAHERMA
1
EPA 200.8
06/15/2015 21:19
JAHERMA
1
EPA 200.8
06/15/2015 21:19
JAHERMA
1
EPA 200.8
06/15/2015 21:19
JAHERMA
1
EPA 200.8
06/15/2015 21:19
JAHERMA
1
EPA 200.8
06/15/2015 21:19
JAHERMA
1
EPA 200.8
06/15/2015 21:19
JAHERMA
1
EPA 200.8
06/15/2015 21:19
JAHERMA
1
EPA 200.8
06/15/2015 21:19
JAHERMA
1
EPA 200.8
06/15/2015 21:19
JAHERMA
1
EPA 200.8
06/15/2015 21:19
JAHERMA
1
EPA 200.8
06/15/2015 21:19
JAHERMA
1
EPA 200.8
06/07/2015 03:19
SLS2560
1
EPA 200.8
06/07/2015 03:19
SLS2560
1
EPA 200.8
06/07/2015 03:19
SLS2560
1
EPA 200.8
06/07/2015 03:19
SLS2560
1
EPA 200.8
06/07/2015 03:19
SLS2560
1
EPA 200.8
06/07/2015 03:19
SLS2560
1
EPA 200.8
06/07/2015 03:19
SLS2560
1
EPA 200.8
06/07/2015 03:19
SLS2560
1
EPA 200.8
06/07/2015 03:19
SLS2560
1
EPA 200.8
06/07/2015 03:19
SLS2560
1
EPA 200.8
06/07/2015 03:19
SLS2560
1
EPA 200.8
06/07/2015 03:19
SLS2560
1
EPA 200.8
06/07/2015 03:19
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/02/201511:59 AGIBBS5
1 SM5310C/EPA9060A 06/05/201511:47 TJA7067
1 SM2540D 06/03/2015 09:00 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050770
Site: MW-16BR
Collection Date: 28 -May -15 12:31 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
06/03/2015 01:32
Vendor Parameter
Complete
EPA 300.0
06/03/2015 01:32
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
0.024
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
120
mg/L
2.5
Sulfate
36
mg/L
1
MERCURY (COLD VAPOR) IN WATER
MHALL3
10
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
06/01/2015 13:55
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
06/01/2015 13:55
MHALL3
Aluminum (AI)
0.083
mg/L
0.005
Barium (Ba)
0.283
mg/L
0.005
Boron (B)
0.116
mg/L
0.05
Iron (Fe)
56.6
mg/L
0.1
Manganese (Mn)
0.723
mg/L
0.005
Strontium (Sr)
0.268
mg/L
0.005
Zinc (Zn)
0.011
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
06/02/2015 11:18
MHALL3
Calcium (Ca)
22.8
mg/L
0.01
Magnesium (Mg)
4.67
mg/L
0.005
Potassium (K)
3.48
mg/L
0.1
Sodium (Na)
19.5
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.128
mg/L
0.005
Barium (Ba)
0.288
mg/L
0.005
Boron (B)
0.117
mg/L
0.05
Iron (Fe)
56.9
mg/L
0.1
Manganese (Mn)
0.715
mg/L
0.005
Strontium (Sr)
0.266
mg/L
0.005
Zinc (Zn)
0.010
mg/L
0.005
Sample #: 2015016467
Matrix: GW -WW
Analytical Lab
Page 14 of 71
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/01/2015 14:45
LSTARLI
25
EPA 300.0
06/03/2015 01:32
BGN9034
10
EPA 300.0
06/03/2015 01:32
BGN9034
1
EPA 245.1
06/01/2015 10:57
ACPAYNE
1
EPA 245.1
06/03/2015 15:48
ACPAYNE
1
EPA 200.7
06/01/2015 13:55
MHALL3
1
EPA 200.7
06/01/2015 13:55
MHALL3
1
EPA 200.7
06/01/2015 13:55
MHALL3
10
EPA 200.7
06/01/2015 13:55
MHALL3
1
EPA 200.7
06/01/2015 13:55
MHALL3
1
EPA 200.7
06/01/2015 13:55
MHALL3
1
EPA 200.7
06/01/2015 13:55
MHALL3
1
EPA 200.7
06/04/2015 13:01
MHH7131
1
EPA 200.7
06/04/2015 13:01
MHH7131
1
EPA 200.7
06/04/2015 13:01
MHH7131
1
EPA 200.7
06/04/2015 13:01
MHH7131
1
EPA 200.7
06/02/2015 11:18
MHALL3
1
EPA 200.7
06/02/2015 11:18
MHALL3
1
EPA 200.7
06/02/2015 11:18
MHALL3
10
EPA 200.7
06/02/2015 11:18
MHALL3
1
EPA 200.7
06/02/2015 11:18
MHALL3
1
EPA 200.7
06/02/2015 11:18
MHALL3
1
EPA 200.7
06/02/2015 11:18
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050770
Site: MW-16BR
Collection Date: 28 -May -15 12:31 PM
Analyte
Result
Units Qualifiers
RDL
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
EPA 200.8
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
1.47
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP -MS
SLS2560
1
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
1.61
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
310
mg/L
25
Total Carbon
TOC
0.700
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
10
mg/L
5
Sample #: 2015016467
Matrix: GW -WW
Analytical Lab
Page 15 of 71
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/15/2015 21:26
JAHERMA
1
EPA 200.8
06/15/2015 21:26
JAHERMA
1
EPA 200.8
06/15/2015 21:26
JAHERMA
1
EPA 200.8
06/15/2015 21:26
JAHERMA
1
EPA 200.8
06/15/2015 21:26
JAHERMA
1
EPA 200.8
06/15/2015 21:26
JAHERMA
1
EPA 200.8
06/15/2015 21:26
JAHERMA
1
EPA 200.8
06/15/2015 21:26
JAHERMA
1
EPA 200.8
06/15/2015 21:26
JAHERMA
1
EPA 200.8
06/15/2015 21:26
JAHERMA
1
EPA 200.8
06/15/2015 21:26
JAHERMA
1
EPA 200.8
06/15/2015 21:26
JAHERMA
1
EPA 200.8
06/15/2015 21:26
JAHERMA
1
EPA 200.8
06/07/2015 03:23
SLS2560
1
EPA 200.8
06/07/2015 03:23
SLS2560
1
EPA 200.8
06/07/2015 03:23
SLS2560
1
EPA 200.8
06/07/2015 03:23
SLS2560
1
EPA 200.8
06/07/2015 03:23
SLS2560
1
EPA 200.8
06/07/2015 03:23
SLS2560
1
EPA 200.8
06/07/2015 03:23
SLS2560
1
EPA 200.8
06/07/2015 03:23
SLS2560
1
EPA 200.8
06/07/2015 03:23
SLS2560
1
EPA 200.8
06/07/2015 03:23
SLS2560
1
EPA 200.8
06/07/2015 03:23
SLS2560
1
EPA 200.8
06/07/2015 03:23
SLS2560
1
EPA 200.8
06/07/2015 03:23
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/02/201511:59 AGIBBS5
1 SM5310C/EPA9060A 06/05/201511:47 TJA7067
1 SM2540D 06/03/2015 09:00 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050770
Site: MW-18BR
Collection Date: 28 -May -15 2:15 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Method
Vendor Parameter
Complete
EPA 353.2
06/01/2015 14:46
NITRITE + NITRATE (COLORIMETRIC)
10
EPA 300.0
Nitrite + Nitrate (Colorimetric)
0.124
mg-N/L
0.01
INORGANIC IONS BY IC
BGN9034
1
EPA 245.1
Chloride
96
mg/L
1
Sulfate
290
mg/L
5
MERCURY (COLD VAPOR) IN WATER
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
Aluminum (AI)
0.012
mg/L
0.005
Barium (Ba)
0.043
mg/L
0.005
Boron (B)
0.861
mg/L
0.05
Iron (Fe)
0.122
mg/L
0.01
Manganese (Mn)
0.324
mg/L
0.005
Strontium (Sr)
0.418
mg/L
0.005
Zinc (Zn)
0.006
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
06/02/2015 11:37
MHALL3
Calcium (Ca)
125
mg/L
0.1
Magnesium (Mg)
27.8
mg/L
0.005
Potassium (K)
9.14
mg/L
0.1
Sodium (Na)
15.2
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
EPA 200.7
06/02/2015 11:37
Aluminum (AI)
0.030
mg/L
0.005
Barium (Ba)
0.043
mg/L
0.005
Boron (B)
0.851
mg/L
0.05
Iron (Fe)
0.125
mg/L
0.01
Manganese (Mn)
0.313
mg/L
0.005
Strontium (Sr)
0.415
mg/L
0.005
Zinc (Zn)
0.008
mg/L
0.005
Sample #: 2015016468
Matrix: GW -WW
Analytical Lab
Page 16 of 71
DF
Method
Analysis Date/Time
Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/01/2015 14:46
LSTARLI
10
EPA 300.0
06/03/2015 01:48
BGN9034
50
EPA 300.0
06/03/2015 01:48
BGN9034
1
EPA 245.1
06/01/2015 10:59
ACPAYNE
1
EPA 245.1
06/03/2015 15:55
ACPAYNE
1
EPA 200.7
1
EPA 200.7
1
EPA 200.7
1
EPA 200.7
1
EPA 200.7
1
EPA 200.7
1
EPA 200.7
10
EPA 200.7
06/04/2015 13:05
MHH7131
1
EPA 200.7
06/04/2015 13:05
MHH7131
1
EPA 200.7
06/04/2015 13:05
MHH7131
1
EPA 200.7
06/04/2015 13:05
MHH7131
1
EPA 200.7
06/02/2015 11:37
MHALL3
1
EPA 200.7
06/02/2015 11:37
MHALL3
1
EPA 200.7
06/02/2015 11:37
MHALL3
1
EPA 200.7
06/02/2015 11:37
MHALL3
1
EPA 200.7
06/02/2015 11:37
MHALL3
1
EPA 200.7
06/02/2015 11:37
MHALL3
1
EPA 200.7
06/02/2015 11:37
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050770
Site: MW-18BR
Collection Date: 28 -May -15 2:15 PM
Analyte
Result
Units Qualifiers
RDL
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
EPA 200.8
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
1.05
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
4.86
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP -MS
SLS2560
1
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
1.02
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
4.67
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
660
mg/L
25
Total Carbon
TOC
0.323
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Sample #: 2015016468
Matrix: GW -WW
Analytical Lab
Page 17 of 71
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/15/2015 21:33
JAHERMA
1
EPA 200.8
06/15/2015 21:33
JAHERMA
1
EPA 200.8
06/15/2015 21:33
JAHERMA
1
EPA 200.8
06/15/2015 21:33
JAHERMA
1
EPA 200.8
06/15/2015 21:33
JAHERMA
1
EPA 200.8
06/15/2015 21:33
JAHERMA
1
EPA 200.8
06/15/2015 21:33
JAHERMA
1
EPA 200.8
06/15/2015 21:33
JAHERMA
1
EPA 200.8
06/15/2015 21:33
JAHERMA
1
EPA 200.8
06/15/2015 21:33
JAHERMA
1
EPA 200.8
06/15/2015 21:33
JAHERMA
1
EPA 200.8
06/15/2015 21:33
JAHERMA
1
EPA 200.8
06/15/2015 21:33
JAHERMA
1
EPA 200.8
06/07/2015 03:28
SLS2560
1
EPA 200.8
06/07/2015 03:28
SLS2560
1
EPA 200.8
06/07/2015 03:28
SLS2560
1
EPA 200.8
06/07/2015 03:28
SLS2560
1
EPA 200.8
06/07/2015 03:28
SLS2560
1
EPA 200.8
06/07/2015 03:28
SLS2560
1
EPA 200.8
06/07/2015 03:28
SLS2560
1
EPA 200.8
06/07/2015 03:28
SLS2560
1
EPA 200.8
06/07/2015 03:28
SLS2560
1
EPA 200.8
06/07/2015 03:28
SLS2560
1
EPA 200.8
06/07/2015 03:28
SLS2560
1
EPA 200.8
06/07/2015 03:28
SLS2560
1
EPA 200.8
06/07/2015 03:28
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/02/201511:59 AGIBBS5
1 SM5310C/EPA9060A 06/05/201511:47 TJA7067
1 SM2540D 06/03/2015 09:00 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050770
Site: MW -18D
Collection Date: 28 -May -15 1:36 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Method
Vendor Parameter
Complete
EPA 353.2
06/01/2015 14:47
NITRITE + NITRATE (COLORIMETRIC)
10
EPA 300.0
Nitrite + Nitrate (Colorimetric)
0.077
mg-N/L
0.01
INORGANIC IONS BY IC
BGN9034
1
EPA 245.1
Chloride
94
mg/L
1
Sulfate
280
mg/L
5
MERCURY (COLD VAPOR) IN WATER
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
Aluminum (AI)
0.019
mg/L
0.005
Barium (Ba)
0.053
mg/L
0.005
Boron (B)
0.789
mg/L
0.05
Iron (Fe)
6.81
mg/L
0.01
Manganese (Mn)
2.89
mg/L
0.005
Strontium (Sr)
0.297
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
06/02/2015 11:25
MHALL3
Calcium (Ca)
118
mg/L
0.1
Magnesium (Mg)
27.6
mg/L
0.005
Potassium (K)
8.62
mg/L
0.1
Sodium (Na)
12.9
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
EPA 200.7
06/02/2015 11:25
Aluminum (AI)
0.093
mg/L
0.005
Barium (Ba)
0.054
mg/L
0.005
Boron (B)
0.793
mg/L
0.05
Iron (Fe)
6.96
mg/L
0.01
Manganese (Mn)
2.87
mg/L
0.005
Strontium (Sr)
0.298
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015016469
Matrix: GW -WW
Analytical Lab
Page 18 of 71
DF
Method
Analysis Date/Time
Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/01/2015 14:47
LSTARLI
10
EPA 300.0
06/03/2015 02:04
BGN9034
50
EPA 300.0
06/03/2015 02:04
BGN9034
1
EPA 245.1
06/01/2015 11:01
ACPAYNE
1
EPA 245.1
06/03/2015 15:57
ACPAYNE
1
EPA 200.7
1
EPA 200.7
1
EPA 200.7
1
EPA 200.7
1
EPA 200.7
1
EPA 200.7
1
EPA 200.7
10
EPA 200.7
06/04/2015 13:09
MHH7131
1
EPA 200.7
06/04/2015 13:09
MHH7131
1
EPA 200.7
06/04/2015 13:09
MHH7131
1
EPA 200.7
06/04/2015 13:09
MHH7131
1
EPA 200.7
06/02/2015 11:25
MHALL3
1
EPA 200.7
06/02/2015 11:25
MHALL3
1
EPA 200.7
06/02/2015 11:25
MHALL3
1
EPA 200.7
06/02/2015 11:25
MHALL3
1
EPA 200.7
06/02/2015 11:25
MHALL3
1
EPA 200.7
06/02/2015 11:25
MHALL3
1
EPA 200.7
06/02/2015 11:25
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050770
Site: MW -18D
Collection Date: 28 -May -15 1:36 PM
Analyte
Result
Units Qualifiers
RDL
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
EPA 200.8
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
4.43
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.40
ug/L
1
Nickel (Ni)
1.67
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP -MS
SLS2560
1
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
4.61
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.40
ug/L
1
Nickel (Ni)
1.89
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
650
mg/L
25
Total Carbon
TOC
1.3
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Sample #: 2015016469
Matrix: GW -WW
Analytical Lab
Page 19 of 71
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
06/15/2015 21:40
JAHERMA
1
EPA 200.8
06/15/2015 21:40
JAHERMA
1
EPA 200.8
06/15/2015 21:40
JAHERMA
1
EPA 200.8
06/15/2015 21:40
JAHERMA
1
EPA 200.8
06/15/2015 21:40
JAHERMA
1
EPA 200.8
06/15/2015 21:40
JAHERMA
1
EPA 200.8
06/15/2015 21:40
JAHERMA
1
EPA 200.8
06/15/2015 21:40
JAHERMA
1
EPA 200.8
06/15/2015 21:40
JAHERMA
1
EPA 200.8
06/15/2015 21:40
JAHERMA
1
EPA 200.8
06/15/2015 21:40
JAHERMA
1
EPA 200.8
06/15/2015 21:40
JAHERMA
1
EPA 200.8
06/15/2015 21:40
JAHERMA
1
EPA 200.8
06/07/2015 03:33
SLS2560
1
EPA 200.8
06/07/2015 03:33
SLS2560
1
EPA 200.8
06/07/2015 03:33
SLS2560
1
EPA 200.8
06/07/2015 03:33
SLS2560
1
EPA 200.8
06/07/2015 03:33
SLS2560
1
EPA 200.8
06/07/2015 03:33
SLS2560
1
EPA 200.8
06/07/2015 03:33
SLS2560
1
EPA 200.8
06/07/2015 03:33
SLS2560
1
EPA 200.8
06/07/2015 03:33
SLS2560
1
EPA 200.8
06/07/2015 03:33
SLS2560
1
EPA 200.8
06/07/2015 03:33
SLS2560
1
EPA 200.8
06/07/2015 03:33
SLS2560
1
EPA 200.8
06/07/2015 03:33
SLS2560
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 06/02/201511:59 AGIBBS5
1 SM5310C/EPA9060A 06/05/201511:47 TJA7067
1 SM2540D 06/03/2015 09:00 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050770
Site: Filter Blank
Collection Date: 28 -May -15 8:26 AM
Analyte
Result
Units
Qualifiers RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
EPA 245.1
06/03/2015 16:00
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
1
EPA 200.7
06/01/2015 14:56
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.014
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
1
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2015016470
Matrix: GW—WW
Analytical Lab
Page 20 of 71
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
06/03/2015 16:00
ACPAYNE
1
EPA 200.7
06/01/2015 14:56
MHALL3
1
EPA 200.7
06/01/2015 14:56
MHALL3
1
EPA 200.7
06/01/2015 14:56
MHALL3
1
EPA 200.7
06/01/2015 14:56
MHALL3
1
EPA 200.7
06/01/2015 14:56
MHALL3
1
EPA 200.7
06/01/2015 14:56
MHALL3
1
EPA 200.7
06/01/2015 14:56
MHALL3
1
EPA 200.8
06/15/2015 21:47
JAHERMA
1
EPA 200.8
06/15/2015 21:47
JAHERMA
1
EPA 200.8
06/15/2015 21:47
JAHERMA
1
EPA 200.8
06/15/2015 21:47
JAHERMA
1
EPA 200.8
06/15/2015 21:47
JAHERMA
1
EPA 200.8
06/15/2015 21:47
JAHERMA
1
EPA 200.8
06/15/2015 21:47
JAHERMA
1
EPA 200.8
06/15/2015 21:47
JAHERMA
1
EPA 200.8
06/15/2015 21:47
JAHERMA
1
EPA 200.8
06/15/2015 21:47
JAHERMA
1
EPA 200.8
06/15/2015 21:47
JAHERMA
1
EPA 200.8
06/15/2015 21:47
JAHERMA
1
EPA 200.8
06/15/2015 21:47
JAHERMA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050770
Site: Equipment Blank
Collection Date: 28 -May -15 8:26 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy
Labs)
1 EPA 300.0
Vendor Parameter
Complete
1 EPA 245.1
06/01/2015 11:04
NITRITE + NITRATE (COLORIMETRIC)
1 EPA 200.7
06/04/2015 13:13
Nitrite + Nitrate (Colorimetric)
0.012
mg-N/L
0.01
INORGANIC IONS BY IC
06/04/2015 13:13
MHH7131
1 EPA 200.7
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
06/02/2015 11:41
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
MHALL3
1 EPA 200.7
06/02/2015 11:41
Calcium (Ca)
0.031
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
06/07/2015 03:37
SLS2560
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Analytical Lab
Page 21 of 71
Sample #: 2015016471
Matrix: GW -WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2
06/01/2015 14:48
LSTARLI
1 EPA 300.0
06/03/2015 00:26
BGN9034
1 EPA 300.0
06/03/2015 00:26
BGN9034
1 EPA 245.1
06/01/2015 11:04
ACPAYNE
1 EPA 200.7
06/04/2015 13:13
MHH7131
1 EPA 200.7
06/04/2015 13:13
MHH7131
1 EPA 200.7
06/04/2015 13:13
MHH7131
1 EPA 200.7
06/04/2015 13:13
MHH7131
1 EPA 200.7
06/02/2015 11:41
MHALL3
1 EPA 200.7
06/02/2015 11:41
MHALL3
1 EPA 200.7
06/02/2015 11:41
MHALL3
1 EPA 200.7
06/02/2015 11:41
MHALL3
1 EPA 200.7
06/02/2015 11:41
MHALL3
1 EPA 200.7
06/02/2015 11:41
MHALL3
1 EPA 200.7
06/02/2015 11:41
MHALL3
1 EPA 200.8
06/07/2015 03:37
SLS2560
1 EPA 200.8
06/07/2015 03:37
SLS2560
1 EPA 200.8
06/07/2015 03:37
SLS2560
1 EPA 200.8
06/07/2015 03:37
SLS2560
1 EPA 200.8
06/07/2015 03:37
SLS2560
1 EPA 200.8
06/07/2015 03:37
SLS2560
1 EPA 200.8
06/07/2015 03:37
SLS2560
1 EPA 200.8
06/07/2015 03:37
SLS2560
1 EPA 200.8
06/07/2015 03:37
SLS2560
1 EPA 200.8
06/07/2015 03:37
SLS2560
1 EPA 200.8
06/07/2015 03:37
SLS2560
1 EPA 200.8
06/07/2015 03:37
SLS2560
1 EPA 200.8
06/07/2015 03:37
SLS2560
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4) Complete Vendor Method V_SHEALY

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050770
Site: Equipment Blank
Collection Date: 28 -May -15 8:26 AM
Analyte Result Units Qualifiers RDL DF
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L 25 1
Total Carbon
Sample #: 2015016471
Matrix: GW—WW
Analytical Lab
Page 22 of 71
Method Analysis Date/Time Analyst
Vendor Method
V_ELE1
SM2540C 06/02/201511:59 AGIBBS5
TOC 0.139 mg/L 0.1 1 SM5310C/EPA9060A 06/05/201511:47 TJA7067
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 06/03/2015 09:00 AGIBBS5

M1
Analytical Lab
Page 23 of 71
Element One Inc.
6319-D Carolina Beach Rd.
Wilmington, NC 28412
Phone: [phone]
Fax: [phone]
el lab@el lab com
*Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits.
Ken Sith, Laboratory Director
24898 Duke Report Packet Compiled by
NC Certifications: DW 37788 and DWQ DENR 604
�ntOne
REPORT OF ANALYSES
Duke Energy
June 9, 2015
Laboratory Services
Client Project Name
AB GW
Assessment water (wells)
13339 Hagers Ferry Road Bid. MG03A
Client Project Number J15050770
Huntersville, NC 28078
PO Number
Sample Matrix GW WW
Sample Type Grab
Date Received
05/29/2015
Date Analyzed 06/01/2015
Method
SM 4500 S2_ D
Time Received
1645
Delivered by FedEx
Received by
LLB
eOne ID Duke Energy ID
Parameter
Result Unit
Dil
DL Date
Time
Sampled
Sampled
24898-1 GW -01
Sulfide
< 0.1 mg/L
1
0.1 05/28/15
0924
24898-2 MW -16A
Sulfide
< 0.1 mg/L
1
0.1 05/28/15
1042
24898-3 MW -05 BR
Sulfide
< 0.1 mg/L
1
0.1 05/28/15
0921
24898-4 CB -09 BR
Sulfide
< 0.1 mg/L
1
0.1 05/28/15
1332
24898-5* CB -09 SL
Sulfide
< 0.2 mg/L
2
0.1 05/28/15
1111
24898-6 MW -16 BR
Sulfide
0.299 mg/L
1
0.1 05/28/15
1231
24898-7 MW -18 BR
Sulfide
< 0.1 mg/L
1
0.1 05/28/15
1415
24898-8 MW -18D
Sulfide
0.200 mg/L
1
0.1 05/28/15
1336
*Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits.
Ken Sith, Laboratory Director
24898 Duke Report Packet Compiled by
NC Certifications: DW 37788 and DWQ DENR 604

Duke Energy
Laboratory Services
13339 Hagers Ferry Road Bid. MG03A
Huntersville, NC 28078
Sample Matrix GW WW Sal
Date Analyzed 06/01/2015 Me
Delivered by FedEx
eOne ID Duke Energy ID
24898-9 Equipment Blank
Analytical Lab
Page 24 of 71
Element One Inc.
6319-D Carolina Beach Rd.
Wilmington, IAC 284112
Phone: [phone]
Fax: [phone]
[e-mail]
REPORT OF ANALYSES
June 9, 2015
Client Project Name AB GW Assessment water (wells)
Client Project Number J15050770
PO Number
iple Type Grab Date Received 05/29/2015
hod SM 4500 S2- D Time Received 1645
Parameter Result Unit Dil
Received by LLB
DL Date Time
Sampled Sampled
Sulfide < 0.1 mg/L 1 0.1 05/28/15 0826
Ken S ith, La oratory Director
24898 Duke Report Packet Compiled by�A-5
NC Certifications: DW 37788 and DWQ DENR 604

Analytical Lab
Page 25 of 71
PIZ
.. ............... ....
......... ... ......... ...
V
i7 i
O
Om
LLI
to
OURIU00 9 moi
T
fit
6,�'
2
WE
PeAlOSSIO
P"10"IO
molaq
-6 0 i
no
Ca
gas) 918;OW
0
Mins
'19046A A
OIUUCqAg*
'*wUQqjvDm
ILL:
-%BJIIN '001
0
a
E
4jv*qS-A (S/
wit
%ni
SCU'S&L
qiuo
dwoo
X
Analytical Lab
Page 25 of 71
PIZ
.. ............... ....
......... ... ......... ...
V
i7 i

eDernentOne SAMPLE SUBMISSION FORM
TAT 7 BD
Hold Time Expiration 06.04.15 @ 0826
Client: Duke Energy
LIMS No J15050770
Project ID Asheville
Analytical Lab
Lab ID" OY4898
Analysis Due Date 06.03.15
Report Due Date 06.09.15
Date Rec:
05.29.15
Time Rec:
0445
Rec By
LLB
H >9 a No Tem 5 6°C Yes No Ref. Method:
If No, Record If No, Record SM4500 S2 D
Sample Identifir_afinn R rt%11 ,rfinn Infnrm,m4i^n
Lab ID
Client ID
Collection Date
Collection Time
An I sis Requested
1
GW -01 D
05/28/15
0924
Su fide
2
MW -16A
05/28/15
_
1042
u i
3
MW -05 BR 05/28/15
0921
4
CB -09 BR
05/28/15
1332
Ifide
5
CB -09 SL
05/28/15
1111
Ifi
6
MW -16 BR
05/28/15
1231
Ifid
7
MW -18 BR
05/28/15
1415
ulfide
8
MW -18D
05/28/15
1336
fide
9
Equipment
Blank 05/28/15
0826ulfid
NOTE for
Sulfide
The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected
at 100 pg/L spike the sample to render the final spike concentration at — 500 pg/L
Lab Communications
All AB Groundwater Assessment jobs need a R oof 0.1
SS Page 1 of 1 Prep By / DateJV\
SS by Labeled By / Date
6/1/201 10:38:48 AM ID Verification By /Dat Kam l l

Analytical Lab
Page 27 of 71
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTIONLIMIT ',u
1.000
CLIENT: Duke
SPK LEVELLuM
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
24894 / 895 / 896 / 897 / 898 / 899
6/1/15 Na2S•9H2O Lot #
10:00 40721
12:50
KAM
STD o.wo
ABS 0700 -- -- ---- - ---- --
Dew
0.000
0.098 0d00
0.300
0.233 j 0200 .333
0.442 0.100
0.654 00°000 zao 4.00 6.00
0.835 x
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: WC2-85-1
QC Std Lot: WC2-85-2
STD ABSORPTION
0W5
4 - -- ---
3.00 1040
10.00
X
10
10
Y
- -4�
Yzs4
1200
M, . ? ..M.,.Np
Sio e
0.083650549MEHAN
0.999259508
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
u /mL
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.0
Std. B. 1.00
0.100
0.9268
10
10
10
<
1.0
Std. B. 2.50
0.230
2.5255
10
10
10
0.253
101.02%
2.5
Std. B. 5.00
0.435
5.0466
10
10
10
0.505
100.93%
5.0
Std. B. 7.50
0.623
7.3586
10
10
10
0.736
98.11%
7.5
Std. B. 10.00
0.817
9.7444
10
10
10
0.974
97.44%
10.0
LRB
0.000
0.0000
10
10
10
<
0
LRB SPK
0.460
5.3541
10
10
10
0.535
107%
5.0
QC
0.454
5.2803
10
10
10
0.528
106%
5.0
24894-1
0.011
-0.1677
10
10
10
< 0.1
24894-1 s k
0.411
4.7515
10
10
10
0.475
95%
5.0
24894-2
0.000
0.0000
10
1 10
10
b.1
24894-2 dup
0.004
-0.2538
10
10
10
< 0.1
24894-2 s k
0.452
5.2557
10
10
10
0.526
105%
5.0
24894-3
0.012
-0.1554
10
10
10
<>0,1
24894-3 s k
0.409
4.7269
10
10
10
0.473
95%
5.0
24894-4
0.003
-0.2661
10
10
10
< 0,1
24894-4 s k
0.453
5.2680
10
10
10
0.527
105%
5.0
24894-5
0.002
-0.2784
10
10
10
0,1
24894-5 s k
0.449
5.2188
10
10
10
0.522
104%
5.0
24895-1
0.003
-0.2661
10
10
10
24895-1 spk
0.422
4.8867
10
10
10
0.489
98%
5.0
24895-2
0.114
1.0990
10
10
10
0.1 "1°0,
24895-2 s k
0.493
5.7599
10
10
10
0.576
93%
5.0
24895-3
0.002
-0.2784
10
10
10
< 0,=1
24895-3 spk
0.400
4.6162
10
10
10
0.462
92%
5.0
24895-4
0.080
0.6809
10
10
10
<
24895-4 s k
0.497 1
5.8091
10
10
10
0.581
116%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.456
5.3049
10
10
10
0.530
1 106% J,
5.0
'luumirrea rvr w/4/ ,fit,- Date: 06/01/15 1 By: (Print) I KAM 1(sign):
Page 1 of 5
7

Page 2 of 5
Analytical Lab
Page 28 of 71
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER ug/mL
DETECTION LIMIT u 1.000
CLIENT:
Duke
SPK LEVELLU-M 5
Lab ID#
24894 / 895 / 896 / 897 / 898 / 899
6/1/15
10:00
12:50
KAM _
MAX ALIQUOT 10.00
Na2S•9H2O Lot # STANDARD conc(ppm) X
40721 ICal Std Lot: W02-85-1 10
QC Std Lot: WC2-85-2 10
STD ABSORPTION Y
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
ug STD
SOLUTION
STD
0.100
°.
10
ABS °,ao
-- -
- e
92.68%
1.0
0.00
1.00
2.50
5.00
7.500.654
10.00
0.000 0wo
2.5255
10
10
---
y
0.098 °°°°
101.02%
�z
Std. B. 5.00
-z�
0.
0.233 o.zm
10
10
10
_2M
0.442 0.+00
5.0
Std. B. 7.50
0.623
7.3586
0000,00 zoo
0.835
am 6.00 em mqo ism
x
Page 2 of 5
Sloe
0.083650549
orrelation
0.999259508
SAMPLE
1. D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS LESS THAN
ug/mL % SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.0
Std. B. 1.00
0.100
0.9268
10
10
10
<
92.68%
1.0
Std. B. 2.50
0.230
2.5255
10
10
10
0.253
101.02%
2.5
Std. B. 5.00
0.435 1
5.0466
10
10
10
0.505
100.93%
5.0
Std. B. 7.50
0.623
7.3586
10
10
10
0.736
98.11%
7.5
Std. B. 10.00
0.817
9.7444
10
10
10
0.974
97.44%
10.0
LRB
0.000
0.0000
10
10
10
<
0
LRB SPK
0.460
5.3541
10
10
10
0.535
107%
5.0
QC
0.454
5.2803
10
10
10
0.528
106%
5.0
24895-5
0.003
-0.2661
10
10
10
- 0.: ,y
24895-5 s k
0.435
5.0466
10
10
10
0.505
101%
5.0
24895-6
0.005
-0.2415
10
10
10
< p,;►
24895-6 dup
0.002
-0.2784
10
10
10
< 0.1
24895-6 s k
0.431
4.9974
10
10
10
0.500
100%
5.0
24895-7
0.000
0.0000
10
10
10
<
24895-7 s k
0.347
3.9644
10
10
10
0.396
79%
5.0
24895-8
0.000
0.0000
10
10
10
24895-8 s k
0.446
5.1819
10
10
10
0.518
104%
5.0
24896-1
0.006
-0.2292
10
10
10
r
24896-1 s k
0.413
4.7761
10
10
10
0.478
96%
5.0
24896-2
0.000
0.0000
10
10
10
24896-2 s k.
0.435
5.0466
10
10
10
0.505
101%
5.0
24896-3
0.019
-0.0693
10
10
10
<,01
24896-3 spk
0.417
4.8252
10
10
10
0.483
97%
5.0
24896-4
• 0.003
-0.2661
10
10
10°0,
7
24896-4 s k
0.448
5.2065
10
10
10
0.521
104%
5.0
24896-5
0.004
-0.2538
10
10
10
Q:1
24896-5 s k
0.421
4.8744
10
10
10
0.487
97%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.456
5.3049
10
1 10
10
0.530
106%
5.0
Submitted for QA/QC- Date: 06/01/15
1 By: (Print)
KAM I (sign): c�
Page 2 of 5

METHOD:
SM 4500 S2- D
ELEMENT ASSAY:
Sulfide
CLIENT:
Duke
Lab ID#
24894 / 895 1896 / 897 / 898
Date:
6/1/15
Time Analysis Begun
10:00
Time Analysis Ended
12:50
Analyst:
KAM
x
y
ug STD
STD,
SOLUTION
ABS
0.00
0.000
1.00
0.098
2.50
0.233
5.00
0.442
750
0654
Analytical Lab
Page 29 of 71
ELEMENT ONE
pectrophotometer UNITS OF ANSWER
Wave Length 664
DETECTION LIMIT�
SPK LEVEL (ug)
MAX ALIQUOT
Na2S-9H2O Lot # STANDARD conc(pprn)
40721 Cal Std Lot: WC2-85-i
QC Std Lot: ft2-85-2
STD ABSORPTION
900
Dam
Sloe
0.083650549
0.=
07M
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
0400
SPIKE
LEVEL
#-Ir-4-42
0.000
0.0000
10
10
10
0�200
.2w
0.0
Std. B. 1.00
Ulm
0.9268
10
10
10
<
92.681/0
1.0
Y
so
600
7.
•
1 000 200 400 600 8.00 1000 1200
10.00 0.835 x
Page 3 of 5
Sloe
0.083650549
orrelation
0.990269508
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
LESS THAN
SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.0
Std. B. 1.00
0.100
0.9268
10
10
10
<
92.681/0
1.0
Std. B. 2.50
0.230
2.5255
10
10
10
0.253
101.02%
2.5
Std. B. 5.00
0.435
1 5.0466
10
10
10
0.505
100.93%
5.0
Std. B. 7.50
0.623
1 7.3586
10
10
10
0,736
98.11%
7.5
Std. B. 10.00
0.817
9.7444
10
10
10
0.974
97.44%
10.0
LRB
0.000
0.0000
10
10
10
<
0
LRB SPK
0.460
5.3541
10
10
10
0.535
107%
5.0
QC
0.454
5.2803
10
10
10
0.528
106%
5.0
24896-6
0.014
1 -0.1308
10
10
10
<
24896-6 s
0.297
3.3495
10
10
10
0.335
67%
5.0
24897-1
0.030
0.0660
10
10
10
24897-1spk
0.388
4.4686
10
10
10
0.447
89%
5.0
24897-2
0.007
-0.2169
10
10
10
<
24897-2 du p
0.001
-0.2907
10
10
10
< 0.1
24897-2 s
0.385
4.4317
10
10
10
0.443
1 89%
5.0
24897-3
0.017
1 -0.0939
10
10
10
1
24897-3 s
0.417
4.8252
10
10
10
0.483
97%
5.0
24897-4
0.005
-0.2415
10
10
1041.
<A�
24897-4 s
0.452
5,2557
10
10
10
0.526
105%
5.0
24898-1
0.005
-0.2415
10
10
10
24898-1 splk
0.403
4.6531
10
10
10
0.465
93%
5.0
24898-2
0.006
-0.2292
10
10
10
Ol
24898-2 s
0.431
4.9974
10
10
10
0.500
100%
5.0
24898-3
0.002
-0.2784
10
10
10
24898-3 s
0.428
4.9605
10
10
10
0.496
99%
5.0
24898-4
0.006
-0.2292
10
10
10
-77
77,71 77
24898-4 s
0.396
4.5670
10
10
10
0.457
91%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.456
5.3049
10
10
10
0.530
106%
Submitted for QA/QC-
Date: 06/01/15
By: (Print)
_,5,0__
Page 3 of 5

Analytical Lab
Page 30 of 71
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT
1.000
CLIENT: Duke
SPK LEVELLuM
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.500.654
10.00
24894 / 895 / 896 / 897 / 898 / 899
6/1/15 Na2S•9H2O Lot #
10:00 40721
12:50
KAM
Y
STD 0.e00
ABS - ----- - _ . -
0.000
0.098 0400"'
0.233 0,2. �
0.442 0+0,
°00000 2 4 6.00
0.835 x
MAX ALIQUOT
STANDARD conc(pp
Cal Std Lot: W
QC Std Lot: W
STD ABSORPTION
--
aw w.q0
_
)
2-85-1
2-85-2
0.M
10.00
X
1 10
1 10
I Y
;So
oo
12
orrelation
0.999259508
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS L SS THAN
ug/mL °o SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.0
Std. B. 1.00
0.100
0.9268
10
10
10
< 192.68%
1.0
Std. B. 2.50
0.230
2.5255
10
10
10
0.253
101.02%
2.5
Std. B. 5.00
0.435
5.0466
10
10
10
0.505 1100.93%
5.0
Std. B. 7.50
0.623
7.3586
10
10
10
0.736 98.11%
7.5
Std. B. 10.00
0.817
9.7444
10
10
10
0.974
97.44%
10.0
LRB
0.000
0.0000
10
10
10
<
0
LRB SPK
0.460
5.3541
10
10
10
0.535
107%
5.0
QC
0.454
5.2803
10
10
10
0.528
106%
5.0
24898-5
0.011
-0.1677
10
10
10
<
24898-5 s k
0.290
3.2634
10
10
10
0.326
65%
5.0
24898-6
0.268
2.9929
10
10
10
24898-6 s k
0.702
8.3301
10
1 10
10
0.833
107%
5.0
24898-7
0.003
-0.2661
10
10
10
-<0o,"
0o
24898-7 s k
0.413
4.7761
10
10
10
0.478
96%
5.0
24898-8
0.201
2.1689
10
10
10
0,217
24898-8 dup
0.187
1.9967
10
10
10
0.200
24898-8 s k
0.572
6.7314
10
10
10
0.673
95%
5.0
24898-9
0.000
0.0000
10
10
10
24898-9 s k
0.447
5.1942
10
10
10
0.519
104%
5.0
24899-1
0.013
-0.1431
10
10
10
<
24899-1 s k
0.307
3.4725
10
10
10
0.347
69%
5.0
24899-2
0.005
-0.2415
10
10
10
<01
24899-2 spk
0.417
4.8252
10
10
10
0.483
97%
5.0
24899-3
0.013
-0.1431
10
10
10
< Oti1 '
24899-3 s k
0.437
5.0712
10
10
10
0.507
101%
5.0
24899-4
0.001
-0.2907
10
1 10
10
24899-4 s k
0.447
5.1942
10
10
10
0.519
104%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.454 1
5.2803
10
10
10
0.528
106%
5
�aubmidea Tor ccAtwL;- Date: 06/01/15 By: (Print) KAM J(s�ign):
Page 4 of 5

ET
HOD : SM 4500 S2- D
ELEMENT ASSAY : Sulfide
Date:
X
I Y
Sloe
ALI in mL
TAKEN
10
10
10
10
10
10
10
10
ug STD
STD I
°.
o
ELUTION
ABS
°6m
0.00
0.000
1.00
0.098
024895-4
2.50
0.233
°.Z,°
5.00
0.442
°+�
7.50
0.654
10.00
0.835
5.5385
0.0000
ELEMENT ONE
Wave Length 664
Na2S•9H2O Lot #
40721
- --
2,00
4.00 -_. 8.00 8.00
x
Analytical Lab
Page 31 of 71
X
1 10
2 10
Y
I
+2°0
SAMPLE
I.D.
Std. B. 0.00
Std. B. 1.00
Std. B. 2.50
Std. B. 5.00
Std. B. 7.50
Std. B. 10.00
SPK
a .':. t _
SAIV ug PER A in mL PREP
ABS ALIQUOT ANALYZED VOL in mL
0.000 0.0000 10 10
0.100 0.9268 10 10
0.230 2.5255 10 10
0.435 5.0466 10 10
0.623 7.3586 10 10
10 10
0.000 0.0000 10 10
0.460 5.3541 10 10
Sloe
ALI in mL
TAKEN
10
10
10
10
10
10
10
10
0.083650549
RESULTS
u cmL
0.253
0.505
0.736
0.974
0.535
`LRB
Correlation
LESS THAN
%SPK REC
82.68%
0.999259508
SPIKE
VEL
LEVEL
0.0
1.0
H97.449/.
.0LRB
0QC
0.454
5.2803
10
10
10
0.528
024895-4
0.045
0.2504
10
10
524895-4
spk
24895-7
0.475
0.000
5.5385
0.0000
10
10
10
10
5
5
1.108
" x,.0,2
.0
24895-7 s k
0.458
5.3295
10
10
5
1.066
107%
5.0
24896-6
0.014
-0.1308
10
10
5
0 2,
24896-6 s k
0.392
4.5178
10
10
5
0.904
90%
5.0
24898-5
0.005
-0.2415
10
10
5-0
Z . .
24898-5 spk
24899-1
0.375
-0.001
4.3087
0.0000
10
10
10
10
5
5
0.862
86%
5.0
24899-1 s k
0.366
4.1981
10
10
5
0.840
84%
5.0
24899-1
0.001
-0.2907
10
10
2
0.51 . "
24899-1 s k
0.414
4.7884
10
10
2
2.394
96%
5.0
Blank
0.000
0.0000
10
10
10
QC
0.455
5.2926
10
1 10
10
0.529
106%
0
Submitted for QA/QC-
Date: 06/01/15
By: (Print)
I
KAM
(sign):
Page 5 of 5

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
Project Name: AB GW Assessment Water - Mayo
Project Number:J15050770
Lot Number:QE29062
Date Completed:06/05/2015
Grant Wilton
Project Manager
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
* QE29062*
Shealy Environmental Services, Inc. Page: 1 of 22
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SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: QE29062
Project Name: AB GW Assessment Water - Mayo
Project Number: J15050770
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page
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SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QE29062
Project Name: AB GW Assessment Water - Mayo
Project Number: J15050770
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
2015016462
Aqueous
05/28/2015 0924
05/29/2015
002
2015016463
Aqueous
05/28/20151042
05/29/2015
003
2015016464
Aqueous
05/28/2015 0921
05/29/2015
004
2015016465
Aqueous
05/28/20151332
05/29/2015
005
2015016466
Aqueous
05/28/20151111
05/29/2015
006
2015016467
Aqueous
05/28/20151231
05/29/2015
007
2015016468
Aqueous
05/28/20151415
05/29/2015
008
2015016469
Aqueous
05/28/20151336
05/29/2015
009
2015016471
Aqueous
05/28/2015 0826
05/29/2015
(9 samples)
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(17 detections)
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SHEALY ENVIRONMENTAL SERVICES,
INC.
Executive Summary
Duke Energy
Lot Number: QE29062
Project Name: AB GW Assessment Water - Mayo
Project Number: J15050770
Sample Sample ID
Matrix
Parameter Method Result Q
Units
Page
001
2015016462
Aqueous
Alkalinity SM 2320B-
13
mg/L
5
001
2015016462
Aqueous
Bicarbonate Alkalinity SM 2320B-
13
mg/L
5
003
2015016464
Aqueous
Alkalinity SM 2320B-
33
mg/L
9
003
2015016464
Aqueous
Bicarbonate Alkalinity SM 2320B-
33
mg/L
9
003
2015016464
Aqueous
Methane RSK - 175
32
ug/L
10
004
2015016465
Aqueous
Alkalinity SM 2320B-
54
mg/L
11
004
2015016465
Aqueous
Bicarbonate Alkalinity SM 2320B-
54
mg/L
11
005
2015016466
Aqueous
Alkalinity SM 2320B-
16
mg/L
13
005
2015016466
Aqueous
Bicarbonate Alkalinity SM 2320B-
16
mg/L
13
006
2015016467
Aqueous
Alkalinity SM 2320B-
26
mg/L
15
006
2015016467
Aqueous
Bicarbonate Alkalinity SM 2320B-
26
mg/L
15
006
2015016467
Aqueous
Methane RSK - 175
17
ug/L
16
007
2015016468
Aqueous
Alkalinity SM 2320B-
42
mg/L
17
007
2015016468
Aqueous
Bicarbonate Alkalinity SM 2320B-
42
mg/L
17
008
2015016469
Aqueous
Alkalinity SM 2320B-
62
mg/L
19
008
2015016469
Aqueous
Bicarbonate Alkalinity SM 2320B-
62
mg/L
19
008
2015016469
Aqueous
Methane RSK - 175
14
ug/L
20
(17 detections)
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE29062-001
Description: 2015016462 Matrix: Aqueous
Date Sampled:05/28/2015 0924 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050770
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/02/2015 1402
HMA 76305
1
(Bicarbonate ) SM 2320B-2011
1 06/02/2015 1402
HMA 06/02/2015 1402
1
(Carbonate Al) SM 2320B-2011
1 06/02/2015 1402
HMA 06/02/2015 1402
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
13
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
13
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QE29062-001
Description: 2015016462 Matrix: Aqueous
Date Sampled:05/28/2015 0924 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050770
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/02/2015 2156 JJG 76386
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE29062-002
Description: 2015016463 Matrix: Aqueous
Date Sampled:05/28/2015 1042 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050770
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/02/2015 1406
HMA 76305
1
(Bicarbonate ) SM 2320B-2011
1 06/02/2015 1406
HMA 06/02/2015 1406
1
(Carbonate Al) SM 2320B-2011
1 06/02/2015 1406
HMA 06/02/2015 1406
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 7 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE29062-002
Description: 2015016463 Matrix: Aqueous
Date Sampled:05/28/2015 1042 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050770
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/02/2015 2206 JJG 76386
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 8 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QE29062-003
Description: 2015016464 Matrix: Aqueous
Date Sampled:05/28/2015 0921 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050770
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/02/2015 1411
HMA 76305
1
(Bicarbonate ) SM 2320B-2011
1 06/02/2015 1411
HMA 06/02/2015 1411
1
(Carbonate Al) SM 2320B-2011
1 06/02/2015 1411
HMA 06/02/2015 1411
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 9 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
33
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
33
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 9 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE29062-003
Description: 2015016464 Matrix: Aqueous
Date Sampled:05/28/2015 0921 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050770
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/02/2015 2218 JJG 76386
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 32 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 10 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QE29062-004
Description: 2015016465 Matrix: Aqueous
Date Sampled:05/28/2015 1332 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050770
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/02/2015 1415
HMA 76305
1
(Bicarbonate ) SM 2320B-2011
1 06/02/2015 1415
HMA 06/02/2015 1415
1
(Carbonate Al) SM 2320B-2011
1 06/02/2015 1415
HMA 06/02/2015 1415
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 11 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
54
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
54
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 11 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE29062-004
Description: 2015016465 Matrix: Aqueous
Date Sampled:05/28/2015 1332 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050770
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/02/2015 2229 JJG 76386
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 12 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QE29062-005
Description: 2015016466 Matrix: Aqueous
Date Sampled:05/28/2015 1111 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050770
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/02/2015 1420
HMA 76305
1
(Bicarbonate ) SM 2320B-2011
1 06/02/2015 1420
HMA 06/02/2015 1420
1
(Carbonate Al) SM 2320B-2011
1 06/02/2015 1420
HMA 06/02/2015 1420
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 13 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
16
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
16
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 13 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE29062-005
Description: 2015016466 Matrix: Aqueous
Date Sampled:05/28/2015 1111 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050770
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/03/2015 1001 DCS 76437
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 14 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QE29062-006
Description: 2015016467 Matrix: Aqueous
Date Sampled:05/28/2015 1231 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050770
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/02/2015 1440
HMA 76305
1
(Bicarbonate ) SM 2320B-2011
1 06/02/2015 1440
HMA 06/02/2015 1440
1
(Carbonate Al) SM 2320B-2011
1 06/02/2015 1440
HMA 06/02/2015 1440
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 15 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
26
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
26
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 15 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE29062-006
Description: 2015016467 Matrix: Aqueous
Date Sampled:05/28/2015 1231 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050770
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/03/2015 1013 DCS 76437
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 17 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 16 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QE29062-007
Description: 2015016468 Matrix: Aqueous
Date Sampled:05/28/2015 1415 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050770
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/02/2015 1444
HMA 76305
1
(Bicarbonate ) SM 2320B-2011
1 06/02/2015 1444
HMA 06/02/2015 1444
1
(Carbonate Al) SM 2320B-2011
1 06/02/2015 1444
HMA 06/02/2015 1444
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 17 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
42
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
42
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 17 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE29062-007
Description: 2015016468 Matrix: Aqueous
Date Sampled:05/28/2015 1415 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050770
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/03/2015 1034 DCS 76437
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 18 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QE29062-008
Description: 2015016469 Matrix: Aqueous
Date Sampled:05/28/2015 1336 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050770
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/02/2015 1449
HMA 76305
1
(Bicarbonate ) SM 2320B-2011
1 06/02/2015 1449
HMA 06/02/2015 1449
1
(Carbonate Al) SM 2320B-2011
1 06/02/2015 1449
HMA 06/02/2015 1449
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 19 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
62
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
62
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 19 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE29062-008
Description: 2015016469 Matrix: Aqueous
Date Sampled:05/28/2015 1336 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050770
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/03/2015 1044 DCS 76437
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 14 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 20 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QE29062-009
Description: 2015016471 Matrix: Aqueous
Date Sampled:05/28/2015 0826 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050770
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 06/02/2015 1528
HMA 76308
1
(Bicarbonate ) SM 2320B-2011
1 06/02/2015 1528
HMA 06/02/2015 1528
1
(Carbonate Al) SM 2320B-2011
1 06/02/2015 1528
HMA 06/02/2015 1528
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 21 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 21 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE29062-009
Description: 2015016471 Matrix: Aqueous
Date Sampled:05/28/2015 0826 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050770
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/03/2015 1054 DCS 76437
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 22 of 22
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QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: QE29062
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - Ii
Sample ID: QQ76305-001 Matrix: Aqueous
Batch: 76305
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 06/02/20151220
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE29062
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - LCS
Sample ID: QQ76305-002 Matrix: Aqueous
Batch: 76305
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 93 1 93 90-110 06/02/20151225
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE29062
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MS
Sample ID: QE29062-008MS Matrix: Aqueous
Batch: 76305
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 62 100 140 1 80 70-130 06/02/20151454
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE29062
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MSD
Sample ID: QE29062-008MD Matrix: Aqueous
Batch: 76305
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Alkalinity 62 100 140 1 82 1.5 70-130 20 06/02/20151501
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE29062
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - Ii
Sample ID: QQ76308-001 Matrix: Aqueous
Batch: 76308
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 06/02/20151515
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE29062
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - LCS
Sample ID: QQ76308-002 Matrix: Aqueous
Batch: 76308
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 94 1 94 90-110 06/02/20151521
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE29062
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MS
Sample ID: QE29062-009MS Matrix: Aqueous
Batch: 76308
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity ND 100 92 1 92 70-130 06/02/20151534
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE29062
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MSD
Sample ID: QE29062-009MD Matrix: Aqueous
Batch: 76308
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Alkalinity ND 100 95 1 95 3.3 70-130 20 06/02/20151541
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE29062
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - MB
Sample ID: QQ76386-001 Matrix: Aqueous
Batch: 76386
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 06/02/20151616
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE29062
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCS
Sample ID: QQ76386-002 Matrix: Aqueous
Batch: 76386
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 150 160 1 107 70-130 06/02/20151533
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE29062
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCSD
Sample ID: QQ76386-003 Matrix: Aqueous
Batch: 76386
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 150 160 1 103 4.1 70-130 30 06/02/20151552
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE29062
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - MB
Sample ID: QQ76437-001 Matrix: Aqueous
Batch: 76437
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 06/03/2015 0943
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE29062
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCS
Sample ID: QQ76437-002 Matrix: Aqueous
Batch: 76437
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 150 170 1 114 70-130 06/03/2015 0911
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE29062
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCSD
Sample ID: QQ76437-003 Matrix: Aqueous
Batch: 76437
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 150 160 1 107 5.9 70-130 30 06/03/2015 0922
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE29062
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

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SHEALY ENVIRONMENTAL SERVICES, INC.
Shealy Enwironmencst Servicz% lnc,
Dmur n" Number: F-ADil16
Revi%T,pn Mpmbri: 17
I .a;a i P 1
Rspkees DaLe: 11107114
ftkttive Dhle: odrAV13
Sample eceipt Checklist (SRC)
1C1ie11r: 1 C_c let• Tnsp"_Icd byMate; x - 'ts lot ft: _�
Means of lece,ipt:
0 SESI 13
❑ UP ❑ Fedi x ❑ Airborne ExN [2-16t:hcr
Yes ❑ No
1. We
ac [E)dv seals resent an the cooler?
Yek El I No F I
ISA 2, If+distad r se�were prosent, were they lotaci irn{l unbFnkeT[?
Gaoler IDADri,ginal teruperature upon r ipt�T3edved (correcled) temperarure upon m ipt:
1 J _ .!r f _�C 84.E ,r a Xc
Method; ❑ Temperature lank [>Againsc nottles IR Gun 1[],_jF__ YR Gun Correction Factor- C- C3 °U
Hathod of coolant: FT WL:(Icy ❑ Blue ice U T} Ice ® Nune
3. if temperature of any cooler �xceodzd &O'C_ was 1-l'Gje4t Ulsallager notified?
Yes ❑ No ❑
h 4 FNI no ied by SRC, phone, note (circle 17e), alter:
(Fora: lers -received aia c4illa nertial courier, Ms arc to be notified
imm tel r.
Y_cs ❑ No ❑
NA 4. T the rumeraial caurfer'n aoAin s attached tl9IS
Yes No ❑
5. 'V CTMC er m d v procedures relin uishtWirc:tived follrwed?
-Yes ❑ NQ ❑
NA Sa Were samples veli. uish it b client to cr,an=crcaal courier's
sires _No
Ci. Wire sample IDs listed oo the COC?
No ❑
7. Were. sample TT)s listed on all sample containers?
`.des No
Fi_ wazi oullcztiion date- time listed ran the COC?
yet M ❑
9. Was colllec:lian date & time listed on all sam le containors?
No
10, Did all( container label infotivalion III, date, tilz,le a ee with the. C`nCl
No ❑
11. Were t sts to be erf'omted listed on the COC?
Nn ❑
12_ laid ai sam ics arriuc in the rn er tttairirrs for each test?
Yes No ❑
13. Did al 11 containers arrive in good condition unbroken, lids on, etc-)?
Yes No ❑
lrl_ Was adEqUate Barn le VOlumC available?
15_ Were. al l sannplcs received within 'r'z the holding ti rine oT 4$ hours, whichever
comes first
Yes ❑ No ®'
16, Wcre an -.arn les cantainerg ini ?
Yes © No
17, Were 1h6rt±. any excess samples nal listed on C ?
Y&% ❑ No ❑
NA ❑ I& Were bubbles resent >` ea -size" 1 a"oor Clmm in diamctea in any V 0A vials?
Yes ❑ No Q
KA & 19. Were all s les received at a PHof <2?
Yes ❑ No ❑
NA 20. Wurc c anile atld/w sulfide sarn pies reucived at a pH >12?
'ices ❑ No ❑
NA[ 21" me applf cable NH3,1TKN+oyanideiphenol (-LD.2mg,+'L) samples free of
reside chlwine7
Yes ❑ No ❑
K 2'.2.4rere llcction to erasures rfaeumente 1]re iho UGC for N seat l+rs?
Yes ❑ Net ❑
NA uT, 23.Were client romarksAcgaesm (P.e. requested dilutions, MS/MS II designations,
etc.,, corrictly tral; ribed Cream the Cot„ into ft commellt Section in LYMS9
Yes Lj I No
Was tha quote number used taken from tie COntainer label?
Sample Preservation ('Must be completed for any samples) i?carr=rtly preserved or %ViLh headspace)
Samples -
r,. were received incorrectly prc.A-erved and were adjul w
accwditr I sin sample
r4mAviag with 01§ 04,E0.i,HCl a0 using Sly ft
acn lei
were received with bubble, >6 mm 1n diameter,
Sate J s
werIZ retseiVEd with TRC >0. X11- (if #21 i.s I`Ia i
Drinking Water
FrOjOct Samples) til-) verified tp be > 2 by ]date:
Samples)
were not r6ceived at a PH + f -�2 and wcrr. adjusted accorrdingjy rtsirrg Sit,-#
Sample label& applied by:_ Vcrifie.d h ! Date..
QkIDLllg f1r5:
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

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