NC0000396_J15050692report_20150823

+ DUKE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Order Number: J15050692
Project Name: ASHEVILLE - AB GW ASSESSMENT WATER
Customer Name(s): Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker
Customer Address: 200 CP and L Drive
Arden, NC 28704
Lab Contact: Mary Ann Ogle Phone: [phone]
/ 0 Mary Ann Ogle
Report Authorized B °� b 2015.06.13 10:39:36
Re
p y �c7i.. -04'00' Date:
(Signature)
Mary Ann Ogle
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
6/12/2015
Page 1 of 50
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
Collected By
Sample Description
2015016079
ASHEVILLE
26 -May -15 10:32 AM
illegible
ABMW-04
2015016080
ASHEVILLE
26 -May -15 12:54 PM
illegible
ABMW-04D
2015016081
ASHEVILLE
26 -May -15 10:35 AM
illegible
ABMW-05S
2015016082
ASHEVILLE
26 -May -15 1:35 PM
illegible
ABMW-04D-DUP
2015016083
ASHEVILLE
26 -May -15 2:18 PM
illegible
ABMW-05D
2015016084
ASHEVILLE
26 -May -15 2:15 PM
illegible
Equipment Blank
2015016085
ASHEVILLE
26 -May -15 2:15 PM
illegible
Filter Blank
7 Total Samples
Page 2 of 50

Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes F./] No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
U Job Summary Report
❑ Sample Identification
n Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Page 3 of 50
Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
66 Chain of Custody
[I/0] Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 6/12/2015

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050692
Site: ABMW-04
Collection Date: 26 -May -15 10:32 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
06/01/2015 09:23
Vendor Parameter
Complete
EPA 300.0
06/01/2015 09:23
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
0.073
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
13
mg/L
1
Sulfate
270
mg/L
5
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/28/2015 12:21
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/28/2015 12:21
MHALL3
Aluminum (AI)
0.045
mg/L
0.005
Barium (Ba)
0.192
mg/L
0.005
Boron (B)
3.62
mg/L
0.05
Iron (Fe)
0.202
mg/L
0.01
Manganese (Mn)
0.121
mg/L
0.005
Strontium (Sr)
3.80
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/27/2015 15:31
MHALL3
Calcium (Ca)
129
mg/L
0.1
Magnesium (Mg)
67.4
mg/L
0.005
Potassium (K)
20.8
mg/L
0.1
Sodium (Na)
49.6
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.488
mg/L
0.005
Barium (Ba)
0.200
mg/L
0.005
Boron (B)
3.66
mg/L
0.05
Iron (Fe)
0.400
mg/L
0.01
Manganese (Mn)
0.117
mg/L
0.005
Strontium (Sr)
3.71
mg/L
0.005
Zinc (Zn)
0.010
mg/L
0.005
Sample #: 2015016079
Matrix: GW -WW
Page 4 of 50
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/01/2015 13:12
LSTARL1
10
EPA 300.0
06/01/2015 09:23
BGN9034
50
EPA 300.0
06/01/2015 09:23
BGN9034
1
EPA 245.1
05/29/2015 12:39
ACPAYNE
1
EPA 245.1
06/01/2015 15:38
ACPAYNE
1
EPA 200.7
05/28/2015 12:21
MHALL3
1
EPA 200.7
05/28/2015 12:21
MHALL3
1
EPA 200.7
05/28/2015 12:21
MHALL3
1
EPA 200.7
05/28/2015 12:21
MHALL3
1
EPA 200.7
05/28/2015 12:21
MHALL3
1
EPA 200.7
05/28/2015 12:21
MHALL3
1
EPA 200.7
05/28/2015 12:21
MHALL3
10
EPA 200.7
06/01/2015 10:27
MHALL3
1
EPA 200.7
06/01/2015 10:27
MHALL3
1
EPA 200.7
06/01/2015 10:27
MHALL3
1
EPA 200.7
06/01/2015 10:27
MHALL3
1
EPA 200.7
05/27/2015 15:31
MHALL3
1
EPA 200.7
05/27/2015 15:31
MHALL3
1
EPA 200.7
05/27/2015 15:31
MHALL3
1
EPA 200.7
05/27/2015 15:31
MHALL3
1
EPA 200.7
05/27/2015 15:31
MHALL3
1
EPA 200.7
05/27/2015 15:31
MHALL3
1
EPA 200.7
05/27/2015 15:31
MHALL3

Certificate of Laboratory Analysis Page 5 of 50
This report shall not be reproduced, except in full.
Order # J15050692
Site: ABMW-04
Sample #: 2015016079
Collection Date: 26 -May -15 10:32
AM
Matrix: GW -WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
DISSOLVED METALS BY ICP -MS
Antimony (Sb)
2.25
ug/L
1
1
EPA 200.8
06/05/2015 15:58
JAHERMA
Arsenic (As)
660
ug/L
10
10
EPA 200.8
06/05/2015 15:58
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
06/05/2015 15:58
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
06/05/2015 15:58
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
06/05/2015 15:58
JAHERMA
Cobalt (Co)
<1
ug/L
1
1
EPA 200.8
06/05/2015 15:58
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
06/05/2015 15:58
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
06/05/2015 15:58
JAHERMA
Molybdenum (Mo)
581
ug/L
10
10
EPA 200.8
06/05/2015 15:58
JAHERMA
Nickel (Ni)
<1
ug/L
1
1
EPA 200.8
06/05/2015 15:58
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
06/05/2015 15:58
JAHERMA
Thallium (TI) Low Level
0.568
ug/L
0.2
1
EPA 200.8
06/05/2015 15:58
JAHERMA
Vanadium (V) Low Level
20.9
ug/L
0.3
1
EPA 200.8
06/05/2015 15:58
JAHERMA
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
2.49
ug/L
1
1
EPA 200.8
06/09/2015 13:59
JAHERMA
Arsenic (As)
780
ug/L
10
10
EPA 200.8
06/09/2015 13:59
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
06/09/2015 13:59
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
06/09/2015 13:59
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
06/09/2015 13:59
JAHERMA
Cobalt (Co)
<1
ug/L
1
1
EPA 200.8
06/09/2015 13:59
JAHERMA
Copper (Cu)
1.04
ug/L
1
1
EPA 200.8
06/09/2015 13:59
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
06/09/2015 13:59
JAHERMA
Molybdenum (Mo)
663
ug/L
10
10
EPA 200.8
06/09/2015 13:59
JAHERMA
Nickel (Ni)
1.11
ug/L
1
1
EPA 200.8
06/09/2015 13:59
JAHERMA
Selenium (Se)
1.09
ug/L
1
1
EPA 200.8
06/09/2015 13:59
JAHERMA
Thallium (TI) Low Level
1.03
ug/L
0.2
1
EPA 200.8
06/09/2015 13:59
JAHERMA
Vanadium (V) Low Level
26.9
ug/L
0.3
1
EPA 200.8
06/09/2015 13:59
JAHERMA
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
850
mg/L
25
1
SM2540C
05/28/201514:15
AGIBBS5
Total Carbon
TOC
0.650
mg/L
0.1
1
SM5310C/EPA9060A
06/03/201516:49
TJA7067
TOTAL SUSPENDED SOLIDS
TSS
11
mg/L
5
1
SM2540D
05/28/2015 08:28
AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050692
Site: ABMW-04D
Collection Date: 26 -May -15 12:54 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
06/01/2015 09:59
Vendor Parameter
Complete
EPA 300.0
06/01/2015 09:59
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
0.016
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
12
mg/L
1
Sulfate
110
mg/L
2.5
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/28/2015 12:24
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/28/2015 12:24
MHALL3
Aluminum (AI)
0.021
mg/L
0.005
Barium (Ba)
0.083
mg/L
0.005
Boron (B)
1.09
mg/L
0.05
Iron (Fe)
5.55
mg/L
0.01
Manganese (Mn)
5.79
mg/L
0.005
Strontium (Sr)
0.180
mg/L
0.005
Zinc (Zn)
0.024
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/27/2015 15:43
MHALL3
Calcium (Ca)
34.6
mg/L
0.01
Magnesium (Mg)
13.9
mg/L
0.005
Potassium (K)
1.95
mg/L
0.1
Sodium (Na)
5.19
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.315
mg/L
0.005
Barium (Ba)
0.085
mg/L
0.005
Boron (B)
1.08
mg/L
0.05
Iron (Fe)
6.36
mg/L
0.01
Manganese (Mn)
5.82
mg/L
0.005
Strontium (Sr)
0.176
mg/L
0.005
Zinc (Zn)
0.022
mg/L
0.005
Sample #: 2015016080
Matrix: GW -WW
Page 6 of 50
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/01/2015 13:16
LSTARL1
10
EPA 300.0
06/01/2015 09:59
BGN9034
25
EPA 300.0
06/01/2015 09:59
BGN9034
1
EPA 245.1
05/29/2015 12:42
ACPAYNE
1
EPA 245.1
06/01/2015 15:41
ACPAYNE
1
EPA 200.7
05/28/2015 12:24
MHALL3
1
EPA 200.7
05/28/2015 12:24
MHALL3
1
EPA 200.7
05/28/2015 12:24
MHALL3
1
EPA 200.7
05/28/2015 12:24
MHALL3
1
EPA 200.7
05/28/2015 12:24
MHALL3
1
EPA 200.7
05/28/2015 12:24
MHALL3
1
EPA 200.7
05/28/2015 12:24
MHALL3
1
EPA 200.7
06/01/2015 10:55
MHALL3
1
EPA 200.7
06/01/2015 10:55
MHALL3
1
EPA 200.7
06/01/2015 10:55
MHALL3
1
EPA 200.7
06/01/2015 10:55
MHALL3
1
EPA 200.7
05/27/2015 15:43
MHALL3
1
EPA 200.7
05/27/2015 15:43
MHALL3
1
EPA 200.7
05/27/2015 15:43
MHALL3
1
EPA 200.7
05/27/2015 15:43
MHALL3
1
EPA 200.7
05/27/2015 15:43
MHALL3
1
EPA 200.7
05/27/2015 15:43
MHALL3
1
EPA 200.7
05/27/2015 15:43
MHALL3

Certificate of Laboratory Analysis Page 7 of 50
This report shall not be reproduced, except in full.
Order # J15050692
Site: ABMW-04D
Sample #: 2015016080
Collection Date: 26 -May -15 12:54
PM
Matrix: GW -WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
DISSOLVED METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
06/05/2015 16:02
JAHERMA
Arsenic (As)
2.36
ug/L
1
1
EPA 200.8
06/05/2015 16:02
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
06/05/2015 16:02
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
06/05/2015 16:02
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
06/05/2015 16:02
JAHERMA
Cobalt (Co)
55.7
ug/L
1
1
EPA 200.8
06/05/2015 16:02
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
06/05/2015 16:02
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
06/05/2015 16:02
JAHERMA
Molybdenum (Mo)
1.16
ug/L
1
1
EPA 200.8
06/05/2015 16:02
JAHERMA
Nickel (Ni)
2.20
ug/L
1
1
EPA 200.8
06/05/2015 16:02
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
06/05/2015 16:02
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
06/05/2015 16:02
JAHERMA
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
06/05/2015 16:02
JAHERMA
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
<1
ug/L
1
1
EPA 200.8
06/09/2015 13:45
JAHERMA
Arsenic (As)
2.68
ug/L
1
1
EPA 200.8
06/09/2015 13:45
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
06/09/2015 13:45
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
06/09/2015 13:45
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
06/09/2015 13:45
JAHERMA
Cobalt (Co)
54.2
ug/L
1
1
EPA 200.8
06/09/2015 13:45
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
06/09/2015 13:45
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
06/09/2015 13:45
JAHERMA
Molybdenum (Mo)
1.01
ug/L
1
1
EPA 200.8
06/09/2015 13:45
JAHERMA
Nickel (Ni)
2.25
ug/L
1
1
EPA 200.8
06/09/2015 13:45
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
06/09/2015 13:45
JAHERMA
Thallium (TI) Low Level
0.319
ug/L
0.2
1
EPA 200.8
06/09/2015 13:45
JAHERMA
Vanadium (V) Low Level
0.564
ug/L
0.3
1
EPA 200.8
06/09/2015 13:45
JAHERMA
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
250
mg/L
25
1
SM2540C
05/28/201514:15
AGIBBS5
Total Carbon
TOC
0.549
mg/L
0.1
1
SM5310C/EPA9060A
06/03/201516:49
TJA7067
TOTAL SUSPENDED SOLIDS
TSS
6.0
mg/L
5
1
SM2540D
05/28/2015 08:28
AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050692
Site: ABMW-05S
Collection Date: 26 -May -15 10:35 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
05/29/2015 20:58
Vendor Parameter
Complete
EPA 300.0
05/29/2015 20:58
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
0.017
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
5.2
mg/L
0.1
Sulfate
20
mg/L
1
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/28/2015 12:28
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/28/2015 12:28
MHALL3
Aluminum (AI)
0.012
mg/L
0.005
Barium (Ba)
0.020
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
4.08
mg/L
0.01
Manganese (Mn)
0.521
mg/L
0.005
Strontium (Sr)
0.083
mg/L
0.005
Zinc (Zn)
0.008
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/27/2015 15:47
MHALL3
Calcium (Ca)
12.6
mg/L
0.01
Magnesium (Mg)
12.6
mg/L
0.005
Potassium (K)
1.29
mg/L
0.1
Sodium (Na)
6.34
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.021
mg/L
0.005
Barium (Ba)
0.021
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
4.80
mg/L
0.01
Manganese (Mn)
0.537
mg/L
0.005
Strontium (Sr)
0.083
mg/L
0.005
Zinc (Zn)
0.006
mg/L
0.005
Sample #: 2015016081
Matrix: GW -WW
Page 8 of 50
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/01/2015 13:17
LSTARL1
1
EPA 300.0
05/29/2015 20:58
BGN9034
10
EPA 300.0
05/29/2015 20:58
BGN9034
1
EPA 245.1
05/29/2015 12:44
ACPAYNE
1
EPA 245.1
06/01/2015 15:43
ACPAYNE
1
EPA 200.7
05/28/2015 12:28
MHALL3
1
EPA 200.7
05/28/2015 12:28
MHALL3
1
EPA 200.7
05/28/2015 12:28
MHALL3
1
EPA 200.7
05/28/2015 12:28
MHALL3
1
EPA 200.7
05/28/2015 12:28
MHALL3
1
EPA 200.7
05/28/2015 12:28
MHALL3
1
EPA 200.7
05/28/2015 12:28
MHALL3
1
EPA 200.7
06/01/2015 10:59
MHALL3
1
EPA 200.7
06/01/2015 10:59
MHALL3
1
EPA 200.7
06/01/2015 10:59
MHALL3
1
EPA 200.7
06/01/2015 10:59
MHALL3
1
EPA 200.7
05/27/2015 15:47
MHALL3
1
EPA 200.7
05/27/2015 15:47
MHALL3
1
EPA 200.7
05/27/2015 15:47
MHALL3
1
EPA 200.7
05/27/2015 15:47
MHALL3
1
EPA 200.7
05/27/2015 15:47
MHALL3
1
EPA 200.7
05/27/2015 15:47
MHALL3
1
EPA 200.7
05/27/2015 15:47
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050692
Site: ABMW-05S
Collection Date: 26 -May -15 10:35 AM
Analyte
Result
DISSOLVED METALS BY ICP -MS
Sample #:
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
16.1
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
3.33
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
16.7
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
3.37
Selenium (Se)
< 1
Thallium (TI) Low Level
0.309
Vanadium (V) Low Level
< 0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
ug/L
TDS
130
Total Carbon
06/05/2015 16:07
TOC
0.698
TOTAL SUSPENDED SOLIDS
1
TSS
< 5
Page 9 of 50
ug/L
1
1
Sample #:
2015016081
JAHERMA
ug/L
1
1
Matrix:
GW -WW
JAHERMA
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
ug/L
1
1
EPA 200.8
06/05/2015 16:07
JAHERMA
ug/L
1
1
EPA 200.8
06/05/2015 16:07
JAHERMA
ug/L
1
1
EPA 200.8
06/05/2015 16:07
JAHERMA
ug/L
1
1
EPA 200.8
06/05/2015 16:07
JAHERMA
ug/L
1
1
EPA 200.8
06/05/2015 16:07
JAHERMA
ug/L
1
1
EPA 200.8
06/05/2015 16:07
JAHERMA
ug/L
1
1
EPA 200.8
06/05/2015 16:07
JAHERMA
ug/L
1
1
EPA 200.8
06/05/2015 16:07
JAHERMA
ug/L
1
1
EPA 200.8
06/05/2015 16:07
JAHERMA
ug/L
1
1
EPA 200.8
06/05/2015 16:07
JAHERMA
ug/L
1
1
EPA 200.8
06/05/2015 16:07
JAHERMA
ug/L
0.2
1
EPA 200.8
06/05/2015 16:07
JAHERMA
ug/L
0.3
1
EPA 200.8
06/05/2015 16:07
JAHERMA
ug/L
1
1
EPA 200.8
06/09/2015 14:04
JAHERMA
ug/L
1
1
EPA 200.8
06/09/2015 14:04
JAHERMA
ug/L
1
1
EPA 200.8
06/09/2015 14:04
JAHERMA
ug/L
1
1
EPA 200.8
06/09/2015 14:04
JAHERMA
ug/L
1
1
EPA 200.8
06/09/2015 14:04
JAHERMA
ug/L
1
1
EPA 200.8
06/09/2015 14:04
JAHERMA
ug/L
1
1
EPA 200.8
06/09/2015 14:04
JAHERMA
ug/L
1
1
EPA 200.8
06/09/2015 14:04
JAHERMA
ug/L
1
1
EPA 200.8
06/09/2015 14:04
JAHERMA
ug/L
1
1
EPA 200.8
06/09/2015 14:04
JAHERMA
ug/L
1
1
EPA 200.8
06/09/2015 14:04
JAHERMA
ug/L
0.2
1
EPA 200.8
06/09/2015 14:04
JAHERMA
ug/L
0.3
1
EPA 200.8
06/09/2015 14:04
JAHERMA
Vendor Method
V_SHEALY
Vendor Method
V_ELE1
mg/L
25
1
SM2540C
05/28/201514:15
AGIBBS5
mg/L
0.1
1
SM5310C/EPA9060A
06/03/201516:49
TJA7067
mg/L
5
1
SM2540D
05/28/2015 08:28
AGIBBS5

Certificate of Laboratory Analysis Page 10 of 50
This report shall not be reproduced, except in full.
Order # J15050692
Site: ABMW-04D-DUP
Collection Date: 26 -May -15 1:35 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
06/02/2015 08:53
Vendor Parameter
Complete
EPA 300.0
06/02/2015 08:53
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
0.037
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
13
mg/L
1
Sulfate
110
mg/L
2.5
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/28/2015 12:40
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/28/2015 12:40
MHALL3
Aluminum (AI)
0.021
mg/L
0.005
Barium (Ba)
0.084
mg/L
0.005
Boron (B)
1.07
mg/L
0.05
Iron (Fe)
5.68
mg/L
0.01
Manganese (Mn)
5.79
mg/L
0.005
Strontium (Sr)
0.175
mg/L
0.005
Zinc (Zn)
0.017
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/27/2015 15:50
MHALL3
Calcium (Ca)
34.9
mg/L
0.01
Magnesium (Mg)
13.9
mg/L
0.005
Potassium (K)
1.95
mg/L
0.1
Sodium (Na)
5.26
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.273
mg/L
0.005
Barium (Ba)
0.084
mg/L
0.005
Boron (B)
1.08
mg/L
0.05
Iron (Fe)
6.29
mg/L
0.01
Manganese (Mn)
5.79
mg/L
0.005
Strontium (Sr)
0.179
mg/L
0.005
Zinc (Zn)
0.026
mg/L
0.005
Sample #: 2015016082
Matrix: GW -WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/01/2015 13:18
LSTARL1
10
EPA 300.0
06/02/2015 08:53
BGN9034
25
EPA 300.0
06/02/2015 08:53
BGN9034
1
EPA 245.1
05/29/2015 12:46
ACPAYNE
1
EPA 245.1
06/01/2015 15:45
ACPAYNE
1
EPA 200.7
05/28/2015 12:40
MHALL3
1
EPA 200.7
05/28/2015 12:40
MHALL3
1
EPA 200.7
05/28/2015 12:40
MHALL3
1
EPA 200.7
05/28/2015 12:40
MHALL3
1
EPA 200.7
05/28/2015 12:40
MHALL3
1
EPA 200.7
05/28/2015 12:40
MHALL3
1
EPA 200.7
05/28/2015 12:40
MHALL3
1
EPA 200.7
06/01/2015 11:12
MHALL3
1
EPA 200.7
06/01/2015 11:12
MHALL3
1
EPA 200.7
06/01/2015 11:12
MHALL3
1
EPA 200.7
06/01/2015 11:12
MHALL3
1
EPA 200.7
05/27/2015 15:50
MHALL3
1
EPA 200.7
05/27/2015 15:50
MHALL3
1
EPA 200.7
05/27/2015 15:50
MHALL3
1
EPA 200.7
05/27/2015 15:50
MHALL3
1
EPA 200.7
05/27/2015 15:50
MHALL3
1
EPA 200.7
05/27/2015 15:50
MHALL3
1
EPA 200.7
05/27/2015 15:50
MHALL3

Certificate of Laboratory Analysis Page 11 of 50
This report shall not be reproduced, except in full.
Order # J15050692
Site: ABMW-04D-DUP
Sample #: 2015016082
Collection Date: 26 -May -15 1:35 PM
Matrix: GW -WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
DISSOLVED METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
06/05/2015 16:11
JAHERMA
Arsenic (As)
1.76
ug/L
1
1
EPA 200.8
06/05/2015 16:11
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
06/05/2015 16:11
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
06/05/2015 16:11
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
06/05/2015 16:11
JAHERMA
Cobalt (Co)
53.8
ug/L
1
1
EPA 200.8
06/05/2015 16:11
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
06/05/2015 16:11
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
06/05/2015 16:11
JAHERMA
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
06/05/2015 16:11
JAHERMA
Nickel (Ni)
2.05
ug/L
1
1
EPA 200.8
06/05/2015 16:11
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
06/05/2015 16:11
JAHERMA
Thallium (TI) Low Level
0.205
ug/L
0.2
1
EPA 200.8
06/05/2015 16:11
JAHERMA
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
06/05/2015 16:11
JAHERMA
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
<1
ug/L
1
1
EPA 200.8
06/09/2015 14:08
JAHERMA
Arsenic (As)
2.83
ug/L
1
1
EPA 200.8
06/09/2015 14:08
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
06/09/2015 14:08
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
06/09/2015 14:08
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
06/09/2015 14:08
JAHERMA
Cobalt (Co)
54.6
ug/L
1
1
EPA 200.8
06/09/2015 14:08
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
06/09/2015 14:08
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
06/09/2015 14:08
JAHERMA
Molybdenum (Mo)
1.08
ug/L
1
1
EPA 200.8
06/09/2015 14:08
JAHERMA
Nickel (Ni)
2.31
ug/L
1
1
EPA 200.8
06/09/2015 14:08
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
06/09/2015 14:08
JAHERMA
Thallium (TI) Low Level
0.291
ug/L
0.2
1
EPA 200.8
06/09/2015 14:08
JAHERMA
Vanadium (V) Low Level
0.451
ug/L
0.3
1
EPA 200.8
06/09/2015 14:08
JAHERMA
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
240
mg/L
25
1
SM2540C
05/28/201514:15
AGIBBS5
Total Carbon
TOC
0.548
mg/L
0.1
1
SM5310C/EPA9060A
06/03/201516:49
TJA7067
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
1
SM2540D
05/28/2015 08:28
AGIBBS5

Certificate of Laboratory Analysis Page 12 of 50
This report shall not be reproduced, except in full.
Order # J15050692
Site: ABMW-05D
Collection Date: 26 -May -15 2:18 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
06/01/2015 14:32
Vendor Parameter
Complete
EPA 300.0
06/01/2015 14:32
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
0.025
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
11
mg/L
1
Sulfate
16
mg/L
1
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/28/2015 12:51
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/28/2015 12:51
MHALL3
Aluminum (AI)
0.034
mg/L
0.005
Barium (Ba)
0.019
mg/L
0.005
Boron (B)
0.106
mg/L
0.05
Iron (Fe)
18.5
mg/L
0.01
Manganese (Mn)
0.357
mg/L
0.005
Strontium (Sr)
0.110
mg/L
0.005
Zinc (Zn)
0.029
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/27/2015 15:54
MHALL3
Calcium (Ca)
16.7
mg/L
0.01
Magnesium (Mg)
10.4
mg/L
0.005
Potassium (K)
2.27
mg/L
0.1
Sodium (Na)
8.01
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.148
mg/L
0.005
Barium (Ba)
0.016
mg/L
0.005
Boron (B)
0.106
mg/L
0.05
Iron (Fe)
19.0
mg/L
0.01
Manganese (Mn)
0.369
mg/L
0.005
Strontium (Sr)
0.108
mg/L
0.005
Zinc (Zn)
0.032
mg/L
0.005
Sample #: 2015016083
Matrix: GW -WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
06/01/2015 13:20
LSTARL1
10
EPA 300.0
06/01/2015 14:32
BGN9034
10
EPA 300.0
06/01/2015 14:32
BGN9034
1
EPA 245.1
05/29/2015 12:49
ACPAYNE
1
EPA 245.1
06/01/2015 15:48
ACPAYNE
1
EPA 200.7
05/28/2015 12:51
MHALL3
1
EPA 200.7
05/28/2015 12:51
MHALL3
1
EPA 200.7
05/28/2015 12:51
MHALL3
1
EPA 200.7
05/28/2015 12:51
MHALL3
1
EPA 200.7
05/28/2015 12:51
MHALL3
1
EPA 200.7
05/28/2015 12:51
MHALL3
1
EPA 200.7
05/28/2015 12:51
MHALL3
1
EPA 200.7
06/01/2015 11:16
MHALL3
1
EPA 200.7
06/01/2015 11:16
MHALL3
1
EPA 200.7
06/01/2015 11:16
MHALL3
1
EPA 200.7
06/01/2015 11:16
MHALL3
1
EPA 200.7
05/27/2015 15:54
MHALL3
1
EPA 200.7
05/27/2015 15:54
MHALL3
1
EPA 200.7
05/27/2015 15:54
MHALL3
1
EPA 200.7
05/27/2015 15:54
MHALL3
1
EPA 200.7
05/27/2015 15:54
MHALL3
1
EPA 200.7
05/27/2015 15:54
MHALL3
1
EPA 200.7
05/27/2015 15:54
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050692
Site: ABMW-05D
Collection Date: 26 -May -15 2:18 PM
Analyte
Result
DISSOLVED METALS BY ICP -MS
Sample #:
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
< 1
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
< 1
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
ug/L
TDS
170
Total Carbon
06/05/2015 16:16
TOC
0.715
TOTAL SUSPENDED SOLIDS
1
TSS
6.0
Page 13 of 50
ug/L
1
1
Sample #:
2015016083
JAHERMA
ug/L
1
1
Matrix:
GW -WW
JAHERMA
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
ug/L
1
1
EPA 200.8
06/05/2015 16:16
JAHERMA
ug/L
1
1
EPA 200.8
06/05/2015 16:16
JAHERMA
ug/L
1
1
EPA 200.8
06/05/2015 16:16
JAHERMA
ug/L
1
1
EPA 200.8
06/05/2015 16:16
JAHERMA
ug/L
1
1
EPA 200.8
06/05/2015 16:16
JAHERMA
ug/L
1
1
EPA 200.8
06/05/2015 16:16
JAHERMA
ug/L
1
1
EPA 200.8
06/05/2015 16:16
JAHERMA
ug/L
1
1
EPA 200.8
06/05/2015 16:16
JAHERMA
ug/L
1
1
EPA 200.8
06/05/2015 16:16
JAHERMA
ug/L
1
1
EPA 200.8
06/05/2015 16:16
JAHERMA
ug/L
1
1
EPA 200.8
06/05/2015 16:16
JAHERMA
ug/L
0.2
1
EPA 200.8
06/05/2015 16:16
JAHERMA
ug/L
0.3
1
EPA 200.8
06/05/2015 16:16
JAHERMA
ug/L
1
1
EPA 200.8
06/09/2015 14:13
JAHERMA
ug/L
1
1
EPA 200.8
06/09/2015 14:13
JAHERMA
ug/L
1
1
EPA 200.8
06/09/2015 14:13
JAHERMA
ug/L
1
1
EPA 200.8
06/09/2015 14:13
JAHERMA
ug/L
1
1
EPA 200.8
06/09/2015 14:13
JAHERMA
ug/L
1
1
EPA 200.8
06/09/2015 14:13
JAHERMA
ug/L
1
1
EPA 200.8
06/09/2015 14:13
JAHERMA
ug/L
1
1
EPA 200.8
06/09/2015 14:13
JAHERMA
ug/L
1
1
EPA 200.8
06/09/2015 14:13
JAHERMA
ug/L
1
1
EPA 200.8
06/09/2015 14:13
JAHERMA
ug/L
1
1
EPA 200.8
06/09/2015 14:13
JAHERMA
ug/L
0.2
1
EPA 200.8
06/09/2015 14:13
JAHERMA
ug/L
0.3
1
EPA 200.8
06/09/2015 14:13
JAHERMA
Vendor Method
V_SHEALY
Vendor Method
V_ELE1
mg/L
25
1
SM2540C
05/28/201514:15
AGIBBS5
mg/L
0.1
1
SM5310C/EPA9060A
06/03/201516:49
TJA7067
mg/L
5
1
SM2540D
05/28/2015 08:28
AGIBBS5

Certificate of Laboratory Analysis Page 14 of 50
This report shall not be reproduced, except in full.
Order # J15050692
Site: Equipment Blank
Collection Date: 26 -May -15 2:15 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy
Labs)
1 EPA 300.0
Vendor Parameter
Complete
1 EPA 300.0
06/01/2015 14:48
NITRITE + NITRATE (COLORIMETRIC)
1 EPA 245.1
05/29/2015 12:51
Nitrite + Nitrate (Colorimetric)
0.075
mg-N/L
0.01
INORGANIC IONS BY IC
06/01/2015 11:20
MHALL3
1 EPA 200.7
Chloride
< 0.1
mg/L
0.1
Sulfate
0.27
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
05/27/2015 15:58
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
MHALL3
1 EPA 200.7
05/27/2015 15:58
Calcium (Ca)
0.016
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
06/09/2015 14:17
JAHERMA
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by Shealy Labs
Methane (CH4) Complete
Sample #: 2015016084
Matrix: GW -WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1 EPA 353.2
06/01/2015 13:21
LSTARL1
1 EPA 300.0
06/01/2015 14:48
BGN9034
1 EPA 300.0
06/01/2015 14:48
BGN9034
1 EPA 245.1
05/29/2015 12:51
ACPAYNE
1 EPA 200.7
06/01/2015 11:20
MHALL3
1 EPA 200.7
06/01/2015 11:20
MHALL3
1 EPA 200.7
06/01/2015 11:20
MHALL3
1 EPA 200.7
06/01/2015 11:20
MHALL3
1 EPA 200.7
05/27/2015 15:58
MHALL3
1 EPA 200.7
05/27/2015 15:58
MHALL3
1 EPA 200.7
05/27/2015 15:58
MHALL3
1 EPA 200.7
05/27/2015 15:58
MHALL3
1 EPA 200.7
05/27/2015 15:58
MHALL3
1 EPA 200.7
05/27/2015 15:58
MHALL3
1 EPA 200.7
05/27/2015 15:58
MHALL3
1 EPA 200.8
06/09/2015 14:17
JAHERMA
1 EPA 200.8
06/09/2015 14:17
JAHERMA
1 EPA 200.8
06/09/2015 14:17
JAHERMA
1 EPA 200.8
06/09/2015 14:17
JAHERMA
1 EPA 200.8
06/09/2015 14:17
JAHERMA
1 EPA 200.8
06/09/2015 14:17
JAHERMA
1 EPA 200.8
06/09/2015 14:17
JAHERMA
1 EPA 200.8
06/09/2015 14:17
JAHERMA
1 EPA 200.8
06/09/2015 14:17
JAHERMA
1 EPA 200.8
06/09/2015 14:17
JAHERMA
1 EPA 200.8
06/09/2015 14:17
JAHERMA
1 EPA 200.8
06/09/2015 14:17
JAHERMA
1 EPA 200.8
06/09/2015 14:17
JAHERMA
Vendor Method V_SHEALY

Certificate of Laboratory Analysis Page 15 of 50
This report shall not be reproduced, except in full.
Order # J15050692
Site: Equipment Blank
Collection Date: 26 -May -15 2:15 PM
Analyte Result Units Qualifiers RDL DF
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L 25 1
Total Carbon
Sample #: 2015016084
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method
V_ELE1
SM2540C 05/28/201514:15 AGIBBS5
TOC 0.198 mg/L 0.1 1 SM5310C/EPA9060A 06/03/201516:49 TJA7067
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 05/28/2015 08:28 AGIBBS5

Certificate of Laboratory Analysis Page 16 of 50
This report shall not be reproduced, except in full.
Order # J15050692
Site: Filter Blank
Collection Date: 26 -May -15 2:15 PM
Analyte
Result
Units
Qualifiers RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
EPA 245.1
06/01/2015 15:50
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
1
EPA 200.7
05/28/2015 12:55
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
0.021
mg/L
0.005
DISSOLVED METALS BY ICP -MS
1
EPA 200.8
06/05/2015 16:21
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2015016085
Matrix: GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
06/01/2015 15:50
ACPAYNE
1
EPA 200.7
05/28/2015 12:55
MHALL3
1
EPA 200.7
05/28/2015 12:55
MHALL3
1
EPA 200.7
05/28/2015 12:55
MHALL3
1
EPA 200.7
05/28/2015 12:55
MHALL3
1
EPA 200.7
05/28/2015 12:55
MHALL3
1
EPA 200.7
05/28/2015 12:55
MHALL3
1
EPA 200.7
05/28/2015 12:55
MHALL3
1
EPA 200.8
06/05/2015 16:21
JAHERMA
1
EPA 200.8
06/05/2015 16:21
JAHERMA
1
EPA 200.8
06/05/2015 16:21
JAHERMA
1
EPA 200.8
06/05/2015 16:21
JAHERMA
1
EPA 200.8
06/05/2015 16:21
JAHERMA
1
EPA 200.8
06/05/2015 16:21
JAHERMA
1
EPA 200.8
06/05/2015 16:21
JAHERMA
1
EPA 200.8
06/05/2015 16:21
JAHERMA
1
EPA 200.8
06/05/2015 16:21
JAHERMA
1
EPA 200.8
06/05/2015 16:21
JAHERMA
1
EPA 200.8
06/05/2015 16:21
JAHERMA
1
EPA 200.8
06/05/2015 16:21
JAHERMA
1
EPA 200.8
06/05/2015 16:21
JAHERMA

REPORT OF ANALYSES
Page 17 of 50
Element One Inc.
6319-D Carolina Beach Rd.
Wilmington, VAC 28412
Phone: [phone]
Fax: [phone]
[e-mail]
Duke Energy
June 9, 2015
Laboratory Services
Client Project Name
AB GW Assessment water Asheville
13339 Hagers
Ferry Road Bid. MG03A
Client Project Number J15050692
Huntersville, NC 28078
PO Number
Sample Matrix
GW WW
Sample Type Grab
Date Received
05/29/2015
Date Analyzed
05/29/2015
Method
SM 4500 S2- D
Time Received
0900
Delivered by
FedEx
Received by
LLB
eOne ID
Duke Energy ID
Parameter
Result Unit
Dil
DL Date
Time
Sampled
Sampled
24881-1
ABMW-04
Sulfide
< 0.1 mg/L
1
0.1 05/26/15
1032
24881-2
ABMW-04D
Sulfide
< 0.1 mg/L
1
0.1 05/26/15
1254
24881-3
ABMW-05S
Sulfide
< 0.5 mg/L
5
0.1 05/26/15
1035
24881-4
ABMW-04D Dup
Sulfide
< 0.1 mg/L
1
0.1 05/26/15
1335
24881-5"
ABMW-05D
Sulfide
< 0.5 mg/L
5
0.1 05/26/15
1418
24881-6
Equipment Blank
Sulfide
< 0.1 mg/L
1
0.1 05/26/15
1415
"Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits.
Ken S ith, Laboratory Director
24881 Duke Report Packet Compiled bA�
NC Certifications: DW 37788 and DWQ DENR 604

• ! , ,..� � r r° � � hn � f�k �, yam, �i�t',3 ,�,� - •R
to
Page 18 of 50
CA
J
V
1
punoiauwnjpwisep
alun!puiesseld qusUodwi'iewo;sno
O
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C
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W
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o
_ 1
N
a
2
CL
W
• ! , ,..� � r r° � � hn � f�k �, yam, �i�t',3 ,�,� - •R
to
Page 18 of 50
�
J
V
1
punoiauwnjpwisep
alun!puiesseld qusUodwi'iewo;sno
punoiauwnjpwisep
alun!puiesseld qusUodwi'iewo;sno
C
�
�
h
_ 1
N
a
2
>
v 4
r$ S
e
I
zq
U
4
v c
4W�
m m �
IL
q m
o
a o.
S2 2 -
y
yk E
us ul
f��
e
wwo

elementOne SAMPLE SUBMISSION FORM
TAT 7 BD
Hold Time Expiration 06.02.15 @ 1032
Client: Duke Energy
LIMS No J15050692
Project ID Asheville
Lab O age J&§1
Analysis Due Date 06.01.15
Report Due Date 06.09.15
Date Rec:
05.29.15
Time Rec:
0900
Rec By
LLB
Sample Identification & Collection Information
Lab ID I
No Tem <_ 6°C es No
Ref. Method:
SM4500 S2 D
If No, Record If No, Record
Sample Identification & Collection Information
Lab ID I
Client ID Collection Date
Collection Time
Anal sis Requested
1
ABMW-04 05/26/15
1032
ulfgdW
-A-B--MW,---04D 05/26/15
1254 (:Sulfide\,
3
ABMW-05S 05/26/15
1035
-9—ulfid6
4
ABMW-04D-DUP 05/26/15
1335
Sulfide'
5_
-,
ABMW -05D 1)5/26/15
1418
6 _J.
Equipment Blank 05/26/15
1415
< f @—I fi �de
NOTE for Sulfide
The
The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected
tj
100 pg/L spike the sample to render the final spike concentration at - 500 pg/L
Lab Communications
All AB Groundwater Assessment iobs need a RL of 0.1
SS Page 1 Prep By / Date kAv--�-
SS by �46 Labeled By/Date Z7A
5/29/2015 10:39:12 AM ID Verification By /Date K�

METHOD:
SM 4500 S2- D
ug STD
ELEMENT ASSAY:
Sulfide
Spectrophotomete
Wave Length 664
CLIENT: Duke
Lab ID#
24879 / 880 / 881 / 882,/ 883
Na2S•9H2O Lot #
40721
Date: 5/29/15
Time Analysis Begun 1330
Time Analysis Ended 1554
Analyst: KAM
X
Y
ug STD
STD
SOLUTION
ABS
0.00
0.000
1.00
0,095
2.50
0.218
5.00
0.415
100
7.50
0.610
app 400 8.00 8.00 1000 12!
10.00
0.778
10
Page 20 of 50
ELEMENT ONE
STANDARD conc(ppm)
Cal Std Lot: WC2-84-1
p�
' V_
600
700
---------"---------- ""--- -- - -"-----
(500
0.077810989
wo
'0.999153155
SAMPLE
I.D.
SAMP
ABS
ug PER ALI in mL
ALIQUOT ANALYZED
PREP
VOL in mL
200
RESULTS
ug/mL
100
SPIKE
LEVEL
aoo
Opp
app 400 8.00 8.00 1000 12!
x
X
10
10
Y
�000
-00
-50o
�I
p
Page 1 of 4
' V_
y
'`
Sloe
0.077810989
Correlation
'0.999153155
SAMPLE
I.D.
SAMP
ABS
ug PER ALI in mL
ALIQUOT ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
LESS THAN
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.0
Std. B. 1.00
0.096
0.9229
10
10
10
<
92.29%
1.0
Std. B. 2.50
0.224
2.6237
10
10
10
0.262
104.95%
2.5
Std. B. 5.00
0.415
5.1616
10
10
10
0.516
103.23%
5.0
Std. B. 7.50
0.609
7.7393
10
10
10
0.774
103.19%
7.5
Std. B. 10.00
0.776
9.9584
10
10
10
0.996
99.58%
10.0
LRB
0.000
0.0000
10
10
10
<
0.0
LRB SPK
0.412
5.1217
10
10
10
0.512
103%
5.0
QC
0.422
5.2546
10
10
10
0.525
105%
5.0
24879-1
0.004
-0.2996
10
10
10
Vit© 1
24879-1 s k
0.400
4.9623
10
10
10
0.496
99%
5.0
24879-2
0.002
1 -0.3261
10
10
10
24879-2 dup
0.009
-0.2331
10
10
10
< 0.1
24879-2 s k
0.408
5.0686
10
10
10
0.507
101%
5.0
24880-1
0.007
-0.2597
10
10
10
<
24880-1 s k
0.328
4.0056
10
10
10
0.401
80%
5.0
24880-2
0.004
-0.2996
10
10
10
,r
24880-2 s k
0.411
5.1084
10
10
10
0.511
102%
5.0
24881-1
0.006
-0.2730
10
10
10
24881-1 s k
0.362
4.4573
10
10
10
0.446
89%
5.0
24881-2
0.008
-0.2464
10
10
10
0 1
24881-2 s k
0.365
4.4972
10
10
10
0.450
90%
5.0
24881-3
0.005
-0.2863
10
10
10
<
24881-3 s k
0.298
3.6070
10
10
10
0.361
72%
5.0
24881-4
0.006
-0.2730
10
10
10
24881-4 s k
0.367
4.5238
10
10
10
0.452
90%
5.0
24881-5
0.009
-0.2331
10
10
10
<
24881-5 s k
0.308
3.7398
10
10
10
0.374
75%
5.0
Blank
0.000
0.0000 1
10
10
10
<
QC
1 0.422
5.2546 1
10
10
10
0.525
105%
5.0
Submitted for QA/QC-
Date: 5/29/15
By: (Print)
KAM(sign):
Page 1 of 4

METHOD: SM 4500 S2- D'
ELEMENT ASSAY: Sulfide
Date:
5/29/15
Time Analysis Begun
1330
Time Analysis Ended
1554
Analyst:
-
RAN
x
Y
ug STD
STD
SOLUTION
ABS
0.00
0.000
1.00
0.095
2.50
0.218
5.00
0.415
7.50
0.610
10.00
0.778
Page 21 of 50
ELEMENT ONE
pectrophotometer
Wave Length 664
UNITS OF ANSW
DETECTION LIMI
SPK LEVELLuca
Na2S•9H2O Lot #
40721
MAX ALIQUOT
STANDARD conc
jCaI Std Lot:
QC Std Lot:
STD ABSORPTIC
0.600
Slope
ALI in mL
TAKEN
10
10
10
10
10
10
0.100
0.
---------..__--._
---- ----
0.500
Y
LRB
0.400
0.0000
10
10
.00
---------------- ------- --
0100
0.0
o.00u
0.412
10.00
X
10
10
Y
---o.00
11 �
�5p0
1,.
i
00 6.00 10.0 1200
X
SAMPLE SAMP ug PER ALI in mL PREP F
1. D. ABS ALIQUOT ANALYZED VOL in mL
Std. B. 0.00 0.000 0.0000 10 10
Std. B. 1.00 0.096 0.9229 10 10
Std. B. 2.50 0.224 2.6237 10 10
Std. B. 5.00 0.415 5.1616 10 10
Std. B. 7.50 0.609 7.7393 10 10
Std. B. 10.00 0.776 9.9584 10 10
Slope
ALI in mL
TAKEN
10
10
10
10
10
10
0.077810989
RESULTS
ug/mL
<
<
0.262
0.516
0.774
0.996
Correlation
LESS THAN
% SPK REC
92.29%
104.95%
103.23%
103.19%
99.58%
0.999153155
SPIKE
LEVEL
0.0
1.0
2.5
5.0
7.5
10.0
LRB
0.000
0.0000
10
10
10
<
0.0
LRB SPK
0.412
5.1217
10
10
10
0.512
103%
5.0
QC
0.422
5.2546
10
10
10
0.525
5.0
24881-6
0.002
-0.3261
10
10
10.
24881-6 s k
0.414
5.1483
10
10
10
0.515
103%
5.0
24882-1
0.010
-0.2198
10
10
10
0`�1-u
24882-1 dup
0.008
-0.2464
10
10
10
< 0.1
24882-1 s k
0.371
4.5769
10
1010
0.458
92%
5.0
24882-2
0.019
-0.1002
10
10
10
<
24882-2 s k
0.280
3.3678
10
10
10
0.337
67%
5.0
24882-3
0.004
-0.2996
10
10
10
<
24882-3 s k
0.337
4.1252
10
10
10
0.413
83%
5.0
24882-4
0.010
-0.2198
10
10
10
<
24882-4 sok
0.318
3.8727
10
10
10
0.387
77%
5.0
24882-5
0.006
-0.2730
10
10
10
0,
24882-5 s k
0.358
4.4042
10
10
10
0.440
88%
5.0
24882-6
0.007
-0.2597
10
10
10
<
24882-6 s k
24882-7
0.344
0.006
4.2182
-0.2730
10
10
10
10
10
10
0.422
<
84%
5.0
24882-7 s k
0.328
4.0056
10
10
10
0.401
80%
5.0
24882-8
24882-8 sok
0.005
0.400
-0.2863
4.9623
10
10
10
10
10
10
. 0:
0.496
99%
5.0
Blank 0.000 0.0000
QC 0.420 5.2280
Submitted for QA/QC- Date: 5/29/15
10
10
10
10
By: (Print)
10
10
<
0.523 105%
KAM (sign):
5.0
Page 2 of 4

METHOD:
SM 4500 S2- D
ELEMENT ASSAY:
Sulfide
CLIENT:
Duke
Lab ID#
24879 / 880 / 881 / 882 / 883'
Date:
5/29/15
Time Analysis Bequ
11330
Time Analysis Ended
11554
X
Y
ug STD
STD
SOLUTION
ABS
0.00
0.000
1.00
0.095
2.50
0.218
5.00
0.415
7.50
0.610
Page 22 of 50
ELEMENT ONE
Wave Length 664
"" "" """ L1°"' " '.UV
SPK LEVEL_uM 5
Na2S•9H2O Lot #
40721
MAX ALIQUOT 10.0
STANDARD conc(ppm) X
Cal Std Lot: WC2-84-1 10
QC Std Lot: WC2-84-2 10
STD ABSORPTION Y
X
SAMPLE SAMP ug PER
I.D. ABS ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
Sloe
ALI in mL
TAKEN
0.0778`10989
RESULTS
ug/mL
Correlation
LESS THAN
% SPK REC
0.999153155
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.0
Std. B. 1.00
0.096
0.9229
10
10
10
<
92.29%
1.0
Std. B. 2.50
0.224
2.6237
10
10
10
0.262
104.95%
2.5
Std. B. 5.00
0.415
5.1616
10
10
10
0.516
103.23%
5.0
Std. B. 7.50
0.609
7.7393
10
10
10
0.774
103.19%
7.5
Std. B. 10.00
0.776
9.9584
10
10
10
0.996
99.58%
10.0
LRB
0.000
0.0000
10
10
10
<
0.0
LRB SPK
0.412
5.1217
10
10
10
0.512
103%
5.0
QC
0.422
5.2546
10
10
10
0.525
5.0
24882-9
0.005
1 -0.2863
10
10
10p
1 �.
24882-9 s k
0.416
5.1749
10
10
100.517
103%
5.0
24883-1
0.007
-0.2597
10
10
10
<
24883-1 s k
0.147
1.6005
10
10
10
0.160
32%
5.0
24883-2
0.007
-0.2597
10
10
10
< ,;
24883-2 dup
0.002
-0.3261
10
10
10
< 0.1
24883-2 s k
0.411
5.1084
10
10
10
0.511
102%
5.0
24883-3
0.006
-0.2730
10
10
10e,Qe=
24883-3 s k
0.392
4.8560
10
10
10
0.486
97%
5.0
24880-1
0.009
-0.2331
10
10
5
24880-1 s k
0.360
4.4308
10
10
5
0.886
89%
5.0
24881-3
0.006
-0.2730
10
10
5
<
24881-3 s k
0.340
4.1650
10
10
5
0.833
83%
5.0
24881-5
0.005
-0.2863
10
10
5
<
24881-5 s k
0.274
3.2881
10
10
5
0.658
66%
5.0
24882-2
0.006
-0.2730
10
10
5
<
24882-2 s k
0.325
3.9657
10
10
5
0.793
79%
5.0
24882-3
0.004
-0.2996
10
10
5
24882-3 s k
0.373
4.6035
10
10
5
0.921
92%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.419
5.2147
10
10
10
0.521
104%
5.0
Submitted for QA/QC-
Date: 5/29/15
By: (Print) KAM (sign):
Page 3 of 4

Page 23 of 50
METHOD:
SM 4500 S2- D
ELEMENT ONE
ABS
ELEMENT ASSAY:
Sulfide
Spectrophotometer
UNITS OF ANSWER
2.50
CLIENT:
Duke
Wavelength 664
,
DETECTION LIMIT (ug)
1.000
Lab ID#
24879 / 880 881 882 883
Correlation
SPK LEVEL u
5
MAX ALIQUOT
10.00
Date: 5/29/15
PREP
ALI in mL
Na2S-91-120 Lot#
STANDARD conc(ppm)
x
Time Analysis Begun
Time Analysis Ended
1330
1554 -
40721
Cal Std Lot: WC2-84-1
10
QC Std Lot: WC2-84-2
10
AnaFYs-t.
KAM
STD ABSORPTION
y
x
10
y 0
< -
0.0
ug STD
STD
SOLUTION
ABS
0.00
0.000
1.00
0.095
2.50
0.218
5.00
0,415
7.50
0.610
No
O.m
Ono
0
y
6.w
x
0.400
MI
1200
.200
w
0..1w°.000
0,00
2.00 400
750
1 10.000.778
1
6.w
x
am
10.OD
1200
Slope
0.077816989
Correlation
0.999153156
SAMPLE
1. D.
SAMP
Ug PER
ALI in ml-
PREP
ALI in mL
RESULTS
LESS THAN
SPIKE
Std. B. 0.00
ABS
ALIQUOT
ANALYZED
VOL in mL
TAKEN
ug/mL
% SPK REC
LEVEL
0.000
0.0000
10
10
10
< -
0.0
Std. B. im
0.096
0.9229
10
-10--10-
Std. B. 2.50
-0.22-4
26-237
10
10
10
<
--104.95%
92.29%
1.0
Std. B 5
td. B. 5.00
4
0.415
-5.1616
76-
10
10
0.262
2.5
B
Std. B.17.50
0.609
9
--1-.7393
10
10
10
0.516
103.23%
5.0
Std. B
B. 10.00
6 00
0
F.776
--'9-.9584
-10
10
10
0.774
103.19%
7.5
0.996
99.580/6-
10.0
L
LRB
0.000
0 000
0.0000
10
10
10
<
LRB SPK
0.412
5.1217
10
10
10
--
-0.512
--1030/.
0.0
5.0
QC
0.422
5.2546
10
10
10
0.525
5.0
24882-4
0.002
-0.3261
10
10
5
24882-4 s
0.361
-4.4441
10
10
5
0.889
89%
5.0
24882-6
0.005
-0.2863
10
10
5
37
24882-6 s
0.387
4.7895
10
10
5
0.958
96%
5.0
24882-7
0.007
-0.2597
10
10
5
24882-7 s
0.401
4.9756
10
10
5
0.995
100%
5.0
24883-1
0.007
-0.2597
10
10
5
<
24883-1 s
0.226
2.6503
10
10
5---
0.530
53%
5.0
24881-3
0.005
-0.2863
10
--
10
2
--
24881-3 du p
0.006
- -0.2730
10
10
2
< 0.5
24881-3 s
0.395
4.8958
10
10
2
2.448
98%
5.0
24881-5
0.005
-0.2863
10
10
2
0.
24881-5 s
0.356
4.3776
10
10
2
2.189
88%
5.0
24882-2
0.003
-0.3128
10
10
2
24882-2 s
0.394
4.8825
10
10
2
2.441
98%
5.0
24833-1
0.007
-0.2597
10
10
2
24883-1spk
0.318
3.8727
10
10
2
<
1.936
77%
5.0
24883-1
0.008
-0.2464
10
10
1
24883-1 s
0.345
4.2315
10
10
1
4.231
85%
5.0
Blank
0.0010
0.0000
10
10
10
QC
Submitted for QA/QC-
0.423
1 5.2679 1
10
10
10
0.527
5.0
Date: 5/29/15
By: (Print)
KAM 1(sign):
777-7,-7
Page 4 of 4

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
Project Name: AB GW Assessment Water - Asheville
Project Number:J15050692
Lot Number:QE29053
Date Completed:06/02/2015
Grant Wilton
Project Manager
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
* QE29053*
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SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: QE29053
Project Name: AB GW Assessment Water - Asheville
Project Number: J15050692
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page
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SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QE29053
Project Name: AB GW Assessment Water - Asheville
Project Number: J15050692
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
2015016079
Aqueous
05/26/20151032
05/29/2015
002
2015016080
Aqueous
05/26/20151254
05/29/2015
003
2015016081
Aqueous
05/26/20151035
05/29/2015
004
2015016082
Aqueous
05/26/20151335
05/29/2015
005
2015016083
Aqueous
05/26/20151418
05/29/2015
006
2015016084
Aqueous
05/26/20151415
05/29/2015
(6 samples)
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(14 detections)
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SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QE29053
Project Name: AB GW Assessment Water - Asheville
Project Number: J15050692
Sample Sample ID
Matrix Parameter Method Result Q
Units
Page
001
2015016079
Aqueous Alkalinity SM 2320B-
400
mg/L
5
001
2015016079
Aqueous Bicarbonate Alkalinity SM 2320B-
400
mg/L
5
001
2015016079
Aqueous Methane RSK - 175
18
ug/L
6
002
2015016080
Aqueous Alkalinity SM 2320B-
51
mg/L
7
002
2015016080
Aqueous Bicarbonate Alkalinity SM 2320B-
51
mg/L
7
003
2015016081
Aqueous Alkalinity SM 2320B-
71
mg/L
9
003
2015016081
Aqueous Bicarbonate Alkalinity SM 2320B-
71
mg/L
9
003
2015016081
Aqueous Methane RSK - 175
32
ug/L
10
004
2015016082
Aqueous Alkalinity SM 2320B-
48
mg/L
11
004
2015016082
Aqueous Bicarbonate Alkalinity SM 2320B-
48
mg/L
11
004
2015016082
Aqueous Methane RSK - 175
11
ug/L
12
005
2015016083
Aqueous Alkalinity SM 2320B-
98
mg/L
13
005
2015016083
Aqueous Bicarbonate Alkalinity SM 2320B-
98
mg/L
13
005
2015016083
Aqueous Methane RSK - 175
210
ug/L
14
(14 detections)
Shealy Environmental Services, Inc. Page: 4 of 16
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE29053-001
Description: 2015016079 Matrix: Aqueous
Date Sampled:05/26/2015 1032 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050692
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 05/30/2015 2031
HMA 76152
1
(Bicarbonate ) SM 2320B-2011
1 05/30/2015 2031
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/30/2015 2031
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
400
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
400
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QE29053-001
Description: 2015016079 Matrix: Aqueous
Date Sampled:05/26/2015 1032 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050692
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/02/2015 1216 DCS 76333
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 18 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE29053-002
Description: 2015016080 Matrix: Aqueous
Date Sampled:05/26/2015 1254 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050692
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 05/30/2015 2054
HMA 76152
1
(Bicarbonate ) SM 2320B-2011
1 05/30/2015 2054
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/30/2015 2054
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
51
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
51
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QE29053-002
Description: 2015016080 Matrix: Aqueous
Date Sampled:05/26/2015 1254 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050692
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/02/2015 1320 DCS 76333
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE29053-003
Description: 2015016081 Matrix: Aqueous
Date Sampled:05/26/2015 1035 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050692
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 23208-2011
1 05/30/2015 2058
HMA 76152
1
(Bicarbonate ) SM 2320B-2011
1 05/30/2015 2058
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/30/2015 2058
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
71
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
71
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QE29053-003
Description: 2015016081 Matrix: Aqueous
Date Sampled:05/26/2015 1035 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050692
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/02/2015 1330 DCS 76333
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 32 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE29053-004
Description: 2015016082 Matrix: Aqueous
Date Sampled:05/26/2015 1335 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050692
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 05/30/2015 2103
HMA 76152
1
(Bicarbonate ) SM 2320B-2011
1 05/30/2015 2103
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/30/2015 2103
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
48
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
48
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QE29053-004
Description: 2015016082 Matrix: Aqueous
Date Sampled:05/26/2015 1335 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050692
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/02/2015 1340 DCS 76333
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 11 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE29053-005
Description: 2015016083 Matrix: Aqueous
Date Sampled:05/26/2015 1418 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050692
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 05/30/2015 2109
HMA 76152
1
(Bicarbonate ) SM 2320B-2011
1 05/30/2015 2109
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/30/2015 2109
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 13 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
98
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
98
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 13 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE29053-005
Description: 2015016083 Matrix: Aqueous
Date Sampled:05/26/2015 1418 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050692
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/02/2015 1350 DCS 76333
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 210 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 14 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QE29053-006
Description: 2015016084 Matrix: Aqueous
Date Sampled:05/26/2015 1415 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050692
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 05/30/2015 2115
HMA 76152
1
(Bicarbonate ) SM 2320B-2011
1 05/30/2015 2115
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/30/2015 2115
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 15 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 15 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE29053-006
Description: 2015016084 Matrix: Aqueous
Date Sampled:05/26/2015 1415 Project Name: AB GW Assessment Water -
Date Received: 05/29/2015 Project Number: J15050692
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 06/02/2015 1400 DCS 76333
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 16 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: QE29053
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - Ii
Sample ID: QQ76152-001 Matrix: Aqueous
Batch: 76152
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 05/30/20151910
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE29053
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - LCS
Sample ID: QQ76152-002 Matrix: Aqueous
Batch: 76152
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 95 1 95 90-110 05/30/20151917
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE29053
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MS
Sample ID: QE29053-001MS Matrix: Aqueous
Batch: 76152
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 400 100 420 N 1 14 70-130 05/30/2015 2041
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE29053
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MSD
Sample ID: QE29053-001MD Matrix: Aqueous
Batch: 76152
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Alkalinity 400 100 420 N 1 16 0.43 70-130 20 05/30/2015 2049
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE29053
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - MB
Sample ID: QQ76333-001 Matrix: Aqueous
Batch: 76333
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 06/02/20151019
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE29053
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCS
Sample ID: QQ76333-002 Matrix: Aqueous
Batch: 76333
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 150 140 1 91 70-130 06/02/2015 0942
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE29053
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCSD
Sample ID: QQ76333-003 Matrix: Aqueous
Batch: 76333
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 150 170 1 112 20 70-130 30 06/02/2015 0958
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE29053
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
0
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
Skaly E viranmcnto! Surices, ln�.
1-30t FnentMrkn*orRAD-13.16 I
Revlrson Number.- 17
C1it11t:
Prlexns (if rrAwi
Yes I I I No
Yes Ll I No
❑ )?M ❑
NA Let' 1 2_ If
Pap Lof1
LdepiM 4aka; 1,1.0N14
Effscuwe Det:. 041IM5
Sample Receipt Checklist (SRC)
. C nnler Tri.y ted by/date: los Lot it: 1 "1C )
iefit ❑ UPS ❑ FedEx ❑ Airborne Exp Irher
C F'to Seals Presellt on the cooler?
ttxly SePls tiwere present_ were rt ay i elect And nnhsrAcP-. 9
Caroler Ill,rf riginal ternperalum upol reccipt/Derivcd (corned) temperature upon receipt:
Method:
[2 Temperature
Lank gainst Bottles IRS ult ID: IR Gun Correcdon Facl.or- C; G oC
thud of coolant'. LZ'
Wet _I0c❑ I]Ne lee Dry Ice Nonea,
if tem rature sof any cooler cxceudcd 6,0'C, was Prc�1ecl Ikianager nolifiied? l
Yes ❑
No ❑ NAV -
PM no ificd. by SRC, phone, nore (circle one), otlref;
[For wolers recta vcd via cornrrrercial 00urier_ FlVis are W be notified
immed' 1aelg_
Yes 0
No ❑ Nth
4_ Ts the ,rar�ereial courier's ac sli attacl�e�l Gtr this form?
Yss
No ❑
S. Were pmpolr Custody pruczdurGs relict uish 'received followcd?
53 Wore sa ]es rclin uiRhed by cliont to cof]a xrcial courier?
Yes ❑ Ion ❑
NAt
Yes 21
No ❑
6. Wure Flans le IIs listed on the. COC?
Yca
No ❑
7. "'Cre 5ample IDs It.st&d on all sample containers'i
MGs
NO ❑
8, Was c. 11 Lion; date $t trine listed on the C:
Yes
No ❑
9. Was C4 iirudun date & time listed on all sample containers?
Yes
NO ❑
1.0. Did M mritaine.r label information , date, time re with the C(k-,',
Yes
N ❑
11. Were sty 0 be �crforme-d listed on the CCC?
Yss unmo
12. Did a1 s ICE arrive in the propercontainers teach test?
13. Did al containers arri4re in god condition unbroken 44 rnx etc, L?
Yes No ❑
Yes
NO ❑
14. Was atle Bate §WVe voFlvzrle available`
Ycs
Na
15. W*rt h1l samples receivmT within ' the holding time or 48 hours, whichever
co first'?
sin ;
Ycs No
Yts ❑
No 1
17, Were here any excess samples not limed on COC?
18. Were:Ti bleS wont >` s-size"lfa°'or 6mm in diamtiq in an 6,iijl]5?
19_ V4'=rc J01 n*taJs/&G?HEK'nutrient sacci lV-S racei ,ped at a pH of <2?
e
20_ Vvi--re1 -anide and?br sulfide sa es receiveH d at >M
Ycs= 7770 -NA
❑
Tiles ❑ No ❑
NA LZ 1
Yes C1 No ❑
NA Z
Yes Q
No F-1NA
O-
21. Were il applicsble Iw1l-31i KN/cylailAcrphcnal nples free of
jresid4 chlaTine?
'Yes a
No ❑
NA
'22. Were i0licction telupciatuics documented on the COC for NC s Jes'?_
Yes [7)
Ncs ❑ NA 2r
23, Were #coC mmarlm/requesCs (i.e. rcqueste[3 dilutions, MSAVISD designatio s,
rte ...)co al r tra.nscri-b-Bd from the COC into the comment SeGtjon in LIMS2
Ym ❑ I
No EYJ 1
24, Was Ike quote number used taken from the container label?
Sample Preservation {Mus( ba ooiiplewd for any samples) ijtcurrrutly preserved or with headspace.)
Sample [$)
_
{vera Moeived illeatrectly preserved and wereadjusted
-accordingly
in sato le tectivingwith (1 §f) HNC1 CI.Naft using SR
_Sample(s)
were feceivcd with bubbles 56 nun in dianloicr,
sa ie(s)
wr're reeeived with TRC >0_2 m Z If #21 is No
SC Drinking Walcr Project Samplo(s).pH verified W be > 2 by � D -ate:
Sample(s)
were nestcarred at a H of c2, and were adjusted accordingly using SR#
{ Sample labels Mlued by.
��. Verified 11y Tate: 1"
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

CHAIN OF CUSTODY RFCORD ANO ANALYSIS REQUEST FORM
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