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Home My WebLink AboutNC0000396_J15050625report_20150823+ DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Order Number: J15050625 Project Name: ASHEVILLE - AB GW ASSESSMENT WATER Customer Name(s): Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker Customer Address: 200 CP and L Drive Arden, NC 28704 Lab Contact: Mary Ann Ogle Phone: 980-875-5274 �n � Mary Ann Ogle Report Authorized By: ✓ 2015.06.10 13:18:43 Date: (Signature) -04'00' Mary Ann Ogle Program Comments: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: 6/9/2015 Pagel of 104 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By Sample Description 2015015706 ASHEVILLE 21 -May -15 10:05 AM illegible CB -01D 2015015707 ASHEVILLE 21 -May -15 8:54 AM illegible MW-02BR 2015015708 ASHEVILLE 21 -May -15 8:51 AM illegible MW -06S 2015015709 ASHEVILLE 21 -May -15 10:02 AM illegible MW -06D 2015015710 ASHEVILLE 21 -May -15 11:25 AM illegible MW -04D 2015015711 ASHEVILLE 21 -May -15 10:59 AM illegible MW-01BR 2015015712 ASHEVILLE 21 -May -15 11:30 AM illegible MW -01D 2015015713 ASHEVILLE 20 -May -15 3:45 PM TDP MW -15D 2015015714 ASHEVILLE 21 -May -15 12:03 PM MY MW -09D 2015015715 ASHEVILLE 21 -May -15 2:05 PM MY MW-09BR 2015015716 ASHEVILLE 21 -May -15 10:49 AM MY MW -09S 2015015717 ASHEVILLE 21 -May -15 1:50 PM TCP MW -12D 2015015718 ASHEVILLE 21 -May -15 2:50 PM TCP MW -03D 2015015719 ASHEVILLE 21 -May -15 9:55 AM illegible Equipment Blank 2015015720 ASHEVILLE 21 -May -15 9:55 AM illegible Filter Blank 2015015721 ASHEVILLE 21 -May -15 3:50 PM MY MW -17A 2015015722 ASHEVILLE 21 -May -15 2:02 PM TDP ABMW-08 17 Total Samples Page 2 of 104 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes F./] No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Page 3 of 104 Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 66 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Reviewed By: Peggy Kendall Date: 6/9/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050625 Site: CB -01 D Collection Date: 21 -May -15 10:05 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) BGN9034 1 EPA 300.0 Vendor Parameter Complete 1 EPA 245.1 05/29/2015 11:19 NITRITE + NITRATE (COLORIMETRIC) 1 EPA 245.1 06/01/2015 14:16 Nitrite + Nitrate (Colorimetric) 0.038 mg-N/L 0.01 INORGANIC IONS BY IC 05/28/2015 09:52 MHALL3 1 EPA 200.7 Chloride 1.1 mg/L 0.1 Sulfate 2.2 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER 05/28/2015 09:52 MHALL3 Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) MHH7131 1 EPA 200.7 Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP 1 EPA 200.7 05/28/2015 09:58 MHH7131 Aluminum (AI) 0.005 mg/L 0.005 Barium (Ba) 0.016 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.449 mg/L 0.01 Manganese (Mn) 0.308 mg/L 0.005 Strontium (Sr) 0.019 mg/L 0.005 Zinc (Zn) 0.021 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 3.72 mg/L 0.01 Magnesium (Mg) 1.12 mg/L 0.005 Potassium (K) 1.54 mg/L 0.1 Sodium (Na) 3.89 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.085 mg/L 0.005 Barium (Ba) 0.018 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.589 mg/L 0.01 Manganese (Mn) 0.286 mg/L 0.005 Strontium (Sr) 0.019 mg/L 0.005 Zinc (Zn) 0.020 mg/L 0.005 Sample #: 2015015706 Matrix: GW -WW Page 4 of 104 DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/29/2015 14:07 LSTARL1 1 EPA 300.0 05/27/2015 20:13 BGN9034 1 EPA 300.0 05/27/2015 20:13 BGN9034 1 EPA 245.1 05/29/2015 11:19 ACPAYNE 1 EPA 245.1 06/01/2015 14:16 ACPAYNE 1 EPA 200.7 05/28/2015 09:52 MHALL3 1 EPA 200.7 05/28/2015 09:52 MHALL3 1 EPA 200.7 05/28/2015 09:52 MHALL3 1 EPA 200.7 05/28/2015 09:52 MHALL3 1 EPA 200.7 05/28/2015 09:52 MHALL3 1 EPA 200.7 05/28/2015 09:52 MHALL3 1 EPA 200.7 05/28/2015 09:52 MHALL3 1 EPA 200.7 05/28/2015 09:58 MHH7131 1 EPA 200.7 05/28/2015 09:58 MHH7131 1 EPA 200.7 05/28/2015 09:58 MHH7131 1 EPA 200.7 05/28/2015 09:58 MHH7131 1 EPA 200.7 05/29/2015 12:08 SLS2560 1 EPA 200.7 05/29/2015 12:08 SLS2560 1 EPA 200.7 05/29/2015 12:08 SLS2560 1 EPA 200.7 05/29/2015 12:08 SLS2560 1 EPA 200.7 05/29/2015 12:08 SLS2560 1 EPA 200.7 05/29/2015 12:08 SLS2560 1 EPA 200.7 05/29/2015 12:08 SLS2560 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050625 Site: CB -01 D Collection Date: 21 -May -15 10:05 AM Analyte Result DISSOLVED METALS BY ICP -MS Sample #: Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 1.63 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 1.44 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) 1.27 Cobalt (Co) 1.66 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 2.07 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level 0.340 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS ug/L TDS 37 Total Carbon 06/04/2015 20:01 TOC 0.518 TOTAL SUSPENDED SOLIDS 1 TSS < 5 Page 5 of 104 ug/L 1 1 Sample #: 2015015706 SLS2560 ug/L 1 Matrix: GW -WW 06/06/2015 10:36 Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 06/04/2015 20:01 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:01 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:01 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:01 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:01 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:01 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:01 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:01 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:01 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:01 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:01 JAHERMA ug/L 0.2 1 EPA 200.8 06/04/2015 20:01 JAHERMA ug/L 0.3 1 EPA 200.8 06/04/2015 20:01 JAHERMA ug/L 1 1 EPA 200.8 06/06/2015 10:36 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:36 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:36 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:36 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:36 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:36 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:36 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:36 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:36 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:36 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:36 SLS2560 ug/L 0.2 1 EPA 200.8 06/06/2015 10:36 SLS2560 ug/L 0.3 1 EPA 200.8 06/06/2015 10:36 SLS2560 Vendor Method V_SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 05/27/201514:10 AGIBBS5 mg/L 0.1 1 SM5310C/EPA9060A 06/02/201513:44 TJA7067 mg/L 5 1 SM2540D 05/27/2015 09:08 AGIBBS5 Certificate of Laboratory Analysis Page 6 of 104 This report shall not be reproduced, except in full. Order # J15050625 Site: MW-02BR Collection Date: 21 -May -15 8:54 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) EPA 300.0 05/27/2015 20:31 Vendor Parameter Complete EPA 300.0 05/27/2015 20:31 NITRITE + NITRATE (COLORIMETRIC) 1 EPA 245.1 Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 INORGANIC IONS BY IC ACPAYNE 1 EPA 200.7 Chloride 5.4 mg/L 0.1 Sulfate 56 mg/L 1 MERCURY (COLD VAPOR) IN WATER MHALL3 1 Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) 05/28/2015 10:04 MHALL3 Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP EPA 200.7 05/28/2015 10:04 MHALL3 Aluminum (AI) 0.020 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) 0.063 mg/L 0.05 Iron (Fe) 0.012 mg/L 0.01 Manganese (Mn) 0.027 mg/L 0.005 Strontium (Sr) 0.079 mg/L 0.005 Zinc (Zn) 0.008 mg/L 0.005 UNDIGESTED METALS BY ICP EPA 200.7 05/29/2015 12:21 SLS2560 Calcium (Ca) 35.1 mg/L 0.01 Magnesium (Mg) 0.689 mg/L 0.005 Potassium (K) 3.41 mg/L 0.1 Sodium (Na) 16.8 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.050 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) 0.064 mg/L 0.05 Iron (Fe) 0.061 mg/L 0.01 Manganese (Mn) 0.025 mg/L 0.005 Strontium (Sr) 0.075 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2015015707 Matrix: GW -WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/29/2015 14:11 LSTARL1 1 EPA 300.0 05/27/2015 20:31 BGN9034 10 EPA 300.0 05/27/2015 20:31 BGN9034 1 EPA 245.1 05/29/2015 11:21 ACPAYNE 1 EPA 245.1 06/01/2015 14:23 ACPAYNE 1 EPA 200.7 05/28/2015 10:04 MHALL3 1 EPA 200.7 05/28/2015 10:04 MHALL3 1 EPA 200.7 05/28/2015 10:04 MHALL3 1 EPA 200.7 05/28/2015 10:04 MHALL3 1 EPA 200.7 05/28/2015 10:04 MHALL3 1 EPA 200.7 05/28/2015 10:04 MHALL3 1 EPA 200.7 05/28/2015 10:04 MHALL3 1 EPA 200.7 05/28/2015 10:10 MHH7131 1 EPA 200.7 05/28/2015 10:10 MHH7131 1 EPA 200.7 05/28/2015 10:10 MHH7131 1 EPA 200.7 05/28/2015 10:10 MHH7131 1 EPA 200.7 05/29/2015 12:21 SLS2560 1 EPA 200.7 05/29/2015 12:21 SLS2560 1 EPA 200.7 05/29/2015 12:21 SLS2560 1 EPA 200.7 05/29/2015 12:21 SLS2560 1 EPA 200.7 05/29/2015 12:21 SLS2560 1 EPA 200.7 05/29/2015 12:21 SLS2560 1 EPA 200.7 05/29/2015 12:21 SLS2560 Certificate of Laboratory Analysis Page 7 of 104 This report shall not be reproduced, except in full. Order # J15050625 Site: MW-02BR Sample #: 2015015707 Collection Date: 21 -May -15 8:54 AM Matrix: GW -WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DISSOLVED METALS BY ICP -MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 06/04/2015 20:05 JAHERMA Arsenic (As) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:05 JAHERMA Beryllium (Be) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:05 JAHERMA Cadmium (Cd) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:05 JAHERMA Chromium (Cr) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:05 JAHERMA Cobalt (Co) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:05 JAHERMA Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/04/2015 20:05 JAHERMA Lead (Pb) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:05 JAHERMA Molybdenum (Mo) 9.70 ug/L 1 1 EPA 200.8 06/04/2015 20:05 JAHERMA Nickel (Ni) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:05 JAHERMA Selenium (Se) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:05 JAHERMA Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/04/2015 20:05 JAHERMA Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 06/04/2015 20:05 JAHERMA TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) <1 ug/L 1 1 EPA 200.8 06/06/2015 10:22 SLS2560 Arsenic (As) <1 ug/L 1 1 EPA 200.8 06/06/2015 10:22 SLS2560 Beryllium (Be) <1 ug/L 1 1 EPA 200.8 06/06/2015 10:22 SLS2560 Cadmium (Cd) <1 ug/L 1 1 EPA 200.8 06/06/2015 10:22 SLS2560 Chromium (Cr) <1 ug/L 1 1 EPA 200.8 06/06/2015 10:22 SLS2560 Cobalt (Co) <1 ug/L 1 1 EPA 200.8 06/06/2015 10:22 SLS2560 Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/06/2015 10:22 SLS2560 Lead (Pb) <1 ug/L 1 1 EPA 200.8 06/06/2015 10:22 SLS2560 Molybdenum (Mo) 9.45 ug/L 1 1 EPA 200.8 06/06/2015 10:22 SLS2560 Nickel (Ni) <1 ug/L 1 1 EPA 200.8 06/06/2015 10:22 SLS2560 Selenium (Se) <1 ug/L 1 1 EPA 200.8 06/06/2015 10:22 SLS2560 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/06/2015 10:22 SLS2560 Vanadium (V) Low Level 0.373 ug/L 0.3 1 EPA 200.8 06/06/2015 10:22 SLS2560 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 180 mg/L 25 1 SM2540C 05/27/201514:10 AGIBBS5 Total Carbon TOC 0.878 mg/L 0.1 1 SM5310C/EPA9060A 06/02/201513:44 TJA7067 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 05/27/2015 09:08 AGIBBS5 Certificate of Laboratory Analysis Page 8 of 104 This report shall not be reproduced, except in full. Order # J15050625 Site: MW -06S Collection Date: 21 -May -15 8:51 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) EPA 300.0 05/28/2015 09:27 Vendor Parameter Complete EPA 300.0 05/28/2015 09:27 NITRITE + NITRATE (COLORIMETRIC) 1 EPA 245.1 Nitrite + Nitrate (Colorimetric) 0.051 mg-N/L 0.01 INORGANIC IONS BY IC ACPAYNE 1 EPA 200.7 Chloride 12 mg/L 1 Sulfate 130 mg/L 2.5 MERCURY (COLD VAPOR) IN WATER MHALL3 1 Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) 05/28/2015 10:07 MHALL3 Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP EPA 200.7 05/28/2015 10:07 MHALL3 Aluminum (AI) 0.019 mg/L 0.005 Barium (Ba) 0.085 mg/L 0.005 Boron (B) 1.09 mg/L 0.05 Iron (Fe) 0.163 mg/L 0.01 Manganese (Mn) 10.0 mg/L 0.005 Strontium (Sr) 0.139 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP EPA 200.7 05/29/2015 12:25 SLS2560 Calcium (Ca) 23.2 mg/L 0.01 Magnesium (Mg) 10.7 mg/L 0.005 Potassium (K) 2.34 mg/L 0.1 Sodium (Na) 14.6 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.062 mg/L 0.005 Barium (Ba) 0.083 mg/L 0.005 Boron (B) 1.05 mg/L 0.05 Iron (Fe) 0.225 mg/L 0.01 Manganese (Mn) 9.97 mg/L 0.005 Strontium (Sr) 0.141 mg/L 0.005 Zinc (Zn) 0.005 mg/L 0.005 Sample #: 2015015708 Matrix: GW -WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/29/2015 14:13 LSTARL1 10 EPA 300.0 05/28/2015 09:27 BGN9034 25 EPA 300.0 05/28/2015 09:27 BGN9034 1 EPA 245.1 05/29/2015 11:24 ACPAYNE 1 EPA 245.1 06/01/2015 14:25 ACPAYNE 1 EPA 200.7 05/28/2015 10:07 MHALL3 1 EPA 200.7 05/28/2015 10:07 MHALL3 1 EPA 200.7 05/28/2015 10:07 MHALL3 1 EPA 200.7 05/28/2015 10:07 MHALL3 1 EPA 200.7 05/28/2015 10:07 MHALL3 1 EPA 200.7 05/28/2015 10:07 MHALL3 1 EPA 200.7 05/28/2015 10:07 MHALL3 1 EPA 200.7 05/28/2015 10:14 MHH7131 1 EPA 200.7 05/28/2015 10:14 MHH7131 1 EPA 200.7 05/28/2015 10:14 MHH7131 1 EPA 200.7 05/28/2015 10:14 MHH7131 1 EPA 200.7 05/29/2015 12:25 SLS2560 1 EPA 200.7 05/29/2015 12:25 SLS2560 1 EPA 200.7 05/29/2015 12:25 SLS2560 1 EPA 200.7 05/29/2015 12:25 SLS2560 1 EPA 200.7 05/29/2015 12:25 SLS2560 1 EPA 200.7 05/29/2015 12:25 SLS2560 1 EPA 200.7 05/29/2015 12:25 SLS2560 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050625 Site: MW -06S Collection Date: 21 -May -15 8:51 AM Analyte Result DISSOLVED METALS BY ICP -MS Sample #: Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 6.66 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) < 1 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 6.17 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) < 1 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS ug/L TDS 220 Total Carbon 06/04/2015 20:10 TOC 0.345 TOTAL SUSPENDED SOLIDS 1 TSS < 5 Page 9 of 104 ug/L 1 1 Sample #: 2015015708 SLS2560 ug/L 1 1 Matrix: GW -WW SLS2560 Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 06/04/2015 20:10 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:10 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:10 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:10 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:10 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:10 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:10 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:10 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:10 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:10 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:10 JAHERMA ug/L 0.2 1 EPA 200.8 06/04/2015 20:10 JAHERMA ug/L 0.3 1 EPA 200.8 06/04/2015 20:10 JAHERMA ug/L 1 1 EPA 200.8 06/06/2015 10:41 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:41 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:41 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:41 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:41 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:41 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:41 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:41 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:41 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:41 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:41 SLS2560 ug/L 0.2 1 EPA 200.8 06/06/2015 10:41 SLS2560 ug/L 0.3 1 EPA 200.8 06/06/2015 10:41 SLS2560 Vendor Method V_SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 05/27/201514:10 AGIBBS5 mg/L 0.1 1 SM5310C/EPA9060A 06/02/201513:44 TJA7067 mg/L 5 1 SM2540D 05/27/2015 09:08 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050625 Site: MW -06D Collection Date: 21 -May -15 10:02 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) EPA 300.0 05/28/2015 09:45 Vendor Parameter Complete EPA 300.0 05/28/2015 09:45 NITRITE + NITRATE (COLORIMETRIC) 1 EPA 245.1 Nitrite + Nitrate (Colorimetric) 0.021 mg-N/L 0.01 INORGANIC IONS BY IC ACPAYNE 1 EPA 200.7 Chloride 11 mg/L 1 Sulfate 150 mg/L 2.5 MERCURY (COLD VAPOR) IN WATER MHALL3 1 Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) 05/28/2015 10:11 MHALL3 Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP EPA 200.7 05/28/2015 10:11 MHALL3 Aluminum (AI) 0.014 mg/L 0.005 Barium (Ba) 0.071 mg/L 0.005 Boron (B) 1.70 mg/L 0.05 Iron (Fe) 0.015 mg/L 0.01 Manganese (Mn) 4.58 mg/L 0.005 Strontium (Sr) 0.306 mg/L 0.005 Zinc (Zn) 0.008 mg/L 0.005 UNDIGESTED METALS BY ICP EPA 200.7 05/29/2015 12:29 SLS2560 Calcium (Ca) 43.2 mg/L 0.01 Magnesium (Mg) 10.6 mg/L 0.005 Potassium (K) 1.65 mg/L 0.1 Sodium (Na) 8.95 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.021 mg/L 0.005 Barium (Ba) 0.069 mg/L 0.005 Boron (B) 1.68 mg/L 0.05 Iron (Fe) 0.023 mg/L 0.01 Manganese (Mn) 4.48 mg/L 0.005 Strontium (Sr) 0.302 mg/L 0.005 Zinc (Zn) 0.006 mg/L 0.005 Page 10 of 104 Sample #: 2015015709 Matrix: GW -WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/29/2015 14:14 LSTARL1 10 EPA 300.0 05/28/2015 09:45 BGN9034 25 EPA 300.0 05/28/2015 09:45 BGN9034 1 EPA 245.1 05/29/2015 11:26 ACPAYNE 1 EPA 245.1 06/01/2015 14:27 ACPAYNE 1 EPA 200.7 05/28/2015 10:11 MHALL3 1 EPA 200.7 05/28/2015 10:11 MHALL3 1 EPA 200.7 05/28/2015 10:11 MHALL3 1 EPA 200.7 05/28/2015 10:11 MHALL3 1 EPA 200.7 05/28/2015 10:11 MHALL3 1 EPA 200.7 05/28/2015 10:11 MHALL3 1 EPA 200.7 05/28/2015 10:11 MHALL3 1 EPA 200.7 05/28/2015 10:18 MHH7131 1 EPA 200.7 05/28/2015 10:18 MHH7131 1 EPA 200.7 05/28/2015 10:18 MHH7131 1 EPA 200.7 05/28/2015 10:18 MHH7131 1 EPA 200.7 05/29/2015 12:29 SLS2560 1 EPA 200.7 05/29/2015 12:29 SLS2560 1 EPA 200.7 05/29/2015 12:29 SLS2560 1 EPA 200.7 05/29/2015 12:29 SLS2560 1 EPA 200.7 05/29/2015 12:29 SLS2560 1 EPA 200.7 05/29/2015 12:29 SLS2560 1 EPA 200.7 05/29/2015 12:29 SLS2560 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050625 Site: MW -06D Collection Date: 21 -May -15 10:02 AM Analyte Result DISSOLVED METALS BY ICP -MS Sample #: Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 4.17 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 1.11 Selenium (Se) < 1 Thallium (TI) Low Level 0.221 Vanadium (V) Low Level < 0.3 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 3.85 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 1.13 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS ug/L TDS 260 Total Carbon 06/04/2015 20:15 TOC 0.304 TOTAL SUSPENDED SOLIDS 1 TSS < 5 Page 11 of 104 ug/L 1 1 Sample #: 2015015709 SLS2560 ug/L 1 1 Matrix: GW -WW SLS2560 Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 06/04/2015 20:15 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:15 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:15 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:15 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:15 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:15 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:15 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:15 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:15 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:15 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 20:15 JAHERMA ug/L 0.2 1 EPA 200.8 06/04/2015 20:15 JAHERMA ug/L 0.3 1 EPA 200.8 06/04/2015 20:15 JAHERMA ug/L 1 1 EPA 200.8 06/06/2015 10:45 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:45 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:45 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:45 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:45 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:45 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:45 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:45 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:45 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:45 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 10:45 SLS2560 ug/L 0.2 1 EPA 200.8 06/06/2015 10:45 SLS2560 ug/L 0.3 1 EPA 200.8 06/06/2015 10:45 SLS2560 Vendor Method V_SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 05/27/201514:10 AGIBBS5 mg/L 0.1 1 SM5310C/EPA9060A 06/02/201513:44 TJA7067 mg/L 5 1 SM2540D 05/27/2015 09:08 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050625 Site: MW -04D Collection Date: 21 -May -15 11:25 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) BGN9034 1 EPA 300.0 Vendor Parameter Complete 1 EPA 245.1 05/29/2015 11:28 NITRITE + NITRATE (COLORIMETRIC) 1 EPA 245.1 06/01/2015 14:30 Nitrite + Nitrate (Colorimetric) 1.6 mg-N/L 0.01 INORGANIC IONS BY IC 05/28/2015 10:15 MHALL3 1 EPA 200.7 Chloride 3.1 mg/L 0.1 Sulfate 1.5 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER 05/28/2015 10:15 MHALL3 Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) MHH7131 1 EPA 200.7 Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP 1 EPA 200.7 05/28/2015 10:23 MHH7131 Aluminum (AI) 0.030 mg/L 0.005 Barium (Ba) 0.031 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.100 mg/L 0.005 Strontium (Sr) 0.028 mg/L 0.005 Zinc (Zn) 0.006 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 2.15 mg/L 0.01 Magnesium (Mg) 1.50 mg/L 0.005 Potassium (K) 1.04 mg/L 0.1 Sodium (Na) 2.49 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.049 mg/L 0.005 Barium (Ba) 0.032 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.034 mg/L 0.01 Manganese (Mn) 0.087 mg/L 0.005 Strontium (Sr) 0.027 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Page 12 of 104 Sample #: 2015015710 Matrix: GW -WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/29/2015 14:16 LSTARL1 1 EPA 300.0 05/27/2015 21:24 BGN9034 1 EPA 300.0 05/27/2015 21:24 BGN9034 1 EPA 245.1 05/29/2015 11:28 ACPAYNE 1 EPA 245.1 06/01/2015 14:30 ACPAYNE 1 EPA 200.7 05/28/2015 10:15 MHALL3 1 EPA 200.7 05/28/2015 10:15 MHALL3 1 EPA 200.7 05/28/2015 10:15 MHALL3 1 EPA 200.7 05/28/2015 10:15 MHALL3 1 EPA 200.7 05/28/2015 10:15 MHALL3 1 EPA 200.7 05/28/2015 10:15 MHALL3 1 EPA 200.7 05/28/2015 10:15 MHALL3 1 EPA 200.7 05/28/2015 10:23 MHH7131 1 EPA 200.7 05/28/2015 10:23 MHH7131 1 EPA 200.7 05/28/2015 10:23 MHH7131 1 EPA 200.7 05/28/2015 10:23 MHH7131 1 EPA 200.7 05/29/2015 12:33 SLS2560 1 EPA 200.7 05/29/2015 12:33 SLS2560 1 EPA 200.7 05/29/2015 12:33 SLS2560 1 EPA 200.7 05/29/2015 12:33 SLS2560 1 EPA 200.7 05/29/2015 12:33 SLS2560 1 EPA 200.7 05/29/2015 12:33 SLS2560 1 EPA 200.7 05/29/2015 12:33 SLS2560 Certificate of Laboratory Analysis Page 13 of 104 This report shall not be reproduced, except in full. Order # J15050625 Site: MW -04D Sample #: 2015015710 Collection Date: 21 -May -15 11:25 AM Matrix: GW -WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DISSOLVED METALS BY ICP -MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 06/04/2015 20:42 JAHERMA Arsenic (As) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:42 JAHERMA Beryllium (Be) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:42 JAHERMA Cadmium (Cd) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:42 JAHERMA Chromium (Cr) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:42 JAHERMA Cobalt (Co) 6.24 ug/L 1 1 EPA 200.8 06/04/2015 20:42 JAHERMA Copper (Cu) 1.31 ug/L 1 1 EPA 200.8 06/04/2015 20:42 JAHERMA Lead (Pb) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:42 JAHERMA Molybdenum (Mo) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:42 JAHERMA Nickel (Ni) 1.12 ug/L 1 1 EPA 200.8 06/04/2015 20:42 JAHERMA Selenium (Se) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:42 JAHERMA Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/04/2015 20:42 JAHERMA Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 06/04/2015 20:42 JAHERMA TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) <1 ug/L 1 1 EPA 200.8 06/06/2015 10:50 SLS2560 Arsenic (As) <1 ug/L 1 1 EPA 200.8 06/06/2015 10:50 SLS2560 Beryllium (Be) <1 ug/L 1 1 EPA 200.8 06/06/2015 10:50 SLS2560 Cadmium (Cd) <1 ug/L 1 1 EPA 200.8 06/06/2015 10:50 SLS2560 Chromium (Cr) <1 ug/L 1 1 EPA 200.8 06/06/2015 10:50 SLS2560 Cobalt (Co) 5.28 ug/L 1 1 EPA 200.8 06/06/2015 10:50 SLS2560 Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/06/2015 10:50 SLS2560 Lead (Pb) <1 ug/L 1 1 EPA 200.8 06/06/2015 10:50 SLS2560 Molybdenum (Mo) <1 ug/L 1 1 EPA 200.8 06/06/2015 10:50 SLS2560 Nickel (Ni) 1.07 ug/L 1 1 EPA 200.8 06/06/2015 10:50 SLS2560 Selenium (Se) <1 ug/L 1 1 EPA 200.8 06/06/2015 10:50 SLS2560 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/06/2015 10:50 SLS2560 Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 06/06/2015 10:50 SLS2560 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 33 mg/L 25 1 SM2540C 05/27/201514:10 AGIBBS5 Total Carbon TOC 0.138 mg/L 0.1 1 SM5310C/EPA9060A 06/02/201513:44 TJA7067 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 05/27/2015 09:08 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050625 Site: MW -01 BR Collection Date: 21 -May -15 10:59 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) BGN9034 1 EPA 300.0 Vendor Parameter Complete 1 EPA 245.1 05/29/2015 11:31 NITRITE + NITRATE (COLORIMETRIC) 1 EPA 245.1 06/01/2015 14:32 Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 INORGANIC IONS BY IC 05/28/2015 10:19 MHALL3 1 EPA 200.7 Chloride 1.2 mg/L 0.1 Sulfate 8.2 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER 05/28/2015 10:19 MHALL3 Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) MHH7131 1 EPA 200.7 Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP 1 EPA 200.7 05/28/2015 10:27 MHH7131 Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.016 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.218 mg/L 0.01 Manganese (Mn) 0.074 mg/L 0.005 Strontium (Sr) 0.078 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 14.1 mg/L 0.01 Magnesium (Mg) 3.10 mg/L 0.005 Potassium (K) 4.05 mg/L 0.1 Sodium (Na) 6.83 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.121 mg/L 0.005 Barium (Ba) 0.015 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.713 mg/L 0.01 Manganese (Mn) 0.077 mg/L 0.005 Strontium (Sr) 0.075 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Page 14 of 104 Sample #: 2015015711 Matrix: GW -WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/29/2015 14:17 LSTARL1 1 EPA 300.0 05/27/2015 21:42 BGN9034 1 EPA 300.0 05/27/2015 21:42 BGN9034 1 EPA 245.1 05/29/2015 11:31 ACPAYNE 1 EPA 245.1 06/01/2015 14:32 ACPAYNE 1 EPA 200.7 05/28/2015 10:19 MHALL3 1 EPA 200.7 05/28/2015 10:19 MHALL3 1 EPA 200.7 05/28/2015 10:19 MHALL3 1 EPA 200.7 05/28/2015 10:19 MHALL3 1 EPA 200.7 05/28/2015 10:19 MHALL3 1 EPA 200.7 05/28/2015 10:19 MHALL3 1 EPA 200.7 05/28/2015 10:19 MHALL3 1 EPA 200.7 05/28/2015 10:27 MHH7131 1 EPA 200.7 05/28/2015 10:27 MHH7131 1 EPA 200.7 05/28/2015 10:27 MHH7131 1 EPA 200.7 05/28/2015 10:27 MHH7131 1 EPA 200.7 05/29/2015 12:37 SLS2560 1 EPA 200.7 05/29/2015 12:37 SLS2560 1 EPA 200.7 05/29/2015 12:37 SLS2560 1 EPA 200.7 05/29/2015 12:37 SLS2560 1 EPA 200.7 05/29/2015 12:37 SLS2560 1 EPA 200.7 05/29/2015 12:37 SLS2560 1 EPA 200.7 05/29/2015 12:37 SLS2560 Certificate of Laboratory Analysis Page 15 of 104 This report shall not be reproduced, except in full. Order # J15050625 Site: MW -01 BR Sample #: 2015015711 Collection Date: 21 -May -15 10:59 AM Matrix: GW -WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DISSOLVED METALS BY ICP -MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 06/04/2015 20:56 JAHERMA Arsenic (As) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:56 JAHERMA Beryllium (Be) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:56 JAHERMA Cadmium (Cd) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:56 JAHERMA Chromium (Cr) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:56 JAHERMA Cobalt (Co) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:56 JAHERMA Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/04/2015 20:56 JAHERMA Lead (Pb) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:56 JAHERMA Molybdenum (Mo) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:56 JAHERMA Nickel (Ni) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:56 JAHERMA Selenium (Se) <1 ug/L 1 1 EPA 200.8 06/04/2015 20:56 JAHERMA Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/04/2015 20:56 JAHERMA Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 06/04/2015 20:56 JAHERMA TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:08 SLS2560 Arsenic (As) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:08 SLS2560 Beryllium (Be) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:08 SLS2560 Cadmium (Cd) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:08 SLS2560 Chromium (Cr) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:08 SLS2560 Cobalt (Co) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:08 SLS2560 Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/06/2015 11:08 SLS2560 Lead (Pb) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:08 SLS2560 Molybdenum (Mo) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:08 SLS2560 Nickel (Ni) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:08 SLS2560 Selenium (Se) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:08 SLS2560 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/06/2015 11:08 SLS2560 Vanadium (V) Low Level 0.322 ug/L 0.3 1 EPA 200.8 06/06/2015 11:08 SLS2560 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 110 mg/L 25 1 SM2540C 05/27/201514:10 AGIBBS5 Total Carbon TOC 0.220 mg/L 0.1 1 SM5310C/EPA9060A 06/02/201513:44 TJA7067 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 05/27/2015 09:08 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050625 Site: MW -01D Collection Date: 21 -May -15 11:30 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) BGN9034 1 EPA 300.0 Vendor Parameter Complete 1 EPA 245.1 05/29/2015 11:33 NITRITE + NITRATE (COLORIMETRIC) 1 EPA 245.1 06/01/2015 14:34 Nitrite + Nitrate (Colorimetric) 1.2 mg-N/L 0.01 INORGANIC IONS BY IC 05/28/2015 10:23 MHALL3 1 EPA 200.7 Chloride 2.9 mg/L 0.1 Sulfate 5.3 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER 05/28/2015 10:23 MHALL3 Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) MHH7131 1 EPA 200.7 Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP 1 EPA 200.7 05/28/2015 10:31 MHH7131 Aluminum (AI) 0.038 mg/L 0.005 Barium (Ba) 0.020 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.189 mg/L 0.01 Manganese (Mn) 0.188 mg/L 0.005 Strontium (Sr) 0.036 mg/L 0.005 Zinc (Zn) 0.026 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 3.04 mg/L 0.01 Magnesium (Mg) 2.45 mg/L 0.005 Potassium (K) 1.49 mg/L 0.1 Sodium (Na) 3.32 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.095 mg/L 0.005 Barium (Ba) 0.020 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.360 mg/L 0.01 Manganese (Mn) 0.221 mg/L 0.005 Strontium (Sr) 0.031 mg/L 0.005 Zinc (Zn) 0.024 mg/L 0.005 Page 16 of 104 Sample #: 2015015712 Matrix: GW -WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/29/2015 14:18 LSTARL1 1 EPA 300.0 05/27/2015 22:00 BGN9034 1 EPA 300.0 05/27/2015 22:00 BGN9034 1 EPA 245.1 05/29/2015 11:33 ACPAYNE 1 EPA 245.1 06/01/2015 14:34 ACPAYNE 1 EPA 200.7 05/28/2015 10:23 MHALL3 1 EPA 200.7 05/28/2015 10:23 MHALL3 1 EPA 200.7 05/28/2015 10:23 MHALL3 1 EPA 200.7 05/28/2015 10:23 MHALL3 1 EPA 200.7 05/28/2015 10:23 MHALL3 1 EPA 200.7 05/28/2015 10:23 MHALL3 1 EPA 200.7 05/28/2015 10:23 MHALL3 1 EPA 200.7 05/28/2015 10:31 MHH7131 1 EPA 200.7 05/28/2015 10:31 MHH7131 1 EPA 200.7 05/28/2015 10:31 MHH7131 1 EPA 200.7 05/28/2015 10:31 MHH7131 1 EPA 200.7 05/29/2015 12:52 SLS2560 1 EPA 200.7 05/29/2015 12:52 SLS2560 1 EPA 200.7 05/29/2015 12:52 SLS2560 1 EPA 200.7 05/29/2015 12:52 SLS2560 1 EPA 200.7 05/29/2015 12:52 SLS2560 1 EPA 200.7 05/29/2015 12:52 SLS2560 1 EPA 200.7 05/29/2015 12:52 SLS2560 Certificate of Laboratory Analysis Page 17 of 104 This report shall not be reproduced, except in full. Order # J15050625 Site: MW -01D Sample #: 2015015712 Collection Date: 21 -May -15 11:30 AM Matrix: GW -WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DISSOLVED METALS BY ICP -MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 06/04/2015 21:01 JAHERMA Arsenic (As) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:01 JAHERMA Beryllium (Be) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:01 JAHERMA Cadmium (Cd) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:01 JAHERMA Chromium (Cr) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:01 JAHERMA Cobalt (Co) 9.35 ug/L 1 1 EPA 200.8 06/04/2015 21:01 JAHERMA Copper (Cu) 1.15 ug/L 1 1 EPA 200.8 06/04/2015 21:01 JAHERMA Lead (Pb) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:01 JAHERMA Molybdenum (Mo) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:01 JAHERMA Nickel (Ni) 5.39 ug/L 1 1 EPA 200.8 06/04/2015 21:01 JAHERMA Selenium (Se) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:01 JAHERMA Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/04/2015 21:01 JAHERMA Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 06/04/2015 21:01 JAHERMA TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:12 SLS2560 Arsenic (As) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:12 SLS2560 Beryllium (Be) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:12 SLS2560 Cadmium (Cd) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:12 SLS2560 Chromium (Cr) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:12 SLS2560 Cobalt (Co) 9.45 ug/L 1 1 EPA 200.8 06/06/2015 11:12 SLS2560 Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/06/2015 11:12 SLS2560 Lead (Pb) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:12 SLS2560 Molybdenum (Mo) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:12 SLS2560 Nickel (Ni) 4.78 ug/L 1 1 EPA 200.8 06/06/2015 11:12 SLS2560 Selenium (Se) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:12 SLS2560 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/06/2015 11:12 SLS2560 Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 06/06/2015 11:12 SLS2560 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 41 mg/L 25 1 SM2540C 05/27/201514:10 AGIBBS5 Total Carbon TOC 0.263 mg/L 0.1 1 SM5310C/EPA9060A 06/02/201513:44 TJA7067 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 05/27/2015 09:08 AGIBBS5 Certificate of Laboratory Analysis Page 18 of 104 This report shall not be reproduced, except in full. Order # J15050625 Site: MW -15D Collection Date: 20 -May -15 3:45 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) BGN9034 1 EPA 300.0 Vendor Parameter Complete 1 EPA 245.1 05/29/2015 11:36 NITRITE + NITRATE (COLORIMETRIC) 1 EPA 245.1 06/01/2015 14:37 Nitrite + Nitrate (Colorimetric) 0.787 mg-N/L 0.01 INORGANIC IONS BY IC 05/28/2015 10:26 MHALL3 1 EPA 200.7 Chloride 7.7 mg/L 0.1 Sulfate 0.29 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER 05/28/2015 10:26 MHALL3 Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) MHH7131 1 EPA 200.7 Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP 1 EPA 200.7 05/28/2015 10:35 MHH7131 Aluminum (AI) 0.005 mg/L 0.005 Barium (Ba) 0.059 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.077 mg/L 0.01 Manganese (Mn) 0.080 mg/L 0.005 Strontium (Sr) 0.105 mg/L 0.005 Zinc (Zn) 0.009 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 7.15 mg/L 0.01 Magnesium (Mg) 2.18 mg/L 0.005 Potassium (K) 2.45 mg/L 0.1 Sodium (Na) 6.49 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.016 mg/L 0.005 Barium (Ba) 0.058 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.109 mg/L 0.01 Manganese (Mn) 0.087 mg/L 0.005 Strontium (Sr) 0.099 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2015015713 Matrix: GW -WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/29/2015 14:19 LSTARL1 1 EPA 300.0 05/27/2015 22:18 BGN9034 1 EPA 300.0 05/27/2015 22:18 BGN9034 1 EPA 245.1 05/29/2015 11:36 ACPAYNE 1 EPA 245.1 06/01/2015 14:37 ACPAYNE 1 EPA 200.7 05/28/2015 10:26 MHALL3 1 EPA 200.7 05/28/2015 10:26 MHALL3 1 EPA 200.7 05/28/2015 10:26 MHALL3 1 EPA 200.7 05/28/2015 10:26 MHALL3 1 EPA 200.7 05/28/2015 10:26 MHALL3 1 EPA 200.7 05/28/2015 10:26 MHALL3 1 EPA 200.7 05/28/2015 10:26 MHALL3 1 EPA 200.7 05/28/2015 10:35 MHH7131 1 EPA 200.7 05/28/2015 10:35 MHH7131 1 EPA 200.7 05/28/2015 10:35 MHH7131 1 EPA 200.7 05/28/2015 10:35 MHH7131 1 EPA 200.7 05/29/2015 12:56 SLS2560 1 EPA 200.7 05/29/2015 12:56 SLS2560 1 EPA 200.7 05/29/2015 12:56 SLS2560 1 EPA 200.7 05/29/2015 12:56 SLS2560 1 EPA 200.7 05/29/2015 12:56 SLS2560 1 EPA 200.7 05/29/2015 12:56 SLS2560 1 EPA 200.7 05/29/2015 12:56 SLS2560 Certificate of Laboratory Analysis Page 19 of 104 This report shall not be reproduced, except in full. Order # J15050625 Site: MW -15D Sample #: 2015015713 Collection Date: 20 -May -15 3:45 PM Matrix: GW -WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DISSOLVED METALS BY ICP -MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 06/04/2015 21:05 JAHERMA Arsenic (As) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:05 JAHERMA Beryllium (Be) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:05 JAHERMA Cadmium (Cd) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:05 JAHERMA Chromium (Cr) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:05 JAHERMA Cobalt (Co) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:05 JAHERMA Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/04/2015 21:05 JAHERMA Lead (Pb) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:05 JAHERMA Molybdenum (Mo) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:05 JAHERMA Nickel (Ni) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:05 JAHERMA Selenium (Se) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:05 JAHERMA Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/04/2015 21:05 JAHERMA Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 06/04/2015 21:05 JAHERMA TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:17 SLS2560 Arsenic (As) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:17 SLS2560 Beryllium (Be) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:17 SLS2560 Cadmium (Cd) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:17 SLS2560 Chromium (Cr) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:17 SLS2560 Cobalt (Co) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:17 SLS2560 Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/06/2015 11:17 SLS2560 Lead (Pb) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:17 SLS2560 Molybdenum (Mo) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:17 SLS2560 Nickel (Ni) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:17 SLS2560 Selenium (Se) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:17 SLS2560 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/06/2015 11:17 SLS2560 Vanadium (V) Low Level 0.502 ug/L 0.3 1 EPA 200.8 06/06/2015 11:17 SLS2560 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 72 mg/L 25 1 SM2540C 05/27/201514:10 AGIBBS5 Total Carbon TOC 0.209 mg/L 0.1 1 SM5310C/EPA9060A 06/02/201513:44 TJA7067 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 05/27/2015 09:08 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050625 Site: MW -09D Collection Date: 21 -May -15 12:03 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) EPA 353.2 05/29/2015 14:20 Vendor Parameter Complete EPA 300.0 05/28/2015 10:39 NITRITE + NITRATE (COLORIMETRIC) 50 EPA 300.0 Nitrite + Nitrate (Colorimetric) 0.083 mg-N/L 0.01 INORGANIC IONS BY IC ACPAYNE 1 EPA 245.1 Chloride 470 mg/L 10 Sulfate 270 mg/L 5 MERCURY (COLD VAPOR) IN WATER MHALL3 1 Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) 05/28/2015 10:30 MHALL3 Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP EPA 200.7 05/28/2015 10:30 MHALL3 Aluminum (AI) 0.037 mg/L 0.005 Barium (Ba) 0.233 mg/L 0.005 Boron (B) 4.63 mg/L 0.05 Iron (Fe) 1.59 mg/L 0.01 Manganese (Mn) 4.01 mg/L 0.005 Strontium (Sr) 1.98 mg/L 0.005 Zinc (Zn) 0.084 mg/L 0.005 UNDIGESTED METALS BY ICP EPA 200.7 05/29/2015 13:00 SLS2560 Calcium (Ca) 253 mg/L 0.1 Magnesium (Mg) 81.9 mg/L 0.005 Potassium (K) 7.31 mg/L 0.1 Sodium (Na) 31.0 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.056 mg/L 0.005 Barium (Ba) 0.237 mg/L 0.005 Boron (B) 4.62 mg/L 0.05 Iron (Fe) 2.17 mg/L 0.01 Manganese (Mn) 3.73 mg/L 0.005 Strontium (Sr) 1.89 mg/L 0.005 Zinc (Zn) 0.084 mg/L 0.005 Page 20 of 104 Sample #: 2015015714 Matrix: GW -WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/29/2015 14:20 LSTARL1 100 EPA 300.0 05/28/2015 10:39 BGN9034 50 EPA 300.0 05/28/2015 10:39 BGN9034 1 EPA 245.1 05/29/2015 11:38 ACPAYNE 1 EPA 245.1 06/01/2015 14:39 ACPAYNE 1 EPA 200.7 05/28/2015 10:30 MHALL3 1 EPA 200.7 05/28/2015 10:30 MHALL3 1 EPA 200.7 05/28/2015 10:30 MHALL3 1 EPA 200.7 05/28/2015 10:30 MHALL3 1 EPA 200.7 05/28/2015 10:30 MHALL3 1 EPA 200.7 05/28/2015 10:30 MHALL3 1 EPA 200.7 05/28/2015 10:30 MHALL3 10 EPA 200.7 05/28/2015 10:39 MHH7131 1 EPA 200.7 05/28/2015 10:39 MHH7131 1 EPA 200.7 05/28/2015 10:39 MHH7131 1 EPA 200.7 05/28/2015 10:39 MHH7131 1 EPA 200.7 05/29/2015 13:00 SLS2560 1 EPA 200.7 05/29/2015 13:00 SLS2560 1 EPA 200.7 05/29/2015 13:00 SLS2560 1 EPA 200.7 05/29/2015 13:00 SLS2560 1 EPA 200.7 05/29/2015 13:00 SLS2560 1 EPA 200.7 05/29/2015 13:00 SLS2560 1 EPA 200.7 05/29/2015 13:00 SLS2560 Certificate of Laboratory Analysis Page 21 of 104 This report shall not be reproduced, except in full. Order # J15050625 Site: MW -09D Sample #: 2015015714 Collection Date: 21 -May -15 12:03 PM Matrix: GW -WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DISSOLVED METALS BY ICP -MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 06/04/2015 21:10 JAHERMA Arsenic (As) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:10 JAHERMA Beryllium (Be) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:10 JAHERMA Cadmium (Cd) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:10 JAHERMA Chromium (Cr) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:10 JAHERMA Cobalt (Co) 16.9 ug/L 1 1 EPA 200.8 06/04/2015 21:10 JAHERMA Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/04/2015 21:10 JAHERMA Lead (Pb) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:10 JAHERMA Molybdenum (Mo) 2.82 ug/L 1 1 EPA 200.8 06/04/2015 21:10 JAHERMA Nickel (Ni) 8.33 ug/L 1 1 EPA 200.8 06/04/2015 21:10 JAHERMA Selenium (Se) 19.6 ug/L 1 1 EPA 200.8 06/04/2015 21:10 JAHERMA Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/04/2015 21:10 JAHERMA Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 06/04/2015 21:10 JAHERMA TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:22 SLS2560 Arsenic (As) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:22 SLS2560 Beryllium (Be) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:22 SLS2560 Cadmium (Cd) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:22 SLS2560 Chromium (Cr) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:22 SLS2560 Cobalt (Co) 17.8 ug/L 1 1 EPA 200.8 06/06/2015 11:22 SLS2560 Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/06/2015 11:22 SLS2560 Lead (Pb) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:22 SLS2560 Molybdenum (Mo) 2.19 ug/L 1 1 EPA 200.8 06/06/2015 11:22 SLS2560 Nickel (Ni) 10.4 ug/L 1 1 EPA 200.8 06/06/2015 11:22 SLS2560 Selenium (Se) 14.8 ug/L 1 1 EPA 200.8 06/06/2015 11:22 SLS2560 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/06/2015 11:22 SLS2560 Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 06/06/2015 11:22 SLS2560 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 1700 mg/L 25 1 SM2540C 05/27/201514:10 AGIBBS5 Total Carbon TOC 0.548 mg/L 0.1 1 SM5310C/EPA9060A 06/02/201513:44 TJA7067 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 05/27/2015 09:08 AGIBBS5 Certificate of Laboratory Analysis Page 22 of 104 This report shall not be reproduced, except in full. Order # J15050625 Site: MW-09BR Collection Date: 21 -May -15 2:05 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) LSTARL1 25 Vendor Parameter Complete 05/28/2015 11:15 NITRITE + NITRATE (COLORIMETRIC) 10 EPA Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 INORGANIC IONS BY IC EPA 245.1 05/29/2015 11:45 Chloride 200 mg/L 2.5 Sulfate 87 mg/L 1 MERCURY (COLD VAPOR) IN WATER EPA 200.7 Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) 200.7 05/28/2015 10:34 Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP 05/28/2015 10:34 MHALL3 Aluminum (AI) 0.006 mg/L 0.005 Barium (Ba) 0.096 mg/L 0.005 Boron (B) 0.554 mg/L 0.05 Iron (Fe) 1.39 mg/L 0.01 Manganese (Mn) 0.243 mg/L 0.005 Strontium (Sr) 0.788 mg/L 0.005 Zinc (Zn) 0.051 mg/L 0.005 UNDIGESTED METALS BY ICP MHH7131 1 EPA Calcium (Ca) 129 mg/L 0.1 Magnesium (Mg) 19.5 mg/L 0.005 Potassium (K) 17.8 mg/L 0.1 Sodium (Na) 24.6 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP EPA 200.7 Aluminum (AI) 0.012 mg/L 0.005 Barium (Ba) 0.100 mg/L 0.005 Boron (B) 0.530 mg/L 0.05 Iron (Fe) 2.54 mg/L 0.01 Manganese (Mn) 0.317 mg/L 0.005 Strontium (Sr) 0.746 mg/L 0.005 Zinc (Zn) 0.028 mg/L 0.005 Sample #: 2015015715 Matrix: GW -WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/29/2015 14:21 LSTARL1 25 EPA 300.0 05/28/2015 11:15 BGN9034 10 EPA 300.0 05/28/2015 11:15 BGN9034 1 EPA 245.1 05/29/2015 11:45 ACPAYNE 1 EPA 245.1 06/01/2015 14:41 ACPAYNE 1 EPA 200.7 05/28/2015 10:34 MHALL3 1 EPA 200.7 05/28/2015 10:34 MHALL3 1 EPA 200.7 05/28/2015 10:34 MHALL3 1 EPA 200.7 05/28/2015 10:34 MHALL3 1 EPA 200.7 05/28/2015 10:34 MHALL3 1 EPA 200.7 05/28/2015 10:34 MHALL3 1 EPA 200.7 05/28/2015 10:34 MHALL3 10 EPA 200.7 05/28/2015 10:43 MHH7131 1 EPA 200.7 05/28/2015 10:43 MHH7131 1 EPA 200.7 05/28/2015 10:43 MHH7131 1 EPA 200.7 05/28/2015 10:43 MHH7131 1 EPA 200.7 05/29/2015 13:04 SLS2560 1 EPA 200.7 05/29/2015 13:04 SLS2560 1 EPA 200.7 05/29/2015 13:04 SLS2560 1 EPA 200.7 05/29/2015 13:04 SLS2560 1 EPA 200.7 05/29/2015 13:04 SLS2560 1 EPA 200.7 05/29/2015 13:04 SLS2560 1 EPA 200.7 05/29/2015 13:04 SLS2560 Certificate of Laboratory Analysis Page 23 of 104 This report shall not be reproduced, except in full. Order # J15050625 Site: MW-09BR Sample #: 2015015715 Collection Date: 21 -May -15 2:05 PM Matrix: GW -WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DISSOLVED METALS BY ICP -MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 06/04/2015 21:14 JAHERMA Arsenic (As) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:14 JAHERMA Beryllium (Be) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:14 JAHERMA Cadmium (Cd) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:14 JAHERMA Chromium (Cr) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:14 JAHERMA Cobalt (Co) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:14 JAHERMA Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/04/2015 21:14 JAHERMA Lead (Pb) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:14 JAHERMA Molybdenum (Mo) 3.47 ug/L 1 1 EPA 200.8 06/04/2015 21:14 JAHERMA Nickel (Ni) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:14 JAHERMA Selenium (Se) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:14 JAHERMA Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/04/2015 21:14 JAHERMA Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 06/04/2015 21:14 JAHERMA TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:26 SLS2560 Arsenic (As) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:26 SLS2560 Beryllium (Be) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:26 SLS2560 Cadmium (Cd) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:26 SLS2560 Chromium (Cr) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:26 SLS2560 Cobalt (Co) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:26 SLS2560 Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/06/2015 11:26 SLS2560 Lead (Pb) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:26 SLS2560 Molybdenum (Mo) 2.48 ug/L 1 1 EPA 200.8 06/06/2015 11:26 SLS2560 Nickel (Ni) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:26 SLS2560 Selenium (Se) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:26 SLS2560 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/06/2015 11:26 SLS2560 Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 06/06/2015 11:26 SLS2560 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 860 mg/L 25 1 SM2540C 05/27/201514:10 AGIBBS5 Total Carbon TOC 0.827 mg/L 0.1 1 SM5310C/EPA9060A 06/02/201513:44 TJA7067 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 05/27/2015 09:08 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050625 Site: MW -09S Collection Date: 21 -May -15 10:49 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) EPA 353.2 05/29/2015 14:28 Vendor Parameter Complete EPA 300.0 05/29/2015 09:42 NITRITE + NITRATE (COLORIMETRIC) 100 EPA 300.0 Nitrite + Nitrate (Colorimetric) 0.666 mg-N/L 0.01 INORGANIC IONS BY IC ACPAYNE 1 EPA 245.1 Chloride 570 mg/L 10 Sulfate 270 mg/L 10 MERCURY (COLD VAPOR) IN WATER MHALL3 1 Mercury (Hg) 0.22 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) 05/28/2015 10:45 MHALL3 Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP EPA 200.7 05/28/2015 10:45 MHALL3 Aluminum (AI) 0.029 mg/L 0.005 Barium (Ba) 0.187 mg/L 0.005 Boron (B) 4.84 mg/L 0.05 Iron (Fe) 0.018 mg/L 0.01 Manganese (Mn) 3.87 mg/L 0.005 Strontium (Sr) 3.04 mg/L 0.005 Zinc (Zn) 0.040 mg/L 0.005 UNDIGESTED METALS BY ICP EPA 200.7 05/29/2015 13:08 SLS2560 Calcium (Ca) 296 mg/L M4 0.1 Magnesium (Mg) 87.7 mg/L M4 0.005 Potassium (K) 3.94 mg/L 0.1 Sodium (Na) 17.5 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.245 mg/L 0.005 Barium (Ba) 0.183 mg/L 0.005 Boron (B) 4.80 mg/L 0.05 Iron (Fe) 0.211 mg/L 0.01 Manganese (Mn) 3.63 mg/L 0.005 Strontium (Sr) 2.95 mg/L 0.005 Zinc (Zn) 0.049 mg/L 0.005 Page 24 of 104 Sample #: 2015015716 Matrix: GW -WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/29/2015 14:28 LSTARL1 100 EPA 300.0 05/29/2015 09:42 BGN9034 100 EPA 300.0 05/29/2015 09:42 BGN9034 1 EPA 245.1 05/29/2015 11:52 ACPAYNE 1 EPA 245.1 06/01/2015 14:49 ACPAYNE 1 EPA 200.7 05/28/2015 10:45 MHALL3 1 EPA 200.7 05/28/2015 10:45 MHALL3 1 EPA 200.7 05/28/2015 10:45 MHALL3 1 EPA 200.7 05/28/2015 10:45 MHALL3 1 EPA 200.7 05/28/2015 10:45 MHALL3 1 EPA 200.7 05/28/2015 10:45 MHALL3 1 EPA 200.7 05/28/2015 10:45 MHALL3 10 EPA 200.7 05/28/2015 10:56 MHH7131 1 EPA 200.7 05/28/2015 10:56 MHH7131 1 EPA 200.7 05/28/2015 10:56 MHH7131 1 EPA 200.7 05/28/2015 10:56 MHH7131 1 EPA 200.7 05/29/2015 13:08 SLS2560 1 EPA 200.7 05/29/2015 13:08 SLS2560 1 EPA 200.7 05/29/2015 13:08 SLS2560 1 EPA 200.7 05/29/2015 13:08 SLS2560 1 EPA 200.7 05/29/2015 13:08 SLS2560 1 EPA 200.7 05/29/2015 13:08 SLS2560 1 EPA 200.7 05/29/2015 13:08 SLS2560 Certificate of Laboratory Analysis Page 25 of 104 This report shall not be reproduced, except in full. Order # J15050625 Site: MW -09S Sample #: 2015015716 Collection Date: 21 -May -15 10:49 AM Matrix: GW -WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DISSOLVED METALS BY ICP -MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 06/04/2015 21:19 JAHERMA Arsenic (As) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:19 JAHERMA Beryllium (Be) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:19 JAHERMA Cadmium (Cd) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:19 JAHERMA Chromium (Cr) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:19 JAHERMA Cobalt (Co) 5.85 ug/L 1 1 EPA 200.8 06/04/2015 21:19 JAHERMA Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/04/2015 21:19 JAHERMA Lead (Pb) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:19 JAHERMA Molybdenum (Mo) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:19 JAHERMA Nickel (Ni) 3.46 ug/L 1 1 EPA 200.8 06/04/2015 21:19 JAHERMA Selenium (Se) 39.3 ug/L 1 1 EPA 200.8 06/04/2015 21:19 JAHERMA Thallium (TI) Low Level 0.213 ug/L 0.2 1 EPA 200.8 06/04/2015 21:19 JAHERMA Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 06/04/2015 21:19 JAHERMA TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:31 SLS2560 Arsenic (As) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:31 SLS2560 Beryllium (Be) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:31 SLS2560 Cadmium (Cd) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:31 SLS2560 Chromium (Cr) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:31 SLS2560 Cobalt (Co) 5.90 ug/L 1 1 EPA 200.8 06/06/2015 11:31 SLS2560 Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/06/2015 11:31 SLS2560 Lead (Pb) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:31 SLS2560 Molybdenum (Mo) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:31 SLS2560 Nickel (Ni) 3.92 ug/L 1 1 EPA 200.8 06/06/2015 11:31 SLS2560 Selenium (Se) 40.6 ug/L 1 1 EPA 200.8 06/06/2015 11:31 SLS2560 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/06/2015 11:31 SLS2560 Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 06/06/2015 11:31 SLS2560 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 1700 mg/L 25 1 SM2540C 05/27/201514:10 AGIBBS5 Total Carbon TOC 0.246 mg/L 0.1 1 SM5310C/EPA9060A 06/02/201513:44 TJA7067 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 05/27/2015 09:08 AGIBBS5 Certificate of Laboratory Analysis Page 26 of 104 This report shall not be reproduced, except in full. Order # J15050625 Site: MW -12D Collection Date: 21 -May -15 1:50 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) 10 EPA Vendor Parameter Complete BGN9034 1 NITRITE + NITRATE (COLORIMETRIC) 300.0 05/28/2015 19:46 Nitrite + Nitrate (Colorimetric) 1.4 mg-N/L 0.01 INORGANIC IONS BY IC ACPAYNE 1 EPA Chloride 9.9 mg/L 1 Sulfate 7.3 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER EPA 200.7 Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) 05/28/2015 10:57 MHALL3 Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP 1 EPA 200.7 Aluminum (AI) 0.060 mg/L 0.005 Barium (Ba) 0.060 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.157 mg/L 0.005 Strontium (Sr) 0.021 mg/L 0.005 Zinc (Zn) 0.033 mg/L 0.005 UNDIGESTED METALS BY ICP 200.7 05/28/2015 11:22 MHH7131 Calcium (Ca) 3.92 mg/L 0.01 Magnesium (Mg) 2.44 mg/L 0.005 Potassium (K) 0.969 mg/L 0.1 Sodium (Na) 4.80 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP 200.7 05/29/2015 13:22 Aluminum (AI) 0.170 mg/L 0.005 Barium (Ba) 0.061 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) 0.118 mg/L 0.01 Manganese (Mn) 0.155 mg/L 0.005 Strontium (Sr) 0.020 mg/L 0.005 Zinc (Zn) 0.029 mg/L 0.005 Sample #: 2015015717 Matrix: GW -WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/29/2015 14:31 LSTARL1 10 EPA 300.0 05/28/2015 19:46 BGN9034 1 EPA 300.0 05/28/2015 19:46 BGN9034 1 EPA 245.1 05/29/2015 11:54 ACPAYNE 1 EPA 245.1 06/01/2015 14:56 ACPAYNE 1 EPA 200.7 05/28/2015 10:57 MHALL3 1 EPA 200.7 05/28/2015 10:57 MHALL3 1 EPA 200.7 05/28/2015 10:57 MHALL3 1 EPA 200.7 05/28/2015 10:57 MHALL3 1 EPA 200.7 05/28/2015 10:57 MHALL3 1 EPA 200.7 05/28/2015 10:57 MHALL3 1 EPA 200.7 05/28/2015 10:57 MHALL3 1 EPA 200.7 05/28/2015 11:22 MHH7131 1 EPA 200.7 05/28/2015 11:22 MHH7131 1 EPA 200.7 05/28/2015 11:22 MHH7131 1 EPA 200.7 05/28/2015 11:22 MHH7131 1 EPA 200.7 05/29/2015 13:22 SLS2560 1 EPA 200.7 05/29/2015 13:22 SLS2560 1 EPA 200.7 05/29/2015 13:22 SLS2560 1 EPA 200.7 05/29/2015 13:22 SLS2560 1 EPA 200.7 05/29/2015 13:22 SLS2560 1 EPA 200.7 05/29/2015 13:22 SLS2560 1 EPA 200.7 05/29/2015 13:22 SLS2560 Certificate of Laboratory Analysis Page 27 of 104 This report shall not be reproduced, except in full. Order # J15050625 Site: MW -12D Sample #: 2015015717 Collection Date: 21 -May -15 1:50 PM Matrix: GW -WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DISSOLVED METALS BY ICP -MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 06/04/2015 21:24 JAHERMA Arsenic (As) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:24 JAHERMA Beryllium (Be) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:24 JAHERMA Cadmium (Cd) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:24 JAHERMA Chromium (Cr) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:24 JAHERMA Cobalt (Co) 2.34 ug/L 1 1 EPA 200.8 06/04/2015 21:24 JAHERMA Copper (Cu) 1.44 ug/L 1 1 EPA 200.8 06/04/2015 21:24 JAHERMA Lead (Pb) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:24 JAHERMA Molybdenum (Mo) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:24 JAHERMA Nickel (Ni) 1.23 ug/L 1 1 EPA 200.8 06/04/2015 21:24 JAHERMA Selenium (Se) <1 ug/L 1 1 EPA 200.8 06/04/2015 21:24 JAHERMA Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/04/2015 21:24 JAHERMA Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 06/04/2015 21:24 JAHERMA TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:44 SLS2560 Arsenic (As) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:44 SLS2560 Beryllium (Be) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:44 SLS2560 Cadmium (Cd) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:44 SLS2560 Chromium (Cr) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:44 SLS2560 Cobalt (Co) 2.15 ug/L 1 1 EPA 200.8 06/06/2015 11:44 SLS2560 Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/06/2015 11:44 SLS2560 Lead (Pb) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:44 SLS2560 Molybdenum (Mo) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:44 SLS2560 Nickel (Ni) 1.27 ug/L 1 1 EPA 200.8 06/06/2015 11:44 SLS2560 Selenium (Se) <1 ug/L 1 1 EPA 200.8 06/06/2015 11:44 SLS2560 Thallium (TI) Low Level 0.674 ug/L 0.2 1 EPA 200.8 06/06/2015 11:44 SLS2560 Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 06/06/2015 11:44 SLS2560 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 50 mg/L 25 1 SM2540C 05/27/201514:10 AGIBBS5 Total Carbon TOC 0.211 mg/L 0.1 1 SM5310C/EPA9060A 06/02/201513:44 TJA7067 TOTAL SUSPENDED SOLIDS TSS 5.0 mg/L 5 1 SM2540D 05/27/2015 09:08 AGIBBS5 Certificate of Laboratory Analysis Page 28 of 104 This report shall not be reproduced, except in full. Order # J15050625 Site: MW -03D Collection Date: 21 -May -15 2:50 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) LSTARL1 10 Vendor Parameter Complete 05/29/2015 10:15 NITRITE + NITRATE (COLORIMETRIC) 25 EPA Nitrite + Nitrate (Colorimetric) 0.029 mg-N/L 0.01 INORGANIC IONS BY IC EPA 245.1 05/29/2015 11:59 Chloride 11 mg/L 1 Sulfate 140 mg/L 2.5 MERCURY (COLD VAPOR) IN WATER EPA 200.7 Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) 200.7 05/28/2015 11:01 Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP 05/28/2015 11:01 MHALL3 Aluminum (AI) 0.032 mg/L 0.005 Barium (Ba) 0.032 mg/L 0.005 Boron (B) 0.541 mg/L 0.05 Iron (Fe) 15.9 mg/L 0.01 Manganese (Mn) 0.608 mg/L 0.005 Strontium (Sr) 0.248 mg/L 0.005 Zinc (Zn) 0.054 mg/L 0.005 UNDIGESTED METALS BY ICP MHH7131 1 EPA Calcium (Ca) 30.9 mg/L 0.01 Magnesium (Mg) 7.28 mg/L 0.005 Potassium (K) 4.32 mg/L 0.1 Sodium (Na) 20.6 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP EPA 200.7 Aluminum (AI) 0.073 mg/L 0.005 Barium (Ba) 0.037 mg/L 0.005 Boron (B) 0.469 mg/L 0.05 Iron (Fe) 12.7 mg/L 0.01 Manganese (Mn) 0.560 mg/L 0.005 Strontium (Sr) 0.250 mg/L 0.005 Zinc (Zn) 0.047 mg/L 0.005 Sample #: 2015015718 Matrix: GW -WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/29/2015 14:32 LSTARL1 10 EPA 300.0 05/29/2015 10:15 BGN9034 25 EPA 300.0 05/29/2015 10:15 BGN9034 1 EPA 245.1 05/29/2015 11:59 ACPAYNE 1 EPA 245.1 06/01/2015 14:58 ACPAYNE 1 EPA 200.7 05/28/2015 11:01 MHALL3 1 EPA 200.7 05/28/2015 11:01 MHALL3 1 EPA 200.7 05/28/2015 11:01 MHALL3 1 EPA 200.7 05/28/2015 11:01 MHALL3 1 EPA 200.7 05/28/2015 11:01 MHALL3 1 EPA 200.7 05/28/2015 11:01 MHALL3 1 EPA 200.7 05/28/2015 11:01 MHALL3 1 EPA 200.7 05/28/2015 11:26 MHH7131 1 EPA 200.7 05/28/2015 11:26 MHH7131 1 EPA 200.7 05/28/2015 11:26 MHH7131 1 EPA 200.7 05/28/2015 11:26 MHH7131 1 EPA 200.7 05/29/2015 13:26 SLS2560 1 EPA 200.7 05/29/2015 13:26 SLS2560 1 EPA 200.7 05/29/2015 13:26 SLS2560 1 EPA 200.7 05/29/2015 13:26 SLS2560 1 EPA 200.7 05/29/2015 13:26 SLS2560 1 EPA 200.7 05/29/2015 13:26 SLS2560 1 EPA 200.7 05/29/2015 13:26 SLS2560 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15050625 Site: MW -03D Collection Date: 21 -May -15 2:50 PM Analyte Result DISSOLVED METALS BY ICP -MS Sample #: Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) < 1 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) < 1 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) < 1 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 3.89 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS ug/L TDS 270 Total Carbon 06/04/2015 21:28 TOC 0.837 TOTAL SUSPENDED SOLIDS 1 TSS 70 Page 29 of 104 ug/L 1 1 Sample #: 2015015718 SLS2560 ug/L 1 Matrix: GW -WW 06/06/2015 11:49 Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 06/04/2015 21:28 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 21:28 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 21:28 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 21:28 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 21:28 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 21:28 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 21:28 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 21:28 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 21:28 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 21:28 JAHERMA ug/L 1 1 EPA 200.8 06/04/2015 21:28 JAHERMA ug/L 0.2 1 EPA 200.8 06/04/2015 21:28 JAHERMA ug/L 0.3 1 EPA 200.8 06/04/2015 21:28 JAHERMA ug/L 1 1 EPA 200.8 06/06/2015 11:49 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 11:49 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 11:49 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 11:49 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 11:49 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 11:49 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 11:49 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 11:49 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 11:49 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 11:49 SLS2560 ug/L 1 1 EPA 200.8 06/06/2015 11:49 SLS2560 ug/L 0.2 1 EPA 200.8 06/06/2015 11:49 SLS2560 ug/L 0.3 1 EPA 200.8 06/06/2015 11:49 SLS2560 Vendor Method V_SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 05/27/201514:10 AGIBBS5 mg/L 0.1 1 SM5310C/EPA9060A 06/02/201513:44 TJA7067 mg/L 5 1 SM2540D 05/27/2015 09:08 AGIBBS5 Certificate of Laboratory Analysis Page 30 of 104 This report shall not be reproduced, except in full. Order # J15050625 Site: Equipment Blank Collection Date: 21 -May -15 9:55 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) 1 EPA 300.0 Vendor Parameter Complete 1 EPA 300.0 05/28/2015 17:35 NITRITE + NITRATE (COLORIMETRIC) 1 EPA 245.1 05/29/2015 12:02 Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 INORGANIC IONS BY IC 05/28/2015 11:30 MHH7131 1 EPA 200.7 Chloride < 0.1 mg/L 0.1 Sulfate < 0.1 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER 05/29/2015 13:30 SLS2560 Mercury (Hg) < 0.05 ug/L 0.05 UNDIGESTED METALS BY ICP SLS2560 1 EPA 200.7 05/29/2015 13:30 Calcium (Ca) 0.014 mg/L 0.01 Magnesium (Mg) < 0.005 mg/L 0.005 Potassium (K) < 0.1 mg/L 0.1 Sodium (Na) < 0.05 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP 06/06/2015 12:07 SLS2560 Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Sample #: 2015015719 Matrix: GW -WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/29/2015 14:34 LSTARL1 1 EPA 300.0 05/28/2015 17:35 BGN9034 1 EPA 300.0 05/28/2015 17:35 BGN9034 1 EPA 245.1 05/29/2015 12:02 ACPAYNE 1 EPA 200.7 05/28/2015 11:30 MHH7131 1 EPA 200.7 05/28/2015 11:30 MHH7131 1 EPA 200.7 05/28/2015 11:30 MHH7131 1 EPA 200.7 05/28/2015 11:30 MHH7131 1 EPA 200.7 05/29/2015 13:30 SLS2560 1 EPA 200.7 05/29/2015 13:30 SLS2560 1 EPA 200.7 05/29/2015 13:30 SLS2560 1 EPA 200.7 05/29/2015 13:30 SLS2560 1 EPA 200.7 05/29/2015 13:30 SLS2560 1 EPA 200.7 05/29/2015 13:30 SLS2560 1 EPA 200.7 05/29/2015 13:30 SLS2560 1 EPA 200.8 06/06/2015 12:07 SLS2560 1 EPA 200.8 06/06/2015 12:07 SLS2560 1 EPA 200.8 06/06/2015 12:07 SLS2560 1 EPA 200.8 06/06/2015 12:07 SLS2560 1 EPA 200.8 06/06/2015 12:07 SLS2560 1 EPA 200.8 06/06/2015 12:07 SLS2560 1 EPA 200.8 06/06/2015 12:07 SLS2560 1 EPA 200.8 06/06/2015 12:07 SLS2560 1 EPA 200.8 06/06/2015 12:07 SLS2560 1 EPA 200.8 06/06/2015 12:07 SLS2560 1 EPA 200.8 06/06/2015 12:07 SLS2560 1 EPA 200.8 06/06/2015 12:07 SLS2560 1 EPA 200.8 06/06/2015 12:07 SLS2560 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY Certificate of Laboratory Analysis Page 31 of 104 This report shall not be reproduced, except in full. Order # J15050625 Site: Equipment Blank Collection Date: 21 -May -15 9:55 AM Analyte Result Units Qualifiers RDL DF SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS TDS < 25 mg/L 25 1 Total Carbon Sample #: 2015015719 Matrix: GW WW Method Analysis Date/Time Analyst Vendor Method V_ELE1 SM2540C 05/27/201514:10 AGIBBS5 TOC 0.138 mg/L 0.1 1 SM5310C/EPA9060A 06/02/201513:44 TJA7067 TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 05/27/2015 09:08 AGIBBS5 Certificate of Laboratory Analysis Page 32 of 104 This report shall not be reproduced, except in full. Order # J15050625 Site: Filter Blank Collection Date: 21 -May -15 9:55 AM Analyte Result Units Qualifiers RDL Mercury Dissolved (cold vapor) in Water (Filtered) EPA 245.1 06/01/2015 15:00 Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP 1 EPA 200.7 05/28/2015 11:05 Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 DISSOLVED METALS BY ICP -MS 1 EPA 200.8 06/04/2015 21:33 Antimony (Sb) < 1 ug/L 1 Arsenic (As) < 1 ug/L 1 Beryllium (Be) < 1 ug/L 1 Cadmium (Cd) < 1 ug/L 1 Chromium (Cr) < 1 ug/L 1 Cobalt (Co) < 1 ug/L 1 Copper (Cu) < 1 ug/L 1 Lead (Pb) < 1 ug/L 1 Molybdenum (Mo) < 1 ug/L 1 Nickel (Ni) < 1 ug/L 1 Selenium (Se) < 1 ug/L 1 Thallium (TI) Low Level < 0.2 ug/L 0.2 Vanadium (V) Low Level < 0.3 ug/L 0.3 Sample #: 2015015720 Matrix: GW WW DF Method Analysis Date/Time Analyst 1 EPA 245.1 06/01/2015 15:00 ACPAYNE 1 EPA 200.7 05/28/2015 11:05 MHALL3 1 EPA 200.7 05/28/2015 11:05 MHALL3 1 EPA 200.7 05/28/2015 11:05 MHALL3 1 EPA 200.7 05/28/2015 11:05 MHALL3 1 EPA 200.7 05/28/2015 11:05 MHALL3 1 EPA 200.7 05/28/2015 11:05 MHALL3 1 EPA 200.7 05/28/2015 11:05 MHALL3 1 EPA 200.8 06/04/2015 21:33 JAHERMA 1 EPA 200.8 06/04/2015 21:33 JAHERMA 1 EPA 200.8 06/04/2015 21:33 JAHERMA 1 EPA 200.8 06/04/2015 21:33 JAHERMA 1 EPA 200.8 06/04/2015 21:33 JAHERMA 1 EPA 200.8 06/04/2015 21:33 JAHERMA 1 EPA 200.8 06/04/2015 21:33 JAHERMA 1 EPA 200.8 06/04/2015 21:33 JAHERMA 1 EPA 200.8 06/04/2015 21:33 JAHERMA 1 EPA 200.8 06/04/2015 21:33 JAHERMA 1 EPA 200.8 06/04/2015 21:33 JAHERMA 1 EPA 200.8 06/04/2015 21:33 JAHERMA 1 EPA 200.8 06/04/2015 21:33 JAHERMA Certificate of Laboratory Analysis Page 33 of 104 This report shall not be reproduced, except in full. Order # J15050625 Site: MW -17A Collection Date: 21 -May -15 3:50 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) EPA 300.0 05/29/2015 10:31 Vendor Parameter Complete EPA 300.0 05/29/2015 10:31 NITRITE + NITRATE (COLORIMETRIC) 1 EPA 245.1 Nitrite + Nitrate (Colorimetric) 0.056 mg-N/L 0.01 INORGANIC IONS BY IC ACPAYNE 1 EPA 200.7 Chloride 390 mg/L 5 Sulfate 160 mg/L 5 MERCURY (COLD VAPOR) IN WATER MHALL3 1 Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) 05/28/2015 11:08 MHALL3 Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP EPA 200.7 05/28/2015 11:08 MHALL3 Aluminum (AI) 0.083 mg/L 0.005 Barium (Ba) 0.126 mg/L 0.005 Boron (B) 1.65 mg/L 0.05 Iron (Fe) 40.4 mg/L 0.01 Manganese (Mn) 14.9 mg/L 0.005 Strontium (Sr) 0.601 mg/L 0.005 Zinc (Zn) 0.077 mg/L 0.005 UNDIGESTED METALS BY ICP EPA 200.7 05/29/2015 13:44 SLS2560 Calcium (Ca) 166 mg/L 0.1 Magnesium (Mg) 51.0 mg/L 0.005 Potassium (K) 4.51 mg/L 0.1 Sodium (Na) 14.0 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 1.97 mg/L 0.005 Barium (Ba) 0.125 mg/L 0.005 Boron (B) 1.54 mg/L 0.05 Iron (Fe) 40.6 mg/L 0.01 Manganese (Mn) 11.9 mg/L 0.005 Strontium (Sr) 0.536 mg/L 0.005 Zinc (Zn) 0.048 mg/L 0.005 Sample #: 2015015721 Matrix: GW -WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/29/2015 14:35 LSTARL1 50 EPA 300.0 05/29/2015 10:31 BGN9034 50 EPA 300.0 05/29/2015 10:31 BGN9034 1 EPA 245.1 05/29/2015 12:04 ACPAYNE 1 EPA 245.1 06/01/2015 15:03 ACPAYNE 1 EPA 200.7 05/28/2015 11:08 MHALL3 1 EPA 200.7 05/28/2015 11:08 MHALL3 1 EPA 200.7 05/28/2015 11:08 MHALL3 1 EPA 200.7 05/28/2015 11:08 MHALL3 1 EPA 200.7 05/28/2015 11:08 MHALL3 1 EPA 200.7 05/28/2015 11:08 MHALL3 1 EPA 200.7 05/28/2015 11:08 MHALL3 10 EPA 200.7 05/28/2015 11:34 MHH7131 1 EPA 200.7 05/28/2015 11:34 MHH7131 1 EPA 200.7 05/28/2015 11:34 MHH7131 1 EPA 200.7 05/28/2015 11:34 MHH7131 1 EPA 200.7 05/29/2015 13:44 SLS2560 1 EPA 200.7 05/29/2015 13:44 SLS2560 1 EPA 200.7 05/29/2015 13:44 SLS2560 1 EPA 200.7 05/29/2015 13:44 SLS2560 1 EPA 200.7 05/29/2015 13:44 SLS2560 1 EPA 200.7 05/29/2015 13:44 SLS2560 1 EPA 200.7 05/29/2015 13:44 SLS2560 Certificate of Laboratory Analysis Page 34 of 104 This report shall not be reproduced, except in full. Order # J15050625 Site: MW -17A Sample #: 2015015721 Collection Date: 21 -May -15 3:50 PM Matrix: GW -WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DISSOLVED METALS BY ICP -MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 06/05/2015 14:07 JAHERMA Arsenic (As) 4.04 ug/L 1 1 EPA 200.8 06/05/2015 14:07 JAHERMA Beryllium (Be) <1 ug/L 1 1 EPA 200.8 06/05/2015 14:07 JAHERMA Cadmium (Cd) <1 ug/L 1 1 EPA 200.8 06/05/2015 14:07 JAHERMA Chromium (Cr) 2.21 ug/L 1 1 EPA 200.8 06/05/2015 14:07 JAHERMA Cobalt (Co) 29.8 ug/L 1 1 EPA 200.8 06/05/2015 14:07 JAHERMA Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/05/2015 14:07 JAHERMA Lead (Pb) <1 ug/L 1 1 EPA 200.8 06/05/2015 14:07 JAHERMA Molybdenum (Mo) 1.07 ug/L 1 1 EPA 200.8 06/05/2015 14:07 JAHERMA Nickel (Ni) 7.13 ug/L 1 1 EPA 200.8 06/05/2015 14:07 JAHERMA Selenium (Se) <1 ug/L 1 1 EPA 200.8 06/05/2015 14:07 JAHERMA Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/05/2015 14:07 JAHERMA Vanadium (V) Low Level 0.347 ug/L 0.3 1 EPA 200.8 06/05/2015 14:07 JAHERMA TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) <1 ug/L 1 1 EPA 200.8 06/06/2015 12:12 SLS2560 Arsenic (As) 3.35 ug/L 1 1 EPA 200.8 06/06/2015 12:12 SLS2560 Beryllium (Be) <1 ug/L 1 1 EPA 200.8 06/06/2015 12:12 SLS2560 Cadmium (Cd) <1 ug/L 1 1 EPA 200.8 06/06/2015 12:12 SLS2560 Chromium (Cr) 3.92 ug/L 1 1 EPA 200.8 06/06/2015 12:12 SLS2560 Cobalt (Co) 25.8 ug/L 1 1 EPA 200.8 06/06/2015 12:12 SLS2560 Copper (Cu) 1.06 ug/L 1 1 EPA 200.8 06/06/2015 12:12 SLS2560 Lead (Pb) <1 ug/L 1 1 EPA 200.8 06/06/2015 12:12 SLS2560 Molybdenum (Mo) <1 ug/L 1 1 EPA 200.8 06/06/2015 12:12 SLS2560 Nickel (Ni) 4.77 ug/L 1 1 EPA 200.8 06/06/2015 12:12 SLS2560 Selenium (Se) <1 ug/L 1 1 EPA 200.8 06/06/2015 12:12 SLS2560 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/06/2015 12:12 SLS2560 Vanadium (V) Low Level 2.63 ug/L 0.3 1 EPA 200.8 06/06/2015 12:12 SLS2560 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 1200 mg/L 25 1 SM2540C 05/27/201514:10 AGIBBS5 Total Carbon TOC 3.9 mg/L 0.1 1 SM5310C/EPA9060A 06/02/201513:44 TJA7067 TOTAL SUSPENDED SOLIDS TSS 67 mg/L 5 1 SM2540D 05/27/2015 09:08 AGIBBS5 Certificate of Laboratory Analysis Page 35 of 104 This report shall not be reproduced, except in full. Order # J15050625 Site: ABMW-08 Collection Date: 21 -May -15 2:02 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) EPA 300.0 05/28/2015 20:36 Vendor Parameter Complete EPA 300.0 05/28/2015 20:36 NITRITE + NITRATE (COLORIMETRIC) 1 EPA 245.1 Nitrite + Nitrate (Colorimetric) 0.012 mg-N/L 0.01 INORGANIC IONS BY IC ACPAYNE 1 EPA 200.7 Chloride 28 mg/L 1 Sulfate < 0.1 mg/L 0.1 MERCURY (COLD VAPOR) IN WATER MHALL3 10 Mercury (Hg) < 0.05 ug/L 0.05 Mercury Dissolved (cold vapor) in Water (Filtered) 05/28/2015 11:12 MHALL3 Mercury (Hg) < 0.05 ug/L 0.05 DISSOLVED METALS BY ICP EPA 200.7 05/28/2015 11:12 MHALL3 Aluminum (AI) 0.172 mg/L 0.005 Barium (Ba) 0.495 mg/L 0.005 Boron (B) 0.268 mg/L 0.05 Iron (Fe) 107 mg/L 0.1 Manganese (Mn) 1.02 mg/L 0.005 Strontium (Sr) 1.05 mg/L 0.005 Zinc (Zn) 0.007 mg/L 0.005 UNDIGESTED METALS BY ICP EPA 200.7 05/29/2015 13:49 SLS2560 Calcium (Ca) 23.3 mg/L 0.01 Magnesium (Mg) 20.8 mg/L 0.005 Potassium (K) 13.5 mg/L 0.1 Sodium (Na) 13.3 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 0.174 mg/L 0.005 Barium (Ba) 0.489 mg/L 0.005 Boron (B) 0.263 mg/L 0.05 Iron (Fe) 108 mg/L 0.1 Manganese (Mn) 0.984 mg/L 0.005 Strontium (Sr) 1.02 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Sample #: 2015015722 Matrix: GW -WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 05/29/2015 14:36 LSTARL1 10 EPA 300.0 05/28/2015 20:36 BGN9034 1 EPA 300.0 05/28/2015 20:36 BGN9034 1 EPA 245.1 05/29/2015 12:06 ACPAYNE 1 EPA 245.1 06/01/2015 15:05 ACPAYNE 1 EPA 200.7 05/28/2015 11:12 MHALL3 1 EPA 200.7 05/28/2015 11:12 MHALL3 1 EPA 200.7 05/28/2015 11:12 MHALL3 10 EPA 200.7 05/28/2015 11:12 MHALL3 1 EPA 200.7 05/28/2015 11:12 MHALL3 1 EPA 200.7 05/28/2015 11:12 MHALL3 1 EPA 200.7 05/28/2015 11:12 MHALL3 1 EPA 200.7 05/28/2015 11:38 MHH7131 1 EPA 200.7 05/28/2015 11:38 MHH7131 1 EPA 200.7 05/28/2015 11:38 MHH7131 1 EPA 200.7 05/28/2015 11:38 MHH7131 1 EPA 200.7 05/29/2015 13:49 SLS2560 1 EPA 200.7 05/29/2015 13:49 SLS2560 1 EPA 200.7 05/29/2015 13:49 SLS2560 10 EPA 200.7 05/29/2015 13:49 SLS2560 1 EPA 200.7 05/29/2015 13:49 SLS2560 1 EPA 200.7 05/29/2015 13:49 SLS2560 1 EPA 200.7 05/29/2015 13:49 SLS2560 Certificate of Laboratory Analysis Page 36 of 104 This report shall not be reproduced, except in full. Order # J15050625 Site: ABMW-08 Sample #: 2015015722 Collection Date: 21 -May -15 2:02 PM Matrix: GW -WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DISSOLVED METALS BY ICP -MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 06/05/2015 14:21 JAHERMA Arsenic (As) 51.1 ug/L 1 1 EPA 200.8 06/05/2015 14:21 JAHERMA Beryllium (Be) <1 ug/L 1 1 EPA 200.8 06/05/2015 14:21 JAHERMA Cadmium (Cd) <1 ug/L 1 1 EPA 200.8 06/05/2015 14:21 JAHERMA Chromium (Cr) <1 ug/L 1 1 EPA 200.8 06/05/2015 14:21 JAHERMA Cobalt (Co) 2.34 ug/L 1 1 EPA 200.8 06/05/2015 14:21 JAHERMA Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/05/2015 14:21 JAHERMA Lead (Pb) <1 ug/L 1 1 EPA 200.8 06/05/2015 14:21 JAHERMA Molybdenum (Mo) 4.89 ug/L 1 1 EPA 200.8 06/05/2015 14:21 JAHERMA Nickel (Ni) 1.16 ug/L 1 1 EPA 200.8 06/05/2015 14:21 JAHERMA Selenium (Se) 1.87 ug/L 1 1 EPA 200.8 06/05/2015 14:21 JAHERMA Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/05/2015 14:21 JAHERMA Vanadium (V) Low Level 0.788 ug/L 0.3 1 EPA 200.8 06/05/2015 14:21 JAHERMA TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) <1 ug/L 1 1 EPA 200.8 06/06/2015 12:16 SLS2560 Arsenic (As) 42.4 ug/L 1 1 EPA 200.8 06/06/2015 12:16 SLS2560 Beryllium (Be) <1 ug/L 1 1 EPA 200.8 06/06/2015 12:16 SLS2560 Cadmium (Cd) <1 ug/L 1 1 EPA 200.8 06/06/2015 12:16 SLS2560 Chromium (Cr) <1 ug/L 1 1 EPA 200.8 06/06/2015 12:16 SLS2560 Cobalt (Co) 2.13 ug/L 1 1 EPA 200.8 06/06/2015 12:16 SLS2560 Copper (Cu) < 1 ug/L 1 1 EPA 200.8 06/06/2015 12:16 SLS2560 Lead (Pb) <1 ug/L 1 1 EPA 200.8 06/06/2015 12:16 SLS2560 Molybdenum (Mo) 4.26 ug/L 1 1 EPA 200.8 06/06/2015 12:16 SLS2560 Nickel (Ni) <1 ug/L 1 1 EPA 200.8 06/06/2015 12:16 SLS2560 Selenium (Se) 1.91 ug/L 1 1 EPA 200.8 06/06/2015 12:16 SLS2560 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 06/06/2015 12:16 SLS2560 Vanadium (V) Low Level 1.14 ug/L 0.3 1 EPA 200.8 06/06/2015 12:16 SLS2560 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 350 mg/L 25 1 SM2540C 05/27/201514:10 AGIBBS5 Total Carbon TOC 56 mg/L 3 30 SM5310C/EPA9060A 06/02/201513:44 TJA7067 TOTAL SUSPENDED SOLIDS TSS 160 mg/L 5 1 SM2540D 05/27/2015 09:08 AGIBBS5 Site: ABMW-08 Collection Date: 21 -May -15 2:02 PM Certificate of Laboratory Analysis Page 37 of 104 This report shall not be reproduced, except in full. Order # J15050625 Sample #: 2015015722 Matrix: GW -WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst Qualifiers: M4 The spike recovery value was unusable since the analyte concentration in the sample was disproportionate to the spike level. The associated Laboratory Control Spike recovery was acceptable. REPORT OF ANALYSES Page 38 of 104 EIP.ment One Inc. 6319-D Carolina Beach Rd. !/ Irvington, NC 28412 Rhone: 910 793-0128 Fax: 910 792-6853 ellab@ellab.com Duke Energy June 2, 2015 Laboratory Services Client Project Name AB GW Assessment water Asheville 13339 Hagers Ferry Road Bld. MG03A Client Project Number J15050625 Huntersville, NC 28078 PO Number Sample Matrix Sample Type Grab Date Received 05/26/2015 Date Analyzed 05/27/2015 Method SM 4500 S2- D Time Received 1400 Delivered by FedEx Received by JRC eOne ID Duke Energy ID Parameter Result Unit Dil DL Date Time Sampled Sampled 24845-1 CB -01 D Sulfide < 0.1 mg/L 1 0.1 05/21/15 1005 24845-2 MW -02 BR Sulfide < 0.1 mg/L 1 0.1 05/21/15 0854 24845-3 MW -06 S Sulfide < 0.1 mg/L 1 0.1 05/21/15 0851 24845-4 MW -06 D Sulfide < 0.1 mg/L 1 0.1 05/21/15 1002 24845-5 MW -04 D Sulfide < 0.1 mg/L 1 0.1 05/21/15 1125 24845-6" MW -01 BR Sulfide < 0.2 mg/L 2 0.1 05/21/15 1059 24845-7 MW -01 D Sulfide < 0.1 mg/L 1 0.1 05/21/15 1130 24845-8 MW -15 D Sulfide < 0.1 mg/L 1 0.1 05/21/15 1545 "Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits. — A Ken Smith, Laboratory Director 24845 Duke Report Packet Compiled byVIS NC Certifications: DW 37788 and DWQ DENR 604 REPORT OF ANALYSES Page 39 of 104 E[ler hent One Inc. 6319-D Carolina Beach Rd. Wilmington, NC 28412 Tone: 910 793-0128 Fax: 910 792-6853 ellab@ellab.corn Duke Energy June 2, 2015 Laboratory Services Client Project Name AB GW Assessment water Asheville 13339 Hagers Ferry Road Bld. MG03A Client Project Number J15050625 Huntersville, NC 28078 PO Number Sample Matrix Sample Type Grab Date Received 05/26/2015 Date Analyzed 05/27/2015 Method SM 4500 Sz- D Time Received 1400 Delivered by FedEx Received by JRC eOne ID Duke Energy ID Parameter Result Unit Dil DL Date Time Sampled Sampled 24845-9* MW -09 D Sulfide < 0.5 mg/L 5 0.1 05/21/15 1203 24845-10 MW -09 BR Sulfide < 0.1 mg/L 1 0.1 05/21/15 1405 24845-11* MW -09 S Sulfide < 0.5 mg/L 5 0.1 05/21/15 1049 24845-12 MW -12 D Sulfide < 0.1 mg/L 1 0.1 05/21/15 1350 24845-13 MW -03 D Sulfide < 0.1 mg/L 1 0.1 05/21/15 1450 24845-14 Equipment Blank Sulfide < 0.1 mg/L 1 0.1 05/21/15 0955 24845-15 MW -17 A Sulfide < 0.1 mg/L 1 0.1 05/21/15 1550 24845-16** ABMW-08 Sulfide < 4.0 mg/L 40 0.1 05/21/15 1402 *Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits. **Sample spike recovery outside of QA limits of 85-115%; unable to meet laboratory QA limits. Ken Smith, Laboratory Director 24845 Duke Report Packet Compiled by-'�-/-5 NC Certifications: DW 37788 and DWQ DENR 604 D W m L L V1 W U 0 ^ �IUOO �I� m f" JQa75 z 0 O i i I i i I Q Z z w C 0! a a �1 y I IM tai � 33 M = i c c WisHO Its T!f L— i J! Zig Q!� ��m h ZIP 3: Q i � x 0; p .5 Vi m !JJ ! w! g �I NS 0i -Y �I 0 LO M! ik m U! m 9 U.! E OL...._..._ Qi2' i o i I3PSA i � 1 im u6'1 W 2 1 i �5 I l0 1 1 j 1 j r ; A LM a i fQ i W i d ip$E7; 1 C7 C `t!j C U i I Q ; i I I_._._._.-.___1 J a W Z Page 40 of 104 OiAI WOE yBll yl l2WOISn� ..... .... ... ; ro 0 0 _ — •- eJ r _ r r r f ,•- r N i .fin c � o m o ` n (¢ ¢I m O L ¢ � n O• punoieuina pajisep aleD+pm aseald :4uepodwj '�awoasn� w 3 e m E g m m Q J O a V E E m E � E N E m l} 1 J Y OiAI WOE yBll yl l2WOISn� ..... .... ... ; ro 0 0 _ — •- eJ r _ r r r f ,•- r N i .fin c Q 1A m ¢ 4 I' (¢ ¢I o W U O L ¢ � n O• punoieuina pajisep aleD+pm aseald :4uepodwj '�awoasn� E E m E � E N l} 1 J Y J a _= U A ~ 9 m a7 rn n m '60 L D C a� m O Z v1 o - a � v u U � o E E E E ei m w � m m .aj m �..m 1= � E as U U d+ T T m+ a n E z z m w w Uj L o Uj Lu ww� a m _ m O9 m m C C C � w 4 E d Ir 11 U e(ementOne SAMPLE SUBMISSION FORM Hold Time Expiration 05.28.15 @ 1408 Client: Duke Energy LIMS No J15050606 Project ID Asheville H >9 Yes No Tem <_ 6°C Yes If No, Record If No, Record Samole Identification & Collection Information Lab Vde 41L&45 Analysis Due Date 05.27.15 Report Due Date 06.04.15 Date Rec -9 '�4.54fp IS Time Rec: --4265 X14 W Rec By JRC No Ref. Method: SM4500 S2 D Lab ID I Client ID Collection Date Collection Time Anal s Requested 1 CB -01 D 05/21/15 1005 id 2 MW -02 BR 05/21/15 0854 3 MW -06 S 05/21/15 0851 Sulfide 4 MW -06D 05/21/15 1002 5 MW -04 D 05/21/15 1125 ulfi 6 MW -01 BR 05/21/15 __ 1059 Sul i 7 MW -01 D 05/21/15 1130 ulfi 8 MW -15 D 05/21/15 1545 ulfid 9 MW -09 D 05/21/15__ 1203 itid 10 MW -09 BR 05/21/15 1405�— u i 11 MW -09 S 05/21/15 1049 Sulfi 12 MW -12 D 05/21/15 1350 u 13 MW -03 D 05/21/15 1450 Su i 14 Equipment Blank 05/21/15 0955 Sulfi 15 MW -17 A 05/21/15 1550 MlMdee16 ABMW-08 05/21/15 1402 NOTE for Sulfide The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected at 100 pg/L spike the sample to render the final spike concentration at — 500 pg/L Lab Communications All AB Groundwater Assessment yobs need a RL of 0.1 SS Page 1 of 1 Prep By / Date M /"\ 5- a 7 k IS SS by Labeled By / Date 5�2(, --N 5/26/2015 :15:12 PM ID Verification By /Date Page 42 of 104 METHOD: SM 4500S2- D ELEMENT ONE ELEMENT ASSAY: Sulfide Spectrophotometer Wave Length 664 UNITS OF ANSWER ug/mL DETECTION LIMIT u 1.000 CLIENT: Duke SPK LEVELLugj 5 Lab ID# 24845 ` Na2S•9H2O Lot # 40721 MAX ALIQUOT 10.00 Date: 5/27/15 STANDARD conc(ppm) X Time Analysis Begun 1530 Cal Std Lot: WC2-84-1 10 Time Analysis Ended 1719 QC Std Lot: WC2-84-2 10 Analyst: KAM STD ABSORPTION Y X Y ug STD SOLUTION STD ABS 0.600 0100 ---- - - - - ---8 -- ---oma 8 0.00 1.00 2.50 5.00 7,50 10.00 0.000 0.101 0.238 0.434 0:636 0.814 060D 0500 Ttoo °°°° Q300 0700 01w 0.00000 700 4oO 6.00 X 6.00 ,om 12 iW SAMPLE 1. D. SAMP ABS ug PER ALIQUOT ALI in mL PREP ANALYZED VOL in mL Slope ALI in mL TAKEN 0.081006593 RESULTS ug/mL Correlation LESS THAN % SPK REC 0.998948659 SPIKE LEVEL Std. B. 0.00 0.000 0.0000 10 10 10 < 0 Std. B. 1.00 0.102 0.8980 10 10 10 < 89.80% 1 Std. B. 2.50 0.236 2.6124 10 10 10 0.261 104.50% 2.5 Std. B. 5.00 0.45 5.3505 10 10 10 0.535 107.01% 5 Std. B. 7.50 0.629 7.6408 10 10 10 0.764 101.88% 7.5 Std. B. 10.00 0.807 9.9182 10 10 10 0.992 99.18% 10 LRB 0.000 0.0000 10 10 10 < 0 LRB SPK 0.444 5.2737 10 10 10 0.527 106% 5.0 QC 0.447 5.3121 10 10 10 0.531 106% 5.0 24845-1 0.007 -0.3175 10 10 10 24845-1 s k 0.399 4.6980 10 10 10 0.470 94% 5.0 24845-2 0.008 -0.3047 10 10 10 'Iwo 6p 24845-2 dup 0.008 -0.3047 10 1 10 10 < 0.1 24845-2 spk 0.412 4.8643 10 10 10 0.486 97% 5.0 24845-3 0.004 -0.3559 10 10 10 Q 24845-3 spk 0.390 4.5828 10 10 10 0.458 92% 5.0 24845-4 0.003 -0.3687 10 10 10, 24845-4 spk 0.401 4.7236 10 10 10 0.472 94% 5.0 24845-5 0.007 -0.3175 10 10 10 717-7777717, " x , 24845-5 spk 0.427 5.0562 10 10 10 0.506 101% 5.0 24845-6 0.009 -0.2919 10 10 10 < 24845-6 spk 0.271 3.0603 10 10 10 0.306 61% 5.0 24845-7 0.005 -0.3431 10 10 10 .. 24845-7 spk 0.392 4.6084 10 10 10 0.461 92% 5.0 24845-8 0.002 -0.3815 10 10 10 < 0.1 24845-8 s k 0.432 5.1202 10 10 10 0.512 102% 5.0 24845-9 0.012 -0.2536 10 10 10 < 24845-9 spk 0.343 3.9815 10 10 10 0.398 80% 5.0 Blank 0.000 0.0000 10 10 10 < QC 0.446 5.2993 10 10 10 0.530 106% 5.0 Submitted for QA/QC- Date: 5/27/15 By: (Print) KAM (sign): Page 1 of 3 Page 43 of 104 METHOD: SM 4500 S2- D ELEMENT ONE ALI in mL ANALYZED ELEMENT ASSAY: Sulfide 0.081006593 RESULTS ug/mL Spectrophotometer Wave Length 664' UNITS OF ANSWER ug/mL DETECTION LIMIT u 1.000' CLIENT: Duke SPK LEVELiuml 5 Lab ID# 24845 Std. B. 1.00 Na2S•9H20 Lot # 40721 MAX ALIQUOT 10.00 Date: 5/27/15 STANDARD conc(ppm) X Time Analysis Begun 1530 Cal Std Lot: WC2-84-1 10 Time Analysis Ended 1719 QC Std Lot: WC2-84-2 10 Analyst: KAM STD ABSORPTION Y X Y 10 10 0.535 o� _ , 00 T so __,000 ug STD SOLUTION STD awo 0.629 1 a'°° - ABS -- - ----- - e 0.00 1.00 2.50 5.00 7.50 10.00 ae 0.000-- a5w 7.5 0.101 Qd00 °3d 0.300 10 0.238 a200 z38 0.434 0.100 99.18% 0.636 0oaoaw zaa .0.o 6.00 Baa low ,z.w 0.814 x SAMPLE 1. D. SAMP ABS ug PER ALIQUOT ALI in mL ANALYZED PREP VOL in mL Slope ALI in mL TAKEN 0.081006593 RESULTS ug/mL Correlation LESS THAN % SPK REC 0.998948659 SPIKE LEVEL Std. B. 0.00 0.000 0.0000 10 10 10 < 0 Std. B. 1.00 0.102 0.8980 10 10 10 < 89.80% 1 Std. B. 2.50 0.236 2.6124 10 10 10 0.261 104.50% 2.5 Std. B. 5.00 0.450 5.3505 10 10 10 0.535 107.01% 5 Std. B. 7.50 0.629 7.6408 10 10 10 0.764 101.88% 7.5 Std. B. 10.00 0.807 9.9182 10 10 10 0.992 99.18% 10 LRB 0.000 0.0000 10 10 10 < 0 LRB SPK 0.444 5.2737 10 10 10 0.527 106% 5.0 QC 0.447 5.3121 10 10 10 0.531 106% 5.0 24845-10 0.017 -0.1896 10 10 10 24845-10 spk 0.391 4.5956 10 10 10 0.460 92% 5.0 24845-11 0.007 -0.3175 10 10 10 < 24845-11 dup 0.007 -0.3175 10 10 10 < 24845-11 spk 0.313 3.5976 10 10 10 0.360 72% 5.0 24845-12 0.009 -0.2919 10 10 10 041 - 24845-12 spk 0.372 4.3525 10 10 10 0.435 87% 5.0 24845-13 0.026 -0.0744 10 1 10 10 24845-13 spk 0.436 5.1714 10 10 10 0.517 103% 5.0 24845-14 0.003 -0.3687 10 10 10n� fl 24845-14 spk 0.426 5.0434 10 10 10 0.504 101% 5.0 24845-15 0.038 1 0.0791 10 10 10 24845-15 spk 0.411 4.8515 10 10 10 0.485 97% 5.0 24845-16 0.010 -0.2792 10 10 10 < 24845-16 spk 0.295 3.3673 10 10 10 0.337 67% 5.0 24845-6 24845-6 spk 0.009 0.380 -0.2919 1 4.4549 10 10 10 10 5_ 5 0.891 89% 5.0 24845-9 0.004 -0.3559 10 10 5 < 24845-9 spk 0.360 4.1990 10 10 5 0.840 84% 5.0 Blank 0.000 0.0000 10 10 10 < QC 0.444 1 5.2737 10 10 10 0.527 105% 5.0 Submitted for QA/QC- Date: 5/27/15 By: (Print) K:AM (sign): Page 2 of 3 Page 44 of 104 METHOD: SM 4500 S2- D ELEMENT ONE ELEMENT ASSAY: Sulfide Spectrophotometer Wave Length 664 UNITS OF ANSWER ug/mL DETECTION LIMIT u 1.000 CLIENT: Duke SPK LEVELLuM 5 Lab ID# 24845 Na2S•9H2O Lot # 40721 MAX ALIQUOT 10.00 Date: 5/27/15 STANDARD conc(ppm) X Time Analysis Begun 1530 Cal Std Lot: WC2-84-1 10 Time Analysis Ended 1719 QC Std Lot: WC2-84-2 10 Analyst: KAM STD ABSORPTION Y X Y ug STD SOLUTION STD ABS 40_ 0700 0.00 1.00 2:50 5.00 7.50 10.00 0.000 0.101 0.238 0.434 0.636 1 0.814 0.600 0500 0400 0400 °.200 .236 °,w 00000 200 so° eao x a.o° low ,za° --,.... SAMPLE I.D. SAMP ABS ug PER ALIQUOT ALI in mL ANALYZED PREP VOL in mL Sloe ALI in mL TAKEN 0.081006593 RESULTS ug/mL Correlation LESS THAN % SPK REC 0.998948659 SPIKE LEVEL Std. B. 0.00 0.000 0.0000 10 10 10 < 0 Std. B. 1.00 0.102 0.8980 10 10 10 < 89.80% 1 Std. B. 2.50 0.236 2.6124 10 10 10 0.261 104.50% 2.5 Std. B. 5.00 0.450 5.3505 10 10 10 0.535 107.01% 5 Std. B. 7.50 0.629 7.6408 10 10 10 0.764 101.88% 7.5 Std. B. 10.00 0.807 9.9182 10 10 10 0.992 99.18% 10 LRB 0.000 0.0000 10 10 10 < 0 LRB SPK 0.444 1 5.2737 10 10 10 0.527 106% 5.0 QC 0.447 5.3121 10 10 10 0.531 106% 5.0 24845-16 0.006 -0.3303 10 10 5 < 24845-16 spk 0.156 1.5889 10 10 5 0.318 32% 5.0 24845-11 0.007 -0.3175 10 10 5 < 24845-11 spk 0.336 3.8919 10 10 5 0.778 78% 5.0 24845-9 0.007 -0.3175 10 10 2 24845-9 spk 0.400 4.7108 10 10 2 2.355 94% 5.0 24845-11 0.010 -0.2792 10 10 2 24845-11 spk 0.392 4.6084 10 10 2 2.304 92% 5.0 24845-16 0.008 -0.3047 10 10 2 < 24845-16 spk 0.075 0.5525 10 10 2 < 11% 5.0 24845-16 0.008 -0.3047 10 10 1 < 24845-16 spk 0.136 1.3330 10 10 1 1.333 27% 5.0 24845-16 0.003 -0.3687 10 10 0.5 < 24845-16 spk 0.238 2.6380 10 10 0.5 5.276 53% 5.0 24845-16 0.007 -0.3175 10 10 0.25 mll,�O� 24845-16 spk 0.323 3.7256 10 10 0.25 14.902 75% 5.0 Blank 0.000 0.0000 10 10 10 < QC 0.444 5.2737 10 10 10 0.527 105% 5.0 Submitted for QA/QC- Date: 5/27/15 By: (Print) KAM (sign): Page 3 of 3 a SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle Project Name: AB GW Assessment Water - Asheville Project Number:J15050625 Lot Number:QE22059 Date Completed:06/01/2015 Grant Wilton Project Manager This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. *QE22059* Shealy Environmental Services, Inc. Page: 1 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Duke Energy Lot Number: QE22059 Project Name: AB GW Assessment Water - Asheville Project Number: J15050625 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page Shealy Environmental Services, Inc. Page: 2 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: QE22059 Project Name: AB GW Assessment Water - Asheville Project Number: J15050625 Sample Number Sample ID Matrix Date Sampled Date Received 001 2015015706 Aqueous 05/21/20151005 05/22/2015 002 2015015707 Aqueous 05/21/2015 0854 05/22/2015 003 2015015708 Aqueous 05/21/2015 0851 05/22/2015 004 2015015709 Aqueous 05/21/20151002 05/22/2015 005 2015015710 Aqueous 05/21/20151125 05/22/2015 006 2015015711 Aqueous 05/21/20151059 05/22/2015 007 2015015712 Aqueous 05/21/20151130 05/22/2015 008 2015015713 Aqueous 05/20/20151545 05/22/2015 009 2015015714 Aqueous 05/21/20151203 05/22/2015 010 2015015715 Aqueous 05/21/20151405 05/22/2015 011 2015015716 Aqueous 05/21/20151049 05/22/2015 012 2015015717 Aqueous 05/21/20151350 05/22/2015 013 2015015718 Aqueous 05/21/20151450 05/22/2015 014 2015015719 Aqueous 05/21/2015 0955 05/22/2015 015 2015015721 Aqueous 05/21/20151550 05/22/2015 016 2015015722 Aqueous 05/21/20151402 05/22/2015 (16 samples) Shealy Environmental Services, Inc. Page: 3 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 (29 detections) Shealy Environmental Services, Inc. Page: 4 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: QE22059 Project Name: AB GW Assessment Water - Asheville Project Number: J15050625 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2015015706 Aqueous Alkalinity SM 2320B- 20 mg/L 5 001 2015015706 Aqueous Bicarbonate Alkalinity SM 2320B- 20 mg/L 5 002 2015015707 Aqueous Alkalinity SM 2320B- 59 mg/L 7 002 2015015707 Aqueous Bicarbonate Alkalinity SM 2320B- 58 mg/L 7 002 2015015707 Aqueous Methane RSK - 175 100 ug/L 8 003 2015015708 Aqueous Methane RSK - 175 12 ug/L 10 004 2015015709 Aqueous Alkalinity SM 2320B- 11 mg/L 11 004 2015015709 Aqueous Bicarbonate Alkalinity SM 2320B- 11 mg/L 11 004 2015015709 Aqueous Methane RSK - 175 57 ug/L 12 006 2015015711 Aqueous Alkalinity SM 2320B- 54 mg/L 15 006 2015015711 Aqueous Bicarbonate Alkalinity SM 2320B- 54 mg/L 15 007 2015015712 Aqueous Alkalinity SM 2320B- 12 mg/L 17 007 2015015712 Aqueous Bicarbonate Alkalinity SM 2320B- 12 mg/L 17 008 2015015713 Aqueous Alkalinity SM 2320B- 30 mg/L 19 008 2015015713 Aqueous Bicarbonate Alkalinity SM 2320B- 30 mg/L 19 009 2015015714 Aqueous Alkalinity SM 2320B- 43 mg/L 21 009 2015015714 Aqueous Bicarbonate Alkalinity SM 2320B- 43 mg/L 21 010 2015015715 Aqueous Alkalinity SM 2320B- 73 mg/L 23 010 2015015715 Aqueous Bicarbonate Alkalinity SM 2320B- 73 mg/L 23 011 2015015716 Aqueous Alkalinity SM 2320B- 42 mg/L 25 011 2015015716 Aqueous Bicarbonate Alkalinity SM 2320B- 42 mg/L 25 013 2015015718 Aqueous Alkalinity SM 2320B- 26 mg/L 29 013 2015015718 Aqueous Bicarbonate Alkalinity SM 2320B- 26 mg/L 29 015 2015015721 Aqueous Alkalinity SM 2320B- 48 mg/L 33 015 2015015721 Aqueous Bicarbonate Alkalinity SM 232013- 48 mg/L 33 015 2015015721 Aqueous Methane RSK - 175 81 ug/L 34 016 2015015722 Aqueous Alkalinity SM 2320B- 180 mg/L 35 016 2015015722 Aqueous Bicarbonate Alkalinity SM 2320B- 180 mg/L 35 016 2015015722 Aqueous Methane RSK - 175 16000 ug/L 36 (29 detections) Shealy Environmental Services, Inc. Page: 4 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22059-001 Description: 2015015706 Matrix: Aqueous Date Sampled:05/21/2015 1005 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 23208-2011 1 05/28/2015 2051 HMA 76014 1 (Bicarbonate ) SM 2320B-2011 1 05/28/2015 2051 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/28/2015 2051 HMA PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 5 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 20 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 20 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 5 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22059-001 Description: 2015015706 Matrix: Aqueous Date Sampled:05/21/2015 1005 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/27/2015 2247 JJG 75920 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 6 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22059-002 Description: 2015015707 Matrix: Aqueous Date Sampled:05/21/2015 0854 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 23208-2011 1 05/28/2015 2057 HMA 76014 1 (Bicarbonate ) SM 2320B-2011 1 05/28/2015 2057 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/28/2015 2057 HMA PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 7 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 59 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 58 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 7 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22059-002 Description: 2015015707 Matrix: Aqueous Date Sampled:05/21/2015 0854 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/27/2015 2300 JJG 75920 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 100 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 8 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22059-003 Description: 2015015708 Matrix: Aqueous Date Sampled:05/21/2015 0851 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 23208-2011 1 05/28/2015 2101 HMA 76014 1 (Bicarbonate ) SM 2320B-2011 1 05/28/2015 2101 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/28/2015 2101 HMA PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 9 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 9 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22059-003 Description: 2015015708 Matrix: Aqueous Date Sampled:05/21/2015 0851 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/27/2015 2321 JJG 75920 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 12 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 10 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22059-004 Description: 2015015709 Matrix: Aqueous Date Sampled:05/21/2015 1002 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 23208-2011 1 05/28/2015 2106 HMA 76014 1 (Bicarbonate ) SM 2320B-2011 1 05/28/2015 2106 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/28/2015 2106 HMA PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 11 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 11 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 11 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 11 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22059-004 Description: 2015015709 Matrix: Aqueous Date Sampled:05/21/2015 1002 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/27/2015 2336 JJG 75920 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 57 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 12 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22059-005 Description: 2015015710 Matrix: Aqueous Date Sampled:05/21/2015 1125 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 23208-2011 1 05/28/20152110 HMA 76014 1 (Bicarbonate ) SM 2320B-2011 1 05/28/20152110 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/28/20152110 HMA PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 13 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 13 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22059-005 Description: 2015015710 Matrix: Aqueous Date Sampled:05/21/2015 1125 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/27/2015 2351 JJG 75920 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 14 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22059-006 Description: 2015015711 Matrix: Aqueous Date Sampled:05/21/2015 1059 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 23208-2011 1 05/28/2015 2117 HMA 76014 1 (Bicarbonate ) SM 2320B-2011 1 05/28/2015 2117 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/28/2015 2117 HMA PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 15 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 54 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 54 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 15 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22059-006 Description: 2015015711 Matrix: Aqueous Date Sampled:05/21/2015 1059 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/28/2015 1512 DCS 75994 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 16 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22059-007 Description: 2015015712 Matrix: Aqueous Date Sampled:05/21/2015 1130 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 23208-2011 1 05/28/2015 2122 HMA 76014 1 (Bicarbonate ) SM 2320B-2011 1 05/28/2015 2122 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/28/2015 2122 HMA PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 17 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 12 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 12 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 17 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22059-007 Description: 2015015712 Matrix: Aqueous Date Sampled:05/21/2015 1130 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/28/2015 1524 DCS 75994 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 18 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22059-008 Description: 2015015713 Matrix: Aqueous Date Sampled:05/20/2015 1545 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 23208-2011 1 05/28/2015 2127 HMA 76014 1 (Bicarbonate ) SM 2320B-2011 1 05/28/2015 2127 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/28/2015 2127 HMA PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 19 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 30 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 30 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 19 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22059-008 Description: 2015015713 Matrix: Aqueous Date Sampled:05/20/2015 1545 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/28/2015 1539 DCS 75994 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 20 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22059-009 Description: 2015015714 Matrix: Aqueous Date Sampled:05/21/2015 1203 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 23208-2011 1 05/28/2015 2147 HMA 76014 1 (Bicarbonate ) SM 2320B-2011 1 05/28/2015 2147 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/28/2015 2147 HMA PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 21 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 43 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 43 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 21 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22059-009 Description: 2015015714 Matrix: Aqueous Date Sampled:05/21/2015 1203 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/28/2015 1551 DCS 75994 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 22 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22059-010 Description: 2015015715 Matrix: Aqueous Date Sampled:05/21/2015 1405 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 23208-2011 1 05/28/2015 2153 HMA 76014 1 (Bicarbonate ) SM 2320B-2011 1 05/28/2015 2153 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/28/2015 2153 HMA PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 23 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 73 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 73 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 23 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22059-010 Description: 2015015715 Matrix: Aqueous Date Sampled:05/21/2015 1405 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/28/2015 1601 DCS 75994 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 24 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22059-011 Description: 2015015716 Matrix: Aqueous Date Sampled:05/21/2015 1049 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 23208-2011 1 05/28/2015 2159 HMA 76014 1 (Bicarbonate ) SM 2320B-2011 1 05/28/2015 2159 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/28/2015 2159 HMA PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 25 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 42 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 42 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 25 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22059-011 Description: 2015015716 Matrix: Aqueous Date Sampled:05/21/2015 1049 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/28/2015 1616 DCS 75994 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 26 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22059-012 Description: 2015015717 Matrix: Aqueous Date Sampled:05/21/2015 1350 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/28/2015 2238 HMA 76015 1 (Bicarbonate ) SM 2320B-2011 1 05/28/2015 2238 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/28/2015 2238 HMA PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 27 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 27 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22059-012 Description: 2015015717 Matrix: Aqueous Date Sampled:05/21/2015 1350 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/28/2015 1655 DCS 75994 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 28 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22059-013 Description: 2015015718 Matrix: Aqueous Date Sampled:05/21/2015 1450 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 23208-2011 1 05/28/2015 2255 HMA 76015 1 (Bicarbonate ) SM 2320B-2011 1 05/28/2015 2255 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/28/2015 2255 HMA PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 29 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 26 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 26 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 29 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22059-013 Description: 2015015718 Matrix: Aqueous Date Sampled:05/21/2015 1450 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/28/2015 1709 DCS 75994 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 30 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22059-014 Description: 2015015719 Matrix: Aqueous Date Sampled:05/21/2015 0955 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 23208-2011 1 05/28/2015 2301 HMA 76015 1 (Bicarbonate ) SM 2320B-2011 1 05/28/2015 2301 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/28/2015 2301 HMA PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 31 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 31 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22059-014 Description: 2015015719 Matrix: Aqueous Date Sampled:05/21/2015 0955 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/28/2015 1720 DCS 75994 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 32 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22059-015 Description: 2015015721 Matrix: Aqueous Date Sampled:05/21/2015 1550 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 05/28/2015 2308 HMA 76015 1 (Bicarbonate ) SM 2320B-2011 1 05/28/2015 2308 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/28/2015 2308 HMA PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 33 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 48 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 48 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 33 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22059-015 Description: 2015015721 Matrix: Aqueous Date Sampled:05/21/2015 1550 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 05/28/2015 2138 JJG 76030 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 81 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 34 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QE22059-016 Description: 2015015722 Matrix: Aqueous Date Sampled:05/21/2015 1402 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 23208-2011 1 05/28/2015 2314 HMA 76015 1 (Bicarbonate ) SM 2320B-2011 1 05/28/2015 2314 HMA 1 (Carbonate Al) SM 2320B-2011 1 05/28/2015 2314 HMA PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 35 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 180 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 180 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 35 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QE22059-016 Description: 2015015722 Matrix: Aqueous Date Sampled:05/21/2015 1402 Project Name: AB GW Assessment Water - Date Received: 05/22/2015 Project Number: J15050625 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 RSK - 175 50 05/29/2015 2243 JJG 76122 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 16000 500 ug/L 2 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 36 of 36 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 QC Summary Shealy Environmental Services, Inc. QC Data for Lot Number: QE22059 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - Ii Sample ID: QQ76014-001 Matrix: Aqueous Batch: 76014 Analytical Method: SM 2320B-2011 Parameter Result Q Dil PQL Units Analysis Date Alkalinity ND 1 10 mg/L 05/28/20151927 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22059 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - LCS Sample ID: QQ76014-002 Matrix: Aqueous Batch: 76014 Analytical Method: SM 2320B-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 100 97 1 97 90-110 05/28/20151933 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22059 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - MS Sample ID: QE22059-01 1 MS Matrix: Aqueous Batch: 76014 Analytical Method: SM 2320B-2011 Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 42 100 130 1 88 70-130 05/28/2015 2206 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22059 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - MSD Sample ID: QE22059-01 1 MD Matrix: Aqueous Batch: 76014 Analytical Method: SM 2320B-2011 Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Alkalinity 42 100 130 1 89 0.57 70-130 20 05/28/2015 2213 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22059 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - Ii Sample ID: QQ76015-001 Matrix: Aqueous Batch: 76015 Analytical Method: SM 2320B-2011 Parameter Result Q Dil PQL Units Analysis Date Alkalinity ND 1 10 mg/L 05/28/2015 2226 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22059 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - LCS Sample ID: QQ76015-002 Matrix: Aqueous Batch: 76015 Analytical Method: SM 2320B-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 100 99 1 99 90-110 05/28/2015 2233 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22059 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - MS Sample ID: QE22059-012MS Matrix: Aqueous Batch: 76015 Analytical Method: SM 2320B-2011 Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity ND 100 100 1 100 70-130 05/28/2015 2244 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22059 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - MSD Sample ID: QE22059-012MD Matrix: Aqueous Batch: 76015 Analytical Method: SM 2320B-2011 Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Alkalinity ND 100 100 1 103 3.0 70-130 20 05/28/2015 2250 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22059 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - MB Sample ID: QQ75920-001 Matrix: Aqueous Batch: 75920 Analytical Method: RSK - 175 Parameter Result Q Dil PQL Units Analysis Date Methane ND 1 10 ug/L 05/27/20151949 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22059 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCS Sample ID: QQ75920-002 Matrix: Aqueous Batch: 75920 Analytical Method: RSK - 175 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Methane 150 140 1 95 70-130 05/27/20151723 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22059 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCSD Sample ID: QQ75920-003 Matrix: Aqueous Batch: 75920 Analytical Method: RSK - 175 Spike Amount Result % Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Methane 150 140 1 92 2.7 70-130 30 05/27/20151744 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22059 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - MB Sample ID: QQ75994-001 Matrix: Aqueous Batch: 75994 Analytical Method: RSK - 175 Parameter Result Q Dil PQL Units Analysis Date Methane ND 1 10 ug/L 05/28/20151448 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22059 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCS Sample ID: QQ75994-002 Matrix: Aqueous Batch: 75994 Analytical Method: RSK - 175 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Methane 150 140 1 92 70-130 05/28/20151353 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22059 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCSD Sample ID: QQ75994-003 Matrix: Aqueous Batch: 75994 Analytical Method: RSK - 175 Spike Amount Result % Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Methane 150 110 1 74 22 70-130 30 05/28/20151413 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22059 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - MB Sample ID: QQ76030-001 Matrix: Aqueous Batch: 76030 Analytical Method: RSK - 175 Parameter Result Q Dil PQL Units Analysis Date Methane ND 1 10 ug/L 05/28/20151924 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22059 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCS Sample ID: QQ76030-002 Matrix: Aqueous Batch: 76030 Analytical Method: RSK - 175 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Methane 150 130 1 87 70-130 05/28/20151818 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22059 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCSD Sample ID: QQ76030-003 Matrix: Aqueous Batch: 76030 Analytical Method: RSK - 175 Spike Amount Result % Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Methane 150 130 1 86 1.6 70-130 30 05/28/20151829 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22059 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - MB Sample ID: QQ76122-001 Matrix: Aqueous Batch: 76122 Analytical Method: RSK - 175 Parameter Result Q Dil PQL Units Analysis Date Methane ND 1 10 ug/L 05/29/20151728 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22059 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCS Sample ID: QQ76122-002 Matrix: Aqueous Batch: 76122 Analytical Method: RSK - 175 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Methane 150 150 1 98 70-130 05/29/20151655 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22059 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCSD Sample ID: QQ76122-003 Matrix: Aqueous Batch: 76122 Analytical Method: RSK - 175 Spike Amount Result % Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Methane 150 140 1 93 5.9 70-130 30 05/29/20151707 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QE22059 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. w WOUWY9�N IROl *� a a c o cs 4 ce �e s � s •r c� � v �6 I I MCD FYI W till LU asap�aW a _ " t .......... i I F�7:J M, ° I. -- I LIU p 1 J a pw� g � � r 4' e it-i ss aC }C 7 }! } v Ell to f 5iiAA!!"ii!! F LILI1 li F'i 1"'+I 'I �. Ln C ply Y {F iL f R ' �I C `i3 lit QopproP, :ma}yyry i- 0 c �1 r 1 a cr 13 IC IL I QQRR `, o i M - ,P 2 1 1 _ ._._. __..1 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report lurs+oduul MswM6^;7� 4 �d iJ d � I y� y1II Z UI j t 3 t� f� -ion # t r � i ` W W v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. S1 Mliy Erroiinnncoow Seavicea, Inc. PRU 1 of I Darnowt Number. F -AV -+315 Etc*czs Dole: 111AM4 Revision M mtbea; 17 E,fialnC DMC: (w.r3cvl S Sample Receipt Checklist (RC) Cooler Inspected byra'dale.`�'s a�11 "*t 0: ."I Means of receipt: ❑ SLSI L] Client ❑ UPS ❑ Fe[1Fx Airborne Exp ether Yes o L Wtx uusteori seals pmeat on tltic coolerr' yes Lj I Wa Lj I NA Z 12. If custo& seals were 2rewnt, were they intact anal unbixi e-09 Cooler IDIDIiginttl iemperab= upgn receiptThuivod (GorrMW4) Lranperaturt-' tapOn Ivxeipt. Method; [] Temperature Blanl€ wins t Bottler IR Gun ID= IR Gun Corrtction Factor 0.0 Method of coolant' [/]Wet I= 0 Alin ice ElDry Ioc El None _ 3. It temperatum of any cooler GACoccde d 6.0°C, was Prraject Matt ager notified? Yes ❑ r;0 ❑ NA PM notified by SRC., phone, note (circle o=), other: (For coolers received via commercial gorier, PMR are to be notified immediate] _) Yes No ❑ NAV 4, Is the Got1merizd raitnor's pHu lcin slip arrwhed to this frirrn? Yes 2T No ❑1 5, Wm ffoper custcldy procedures rc _ uisheadl'received followed? Yes ❑ No ❑ NA 5m W= samples rel in uishexi • client tocommcrcial Upuner7 _ Yes No J f, Were gang ple IDs listed on this COC? ?, Were sample IDs listed on all :t le containersa Yes 1^i, ❑ Yes No ❑ Was colk,--tion date 8t time listed on the COC? Yes No ❑ 9. Was collection date & tim listed on all sam 1e: clontailiers? Yes Na ❑ 1 10, Did all container label infonnation 'ID date time agree with the: COC? YCs NO 11. WCIe tR�ts to ba pufonuLd fisted cit tine COC? Y IPr No ❑ 12, Did all smMles arrive in tbz proper containers for each test? Yes ❑ 13, Did ail containers arrive in good eandition artbr&M� lids on. etc.)? Yexa La 71= 14, Was adequate sarn le vviumes availablcl Pers No E] 15, Were all samples roceivad witlliti,'./3 tyle holding time or 48 hoturs- whishcvi:r corncs first? Ym ❑ I 24o 16. Were any sam les containers ? Yes ❑ No , Were there auv excxss ga les not listed om �C:t OO Yes ?iv �' NA -03+18. W= bubbles rewnt >" ea -size" "err 5mm in diameter in an VCA vials? y m, ElNo NA a 19, Were all aletalsiO%& eHEIvVnutdmt rca les received ata H €t'f <27 Yes ElNa ❑ NA f;J1t' 20. m all cyanidc amVor sulfide samples received ata pH>127 Yes 11 No ❑ NA B' 21. 1tE'ere 211 applicable NH3,rrKAcyanide+pheno1 (<0,2rnp'Q samples frrc of residual chlnrine? Yes ❑ No ❑ NA 22. Were collection rem eraturas docummtcd on the: Gil for NC'. sarta les? Ycs ❑ No ❑ NA 23' Wen client rvnarlm0rogacsts (i.e. reyt;t AW dilutions, MRIMSD designotioans, etc— -) orarnaetly transonbcd from the C OC. into thecomnierit section in LIM S? Yes 0 Iva 24. Was the uote mmmberused taken from the conlaincr larb& Sample Preservation (Ivlilst be conipleted for anis' sample.(s) incorrectly prc creed or with headspac4e.) sarvie,(sl w= recoived itxcxarrectly preserved and wcrc adjusted] acc ordin l y in seta le reccivin wilh IIZSDa,HN+t HICl Na0H using SR:9 S s) warc rovers +with baubbles >6 rant in diameter. S l s wrrc r eived with 'IRC >10.2 Iro If 421 is No) SC Drinking Water Project Sample(s) pi -I verified to be -} 2 by mate_ 5 Wsj were not received at let pH of <2 and were adjusted acc(dinglyr train SRO Setts le labels a ied b : + v' - Vanfied Date: I.]L C ommcnta: Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Ouke Energy Analytical Lahore" Limn cc CURWY Sample Log ------------------------- — 4.5hr"Irlic Unit CHAIN OF CUSTODY RECORn AND ANALYSIS REQUEST FORM - ---------------- - --- - - ----------------------------------------------- FO: rab-V AftiWLUcal tailor UMOR!Z Synterra EDD PB98 Cd MAI Cady Wm3tw 113 w" Tdul) Ofd GW -WW _1_ u M, DiST111BUTIOIN i3SA H.Rm F" Rd 45ou-15 Hwntam�., (d -C 25OFS d By Doom& Tl� nwGINAL W LAB COPY to CHEN I r"FM4d" SAVPtE FROOMM Few. LFG 1.112 L —7 GrkrdWdlar— NPOES— ... .... DrwIdnq Wakw U11 m4nwnt watvr ro: ACRA Waste COC REV DATE SHEALY ------------------ "n-anksaaa PO 1142089nuoola-as arnl! kwp. rwm- Dr"0w*uwtP qee our Ina ke ,4sMam�rNd! Yr EQ. aluroo JmL) 20M 40 mi Y* M mc ou 25o IMCMAS Element I P0 1142133 tMrjut Typa PET gtms "t M1 PET PET v i3tk3'" or 10 ri, zupi�wuw uAl dMworrMN b Sample Desc ul c6 2 F S 47 IW u rm 15 cammum Fv 11 g GPS Location 0 3 > 03 rkm jNFww. %f I U > 1 _j C) I Uzi I X 1 2 13 .3 0 2 so 1130 ix 10 7— All - C; Ir ?;]fir it Or I x 'FiftarMaRk mi- i gA -6t. --A- I L WAN�L--409- sfuld _Mwi 'rap A F---' t -L-] I -71 �r TOTAL elT Hells nA: I3•y f`:PF . MbfiffhMs tdf!7- V-1 ZZI (AIJ,04 ELEW-NTS Ily ICP_M% flIRMI. A9, j*q, ea, Co. Cr, Cu. Mu, NO. Rb., 5b, Sm. 11 (LL).. V (Ll -1 6Ll-MFiNTSvyICF' jTNMj: Ai, W,B.F*,Ma, 5r,Zo 1CP-ufkd1wQv1*d Ca, mg, K, r" HP try 24b 1 1llbbfflV43d MMtMFM 4110 M8141% 1CP, IM9,09 13 i Tatel 11 Roquowwd Turmearind '14 U00F, V E 7 Days 48 I -Ir ASAP - 'Add Cos[ YVIF APPIV i Tatel 11