NC0000396_J15050533report_20150823

DUE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Order Number: J15050533
Project Name: ASHEVILLE - AB GW ASSESSMENT WATER
Customer Name(s): Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker
Customer Address: 200 CP and L Drive
Arden,NC 28704
Lab Contact: Mary Ann Ogle Phone: [phone]
^ / Mary Ann Ogle
Report Authorized By: f 2015.06.08 09:58:26 pate: 6/8/2015
(Signature) ✓ -04'00'
Mary Ann Ogle
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Analytical Lab
Page 1 of 64
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
Collected By
Sample Description
2015015349
ASHEVILLE
19 -May -15 10:00 AM
illegible
PZ -26
2015015350
ASHEVILLE
19 -May -15 1:45 PM
illegible
PZ -24
2015015351
ASHEVILLE
19 -May -15 11:07 AM
illegible
CB -3
2015015352
ASHEVILLE
18 -May -15 4:11 PM
illegible
PZ -23
2015015353
ASHEVILLE
19 -May -15 11:56 AM
illegible
P-104
2015015354
ASHEVILLE
19 -May -15 2:23 PM
illegible
P-101
2015015355
ASHEVILLE
19 -May -15 1:58 PM
illegible
AMW-1B
2015015356
ASHEVILLE
19 -May -15 2:00 PM
illegible
Equipment Blank
2015015357
ASHEVILLE
19 -May -15 2:00 PM
illegible
Filter Blank
9 Total Samples
Analytical Lab
Page 2 of 64

Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals 0 Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable. 0 Yes F-] No
Report Sections Included:
E%-'] Job Summary Report
❑� Sample Identification
Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Analytical Lab
Page 3 of 64
❑d Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Mary Ann Ogle Date: 6/8/2015

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050533
Site: PZ -26
Collection Date: 19 -May -15 10:00 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
BGN9034
1 EPA 300.0
Vendor Parameter
Complete
1 EPA 245.1
05/28/2015 11:57
NITRITE + NITRATE (COLORIMETRIC)
1 EPA 245.1
05/29/2015 13:22
Nitrite + Nitrate (Colorimetric)
2.0
mg-N/L
0.01
INORGANIC IONS BY IC
05/20/2015 11:56
MHALL3
1 EPA 200.7
Chloride
2.8
mg/L
0.1
Sulfate
0.13
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
05/20/2015 11:56
MHALL3
Mercury (Hg)
0.13
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
MHALL3
1 EPA 200.7
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
1 EPA 200.7
05/20/2015 13:23
MHALL3
Aluminum (AI)
0.038
mg/L
0.005
Barium (Ba)
0.042
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.028
mg/L
0.005
Strontium (Sr)
0.009
mg/L
0.005
Zinc (Zn)
0.019
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
0.525
mg/L
0.01
Magnesium (Mg)
2.33
mg/L
0.005
Potassium (K)
0.781
mg/L
0.1
Sodium (Na)
2.00
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.213
mg/L
0.005
Barium (Ba)
0.045
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.189
mg/L
0.01
Manganese (Mn)
0.034
mg/L
0.005
Strontium (Sr)
0.009
mg/L
0.005
Zinc (Zn)
0.015
mg/L
0.005
Sample #: 2015015349
Matrix: GW -WW
Analytical Lab
Page 4 of 64
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1 EPA 353.2
05/27/2015 12:51
LSTARLI
1 EPA 300.0
05/22/2015 16:41
BGN9034
1 EPA 300.0
05/22/2015 16:41
BGN9034
1 EPA 245.1
05/28/2015 11:57
ACPAYNE
1 EPA 245.1
05/29/2015 13:22
ACPAYNE
1 EPA 200.7
05/20/2015 11:56
MHALL3
1 EPA 200.7
05/20/2015 11:56
MHALL3
1 EPA 200.7
05/20/2015 11:56
MHALL3
1 EPA 200.7
05/20/2015 11:56
MHALL3
1 EPA 200.7
05/20/2015 11:56
MHALL3
1 EPA 200.7
05/20/2015 11:56
MHALL3
1 EPA 200.7
05/20/2015 11:56
MHALL3
1 EPA 200.7
05/20/2015 13:23
MHALL3
1 EPA 200.7
05/20/2015 13:23
MHALL3
1 EPA 200.7
05/20/2015 13:23
MHALL3
1 EPA 200.7
05/20/2015 13:23
MHALL3
1 EPA 200.7
05/20/2015 15:46
MHALL3
1 EPA 200.7
05/20/2015 15:46
MHALL3
1 EPA 200.7
05/20/2015 15:46
MHALL3
1 EPA 200.7
05/20/2015 15:46
MHALL3
1 EPA 200.7
05/20/2015 15:46
MHALL3
1 EPA 200.7
05/20/2015 15:46
MHALL3
1 EPA 200.7
05/20/2015 15:46
MHALL3

Analytical Lab
Certificate of Laboratory Analysis Page 5 of 64
This report shall not be reproduced, except in full.
Order # J15050533
Site: PZ -26
Sample #: 2015015349
Collection Date: 19 -May -15 10:00
AM
Matrix: GW
-WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
DISSOLVED METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
06/04/2015 12:11
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:11
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:11
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:11
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:11
JAHERMA
Cobalt (Co)
2.10
ug/L
1
1
EPA 200.8
06/04/2015 12:11
JAHERMA
Copper (Cu)
1.77
ug/L
1
1
EPA 200.8
06/04/2015 12:11
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:11
JAHERMA
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:11
JAHERMA
Nickel (Ni)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:11
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:11
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
06/04/2015 12:11
JAHERMA
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
06/04/2015 12:11
JAHERMA
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
<1
ug/L
1
1
EPA 200.8
06/02/2015 17:39
SLS2560
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
06/02/2015 17:39
SLS2560
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
06/02/2015 17:39
SLS2560
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
06/02/2015 17:39
SLS2560
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
06/02/2015 17:39
SLS2560
Cobalt (Co)
2.23
ug/L
1
1
EPA 200.8
06/02/2015 17:39
SLS2560
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
06/02/2015 17:39
SLS2560
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
06/02/2015 17:39
SLS2560
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
06/02/2015 17:39
SLS2560
Nickel (Ni)
<1
ug/L
1
1
EPA 200.8
06/02/2015 17:39
SLS2560
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
06/02/2015 17:39
SLS2560
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
06/02/2015 17:39
SLS2560
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
06/02/2015 17:39
SLS2560
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
< 25
mg/L
25
1
SM2540C
05/20/2015 14:09
AGIBBS5
Total Carbon
TOC
0.193
mg/L
0.1
1
SM5310C/EPA9060A
05/26/201514:02
TJA7067
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
1
SM2540D
05/20/2015 10:25
AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050533
Site: PZ -24
Collection Date: 19 -May -15 1:45 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
05/22/2015 14:00
Vendor Parameter
Complete
EPA 300.0
05/22/2015 14:00
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
0.027
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
6.8
mg/L
1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
MHALL3
10
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/20/2015 12:07
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/20/2015 12:07
MHALL3
Aluminum (AI)
0.098
mg/L
0.005
Barium (Ba)
0.227
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
66.0
mg/L
0.1
Manganese (Mn)
1.95
mg/L
0.005
Strontium (Sr)
0.199
mg/L
0.005
Zinc (Zn)
0.028
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/20/2015 15:50
MHALL3
Calcium (Ca)
36.8
mg/L
0.01
Magnesium (Mg)
8.45
mg/L
0.005
Potassium (K)
6.78
mg/L
0.1
Sodium (Na)
5.24
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
2.48
mg/L
0.005
Barium (Ba)
0.243
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
69.2
mg/L
0.1
Manganese (Mn)
2.00
mg/L
0.005
Strontium (Sr)
0.202
mg/L
0.005
Zinc (Zn)
0.006
mg/L
0.005
Sample #: 2015015350
Matrix: GW -WW
Analytical Lab
Page 6 of 64
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
05/27/2015 12:54
LSTARLI
10
EPA 300.0
05/22/2015 14:00
BGN9034
1
EPA 300.0
05/22/2015 14:00
BGN9034
1
EPA 245.1
05/28/2015 12:00
ACPAYNE
1
EPA 245.1
05/29/2015 13:31
ACPAYNE
1
EPA 200.7
05/20/2015 12:07
MHALL3
1
EPA 200.7
05/20/2015 12:07
MHALL3
1
EPA 200.7
05/20/2015 12:07
MHALL3
10
EPA 200.7
05/20/2015 12:07
MHALL3
1
EPA 200.7
05/20/2015 12:07
MHALL3
1
EPA 200.7
05/20/2015 12:07
MHALL3
1
EPA 200.7
05/20/2015 12:07
MHALL3
1
EPA 200.7
05/20/2015 13:27
MHALL3
1
EPA 200.7
05/20/2015 13:27
MHALL3
1
EPA 200.7
05/20/2015 13:27
MHALL3
1
EPA 200.7
05/20/2015 13:27
MHALL3
1
EPA 200.7
05/20/2015 15:50
MHALL3
1
EPA 200.7
05/20/2015 15:50
MHALL3
1
EPA 200.7
05/20/2015 15:50
MHALL3
10
EPA 200.7
05/20/2015 15:50
MHALL3
1
EPA 200.7
05/20/2015 15:50
MHALL3
1
EPA 200.7
05/20/2015 15:50
MHALL3
1
EPA 200.7
05/20/2015 15:50
MHALL3

Analytical Lab
Certificate of Laboratory Analysis Page 7 of 64
This report shall not be reproduced, except in full.
Order # J15050533
Site: PZ -24
Sample #: 2015015350
Collection Date: 19 -May -15 1:45 PM
Matrix: GW
-WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
DISSOLVED METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
06/04/2015 12:25
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:25
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:25
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:25
JAHERMA
Chromium (Cr)
1.09
ug/L
1
1
EPA 200.8
06/04/2015 12:25
JAHERMA
Cobalt (Co)
3.94
ug/L
1
1
EPA 200.8
06/04/2015 12:25
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
06/04/2015 12:25
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:25
JAHERMA
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:25
JAHERMA
Nickel (Ni)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:25
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:25
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
06/04/2015 12:25
JAHERMA
Vanadium (V) Low Level
1.41
ug/L
0.3
1
EPA 200.8
06/04/2015 12:25
JAHERMA
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
<1
ug/L
1
1
EPA 200.8
06/02/2015 17:57
SLS2560
Arsenic (As)
1.11
ug/L
1
1
EPA 200.8
06/02/2015 17:57
SLS2560
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
06/02/2015 17:57
SLS2560
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
06/02/2015 17:57
SLS2560
Chromium (Cr)
4.49
ug/L
1
1
EPA 200.8
06/02/2015 17:57
SLS2560
Cobalt (Co)
4.35
ug/L
1
1
EPA 200.8
06/02/2015 17:57
SLS2560
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
06/02/2015 17:57
SLS2560
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
06/02/2015 17:57
SLS2560
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
06/02/2015 17:57
SLS2560
Nickel (Ni)
3.56
ug/L
1
1
EPA 200.8
06/02/2015 17:57
SLS2560
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
06/02/2015 17:57
SLS2560
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
06/02/2015 17:57
SLS2560
Vanadium (V) Low Level
4.25
ug/L
0.3
1
EPA 200.8
06/02/2015 17:57
SLS2560
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
260
mg/L
25
1
SM2540C
05/20/201514:09
AGIBBS5
Total Carbon
TOC
9.0
mg/L
0.1
1
SM5310C/EPA9060A
05/26/201514:02
TJA7067
TOTAL SUSPENDED SOLIDS
TSS
44
mg/L
5
1
SM2540D
05/20/201510:25
AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050533
Site: CB -3
Collection Date: 19 -May -15 11:07 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
05/26/2015 14:25
Vendor Parameter
Complete
EPA 300.0
05/26/2015 14:25
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
0.465
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
8.8
mg/L
0.1
Sulfate
150
mg/L
2.5
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
0.10
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/20/2015 12:04
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/20/2015 12:04
MHALL3
Aluminum (AI)
0.006
mg/L
0.005
Barium (Ba)
0.037
mg/L
0.005
Boron (B)
0.929
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.317
mg/L
0.005
Strontium (Sr)
0.575
mg/L
0.005
Zinc (Zn)
0.036
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/20/2015 15:54
MHALL3
Calcium (Ca)
34.2
mg/L
0.01
Magnesium (Mg)
6.40
mg/L
0.005
Potassium (K)
11.8
mg/L
0.1
Sodium (Na)
13.1
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.867
mg/L
0.005
Barium (Ba)
0.040
mg/L
0.005
Boron (B)
0.947
mg/L
0.05
Iron (Fe)
0.844
mg/L
0.01
Manganese (Mn)
0.331
mg/L
0.005
Strontium (Sr)
0.584
mg/L
0.005
Zinc (Zn)
0.029
mg/L
0.005
Sample #: 2015015351
Matrix: GW -WW
Analytical Lab
Page 8 of 64
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
05/27/2015 12:48
LSTARLI
1
EPA 300.0
05/26/2015 14:25
BGN9034
25
EPA 300.0
05/26/2015 14:25
BGN9034
1
EPA 245.1
05/28/2015 12:02
ACPAYNE
1
EPA 245.1
05/29/2015 13:34
ACPAYNE
1
EPA 200.7
05/20/2015 12:04
MHALL3
1
EPA 200.7
05/20/2015 12:04
MHALL3
1
EPA 200.7
05/20/2015 12:04
MHALL3
1
EPA 200.7
05/20/2015 12:04
MHALL3
1
EPA 200.7
05/20/2015 12:04
MHALL3
1
EPA 200.7
05/20/2015 12:04
MHALL3
1
EPA 200.7
05/20/2015 12:04
MHALL3
1
EPA 200.7
05/20/2015 13:30
MHALL3
1
EPA 200.7
05/20/2015 13:30
MHALL3
1
EPA 200.7
05/20/2015 13:30
MHALL3
1
EPA 200.7
05/20/2015 13:30
MHALL3
1
EPA 200.7
05/20/2015 15:54
MHALL3
1
EPA 200.7
05/20/2015 15:54
MHALL3
1
EPA 200.7
05/20/2015 15:54
MHALL3
1
EPA 200.7
05/20/2015 15:54
MHALL3
1
EPA 200.7
05/20/2015 15:54
MHALL3
1
EPA 200.7
05/20/2015 15:54
MHALL3
1
EPA 200.7
05/20/2015 15:54
MHALL3

Analytical Lab
Certificate of Laboratory Analysis Page 9 of 64
This report shall not be reproduced, except in full.
Order # J15050533
Site: CB -3
Sample #: 2015015351
Collection Date: 19 -May -15 11:07
AM
Matrix: GW
-WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
DISSOLVED METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
06/04/2015 12:29
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:29
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:29
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:29
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:29
JAHERMA
Cobalt (Co)
1.74
ug/L
1
1
EPA 200.8
06/04/2015 12:29
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
06/04/2015 12:29
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:29
JAHERMA
Molybdenum (Mo)
5.21
ug/L
1
1
EPA 200.8
06/04/2015 12:29
JAHERMA
Nickel (Ni)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:29
JAHERMA
Selenium (Se)
3.50
ug/L
1
1
EPA 200.8
06/04/2015 12:29
JAHERMA
Thallium (TI) Low Level
0.497
ug/L
0.2
1
EPA 200.8
06/04/2015 12:29
JAHERMA
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
06/04/2015 12:29
JAHERMA
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:02
SLS2560
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:02
SLS2560
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:02
SLS2560
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:02
SLS2560
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:02
SLS2560
Cobalt (Co)
1.88
ug/L
1
1
EPA 200.8
06/02/2015 18:02
SLS2560
Copper (Cu)
1.22
ug/L
1
1
EPA 200.8
06/02/2015 18:02
SLS2560
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:02
SLS2560
Molybdenum (Mo)
5.49
ug/L
1
1
EPA 200.8
06/02/2015 18:02
SLS2560
Nickel (Ni)
1.84
ug/L
1
1
EPA 200.8
06/02/2015 18:02
SLS2560
Selenium (Se)
3.03
ug/L
1
1
EPA 200.8
06/02/2015 18:02
SLS2560
Thallium (TI) Low Level
0.398
ug/L
0.2
1
EPA 200.8
06/02/2015 18:02
SLS2560
Vanadium (V) Low Level
0.675
ug/L
0.3
1
EPA 200.8
06/02/2015 18:02
SLS2560
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
240
mg/L
25
1
SM2540C
05/20/201514:09
AGIBBS5
Total Carbon
TOC
0.273
mg/L
0.1
1
SM5310C/EPA9060A
05/26/201514:02
TJA7067
TOTAL SUSPENDED SOLIDS
TSS
14
mg/L
5
1
SM2540D
05/20/201510:25
AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050533
Site: PZ -23
Collection Date: 18 -May -15 4:11 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
05/22/2015 17:35
Vendor Parameter
Complete
EPA 300.0
05/22/2015 17:35
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
0.771
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
4.4
mg/L
0.1
Sulfate
62
mg/L
1
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/20/2015 11:52
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/20/2015 11:52
MHALL3
Aluminum (AI)
0.011
mg/L
0.005
Barium (Ba)
0.059
mg/L
0.005
Boron (B)
0.250
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
3.68
mg/L
0.005
Strontium (Sr)
0.111
mg/L
0.005
Zinc (Zn)
0.018
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/20/2015 15:57
MHALL3
Calcium (Ca)
13.1
mg/L
0.01
Magnesium (Mg)
3.68
mg/L
0.005
Potassium (K)
2.15
mg/L
0.1
Sodium (Na)
16.5
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.332
mg/L
0.005
Barium (Ba)
0.064
mg/L
0.005
Boron (B)
0.226
mg/L
0.05
Iron (Fe)
0.358
mg/L
0.01
Manganese (Mn)
3.64
mg/L
0.005
Strontium (Sr)
0.112
mg/L
0.005
Zinc (Zn)
0.014
mg/L
0.005
Sample #: 2015015352
Matrix: GW -WW
Analytical Lab
Page 10 of 64
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
05/27/2015 12:55
LSTARLI
1
EPA 300.0
05/22/2015 17:35
BGN9034
10
EPA 300.0
05/22/2015 17:35
BGN9034
1
EPA 245.1
05/28/2015 12:05
ACPAYNE
1
EPA 245.1
05/29/2015 13:36
ACPAYNE
1
EPA 200.7
05/20/2015 11:52
MHALL3
1
EPA 200.7
05/20/2015 11:52
MHALL3
1
EPA 200.7
05/20/2015 11:52
MHALL3
1
EPA 200.7
05/20/2015 11:52
MHALL3
1
EPA 200.7
05/20/2015 11:52
MHALL3
1
EPA 200.7
05/20/2015 11:52
MHALL3
1
EPA 200.7
05/20/2015 11:52
MHALL3
1
EPA 200.7
05/20/2015 13:34
MHALL3
1
EPA 200.7
05/20/2015 13:34
MHALL3
1
EPA 200.7
05/20/2015 13:34
MHALL3
1
EPA 200.7
05/20/2015 13:34
MHALL3
1
EPA 200.7
05/20/2015 15:57
MHALL3
1
EPA 200.7
05/20/2015 15:57
MHALL3
1
EPA 200.7
05/20/2015 15:57
MHALL3
1
EPA 200.7
05/20/2015 15:57
MHALL3
1
EPA 200.7
05/20/2015 15:57
MHALL3
1
EPA 200.7
05/20/2015 15:57
MHALL3
1
EPA 200.7
05/20/2015 15:57
MHALL3

Analytical Lab
Certificate of Laboratory Analysis Page 11 of 64
This report shall not be reproduced, except in full.
Order # J15050533
Site: PZ -23
Sample #: 2015015352
Collection Date: 18 -May -15 4:11 PM
Matrix: GW
-WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
DISSOLVED METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
06/04/2015 13:28
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
06/04/2015 13:28
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
06/04/2015 13:28
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
06/04/2015 13:28
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
06/04/2015 13:28
JAHERMA
Cobalt (Co)
25.0
ug/L
1
1
EPA 200.8
06/04/2015 13:28
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
06/04/2015 13:28
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
06/04/2015 13:28
JAHERMA
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
06/04/2015 13:28
JAHERMA
Nickel (Ni)
<1
ug/L
1
1
EPA 200.8
06/04/2015 13:28
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
06/04/2015 13:28
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
06/04/2015 13:28
JAHERMA
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
06/04/2015 13:28
JAHERMA
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:06
SLS2560
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:06
SLS2560
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:06
SLS2560
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:06
SLS2560
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:06
SLS2560
Cobalt (Co)
22.4
ug/L
1
1
EPA 200.8
06/02/2015 18:06
SLS2560
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
06/02/2015 18:06
SLS2560
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:06
SLS2560
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:06
SLS2560
Nickel (Ni)
1.43
ug/L
1
1
EPA 200.8
06/02/2015 18:06
SLS2560
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:06
SLS2560
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
06/02/2015 18:06
SLS2560
Vanadium (V) Low Level
0.389
ug/L
0.3
1
EPA 200.8
06/02/2015 18:06
SLS2560
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
120
mg/L
25
1
SM2540C
05/20/201514:09
AGIBBS5
Total Carbon
TOC
0.301
mg/L
0.1
1
SM5310C/EPA9060A
05/26/201514:02
TJA7067
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
1
SM2540D
05/20/2015 10:25
AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050533
Site: P-104
Collection Date: 19 -May -15 11:56 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
05/22/2015 17:52
Vendor Parameter
Complete
EPA 300.0
05/22/2015 17:52
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
4.7
mg-N/L
0.1
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
7.1
mg/L
0.1
Sulfate
41
mg/L
1
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/20/2015 12:00
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/20/2015 12:00
MHALL3
Aluminum (AI)
0.012
mg/L
0.005
Barium (Ba)
0.048
mg/L
0.005
Boron (B)
0.208
mg/L
0.05
Iron (Fe)
0.028
mg/L
0.01
Manganese (Mn)
1.12
mg/L
0.005
Strontium (Sr)
0.095
mg/L
0.005
Zinc (Zn)
0.079
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/20/2015 16:09
MHALL3
Calcium (Ca)
20.3
mg/L
R1 0.01
Magnesium (Mg)
8.52
mg/L
0.005
Potassium (K)
1.46
mg/L
0.1
Sodium (Na)
6.04
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.670
mg/L
0.005
Barium (Ba)
0.048
mg/L
0.005
Boron (B)
0.194
mg/L
0.05
Iron (Fe)
0.737
mg/L
0.01
Manganese (Mn)
1.15
mg/L
0.005
Strontium (Sr)
0.088
mg/L
0.005
Zinc (Zn)
0.068
mg/L
0.005
Sample #: 2015015353
Matrix: GW -WW
Analytical Lab
Page 12 of 64
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
10
EPA 353.2
05/27/2015 12:56
LSTARLI
1
EPA 300.0
05/22/2015 17:52
BGN9034
10
EPA 300.0
05/22/2015 17:52
BGN9034
1
EPA 245.1
05/28/2015 12:07
ACPAYNE
1
EPA 245.1
05/29/2015 13:38
ACPAYNE
1
EPA 200.7
05/20/2015 12:00
MHALL3
1
EPA 200.7
05/20/2015 12:00
MHALL3
1
EPA 200.7
05/20/2015 12:00
MHALL3
1
EPA 200.7
05/20/2015 12:00
MHALL3
1
EPA 200.7
05/20/2015 12:00
MHALL3
1
EPA 200.7
05/20/2015 12:00
MHALL3
1
EPA 200.7
05/20/2015 12:00
MHALL3
1
EPA 200.7
05/20/2015 13:55
MHALL3
1
EPA 200.7
05/20/2015 13:55
MHALL3
1
EPA 200.7
05/20/2015 13:55
MHALL3
1
EPA 200.7
05/20/2015 13:55
MHALL3
1
EPA 200.7
05/20/2015 16:09
MHALL3
1
EPA 200.7
05/20/2015 16:09
MHALL3
1
EPA 200.7
05/20/2015 16:09
MHALL3
1
EPA 200.7
05/20/2015 16:09
MHALL3
1
EPA 200.7
05/20/2015 16:09
MHALL3
1
EPA 200.7
05/20/2015 16:09
MHALL3
1
EPA 200.7
05/20/2015 16:09
MHALL3

Analytical Lab
Certificate of Laboratory Analysis Page 13 of 64
This report shall not be reproduced, except in full.
Order # J15050533
Site: P-104
Sample #: 2015015353
Collection Date: 19 -May -15 11:56
AM
Matrix: GW
-WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
DISSOLVED METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
06/04/2015 12:38
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:38
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:38
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:38
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:38
JAHERMA
Cobalt (Co)
26.4
ug/L
1
1
EPA 200.8
06/04/2015 12:38
JAHERMA
Copper (Cu)
1.03
ug/L
1
1
EPA 200.8
06/04/2015 12:38
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:38
JAHERMA
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:38
JAHERMA
Nickel (Ni)
2.66
ug/L
1
1
EPA 200.8
06/04/2015 12:38
JAHERMA
Selenium (Se)
2.08
ug/L
1
1
EPA 200.8
06/04/2015 12:38
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
06/04/2015 12:38
JAHERMA
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
06/04/2015 12:38
JAHERMA
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:11
SLS2560
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:11
SLS2560
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:11
SLS2560
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:11
SLS2560
Chromium (Cr)
1.64
ug/L
1
1
EPA 200.8
06/02/2015 18:11
SLS2560
Cobalt (Co)
26.8
ug/L
1
1
EPA 200.8
06/02/2015 18:11
SLS2560
Copper (Cu)
1.06
ug/L
1
1
EPA 200.8
06/02/2015 18:11
SLS2560
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:11
SLS2560
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:11
SLS2560
Nickel (Ni)
3.56
ug/L
1
1
EPA 200.8
06/02/2015 18:11
SLS2560
Selenium (Se)
1.37
ug/L
1
1
EPA 200.8
06/02/2015 18:11
SLS2560
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
06/02/2015 18:11
SLS2560
Vanadium (V) Low Level
0.559
ug/L
0.3
1
EPA 200.8
06/02/2015 18:11
SLS2560
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
140
mg/L
25
1
SM2540C
05/20/201514:09
AGIBBS5
Total Carbon
TOC
0.170
mg/L
0.1
1
SM5310C/EPA9060A
05/26/201514:02
TJA7067
TOTAL SUSPENDED SOLIDS
TSS
8.0
mg/L
5
1
SM2540D
05/20/201510:25
AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050533
Site: P-101
Collection Date: 19 -May -15 2:23 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
05/26/2015 14:43
Vendor Parameter
Complete
EPA 300.0
05/26/2015 14:43
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
12
mg/L
1
Sulfate
160
mg/L
2.5
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/20/2015 11:48
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/20/2015 11:48
MHALL3
Aluminum (AI)
0.008
mg/L
0.005
Barium (Ba)
0.075
mg/L
0.005
Boron (B)
1.24
mg/L
0.05
Iron (Fe)
0.035
mg/L
0.01
Manganese (Mn)
2.28
mg/L
0.005
Strontium (Sr)
0.356
mg/L
0.005
Zinc (Zn)
0.033
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/20/2015 16:20
MHALL3
Calcium (Ca)
36.2
mg/L
0.01
Magnesium (Mg)
14.0
mg/L
0.005
Potassium (K)
2.24
mg/L
0.1
Sodium (Na)
14.3
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.123
mg/L
0.005
Barium (Ba)
0.076
mg/L
0.005
Boron (B)
1.20
mg/L
0.05
Iron (Fe)
0.155
mg/L
0.01
Manganese (Mn)
2.32
mg/L
0.005
Strontium (Sr)
0.362
mg/L
0.005
Zinc (Zn)
0.027
mg/L
0.005
Sample #: 2015015354
Matrix: GW -WW
Analytical Lab
Page 14 of 64
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
05/27/2015 12:57
LSTARLI
10
EPA 300.0
05/26/2015 14:43
BGN9034
25
EPA 300.0
05/26/2015 14:43
BGN9034
1
EPA 245.1
05/28/2015 12:09
ACPAYNE
1
EPA 245.1
05/29/2015 13:41
ACPAYNE
1
EPA 200.7
05/20/2015 11:48
MHALL3
1
EPA 200.7
05/20/2015 11:48
MHALL3
1
EPA 200.7
05/20/2015 11:48
MHALL3
1
EPA 200.7
05/20/2015 11:48
MHALL3
1
EPA 200.7
05/20/2015 11:48
MHALL3
1
EPA 200.7
05/20/2015 11:48
MHALL3
1
EPA 200.7
05/20/2015 11:48
MHALL3
1
EPA 200.7
05/20/2015 13:38
MHALL3
1
EPA 200.7
05/20/2015 13:38
MHALL3
1
EPA 200.7
05/20/2015 13:38
MHALL3
1
EPA 200.7
05/20/2015 13:38
MHALL3
1
EPA 200.7
05/20/2015 16:20
MHALL3
1
EPA 200.7
05/20/2015 16:20
MHALL3
1
EPA 200.7
05/20/2015 16:20
MHALL3
1
EPA 200.7
05/20/2015 16:20
MHALL3
1
EPA 200.7
05/20/2015 16:20
MHALL3
1
EPA 200.7
05/20/2015 16:20
MHALL3
1
EPA 200.7
05/20/2015 16:20
MHALL3

Analytical Lab
Certificate of Laboratory Analysis Page 15 of 64
This report shall not be reproduced, except in full.
Order # J15050533
Site: P-101
Sample #: 2015015354
Collection Date: 19 -May -15 2:23 PM
Matrix: GW
-WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
DISSOLVED METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
06/04/2015 12:43
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:43
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:43
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:43
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:43
JAHERMA
Cobalt (Co)
14.6
ug/L
1
1
EPA 200.8
06/04/2015 12:43
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
06/04/2015 12:43
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:43
JAHERMA
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:43
JAHERMA
Nickel (Ni)
2.20
ug/L
1
1
EPA 200.8
06/04/2015 12:43
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:43
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
06/04/2015 12:43
JAHERMA
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
06/04/2015 12:43
JAHERMA
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:15
SLS2560
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:15
SLS2560
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:15
SLS2560
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:15
SLS2560
Chromium (Cr)
2.34
ug/L
1
1
EPA 200.8
06/02/2015 18:15
SLS2560
Cobalt (Co)
14.3
ug/L
1
1
EPA 200.8
06/02/2015 18:15
SLS2560
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
06/02/2015 18:15
SLS2560
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:15
SLS2560
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:15
SLS2560
Nickel (Ni)
4.18
ug/L
1
1
EPA 200.8
06/02/2015 18:15
SLS2560
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:15
SLS2560
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
06/02/2015 18:15
SLS2560
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
06/02/2015 18:15
SLS2560
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
260
mg/L
25
1
SM2540C
05/20/201514:09
AGIBBS5
Total Carbon
TOC
0.268
mg/L
0.1
1
SM5310C/EPA9060A
05/26/201514:02
TJA7067
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
1
SM2540D
05/20/2015 10:25
AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050533
Site: AMW-1 B
Collection Date: 19 -May -15 1:58 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
05/26/2015 15:01
Vendor Parameter
Complete
EPA 300.0
05/26/2015 15:01
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
0.015
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
9.3
mg/L
0.1
Sulfate
120
mg/L
2.5
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/20/2015 12:19
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/20/2015 12:19
MHALL3
Aluminum (AI)
0.035
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
0.421
mg/L
0.05
Iron (Fe)
5.91
mg/L
0.01
Manganese (Mn)
0.373
mg/L
0.005
Strontium (Sr)
0.083
mg/L
0.005
Zinc (Zn)
0.014
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/20/2015 16:25
MHALL3
Calcium (Ca)
53.5
mg/L
0.01
Magnesium (Mg)
2.74
mg/L
0.005
Potassium (K)
2.57
mg/L
0.1
Sodium (Na)
22.1
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.095
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
0.422
mg/L
0.05
Iron (Fe)
6.66
mg/L
0.01
Manganese (Mn)
0.362
mg/L
0.005
Strontium (Sr)
0.085
mg/L
0.005
Zinc (Zn)
0.006
mg/L
0.005
Sample #: 2015015355
Matrix: GW -WW
Analytical Lab
Page 16 of 64
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
05/27/2015 12:59
LSTARLI
1
EPA 300.0
05/26/2015 15:01
BGN9034
25
EPA 300.0
05/26/2015 15:01
BGN9034
1
EPA 245.1
05/28/2015 12:12
ACPAYNE
1
EPA 245.1
05/29/2015 13:43
ACPAYNE
1
EPA 200.7
05/20/2015 12:19
MHALL3
1
EPA 200.7
05/20/2015 12:19
MHALL3
1
EPA 200.7
05/20/2015 12:19
MHALL3
1
EPA 200.7
05/20/2015 12:19
MHALL3
1
EPA 200.7
05/20/2015 12:19
MHALL3
1
EPA 200.7
05/20/2015 12:19
MHALL3
1
EPA 200.7
05/20/2015 12:19
MHALL3
1
EPA 200.7
05/20/2015 13:42
MHALL3
1
EPA 200.7
05/20/2015 13:42
MHALL3
1
EPA 200.7
05/20/2015 13:42
MHALL3
1
EPA 200.7
05/20/2015 13:42
MHALL3
1
EPA 200.7
05/20/2015 16:25
MHALL3
1
EPA 200.7
05/20/2015 16:25
MHALL3
1
EPA 200.7
05/20/2015 16:25
MHALL3
1
EPA 200.7
05/20/2015 16:25
MHALL3
1
EPA 200.7
05/20/2015 16:25
MHALL3
1
EPA 200.7
05/20/2015 16:25
MHALL3
1
EPA 200.7
05/20/2015 16:25
MHALL3

Analytical Lab
Certificate of Laboratory Analysis Page 17 of 64
This report shall not be reproduced, except in full.
Order # J15050533
Site: AMW-1 B
Sample #: 2015015355
Collection Date: 19 -May -15 1:58 PM
Matrix: GW
-WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
DISSOLVED METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
06/04/2015 12:48
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:48
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:48
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:48
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:48
JAHERMA
Cobalt (Co)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:48
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
06/04/2015 12:48
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:48
JAHERMA
Molybdenum (Mo)
2.45
ug/L
1
1
EPA 200.8
06/04/2015 12:48
JAHERMA
Nickel (Ni)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:48
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
06/04/2015 12:48
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
06/04/2015 12:48
JAHERMA
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
06/04/2015 12:48
JAHERMA
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:29
SLS2560
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:29
SLS2560
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:29
SLS2560
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:29
SLS2560
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:29
SLS2560
Cobalt (Co)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:29
SLS2560
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
06/02/2015 18:29
SLS2560
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:29
SLS2560
Molybdenum (Mo)
2.55
ug/L
1
1
EPA 200.8
06/02/2015 18:29
SLS2560
Nickel (Ni)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:29
SLS2560
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
06/02/2015 18:29
SLS2560
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
06/02/2015 18:29
SLS2560
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
06/02/2015 18:29
SLS2560
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
280
mg/L
25
1
SM2540C
05/20/201514:09
AGIBBS5
Total Carbon
TOC
0.558
mg/L
0.1
1
SM5310C/EPA9060A
05/26/201514:02
TJA7067
TOTAL SUSPENDED SOLIDS
TSS
6.0
mg/L
5
1
SM2540D
05/20/201510:25
AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050533
Site: Equipment Blank
Collection Date: 19 -May -15 2:00 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy
Labs)
1 EPA 300.0
Vendor Parameter
Complete
1 EPA 245.1
05/28/2015 12:14
NITRITE + NITRATE (COLORIMETRIC)
1 EPA 200.7
05/20/2015 14:15
Nitrite + Nitrate (Colorimetric)
0.024
mg-N/L
0.01
INORGANIC IONS BY IC
05/20/2015 14:15
MHALL3
1 EPA 200.7
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
05/20/2015 16:29
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
MHALL3
1 EPA 200.7
05/20/2015 16:29
Calcium (Ca)
0.049
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
06/02/2015 18:34
SLS2560
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Analytical Lab
Page 18 of 64
Sample #: 2015015356
Matrix: GW -WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2
05/27/2015 13:00
LSTARLI
1 EPA 300.0
05/22/2015 15:47
BGN9034
1 EPA 300.0
05/22/2015 15:47
BGN9034
1 EPA 245.1
05/28/2015 12:14
ACPAYNE
1 EPA 200.7
05/20/2015 14:15
MHALL3
1 EPA 200.7
05/20/2015 14:15
MHALL3
1 EPA 200.7
05/20/2015 14:15
MHALL3
1 EPA 200.7
05/20/2015 14:15
MHALL3
1 EPA 200.7
05/20/2015 16:29
MHALL3
1 EPA 200.7
05/20/2015 16:29
MHALL3
1 EPA 200.7
05/20/2015 16:29
MHALL3
1 EPA 200.7
05/20/2015 16:29
MHALL3
1 EPA 200.7
05/20/2015 16:29
MHALL3
1 EPA 200.7
05/20/2015 16:29
MHALL3
1 EPA 200.7
05/20/2015 16:29
MHALL3
1 EPA 200.8
06/02/2015 18:34
SLS2560
1 EPA 200.8
06/02/2015 18:34
SLS2560
1 EPA 200.8
06/02/2015 18:34
SLS2560
1 EPA 200.8
06/02/2015 18:34
SLS2560
1 EPA 200.8
06/02/2015 18:34
SLS2560
1 EPA 200.8
06/02/2015 18:34
SLS2560
1 EPA 200.8
06/02/2015 18:34
SLS2560
1 EPA 200.8
06/02/2015 18:34
SLS2560
1 EPA 200.8
06/02/2015 18:34
SLS2560
1 EPA 200.8
06/02/2015 18:34
SLS2560
1 EPA 200.8
06/02/2015 18:34
SLS2560
1 EPA 200.8
06/02/2015 18:34
SLS2560
1 EPA 200.8
06/02/2015 18:34
SLS2560
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4) Complete Vendor Method V_SHEALY

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050533
Site: Equipment Blank
Collection Date: 19 -May -15 2:00 PM
Analyte Result Units Qualifiers RDL DF
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L 25 1
Total Carbon
Sample #: 2015015356
Matrix: GW—WW
Analytical Lab
Page 19 of 64
Method Analysis Date/Time Analyst
Vendor Method
V_ELE1
SM2540C 05/20/201514:09 AGIBBS5
TOC 0.149 mg/L 0.1 1 SM5310C/EPA9060A 05/27/201511:59 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 05/20/2015 10:25 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050533
Site: Filter Blank
Collection Date: 19 -May -15 2:00 PM
Analyte Result Units Qualifiers RDL DF
Mercury Dissolved (cold vapor) in Water (Filtered)
Mercury (Hg)
< 0.05
ug/L
DISSOLVED METALS BY ICP
ACPAYNE
0.005
Aluminum (AI)
< 0.005
mg/L
Barium (Ba)
< 0.005
mg/L
Boron (B)
< 0.05
mg/L
Iron (Fe)
< 0.01
mg/L
Manganese (Mn)
< 0.005
mg/L
Strontium (Sr)
< 0.005
mg/L
Zinc (Zn)
< 0.005
mg/L
DISSOLVED METALS BY ICP -MS
05/20/2015 12:34
MHALL3
Antimony (Sb)
< 1
ug/L
Arsenic (As)
< 1
ug/L
Beryllium (Be)
< 1
ug/L
Cadmium (Cd)
< 1
ug/L
Chromium (Cr)
< 1
ug/L
Cobalt (Co)
< 1
ug/L
Copper (Cu)
< 1
ug/L
Lead (Pb)
< 1
ug/L
Molybdenum (Mo)
< 1
ug/L
Nickel (Ni)
< 1
ug/L
Selenium (Se)
< 1
ug/L
Thallium (TI) Low Level
< 0.2
ug/L
Vanadium (V) Low Level
< 0.3
ug/L
Sample #: 2015015357
Matrix: GW -WW
Analytical Lab
Page 20 of 64
Method Analysis Date/Time Analyst
0.05
1
EPA 245.1
05/29/2015 13:45
ACPAYNE
0.005
1
EPA 200.7
05/20/2015 12:34
MHALL3
0.005
1
EPA 200.7
05/20/2015 12:34
MHALL3
0.05
1
EPA 200.7
05/20/2015 12:34
MHALL3
0.01
1
EPA 200.7
05/20/2015 12:34
MHALL3
0.005
1
EPA 200.7
05/20/2015 12:34
MHALL3
0.005
1
EPA 200.7
05/20/2015 12:34
MHALL3
0.005
1
EPA 200.7
05/20/2015 12:34
MHALL3
1
1
EPA 200.8
06/04/2015 12:52
JAHERMA
1
1
EPA 200.8
06/04/2015 12:52
JAHERMA
1
1
EPA 200.8
06/04/2015 12:52
JAHERMA
1
1
EPA 200.8
06/04/2015 12:52
JAHERMA
1
1
EPA 200.8
06/04/2015 12:52
JAHERMA
1
1
EPA 200.8
06/04/2015 12:52
JAHERMA
1
1
EPA 200.8
06/04/2015 12:52
JAHERMA
1
1
EPA 200.8
06/04/2015 12:52
JAHERMA
1
1
EPA 200.8
06/04/2015 12:52
JAHERMA
1
1
EPA 200.8
06/04/2015 12:52
JAHERMA
1
1
EPA 200.8
06/04/2015 12:52
JAHERMA
0.2
1
EPA 200.8
06/04/2015 12:52
JAHERMA
0.3
1
EPA 200.8
06/04/2015 12:52
JAHERMA
Qualifiers:
R1 Relative Percent Difference exceeded method acceptance limits, see additional notes.
-- Additional Information --
R1 - Calcium RPD for this MS/MSD was above the control limit of 20% (30.1 %). Matrix interference from the high
sample concentration of this element is suspected.

REPORT OF ANALYSES
Analytical Lab
Page 21 of 64
Element One 9nc.
6319-D Carolina Beach Rd.
Wilmington, NC 28412
Phone: [phone]
[fax: [phone]
[e-mail]
Duke Energy
June 2, 2015
Laboratory Services
Client Project Name
AB GW
Assessment
water Asheville
13339 Hagers
Ferry Road Bld. MG03A
Client Project Number J15050533
Huntersville, NC
28078
PO Number
Sample Matrix
Sample Type Grab
Date Received
05/22/2015
Date Analyzed
05/22/2015
Method
SM 4500 S2- D
Time Received
1205
Delivered by
FedEx
Received by
JRC
eOne ID
Duke Energy ID
Parameter
Result Unit
Dil
DL
Date
Time
Sampled
Sampled
24833-1
PZ -26
Sulfide
< 0.1 mg/L
1
0.1
05/19/15
1000
24833-2
PZ -24
Sulfide
< 0.1 mg/L
1
0.1
05/19/15
1345
24833-3"
CB -3
Sulfide
< 0.5 mg/L
5
0.1
05/19/15
1107
24833-4
PZ -23
Sulfide
< 0.1 mg/L
1
0.1
05/19/15
1611
24833-5
P-104
Sulfide
< 0.1 mg/L
1
0.1
05/19/15
1156
24833-6*
P-101
Sulfide
< 0.5 mg/L
5
0.1
05/19/15
1423
24833-7
AMW-1 B
Sulfide
< 0.1 mg/L
1
0.1
05/19/15
1358
24833-8
Equipment Blank
Sulfide
< 0.1 mg/L
1
0.1
05/19115
1400
'Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits.
i
Ken Smith, Laboratory Director
24833 Duke Report Packet Compiled by—,QA-
NC Certifications: DW 37788 and DWQ DENR 604

Analytical Lab
Page 22 of 64
W
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Analytical Lab
elementOne SAMPLE SUBMISSION FORM Lab Ibge'�4933
TAT 7 BD
Hold Time Expiration 05.25.15 @ 1611
Client: Duke Energy
LIMS No J15050533
Project ID Asheville
>9
No I Temps 6°C
If No, Record I If No, Record
Sample Identification & Collection Information
Analysis Due Date 05.22.15
Report Due Date 06.02.15
Date Rec:
05.22.15
Time Rec:
1205
Rec By
JRC
No Ref. Method:
SM4500 S2 D
Lab ID
Client ID
Collection Date
Collection Time
Analysis Requested
1
PZ -26
05/19/15
1000
de
2
PZ -24
05/19/15
1345
1107
4
5
PZ -23
P-104
05/18/15
05/19/15
1611
1156
VSulfi,,,,,de05/19/15
6
P-101
05/19/15
1423
7
AMW-1 B
05/19/15
1358
ulfi
8
Equipment Blank
05/19/15Y
1400 _
ulfi
NOTE for Sulfide
The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected
at 100 pg/L spike the sample to render the final spike concentration at - 500 pg/L
Lab Communications
All AB Groundwater Assessment yobs need a RL of 0.1
SS Page 1 of 1 Prep By / Date%�r^ 5 ' �-� 15
SS by Labeled By / Date - ,. - ZZ ---1
5/22/201 3:54:13 PM ID Verification By /Date' V<Ar\ 5 ��� l5

Analytical Lab
Page 24 of 64
METHOD:
SM4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
UNITS OF ANSWER
ug/mL
CLIENT:
Duke
Wave Length
664
DETECTION LIMIT u
1.000
SPK LEVEL u
5
Lab ID#
24832/833/834/835/836/,837/$38
MAX ALIQUOT
10.00
Date:
5.22.15
Na2S-9H2O
Lot #
STANDARD conc(ppm)
X
Time Analysis Begun
1400
40721
Cal Std Lot:
WC2-82-2
10
Time Analysis Ended
1817
QC Std Lot:
WC2-82-3
10
Analyst:
KAM
Page
1 of 8
STD ABSORPTION
y
X
Y
ug STD
STD
0No
0.800
SOLUTION
ABS
0]00 --
-
- - - ----
-
- . - - -
0.00
0.000
0.�
1.00
0,098
Y
0000
2s
-2W
2.50
0,226
0300 ------
0200
-
-- -----
- --
- --------- -
--- - -
. -,so
'i
5.00
0.426
elm
-•.-+a oo
7.50
0.607
°°°°
10.00
0.778
0.00
200
4 O
8.00
X
8.00
10.00
12.00
Sloe
0.077457143
Correlation
0.99866797911
SAMPLE
SAMP
ug PER
ALI in mL
PREP
ALI in mL
RESULTS
LESS THAN
SPIKE
I.D.
ABS
ALIQUOT
ANALYZED
VOL in mL
TAKEN
ug/mL
% SPK REC
LEVEL
Std. B. 0.00
0
0.0000
10
10
10
<
Std. B. 1.00
0.096
0.8053
10
10
10
<
81%
1
Std. B. 2.50
0.225
2.5569
10
10
10
0.256
102%
2.5
Std. B. 5.00
0.441 1
5.4897
10
10
10
0.549
110%
5
Std. B. 7.50
0.61 1
7.7844
10
10
10
0.778
104%
7.5
Std. B. 10.00
0.772
9.9840
10
10
10
0.998
100%
10
LRB
0.00
0.0000
10
10
10
<
LRB SPK
0.437
5.4354
10
10
10
0.544
109%
5.0
QC
0.434
5.3947
10
10
10
0.539
108%
5.0
24832
0.004
-0.4438
10
10
10
24832 dup
0.004
-0.4438
10
10
10
NA
24832 spk
0.442
5.5033
10
10
10
0.550
110%
5.0
24833-1
0.009
-0.3759
10
10
10
24833-1 s k
0.434
5.3947
10
10
10
0.539
108%
5.0
24833-2
0.039
0.0314
10
10
10
< 1
0,
24833-2 s k
0.433
5.3811
10
10
10
0.538
108%
5.0
24833-3
0.009
-0.3759
10
10
10
<
24833-3 s k
0.346
4.1998
10
10
10
0.420
84%
5.0
24833-4
0.005
-0.4302
10
10
10
< 0„
24833-4 s k
0.354
4.3084
10
10
10
0.431
86%
5.0
24833-5
0.013
-0.3216
10
10
10
<,0:
24833-5 s k
0.3B3
4.7022
10
10
10
0.470
94%
5.0
24833-6
0.031
-0.0772
10
10
10
<
24833-6 s k
0.329
3.9690
10
10
10
0.397
79%
5.0
24833-7
0.012
-0.3352
10
10
10
< Li
24833-7 s k
0.399
4.9194
10
10
10
0.492
98%
5.0
24833-8
0.003
-0.4574
10
10
10
24833-8 s k
0.433
5.3811
10
10
10
0.538
108%
5.0
Blank
0
0.0000
10
10
10
<
QC
Submitted for QA/QC-
0.435
5.408217
10
10
10
0.541
108%
5.0
Date:
5.22.15
By: (Print)
KAM (sign):

METHOD:
SM 4500 S2- D
ELEMENT ASSAY:
Sulfide
CLIENT:
Duke
Lab ID#
24832/833/834/835/836/837/1
Date:
15.22.15
Time Analysis Begun
11400
Time Analvsis Ended
11817`
X
Y
ug STD
STD
SOLUTION
ABS
0.00
0.000
1.00
0.098
2.50
0.226
5.00
0.426
7.50
0.607
10.00
0.778
Wave Length 664
Na2S•9H20 Lot #
40721
Page 2 of 8
Analytical Lab
Page 25 of 64
ELEMENT ONE
STANDARD conc(ppm) X
Cal Std Lot: WC2-82-2 10
QC Std Lot: WC2-82-3 10
STD ABSORPTION Y
o.�
SAMP ug PER
ABS ALIQUOT
0.700
0.800
PREP
VOL in mL
0500
0.077457143
RESULTS
ug/mL
0400
xe
0.300
--
----- -
.200
10
o.100
10
0.000
0.00
x
SAMPLE
I.D.
SAMP ug PER
ABS ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
Slope e
ALI in mL
TAKEN
0.077457143
RESULTS
ug/mL
Correlation
LESS THAN
% SPK REC
0.998667979
SPIKE
LEVEL
Std. B. 0.00
0
0.0000
10
10
10
<
Std. B. 1.00
0.096
0.8053
10
10
10
<
81%
1
Std. B. 2.50
0.225
2.5569
10
10
10
0.256
102%
2.5
Std. B. 5.00
0.441
5.4897
10
10
10
0.549
110%
5
Std. B. 7.50
0.61
7.7844
10
10
10
0.778
104%
7.5
Std. B. 10.00
0.772
9.9840
10
10
10
0.998
100%
10
LRB
0.00
0.0000
10
10
10
<
LRB SPK
0.437
5.4354
10
10
10
0.544
109%
5.0
QC
0.434
5.3947
10
10
10
0.539
108%
5.0
24834-1
0.009
-0.3759
10
10
10
24834-1 s k
0.386
4.7429
10
10
10
0.474
95%
5.0
24834-2
0.016
-0.2809
10
10
10
<
24834-2 dup
0.019
-0.2402
10
10
10
<
NA
24834-2 s k
0.330
3.9826
10
10
10
0.398
80%
5.0
24834-3
0.014
-0.3080
10
10
10
<:'1
24834-3 s k
0.378
4.6343
10
10
10
0.463
93%
5.0
24834-4
0.017
-0.2673
10
10
10
= <
24834-4 s k
0.414
5.1231
10
10
10
0.512
102%
5.0
24834-5
0.009
-0.3759
10
10
10
24834-5 s k
0.432
5.3675
10
10
10
0.537
107%
5.0
24834-6
0.003
-0.4574
10
10
10
<„1
24834-6 s k
0.432
5.3675
10
10
10
0.537
107%
5.0
24835-1
0.007
-0.4031
10
10
10
24835-1 s k
0.404
4.9873
10
10
10
0.499
100%
5.0
24835-2
0.003
-0.4574
10
10
10
<rp
24835-2 s k
0.431
5.3539
10
10
10
0.535
107%
5.0
24835-3
0.005
-0.4302
10
10
10,p,
24835-3 s k
0.433
5.3811
10
10
10
0.538
108%
5.0
Blank
0
0.0000
10
10
10
<
QC
0.435
5.4082
1 10
10
10
1 0.541
108%
5.0
Submitted for QA/QC-
Date:
5.22.15
By: (Print)
KAM
(sign): '

METHOD:
SM 4500 S2 --D
ELEMENT ASSAY:
Sulfide
CLIENT:
Duke
Lab ID#
24832/833/834/835/835/837/838
Date:
5.22.15
Time Analysis Begun
1400
Time Analysis Ended
1817
Ug 5TD
SOLUTION
STD
ABS
0.00
0.000
1.00
0.098
2.50
0.226
5.00
0.426
7.50
0.607
10.00
0.778
Analytical Lab
Page 26 of 64
ELEMENT ONE
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
DETECTION LIMIT (ud
SPK LEVEL u
Na2S•9H2O Lot #
40721
Page 3 of 8
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: W(
QC Std Lot: W(
STD ABSORPTION
X
10.00 1200
X
SAMPLE
I.D.
Std. B. 0.00
SAMP
ABS
0
�
ug PER
ALIQUOT
0.0000
ALI in mL
ANALYZED
10
PREP
VOL in mL
10
Sloe
ALI in mL
TAKEN
10
0.077457143
RESULTS
ug/mL
<
Correlation
LESS THAN
% SPK REC
0_.998667979
SPIKE
LEVEL
Std. B. 1.00
Std. B. 2.50
Std. B. 5.00
Std. B. 7.50
Std. B. 10.00
0.096
0.225
0.441
0.61
0.772
0.8053
2.5569
5.4897
7.7844
9.9840
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
<
0.256
0.549
0.778
0.998
81%
102%
110%
104%
100%
1
2.5
5
7.5
10
LRB
0.00
0.0000
10
10
10
<
LRB SPK
0.437
5.4354
10
10
10
0.544
109%
5.0
QC
0.434
5.3947
10
10
10
0.539
108%
5.0
24835-4
0.005
-0.4302
10
10
10
24835-4 s k
0.435
5.4082
10
10
10
0.541
108%
5.0
24835-5
0.042
0.0721
10
10
10
24835-5 s k
0.442
5.5033
10
10
10
0.550
110%
5.0
24835-6
0.008
-0.3895
10
10
10
<
24835-6 dup
0.006
-0.4167
10
10
10
<
NA
24835-6 s k
0.307
3.6703
10
10
10
0.367
73%
5.0
24835-7
0.01
-0.3624
10
10
10
< 0
24835-7 s k
0.377
4.6207
10
10
10
0.462
92%
5.0
24835-8
0.004
-0.4438
10
10
10
<
24835-8 s k
0.317
3.8061
10
10
10
0.381
76%
5.0
24835-9
0.002
-0.4710
10
10
10
24835-9 s k
0.445
5.5440
10
10
10
0.554
111%
5.0
24836-1
0.011
-0.3488
10
10
10
0 �
24836-1 s k
0.413
5.1095
10
10
10
0.511
102%
5.0
24836-2
0.008
-0.3895
10
10
10
<<p
24836-2 s k
0.355
4.3220
10
10
10
0.432
86%
5.0
24836-3
24836-3 s k
0.006
0.452
-0.4167
5.6391
10
10
10
10
10
10
„; p;1„
0.564
113%
5.0
Blank
0
0.0000
10
10
10
<
QC 0.435
Submitted for QA/QC-
5.4082
Date:
10 1
5.22.15
10
By: (Print)
10
0.5414(s
KAM
108%
ign):642
5.0

METHOD:
SM 4500 S2- D
ELEMENT ASSAY:
Sulfide
CLIENT:
Duke
Lab ID#
24832/833/834/835/836/837/81
Date:
5.22.15
Time Analysis Begun
1400
Time Analysis Ended
1817
Analyst:
KAM
X I
Y
ug STD
STD
SOLUTION
ABS
0.00
0.000
1.00
0.098
Na2S•9H2O Lot #
2.50
0,226
40721
5.00
0.426
ALI in mL
TAKEN
7.50
0.607
Page -4 -of -8-
Analytical Lab
Page 27 of 64
ELEMENT ONE
Wave Length 664
VC 1 CV I 1 1
SPK LEVEL
Sloe
0.077457143
MAX ALIQU,
Na2S•9H2O Lot #
SAMPLE
I.D.
STANDARD
40721
ALI in ml-
ANALYZED
Cal Std Lot:
ALI in mL
TAKEN
RESULTS
ug/mL
QC Std Lot:
Page -4 -of -8-
JSTDABSOF
0
Li
X
Y
Sloe
0.077457143
Correlation
0.998667979
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in ml-
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
LESS THAN
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0
0.0000
10
10
10
<
Std. B. 1.00
0.096
0.8053
10
10
10
<
81%
1
Std. B. 2.50
0.225
2.5569
10
10
10
0.256
102%
2.5
Std. B. 5.00
0.441
5.4897
10
10
10
0.549
110%
5
Std. B. 7.50
0.61
7.7844
10
10
10
0.778
104%
7.5
Std. B. 10.00
0.772
9.9840
10
10
10
0.998
100%
10
LRB
0.00
0.0000
10
10
10
<
LRB SPK
0.437
5.4354
10
10
10
0.544
109%
5.0
QC
0.434
5.3947
10
10
10
0.539
108%
5.0
24836-4
0.006
-0.4167
10
10
10
< 0
24836-4 s k
0.408
5.0416
10
10
10
0.504
101%
5.0
24836-5
0.011
-0.3488
10
10
10
77777-777,777-7 7g,77
24836-5 s k
0.43
5.3404
10
10
10
0.534
107%
5.0
24836-6
0.002
-0.4710
10
10
10
24836-6 s k
0.419
5.1910
10
10
10
0.519
104%
5.0
24836-7
0.005
-0.4302
10
10
10
<
24836-7 dup
0.006
-0.4167
10
10
10
<
NA
24836-7 s k
0.469
5.8699
10
10
10
0.587
117%
5.0
24836-8
0.005
-0.4302
10
10
10
<
24836-8 s k
0.326
3.9283
10
10
10
0.393
79%
5.0
24836-9
0.006
-0.4167
10
10
10
< p
24836-9 s k
0.443
5.5169
10
10
10
0.552
110%
5.0
24836-10
0.011
-0.3488
10
10
10
-777 7
0: j
24836-10 s k
0.442
5.5033
10
10
10
0.550
110%
5.0
24837-1
0.03
-0.0908
1010
10
24837-1 s k
0.391
4.8108
10
10
10
0.481
96%
5.0
24837-2
0.045
0.1129
10
10
10
<
24837-2 s k
0.24
2.7606
10
10
10
0.276
55%
5.0
Blank
0
0.0000
10
10
10
<
QC 0.432
Submittedor QA/QC-
5.3675
Date:
1 10
5.22.15
10
By: (Print)
10
0.537
KAM
107%
(sign):
5.0

METHOD:
SM 4500 S2- D
ELEMENT ASSAY:
Sulfide
CLIENT:
Duke
Lab ID#
24832/833/834/835/836/837/8
Date:
15.22.15
Time Analysis Begun
1400
Time AnalvsIs Ended
11817
X
Y
ug STD
STD
SOLUTION
ABS
0.00
0.000
1.00
0.098
2.50
0.226
5.00
0.426
7.50
0.607
10.00
0.778
ELEMENT ONE
Wave Length 664
Na2S•9H2O Lot #
40721
Page 5 of 8
Analytical Lab
Page 28 of 64
)m)
WC2-82-2
WC2-82-3
SAMPLE
1. D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
Sloe
ALI in mL
TAKEN
0.077457143
RESULTS
ug/mL
Correlation
LESS THAN
% SPK REC
0.998667979
SPIKE
LEVEL
Std. B. 0.00
0
0.0000
10
10
10
<
Std. B. 1.00
0.096
0.8053
10
10
10
<
81%
1
Std. B. 2.50
0.225
2.5569
10
10
10
0.256
102%
2.5
Std. B. 5.00
0.441
5.4897
10
10
10
0.549
110%
5
Std. B. 7.50
0.61
7.7844
10
10
10
0.778
104%
7.5
Std. B. 10.00
0.772
9.9840
10
10
10
0.998
100%
10
LRB
0.00
0.0000
10
10
10
<
LRB SPK
0.437
5.4354
10
10
10
0.544
109%
5.0
QC
0.434
5.3947
10
10
10
0.539
108%
5.0
24837-3
0.01
-0.3624
10
10
10
24837-3 S k
0.376
4.6072
10
10
10
0.461
92%
5.0
24837-4
0.05
0.1808
10
10
10
<
24837-4 s k
0.229
2.6112
10
10
10
0.261
52%
5.0
24837-5
0.053
0.2215
10
10
10
<
24837-5 s k
0.212
2.3804
10
10
10
0.238
48%
5.0
24837-6
0.005
-0.4302
10
10
10
24837-6 s k
0.42
5.2046
10
10
10
0.520
104%
5.0
24837-7
0.012
-0.3352
10
10
10
0,:1
24837-7 dup
0.015
-0.2945
10
10
10
NA
24837-7 s k
0.385
4.7294
10
10
10
0.473
95%
5.0
24837-8
0.39
4.7972
10
10
10
0.480
24837-8 s k
0.686
8.8163
10
10
10
0.882
80%
5.0
24837-9
0.022
-0.1994
10
10
10
24837-9 s k
0.352
4.2813
10
10
10
0.428
86%
5.0
24837-10
0.005
-0.4302
10
10
10
<
24837-10 s k
0.335
4.0505
10
10
10
0.405
81%
5.0
24838
0.009
-0.3759
10
10
10
<
24838 s k
0.012
-0.3352
10
10
10
<
-7%
5.0
Blank
0
0.0000
10
10
10
<
QC
0.435
5.4082
10
10
10
0.541
108%
5.0
Submitted for QA/QC-
Date:
5.22.15
By: (Print)
K:AM
(sign):
X

Analytical Lab
Page 29 of 64
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
SPK LEVELju_M
1.000
5
CLIENT:
Duke
Lab ID# 24832/833/834/835/836/837/838
Date: 5.22.15 Na2S•9H2O Lot#
Time Analysis Begun 1400 40721
Time Analysis Ended 1817
Analyst: KAM Page,6 of 8
X Y
ug STD STD o.WO
SOLUTION ABS
0.00 0.000
1.00 0.098 0.000
2.50 0.226 °.300 - -- ---- - - -- --
- -'-- .726
5.00 0.426 0,00 --- 0�- -- ------ -- ----- - -
7.500.607 °"OW 2W O.W 0.00
10.00 0.778 X
Slope
SAMPLE SAMP ug PER ALI in mL PREP ALI in mL
I.D. ABS ALIQUOT ANALYZED VOL in mL TAKEN
MAX ALIQUOT
STANDARD conc(ppm)
1 Cal Std Lot: WC2-82-2
1 QC Std Lot: WC2-82-3
1 STD ABSORPTION
--- ---- ---
- - --- - - - - -
BW 10.W
0.077457143 Correlation
RESULTS LESS THAN
ug/mL % SPK REC
10.00
X
10
10
Y
-,�
12.W
0.998667979
SPIKE
LEVEL
Std. B. 0.00
0
0.0000
10
10
10
<
Std. B. 1.00
0.096
0.8053
10
10
10
<
81%
1
Std. B. 2.50
0.225
2.5569
10
10
10
0.256
102%
2.5
Std. B. 5.00
0.441
5.4897
10
10
10
0.549
110%
5
Std. B. 7.50
0.61
7.7844
10
10
10
0.778
104%
7.5
Std. B. 10.00
0.772
9.9840
10
10
10
0.998
100%
10
LRB
0.00
0.0000
10
10
10
<
LRB SPK
0.437
5.4354
10
10
10
0.544
109%
5.0
QC
0.434
5.3947
10
10
10
0.539
108%
5.0
24833-3
0.005
-0.4302
10
10
5
<
24833-3 s k
0.338
4.0912
10
10
5
0.818
82%
5.0
24833-6
0.006
-0.4167
10
10
5
<
24833-6 s k
0.333
4.0233
10
10
5
0.805
80%
5.0
24834-2
0.015
-0.2945
10
10
5
24834-2 s k
0.362
4.4171
10
10
5
0.883
88%
5.0
24835-6
0.002
-0.4710
10
10
5
<
24835-6 s k
0.286
3.3851
10
10
5
0.677
68%
5.0
24835-8
0
0.0000
10
10
5
<
24835-8 spk
0.321
3.8604
10
10
5
0.772
77%
5.0
24836-7
0.004
-0.4438
10
10
5
24836-7 dup
0.002
-0.4710
10
10
5
NA
24836-7 s k
0.371
4.5393
10
10
5
0.908
91%
5.0
24836-8
0
0.0000
10
10
5
<
24836-8 spk
0.3
3.5752
10
10
5
0.715
72%
5.0
24837-2
0.034
-0.0365
10
10
5
<
24837-2 spk
0.271
3.1815
10
10
5
0.636
64%
5.0
24837-4
0.052
0.2079
10
10
5
<
24837-4 s k
0.162
1.7015
10
10
5
0.340
34%
5.0
24837-5
0.031
-0.0772
10
10
5
<
24837-5 s k
0.28
3.3037
10
10
5
0.661
66%
5.0
Blank
0
0.0000
10
10
10
<
QC
0.435
5.4082
10
10 1
10
0.5411
108%
5.0
Submitted for QA/QC-
Date:
5.22.15
By: (Print)
KAM
(sign):
1
/Z

METHOD: SM 4500 S2- D
ELEMENT ASSAY: Sulfide
Date: 15.22.15
Time Analysis Begun 11400
Time Ana1vs1s Ended 11817
X
Y
ug STD
STD
SOLUTION
ABS
0.00
0.000
1.00
x
2.50
0.226
5100
0.426
7.50
0.607
10.00
0,778
Analytical Lab
Page 30 of 64
ELEMENT ONE
Wave Length 664
"` 1 "'j [wil "lvjl 1--kuql
j.UU1
SPK 1EYEL. Lug)
5
Na2S-9H2O Lot #
40721
Page 7 of 8STD
MAX ALIQUOT
10.5
STANDARD conc(ppm)
x
Cal Sid Lot: WC2-82-2
16
QC Std Lot: WC2-82-3
10
ABSORPTION
Y
Slope
0.077457143
Correlation
-0.998667979
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
LESS THAN
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0
0.0000
10
10
10
<
Std. B. 1.00
0.096
0.8053
10
10
10
<
81%
1
Std. B. 2.50
0.225
2.5569
10
10
10
0.2-56
102%
2.5
Std. B. 5.00
0.441
5.4897
10
10
10
0,549
110%
5
Std. B. 7.50
0.61
7.7844
10
10
10
0.778
104%
7.5
Sid. B. 10.00
0.772
9.9840
10
10
10
0.998
100%
10
LRB
0.00
0.0000
10
10
10
<
LRB SPK
0.437
5.4354
1 10
10
10
0.544
109%
5.0
QC
0.434
5.3947
10
10
10
0.539
108%
5.0
24837-8
0.26
3.0321
10
10
5
0.606
24837-8 s
0.556
7.0512
10
10
5
1.410
80%
5.0
24837-10
0.006
-0.4167
10
10
5
<
24837-10 s
0.337
4.0776
10
10
5
0.816
82%
5.0
24838
0.003
-0.4574
10
10
1
<
24838 s
0.249
2.8828
10
10
1
2.883
58%
5.0
24833-3
0.002
-0.4710
10
10
2
<
24833-3 s
0.419
5.1910
10
10
2
2.596
104%
5.0
24833-6
0.005
-0.4302
10
10
2
,6'
24833-6 s
0.409
5.0552
10
10
2
2.528
101%
5.0
24835-6
0.002
-0.4710
10
10
2
24835-6 spk
0.375
4.5936
10
10
2
2.297
92%
5.0
24835-8
0
0.0000
10
10
2
e.
24835-8spk
0.411
5.0824
10
10
2
2.541
102%
5.0
24836-8
0.011
-0.3488
10
10
2
24836-8 s
0.395
4.8651
10
10
2
2.433
97%
5.0
24837-2
0.008
-0.3895
10
10
2
24837-2 s
0.396
4.8787
10
10
2
2.439
98%
5.0
24837-4
0.028
-0.1179
10
10
2
<
24837-4 s
0.308
3.6839
10
10
2
1.842
74%
5.0
Blank
0.00
0.0000
10
10
10
<
QC
0.435
5.4082
10
10
10
0.541
108%
5.0
Submifted for QA/QC-
Date:
5.22.15
By: (Print)
KAM
(sign):
L7_-

METHOD:
SM 4500 S2- D
ELEMENT ASSAY:
Sulfide
CLIENT:
Duke
Lab 1D#
24832/833/834/8351836/8373
Date:
5.22.15
Time Analysis Begun
1400
TIMGAnaIvsIs Ended
1817
Ug b I U
SOLUTION
STD
ABS
0.00
0.000
1.00
0.098
2.50
0.226
5.00
0.426
7.50
0.607
10.00
0,778
Wave Length 664
Na2S-9H20 Lot #
40721
- - - ------ -Page -89f 8-,
ELEMENT ONE
Analytical Lab
Page 31 of 64
I
STANDARD conc(ppm) x
Cal Std Lot: WC2-82-2 10
QC Std Lot: WC2-82-3 10 1
X
to..
SAMPLE
I.D.
Std. B. 0.00
SAMP
ABS
o
0,700
°eoo
-
0500 0500
0.077457143
RESULTS
ug/mL
<
y
0,400
0.998667979
SPIKE
LEVEL
0
0.096
0.225
0.441
0.61
0.772
0.200
10
10 1
10
10
10
10
10
10
10
10
10
10
10
10
10
<
0.256
0.549
0.778
0.998
81%
102%
110%
104%
100%
X
to..
SAMPLE
I.D.
Std. B. 0.00
SAMP
ABS
o
Ug PER ALI in mL
ALIQUOT ANALYZED
0.0000 10
PREP
VOL in mL
10
Sloe
ALI in mL
TAKEN
10
0.077457143
RESULTS
ug/mL
<
Correlation
LESS THAN
% SPK REC
0.998667979
SPIKE
LEVEL
Std. B. 1.00
Std. B. 2.50
Std. B. 5.00
Std. B. 7.50
Std, B. 10.00
0.096
0.225
0.441
0.61
0.772
0.8053
2.5569
5.4897
7.7844
9.9840
10
10 1
10
10
10
10
10
10
10
10
10
10
10
10
10
<
0.256
0.549
0.778
0.998
81%
102%
110%
104%
100%
1
2.5
7.5
10
LRB
- 0-00
0.0000
10
10
10
<
LRB SPK
0.437
5.4354
10
10
10
0.544
109%
5.0
QC
- 0.434
5.3947
10
10
10
0.539
108%
5.0
24837-5
0.015
-0.2945
10
10
2
,
24837-5 spk
0.389-T
4.7837
10
10
2
2.3 92
96%
5.0
24837-8
0.112
1.0226
10
10
2
J
24837-8 s
0.481
6.0328
10
10
2
3.016
100%
5.0
24837-10
0.005
-0.4302
10
10
2
24837-10 s
0.383
4.7022
10
10
2
2.351
94%
5.0
24838
0.004
-0.4438
10 1
10
0.5
24838 s
0.302
3.6024
10
10
0.5
7.205
72%
5.0
24837-4
0.017
-0.2673
10
10
24837-4 splk
0.385
4.7294
10
10
1
4.729
95%
5.0
Blank
0.000
0.0000
10
10
10
<
, 0.434
QC-QA/QC-
Submitted QAIQC - _
6
5.3947
Date:
10
5.22.17
10
By: (Print)
0.539
KAM
108%
(sign):
5.0

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
Project Name: AB GW Assessment Water - Asheville
Project Number:J15050533
Lot Number:QE22015
Date Completed:06/02/2015
Grant Wilton
Project Manager
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
*QE22015*
Shealy Environmental Services, Inc. Page: 1 of 19
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: QE22015
Project Name: AB GW Assessment Water - Asheville
Project Number: J15050533
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page
Methane Analysis - Methid 8015C
The sample vials for sample 2015015355 were accidently disposed prior to analysis.
Shealy Environmental Services, Inc. Page: 2 of 19
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QE22015
Project Name: AB GW Assessment Water - Asheville
Project Number: J15050533
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
2015015349
Aqueous
05/19/20151000
05/22/2015
002
2015015350
Aqueous
05/19/20151345
05/22/2015
003
2015015351
Aqueous
05/19/20151107
05/22/2015
004
2015015352
Aqueous
05/18/20151611
05/22/2015
005
2015015353
Aqueous
05/19/20151156
05/22/2015
006
2015015354
Aqueous
05/19/20151423
05/22/2015
007
2015015355
Aqueous
05/19/20151358
05/22/2015
008
2015015356
Aqueous
05/19/20151400
05/22/2015
(8 samples)
Shealy Environmental Services, Inc. Page: 3 of 19
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

(15 detections)
Shealy Environmental Services, Inc. Page: 4 of 19
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QE22015
Project Name:
AB GW Assessment Water - Asheville
Project Number: J15050533
Sample Sample ID
Matrix
Parameter Method
Result Q
Units
Page
002
2015015350
Aqueous
Alkalinity SM 2320B-
170
mg/L
7
002
2015015350
Aqueous
Bicarbonate Alkalinity SM 2320B-
170
mg/L
7
002
2015015350
Aqueous
Methane RSK - 175
14000
ug/L
8
003
2015015351
Aqueous
Alkalinity SM 2320B-
17
mg/L
9
003
2015015351
Aqueous
Bicarbonate Alkalinity SM 2320B-
17
mg/L
9
003
2015015351
Aqueous
Methane RSK - 175
100
ug/L
10
004
2015015352
Aqueous
Alkalinity SM 2320B-
20
mg/L
11
004
2015015352
Aqueous
Bicarbonate Alkalinity SM 2320B-
20
mg/L
11
004
2015015352
Aqueous
Methane RSK - 175
29
ug/L
12
005
2015015353
Aqueous
Alkalinity SM 2320B-
30
mg/L
13
005
2015015353
Aqueous
Bicarbonate Alkalinity SM 2320B-
30
mg/L
13
006
2015015354
Aqueous
Alkalinity SM 2320B-
10
mg/L
15
006
2015015354
Aqueous
Bicarbonate Alkalinity SM 2320B-
10
mg/L
15
007
2015015355
Aqueous
Alkalinity SM 2320B-
51
mg/L
17
007
2015015355
Aqueous
Bicarbonate Alkalinity SM 2320B-
51
mg/L
17
(15 detections)
Shealy Environmental Services, Inc. Page: 4 of 19
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE22015-001
Description: 2015015349 Matrix: Aqueous
Date Sampled:05/19/2015 1000 Project Name: AB GW Assessment Water -
Date Received: 05/22/2015 Project Number: J15050533
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 23208-2011
1 05/27/2015 2013
HMA 75906
1
(Bicarbonate ) SM 2320B-2011
1 05/28/2015 2013
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/28/2015 2013
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QE22015-001
Description: 2015015349 Matrix: Aqueous
Date Sampled:05/19/2015 1000 Project Name: AB GW Assessment Water -
Date Received: 05/22/2015 Project Number: J15050533
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/26/2015 2033 JJG 75816
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 6 of 19
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QE22015-002
Description: 2015015350 Matrix: Aqueous
Date Sampled:05/19/2015 1345 Project Name: AB GW Assessment Water -
Date Received: 05/22/2015 Project Number: J15050533
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 23208-2011
1 05/27/2015 2020
HMA 75906
1
(Bicarbonate ) SM 2320B-2011
1 05/28/2015 2020
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/28/2015 2020
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
170
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
170
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QE22015-002
Description: 2015015350 Matrix: Aqueous
Date Sampled:05/19/2015 1345 Project Name: AB GW Assessment Water -
Date Received: 05/22/2015 Project Number: J15050533
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 50 05/27/2015 1351 DCS 75869
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 14000 500 ug/L 2
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE22015-003
Description: 2015015351 Matrix: Aqueous
Date Sampled:05/19/2015 1107 Project Name: AB GW Assessment Water -
Date Received: 05/22/2015 Project Number: J15050533
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 23208-2011
1 05/27/2015 2025
HMA 75906
1
(Bicarbonate ) SM 2320B-2011
1 05/28/2015 2025
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/28/2015 2025
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
17
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
17
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QE22015-003
Description: 2015015351 Matrix: Aqueous
Date Sampled:05/19/2015 1107 Project Name: AB GW Assessment Water -
Date Received: 05/22/2015 Project Number: J15050533
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/26/2015 2108 JJG 75816
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 100 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE22015-004
Description: 2015015352 Matrix: Aqueous
Date Sampled:05/18/2015 1611 Project Name: AB GW Assessment Water -
Date Received: 05/22/2015 Project Number: J15050533
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 23208-2011
1 05/27/2015 2029
HMA 75906
1
(Bicarbonate ) SM 2320B-2011
1 05/28/2015 2029
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/28/2015 2029
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
20
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
20
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QE22015-004
Description: 2015015352 Matrix: Aqueous
Date Sampled:05/18/2015 1611 Project Name: AB GW Assessment Water -
Date Received: 05/22/2015 Project Number: J15050533
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/26/2015 2119 JJG 75816
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 29 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE22015-005
Description: 2015015353 Matrix: Aqueous
Date Sampled:05/19/2015 1156 Project Name: AB GW Assessment Water -
Date Received: 05/22/2015 Project Number: J15050533
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 23208-2011
1 05/27/2015 2033
HMA 75906
1
(Bicarbonate ) SM 2320B-2011
1 05/28/2015 2033
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/28/2015 2033
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
30
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
30
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QE22015-005
Description: 2015015353 Matrix: Aqueous
Date Sampled:05/19/2015 1156 Project Name: AB GW Assessment Water -
Date Received: 05/22/2015 Project Number: J15050533
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/26/2015 2130 JJG 75816
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 14 of 19
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE22015-006
Description: 2015015354 Matrix: Aqueous
Date Sampled:05/19/2015 1423 Project Name: AB GW Assessment Water -
Date Received: 05/22/2015 Project Number: J15050533
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 23208-2011
1 05/27/2015 2051
HMA 75906
1
(Bicarbonate ) SM 2320B-2011
1 05/28/2015 2051
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/28/2015 2051
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
10
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
10
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QE22015-006
Description: 2015015354 Matrix: Aqueous
Date Sampled:05/19/2015 1423 Project Name: AB GW Assessment Water -
Date Received: 05/22/2015 Project Number: J15050533
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/26/2015 2142 JJG 75816
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE22015-007
Description: 2015015355 Matrix: Aqueous
Date Sampled:05/19/2015 1358 Project Name: AB GW Assessment Water -
Date Received: 05/22/2015 Project Number: J15050533
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 23208-2011
1 05/27/2015 2056
HMA 75906
1
(Bicarbonate ) SM 2320B-2011
1 05/28/2015 2056
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/28/2015 2056
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
51
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
51
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE22015-008
Description: 2015015356 Matrix: Aqueous
Date Sampled:05/19/2015 1400 Project Name: AB GW Assessment Water -
Date Received: 05/22/2015 Project Number: J15050533
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 23208-2011
1 05/27/20152100
HMA 75906
1
(Bicarbonate ) SM 2320B-2011
1 05/28/20152100
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/28/20152100
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QE22015-008
Description: 2015015356 Matrix: Aqueous
Date Sampled:05/19/2015 1400 Project Name: AB GW Assessment Water -
Date Received: 05/22/2015 Project Number: J15050533
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/26/2015 2153 JJG 75816
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: QE22015
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - Ii
Sample ID: QQ75906-001 Matrix: Aqueous
Batch: 75906
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 05/27/20151842
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE22015
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - LCS
Sample ID: QQ75906-002 Matrix: Aqueous
Batch: 75906
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 93 1 93 90-110 05/27/20151849
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE22015
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MS
Sample ID: QE22015-008MS Matrix: Aqueous
Batch: 75906
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity ND 100 90 1 90 70-130 05/27/2015 2106
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE22015
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MSD
Sample ID: QE22015-008MD Matrix: Aqueous
Batch: 75906
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Alkalinity ND 100 90 1 90 0.51 70-130 20 05/27/2015 2113
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE22015
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - MB
Sample ID: QQ75816-001 Matrix: Aqueous
Batch: 75816
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 05/26/2015 2021
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE22015
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCS
Sample ID: QQ75816-002 Matrix: Aqueous
Batch: 75816
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 150 140 1 94 70-130 05/26/20151951
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE22015
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCSD
Sample ID: QQ75816-003 Matrix: Aqueous
Batch: 75816
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 150 140 1 93 1.5 70-130 30 05/26/2015 2004
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE22015
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - MB
Sample ID: QQ75869-001 Matrix: Aqueous
Batch: 75869
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 05/27/20151038
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE22015
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCS
Sample ID: QQ75869-002 Matrix: Aqueous
Batch: 75869
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 150 120 1 77 70-130 05/27/20151017
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE22015
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCSD
Sample ID: QQ75869-003 Matrix: Aqueous
Batch: 75869
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 150 130 1 88 13 70-130 30 05/27/20151027
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE22015
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
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Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
S&Aly Enviranmrntol Srrvires, h, .
Dccvnrcnt 1dember. F -' !P-0 6
Revi%irm dumber. 17
]pare I mf L
5lsplaces bait: ] t e�)7114
EffarUwe Dale. &V34.+1.5
Sample Receipt Checklist (SKIN)
Client: 3)[i, Le, V i,,YV-OtA Cooler Inspected byfdate= i� Lot #t; 01
0
Means €if reccipt: SESI Client ❑ UP S ❑ FcdEx ❑ Airborne fxp ❑ other
7 es U No LaiI.
Were custody seals present onthe cooleO
Yas Ll No Lj I NA
2, if 4-,ustok seals were 'resent, were they iulratt and unbroken?
Cooler ID10riginuall ternperattrre upon re ipt'Derived (corrected) tenapesature upon receipt;
r r "° i l �c
Method; 0 Tertrperawre B1 ik A�galinst Bottleii M Gun rlDO IR Gun Correction Factor:
Method of coolant: �t ice ❑ Blue Ice ❑ D lee None
Yes ❑ No © NAe
.3. If temperature of any cooler exceeded b-O°C, was Project Mzmner notified?
RM notified by SRC, phone, note (.Circle ane), other
(For coolem received via commercial c*lurier, P.Ms are to be notified
immediatal
Yes >rD NA
4. Is the iooulmercial courier's packinK slip allache:d to this fn m?
Yes Ain ❑
Brom . 2. r cusiod mxedalres reliri uisheddreceivctl follawed?
Yes NO 1qA
Sa Wem samples relin uishad by client to s ammercial courier?
Yrs ❑
6. 1iG'cm sam lc IDs listed on the COC:7
Yes ❑
7, Were sample 1Ds listed on all earn 1e colitai11
Y+ s
S. Was cuJcutivn .Clash; & time listed sin the: 00C?
Yes v ®
9. Was cobegtion date & [Urw live -d eta all sacra le contuners?
Ye c ,� ❑
10. Did all container label inforrnation (ID, date, time) ag a wh]-k the COC?
YesAso Q
11. Wffe tests to be fortnetlr lister] orl the CDC7
Yes _ o12.
Did all les =ive Lo the propercontaimrs for each test?
Yes [j o ❑ T
13, Did all eontaLners arnve in good condition(unbroken, lids on, etc-)?
Yes V Ain ❑
14. Was adequate sample volume a- -affable?
Yes ❑ No
Yes ❑ No IM-
15, Wire all swCrles received within' the holdiing tithe or 48 1,3o1.lrs, whichever
comes first?
16. Werc any sero les containcrs missing?
Yes ❑ 14o
Yes ❑ NQ NA. ❑
17. 'more there any a ce-L32 €,2m , leR nol listed on {X)C,
LiJer� blabbls�s rxt " ¢ i �i°a"i1r rr4ii irl [l]amCl r �n an Jf]A vr7al ?
Y ❑ No NA
9. orae all met€ lV0&iGJHEMi utrient samples received at a K of <2?
Yes No ❑ NAL
. i>Sr`i rie all cyanide and or sulftdc sam lcs recciv5d ata H >12?
Yrs ❑ No Q G�l
21, Were all applicable NlUiT1�I41ic aaide phenol (1-0,2mgVL) salinples free of
residual srlilorin�t'�
Yes No ❑
. Were colltction tempetAtures docttmentead an the COC for NC sm les7
❑ Ara ❑
yesetc....
23. Were client rerrjarkssireglxws (Le- requeste>d dilutions, MSc' SU designations,
correctly transenbed from the COC into the comment section in LIMB?
Yes ldo
24- Was the quote number used taken hon the contsincr lab�cl?
sample. preservation (Must bye complrtud for any shnitplt:(s) incorrectly preservW or with li-e-adspccej
Sarmple(s) were received incorrectly presLTvt-s,1 and were Hkl)tlslcd
accordingly is earn le re,:eivirt with (FLSO, HNO3.Ht='1 €r using SR iF
sample(s)
;we received with bubbles >b mm in dianieter.
sample(s))
were accciucd with TRC >4.2 m&fL K921 is Nu
SC Drinking Water Projecl; Sample(s) pH verified to bt- 5 2 by .Crate;
Sam Ics h were not received ata pEl of<2 grid whine adjuswd A000rd.ingly wing Sly
Sample labels applied by,
Verified by. Date; �j- —I
co rrtgnli;
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

CRAM OF CUSTODY RECORD AND ANALYSIS-RFt�_l_..IES_T FORM- - -
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