NC0000396_J15050442report_20150823

+ DUKE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Order Number: J15050442
Project Name: ASHEVILLE - AB GW ASSESSMENT WATER
Customer Name(s): Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker
Customer Address: 200 CP and L Drive
Arden, NC 28704
Lab Contact: Mary Ann Ogle Phone: [phone]
�n j j ( Mary Ann Ogle
Report Authorized By: % "( /// 2015.05.29 16:11:36 Date:
(Signature) 7 -04'00'
Mary Ann Ogle
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
5/29/2015
Page 1 of 41
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
2015014871
2015014872
2015014873
2015014874
4 Total Samples
Collected By
Sample Description
ASHEVILLE
15 -May -15 10:52 AM
illegible
PZ -17S
ASHEVILLE
15 -May -15 10:15 AM
illegible
PZ -17D
ASHEVILLE
15 -May -15 12:10 PM
illegible
Equipment Blank
ASHEVILLE
15 -May -15 12:10 PM
illegible
Filter Blank
Page 2 of 41

Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes F./] No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
U Job Summary Report
❑ Sample Identification
n Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Page 3 of 41
Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
66 Chain of Custody
[I/0] Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 5/29/2015

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050442
Site: PZ -17S
Collection Date: 15 -May -15 10:52 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
05/21/2015 14:13
Vendor Parameter
Complete
EPA 300.0
05/21/2015 14:13
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
0.443
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
1.9
mg/L
0.1
Sulfate
19
mg/L
1
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/18/2015 12:38
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/18/2015 12:38
MHALL3
Aluminum (AI)
0.043
mg/L
0.005
Barium (Ba)
0.069
mg/L
0.005
Boron (B)
0.053
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.024
mg/L
0.005
Strontium (Sr)
0.119
mg/L
0.005
Zinc (Zn)
0.019
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/19/2015 15:47
MHALL3
Calcium (Ca)
4.73
mg/L
0.01
Magnesium (Mg)
0.993
mg/L
0.005
Potassium (K)
2.83
mg/L
0.1
Sodium (Na)
2.74
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.061
mg/L
0.005
Barium (Ba)
0.072
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.017
mg/L
0.01
Manganese (Mn)
0.024
mg/L
0.005
Strontium (Sr)
0.122
mg/L
0.005
Zinc (Zn)
0.006
mg/L
0.005
Sample #: 2015014871
Matrix: GW -WW
Page 4 of 41
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
05/26/2015 12:11
LSTARL1
1
EPA 300.0
05/21/2015 14:13
BGN9034
10
EPA 300.0
05/21/2015 14:13
BGN9034
1
EPA 245.1
05/20/2015 12:23
ACPAYNE
1
EPA 245.1
05/20/2015 13:43
ACPAYNE
1
EPA 200.7
05/18/2015 12:38
MHALL3
1
EPA 200.7
05/18/2015 12:38
MHALL3
1
EPA 200.7
05/18/2015 12:38
MHALL3
1
EPA 200.7
05/18/2015 12:38
MHALL3
1
EPA 200.7
05/18/2015 12:38
MHALL3
1
EPA 200.7
05/18/2015 12:38
MHALL3
1
EPA 200.7
05/18/2015 12:38
MHALL3
1
EPA 200.7
05/18/2015 15:18
MHALL3
1
EPA 200.7
05/18/2015 15:18
MHALL3
1
EPA 200.7
05/18/2015 15:18
MHALL3
1
EPA 200.7
05/18/2015 15:18
MHALL3
1
EPA 200.7
05/19/2015 15:47
MHALL3
1
EPA 200.7
05/19/2015 15:47
MHALL3
1
EPA 200.7
05/19/2015 15:47
MHALL3
1
EPA 200.7
05/19/2015 15:47
MHALL3
1
EPA 200.7
05/19/2015 15:47
MHALL3
1
EPA 200.7
05/19/2015 15:47
MHALL3
1
EPA 200.7
05/19/2015 15:47
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050442
Site: PZ -17S
Collection Date: 15 -May -15 10:52 AM
Analyte
Result
DISSOLVED METALS BY ICP -MS
Sample #:
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper(Cu)
1.85
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
1.45
Selenium (Se)
10.4
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper(Cu)
1.88
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
1.61
Selenium (Se)
11.0
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
ug/L
TDS
44
Total Carbon
05/28/2015 12:50
TOC
0.269
TOTAL SUSPENDED SOLIDS
1
TSS
< 5
Page 5 of 41
ug/L
1
1
Sample #:
2015014871
DJSULL1
ug/L
1
1
Matrix:
GW -WW
DJSULL1
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
ug/L
1
1
EPA 200.8
05/28/2015 12:50
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 12:50
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 12:50
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 12:50
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 12:50
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 12:50
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 12:50
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 12:50
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 12:50
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 12:50
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 12:50
DJSULL1
ug/L
0.2
1
EPA 200.8
05/28/2015 12:50
DJSULL1
ug/L
0.3
1
EPA 200.8
05/28/2015 12:50
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 17:05
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 17:05
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 17:05
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 17:05
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 17:05
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 17:05
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 17:05
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 17:05
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 17:05
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 17:05
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 17:05
DJSULL1
ug/L
0.2
1
EPA 200.8
05/19/2015 17:05
DJSULL1
ug/L
0.3
1
EPA 200.8
05/19/2015 17:05
DJSULL1
Vendor Method
V_SHEALY
Vendor Method
V_ELE1
mg/L
25
1
SM2540C
05/20/201514:30
AGIBBS5
mg/L
0.1
1
SM5310C/EPA9060A
05/20/201514:33
TJA7067
mg/L
5
1
SM2540D
05/19/201511:30
AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050442
Site: PZ -17D
Collection Date: 15 -May -15 10:15 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
05/22/2015 09:15
Vendor Parameter
Complete
EPA 300.0
05/22/2015 09:15
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
0.298
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
9.4
mg/L
0.1
Sulfate
140
mg/L
2.5
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/18/2015 12:17
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/18/2015 12:17
MHALL3
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.058
mg/L
0.005
Boron (B)
0.870
mg/L
0.05
Iron (Fe)
0.192
mg/L
0.01
Manganese (Mn)
0.036
mg/L
0.005
Strontium (Sr)
0.307
mg/L
0.005
Zinc (Zn)
0.051
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/19/2015 15:51
MHALL3
Calcium (Ca)
63.7
mg/L
0.01
Magnesium (Mg)
9.67
mg/L
0.005
Potassium (K)
8.03
mg/L
0.1
Sodium (Na)
11.1
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.073
mg/L
0.005
Barium (Ba)
0.060
mg/L
0.005
Boron (B)
0.889
mg/L
0.05
Iron (Fe)
0.450
mg/L
0.01
Manganese (Mn)
0.048
mg/L
0.005
Strontium (Sr)
0.315
mg/L
0.005
Zinc (Zn)
0.047
mg/L
0.005
Sample #: 2015014872
Matrix: GW -WW
Page 6 of 41
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
05/26/2015 12:12
LSTARL1
1
EPA 300.0
05/22/2015 09:15
BGN9034
25
EPA 300.0
05/22/2015 09:15
BGN9034
1
EPA 245.1
05/20/2015 12:25
ACPAYNE
1
EPA 245.1
05/20/2015 13:50
ACPAYNE
1
EPA 200.7
05/18/2015 12:17
MHALL3
1
EPA 200.7
05/18/2015 12:17
MHALL3
1
EPA 200.7
05/18/2015 12:17
MHALL3
1
EPA 200.7
05/18/2015 12:17
MHALL3
1
EPA 200.7
05/18/2015 12:17
MHALL3
1
EPA 200.7
05/18/2015 12:17
MHALL3
1
EPA 200.7
05/18/2015 12:17
MHALL3
1
EPA 200.7
05/18/2015 15:29
MHALL3
1
EPA 200.7
05/18/2015 15:29
MHALL3
1
EPA 200.7
05/18/2015 15:29
MHALL3
1
EPA 200.7
05/18/2015 15:29
MHALL3
1
EPA 200.7
05/19/2015 15:51
MHALL3
1
EPA 200.7
05/19/2015 15:51
MHALL3
1
EPA 200.7
05/19/2015 15:51
MHALL3
1
EPA 200.7
05/19/2015 15:51
MHALL3
1
EPA 200.7
05/19/2015 15:51
MHALL3
1
EPA 200.7
05/19/2015 15:51
MHALL3
1
EPA 200.7
05/19/2015 15:51
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050442
Site: PZ -17D
Collection Date: 15 -May -15 10:15 AM
Analyte
Result
DISSOLVED METALS BY ICP -MS
Sample #:
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
1.29
Cobalt (Co)
< 1
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
6.95
Selenium (Se)
23.6
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
8.66
Cobalt (Co)
< 1
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
11.2
Selenium (Se)
22.2
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
ug/L
TDS
320
Total Carbon
05/28/2015 12:55
TOC
0.314
TOTAL SUSPENDED SOLIDS
1
TSS
7.0
Page 7 of 41
ug/L
1
1
Sample #:
2015014872
DJSULL1
ug/L
1
1
Matrix:
GW -WW
DJSULL1
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
ug/L
1
1
EPA 200.8
05/28/2015 12:55
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 12:55
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 12:55
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 12:55
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 12:55
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 12:55
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 12:55
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 12:55
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 12:55
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 12:55
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 12:55
DJSULL1
ug/L
0.2
1
EPA 200.8
05/28/2015 12:55
DJSULL1
ug/L
0.3
1
EPA 200.8
05/28/2015 12:55
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 17:10
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 17:10
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 17:10
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 17:10
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 17:10
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 17:10
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 17:10
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 17:10
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 17:10
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 17:10
DJSULL1
ug/L
1
1
EPA 200.8
05/19/2015 17:10
DJSULL1
ug/L
0.2
1
EPA 200.8
05/19/2015 17:10
DJSULL1
ug/L
0.3
1
EPA 200.8
05/19/2015 17:10
DJSULL1
Vendor Method
V_SHEALY
Vendor Method
V_ELE1
mg/L
25
1
SM2540C
05/20/201514:30
AGIBBS5
mg/L
0.1
1
SM5310C/EPA9060A
05/20/201514:33
TJA7067
mg/L
5
1
SM2540D
05/19/201511:30
AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050442
Site: Equipment Blank
Collection Date: 15 -May -15 12:10 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy
Labs)
1 EPA 300.0
Vendor Parameter
Complete
1 EPA 300.0
05/21/2015 16:08
NITRITE + NITRATE (COLORIMETRIC)
1 EPA 245.1
05/20/2015 12:28
Nitrite + Nitrate (Colorimetric)
0.031
mg-N/L
0.01
INORGANIC IONS BY IC
05/18/2015 15:06
MHALL3
1 EPA 200.7
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
05/19/2015 15:55
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
MHALL3
1 EPA 200.7
05/19/2015 15:55
Calcium (Ca)
0.012
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
05/19/2015 17:14
DJSULL1
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Page 8 of 41
Sample #: 2015014873
Matrix: GW -WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1 EPA 353.2
05/26/2015 12:13
LSTARL1
1 EPA 300.0
05/21/2015 16:08
BGN9034
1 EPA 300.0
05/21/2015 16:08
BGN9034
1 EPA 245.1
05/20/2015 12:28
ACPAYNE
1 EPA 200.7
05/18/2015 15:06
MHALL3
1 EPA 200.7
05/18/2015 15:06
MHALL3
1 EPA 200.7
05/18/2015 15:06
MHALL3
1 EPA 200.7
05/18/2015 15:06
MHALL3
1 EPA 200.7
05/19/2015 15:55
MHALL3
1 EPA 200.7
05/19/2015 15:55
MHALL3
1 EPA 200.7
05/19/2015 15:55
MHALL3
1 EPA 200.7
05/19/2015 15:55
MHALL3
1 EPA 200.7
05/19/2015 15:55
MHALL3
1 EPA 200.7
05/19/2015 15:55
MHALL3
1 EPA 200.7
05/19/2015 15:55
MHALL3
1 EPA 200.8
05/19/2015 17:14
DJSULL1
1 EPA 200.8
05/19/2015 17:14
DJSULL1
1 EPA 200.8
05/19/2015 17:14
DJSULL1
1 EPA 200.8
05/19/2015 17:14
DJSULL1
1 EPA 200.8
05/19/2015 17:14
DJSULL1
1 EPA 200.8
05/19/2015 17:14
DJSULL1
1 EPA 200.8
05/19/2015 17:14
DJSULL1
1 EPA 200.8
05/19/2015 17:14
DJSULL1
1 EPA 200.8
05/19/2015 17:14
DJSULL1
1 EPA 200.8
05/19/2015 17:14
DJSULL1
1 EPA 200.8
05/19/2015 17:14
DJSULL1
1 EPA 200.8
05/19/2015 17:14
DJSULL1
1 EPA 200.8
05/19/2015 17:14
DJSULL1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4) Complete Vendor Method V_SHEALY

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050442
Site: Equipment Blank
Collection Date: 15-Mav-15 12:10 PM
Analyte Result Units Qualifiers RDL DF
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L 25 1
Total Carbon
Sample #: 2015014873
Matrix: GW WW
Page 9 of 41
Method Analysis Date/Time Analyst
Vendor Method
V_ELE1
SM2540C 05/20/201514:30 AGIBBS5
TOC 0.112 mg/L 0.1 1 SM5310C/EPA9060A 05/20/201514:33 TJA7067
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 05/19/2015 11:30 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050442
Site: Filter Blank
Collection Date: 15 -May -15 12:10 PM
Analyte
Result
Units
Qualifiers RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
EPA 245.1
05/20/2015 13:57
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
1
EPA 200.7
05/18/2015 12:49
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP -MS
1
EPA 200.8
05/28/2015 12:59
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2015014874
Matrix: GW -WW
Page 10 of 41
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
05/20/2015 13:57
ACPAYNE
1
EPA 200.7
05/18/2015 12:49
MHALL3
1
EPA 200.7
05/18/2015 12:49
MHALL3
1
EPA 200.7
05/18/2015 12:49
MHALL3
1
EPA 200.7
05/18/2015 12:49
MHALL3
1
EPA 200.7
05/18/2015 12:49
MHALL3
1
EPA 200.7
05/18/2015 12:49
MHALL3
1
EPA 200.7
05/18/2015 12:49
MHALL3
1
EPA 200.8
05/28/2015 12:59
DJSULL1
1
EPA 200.8
05/28/2015 12:59
DJSULL1
1
EPA 200.8
05/28/2015 12:59
DJSULL1
1
EPA 200.8
05/28/2015 12:59
DJSULL1
1
EPA 200.8
05/28/2015 12:59
DJSULL1
1
EPA 200.8
05/28/2015 12:59
DJSULL1
1
EPA 200.8
05/28/2015 12:59
DJSULL1
1
EPA 200.8
05/28/2015 12:59
DJSULL1
1
EPA 200.8
05/28/2015 12:59
DJSULL1
1
EPA 200.8
05/28/2015 12:59
DJSULL1
1
EPA 200.8
05/28/2015 12:59
DJSULL1
1
EPA 200.8
05/28/2015 12:59
DJSULL1
1
EPA 200.8
05/28/2015 12:59
DJSULL1

min
REPORT OF ANALYSES
Page 11 of 41
Element One Inca
6319-D Carolina Beach Rd.
Wilmington, NC 28412
Phone: [phone]
(fax: [phone]
[e-mail]
Duke Energy
May 28, 2015
Laboratory Services
Client Project Name AB GW Assessment water Asheville
13339 Hagers Ferry Road Bid. MG03A
Client Project Number J15050442
Huntersville, NC 28078
PO Number
Sample Matrix
Sample Type Grab
Date Received
05/19/2015
Date Analyzed 05/20/2015
Method
SM 4500 S2- D
Time Received
1400
Delivered by FedEx
Received by
JRC
eOne ID Duke Energy ID
Parameter
Result Unit Dil
DL Date
Time
Sampled
Sampled
24796-1 PZ -17S
Sulfide
< 0.1 mg/L 1
0.1 05/15/15
1052
24796-2 PZ -17D
Sulfide
< 0.1 mg/L 1
0.1 05/15/15
1015
24796-3 Equipment Blank
Sulfide
< 0.1 mg/L 1
0.1 05/15/15
1210
Ken Smith, Laboratory Director
24796 Duke Report Packet Compiled by !!!�2
NC Certifications: DW 37788 and DWQ DENR 604

O
IL
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Page 12 of 41
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elementOne SAMPLE SUBMISSION FORM Lab D" 24796
24796
TAT 7 BD
Hold Time Expiration 05.22.15 @ 1015
Client: Duke Energy
LIMS No J15050442
Project ID Asheville
Analysis Due Date 05.20.15
Report Due Date 05.28.15
Date Rec:
05.19.15
Time Rec:
1400
Rec By
J RC
H >9 a No
I Tem <_ 6°C Yes No
Ref. Method:
SM4500 S2 D
If No, Record
If No, Record
Sample Identification $ Collection Information
Lab ID I
Client ID
Collection Date Collection Time Anal sis Requested
1
PZ -17S
05/15/15 1052
2
PZ -17D
05/15/15 1015 Ulf'
3
Equipment
Blank 05/15/815 1210 u '
NOTE for Sulfide
The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected
at 100 pg/L spike the sample to render the final spike concentration at - 500 pg/L
Lab Communications
All AB Groundwater Assessment jobs need a RL of 0.1
SS Page 1 of 1 Prep By / Date 5 oZc
SS by Labeled By / Date
5/20/2015 —8f55: 1-2 AM ID Verification By /Date v
15o I S

Page 14 of 41
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT: Duke
SPK LEVELLuM
5
Lab ID#
24794/ 24795124796/ 24797 / 24798
Na2S•9H2O Lot#
40721
MAX ALIQUOT
10.00
Date: 05/20/15
STANDARD conc(ppm)
X
Time Analysis Begun 9:30
lCal Std Lot:
WC2-81-3
Time Analysis Ended 14:40
JQC Std Lot:
WC2-81-4
Analyst: KAM
STD ABSORPTION
Y
X
ug STD
SOLUTION
0,00
1.00
2.50
5.00
7.50
10.00
Y
STD
ABS
0.000
0.096
0.241
0.447
0.635
0.806
09m
I ..
a'oo-----
°'°°0.
0.2W
0AW
0'0°0.00
-
2.00
4.00
---
a.ao
x
- -
a.00 low
oma
-sem
11.00
Slope
0.080628571
Correlation
: 0.898105892
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
LESS THAN
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.00
Std. B. 1.00
0.101
0.7975
10
10
10
<
79.75%
1.00
Std. B. 2.50
0.238
2.5927
10
10
10
0.259
103.71%
2.50
Std. B. 5.00
0.448
5.3445
10
10
10
0.534
106.89%
5.00
Std. B. 7.50
0.653
8.0307
10
10
10
0.803
107.08%
1 7.50
Std. B. 10.00
0.794
9.8784
10
10
10
0.988
98.78%
10.00
LRB
0.000
0.0000
10
10
10
<
0.00
LRB SPK
0.451
5.3838 1
10
10
10
0.538
108%
5.0
QC
0.461
5.5148
10
10
10
0.551
110%
5.0
24794-2
0.091
0.6665
10
10
10
X"R1
24794-2 s k
0.471
5.6459
10
10
10
0.565
113%
5.0
24794-3
0.027
-0.1721
10
10
10
<
24794-3 dup
0.027
-0.1721
10
10
10
<
24794-3 s k
0.361
4.2045
10
10
10
0.420
84%
5.0
24794-4
0.001
-0.5128
10
10
10
24794-45 k
0.375
4.3879
10
10
10
0.439
88%
5.0
24795-1
0.001
-0.5128
10
10
10
24795-1 s k
0.439
5.2266
10
10
10
0.523
105%
5.0
24795-2
0.006
-0.4473
10
10
10fl.i�
24795-2 s k
0.417
4.9383
10
10
10
0.494
99%
5.0
24795-3
0.009
-0.4080
10
10
10>b<}!1
24795-3 s k
0.426
5.0562
10
10
10
0.506
101%
5.0
24795-4
0.018
-0.2901
10
10
10
<
24795-4 s k
0.266
2.9858
10
10
10
0.299
60%
5.0
24795-5
0.031
-0.1197
10
10
10
24795-5 s k
0.428
5.0824
10
10
10
0.508
102%
5.0
24795-6
0.001
-0.5128
10
10
10'nF0.0
24795-6 s k
0.398
4.6893
10
10
10
0.469
94%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.460
5.5017
10
10
10
0.550
110%
5.0
.Submitted for QAIQC-
Date: 05/20/15
By: (Print)
KAM
(sign):
�-
Page 1 of 5

Page 15 of 41
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT:
Duke
SPK LEVELJyM
5
Lab ID#
24794 / 24795,/ 24796 / 24797,/ 24798
Na2S•9H2O Lot #
40721
MAX ALIQUOT
10.00
Date:
05/20/15
STANDARD conc(pp_m)
X
Time Analysis Begun
9:30
lCal Std Lot:
I WC2-81-3
Time Analysis Ended
14:40
JQC Std Lot:
I WC2-81-4
Analyst:
KAM
STD ABSORPTION
Y
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
STD
ABS
0.000
0.096
0.241
0.447
0.635
1 0.806
°.
0wo
0500
°�° --
u�
0+00
0000
0.00
----
2.00
4.00
-'- -
5.00
x
-- -
5.00
10.00
-°°°
-_-- --
17.00
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
Sloe
ALI in mL
TAKEN
0.080628571_
RESULTS
ug/mL
Correlation
LESS THAN
% SPK REC
0.998105892
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.00
Std. B. 1.00
0.101
0.7975
10
10
10
<
79.75%
1.00
Std. B. 2.50
0.238
2.5927
10
10
10
0.259
103.71%
2.50
Std. B. 5.00
0.448
5.3445
10
10
10
0.534
106.89%
5.00
Std. B. 7.50
0.653
8.0307
10
10
10
0.803
107.08%
7.50
Std. B. 10.00
0.794
9.8784
10
10
10
0.988
98.78%
10.00
LRB
0.000
0.0000
10
10
10
<
0.00
LRB SPK
0.451
5.3838
10
10
10
0.538
108%
5.0
QC
0.461
5.5148
10
10
10
0.551
110%
5.0
24795-7
0.006
-0.4473
10
10
10
<
24795-7 s k
0.155
1.5051
10
10
10
0.151
30%
5.0
24795-8
0.003
-0.4866
10
10
10
d.(1
24795-8 d up
0.002
-0.4997
10
10
10
< 0.1
24795-8 s k
0.434
5.1610
10
10
10
0.516
103%
5.0
24795-9
0.007
-0.4342
10
10
1001
24795-9 s k
0.421
4.9907
10
10
10
0.499
100%
5.0
24796-1
0.002
-0.4997
10
10
10
24796-1 s k
0.440
5.2397
10
10
10
0.524
105%
5.0
24796-2
0.004
-0.4735
10
10
10
£;01
24796-2 s k
0.415
4.9121
10
10
10
0.491
98%
5.0
24796-3
0.003
-0.4866
10
10
10+'
24796-3 s k
0.431
5.1217
10
10
10
0.512
102%
5.0
24797-1
1.443
18.3826
10
10
10
1.838
24797-1 s k
1.595
20.3744
10
10
10
2.037
40%
5.0
24797-2
0.002
-0.4997
10
10
10
24797-2 s k
0.387
4.5452
10
10
10
0.455
91%
5.0
24797-3
0.039
-0.0149
10
10
10
24797-3 s k
0.367
4.2831
10
10
10
0.428
86%
5.0
Blank
0.000
0.0000 1
10
10
10
<
QC
0.459
5.4886
10
10
10
0.549
110%
5.0
Submitted Or Q Q
Date: 05/20/15
By: (Print)
KAM
(sign):`.
Page 2 of 5

Page 16 of 41
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Duke
24794 / 24795 / 24796,1'24797 24798
05/20/15
9:30
14:40
KAM
Y o�
Spectrophotometer
Wave Length 664
Na2S•9H2O Lot #
40721
UNITS OF ANSWER
DETECTION LIMIT u
SPK LEVEL u
MAX ALIQUOT
STANDARD conc(ppm)
1 Cal Std Lot:
1 QC Std Lot:
STD ABSORPTION
ug/mL
1.000
5
10.00'
X
WC2-81-3
WC2-81-4
Y
CLIENT:
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
STD
0.wo
ABS 0.700
610
0.00
1.00
2.50
5.00
7.50
10.00
0.000
3
0.096
.-7
=5��
0300
- ---
°°
0.241 0100
j
0.447 0.100
---
00°°
0.635
0.806
0.63
2.W
4.00e.ao
x
e.00
10.ao izm
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
Sloe
ALI in mL
TAKEN
0:080628571'
RESULTS
ug/mL
Correlation
LESS THAN
% SPK REC
0.998.105892`I
SPIKE
LEVEL
Std. B. 0.00
Std. B. 1.00
0.000
0.101
1 0.0000
1 0.7975
10
10
10
10
10
10
<
<
79.75%
0.00
1.00
Std. B. 2.50
Std. B. 5.00
Std. B. 7.50
Std. B. 10.00
0.238
0.448
0.653
0.794
2.5927
5.3445
8.0307
9.8784
10
10
10
10
10
10
10
10
10
10
10
10
0.259
0.534
0.803
0.988
103.71%
106.89%
107.08%
98.78%
2.50
5.00
7.50
10.00
LRB
0.000
0.0000
10
10
10
<
0.00
LRB SPK
0.451
5.3838
10
10 1
10
0.538
108%
5.0
QC
0.461
5.5148
10
10
10
0.551
110%
5.0
24797-4
0.007
-0.4342
10
10
10'_
24797-4 s k
0.404
4.7679
10
10
10
0.477
95%
5.0
24797-5
0.006
-0.4473
10
10
10
24797-5 S k
0.415
4.9121
10
10
10
0.491
98%
5.0
24797-6
0.011
-0.3818
10
10
10,E
24797-6 dup
0.014
-0.3425
10
10
10
< 0.1
24797-6 s k
0.377
4.4141
10
10
10
0.441
88%
5.0
7-7
0.041
0.0113
10
10
10
0� „
24797-7 s k
0.370
4.3224
10
10
10
0.432
86%
5.0
24797-8
0.013
-0.3556
10
10
10
<
24797-8 s k
0.350
4.0603
10
10
10
0.406
81%
5.0
24797-9
0.033
-0.0935
10
10
10
«0a t
24797-9 s k
0.375
4.3879
10
10
10
0.439
88%
5.0
24798-1
0.002
-0.4997
10
10
10
<
24798-1 s k
0.301
3.4183
10
10
10
0.342
68%
5.0
24798-2
0.006
-0.4473
10
10
10};'
24798-2 s k
0.401
4.7286
10
10
10
0.473
95%
5.0
24798-3
0.004
-0.4735
10
10
10
<
24798-3 s k
0.339
3.9162
10
10
10
0.392
78%
5.0
Blank
0.000
0.0000
10
10
10
<
QC 0.460 5.5017
Submitted Or Q CQC- Date: 05/20/15
10
10
By: (Print)
10
0.550 110% 5.0
KAM (sign):
Page 3 of 5

Page 17 of 41
METHOD: SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY: Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
DETECTION LIMu
ITSPK
CLIENT: Duke
LEVEL u
Lab ID# 24794 / 24795 / 24796 / 24797 /'24798
Na2S•91-12O Lot #
40721
MAX ALIQUOT
Date: 05/20/15
STANDARD conc(ppm)
Time Analysis Begun 9:30<
Cal Std Lot:
Time Analysis Ended 14:40
QC Std Lot:
Analyst: KAM`
STD ABSORPTION
ug 61 U 5TU j
SOLUTION
ABS
0.00
0.000
1.00
0.096
2.50
0.241
5.00
0.447
7.50
0.635
x
X
Page 4 of 5
Sloe
0.080628571
Correlation
0.998105892
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
LESS THAN
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.00
Std. B. 1.00
0.101
0.7975
10
10
10
<
79.75%
1.00
Std. B. 2.50
0.238
2.5927
10
10
10
0.259
103.71%
2.50
Std. B. 5.00
0.448
5.3445
10
10
10
0.534
106.89%
5.00
Std. B. 7.50
0.653
8.0307
10
10
10
0.803
107.08%
7.50
Std. B. 10.00
0.794
9.8784
10
10
10
0.988
98.78%
10.00
LRB
0.000
0.0000
10
10
10
<
0.00
LRB SPK
0.451
5.3838
10
10
10
0.538
108%
5.0
QC
0.461
5.5148
10
10
10
0.551
110%
5.0
24798-4
0.002
-0.4997
10
10
10
e�iq
24798-4 s k
0.421
4.9907
10
10
10
0.499
100%
5.0
24794-3
0.015
-0.3294
10
10
5
24794-3 s k
0.385
4.5190
10
10
5
0.904
90%
5.0
24795-4
0.013
-0.3556
10
10
5
<
24795-4 s k
0.272
3.0383
10
10
5
0.608
61%
5.0
24795-7
0.008
-0.4211
10
10
5
<
24795-7 s k
0.308
3.5100
10
10
5
0.702
70%
5.0
24797-1
0.859
10.7301
10
10
5
2.146
24797-1 dup
0.867
10.8349
10
10
5
2.167
24797-1 s k
1.155
14.6088
10
10
5
2.922
75%
5.0
24797-8
0.010
-0.3949
10
10
5fi
2°
24797-8 s k
0.385
4.5190
10
10
5
0.904
90%
5.0
24798-1
0.004
-0.4735
10
10
5
<
24798-1 s k
0.354
4.1128
10
10
5
0.823
82%
5.0
24798-3
0.002
-0.4997
10
10
5
w' 'A
24798-3 s k
0.368
4.2962
10
10
5
0.859
86%
5.0
24795-4
0.006
-0.4473
10
10
2
<
24795-4 s k
0.033
-0.0935
10
10
2
<
-2%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.459
5.4886
10
10
10
0.549
110%
5.0
Su mitted for QA/13C
-
Date: 05/20/15
By: (Print)
KAM
(sign):
Page 4 of 5

Page 18 of 41
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
Na2S•9H2O Lot #
40721
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
SPK LEYELLuM
MAX ALIQUOT
1:000
5
10.00
CLIENT:
Lab ID#
Duke
24794 / 24795 124796 / 24797 / 24798
Date:
05/20/15
STANDARD conc(ppm)
X
Time Analysis Begun
9:30
Cal Std Lot:
WC2-81-3
Time Analysis Ended
14:40
1 QC Std Lot:
WC2-81-4
Analyst:
KAM
STD ABSORPTION
Y
ug STD
SOLUTION
2.50
5.00
7.50
10.00
STD
ABS
0.000
0.096 `
0.241
0.447
0.635
0.806
o.Wo
Fo.wo
0.1000.00
061.00
°-4
0.700
0+00
o.aoo060 .
Z.2441
7.00
4.00
6.a0
x
8.60 +0a0
,
700
i
-
SAMPLE
I.D.
Std. B. 0.00
Std. B. 1.00
Std. B. 2.50
Std. B. 5.00
Std. B. 7.50
Std. B. 10.00
SAMP
ABS
0.000 1
0.101
0.238 1
0.448 1
0.653
0.794
ug PER
ALIQUOT
0.0000
0.7975
2.5927
5.3445
8.0307
9.8784
ALI in mL
ANALYZED
10
10
10
10
10
10
PREP
VOL in mL
10
10
10
10
10
10
Sloe
ALI in mL
TAKEN
10
10
10
10
10
10
0.080628571 Correlation
RESULTS LESS THAN
ug/mL % SPK REC
<
< 79.75%
0.259 103.71%
0.534 106.89%
0.803 107.08%
0.988 98.78%
0.9.98105892
SPIKE
LEVEL
0.00
1.00
2.50
5.00
7.50
10.00
LRB
0.000
0.0000
10
10
10
<
0.00
LRB SPK
0.451
5.3838
10
10
10
0.538 108%
5.0
QC
0.461
5.5148
10
10
10
0.551 110%
5.0
24796-7
0.006
-0.4473
10
10
2
77-77,
24796-7 s k
0.384
4.5059
10
10
2
2.253 90%
5.D
24797-1
0.383
4.4928
10
10
2�i
o46_
24797-1 s k
0.718
8.8825
10
10
2
4.441 88%
5.0
24798-1
0.002
-0.4997
10
10
277
77, 77
O
24798-1 s k
0.400
4.7155
10
10
2
2.358 94%
5.0
24795-4
0.005
-0.4604
10
10
0.2
24795-4
0.309
3.5231
10
10
0.2
17.615 70%
5.0
Blank
0.000
0.0000
10
10
10
<
QC 5.4886
SU mltted for QA/QC- Date: 05/20/15
10
10
By: (Print)
10
---0.459
0.549 110%
KAM (sign):
5.0
Page 5 of 5

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
Project Name: AB GW Assessment Water - Asheville
Project Number:J15050442
Lot Number:QE19005
Date Completed:05/22/2015
Grant Wilton
Project Manager
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
*QE19005*
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SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: QE19005
Project Name: AB GW Assessment Water - Asheville
Project Number: J15050442
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page
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SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QE19005
Project Name: AB GW Assessment Water - Asheville
Project Number: J15050442
Sample Number Sample ID Matrix Date Sampled Date Received
001 2015014871 Aqueous 05/15/20151052 05/18/2015
002 2015014872 Aqueous 05/15/20151015 05/18/2015
003 2015014873
(3 samples)
Aqueous 05/15/20151210 05/18/2015
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SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QE19005
Project Name: AB GW Assessment Water - Asheville
Project Number: J15050442
Sample Sample ID Matrix Parameter Method Result Q Units Page
002 2015014872 Aqueous Alkalinity SM 2320B- 62 mg/L 7
002 2015014872 Aqueous Bicarbonate Alkalinity SM 2320B- 62 mg/L 7
(2 detections)
Shealy Environmental Services, Inc. Page: 4 of 10
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE19005-001
Description: 2015014871 Matrix: Aqueous
Date Sampled:05/15/2015 1052 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050442
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 05/20/2015 2037
HMA 75452
1
(Bicarbonate ) SM 2320B-2011
1 05/20/2015 2037
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/20/2015 2037
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QE19005-001
Description: 2015014871 Matrix: Aqueous
Date Sampled:05/15/2015 1052 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050442
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/20/2015 1431 DCS 75426
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE19005-002
Description: 2015014872 Matrix: Aqueous
Date Sampled:05/15/2015 1015 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050442
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 05/20/2015 2044
HMA 75452
1
(Bicarbonate ) SM 2320B-2011
1 05/20/2015 2044
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/20/2015 2044
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
62
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
62
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QE19005-002
Description: 2015014872 Matrix: Aqueous
Date Sampled:05/15/2015 1015 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050442
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/20/2015 1451 DCS 75426
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE19005-003
Description: 2015014873 Matrix: Aqueous
Date Sampled:05/15/2015 1210 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050442
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 05/20/2015 2106
HMA 75453
1
(Bicarbonate ) SM 2320B-2011
1 05/20/2015 2106
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/20/2015 2106
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QE19005-003
Description: 2015014873 Matrix: Aqueous
Date Sampled:05/15/2015 1210 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050442
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/20/2015 1501 DCS 75426
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: QE19005
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Inorganic non-metals - Ii
Sample ID: QQ75452-001 Matrix: Aqueous
Batch: 75452
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 05/20/20151751
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE19005
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Inorganic non-metals - LCS
Sample ID: QQ75452-002 Matrix: Aqueous
Batch: 75452
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 90 1 90 90-110 05/20/20151757
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE19005
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Inorganic non-metals - Ii
Sample ID: QQ75453-001 Matrix: Aqueous
Batch: 75453
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 05/20/2015 2055
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE19005
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Inorganic non-metals - LCS
Sample ID: QQ75453-002 Matrix: Aqueous
Batch: 75453
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 90 1 90 90-110 05/20/2015 2102
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE19005
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Inorganic non-metals - MS
Sample ID: QE19005-003MS Matrix: Aqueous
Batch: 75453
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity ND 100 88 1 88 70-130 05/20/2015 2111
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE19005
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Inorganic non-metals - MSD
Sample ID: QE19005-003MD Matrix: Aqueous
Batch: 75453
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Alkalinity ND 100 92 1 92 3.7 70-130 20 05/20/2015 2117
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE19005
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - MB
Sample ID: QQ75426-001 Matrix: Aqueous
Batch: 75426
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 05/20/2015 0958
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE19005
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCS
Sample ID: QQ75426-002 Matrix: Aqueous
Batch: 75426
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 150 130 1 84 70-130 05/20/2015 0932
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE19005
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCSD
Sample ID: QQ75426-003 Matrix: Aqueous
Batch: 75426
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 150 130 1 85 1.9 70-130 30 05/20/2015 0946
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE19005
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
Shenly Environs ail Sorrier„ In:
[hiCumenl Nvcibed. F-AC016
AcAsion Numbcr LT
Sample Receipt Checklist (SRC.)
f -age I of l
R�pla:ss Dale. 1 DONA
tmiL- -UU Mtn 0mfw I
C:lment: Le' ErZt'rr !4 Cooler Inspected bye{date; i qrf Lot #: Q e t
means of receiptS2S1r ❑ Client ❑ ITS ❑ Ai)Qme ]Exp `�tn�12cr
Yes ❑ I No PT I l . were custody seals MSCIlt on the cooler? _
Ycs Ll I No N 2. If custody scats wcrc prcscnt, were, dle y in1.ar;t and unbroken ?
Cooler II lOriginal temperature upon nmeiptlDerived (correoled) lramperaturc upon rwelpt:
'DC I I $c 9C } � or
I+�l third; Fcmp�ratur�. lank ❑ Against Bottics III dip ; IR Galin Correction Factor. _0
cibu€1 of e0olarot. Wet l Bluc Icc ❑ Dry Ice L None
3 _ If temperature of any cooler exceeded 6.4cC, was Prcj ect Manager notified?
Yes 0No ❑ NA PM notified by SRC, phone, note (circle onc), uthur:
(For 000lers received via onlnniercial. oouncr, Perls arc to be notified
Ysz ❑
Yes
No
Pic) ❑
NA ❑
4. Is tine packing slip attachrd to Mu fiarm?
5. Were Furopenr pustGdy procedLues rely ish 'reecivGd) followed?
Yes ❑
NA ❑Sa
Were sara les rplingiiished by eiient to -cornrnercial courier?
Yeg
yo ❑
6. Wore sam lC'IDs listed on the COC?
Yes
a ❑
7 Were sa,n+ le IDs listedd oil all sans lc containers?
Yeas
Yes
Yes
jqo ❑
a
o ❑
S. Was collectiork elate & time listed on the COC 9
9_ Was collection date & dune listed on A s.atnjle +Louminm?
10. Did ali €xrnlainer label information ID, date, time agree with the COC:?
Yrs Ea
yo D
11. Wffe tests 10 be perfonned listed on the COC?
Yes
No ❑
12. laid all samples arrive in the pEpKr contain for each test?
pies
a n
13. [did all contairliers arrive in good coiid.ition uabro en, lids on. etc. ?
Yes
No
14. 'W'as adequate wm Ic -volume available?
Yes ❑
No
15. W'cre all samples received within lei the. holding time or 48 hours, whichover
CQUales first?
Yes
Yes ❑
No
N6 ET
_
16. were stay Saul les Contain Missi
e?
17. %Fere there Rny excess sate Les nor listed on COC?
e4 0
Ye- ❑
No
No ❑
NA
NA
J8.1 are bubbles present?"pea-size" ("A"or 6rllln lel diameter) In any VDA Vlnk?
19.crc all uiLcta1&f0&G4MWjautficat sam los received ata pH of <2?
Yes -0 -
es
No El
NAV
20. Were all cyanide and/or sulfide samples received ata pH >12?
Yes ❑
No ❑
N
21 _ Were all applicable NH3lf Cq/cyanidc1phcnal (<0.2m&(L) samples frwe maf�
residual chlorine?
Yrs ❑
NoM__NAjf
22. Were collrctiian tcmperaturmdDcumciaLrd on the COC for NC 1cs?
Yes [
No
N
23. Were client remarkdrequests (i.e. rcgmesttd diilutio=._ h� &MSL] dessignatious,
mc_) o6ntetly transcribed from the COC into the crayfierit section in LM?
Yes ❑
Na
24, Was the quote number used taken fnrrm the canttainer label?
Sample Preservation (Must be compiezed for auy sample(s) incorrecciy preser..ui nr w:th head- pare.)
Sample(s) wrrc rccciyr�d incurr sly prrscnc� and were udjusted
vcwrdingly in sample tewivi with 7SO4,HN0a,HC1,Na0K) using S.R 9
Sam les
vcrC received with bubbles >6 mm in diameter.
sample(s)
were. received wit11 7RC" a0.2 rn If 921 is Na)
SC Drinking Water Project
9!n&L@
Sainple(s) pH verified to he. > 2 by Datc:
werencit teeeived ata pLf sof C2 and were a jested accordhyly usins Sits
Sample labels applied
` v:
rAAJP Veriftcd by; bate: ^f q—(j
Comments:
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

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