NC0000396_J15050421report_20150823

+ DUKE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Order Number: J15050421
Project Name: ASHEVILLE - AB GW ASSESSMENT WATER
Customer Name(s): Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker
Customer Address: 200 CP and L Drive
Arden, NC 28704
Lab Contact: Mary Ann Ogle Phone: [phone]
� 0, � Mary Ann Ogle
Report Authorized By: i "I I f 2015.05.2916:05:0bate: 5/29/2015
(Signature) (/ / -04'00'
Mary Ann Ogle
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
Page 1 of 70
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
Collected By
Sample Description
2015014746
ASHEVILLE
13 -May -15 2:50 PM
illegible
ADP -7
2015014747
ASHEVILLE
13 -May -15 2:25 PM
illegible
P-105
2015014748
ASHEVILLE
13 -May -15 4:30 PM
illegible
DP -1
2015014749
ASHEVILLE
14 -May -15 9:13 AM
illegible
ABMW-08
2015014750
ASHEVILLE
14 -May -15 10:58 AM
illegible
GW-01BR
2015014751
ASHEVILLE
14 -May -15 2:50 PM
illegible
GW -2
2015014752
ASHEVILLE
14 -May -15 1:58 PM
illegible
GW -3
2015014761
ASHEVILLE
13 -May -15 1:00 PM
Equipment Blank
2015014762
ASHEVILLE
14 -May -15 8:45 AM
Equipment Blank
2015014763
ASHEVILLE
13 -May -15 1:00 PM
Filter Blank
2015014764
ASHEVILLE
14 -May -15 8:45 AM
Filter Blank
11 Total Samples
Page 2 of 70

Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes F./] No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
U Job Summary Report
❑ Sample Identification
n Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Page 3 of 70
Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
66 Chain of Custody
[I/0] Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 5/29/2015

Certificate of Laboratory Analysis Page 4 of 70
This report shall not be reproduced, except in full.
Order # J15050421
Site: ADP -7
Collection Date: 13 -May -15 2:50 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
05/21/2015 09:20
Vendor Parameter
Complete
EPA 300.0
05/21/2015 09:20
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
0.727
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
10
mg/L
1
Sulfate
27
mg/L
1
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/18/2015 11:43
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/18/2015 11:43
MHALL3
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.011
mg/L
0.005
Boron (B)
0.134
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.014
mg/L
0.005
Strontium (Sr)
0.046
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/19/2015 12:54
MHALL3
Calcium (Ca)
16.4
mg/L
0.01
Magnesium (Mg)
6.76
mg/L
0.005
Potassium (K)
0.597
mg/L
0.1
Sodium (Na)
4.07
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.029
mg/L
0.005
Barium (Ba)
0.013
mg/L
0.005
Boron (B)
0.119
mg/L
0.05
Iron (Fe)
0.038
mg/L
0.01
Manganese (Mn)
0.012
mg/L
0.005
Strontium (Sr)
0.047
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015014746
Matrix: GW -WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
05/26/2015 11:53
LSTARL1
10
EPA 300.0
05/21/2015 09:20
BGN9034
10
EPA 300.0
05/21/2015 09:20
BGN9034
1
EPA 245.1
05/20/2015 11:31
ACPAYNE
1
EPA 245.1
05/20/2015 13:17
ACPAYNE
1
EPA 200.7
05/18/2015 11:43
MHALL3
1
EPA 200.7
05/18/2015 11:43
MHALL3
1
EPA 200.7
05/18/2015 11:43
MHALL3
1
EPA 200.7
05/18/2015 11:43
MHALL3
1
EPA 200.7
05/18/2015 11:43
MHALL3
1
EPA 200.7
05/18/2015 11:43
MHALL3
1
EPA 200.7
05/18/2015 11:43
MHALL3
1
EPA 200.7
05/18/2015 14:34
MHALL3
1
EPA 200.7
05/18/2015 14:34
MHALL3
1
EPA 200.7
05/18/2015 14:34
MHALL3
1
EPA 200.7
05/18/2015 14:34
MHALL3
1
EPA 200.7
05/19/2015 12:54
MHALL3
1
EPA 200.7
05/19/2015 12:54
MHALL3
1
EPA 200.7
05/19/2015 12:54
MHALL3
1
EPA 200.7
05/19/2015 12:54
MHALL3
1
EPA 200.7
05/19/2015 12:54
MHALL3
1
EPA 200.7
05/19/2015 12:54
MHALL3
1
EPA 200.7
05/19/2015 12:54
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050421
Site: ADP -7
Collection Date: 13 -May -15 2:50 PM
Analyte
Result
DISSOLVED METALS BY ICP -MS
Sample #:
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
< 1
Selenium (Se)
20.0
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
< 1
Selenium (Se)
19.0
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
ug/L
TDS
96
Total Carbon
05/28/2015 14:48
TOC
0.261
TOTAL SUSPENDED SOLIDS
1
TSS
< 5
Page 5 of 70
ug/L
1
1
Sample #:
2015014746
DJSULL1
ug/L
1
1
Matrix:
GW -WW
DJSULL1
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
ug/L
1
1
EPA 200.8
05/28/2015 14:48
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 14:48
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 14:48
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 14:48
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 14:48
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 14:48
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 14:48
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 14:48
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 14:48
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 14:48
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 14:48
DJSULL1
ug/L
0.2
1
EPA 200.8
05/28/2015 14:48
DJSULL1
ug/L
0.3
1
EPA 200.8
05/28/2015 14:48
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:07
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:07
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:07
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:07
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:07
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:07
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:07
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:07
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:07
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:07
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:07
DJSULL1
ug/L
0.2
1
EPA 200.8
05/20/2015 13:07
DJSULL1
ug/L
0.3
1
EPA 200.8
05/20/2015 13:07
DJSULL1
Vendor Method
V_SHEALY
Vendor Method
V_ELE1
mg/L
25
1
SM2540C
05/18/201514:24
AGIBBS5
mg/L
0.1
1
SM5310C/EPA9060A
05/20/201514:33
TJA7067
mg/L
5
1
SM2540D
05/18/2015 09:26
AGIBBS5

Certificate of Laboratory Analysis Page 6 of 70
This report shall not be reproduced, except in full.
Order # J15050421
Site: P-105
Collection Date: 13 -May -15 2:25 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
05/21/2015 12:35
Vendor Parameter
Complete
EPA 300.0
05/21/2015 12:35
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
1.4
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
9.0
mg/L
1
Sulfate
3.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/18/2015 11:54
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/18/2015 11:54
MHALL3
Aluminum (AI)
0.036
mg/L
0.005
Barium (Ba)
0.024
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.012
mg/L
0.01
Manganese (Mn)
0.110
mg/L
0.005
Strontium (Sr)
0.026
mg/L
0.005
Zinc (Zn)
0.044
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/19/2015 13:06
MHALL3
Calcium (Ca)
3.41
mg/L
0.01
Magnesium (Mg)
2.95
mg/L
0.005
Potassium (K)
0.919
mg/L
0.1
Sodium (Na)
2.58
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.412
mg/L
0.005
Barium (Ba)
0.028
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.422
mg/L
0.01
Manganese (Mn)
0.120
mg/L
0.005
Strontium (Sr)
0.026
mg/L
0.005
Zinc (Zn)
0.047
mg/L
0.005
Sample #: 2015014747
Matrix: GW -WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
05/26/2015 11:54
LSTARL1
10
EPA 300.0
05/21/2015 12:35
BGN9034
1
EPA 300.0
05/21/2015 12:35
BGN9034
1
EPA 245.1
05/21/2015 15:44
ACPAYNE
1
EPA 245.1
05/20/2015 13:24
ACPAYNE
1
EPA 200.7
05/18/2015 11:54
MHALL3
1
EPA 200.7
05/18/2015 11:54
MHALL3
1
EPA 200.7
05/18/2015 11:54
MHALL3
1
EPA 200.7
05/18/2015 11:54
MHALL3
1
EPA 200.7
05/18/2015 11:54
MHALL3
1
EPA 200.7
05/18/2015 11:54
MHALL3
1
EPA 200.7
05/18/2015 11:54
MHALL3
1
EPA 200.7
05/18/2015 14:23
MHALL3
1
EPA 200.7
05/18/2015 14:23
MHALL3
1
EPA 200.7
05/18/2015 14:23
MHALL3
1
EPA 200.7
05/18/2015 14:23
MHALL3
1
EPA 200.7
05/19/2015 13:06
MHALL3
1
EPA 200.7
05/19/2015 13:06
MHALL3
1
EPA 200.7
05/19/2015 13:06
MHALL3
1
EPA 200.7
05/19/2015 13:06
MHALL3
1
EPA 200.7
05/19/2015 13:06
MHALL3
1
EPA 200.7
05/19/2015 13:06
MHALL3
1
EPA 200.7
05/19/2015 13:06
MHALL3

Certificate of Laboratory Analysis Page 7 of 70
This report shall not be reproduced, except in full.
Order # J15050421
Site: P-105
Sample #: 2015014747
Collection Date: 13 -May -15 2:25 PM
Matrix: GW -WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
DISSOLVED METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 15:02
DJSULL1
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 15:02
DJSULL1
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 15:02
DJSULL1
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 15:02
DJSULL1
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 15:02
DJSULL1
Cobalt (Co)
3.66
ug/L
1
1
EPA 200.8
05/28/2015 15:02
DJSULL1
Copper (Cu)
1.62
ug/L
1
1
EPA 200.8
05/28/2015 15:02
DJSULL1
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 15:02
DJSULL1
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 15:02
DJSULL1
Nickel (Ni)
1.99
ug/L
1
1
EPA 200.8
05/28/2015 15:02
DJSULL1
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 15:02
DJSULL1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
05/28/2015 15:02
DJSULL1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
05/28/2015 15:02
DJSULL1
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
05/20/2015 12:44
DJSULL1
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
05/20/2015 12:44
DJSULL1
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
05/20/2015 12:44
DJSULL1
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
05/20/2015 12:44
DJSULL1
Chromium (Cr)
2.50
ug/L
1
1
EPA 200.8
05/20/2015 12:44
DJSULL1
Cobalt (Co)
3.97
ug/L
1
1
EPA 200.8
05/20/2015 12:44
DJSULL1
Copper (Cu)
1.10
ug/L
1
1
EPA 200.8
05/20/2015 12:44
DJSULL1
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
05/20/2015 12:44
DJSULL1
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
05/20/2015 12:44
DJSULL1
Nickel (Ni)
5.01
ug/L
1
1
EPA 200.8
05/20/2015 12:44
DJSULL1
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
05/20/2015 12:44
DJSULL1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
05/20/2015 12:44
DJSULL1
Vanadium (V) Low Level
0.584
ug/L
0.3
1
EPA 200.8
05/20/2015 12:44
DJSULL1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
44
mg/L
25
1
SM2540C
05/18/201514:24
AGIBBS5
Total Carbon
TOC
0.145
mg/L
0.1
1
SM5310C/EPA9060A
05/20/201514:33
TJA7067
TOTAL SUSPENDED SOLIDS
TSS
26
mg/L
5
1
SM2540D
05/18/2015 09:26
AGIBBS5

Certificate of Laboratory Analysis Page 8 of 70
This report shall not be reproduced, except in full.
Order # J15050421
Site: DP -1
Collection Date: 13 -May -15 4:30 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
05/21/2015 12:52
Vendor Parameter
Complete
EPA 300.0
05/21/2015 12:52
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
0.015
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
2.3
mg/L
0.1
Sulfate
96
mg/L
1
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/18/2015 11:58
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/18/2015 11:58
MHALL3
Aluminum (AI)
0.016
mg/L
0.005
Barium (Ba)
0.148
mg/L
0.005
Boron (B)
0.409
mg/L
0.05
Iron (Fe)
5.81
mg/L
0.01
Manganese (Mn)
1.58
mg/L
0.005
Strontium (Sr)
1.81
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/19/2015 13:09
MHALL3
Calcium (Ca)
98.3
mg/L
0.01
Magnesium (Mg)
8.96
mg/L
0.005
Potassium (K)
8.18
mg/L
0.1
Sodium (Na)
6.22
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.153
mg/L
0.005
Barium (Ba)
0.163
mg/L
0.005
Boron (B)
0.378
mg/L
0.05
Iron (Fe)
8.77
mg/L
0.01
Manganese (Mn)
1.57
mg/L
0.005
Strontium (Sr)
1.81
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015014748
Matrix: GW -WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
05/26/2015 11:55
LSTARL1
1
EPA 300.0
05/21/2015 12:52
BGN9034
10
EPA 300.0
05/21/2015 12:52
BGN9034
1
EPA 245.1
05/21/2015 15:46
ACPAYNE
1
EPA 245.1
05/20/2015 13:26
ACPAYNE
1
EPA 200.7
05/18/2015 11:58
MHALL3
1
EPA 200.7
05/18/2015 11:58
MHALL3
1
EPA 200.7
05/18/2015 11:58
MHALL3
1
EPA 200.7
05/18/2015 11:58
MHALL3
1
EPA 200.7
05/18/2015 11:58
MHALL3
1
EPA 200.7
05/18/2015 11:58
MHALL3
1
EPA 200.7
05/18/2015 11:58
MHALL3
1
EPA 200.7
05/18/2015 14:38
MHALL3
1
EPA 200.7
05/18/2015 14:38
MHALL3
1
EPA 200.7
05/18/2015 14:38
MHALL3
1
EPA 200.7
05/18/2015 14:38
MHALL3
1
EPA 200.7
05/19/2015 13:09
MHALL3
1
EPA 200.7
05/19/2015 13:09
MHALL3
1
EPA 200.7
05/19/2015 13:09
MHALL3
1
EPA 200.7
05/19/2015 13:09
MHALL3
1
EPA 200.7
05/19/2015 13:09
MHALL3
1
EPA 200.7
05/19/2015 13:09
MHALL3
1
EPA 200.7
05/19/2015 13:09
MHALL3

Certificate of Laboratory Analysis Page 9 of 70
This report shall not be reproduced, except in full.
Order # J15050421
Site: DP -1
Sample #: 2015014748
Collection Date: 13 -May -15 4:30 PM
Matrix: GW -WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
DISSOLVED METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 15:06
DJSULL1
Arsenic (As)
640
ug/L
10
10
EPA 200.8
05/28/2015 15:06
DJSULL1
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 15:06
DJSULL1
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 15:06
DJSULL1
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 15:06
DJSULL1
Cobalt (Co)
20.4
ug/L
1
1
EPA 200.8
05/28/2015 15:06
DJSULL1
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 15:06
DJSULL1
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 15:06
DJSULL1
Molybdenum (Mo)
49.5
ug/L
1
1
EPA 200.8
05/28/2015 15:06
DJSULL1
Nickel (Ni)
3.46
ug/L
1
1
EPA 200.8
05/28/2015 15:06
DJSULL1
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 15:06
DJSULL1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
05/28/2015 15:06
DJSULL1
Vanadium (V) Low Level
0.762
ug/L
0.3
1
EPA 200.8
05/28/2015 15:06
DJSULL1
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
05/20/2015 13:12
DJSULL1
Arsenic (As)
1180
ug/L
10
10
EPA 200.8
05/20/2015 13:12
DJSULL1
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
05/20/2015 13:12
DJSULL1
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
05/20/2015 13:12
DJSULL1
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
05/20/2015 13:12
DJSULL1
Cobalt (Co)
20.7
ug/L
1
1
EPA 200.8
05/20/2015 13:12
DJSULL1
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
05/20/2015 13:12
DJSULL1
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
05/20/2015 13:12
DJSULL1
Molybdenum (Mo)
51.6
ug/L
1
1
EPA 200.8
05/20/2015 13:12
DJSULL1
Nickel (Ni)
3.64
ug/L
1
1
EPA 200.8
05/20/2015 13:12
DJSULL1
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
05/20/2015 13:12
DJSULL1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
05/20/2015 13:12
DJSULL1
Vanadium (V) Low Level
3.12
ug/L
0.3
1
EPA 200.8
05/20/2015 13:12
DJSULL1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
370
mg/L
25
1
SM2540C
05/18/201514:24
AGIBBS5
Total Carbon
TOC
0.490
mg/L
0.1
1
SM5310C/EPA9060A
05/20/201514:33
TJA7067
TOTAL SUSPENDED SOLIDS
TSS
22
mg/L
5
1
SM2540D
05/18/2015 09:26
AGIBBS5

Certificate of Laboratory Analysis Page 10 of 70
This report shall not be reproduced, except in full.
Order # J15050421
Site: ABMW-08
Collection Date: 14 -May -15 9:13 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
05/21/2015 13:08
Vendor Parameter
Complete
EPA 300.0
05/21/2015 13:08
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
0.031
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
23
mg/L
1
Sulfate
0.48
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
MHALL3
10
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/18/2015 12:02
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/18/2015 12:02
MHALL3
Aluminum (AI)
0.090
mg/L
0.005
Barium (Ba)
0.386
mg/L
0.005
Boron (B)
0.289
mg/L
0.05
Iron (Fe)
81.2
mg/L
0.1
Manganese (Mn)
0.728
mg/L
0.005
Strontium (Sr)
1.00
mg/L
0.005
Zinc (Zn)
0.006
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/19/2015 13:13
MHALL3
Calcium (Ca)
20.0
mg/L
0.01
Magnesium (Mg)
19.7
mg/L
0.005
Potassium (K)
14.5
mg/L
0.1
Sodium (Na)
10.4
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.795
mg/L
0.005
Barium (Ba)
0.383
mg/L
0.005
Boron (B)
0.276
mg/L
0.05
Iron (Fe)
83.4
mg/L
0.1
Manganese (Mn)
0.711
mg/L
0.005
Strontium (Sr)
0.973
mg/L
0.005
Zinc (Zn)
0.007
mg/L
0.005
Sample #: 2015014749
Matrix: GW -WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
05/26/2015 11:56
LSTARL1
10
EPA 300.0
05/21/2015 13:08
BGN9034
1
EPA 300.0
05/21/2015 13:08
BGN9034
1
EPA 245.1
05/21/2015 15:49
ACPAYNE
1
EPA 245.1
05/20/2015 13:28
ACPAYNE
1
EPA 200.7
05/18/2015 12:02
MHALL3
1
EPA 200.7
05/18/2015 12:02
MHALL3
1
EPA 200.7
05/18/2015 12:02
MHALL3
10
EPA 200.7
05/18/2015 12:02
MHALL3
1
EPA 200.7
05/18/2015 12:02
MHALL3
1
EPA 200.7
05/18/2015 12:02
MHALL3
1
EPA 200.7
05/18/2015 12:02
MHALL3
1
EPA 200.7
05/18/2015 14:44
MHALL3
1
EPA 200.7
05/18/2015 14:44
MHALL3
1
EPA 200.7
05/18/2015 14:44
MHALL3
1
EPA 200.7
05/18/2015 14:44
MHALL3
1
EPA 200.7
05/19/2015 13:13
MHALL3
1
EPA 200.7
05/19/2015 13:13
MHALL3
1
EPA 200.7
05/19/2015 13:13
MHALL3
10
EPA 200.7
05/19/2015 13:13
MHALL3
1
EPA 200.7
05/19/2015 13:13
MHALL3
1
EPA 200.7
05/19/2015 13:13
MHALL3
1
EPA 200.7
05/19/2015 13:13
MHALL3

Certificate of Laboratory Analysis Page 11 of 70
This report shall not be reproduced, except in full.
Order # J15050421
Site: ABMW-08
Sample #: 2015014749
Collection Date: 14 -May -15 9:13 AM
Matrix: GW -WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
DISSOLVED METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 15:11
DJSULL1
Arsenic (As)
30.8
ug/L
1
1
EPA 200.8
05/28/2015 15:11
DJSULL1
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 15:11
DJSULL1
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 15:11
DJSULL1
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 15:11
DJSULL1
Cobalt (Co)
2.43
ug/L
1
1
EPA 200.8
05/28/2015 15:11
DJSULL1
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 15:11
DJSULL1
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
05/28/2015 15:11
DJSULL1
Molybdenum (Mo)
2.75
ug/L
1
1
EPA 200.8
05/28/2015 15:11
DJSULL1
Nickel (Ni)
1.68
ug/L
1
1
EPA 200.8
05/28/2015 15:11
DJSULL1
Selenium (Se)
3.33
ug/L
1
1
EPA 200.8
05/28/2015 15:11
DJSULL1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
05/28/2015 15:11
DJSULL1
Vanadium (V) Low Level
0.598
ug/L
0.3
1
EPA 200.8
05/28/2015 15:11
DJSULL1
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
05/20/2015 13:16
DJSULL1
Arsenic (As)
35.6
ug/L
1
1
EPA 200.8
05/20/2015 13:16
DJSULL1
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
05/20/2015 13:16
DJSULL1
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
05/20/2015 13:16
DJSULL1
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
05/20/2015 13:16
DJSULL1
Cobalt (Co)
2.72
ug/L
1
1
EPA 200.8
05/20/2015 13:16
DJSULL1
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
05/20/2015 13:16
DJSULL1
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
05/20/2015 13:16
DJSULL1
Molybdenum (Mo)
1.77
ug/L
1
1
EPA 200.8
05/20/2015 13:16
DJSULL1
Nickel (Ni)
1.90
ug/L
1
1
EPA 200.8
05/20/2015 13:16
DJSULL1
Selenium (Se)
2.23
ug/L
1
1
EPA 200.8
05/20/2015 13:16
DJSULL1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
05/20/2015 13:16
DJSULL1
Vanadium (V) Low Level
1.21
ug/L
0.3
1
EPA 200.8
05/20/2015 13:16
DJSULL1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
320
mg/L
25
1
SM2540C
05/18/201514:24
AGIBBS5
Total Carbon
TOC
56
mg/L
3
30
SM5310C/EPA9060A
05/20/201514:33
TJA7067
TOTAL SUSPENDED SOLIDS
TSS
120
mg/L
5
1
SM2540D
05/18/2015 09:26
AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050421
Site: GW -01 BR
Collection Date: 14 -May -15 10:58 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
BGN9034
1 EPA 300.0
Vendor Parameter
Complete
1 EPA 245.1
05/21/2015 15:51
NITRITE + NITRATE (COLORIMETRIC)
1 EPA 245.1
05/20/2015 13:31
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
05/18/2015 12:06
MHALL3
1 EPA 200.7
Chloride
1.3
mg/L
0.1
Sulfate
8.5
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
05/18/2015 12:06
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
MHALL3
1 EPA 200.7
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
1 EPA 200.7
05/18/2015 14:47
MHALL3
Aluminum (AI)
0.007
mg/L
0.005
Barium (Ba)
0.012
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
1.52
mg/L
0.01
Manganese (Mn)
0.089
mg/L
0.005
Strontium (Sr)
0.082
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
17.4
mg/L
0.01
Magnesium (Mg)
3.46
mg/L
0.005
Potassium (K)
2.36
mg/L
0.1
Sodium (Na)
6.02
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.080
mg/L
0.005
Barium (Ba)
0.012
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
1.78
mg/L
0.01
Manganese (Mn)
0.093
mg/L
0.005
Strontium (Sr)
0.084
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015014750
Matrix: GW -WW
Page 12 of 70
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1 EPA 353.2
05/26/2015 11:57
LSTARL1
1 EPA 300.0
05/21/2015 13:24
BGN9034
1 EPA 300.0
05/21/2015 13:24
BGN9034
1 EPA 245.1
05/21/2015 15:51
ACPAYNE
1 EPA 245.1
05/20/2015 13:31
ACPAYNE
1 EPA 200.7
05/18/2015 12:06
MHALL3
1 EPA 200.7
05/18/2015 12:06
MHALL3
1 EPA 200.7
05/18/2015 12:06
MHALL3
1 EPA 200.7
05/18/2015 12:06
MHALL3
1 EPA 200.7
05/18/2015 12:06
MHALL3
1 EPA 200.7
05/18/2015 12:06
MHALL3
1 EPA 200.7
05/18/2015 12:06
MHALL3
1 EPA 200.7
05/18/2015 14:47
MHALL3
1 EPA 200.7
05/18/2015 14:47
MHALL3
1 EPA 200.7
05/18/2015 14:47
MHALL3
1 EPA 200.7
05/18/2015 14:47
MHALL3
1 EPA 200.7
05/19/2015 13:17
MHALL3
1 EPA 200.7
05/19/2015 13:17
MHALL3
1 EPA 200.7
05/19/2015 13:17
MHALL3
1 EPA 200.7
05/19/2015 13:17
MHALL3
1 EPA 200.7
05/19/2015 13:17
MHALL3
1 EPA 200.7
05/19/2015 13:17
MHALL3
1 EPA 200.7
05/19/2015 13:17
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050421
Site: GW -01 BR
Collection Date: 14 -May -15 10:58 AM
Analyte
Result
DISSOLVED METALS BY ICP -MS
Sample #:
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
< 1
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
< 1
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
0.575
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
ug/L
TDS
110
Total Carbon
05/28/2015 15:15
TOC
0.221
TOTAL SUSPENDED SOLIDS
1
TSS
< 5
Page 13 of 70
ug/L
1
1
Sample #:
2015014750
DJSULL1
ug/L
1
1
Matrix:
GW -WW
DJSULL1
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
ug/L
1
1
EPA 200.8
05/28/2015 15:15
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:15
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:15
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:15
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:15
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:15
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:15
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:15
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:15
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:15
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:15
DJSULL1
ug/L
0.2
1
EPA 200.8
05/28/2015 15:15
DJSULL1
ug/L
0.3
1
EPA 200.8
05/28/2015 15:15
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:21
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:21
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:21
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:21
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:21
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:21
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:21
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:21
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:21
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:21
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:21
DJSULL1
ug/L
0.2
1
EPA 200.8
05/20/2015 13:21
DJSULL1
ug/L
0.3
1
EPA 200.8
05/20/2015 13:21
DJSULL1
Vendor Method
V_SHEALY
Vendor Method
V_ELE1
mg/L
25
1
SM2540C
05/18/201514:24
AGIBBS5
mg/L
0.1
1
SM5310C/EPA9060A
05/20/201514:33
TJA7067
mg/L
5
1
SM2540D
05/18/2015 09:26
AGIBBS5

Certificate of Laboratory Analysis Page 14 of 70
This report shall not be reproduced, except in full.
Order # J15050421
Site: GW -2
Collection Date: 14 -May -15 2:50 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
05/21/2015 13:41
Vendor Parameter
Complete
EPA 300.0
05/21/2015 13:41
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
0.630
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
230
mg/L
5
Sulfate
85
mg/L
1
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/18/2015 12:10
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/18/2015 12:10
MHALL3
Aluminum (AI)
0.124
mg/L
0.005
Barium (Ba)
0.250
mg/L
0.005
Boron (B)
1.03
mg/L
0.05
Iron (Fe)
0.014
mg/L
0.01
Manganese (Mn)
1.85
mg/L
0.005
Strontium (Sr)
0.546
mg/L
0.005
Zinc (Zn)
0.261
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/19/2015 13:21
MHALL3
Calcium (Ca)
112
mg/L
0.1
Magnesium (Mg)
34.6
mg/L
0.005
Potassium (K)
3.94
mg/L
0.1
Sodium (Na)
6.92
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.274
mg/L
0.005
Barium (Ba)
0.273
mg/L
0.005
Boron (B)
1.05
mg/L
0.05
Iron (Fe)
0.115
mg/L
0.01
Manganese (Mn)
1.78
mg/L
0.005
Strontium (Sr)
0.556
mg/L
0.005
Zinc (Zn)
0.043
mg/L
0.005
Sample #: 2015014751
Matrix: GW -WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
05/26/2015 12:07
LSTARL1
50
EPA 300.0
05/21/2015 13:41
BGN9034
10
EPA 300.0
05/21/2015 13:41
BGN9034
1
EPA 245.1
05/21/2015 15:57
ACPAYNE
1
EPA 245.1
05/20/2015 13:33
ACPAYNE
1
EPA 200.7
05/18/2015 12:10
MHALL3
1
EPA 200.7
05/18/2015 12:10
MHALL3
1
EPA 200.7
05/18/2015 12:10
MHALL3
1
EPA 200.7
05/18/2015 12:10
MHALL3
1
EPA 200.7
05/18/2015 12:10
MHALL3
1
EPA 200.7
05/18/2015 12:10
MHALL3
1
EPA 200.7
05/18/2015 12:10
MHALL3
10
EPA 200.7
05/18/2015 14:51
MHALL3
1
EPA 200.7
05/18/2015 14:51
MHALL3
1
EPA 200.7
05/18/2015 14:51
MHALL3
1
EPA 200.7
05/18/2015 14:51
MHALL3
1
EPA 200.7
05/19/2015 13:21
MHALL3
1
EPA 200.7
05/19/2015 13:21
MHALL3
1
EPA 200.7
05/19/2015 13:21
MHALL3
1
EPA 200.7
05/19/2015 13:21
MHALL3
1
EPA 200.7
05/19/2015 13:21
MHALL3
1
EPA 200.7
05/19/2015 13:21
MHALL3
1
EPA 200.7
05/19/2015 13:21
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050421
Site: GW -2
Collection Date: 14 -May -15 2:50 PM
Analyte
Result
DISSOLVED METALS BY ICP -MS
Sample #:
Antimony (Sb)
< 1
Arsenic (As)
1.44
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
12.7
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
7.28
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
Arsenic (As)
1.02
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
11.9
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
7.55
Selenium (Se)
1.01
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
ug/L
TDS
720
Total Carbon
05/28/2015 15:20
TOC
0.357
TOTAL SUSPENDED SOLIDS
1
TSS
< 5
Page 15 of 70
ug/L
1
1
Sample #:
2015014751
DJSULL1
ug/L
1
1
Matrix:
GW -WW
DJSULL1
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
ug/L
1
1
EPA 200.8
05/28/2015 15:20
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:20
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:20
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:20
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:20
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:20
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:20
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:20
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:20
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:20
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:20
DJSULL1
ug/L
0.2
1
EPA 200.8
05/28/2015 15:20
DJSULL1
ug/L
0.3
1
EPA 200.8
05/28/2015 15:20
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:25
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:25
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:25
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:25
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:25
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:25
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:25
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:25
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:25
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:25
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:25
DJSULL1
ug/L
0.2
1
EPA 200.8
05/20/2015 13:25
DJSULL1
ug/L
0.3
1
EPA 200.8
05/20/2015 13:25
DJSULL1
Vendor Method
V_SHEALY
Vendor Method
V_ELE1
mg/L
25
1
SM2540C
05/18/201514:24
AGIBBS5
mg/L
0.1
1
SM5310C/EPA9060A
05/20/201514:33
TJA7067
mg/L
5
1
SM2540D
05/18/2015 09:26
AGIBBS5

Certificate of Laboratory Analysis Page 16 of 70
This report shall not be reproduced, except in full.
Order # J15050421
Site: GW -3
Collection Date: 14 -May -15 1:58 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
05/21/2015 13:57
Vendor Parameter
Complete
EPA 300.0
05/21/2015 13:57
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
0.606
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
39
mg/L
1
Sulfate
170
mg/L
2.5
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/18/2015 12:13
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/18/2015 12:13
MHALL3
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.046
mg/L
0.005
Boron (B)
1.36
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.455
mg/L
0.005
Strontium (Sr)
0.813
mg/L
0.005
Zinc (Zn)
0.006
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/19/2015 13:25
MHALL3
Calcium (Ca)
75.5
mg/L
0.01
Magnesium (Mg)
21.4
mg/L
0.005
Potassium (K)
3.08
mg/L
0.1
Sodium (Na)
12.5
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.431
mg/L
0.005
Barium (Ba)
0.042
mg/L
0.005
Boron (B)
1.17
mg/L
0.05
Iron (Fe)
0.485
mg/L
0.01
Manganese (Mn)
0.555
mg/L
0.005
Strontium (Sr)
0.679
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015014752
Matrix: GW -WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
05/26/2015 12:03
LSTARL1
10
EPA 300.0
05/21/2015 13:57
BGN9034
25
EPA 300.0
05/21/2015 13:57
BGN9034
1
EPA 245.1
05/21/2015 15:59
ACPAYNE
1
EPA 245.1
05/20/2015 13:36
ACPAYNE
1
EPA 200.7
05/18/2015 12:13
MHALL3
1
EPA 200.7
05/18/2015 12:13
MHALL3
1
EPA 200.7
05/18/2015 12:13
MHALL3
1
EPA 200.7
05/18/2015 12:13
MHALL3
1
EPA 200.7
05/18/2015 12:13
MHALL3
1
EPA 200.7
05/18/2015 12:13
MHALL3
1
EPA 200.7
05/18/2015 12:13
MHALL3
1
EPA 200.7
05/18/2015 14:55
MHALL3
1
EPA 200.7
05/18/2015 14:55
MHALL3
1
EPA 200.7
05/18/2015 14:55
MHALL3
1
EPA 200.7
05/18/2015 14:55
MHALL3
1
EPA 200.7
05/19/2015 13:25
MHALL3
1
EPA 200.7
05/19/2015 13:25
MHALL3
1
EPA 200.7
05/19/2015 13:25
MHALL3
1
EPA 200.7
05/19/2015 13:25
MHALL3
1
EPA 200.7
05/19/2015 13:25
MHALL3
1
EPA 200.7
05/19/2015 13:25
MHALL3
1
EPA 200.7
05/19/2015 13:25
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050421
Site: GW -3
Collection Date: 14 -May -15 1:58 PM
Analyte
Result
DISSOLVED METALS BY ICP -MS
Sample #:
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
< 1
Selenium (Se)
2.00
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
17.2
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
< 1
Selenium (Se)
2.84
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
0.301
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
ug/L
TDS
440
Total Carbon
05/28/2015 15:24
TOC
0.671
TOTAL SUSPENDED SOLIDS
1
TSS
7.0
Page 17 of 70
ug/L
1
1
Sample #:
2015014752
DJSULL1
ug/L
1
1
Matrix:
GW -WW
DJSULL1
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
ug/L
1
1
EPA 200.8
05/28/2015 15:24
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:24
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:24
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:24
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:24
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:24
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:24
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:24
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:24
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:24
DJSULL1
ug/L
1
1
EPA 200.8
05/28/2015 15:24
DJSULL1
ug/L
0.2
1
EPA 200.8
05/28/2015 15:24
DJSULL1
ug/L
0.3
1
EPA 200.8
05/28/2015 15:24
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:30
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:30
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:30
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:30
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:30
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:30
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:30
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:30
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:30
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:30
DJSULL1
ug/L
1
1
EPA 200.8
05/20/2015 13:30
DJSULL1
ug/L
0.2
1
EPA 200.8
05/20/2015 13:30
DJSULL1
ug/L
0.3
1
EPA 200.8
05/20/2015 13:30
DJSULL1
Vendor Method
V_SHEALY
Vendor Method
V_ELE1
mg/L
25
1
SM2540C
05/18/201514:24
AGIBBS5
mg/L
0.1
1
SM5310C/EPA9060A
05/20/201514:33
TJA7067
mg/L
5
1
SM2540D
05/18/2015 09:26
AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050421
Site: Equipment Blank
Collection Date: 13 -May -15 1:00 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy
Labs)
1 EPA 300.0
Vendor Parameter
Complete
1 EPA 300.0
05/21/2015 11:46
NITRITE + NITRATE (COLORIMETRIC)
1 EPA 245.1
05/21/2015 16:01
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
05/18/2015 14:59
MHALL3
1 EPA 200.7
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
05/19/2015 13:29
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
MHALL3
1 EPA 200.7
05/19/2015 13:29
Calcium (Ca)
< 0.01
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
05/20/2015 12:58
DJSULL1
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Page 18 of 70
Sample #: 2015014761
Matrix: GW -WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1 EPA 353.2
05/26/2015 12:08
LSTARL1
1 EPA 300.0
05/21/2015 11:46
BGN9034
1 EPA 300.0
05/21/2015 11:46
BGN9034
1 EPA 245.1
05/21/2015 16:01
ACPAYNE
1 EPA 200.7
05/18/2015 14:59
MHALL3
1 EPA 200.7
05/18/2015 14:59
MHALL3
1 EPA 200.7
05/18/2015 14:59
MHALL3
1 EPA 200.7
05/18/2015 14:59
MHALL3
1 EPA 200.7
05/19/2015 13:29
MHALL3
1 EPA 200.7
05/19/2015 13:29
MHALL3
1 EPA 200.7
05/19/2015 13:29
MHALL3
1 EPA 200.7
05/19/2015 13:29
MHALL3
1 EPA 200.7
05/19/2015 13:29
MHALL3
1 EPA 200.7
05/19/2015 13:29
MHALL3
1 EPA 200.7
05/19/2015 13:29
MHALL3
1 EPA 200.8
05/20/2015 12:58
DJSULL1
1 EPA 200.8
05/20/2015 12:58
DJSULL1
1 EPA 200.8
05/20/2015 12:58
DJSULL1
1 EPA 200.8
05/20/2015 12:58
DJSULL1
1 EPA 200.8
05/20/2015 12:58
DJSULL1
1 EPA 200.8
05/20/2015 12:58
DJSULL1
1 EPA 200.8
05/20/2015 12:58
DJSULL1
1 EPA 200.8
05/20/2015 12:58
DJSULL1
1 EPA 200.8
05/20/2015 12:58
DJSULL1
1 EPA 200.8
05/20/2015 12:58
DJSULL1
1 EPA 200.8
05/20/2015 12:58
DJSULL1
1 EPA 200.8
05/20/2015 12:58
DJSULL1
1 EPA 200.8
05/20/2015 12:58
DJSULL1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4) Complete Vendor Method V_SHEALY

Certificate of Laboratory Analysis Page 19 of 70
This report shall not be reproduced, except in full.
Order # J15050421
Site: Equipment Blank
Collection Date: 13 -May -15 1:00 PM
Analyte Result Units Qualifiers RDL DF
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L 25 1
Total Carbon
Sample #: 2015014761
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method
V_ELE1
SM2540C 05/18/201514:24 AGIBBS5
TOC 0.106 mg/L 0.1 1 SM5310C/EPA9060A 05/20/201514:33 TJA7067
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 05/18/2015 09:26 AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050421
Site: Equipment Blank
Collection Date: 14 -May -15 8:45 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy
Labs)
1 EPA 300.0
Vendor Parameter
Complete
1 EPA 300.0
05/21/2015 12:03
NITRITE + NITRATE (COLORIMETRIC)
1 EPA 245.1
05/21/2015 16:19
Nitrite + Nitrate (Colorimetric)
0.107
mg-N/L
0.01
INORGANIC IONS BY IC
05/18/2015 15:03
MHALL3
1 EPA 200.7
Chloride
< 0.1
mg/L
0.1
Sulfate
0.17
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
05/19/2015 13:33
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
MHALL3
1 EPA 200.7
05/19/2015 13:33
Calcium (Ca)
< 0.01
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
05/20/2015 13:02
DJSULL1
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Page 20 of 70
Sample #: 2015014762
Matrix: GW -WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1 EPA 353.2
05/26/2015 12:09
LSTARL1
1 EPA 300.0
05/21/2015 12:03
BGN9034
1 EPA 300.0
05/21/2015 12:03
BGN9034
1 EPA 245.1
05/21/2015 16:19
ACPAYNE
1 EPA 200.7
05/18/2015 15:03
MHALL3
1 EPA 200.7
05/18/2015 15:03
MHALL3
1 EPA 200.7
05/18/2015 15:03
MHALL3
1 EPA 200.7
05/18/2015 15:03
MHALL3
1 EPA 200.7
05/19/2015 13:33
MHALL3
1 EPA 200.7
05/19/2015 13:33
MHALL3
1 EPA 200.7
05/19/2015 13:33
MHALL3
1 EPA 200.7
05/19/2015 13:33
MHALL3
1 EPA 200.7
05/19/2015 13:33
MHALL3
1 EPA 200.7
05/19/2015 13:33
MHALL3
1 EPA 200.7
05/19/2015 13:33
MHALL3
1 EPA 200.8
05/20/2015 13:02
DJSULL1
1 EPA 200.8
05/20/2015 13:02
DJSULL1
1 EPA 200.8
05/20/2015 13:02
DJSULL1
1 EPA 200.8
05/20/2015 13:02
DJSULL1
1 EPA 200.8
05/20/2015 13:02
DJSULL1
1 EPA 200.8
05/20/2015 13:02
DJSULL1
1 EPA 200.8
05/20/2015 13:02
DJSULL1
1 EPA 200.8
05/20/2015 13:02
DJSULL1
1 EPA 200.8
05/20/2015 13:02
DJSULL1
1 EPA 200.8
05/20/2015 13:02
DJSULL1
1 EPA 200.8
05/20/2015 13:02
DJSULL1
1 EPA 200.8
05/20/2015 13:02
DJSULL1
1 EPA 200.8
05/20/2015 13:02
DJSULL1
METHANE - (Analysis Performed by Shealy Labs)
Methane (CH4) Complete Vendor Method V_SHEALY

Certificate of Laboratory Analysis Page 21 of 70
This report shall not be reproduced, except in full.
Order # J15050421
Site: Equipment Blank
Collection Date: 14 -May -15 8:45 AM
Analyte Result Units Qualifiers RDL DF
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L 25 1
Total Carbon
Sample #: 2015014762
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method
V_ELE1
SM2540C 05/18/201514:24 AGIBBS5
TOC 0.112 mg/L 0.1 1 SM5310C/EPA9060A 05/20/201514:33 TJA7067
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 05/18/2015 09:26 AGIBBS5

Certificate of Laboratory Analysis Page 22 of 70
This report shall not be reproduced, except in full.
Order # J15050421
Site: Filter Blank
Collection Date: 13 -May -15 1:00 PM
Analyte
Result
Units
Qualifiers RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
EPA 245.1
05/20/2015 13:38
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
1
EPA 200.7
05/18/2015 12:21
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP -MS
1
EPA 200.8
05/28/2015 15:29
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2015014763
Matrix: GW -WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
05/20/2015 13:38
ACPAYNE
1
EPA 200.7
05/18/2015 12:21
MHALL3
1
EPA 200.7
05/18/2015 12:21
MHALL3
1
EPA 200.7
05/18/2015 12:21
MHALL3
1
EPA 200.7
05/18/2015 12:21
MHALL3
1
EPA 200.7
05/18/2015 12:21
MHALL3
1
EPA 200.7
05/18/2015 12:21
MHALL3
1
EPA 200.7
05/18/2015 12:21
MHALL3
1
EPA 200.8
05/28/2015 15:29
DJSULL1
1
EPA 200.8
05/28/2015 15:29
DJSULL1
1
EPA 200.8
05/28/2015 15:29
DJSULL1
1
EPA 200.8
05/28/2015 15:29
DJSULL1
1
EPA 200.8
05/28/2015 15:29
DJSULL1
1
EPA 200.8
05/28/2015 15:29
DJSULL1
1
EPA 200.8
05/28/2015 15:29
DJSULL1
1
EPA 200.8
05/28/2015 15:29
DJSULL1
1
EPA 200.8
05/28/2015 15:29
DJSULL1
1
EPA 200.8
05/28/2015 15:29
DJSULL1
1
EPA 200.8
05/28/2015 15:29
DJSULL1
1
EPA 200.8
05/28/2015 15:29
DJSULL1
1
EPA 200.8
05/28/2015 15:29
DJSULL1

Certificate of Laboratory Analysis Page 23 of 70
This report shall not be reproduced, except in full.
Order # J15050421
Site: Filter Blank
Collection Date: 14 -May -15 8:45 AM
Analyte
Result
Units
Qualifiers RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
EPA 245.1
05/20/2015 13:40
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
1
EPA 200.7
05/18/2015 12:25
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP -MS
1
EPA 200.8
05/28/2015 15:34
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2015014764
Matrix: GW -WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
05/20/2015 13:40
ACPAYNE
1
EPA 200.7
05/18/2015 12:25
MHALL3
1
EPA 200.7
05/18/2015 12:25
MHALL3
1
EPA 200.7
05/18/2015 12:25
MHALL3
1
EPA 200.7
05/18/2015 12:25
MHALL3
1
EPA 200.7
05/18/2015 12:25
MHALL3
1
EPA 200.7
05/18/2015 12:25
MHALL3
1
EPA 200.7
05/18/2015 12:25
MHALL3
1
EPA 200.8
05/28/2015 15:34
DJSULL1
1
EPA 200.8
05/28/2015 15:34
DJSULL1
1
EPA 200.8
05/28/2015 15:34
DJSULL1
1
EPA 200.8
05/28/2015 15:34
DJSULL1
1
EPA 200.8
05/28/2015 15:34
DJSULL1
1
EPA 200.8
05/28/2015 15:34
DJSULL1
1
EPA 200.8
05/28/2015 15:34
DJSULL1
1
EPA 200.8
05/28/2015 15:34
DJSULL1
1
EPA 200.8
05/28/2015 15:34
DJSULL1
1
EPA 200.8
05/28/2015 15:34
DJSULL1
1
EPA 200.8
05/28/2015 15:34
DJSULL1
1
EPA 200.8
05/28/2015 15:34
DJSULL1
1
EPA 200.8
05/28/2015 15:34
DJSULL1

eke entOne
REPORT OF ANALYSES
Page 24 of 70
Element One 9nc.
6319-D Carolina Beach Rd.
Wilmington, NC 28412
Phone: [phone]
Fax: [phone]
e1labOal lah.com
Duke Energy
May 28, 2015
Laboratory Services
Client Project Name
AB GW Assessment water Asheville
13339 Hagers
Ferry Road Bld. MG03A
Client Project Number J15050421
Huntersville, NC 28078
PO Number
Sample Matrix
Sample Type Grab
Date Received
05/19/2015
Date Analyzed
05/20/2015
Method
SM 4500 S2- D
Time Received
1400
Delivered by
FedEx
Received by
JRC
eOne ID
Duke Energy ID
Parameter
Result
Unit
Dil
DL
Date
Time
Sampled
Sampled
24795-1
ADP -7
Sulfide
< 0.1
mg/L
1
0.1
05/13/15
1450
24795-2
P-105
Sulfide
< 0.1
mg/L
1
0.1
05/13/15
1425
24795-3
DP -1
Sulfide
< 0.1
mg/L
1
0.1
05/13/15
1630
24795-4**
ABMW-08
Sulfide
< 5.0
mg/L
50
0.1
05/14/15
0913
24795-5
GW -01 BR
Sulfide
< 0.1
mg/L
1
0.1
05/14/15
1058
24795-6
GW -2
Sulfide
< 0.1
mg/L
1
0.1
05/14/15
1450
24795-7*
GW -3
Sulfide
< 0.5
mg/L
5
0.1
05/14/15
1358
24795-8
Equipment Blank
Sulfide
< 0.1
mg/L
1
0.1
05/13/15
1300
*Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits.
**Sample spike recovery outside of QA limits of 85-115%; unable to meet laboratory QA limits.
— C14�;4�/-
Ken Smith, Laboratory Director
24795 Duke Report Packet Compiled byk�-
NC Certifications: DW 37788 and DWQ DENR 604

�I
Duke Energy
Laboratory Services
13339 Hagers Ferry Road Bld. MG03A
Huntersville, NC 28078
Sample Matrix Sai
Date Analyzed 05/20/2015 Me
Delivered by FedEx
eOne ID Duke Energy ID
24795-9 Equipment Blank
Page 25 of 70
Eernent One Ilnc.
6319-D Carolina Beach Rd.
Wilmington, NC 28412
(Tone: 910 793-0128
Fax: [phone]
[e-mail]
REPORT OF ANALYSES
May 28, 2015
Client Project Name AB GW Assessment water Asheville
Client Project Number J15050421
PO Number
nple Type Grab Date Received 05/19/2015
hod SM 4500 S2- D Time Received 1400
Parameter Result Unit Dil
Received by JRC
DL Date Time
Sampled Sampled
Sulfide < 0.1 mg/L 1 0.1 05/14/15 0845
Ken Smith, Laboratory Director
24795 Duke Report Packet Compiled by
NC Certifications: DW 37788 and DWQ DENR 604

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elernentOne SAMPLE SUBMISSION FORM Lab IIY 2724°795
TAT 7 BD
Hold Time Expiration 05.20.15 @ 1300
Client: Duke Energy
LIMS No J15050421
Project ID Asheville
Analysis Due Date 05.20.15
Report Due Date 05.28.15
Date Rec:
05.15.15
Time Rec:
1400
Rec By
J RC
H >9 es• No
Tem <_ 6°C es No
Ref. Method:
SM4500 S2 D
If No, Record
If No, Record
Sample Identification & Collection Information
Lab ID
Client ID
Collection Date
Collection Time
Analysis Requested
1
ADP -7
05/13/15
1450u
ide`
2
P-105
05/13/15
1425
3
DP -1
05/13/15
1630
ulf'
4
ABMW-08
_ 05/14/15
0913
ulfid
5
GW -01 BR
05/14/15
1058
ulfide
6
GW -2
_ 05/14/15
1450
u fid
7
GW -3
05/14/15
1358
u id >
8
Equipment
Blank _ 05/13/15
1300
ulfi e
9
Equipment
Blank 05/14/15
0845
ulfi
NOTE for
Sulfide
The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected
at 100 pg/L spike the sample to render the final spike concentration at -- 500 pg/L
Lab Communications
All AB Groundwater Assessment jobs need a RL of 0.1
SS Page 1 of 1 Prep By /Date M 5d j S
SS by Labeled By / Date
5/19/2015 :57:51 PM ID Verification By /Date d /

Page 28 of 70
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT: Duke
SPK LEVEL u
5
Lab ID#
24754'/ 24795 / 24796 / 247971 24798
Na2S•9H2O Lot #
40721
MAX ALIQUOT
10.00
Date: 05/20/15
STANDARD conc(ppm)
X
Time Analysis Begun 9:30
Cal Std Lot:
WC2-81-3
Time Analysis Ended 14:40
QC Std Lot:
WC2-81-4
Analyst: KAM
STD ABSORPTION
Y
X
ug STD
SOLUTION
0.00
1.00
2;50
5.00
7.50
10.00
Y
STD
ABS
0.000
0.096
0.241
0.447
0.635
0.806
oso0
ano
osm
05m
0.4m
0.Mmo
0.+�
0. 0.00
-
200
--
°.W
0.00
X
6.00
-- ---
10.00
-0.
s�
,zoo
i
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
Slope
ALI in mL
TAKEN
0.0$0628571
RESULTS
u/mL
Correlation
LESS THAN
% SPK REC
0.898105892
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.00
Std. B. 1.00
0.101
0.7975
10
10
10
<
79.75%
1.00
Std. B. 2.50
0.238
2.5927
10
10
10
0.259
103.71%
2.50
Std. B. 5.00
0.448
5.3445
10
10
10
0.534
106.89%
5.00
Std. B. 7.50
0.653
8.0307
10
10
10
0.803
107.08%
7.50
Std. B. 10.00
0.794
9.8784
10
10
10
0.988
98.78%
10.00
LRB
0.000
0.0000
10
10
10
<
0.00
LRB SPK
0.451
5.3838
10
10
10
0.538
108%
5.0
QC
0.461
5.5148
10
10
10
0.551
110%
5.0
24794-2
0.091
0.6665
10
10
10
24794-2 s k
0.471
5.6459
10
10
10
0.565
113%
5.0
24794-3
0.027
-0.1721
10
10
10
<
24794-3 dup
0.027
-0.1721
10
10
10
<
24794-3 s k
0.361
4.2045
10
10
10
0.420
84%
5.0
24794-4
0.001
-0.5128
10
10
10
24794-4s k
0.375
4.3879
10
10
10
0.439
88%
5.0
24795-1
0.001
-0.5128
10
10
10
24795-1 s k
0.439
5.2266
10
10
10
0.523
105%
5.0
24795-2
0.006
-0.4473
10
10
10�
1
24795-2 s k
0.417
4.9383
10
10
10
0.494
99%
5.0
24795-3
0.009
-0.4080
10
10
10�
`
24795-3 s k
0.426
5.0562
10
10
10
0.506
101%
5.0
24795-4
0.018
-0.2901
10
10
10
<
24795-4 s k
0.268
2.9858
10
10
10
0.299
60%
5.0
24795-5
0.031
-0.1197
10
10
10
24795-5 s k
0.428
5.0824
10
10
10
0.508
102%
5.0
24795-6
0.001
-0.5128
10
10
10
24795-6 s k
0.398
4.6893
10
10
10
0.469
94%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
SU muted or Q
0.460
QC -
5.5017
Date: 05/20/15
10
10
By: (Print)
1 10 0.550
I KAM
110%
(sign):
5.0
Page 1 of 5

METHOD:
ELEMENT ASSAY:
CLIENT:
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
X
ug Sl
)LUT
0.00
1.00
2.50
5.00
7.50
SM 4500 S2- Q
ulfide Spectrophotomet;
ike Wave Length 664
1794 / 24795 / 24796 / 24797/ 24798
i/20/15 Na2S•91-12O Lot #
30 40721
1:40
NM
-�
ABS
0.000
0.096
0.241
0.447
0.635
Page 29 of 70
ELEMENT ONE
STANDARD conc(ppm) X
Cal Std Lot: WC2-81-3
QC Std Lot: WC2-81-4
STD ABSORPTION Y
x
.
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
Sloe
ALI in mL
TAKEN
0.080628571
RESULTS
ug/mL
Correlation
LESS THAN
% SPK REC
0.998105892
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.00
Std. B. 1.00
0.101
0.7975
10
10
10
<
79.75%
1.00
Std. B. 2.50
0.238
2.5927
10
10
10
0.259
103.71%
2.50
Std. B. 5.00
0.448
5.3445
10
10
10
0.534
106.89%
5.00
Std. B. 7.50
0.653
8.0307
10
10
10
0.803
107.08%
7.50
Std. B. 10.00
0.794
9.8784
10
10
10
0.988
98.78%
10.00
LRB
0.000
0.0000
10
10
10
<
0.00
LRB SPK
0.451
1 5.3838
10
10
10
0.538
108%
5.0
QC
0.461
5.5148
10
10
10
0.551
110%
5.0
24795-7
0.006
-0.4473
10
10
10
<
24795-7 s k
0.155
1.5051
10
10
10
0.151
30%
5.0
24795-8
0.003
-0.4866
10
10
10
77
24795-8 dup
0.002
-0.4997
10
10
10
< 0.1
24795-8 s k
0.434
5.1610
10
10
10
0.516
103%
5.0
24795-9
0.007
-0.4342
10
10
10�
24795-9 s k
0.421
4.9907
10
10
10
0.499
100%
5.0
24796-1
0.002
-0.4997
10
10
10
,(}
24796-1 s k
0.440
5.2397
10
10
10
0.524
105%
5.0
24796-2
0.004
-0.4735
10
10
10
777
01,
24796-2 s k
0.415
4.9121
10
10
10
0.491
98%
5.0
24796-3
0.003
-0.4866
10
10
10
wQ
24796-3 s k
0.431
5.1217
10
10
10
0.512
102%
5.0
24797-1
1.443
18.3826
10
10
10
1.838
24797-1 s k
1.595
20.3744
10
10
10
2.037
40%
5.0
24797-2
0.002
-0.4997
10
10
10
24797-2 S k
0.387
4.5452
10
10
10
0.455
91%
5.0
24797-3
0.039
-0.0149
1010
10
7 - 1
0
24797-3 s k
0.367
4.2831
10
10
10
0.428
86%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
Submitted for QA/QC
0.459
-
5.4886
Date: 05/20/15By:
10
10
(Print)
10
0.549
KAM
110%
(sign): i
5.0
Page 2 of 5

Page 30 of 70
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
SPK LEVEL u
1.000
5
CLIENT:
Duke
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
�a
SAMPLE
I.D.
24794 / 24795 / 24796 /24797 % 24798
05/20/15
9:30
14:40
KAM
Y
STD °.� --
ABS 0700
0.000 aWD;
0.0960 30D
0.241 °.z� z.,
0,2W
0.447 °,m
0.635 0.000].W
0.806
SAMP ug PER ALI in mL
ABS ALIQUOT ANALYZED
Na2S,9H2O Lot #
40721
- - --- --- --
<.W 6.0D
x
Sloe
PREP ALI in mL
VOL in mL TAKEN
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot:
1 QC Std Lot:
STD ABSORPTION
----- °.
8.0D ,°.w
0.080628571Correlation
RESULTS LESS THAN
ug/mL % SPK REC
10.0_0
X
WC2-81-3
WC2-81-4
Y
�o�
,:.W
0.998105892
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.00
Std. B. 1.00
0.101
0.7975
10
10
10
<
79.75%
1.00
Std. B. 2.50
0.238
2.5927
10
10
10
0.259
103.71%
2.50
Std. B. 5.00
0.448
5.3445
10
10
10
0.534
106.89%
5.00
Std. B. 7.50
0.653
8.0307
10
10
10
0.803
107.08%
7.50
Std. B. 10.00
0.794
9.8784
10
10
10
0.988
98.78%
10.00
LRB
0.000
0.0000
10
10
10
<
0.00
LRB SPK
0.451
5.3838
10
10
10
0.538
108%
5.0
QC
0.461
5.5148
10
10
10
0.551
110%
5.0
24797-4
0.007
-0.4342
10
10
10
< 01
24797-4 s k
0.404
4.7679
10
10
10
0.477
95%
5.0
24797-5
0.006
-0.4473
10
10
10
0.1,
24797-5 s k
0.415
4.9121
10
10
10
0.491
98%
5.0
24797-6
0.011
-0.3818
10
10
10
W
�?w u
24797-6 dup
0.014
-0.3425
10
10
10
< 0.1
24797-6 s k
0.377
4.4141
10
10
10
0.441
88%
5.0
24797-7
0.041
0.0113
10
10
10
p1
24797-7 s k
0.370
4.3224
10
10
10
0.432
86%
5.0
24797-8
0.013
-0.3556
10
10
10
<
24797-8 s k
0.350
4.0603
10
10
10
0.406
81%
5.0
24797-9
0.033
-0.0935
10
10
10
24797-9 s k
0.375
4.3879
10
10
10
0.439
88%
5.0
24798-1
0.002
-0.4997
10
10
10
<
24798-1 s k
0.301
3.4183
10
10
10
0.342
68%
5.0
24798-2
0.006
-0.4473
10
10
10
<-k
24798-2 s k
0.401
4.7286
10
10
10
0.473
95%
5.0
24798-3
0.004
-0.4735
10
10
10
<
24798-3 s k
0.339
3.9162
10
10
10
0.392
78%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.460
5.5017
10
10
10
0.550
110%
5.0
Submitted for Q QC- Date: 05/20/15
By: (Print)
KAM
(sign):
Z/
Page 3 of 5

Page 31 of 70
METHOD:
SM 4500 S2 -`D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT:
Duke
SPK LEVEL u
5
Lab ID#
24794 / 24795
05/20/15
9:30
14:40
KAM
Y
/ 24796 ! 24797
°.�
/ 24798 -
Na2S•9H2O Lot#
40721
MAX ALIQUOT
STANDARD c_onc(ppm)
lCal Std Lot: I
IQC Std Lot: I
STD ABSORPTION
10.00
X
WC2-81-3
WC2-81-4
Y
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
STD
07M
ABS
0500
--°�
0.00
1.00
2.50
5.00
7.50
10.00
0.000
0.096
0400
0.241
0200<°
0.447
0.+00
0000
0.635
0.806
°A°
Z 0°
4.°°
e.°°
x
&0°
1°A° ,2
M
Sloe
0.080628571':
Correlation
0.908105892
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
LESS THAN
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0.00
Std. B. 1.00
0.101
0.7975
10
10
10
<
79.75%
1.00
Std. B. 2.50
0.238
2.5927 1
10
10
1 10
0.259
103.71%
2.50
Std. B. 5.00
0.448
5.3445
10
10
10
0.534
106.89%
5.00
Std. B. 7.50
0.653
8.0307
10
10
10
0.803
107.08%
7.50
Std. B. 10.00
0.794
9.8784
10
10
10
0.988
98.78%
10.00
LRB
0.000
0.0000
10
10
10
<
0.00
LRB SPK
0.451
5.3838 1
10
10
10
0.538
108%
5.0
QC
0.461
5.5148
10
10
10
0.551
110%
5.0
24798-4
0.002
-0.4997
10
10
10
,...`-
24798-4 s k
0.421
4.9907
10
10
10
0.499
100%
5.0
24794-3
0.015
-0.3294
10
10
5
24794-3 s k
0.385
4.5190
10
10
5
0.904
90%
5.0
24795-4
0.013
-0.3556
10
10
5
<
24795-4 s k
0.272
3.0383
10
10
5
0.608
61%
5.0
24795-7
0.008
-0.4211
10
10
5
<
24795-7 s k
0.308
3.5100
10
10
5
0.702
70%
5.0
24797-1
0.859
10.7301
10
10
5
2.146
24797-1dup
0.867
10.8349
10
10
5
2.167
24797-1 s k
1.155
14.6088
10
10
5
2.922
75%
5.0
24797-8
0.010
-0.3949
10
10
50„
24797-8 s k
0.385
1 4.5190
10
10
5
0.904
90%
5.0
24798-1
0.004
-0.4735
10
10
5
<
24798-1 s k
0.354
4.1128
10
10
5
0.823
82%
5.0
24798-3
0.002
-0.4997
10
10
5
24798-3 s k
0.368
4.2962
10
10
5
0.859
86%
5.0
24795-4
0.006
-0.4473
10
10
2
<
24795-4 s k
0.033
-0.0935
10
10
2
<
-2%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.459
5.4886
10
10
10
0.549
110%
5.0
Submitted for QA/QC- Date: 05/20/15
By: (Print)
KAM
(sign):
Page 4 of 5

Page 32 of 70
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
Na2S•9H2O Lot #
40721
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT: Duke
Lab ID# 24794 / 24795 / 24796 / 24797 / 24798
SPK LEVEL u
MAX ALIQUOT
5
10.00
Date: 05/20/15
STANDARD conc(ppm)
X
Time Analysis Begun 9:30
Cal Std Lot:
WC2-81-3
Time Analysis Ended 14:40
1 QC Std Lot:
WC2-81-4
Analyst: KAM'
STD ABSORPTION
Y
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
Y
STD
ABS
0.0000.
0.096
0.241
0.447
0.635
1 0.806
B.B00
0T000
0 4W
=111
0.100
0
010
]m
400
6w
x
B.D0 low
�
-
12.00
SAMPLE
I.D.
Std. B. 0.00
Std. B. 1.00
Std. B. 2.50
Std. B. 5.00
Std. B. 7.50
Std. B. 10.00
SAMP
ABS
0.000
0.101
0.238
0.448
0.653
0.794
ug PER
ALIQUOT
0.0000
0.7975
2.5927
5.3445
8.0307
9.8784
ALI in mL .
ANALYZED
10
10
10
10
10
10
PREP
VOL in mL
10
10
10
10
10
10
Sloe
ALI in mL
TAKEN
10
10
10
10
10
10
0.080628571` Correlation
RESULTS LESS THAN
ug/mL % SPK REC
<
< 79.75%
0.259 103.71%
0.534 106.89%
0.803 107.08%
0.988 98.78%
0.9981058921
SPIKE
LEVEL
0.00
1.00
2.50
5.00
7.50
10.00
LRB
0.000
0.0000
10
10
10
<
0.00
LRB SPK
0.451
5.3838
10
10
10
0.538 108%
5.0
QC
0.461
5.5148
10
10
10
0.551 110%
5.0
24796-7
0.006
-0.4473
10
10
2
< pi
24796-7 s k
0.384
4.5059
10
10
2
2.253 90%
5.0
4797-1
0.383
4.4928
10
10
2
2:4
24797-1 s k
0.718
8.8825
10
10
2
4.441 88%
5.0
8-1
0.002
-0.4997
10
10
2
24798-1 s k
0.400
4.7155
10
10
2
2.358 94%
5.0
24795-4
0.005
-0.4604
10
10
0.2
5r0
24795-4
0.309
3.5231
10
10
0.2
17.615 70%
5.0
Blank
0.000 1
0.0000
10
10
10
<
QC
U mltte fOr Q
0.459 1 5.4886
QC- Date: 05/20/15
10
10
By: (Print)
10 0.549 110%
KAM (sign): o
5.0
Page 5 of 5

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
Project Name: AB GW Assessment Water - Asheville
Project Number:J15050421
Lot Number:QE19004
Date Completed:05/22/2015
Grant Wilton
Project Manager
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
* QE1 9004*
Shealy Environmental Services, Inc. Page: 1 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: QE19004
Project Name: AB GW Assessment Water - Asheville
Project Number: J15050421
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page
Shealy Environmental Services, Inc. Page: 2 of 22
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SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QE19004
Project Name: AB GW Assessment Water - Asheville
Project Number: J15050421
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
2015014746
Aqueous
05/13/20151450
05/18/2015
002
2015014747
Aqueous
05/13/20151425
05/18/2015
003
2015014748
Aqueous
05/13/20151630
05/18/2015
004
2015014749
Aqueous
05/14/2015 0913
05/18/2015
005
2015014750
Aqueous
05/14/20151058
05/18/2015
006
2015014751
Aqueous
05/14/20151450
05/18/2015
007
2015014752
Aqueous
05/14/20151358
05/18/2015
008
2015014761
Aqueous
05/13/20151300
05/18/2015
009
2015014762
Aqueous
05/14/2015 0845
05/18/2015
(9 samples)
Shealy Environmental Services, Inc. Page: 3 of 22
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(14 detections)
Shealy Environmental Services, Inc. Page: 4 of 22
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SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QE19004
Project Name: AB GW Assessment Water - Asheville
Project Number: J15050421
Sample Sample ID
Matrix Parameter Method Result Q
Units
Page
001
2015014746
Aqueous Alkalinity SM 2320B-
25
mg/L
5
001
2015014746
Aqueous Bicarbonate Alkalinity SM 2320B-
25
mg/L
5
003
2015014748
Aqueous Alkalinity SM 2320B-
180
mg/L
9
003
2015014748
Aqueous Bicarbonate Alkalinity SM 2320B-
180
mg/L
9
003
2015014748
Aqueous Methane RSK - 175
23
ug/L
10
004
2015014749
Aqueous Alkalinity SM 2320B-
170
mg/L
11
004
2015014749
Aqueous Bicarbonate Alkalinity SM 2320B-
170
mg/L
11
004
2015014749
Aqueous Methane RSK - 175
6400
ug/L
12
005
2015014750
Aqueous Alkalinity SM 2320B-
57
mg/L
13
005
2015014750
Aqueous Bicarbonate Alkalinity SM 2320B-
57
mg/L
13
006
2015014751
Aqueous Alkalinity SM 2320B-
21
mg/L
15
006
2015014751
Aqueous Bicarbonate Alkalinity SM 2320B-
21
mg/L
15
007
2015014752
Aqueous Alkalinity SM 2320B-
55
mg/L
17
007
2015014752
Aqueous Bicarbonate Alkalinity SM 2320B-
55
mg/L
17
(14 detections)
Shealy Environmental Services, Inc. Page: 4 of 22
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE19004-001
Description: 2015014746 Matrix: Aqueous
Date Sampled:05/13/2015 1450 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050421
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 05/20/2015 1917
HMA 75452
1
(Bicarbonate ) SM 2320B-2011
1 05/20/2015 1917
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/20/2015 1917
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 5 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
25
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
25
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 5 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE19004-001
Description: 2015014746 Matrix: Aqueous
Date Sampled:05/13/2015 1450 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050421
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/20/2015 1143 DCS 75426
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 6 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QE19004-002
Description: 2015014747 Matrix: Aqueous
Date Sampled:05/13/2015 1425 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050421
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 05/20/2015 1931
HMA 75452
1
(Bicarbonate ) SM 2320B-2011
1 05/20/2015 1931
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/20/2015 1931
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 7 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 7 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE19004-002
Description: 2015014747 Matrix: Aqueous
Date Sampled:05/13/2015 1425 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050421
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/20/2015 1155 DCS 75426
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 8 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QE19004-003
Description: 2015014748 Matrix: Aqueous
Date Sampled:05/13/2015 1630 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050421
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 23208-2011
1 05/20/2015 1938
HMA 75452
1
(Bicarbonate ) SM 2320B-2011
1 05/20/2015 1938
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/20/2015 1938
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 9 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
180
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
180
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 9 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE19004-003
Description: 2015014748 Matrix: Aqueous
Date Sampled:05/13/2015 1630 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050421
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/20/2015 1238 DCS 75426
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 23 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 10 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QE19004-004
Description: 2015014749 Matrix: Aqueous
Date Sampled:05/14/2015 0913 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050421
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 05/20/2015 1945
HMA 75452
1
(Bicarbonate ) SM 2320B-2011
1 05/20/2015 1945
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/20/2015 1945
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 11 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
170
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
170
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 11 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE19004-004
Description: 2015014749 Matrix: Aqueous
Date Sampled:05/14/2015 0913 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050421
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 20 05/21/2015 1104 DCS 75549
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 6400 200 ug/L 2
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 12 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QE19004-005
Description: 2015014750 Matrix: Aqueous
Date Sampled:05/14/2015 1058 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050421
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 05/20/2015 1949
HMA 75452
1
(Bicarbonate ) SM 2320B-2011
1 05/20/2015 1949
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/20/2015 1949
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 13 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
57
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
57
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 13 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE19004-005
Description: 2015014750 Matrix: Aqueous
Date Sampled:05/14/2015 1058 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050421
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/20/2015 1329 DCS 75426
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 14 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QE19004-006
Description: 2015014751 Matrix: Aqueous
Date Sampled:05/14/2015 1450 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050421
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 05/20/2015 1955
HMA 75452
1
(Bicarbonate ) SM 2320B-2011
1 05/20/2015 1955
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/20/2015 1955
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 15 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
21
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
21
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 15 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE19004-006
Description: 2015014751 Matrix: Aqueous
Date Sampled:05/14/2015 1450 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050421
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/20/2015 1339 DCS 75426
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 16 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QE19004-007
Description: 2015014752 Matrix: Aqueous
Date Sampled:05/14/2015 1358 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050421
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 05/20/2015 2001
HMA 75452
1
(Bicarbonate ) SM 2320B-2011
1 05/20/2015 2001
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/20/2015 2001
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 17 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
55
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
55
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 17 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE19004-007
Description: 2015014752 Matrix: Aqueous
Date Sampled:05/14/2015 1358 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050421
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/20/2015 1353 DCS 75426
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 18 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QE19004-008
Description: 2015014761 Matrix: Aqueous
Date Sampled:05/13/2015 1300 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050421
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 05/20/2015 2006
HMA 75452
1
(Bicarbonate ) SM 2320B-2011
1 05/20/2015 2006
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/20/2015 2006
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 19 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 19 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE19004-008
Description: 2015014761 Matrix: Aqueous
Date Sampled:05/13/2015 1300 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050421
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/20/2015 1404 DCS 75426
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 20 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QE19004-009
Description: 2015014762 Matrix: Aqueous
Date Sampled:05/14/2015 0845 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050421
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 05/20/2015 2022
HMA 75452
1
(Bicarbonate ) SM 2320B-2011
1 05/20/2015 2022
HMA
1
(Carbonate Al) SM 2320B-2011
1 05/20/2015 2022
HMA
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 21 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 21 of 22
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE19004-009
Description: 2015014762 Matrix: Aqueous
Date Sampled:05/14/2015 0845 Project Name: AB GW Assessment Water -
Date Received: 05/18/2015 Project Number: J15050421
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/20/2015 1418 DCS 75426
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: QE19004
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - Ii
Sample ID: QQ75452-001 Matrix: Aqueous
Batch: 75452
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 05/20/20151751
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE19004
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - LCS
Sample ID: QQ75452-002 Matrix: Aqueous
Batch: 75452
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 90 1 90 90-110 05/20/20151757
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE19004
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MS
Sample ID: QE19004-001MS Matrix: Aqueous
Batch: 75452
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 25 100 25 N 1 -0.19 70-130 05/20/20151921
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE19004
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MSD
Sample ID: QE19004-001MD Matrix: Aqueous
Batch: 75452
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Alkalinity 25 100 26 N 1 0.94 4.4 70-130 20 05/20/20151927
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE19004
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MS
Sample ID: QE19004-009MS Matrix: Aqueous
Batch: 75452
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity ND 100 90 1 90 70-130 05/20/2015 2027
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE19004
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MSD
Sample ID: QE19004-009MD Matrix: Aqueous
Batch: 75452
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Alkalinity ND 100 90 1 90 0.17 70-130 20 05/20/2015 2033
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE19004
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - MB
Sample ID: QQ75426-001 Matrix: Aqueous
Batch: 75426
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 05/20/2015 0958
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE19004
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCS
Sample ID: QQ75426-002 Matrix: Aqueous
Batch: 75426
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 150 130 1 84 70-130 05/20/2015 0932
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE19004
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCSD
Sample ID: QQ75426-003 Matrix: Aqueous
Batch: 75426
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 150 130 1 85 1.9 70-130 30 05/20/2015 0946
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE19004
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - MB
Sample ID: QQ75549-001 Matrix: Aqueous
Batch: 75549
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 05/21/2015 0959
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE19004
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCS
Sample ID: QQ75549-002 Matrix: Aqueous
Batch: 75549
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 150 120 1 79 70-130 05/21/2015 0933
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE19004
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCSD
Sample ID: QQ75549-003 Matrix: Aqueous
Batch: 75549
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 150 110 1 72 8.5 70-130 30 05/21/2015 0945
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE19004
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
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Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

SHEALY ENVIRONMENTAL SERVICES, INC.
$II[&EyIrV7rONIrCIy3AI Services, rnr_ Fav
p L of
Dccumcnt NYnlbdr- F•AEO.016 Repla ue& Date! I Ie07A4
Kf Viyaon Nuoel7ia': f? EfFperl We D40;; 06N-"3WJ 5
Sample Receipt Cheeklist (SRC)
Client; UtE t'1e1{ Cooler Inspected by.+daie: rL,,V.+ w + q1-1 Lot 4_ Q E d 1 Wq
Me UiS 4t'.1eL-C7.y[: LEST EIChent ElUPS [71FedE?L LlAirborno i Exp ther
Yes
- 0
1. WM custody seals present on the choler?
Y'es ❑
No U I NAA
are est;n1, vrwa they intact and unbrQken'�
Cooler ID10riginal. tx mperalturc upon rarzipt)Dcrivod (corrected") tern.=perature upon receipt:
Method- 7'crnperatvre lank ❑ Againxt Bottles LR Gino ID= IR Gun Correction Factor
Method of coolant: Wet Ice C Blue Ioe ❑ Dry lee Q Nene
Yes [J Nj ❑ [NA 2,1PM
3. if ieniperature of atiyr ca-fler exceeded 6.000, was Project Manager no[iiied?
tio6fied by SRC phone, now (circle onc), other:
(For 000lerc r"eived via crimmcrcial courier, PMs are to be notified
hilmediatel I -
Yes © No NA ❑
4- Is the c4xruiercial courie=r's packing:slip atgclied u7 this feri:W
1'e3 NQ.
5. Were propar custwy procedurcs (ruljpq ldshcA+roaci%,Qd) follmVed?
-U
Yes [I NA L)
5a;r = samples ralinquishodby client to commercial cnurier'?
Yes o ❑
6, Were sarnpk IDs listed on #lie COC?
Yid; o ❑
7- Were sample IDs listed on iall saris ,le cmita,ners?
Yes o
8. Was coLle�ction bate & time listed con the COC?
Yes b ]
9. Was ecr.11ectiou Lute & time listed on all warn le cunwincn?
Yes o ❑
10. Did all container label informal ion 1Ddat time a e with the CCC`?
'fraa A Vo ❑
11- Were tests to be orincd .Lstcd on this COC'
Yes ffFrNo j
12. Did all samples arrive; in the ppoper containers for each test?
Yes a ❑
13. Did all coriudaers arrive in izood condition (unbroken. lids on, etc.)?
3fes No ❑
14- Was adequate sample volume available?
Yes ❑ 1414
13. Were all samples received within 'r'x the holding time or 4$ hours, wh ich�cver
OdmCS first?
3"es No
16, Were any samples containers missln ?
Ycs ❑ X[!
Yes ❑ No ❑ NA
17. Nkrere there any excess sam lts not listrd on COC?
l R, V4rere Iyubbles present>x' ea -size" (rA"rfr Glum in diameter) is any VOA vials?
Yes No ❑ N_4
19, Were all metals+'C1&UlIIE,M(inutriexnt samples received at a pH of 2.?
Yr -i ❑ Ne ❑ PIA
Yes Q No Cl NA ze21-
20. Wcrc all cyanide arl&or sulfide sa 1p?l reL sive l at ii pH X12?
Wm all applicable -NH3JKNicyanidv,1phenol (<0.2lirl samples free of
residual chlorine.
'fifes ❑ No ❑ NAZ
22. Were oollec:tion tern era=cs documentod on the CLIC for NC sam los?
Yes [) Para ❑ �NA
23. Were Client ycawrlc ire�uests {i, -e- requested dilutigrs, M.,'MSD dcsi,natians,
ctc.., correctly transcribed from the COC` into the comment stetibil in LIMB?
Yes N"
24.; r., the oats Dumber used W=frorn t1ke cimlainer label'?
Saluple preservation ('must be complowd fur any sample(s) incorrectly presen°epi or with headspaoc)
Samplc(sj __. were received incorrectly preserved and were adj u; --ted
"! according) iia &arr7 le reeeivin with lI SO.,Hh1Cw,,HCl NaOH) using SR #
Sao les
vrert received with bubbles. >6 mm in diameter.
Sampl s
were rceeived with TRC >0.2 If ##21 is NO
SC Drinking Water Projc:t Sample(s) pH verified to be > 2 by Date;
Sam ic:( were not remiv"ed at a pH of <2 and were ad usird l,UtrjrdiriPly Using SR#i
Sample labels applicc by:_ . L AJ2 Verified by; Date. ci — 5
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

CHAIN OF CUSTOOY RECORD AND ANALYSIS REQUEST FORM
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