NC0000396_J15050104report_20150823

+ DUKE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Order Number: J15050104
Project Name: ASHEVILLE - AB GW ASSESSMENT WATER
Customer Name(s): Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker
Customer Address: 200 CP and L Drive
Arden, NC 28704
Lab Contact: �Mary Ann Oale Mary Ann Ogle Phone: [phone]
2015.05.21
Report Authorized By: (� ✓ 11:40:32 -04'00' Date:
(Signature)
Mary Ann Ogle
Program Comments:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
5/21/2015
Analytical Lab
Page 1 of 52
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
Collected By
Sample Description
2015013479
ASHEVILLE
04 -May -15 9:15 AM
Russo
MW -09 D
2015013480
ASHEVILLE
04 -May -15 11:30 AM
Russo
MW -09 BR
2015013481
ASHEVILLE
04 -May -15 9:00 AM
Russo
MW -18 D
2015013482
ASHEVILLE
04 -May -15 10:15 AM
Russo
MW -18 BR
2015013483
ASHEVILLE
04 -May -15 3:25 PM
Russo
MW -05 BR
2015013484
ASHEVILLE
04 -May -15 8:45 AM
Russo
Equipment Blank
2015013485
ASHEVILLE
04 -May -15 8:45 AM
Russo
Filter Blank
7 Total Samples
Analytical Lab
Page 2 of 52

Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes F./] No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
U Job Summary Report
❑ Sample Identification
n Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Analytical Lab
Page 3 of 52
Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
d❑ Chain of Custody
[I/0] Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 5/21/2015

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050104
Site: MW -09 D
Collection Date: 04 -May -15 9:15 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 353.2
05/07/2015 11:24
Vendor Parameter
Complete
EPA 300.0
05/11/2015 09:13
NITRITE + NITRATE (COLORIMETRIC)
100
EPA 300.0
Nitrite + Nitrate (Colorimetric)
0.439
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 245.1
Chloride
500
mg/L
10
Sulfate
250
mg/L
10
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/07/2015 12:49
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/07/2015 12:49
MHALL3
Aluminum (AI)
0.045
mg/L
0.005
Barium (Ba)
0.302
mg/L
0.005
Boron (B)
4.48
mg/L
0.05
Iron (Fe)
3.17
mg/L
0.01
Manganese (Mn)
3.69
mg/L
0.005
Strontium (Sr)
1.74
mg/L
0.005
Zinc (Zn)
0.082
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/08/2015 10:45
MHALL3
Calcium (Ca)
254
mg/L
0.1
Magnesium (Mg)
79.4
mg/L
0.005
Potassium (K)
7.84
mg/L
0.1
Sodium (Na)
22.4
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.187
mg/L
0.005
Barium (Ba)
0.304
mg/L
0.005
Boron (B)
4.42
mg/L
0.05
Iron (Fe)
3.30
mg/L
0.01
Manganese (Mn)
3.67
mg/L
0.005
Strontium (Sr)
1.76
mg/L
0.005
Zinc (Zn)
0.080
mg/L
0.005
Analytical Lab
Page 4 of 52
Sample #: 2015013479
Matrix: GW -WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
05/07/2015 11:24
LSTARL1
100
EPA 300.0
05/11/2015 09:13
BGN9034
100
EPA 300.0
05/11/2015 09:13
BGN9034
1
EPA 245.1
05/08/2015 13:00
ACPAYNE
1
EPA 245.1
05/08/2015 13:00
ACPAYNE
1
EPA 200.7
05/07/2015 12:49
MHALL3
1
EPA 200.7
05/07/2015 12:49
MHALL3
1
EPA 200.7
05/07/2015 12:49
MHALL3
1
EPA 200.7
05/07/2015 12:49
MHALL3
1
EPA 200.7
05/07/2015 12:49
MHALL3
1
EPA 200.7
05/07/2015 12:49
MHALL3
1
EPA 200.7
05/07/2015 12:49
MHALL3
10
EPA 200.7
05/07/2015 14:22
MHALL3
10
EPA 200.7
05/07/2015 14:22
MHALL3
1
EPA 200.7
05/07/2015 14:22
MHALL3
1
EPA 200.7
05/07/2015 14:22
MHALL3
1
EPA 200.7
05/08/2015 10:45
MHALL3
1
EPA 200.7
05/08/2015 10:45
MHALL3
1
EPA 200.7
05/08/2015 10:45
MHALL3
1
EPA 200.7
05/08/2015 10:45
MHALL3
1
EPA 200.7
05/08/2015 10:45
MHALL3
1
EPA 200.7
05/08/2015 10:45
MHALL3
1
EPA 200.7
05/08/2015 10:45
MHALL3

Analytical Lab
Certificate of Laboratory Analysis Page 5 of 52
This report shall not be reproduced, except in full.
Order # J15050104
Site: MW -09 D
Sample #: 2015013479
Collection Date: 04 -May -15 9:15 AM
Matrix: GW -WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
DISSOLVED METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
05/13/2015 16:22
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
05/13/2015 16:22
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
05/13/2015 16:22
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
05/13/2015 16:22
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
05/13/2015 16:22
JAHERMA
Cobalt (Co)
25.9
ug/L
1
1
EPA 200.8
05/13/2015 16:22
JAHERMA
Copper (Cu)
1.02
ug/L
1
1
EPA 200.8
05/13/2015 16:22
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
05/13/2015 16:22
JAHERMA
Molybdenum (Mo)
2.04
ug/L
1
1
EPA 200.8
05/13/2015 16:22
JAHERMA
Nickel (Ni)
14.3
ug/L
1
1
EPA 200.8
05/13/2015 16:22
JAHERMA
Selenium (Se)
32.9
ug/L
1
1
EPA 200.8
05/13/2015 16:22
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
05/13/2015 16:22
JAHERMA
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
05/13/2015 16:22
JAHERMA
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:15
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:15
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:15
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:15
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:15
JAHERMA
Cobalt (Co)
26.9
ug/L
1
1
EPA 200.8
05/12/2015 11:15
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
05/12/2015 11:15
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:15
JAHERMA
Molybdenum (Mo)
2.16
ug/L
1
1
EPA 200.8
05/12/2015 11:15
JAHERMA
Nickel (Ni)
14.9
ug/L
1
1
EPA 200.8
05/12/2015 11:15
JAHERMA
Selenium (Se)
32.2
ug/L
1
1
EPA 200.8
05/12/2015 11:15
JAHERMA
Thallium (TI) Low Level
0.327
ug/L
0.2
1
EPA 200.8
05/12/2015 11:15
JAHERMA
Vanadium (V) Low Level
0.516
ug/L
0.3
1
EPA 200.8
05/12/2015 11:15
JAHERMA
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
1700
mg/L
25
1
SM2540C
05/07/201510:20
AGIBBS5
Total Carbon
TOC
0.658
mg/L
0.1
1
SM5310C/EPA9060A
05/07/201514:53
GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS
6.0
mg/L
5
1
SM2540D
05/06/2015 08:52
AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050104
Site: MW -09 BR
Collection Date: 04 -May -15 11:30 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
05/11/2015 09:46
Vendor Parameter
Complete
EPA 300.0
05/11/2015 09:46
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
190
mg/L
2
Sulfate
86
mg/L
1
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/07/2015 12:45
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/07/2015 12:45
MHALL3
Aluminum (AI)
0.007
mg/L
0.005
Barium (Ba)
0.121
mg/L
0.005
Boron (B)
0.489
mg/L
0.05
Iron (Fe)
0.289
mg/L
0.01
Manganese (Mn)
0.230
mg/L
0.005
Strontium (Sr)
0.676
mg/L
0.005
Zinc (Zn)
0.099
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/08/2015 10:49
MHALL3
Calcium (Ca)
121
mg/L
0.1
Magnesium (Mg)
17.1
mg/L
0.005
Potassium (K)
16.8
mg/L
0.1
Sodium (Na)
24.7
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.044
mg/L
0.005
Barium (Ba)
0.129
mg/L
0.005
Boron (B)
0.490
mg/L
0.05
Iron (Fe)
1.57
mg/L
0.01
Manganese (Mn)
0.247
mg/L
0.005
Strontium (Sr)
0.697
mg/L
0.005
Zinc (Zn)
0.101
mg/L
0.005
Sample #: 2015013480
Matrix: GW -WW
Analytical Lab
Page 6 of 52
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
05/07/2015 11:26
LSTARL1
20
EPA 300.0
05/11/2015 09:46
BGN9034
10
EPA 300.0
05/11/2015 09:46
BGN9034
1
EPA 245.1
05/08/2015 13:07
ACPAYNE
1
EPA 245.1
05/08/2015 13:07
ACPAYNE
1
EPA 200.7
05/07/2015 12:45
MHALL3
1
EPA 200.7
05/07/2015 12:45
MHALL3
1
EPA 200.7
05/07/2015 12:45
MHALL3
1
EPA 200.7
05/07/2015 12:45
MHALL3
1
EPA 200.7
05/07/2015 12:45
MHALL3
1
EPA 200.7
05/07/2015 12:45
MHALL3
1
EPA 200.7
05/07/2015 12:45
MHALL3
10
EPA 200.7
05/07/2015 14:30
MHALL3
1
EPA 200.7
05/07/2015 14:30
MHALL3
1
EPA 200.7
05/07/2015 14:30
MHALL3
1
EPA 200.7
05/07/2015 14:30
MHALL3
1
EPA 200.7
05/08/2015 10:49
MHALL3
1
EPA 200.7
05/08/2015 10:49
MHALL3
1
EPA 200.7
05/08/2015 10:49
MHALL3
1
EPA 200.7
05/08/2015 10:49
MHALL3
1
EPA 200.7
05/08/2015 10:49
MHALL3
1
EPA 200.7
05/08/2015 10:49
MHALL3
1
EPA 200.7
05/08/2015 10:49
MHALL3

Analytical Lab
Certificate of Laboratory Analysis Page 7 of 52
This report shall not be reproduced, except in full.
Order # J15050104
Site: MW -09 BR
Sample #: 2015013480
Collection Date: 04 -May -15 11:30
AM
Matrix: GW -WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
DISSOLVED METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
05/13/2015 16:45
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
05/13/2015 16:45
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
05/13/2015 16:45
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
05/13/2015 16:45
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
05/13/2015 16:45
JAHERMA
Cobalt (Co)
<1
ug/L
1
1
EPA 200.8
05/13/2015 16:45
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
05/13/2015 16:45
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
05/13/2015 16:45
JAHERMA
Molybdenum (Mo)
4.22
ug/L
1
1
EPA 200.8
05/13/2015 16:45
JAHERMA
Nickel (Ni)
<1
ug/L
1
1
EPA 200.8
05/13/2015 16:45
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
05/13/2015 16:45
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
05/13/2015 16:45
JAHERMA
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
05/13/2015 16:45
JAHERMA
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:20
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:20
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:20
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:20
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:20
JAHERMA
Cobalt (Co)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:20
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
05/12/2015 11:20
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:20
JAHERMA
Molybdenum (Mo)
4.17
ug/L
1
1
EPA 200.8
05/12/2015 11:20
JAHERMA
Nickel (Ni)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:20
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:20
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
05/12/2015 11:20
JAHERMA
Vanadium (V) Low Level
0.379
ug/L
0.3
1
EPA 200.8
05/12/2015 11:20
JAHERMA
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
760
mg/L
25
1
SM2540C
05/07/201510:20
AGIBBS5
Total Carbon
TOC
1.1
mg/L
0.1
1
SM5310C/EPA9060A
05/07/201514:53
GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS
<5
mg/L
5
1
SM2540D
05/06/2015 08:52
AGIBBS5

Analytical Lab
Certificate of Laboratory Analysis Page 8 of 52
This report shall not be reproduced, except in full.
Order # J15050104
Site: MW -18 D
Collection Date: 04 -May -15 9:00 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
05/11/2015 10:02
Vendor Parameter
Complete
EPA 300.0
05/11/2015 10:02
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
0.102
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
88
mg/L
1
Sulfate
260
mg/L
5
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/07/2015 12:41
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/07/2015 12:41
MHALL3
Aluminum (AI)
0.015
mg/L
0.005
Barium (Ba)
0.066
mg/L
0.005
Boron (B)
0.796
mg/L
0.05
Iron (Fe)
3.67
mg/L
0.01
Manganese (Mn)
1.81
mg/L
0.005
Strontium (Sr)
0.316
mg/L
0.005
Zinc (Zn)
0.016
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/08/2015 10:53
MHALL3
Calcium (Ca)
110
mg/L
0.1
Magnesium (Mg)
25.8
mg/L
0.005
Potassium (K)
8.86
mg/L
0.1
Sodium (Na)
15.2
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.168
mg/L
0.005
Barium (Ba)
0.067
mg/L
0.005
Boron (B)
0.807
mg/L
0.05
Iron (Fe)
3.53
mg/L
0.01
Manganese (Mn)
1.51
mg/L
0.005
Strontium (Sr)
0.321
mg/L
0.005
Zinc (Zn)
0.006
mg/L
0.005
Sample #: 2015013481
Matrix: GW -WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
05/07/2015 11:27
LSTARL1
10
EPA 300.0
05/11/2015 10:02
BGN9034
50
EPA 300.0
05/11/2015 10:02
BGN9034
1
EPA 245.1
05/08/2015 13:09
ACPAYNE
1
EPA 245.1
05/08/2015 13:09
ACPAYNE
1
EPA 200.7
05/07/2015 12:41
MHALL3
1
EPA 200.7
05/07/2015 12:41
MHALL3
1
EPA 200.7
05/07/2015 12:41
MHALL3
1
EPA 200.7
05/07/2015 12:41
MHALL3
1
EPA 200.7
05/07/2015 12:41
MHALL3
1
EPA 200.7
05/07/2015 12:41
MHALL3
1
EPA 200.7
05/07/2015 12:41
MHALL3
10
EPA 200.7
05/07/2015 14:38
MHALL3
1
EPA 200.7
05/07/2015 14:38
MHALL3
1
EPA 200.7
05/07/2015 14:38
MHALL3
1
EPA 200.7
05/07/2015 14:38
MHALL3
1
EPA 200.7
05/08/2015 10:53
MHALL3
1
EPA 200.7
05/08/2015 10:53
MHALL3
1
EPA 200.7
05/08/2015 10:53
MHALL3
1
EPA 200.7
05/08/2015 10:53
MHALL3
1
EPA 200.7
05/08/2015 10:53
MHALL3
1
EPA 200.7
05/08/2015 10:53
MHALL3
1
EPA 200.7
05/08/2015 10:53
MHALL3

Analytical Lab
Certificate of Laboratory Analysis Page 9 of 52
This report shall not be reproduced, except in full.
Order # J15050104
Site: MW -18 D
Sample #: 2015013481
Collection Date: 04 -May -15 9:00 AM
Matrix: GW -WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
DISSOLVED METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
05/13/2015 16:59
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
05/13/2015 16:59
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
05/13/2015 16:59
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
05/13/2015 16:59
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
05/13/2015 16:59
JAHERMA
Cobalt (Co)
6.95
ug/L
1
1
EPA 200.8
05/13/2015 16:59
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
05/13/2015 16:59
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
05/13/2015 16:59
JAHERMA
Molybdenum (Mo)
1.50
ug/L
1
1
EPA 200.8
05/13/2015 16:59
JAHERMA
Nickel (Ni)
3.03
ug/L
1
1
EPA 200.8
05/13/2015 16:59
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
05/13/2015 16:59
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
05/13/2015 16:59
JAHERMA
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
05/13/2015 16:59
JAHERMA
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:24
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:24
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:24
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:24
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:24
JAHERMA
Cobalt (Co)
7.35
ug/L
1
1
EPA 200.8
05/12/2015 11:24
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
05/12/2015 11:24
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:24
JAHERMA
Molybdenum (Mo)
1.45
ug/L
1
1
EPA 200.8
05/12/2015 11:24
JAHERMA
Nickel (Ni)
2.87
ug/L
1
1
EPA 200.8
05/12/2015 11:24
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:24
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
05/12/2015 11:24
JAHERMA
Vanadium (V) Low Level
0.523
ug/L
0.3
1
EPA 200.8
05/12/2015 11:24
JAHERMA
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
620
mg/L
25
1
SM2540C
05/07/201510:20
AGIBBS5
Total Carbon
TOC
0.697
mg/L
0.1
1
SM5310C/EPA9060A
05/07/201514:53
GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS
<5
mg/L
5
1
SM2540D
05/06/2015 08:52
AGIBBS5

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050104
Site: MW -18 D
Collection Date: 04 -May -15 9:00 AM
Sample #: 2015013481
Matrix: GW—WW
Analytical Lab
Page 10 of 52
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050104
Site: MW -18 BR
Collection Date: 04 -May -15 10:15 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
EPA 300.0
05/11/2015 10:35
Vendor Parameter
Complete
EPA 300.0
05/11/2015 10:35
NITRITE + NITRATE (COLORIMETRIC)
1
EPA 245.1
Nitrite + Nitrate (Colorimetric)
0.261
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA 200.7
Chloride
97
mg/L
1
Sulfate
260
mg/L
5
MERCURY (COLD VAPOR) IN WATER
MHALL3
1
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/07/2015 13:31
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
EPA 200.7
05/07/2015 13:31
MHALL3
Aluminum (AI)
0.009
mg/L
0.005
Barium (Ba)
0.049
mg/L
0.005
Boron (B)
0.878
mg/L
0.05
Iron (Fe)
0.027
mg/L
0.01
Manganese (Mn)
0.224
mg/L
0.005
Strontium (Sr)
0.434
mg/L
0.005
Zinc (Zn)
0.018
mg/L
0.005
UNDIGESTED METALS BY ICP
EPA 200.7
05/08/2015 10:57
MHALL3
Calcium (Ca)
123
mg/L
0.1
Magnesium (Mg)
24.4
mg/L
0.005
Potassium (K)
9.10
mg/L
0.1
Sodium (Na)
15.5
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.066
mg/L
0.005
Barium (Ba)
0.048
mg/L
0.005
Boron (B)
0.892
mg/L
0.05
Iron (Fe)
0.092
mg/L
0.01
Manganese (Mn)
0.227
mg/L
0.005
Strontium (Sr)
0.443
mg/L
0.005
Zinc (Zn)
0.008
mg/L
0.005
Sample #: 2015013482
Matrix: GW -WW
Analytical Lab
Page 11 of 52
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA 353.2
05/07/2015 11:28
LSTARL1
10
EPA 300.0
05/11/2015 10:35
BGN9034
50
EPA 300.0
05/11/2015 10:35
BGN9034
1
EPA 245.1
05/08/2015 13:11
ACPAYNE
1
EPA 245.1
05/08/2015 13:11
ACPAYNE
1
EPA 200.7
05/07/2015 13:31
MHALL3
1
EPA 200.7
05/07/2015 13:31
MHALL3
1
EPA 200.7
05/07/2015 13:31
MHALL3
1
EPA 200.7
05/07/2015 13:31
MHALL3
1
EPA 200.7
05/07/2015 13:31
MHALL3
1
EPA 200.7
05/07/2015 13:31
MHALL3
1
EPA 200.7
05/07/2015 13:31
MHALL3
10
EPA 200.7
05/07/2015 14:46
MHALL3
1
EPA 200.7
05/07/2015 14:46
MHALL3
1
EPA 200.7
05/07/2015 14:46
MHALL3
1
EPA 200.7
05/07/2015 14:46
MHALL3
1
EPA 200.7
05/08/2015 10:57
MHALL3
1
EPA 200.7
05/08/2015 10:57
MHALL3
1
EPA 200.7
05/08/2015 10:57
MHALL3
1
EPA 200.7
05/08/2015 10:57
MHALL3
1
EPA 200.7
05/08/2015 10:57
MHALL3
1
EPA 200.7
05/08/2015 10:57
MHALL3
1
EPA 200.7
05/08/2015 10:57
MHALL3

Certificate of LaboratoryAnalysis Analytical Lab
y Page 12 of 52
This report shall not be reproduced, except in full.
Order # J15050104
Site: MW -18 BR
Sample #: 2015013482
Collection Date: 04 -May -15 10:15
AM
Matrix: GW -WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
DISSOLVED METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
05/13/2015 17:04
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
05/13/2015 17:04
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
05/13/2015 17:04
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
05/13/2015 17:04
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
05/13/2015 17:04
JAHERMA
Cobalt (Co)
<1
ug/L
1
1
EPA 200.8
05/13/2015 17:04
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
05/13/2015 17:04
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
05/13/2015 17:04
JAHERMA
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
05/13/2015 17:04
JAHERMA
Nickel (Ni)
4.33
ug/L
1
1
EPA 200.8
05/13/2015 17:04
JAHERMA
Selenium (Se)
1.45
ug/L
1
1
EPA 200.8
05/13/2015 17:04
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
05/13/2015 17:04
JAHERMA
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
05/13/2015 17:04
JAHERMA
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:29
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:29
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:29
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:29
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:29
JAHERMA
Cobalt (Co)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:29
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
05/12/2015 11:29
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:29
JAHERMA
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
05/12/2015 11:29
JAHERMA
Nickel (Ni)
4.16
ug/L
1
1
EPA 200.8
05/12/2015 11:29
JAHERMA
Selenium (Se)
1.40
ug/L
1
1
EPA 200.8
05/12/2015 11:29
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
05/12/2015 11:29
JAHERMA
Vanadium (V) Low Level
0.554
ug/L
0.3
1
EPA 200.8
05/12/2015 11:29
JAHERMA
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
660
mg/L
25
1
SM2540C
05/07/201510:20
AGIBBS5
Total Carbon
TOC
0.373
mg/L
0.1
1
SM5310C/EPA9060A
05/07/201514:53
GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS
<5
mg/L
5
1
SM2540D
05/06/2015 08:52
AGIBBS5

Certificate of LaboratoryAnalysis Analytical Lab
y Page 13 of 52
This report shall not be reproduced, except in full.
Order # J15050104
Site: MW -05 BR
Collection Date: 04 -May -15 3:25 PM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
1
EPA
Vendor Parameter
Complete
BGN9034
20
NITRITE + NITRATE (COLORIMETRIC)
300.0
05/11/2015 11:08
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
ACPAYNE
1
EPA
Chloride
6.6
mg/L
0.1
Sulfate
120
mg/L
2
MERCURY (COLD VAPOR) IN WATER
EPA
200.7
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
05/07/2015 12:11
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
1
EPA
200.7
Aluminum (AI)
0.014
mg/L
0.005
Barium (Ba)
0.017
mg/L
0.005
Boron (B)
0.411
mg/L
0.05
Iron (Fe)
11.4
mg/L
0.01
Manganese (Mn)
0.148
mg/L
0.005
Strontium (Sr)
0.310
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
200.7
05/07/2015 15:05
MHALL3
Calcium (Ca)
39.9
mg/L
0.01
Magnesium (Mg)
5.02
mg/L
0.005
Potassium (K)
3.76
mg/L
0.1
Sodium (Na)
15.5
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
200.7
05/08/2015 11:00
Aluminum (AI)
0.111
mg/L
0.005
Barium (Ba)
0.019
mg/L
0.005
Boron (B)
0.418
mg/L
0.05
Iron (Fe)
18.8
mg/L
0.01
Manganese (Mn)
0.172
mg/L
0.005
Strontium (Sr)
0.318
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015013483
Matrix: GW -WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1
EPA
353.2
05/07/2015 11:29
LSTARL1
1
EPA
300.0
05/11/2015 11:08
BGN9034
20
EPA
300.0
05/11/2015 11:08
BGN9034
1
EPA
245.1
05/08/2015 13:14
ACPAYNE
1
EPA
245.1
05/08/2015 13:14
ACPAYNE
1
EPA
200.7
05/07/2015 12:11
MHALL3
1
EPA
200.7
05/07/2015 12:11
MHALL3
1
EPA
200.7
05/07/2015 12:11
MHALL3
1
EPA
200.7
05/07/2015 12:11
MHALL3
1
EPA
200.7
05/07/2015 12:11
MHALL3
1
EPA
200.7
05/07/2015 12:11
MHALL3
1
EPA
200.7
05/07/2015 12:11
MHALL3
1
EPA
200.7
05/07/2015 15:05
MHALL3
1
EPA
200.7
05/07/2015 15:05
MHALL3
1
EPA
200.7
05/07/2015 15:05
MHALL3
1
EPA
200.7
05/07/2015 15:05
MHALL3
1
EPA
200.7
05/08/2015 11:00
MHALL3
1
EPA
200.7
05/08/2015 11:00
MHALL3
1
EPA
200.7
05/08/2015 11:00
MHALL3
1
EPA
200.7
05/08/2015 11:00
MHALL3
1
EPA
200.7
05/08/2015 11:00
MHALL3
1
EPA
200.7
05/08/2015 11:00
MHALL3
1
EPA
200.7
05/08/2015 11:00
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15050104
Site: MW -05 BR
Collection Date: 04 -May -15 3:25 PM
Analyte
Result
DISSOLVED METALS BY ICP -MS
Sample #:
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
< 1
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
< 0.3
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
Arsenic (As)
< 1
Beryllium (Be)
< 1
Cadmium (Cd)
< 1
Chromium (Cr)
< 1
Cobalt (Co)
< 1
Copper (Cu)
< 1
Lead (Pb)
< 1
Molybdenum (Mo)
< 1
Nickel (Ni)
< 1
Selenium (Se)
< 1
Thallium (TI) Low Level
< 0.2
Vanadium (V) Low Level
0.368
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
ug/L
TDS
250
Total Carbon
05/13/2015 17:08
TOC
0.399
TOTAL SUSPENDED SOLIDS
1
TSS
40
Analytical Lab
Page 14 of 52
ug/L
1
1
Sample #:
2015013483
JAHERMA
ug/L
1
1
Matrix:
GW -WW
JAHERMA
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
ug/L
1
1
EPA 200.8
05/13/2015 17:08
JAHERMA
ug/L
1
1
EPA 200.8
05/13/2015 17:08
JAHERMA
ug/L
1
1
EPA 200.8
05/13/2015 17:08
JAHERMA
ug/L
1
1
EPA 200.8
05/13/2015 17:08
JAHERMA
ug/L
1
1
EPA 200.8
05/13/2015 17:08
JAHERMA
ug/L
1
1
EPA 200.8
05/13/2015 17:08
JAHERMA
ug/L
1
1
EPA 200.8
05/13/2015 17:08
JAHERMA
ug/L
1
1
EPA 200.8
05/13/2015 17:08
JAHERMA
ug/L
1
1
EPA 200.8
05/13/2015 17:08
JAHERMA
ug/L
1
1
EPA 200.8
05/13/2015 17:08
JAHERMA
ug/L
1
1
EPA 200.8
05/13/2015 17:08
JAHERMA
ug/L
0.2
1
EPA 200.8
05/13/2015 17:08
JAHERMA
ug/L
0.3
1
EPA 200.8
05/13/2015 17:08
JAHERMA
ug/L
1
1
EPA 200.8
05/12/2015 11:34
JAHERMA
ug/L
1
1
EPA 200.8
05/12/2015 11:34
JAHERMA
ug/L
1
1
EPA 200.8
05/12/2015 11:34
JAHERMA
ug/L
1
1
EPA 200.8
05/12/2015 11:34
JAHERMA
ug/L
1
1
EPA 200.8
05/12/2015 11:34
JAHERMA
ug/L
1
1
EPA 200.8
05/12/2015 11:34
JAHERMA
ug/L
1
1
EPA 200.8
05/12/2015 11:34
JAHERMA
ug/L
1
1
EPA 200.8
05/12/2015 11:34
JAHERMA
ug/L
1
1
EPA 200.8
05/12/2015 11:34
JAHERMA
ug/L
1
1
EPA 200.8
05/12/2015 11:34
JAHERMA
ug/L
1
1
EPA 200.8
05/12/2015 11:34
JAHERMA
ug/L
0.2
1
EPA 200.8
05/12/2015 11:34
JAHERMA
ug/L
0.3
1
EPA 200.8
05/12/2015 11:34
JAHERMA
Vendor Method V SHEALY
Vendor Method
V_ELE1
mg/L
25 1 SM2540C
05/07/201510:20 AGIBBS5
mg/L
0.1 1 SM5310C/EPA9060A
05/07/201514:53 GHUTCHI
mg/L
5 1 SM2540D
05/06/2015 08:52 AGIBBS5

Certificate of LaboratoryAnalysis Analytical Lab
y Page 15 of 52
This report shall not be reproduced, except in full.
Order # J15050104
Site: Equipment Blank
Collection Date: 04 -May -15 8:45 AM
Analyte
Result
Units
Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy
Labs)
1 EPA 300.0
Vendor Parameter
Complete
1 EPA 300.0
05/08/2015 17:03
NITRITE + NITRATE (COLORIMETRIC)
1 EPA 245.1
05/08/2015 12:24
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
05/07/2015 16:04
MHALL3
1 EPA 200.7
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
05/08/2015 11:04
MHALL3
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
MHALL3
1 EPA 200.7
05/08/2015 11:04
Calcium (Ca)
< 0.01
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
05/12/2015 11:38
JAHERMA
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by Shealy Labs
Methane (CH4) Complete
Sample #: 2015013484
Matrix: GW -WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1 EPA 353.2
05/07/2015 11:30
LSTARL1
1 EPA 300.0
05/08/2015 17:03
BGN9034
1 EPA 300.0
05/08/2015 17:03
BGN9034
1 EPA 245.1
05/08/2015 12:24
ACPAYNE
1 EPA 200.7
05/07/2015 16:04
MHALL3
1 EPA 200.7
05/07/2015 16:04
MHALL3
1 EPA 200.7
05/07/2015 16:04
MHALL3
1 EPA 200.7
05/07/2015 16:04
MHALL3
1 EPA 200.7
05/08/2015 11:04
MHALL3
1 EPA 200.7
05/08/2015 11:04
MHALL3
1 EPA 200.7
05/08/2015 11:04
MHALL3
1 EPA 200.7
05/08/2015 11:04
MHALL3
1 EPA 200.7
05/08/2015 11:04
MHALL3
1 EPA 200.7
05/08/2015 11:04
MHALL3
1 EPA 200.7
05/08/2015 11:04
MHALL3
1 EPA 200.8
05/12/2015 11:38
JAHERMA
1 EPA 200.8
05/12/2015 11:38
JAHERMA
1 EPA 200.8
05/12/2015 11:38
JAHERMA
1 EPA 200.8
05/12/2015 11:38
JAHERMA
1 EPA 200.8
05/12/2015 11:38
JAHERMA
1 EPA 200.8
05/12/2015 11:38
JAHERMA
1 EPA 200.8
05/12/2015 11:38
JAHERMA
1 EPA 200.8
05/12/2015 11:38
JAHERMA
1 EPA 200.8
05/12/2015 11:38
JAHERMA
1 EPA 200.8
05/12/2015 11:38
JAHERMA
1 EPA 200.8
05/12/2015 11:38
JAHERMA
1 EPA 200.8
05/12/2015 11:38
JAHERMA
1 EPA 200.8
05/12/2015 11:38
JAHERMA
Vendor Method V_SHEALY

Certificate of LaboratoryAnalysis Analytical Lab
y Page 16 of 52
This report shall not be reproduced, except in full.
Order # J15050104
Site: Equipment Blank
Collection Date: 04 -May -15 8:45 AM
Analyte Result Units Qualifiers RDL DF
SULFIDE - (Analysis Performed by Element One)
Vendor Parameter Complete
TOTAL DISSOLVED SOLIDS
TDS < 25 mg/L 25 1
Total Carbon
Sample #: 2015013484
Matrix: GW WW
Method Analysis Date/Time Analyst
Vendor Method
V_ELE1
SM2540C 05/07/201510:20 AGIBBS5
TOC < 0.1 mg/L 0.1 1 SM5310C/EPA9060A 05/07/2015 14:53 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 05/06/2015 08:52 AGIBBS5

Certificate of LaboratoryAnalysis Analytical Lab
y Page 17 of 52
This report shall not be reproduced, except in full.
Order # J15050104
Site: Filter Blank
Collection Date: 04 -May -15 8:45 AM
Analyte
Result
Units
Qualifiers RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
EPA 245.1
05/08/2015 13:16
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
1
EPA 200.7
05/07/2015 12:53
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP -MS
1
EPA 200.8
05/13/2015 17:13
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2015013485
Matrix: GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
05/08/2015 13:16
ACPAYNE
1
EPA 200.7
05/07/2015 12:53
MHALL3
1
EPA 200.7
05/07/2015 12:53
MHALL3
1
EPA 200.7
05/07/2015 12:53
MHALL3
1
EPA 200.7
05/07/2015 12:53
MHALL3
1
EPA 200.7
05/07/2015 12:53
MHALL3
1
EPA 200.7
05/07/2015 12:53
MHALL3
1
EPA 200.7
05/07/2015 12:53
MHALL3
1
EPA 200.8
05/13/2015 17:13
JAHERMA
1
EPA 200.8
05/13/2015 17:13
JAHERMA
1
EPA 200.8
05/13/2015 17:13
JAHERMA
1
EPA 200.8
05/13/2015 17:13
JAHERMA
1
EPA 200.8
05/13/2015 17:13
JAHERMA
1
EPA 200.8
05/13/2015 17:13
JAHERMA
1
EPA 200.8
05/13/2015 17:13
JAHERMA
1
EPA 200.8
05/13/2015 17:13
JAHERMA
1
EPA 200.8
05/13/2015 17:13
JAHERMA
1
EPA 200.8
05/13/2015 17:13
JAHERMA
1
EPA 200.8
05/13/2015 17:13
JAHERMA
1
EPA 200.8
05/13/2015 17:13
JAHERMA
1
EPA 200.8
05/13/2015 17:13
JAHERMA

Analytical Lab
Page 18 of 52
[Element One Inc.
6319-D Carolina Beach Rd.
Wilmington, NC 28412
(phone: [phone]
Katt: 910 792-6853
el lab ne1lab coma
*Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits.
Ken Smit , Laboratory Director
24692 Duke Report Packet Compiled by_
NC Certifications: DW 37788 and DWQ DENR 604
tOne
REPORT OF ANALYSES
Duke Energy
May 8, 2015
Laboratory Services
Client Project Name
AB GW Assessment water- Asheville
13339 Hagers Ferry Road Bid. MG03A
Client Project Number J15050104
Huntersville, NC 28078
PO Number
Sample Matrix GW WW
Sample Type Grab
Date Received
05/07/2015
Date Analyzed 05/07/2015
Method
SM 4500 S2_ D
Time Received
1100
Delivered by FedEx
Received by
LLB
eOne ID Duke Energy ID
Parameter
Result Unit
Dil
DL Date
Time
Sampled
Sampled
24692-1 MW -09 D
Sulfide
< 0.1 mg/L
1
0.1 05/04/15
0915
24692-2' MW -09 BR
Sulfide
< 0.5 mg/L
5
0.1 05/04/15
1130
24692-3 MW -18 D
Sulfide
< 0.1 mg/L
1
0.1 05/04/15
0900
24692-4 MW -18 BR
Sulfide
< 0.1 mg/L
1
0.1 05/04/15
1015
24692-5 MW -05 BR
Sulfide
< 0.1 mg/L
1
0.1 05/04/15
1525
24692-6 Equipment Blank
Sulfide
< 0.1 mg/L
1
0.1 05/04/15
0845
*Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits.
Ken Smit , Laboratory Director
24692 Duke Report Packet Compiled by_
NC Certifications: DW 37788 and DWQ DENR 604

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Analytical Lab
Page 19 of 52
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Analytical Lab
elementOne SAMPLE SUBMISSION FORM Lab 11Y2 :IU92
TAT 7 BD Analysis Due Date 05.08.15
Hold Time Expiration 05.11.15 @ 0915 Report Due Date 05.18.15
Client: Duke Energy Date Rec: 05.07.15
LIMS No J15050104 Time Rec: 1100
Project ID Asheville Rec By LLB
H >9 &ej No I Tem <_ 6°C es No Ref. Method:
If No, Record I If No, Record SM4500 S2 D
Samnle Identification lir Cnllpcfinn Infnrma+inn
Lab ID
Client ID
Collection Date Collection Time sis Requested
1
MW -09 D
05/04/15 0915 Ifi
2
MW -09 BR
05/04/15 1130
3
MW -18 D
05/04/15 0900 uIfid
4
MW -18 BR
05/04/15 T1015 Ifi
5
MW -05 BR
05/04/15 1525 I
6
Equipment Blank 05/04/15 0845 ulfi
NOTE for Sulfide
The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected
at 100 pg/L spike the sample to render the final spike concentration at — 500 pg/L
Lab Communications
All AB Groundwater Assessment jobs need a RL of 0.1
SS Page 1 of 1 Prep By / Date AIV\SS l I
bLabeled By /Date
5/
5/7/2015 12:00 5:41 PM ID Verification By /Date WQ.� S 7

Analytical Lab
Page 21 of 52
METHOD: SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY: Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER ug/mL
DETECTION LIMIT u 1.000
CLIENT: Duke
SPK LEVEL (u4) 5
Lab ID# 24692 / 24693 / 24694
Na2S•9H2O Lot #
40721
MAX ALIQUOT 10.00
Date: 5/7/15
STANDARD conc(ppm) X
Time Analysis Begun 14:10
Cal Std Lot: W0. - -1$- 10
JQC Std Lot: WC 2- -)`S -
Time Analysis Ended 16:50
Analyst: KAM
STD ABSORPTION Y
X Y
0.612
ug STD
STD
o,00
SOLUTION
ABS
- - ---
0:00
0.000
Y
0400
1.00
0.099
0.0000
2.50
0.228
u,00
5.00
0.422
z.
7.50
0.612
0.8689
10.00 0.776
o�
o"
SAMP
ABS
o,00
--
0600
- - ---
o500
Correlation
LESS THAN
% SPK REC
Y
0400
Std. B. 0.00
DOwo
0.0000
o zao
_
zze
u,00
<
0000
oao
z.
SAMPLE
1. D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
Slope
ALI in mL
TAKEN
0.077389017
RESULTS
ug/mL
Correlation
LESS THAN
% SPK REC
0.998582271'
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.100
0.8689
10
10
10
<
86.89%
1
Std. B. 2.50
0.227
2.5864
10
10
10
0.259
103.46%
2.5
Std. B. 5.00
0.421
5.2102
10
10
10
0.521
104.20%
5
Std. B. 7.50
0.612
7.7933
10
10
10
0.779
103.91%
7.5
Std. B. 10.00
0.783
10.1060
10
10
10
1.011
101.06%
10
LRB
0.000
0.0000
10
10
10
<
0
LRB SPK
0.414
5.1155
10
10
10
0.512
103%
5.0
QC
0.394
4.8450
10
10
10
0.485
5.0
24692-1
0.008
-0.3754
10
10
10
t. A' v
24692-1 s k
0.359
4.3717
10
10
10
0.437
87%
5.0
24692-2
0.009
-0.3619
10
10
10
<
24692-2 dup
0.017
-0.2537
10
10
10
<
24692-2 spk
0.285
3.3709
10
10
10
0.337
67%
5.0
24692-3
0.006
-0.4024
10
10
10
777
_!ftx1 '..
24692-3 spk
0.375
4.5880
10
10
10
0.459
92%
5.0
24692-4
0.003
-0.4430
10
10
10
24692-4 s k
0.384
4.7098
10
10
10
0.471
94%
5.0
24692-5
0.006
-0.4024
10
10
10
; . �.1
24692-5 s k
0.385
4.7233
10
10
10
0.472
94%
5.0
24692-6
0.006
-0.4024
10
10
10x
24692-6 spk
0.415
5.1290
10
10
10
0.513
103%
5.0
24693
0.002
-0.4565
10
10
10
c 11
24693 s k
0.407
5.0208
10
10
10
0.502
100%
5.0
24694-1
0.007
-0.3889
10
10
103p0
24694-1 s k
0.371
4.5339
10
10
10
0.453
91%
5.0
24694-2
0.003
-0.4430
10
10
10
<
24694-2 s k
0.317
3.8036
10
10
10
0.380
76%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.389
4.7774
10
10 1
10
0.478
96%
5.0
Submitted for QA/QC-
Date: 5/7/15
By: (Print) IKAM
(sign):,
Page 1 of 3

Analytical Lab
Page 22 of 52
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT (u
1.000
CLIENT: Duke
SPK LEVEL (uM
5
Lab ID#
24692 / 24693 / 24694
Na2S•9H2O Lot #
40721
MAX ALIQUOT
10.00
Date: 5/7/15
STANDARD conc(ppm)
X
Time Analysis Begun 14:10
Cal Std Lot: Wt.1-14 - -j)
10
Time Analysis Ended 16:50
QC Std Lot: eJC1 - 1� 1
Analyst: KAM
STD ABSORPTION
Y
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
STD
ABS
0.000
0.099
0.228
0.422
0.612
0.776
0600
j 07W
0s
0500
0400
03°°-
0.2
01W
0.00
--
.228
200 400
--
8.00
x
- -
-
8.00
10.00
-.-0.
-5^
-'�
--0
o0
1200
SAMPLE
I.D.
SAMP
ABS
ug PER _
ALIQUOT
.
ALI in mL
ANALYZED
PREP
VOL in mL
Slope
ALI in mL
TAKEN
0.07738901`1
RESULTS
ug/mL
Correlation
LESS THAN
% SPK REC
0.998582271`.
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.100
0.8689
10
10
10
<
86.89%
1
Std. B. 2.50
0.227
2.5864
10
10
10
0.259
103.46%
2.5
Std. B. 5.00
0.421
5.2102
10
10
10
0.521
104.20%
5
Std. B. 7.50
0.612
7.7933
10
10
10
0.779
103.91%
7.5
Std. B. 10.00
0.783
10.1060
10
10
10
1.011
101.06%
10
LRB
0.000
0.0000
10
10
10
<
0
LRB SPK
0.414
5.1155
10
10
10
0.512
103%
5.0
QC
0.394
4.8450
10
10
10
0.485
5.0
24694-3
0.020
-0.2131
10
10
10
<
24694-3 s k
0.346
4.1958
10
10
10
0.420
84%
5.0
24694-4
0.007
-0.3889
10
10
10
<
24694-4 dup
0.010
-0.3483
10
10
10
< 0:1
24694-4 s k
0.373
4.5610
10
10
10
0.456
91%
5.0
24694-5
0.040
0.0574
10
10
10
'' -
24694-5 s k
0.391
4.8044
10
10
10
0.480
96%
5.0
24694-6
0.322
3.8713
10
10
10
= T03
24694-6 s k
0.691
8.8617
10
10
10
0.886
100%
5.0
24694-7
0.032
-0.0508
10
10
10
24694-7 spk
0.429
5.3184
10
10
10
0.532
106%
5.0
24694-8
0.014
-0.2942
10
10
10
<0.1
24694-8 s k
0.382
4.6827
10
10
10
0.468
94%
5.0
24694-9
0.012
-0.3213
10
10
10,
- .
24694-9 s k
0.402
4.9532
10
10
10
0.495
99%
5.0
24694-10
0.018
-0.2401
10
10
10
<,9,� , s
24694-10 s k
0.387
4.7503
10
10
10
0.475
95%
5.0
24694-11
0.011
-0.3348
10
10
10
�0=
24694-11 s k
1 0.404
4.9802
10
10
10
0.498
100%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.388
4.7639
10
10
10
0.476
95%
5.0
Submitted for QA/QC-
Date: 5/7/15
By: (Print)
KAM
(sign):
Page 2 of 3

Analytical Lab
Page 23 of 52
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER ug/mL
DETECTION LIMIT (u 1.000
CLIENT:
Duke
SPK LEVEL (ug) 5
Lab ID#
24692 / 24693 / 24694
Na2S•9H2O Lot #
40721
MAX ALIQUOT 10.00
Date:
5/7/15
_
STANDARD conc(ppm) X
Time Analysis Begun
14:10
ICal Std Lot: WCL -T -3 '• 10
IQC Std Lot: W e I. -I $ - `i
Time Analysis Ended
16:50
Analyst:
KAM
ISTD ABSORPTION Y
1
Std. B. 2.50
0.227
ug STD
STD
0700
SOLUTION
ABS
-- ---- ----
0.00
0.000
Y�
o�
1.00
0.099
--- -- - ---
2.50
0.228
0100
5.00
0.422
2W am Rm oM M
7.50
0.612
0.8689
10.00 1 0.776
o�
o�
SAMP
ABS
0700
---
06W
-- ---- ----
0.077389011
RESULTS
ug/mL
Correlation
LESS THAN
% SPK REC
Y�
o�
Std, B. 0.00
o--
--- -- - ---
02M
.72B
0100
<
o�
ow
2W am Rm oM M
SAMPLE
1. D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
Slope
ALI in mL
TAKEN
0.077389011
RESULTS
ug/mL
Correlation
LESS THAN
% SPK REC
0.998582271
SPIKE
LEVEL
Std, B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.100
0.8689
10
10
10
<
86.89%
1
Std. B. 2.50
0.227
2.5864
10
10
10
0.259
103.46%
2.5
Std. B. 5.00
0.421
5.2102
10
10
10
0.521
104.20%
5
Std. B. 7.50
0.612
7.7933
10
10
10
0.779
103.91%
7.5
Std. B. 10.00
0.783
10.1060
10
10
10
1.011
101.06%
10
LRB
0.000
0.0000
10
10
10
<
0
LRB SPK
0.414
5.1155
10
10
10
0.512
103%
5.0
QC
0.394
4.8450
10
10
10
0.485
97%
5.0
24692-2
0.010
-0.3483
10
10
5
<
24692-2 spk
0.328
3.9524
10
10
5
0.790
79%
5.0
24694-2
0.006
-0.4024
10 1
10
5
<
24694-2 spk
0.347
4.2094
10
10
5
0.842
84%
5.0
24694-3
0.009
-0.3619
10
10
5=pt
24694-3 spk
0.371
4.5339
10
10
5
0.907
91%
5.0
24692-2
0.001
-0.4700
10
10
2
24692-2 dup
0.005
-0.4159
10
10
2
<
24692-2 s k
0.357
4.3446
10
10
2
2.172
87%
5.0
24694-2
0.003
-0.4430
10
10
2
24694-2 spk
0.382
4.6827
10
10
2
2.341
94%
5.0
purchased std. QC
0.415
5.1290
10
10
10
0.513
103%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.385
4.7233
10
10
10
0.472
94%
5.0
Submitted for QA/QC-
Date: 5/7/15
By: (Print)
KAM
(sign)
%1
Page 3 of 3

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
Project Name: AB GW Assessment Water - Asheville
Project Number:J15050104
Lot Number:QE07085
Date Completed:05/14/2015
Grant Wilton
Project Manager
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
*QE07085*
Shealy Environmental Services, Inc. Page: 1 of 16
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SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: QE07085
Project Name: AB GW Assessment Water - Asheville
Project Number: J15050104
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page
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SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QE07085
Project Name: AB GW Assessment Water - Asheville
Project Number: J15050104
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
2015013479
Aqueous
05/04/2015 0915
05/07/2015
002
2015013480
Aqueous
05/04/20151130
05/07/2015
003
2015013481
Aqueous
05/04/2015 0900
05/07/2015
004
2015013482
Aqueous
05/04/20151015
05/07/2015
005
2015013483
Aqueous
05/04/20151525
05/07/2015
006
2015013484
Aqueous
05/04/2015 0845
05/07/2015
(6 samples)
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SHEALY ENVIRONMENTAL SERVICES, INC.
(10 detections)
Shealy Environmental Services, Inc. Page: 4 of 16
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Executive Summary
Duke Energy
Lot Number: QE07085
Project Name:
AB GW Assessment Water - Asheville
Project Number: J15050104
Sample Sample ID
Matrix
Parameter Method Result Q
Units
Page
001
2015013479
Aqueous
Alkalinity SM 2320B-
40
mg/L
5
001
2015013479
Aqueous
Bicarbonate Alkalinity SM 2320B-
40
mg/L
5
002
2015013480
Aqueous
Alkalinity SM 2320B-
77
mg/L
7
002
2015013480
Aqueous
Bicarbonate Alkalinity SM 2320B-
77
mg/L
7
003
2015013481
Aqueous
Alkalinity SM 2320B-
43
mg/L
9
003
2015013481
Aqueous
Bicarbonate Alkalinity SM 2320B-
43
mg/L
9
004
2015013482
Aqueous
Alkalinity SM 2320B-
47
mg/L
11
004
2015013482
Aqueous
Bicarbonate Alkalinity SM 2320B-
47
mg/L
11
005
2015013483
Aqueous
Alkalinity SM 2320B-
29
mg/L
13
005
2015013483
Aqueous
Bicarbonate Alkalinity SM 2320B-
29
mg/L
13
(10 detections)
Shealy Environmental Services, Inc. Page: 4 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QE07085-001
Description: 2015013479 Matrix: Aqueous
Date Sampled:05/04/2015 0915 Project Name: AB GW Assessment Water -
Date Received: 05/07/2015 Project Number: J15050104
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 23208-2011
1 05/08/2015 2305
HMA 74435
1
(Bicarbonate ) SM 2320B-2011
1 05/08/2015 2305
HMA 05/08/2015 2305
1
(Carbonate Al) SM 2320B-2011
1 05/08/2015 2305
HMA 05/08/2015 2305
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 5 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
40
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
40
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 5 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE07085-001
Description: 2015013479 Matrix: Aqueous
Date Sampled:05/04/2015 0915 Project Name: AB GW Assessment Water -
Date Received: 05/07/2015 Project Number: J15050104
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/10/2015 1353 DCS 74477
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 6 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QE07085-002
Description: 2015013480 Matrix: Aqueous
Date Sampled:05/04/2015 1130 Project Name: AB GW Assessment Water -
Date Received: 05/07/2015 Project Number: J15050104
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 23208-2011
1 05/08/2015 2341
HMA 74436
1
(Bicarbonate ) SM 2320B-2011
1 05/08/2015 2341
HMA 05/08/2015 2341
1
(Carbonate Al) SM 2320B-2011
1 05/08/2015 2341
HMA 05/08/2015 2341
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 7 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
77
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
77
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 7 of 16
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Methane
Client: Duke Energy Laboratory ID: QE07085-002
Description: 2015013480 Matrix: Aqueous
Date Sampled:05/04/2015 1130 Project Name: AB GW Assessment Water -
Date Received: 05/07/2015 Project Number: J15050104
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/10/2015 1403 DCS 74477
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 8 of 16
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE07085-003
Description: 2015013481 Matrix: Aqueous
Date Sampled:05/04/2015 0900 Project Name: AB GW Assessment Water -
Date Received: 05/07/2015 Project Number: J15050104
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 23208-2011
1 05/08/2015 2359
HMA 74436
1
(Bicarbonate ) SM 2320B-2011
1 05/08/2015 2359
HMA 05/08/2015 2359
1
(Carbonate Al) SM 2320B-2011
1 05/08/2015 2359
HMA 05/08/2015 2359
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 9 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
43
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
43
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 9 of 16
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Methane
Client: Duke Energy Laboratory ID: QE07085-003
Description: 2015013481 Matrix: Aqueous
Date Sampled:05/04/2015 0900 Project Name: AB GW Assessment Water -
Date Received: 05/07/2015 Project Number: J15050104
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/10/2015 1414 DCS 74477
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 10 of 16
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE07085-004
Description: 2015013482 Matrix: Aqueous
Date Sampled:05/04/2015 1015 Project Name: AB GW Assessment Water -
Date Received: 05/07/2015 Project Number: J15050104
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 05/09/2015 0004
HMA 74436
1
(Bicarbonate ) SM 2320B-2011
1 05/09/2015 0004
HMA 05/09/2015 0004
1
(Carbonate Al) SM 2320B-2011
1 05/09/2015 0004
HMA 05/09/2015 0004
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 11 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
47
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
47
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 11 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE07085-004
Description: 2015013482 Matrix: Aqueous
Date Sampled:05/04/2015 1015 Project Name: AB GW Assessment Water -
Date Received: 05/07/2015 Project Number: J15050104
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/10/2015 1424 DCS 74477
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QE07085-005
Description: 2015013483 Matrix: Aqueous
Date Sampled:05/04/2015 1525 Project Name: AB GW Assessment Water -
Date Received: 05/07/2015 Project Number: J15050104
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 05/09/2015 0009
HMA 74436
1
(Bicarbonate ) SM 2320B-2011
1 05/09/2015 0009
HMA 05/09/2015 0009
1
(Carbonate Al) SM 2320B-2011
1 05/09/2015 0009
HMA 05/09/2015 0009
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 13 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
29
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
29
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 13 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE07085-005
Description: 2015013483 Matrix: Aqueous
Date Sampled:05/04/2015 1525 Project Name: AB GW Assessment Water -
Date Received: 05/07/2015 Project Number: J15050104
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/10/2015 1435 DCS 74477
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 14 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals
Client: Duke Energy Laboratory ID: QE07085-006
Description: 2015013484 Matrix: Aqueous
Date Sampled:05/04/2015 0845 Project Name: AB GW Assessment Water -
Date Received: 05/07/2015 Project Number: J15050104
Run Prep Method
Analytical Method
Dilution Analysis Date
Analyst Prep Date Batch
1
(Alkalinity) SM 2320B-2011
1 05/09/2015 0013
HMA 74436
1
(Bicarbonate ) SM 2320B-2011
1 05/09/2015 0013
HMA 05/09/2015 0013
1
(Carbonate Al) SM 2320B-2011
1 05/09/2015 0013
HMA 05/09/2015 0013
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 15 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units
Run
Alkalinity
SM 2320B-20
ND
10
mg/L
1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L
1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 15 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane
Client: Duke Energy Laboratory ID: QE07085-006
Description: 2015013484 Matrix: Aqueous
Date Sampled:05/04/2015 0845 Project Name: AB GW Assessment Water -
Date Received: 05/07/2015 Project Number: J15050104
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 05/10/2015 1445 DCS 74477
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 16 of 16
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: QE07085
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - Ii
Sample ID: QQ74435-001 Matrix: Aqueous
Batch: 74435
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 05/08/20151937
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE07085
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - LCS
Sample ID: QQ74435-002 Matrix: Aqueous
Batch: 74435
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 94 1 94 90-110 05/08/20151943
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE07085
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - Ii
Sample ID: QQ74436-001 Matrix: Aqueous
Batch: 74436
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 05/08/2015 0032
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE07085
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - LCS
Sample ID: QQ74436-002 Matrix: Aqueous
Batch: 74436
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 95 1 95 90-110 05/08/2015 2335
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE07085
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MS
Sample ID: QE07085-002MS Matrix: Aqueous
Batch: 74436
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 77 100 140 N 1 61 70-130 05/08/2015 2347
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE07085
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Inorganic non-metals - MSD
Sample ID: QE07085-002MD Matrix: Aqueous
Batch: 74436
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Alkalinity 77 100 140 N 1 63 1.8 70-130 20 05/08/2015 2353
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE07085
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - MB
Sample ID: QQ74477-001 Matrix: Aqueous
Batch: 74477
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 05/10/20151201
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE07085
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCS
Sample ID: QQ74477-002 Matrix: Aqueous
Batch: 74477
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 150 140 1 91 70-130 05/10/20151140
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE07085
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

Methane - LCSD
Sample ID: QQ74477-003 Matrix: Aqueous
Batch: 74477
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 150 140 1 90 1.6 70-130 30 05/10/20151150
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QE07085
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

(fl,

SHEALY ENVIRONMENTAL SERVICES, INC.
Shealy Fnviromm Uel SeaNjoes, Inc.
DwumW Nvmher: F -AD -016
Revixian Nambtr 17
Paje I of t
RElill3M pale; 11eCRA4
tfrwlirt Uatc: &V30a5
Sample receipt Chccklist (SRC)
Client: i1c r Cooler Inspected by?dale" *r+ + o-,-,s-�, Lot ik O k e
Mcaas of receipt= E;r5LS.1 ❑ Clicat ❑ UPS ❑ Fedi x ❑ 4irb=t Up ❑ Other
Yes
iEz
1_ Were custody sells tsreslsllt on
A
�thercool�er?_
. If'acrll toe `sealswera Scn4, ► and unbroken?
Cwler lJ origir+al mmperanae: upon receip Derived (corrected) temperate m upon roocipt=
! "C
' + _aC r o + r OC
bictl od:
2TcaiperaturFylarLk
❑ Against ButileK IR Gun ID; IR. Gun Correction Facton
ialhod of coolant; L2r
Wet Ice Blue ice ❑ Dry Icc Mone
Sate le(s)
were received with hubbleg'>b mm in diameter_
3. if teniperatur+c of any cwter exceeded 6.0'C, was Frojoct Mrlrmgrzr nolii`ied?
c` ❑
° �' Z
PKI notified by NRC, phone, nobs (circle one.), other,
were not received at a pH of <2 and were ad usmd accordingly tiging SRi#
S itnnle labels applied by
(Far 000leis received via mramcmial courier, PM% are to be notified
inu nediatel .
�i as ❑
1xlo ❑ NA
4, Is the commercial courier's padicing slip attauh,,d to US forni?
Yes
No
5. Werc or miAtody proccdurcs relin uisl ,°receivaed Mlowed?
Yes
No ❑ NA
3a Were samples relinquished by client to commercial courier'?
'has.
NO
6, Were s le sted on
Yes
i+T0 []
7. Were surd le IIs listed on all sale oointainers?
Yea
NO
S. Was collection date & time listed oa the CIGC'? _
Yes
No ❑
9. Was collection dole & time listed on keel sit 1e ccutalners?
Yr8
Zed ❑
10. Did all cautainerIAN-] infomation ID_ dater, tim7) aYlcr wish tike COC?
Yes
ren ❑
11, Were tests to be performed listed ctrl the COC'?
Yes
Nva ❑
12. Did all sant les arrive in the Wer cDntsincrs far careh lull?
yes
h10 ❑
13. Did all coanUiners arrive in od condition (unbrokt:n lids on, etc)?
Yes Lo
Na
14, �Nas ad nate sample volume available°?
15, were all samples rcoeivW within 1/2 the holding time, or d$ hours, whichevcr
Yes ❑
No
came,s first?
Yes ❑
Nes
16. WCtC Gln Stn les Conrainers Missing?
Ycs ❑
No
17. Vi+'ero there any cxcess sar nples not listed ole COO
Yes
No NA. ❑
18, W= bubbles r+r_sent >` . -rizZ' (-W'or 6nun in diameter) in any VQA vzalV
Y ❑too
—NA;;?,
19. Were all mctu100&Q1HEMlnutricnt mmjp les received at 8 H of <27
Yes
New ❑ NA-
20. Were all c nide and/or s,ulf"ide satn les recoi4ed ata H :�1�i
2l, Were all applicable 1%1113fCKN`c.yanicde.'pheaol l;�-ij_�mWL) samples free of
••, ,—, "",-� ".,�
resi+l"tchlonne?
Yes Neo ❑ NA
22. V4`cre collection tcmperalures documcnt*d. on the CCC for NC sam 1 -ca?
23. Wire client rcrnaiicslregiwsts (i -c- reqoested dilutions, MSI SD desigmtii
Yes ❑ No ❑ NA Pr
etc...) rxrmefly transcn from the COC into the cmiliment section in LIMS`
yCs ❑ No
24. Was the quote number used taken from the container label"
Sample Preservation (14 uM be completed for any sample(s) incorrectly preservrd ur with It dspa,cc.)
Saunple(r)
+a rc r ivvd iieq+rrectly preserved and were adi
acoordingl y in, sample resViuir,
with (H�S()4,HI O10 HCI,NaOH) iisling SR #
Sate le(s)
were received with hubbleg'>b mm in diameter_
Sam 1C s)
v%r= received with TRC "_2 rel +l. (If 921 is
SC Dr6king Watsr Project Sample(s) pH verified to he > ? by Date'
Sample's)
were not received at a pH of <2 and were ad usmd accordingly tiging SRi#
S itnnle labels applied by
Verified hy: Date: {
Comments;
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com Level 1 Report v2.1

-. ........... . .
Duke Energy.Order
Duke Energy Analytical Laboratory
Mata CodeMG03A2lRwadary?4061
mraer aaar ` — "a" ..r..
- Matrix GW VYW s.,�..orroh.uw®—
A {
I SdSb P &,q
14C_
sc
i Page _1_ 0f _i_
DISTRIBUTION
Ana
Analytical Laboratory
i Chain of Custody i
73339 Hagar. ferry Rd
Huntera++lle• N. C. 26070`
(70AJ 6755266
s1
Logged a Data 6 7l,na
y
! L� ��%�
_
SAMPLE
_
PROGRAM
ORIGINAL to LAB, COPY to CLIENT
Pag
I Sample L Ground Water tdPDES_
L ra::izxx�o7ssa?e.-----.� iWnr Drinking Water usT_
Phmw No: r % RCRR waste-
!
COG REV DATE 1!22/2095
Project Mame AB GW Asaesament caster
��
V cooia� em-
menti ....... _..----._Qs..l
c .--- _-_-_-.--..^
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.-,------. _..._
Cllent yJ
rae Mn:
9E0.676-6032
ro
i QO 1142133 Twill,- (o.48 um' �Y
Unfiltered
ni
Oliver"
11 1 r
Business Unit:
Ppm• ReeP. Cerr-r rc
- rvauva lu icy Ise
SHEALY
Hxsoo
ice v `"
eSoo
Project to;
Acl,+ay ID: Metl code: I
MG03A3 '
to (mL) 2000 40 mi 300
PO 1142089
126
Soo
S00 250
steam:
ar Type PET glass PET
PET
PET PET
HDPE HDPE
Sample Description or ID
Cuyiofner to eom11rlete 4110 aPNrapf11ata
non-shaded areas.
R y
p
g
w E E
c_ d,
�+ a
9 H
8
e
° '° as
az
m t117 w
-
r.. .._.._.._.._.._
GPS Location
Collection Information g
s�
a ro
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U
® Z
a u!
x u y I
s M U rn
G
m m
E
o
F
Date Time store u'
i:Zv 10
--
�/
5!4`I5 gfs VSSJ
a�t'IWal
x q 2 1
1
9 a
1 1
s
MW-09 69
{f
r44
��z
Mw^16 art
5httr yrs kus�
a
_
Mw -or 13R
S1411.3 If S s {40
K
0
0
`
t i
0
- �i
0
0
a
( 4„A,
Filter Blank
- --
- —
TOTAL
4 2
_-- rtraTomrr rn nrgn e. nair onruw
.Relinquished
ByTma
Accepted $,e
?
�
DaTi e
ael7ime
- - -
�R®queat3Turnrond Tta!
/
`14 Day-,l
Rellnquiehed
v
Rellnquishad By
Da l e
_
+
Acc=
DatelTime
ra
7 Days
�,,
biq
y
D
sealdrLcoops ySeal/Locked
DaleiTinta
'48 Hr
E r
CommenYa
ELEMENTS by !Co MS (TRM), A*, 9e, rd, i".n, Cr, Cu, Mo, Ni. Ph, Sb, Se, Tl ILL). V (LL)
v D
�
`Other_ASAP
ELEMENTS
by ICY (TRM): Al, Be, B, Fe, Mn, Sr,
Zn ICP_llrtdlgoated Go, Mg, K. No
Hg by 245.1
w
• Add. Cast Will Apply
®issr)IveYl metals
all metals ICP. IMS,Iiq
V
ytical Lab
52 of 52