Loading...
HomeMy WebLinkAboutNC0000396_J15040636 Report_20150823+ DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Order Number: J15040636 Project Name: ASHEVILLE - AB GW ASSESSMENT SOIL Customer Name(s): Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker Customer Address: 200 CP and L Drive Arden, NC 28704 Lab Contact: Margaret Galvin -Karr Phone: 980-875-5219 MXG4644 (101161) Report Authorized By: V�t_�IrG�Y 2015.06.01 10:09:13 Date: (Signature) -04'00' Margaret Galvin -Karr Program Comments: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 5/28/2015 1 of 81 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Sample ID Plant/Station Collection Date and Time Collected By 2 of 81 Sample Description 2015012116 ASHEVILLE 22 -Apr -15 1:45 PM Russo Well Equipment Blank 2015012117 ASHEVILLE 22 -Apr -15 10:35 AM Russo Well MW -18 SB (1-1.5) 2015012118 ASHEVILLE 22 -Apr -15 11:15 AM Russo Well MW -18 SB (6-7) 2015012119 ASHEVILLE 22 -Apr -15 2:20 PM Russo Well MW -18 SB (20-22) 2015012120 ASHEVILLE 22 -Apr -15 2:20 PM Russo Well CB -08 SB (2-3) 2015012121 ASHEVILLE 22 -Apr -15 4:30 PM Russo Well CB -08 SB (21-22) 2015012122 ASHEVILLE 22 -Apr -15 4:40 PM Russo Well CB -08 SB (27-29) 2015012123 ASHEVILLE 22 -Apr -15 4:50 PM Russo Well CB -08 SB (34-36) 8 Total Samples Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes F./] No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Reviewed By: Date: 3of81 Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 0 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Certificate of Laboratory Analysis 4 of 81 This report shall not be reproduced, except in full. Order # J15040636 Site: Well Equipment Blank Collection Date: 22 -Apr -15 1:45 PM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015012116 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040636 Site: Well MW -18 SB (1-1.5) Collection Date: 22 -Apr -15 10:35 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 5of81 Sample #: 2015012117 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040636 Site: Well MW -18 SB (6-7) Collection Date: 22 -Apr -15 11:15 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6of81 Sample #: 2015012118 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040636 Site: Well MW -18 SB (20-22) Collection Date: 22 -Apr -15 2:20 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 7of81 Sample #: 2015012119 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040636 Site: Well CB -08 SB (2-3) Collection Date: 22 -Apr -15 2:20 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 8of81 Sample #: 2015012120 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040636 Site: Well CB -08 SB (21-22) Collection Date: 22 -Apr -15 4:30 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 9of81 Sample #: 2015012121 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040636 Site: Well CB -08 SB (27-29) Collection Date: 22 -Apr -15 4:40 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 10 of 81 Sample #: 2015012122 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040636 Site: Well CB -08 SB (34-36) Collection Date: 22 -Apr -15 4:50 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 11 of 81 Sample #: 2015012123 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE aceAnaiXical www.pacelabs.com May 18, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 RE: Project: J15040636 Pace Project No.: 92247233 Pace Analytical Services, Inc. 9800 )iQ,8y fte. Suite 100 Huntersville, NC 28078 (704)875-9092 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on April 27, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy HiQ p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� ��� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 69 lacmnalyfica( www.pacelabs.com Project: J15040636 Pace Project No.: 92247233 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21 -A Certification #: 2926.01 Alaska Certification #: UST -078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ -0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH -0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. 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Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN -002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE -OS -28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 69 aceAnaiXical www.pacelabs.com Project: J15040636 Pace Project No.: 92247233 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 ffli '8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 69 aceAnaiXical www.pacelabs.com SAMPLE SUMMARY Project: J15040636 Pace Project No.: 92247233 Lab ID Sample ID Matrix Date Collected Date Received 92247233001 2015012116 Water 04/22/1513:45 04/27/1517:30 92247233002 2015012117 Solid 04/22/1510:35 04/27/1517:30 92247233003 2015012117 SPLP Water 04/22/15 10:35 04/27/15 17:30 92247233004 2015012118 Solid 04/22/1511:15 04/27/1517:30 92247233005 2015012119 Solid 04/22/1514:20 04/27/1517:30 92247233006 2015012120 Solid 04/22/1514:20 04/27/1517:30 92247233007 2015012121 Solid 04/22/1516:30 04/27/1517:30 92247233008 2015012122 Solid 04/22/1516:40 04/27/1517:30 92247233009 2015012122 SPLP Water 04/22/15 16:40 04/27/15 17:30 92247233010 2015012123 Solid 04/22/1516:50 04/27/1517:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 f ig'8y fte. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 69 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 9800 ffli '8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15040636 92247233 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92247233001 2015012116 EPA 6020A RJS 24 PASI-M EPA 7470A JDD 1 PASI-M 92247233002 2015012117 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92247233003 2015012117 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A JDD 1 PASI-M 92247233004 2015012118 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92247233005 2015012119 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92247233006 2015012120 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 69 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 9800 fflic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040636 Pace Project No.: 92247233 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92247233007 2015012121 EPA 6010 TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92247233008 2015012122 EPA 6010 CKJ, TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92247233009 2015012122 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A JDD 1 PASI-M 92247233010 2015012123 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 69 aceAnaiXical www.pacelabs.com Project: J15040636 Pace Project No.: 92247233 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 9800 ffli '8f ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92247233001 2015012116 EPA 6020A Aluminum 77.1 ug/L 10.0 05/06/15 09:14 EPA 6020A Antimony 0.28J ug/L 0.50 05/05/15 13:51 EPA 6020A Barium 1.5 ug/L 0.30 05/05/15 13:51 EPA 6020A Boron 1.51 ug/L 5.0 05/05/15 13:51 EPA 6020A Calcium 655 ug/L 40.0 05/05/15 13:51 EPA 6020A Chromium 2.3 ug/L 0.50 05/05/15 13:51 EPA 6020A Cobalt 18.0 ug/L 0.50 05/05/15 13:51 EPA 6020A Copper 3.0 ug/L 1.0 05/05/15 13:51 EPA 6020A Iron 437 ug/L 50.0 05/05/15 13:51 EPA 6020A Lead 0.16 ug/L 0.10 05/05/15 13:51 EPA 6020A Magnesium 43.8 ug/L 10.0 05/05/15 13:51 EPA 6020A Manganese 12.6 ug/L 0.50 05/05/15 13:51 EPA 6020A Molybdenum 0.14J ug/L 0.50 05/05/15 13:51 EPA 6020A Nickel 0.80 ug/L 0.50 05/05/15 13:51 EPA 6020A Potassium 62.4 ug/L 50.0 05/05/15 13:51 EPA 6020A Sodium 49.6J ug/L 50.0 05/05/15 13:51 EPA 6020A Strontium 0.97 ug/L 0.50 05/05/15 13:51 EPA 6020A Zinc 9.3 ug/L 5.0 05/05/15 13:51 92247233002 2015012117 EPA 6010 Aluminum 9180 mg/kg 32.5 05/07/15 11:26 EPA 6010 Barium 39.4 mg/kg 3.2 05/07/15 11:26 EPA 6010 Beryllium 0.56 mg/kg 0.32 05/07/15 11:26 EPA 6010 Calcium 174 mg/kg 162 05/07/15 11:26 EPA 6010 Chromium 8.3 mg/kg 1.6 05/07/15 11:26 EPA 6010 Copper 2.7 mg/kg 1.6 05/07/15 11:26 EPA 6010 Iron 9190 mg/kg 13.0 05/07/15 11:26 EPA 6010 Magnesium 2220 mg/kg 162 05/07/15 11:26 EPA 6010 Manganese 77.2 mg/kg 1.6 05/07/15 11:26 EPA 6010 Nickel 4.7 mg/kg 1.6 05/07/15 11:26 EPA 6010 Potassium 1350 mg/kg 325 05/07/15 11:26 EPA 6010 Strontium 2.6J mg/kg 3.2 05/07/15 11:26 EPA 6010 Zinc 26.0 mg/kg 6.5 05/07/15 11:26 EPA 6020 Cobalt 3.6J mg/kg 6.5 05/06/15 18:20 EPA 6020 Lead 3.3J mg/kg 6.5 05/06/15 18:20 EPA 6020 Vanadium 12.7 mg/kg 6.5 05/06/15 18:20 ASTM D2974-87 Percent Moisture 19.4 % 0.10 05/13/15 10:30 EPA 9045 pH at 25 Degrees C 5.9 Std. Units 0.10 04/29/15 14:50 EPA 300.0 Sulfate 5.2 mg/L 2.5 05/07/15 13:56 B EPA 353.2 Nitrogen, Nitrate 0.36 mg/L 0.25 05/13/15 13:35 H1 EPA 9060 Total Organic Carbon 1730 mg/kg 747 05/14/15 13:31 EPA 9060 Total Organic Carbon 1710 mg/kg 740 05/14/15 13:38 EPA 9060 Total Organic Carbon 1600 mg/kg 745 05/14/15 13:43 EPA 9060 Total Organic Carbon 1550 mg/kg 740 05/14/15 13:49 EPA 9060 Mean Total Organic Carbon 1650 mg/kg 743 05/14/15 13:31 EPA 9060 RSD% 5.1 % 05/14/15 13:31 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 69 aceAnaiXical www.pacelabs.com Project: J15040636 Pace Project No.: 92247233 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 9800 ffli ,8yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92247233003 2015012117 SPLP EPA 6020A Aluminum 21500 ug/L 10.0 05/14/15 20:59 EPA 6020A Antimony 1.0 ug/L 0.50 05/14/15 20:59 EPA 6020A Arsenic 2.7 ug/L 0.50 05/14/15 20:59 EPA 6020A Barium 193 ug/L 0.30 05/14/15 20:59 EPA 6020A Beryllium 1.4 ug/L 0.20 05/14/15 20:59 EPA 6020A Boron 45.2 ug/L 5.0 05/14/15 20:59 EPA 6020A Cadmium 0.11 ug/L 0.080 05/14/15 20:59 EPA 6020A Calcium 1640 ug/L 40.0 05/14/15 20:59 EPA 6020A Chromium 12.0 ug/L 0.50 05/14/15 20:59 EPA 6020A Cobalt 4.8 ug/L 0.50 05/14/15 20:59 EPA 6020A Copper 5.3 ug/L 1.0 05/14/15 20:59 EPA 6020A Iron 11600 ug/L 50.0 05/14/15 20:59 EPA 6020A Lead 8.0 ug/L 0.10 05/14/15 20:59 EPA 6020A Magnesium 756 ug/L 10.0 05/14/15 20:59 EPA 6020A Manganese 47.0 ug/L 0.50 05/14/15 20:59 EPA 6020A Molybdenum 8.2 ug/L 0.50 05/14/15 20:59 EPA 6020A Nickel 6.3 ug/L 0.50 05/14/15 20:59 EPA 6020A Potassium 788 ug/L 50.0 05/14/15 20:59 EPA 6020A Selenium 1.6 ug/L 0.50 05/14/15 20:59 EPA 6020A Sodium 1430 ug/L 50.0 05/14/15 20:59 EPA 6020A Strontium 21.3 ug/L 0.50 05/14/15 20:59 EPA 6020A Thallium 0.19 ug/L 0.10 05/14/15 20:59 EPA 6020A Vanadium 19.9 ug/L 1.0 05/14/15 20:59 EPA 6020A Zinc 110 ug/L 5.0 05/14/15 20:59 92247233004 2015012118 EPA 6010 Aluminum 8870 mg/kg 35.5 05/07/15 11:30 EPA 6010 Barium 37.0 mg/kg 3.6 05/07/15 11:30 EPA 6010 Beryllium 0.50 mg/kg 0.36 05/07/15 11:30 EPA 6010 Calcium 181 mg/kg 178 05/07/15 11:30 EPA 6010 Chromium 8.4 mg/kg 1.8 05/07/15 11:30 EPA 6010 Copper 3.4 mg/kg 1.8 05/07/15 11:30 EPA 6010 Iron 9930 mg/kg 14.2 05/07/15 11:30 EPA 6010 Magnesium 2260 mg/kg 178 05/07/15 11:30 EPA 6010 Manganese 85.6 mg/kg 1.8 05/07/15 11:30 EPA 6010 Nickel 4.4 mg/kg 1.8 05/07/15 11:30 EPA 6010 Potassium 1470 mg/kg 355 05/07/15 11:30 EPA 6010 Strontium 2.6J mg/kg 3.6 05/07/15 11:30 EPA 6010 Zinc 26.4 mg/kg 7.1 05/07/15 11:30 EPA 6020 Cobalt 3.6J mg/kg 7.1 05/06/15 18:23 EPA 6020 Vanadium 14.1 mg/kg 7.1 05/06/15 18:23 EPA 7471 Mercury 0.0086J mg/kg 0.011 05/07/15 14:21 ASTM D2974-87 Percent Moisture 26.4 % 0.10 05/13/15 10:30 EPA 9045 pH at 25 Degrees C 6.4 Std. Units 0.10 04/29/15 14:50 EPA 9060 Total Organic Carbon 2050 mg/kg 808 05/14/15 13:55 EPA 9060 Total Organic Carbon 1950 mg/kg 820 05/14/15 14:02 EPA 9060 Total Organic Carbon 2340 mg/kg 812 05/14/15 14:07 EPA 9060 Total Organic Carbon 2080 mg/kg 808 05/14/15 14:14 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Qualifiers Page 8 of 69 aceAnaiXical www.pacelabs.com Project: J15040636 Pace Project No.: 92247233 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 9800 KPi '8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92247233004 2015012118 EPA 9060 Mean Total Organic Carbon 2110 mg/kg 812 05/14/15 13:55 EPA 9060 RSD% 7.8 % 05/14/15 13:55 92247233005 2015012119 EPA 6010 Aluminum 14700 mg/kg 24.4 05/07/15 11:34 EPA 6010 Barium 242 mg/kg 2.4 05/07/15 11:34 EPA 6010 Beryllium 0.54 mg/kg 0.24 05/07/15 11:34 EPA 6010 Boron 26.9 mg/kg 12.2 05/07/15 11:34 EPA 6010 Calcium 2830 mg/kg 122 05/07/15 11:34 EPA 6010 Chromium 24.8 mg/kg 1.2 05/07/15 11:34 EPA 6010 Copper 15.0 mg/kg 1.2 05/07/15 11:34 EPA 6010 Iron 28200 mg/kg 9.7 05/07/15 11:34 EPA 6010 Magnesium 8720 mg/kg 122 05/07/15 11:34 EPA 6010 Manganese 165 mg/kg 1.2 05/07/15 11:34 EPA 6010 Nickel 15.9 mg/kg 1.2 05/07/15 11:34 EPA 6010 Potassium 8140 mg/kg 244 05/07/15 11:34 EPA 6010 Sodium 231J mg/kg 244 05/07/1511:34 EPA 6010 Strontium 10.5 mg/kg 2.4 05/07/15 11:34 EPA 6010 Zinc 95.6 mg/kg 4.9 05/07/15 11:34 EPA 6020 Cobalt 11.8 mg/kg 4.9 05/06/15 18:25 EPA 6020 Lead 2.5J mg/kg 4.9 05/06/15 18:25 EPA 6020 Vanadium 41.4 mg/kg 4.9 05/06/15 18:25 ASTM D2974-87 Percent Moisture 1.9 % 0.10 05/13/15 10:30 EPA 9045 pH at 25 Degrees C 7.1 Std. Units 0.10 04/29/15 14:50 EPA 9060 RSD% 5.0 % 05/14/15 14:19 92247233006 2015012120 EPA 6010 Aluminum 20100 mg/kg 28.0 05/07/15 11:39 EPA 6010 Barium 87.5 mg/kg 2.8 05/07/15 11:39 EPA 6010 Beryllium 0.62 mg/kg 0.28 05/07/15 11:39 EPA 6010 Boron 23.3 mg/kg 14.0 05/07/15 11:39 EPA 6010 Calcium 185 mg/kg 140 05/07/15 11:39 EPA 6010 Chromium 19.4 mg/kg 1.4 05/07/15 11:39 EPA 6010 Copper 5.6 mg/kg 1.4 05/07/15 11:39 EPA 6010 Iron 23300 mg/kg 11.2 05/07/15 11:39 EPA 6010 Magnesium 1110 mg/kg 140 05/07/15 11:39 EPA 6010 Manganese 99.5 mg/kg 1.4 05/07/15 11:39 EPA 6010 Nickel 5.4 mg/kg 1.4 05/07/15 11:39 EPA 6010 Potassium 785 mg/kg 280 05/07/15 11:39 EPA 6010 Strontium 3.1 mg/kg 2.8 05/07/15 11:39 EPA 6010 Zinc 27.8 mg/kg 5.6 05/07/15 11:39 EPA 6020 Arsenic 2.9J mg/kg 5.6 05/06/15 18:35 EPA 6020 Cobalt 4.5J mg/kg 5.6 05/06/15 18:35 EPA 6020 Lead 12.0 mg/kg 5.6 05/06/15 18:35 EPA 6020 Vanadium 36.1 mg/kg 5.6 05/06/15 18:35 EPA 7471 Mercury 0.029 mg/kg 0.0096 05/07/15 14:25 ASTM D2974-87 Percent Moisture 14.1 % 0.10 05/13/15 10:30 EPA 9045 pH at 25 Degrees C 5.7 Std. Units 0.10 04/29/15 14:50 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 69 aceAnaiXical www.pacelabs.com Project: J15040636 Pace Project No.: 92247233 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 9800 tf�nic&yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92247233006 2015012120 EPA 9060 Total Organic Carbon 2730 mg/kg 701 05/14/15 14:45 EPA 9060 Total Organic Carbon 3210 mg/kg 695 05/14/15 14:50 EPA 9060 Total Organic Carbon 3910 mg/kg 699 05/14/15 14:56 EPA 9060 Total Organic Carbon 3050 mg/kg 694 05/14/15 15:02 EPA 9060 Mean Total Organic Carbon 3230 mg/kg 697 05/14/15 14:45 EPA 9060 RSD% 15.5 % 05/14/15 14:45 92247233007 2015012121 EPA 6010 Aluminum 27700 mg/kg 52.7 05/08/15 15:09 EPA 6010 Barium 230 mg/kg 5.3 05/08/15 15:09 EPA 6010 Beryllium 1.9 mg/kg 0.53 05/08/15 15:09 EPA 6010 Boron 32.8 mg/kg 26.3 05/08/15 15:09 EPA 6010 Chromium 26.3 mg/kg 2.6 05/08/15 15:09 EPA 6010 Copper 5.1 mg/kg 2.6 05/08/15 15:09 EPA 6010 Iron 32300 mg/kg 21.1 05/08/15 15:09 EPA 6010 Magnesium 8400 mg/kg 263 05/08/15 15:09 EPA 6010 Manganese 569 mg/kg 2.6 05/08/15 15:09 EPA 6010 Nickel 25.1 mg/kg 2.6 05/08/15 15:09 EPA 6010 Potassium 7680 mg/kg 527 05/08/15 15:09 EPA 6010 Strontium 7.2 mg/kg 5.3 05/08/15 15:09 EPA 6010 Zinc 149 mg/kg 10.5 05/08/15 15:09 EPA 6020 Cobalt 23.5 mg/kg 5.3 05/06/15 18:37 EPA 6020 Lead 12.6 mg/kg 5.3 05/06/15 18:37 EPA 6020 Selenium 3.7J mg/kg 5.3 05/06/15 18:37 EPA 6020 Vanadium 36.0 mg/kg 5.3 05/06/15 18:37 ASTM D2974-87 Percent Moisture 3.9 % 0.10 05/13/15 10:31 EPA 9045 pH at 25 Degrees C 5.5 Std. Units 0.10 04/29/15 14:50 EPA 9060 RSD% 1.6 % 05/15/15 15:08 92247233008 2015012122 EPA 6010 Aluminum 40100 mg/kg 30.4 05/07/15 12:26 EPA 6010 Barium 356 mg/kg 3.0 05/07/15 12:26 EPA 6010 Beryllium 2.0 mg/kg 0.61 05/08/15 15:13 EPA 6010 Boron 50.0 mg/kg 30.4 05/08/15 15:13 EPA 6010 Calcium 169 mg/kg 152 05/07/15 12:26 EPA 6010 Chromium 48.5 mg/kg 3.0 05/08/15 15:13 EPA 6010 Copper 178 mg/kg 3.0 05/08/15 15:13 EPA 6010 Iron 45600 mg/kg 12.2 05/07/15 12:26 EPA 6010 Magnesium 13300 mg/kg 152 05/07/15 12:26 EPA 6010 Manganese 1020 mg/kg 3.0 05/08/15 15:13 EPA 6010 Nickel 37.4 mg/kg 1.5 05/07/15 12:26 EPA 6010 Potassium 12200 mg/kg 304 05/07/15 12:26 EPA 6010 Sodium 158J mg/kg 304 05/07/15 12:26 EPA 6010 Strontium 1.6J mg/kg 3.0 05/07/15 12:26 EPA 6010 Zinc 203 mg/kg 6.1 05/07/15 12:26 EPA 6020 Cobalt 32.3 mg/kg 6.1 05/06/15 18:39 EPA 6020 Lead 21.6 mg/kg 6.1 05/06/15 18:39 EPA 6020 Selenium 3.9J mg/kg 6.1 05/06/15 18:39 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Qualifiers Page 10 of 69 aceAnaiXical www.pacelabs.com Project: J15040636 Pace Project No.: 92247233 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 9800 K2'8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92247233008 2015012122 EPA 6020 Vanadium 50.3 mg/kg 6.1 05/06/15 18:39 ASTM D2974-87 Percent Moisture 16.3 % 0.10 05/13/15 10:31 EPA 9045 pH at 25 Degrees C 5.8 Std. Units 0.10 04/29/15 14:50 EPA 300.0 Sulfate 3.5 mg/L 2.4 05/07/15 14:09 B EPA 353.2 Nitrogen, Nitrate 0.24 mg/L 0.24 05/13/15 13:36 H1 EPA 9060 RSD% 3.2 % 05/15/15 16:16 92247233009 2015012122 SPLP EPA 6020A Aluminum 27.4 ug/L 10.0 05/14/15 21:02 EPA 6020A Barium 75.9 ug/L 0.30 05/14/15 21:02 EPA 6020A Boron 36.1 ug/L 5.0 05/14/15 21:02 EPA 6020A Calcium 169 ug/L 40.0 05/14/15 21:02 EPA 6020A Chromium 0.27J ug/L 0.50 05/14/15 21:02 EPA 6020A Cobalt 0.82 ug/L 0.50 05/14/15 21:02 EPA 6020A Copper 2.7 ug/L 1.0 05/14/15 21:02 EPA 6020A Iron 16AJ ug/L 50.0 05/14/15 21:02 EPA 6020A Lead 0.14 ug/L 0.10 05/14/15 21:02 EPA 6020A Magnesium 83.0 ug/L 10.0 05/14/15 21:02 EPA 6020A Manganese 37.4 ug/L 0.50 05/14/15 21:02 EPA 6020A Nickel 0.32J ug/L 0.50 05/14/15 21:02 EPA 6020A Potassium 140 ug/L 50.0 05/14/15 21:02 EPA 6020A Sodium 1220 ug/L 50.0 05/14/15 21:02 EPA 6020A Strontium 2.6 ug/L 0.50 05/14/15 21:02 EPA 6020A Zinc 30.4 ug/L 5.0 05/14/15 21:02 92247233010 2015012123 EPA 6010 Aluminum 28300 mg/kg 27.6 05/07/15 12:31 EPA 6010 Barium 232 mg/kg 2.8 05/07/15 12:31 EPA 6010 Beryllium 1.5 mg/kg 0.28 05/07/15 12:31 EPA 6010 Boron 31.5 mg/kg 13.8 05/07/15 12:31 EPA 6010 Calcium 218 mg/kg 138 05/07/15 12:31 EPA 6010 Chromium 34.1 mg/kg 1.4 05/07/15 12:31 EPA 6010 Copper 9.1 mg/kg 1.4 05/07/15 12:31 EPA 6010 Iron 36400 mg/kg 11.0 05/07/15 12:31 EPA 6010 Magnesium 11700 mg/kg 138 05/07/15 12:31 EPA 6010 Manganese 570 mg/kg 1.4 05/07/15 12:31 EPA 6010 Nickel 33.3 mg/kg 1.4 05/07/15 12:31 EPA 6010 Potassium 10300 mg/kg 276 05/07/15 12:31 EPA 6010 Strontium 10.1 mg/kg 2.8 05/07/15 12:31 EPA 6010 Zinc 130 mg/kg 5.5 05/07/15 12:31 EPA 6020 Cobalt 22.9 mg/kg 5.5 05/06/15 18:42 EPA 6020 Lead 6.3 mg/kg 5.5 05/06/15 18:42 EPA 6020 Selenium 2.8J mg/kg 5.5 05/06/15 18:42 EPA 6020 Vanadium 31.7 mg/kg 5.5 05/06/15 18:42 ASTM D2974-87 Percent Moisture 5.0 % 0.10 05/13/15 10:31 EPA 9045 pH at 25 Degrees C 6.3 Std. Units 0.10 04/29/15 14:50 EPA 9060 RSD% 3.2 % 05/15/15 16:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 69 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KS'8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040636 Pace Project No.: 92247233 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: May 18, 2015 General Information: 7 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23950 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247232001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1203100) • Aluminum • Iron • Molybdenum • MSD (Lab ID: 1203101) • Aluminum • Barium • Calcium • Iron • Manganese • Strontium R1: RPD value was outside control limits. • MSD (Lab ID: 1203101) • Calcium • Molybdenum • Strontium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 69 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15040636 Pace Project No.: 92247233 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: May 18, 2015 Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICP / 14654 Analyte Comments: QC Batch: MPRP/23950 Pace Analytical Services, Inc. 9800 K4'8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. • BLANK (Lab ID: 1203098) • Manganese • BLANK (Lab ID: 1203098) • Manganese REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 69 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPi '8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040636 Pace Project No.: 92247233 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: May 18, 2015 General Information: 7 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23951 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247232001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1203104) • Arsenic • Selenium • Thallium • Vanadium • MSD (Lab ID: 1203105) • Arsenic • Lead • Selenium • Thallium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 69 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %'8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040636 Pace Project No.: 92247233 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: May 18, 2015 Analyte Comments: QC Batch: MPRP/23951 N2: The lab does not hold TNI accreditation for this parameter. •2015012117 (Lab ID:92247233002) • Antimony •2015012118 (Lab ID:92247233004) • Antimony •2015012119 (Lab ID:92247233005) • Antimony •2015012120 (Lab ID:92247233006) • Antimony •2015012121 (Lab ID:92247233007) • Antimony •2015012122 (Lab ID:92247233008) • Antimony •2015012123 (Lab ID:92247233010) • Antimony • BLANK (Lab ID: 1203102) • Antimony • LCS (Lab ID: 1203103) • Antimony • MS (Lab ID: 1203104) • Antimony • MSD (Lab ID: 1203105) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 69 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040636 Pace Project No.: 92247233 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: May 18, 2015 General Information: 3 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/54062 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247374001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1953030) • Aluminum • MSD (Lab ID: 1953031) • Aluminum QC Batch: MPRP/54343 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92249101001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1963687) • Aluminum • MSD (Lab ID: 1963688) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 69 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPi '8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040636 Pace Project No.: 92247233 Method: EPA 7470A Description: 7470A Mercury Client: Duke Energy Date: May 18, 2015 General Information: 3 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 69 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 tf� '8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040636 Pace Project No.: 92247233 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: May 18, 2015 General Information: 7 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MERP/5678 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247232001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1203120) • Mercury • MSD (Lab ID: 1203121) • Mercury Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 69 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 tri '8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040636 Pace Project No.: 92247233 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: May 18, 2015 General Information: 7 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. QC Batch: WET/37120 D6: The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. • DUP (Lab ID: 1445735) • pH at 25 Degrees C Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 69 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 �nlc&)rfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040636 Pace Project No.: 92247233 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: May 18, 2015 General Information: 2 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/22837 B: Analyte was detected in the associated method blank. • BLANK for HBN 262746 [WETA/228 (Lab ID: 1452663) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 69 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 �Q%yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040636 Pace Project No.: 92247233 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: May 18, 2015 General Information: 2 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015012117 (Lab ID: 92247233002) •2015012122 (Lab ID: 92247233008) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 69 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15040636 Pace Project No.: 92247233 Method: SM 4500 -CI -E Description: 4500 Chloride, SPLP Client: Duke Energy Date: May 18, 2015 Pace Analytical Services, Inc. 9800 t S'8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 2 samples were analyzed for SM 4500 -CI -E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 69 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 t 4'8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040636 Pace Project No.: 92247233 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: May 18, 2015 General Information: 7 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/46021 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015012117 (Lab ID:92247233002) • Chloride • Sulfate •2015012118 (Lab ID:92247233004) • Chloride • Sulfate •2015012119 (Lab ID:92247233005) • Chloride • Sulfate •2015012120 (Lab ID:92247233006) • Chloride • Sulfate •2015012121 (Lab ID:92247233007) • Chloride • Sulfate •2015012122 (Lab ID:92247233008) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 69 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %'8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040636 Pace Project No.: 92247233 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: May 18, 2015 Analyte Comments: QC Batch: WETA/46021 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015012123 (Lab ID: 92247233010) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 69 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 tri '8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040636 Pace Project No.: 92247233 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: May 18, 2015 General Information: 7 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015012117 (Lab ID:92247233002) •2015012118 (Lab ID:92247233004) •2015012119 (Lab ID:92247233005) •2015012120 (Lab ID:92247233006) •2015012121 (Lab ID:92247233007) •2015012122 (Lab ID:92247233008) •2015012123 (Lab ID:92247233010) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 69 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040636 Pace Project No.: 92247233 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: May 18, 2015 General Information: 7 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 69 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040636 Pace Project No.: 92247233 Pace Analytical Services, Inc. 9800 Kai '8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015012116 Lab ID: 92247233001 Collected: 04/22/15 13:45 Received: 04/27/15 17:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 05/18/2015 05:09 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 77.1 ug/L 10.0 3.0 1 05/01/15 11:28 05/06/15 09:14 7429-90-5 0.28J ug/L 0.50 0.15 1 05/01/15 11:28 05/05/15 13:51 7440-36-0 ND ug/L 0.50 0.11 1 05/01/1511:28 05/05/1513:51 7440-38-2 1.5 ug/L 0.30 0.081 1 05/01/1511:28 05/05/1513:51 7440-39-3 ND ug/L 0.20 0.067 1 05/01/1511:28 05/05/1513:51 7440-41-7 1.5J ug/L 5.0 1.1 1 05/01/1511:28 05/05/1513:51 7440-42-8 ND ug/L 0.080 0.024 1 05/01/1511:28 05/05/1513:51 7440-43-9 655 ug/L 40.0 16.0 1 05/01/1511:28 05/05/1513:51 7440-70-2 2.3 ug/L 0.50 0.17 1 05/01/1511:28 05/05/1513:51 7440-47-3 18.0 ug/L 0.50 0.13 1 05/01/15 11:28 05/05/15 13:51 7440-48-4 3.0 ug/L 1.0 0.21 1 05/01/15 11:28 05/05/15 13:51 7440-50-8 437 ug/L 50.0 13.7 1 05/01/1511:28 05/05/1513:51 7439-89-6 0.16 ug/L 0.10 0.046 1 05/01/1511:28 05/05/1513:51 7439-92-1 43.8 ug/L 10.0 3.2 1 05/01/1511:28 05/05/1513:51 7439-95-4 12.6 ug/L 0.50 0.24 1 05/01/15 11:28 05/05/15 13:51 7439-96-5 0.14J ug/L 0.50 0.094 1 05/01/1511:28 05/05/1513:51 7439-98-7 0.80 ug/L 0.50 0.16 1 05/01/1511:28 05/05/1513:51 7440-02-0 62.4 ug/L 50.0 11.7 1 05/01/15 11:28 05/05/15 13:51 7440-09-7 ND ug/L 0.50 0.20 1 05/01/1511:28 05/05/1513:51 7782-49-2 49.6J ug/L 50.0 16.3 1 05/01/1511:28 05/05/1513:51 7440-23-5 0.97 ug/L 0.50 0.13 1 05/01/1511:28 05/05/1513:51 7440-24-6 ND ug/L 0.10 0.015 1 05/01/1511:28 05/05/1513:51 7440-28-0 ND ug/L 1.0 0.28 1 05/01/1511:28 05/05/1513:51 7440-62-2 9.3 ug/L 5.0 2.4 1 05/01/1511:28 05/05/1513:51 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 05/01/15 21:15 05/04/15 16:26 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 69 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040636 Pace Project No.: 92247233 Pace Analytical Services, Inc. 9800 Kai '8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015012117 Lab ID: 92247233002 Collected: 04/22/15 10:35 Received: 04/27/15 17:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 05/18/2015 05:09 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 9180 mg/kg 32.5 16.2 5 05/06/1513:50 05/07/1511:26 7429-90-5 39.4 mg/kg 3.2 1.6 5 05/06/1513:50 05/07/1511:26 7440-39-3 0.56 mg/kg 0.32 0.16 5 05/06/1513:50 05/07/1511:26 7440-41-7 ND mg/kg 16.2 8.1 5 05/06/1513:50 05/07/1511:26 7440-42-8 174 mg/kg 162 81.2 5 05/06/1513:50 05/07/1511:26 7440-70-2 8.3 mg/kg 1.6 0.81 5 05/06/1513:50 05/07/1511:26 7440-47-3 2.7 mg/kg 1.6 0.81 5 05/06/1513:50 05/07/1511:26 7440-50-8 9190 mg/kg 13.0 6.5 5 05/06/1513:50 05/07/1511:26 7439-89-6 2220 mg/kg 162 81.2 5 05/06/1513:50 05/07/1511:26 7439-95-4 77.2 mg/kg 1.6 0.81 5 05/06/1513:50 05/07/1511:26 7439-96-5 ND mg/kg 3.2 1.6 5 05/06/1513:50 05/07/1511:26 7439-98-7 4.7 mg/kg 1.6 0.81 5 05/06/1513:50 05/07/1511:26 7440-02-0 1350 mg/kg 325 162 5 05/06/1513:50 05/07/1511:26 7440-09-7 ND mg/kg 325 162 5 05/06/1513:50 05/07/1511:26 7440-23-5 2.6J mg/kg 3.2 1.6 5 05/06/1513:50 05/07/1511:26 7440-24-6 26.0 mg/kg 6.5 3.2 5 05/06/1513:50 05/07/1511:26 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 6.5 3.2 100 05/06/1513:50 05/06/1518:20 7440-36-0 ND mg/kg 6.5 3.2 100 05/06/1513:50 05/06/1518:20 7440-38-2 ND mg/kg 0.78 0.39 100 05/06/1513:50 05/06/1518:20 7440-43-9 3.6J mg/kg 6.5 3.2 100 05/06/1513:50 05/06/1518:20 7440-48-4 3.3J mg/kg 6.5 3.2 100 05/06/1513:50 05/06/1518:20 7439-92-1 ND mg/kg 6.5 3.2 100 05/06/1513:50 05/06/1518:20 7782-49-2 ND mg/kg 6.5 3.2 100 05/06/1513:50 05/06/1518:20 7440-28-0 12.7 mg/kg 6.5 3.2 100 05/06/1513:50 05/06/1518:20 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.0098 0.0049 1 05/06/1513:45 05/07/1514:19 7439-97-6 Analytical Method: ASTM D2974-87 19.4 % 0.10 0.10 1 05/13/1510:30 Analytical Method: EPA 9045 5.9 Std. Units 0.10 0.10 1 04/29/15 14:50 N2 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/30/15 04:20 5.2 mg/L 2.5 1.2 1 05/07/1513:56 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/30/15 04:20 0.36 mg/L 0.25 0.25 1 05/13/1513:35 H1 Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 04/30/15 04:20 ND mg/L 6.2 3.1 1 05/09/15 03:42 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 69 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 %'8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040636 Pace Project No.: 92247233 Sample: 2015012117 Lab ID: 92247233002 Collected: 04/22/15 10:35 Received: 04/27/15 17:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 308 154 5 05/02/15 21:56 16887-00-6 D3 Sulfate ND mg/kg 308 154 5 05/02/15 21:56 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 30.8 15.4 5 05/02/15 21:56 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1730 mg/kg 747 373 1 05/14/15 13:31 7440-44-0 Total Organic Carbon 1710 mg/kg 740 370 1 05/14/15 13:38 7440-44-0 Total Organic Carbon 1600 mg/kg 745 373 1 05/14/15 13:43 7440-44-0 Total Organic Carbon 1550 mg/kg 740 370 1 05/14/15 13:49 7440-44-0 Mean Total Organic Carbon 1650 mg/kg 743 372 1 05/14/15 13:31 7440-44-0 Surrogates RSD% 5.1 % 1 05/14/1513:31 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 29 of 69 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040636 Pace Project No.: 92247233 Pace Analytical Services, Inc. 9800 1inlc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015012117 SPLP Lab ID: 92247233003 Collected: 04/22/15 10:35 Received: 04/27/15 17:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 05/18/2015 05:09 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 21500 ug/L 10.0 3.0 1 05/14/15 07:47 05/14/15 20:59 7429-90-5 1.0 ug/L 0.50 0.15 1 05/14/15 07:47 05/14/15 20:59 7440-36-0 2.7 ug/L 0.50 0.11 1 05/14/15 07:47 05/14/15 20:59 7440-38-2 193 ug/L 0.30 0.081 1 05/14/15 07:47 05/14/15 20:59 7440-39-3 1.4 ug/L 0.20 0.067 1 05/14/15 07:47 05/14/15 20:59 7440-41-7 45.2 ug/L 5.0 1.1 1 05/14/15 07:47 05/14/15 20:59 7440-42-8 0.11 ug/L 0.080 0.024 1 05/14/15 07:47 05/14/15 20:59 7440-43-9 1640 ug/L 40.0 16.0 1 05/14/15 07:47 05/14/15 20:59 7440-70-2 12.0 ug/L 0.50 0.17 1 05/14/15 07:47 05/14/15 20:59 7440-47-3 4.8 ug/L 0.50 0.13 1 05/14/15 07:47 05/14/15 20:59 7440-48-4 5.3 ug/L 1.0 0.21 1 05/14/15 07:47 05/14/15 20:59 7440-50-8 11600 ug/L 50.0 13.7 1 05/14/15 07:47 05/14/15 20:59 7439-89-6 8.0 ug/L 0.10 0.046 1 05/14/15 07:47 05/14/15 20:59 7439-92-1 756 ug/L 10.0 3.2 1 05/14/15 07:47 05/14/15 20:59 7439-95-4 47.0 ug/L 0.50 0.24 1 05/14/15 07:47 05/14/15 20:59 7439-96-5 8.2 ug/L 0.50 0.094 1 05/14/15 07:47 05/14/15 20:59 7439-98-7 6.3 ug/L 0.50 0.16 1 05/14/15 07:47 05/14/15 20:59 7440-02-0 788 ug/L 50.0 11.7 1 05/14/15 07:47 05/14/15 20:59 7440-09-7 1.6 ug/L 0.50 0.20 1 05/14/15 07:47 05/14/15 20:59 7782-49-2 1430 ug/L 50.0 16.3 1 05/14/15 07:47 05/14/15 20:59 7440-23-5 21.3 ug/L 0.50 0.13 1 05/14/15 07:47 05/14/15 20:59 7440-24-6 0.19 ug/L 0.10 0.015 1 05/14/15 07:47 05/14/15 20:59 7440-28-0 19.9 ug/L 1.0 0.28 1 05/14/15 07:47 05/14/15 20:59 7440-62-2 110 ug/L 5.0 2.4 1 05/14/15 07:47 05/14/15 20:59 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 05/14/15 11:05 05/14/15 21:42 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 30 of 69 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040636 Pace Project No.: 92247233 Sample: 2015012118 Lab ID: 92247233004 Collected: 04/22/15 11:15 Received: 04/27/15 17:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 8870 mg/kg 35.5 17.8 5 05/06/1513:50 05/07/1511:30 7429-90-5 Barium 37.0 mg/kg 3.6 1.8 5 05/06/1513:50 05/07/1511:30 7440-39-3 Beryllium 0.50 mg/kg 0.36 0.18 5 05/06/1513:50 05/07/1511:30 7440-41-7 Boron ND mg/kg 17.8 8.9 5 05/06/1513:50 05/07/1511:30 7440-42-8 Calcium 181 mg/kg 178 88.8 5 05/06/1513:50 05/07/1511:30 7440-70-2 Chromium 8.4 mg/kg 1.8 0.89 5 05/06/1513:50 05/07/1511:30 7440-47-3 Copper 3.4 mg/kg 1.8 0.89 5 05/06/1513:50 05/07/1511:30 7440-50-8 Iron 9930 mg/kg 14.2 7.1 5 05/06/1513:50 05/07/1511:30 7439-89-6 Magnesium 2260 mg/kg 178 88.8 5 05/06/1513:50 05/07/1511:30 7439-95-4 Manganese 85.6 mg/kg 1.8 0.89 5 05/06/1513:50 05/07/1511:30 7439-96-5 Molybdenum ND mg/kg 3.6 1.8 5 05/06/1513:50 05/07/1511:30 7439-98-7 Nickel 4.4 mg/kg 1.8 0.89 5 05/06/1513:50 05/07/1511:30 7440-02-0 Potassium 1470 mg/kg 355 178 5 05/06/1513:50 05/07/1511:30 7440-09-7 Sodium ND mg/kg 355 178 5 05/06/1513:50 05/07/1511:30 7440-23-5 Strontium 2.6J mg/kg 3.6 1.8 5 05/06/1513:50 05/07/1511:30 7440-24-6 Zinc 26.4 mg/kg 7.1 3.6 5 05/06/1513:50 05/07/1511:30 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 7.1 3.6 100 05/06/1513:50 05/06/1518:23 7440-36-0 N2 Arsenic ND mg/kg 7.1 3.6 100 05/06/1513:50 05/06/1518:23 7440-38-2 Cadmium ND mg/kg 0.85 0.43 100 05/06/1513:50 05/06/1518:23 7440-43-9 Cobalt 3.6J mg/kg 7.1 3.6 100 05/06/1513:50 05/06/1518:23 7440-48-4 Lead ND mg/kg 7.1 3.6 100 05/06/1513:50 05/06/1518:23 7439-92-1 Selenium ND mg/kg 7.1 3.6 100 05/06/1513:50 05/06/1518:23 7782-49-2 Thallium ND mg/kg 7.1 3.6 100 05/06/1513:50 05/06/1518:23 7440-28-0 Vanadium 14.1 mg/kg 7.1 3.6 100 05/06/1513:50 05/06/1518:23 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.0086J mg/kg 0.011 0.0054 1 05/06/1513:45 05/07/1514:21 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 26.4 % 0.10 0.10 1 05/13/15 10:30 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.4 Std. Units 0.10 0.10 1 04/29/15 14:50 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 340 170 5 05/02/15 22:18 16887-00-6 D3 Sulfate ND mg/kg 340 170 5 05/02/15 22:18 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 34.0 17.0 5 05/02/15 22:18 14797-55-8 H3 Date: 05/18/2015 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 31 of 69 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040636 Pace Project No.: 92247233 Pace Analytical Services, Inc. 9800 %%Yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015012118 Lab ID: 92247233004 Collected: 04/22/15 11:15 Received: 04/27/15 17:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 2050 mg/kg 808 404 1 05/14/15 13:55 7440-44-0 Total Organic Carbon 1950 mg/kg 820 410 1 05/14/15 14:02 7440-44-0 Total Organic Carbon 2340 mg/kg 812 406 1 05/14/15 14:07 7440-44-0 Total Organic Carbon 2080 mg/kg 808 404 1 05/14/15 14:14 7440-44-0 Mean Total Organic Carbon 2110 mg/kg 812 406 1 05/14/15 13:55 7440-44-0 Surrogates RSD% 7.8 % 1 05/14/1513:55 Date: 05/18/2015 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 32 of 69 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 %'8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040636 Pace Project No.: 92247233 Sample: 2015012119 Lab ID: 92247233005 Collected: 04/22/15 14:20 Received: 04/27/15 17:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 14700 mg/kg 24.4 12.2 5 05/06/1513:50 05/07/1511:34 7429-90-5 Barium 242 mg/kg 2.4 1.2 5 05/06/1513:50 05/07/1511:34 7440-39-3 Beryllium 0.54 mg/kg 0.24 0.12 5 05/06/1513:50 05/07/1511:34 7440-41-7 Boron 26.9 mg/kg 12.2 6.1 5 05/06/1513:50 05/07/1511:34 7440-42-8 Calcium 2830 mg/kg 122 60.9 5 05/06/1513:50 05/07/1511:34 7440-70-2 Chromium 24.8 mg/kg 1.2 0.61 5 05/06/1513:50 05/07/1511:34 7440-47-3 Copper 15.0 mg/kg 1.2 0.61 5 05/06/1513:50 05/07/1511:34 7440-50-8 Iron 28200 mg/kg 9.7 4.9 5 05/06/1513:50 05/07/1511:34 7439-89-6 Magnesium 8720 mg/kg 122 60.9 5 05/06/1513:50 05/07/1511:34 7439-95-4 Manganese 165 mg/kg 1.2 0.61 5 05/06/1513:50 05/07/1511:34 7439-96-5 Molybdenum ND mg/kg 2.4 1.2 5 05/06/1513:50 05/07/1511:34 7439-98-7 Nickel 15.9 mg/kg 1.2 0.61 5 05/06/1513:50 05/07/1511:34 7440-02-0 Potassium 8140 mg/kg 244 122 5 05/06/1513:50 05/07/1511:34 7440-09-7 Sodium 231J mg/kg 244 122 5 05/06/1513:50 05/07/1511:34 7440-23-5 Strontium 10.5 mg/kg 2.4 1.2 5 05/06/1513:50 05/07/1511:34 7440-24-6 Zinc 95.6 mg/kg 4.9 2.4 5 05/06/1513:50 05/07/1511:34 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 4.9 2.4 100 05/06/1513:50 05/06/1518:25 7440-36-0 N2 Arsenic ND mg/kg 4.9 2.4 100 05/06/1513:50 05/06/1518:25 7440-38-2 Cadmium ND mg/kg 0.58 0.29 100 05/06/1513:50 05/06/1518:25 7440-43-9 Cobalt 11.8 mg/kg 4.9 2.4 100 05/06/1513:50 05/06/1518:25 7440-48-4 Lead 2.5J mg/kg 4.9 2.4 100 05/06/1513:50 05/06/1518:25 7439-92-1 Selenium ND mg/kg 4.9 2.4 100 05/06/1513:50 05/06/1518:25 7782-49-2 Thallium ND mg/kg 4.9 2.4 100 05/06/1513:50 05/06/1518:25 7440-28-0 Vanadium 41.4 mg/kg 4.9 2.4 100 05/06/1513:50 05/06/1518:25 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0081 0.0040 1 05/06/1513:45 05/07/1514:23 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 1.9 % 0.10 0.10 1 05/13/15 10:30 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 7.1 Std. Units 0.10 0.10 1 04/29/15 14:50 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 254 127 5 05/02/15 22:39 16887-00-6 D3 Sulfate ND mg/kg 254 127 5 05/02/15 22:39 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 25.4 12.7 5 05/02/15 22:39 14797-55-8 H3 Date: 05/18/2015 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 33 of 69 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040636 Pace Project No.: 92247233 Pace Analytical Services, Inc. 9800 %'8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015012119 Lab ID: 92247233005 Collected: 04/22/15 14:20 Received: 04/27/15 17:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 609 304 1 05/14/15 14:19 7440-44-0 Total Organic Carbon ND mg/kg 612 306 1 05/14/15 14:25 7440-44-0 Total Organic Carbon ND mg/kg 606 303 1 05/14/15 14:31 7440-44-0 Total Organic Carbon ND mg/kg 607 303 1 05/14/15 14:38 7440-44-0 Mean Total Organic Carbon ND mg/kg 608 304 1 05/14/15 14:19 7440-44-0 Surrogates RSD% 5.0 % 1 05/14/1514:19 Date: 05/18/2015 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 34 of 69 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 %'8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040636 Pace Project No.: 92247233 Sample: 2015012120 Lab ID: 92247233006 Collected: 04/22/15 14:20 Received: 04/27/15 17:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 20100 mg/kg 28.0 14.0 5 05/06/1513:50 05/07/1511:39 7429-90-5 Barium 87.5 mg/kg 2.8 1.4 5 05/06/1513:50 05/07/1511:39 7440-39-3 Beryllium 0.62 mg/kg 0.28 0.14 5 05/06/1513:50 05/07/1511:39 7440-41-7 Boron 23.3 mg/kg 14.0 7.0 5 05/06/1513:50 05/07/1511:39 7440-42-8 Calcium 185 mg/kg 140 70.1 5 05/06/1513:50 05/07/1511:39 7440-70-2 Chromium 19.4 mg/kg 1.4 0.70 5 05/06/1513:50 05/07/1511:39 7440-47-3 Copper 5.6 mg/kg 1.4 0.70 5 05/06/1513:50 05/07/1511:39 7440-50-8 Iron 23300 mg/kg 11.2 5.6 5 05/06/1513:50 05/07/1511:39 7439-89-6 Magnesium 1110 mg/kg 140 70.1 5 05/06/1513:50 05/07/1511:39 7439-95-4 Manganese 99.5 mg/kg 1.4 0.70 5 05/06/1513:50 05/07/1511:39 7439-96-5 Molybdenum ND mg/kg 2.8 1.4 5 05/06/1513:50 05/07/1511:39 7439-98-7 Nickel 5.4 mg/kg 1.4 0.70 5 05/06/1513:50 05/07/1511:39 7440-02-0 Potassium 785 mg/kg 280 140 5 05/06/1513:50 05/07/1511:39 7440-09-7 Sodium ND mg/kg 280 140 5 05/06/1513:50 05/07/1511:39 7440-23-5 Strontium 3.1 mg/kg 2.8 1.4 5 05/06/1513:50 05/07/1511:39 7440-24-6 Zinc 27.8 mg/kg 5.6 2.8 5 05/06/1513:50 05/07/1511:39 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 5.6 2.8 100 05/06/1513:50 05/06/1518:35 7440-36-0 N2 Arsenic 2.9J mg/kg 5.6 2.8 100 05/06/1513:50 05/06/1518:35 7440-38-2 Cadmium ND mg/kg 0.67 0.34 100 05/06/1513:50 05/06/1518:35 7440-43-9 Cobalt 4.5J mg/kg 5.6 2.8 100 05/06/1513:50 05/06/1518:35 7440-48-4 Lead 12.0 mg/kg 5.6 2.8 100 05/06/1513:50 05/06/1518:35 7439-92-1 Selenium ND mg/kg 5.6 2.8 100 05/06/1513:50 05/06/1518:35 7782-49-2 Thallium ND mg/kg 5.6 2.8 100 05/06/1513:50 05/06/1518:35 7440-28-0 Vanadium 36.1 mg/kg 5.6 2.8 100 05/06/1513:50 05/06/1518:35 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.029 mg/kg 0.0096 0.0048 1 05/06/1513:45 05/07/1514:25 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 14.1 % 0.10 0.10 1 05/13/15 10:30 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.7 Std. Units 0.10 0.10 1 04/29/15 14:50 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 289 145 5 05/02/15 23:01 16887-00-6 D3 Sulfate ND mg/kg 289 145 5 05/02/15 23:01 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 28.9 14.5 5 05/02/15 23:01 14797-55-8 H3 Date: 05/18/2015 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 35 of 69 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040636 Pace Project No.: 92247233 Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015012120 Lab ID: 92247233006 Collected: 04/22/15 14:20 Received: 04/27/15 17:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 2730 mg/kg 701 350 1 05/14/15 14:45 7440-44-0 Total Organic Carbon 3210 mg/kg 695 347 1 05/14/15 14:50 7440-44-0 Total Organic Carbon 3910 mg/kg 699 350 1 05/14/15 14:56 7440-44-0 Total Organic Carbon 3050 mg/kg 694 347 1 05/14/15 15:02 7440-44-0 Mean Total Organic Carbon 3230 mg/kg 697 349 1 05/14/15 14:45 7440-44-0 Surrogates RSD% 15.5 % 1 05/14/1514:45 Date: 05/18/2015 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 36 of 69 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 %c&ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040636 Pace Project No.: 92247233 Sample: 2015012121 Lab ID: 92247233007 Collected: 04/22/15 16:30 Received: 04/27/15 17:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 27700 mg/kg 52.7 26.3 10 05/06/1513:50 05/08/1515:09 7429-90-5 Barium 230 mg/kg 5.3 2.6 10 05/06/1513:50 05/08/1515:09 7440-39-3 Beryllium 1.9 mg/kg 0.53 0.26 10 05/06/1513:50 05/08/1515:09 7440-41-7 Boron 32.8 mg/kg 26.3 13.2 10 05/06/1513:50 05/08/1515:09 7440-42-8 Calcium ND mg/kg 263 132 10 05/06/1513:50 05/08/1515:09 7440-70-2 Chromium 26.3 mg/kg 2.6 1.3 10 05/06/1513:50 05/08/1515:09 7440-47-3 Copper 5.1 mg/kg 2.6 1.3 10 05/06/1513:50 05/08/1515:09 7440-50-8 Iron 32300 mg/kg 21.1 10.5 10 05/06/1513:50 05/08/1515:09 7439-89-6 Magnesium 8400 mg/kg 263 132 10 05/06/1513:50 05/08/1515:09 7439-95-4 Manganese 569 mg/kg 2.6 1.3 10 05/06/1513:50 05/08/1515:09 7439-96-5 Molybdenum ND mg/kg 5.3 2.6 10 05/06/1513:50 05/08/1515:09 7439-98-7 Nickel 25.1 mg/kg 2.6 1.3 10 05/06/1513:50 05/08/1515:09 7440-02-0 Potassium 7680 mg/kg 527 263 10 05/06/1513:50 05/08/1515:09 7440-09-7 Sodium ND mg/kg 527 263 10 05/06/1513:50 05/08/1515:09 7440-23-5 Strontium 7.2 mg/kg 5.3 2.6 10 05/06/1513:50 05/08/1515:09 7440-24-6 Zinc 149 mg/kg 10.5 5.3 10 05/06/1513:50 05/08/1515:09 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 5.3 2.6 100 05/06/1513:50 05/06/1518:37 7440-36-0 N2 Arsenic ND mg/kg 5.3 2.6 100 05/06/1513:50 05/06/1518:37 7440-38-2 Cadmium ND mg/kg 0.63 0.32 100 05/06/1513:50 05/06/1518:37 7440-43-9 Cobalt 23.5 mg/kg 5.3 2.6 100 05/06/1513:50 05/06/1518:37 7440-48-4 Lead 12.6 mg/kg 5.3 2.6 100 05/06/1513:50 05/06/1518:37 7439-92-1 Selenium 3.7J mg/kg 5.3 2.6 100 05/06/1513:50 05/06/1518:37 7782-49-2 Thallium ND mg/kg 5.3 2.6 100 05/06/1513:50 05/06/1518:37 7440-28-0 Vanadium 36.0 mg/kg 5.3 2.6 100 05/06/1513:50 05/06/1518:37 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0085 0.0042 1 05/06/1513:45 05/07/1514:27 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 3.9 % 0.10 0.10 1 05/13/15 10:31 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.5 Std. Units 0.10 0.10 1 04/29/15 14:50 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 260 130 5 05/02/15 23:22 16887-00-6 D3 Sulfate ND mg/kg 260 130 5 05/02/15 23:22 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 26.0 13.0 5 05/02/15 23:22 14797-55-8 H3 Date: 05/18/2015 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 37 of 69 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040636 Pace Project No.: 92247233 Pace Analytical Services, Inc. 9800 %'8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015012121 Lab ID: 92247233007 Collected: 04/22/15 16:30 Received: 04/27/15 17:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 629 315 1 05/15/15 15:08 7440-44-0 Total Organic Carbon ND mg/kg 620 310 1 05/15/15 15:14 7440-44-0 Total Organic Carbon ND mg/kg 620 310 1 05/15/15 15:19 7440-44-0 Total Organic Carbon ND mg/kg 627 313 1 05/15/15 15:24 7440-44-0 Mean Total Organic Carbon ND mg/kg 624 312 1 05/15/15 15:08 7440-44-0 Surrogates RSD% 1.6 % 1 05/15/1515:08 Date: 05/18/2015 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 38 of 69 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040636 Pace Project No.: 92247233 Pace Analytical Services, Inc. 9800 Iji '8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015012122 Lab ID: 92247233008 Collected: 04/22/15 16:40 Received: 04/27/15 17:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 05/18/2015 05:09 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 40100 mg/kg 30.4 15.2 5 05/06/1513:50 05/07/1512:26 7429-90-5 356 mg/kg 3.0 1.5 5 05/06/1513:50 05/07/1512:26 7440-39-3 2.0 mg/kg 0.61 0.30 10 05/06/1513:50 05/08/1515:13 7440-41-7 50.0 mg/kg 30.4 15.2 10 05/06/1513:50 05/08/1515:13 7440-42-8 169 mg/kg 152 76.0 5 05/06/1513:50 05/07/1512:26 7440-70-2 48.5 mg/kg 3.0 1.5 10 05/06/1513:50 05/08/1515:13 7440-47-3 178 mg/kg 3.0 1.5 10 05/06/1513:50 05/08/1515:13 7440-50-8 45600 mg/kg 12.2 6.1 5 05/06/1513:50 05/07/1512:26 7439-89-6 13300 mg/kg 152 76.0 5 05/06/1513:50 05/07/1512:26 7439-95-4 1020 mg/kg 3.0 1.5 10 05/06/1513:50 05/08/1515:13 7439-96-5 ND mg/kg 3.0 1.5 5 05/06/1513:50 05/07/1512:26 7439-98-7 37.4 mg/kg 1.5 0.76 5 05/06/1513:50 05/07/1512:26 7440-02-0 12200 mg/kg 304 152 5 05/06/1513:50 05/07/1512:26 7440-09-7 158J mg/kg 304 152 5 05/06/1513:50 05/07/1512:26 7440-23-5 1.6J mg/kg 3.0 1.5 5 05/06/1513:50 05/07/1512:26 7440-24-6 203 mg/kg 6.1 3.0 5 05/06/1513:50 05/07/1512:26 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 6.1 3.0 100 05/06/1513:50 05/06/1518:39 7440-36-0 ND mg/kg 6.1 3.0 100 05/06/1513:50 05/06/1518:39 7440-38-2 ND mg/kg 0.73 0.37 100 05/06/1513:50 05/06/1518:39 7440-43-9 32.3 mg/kg 6.1 3.0 100 05/06/1513:50 05/06/1518:39 7440-48-4 21.6 mg/kg 6.1 3.0 100 05/06/1513:50 05/06/1518:39 7439-92-1 3.9J mg/kg 6.1 3.0 100 05/06/1513:50 05/06/1518:39 7782-49-2 ND mg/kg 6.1 3.0 100 05/06/1513:50 05/06/1518:39 7440-28-0 50.3 mg/kg 6.1 3.0 100 05/06/1513:50 05/06/1518:39 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.0092 0.0046 1 05/06/1513:45 05/07/1514:29 7439-97-6 Analytical Method: ASTM D2974-87 16.3 % 0.10 0.10 1 05/13/1510:31 Analytical Method: EPA 9045 5.8 Std. Units 0.10 0.10 1 04/29/15 14:50 N2 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/30/15 04:20 3.5 mg/L 2.4 1.2 1 05/07/1514:09 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/30/15 04:20 0.24 mg/L 0.24 0.24 1 05/13/1513:36 H1 Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 04/30/15 04:20 ND mg/L 6.0 3.0 1 05/09/15 03:42 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 39 of 69 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 1jiT'8yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040636 Pace Project No.: 92247233 Sample: 2015012122 Lab ID: 92247233008 Collected: 04/22/15 16:40 Received: 04/27/15 17:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 298 149 5 05/02/15 23:44 16887-00-6 D3 Sulfate ND mg/kg 298 149 5 05/02/15 23:44 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 29.8 14.9 5 05/02/15 23:44 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 718 359 1 05/15/15 16:16 7440-44-0 Total Organic Carbon ND mg/kg 712 356 1 05/15/15 16:22 7440-44-0 Total Organic Carbon ND mg/kg 716 358 1 05/15/15 16:27 7440-44-0 Total Organic Carbon ND mg/kg 716 358 1 05/15/15 16:34 7440-44-0 Mean Total Organic Carbon ND mg/kg 716 358 1 05/15/15 16:16 7440-44-0 Surrogates RSD% 3.2 % 1 05/15/1516:16 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 40 of 69 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040636 Pace Project No.: 92247233 Pace Analytical Services, Inc. 9800 IjiQ%yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015012122 SPLP Lab ID: 92247233009 Collected: 04/22/15 16:40 Received: 04/27/15 17:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 05/18/2015 05:09 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 27.4 ug/L 10.0 3.0 1 05/14/15 07:47 05/14/15 21:02 7429-90-5 ND ug/L 0.50 0.15 1 05/14/15 07:47 05/14/15 21:02 7440-36-0 ND ug/L 0.50 0.11 1 05/14/15 07:47 05/14/15 21:02 7440-38-2 75.9 ug/L 0.30 0.081 1 05/14/15 07:47 05/14/15 21:02 7440-39-3 ND ug/L 0.20 0.067 1 05/14/15 07:47 05/14/15 21:02 7440-41-7 36.1 ug/L 5.0 1.1 1 05/14/15 07:47 05/14/15 21:02 7440-42-8 ND ug/L 0.080 0.024 1 05/14/15 07:47 05/14/15 21:02 7440-43-9 169 ug/L 40.0 16.0 1 05/14/15 07:47 05/14/15 21:02 7440-70-2 0.27J ug/L 0.50 0.17 1 05/14/15 07:47 05/14/15 21:02 7440-47-3 0.82 ug/L 0.50 0.13 1 05/14/15 07:47 05/14/15 21:02 7440-48-4 2.7 ug/L 1.0 0.21 1 05/14/15 07:47 05/14/15 21:02 7440-50-8 16.1J ug/L 50.0 13.7 1 05/14/15 07:47 05/14/15 21:02 7439-89-6 0.14 ug/L 0.10 0.046 1 05/14/15 07:47 05/14/15 21:02 7439-92-1 83.0 ug/L 10.0 3.2 1 05/14/15 07:47 05/14/15 21:02 7439-95-4 37.4 ug/L 0.50 0.24 1 05/14/15 07:47 05/14/15 21:02 7439-96-5 ND ug/L 0.50 0.094 1 05/14/15 07:47 05/14/15 21:02 7439-98-7 0.32J ug/L 0.50 0.16 1 05/14/15 07:47 05/14/15 21:02 7440-02-0 140 ug/L 50.0 11.7 1 05/14/15 07:47 05/14/15 21:02 7440-09-7 ND ug/L 0.50 0.20 1 05/14/15 07:47 05/14/15 21:02 7782-49-2 1220 ug/L 50.0 16.3 1 05/14/15 07:47 05/14/15 21:02 7440-23-5 2.6 ug/L 0.50 0.13 1 05/14/15 07:47 05/14/15 21:02 7440-24-6 ND ug/L 0.10 0.015 1 05/14/15 07:47 05/14/15 21:02 7440-28-0 ND ug/L 1.0 0.28 1 05/14/15 07:47 05/14/15 21:02 7440-62-2 30.4 ug/L 5.0 2.4 1 05/14/15 07:47 05/14/15 21:02 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 05/14/15 11:05 05/14/15 21:44 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 41 of 69 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 I S'8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040636 Pace Project No.: 92247233 Sample: 2015012123 Lab ID: 92247233010 Collected: 04/22/15 16:50 Received: 04/27/15 17:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 28300 mg/kg 27.6 13.8 5 05/06/1513:50 05/07/1512:31 7429-90-5 Barium 232 mg/kg 2.8 1.4 5 05/06/1513:50 05/07/1512:31 7440-39-3 Beryllium 1.5 mg/kg 0.28 0.14 5 05/06/1513:50 05/07/1512:31 7440-41-7 Boron 31.5 mg/kg 13.8 6.9 5 05/06/1513:50 05/07/1512:31 7440-42-8 Calcium 218 mg/kg 138 68.9 5 05/06/1513:50 05/07/1512:31 7440-70-2 Chromium 34.1 mg/kg 1.4 0.69 5 05/06/1513:50 05/07/1512:31 7440-47-3 Copper 9.1 mg/kg 1.4 0.69 5 05/06/1513:50 05/07/1512:31 7440-50-8 Iron 36400 mg/kg 11.0 5.5 5 05/06/1513:50 05/07/1512:31 7439-89-6 Magnesium 11700 mg/kg 138 68.9 5 05/06/1513:50 05/07/1512:31 7439-95-4 Manganese 570 mg/kg 1.4 0.69 5 05/06/1513:50 05/07/1512:31 7439-96-5 Molybdenum ND mg/kg 2.8 1.4 5 05/06/1513:50 05/07/1512:31 7439-98-7 Nickel 33.3 mg/kg 1.4 0.69 5 05/06/1513:50 05/07/1512:31 7440-02-0 Potassium 10300 mg/kg 276 138 5 05/06/1513:50 05/07/1512:31 7440-09-7 Sodium ND mg/kg 276 138 5 05/06/1513:50 05/07/1512:31 7440-23-5 Strontium 10.1 mg/kg 2.8 1.4 5 05/06/1513:50 05/07/1512:31 7440-24-6 Zinc 130 mg/kg 5.5 2.8 5 05/06/1513:50 05/07/1512:31 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 5.5 2.8 100 05/06/1513:50 05/06/1518:42 7440-36-0 N2 Arsenic ND mg/kg 5.5 2.8 100 05/06/1513:50 05/06/1518:42 7440-38-2 Cadmium ND mg/kg 0.66 0.33 100 05/06/1513:50 05/06/1518:42 7440-43-9 Cobalt 22.9 mg/kg 5.5 2.8 100 05/06/1513:50 05/06/1518:42 7440-48-4 Lead 6.3 mg/kg 5.5 2.8 100 05/06/1513:50 05/06/1518:42 7439-92-1 Selenium 2.8J mg/kg 5.5 2.8 100 05/06/1513:50 05/06/1518:42 7782-49-2 Thallium ND mg/kg 5.5 2.8 100 05/06/1513:50 05/06/1518:42 7440-28-0 Vanadium 31.7 mg/kg 5.5 2.8 100 05/06/1513:50 05/06/1518:42 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.0083 0.0042 1 05/06/1513:45 05/07/1514:32 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 5.0 % 0.10 0.10 1 05/13/15 10:31 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.3 Std. Units 0.10 0.10 1 04/29/15 14:50 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 262 131 5 05/03/15 00:48 16887-00-6 D3 Sulfate ND mg/kg 262 131 5 05/03/15 00:48 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 26.2 13.1 5 05/03/15 00:48 14797-55-8 H3 Date: 05/18/2015 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 42 of 69 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040636 Pace Project No.: 92247233 Pace Analytical Services, Inc. 9800 14'8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015012123 Lab ID: 92247233010 Collected: 04/22/15 16:50 Received: 04/27/15 17:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 634 317 1 05/15/15 16:40 7440-44-0 Total Organic Carbon ND mg/kg 635 318 1 05/15/15 16:46 7440-44-0 Total Organic Carbon ND mg/kg 637 319 1 05/15/15 16:52 7440-44-0 Total Organic Carbon ND mg/kg 635 318 1 05/15/15 16:58 7440-44-0 Mean Total Organic Carbon ND mg/kg 635 318 1 05/15/15 16:40 7440-44-0 Surrogates RSD% 3.2 % 1 05/15/1516:40 Date: 05/18/2015 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 43 of 69 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Ijigc&y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040636 Pace Project No.: 92247233 QC Batch: MERP/13401 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92247233001 METHOD BLANK: 1953012 Matrix: Water Associated Lab Samples: 92247233001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 05/04/1516:06 LABORATORY CONTROL SAMPLE: 1953013 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.0 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1953014 1953015 MS MSD 92247233001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.1 5.1 103 102 80-120 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 44 of 69 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 16,8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040636 Pace Project No.: 92247233 QC Batch: MERP/13538 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92247233003, 92247233009 METHOD BLANK: 1965167 Matrix: Water Associated Lab Samples: 92247233003, 92247233009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 05/14/15 21:03 LABORATORY CONTROL SAMPLE: 1965168 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.7 94 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1965262 1965263 MS MSD 10306022003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 4.7 4.8 93 95 80-120 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 45 of 69 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Ijc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040636 Pace Project No.: 92247233 QC Batch: MERP/5678 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92247233002,92247233004,92247233005,92247233006,92247233007,92247233008,92247233010 METHOD BLANK: 1203118 Matrix: Solid Associated Lab Samples: 92247233002, 92247233004, 92247233005, 92247233006, 92247233007, 92247233008, 92247233010 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0081 05/07/1513:36 LABORATORY CONTROL SAMPLE: 1203119 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .077 0.083 108 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1203120 1203121 MS MSD 92247232001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 0.036 .185 .194 0.18 0.16 78 65 80-120 11 20 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 46 of 69 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040636 Pace Project No.: 92247233 Pace Analytical Services, Inc. 9800 Ijgc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: MPRP/23950 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92247233002, 92247233004, 92247233005, 92247233006, 92247233007, 92247233008, 92247233010 METHOD BLANK: 1203098 Matrix: Solid Associated Lab Samples: 92247233002, 92247233004, 92247233005, 92247233006, 92247233007, 92247233008, 92247233010 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Aluminum mg/kg ND 5.0 05/07/1512:04 Barium mg/kg ND 0.50 05/07/1512:04 Beryllium mg/kg ND 0.050 05/07/1512:04 Boron mg/kg ND 2.5 05/07/1512:04 Calcium mg/kg ND 25.1 05/07/1512:04 Chromium mg/kg ND 0.25 05/07/1512:04 Copper mg/kg ND 0.25 05/07/1512:04 Iron mg/kg ND 2.0 05/07/1512:04 Magnesium mg/kg ND 25.1 05/07/1512:04 Manganese mg/kg 0.20J 0.25 05/07/1512:04 P8 Molybdenum mg/kg ND 0.50 05/07/1512:04 Nickel mg/kg ND 0.25 05/07/1512:04 Potassium mg/kg ND 50.3 05/07/1512:04 Sodium mg/kg ND 50.3 05/07/1512:04 Strontium mg/kg ND 0.50 05/07/1512:04 Zinc mg/kg ND 1.0 05/07/1512:04 LABORATORY CONTROL SAMPLE: Parameter 1203099 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum mg/kg 122 127 104 80-120 Barium mg/kg 12.2 12.5 102 80-120 Beryllium mg/kg 1.2 1.3 103 80-120 Boron mg/kg 122 124 101 80-120 Calcium mg/kg 611 637 104 80-120 Chromium mg/kg 12.2 12.2 100 80-120 Copper mg/kg 12.2 12.2 100 80-120 Iron mg/kg 122 121 99 80-120 Magnesium mg/kg 611 623 102 80-120 Manganese mg/kg 12.2 12.8 105 80-120 Molybdenum mg/kg 12.2 11.8 96 80-120 Nickel mg/kg 12.2 12.3 100 80-120 Potassium mg/kg 611 591 97 80-120 Sodium mg/kg 611 645 106 80-120 Strontium mg/kg 12.2 12.2 100 80-120 Zinc mg/kg 61.1 61.9 101 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 47 of 69 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Iji %Yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040636 Pace Project No.: 92247233 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1203100 1203101 MS MSD 92247232001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 8980 303 296 12500 12400 1160 1160 75-125 1 20 M1 Barium mg/kg 31.5 30.3 29.6 62.1 69.1 101 128 75-125 11 20 M1 Beryllium mg/kg ND 3.08 2.84 3.1 2.9 96 94 75-125 4 20 Boron mg/kg 43.1 303 296 330 331 95 98 75-125 1 20 Calcium mg/kg 4920 1510 1470 6580 8370 110 234 75-125 24 20 M1,R1 Chromium mg/kg 11.3 30.3 29.6 41.6 39.8 100 97 75-125 4 20 Copper mg/kg 3.9 30.3 29.6 32.7 32.1 95 96 75-125 2 20 Iron mg/kg 14000 303 296 13000 14900 -324 308 75-125 14 20 M1 Magnesium mg/kg 313 1510 1470 1890 1880 104 106 75-125 1 20 Manganese mg/kg 102 30.3 29.6 135 143 108 138 75-125 6 20 M1 Molybdenum mg/kg 168 30.3 29.6 282 196 379 98 75-125 36 20 M1,R1 Nickel mg/kg 2.6J 30.3 29.6 35.2 32.4 108 101 75-125 8 20 Potassium mg/kg ND 1510 1470 1590 1520 97 94 75-125 5 20 Sodium mg/kg ND 1510 1470 1720 1650 100 98 75-125 4 20 Strontium mg/kg 195 30.3 29.6 226 291 101 325 75-125 25 20 M1,R1 Zinc mg/kg ND 151 147 158 149 101 98 75-125 6 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 48 of 69 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040636 Pace Project No.: 92247233 Pace Analytical Services, Inc. 9800 t 6,8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: MPRP/23951 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92247233002, 92247233004, 92247233005, 92247233006, 92247233007, 92247233008, 92247233010 METHOD BLANK: 1203102 Matrix: Solid Associated Lab Samples: 92247233002, 92247233004, 92247233005, 92247233006, 92247233007, 92247233008, 92247233010 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.049 05/06/1517:35 N2 Arsenic mg/kg ND 0.049 05/06/1517:35 Cadmium mg/kg ND 0.0059 05/06/1517:35 Cobalt mg/kg ND 0.049 05/06/1517:35 Lead mg/kg ND 0.049 05/06/1517:35 Selenium mg/kg ND 0.049 05/06/1517:35 Thallium mg/kg ND 0.049 05/06/1517:35 Vanadium mg/kg ND 0.049 05/06/1517:35 LABORATORY CONTROL SAMPLE: 1203103 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony mg/kg 2.6 2.7 105 80-120 N2 Arsenic mg/kg 2.6 2.7 104 80-120 Cadmium mg/kg .26 0.25 99 80-120 Cobalt mg/kg 2.6 2.7 105 80-120 Lead mg/kg 2.6 2.6 103 80-120 Selenium mg/kg 2.6 2.8 108 80-120 Thallium mg/kg 2.6 2.7 104 80-120 Vanadium mg/kg 2.6 2.7 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1203104 1203105 MS MSD 92247232001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 5.68 6.15 ND ND 77 76 75-125 20 N2 Arsenic mg/kg 613 5.68 6.15 576 605 -646 -129 75-125 5 20 M6 Cadmium mg/kg ND .568 .615 0.85J 0.79J 111 94 75-125 20 Cobalt mg/kg ND 5.68 6.15 8.8J 9.51 103 106 75-125 20 Lead mg/kg 7.3J 5.68 6.15 13.1 15.2 101 127 75-125 15 20 M6 Selenium mg/kg ND 5.68 6.15 6.2J ND 55 49 75-125 20 M6 Thallium mg/kg ND 5.68 6.15 5.81 6AJ 70 73 75-125 20 M6 Vanadium mg/kg 23.4 5.68 6.15 27.2 30.0 66 106 75-125 10 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 49 of 69 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040636 Pace Project No.: 92247233 QC Batch: MPRP/54062 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92247233001 METHOD BLANK: 1953028 Associated Lab Samples: 92247233001 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed Qualifiers Aluminum ug/L 3.1J 10.0 05/05/1513:47 Antimony ug/L ND 0.50 05/05/1513:47 Arsenic ug/L ND 0.50 05/05/1513:47 Barium ug/L ND 0.30 05/05/1513:47 Beryllium ug/L ND 0.20 05/05/1513:47 Boron ug/L ND 5.0 05/05/1513:47 Cadmium ug/L ND 0.080 05/05/1513:47 Calcium ug/L ND 40.0 05/05/1513:47 Chromium ug/L ND 0.50 05/05/1513:47 Cobalt ug/L ND 0.50 05/05/1513:47 Copper ug/L 0.28J 1.0 05/05/1513:47 Iron ug/L ND 50.0 05/05/1513:47 Lead ug/L ND 0.10 05/05/1513:47 Magnesium ug/L 3.6J 10.0 05/05/1513:47 Manganese ug/L 0.24J 0.50 05/05/1513:47 Molybdenum ug/L ND 0.50 05/05/1513:47 Nickel ug/L ND 0.50 05/05/1513:47 Potassium ug/L ND 50.0 05/05/1513:47 Selenium ug/L ND 0.50 05/05/1513:47 Sodium ug/L ND 50.0 05/05/1513:47 Strontium ug/L ND 0.50 05/05/1513:47 Thallium ug/L ND 0.10 05/05/1513:47 Vanadium ug/L ND 1.0 05/05/1513:47 Zinc ug/L ND 5.0 05/05/1513:47 Pace Analytical Services, Inc. 9800 �T igyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1953029 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 80.3 100 80-120 Antimony ug/L 80 78.2 98 80-120 Arsenic ug/L 80 79.4 99 80-120 Barium ug/L 80 78.9 99 80-120 Beryllium ug/L 80 81.2 102 80-120 Boron ug/L 80 80.1 100 80-120 Cadmium ug/L 80 78.8 98 80-120 Calcium ug/L 1000 930 93 80-120 Chromium ug/L 80 83.9 105 80-120 Cobalt ug/L 80 79.0 99 80-120 Copper ug/L 80 82.7 103 80-120 Iron ug/L 1000 1020 102 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 50 of 69 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 �Q%yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040636 Pace Project No.: 92247233 LABORATORY CONTROL SAMPLE: 1953029 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 82.0 103 80-120 Magnesium ug/L 1000 1020 102 80-120 Manganese ug/L 80 79.0 99 80-120 Molybdenum ug/L 80 78.6 98 80-120 Nickel ug/L 80 81.0 101 80-120 Potassium ug/L 1000 1020 102 80-120 Selenium ug/L 80 79.3 99 80-120 Sodium ug/L 1000 981 98 80-120 Strontium ug/L 80 77.8 97 80-120 Thallium ug/L 80 80.2 100 80-120 Vanadium ug/L 80 82.4 103 80-120 Zinc ug/L 80 80.6 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1953030 1953031 MS MSD 92247374001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 1340 80 80 1490 1720 192 478 75-125 14 20 M1 Antimony ug/L ND 80 80 79.8 77.2 100 96 75-125 3 20 Arsenic ug/L 0.91 80 80 80.0 78.2 99 97 75-125 2 20 Barium ug/L 47.7 80 80 125 123 97 94 75-125 2 20 Beryllium ug/L 0.22 80 80 81.4 79.0 101 99 75-125 3 20 Boron ug/L 1.51 80 80 83.1 81.7 102 100 75-125 2 20 Cadmium ug/L 0.25 80 80 78.7 77.1 98 96 75-125 2 20 Calcium ug/L 3950 1000 1000 4870 4760 92 81 75-125 2 20 Chromium ug/L 1.8 80 80 84.9 83.9 104 103 75-125 1 20 Cobalt ug/L 7.4 80 80 85.6 83.9 98 96 75-125 2 20 Copper ug/L 35.4 80 80 118 115 103 99 75-125 3 20 Iron ug/L 1040 1000 1000 2040 2180 101 115 75-125 6 20 Lead ug/L 53.8 80 80 135 132 101 98 75-125 2 20 Magnesium ug/L 1040 1000 1000 2050 2010 101 97 75-125 2 20 Manganese ug/L 229 80 80 306 298 96 86 75-125 3 20 Molybdenum ug/L ND 80 80 78.9 76.5 99 96 75-125 3 20 Nickel ug/L 3.1 80 80 84.4 81.6 102 98 75-125 3 20 Potassium ug/L 554 1000 1000 1540 1540 99 98 75-125 0 20 Selenium ug/L 1.3 80 80 80.6 76.9 99 94 75-125 5 20 Sodium ug/L 139 1000 1000 1120 1090 98 95 75-125 3 20 Strontium ug/L 9.0 80 80 86.6 84.5 97 94 75-125 2 20 Thallium ug/L 0.046J 80 80 82.6 81.5 103 102 75-125 1 20 Vanadium ug/L 3.7 80 80 85.6 84.8 102 101 75-125 1 20 Zinc ug/L 41.7 80 80 122 120 100 98 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 51 of 69 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040636 Pace Project No.: 92247233 QC Batch: MPRP/54343 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92247233003, 92247233009 METHOD BLANK: 1963685 Associated Lab Samples: 92247233003, 92247233009 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 05/15/1513:22 ND 0.50 05/14/15 20:15 ND 0.50 05/14/15 20:15 ND 0.30 05/14/15 20:15 ND 0.20 05/14/15 20:15 1.8J 5.0 05/14/15 20:15 ND 0.080 05/14/15 20:15 ND 40.0 05/14/15 20:15 ND 0.50 05/14/15 20:15 ND 0.50 05/14/15 20:15 ND 1.0 05/14/15 20:15 ND 50.0 05/14/15 20:15 ND 0.10 05/14/15 20:15 ND 10.0 05/14/15 20:15 ND 0.50 05/14/15 20:15 ND 0.50 05/14/15 20:15 ND 0.50 05/14/15 20:15 ND 50.0 05/14/15 20:15 ND 0.50 05/14/15 20:15 ND 50.0 05/14/15 20:15 ND 0.50 05/14/15 20:15 ND 0.10 05/14/15 20:15 ND 1.0 05/14/15 20:15 ND 5.0 05/14/15 20:15 Qualifiers Pace Analytical Services, Inc. 9800 t S igy ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1963686 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 81.6 102 80-120 Antimony ug/L 80 75.9 95 80-120 Arsenic ug/L 80 80.1 100 80-120 Barium ug/L 80 85.2 106 80-120 Beryllium ug/L 80 77.7 97 80-120 Boron ug/L 80 78.7 98 80-120 Cadmium ug/L 80 84.0 105 80-120 Calcium ug/L 1000 1020 102 80-120 Chromium ug/L 80 83.0 104 80-120 Cobalt ug/L 80 81.5 102 80-120 Copper ug/L 80 84.6 106 80-120 Iron ug/L 1000 1030 103 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 52 of 69 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 t 4,8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040636 Pace Project No.: 92247233 LABORATORY CONTROL SAMPLE: 1963686 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 83.9 105 80-120 Magnesium ug/L 1000 934 93 80-120 Manganese ug/L 80 79.9 100 80-120 Molybdenum ug/L 80 81.5 102 80-120 Nickel ug/L 80 81.8 102 80-120 Potassium ug/L 1000 950 95 80-120 Selenium ug/L 80 79.8 100 80-120 Sodium ug/L 1000 1010 101 80-120 Strontium ug/L 80 77.1 96 80-120 Thallium ug/L 80 89.1 111 80-120 Vanadium ug/L 80 81.0 101 80-120 Zinc ug/L 80 83.8 105 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1963687 1963688 MS MSD 92249101001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 643 80 80 1200 1210 694 713 75-125 1 20 M1 Antimony ug/L ND 80 80 76.8 77.4 96 97 75-125 1 20 Arsenic ug/L 0.60 80 80 82.3 83.8 102 104 75-125 2 20 Barium ug/L 11.3 80 80 92.0 91.9 101 101 75-125 0 20 Beryllium ug/L ND 80 80 79.8 82.8 100 104 75-125 4 20 Boron ug/L 2.2J 80 80 82.5 86.0 100 105 75-125 4 20 Cadmium ug/L ND 80 80 85.9 85.7 107 107 75-125 0 20 Calcium ug/L 1150 1000 1000 2170 2050 102 90 75-125 6 20 Chromium ug/L 3.5 80 80 86.1 86.1 103 103 75-125 0 20 Cobalt ug/L 0.65 80 80 82.6 82.3 102 102 75-125 0 20 Copper ug/L 2.5 80 80 88.3 88.0 107 107 75-125 0 20 Iron ug/L 2690 1000 1000 3780 3740 109 105 75-125 1 20 Lead ug/L 0.44 80 80 81.6 82.0 101 102 75-125 0 20 Magnesium ug/L 214 1000 1000 1160 1150 94 94 75-125 0 20 Manganese ug/L 37.8 80 80 117 116 99 98 75-125 0 20 Molybdenum ug/L 2.4 80 80 85.3 84.7 104 103 75-125 1 20 Nickel ug/L 3.2 80 80 85.1 85.7 102 103 75-125 1 20 Potassium ug/L 468 1000 1000 1350 1390 89 92 75-125 2 20 Selenium ug/L 0.32J 80 80 81.1 83.4 101 104 75-125 3 20 Sodium ug/L 364 1000 1000 1370 1390 101 103 75-125 1 20 Strontium ug/L 4.4 80 80 84.6 85.0 100 101 75-125 0 20 Thallium ug/L 0.018J 80 80 87.1 88.1 109 110 75-125 1 20 Vanadium ug/L 2.5 80 80 83.5 82.9 101 100 75-125 1 20 Zinc ug/L 4.5J 80 80 87.6 89.1 104 106 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 53 of 69 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 �g%yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040636 Pace Project No.: 92247233 QC Batch: PMST/3554 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92247233002,92247233004,92247233005,92247233006,92247233007,92247233008,92247233010 SAMPLE DUPLICATE: 1211608 35185823001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 82.0 76.6 7 10 SAMPLE DUPLICATE: 1211609 92247383010 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 16.8 18.9 12 10 D6 SAMPLE DUPLICATE: 1211610 92247834001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 56.4 56.6 0 10 SAMPLE DUPLICATE: 1211611 92247835014 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 35.2 33.3 6 10 SAMPLE DUPLICATE: 1211612 92247827006 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 12.5 13.5 7 10 SAMPLE DUPLICATE: 1211613 35187206001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 65.0 68.0 5 10 SAMPLE DUPLICATE: 1211614 92248416004 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 24.5 23.9 3 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 54 of 69 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 t 6,8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040636 Pace Project No.: 92247233 SAMPLE DUPLICATE: 1211615 92248416014 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 12.6 11.6 9 10 SAMPLE DUPLICATE: 1211616 92248424009 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 18.7 18.7 0 10 SAMPLE DUPLICATE: 1211617 92248424020 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 38.9 38.8 0 10 SAMPLE DUPLICATE: 1211618 35187430003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 25.1 27.5 9 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 55 of 69 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040636 Pace Project No.: 92247233 Pace Analytical Services, Inc. 9800 ",8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: WET/37120 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92247233002,92247233004,92247233005,92247233006,92247233007,92247233008,92247233010 SAMPLE DUPLICATE: 1445734 92246794001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 8.4 8.3 0 10 SAMPLE DUPLICATE: 1445735 92247232003 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.9 7.0 1 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 56 of 69 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 �gc&y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040636 Pace Project No.: 92247233 QC Batch: WETA/22837 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92247233002, 92247233008 METHOD BLANK: 1452663 Matrix: Water Associated Lab Samples: 92247233002, 92247233008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L 4.0 2.0 05/07/1511:13 LABORATORY CONTROL SAMPLE: 1452664 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 20.0 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1452665 1452666 MS MSD 92247080002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 11.4 22.5 22.5 34.3 34.4 102 102 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 57 of 69 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040636 Pace Project No.: 92247233 QC Batch: WETA/22905 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92247233002, 92247233008 METHOD BLANK: 1457411 Matrix: Water Associated Lab Samples: 92247233002, 92247233008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.16 0.020 05/13/15 13:14 Z2 LABORATORY CONTROL SAMPLE: 1457412 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.5 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1457413 1457414 MS MSD 92247080002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 0.23 2.8 2.8 3.1 3.1 103 103 90-110 1 10 H1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1457545 1457546 MS MSD 92247233008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L 0.24 3 3 3.3 3.3 103 104 90-110 0 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 58 of 69 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 t 6,8y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040636 Pace Project No.: 92247233 QC Batch: WETA/22862 Analysis Method: SM 4500 -CI -E QC Batch Method: SM 4500 -CI -E Analysis Description: 4500 Chloride Associated Lab Samples: 92247233002, 92247233008 METHOD BLANK: 1454397 Matrix: Water Associated Lab Samples: 92247233002, 92247233008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 05/09/15 03:31 LABORATORY CONTROL SAMPLE: 1454398 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.2 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1454399 1454400 MS MSD 92245627014 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 27.5 27.5 29.0 28.7 103 103 90-110 1 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1454401 1454402 MS MSD 92247233008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 23.9 23.9 24.8 24.6 101 100 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 59 of 69 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040636 Pace Project No.: 92247233 Pace Analytical Services, Inc. 9800 �T igyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: WETA/46021 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92247233002,92247233004,92247233005,92247233006,92247233007,92247233008,92247233010 METHOD BLANK: 1202076 1202077 Matrix: Solid Units Associated Lab Samples: mg/kg Sulfate mg/kg Blank Reporting 1202079 Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.8 05/02/1519:05 Sulfate mg/kg ND 49.8 05/02/1519:05 LABORATORY CONTROL SAMPLE: 1202077 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1202079 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1202078 Parameter Chloride Sulfate Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 499 486 97 80-120 499 481 96 80-120 92247232001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 1180 1160 79 80-120 M1 449J 1180 1440 84 80-120 92247232001 Dup Units Result Result mg/kg ND ND mg/kg 449J 428J Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 60 of 69 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 t Q igy ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040636 Pace Project No.: 92247233 QC Batch: WETA/46020 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92247233002,92247233004,92247233005,92247233006,92247233007,92247233008,92247233010 METHOD BLANK: 1202072 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 05/02/15 19:05 LABORATORY CONTROL SAMPLE: 1202073 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 49.9 49.0 98 80-120 MATRIX SPIKE SAMPLE: 1202075 92247232001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 118 111 94 80-120 H3 SAMPLE DUPLICATE: 1202074 92247232001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 61 of 69 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040636 Pace Project No.: 92247233 QC Batch: WETA/28457 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92247233002, 92247233004, 92247233005, 92247233006 METHOD BLANK: 1155940 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 05/14/15 07:20 LABORATORY CONTROL SAMPLE: 1155941 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 118000 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1155942 1155943 MS MSD 92247068001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg ND 8580 8510 8380 7830 94 89 50-150 7 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1155944 1155945 MS MSD 92247080001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 932 6990 6960 7150 7530 89 95 50-150 5 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 62 of 69 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040636 Pace Project No.: 92247233 QC Batch: WETA/28497 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92247233007, 92247233008, 92247233010 METHOD BLANK: 1157782 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 05/15/15 14:22 LABORATORY CONTROL SAMPLE: 1157783 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 127000 106 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1157784 1157785 MS MSD 92247233007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg ND 6250 6260 6250 6450 96 99 50-150 3 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 63 of 69 aceAnaiXical www.pacelabs.com QUALIFIERS Project: J15040636 Pace Project No.: 92247233 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. Pace Analytical Services, Inc. 9800 �gc&y ft.. Suite 100 Huntersville, NC 28078 (704)875-9092 RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICP/14654 [1] Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TNI accreditation for this parameter. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 64 of 69 Pace Analytical Services, Inc aceAnalXical ® 9800 t��c&rrfte. Suite 100 Huntersville, INC 28078 www.pacelabs.com (704)875-9092 QUALIFIERS Project: J15040636 Pace Project No.: 92247233 ANALYTE QUALIFIERS P8 Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. R1 RPD value was outside control limits. Z2 Analyte present in the associated method blank above the detection limit. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 65 of 69 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, Inc. 9800 ",8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040636 Pace Project No.: 92247233 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92247233002 2015012117 EPA 3050 MPRP/23950 EPA 6010 ICP/14654 92247233004 2015012118 EPA 3050 MPRP/23950 EPA 6010 ICP/14654 92247233005 2015012119 EPA 3050 MPRP/23950 EPA 6010 ICP/14654 92247233006 2015012120 EPA 3050 MPRP/23950 EPA 6010 ICP/14654 92247233007 2015012121 EPA 3050 MPRP/23950 EPA 6010 ICP/14654 92247233008 2015012122 EPA 3050 MPRP/23950 EPA6010 ICP/14654 92247233010 2015012123 EPA 3050 MPRP/23950 EPA 6010 ICP/14654 92247233002 2015012117 EPA 3050 MPRP/23951 EPA 6020 ICPM/9732 92247233004 2015012118 EPA 3050 MPRP/23951 EPA 6020 ICPM/9732 92247233005 2015012119 EPA 3050 MPRP/23951 EPA 6020 ICPM/9732 92247233006 2015012120 EPA 3050 MPRP/23951 EPA 6020 ICPM/9732 92247233007 2015012121 EPA 3050 MPRP/23951 EPA 6020 ICPM/9732 92247233008 2015012122 EPA 3050 MPRP/23951 EPA 6020 ICPM/9732 92247233010 2015012123 EPA 3050 MPRP/23951 EPA 6020 ICPM/9732 92247233001 2015012116 EPA 3020 MPRP/54062 EPA 6020A ICPM/24072 92247233003 2015012117 SPLP EPA 3020 MPRP/54343 EPA 6020A ICPM/24273 92247233009 2015012122 SPLP EPA 3020 MPRP/54343 EPA 6020A ICPM/24273 92247233001 2015012116 EPA 7470A MERP/13401 EPA 7470A MERC/15595 92247233003 2015012117 SPLP EPA 7470A MERP/13538 EPA 7470A MERC/15723 92247233009 2015012122 SPLP EPA 7470A MERP/13538 EPA 7470A MERC/15723 92247233002 2015012117 EPA 7471 MERP/5678 EPA 7471 MERC/5668 92247233004 2015012118 EPA 7471 MERP/5678 EPA 7471 MERC/5668 92247233005 2015012119 EPA 7471 MERP/5678 EPA 7471 MERC/5668 92247233006 2015012120 EPA 7471 MERP/5678 EPA 7471 MERC/5668 92247233007 2015012121 EPA 7471 MERP/5678 EPA 7471 MERC/5668 92247233008 2015012122 EPA 7471 MERP/5678 EPA 7471 MERC/5668 92247233010 2015012123 EPA 7471 MERP/5678 EPA 7471 MERC/5668 92247233002 2015012117 ASTM D2974-87 PMST/3554 92247233004 2015012118 ASTM D2974-87 PMST/3554 92247233005 2015012119 ASTM D2974-87 PMST/3554 92247233006 2015012120 ASTM D2974-87 PMST/3554 92247233007 2015012121 ASTM D2974-87 PMST/3554 92247233008 2015012122 ASTM D2974-87 PMST/3554 92247233010 2015012123 ASTM D2974-87 PMST/3554 92247233002 2015012117 EPA 9045 WET/37120 92247233004 2015012118 EPA 9045 WET/37120 92247233005 2015012119 EPA 9045 WET/37120 92247233006 2015012120 EPA 9045 WET/37120 92247233007 2015012121 EPA 9045 WET/37120 92247233008 2015012122 EPA 9045 WET/37120 92247233010 2015012123 EPA 9045 WET/37120 92247233002 2015012117 EPA 300.0 WETA/22837 92247233008 2015012122 EPA 300.0 WETA/22837 92247233002 2015012117 EPA 353.2 WETA/22905 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/18/2015 05:09 PM without the written consent of Pace Analytical Services, Inc.. Page 66 of 69 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15040636 Pace Project No.: 92247233 Lab ID Sample ID QC Batch Method QC Batch 92247233008 2015012122 EPA 353.2 WETA/22905 92247233002 2015012117 SM 4500 -CI -E WETA/22862 92247233008 2015012122 SM 4500 -CI -E WETA/22862 92247233002 2015012117 EPA 9056 WETA/46021 92247233004 2015012118 EPA 9056 WETA/46021 92247233005 2015012119 EPA 9056 WETA/46021 92247233006 2015012120 EPA 9056 WETA/46021 92247233007 2015012121 EPA 9056 WETA/46021 92247233008 2015012122 EPA 9056 WETA/46021 92247233010 2015012123 EPA 9056 WETA/46021 92247233002 2015012117 EPA 9056 WETA/46020 92247233004 2015012118 EPA 9056 WETA/46020 92247233005 2015012119 EPA 9056 WETA/46020 92247233006 2015012120 EPA 9056 WETA/46020 92247233007 2015012121 EPA 9056 WETA/46020 92247233008 2015012122 EPA 9056 WETA/46020 92247233010 2015012123 EPA 9056 WETA/46020 92247233002 2015012117 EPA 9060 WETA/28457 92247233002 2015012117 EPA 9060 WETA/28458 92247233004 2015012118 EPA 9060 WETA/28457 92247233004 2015012118 EPA 9060 WETA/28458 92247233005 2015012119 EPA 9060 WETA/28457 92247233005 2015012119 EPA 9060 WETA/28458 92247233006 2015012120 EPA 9060 WETA/28457 92247233006 2015012120 EPA 9060 WETA/28458 92247233007 2015012121 EPA 9060 WETA/28497 92247233007 2015012121 EPA 9060 WETA/28498 92247233008 2015012122 EPA 9060 WETA/28497 92247233008 2015012122 EPA 9060 WETA/28498 92247233010 2015012123 EPA 9060 WETA/28497 92247233010 2015012123 EPA 9060 WETA/28498 Date: 05/18/2015 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 %'8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Analytical Method Analytical Batch Page 67 of 69 �ce�zfy�fcaTa �761I11 !G VVINf�tV.■ ■+ r+■■ ■�•■■-• Document Number; F-CHR-CS-003-rev°1 int Name: er: ❑ Fed Ex ❑ UPS® IJSP0"CiZ"'S Commercial[] 6c Other rdy seal on CoolerlBox present: F-1,L/f yes �no Seats intact: ❑ yes no ng Material: ❑ Bubble VDD LJ Bubble Bags ❑ None ❑ Other nometer Used: IR Gun �140 Type of Ice: (�> Blue None b samples on ice, cooling process has begun i Correction Factor T1401 No Correction �. 7Biological Tissue is Frozen: Yes No N 1 Date and Int ° iii o pE on a r� int voted Cooler Temp.: 1r C contents: should be above freezing to 6°C Comments: r of Custody Present: i of Custody Filled Out: i of Custody Relingulsh )ter Name & Signature ales Arrived within Hold i Turn Aroun dent Volume: act Containers Used: }ace Containers Used: .alners Intact: red volume received for 1ple Labels match COC: Includes dateltimellD/Ar tests eon ontainers needing preservation are found to be in pliance with EPA recommendation. sirens: VOA. aallrorm. 700.0&G. WI -DRO (Water) _ M__.Y_es ONO ❑NIA 1. f_.txes ONO ❑NIA 2. Mes ❑ No ❑ NIA 3. Oyes No ❑NIA 4. [tes ❑No ❑NIA $. ❑Yes No 13NIA 6. Dyes ©too 0NIA 17. Dyes ❑No ❑NIA ©No 13N1A & ❑NIA ONO ❑NIA ❑Yes ONO &11A11. t Yes No 17NIA 12. []Yes ONO EINIA 13, ❑Yes ONO �WA ❑Yes rdspace in VOA Vials (>Smm): DYes ONO ®NIA 15. Blank Present: ❑Yes ONO NIA 16. r Blank Custody Seals Present ❑Yes ❑NO dNIA -e Trip Blank Lot # (if purchased): ant Notifrcationl Resolution: Field Data Required? Y I N Person Contacted: Daterrime: :omments/ Resolution: 1URF Review:G S Date: �# ° � �47L�� SRF Review: Date: �2 r Tote: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this farm will be sent to the North Carolina DEHNR Certification Office (i.e out of hold, incorrect preservative, out of temp, 52247233 incorrect containers) =31 Page 68 of 69 O C] uj z kA �I ^moi LL � V ! a LU C LU ! 7 E !0 I I i22 QUJ 0 j R �IJ y�- jC 0 Za 1n <i i Qi _ Z! l 0, M� O L._ ----- L. i-------------- LL _._._.-._,_ 'CL. i !' r 0i n i Z1y 4rr�I <Iapp mm�jN l �i LQQ; �ZN W� S.is c�Tsm j10 a�? LLi I I 1 i g o N r V h Q L' D P p C Q C 0 i a a T'a a b N a c g d a ti t N6 i # 00 C F W lu r o CL a z u Q (j)w $ $ ,z p W C LO 1 m ryejj or suiunloo oreNdoldde ojoldmoo of jaworsno lul .0 Okul, I N� ytjj � I V 0 i a a T'a a b a t N6 i m 0 F W lu CL a z \ (j)w $ $ ,z p W C LO 1 E am OM � Ir �V 00 v E N U a N U co d� [D � mz y Z IL Qu C �C �a J C K N rra Page 69 of 69 _ CHAIN OF CUSTODY RECORD AND ANALYSIS REOUEST FORM �7��•rt��� I=©i� 81 of 81 C f D DUKE Analytical Laboratory Services - -i � -- _ _._._._._._._._.-•-.-•-•-•- -Analytical Laborato Use Only_. ._._--------------------.- V e Mail Code MG03A2 (Building 7405) � work Order NCI Page 1 of 'I ENERGY � 13339 Hlle, I i )5-O l0C13 Matrix: SOIL Huntersvins, _X sc i — DISTRIBUTION Samples Originating From off � - tRlG I M N. , 280 38078 i ILogged a/YQ Oate 8 Time _.4_._.. _ -- =..T -- _I ! ORIGINAL t0 LAB, 14 Clays 5- 2 1980) 875-5245 U_ q _._._._ Fax1980l8784J49 ............_I f 'Z��I� S� 1 COPY to CLIENT SAMPLE PROGRAM Ground Water_ NPDESj other Plant _ 1lProiect Nam. er As All Groundwater Assessment -Soil 2)Phone No: (Wells" Asheville ± ry//���(r�'CC PJi�+C Cooler Tem C 4)Faa No: r - i REW DATE 2.f10f2015 c3)Cfient -? G-rr L�.G Lff -- --- -- - ' 7 J y • G r .. — -- Date aWRock O ned P4 sr DaterTim. AB GW i PO 1142081 r serv.:1=H - =Ice = one 7iMall Code: H •48 Hr Z4teommeMa Metals: Al, Sb, As, ia, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, fill, K, Se, Na, Sr, TI, V, Zn, Mercury, pH *0Ititx_ Mr Anions: Cl, Nitrate -N, SO4 Sediment Specific Parameters: %Solids CEC Particle Size Distribution Redox Potential _24 -A," r —t W." A;, a 5tayslness Unit: 6 Pro t � Ib: - s at to igiProcess Ip r tD COQ 1'j to n 8) Oparnlnp Unit 3 at,Acnvity IP; - �l G lu N W �_ a y G =1 t When specific accounting has been eatablishad and ie tot Indicated above Preservatives when used must be W a we need the following: f) Enter correct accounting in elf 5 accounting fields above, or added within 15 minutes of sample 3_ Provide correct accounting for O rating Unit and Process to ` O ;3 h qp U r t _� collection s_ = � '-' p C tl7 O N I• LAB USE ONLY I 14 Matrix Collection Information "� IV b a 0 Y1 r V r C M a �t 9 (soil, Sediment, Ash) 13 "tae to "Sample Description or ID Dale Time SE nature E t2 0 Vr O , a U a r Q Q ►- ° a r. m t� e., e, U! < Z g ;Q ¢ l�ia izoi m I I �[ ., to �lullr w` -10 .9 �s� rgxl� QUS.s� i— -_ t r SLI �/a-1Z �+ 1 1� CI3 -. C} J% Z I - 2- 7J L�'..`�i� �,-1 -7— L� O --- C( - r -_I - ---- --- - - - 3 f 1 1 1 i WATER EQUIPMENT BLANK 9 PEffiD _ -- -. •----�---'---_ �,r�7r vaternme � Aceeptetl By: r Uatdiima �'" r� 22 Requested Turnaround Relln ulahed 4 BY OatsRrrlme Acca _. �t� I}Y: Uatanima r�..L7[l_ � 5� 14 Clays oalrrlme 7 A a t ar LRelinquis � n a1 wtert[ma '� '7 Days {{ -? G-rr L�.G Lff -- --- -- - ' 7 J y • G r .. — -- Date aWRock O ned P4 sr DaterTim. •48 Hr Z4teommeMa Metals: Al, Sb, As, ia, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, fill, K, Se, Na, Sr, TI, V, Zn, Mercury, pH *0Ititx_ Mr Anions: Cl, Nitrate -N, SO4 Sediment Specific Parameters: %Solids CEC Particle Size Distribution Redox Potential _24 -A," r —t W." A;, a