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Home My WebLink AboutNC0000396_J15040313 Report_20150823+ DUKE Analytical Laboratory Page 1of81 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report J15040313 ASHEVILLE - AB GW ASSESSMENT SOIL Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker 200 CP and L Drive Arden, NC 28704 Margaret Galvin -Karr Phone: 980-875-5219 MXG4644 (1 01161) R Y, zols.os.29n:51:0s1:o7-04-00- Date: Margaret Galvin -Karr Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 5/27/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015010642 ASHEVILLE 13 -Apr -15 4:20 PM illegible AB-3SB (3-5) 2015010643 ASHEVILLE 13 -Apr -15 4:25 PM illegible AB-3SB (3-5) 2015010644 ASHEVILLE 14 -Apr -15 1:40 PM illegible MW-9SB (12-17) 2015010645 ASHEVILLE 14 -Apr -15 2:15 PM illegible MW-9SB (33-34) 2015010646 ASHEVILLE 14 -Apr -15 2:00 PM illegible MW-9SB (19-20) 2015010647 ASHEVILLE 13 -Apr -15 3:25 PM illegible Equipment Blank 6 Total Samples Page 2 of 81 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes F./] No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Page 3 of 81 Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 66 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Reviewed By: Peggy Kendall Date: 5/27/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040313 Site: AB-3SB (3-5) Collection Date: 13 -Apr -15 4:20 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 4 of 81 Sample #: 2015010642 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040313 Site: AB-3SB (3-5) Collection Date: 13 -Apr -15 4:25 PM Analyte Result Units Qualifiers RDL PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 5 of 81 Sample #: 2015010643 Matrix: SOIL DF Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040313 Site: MW-9SB (12-17) Collection Date: 14 -Apr -15 1:40 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 6 of 81 Sample #: 2015010644 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040313 Site: MW-9SB (33-34) Collection Date: 14 -Apr -15 2:15 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 7 of 81 Sample #: 2015010645 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040313 Site: MW-9SB (19-20) Collection Date: 14 -Apr -15 2:00 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 8 of 81 Sample #: 2015010646 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis Page 9 of 81 This report shall not be reproduced, except in full. Order # J15040313 Site: Equipment Blank Collection Date: 13 -Apr -15 3:25 PM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015010647 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE aceAnaiXical www.pacelabs.com May 08, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 RE: Project: J15040313 Pace Project No.: 92245637 Pace Analytical Services, Inc. 098pli6,8f fte. Suite 100 y Huntersville, INC 28078 (704)875-9092 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on April 15, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy HiQ p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 71 lacmnalyfica( www.pacelabs.com Project: J15040313 Pace Project No.: 92245637 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21 -A Certification #: 2926.01 Alaska Certification #: UST -078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ -0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH -0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. 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Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN -002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE -OS -28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 71 aceAnaiXical www.pacelabs.com Project: J15040313 Pace Project No.: 92245637 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. �Q�ff�i�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Page 3 of 71 aceAnaiXical www.pacelabs.com SAMPLE SUMMARY Project: J15040313 Pace Project No.: 92245637 Lab ID Sample ID Matrix Date Collected Date Received 92245637001 2015010642 Solid 04/13/1516:20 04/15/1515:30 92245637002 2015010643 Solid 04/13/1516:25 04/15/1515:30 92245637003 2015010644 Solid 04/14/1513:40 04/15/1515:30 92245637004 2015010645 Solid 04/14/1514:15 04/15/1515:30 92245637005 2015010646 Solid 04/14/1514:00 04/15/1515:30 92245637006 2015010647 Water 04/13/1515:25 04/15/1515:30 92245637007 2015010643 SPLP Water 04/13/15 16:25 04/15/15 15:30 92245637008 2015010644 SPLP Water 04/14/15 13:40 04/15/15 15:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. �Q�ff�i�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Page 4 of 71 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. �Q�fflic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15040313 92245637 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92245637001 2015010642 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CRT 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 TEP 1 PASI-A EPA 9056 KHC 2 PASI-O EPA 9056 KHC 1 PASI-O EPA 9060 TJJ 6 PASI-G 92245637002 2015010643 EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E SER 1 PASI-A 92245637003 2015010644 EPA 6010 CKJ, TAP 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CRT 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 TEP 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92245637004 2015010645 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CRT 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 TEP 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92245637005 2015010646 EPA 6010 CKJ 16 PASI-0 EPA 6020 DRS 8 PASI-O EPA 7471 CRT 1 PASI-O ASTM D2974-87 MLO 1 PASI-O EPA 9045 TEP 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 71 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15040313 Pace Project No.: 92245637 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 9060 TJJ 6 PASI-G 92245637006 2015010647 EPA 6020A RJS 24 PASI-M EPA 7470 JDD 1 PASI-M 92245637007 2015010643 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A JDD 1 PASI-M 92245637008 2015010644 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A JDD 1 PASI-M REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 71 aceAnaiXical www.pacelabs.com SUMMARY OF DETECTION Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15040313 92245637 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92245637001 2015010642 EPA 6010 Aluminum 20700 mg/kg 39.1 04/26/15 01:16 M1 EPA 6010 Barium 462 mg/kg 3.9 04/26/15 01:16 M1 EPA 6010 Beryllium 2.7 mg/kg 0.39 04/26/15 01:16 EPA 6010 Calcium 2010 mg/kg 195 04/26/15 01:16 EPA 6010 Chromium 31.7 mg/kg 2.0 04/26/1501:16 M1,R1 EPA 6010 Copper 40.4 mg/kg 2.0 04/26/15 01:16 EPA 6010 Iron 29600 mg/kg 15.6 04/26/15 01:16 M1 EPA 6010 Magnesium 2100 mg/kg 195 04/26/15 01:16 M1 EPA 6010 Manganese 281 mg/kg 2.0 04/26/15 01:16 M1 EPA 6010 Molybdenum 6.8 mg/kg 3.9 04/26/15 01:16 EPA 6010 Nickel 24.1 mg/kg 2.0 04/26/15 01:16 EPA 6010 Potassium 2690 mg/kg 391 04/26/15 01:16 M1 EPA 6010 Sodium 224J mg/kg 391 04/26/15 01:16 EPA 6010 Strontium 148 mg/kg 3.9 04/26/15 01:16 M1 EPA 6010 Zinc 49.1 mg/kg 7.8 04/26/15 01:16 EPA 6020 Arsenic 71.4 mg/kg 7.8 04/26/15 11:49 M6 EPA 6020 Cobalt 18.7 mg/kg 7.8 04/26/15 11:49 M6 EPA 6020 Lead 16.1 mg/kg 7.8 04/26/15 11:49 M6 EPA 6020 Selenium 11.8 mg/kg 7.8 04/26/15 11:49 M6 EPA 6020 Vanadium 54.9 mg/kg 7.8 04/26/15 11:49 M6 EPA 7471 Mercury 0.18 mg/kg 0.011 04/24/15 17:44 ASTM D2974-87 Percent Moisture 33.0 % 0.10 04/24/15 14:04 EPA 9045 pH at 25 Degrees C 7.4 Std. Units 0.10 04/21/15 11:55 H1 EPA 9056 Sulfate 187J mg/kg 366 04/23/1513:23 D3,M1 EPA 9060 Total Organic Carbon 51500 mg/kg 5850 05/06/15 20:40 EPA 9060 Total Organic Carbon 52400 mg/kg 5850 05/06/15 20:45 EPA 9060 Total Organic Carbon 53900 mg/kg 5970 05/06/15 20:52 EPA 9060 Total Organic Carbon 51500 mg/kg 5940 05/06/15 20:59 EPA 9060 Mean Total Organic Carbon 52300 mg/kg 5900 05/06/15 20:40 EPA 9060 RSD% 2.2 % 05/06/15 20:40 92245637002 2015010643 EPA 300.0 Sulfate 11.0 mg/L 2.0 04/29/15 16:38 B 92245637003 2015010644 EPA 6010 Aluminum 37000 mg/kg 27.3 04/26/15 00:31 EPA 6010 Barium 351 mg/kg 2.7 04/26/15 00:31 EPA 6010 Beryllium 8.9 mg/kg 0.55 04/26/15 23:45 EPA 6010 Calcium 768 mg/kg 136 04/26/15 00:31 EPA 6010 Chromium 185 mg/kg 2.7 04/26/15 23:45 EPA 6010 Copper 21.1 mg/kg 2.7 04/26/15 23:45 EPA 6010 Iron 54600 mg/kg 10.9 04/26/15 00:31 EPA 6010 Magnesium 13700 mg/kg 136 04/26/15 00:31 EPA 6010 Manganese 1170 mg/kg 2.7 04/26/15 23:45 EPA 6010 Nickel 92.6 mg/kg 1.4 04/26/15 00:31 EPA 6010 Potassium 7010 mg/kg 273 04/26/15 00:31 EPA 6010 Strontium 4.4 mg/kg 2.7 04/26/15 00:31 EPA 6010 Zinc 98.1 mg/kg 5.5 04/26/15 00:31 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 71 aceAnaiXical www.pacelabs.com Project: J15040313 Pace Project No.: 92245637 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. �Q�fflic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92245637003 2015010644 EPA 6020 Cobalt 33.7 mg/kg 5.5 04/26/15 11:24 EPA 6020 Lead 8.7 mg/kg 5.5 04/26/15 11:24 EPA 6020 Vanadium 171 mg/kg 5.5 04/26/15 11:24 ASTM D2974-87 Percent Moisture 5.3 % 0.10 04/24/15 14:04 EPA 9045 pH at 25 Degrees C 7.0 Std. Units 0.10 04/21/15 11:55 H1 EPA 300.0 Sulfate 3.2 mg/L 2.1 04/29/15 17:18 B EPA 9060 RSD% 8.5 % 05/07/15 12:25 92245637004 2015010645 EPA 6010 Aluminum 24900 mg/kg 28.0 04/26/15 00:35 EPA 6010 Barium 173 mg/kg 2.8 04/26/15 00:35 EPA 6010 Beryllium 1.0 mg/kg 0.28 04/26/15 00:35 EPA 6010 Calcium 2710 mg/kg 140 04/26/15 00:35 EPA 6010 Chromium 44.7 mg/kg 1.4 04/26/15 00:35 EPA 6010 Copper 13.6 mg/kg 1.4 04/26/15 00:35 EPA 6010 Iron 17800 mg/kg 11.2 04/26/15 00:35 EPA 6010 Magnesium 14700 mg/kg 140 04/26/15 00:35 EPA 6010 Manganese 230 mg/kg 1.4 04/26/15 00:35 EPA 6010 Nickel 81.7 mg/kg 1.4 04/26/15 00:35 EPA 6010 Potassium 7950 mg/kg 280 04/26/15 00:35 EPA 6010 Sodium 409 mg/kg 280 04/26/15 00:35 EPA 6010 Strontium 11.9 mg/kg 2.8 04/26/15 00:35 EPA 6010 Zinc 42.8 mg/kg 5.6 04/26/15 00:35 EPA 6020 Cobalt 21.6 mg/kg 5.6 04/26/15 11:26 EPA 6020 Vanadium 35.4 mg/kg 5.6 04/26/15 11:26 ASTM D2974-87 Percent Moisture 9.5 % 0.10 04/24/15 14:04 EPA 9045 pH at 25 Degrees C 7.3 Std. Units 0.10 04/21/15 11:55 H1 EPA 9060 RSD% 2.3 % 05/07/15 12:49 92245637005 2015010646 EPA 6010 Aluminum 27300 mg/kg 28.2 04/26/15 00:39 EPA 6010 Barium 288 mg/kg 2.8 04/26/15 00:39 EPA 6010 Beryllium 7.5 mg/kg 0.28 04/26/15 00:39 EPA 6010 Calcium 1450 mg/kg 141 04/26/15 00:39 EPA 6010 Chromium 98.7 mg/kg 1.4 04/26/15 00:39 EPA 6010 Copper 17.6 mg/kg 1.4 04/26/15 00:39 EPA 6010 Iron 37400 mg/kg 11.3 04/26/15 00:39 EPA 6010 Magnesium 10800 mg/kg 141 04/26/15 00:39 EPA 6010 Manganese 950 mg/kg 1.4 04/26/15 00:39 EPA 6010 Nickel 56.9 mg/kg 1.4 04/26/15 00:39 EPA 6010 Potassium 5380 mg/kg 282 04/26/15 00:39 EPA 6010 Strontium 6.1 mg/kg 2.8 04/26/15 00:39 EPA 6010 Zinc 69.3 mg/kg 5.6 04/26/15 00:39 EPA 6020 Cobalt 27.0 mg/kg 5.6 04/26/15 11:28 EPA 6020 Lead 7.7 mg/kg 5.6 04/26/15 11:28 EPA 6020 Vanadium 104 mg/kg 5.6 04/26/15 11:28 ASTM D2974-87 Percent Moisture 10.8 % 0.10 04/24/15 14:04 EPA 9045 pH at 25 Degrees C 6.3 Std. Units 0.10 04/21/15 11:55 H1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Qualifiers Page 8 of 71 aceAnaiXical www.pacelabs.com SUMMARY OF DETECTION Project: J15040313 Pace Project No.: 92245637 Pace Analytical Services, Inc. �Q�ffligc&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed 92245637005 2015010646 EPA 9060 RSD% 3.0 % 05/07/15 13:12 92245637006 2015010647 EPA 6020A Aluminum 212 ug/L 10.0 04/21/15 04:53 EPA 6020A Antimony 0.23J ug/L 0.50 04/21/15 04:53 EPA 6020A Arsenic 2.7 ug/L 0.50 04/21/15 04:53 EPA 6020A Barium 4.0 ug/L 0.30 04/21/15 04:53 EPA 6020A Calcium 277 ug/L 40.0 04/23/15 00:56 EPA 6020A Chromium 14.5 ug/L 0.50 04/21/15 04:53 EPA 6020A Cobalt 15.4 ug/L 0.50 04/21/15 04:53 EPA 6020A Copper 4.5 ug/L 1.0 04/21/15 04:53 EPA 6020A Iron 2850 ug/L 50.0 04/21/15 04:53 EPA 6020A Lead 0.28 ug/L 0.10 04/21/15 04:53 EPA 6020A Magnesium 57.1 ug/L 10.0 04/21/15 04:53 EPA 6020A Manganese 38.8 ug/L 0.50 04/21/15 04:53 EPA 6020A Molybdenum 2.0 ug/L 0.50 04/21/15 04:53 EPA 6020A Nickel 4.6 ug/L 0.50 04/21/15 04:53 EPA 6020A Potassium 108 ug/L 50.0 04/21/15 04:53 EPA 6020A Sodium 156 ug/L 50.0 04/21/15 04:53 EPA 6020A Strontium 1.3 ug/L 0.50 04/21/15 04:53 EPA 6020A Vanadium 0.36J ug/L 1.0 04/21/15 04:53 EPA 6020A Zinc 11.7 ug/L 5.0 04/21/15 04:53 92245637007 2015010643 SPLP EPA 6020A Aluminum 30300 ug/L 50.0 05/05/15 16:20 EPA 6020A Antimony 2.7 ug/L 0.50 05/04/15 16:57 EPA 6020A Arsenic 53.7 ug/L 0.50 05/04/15 16:57 EPA 6020A Barium 481 ug/L 1.5 05/05/15 16:20 EPA 6020A Beryllium 0.93 ug/L 0.20 05/04/15 16:57 EPA 6020A Boron 140 ug/L 5.0 05/04/15 16:57 EPA 6020A Cadmium 0.10 ug/L 0.080 05/04/15 16:57 EPA 6020A Calcium 7120 ug/L 40.0 05/04/15 16:57 EPA 6020A Chromium 29.4 ug/L 0.50 05/04/15 16:57 EPA 6020A Cobalt 7.1 ug/L 0.50 05/04/15 16:57 EPA 6020A Copper 18.4 ug/L 5.0 05/05/15 16:20 EPA 6020A Iron 18000 ug/L 50.0 05/04/15 16:57 EPA 6020A Lead 7.4 ug/L 0.10 05/04/15 16:57 EPA 6020A Magnesium 1750 ug/L 10.0 05/04/15 16:57 EPA 6020A Manganese 78.5 ug/L 0.50 05/04/15 16:57 EPA 6020A Molybdenum 73.5 ug/L 0.50 05/04/15 16:57 EPA 6020A Nickel 15.0 ug/L 0.50 05/04/15 16:57 EPA 6020A Potassium 2020 ug/L 50.0 05/04/15 16:57 EPA 6020A Selenium 23.9 ug/L 0.50 05/04/15 16:57 EPA 6020A Sodium 1720 ug/L 50.0 05/04/15 16:57 EPA 6020A Strontium 286 ug/L 0.50 05/04/15 16:57 EPA 6020A Thallium 0.40 ug/L 0.10 05/04/15 16:57 EPA 6020A Vanadium 51.7 ug/L 1.0 05/04/15 16:57 EPA 6020A Zinc 79.5 ug/L 5.0 05/04/15 16:57 REPORT OF LABORATORY ANALYSIS Qualifiers This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 71 aceAnaiXical www.pacelabs.com Project: J15040313 Pace Project No.: 92245637 Lab Sample ID Method 92245637007 EPA 7470A 92245637008 EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A EPA 6020A Client Sample ID Parameters 2015010643 SPLP Mercury 2015010644 SPLP Aluminum Barium Boron Calcium Chromium Copper Magnesium Manganese Potassium Sodium Strontium Zinc SUMMARY OF DETECTION Result UnitE 0.30 0.026J ug/L 22.3 ug/L 120 ug/L 61.4 ug/L 484 ug/L 1.6 ug/L 0.26J ug/L 225 ug/L 2.3 ug/L 48.OJ ug/L 1850 ug/L 6.0 ug/L 11.6 ug/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Report Limit Analyzed Qualifiers 0.20 05/04/15 20:44 10.0 05/04/1516:59 0.30 05/04/1516:59 5.0 05/04/1516:59 40.0 05/04/1516:59 0.50 05/04/1516:59 1.0 05/05/1516:23 10.0 05/04/1516:59 0.50 05/04/1516:59 50.0 05/04/1516:59 50.0 05/04/1516:59 0.50 05/04/1516:59 5.0 05/04/1516:59 Page 10 of 71 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0988 i vfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040313 Pace Project No.: 92245637 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: May 08, 2015 General Information: 4 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23716 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245627003 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1188469) • Aluminum • Barium • Iron • Potassium • Strontium • MSD (Lab ID: 1188470) • Aluminum • Barium • Beryllium • Calcium • Copper • Potassium • Strontium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 71 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15040313 Pace Project No.: 92245637 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: May 08, 2015 QC Batch: MPRP/23746 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245637001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1190237) • Aluminum • Barium • Chromium • Iron • Manganese • Potassium • Strontium • MSD (Lab ID: 1190238) • Aluminum • Barium • Iron • Magnesium • Manganese • Potassium • Strontium R1: RPD value was outside control limits. • MSD (Lab ID: 1190238) • Chromium Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICP / 14506 • QC Batch: ICP / 14514 Analyte Comments: Pace Analytical Services, Inc. 098gKinvfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 QC Batch: MPRP/23716 P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. • BLANK (Lab ID: 1188467) • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 71 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gKinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040313 Pace Project No.: 92245637 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: May 08, 2015 General Information: 4 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23717 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245627003 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1188475) • Antimony • Arsenic • Cadmium • Cobalt • Lead • Selenium • Thallium • Vanadium • MSD (Lab ID: 1188476) • Antimony • Arsenic • Cadmium • Cobalt REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 71 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gKinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040313 Pace Project No.: 92245637 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: May 08, 2015 QC Batch: MPRP/23717 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245627003 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • Lead • Selenium • Thallium • Vanadium QC Batch: MPRP/23747 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245637001 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1190235) • Antimony • Arsenic • Cadmium • Cobalt • Lead • Selenium • Thallium • Vanadium • MSD (Lab ID: 1190236) • Antimony • Arsenic • Cadmium • Cobalt • Lead • Selenium • Thallium • Vanadium Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICPM / 9649 Analyte Comments: QC Batch: MPRP/23717 N2: The lab does not hold TNI accreditation for this parameter. •2015010644 (Lab ID:92245637003) • Antimony •2015010645 (Lab ID:92245637004) • Antimony •2015010646 (Lab ID:92245637005) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 71 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gK4-8yfte. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040313 Pace Project No.: 92245637 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: May 08, 2015 Analyte Comments: QC Batch: MPRP/23717 N2: The lab does not hold TNI accreditation for this parameter. • BLANK (Lab ID: 1188473) • Antimony • LCS (Lab ID: 1188474) • Antimony • MS (Lab ID: 1188475) • Antimony • MSD (Lab ID: 1188476) • Antimony QC Batch: MPRP/23747 N2: The lab does not hold TNI accreditation for this parameter. •2015010642 (Lab ID: 92245637001) • Antimony • BLANK (Lab ID: 1190231) • Antimony • LCS (Lab ID: 1190232) • Antimony • MS (Lab ID: 1190235) • Antimony • MSD (Lab ID: 1190236) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 71 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0988 i vfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040313 Pace Project No.: 92245637 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: May 08, 2015 General Information: 3 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/53712 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245612006 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1943026) • Copper • Zinc R1: RPD value was outside control limits. • MSD (Lab ID: 1943027) • Copper • Zinc QC Batch: MPRP/54102 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247835001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1954383) • Aluminum • Calcium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 71 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 09Q�K�i vfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040313 Pace Project No.: 92245637 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: May 08, 2015 QC Batch: MPRP/54102 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92247835001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • Iron • Magnesium • MSD (Lab ID: 1954384) • Aluminum • Calcium • Iron • Magnesium • Thallium Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 71 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098v i vfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040313 Pace Project No.: 92245637 Method: EPA 7470 Description: 7470 Mercury Client: Duke Energy Date: May 08, 2015 General Information: 1 sample was analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 71 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0988 i vfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040313 Pace Project No.: 92245637 Method: EPA 7470A Description: 7470A Mercury Client: Duke Energy Date: May 08, 2015 General Information: 2 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 71 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0988 i vfte. Suite 100 �J Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040313 Pace Project No.: 92245637 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: May 08, 2015 General Information: 4 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MERP/5636 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35181969003 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1193928) • Mercury • MSD (Lab ID: 1193929) • Mercury R1: RPD value was outside control limits. • MSD (Lab ID: 1193929) • Mercury Additional Comments: Analyte Comments: QC Batch: MERP/5636 D4: Sample was diluted due to the presence of high levels of target analytes. • MS (Lab ID: 1193928) • Mercury REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 71 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040313 Pace Project No.: 92245637 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: May 08, 2015 Analyte Comments QC Batch: MERP/5636 D4: Sample was diluted due to the presence of high levels of target analytes. • MSD (Lab ID: 1193929) • Mercury REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 71 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninvfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040313 Pace Project No.: 92245637 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: May 08, 2015 General Information: 4 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015010642 (Lab ID: 92245637001) •2015010644 (Lab ID: 92245637003) •2015010645 (Lab ID: 92245637004) •2015010646 (Lab ID: 92245637005) Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 71 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040313 Pace Project No.: 92245637 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: May 08, 2015 General Information: 2 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/22735 B: Analyte was detected in the associated method blank. • BLANK for HBN 261569 [WETA/227 (Lab ID: 1445696) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 71 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040313 Pace Project No.: 92245637 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: May 08, 2015 General Information: 2 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015010643 (Lab ID: 92245637002) •2015010644 (Lab ID: 92245637003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 71 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15040313 Pace Project No.: 92245637 Method: SM 4500 -CI -E Description: 4500 Chloride, SPLP Client: Duke Energy Date: May 08, 2015 Pace Analytical Services, Inc. 09Q�K�i vfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 General Information: 2 samples were analyzed for SM 4500 -CI -E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 71 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040313 Pace Project No.: 92245637 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: May 08, 2015 General Information: 4 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/45549 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015010644 (Lab ID:92245637003) • Chloride • Sulfate •2015010645 (Lab ID:92245637004) • Chloride • Sulfate •2015010646 (Lab ID:92245637005) • Chloride • Sulfate QC Batch: WETA/45694 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015010642 (Lab ID: 92245637001) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 71 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040313 Pace Project No.: 92245637 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: May 08, 2015 General Information: 4 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015010642 (Lab ID: 92245637001) •2015010644 (Lab ID: 92245637003) •2015010645 (Lab ID: 92245637004) •2015010646 (Lab ID: 92245637005) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 71 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098v i vfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040313 Pace Project No.: 92245637 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: May 08, 2015 General Information: 4 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 71 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040313 Pace Project No.: 92245637 Pace Analytical Services, Inc. 098ninyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015010642 Lab ID: 92245637001 Collected: 04/13/15 16:20 Received: 04/15/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 05/08/2015 03:41 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 20700 mg/kg 39.1 19.5 5 04/22/15 14:50 04/26/15 01:16 7429-90-5 462 mg/kg 3.9 2.0 5 04/22/15 14:50 04/26/15 01:16 7440-39-3 2.7 mg/kg 0.39 0.20 5 04/22/15 14:50 04/26/15 01:16 7440-41-7 ND mg/kg 19.5 9.8 5 04/22/15 14:50 04/26/15 01:16 7440-42-8 2010 mg/kg 195 97.7 5 04/22/15 14:50 04/26/15 01:16 7440-70-2 31.7 mg/kg 2.0 0.98 5 04/22/15 14:50 04/26/15 01:16 7440-47-3 40.4 mg/kg 2.0 0.98 5 04/22/15 14:50 04/26/15 01:16 7440-50-8 29600 mg/kg 15.6 7.8 5 04/22/15 14:50 04/26/15 01:16 7439-89-6 2100 mg/kg 195 97.7 5 04/22/15 14:50 04/26/15 01:16 7439-95-4 281 mg/kg 2.0 0.98 5 04/22/15 14:50 04/26/15 01:16 7439-96-5 6.8 mg/kg 3.9 2.0 5 04/22/15 14:50 04/26/15 01:16 7439-98-7 24.1 mg/kg 2.0 0.98 5 04/22/15 14:50 04/26/15 01:16 7440-02-0 2690 mg/kg 391 195 5 04/22/15 14:50 04/26/15 01:16 7440-09-7 224J mg/kg 391 195 5 04/22/15 14:50 04/26/15 01:16 7440-23-5 148 mg/kg 3.9 2.0 5 04/22/15 14:50 04/26/15 01:16 7440-24-6 49.1 mg/kg 7.8 3.9 5 04/22/15 14:50 04/26/15 01:16 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 7.8 3.9 100 04/22/1514:50 04/26/1511:49 7440-36-0 71.4 mg/kg 7.8 3.9 100 04/22/1514:50 04/26/1511:49 7440-38-2 ND mg/kg 0.94 0.47 100 04/22/1514:50 04/26/1511:49 7440-43-9 18.7 mg/kg 7.8 3.9 100 04/22/1514:50 04/26/1511:49 7440-48-4 16.1 mg/kg 7.8 3.9 100 04/22/1514:50 04/26/1511:49 7439-92-1 11.8 mg/kg 7.8 3.9 100 04/22/1514:50 04/26/1511:49 7782-49-2 ND mg/kg 7.8 3.9 100 04/22/1514:50 04/26/1511:49 7440-28-0 54.9 mg/kg 7.8 3.9 100 04/22/1514:50 04/26/1511:49 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 0.18 mg/kg 0.011 0.0057 1 04/24/1514:59 04/24/1517:44 7439-97-6 Analytical Method: ASTM D2974-87 33.0 % 0.10 0.10 1 04/24/1514:04 Analytical Method: EPA 9045 7.4 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 366 183 5 187J mg/kg 366 183 5 Analytical Method: EPA 9056 ND mg/kg 36.6 18.3 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. ,81APIi1f601111.7 M1 M1 M1,R1 M1 M1 M1 M1 M1 M6, N2 M6 M6 M6 M6 M6 M6 M6 I:fl 04/23/1513:23 16887-00-6 D3,M1 04/23/1513:23 14808-79-8 D3,M1 04/23/1513:23 14797-55-8 H3,M1 Page 29 of 71 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040313 Pace Project No.: 92245637 Pace Analytical Services, Inc. 098ninyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015010642 Lab ID: 92245637001 Collected: 04/13/15 16:20 Received: 04/15/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 51500 mg/kg 5850 2920 1 05/06/15 20:40 7440-44-0 Total Organic Carbon 52400 mg/kg 5850 2920 1 05/06/15 20:45 7440-44-0 Total Organic Carbon 53900 mg/kg 5970 2990 1 05/06/15 20:52 7440-44-0 Total Organic Carbon 51500 mg/kg 5940 2970 1 05/06/15 20:59 7440-44-0 Mean Total Organic Carbon 52300 mg/kg 5900 2950 1 05/06/15 20:40 7440-44-0 Surrogates RSD% 2.2 % 1 05/06/15 20:40 Date: 05/08/2015 03:41 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 30 of 71 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040313 Pace Project No.: 92245637 Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015010643 Lab ID: 92245637002 Collected: 04/13/15 16:25 Received: 04/15/15 15:30 Matrix: Solid Results reported on a "wet -weight" basis Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 300.0 IC Anions, SPLP Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/16/15 03:15 Sulfate 11.0 mg/L 2.0 1.0 1 04/29/1516:38 14808-79-8 B 353.2 Nitrogen, NO2/NO3, SPLP Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/16/15 03:15 Nitrogen, Nitrate ND mg/L 0.20 0.20 1 04/29/15 21:07 H1 4500 Chloride, SPLP Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 04/16/15 03:15 Chloride ND mg/L 5.0 2.5 1 04/30/15 01:48 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 31 of 71 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040313 Pace Project No.: 92245637 Pace Analytical Services, Inc. 098gWinic&�rfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015010644 Lab ID: 92245637003 Collected: 04/14/15 13:40 Received: 04/15/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 300.0 IC Anions, SPLP Sulfate 353.2 Nitrogen, NO2/NO3, SPLP Nitrogen, Nitrate 4500 Chloride, SPLP Chloride Date: 05/08/2015 03:41 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 37000 mg/kg 27.3 13.6 5 04/21/15 14:40 04/26/15 00:31 7429-90-5 351 mg/kg 2.7 1.4 5 04/21/15 14:40 04/26/15 00:31 7440-39-3 8.9 mg/kg 0.55 0.27 10 04/21/15 14:40 04/26/15 23:45 7440-41-7 ND mg/kg 27.3 13.6 10 04/21/1514:40 04/26/1523:45 7440-42-8 768 mg/kg 136 68.1 5 04/21/15 14:40 04/26/15 00:31 7440-70-2 185 mg/kg 2.7 1.4 10 04/21/15 14:40 04/26/15 23:45 7440-47-3 21.1 mg/kg 2.7 1.4 10 04/21/15 14:40 04/26/15 23:45 7440-50-8 54600 mg/kg 10.9 5.5 5 04/21/1514:40 04/26/1500:31 7439-89-6 13700 mg/kg 136 68.1 5 04/21/15 14:40 04/26/15 00:31 7439-95-4 1170 mg/kg 2.7 1.4 10 04/21/15 14:40 04/26/15 23:45 7439-96-5 ND mg/kg 2.7 1.4 5 04/21/15 14:40 04/26/15 00:31 7439-98-7 92.6 mg/kg 1.4 0.68 5 04/21/15 14:40 04/26/15 00:31 7440-02-0 7010 mg/kg 273 136 5 04/21/15 14:40 04/26/15 00:31 7440-09-7 ND mg/kg 273 136 5 04/21/15 14:40 04/26/15 00:31 7440-23-5 4.4 mg/kg 2.7 1.4 5 04/21/15 14:40 04/26/15 00:31 7440-24-6 98.1 mg/kg 5.5 2.7 5 04/21/1514:40 04/26/1500:31 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 5.5 2.7 100 04/21/1514:40 04/26/1511:24 7440-36-0 N2 ND mg/kg 5.5 2.7 100 04/21/1514:40 04/26/1511:24 7440-38-2 ND mg/kg 0.65 0.33 100 04/21/1514:40 04/26/1511:24 7440-43-9 33.7 mg/kg 5.5 2.7 100 04/21/1514:40 04/26/1511:24 7440-48-4 8.7 mg/kg 5.5 2.7 100 04/21/1514:40 04/26/1511:24 7439-92-1 ND mg/kg 5.5 2.7 100 04/21/1514:40 04/26/1511:24 7782-49-2 ND mg/kg 5.5 2.7 100 04/21/1514:40 04/26/1511:24 7440-28-0 171 mg/kg 5.5 2.7 100 04/21/15 14:40 04/26/15 11:24 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.0088 0.0044 1 04/23/15 08:30 04/23/15 17:48 7439-97-6 Analytical Method: ASTM D2974-87 5.3 % 0.10 0.10 1 04/24/1514:04 Analytical Method: EPA 9045 7.0 Std. Units 0.10 0.10 1 04/21/15 11:55 H1 Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/16/15 03:15 3.2 mg/L 2.1 1.1 1 04/29/1517:18 14808-79-8 B Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/16/15 03:15 ND mg/L 0.21 0.21 1 04/29/15 21:08 H1 Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 04/16/15 03:15 ND mg/L 5.3 2.6 1 04/30/15 01:50 16887-00-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 32 of 71 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 098oinffte. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15040313 Pace Project No.: 92245637 Sample: 2015010644 Lab ID: 92245637003 Collected: 04/14/15 13:40 Received: 04/15/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 265 133 5 04/19/1514:16 16887-00-6 D3 Sulfate ND mg/kg 265 133 5 04/19/1514:16 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 26.5 13.3 5 04/19/15 14:16 14797-55-8 H3 Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 631 316 1 05/07/15 12:25 7440-44-0 Total Organic Carbon ND mg/kg 635 318 1 05/07/15 12:31 7440-44-0 Total Organic Carbon ND mg/kg 633 317 1 05/07/15 12:37 7440-44-0 Total Organic Carbon ND mg/kg 635 318 1 05/07/15 12:42 7440-44-0 Mean Total Organic Carbon ND mg/kg 634 317 1 05/07/15 12:25 7440-44-0 Surrogates RSD% 8.5 % 1 05/07/1512:25 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 33 of 71 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040313 Pace Project No.: 92245637 Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015010645 Lab ID: 92245637004 Collected: 04/14/15 14:15 Received: 04/15/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 05/08/2015 03:41 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 24900 mg/kg 28.0 14.0 5 04/21/15 14:40 04/26/15 00:35 7429-90-5 173 mg/kg 2.8 1.4 5 04/21/15 14:40 04/26/15 00:35 7440-39-3 1.0 mg/kg 0.28 0.14 5 04/21/15 14:40 04/26/15 00:35 7440-41-7 ND mg/kg 14.0 7.0 5 04/21/1514:40 04/26/1500:35 7440-42-8 2710 mg/kg 140 70.0 5 04/21/15 14:40 04/26/15 00:35 7440-70-2 44.7 mg/kg 1.4 0.70 5 04/21/15 14:40 04/26/15 00:35 7440-47-3 13.6 mg/kg 1.4 0.70 5 04/21/15 14:40 04/26/15 00:35 7440-50-8 17800 mg/kg 11.2 5.6 5 04/21/1514:40 04/26/1500:35 7439-89-6 14700 mg/kg 140 70.0 5 04/21/15 14:40 04/26/15 00:35 7439-95-4 230 mg/kg 1.4 0.70 5 04/21/15 14:40 04/26/15 00:35 7439-96-5 ND mg/kg 2.8 1.4 5 04/21/15 14:40 04/26/15 00:35 7439-98-7 81.7 mg/kg 1.4 0.70 5 04/21/15 14:40 04/26/15 00:35 7440-02-0 7950 mg/kg 280 140 5 04/21/15 14:40 04/26/15 00:35 7440-09-7 409 mg/kg 280 140 5 04/21/15 14:40 04/26/15 00:35 7440-23-5 11.9 mg/kg 2.8 1.4 5 04/21/15 14:40 04/26/15 00:35 7440-24-6 42.8 mg/kg 5.6 2.8 5 04/21/1514:40 04/26/1500:35 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 5.6 2.8 100 04/21/1514:40 04/26/1511:26 7440-36-0 ND mg/kg 5.6 2.8 100 04/21/1514:40 04/26/1511:26 7440-38-2 ND mg/kg 0.67 0.34 100 04/21/1514:40 04/26/1511:26 7440-43-9 21.6 mg/kg 5.6 2.8 100 04/21/1514:40 04/26/1511:26 7440-48-4 ND mg/kg 5.6 2.8 100 04/21/1514:40 04/26/1511:26 7439-92-1 ND mg/kg 5.6 2.8 100 04/21/1514:40 04/26/1511:26 7782-49-2 ND mg/kg 5.6 2.8 100 04/21/1514:40 04/26/1511:26 7440-28-0 35.4 mg/kg 5.6 2.8 100 04/21/15 14:40 04/26/15 11:26 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.0084 0.0042 1 04/23/15 08:30 04/23/15 17:59 7439-97-6 Analytical Method: ASTM D2974-87 9.5 % 0.10 0.10 1 04/24/1514:04 Analytical Method: EPA 9045 7.3 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 276 138 5 ND mg/kg 276 138 5 Analytical Method: EPA 9056 ND mg/kg 27.6 13.8 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. ,81APIi1f601111.7 N2 I:fl 04/19/1514:37 16887-00-6 D3 04/19/1514:37 14808-79-8 D3 04/19/1514:37 14797-55-8 H3 Page 34 of 71 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040313 Pace Project No.: 92245637 Pace Analytical Services, Inc. 0988 i vfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015010645 Lab ID: 92245637004 Collected: 04/14/15 14:15 Received: 04/15/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 659 330 1 05/07/15 12:49 7440-44-0 Total Organic Carbon ND mg/kg 663 331 1 05/07/15 12:54 7440-44-0 Total Organic Carbon ND mg/kg 669 334 1 05/07/15 13:00 7440-44-0 Total Organic Carbon ND mg/kg 663 332 1 05/07/15 13:07 7440-44-0 Mean Total Organic Carbon ND mg/kg 663 332 1 05/07/15 12:49 7440-44-0 Surrogates RSD% 2.3 % 1 05/07/1512:49 Date: 05/08/2015 03:41 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 35 of 71 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040313 Pace Project No.: 92245637 Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015010646 Lab ID: 92245637005 Collected: 04/14/15 14:00 Received: 04/15/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Aluminum Barium Beryllium Boron Calcium Chromium Copper Iron Magnesium Manganese Molybdenum Nickel Potassium Sodium Strontium Zinc 6020 MET ICPMS Antimony Arsenic Cadmium Cobalt Lead Selenium Thallium Vanadium 7471 Mercury Mercury Percent Moisture Percent Moisture 9045 pH Soil pH at 25 Degrees C 9056 IC Anions Chloride Sulfate 9056 IC Anions 48hr Nitrate as N Date: 05/08/2015 03:41 PM Analytical Method: EPA 6010 Preparation Method: EPA 3050 27300 mg/kg 28.2 14.1 5 04/21/15 14:40 04/26/15 00:39 7429-90-5 288 mg/kg 2.8 1.4 5 04/21/15 14:40 04/26/15 00:39 7440-39-3 7.5 mg/kg 0.28 0.14 5 04/21/15 14:40 04/26/15 00:39 7440-41-7 ND mg/kg 14.1 7.0 5 04/21/1514:40 04/26/1500:39 7440-42-8 1450 mg/kg 141 70.4 5 04/21/15 14:40 04/26/15 00:39 7440-70-2 98.7 mg/kg 1.4 0.70 5 04/21/15 14:40 04/26/15 00:39 7440-47-3 17.6 mg/kg 1.4 0.70 5 04/21/15 14:40 04/26/15 00:39 7440-50-8 37400 mg/kg 11.3 5.6 5 04/21/1514:40 04/26/1500:39 7439-89-6 10800 mg/kg 141 70.4 5 04/21/15 14:40 04/26/15 00:39 7439-95-4 950 mg/kg 1.4 0.70 5 04/21/15 14:40 04/26/15 00:39 7439-96-5 ND mg/kg 2.8 1.4 5 04/21/15 14:40 04/26/15 00:39 7439-98-7 56.9 mg/kg 1.4 0.70 5 04/21/15 14:40 04/26/15 00:39 7440-02-0 5380 mg/kg 282 141 5 04/21/15 14:40 04/26/15 00:39 7440-09-7 ND mg/kg 282 141 5 04/21/15 14:40 04/26/15 00:39 7440-23-5 6.1 mg/kg 2.8 1.4 5 04/21/15 14:40 04/26/15 00:39 7440-24-6 69.3 mg/kg 5.6 2.8 5 04/21/1514:40 04/26/1500:39 7440-66-6 Analytical Method: EPA 6020 Preparation Method: EPA 3050 ND mg/kg 5.6 2.8 100 04/21/1514:40 04/26/1511:28 7440-36-0 ND mg/kg 5.6 2.8 100 04/21/1514:40 04/26/1511:28 7440-38-2 ND mg/kg 0.68 0.34 100 04/21/1514:40 04/26/1511:28 7440-43-9 27.0 mg/kg 5.6 2.8 100 04/21/1514:40 04/26/1511:28 7440-48-4 7.7 mg/kg 5.6 2.8 100 04/21/1514:40 04/26/1511:28 7439-92-1 ND mg/kg 5.6 2.8 100 04/21/1514:40 04/26/1511:28 7782-49-2 ND mg/kg 5.6 2.8 100 04/21/1514:40 04/26/1511:28 7440-28-0 104 mg/kg 5.6 2.8 100 04/21/15 14:40 04/26/15 11:28 7440-62-2 Analytical Method: EPA 7471 Preparation Method: EPA 7471 ND mg/kg 0.0090 0.0045 1 04/23/15 08:30 04/23/15 18:03 7439-97-6 Analytical Method: ASTM D2974-87 10.8 % 0.10 0.10 1 04/24/1514:04 Analytical Method: EPA 9045 6.3 Std. Units 0.10 0.10 1 Analytical Method: EPA 9056 ND mg/kg 280 140 5 ND mg/kg 280 140 5 Analytical Method: EPA 9056 ND mg/kg 28.0 14.0 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. ,81APIi1f601111.7 N2 I:fl 04/19/1514:59 16887-00-6 D3 04/19/1514:59 14808-79-8 D3 04/19/1514:59 14797-55-8 H3 Page 36 of 71 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040313 Pace Project No.: 92245637 Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015010646 Lab ID: 92245637005 Collected: 04/14/15 14:00 Received: 04/15/15 15:30 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon ND mg/kg 669 334 1 05/07/15 13:12 7440-44-0 Total Organic Carbon ND mg/kg 667 334 1 05/07/15 13:18 7440-44-0 Total Organic Carbon ND mg/kg 675 338 1 05/07/15 13:24 7440-44-0 Total Organic Carbon ND mg/kg 671 336 1 05/07/15 13:30 7440-44-0 Mean Total Organic Carbon ND mg/kg 671 335 1 05/07/15 13:12 7440-44-0 Surrogates RSD% 3.0 % 1 05/07/1513:12 Date: 05/08/2015 03:41 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 37 of 71 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040313 Pace Project No.: 92245637 Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015010647 Lab ID: 92245637006 Collected: 04/13/15 15:25 Received: 04/15/15 15:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�r 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 05/08/2015 03:41 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 212 ug/L 10.0 3.0 1 04/20/15 06:33 04/21/15 04:53 7429-90-5 0.23J ug/L 0.50 0.15 1 04/20/15 06:33 04/21/15 04:53 7440-36-0 2.7 ug/L 0.50 0.11 1 04/20/15 06:33 04/21/15 04:53 7440-38-2 4.0 ug/L 0.30 0.081 1 04/20/15 06:33 04/21/15 04:53 7440-39-3 ND ug/L 0.20 0.067 1 04/20/15 06:33 04/21/15 04:53 7440-41-7 ND ug/L 5.0 1.1 1 04/20/15 06:33 04/21/15 04:53 7440-42-8 ND ug/L 0.080 0.024 1 04/20/15 06:33 04/21/15 04:53 7440-43-9 277 ug/L 40.0 16.0 1 04/20/15 06:33 04/23/15 00:56 7440-70-2 14.5 ug/L 0.50 0.17 1 04/20/15 06:33 04/21/15 04:53 7440-47-3 15.4 ug/L 0.50 0.13 1 04/20/15 06:33 04/21/15 04:53 7440-48-4 4.5 ug/L 1.0 0.21 1 04/20/15 06:33 04/21/15 04:53 7440-50-8 2850 ug/L 50.0 13.7 1 04/20/15 06:33 04/21/15 04:53 7439-89-6 0.28 ug/L 0.10 0.046 1 04/20/15 06:33 04/21/15 04:53 7439-92-1 57.1 ug/L 10.0 3.2 1 04/20/15 06:33 04/21/15 04:53 7439-95-4 38.8 ug/L 0.50 0.24 1 04/20/15 06:33 04/21/15 04:53 7439-96-5 2.0 ug/L 0.50 0.094 1 04/20/15 06:33 04/21/15 04:53 7439-98-7 4.6 ug/L 0.50 0.16 1 04/20/15 06:33 04/21/15 04:53 7440-02-0 108 ug/L 50.0 11.7 1 04/20/15 06:33 04/21/15 04:53 7440-09-7 ND ug/L 0.50 0.20 1 04/20/15 06:33 04/21/15 04:53 7782-49-2 156 ug/L 50.0 16.3 1 04/20/15 06:33 04/21/15 04:53 7440-23-5 1.3 ug/L 0.50 0.13 1 04/20/15 06:33 04/21/15 04:53 7440-24-6 ND ug/L 0.10 0.015 1 04/20/15 06:33 04/21/15 04:53 7440-28-0 0.36J ug/L 1.0 0.28 1 04/20/15 06:33 04/21/15 04:53 7440-62-2 11.7 ug/L 5.0 2.4 1 04/20/15 06:33 04/21/15 04:53 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/20/15 11:15 04/20/15 20:01 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 38 of 71 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040313 Pace Project No.: 92245637 Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015010643 SPLP Lab ID: 92245637007 Collected: 04/13/15 16:25 Received: 04/15/15 15:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\��il=11 a � 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 05/08/2015 03:41 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 30300 ug/L 50.0 14.9 5 05/04/15 08:49 05/05/15 16:20 7429-90-5 2.7 ug/L 0.50 0.15 1 05/04/15 08:49 05/04/15 16:57 7440-36-0 53.7 ug/L 0.50 0.11 1 05/04/15 08:49 05/04/15 16:57 7440-38-2 481 ug/L 1.5 0.40 5 05/04/15 08:49 05/05/15 16:20 7440-39-3 0.93 ug/L 0.20 0.067 1 05/04/15 08:49 05/04/15 16:57 7440-41-7 140 ug/L 5.0 1.1 1 05/04/15 08:49 05/04/15 16:57 7440-42-8 0.10 ug/L 0.080 0.024 1 05/04/15 08:49 05/04/15 16:57 7440-43-9 7120 ug/L 40.0 16.0 1 05/04/15 08:49 05/04/15 16:57 7440-70-2 29.4 ug/L 0.50 0.17 1 05/04/15 08:49 05/04/15 16:57 7440-47-3 7.1 ug/L 0.50 0.13 1 05/04/15 08:49 05/04/15 16:57 7440-48-4 18.4 ug/L 5.0 1.1 5 05/04/15 08:49 05/05/15 16:20 7440-50-8 18000 ug/L 50.0 13.7 1 05/04/15 08:49 05/04/15 16:57 7439-89-6 7.4 ug/L 0.10 0.046 1 05/04/15 08:49 05/04/15 16:57 7439-92-1 1750 ug/L 10.0 3.2 1 05/04/15 08:49 05/04/15 16:57 7439-95-4 78.5 ug/L 0.50 0.24 1 05/04/15 08:49 05/04/15 16:57 7439-96-5 73.5 ug/L 0.50 0.094 1 05/04/15 08:49 05/04/15 16:57 7439-98-7 15.0 ug/L 0.50 0.16 1 05/04/15 08:49 05/04/15 16:57 7440-02-0 2020 ug/L 50.0 11.7 1 05/04/15 08:49 05/04/15 16:57 7440-09-7 23.9 ug/L 0.50 0.20 1 05/04/15 08:49 05/04/15 16:57 7782-49-2 1720 ug/L 50.0 16.3 1 05/04/15 08:49 05/04/15 16:57 7440-23-5 286 ug/L 0.50 0.13 1 05/04/15 08:49 05/04/15 16:57 7440-24-6 0.40 ug/L 0.10 0.015 1 05/04/15 08:49 05/04/15 16:57 7440-28-0 51.7 ug/L 1.0 0.28 1 05/04/15 08:49 05/04/15 16:57 7440-62-2 79.5 ug/L 5.0 2.4 1 05/04/15 08:49 05/04/15 16:57 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A 0.026J ug/L 0.20 0.022 1 05/04/15 12:00 05/04/15 20:44 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 39 of 71 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040313 Pace Project No.: 92245637 Pace Analytical Services, Inc. 098m.8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015010644 SPLP Lab ID: 92245637008 Collected: 04/14/15 13:40 Received: 04/15/15 15:30 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 05/08/2015 03:41 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 22.3 ug/L 10.0 3.0 1 05/04/15 08:49 05/04/15 16:59 7429-90-5 ND ug/L 0.50 0.15 1 05/04/15 08:49 05/04/15 16:59 7440-36-0 ND ug/L 0.50 0.11 1 05/04/15 08:49 05/04/15 16:59 7440-38-2 120 ug/L 0.30 0.081 1 05/04/15 08:49 05/04/15 16:59 7440-39-3 ND ug/L 0.20 0.067 1 05/04/15 08:49 05/04/15 16:59 7440-41-7 61.4 ug/L 5.0 1.1 1 05/04/15 08:49 05/04/15 16:59 7440-42-8 ND ug/L 0.080 0.024 1 05/04/15 08:49 05/04/15 16:59 7440-43-9 484 ug/L 40.0 16.0 1 05/04/15 08:49 05/04/15 16:59 7440-70-2 1.6 ug/L 0.50 0.17 1 05/04/15 08:49 05/04/15 16:59 7440-47-3 ND ug/L 0.50 0.13 1 05/04/15 08:49 05/04/15 16:59 7440-48-4 0.26J ug/L 1.0 0.21 1 05/04/15 08:49 05/05/15 16:23 7440-50-8 ND ug/L 50.0 13.7 1 05/04/15 08:49 05/04/15 16:59 7439-89-6 ND ug/L 0.10 0.046 1 05/04/15 08:49 05/04/15 16:59 7439-92-1 225 ug/L 10.0 3.2 1 05/04/15 08:49 05/04/15 16:59 7439-95-4 2.3 ug/L 0.50 0.24 1 05/04/15 08:49 05/04/15 16:59 7439-96-5 ND ug/L 0.50 0.094 1 05/04/15 08:49 05/04/15 16:59 7439-98-7 ND ug/L 0.50 0.16 1 05/04/15 08:49 05/04/15 16:59 7440-02-0 48.OJ ug/L 50.0 11.7 1 05/04/15 08:49 05/04/15 16:59 7440-09-7 ND ug/L 0.50 0.20 1 05/04/15 08:49 05/04/15 16:59 7782-49-2 1850 ug/L 50.0 16.3 1 05/04/15 08:49 05/04/15 16:59 7440-23-5 6.0 ug/L 0.50 0.13 1 05/04/15 08:49 05/04/15 16:59 7440-24-6 ND ug/L 0.10 0.015 1 05/04/15 08:49 05/04/15 16:59 7440-28-0 ND ug/L 1.0 0.28 1 05/04/15 08:49 05/04/15 16:59 7440-62-2 11.6 ug/L 5.0 2.4 1 05/04/15 08:49 05/04/15 16:59 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 05/04/15 12:00 05/04/15 20:46 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 40 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040313 Pace Project No.: 92245637 QC Batch: MERP/13265 Analysis Method: EPA 7470 QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury Associated Lab Samples: 92245637006 METHOD BLANK: 1942361 Matrix: Water Associated Lab Samples: 92245637006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 04/20/1519:41 LABORATORY CONTROL SAMPLE: 1942362 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 5.1 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1942363 1942364 MS MSD 92243757012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.2 5.0 103 100 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 41 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098onlc8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040313 Pace Project No.: 92245637 QC Batch: MERP/13418 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470A Mercury Water Associated Lab Samples: 92245637007, 92245637008 METHOD BLANK: 1954385 Matrix: Water Associated Lab Samples: 92245637007, 92245637008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 05/04/15 20:27 LABORATORY CONTROL SAMPLE: 1954386 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 5 4.8 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1954387 1954388 MS MSD 92247835002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 5 5 5.1 5.2 103 103 80-120 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 42 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040313 Pace Project No.: 92245637 QC Batch: MERP/5618 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92245637003, 92245637004, 92245637005 METHOD BLANK: 1190449 Matrix: Solid Associated Lab Samples: 92245637003, 92245637004, 92245637005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0079 04/23/1517:44 LABORATORY CONTROL SAMPLE: 1190450 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .078 0.070 90 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1191846 1191847 MS MSD 92245637003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg ND .0845 .0824 0.072 0.070 86 85 80-120 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 43 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098nnyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040313 Pace Project No.: 92245637 QC Batch: MERP/5636 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92245637001 METHOD BLANK: 1193926 Matrix: Solid Associated Lab Samples: 92245637001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0081 04/24/1517:18 LABORATORY CONTROL SAMPLE: 1193927 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .081 0.077 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1193928 1193929 MS MSD 35181969003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg 6.9 .0901 .0856 5.8 3.5 -1210 -3920 80-120 48 20 D4,M6, R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 44 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040313 Pace Project No.: 92245637 QC Batch: MPRP/23716 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92245637003, 92245637004, 92245637005 METHOD BLANK: 1188467 Matrix: Associated Lab Samples: 92245637003, 92245637004, 92245637005 Blank Parameter Units Result Solid Reporting Limit Analyzed Aluminum mg/kg ND 5.2 04/25/15 22:53 Barium mg/kg ND 0.52 04/25/15 22:53 Beryllium mg/kg ND 0.052 04/25/15 22:53 Boron mg/kg ND 2.6 04/25/15 22:53 Calcium mg/kg ND 25.9 04/25/15 22:53 Chromium mg/kg ND 0.26 04/25/15 22:53 Copper mg/kg ND 0.26 04/25/15 22:53 Iron mg/kg 1.8J 2.1 04/25/15 22:53 P8 Magnesium mg/kg ND 25.9 04/25/15 22:53 Manganese mg/kg ND 0.26 04/25/15 22:53 Molybdenum mg/kg ND 0.52 04/25/15 22:53 Nickel mg/kg ND 0.26 04/25/15 22:53 Potassium mg/kg ND 51.8 04/25/15 22:53 Sodium mg/kg ND 51.8 04/25/15 22:53 Strontium mg/kg ND 0.52 04/25/15 22:53 Zinc mg/kg ND 1.0 04/25/15 22:53 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1188468 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 129 131 102 80-120 Barium mg/kg 12.9 13.2 103 80-120 Beryllium mg/kg 1.3 1.3 101 80-120 Boron mg/kg 129 126 98 80-120 Calcium mg/kg 645 665 103 80-120 Chromium mg/kg 12.9 12.5 97 80-120 Copper mg/kg 12.9 12.5 97 80-120 Iron mg/kg 129 131 101 80-120 Magnesium mg/kg 645 646 100 80-120 Manganese mg/kg 12.9 12.8 99 80-120 Molybdenum mg/kg 12.9 12.7 98 80-120 Nickel mg/kg 12.9 13.1 102 80-120 Potassium mg/kg 645 646 100 80-120 Sodium mg/kg 645 673 104 80-120 Strontium mg/kg 12.9 13.1 101 80-120 Zinc mg/kg 64.5 65.1 101 80-120 Pace Analytical Services, Inc. 098mvfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 45 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098nnyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040313 Pace Project No.: 92245637 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1188469 1188470 MS MSD 92245627003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 5200 224 220 8480 9980 1470 2170 75-125 16 20 M1 Barium mg/kg 482 22.4 22 558 617 340 615 75-125 10 20 M1 Beryllium mg/kg 1.1 2.25 2.25 3.6 4.1 112 135 75-125 12 20 M1 Boron mg/kg ND 224 220 189 200 83 89 75-125 6 20 Calcium mg/kg 1390 1110 1100 2790 3070 125 152 75-125 10 20 M1 Chromium mg/kg 10.5 22.4 22 29.7 33.3 86 104 75-125 11 20 Copper mg/kg 19.3 22.4 22 44.9 51.1 115 145 75-125 13 20 M1 Iron mg/kg 20500 224 220 18000 20700 -1110 84 75-125 14 20 M1 Magnesium mg/kg 447 1110 1100 1630 1780 106 121 75-125 9 20 Manganese mg/kg 56.2 22.4 22 79.0 82.8 102 121 75-125 5 20 Molybdenum mg/kg ND 22.4 22 20.3 21.7 84 91 75-125 6 20 Nickel mg/kg 13.0 22.4 22 35.1 39.2 99 119 75-125 11 20 Potassium mg/kg 853 1110 1100 2540 2840 151 181 75-125 11 20 M1 Sodium mg/kg ND 1110 1100 1170 1230 99 106 75-125 5 20 Strontium mg/kg 97.4 22.4 22 159 184 276 395 75-125 15 20 M1 Zinc mg/kg 9.7 111 110 113 121 92 101 75-125 7 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 46 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040313 Pace Project No.: 92245637 QC Batch: MPRP/23746 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92245637001 METHOD BLANK: 1190227 Associated Lab Samples: 92245637001 Parameter Units Aluminum mg/kg Barium mg/kg Beryllium mg/kg Boron mg/kg Calcium mg/kg Chromium mg/kg Copper mg/kg Iron mg/kg Magnesium mg/kg Manganese mg/kg Molybdenum mg/kg Nickel mg/kg Potassium mg/kg Sodium mg/kg Strontium mg/kg Zinc mg/kg Matrix: Solid Blank Result Reporting Limit Analyzed ND 4.9 04/26/15 00:56 ND 0.49 04/26/15 00:56 ND 0.049 04/26/15 00:56 ND 2.4 04/26/15 00:56 ND 24.3 04/26/15 00:56 ND 0.24 04/26/15 00:56 ND 0.24 04/26/15 00:56 ND 1.9 04/26/15 00:56 ND 24.3 04/26/15 00:56 ND 0.24 04/26/15 00:56 ND 0.49 04/26/15 00:56 ND 0.24 04/26/15 00:56 ND 48.7 04/26/15 00:56 ND 48.7 04/26/15 00:56 ND 0.49 04/26/15 00:56 ND 0.97 04/26/15 00:56 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1190228 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 122 124 102 80-120 Barium mg/kg 12.2 12.6 103 80-120 Beryllium mg/kg 1.2 1.2 102 80-120 Boron mg/kg 122 121 99 80-120 Calcium mg/kg 610 626 103 80-120 Chromium mg/kg 12.2 11.9 98 80-120 Copper mg/kg 12.2 11.9 98 80-120 Iron mg/kg 122 123 101 80-120 Magnesium mg/kg 610 611 100 80-120 Manganese mg/kg 12.2 12.2 100 80-120 Molybdenum mg/kg 12.2 12.0 99 80-120 Nickel mg/kg 12.2 12.5 102 80-120 Potassium mg/kg 610 614 101 80-120 Sodium mg/kg 610 640 105 80-120 Strontium mg/kg 12.2 12.4 101 80-120 Zinc mg/kg 61 62.0 102 80-120 Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 47 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 0988 i vfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15040313 Pace Project No.: 92245637 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1190237 1190238 MS MSD 92245637001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 20700 196 194 26500 24700 2950 2040 75-125 7 20 M1 Barium mg/kg 462 19.6 19.4 422 447 -202 -73 75-125 6 20 M1 Beryllium mg/kg 2.7 1.94 1.94 4.5 4.5 89 89 75-125 0 20 Boron mg/kg ND 196 194 159 167 78 83 75-125 5 20 Calcium mg/kg 2010 976 970 2820 2810 83 83 75-125 0 20 Chromium mg/kg 31.7 19.6 19.4 60.7 47.7 148 82 75-125 24 20 M1,R1 Copper mg/kg 40.4 19.6 19.4 56.3 54.9 81 75 75-125 3 20 Iron mg/kg 29600 196 194 31800 28800 1110 -434 75-125 10 20 M1 Magnesium mg/kg 2100 976 970 3170 3810 110 177 75-125 18 20 M1 Manganese mg/kg 281 19.6 19.4 324 375 221 483 75-125 14 20 M1 Molybdenum mg/kg 6.8 19.6 19.4 23.0 23.9 83 88 75-125 4 20 Nickel mg/kg 24.1 19.6 19.4 45.0 43.2 107 98 75-125 4 20 Potassium mg/kg 2690 976 970 3920 4260 126 162 75-125 8 20 M1 Sodium mg/kg 224J 976 970 1140 1160 94 97 75-125 2 20 Strontium mg/kg 148 19.6 19.4 162 157 71 44 75-125 3 20 M1 Zinc mg/kg 49.1 97.6 97 138 149 91 103 75-125 8 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 48 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040313 Pace Project No.: 92245637 QC Batch: MPRP/23717 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92245637003, 92245637004, 92245637005 METHOD BLANK: 1188473 Matrix: Solid LCS Result Associated Lab Samples: 92245637003, 92245637004, 92245637005 mg/kg 2.6 2.6 99 Blank Reporting mg/kg Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.051 04/26/1510:31 N2 Arsenic mg/kg ND 0.051 04/26/1510:31 Cadmium mg/kg ND 0.0062 04/26/1510:31 Cobalt mg/kg ND 0.051 04/26/1510:31 Lead mg/kg ND 0.051 04/26/1510:31 Selenium mg/kg ND 0.051 04/26/1510:31 Thallium mg/kg ND 0.051 04/26/1510:31 Vanadium mg/kg ND 0.051 04/26/1510:31 Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1188474 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.6 2.6 99 80-120 N2 Arsenic mg/kg 2.6 2.7 103 80-120 Cadmium mg/kg .26 0.26 99 80-120 Cobalt mg/kg 2.6 2.7 104 80-120 Lead mg/kg 2.6 2.6 100 80-120 Selenium mg/kg 2.6 2.6 99 80-120 Thallium mg/kg 2.6 2.6 101 80-120 Vanadium mg/kg 2.6 2.7 103 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1188475 1188476 MS MSD 92245627003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 4.51 4.16 17.2 14.8 381 351 75-125 15 20 M6, N2 Arsenic mg/kg 21.8 4.51 4.16 51.2 55.5 661 816 75-125 8 20 M6 Cadmium mg/kg 0.59J .451 .416 2.4 2.2 411 397 75-125 8 20 M6 Cobalt mg/kg 6.9J 4.51 4.16 29.1 30.3 500 567 75-125 4 20 M6 Lead mg/kg ND 4.51 4.16 27.4 28.6 525 594 75-125 4 20 M6 Selenium mg/kg 6.9J 4.51 4.16 29.5 29.0 507 533 75-125 2 20 M6 Thallium mg/kg ND 4.51 4.16 20.6 19.4 444 450 75-125 6 20 M6 Vanadium mg/kg 20.4 4.51 4.16 49.4 54.1 650 816 75-125 9 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 49 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040313 Pace Project No.: 92245637 QC Batch: MPRP/23747 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92245637001 METHOD BLANK: 1190231 Matrix: Solid Associated Lab Samples: 92245637001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.050 04/27/1514:25 N2 Arsenic mg/kg ND 0.050 04/27/1514:25 Cadmium mg/kg ND 0.0060 04/27/1514:25 Cobalt mg/kg ND 0.050 04/27/1514:25 Lead mg/kg ND 0.050 04/27/1514:25 Selenium mg/kg ND 0.050 04/27/1514:25 Thallium mg/kg ND 0.050 04/27/1514:25 Vanadium mg/kg ND 0.050 04/27/1514:25 Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 1190232 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony mg/kg 2.5 2.6 103 80-120 N2 Arsenic mg/kg 2.5 2.7 107 80-120 Cadmium mg/kg .25 0.26 103 80-120 Cobalt mg/kg 2.5 2.7 105 80-120 Lead mg/kg 2.5 2.6 102 80-120 Selenium mg/kg 2.5 2.7 104 80-120 Thallium mg/kg 2.5 2.6 103 80-120 Vanadium mg/kg 2.5 2.7 105 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1190235 1190236 MS MSD 92245637001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 3.88 3.58 12.1 11.6 281 294 75-125 4 20 M6, N2 Arsenic mg/kg 71.4 3.88 3.58 62.9 62.6 -219 -247 75-125 0 20 M6 Cadmium mg/kg ND .388 .358 1.8 1.8 379 419 75-125 1 20 M6 Cobalt mg/kg 18.7 3.88 3.58 35.7 33.8 438 423 75-125 6 20 M6 Lead mg/kg 16.1 3.88 3.58 33.1 31.7 439 437 75-125 5 20 M6 Selenium mg/kg 11.8 3.88 3.58 26.5 25.4 380 384 75-125 4 20 M6 Thallium mg/kg ND 3.88 3.58 16.5 15.8 403 419 75-125 4 20 M6 Vanadium mg/kg 54.9 3.88 3.58 70.8 68.4 410 381 75-125 3 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 50 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040313 Pace Project No.: 92245637 QC Batch: MPRP/53712 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92245637006 METHOD BLANK: 1942408 Associated Lab Samples: 92245637006 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 04/21/15 03:54 ND 0.50 04/21/15 03:54 ND 0.50 04/21/15 03:54 ND 0.30 04/21/15 03:54 ND 0.20 04/21/15 03:54 ND 5.0 04/21/15 03:54 ND 0.080 04/21/15 03:54 ND 40.0 04/21/15 03:54 ND 0.50 04/21/15 03:54 ND 0.50 04/21/15 03:54 ND 1.0 04/21/15 03:54 ND 50.0 04/21/15 03:54 ND 0.10 04/21/15 03:54 ND 10.0 04/21/15 03:54 ND 0.50 04/21/15 03:54 ND 0.50 04/21/15 03:54 ND 0.50 04/21/15 03:54 ND 50.0 04/21/15 03:54 ND 0.50 04/21/15 03:54 ND 50.0 04/21/15 03:54 ND 0.50 04/21/15 03:54 ND 0.10 04/21/15 03:54 ND 1.0 04/21/15 03:54 ND 5.0 04/21/15 03:54 Qualifiers Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1942409 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 75.1 94 80-120 Antimony ug/L 80 79.8 100 80-120 Arsenic ug/L 80 78.9 99 80-120 Barium ug/L 80 78.9 99 80-120 Beryllium ug/L 80 76.6 96 80-120 Boron ug/L 80 78.1 98 80-120 Cadmium ug/L 80 78.4 98 80-120 Calcium ug/L 1000 908 91 80-120 Chromium ug/L 80 78.7 98 80-120 Cobalt ug/L 80 77.4 97 80-120 Copper ug/L 80 76.8 96 80-120 Iron ug/L 1000 983 98 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 51 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098oinic&�rfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15040313 Pace Project No.: 92245637 LABORATORY CONTROL SAMPLE: 1942409 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 79.1 99 80-120 Magnesium ug/L 1000 960 96 80-120 Manganese ug/L 80 78.6 98 80-120 Molybdenum ug/L 80 75.6 95 80-120 Nickel ug/L 80 80.3 100 80-120 Potassium ug/L 1000 985 98 80-120 Selenium ug/L 80 79.2 99 80-120 Sodium ug/L 1000 958 96 80-120 Strontium ug/L 80 77.4 97 80-120 Thallium ug/L 80 77.3 97 80-120 Vanadium ug/L 80 78.8 99 80-120 Zinc ug/L 80 79.9 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1943026 1943027 MS MSD 92245612006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L ND 80 80 83.9 76.5 105 95 75-125 9 20 Antimony ug/L ND 80 80 79.9 79.8 100 100 75-125 0 20 Arsenic ug/L ND 80 80 78.9 80.7 99 101 75-125 2 20 Barium ug/L ND 80 80 79.7 77.8 100 97 75-125 2 20 Beryllium ug/L ND 80 80 75.7 75.9 95 95 75-125 0 20 Boron ug/L ND 80 80 78.4 75.1 98 94 75-125 4 20 Cadmium ug/L ND 80 80 78.2 78.2 98 98 75-125 0 20 Calcium ug/L ND 1000 1000 956 1050 95 104 75-125 9 20 Chromium ug/L ND 80 80 78.6 78.1 98 98 75-125 1 20 Cobalt ug/L ND 80 80 78.4 78.3 98 98 75-125 0 20 Copper ug/L ND 80 80 130 78.9 162 98 75-125 49 20 M1,R1 Iron ug/L ND 1000 1000 970 987 97 99 75-125 2 20 Lead ug/L ND 80 80 82.6 79.2 103 99 75-125 4 20 Magnesium ug/L ND 1000 1000 966 977 96 98 75-125 1 20 Manganese ug/L ND 80 80 79.1 78.8 99 98 75-125 0 20 Molybdenum ug/L ND 80 80 76.2 75.6 95 94 75-125 1 20 Nickel ug/L ND 80 80 81.8 81.0 102 101 75-125 1 20 Potassium ug/L ND 1000 1000 973 975 97 97 75-125 0 20 Selenium ug/L ND 80 80 80.5 79.0 101 99 75-125 2 20 Sodium ug/L ND 1000 1000 980 951 98 95 75-125 3 20 Strontium ug/L ND 80 80 77.5 77.4 97 97 75-125 0 20 Thallium ug/L ND 80 80 79.4 79.1 99 99 75-125 0 20 Vanadium ug/L ND 80 80 79.0 79.6 99 99 75-125 1 20 Zinc ug/L ND 80 80 118 79.7 146 98 75-125 39 20 M1,R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 52 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040313 Pace Project No.: 92245637 QC Batch: MPRP/54102 Analysis Method: EPA 6020A QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4 Associated Lab Samples: 92245637007, 92245637008 METHOD BLANK: 1954381 Associated Lab Samples: 92245637007, 92245637008 Parameter Units Aluminum ug/L Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Boron ug/L Cadmium ug/L Calcium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Magnesium ug/L Manganese ug/L Molybdenum ug/L Nickel ug/L Potassium ug/L Selenium ug/L Sodium ug/L Strontium ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Matrix: Water Blank Result Reporting Limit Analyzed ND 10.0 05/04/1516:41 ND 0.50 05/04/1516:41 ND 0.50 05/04/1516:41 ND 0.30 05/04/1516:41 ND 0.20 05/04/1516:41 ND 5.0 05/04/1516:41 ND 0.080 05/04/1516:41 ND 40.0 05/04/1516:41 ND 0.50 05/04/1516:41 ND 0.50 05/04/1516:41 ND 1.0 05/05/1516:04 ND 50.0 05/04/1516:41 ND 0.10 05/04/1516:41 ND 10.0 05/04/1516:41 ND 0.50 05/04/1516:41 ND 0.50 05/04/1516:41 ND 0.50 05/04/1516:41 ND 50.0 05/04/1516:41 ND 0.50 05/04/1516:41 ND 50.0 05/04/1516:41 ND 0.50 05/04/1516:41 ND 0.10 05/04/1516:41 ND 1.0 05/04/1516:41 ND 5.0 05/04/1516:41 Qualifiers Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1954382 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Aluminum ug/L 80 81.4 102 80-120 Antimony ug/L 80 81.8 102 80-120 Arsenic ug/L 80 78.7 98 80-120 Barium ug/L 80 93.0 116 80-120 Beryllium ug/L 80 82.9 104 80-120 Boron ug/L 80 83.9 105 80-120 Cadmium ug/L 80 84.8 106 80-120 Calcium ug/L 1000 1100 110 80-120 Chromium ug/L 80 80.7 101 80-120 Cobalt ug/L 80 82.3 103 80-120 Copper ug/L 80 84.5 106 80-120 Iron ug/L 1000 1100 110 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 53 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15040313 Pace Project No.: 92245637 LABORATORY CONTROL SAMPLE: 1954382 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lead ug/L 80 79.9 100 80-120 Magnesium ug/L 1000 1030 103 80-120 Manganese ug/L 80 78.3 98 80-120 Molybdenum ug/L 80 80.0 100 80-120 Nickel ug/L 80 84.8 106 80-120 Potassium ug/L 1000 975 97 80-120 Selenium ug/L 80 88.1 110 80-120 Sodium ug/L 1000 997 100 80-120 Strontium ug/L 80 85.2 107 80-120 Thallium ug/L 80 91.2 114 80-120 Vanadium ug/L 80 81.0 101 80-120 Zinc ug/L 80 85.9 107 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1954383 1954384 MS MSD 92247835001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum ug/L 2510 80 80 4310 4250 2250 2180 75-125 1 20 M1 Antimony ug/L 0.43J 80 80 73.3 76.3 91 95 75-125 4 20 Arsenic ug/L 0.27J 80 80 80.4 82.5 100 103 75-125 3 20 Barium ug/L 17.0 80 80 107 113 112 120 75-125 6 20 Beryllium ug/L ND 80 80 89.4 92.4 112 115 75-125 3 20 Boron ug/L 4AJ 80 80 102 101 122 121 75-125 1 20 Cadmium ug/L 0.063J 80 80 85.9 88.8 107 111 75-125 3 20 Calcium ug/L 2110 1000 1000 3750 3810 164 170 75-125 1 20 M1 Chromium ug/L 17.4 80 80 102 105 106 110 75-125 3 20 Cobalt ug/L 2.1 80 80 78.7 81.6 96 99 75-125 4 20 Copper ug/L 9.1 80 80 88.0 91.0 99 102 75-125 3 20 Iron ug/L 8200 1000 1000 10200 10500 201 226 75-125 2 20 M1 Lead ug/L 0.51 80 80 79.4 80.8 99 100 75-125 2 20 Magnesium ug/L 990 1000 1000 2400 2430 141 144 75-125 1 20 M1 Manganese ug/L 78.0 80 80 168 175 112 121 75-125 4 20 Molybdenum ug/L 4.8 80 80 86.2 89.6 102 106 75-125 4 20 Nickel ug/L 4.6 80 80 92.2 95.4 109 113 75-125 3 20 Potassium ug/L 775 1000 1000 1660 1720 88 94 75-125 4 20 Selenium ug/L ND 80 80 90.4 91.2 113 114 75-125 1 20 Sodium ug/L 603 1000 1000 1670 1730 107 113 75-125 4 20 Strontium ug/L 13.3 80 80 97.3 102 105 111 75-125 5 20 Thallium ug/L ND 80 80 98.0 102 122 128 75-125 4 20 M1 Vanadium ug/L 9.9 80 80 96.3 98.5 108 111 75-125 2 20 Zinc ug/L 12.2 80 80 97.8 101 107 111 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 54 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098mvfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040313 Pace Project No.: 92245637 QC Batch: PMST/3483 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92245637001, 92245637003, 92245637004, 92245637005 SAMPLE DUPLICATE: 1194018 92244129001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 2.6 2.5 3 10 SAMPLE DUPLICATE: 1194019 35183820021 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 0.10U ND 10 SAMPLE DUPLICATE: 1194020 35184326002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 4.5 5.2 15 10 D6 SAMPLE DUPLICATE: 1194021 35184489003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 1.1 2.2 66 10 D6 SAMPLE DUPLICATE: 1194022 35184621009 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 7.7 5.9 27 10 D6 SAMPLE DUPLICATE: 1194023 35184604005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 5.5 3.3 50 10 D6 SAMPLE DUPLICATE: 1194024 35184671005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 2.5 33.0 171 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 55 of 71 aceAnaiXical www.pacelabs.com Project: J15040313 Pace Project No.: 92245637 SAMPLE DUPLICATE: 1194025 Parameter Percent Moisture SAMPLE DUPLICATE: 1194026 Parameter Percent Moisture SAMPLE DUPLICATE: 1194027 Parameter Percent Moisture Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA 35184713002 Dup Max Units Result Result RPD RPD Qualifiers 13.6 15.2 11 10 D6 35184791007 Dup Max Units Result Result RPD RPD Qualifiers % 2.2 4.6 70 10 D6 35185205004 Dup Max Units Result Result RPD RPD Qualifiers % 0.96 0.45 72 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 56 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040313 Pace Project No.: 92245637 QC Batch: WET/36947 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92245637001, 92245637003, 92245637004, 92245637005 Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 SAMPLE DUPLICATE: 1438913 92246075013 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.4 6.3 2 10 H3 SAMPLE DUPLICATE: 1438914 92245627010 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.3 6.5 4 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 57 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 0988 i vfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15040313 Pace Project No.: 92245637 QC Batch: WETA/22735 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92245637002, 92245637003 METHOD BLANK: 1445696 Matrix: Water Associated Lab Samples: 92245637002, 92245637003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L 3.4 2.0 04/29/1513:00 LABORATORY CONTROL SAMPLE: 1445697 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate mg/L 20 19.4 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1445698 1445699 MS MSD 92245352011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 1.7J 23.9 23.9 23.5 23.2 91 90 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1445700 1445701 MS MSD 92245637002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate mg/L 11.0 20 20 31.2 31.3 101 102 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 58 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15040313 Pace Project No.: 92245637 QC Batch: WETA/22748 Analysis Method: EPA 353.2 QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92245637002, 92245637003 METHOD BLANK: 1446743 Matrix: Water Associated Lab Samples: 92245637002, 92245637003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L 0.15 0.020 04/29/15 20:34 Z2 LABORATORY CONTROL SAMPLE: 1446744 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 2.5 2.6 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1446745 1446746 MS MSD 92245352011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 3 3 3.3 3.3 103 103 90-110 0 10 H1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1446747 1446748 MS MSD 92245352012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate mg/L ND 3.2 3.2 3.5 3.4 102 102 90-110 0 10 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 59 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098oinyfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15040313 Pace Project No.: 92245637 QC Batch: WETA/22743 Analysis Method: SM 4500 -CI -E QC Batch Method: SM 4500 -CI -E Analysis Description: 4500 Chloride Associated Lab Samples: 92245637002, 92245637003 METHOD BLANK: 1446034 Matrix: Water Associated Lab Samples: 92245637002, 92245637003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 04/30/15 01:35 LABORATORY CONTROL SAMPLE: 1446035 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 21.1 106 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1446036 1446037 MS MSD 92245352011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 23.9 23.9 24.6 24.4 102 101 90-110 1 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1446038 1446039 MS MSD 92245637002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride mg/L ND 20 20 22.3 22.0 103 101 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 60 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040313 Pace Project No.: 92245637 QC Batch: WETA/45549 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92245637003, 92245637004, 92245637005 METHOD BLANK: 1187892 1187893 Matrix: Solid Units Associated Lab Samples: mg/kg Sulfate mg/kg Blank Reporting 1187895 Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.9 04/18/15 20:52 Sulfate mg/kg ND 49.9 04/18/15 20:52 LABORATORY CONTROL SAMPLE: 1187893 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1187895 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1187894 Parameter Chloride Sulfate Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 500 485 97 80-120 500 484 97 80-120 92245417003 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 590 556 94 80-120 ND 590 578 98 80-120 92245417003 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 61 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040313 Pace Project No.: 92245637 QC Batch: WETA/45694 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92245637001 METHOD BLANK: 1192005 1192006 Matrix: Solid Units Associated Lab Samples: mg/kg Sulfate mg/kg Blank Reporting 1192008 Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 50.6 04/23/1512:41 Sulfate mg/kg ND 50.6 04/23/1512:41 LABORATORY CONTROL SAMPLE: 1192006 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1192008 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1192007 Parameter Chloride Sulfate Pace Analytical Services, Inc. 098onic8ffte. Suite 100 Huntersville, NC 28078 (704)875-9092 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 502 479 95 80-120 502 476 95 80-120 92245637001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 3670 680 15 80-120 M1 187J 3670 800 17 80-120 M1 92245637001 Dup Units Result Result mg/kg ND ND mg/kg 187J 201J Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 62 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040313 Pace Project No.: 92245637 QC Batch: WETA/45548 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92245637003, 92245637004, 92245637005 METHOD BLANK: 1187887 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 04/18/15 20:52 LABORATORY CONTROL SAMPLE: 1187888 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 50 50.3 101 80-120 MATRIX SPIKE SAMPLE: 1187890 92245417003 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 59 55.5 94 80-120 H3 SAMPLE DUPLICATE: 1187889 92245417003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 63 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 0988 i vfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15040313 Pace Project No.: 92245637 QC Batch: WETA/45718 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92245637001 METHOD BLANK: 1192873 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.1 04/23/15 12:41 LABORATORY CONTROL SAMPLE: 1192874 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 50.2 49.1 98 80-120 MATRIX SPIKE SAMPLE: 1192876 92245637001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 367 67.4 18 80-120 H3,M1 SAMPLE DUPLICATE: 1192875 92245637001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 64 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 0988 i vfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: J15040313 Pace Project No.: 92245637 QC Batch: WETA/28320 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92245637001, 92245637003, 92245637004, 92245637005 METHOD BLANK: 1151702 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 05/06/15 13:21 LABORATORY CONTROL SAMPLE: 1151703 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 125000 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1151704 1151705 MS MSD 92245627003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 104000 91000 91700 208000 206000 114 111 50-150 1 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1151706 1151707 MS MSD 92245627004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 82900 65500 64400 160000 141000 118 90 50-150 13 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 65 of 71 aceAnaiXical www.pacelabs.com QUALIFIERS Project: J15040313 Pace Project No.: 92245637 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-M Pace Analytical Services - Minneapolis PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICP/14506 [1] Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. Batch: ICPM/9649 [1j Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. Batch: ICP/14514 [1] Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D4 Sample was diluted due to the presence of high levels of target analytes. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 66 of 71 aceAnaiXical www.pacelabs.com QUALIFIERS Project: J15040313 Pace Project No.: 92245637 ANALYTE QUALIFIERS Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, INC 28078 (704)875-9092 H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TNI accreditation for this parameter. P8 Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. R1 RPD value was outside control limits. Z2 Analyte present in the associated method blank above the detection limit. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 67 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, Inc. 0988 i vfte. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15040313 92245637 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92245637001 2015010642 EPA 3050 MPRP/23746 EPA 6010 ICP/14514 92245637003 2015010644 EPA 3050 MPRP/23716 EPA 6010 ICP/14506 92245637004 2015010645 EPA 3050 MPRP/23716 EPA6010 ICP/14506 92245637005 2015010646 EPA 3050 MPRP/23716 EPA 6010 ICP/14506 92245637001 2015010642 EPA 3050 MPRP/23747 EPA 6020 ICPM/9654 92245637003 2015010644 EPA 3050 MPRP/23717 EPA 6020 ICPM/9649 92245637004 2015010645 EPA 3050 MPRP/23717 EPA 6020 ICPM/9649 92245637005 2015010646 EPA 3050 MPRP/23717 EPA 6020 ICPM/9649 92245637006 2015010647 EPA 3020 MPRP/53712 EPA 6020A ICPM/23855 92245637007 2015010643 SPLP EPA 3020 MPRP/54102 EPA 6020A ICPM/24074 92245637008 2015010644 SPLP EPA 3020 MPRP/54102 EPA 6020A ICPM/24074 92245637006 2015010647 EPA 7470 MERP/13265 EPA 7470 MERC/15439 92245637007 2015010643 SPLP EPA 7470A MERP/13418 EPA 7470A MERC/15601 92245637008 2015010644 SPLP EPA 7470A MERP/13418 EPA 7470A MERC/15601 92245637001 2015010642 EPA 7471 MERP/5636 EPA 7471 MERC/5622 92245637003 2015010644 EPA 7471 MERP/5618 EPA 7471 MERC/5615 92245637004 2015010645 EPA 7471 MERP/5618 EPA 7471 MERC/5615 92245637005 2015010646 EPA 7471 MERP/5618 EPA 7471 MERC/5615 92245637001 2015010642 ASTM D2974-87 PMST/3483 92245637003 2015010644 ASTM D2974-87 PMST/3483 92245637004 2015010645 ASTM D2974-87 PMST/3483 92245637005 2015010646 ASTM D2974-87 PMST/3483 92245637001 2015010642 EPA 9045 WET/36947 92245637003 2015010644 EPA 9045 WET/36947 92245637004 2015010645 EPA 9045 WET/36947 92245637005 2015010646 EPA 9045 WET/36947 92245637002 2015010643 EPA 300.0 WETA/22735 92245637003 2015010644 EPA 300.0 WETA/22735 92245637002 2015010643 EPA 353.2 WETA/22748 92245637003 2015010644 EPA 353.2 WETA/22748 92245637002 2015010643 SM 4500 -CI -E WETA/22743 92245637003 2015010644 SM 4500 -CI -E WETA/22743 92245637001 2015010642 EPA 9056 WETA/45694 92245637003 2015010644 EPA 9056 WETA/45549 92245637004 2015010645 EPA 9056 WETA/45549 92245637005 2015010646 EPA 9056 WETA/45549 92245637001 2015010642 EPA 9056 WETA/45718 92245637003 2015010644 EPA 9056 WETA/45548 92245637004 2015010645 EPA 9056 WETA/45548 92245637005 2015010646 EPA 9056 WETA/45548 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/08/2015 03:41 PM without the written consent of Pace Analytical Services, Inc.. Page 68 of 71 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15040313 Pace Project No.: 92245637 Lab ID Sample ID QC Batch Method QC Batch 92245637001 2015010642 EPA 9060 WETA/28320 92245637001 2015010642 EPA 9060 WETA/28321 92245637003 2015010644 EPA 9060 WETA/28320 92245637003 2015010644 EPA 9060 WETA/28321 92245637004 2015010645 EPA 9060 WETA/28320 92245637004 2015010645 EPA 9060 WETA/28321 92245637005 2015010646 EPA 9060 WETA/28320 92245637005 2015010646 EPA 9060 WETA/28321 Date: 05/08/2015 03:41 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 098onyfte. Suite 100 Huntersville, NC 28078 (704)875-9092 Analytical Method Analytical Batch Page 69 of 71 Document Name: f aceAnalytical Sample Condition Upon Recei Document Number: F-CHR-CS-003-rev.15 Client Name: LA 14, nr' Document Revised: September 22.20'14 Pa e 1 of 2 Issuing Aut pj79 of 81 Pace Huntersville Quality Office Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client ❑ mercial❑ /.ae.Other Custody SeaE on CoolerlBox Present: ❑ yew no Seals in yes ❑ no Packing Material: ❑ Bubbie VDD _ Bubble Bags ❑ None ❑ Other Thermometer Used: IR Gun 140 Type of lce:t Blue None []-Samples on ice, cooling process has begun Temp Correction Factor T1401 No Correction t' -C Biological Tissue is Frozen: Yes No rA Date and Initials of pe n ex mi (/ Corrected Cooler Temp.: V contents: Temp should be above freezing to G'C Comments: Chain of Custody Present: Des ❑N!A 1. Chain of Custody Filled Out; es ❑NIA 2. Chain of Custody Relinquished: es ❑NIA 3. Sampler Name & Signature on COC: 016, ❑ ❑NIA 4. Samples Arrived within Hold Time: ❑ es ❑No ❑ 5. Short Hold Time Analysis (<72hr): ©Yes ❑ fA 6. Rush Turn Around Time Requested: 0Yeso,0N1A 7. 6 ❑NIA 8. Sufficient Volume: es Correct Containers Used:es ❑No ❑ K 9. -Pace Containers Used: Dyes o ❑NIA Containers Intact: ❑es El N. QNIA 1 Filtered volume received for Dissolved tests Dyes ❑ E] IA 11. Sample Labels match COC: la s ❑No ❑NIA 12. - -Includes dateltimellDlAnalysis Matrix: All containers needing preservation have been chocked. es gJo ❑NIA 13. All containers needing preservation are found to be in Yes ❑No ❑NdA compliance with EPA recommendation. exceptions: VOA, coliform, FOC, O&G, WI -DRO (water) Dyes ❑N Samples checked for dechlorination: ❑Yes ❑No ❑ IA Headspace in VOA Vials (>6mm): Dyes ❑No 0N1A 15. Trip Blank Present: ❑Yes ❑No ❑ IA Q. Trip Blank Custody Seals Present Dyes ❑No 046/ Pace Trip Blank Lot # (if purchased): Client Notification! Resolution: Field Data Required? Y 1 N Person Contacted: Date/Time: Comments/ Resolution: SCURF Review: Date: W0#:92245'6-3---7 0#:92245637 SRF Review: Date: 1rQ !S Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (Le out of hold, incorrect preservative, out of temp, 92243637 incorrect containers) Page 70 of 71 CA b n w - - -.. T.._ ,_ _ - _• 5 L n C C � � c p S � yyyOE` I F Customer to completo appropriala columna to 0 c v M m X it j L I L V! lh O v Page 80 of 81 Cuetonw must Complete CL a am m n b C � >J r 1 m i2 � �; +.� �' o a v � y '"^ o — Le O as A ro n 3 9 F� D n ±� v 0 7 O. " O C O A ryoCL 3 ©a^ 4 N a a C RR 3 m S n m M (D N Y Q N Y "Grab Req Ire m x? a� Total Metals , Anions, �-� w! i O! N CL v A i 0V q S a[( pH , w MO m n w pn a °c n "[ 1 -8 oz jar (PACE) 5 rr!;U d 3 1'0 SCIt a V t N a p v e n m g R „ z i 6 4 (PACE) u Z I a � i Pt O SPLP - Total Metals 0 -n I o I I a am m � >J r 1 m i2 � �; +.� �' 1m 0 1m �1 '"^ o — Le O as A n 3 9 F� D 10 ~5 a M rn 'D �0�p y 42.0> v O. " 0 O3 n�p 1tv C 9l$ IZ w 13 yI m m OR "Comp. lap alys s I u n o $ !n a i D DI "Grab Req Ire m x? a� Total Metals , Anions, �-� w! i O! N a[( pH ;: i cn "[ 1 -8 oz jar (PACE) 5 rr!;U 1'0 SCIt a o!M 0010 TQC 1- 4 oz jar a 3 a i m (PACE) 3. ®! -^i SPLP - Total Metals 0 -n and Anions ; Q 2 - 8 oz jars (PACE) 5 p a f o Sediment specific tests 2 - 8 oz jar (ACCESS a ; ANALYTICAL) 5 m i i I Ii i-0 Q m I8IK I i u. I :00 a Da r S e7 O C z�z� �rolaI p of Conlalners Page 71 of 71 CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM Page 81 of 81 DUKE Analytical Laboratory Services i Mail Code MG03A2 (Building 7405) ! i work order Analytical Laboratory Use Onlyi / Accepted B Date/ri Pew 1 t Sd x 40� 13339 Hagers Ferry Rd ! ! Matdx: SOIL Days _d X ✓ Relinquish _ Acc y; Da m! I TI DISTRIBUTION Hunte(9ville, C. 2eo7a ( a ENERGY ! 1 `J' Ileeped By Dete a 7'Im. SamplesDd Originating From DH _ ORIGINAL LAB, 24)Comments Metals: At, Sb, As, Ba, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Na, Sr, TI, V, Zn, Mercury, pH$j{r".`` 5- (960) E75-5245 1 975-4349 1 - �� i I ��)mJ �" Add Cost Will Apply L i COPY to CLIENT _ _ _ _ _ _Fax,9a0Z ------------ I "" " - SAMPLE PROGRAM Ground Water_ NPDESI 1)Project Name AB Groundwater Assessment - Soil 2)Phone No: /t L Other_ Plant_ 1 m Asheville Cooler T mo IC) REV DATE 2/10/2015 ii 3)CIknd E 4)Fax No: AB GW t6Pr serv.:1=H SYNTERRA EGD n 2=H SO4 3=H E 4=Ice = one LO to to 5)Business IMM: '�6)Pro t to: 7)Mat1 Code: 8) Operating UnM: 9)Activhy ID: 10)Process ID PACE 1142081 y 1. C ` M PO W Q L) W m V Q v Lt lmDOrtant: When specific accounting has been established and is not indicated above Preservatives when used must be rn d N a fl. N J O o U we need the following: 1) Enter correct accounting in all 5 accounting fields above, Or 2 Provide correct acc.untin for O eratin Unit and Process ID. added within 15 minutes of sample to r_ N v O to h w ` rn Q W O collection IA p I • USE ONLY I Matrix "Collection Information O W ` U OLAB _ N E W J 't3 ) L) I „ ! (Soli, Sediment, Ash) 13 i Lab ID ; Sam le Description or ID Data Time Si nature E tj co 0 Z ~ C, r , L) O Q - d J co O_ C e fn cp N Q 4) N t-% Z N 1_ 1,/.� S - - •Ar8 — 3S 3' S ' 13 ►l¢20 'Sa- 1 � S' 4 Il Is le2S 2 04 : » MW 1 33 -34''API wly 1 1 1 t(a'; 01.0 Q -%DI) N moo I Iz a t is 131 Isar X I I� 1 I tj t � I 1 1 I I WATER EQUIPMENT BLANK (1 PER DAY) 21)Relinquished B Date/Time r - S Accepted By: Date/T{me 22 / Accepted B Date/ri a Requested(jTlurTjn rohund L �) Relinquished By _ Date/Tlitte Days _d X ✓ Relinquish _ Acc y; Da m! Days Sealed/Locked By te/Tirne sea (Lock opened By DateMma • 48 Hr 24)Comments Metals: At, Sb, As, Ba, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Na, Sr, TI, V, Zn, Mercury, pH$j{r".`` Anions: Cl, Nitrate -N, SO4 Sediment Specific Parameters: %Solids, CEC, Particle Size Distribution, Redox Potential Add Cost Will Apply