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Home My WebLink AboutNC0000396_J15040226 Report_20150823DUE Analytical Laboratory Page 1of85 ENERGY Order Number: Project Name: Customer Name(s): Customer Address: Lab Contact: Report Authorized By: (Signature) Program Comments: 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report J15040226 ASHEVILLE - AB GW ASSESSMENT SOIL Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker 200 CP and L Drive Arden,NC 28704 Margaret Galvin -Karr Phone: 980-875-5219 MXG4644(101161) e 2015.05.1810:31:22 U -04'00'Date: Margaret Galvin -Karr Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 5/6/2015 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015010182 ASHEVILLE 07 -Apr -15 9:40 AM Russo Equipment Blank 2015010183 ASHEVILLE 07 -Apr -15 9:40 AM Russo ABMW-07 SB (3-4) 2015010184 ASHEVILLE 07 -Apr -15 11:25 AM Russo ABMW07 SB (7-9) 2015010185 ASHEVILLE 07 -Apr -15 10:45 AM Russo ABMW-07 SB (14-16) 2015010186 ASHEVILLE 07 -Apr -15 11:30 AM Russo ABMW-07 SB (26-27) 2015010187 ASHEVILLE 07 -Apr -15 9:55 AM Russo MW -07 SB (1-2) 2015010188 ASHEVILLE 07 -Apr -15 12:35 PM Russo MW -07 SB (10-11) 2015010189 ASHEVILLE 07 -Apr -15 12:40 PM Russo MW -07 SB (16-17) 8 Total Samples Page 2 of 85 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes No All laboratory QA/QC requirements are acceptable. (] Yes ❑ No Report Sections Included: LU Job Summary Report ❑ Sample Identification P/1 Technical Validation of Data Package J❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Page 3 of 85 LVI Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries d❑ Chain of Custody LVI Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 5/6/2015 Certificate of Laboratory Analysis Page 4 of 85 This report shall not be reproduced, except in full. Order # J15040226 Site: Equipment Blank Collection Date: 07 -Apr -15 9:40 AM Analyte Result Units Qualifiers RDL DF METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Sample #: 2015010182 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040226 Site: ABMW-07 SB (3-4) Collection Date: 07 -Apr -15 9:40 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 5 of 85 Sample #: 2015010183 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040226 Site: ABMW07 SB (7-9) Collection Date: 07 -Apr -15 11:25 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 6 of 85 Sample #: 2015010184 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040226 Site: ABMW-07 SB (14-16) Collection Date: 07 -Apr -15 10:45 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 7 of 85 Sample #: 2015010185 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040226 Site: ABMW-07 SB (26-27) Collection Date: 07 -Apr -15 11:30 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 8 of 85 Sample #: 2015010186 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040226 Site: MW -07 SB (1-2) Collection Date: 07 -Apr -15 9:55 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 9 of 85 Sample #: 2015010187 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040226 Site: MW -07 SB (10-11) Collection Date: 07 -Apr -15 12:35 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SPLP LEACHATE - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 10 of 85 Sample #: 2015010188 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040226 Site: MW -07 SB (16-17) Collection Date: 07 -Apr -15 12:40 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Page 11 of 85 Sample #: 2015010189 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE aceAnaiXical www.pacelabs.com April 29, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 RE: Project: J15040226 Pace Project No.: 92245084 Pace Analytical Services, Inc. �Q�ff�i�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on April 10, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy HiQ p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 73 lacmnalyfica( www.pacelabs.com Project: J15040226 Pace Project No.: 92245084 Minnesota Certification IDs 1700 Elm Street SE Suite 200, Minneapolis, MN 55414 A21 -A Certification #: 2926.01 Alaska Certification #: UST -078 Alaska Certification #MN00064 Alabama Certification #40770 Arizona Certification #: AZ -0014 Arkansas Certification #: 88-0680 California Certification #: 01155CA Colorado Certification #Pace Connecticut Certification #: PH -0256 EPA Region 8 Certification #: 8TMS-L Florida/NELAP Certification #: E87605 Guam Certification #:14-008r Georgia Certification #: 959 Georgia EPD #: Pace Idaho Certification #: MN00064 Hawaii Certification #MN00064 Illinois Certification #: 200011 Indiana Certification#C-MN-01 Iowa Certification #: 368 Kansas Certification #: E-10167 Kentucky Dept of Envi. Protection - DW #90062 Kentucky Dept of Envi. 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Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Minnesota Certification #: 027-053-137 Mississippi Certification #: Pace Montana Certification #: MT0092 Nevada Certification #: MN_00064 Nebraska Certification #: Pace New Jersey Certification #: MN -002 New York Certification #: 11647 North Carolina Certification #: 530 North Carolina State Public Health #: 27700 North Dakota Certification #: R-036 Ohio EPA#: 4150 Ohio VAP Certification #: CL101 Oklahoma Certification #: 9507 Oregon Certification #: MN200001 Oregon Certification #: MN300001 Pennsylvania Certification #: 68-00563 Puerto Rico Certification Saipan (CNMI) #:MP0003 South Carolina #:74003001 Texas Certification #: T104704192 Tennessee Certification #: 02818 Utah Certification #: MN000642013-4 Virginia DGS Certification #: 251 Virginia/VELAP Certification #: Pace Washington Certification #: C486 West Virginia Certification #: 382 West Virginia DHHR #:9952C Wisconsin Certification #: 999407970 Montana Certification #: Cert 0074 Nebraska Certification: NE -OS -28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification #: FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 73 aceAnaiXical www.pacelabs.com Project: J15040226 Pace Project No.: 92245084 Asheville Certification IDs North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 CERTIFICATIONS West Virginia Certification #: 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. �Q�ff�ic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Page 3 of 73 aceAnaiXical www.pacelabs.com SAMPLE SUMMARY Project: J15040226 Pace Project No.: 92245084 Lab ID Sample ID Matrix Date Collected Date Received 92245084001 2015010182 Water 04/07/15 09:40 04/10/15 16:35 92245084002 2015010183 SPLP Water 04/07/15 09:40 04/10/15 16:35 92245084003 2015010185 SPLP Water 04/07/15 10:45 04/10/15 16:35 92245084004 2015010188 SPLP Water 04/07/15 12:35 04/10/15 16:35 92245084005 2015010183 Solid 04/07/15 09:40 04/10/15 16:35 92245084006 2015010185 Solid 04/07/1510:45 04/10/1516:35 92245084007 2015010188 Solid 04/07/1510:45 04/10/1516:35 92245084008 2015010184 Solid 04/07/1511:25 04/10/1516:35 92245084009 2015010186 Solid 04/07/1511:30 04/10/1516:35 92245084010 2015010187 Solid 04/07/15 09:55 04/10/15 16:35 92245084011 2015010189 Solid 04/07/1512:40 04/10/1516:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. �Q�ff�i�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Page 4 of 73 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15040226 92245084 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92245084001 2015010182 EPA 6020A RJS 24 PASI-M EPA 7470 JDD 1 PASI-M 92245084002 2015010183 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A DM 1 PASI-M 92245084003 2015010185 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A DM 1 PASI-M 92245084004 2015010188 SPLP EPA 6020A TT3 24 PASI-M EPA 7470A DM 1 PASI-M 92245084005 2015010183 EPA 6010 CKJ, TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AEM 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92245084006 2015010185 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AEM 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A SM 4500 -CI -E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92245084007 2015010188 EPA 6010 CKJ, TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AEM 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 300.0 AES2 1 PASI-A EPA 353.2 DMN 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 73 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Project: J15040226 Pace Project No.: 92245084 Pace Analytical Services, Inc. �Q�fflic&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID Method Analysts Analytes Reported Laboratory SM 4500 -CI -E SER 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92245084008 2015010184 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AIS 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92245084009 2015010186 EPA 6010 CKJ, TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AIS 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92245084010 2015010187 EPA 6010 CKJ, TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AIS 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92245084011 2015010189 EPA 6010 CKJ, TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AIS 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 73 aceAnaiXical www.pacelabs.com Project: J15040226 Pace Project No.: 92245084 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. �Q�ffligc&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92245084001 2015010182 EPA 6020A Aluminum 612 ug/L 10.0 04/17/15 18:08 EPA 6020A Barium 18.0 ug/L 0.30 04/17/15 18:08 EPA 6020A Calcium 294 ug/L 40.0 04/20/15 15:03 EPA 6020A Chromium 3.3 ug/L 0.50 04/17/15 18:08 EPA 6020A Cobalt 32.1 ug/L 0.50 04/17/15 18:08 EPA 6020A Copper 3.0 ug/L 1.0 04/17/15 18:08 EPA 6020A Iron 2000 ug/L 50.0 04/17/15 18:08 EPA 6020A Lead 1.6 ug/L 0.10 04/17/15 18:08 EPA 6020A Magnesium 182 ug/L 10.0 04/17/15 18:08 EPA 6020A Manganese 181 ug/L 0.50 04/17/15 18:08 EPA 6020A Molybdenum 0.85 ug/L 0.50 04/17/15 18:08 EPA 6020A Nickel 1.8 ug/L 0.50 04/17/15 18:08 EPA 6020A Potassium 180 ug/L 50.0 04/17/15 18:08 EPA 6020A Sodium 243 ug/L 50.0 04/17/15 18:08 EPA 6020A Strontium 1.1 ug/L 0.50 04/17/15 18:08 EPA 6020A Zinc 8.9 ug/L 5.0 04/17/15 18:08 92245084002 2015010183 SPLP EPA 6020A Aluminum 6850 ug/L 50.0 04/24/1514:42 M1 EPA 6020A Antimony 6.2 ug/L 2.5 04/24/15 14:42 EPA 6020A Arsenic 111 ug/L 2.5 04/24/15 14:42 EPA 6020A Barium 360 ug/L 1.5 04/24/15 14:42 EPA 6020A Beryllium 0.52J ug/L 1.0 04/24/15 14:42 EPA 6020A Boron 140 ug/L 25.0 04/24/15 14:42 EPA 6020A Calcium 5080 ug/L 200 04/24/15 14:42 EPA 6020A Chromium 16.1 ug/L 2.5 04/24/15 14:42 EPA 6020A Cobalt 2.9 ug/L 2.5 04/24/15 14:42 EPA 6020A Copper 10.8 ug/L 5.0 04/24/15 14:42 EPA 6020A Iron 4990 ug/L 250 04/24/15 14:42 EPA 6020A Lead 3.4 ug/L 0.50 04/24/15 14:42 EPA 6020A Magnesium 722 ug/L 50.0 04/24/15 14:42 EPA 6020A Manganese 32.3 ug/L 2.5 04/24/15 14:42 EPA 6020A Molybdenum 50.3 ug/L 2.5 04/24/15 14:42 EPA 6020A Nickel 4.5 ug/L 2.5 04/24/15 14:42 EPA 6020A Potassium 818 ug/L 250 04/24/15 14:42 EPA 6020A Selenium 65.5 ug/L 2.5 04/24/15 14:42 EPA 6020A Sodium 2660 ug/L 250 04/24/15 14:42 EPA 6020A Strontium 218 ug/L 2.5 04/24/15 14:42 EPA 6020A Thallium 0.26J ug/L 0.50 04/24/15 14:42 EPA 6020A Vanadium 67.7 ug/L 5.0 04/24/15 14:42 EPA 6020A Zinc 53.8 ug/L 25.0 04/24/15 14:42 92245084003 2015010185 SPLP EPA 6020A Aluminum 8.2J ug/L 10.0 04/24/15 14:22 EPA 6020A Antimony 0.36J ug/L 0.50 04/24/15 14:22 EPA 6020A Barium 129 ug/L 0.30 04/24/15 14:22 EPA 6020A Boron 97.9 ug/L 5.0 04/24/15 14:22 EPA 6020A Cadmium 0.031J ug/L 0.080 04/24/1514:22 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 73 aceAnaiXical www.pacelabs.com Project: J15040226 Pace Project No.: 92245084 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. �Q�ffli�c&fie. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92245084003 2015010185 SPLP EPA 6020A Calcium 2430 ug/L 40.0 04/24/15 14:22 EPA 6020A Chromium 0.84 ug/L 0.50 04/24/15 14:22 EPA 6020A Cobalt 0.45J ug/L 0.50 04/24/15 14:22 EPA 6020A Magnesium 255 ug/L 10.0 04/24/15 14:22 EPA 6020A Manganese 15.6 ug/L 0.50 04/24/15 14:22 EPA 6020A Molybdenum 97.6 ug/L 0.50 04/24/15 14:22 EPA 6020A Nickel 0.27J ug/L 0.50 04/24/15 14:22 EPA 6020A Potassium 1930 ug/L 50.0 04/24/15 14:22 EPA 6020A Sodium 2070 ug/L 50.0 04/24/15 14:22 EPA 6020A Strontium 59.8 ug/L 0.50 04/24/15 14:22 EPA 6020A Thallium 0.0191 ug/L 0.10 04/24/15 14:22 EPA 6020A Zinc 39.0 ug/L 5.0 04/24/15 14:22 92245084004 2015010188 SPLP EPA 6020A Aluminum 10.7 ug/L 10.0 04/24/15 14:25 EPA 6020A Barium 131 ug/L 0.30 04/24/15 14:25 EPA 6020A Boron 74.2 ug/L 5.0 04/24/15 14:25 EPA 6020A Calcium 1270 ug/L 40.0 04/24/15 14:25 EPA 6020A Chromium 0.31J ug/L 0.50 04/24/1514:25 EPA 6020A Cobalt 1.8 ug/L 0.50 04/24/15 14:25 EPA 6020A Magnesium 326 ug/L 10.0 04/24/15 14:25 EPA 6020A Manganese 129 ug/L 0.50 04/24/15 14:25 EPA 6020A Molybdenum 12.4 ug/L 0.50 04/24/15 14:25 EPA 6020A Nickel 0.22J ug/L 0.50 04/24/15 14:25 EPA 6020A Potassium 1450 ug/L 50.0 04/24/15 14:25 EPA 6020A Sodium 2660 ug/L 50.0 04/24/15 14:25 EPA 6020A Strontium 39.9 ug/L 0.50 04/24/15 14:25 EPA 6020A Zinc 21.3 ug/L 5.0 04/24/15 14:25 92245084005 2015010183 EPA 6010 Aluminum 11700 mg/kg 6.4 04/20/15 15:22 EPA 6010 Barium 412 mg/kg 0.64 04/20/15 15:22 EPA 6010 Beryllium 3.4 mg/kg 0.32 04/25/15 15:12 EPA 6010 Boron 14AJ mg/kg 16.1 04/25/15 15:12 EPA 6010 Calcium 3770 mg/kg 32.1 04/20/15 15:22 EPA 6010 Chromium 27.9 mg/kg 1.6 04/25/15 15:12 EPA 6010 Copper 46.1 mg/kg 1.6 04/25/15 15:12 EPA 6010 Iron 12200 mg/kg 2.6 04/20/15 15:22 EPA 6010 Magnesium 1200 mg/kg 32.1 04/20/15 15:22 EPA 6010 Manganese 177 mg/kg 1.6 04/25/15 15:12 EPA 6010 Molybdenum 3.0 mg/kg 0.64 04/20/15 15:22 EPA 6010 Nickel 19.3 mg/kg 0.32 04/20/15 15:22 EPA 6010 Potassium 2130 mg/kg 64.3 04/20/15 15:22 EPA 6010 Sodium 259 mg/kg 64.3 04/20/15 15:22 EPA 6010 Strontium 183 mg/kg 0.64 04/20/15 15:22 EPA 6010 Zinc 33.1 mg/kg 1.3 04/20/15 15:22 EPA 6020 Arsenic 82.2 mg/kg 6.4 04/22/15 02:39 EPA 6020 Cadmium 0.48J mg/kg 0.77 04/22/15 02:39 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. D3 D3 D3 D3 Qualifiers Page 8 of 73 aceAnaiXical www.pacelabs.com Project: J15040226 Pace Project No.: 92245084 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 0988 i - �e. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92245084005 2015010183 EPA 6020 Cobalt 14.1 mg/kg 6.4 04/22/15 02:39 EPA 6020 Lead 18.4 mg/kg 6.4 04/22/15 02:39 EPA 6020 Selenium 8.3 mg/kg 6.4 04/22/15 02:39 EPA 6020 Vanadium 68.0 mg/kg 6.4 04/22/15 02:39 EPA 7471 Mercury 0.24 mg/kg 0.010 04/20/15 21:21 ASTM D2974-87 Percent Moisture 21.8 % 0.10 04/16/15 16:16 EPA 9045 pH at 25 Degrees C 7.2 Std. Units 0.10 04/14/15 15:10 EPA 300.0 Sulfate 11.9 mg/L 2.6 04/19/15 15:11 EPA 353.2 Nitrogen, Nitrate 0.29 mg/L 0.26 04/22/15 17:33 EPA 9056 Sulfate 183J mg/kg 324 04/15/15 14:51 EPA 9060 Total Organic Carbon 83900 mg/kg 6400 04/28/15 09:13 EPA 9060 Total Organic Carbon 92100 mg/kg 6770 04/28/15 09:19 EPA 9060 Total Organic Carbon 92300 mg/kg 6330 04/28/15 09:25 EPA 9060 Total Organic Carbon 82700 mg/kg 6620 04/28/15 09:31 EPA 9060 Mean Total Organic Carbon 87800 mg/kg 6530 04/28/15 09:13 EPA 9060 RSD% 5.9 % 04/28/15 09:13 92245084006 2015010185 EPA 6010 Aluminum 38900 mg/kg 71.6 04/25/15 15:28 EPA 6010 Barium 116 mg/kg 7.2 04/25/15 15:28 EPA 6010 Beryllium 3.1 mg/kg 0.72 04/25/15 15:28 EPA 6010 Calcium 533 mg/kg 358 04/25/15 15:28 EPA 6010 Chromium 24.2 mg/kg 3.6 04/25/15 15:28 EPA 6010 Copper 46.9 mg/kg 3.6 04/25/15 15:28 EPA 6010 Iron 54000 mg/kg 28.6 04/25/15 15:28 EPA 6010 Magnesium 7760 mg/kg 358 04/25/15 15:28 EPA 6010 Manganese 2200 mg/kg 3.6 04/25/15 15:28 EPA 6010 Molybdenum 42.3 mg/kg 7.2 04/25/15 15:28 EPA 6010 Nickel 42.5 mg/kg 3.6 04/25/15 15:28 EPA 6010 Potassium 6280 mg/kg 716 04/25/15 15:28 EPA 6010 Strontium 31.0 mg/kg 7.2 04/25/15 15:28 EPA 6010 Zinc 161 mg/kg 14.3 04/25/15 15:28 EPA 6020 Cobalt 206 mg/kg 7.2 04/22/15 02:41 EPA 6020 Lead 8.3 mg/kg 7.2 04/22/15 02:41 EPA 6020 Selenium 3.9J mg/kg 7.2 04/22/15 02:41 EPA 6020 Vanadium 39.2 mg/kg 7.2 04/22/15 02:41 ASTM D2974-87 Percent Moisture 29.1 % 0.10 04/16/15 16:16 EPA 9045 pH at 25 Degrees C 6.7 Std. Units 0.10 04/14/15 15:10 EPA 300.0 Sulfate 11.7 mg/L 2.8 04/19/15 15:25 EPA 9060 Total Organic Carbon 2680 mg/kg 849 04/28/15 10:23 EPA 9060 Total Organic Carbon 2530 mg/kg 843 04/28/15 10:30 EPA 9060 Total Organic Carbon 2180 mg/kg 846 04/28/15 10:36 EPA 9060 Total Organic Carbon 2260 mg/kg 845 04/28/15 10:43 EPA 9060 Mean Total Organic Carbon 2410 mg/kg 846 04/28/15 10:23 EPA 9060 RSD% 9.7 % 04/28/15 10:23 92245084007 2015010188 EPA 6010 Aluminum 13300 mg/kg 7.0 04/20/15 15:31 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. B H1 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 B Qualifiers Page 9 of 73 aceAnaiXical www.pacelabs.com Project: J15040226 Pace Project No.: 92245084 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 0988 nlc&� e. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92245084007 2015010188 EPA 6010 Barium 103 mg/kg 0.70 04/20/15 15:31 EPA 6010 Beryllium 1.0 mg/kg 0.35 04/25/15 15:32 EPA 6010 Calcium 2650 mg/kg 35.2 04/20/15 15:31 EPA 6010 Chromium 22.5 mg/kg 1.8 04/25/15 15:32 EPA 6010 Copper 17.0 mg/kg 1.8 04/25/15 15:32 EPA 6010 Iron 53200 mg/kg 14.1 04/25/15 15:32 EPA 6010 Magnesium 6780 mg/kg 35.2 04/20/15 15:31 EPA 6010 Manganese 669 mg/kg 1.8 04/25/15 15:32 EPA 6010 Nickel 26.8 mg/kg 0.35 04/20/15 15:31 EPA 6010 Potassium 1270 mg/kg 70.5 04/20/15 15:31 EPA 6010 Sodium 108 mg/kg 70.5 04/20/15 15:31 EPA 6010 Strontium 19.4 mg/kg 0.70 04/20/15 15:31 EPA 6010 Zinc 99.0 mg/kg 1.4 04/20/15 15:31 EPA 6020 Arsenic 3.6J mg/kg 7.0 04/22/15 02:44 EPA 6020 Cobalt 18.3 mg/kg 7.0 04/22/15 02:44 EPA 6020 Lead 25.2 mg/kg 7.0 04/22/15 02:44 EPA 6020 Vanadium 26.7 mg/kg 7.0 04/22/15 02:44 ASTM D2974-87 Percent Moisture 26.0 % 0.10 04/16/15 16:17 EPA 9045 pH at 25 Degrees C 6.4 Std. Units 0.10 04/14/15 15:10 EPA 300.0 Sulfate 9.9 mg/L 2.7 04/19/15 15:38 EPA 9060 Total Organic Carbon 646J mg/kg 806 04/28/15 10:49 EPA 9060 Total Organic Carbon 725J mg/kg 810 04/28/15 10:56 EPA 9060 Total Organic Carbon 679J mg/kg 805 04/28/15 11:01 EPA 9060 Total Organic Carbon 673J mg/kg 815 04/28/15 11:06 EPA 9060 Mean Total Organic Carbon 681J mg/kg 809 04/28/15 10:49 EPA 9060 RSD% 4.8 % 04/28/15 10:49 92245084008 2015010184 EPA 6010 Aluminum 22500 mg/kg 35.6 04/25/15 15:36 EPA 6010 Barium 395 mg/kg 3.6 04/25/15 15:36 EPA 6010 Beryllium 3.7 mg/kg 0.36 04/25/15 15:36 EPA 6010 Boron 10.8J mg/kg 17.8 04/25/15 15:36 EPA 6010 Calcium 2930 mg/kg 178 04/25/15 15:36 EPA 6010 Chromium 34.2 mg/kg 1.8 04/25/15 15:36 EPA 6010 Copper 59.0 mg/kg 1.8 04/25/15 15:36 EPA 6010 Iron 27300 mg/kg 14.2 04/25/15 15:36 EPA 6010 Magnesium 2590 mg/kg 178 04/25/15 15:36 EPA 6010 Manganese 200 mg/kg 1.8 04/25/15 15:36 EPA 6010 Molybdenum 10.6 mg/kg 3.6 04/25/15 15:36 EPA 6010 Nickel 28.4 mg/kg 1.8 04/25/15 15:36 EPA 6010 Potassium 3290 mg/kg 356 04/25/15 15:36 EPA 6010 Sodium 384 mg/kg 356 04/25/15 15:36 EPA 6010 Strontium 245 mg/kg 3.6 04/25/15 15:36 EPA 6010 Zinc 77.2 mg/kg 7.1 04/25/15 15:36 EPA 6020 Arsenic 105 mg/kg 7.1 04/22/15 02:46 EPA 6020 Cadmium 0.43J mg/kg 0.85 04/22/15 02:46 EPA 6020 Cobalt 20.6 mg/kg 7.1 04/22/15 02:46 EPA 6020 Lead 21.2 mg/kg 7.1 04/22/15 02:46 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. D3 D3 D3 D3 B D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 Qualifiers Page 10 of 73 aceAnaiXical www.pacelabs.com Project: J15040226 Pace Project No.: 92245084 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 0988 �c&� e. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92245084008 2015010184 EPA 6020 Selenium 11.9 mg/kg 7.1 04/22/15 02:46 EPA 6020 Vanadium 80.5 mg/kg 7.1 04/22/15 02:46 EPA 7471 Mercury 0.14 mg/kg 0.011 04/20/15 21:28 ASTM D2974-87 Percent Moisture 29.4 % 0.10 04/17/15 09:32 EPA 9045 pH at 25 Degrees C 7.3 Std. Units 0.10 04/14/15 15:10 EPA 9056 Sulfate 1901 mg/kg 361 04/15/15 15:55 EPA 9060 Total Organic Carbon 33100 mg/kg 8300 04/28/15 11:12 EPA 9060 Total Organic Carbon 36100 mg/kg 8210 04/28/15 11:18 EPA 9060 Total Organic Carbon 38100 mg/kg 7870 04/28/15 11:24 EPA 9060 Total Organic Carbon 34400 mg/kg 8080 04/28/15 11:29 EPA 9060 Mean Total Organic Carbon 35400 mg/kg 8110 04/28/15 11:12 EPA 9060 RSD% 6.2 % 04/28/15 11:12 92245084009 2015010186 EPA 6010 Aluminum 25800 mg/kg 113 04/25/15 18:07 EPA 6010 Barium 182 mg/kg 11.3 04/25/15 18:07 EPA 6010 Calcium 324J mg/kg 564 04/25/15 18:07 EPA 6010 Chromium 24.8 mg/kg 14.1 04/26/15 22:56 EPA 6010 Copper 67.7 mg/kg 14.1 04/26/15 22:56 EPA 6010 Iron 46700 mg/kg 45.1 04/25/15 18:07 EPA 6010 Magnesium 11000 mg/kg 564 04/25/15 18:07 EPA 6010 Manganese 854 mg/kg 14.1 04/26/15 22:56 EPA 6010 Nickel 26.5 mg/kg 5.6 04/25/15 18:07 EPA 6010 Potassium 10200 mg/kg 1130 04/25/15 18:07 EPA 6010 Zinc 130 mg/kg 22.6 04/25/15 18:07 EPA 6020 Arsenic 5.5J mg/kg 5.6 04/22/15 02:48 EPA 6020 Cobalt 25.0 mg/kg 5.6 04/22/15 02:48 EPA 6020 Lead 4.3J mg/kg 5.6 04/22/15 02:48 EPA 6020 Selenium 10 mg/kg 5.6 04/22/15 02:48 EPA 6020 Vanadium 38.8 mg/kg 5.6 04/22/15 02:48 ASTM D2974-87 Percent Moisture 12.8 % 0.10 04/17/15 09:32 EPA 9045 pH at 25 Degrees C 5.6 Std. Units 0.10 04/14/15 15:10 EPA 9060 RSD% 3.6 % 04/28/15 19:07 92245084010 2015010187 EPA 6010 Aluminum 18600 mg/kg 7.5 04/20/15 15:45 EPA 6010 Barium 85.9 mg/kg 0.75 04/20/15 15:45 EPA 6010 Beryllium 0.79 mg/kg 0.37 04/25/15 15:44 EPA 6010 Calcium 268 mg/kg 37.5 04/20/15 15:45 EPA 6010 Chromium 25.5 mg/kg 1.9 04/25/15 15:44 EPA 6010 Copper 11.8 mg/kg 1.9 04/25/15 15:44 EPA 6010 Iron 18600 mg/kg 3.0 04/20/15 15:45 EPA 6010 Magnesium 2210 mg/kg 37.5 04/20/15 15:45 EPA 6010 Manganese 162 mg/kg 1.9 04/25/15 15:44 EPA 6010 Molybdenum 0.82 mg/kg 0.75 04/20/15 15:45 EPA 6010 Nickel 9.4 mg/kg 0.37 04/20/15 15:45 EPA 6010 Potassium 1740 mg/kg 75.0 04/20/15 15:45 EPA 6010 Strontium 2.3 mg/kg 0.75 04/20/15 15:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 D3 Qualifiers Page 11 of 73 aceAnaiXical www.pacelabs.com Project: J15040226 Pace Project No.: 92245084 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 0988 �c&� e. Suite 100 y Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92245084010 2015010187 EPA 6010 Zinc 37.4 mg/kg 1.5 04/20/15 15:45 EPA 6020 Cobalt 10.7 mg/kg 7.5 04/22/15 02:50 EPA 6020 Lead 14.5 mg/kg 7.5 04/22/15 02:50 EPA 6020 Vanadium 39.4 mg/kg 7.5 04/22/15 02:50 EPA 7471 Mercury 0.023 mg/kg 0.012 04/20/15 21:32 ASTM D2974-87 Percent Moisture 31.7 % 0.10 04/17/15 09:32 EPA 9045 pH at 25 Degrees C 5.3 Std. Units 0.10 04/14/15 15:10 EPA 9060 Total Organic Carbon 8470 mg/kg 874 04/28/15 12:00 EPA 9060 Total Organic Carbon 8000 mg/kg 874 04/28/15 12:06 EPA 9060 Total Organic Carbon 8210 mg/kg 881 04/28/15 12:11 EPA 9060 Total Organic Carbon 8360 mg/kg 875 04/28/15 12:18 EPA 9060 Mean Total Organic Carbon 8260 mg/kg 876 04/28/15 12:00 EPA 9060 RSD% 2.5 % 04/28/15 12:00 92245084011 2015010189 EPA 6010 Aluminum 8750 mg/kg 6.9 04/20/15 15:49 EPA 6010 Barium 136 mg/kg 0.69 04/20/15 15:49 EPA 6010 Beryllium 0.61 mg/kg 0.34 04/25/15 15:48 EPA 6010 Calcium 735 mg/kg 34.3 04/20/15 15:49 EPA 6010 Chromium 11.4 mg/kg 1.7 04/25/15 15:48 EPA 6010 Copper 15.5 mg/kg 1.7 04/25/15 15:48 EPA 6010 Iron 12700 mg/kg 2.7 04/20/15 15:49 EPA 6010 Magnesium 1680 mg/kg 34.3 04/20/15 15:49 EPA 6010 Manganese 257 mg/kg 1.7 04/25/15 15:48 EPA 6010 Molybdenum 0.551 mg/kg 0.69 04/20/15 15:49 EPA 6010 Nickel 3.7 mg/kg 0.34 04/20/15 15:49 EPA 6010 Potassium 3140 mg/kg 68.6 04/20/15 15:49 EPA 6010 Sodium 163 mg/kg 68.6 04/20/15 15:49 EPA 6010 Strontium 5.6 mg/kg 0.69 04/20/15 15:49 EPA 6010 Zinc 33.4 mg/kg 1.4 04/20/15 15:49 EPA 6020 Cobalt 6.5J mg/kg 6.9 04/22/15 02:53 EPA 6020 Lead 5AJ mg/kg 6.9 04/22/15 02:53 EPA 6020 Vanadium 17.7 mg/kg 6.9 04/22/15 02:53 ASTM D2974-87 Percent Moisture 24.0 % 0.10 04/17/15 09:32 EPA 9045 pH at 25 Degrees C 7.4 Std. Units 0.10 04/14/15 15:10 EPA 9060 RSD% 2.1 % 04/28/15 12:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. D3 D3 D3 D3 Page 12 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gK4-8y8'1�e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040226 Pace Project No.: 92245084 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 29, 2015 General Information: 7 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23696 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245094011 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1188077) • Aluminum • Barium • Chromium • Iron • Magnesium • Manganese • Nickel • Potassium • Strontium • Zinc • MSD (Lab ID: 1188078) • Aluminum • Barium • Chromium • Copper • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0988 �c&� e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040226 Pace Project No.: 92245084 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 29, 2015 QC Batch: MPRP/23696 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245094011 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • Magnesium • Manganese • Nickel • Potassium • Strontium • Zinc Additional Comments: Analyte Comments: QC Batch: MPRP/23696 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015010183 (Lab ID: 92245084005) • Boron • Chromium • Copper • Manganese •2015010184 (Lab ID: 92245084008) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •2015010185 (Lab ID: 92245084006) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0988 �c&� e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040226 Pace Project No.: 92245084 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 29, 2015 Analyte Comments: QC Batch: MPRP/23696 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015010185 (Lab ID: 92245084006) • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •2015010186 (Lab ID: 92245084009) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc •2015010187 (Lab ID: 92245084010) • Boron • Beryllium • Chromium • Copper • Manganese •2015010188 (Lab ID: 92245084007) • Boron • Beryllium • Chromium • Copper • Manganese •2015010189 (Lab ID: 92245084011) • Boron • Beryllium • Chromium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 73 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15040226 Pace Project No.: 92245084 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 29, 2015 Analyte Comments: QC Batch: MPRP/23696 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015010189 (Lab ID: 92245084011) • Copper • Manganese • MS (Lab ID: 1188077) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc • MSD (Lab ID: 1188078) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc Pace Analytical Services, Inc. 0988 c&� e. Suite 100 y Huntersville, NC 28078 (704)875-9092 P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. • BLANK (Lab ID: 1188075) • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0988 gc&) e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040226 Pace Project No.: 92245084 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 29, 2015 General Information: 7 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23697 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245094012 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1188081) • Antimony • Cobalt • Lead • MSD (Lab ID: 1188082) • Antimony • Cobalt • Lead • Vanadium R1: RPD value was outside control limits. • MSD (Lab ID: 1188082) • Cobalt • Vanadium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 0988 �c&� e. Suite 100 �J Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040226 Pace Project No.: 92245084 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 29, 2015 Additional Comments: Batch Comments: Batch was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICPM / 9631 Analyte Comments: QC Batch: MPRP/23697 N2: The lab does not hold TNI accreditation for this parameter. •2015010183 (Lab ID:92245084005) • Antimony •2015010184 (Lab ID:92245084008) • Antimony •2015010185 (Lab ID:92245084006) • Antimony •2015010186 (Lab ID:92245084009) • Antimony •2015010187 (Lab ID:92245084010) • Antimony •2015010188 (Lab ID:92245084007) • Antimony •2015010189 (Lab ID: 92245084011) • Antimony • BLANK (Lab ID: 1188079) • Antimony • LCS (Lab ID: 1188080) • Antimony • MS (Lab ID: 1188081) • Antimony • MSD (Lab ID: 1188082) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098ninyeie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040226 Pace Project No.: 92245084 Method: EPA 6020A Description: 6020A MET ICPMS Client: Duke Energy Date: April 29, 2015 General Information: 4 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3020 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/53858 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245084002 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1946768) • Aluminum • MSD (Lab ID: 1946769) • Aluminum Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098glsinive) e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040226 Pace Project No.: 92245084 Method: EPA 7470 Description: 7470 Mercury Client: Duke Energy Date: April 29, 2015 General Information: 1 sample was analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098glsinyeie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040226 Pace Project No.: 92245084 Method: EPA 7470A Description: 7470A Mercury Client: Duke Energy Date: April 29, 2015 General Information: 3 samples were analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7470A with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098glsinyeie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040226 Pace Project No.: 92245084 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: April 29, 2015 General Information: 7 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098glsi4v8'1�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040226 Pace Project No.: 92245084 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: April 29, 2015 General Information: 7 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098glsinyeie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040226 Pace Project No.: 92245084 Method: EPA 300.0 Description: 300.0 IC Anions, SPLP Client: Duke Energy Date: April 29, 2015 General Information: 3 samples were analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. QC Batch: WETA/22607 B: Analyte was detected in the associated method blank. • BLANK for HBN 260035 [WETA/226 (Lab ID: 1437291) • Sulfate Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098glsinyeie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040226 Pace Project No.: 92245084 Method: EPA 353.2 Description: 353.2 Nitrogen, NO2/NO3, SPLP Client: Duke Energy Date: April 29, 2015 General Information: 3 samples were analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-11: Analysis conducted outside the EPA method holding time. •2015010183 (Lab ID: 92245084005) •2015010185 (Lab ID: 92245084006) •2015010188 (Lab ID: 92245084007) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 73 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15040226 Pace Project No.: 92245084 Method: SM 4500 -CI -E Description: 4500 Chloride, SPLP Client: Duke Energy Date: April 29, 2015 Pace Analytical Services, Inc. 0988 c&� e. Suite 100 y Huntersville, NC 28078 (704)875-9092 General Information: 3 samples were analyzed for SM 4500 -CI -E. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098glsinyeie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040226 Pace Project No.: 92245084 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: April 29, 2015 General Information: 7 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/45424 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015010183 (Lab ID:92245084005) • Chloride • Sulfate •2015010184 (Lab ID:92245084008) • Chloride • Sulfate •2015010185 (Lab ID:92245084006) • Chloride • Sulfate •2015010186 (Lab ID:92245084009) • Chloride • Sulfate •2015010187 (Lab ID:92245084010) • Chloride • Sulfate •2015010188 (Lab ID:92245084007) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098glsinyeie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040226 Pace Project No.: 92245084 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: April 29, 2015 Analyte Comments: QC Batch: WETA/45424 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015010189 (Lab ID: 92245084011) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 28 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gwinyeie. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040226 Pace Project No.: 92245084 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: April 29, 2015 General Information: 7 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015010183 (Lab ID:92245084005) •2015010184 (Lab ID:92245084008) •2015010185 (Lab ID:92245084006) •2015010186 (Lab ID:92245084009) •2015010187 (Lab ID:92245084010) •2015010188 (Lab ID:92245084007) •2015010189 (Lab ID: 92245084011) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 29 of 73 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 098gwinlve� e. Suite 100 y Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040226 Pace Project No.: 92245084 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: April 29, 2015 General Information: 7 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 30 of 73 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040226 Pace Project No.: 92245084 Pace Analytical Services, Inc. 098g we ie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015010182 Lab ID: 92245084001 Collected: 04/07/15 09:40 Received: 04/10/15 16:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;I➢ZI7c\�i,I=11 l[99�r 6? Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470 Mercury Mercury Date: 04/29/2015 02:39 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 612 ug/L 10.0 3.0 1 04/15/15 22:19 04/17/15 18:08 7429-90-5 ND ug/L 0.50 0.15 1 04/15/15 22:19 04/17/15 18:08 7440-36-0 ND ug/L 0.50 0.11 1 04/15/15 22:19 04/17/15 18:08 7440-38-2 18.0 ug/L 0.30 0.081 1 04/15/15 22:19 04/17/15 18:08 7440-39-3 ND ug/L 0.20 0.067 1 04/15/15 22:19 04/17/15 18:08 7440-41-7 ND ug/L 5.0 1.1 1 04/15/15 22:19 04/20/15 15:03 7440-42-8 ND ug/L 0.080 0.024 1 04/15/15 22:19 04/17/15 18:08 7440-43-9 294 ug/L 40.0 16.0 1 04/15/15 22:19 04/20/15 15:03 7440-70-2 3.3 ug/L 0.50 0.17 1 04/15/15 22:19 04/17/15 18:08 7440-47-3 32.1 ug/L 0.50 0.13 1 04/15/15 22:19 04/17/15 18:08 7440-48-4 3.0 ug/L 1.0 0.21 1 04/15/15 22:19 04/17/15 18:08 7440-50-8 2000 ug/L 50.0 13.7 1 04/15/15 22:19 04/17/15 18:08 7439-89-6 1.6 ug/L 0.10 0.046 1 04/15/15 22:19 04/17/15 18:08 7439-92-1 182 ug/L 10.0 3.2 1 04/15/15 22:19 04/17/15 18:08 7439-95-4 181 ug/L 0.50 0.24 1 04/15/15 22:19 04/17/15 18:08 7439-96-5 0.85 ug/L 0.50 0.094 1 04/15/15 22:19 04/17/15 18:08 7439-98-7 1.8 ug/L 0.50 0.16 1 04/15/15 22:19 04/17/15 18:08 7440-02-0 180 ug/L 50.0 11.7 1 04/15/15 22:19 04/17/15 18:08 7440-09-7 ND ug/L 0.50 0.20 1 04/15/15 22:19 04/17/15 18:08 7782-49-2 243 ug/L 50.0 16.3 1 04/15/15 22:19 04/17/15 18:08 7440-23-5 1.1 ug/L 0.50 0.13 1 04/15/15 22:19 04/17/15 18:08 7440-24-6 ND ug/L 0.10 0.015 1 04/15/15 22:19 04/17/15 18:08 7440-28-0 ND ug/L 1.0 0.28 1 04/15/15 22:19 04/20/15 15:03 7440-62-2 8.9 ug/L 5.0 2.4 1 04/15/15 22:19 04/17/15 18:08 7440-66-6 Analytical Method: EPA 7470 Preparation Method: EPA 7470 ND ug/L 0.20 0.022 1 04/16/15 08:58 04/16/15 19:56 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 31 of 73 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040226 Pace Project No.: 92245084 Pace Analytical Services, Inc. 098g we ie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015010183 SPLP Lab ID: 92245084002 Collected: 04/07/15 09:40 Received: 04/10/15 16:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 04/29/2015 02:39 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 6850 ug/L 50.0 14.9 1 04/23/1517:20 04/24/1514:42 7429-90-5 M1 6.2 ug/L 2.5 0.74 1 04/23/1517:20 04/24/1514:42 7440-36-0 111 ug/L 2.5 0.56 1 04/23/1517:20 04/24/1514:42 7440-38-2 360 ug/L 1.5 0.40 1 04/23/1517:20 04/24/1514:42 7440-39-3 0.52J ug/L 1.0 0.34 1 04/23/1517:20 04/24/1514:42 7440-41-7 140 ug/L 25.0 5.6 1 04/23/1517:20 04/24/1514:42 7440-42-8 ND ug/L 0.40 0.12 1 04/23/1517:20 04/24/1514:42 7440-43-9 5080 ug/L 200 80.0 1 04/23/1517:20 04/24/1514:42 7440-70-2 16.1 ug/L 2.5 0.84 1 04/23/1517:20 04/24/1514:42 7440-47-3 2.9 ug/L 2.5 0.63 1 04/23/1517:20 04/24/1514:42 7440-48-4 10.8 ug/L 5.0 1.1 1 04/23/1517:20 04/24/1514:42 7440-50-8 4990 ug/L 250 68.5 1 04/23/1517:20 04/24/1514:42 7439-89-6 3.4 ug/L 0.50 0.23 1 04/23/1517:20 04/24/1514:42 7439-92-1 722 ug/L 50.0 15.8 1 04/23/1517:20 04/24/1514:42 7439-95-4 32.3 ug/L 2.5 1.2 1 04/23/1517:20 04/24/1514:42 7439-96-5 50.3 ug/L 2.5 0.47 1 04/23/1517:20 04/24/1514:42 7439-98-7 4.5 ug/L 2.5 0.81 1 04/23/1517:20 04/24/1514:42 7440-02-0 818 ug/L 250 58.7 1 04/23/1517:20 04/24/1514:42 7440-09-7 65.5 ug/L 2.5 1.0 1 04/23/1517:20 04/24/1514:42 7782-49-2 2660 ug/L 250 81.5 1 04/23/1517:20 04/24/1514:42 7440-23-5 218 ug/L 2.5 0.66 1 04/23/1517:20 04/24/1514:42 7440-24-6 0.26J ug/L 0.50 0.077 1 04/23/1517:20 04/24/1514:42 7440-28-0 67.7 ug/L 5.0 1.4 1 04/23/1517:20 04/24/1514:42 7440-62-2 53.8 ug/L 25.0 12.0 1 04/23/1517:20 04/24/1514:42 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 04/23/1518:30 04/24/1511:22 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 32 of 73 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040226 Pace Project No.: 92245084 Pace Analytical Services, Inc. 098gW4.8y�e. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015010185 SPLP Lab ID: 92245084003 Collected: 04/07/15 10:45 Received: 04/10/15 16:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 04/29/2015 02:39 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 8.2J ug/L 10.0 3.0 1 04/23/1517:20 04/24/1514:22 7429-90-5 0.36J ug/L 0.50 0.15 1 04/23/1517:20 04/24/1514:22 7440-36-0 ND ug/L 0.50 0.11 1 04/23/1517:20 04/24/1514:22 7440-38-2 129 ug/L 0.30 0.081 1 04/23/1517:20 04/24/1514:22 7440-39-3 ND ug/L 0.20 0.067 1 04/23/1517:20 04/24/1514:22 7440-41-7 97.9 ug/L 5.0 1.1 1 04/23/1517:20 04/24/1514:22 7440-42-8 0.031J ug/L 0.080 0.024 1 04/23/1517:20 04/24/1514:22 7440-43-9 2430 ug/L 40.0 16.0 1 04/23/1517:20 04/24/1514:22 7440-70-2 0.84 ug/L 0.50 0.17 1 04/23/1517:20 04/24/1514:22 7440-47-3 0.45J ug/L 0.50 0.13 1 04/23/1517:20 04/24/1514:22 7440-48-4 ND ug/L 1.0 0.21 1 04/23/1517:20 04/24/1514:22 7440-50-8 ND ug/L 50.0 13.7 1 04/23/1517:20 04/24/1514:22 7439-89-6 ND ug/L 0.10 0.046 1 04/23/1517:20 04/24/1514:22 7439-92-1 255 ug/L 10.0 3.2 1 04/23/1517:20 04/24/1514:22 7439-95-4 15.6 ug/L 0.50 0.24 1 04/23/1517:20 04/24/1514:22 7439-96-5 97.6 ug/L 0.50 0.094 1 04/23/1517:20 04/24/1514:22 7439-98-7 0.27J ug/L 0.50 0.16 1 04/23/1517:20 04/24/1514:22 7440-02-0 1930 ug/L 50.0 11.7 1 04/23/1517:20 04/24/1514:22 7440-09-7 ND ug/L 0.50 0.20 1 04/23/1517:20 04/24/1514:22 7782-49-2 2070 ug/L 50.0 16.3 1 04/23/1517:20 04/24/1514:22 7440-23-5 59.8 ug/L 0.50 0.13 1 04/23/1517:20 04/24/1514:22 7440-24-6 0.0191 ug/L 0.10 0.015 1 04/23/1517:20 04/24/1514:22 7440-28-0 ND ug/L 1.0 0.28 1 04/23/1517:20 04/24/1514:22 7440-62-2 39.0 ug/L 5.0 2.4 1 04/23/1517:20 04/24/1514:22 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 04/23/1518:30 04/24/1511:24 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 33 of 73 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040226 Pace Project No.: 92245084 Pace Analytical Services, Inc. 098g we ie. Suite 100 y Huntersville, NC 28078 (704)875-9092 Sample: 2015010188 SPLP Lab ID: 92245084004 Collected: 04/07/15 12:35 Received: 04/10/15 16:35 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual ;T➢Z17c\�iil=11 a Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Magnesium Manganese Molybdenum Nickel Potassium Selenium Sodium Strontium Thallium Vanadium Zinc 7470A Mercury Mercury Date: 04/29/2015 02:39 PM Analytical Method: EPA 6020A Preparation Method: EPA 3020 10.7 ug/L 10.0 3.0 1 04/23/1517:20 04/24/1514:25 7429-90-5 ND ug/L 0.50 0.15 1 04/23/1517:20 04/24/1514:25 7440-36-0 ND ug/L 0.50 0.11 1 04/23/1517:20 04/24/1514:25 7440-38-2 131 ug/L 0.30 0.081 1 04/23/1517:20 04/24/1514:25 7440-39-3 ND ug/L 0.20 0.067 1 04/23/1517:20 04/24/1514:25 7440-41-7 74.2 ug/L 5.0 1.1 1 04/23/1517:20 04/24/1514:25 7440-42-8 ND ug/L 0.080 0.024 1 04/23/1517:20 04/24/1514:25 7440-43-9 1270 ug/L 40.0 16.0 1 04/23/1517:20 04/24/1514:25 7440-70-2 0.31J ug/L 0.50 0.17 1 04/23/1517:20 04/24/1514:25 7440-47-3 1.8 ug/L 0.50 0.13 1 04/23/1517:20 04/24/1514:25 7440-48-4 ND ug/L 1.0 0.21 1 04/23/1517:20 04/24/1514:25 7440-50-8 ND ug/L 50.0 13.7 1 04/23/1517:20 04/24/1514:25 7439-89-6 ND ug/L 0.10 0.046 1 04/23/1517:20 04/24/1514:25 7439-92-1 326 ug/L 10.0 3.2 1 04/23/1517:20 04/24/1514:25 7439-95-4 129 ug/L 0.50 0.24 1 04/23/1517:20 04/24/1514:25 7439-96-5 12.4 ug/L 0.50 0.094 1 04/23/1517:20 04/24/1514:25 7439-98-7 0.22J ug/L 0.50 0.16 1 04/23/1517:20 04/24/1514:25 7440-02-0 1450 ug/L 50.0 11.7 1 04/23/1517:20 04/24/1514:25 7440-09-7 ND ug/L 0.50 0.20 1 04/23/1517:20 04/24/1514:25 7782-49-2 2660 ug/L 50.0 16.3 1 04/23/1517:20 04/24/1514:25 7440-23-5 39.9 ug/L 0.50 0.13 1 04/23/1517:20 04/24/1514:25 7440-24-6 ND ug/L 0.10 0.015 1 04/23/1517:20 04/24/1514:25 7440-28-0 ND ug/L 1.0 0.28 1 04/23/1517:20 04/24/1514:25 7440-62-2 21.3 ug/L 5.0 2.4 1 04/23/1517:20 04/24/1514:25 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.022 1 04/23/1518:30 04/24/1511:26 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 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