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Home My WebLink AboutNC0000396_J15040223 Report_20150823+ DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Order Number: J15040223 Project Name: ASHEVILLE - AB GW ASSESSMENT SOIL Customer Name(s): Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker Customer Address: 200 CP and L Drive Arden, NC 28704 Lab Contact: Margaret Galvin -Karr Phone: 980-875-5219 Report Authorized By: G MXG4644 (101161) (Signature) RGY 2015.05.2911:11:09-04'00 Date: Margaret Galvin -Karr Program Comments: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 5/21/2015 1 of 53 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: 2 of 53 Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015010176 ASHEVILLE 09 -Apr -15 9:15 AM illegible Well SW -06 2015010190 ASHEVILLE 09 -Apr -15 10:40 AM illegible Well SW -07 2015010191 ASHEVILLE 09 -Apr -15 10:35 AM illegible Well SW -07 Dup 3 Total Samples Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes F./] No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Reviewed By: Date: 3 of 53 Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 0 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040223 Site: Well SW -06 Collection Date: 09 -Apr -15 9:15 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 4 of 53 Sample #: 2015010176 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040223 Site: Well SW -07 Collection Date: 09 -Apr -15 10:40 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 5 of 53 Sample #: 2015010190 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040223 Site: Well SW -07 Dup Collection Date: 09 -Apr -15 10:35 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6 of 53 Sample #: 2015010191 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE aceAnaiXical www.pacelabs.com May 04, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 RE: Project: J15040223 Pace Project No.: 92245118 Pace Analytical Services, Inc. 9800 Kic&fie. Suite 100 Huntersville, INC 28078 (704)875-9092 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on April 10, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy HiQ p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 35 aceAnaiXical www.pacelabs.com Project: J15040223 Pace Project No.: 92245118 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification M PH -0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate M 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification M E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 Pace Analytical Services, Inc. 9800 Kigc&y&ie. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Montana Certification #: Cert 0074 Nebraska Certification: NE -OS -28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification M FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification M 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 35 aceAnaiXical www.pacelabs.com SAMPLE SUMMARY Project: J15040223 Pace Project No.: 92245118 Lab ID Sample ID Matrix Date Collected Date Received 92245118001 2015010176 Solid 04/09/15 09:15 04/10/15 16:35 92245118002 2015010190 Solid 04/09/1510:40 04/10/1516:35 92245118003 2015010191 Solid 04/09/1510:35 04/10/1516:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kig%y& jie. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 35 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15040223 92245118 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92245118001 2015010176 EPA 6010 TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AEM 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92245118002 2015010190 EPA 6010 CKJ, TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AEM 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92245118003 2015010191 EPA 6010 CKJ, TAP 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AEM 1 PASI-O EPA 9045 MAB 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 35 aceAnaiXical www.pacelabs.com Project: J15040223 Pace Project No.: 92245118 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 9800 Klinic8y&1re. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92245118001 2015010176 EPA 6010 Aluminum 2370 mg/kg 6.7 04/20/15 14:34 EPA 6010 Barium 21.9 mg/kg 0.67 04/20/15 14:34 EPA 6010 Beryllium 0.14 mg/kg 0.067 04/20/15 14:34 EPA 6010 Boron 3.4 mg/kg 3.4 04/20/15 14:34 EPA 6010 Calcium 190 mg/kg 33.6 04/20/15 14:34 EPA 6010 Chromium 6.0 mg/kg 0.34 04/20/15 14:34 EPA 6010 Copper 4.3 mg/kg 0.34 04/20/15 14:34 EPA 6010 Iron 4690 mg/kg 2.7 04/20/15 14:34 EPA 6010 Magnesium 765 mg/kg 33.6 04/20/15 14:34 EPA 6010 Manganese 86.2 mg/kg 0.34 04/20/15 14:34 EPA 6010 Nickel 2.4 mg/kg 0.34 04/20/15 14:34 EPA 6010 Potassium 749 mg/kg 67.3 04/20/15 14:34 EPA 6010 Strontium 1.8 mg/kg 0.67 04/20/15 14:34 EPA 6010 Zinc 25.2 mg/kg 1.3 04/20/15 14:34 EPA 6020 Vanadium 8.0 mg/kg 6.7 04/22/15 02:14 EPA 7471 Mercury 0.00991 mg/kg 0.012 04/20/15 21:00 ASTM D2974-87 Percent Moisture 29.5 % 0.10 04/16/15 16:10 EPA 9045 pH at 25 Degrees C 6.5 Std. Units 0.10 04/16/15 10:45 EPA 9060 Total Organic Carbon 1820 mg/kg 851 05/01/15 09:20 EPA 9060 Total Organic Carbon 1660 mg/kg 859 05/01/15 09:25 EPA 9060 Total Organic Carbon 1500 mg/kg 847 05/01/15 09:32 EPA 9060 Total Organic Carbon 3320 mg/kg 844 05/01/15 09:38 EPA 9060 Mean Total Organic Carbon 2070 mg/kg 850 05/01/15 09:20 EPA 9060 RSD% 40.5 % 05/01/15 09:20 92245118002 2015010190 EPA 6010 Aluminum 5790 mg/kg 7.2 04/20/15 14:38 EPA 6010 Barium 37.6 mg/kg 0.72 04/20/15 14:38 EPA 6010 Beryllium 1.1 mg/kg 0.36 04/25/15 14:59 EPA 6010 Calcium 190 mg/kg 35.9 04/20/15 14:38 EPA 6010 Chromium 22.6 mg/kg 1.8 04/25/15 14:59 EPA 6010 Copper 13.8 mg/kg 1.8 04/25/15 14:59 EPA 6010 Iron 23800 mg/kg 2.9 04/20/15 14:38 EPA 6010 Magnesium 1830 mg/kg 35.9 04/20/15 14:38 EPA 6010 Manganese 99.9 mg/kg 1.8 04/25/15 14:59 EPA 6010 Molybdenum 2.0 mg/kg 0.72 04/20/15 14:38 EPA 6010 Nickel 6.5 mg/kg 0.36 04/20/15 14:38 EPA 6010 Potassium 1600 mg/kg 71.8 04/20/15 14:38 EPA 6010 Strontium 1.5 mg/kg 0.72 04/20/15 14:38 EPA 6010 Zinc 47.2 mg/kg 1.4 04/20/15 14:38 EPA 6020 Cobalt 7.4 mg/kg 7.2 04/22/15 02:16 EPA 6020 Lead 10.3 mg/kg 7.2 04/22/15 02:16 EPA 6020 Vanadium 23.9 mg/kg 7.2 04/22/15 02:16 ASTM D2974-87 Percent Moisture 31.4 % 0.10 04/16/15 16:11 EPA 9045 pH at 25 Degrees C 5.6 Std. Units 0.10 04/16/15 10:45 EPA 9060 Total Organic Carbon 6640 mg/kg 878 05/01/15 09:43 EPA 9060 Total Organic Carbon 4050 mg/kg 874 05/01/15 09:49 EPA 9060 Total Organic Carbon 4770 mg/kg 877 05/01/15 09:55 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 1g D3 D3 D3 D3 Qualifiers Page 5 of 35 aceAnaiXical www.pacelabs.com SUMMARY OF DETECTION Pace Analytical Services, Inc. 9800 ff�i�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15040223 92245118 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92245118002 2015010190 EPA 9060 Total Organic Carbon 3150 mg/kg 878 05/01/15 10:01 EPA 9060 Mean Total Organic Carbon 4650 mg/kg 877 05/01/15 09:43 EPA 9060 RSD% 31.8 % 05/01/15 09:43 92245118003 2015010191 EPA 6010 Aluminum 8290 mg/kg 8.5 04/20/15 14:42 EPA 6010 Barium 70.1 mg/kg 0.85 04/20/15 14:42 EPA 6010 Beryllium 0.94 mg/kg 0.42 04/25/15 15:03 D3 EPA 6010 Calcium 326 mg/kg 42.3 04/20/15 14:42 EPA 6010 Chromium 37.8 mg/kg 2.1 04/25/15 15:03 D3 EPA 6010 Copper 17.5 mg/kg 2.1 04/25/15 15:03 D3 EPA 6010 Iron 18300 mg/kg 3.4 04/20/15 14:42 EPA 6010 Magnesium 3690 mg/kg 42.3 04/20/15 14:42 EPA 6010 Manganese 141 mg/kg 2.1 04/25/15 15:03 D3 EPA 6010 Molybdenum 3.9 mg/kg 0.85 04/20/15 14:42 EPA 6010 Nickel 13.1 mg/kg 0.42 04/20/15 14:42 EPA 6010 Potassium 3200 mg/kg 84.5 04/20/15 14:42 EPA 6010 Strontium 2.5 mg/kg 0.85 04/20/15 14:42 EPA 6010 Zinc 69.6 mg/kg 1.7 04/20/15 14:42 EPA 6020 Cobalt 10.1 mg/kg 8.5 04/22/15 02:19 EPA 6020 Lead 11.7 mg/kg 8.5 04/22/15 02:19 EPA 6020 Vanadium 29.4 mg/kg 8.5 04/22/15 02:19 ASTM D2974-87 Percent Moisture 38.1 % 0.10 04/16/15 16:11 EPA 9045 pH at 25 Degrees C 5.7 Std. Units 0.10 04/16/15 10:45 EPA 9060 Total Organic Carbon 5090 mg/kg 968 05/01/15 10:08 EPA 9060 Total Organic Carbon 5240 mg/kg 976 05/01/15 10:13 EPA 9060 Total Organic Carbon 6090 mg/kg 961 05/01/15 10:20 EPA 9060 Total Organic Carbon 9120 mg/kg 963 05/01/15 10:27 EPA 9060 Mean Total Organic Carbon 6380 mg/kg 967 05/01/15 10:08 EPA 9060 RSD% 29.4 % 05/01/1510:08 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 35 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 f igg8y&j.. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040223 Pace Project No.: 92245118 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: May 04, 2015 General Information: 3 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23696 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245094011 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1188077) • Aluminum • Barium • Chromium • Iron • Magnesium • Manganese • Nickel • Potassium • Strontium • Zinc • MSD (Lab ID: 1188078) • Aluminum • Barium • Chromium • Copper • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 35 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040223 Pace Project No.: 92245118 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: May 04, 2015 QC Batch: MPRP/23696 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245094011 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • Magnesium • Manganese • Nickel • Potassium • Strontium • Zinc Additional Comments: Analyte Comments: QC Batch: MPRP/23696 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015010190 (Lab ID: 92245118002) • Boron • Beryllium • Chromium • Copper • Manganese •2015010191 (Lab ID: 92245118003) • Boron • Beryllium • Chromium • Copper • Manganese • MS (Lab ID: 1188077) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 35 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15040223 Pace Project No.: 92245118 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: May 04, 2015 Analyte Comments: QC Batch: MPRP/23696 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • MSD (Lab ID: 1188078) • Aluminum • Boron • Barium • Beryllium • Calcium • Chromium • Copper • Iron • Potassium • Magnesium • Manganese • Molybdenum • Sodium • Nickel • Strontium • Zinc Pace Analytical Services, Inc. 9800 f igg8y&j.. Suite 100 Huntersville, NC 28078 (704)875-9092 P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. • BLANK (Lab ID: 1188075) • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 35 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040223 Pace Project No.: 92245118 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: May 04, 2015 General Information: 3 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23697 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245094012 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1188081) • Antimony • Cobalt • Lead • MSD (Lab ID: 1188082) • Antimony • Cobalt • Lead • Vanadium R1: RPD value was outside control limits. • MSD (Lab ID: 1188082) • Cobalt • Vanadium REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 35 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 fflic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040223 Pace Project No.: 92245118 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: May 04, 2015 Additional Comments: Batch Comments: Batch was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICPM / 9631 Analyte Comments: QC Batch: MPRP/23697 N2: The lab does not hold TNI accreditation for this parameter. •2015010176 (Lab ID: 92245118001) • Antimony •2015010190 (Lab ID: 92245118002) • Antimony •2015010191 (Lab ID: 92245118003) • Antimony • BLANK (Lab ID: 1188079) • Antimony • LCS (Lab ID: 1188080) • Antimony • MS (Lab ID: 1188081) • Antimony • MSD (Lab ID: 1188082) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 35 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffligc&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040223 Pace Project No.: 92245118 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: May 04, 2015 General Information: 3 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 35 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040223 Pace Project No.: 92245118 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: May 04, 2015 General Information: 3 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 35 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040223 Pace Project No.: 92245118 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: May 04, 2015 General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/45422 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015010176 (Lab ID: 92245118001) • Chloride • Sulfate •2015010190 (Lab ID: 92245118002) • Chloride • Sulfate •2015010191 (Lab ID: 92245118003) • Chloride • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 35 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 tf�nic&)r&jre. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040223 Pace Project No.: 92245118 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: May 04, 2015 General Information: 3 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015010176 (Lab ID: 92245118001) •2015010190 (Lab ID: 92245118002) •2015010191 (Lab ID: 92245118003) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 35 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040223 Pace Project No.: 92245118 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: May 04, 2015 General Information: 3 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/28281 1g: % RSD > 40 •2015010176 (Lab ID: 92245118001) • Mean Total Organic Carbon This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 35 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 KS'8y&J.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040223 Pace Project No.: 92245118 Sample: 2015010176 Lab ID: 92245118001 Collected: 04/09/15 09:15 Received: 04/10/15 16:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 2370 mg/kg 6.7 3.4 1 04/19/15 05:38 04/20/15 14:34 7429-90-5 Barium 21.9 mg/kg 0.67 0.34 1 04/19/15 05:38 04/20/15 14:34 7440-39-3 Beryllium 0.14 mg/kg 0.067 0.034 1 04/19/15 05:38 04/20/15 14:34 7440-41-7 Boron 3.4 mg/kg 3.4 1.7 1 04/19/15 05:38 04/20/15 14:34 7440-42-8 Calcium 190 mg/kg 33.6 16.8 1 04/19/15 05:38 04/20/15 14:34 7440-70-2 Chromium 6.0 mg/kg 0.34 0.17 1 04/19/15 05:38 04/20/15 14:34 7440-47-3 Copper 4.3 mg/kg 0.34 0.17 1 04/19/15 05:38 04/20/15 14:34 7440-50-8 Iron 4690 mg/kg 2.7 1.3 1 04/19/15 05:38 04/20/15 14:34 7439-89-6 Magnesium 765 mg/kg 33.6 16.8 1 04/19/15 05:38 04/20/15 14:34 7439-95-4 Manganese 86.2 mg/kg 0.34 0.17 1 04/19/15 05:38 04/20/15 14:34 7439-96-5 Molybdenum ND mg/kg 0.67 0.34 1 04/19/15 05:38 04/20/15 14:34 7439-98-7 Nickel 2.4 mg/kg 0.34 0.17 1 04/19/15 05:38 04/20/15 14:34 7440-02-0 Potassium 749 mg/kg 67.3 33.6 1 04/19/15 05:38 04/20/15 14:34 7440-09-7 Sodium ND mg/kg 67.3 33.6 1 04/19/15 05:38 04/20/15 14:34 7440-23-5 Strontium 1.8 mg/kg 0.67 0.34 1 04/19/15 05:38 04/20/15 14:34 7440-24-6 Zinc 25.2 mg/kg 1.3 0.67 1 04/19/15 05:38 04/20/15 14:34 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 6.7 3.4 100 04/19/15 05:38 04/22/15 02:14 7440-36-0 N2 Arsenic ND mg/kg 6.7 3.4 100 04/19/15 05:38 04/22/15 02:14 7440-38-2 Cadmium ND mg/kg 0.81 0.40 100 04/19/15 05:38 04/22/15 02:14 7440-43-9 Cobalt ND mg/kg 6.7 3.4 100 04/19/15 05:38 04/22/15 02:14 7440-48-4 Lead ND mg/kg 6.7 3.4 100 04/19/15 05:38 04/22/15 02:14 7439-92-1 Selenium ND mg/kg 6.7 3.4 100 04/19/15 05:38 04/22/15 02:14 7782-49-2 Thallium ND mg/kg 6.7 3.4 100 04/19/15 05:38 04/22/15 02:14 7440-28-0 Vanadium 8.0 mg/kg 6.7 3.4 100 04/19/15 05:38 04/22/15 02:14 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.00991 mg/kg 0.012 0.0058 1 04/19/15 05:30 04/20/15 21:00 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 29.5 % 0.10 0.10 1 04/16/15 16:10 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.5 Std. Units 0.10 0.10 1 04/16/15 10:45 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 348 174 5 04/15/15 21:16 16887-00-6 D3 Sulfate ND mg/kg 348 174 5 04/15/15 21:16 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 34.8 17.4 5 04/15/15 21:16 14797-55-8 H3 Date: 05/04/2015 10:26 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 35 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 K4'8y&J.. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040223 Pace Project No.: 92245118 Sample: 2015010176 Lab ID: 92245118001 Collected: 04/09/15 09:15 Received: 04/10/15 16:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 1820 mg/kg 851 425 1 05/01/15 09:20 7440-44-0 Total Organic Carbon 1660 mg/kg 859 430 1 05/01/15 09:25 7440-44-0 Total Organic Carbon 1500 mg/kg 847 423 1 05/01/15 09:32 7440-44-0 Total Organic Carbon 3320 mg/kg 844 422 1 05/01/15 09:38 7440-44-0 Mean Total Organic Carbon 2070 mg/kg 850 425 1 05/01/15 09:20 7440-44-0 1g Surrogates RSD% 40.5 % 1 05/01/15 09:20 Date: 05/04/2015 10:26 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 35 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 KP�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040223 Pace Project No.: 92245118 Sample: 2015010190 Lab ID: 92245118002 Collected: 04/09/15 10:40 Received: 04/10/15 16:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 5790 mg/kg 7.2 3.6 1 04/19/15 05:38 04/20/15 14:38 7429-90-5 Barium 37.6 mg/kg 0.72 0.36 1 04/19/15 05:38 04/20/15 14:38 7440-39-3 Beryllium 1.1 mg/kg 0.36 0.18 5 04/19/15 05:38 04/25/15 14:59 7440-41-7 D3 Boron ND mg/kg 17.9 9.0 5 04/19/15 05:38 04/25/15 14:59 7440-42-8 D3 Calcium 190 mg/kg 35.9 17.9 1 04/19/15 05:38 04/20/15 14:38 7440-70-2 Chromium 22.6 mg/kg 1.8 0.90 5 04/19/15 05:38 04/25/15 14:59 7440-47-3 D3 Copper 13.8 mg/kg 1.8 0.90 5 04/19/15 05:38 04/25/15 14:59 7440-50-8 D3 Iron 23800 mg/kg 2.9 1.4 1 04/19/15 05:38 04/20/15 14:38 7439-89-6 Magnesium 1830 mg/kg 35.9 17.9 1 04/19/15 05:38 04/20/15 14:38 7439-95-4 Manganese 99.9 mg/kg 1.8 0.90 5 04/19/15 05:38 04/25/15 14:59 7439-96-5 D3 Molybdenum 2.0 mg/kg 0.72 0.36 1 04/19/15 05:38 04/20/15 14:38 7439-98-7 Nickel 6.5 mg/kg 0.36 0.18 1 04/19/15 05:38 04/20/15 14:38 7440-02-0 Potassium 1600 mg/kg 71.8 35.9 1 04/19/15 05:38 04/20/15 14:38 7440-09-7 Sodium ND mg/kg 71.8 35.9 1 04/19/15 05:38 04/20/15 14:38 7440-23-5 Strontium 1.5 mg/kg 0.72 0.36 1 04/19/15 05:38 04/20/15 14:38 7440-24-6 Zinc 47.2 mg/kg 1.4 0.72 1 04/19/15 05:38 04/20/15 14:38 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 7.2 3.6 100 04/19/15 05:38 04/22/15 02:16 7440-36-0 N2 Arsenic ND mg/kg 7.2 3.6 100 04/19/15 05:38 04/22/15 02:16 7440-38-2 Cadmium ND mg/kg 0.86 0.43 100 04/19/15 05:38 04/22/15 02:16 7440-43-9 Cobalt 7.4 mg/kg 7.2 3.6 100 04/19/15 05:38 04/22/15 02:16 7440-48-4 Lead 10.3 mg/kg 7.2 3.6 100 04/19/15 05:38 04/22/15 02:16 7439-92-1 Selenium ND mg/kg 7.2 3.6 100 04/19/15 05:38 04/22/15 02:16 7782-49-2 Thallium ND mg/kg 7.2 3.6 100 04/19/15 05:38 04/22/15 02:16 7440-28-0 Vanadium 23.9 mg/kg 7.2 3.6 100 04/19/15 05:38 04/22/15 02:16 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.011 0.0056 1 04/19/15 05:30 04/20/15 21:02 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 31.4 % 0.10 0.10 1 04/16/15 16:11 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.6 Std. Units 0.10 0.10 1 04/16/15 10:45 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 360 180 5 04/15/15 22:21 16887-00-6 D3 Sulfate ND mg/kg 360 180 5 04/15/15 22:21 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 36.0 18.0 5 04/15/15 22:21 14797-55-8 H3 Date: 05/04/2015 10:26 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 35 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040223 Pace Project No.: 92245118 Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015010190 Lab ID: 92245118002 Collected: 04/09/15 10:40 Received: 04/10/15 16:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 6640 mg/kg 878 439 1 05/01/15 09:43 7440-44-0 Total Organic Carbon 4050 mg/kg 874 437 1 05/01/15 09:49 7440-44-0 Total Organic Carbon 4770 mg/kg 877 439 1 05/01/15 09:55 7440-44-0 Total Organic Carbon 3150 mg/kg 878 439 1 05/01/15 10:01 7440-44-0 Mean Total Organic Carbon 4650 mg/kg 877 438 1 05/01/15 09:43 7440-44-0 Surrogates RSD% 31.8 % 1 05/01/15 09:43 Date: 05/04/2015 10:26 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 35 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040223 Pace Project No.: 92245118 Sample: 2015010191 Lab ID: 92245118003 Collected: 04/09/15 10:35 Received: 04/10/15 16:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 8290 mg/kg 8.5 4.2 1 04/19/15 05:38 04/20/15 14:42 7429-90-5 Barium 70.1 mg/kg 0.85 0.42 1 04/19/15 05:38 04/20/15 14:42 7440-39-3 Beryllium 0.94 mg/kg 0.42 0.21 5 04/19/15 05:38 04/25/15 15:03 7440-41-7 D3 Boron ND mg/kg 21.1 10.6 5 04/19/15 05:38 04/25/15 15:03 7440-42-8 D3 Calcium 326 mg/kg 42.3 21.1 1 04/19/15 05:38 04/20/15 14:42 7440-70-2 Chromium 37.8 mg/kg 2.1 1.1 5 04/19/15 05:38 04/25/15 15:03 7440-47-3 D3 Copper 17.5 mg/kg 2.1 1.1 5 04/19/15 05:38 04/25/15 15:03 7440-50-8 D3 Iron 18300 mg/kg 3.4 1.7 1 04/19/15 05:38 04/20/15 14:42 7439-89-6 Magnesium 3690 mg/kg 42.3 21.1 1 04/19/15 05:38 04/20/15 14:42 7439-95-4 Manganese 141 mg/kg 2.1 1.1 5 04/19/15 05:38 04/25/15 15:03 7439-96-5 D3 Molybdenum 3.9 mg/kg 0.85 0.42 1 04/19/15 05:38 04/20/15 14:42 7439-98-7 Nickel 13.1 mg/kg 0.42 0.21 1 04/19/15 05:38 04/20/15 14:42 7440-02-0 Potassium 3200 mg/kg 84.5 42.3 1 04/19/15 05:38 04/20/15 14:42 7440-09-7 Sodium ND mg/kg 84.5 42.3 1 04/19/15 05:38 04/20/15 14:42 7440-23-5 Strontium 2.5 mg/kg 0.85 0.42 1 04/19/15 05:38 04/20/15 14:42 7440-24-6 Zinc 69.6 mg/kg 1.7 0.85 1 04/19/15 05:38 04/20/15 14:42 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 8.5 4.2 100 04/19/15 05:38 04/22/15 02:19 7440-36-0 N2 Arsenic ND mg/kg 8.5 4.2 100 04/19/15 05:38 04/22/15 02:19 7440-38-2 Cadmium ND mg/kg 1.0 0.51 100 04/19/15 05:38 04/22/15 02:19 7440-43-9 Cobalt 10.1 mg/kg 8.5 4.2 100 04/19/15 05:38 04/22/15 02:19 7440-48-4 Lead 11.7 mg/kg 8.5 4.2 100 04/19/15 05:38 04/22/15 02:19 7439-92-1 Selenium ND mg/kg 8.5 4.2 100 04/19/15 05:38 04/22/15 02:19 7782-49-2 Thallium ND mg/kg 8.5 4.2 100 04/19/15 05:38 04/22/15 02:19 7440-28-0 Vanadium 29.4 mg/kg 8.5 4.2 100 04/19/15 05:38 04/22/15 02:19 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury ND mg/kg 0.013 0.0064 1 04/19/15 05:30 04/20/15 21:04 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 38.1 % 0.10 0.10 1 04/16/15 16:11 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 5.7 Std. Units 0.10 0.10 1 04/16/15 10:45 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 406 203 5 04/15/15 22:42 16887-00-6 D3 Sulfate ND mg/kg 406 203 5 04/15/15 22:42 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 40.6 20.3 5 04/15/15 22:42 14797-55-8 H3 Date: 05/04/2015 10:26 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 35 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040223 Pace Project No.: 92245118 Pace Analytical Services, Inc. 9800 KPgc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015010191 Lab ID: 92245118003 Collected: 04/09/15 10:35 Received: 04/10/15 16:35 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 5090 mg/kg 968 484 1 05/01/15 10:08 7440-44-0 Total Organic Carbon 5240 mg/kg 976 488 1 05/01/15 10:13 7440-44-0 Total Organic Carbon 6090 mg/kg 961 480 1 05/01/15 10:20 7440-44-0 Total Organic Carbon 9120 mg/kg 963 481 1 05/01/15 10:27 7440-44-0 Mean Total Organic Carbon 6380 mg/kg 967 484 1 05/01/15 10:08 7440-44-0 Surrogates RSD% 29.4 % 1 05/01/1510:08 Date: 05/04/2015 10:26 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 35 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040223 Pace Project No.: 92245118 QC Batch: MERP/5604 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92245118001, 92245118002, 92245118003 METHOD BLANK: 1188083 Matrix: Solid Associated Lab Samples: 92245118001, 92245118002, 92245118003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0081 04/20/15 20:38 LABORATORY CONTROL SAMPLE: 1188084 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .082 0.066 81 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1188085 1188086 MS MSD 92245094011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg ND .12 .117 0.11 0.10 89 86 80-120 6 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/04/2015 10:26 AM without the written consent of Pace Analytical Services, Inc.. Page 23 of 35 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040223 Pace Project No.: 92245118 QC Batch: MPRP/23696 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92245118001, 92245118002, 92245118003 METHOD BLANK: 1188075 Matrix: Associated Lab Samples: 92245118001, 92245118002, 92245118003 Blank Parameter Units Result Solid Reporting Limit Analyzed Aluminum mg/kg ND 5.2 04/25/1514:10 Barium mg/kg ND 0.52 04/25/1514:10 Beryllium mg/kg ND 0.052 04/25/1514:10 Boron mg/kg ND 2.6 04/25/1514:10 Calcium mg/kg ND 25.8 04/25/1514:10 Chromium mg/kg ND 0.26 04/25/1514:10 Copper mg/kg ND 0.26 04/25/1514:10 Iron mg/kg 1 AJ 2.1 04/25/15 14:10 P8 Magnesium mg/kg ND 25.8 04/25/1514:10 Manganese mg/kg ND 0.26 04/25/1514:10 Molybdenum mg/kg ND 0.52 04/25/1514:10 Nickel mg/kg ND 0.26 04/25/1514:10 Potassium mg/kg ND 51.7 04/25/1514:10 Sodium mg/kg ND 51.7 04/25/1514:10 Strontium mg/kg ND 0.52 04/25/1514:10 Zinc mg/kg ND 1.0 04/25/1514:10 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1188076 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 122 126 103 80-120 Barium mg/kg 12.2 12.6 103 80-120 Beryllium mg/kg 1.2 1.3 105 80-120 Boron mg/kg 122 122 100 80-120 Calcium mg/kg 608 644 106 80-120 Chromium mg/kg 12.2 12.1 100 80-120 Copper mg/kg 12.2 11.9 98 80-120 Iron mg/kg 122 127 105 80-120 Magnesium mg/kg 608 627 103 80-120 Manganese mg/kg 12.2 12.5 103 80-120 Molybdenum mg/kg 12.2 12.2 101 80-120 Nickel mg/kg 12.2 12.7 104 80-120 Potassium mg/kg 608 626 103 80-120 Sodium mg/kg 608 640 105 80-120 Strontium mg/kg 12.2 12.5 103 80-120 Zinc mg/kg 60.8 63.3 104 80-120 Pace Analytical Services, Inc. 9800 %c&y&jre. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/04/2015 10:26 AM without the written consent of Pace Analytical Services, Inc.. Page 24 of 35 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 K�n�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040223 Pace Project No.: 92245118 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1188077 1188078 MS MSD 92245094011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua] Aluminum mg/kg 20700 186 174 31300 33500 5680 7350 75-125 7 20 D3,M1 Barium mg/kg 149 18.6 17.4 269 274 643 715 75-125 2 20 D3,M1 Beryllium mg/kg 2.3 1.86 1.72 4.1 4.3 97 116 75-125 5 20 D3 Boron mg/kg ND 186 174 144 136 77 78 75-125 6 20 D3 Calcium mg/kg 525 929 872 1560 1500 111 112 75-125 4 20 D3 Chromium mg/kg 47.5 18.6 17.4 122 119 401 412 75-125 2 20 D3,M1 Copper mg/kg 37.5 18.6 17.4 55.6 61.2 98 136 75-125 10 20 D3,M1 Iron mg/kg 60700 186 174 64600 63300 2070 1460 75-125 2 20 D3,M1 Magnesium mg/kg 5520 929 872 11300 12100 616 749 75-125 7 20 D3,M1 Manganese mg/kg 942 18.6 17.4 1120 1040 975 538 75-125 8 20 D3,M1 Molybdenum mg/kg 44.6 18.6 17.4 62.9 65.7 98 121 75-125 4 20 D3 Nickel mg/kg 30.2 18.6 17.4 74.8 81.5 240 294 75-125 8 20 D3,M1 Potassium mg/kg 4200 929 872 8300 9180 441 571 75-125 10 20 D3,M1 Sodium mg/kg ND 929 872 943 886 101 102 75-125 6 20 D3 Strontium mg/kg 27.4 18.6 17.4 51.2 49.6 128 128 75-125 3 20 D3,M1 Zinc mg/kg 83.5 92.9 87.2 202 201 128 135 75-125 0 20 D3,M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/04/2015 10:26 AM without the written consent of Pace Analytical Services, Inc.. Page 25 of 35 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040223 Pace Project No.: 92245118 QC Batch: MPRP/23697 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92245118001, 92245118002, 92245118003 METHOD BLANK: 1188079 Matrix: Solid LCS Result Associated Lab Samples: 92245118001, 92245118002, 92245118003 mg/kg 2.5 2.5 101 Blank Reporting mg/kg Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.052 04/22/15 01:45 N2 Arsenic mg/kg ND 0.052 04/22/15 01:45 Cadmium mg/kg ND 0.0063 04/22/15 01:45 Cobalt mg/kg ND 0.052 04/22/15 01:45 Lead mg/kg ND 0.052 04/22/15 01:45 Selenium mg/kg ND 0.052 04/22/15 01:45 Thallium mg/kg ND 0.052 04/22/15 01:45 Vanadium mg/kg ND 0.052 04/22/15 01:45 Pace Analytical Services, Inc. 9800 t Qgigy&j.. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1188080 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.5 2.5 101 80-120 N2 Arsenic mg/kg 2.5 2.6 106 80-120 Cadmium mg/kg .25 0.26 104 80-120 Cobalt mg/kg 2.5 2.6 106 80-120 Lead mg/kg 2.5 2.5 101 80-120 Selenium mg/kg 2.5 2.5 103 80-120 Thallium mg/kg 2.5 2.6 103 80-120 Vanadium mg/kg 2.5 2.6 106 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1188081 1188082 MS MSD 92245094012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 3.59 3.89 ND ND 51 71 75-125 20 M6, N2 Arsenic mg/kg ND 3.59 3.89 5.1J 4.7J 107 92 75-125 20 Cadmium mg/kg ND .359 .389 ND ND 88 76 75-125 20 Cobalt mg/kg 17.2 3.59 3.89 23.3 35.9 166 487 75-125 43 20 M6,R1 Lead mg/kg 7.6J 3.59 3.89 12.7 14.7 139 183 75-125 14 20 M6 Selenium mg/kg ND 3.59 3.89 6.OJ 5.9J 90 84 75-125 20 Thallium mg/kg ND 3.59 3.89 4.5J 4.6J 106 103 75-125 20 Vanadium mg/kg 29.1 3.59 3.89 33.5 57.3 119 732 75-125 52 20 M6, R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/04/2015 10:26 AM without the written consent of Pace Analytical Services, Inc.. Page 26 of 35 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040223 Pace Project No.: 92245118 QC Batch: PMST/3452 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92245118001, 92245118002, 92245118003 SAMPLE DUPLICATE: 1185592 35183639002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 13.8 14.2 3 10 SAMPLE DUPLICATE: 1185593 92245092006 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 15.8 16.1 2 10 SAMPLE DUPLICATE: 1185594 92245094007 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 34.6 35.1 1 10 SAMPLE DUPLICATE: 1185595 92245118003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 38.1 38.1 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/04/2015 10:26 AM without the written consent of Pace Analytical Services, Inc.. Page 27 of 35 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040223 Pace Project No.: 92245118 QC Batch: WET/36839 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92245118001, 92245118002, 92245118003 Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE DUPLICATE: 1434730 92245092011 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.0 6.0 0 10 SAMPLE DUPLICATE: 1434731 92245094013 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 7.5 7.5 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/04/2015 10:26 AM without the written consent of Pace Analytical Services, Inc.. Page 28 of 35 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040223 Pace Project No.: 92245118 QC Batch: WETA/45422 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92245118001, 92245118002, 92245118003 METHOD BLANK: 1183715 1183716 Matrix: Solid Units Associated Lab Samples: mg/kg Sulfate mg/kg Blank Reporting 1183718 Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.8 04/15/15 20:34 Sulfate mg/kg ND 49.8 04/15/15 20:34 LABORATORY CONTROL SAMPLE: 1183716 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1183718 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1183717 Parameter Chloride Sulfate Pace Analytical Services, Inc. 9800 %c&y&jre. Suite 100 Huntersville, NC 28078 (704)875-9092 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 503 484 96 80-120 503 473 94 80-120 92245118001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 722 634 88 80-120 ND 722 649 90 80-120 92245118001 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/04/2015 10:26 AM without the written consent of Pace Analytical Services, Inc.. Page 29 of 35 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040223 Pace Project No.: 92245118 QC Batch: WETA/45423 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92245118001, 92245118002, 92245118003 METHOD BLANK: 1183719 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 04/15/15 20:34 LABORATORY CONTROL SAMPLE: 1183720 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 50.3 48.1 96 80-120 MATRIX SPIKE SAMPLE: 1183722 92245118001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 72.2 64.5 89 80-120 H3 SAMPLE DUPLICATE: 1183721 92245118001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/04/2015 10:26 AM without the written consent of Pace Analytical Services, Inc.. Page 30 of 35 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040223 Pace Project No.: 92245118 QC Batch: WETA/28281 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92245118001, 92245118002, 92245118003 METHOD BLANK: 1149647 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 05/01/15 06:31 LABORATORY CONTROL SAMPLE: 1149648 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 121000 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1149649 1149650 MS MSD 92245143001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 1110 6790 6740 7310 6820 91 85 50-150 7 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1149651 1149652 MS MSD 92245118003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 6380 9710 9670 15600 17900 95 119 50-150 14 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/04/2015 10:26 AM without the written consent of Pace Analytical Services, Inc.. Page 31 of 35 aceAnaiXical www.pacelabs.com QUALIFIERS Project: J15040223 Pace Project No.: 92245118 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. Pace Analytical Services, Inc. 9800 K�gc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICPM/9631 [1] Batch was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS 1g % RSD >40 D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TNI accreditation for this parameter. P8 Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/04/2015 10:26 AM without the written consent of Pace Analytical Services, Inc.. Page 32 of 35 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15040223 Pace Project No.: 92245118 Pace Analytical Services, Inc. 9800 K3�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92245118001 2015010176 EPA 3050 MPRP/23696 EPA 6010 92245118002 2015010190 EPA 3050 MPRP/23696 EPA 6010 92245118003 2015010191 EPA 3050 MPRP/23696 EPA 6010 92245118001 2015010176 EPA 3050 MPRP/23697 EPA 6020 92245118002 2015010190 EPA 3050 MPRP/23697 EPA 6020 92245118003 2015010191 EPA 3050 MPRP/23697 EPA 6020 92245118001 2015010176 EPA 7471 MERP/5604 EPA 7471 92245118002 2015010190 EPA 7471 MERP/5604 EPA 7471 92245118003 2015010191 EPA 7471 MERP/5604 EPA 7471 92245118001 2015010176 ASTM D2974-87 PMST/3452 92245118002 2015010190 ASTM D2974-87 PMST/3452 92245118003 2015010191 ASTM D2974-87 PMST/3452 92245118001 2015010176 EPA 9045 WET/36839 92245118002 2015010190 EPA 9045 WET/36839 92245118003 2015010191 EPA 9045 WET/36839 92245118001 2015010176 EPA 9056 WETA/45422 92245118002 2015010190 EPA 9056 WETA/45422 92245118003 2015010191 EPA 9056 WETA/45422 92245118001 2015010176 EPA 9056 WETA/45423 92245118002 2015010190 EPA 9056 WETA/45423 92245118003 2015010191 EPA 9056 WETA/45423 92245118001 2015010176 EPA 9060 WETA/28281 92245118001 2015010176 EPA 9060 WETA/28282 92245118002 2015010190 EPA 9060 WETA/28281 92245118002 2015010190 EPA 9060 WETA/28282 92245118003 2015010191 EPA 9060 WETA/28281 92245118003 2015010191 EPA 9060 WETA/28282 Date: 05/04/2015 10:26 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Analytical Batch ICP/14483 ICP/14483 ICP/14483 ICPM/9631 ICPM/9631 ICPM/9631 MERC/5594 MERC/5594 MERC/5594 Page 33 of 35 Document Name: Document Revised: September 22. 1U14 aceAIMMical- Sample Condition Upon Receipt SCUR Pae 1 of 2 Document Number: Issuing AuthorRV:of 53 Ir F-CHR-CS-003-rev.15 Pace Huntersville Quality Office Client Name: 0 Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client❑ Commercial[I Other 12ISTIN ' Custody Seal on Cooler/Box Present: ❑ yes ❑ no Seals intact: ❑ yes ❑ no r Packing Material: ❑ Bubble vDp El"Bubble ubble Bags [] None ❑ Other Thermometer Used: 1R Gun (T'140' Type of Ice: Ie ' Blue None Samples on ice, cooling process has begun Tomn r".nrrari'inn Faranr T1AA1 Nn C orrpcfinn r. Corrected Cooler Temp.: l- °C Bi010 iCal T' sue Is Frozen: Yes No g Hate and Initials of plrta examining contents: d'� !�— Temp should be above freezing to °C Comments: Chain of Custody Present: Yes No ❑NIA 1. Chain of Custody Filled Out: &Y'es PNO ❑NIA 2. Chain of Custody Relinquished:es - vf'o ❑NIA 3. Sampler Name & Signature on COC: Yes ❑ ❑N/A 4. Samples Arrived within Hold Time: s C7No PWA 5. Short Hold Time Analysis (<72hr): Dyes o NIA 6. Rush Turn Around Time Requested: Oyes o ❑NIA 7. Sufficient Volume:es No ❑NIA 8. Correct Containers Used:es ❑No NIA 9. -Pace Containers Used: ❑Ye No ❑NIA Containers Intact: Yes ONO ©NIA 1 Filtered volume received for Dissolved tests Dyes cr, ❑ /A 11. Sample Labels match COC: ❑ es ©No ❑NIA 12. -includes date/time/[D/Analysis Matrix: ASI containers needing preservation have been checked. ❑Yes ON, NIA All containers needing preservation are found to be in QYes ❑No ❑NIA compliance with EPA recommendation. exceptions: VOA, coliform, TOC, O&G, WI -DRO (water) ❑YesNLJ o Samples checked for dechlorination: ❑Yes ONO NI 14. Headspace in VOA Vials (>6mm): ❑Yes ❑No EI A 15. Trip Blank Present: ❑Yes ONO ` 16. Trip Blank Custody Seals Present ❑Yes E]No `❑NiA Pace Trip Blank Lot # (if purchased): Client Notification! Resolution: Field Data Required? Y / N Person Contacted: Datefiime: Comments/ Resolution: SCURF Review: Date: 141 SRF Review: I 1(W I Date: I Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of hold, incorrect preservative, out of temp, incorrect containers) WO#92245118 11111111111111111111111 92245118 Page 34 of 35 m fl c M M z cc A z R M a3 mi E i G 2 Cusromer to cGrnplete appropriate columns to right I �e 0 Cuslomor must Complete >usf a m o 0 Ta o;� p C a O I�� - - p - : D a •-•o -•-• -•1 O ;O nF-1 CD § F -i Sr) Z C (Dm ! j a r 3> (PACE) G a m I a a is rw o m $ 1 rn C a _ N P S]7 =R.al a 0 � I I C7 v G7 C "•°' 3 o Q a I I I O o SPLP - Total Metals 3�t 0 v 'n iO I m CO I q ''camp. rD 18rnGrab O i =� Req lre 3 e 2- 8 oz jars (PACE) m �gm -a a w PH u m a t- i 1 -8 oz to 5 i� 2. w C s 2 ti S a a m nl I of 9p or e a oI Jj11a a I m v t I 1 of 5 e; n� rr-J f I ! I r i �i 6 m� ID n4� E 'roe oy+za Q im 5 [niz V a IQ 1 W y 2 1 0 i CD O I�� - - p - : D a •-•o -•-• -•1 O ;O nF-1 CD § F -i Sr) Z C (Dm ! j a r 3> (PACE) G a m I a a is 0 04 1-4 (D z $ 1 rn C a _ N P S]7 W I C7 v G7 C "•°' 3 fo I SPLP - Total Metals 3�t 0 v 'n iO I m CO F i D ''camp. 18rnGrab O i Req lre e ® 2- 8 oz jars (PACE) Total Metals, Anions, Do r -a a PH 04 t- i 1 -8 oz jar (PACE) 5 i� a ;l Oim Sediment specific oiO TCC 1- 4 oz jar 4 g C; m r (PACE) m a O m! {!� 0. —� P I SPLP - Total Metals 0 s 'n and Anions O i I I I I 2- 8 oz jars (PACE) g Do r 5� 3 i� Sediment specific tests 2 - 8 oz jar m i (ACCESS i I I l ANALYTICAL) 5 I !� s 3 0 2A i I -� Af6 0 :a(s o 0 Llv I y V J _ 4 E7 r 03 C -'i O y M + 0 x z M 70 Total tt of Containers Pa9eC3 5 of 35 0 ACCESS ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Duke Energy 13339 Hagers Ferry Rd. Huntersville NC 28078 ATTENTION Marge Galvin -Karr PROJECT ID J15040223 LABORATORY REPORT NUMBER 1504C41 DATE April 28, 2015 Primary Data Review By Secondary Data Review By Ashley Amick Chantelle Kanhai Project Manager, Access Analytical Project Manager, AES aamick@axs-inc.com PLEASE NOTE: 42 of 53 - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL -E87582, NELAP certified laboratory # E87582 - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 1 of 7 (� DUKE ENERi _na_ CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST' FORM _ - -Alytical Laboratory - Services -i i _._ - -. ._. ..._.- -Ana cal Laboratory Use Only MMI Coda MG03A2 (Building 74051 3799 Hagem Forty Rd ri ork uil4 O ZZ,3 McMtc: SAIL 1Samples v ad ro Fm Huntersvflle, N. C. 28078 i j14999d By Date s Time Y� (980) 875.5245 I - - - - ............i IV-/ -I 3 SAMPLE PROGRAM GmundVJater— NF iVendor i I — othtx__ Plant,_,,,_ tpr°)K' 1°a"te AB Ground(�water ssessment - Soil -Fl alCtktN �Y►' { l L�TfY�. AS GW 6� �« 'q-" No: SlBuain�aa Unit 6iPcOJatt ID: TN1eq Coda: aj Opsradn9 UntC 9).0.ttWlty 10: 700Proc ku� O U V Q O V1lttwn wocH'ic accowd" has flown eutabilehed A0012 not lndlrated above we need the fdlowknq: 11 Etter Cbrntct accotmtlna in all 5 accounting fieldw Above, or 2 Provide Corset aeeourttln for O ratln elntt and Process 3D. 1 LAS USE ONLY I ii llub ID iAatrlk (3oq s.dlmara. Aatt) pI�i T TyLo.�s`� 0 4. w _ is U V Q O co a .m p k i G V7 R N w a Q F kv i i• WATER or ID EQUIPMENT BLANK 0 PER Access Analytical Cooler Tem C PO Number 1,142057serv.:1=H • 3-H ice - one tq 'ci' 1i v PACE eo all m o - N PO 114208.' Q irlvdt;i>E a� a a g. o � addedwi[leire^PSnitnuiauoL`a8atpft aD oo V 'ColleCtiort m P. 8, Cd; Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Na, Sr, TI, V, Zn, Memury, PH 4 % Sediment SpecIfIc ParamNtara: 4WOUft, CEC, Pei ftIe Redox 1 ERRA —� E01) i DISTRIBUTION ORIGINAL to LAS, COPY to CLIENT 3 & / 72Requested Tumaround LJ'36 14 Dep x y�•;t315 -7 Days - 48 Hr LR3eling]atsh� d Bye f f. Date/Time: _Bage 2 of Received By: — FE�Ey --.,.,..,.. _ I6Ve LLN Date/Time: r! .� � ; IS 0 U lection Information is U V Q O co —Ea m wU Tome SF nzdure p CL r V7 R N w a Q P. 8, Cd; Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Na, Sr, TI, V, Zn, Memury, PH 4 % Sediment SpecIfIc ParamNtara: 4WOUft, CEC, Pei ftIe Redox 1 ERRA —� E01) i DISTRIBUTION ORIGINAL to LAS, COPY to CLIENT 3 & / 72Requested Tumaround LJ'36 14 Dep x y�•;t315 -7 Days - 48 Hr LR3eling]atsh� d Bye f f. Date/Time: _Bage 2 of Received By: — FE�Ey --.,.,..,.. _ I6Ve LLN Date/Time: r! .� � ; IS Analytical Environmental Services, Inc Date: 28 -Apr -15 44 of 53 Client: Duke Energy Project: Asheville Plant Case Narrative Lab ID: 1504C41 REDOX POTENTIAL: 1504C41-001 106.6 mV 123.2 mV 144.1 mV 1504C41-002 219.3 mV 149.3 mV 137.0 mV 1504C41-003 50.1mV 47.9 mV 40.8 mV LCS TRUE VALUE: 240mV LCS: 262.3 mV 109.3% Recovery Page 3 of 7 Analytical Environmental Services, Inc Date: 28 -Apr -15 45 of 53 Client: Duke Energy Client Sample ID: SW -06 Project Name: Asheville Plant Collection Date: 4/9/2015 9:15:00 AM Lab ID: 1504C41-001 Matrix: Sediment Reporting Dilution Analyses Result Qual Units BatchID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity Qualifiers: * Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value (SW9081) BRL 1.0 meq/100g 206119 1 04/17/2015 22:24 JL E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Nan See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 4 of 7 Analytical Environmental Services, Inc Date: 28 -Apr -15 46 of 53 Client: Duke Energy Client Sample ID: SW -07 Project Name: Asheville Plant Collection Date: 4/9/2015 10:40:00 AM Lab ID: 1504C41-002 Matrix: Sediment Reporting Dilution Analyses Result Qual Units BatchID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity Qualifiers: z Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value (SW9081) 3.8 1.0 meq/100g 206119 1 04/17/2015 22:28 JL E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 5 of 7 Analytical Environmental Services, Inc Date: 28 -Apr -15 47 of 53 Client: Duke Energy Client Sample ID: SW -07 DUP Project Name: Asheville Plant Collection Date: 4/9/2015 10:35:00 AM Lab ID: 1504C41-003 Matrix: Sediment Reporting Dilution Analyses Result Qual Units BatchID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity (SW9081) 1.7 1.0 meq/100g 206119 1 04/17/2015 22:31 JL Q ualiners: * Value exceeds maximum contaminant level E Estimated (value above quantitation range) BRL Below reporting limit S Spike Recovery outside limits due to matrix H Holding times for preparation or analysis exceeded Narr See case narrative N Analyte not NELAC certified NC Not confirmed B Analyte detected in the associated method blank < Less than Result value > Greater than Result value J Estimated value detected below Reporting Limit Page 6 of 7 48 of 53 Analytical Environmental Services, Ine. Sample/Cooler Receipt Checklist Client Work Order Number 1,:S-�XC4V Checklist completed by Signature Date Carrier name: FedEx V U- PS Courier Client US \Mail Other Shipping container/cooler in good condition? Yes Custody seals intact on shipping container/cooler? Yes ` No Custody seals intact on sample bottles? Yes o Container/Temp Blank temperature in compliance? (0°56°C)* Yes No �� Cooler 41 a..Cooler #2 Cooler #3 Cooler 44 Chain of custody present? Chain of custody signed when relinquished and received? Chain of custody agrees with sample labels? Samples in proper container/bottle? Sample containers intact? Sufficient sample volume for indicated test? All samples received within holding time? Was TAT marked on the COC? Yes No Yes �,Z'^ No Yes No Yes _ No Yes V No _ Yes No Yes i/ No Yes V No Proceed with Standard TAT as per project history? Yes _ No Water - VOA vials have zero headspace? No VOA vials submitted ✓_ Yes Water - pH acceptable upon receipt? Yes ',- No Adjusted? Sample Condition; Goad k--"" Other(Explain) (For diffusive samples or A1HA lead) Is a known blank included? See Case Narrative for resolution of the Non -Conformance. Not Present Not Present Not Present` Coolcr#5 Cooler #6 Not Applicable No Not Applicable Checked by Yes _ No L� * Samples do not have to comply with the given range for certain parameters. \ Aes server111Sample ReeeiptlMy DocumentslCOCs and pH Adjustment ShcoMample_Cooler Recipt Checklist Rev I.rtf Page 7 of 7 April 27, 2015 Access Analytical 7478 Carlisle Street Irmo, South Carolina 29063 Attn: Mr. Ashley Amick Re: Summary of Laboratory Testing AB Groundwater Assessment Terracon Project No. 73075016 (WOJ15040223) Dear Mr. Amick: 49 of 53 Irerracon Terracon has performed the requested laboratory testing program indicated by your Chain of Custody Record, dated 04/18/15. The correspondence indicated hydrometer testing for Samples SW -06, SW -07, and SW-07DUP. The results have been electronically forwarded to you in PDF format at aamick@accessanalyticalinc.com, as instructed. If there are any questions regarding the results or if we can be of additional service, please contact us. Sincerely, Terracon Consultants, Inc. Rebecca Simms, CET Laboratory Manager Attachments Copies: 1xc: Above (PDF via email) 1xc: File lZ63Mdil Phillip A. Morrison, P.E. Geotechnical Department Manager Terracon Consultants, Inc. 521 Clemson Road Columbia, South Carolina 29229 P [803] 741 9000 F [803] 741 9900 terracon.com 95 90 85 80 75 70 65 T 60 w >- 55 M Z 50 LL z 45 LU ry 40 LU o_ 35 30 25 20 15 10 5 0 GRAIN SIZE DISTRIBUTION ASTM D422 U.S. SIEVE OPENING IN INCHES I U.S. SIEVE NUMBERS I HYDROMETER 6 4 3 1.5 3/4 i 3/8 s 4 b 8 i u 14 i b 20 su 40 ou 60 i uu 140 zuu 100 10 1 0.1 GRAIN SIZE IN MILLIMETERS 0.01 50 of 53 J 0.001 COBBLES GRAVEL SAND SILT OR CLAY coarse I fine coarse medium I fine Boring ID Depth AASHTO Classification LL PL PI Cc Cu • SW -06 0 Q 1.27 6.29 Boring ID Depthl D,00 D60 D30 D,0 %Gravel %Sand %Silt %Clay 10 SW -06 0 12.7 0.956 0.429 0.152 5.4 89.0 2.3 3.2 PROJECT: AB GW Assessment - Asheville Sediment PROJECT NUMBER: 73075016 SITE: Asheville, North Carolina Irerracon CLIENT: Access Analytial 521 Clemson Road Columbia, South Carolina 100 95 90 85 80 75 70 65 H 2 60 w >- 55 m ry Z 50 LL z 45 w 40 w CL 35 30 25 20 15 10 5 0 GRAIN SIZE DISTRIBUTION 51 of 53 ASTM D422 U.S. SIEVE OPENING IN INCHES I U.S. SIEVE NUMBERS I HYDROMETER a 4 z 2 9 r 1 zid 1/2z/Q 3 d 6 A10 1416 qn 30 do 50 an 1001Ar, 200 100 10 1 0.1 GRAIN SIZE IN MILLIMETERS 0.01 0.001 I COBBLES GRAVEL SAND SILT OR CLAY i coarse I fine coarse I medium I fine Boring ID Depth AASHTO Classification LL PL PI Cc Cu • SW -07 0 () 1.01 3.67 Boring ID Depthl D,00 D60 D30 D10 %Gravel %Sand %Silt %Clay 19 SW -07 0 12.7 0.394 0.206 0.107 4.0 91.0 1.8 3.2 PROJECT: AB GW Assessment - Asheville Sediment PROJECT NUMBER: 73075016 SITE: Asheville, North Carolina 1 rerracon CLIENT: Access Analytial 521 Clemson Road Columbia, South Carolina 100 95 90 85 80 75 70 65 H 2 60 w >- 55 m ry Z 50 LL z 45 w 40 w CL 35 30 25 20 15 10 5 0 GRAIN SIZE DISTRIBUTION 52 of 53 ASTM D422 U.S. SIEVE OPENING IN INCHES U.S. SIEVE NUMBERS I HYDROMETER A i iii z a in 1 In Gn inn Onn ■111111■■�ulIY11■11■■IY1111■■■■II 100 10 1 0.1 GRAIN SIZE IN MILLIMETERS 0.01 J 0.001 COBBLES GRAVEL SAND SILT OR CLAY coarse I fine coarse I medium I fine Boring ID Depth AASHTO Classification LL PL PI Cc Cu • SW -07 DUP 0 () 1.18 4.44 Boring ID Depthl D,00 D60 Dao D10 9/Gravel %Sand %Silt %Clay 19SW-07 DUP 0 19 0.376 0.194 0.085 8.1 83.5 3.7 4.8 PROJECT: AB GW Assessment - Asheville Sediment PROJECT NUMBER: 73075016 SITE: Asheville, North Carolina 1 rerracon CLIENT: Access Analytial 521 Clemson Road Columbia, South Carolina CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM ------------ labirivatory use only i SYNTERRA EDD 7 Servic" M_'L_ SIC_ Mgg CWM WOW z S(ML ORIGMAL bD LAS, DUKE I p.j COPY bD CLIENT "wwwaIAim, W. 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