NC0000396_J15040217 Report_20150823

+ DUKE Analytical Laboratory
ENERGY
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
Order Number: J15040217
Project Name: ASHEVILLE - AB GW ASSESSMENT SOIL
Customer Name(s): Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker
Customer Address: 200 CP and L Drive
Arden, NC 28704
Lab Contact: Margaret Galvin -Karr Phone: [phone]
MXG4644 (101 161)
Report Authorized By: �`IVKG�Y zo15.o5.z9 10:25:48 Date:
(Signature) `1 -04'00'
Margaret Galvin -Karr
Program Comments:
Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report.
Data Flags & Calculations:
5/19/2015
`Irastoic]
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions: 2 of 103
Collection
Sample ID Plant/Station Date and Time Collected By Sample Description
2015010112
ASHEVILLE
31 -Mar -15 2:00 PM
Russo
Equipment Blank
2015010113
ASHEVILLE
31 -Mar -15 2:50 PM
Russo
MW -09 SB (1-2)
2015010114
ASHEVILLE
02 -Apr -15 9:25 AM
Russo
Equipment Blank
2015010115
ASHEVILLE
02 -Apr -15 9:50 AM
Russo
MW -01 SB (1-2)
2015010116
ASHEVILLE
02 -Apr -15 1:20 PM
Russo
MW -01 SB (7-8)
2015010117
ASHEVILLE
02 -Apr -15 1:30 PM
Russo
MW -01 SB (12-13)
2015010118
ASHEVILLE
02 -Apr -15 1:40 PM
Russo
MW -01 SB (38-40)
2015010119
ASHEVILLE
06 -Apr -15 4:00 PM
Russo
AB -09 SB (5-6)
2015010120
ASHEVILLE
06 -Apr -15 4:10 PM
Russo
AB -09 SB (33-35)
2015010121
ASHEVILLE
06 -Apr -15 4:45 PM
Russo
AB -09 SB (38-39)
2015010122
ASHEVILLE
06 -Apr -15 5:00 PM
Russo
AB -09 SB (46-47)
2015010123
ASHEVILLE
06 -Apr -15 5:05 PM
Russo
AB -09 SB (56-59)
12 Total Samples

Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes F./] No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
U Job Summary Report
❑ Sample Identification
n Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Reviewed By: Date:
3 of 103
Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
0 Chain of Custody
[I/0] Electronic Data Deliverable (EDD) Sent Separately

Certificate of Laboratory Analysis 4 of 103
This report shall not be reproduced, except in full.
Order # J15040217
Site: Equipment Blank
Collection Date: 31 -Mar -15 2:00 PM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015010112
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040217
Site: MW -09 SB (1-2)
Collection Date: 31 -Mar -15 2:50 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
5 of 103
Sample #: 2015010113
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis 6 of 103
This report shall not be reproduced, except in full.
Order # J15040217
Site: Equipment Blank
Collection Date: 02 -Apr -15 9:25 AM
Analyte Result Units Qualifiers RDL DF
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015010114
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040217
Site: MW -01 SB (1-2)
Collection Date: 02 -Apr -15 9:50 AM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
7 of 103
Sample #: 2015010115
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040217
Site: MW -01 SB (7-8)
Collection Date: 02 -Apr -15 1:20 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
8 of 103
Sample #: 2015010116
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040217
Site: MW -01 SB (12-13)
Collection Date: 02 -Apr -15 1:30 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
9 of 103
Sample #: 2015010117
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040217
Site: MW -01 SB (38-40)
Collection Date: 02 -Apr -15 1:40 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
10 of 103
Sample #: 2015010118
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040217
Site: AB -09 SB (5-6)
Collection Date: 06 -Apr -15 4:00 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
11 of 103
Sample #: 2015010119
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040217
Site: AB -09 SB (33-35)
Collection Date: 06 -Apr -15 4:10 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
SPLP LEACHATE - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
12 of 103
Sample #: 2015010120
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040217
Site: AB -09 SB (38-39)
Collection Date: 06 -Apr -15 4:45 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
13 of 103
Sample #: 2015010121
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040217
Site: AB -09 SB (46-47)
Collection Date: 06 -Apr -15 5:00 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
14 of 103
Sample #: 2015010122
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15040217
Site: AB -09 SB (56-59)
Collection Date: 06 -Apr -15 5:05 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
15 of 103
Sample #: 2015010123
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

aceAnaiXical
www.pacelabs.com
April 28, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
RE: Project: J15040217
Pace Project No.: 92245094
Pace Analytical Services, Inc.
980011�i yoAje. Suite 100
Huntersville, INC 28078
[phone]
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on April 10, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Marge Galvin -Karr, Duke Energy
Program Manager, Duke Energy
Rodney Wilke, Duke Energy
HiQ p«FO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
lqe� ��� without the written consent of Pace Analytical Services, Inc..
BRAT,
Page 1 of 87

lacmnalyfica(
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Project: J15040217
Pace Project No.: 92245094
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
A21 -A Certification #: 2926.01
Alaska Certification #: UST -078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ -0014
Arkansas Certification #: 88-0680
California Certification #: 01155CA
Colorado Certification #Pace
Connecticut Certification #: PH -0256
EPA Region 8 Certification #: 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification #:14-008r
Georgia Certification #: 959
Georgia EPD #: Pace
Idaho Certification #: MN00064
Hawaii Certification #MN00064
Illinois Certification #: 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
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Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification #: 3086
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Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Ormond Beach Certification IDs
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Delaware Certification: FL NELAC Reciprocity
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Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
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Green Bay Certification IDs
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Illinois Certification #: 200050
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Louisiana Certification #: 04168
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Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Pace Analytical Services, Inc.
98001YrwyNe. Suite 100
Huntersville, NC 28078
[phone]
CERTIFICATIONS
Minnesota Certification #: 027-053-137
Mississippi Certification #: Pace
Montana Certification #: MT0092
Nevada Certification #: MN_00064
Nebraska Certification #: Pace
New Jersey Certification #: MN -002
New York Certification #: 11647
North Carolina Certification #: 530
North Carolina State Public Health #: 27700
North Dakota Certification #: R-036
Ohio EPA#: 4150
Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
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South Carolina #:74003001
Texas Certification #: T104704192
Tennessee Certification #: 02818
Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251
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Washington Certification #: C486
West Virginia Certification #: 382
West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
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Nebraska Certification: NE -OS -28-14
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North Carolina Environmental Certificate #: 667
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South Carolina Certification: #96042001
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Texas Certification: FL NELAC Reciprocity
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Washington Certification #: C955
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Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
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North Carolina Drinking Water Certification #: 37712
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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aceAnaiXical
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Project: J15040217
Pace Project No.: 92245094
Asheville Certification IDs
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
CERTIFICATIONS
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
98001�YOAJe. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 87

aceAnaiXical
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SAMPLE SUMMARY
Project: J15040217
Pace Project No.: 92245094
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92245094001
2015010112
Water
03/31/1514:00
04/10/1516:35
92245094002
2015010114
Water
04/02/15 09:25
04/10/1516:35
92245094003
2015010120 SPLP
Water
04/06/15 16:10
04/10/15 16:35
92245094004
2015010113
Solid
03/31/1514:50
04/10/1516:35
92245094005
2015010115
Solid
04/02/15 09:50
04/10/15 16:35
92245094006
2015010116
Solid
04/02/1513:20
04/10/1516:35
92245094007
2015010117
Solid
04/02/1513:30
04/10/1516:35
92245094008
2015010118
Solid
04/02/1513:40
04/10/1516:35
92245094009
2015010119
Solid
04/06/1516:00
04/10/1516:35
92245094010
2015010121
Solid
04/06/1516:45
04/10/1516:35
92245094011
2015010122
Solid
04/06/1517:00
04/10/1516:35
92245094012
2015010123
Solid
04/06/1517:05
04/10/1516:35
92245094013
2015010120
Solid
04/06/1516:10
04/10/1516:35
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
98001qr6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 87

aceAnaiXical
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SAMPLE ANALYTE COUNT
Pace Analytical Services, Inc.
9800�8rpyoAje. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
J15040217
92245094
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92245094001
2015010112
EPA 6020A
TT3
24
PASI-M
EPA 7470
LMW
1
PASI-M
92245094002
2015010114
EPA 6020A
TT3
24
PASI-M
EPA 7470
LMW
1
PASI-M
92245094003
2015010120 SPLP
EPA 6020A
TT3
24
PASI-M
EPA 7470A
LMW
1
PASI-M
92245094004
2015010113
EPA 6010
CKJ
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA 7471
TAP
1
PASI-O
ASTM D2974-87
AEM
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 9056
KHC
2
PASI-O
EPA 9056
KHC
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245094005
2015010115
EPA 6010
TAP
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA 7471
TAP
1
PASI-O
ASTM D2974-87
AEM
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 9056
KHC
2
PASI-O
EPA 9056
KHC
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245094006
2015010116
EPA 6010
CKJ
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA 7471
TAP
1
PASI-O
ASTM D2974-87
AEM
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 9056
KHC
2
PASI-O
EPA 9056
KHC
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245094007
2015010117
EPA 6010
CKJ
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA 7471
TAP
1
PASI-O
ASTM D2974-87
AEM
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 9056
KHC
2
PASI-O
EPA 9056
KHC
1
PASI-O
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 5 of 87

aceAnaiXical
www.pacelabs.com
SAMPLE ANALYTE COUNT
Pace Analytical Services, Inc.
980c�)irpyoAje. Suite 100
Huntersville, NC 28078
[phone]
Project:
J15040217
Pace Project No.:
92245094
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
EPA 9060
TJJ
6
PASI-G
92245094008
2015010118
EPA 6010
CKJ
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA 7471
TAP
1
PASI-O
ASTM D2974-87
AEM
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 9056
KHC
2
PASI-O
EPA 9056
KHC
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245094009
2015010119
EPA 6010
CKJ
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA 7471
TAP
1
PASI-O
ASTM D2974-87
AEM
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 9056
KHC
2
PASI-O
EPA 9056
KHC
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245094010
2015010121
EPA 6010
CKJ
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA 7471
TAP
1
PASI-O
ASTM D2974-87
AEM
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 9056
KHC
2
PASI-O
EPA 9056
KHC
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245094011
2015010122
EPA 6010
CKJ
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
AEM
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 9056
KHC
2
PASI-O
EPA 9056
KHC
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245094012
2015010123
EPA 6010
CKJ, TAP
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
AEM
1
PASI-O
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 6 of 87

aceAnaiXical
www.pacelabs.com
SAMPLE ANALYTE COUNT
Project: J15040217
Pace Project No.: 92245094
Pace Analytical Services, Inc.
9800�qrpyoAje. Suite 100
Huntersville, NC 28078
[phone]
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
EPA 9045
MAB
1
PASI-A
EPA 9056
KHC
2
PASI-O
EPA 9056
KHC
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92245094013 2015010120 EPA 6010
CKJ
16
PASI-0
EPA 6020
CRT
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
AEM
1
PASI-O
EPA 9045
MAB
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 4500 -CI -E
SER
1
PASI-A
EPA 9056
KHC
2
PASI-O
EPA 9056
KHC
1
PASI-O
EPA 9060
TJJ
6
PASI-G
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 7 of 87

aceAnaiXical
www.pacelabs.com
Project: J15040217
Pace Project No.: 92245094
Lab Sample ID Client Sample ID
Method Parameters
Pace Analytical Services, Inc.
9800�SrpyoAje. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92245094001
2015010112
EPA 6020A
Aluminum
198
ug/L
10.0
04/15/15 16:29
EPA 6020A
Barium
4.7
ug/L
0.30
04/15/15 16:29
EPA 6020A
Calcium
913
ug/L
40.0
04/15/15 16:29
EPA 6020A
Chromium
3.0
ug/L
0.50
04/15/15 16:29
EPA 6020A
Cobalt
5.0
ug/L
0.50
04/15/15 16:29
EPA 6020A
Copper
3.4
ug/L
1.0
04/15/15 16:29
EPA 6020A
Iron
2430
ug/L
50.0
04/15/15 16:29
EPA 6020A
Lead
0.38
ug/L
0.10
04/16/15 10:47
EPA 6020A
Magnesium
176
ug/L
10.0
04/16/15 10:47
EPA 6020A
Manganese
27.9
ug/L
0.50
04/15/15 16:29
EPA 6020A
Molybdenum
1.5
ug/L
0.50
04/15/15 16:29
EPA 6020A
Nickel
2.6
ug/L
0.50
04/15/15 16:29
EPA 6020A
Potassium
127
ug/L
50.0
04/15/15 16:29
EPA 6020A
Sodium
226
ug/L
50.0
04/15/15 16:29
EPA 6020A
Strontium
2.4
ug/L
0.50
04/15/15 16:29
EPA 6020A
Zinc
9.5
ug/L
5.0
04/15/15 16:29
92245094002
2015010114
EPA 6020A
Aluminum
511
ug/L
10.0
04/15/15 16:35
EPA 6020A
Barium
7.6
ug/L
0.30
04/15/15 16:35
EPA 6020A
Calcium
505
ug/L
40.0
04/15/15 16:35
EPA 6020A
Chromium
1.8
ug/L
0.50
04/15/15 16:35
EPA 6020A
Cobalt
0.69
ug/L
0.50
04/15/15 16:35
EPA 6020A
Copper
1.1
ug/L
1.0
04/15/15 16:35
EPA 6020A
Iron
689
ug/L
50.0
04/15/15 16:35
EPA 6020A
Lead
0.55
ug/L
0.10
04/15/15 16:35
EPA 6020A
Magnesium
106
ug/L
10.0
04/16/15 10:50
EPA 6020A
Manganese
18.7
ug/L
0.50
04/15/15 16:35
EPA 6020A
Potassium
146
ug/L
50.0
04/15/15 16:35
EPA 6020A
Sodium
234
ug/L
50.0
04/15/15 16:35
EPA 6020A
Strontium
2.2
ug/L
0.50
04/15/15 16:35
EPA 6020A
Zinc
5.6
ug/L
5.0
04/15/15 16:35
92245094003
2015010120 SPLP
EPA 6020A
Aluminum
1640
ug/L
10.0
04/23/15 15:04
EPA 6020A
Antimony
4.2
ug/L
0.50
04/23/15 15:04
EPA 6020A
Arsenic
270
ug/L
0.50
04/23/15 15:04
EPA 6020A
Barium
369
ug/L
0.30
04/23/15 15:04
EPA 6020A
Beryllium
0.89
ug/L
0.20
04/23/15 15:04
EPA 6020A
Boron
60.8
ug/L
5.0
04/23/15 15:04
EPA 6020A
Cadmium
0.56
ug/L
0.080
04/23/15 15:04
EPA 6020A
Calcium
2750
ug/L
40.0
04/23/15 15:04
EPA 6020A
Chromium
11.9
ug/L
0.50
04/23/15 15:04
EPA 6020A
Cobalt
1.3
ug/L
0.50
04/23/15 15:04
EPA 6020A
Copper
13.2
ug/L
1.0
04/23/15 15:04
EPA 6020A
Iron
899
ug/L
50.0
04/23/15 15:04
EPA 6020A
Lead
4.6
ug/L
0.10
04/23/15 15:04
EPA 6020A
Magnesium
418
ug/L
10.0
04/23/15 15:04
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Qualifiers
Page 8 of 87

aceAnaiXical
www.pacelabs.com
Project: J15040217
Pace Project No.: 92245094
Lab Sample ID Client Sample ID
Method Parameters
Pace Analytical Services, Inc.
9800A'ir6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92245094003
2015010120 SPLP
EPA 6020A
Manganese
27.1
ug/L
0.50
04/23/15 15:04
EPA 6020A
Molybdenum
2.9
ug/L
0.50
04/23/15 15:04
EPA 6020A
Nickel
2.4
ug/L
0.50
04/23/15 15:04
EPA 6020A
Potassium
731
ug/L
50.0
04/23/15 15:04
EPA 6020A
Selenium
11.4
ug/L
0.50
04/23/15 15:04
EPA 6020A
Sodium
1140
ug/L
50.0
04/23/15 15:04
EPA 6020A
Strontium
143
ug/L
0.50
04/23/15 15:04
EPA 6020A
Thallium
1.2
ug/L
0.10
04/23/15 15:04
EPA 6020A
Vanadium
139
ug/L
1.0
04/23/15 15:04
EPA 6020A
Zinc
47.8
ug/L
5.0
04/23/15 15:04
EPA 7470A
Mercury
0.030J
ug/L
0.20
04/23/15 19:57
92245094004
2015010113
EPA 6010
Aluminum
34200
mg/kg
33.5
04/25/15 17:42
EPA 6010
Barium
75.2
mg/kg
3.3
04/25/15 17:42
EPA 6010
Beryllium
0.82
mg/kg
0.33
04/25/15 17:42
EPA 6010
Calcium
102J
mg/kg
167
04/25/15 17:42
EPA 6010
Chromium
17.8
mg/kg
1.7
04/25/15 17:42
EPA 6010
Copper
33.0
mg/kg
1.7
04/25/15 17:42
EPA 6010
Iron
39200
mg/kg
13.4
04/25/15 17:42
EPA 6010
Magnesium
3000
mg/kg
167
04/25/15 17:42
EPA 6010
Manganese
548
mg/kg
1.7
04/25/15 17:42
EPA 6010
Nickel
10.2
mg/kg
1.7
04/25/15 17:42
EPA 6010
Potassium
2740
mg/kg
335
04/25/15 17:42
EPA 6010
Strontium
2AJ
mg/kg
3.3
04/25/15 17:42
EPA 6010
Zinc
55.7
mg/kg
6.7
04/25/15 17:42
EPA 6020
Cobalt
29.6
mg/kg
6.7
04/22/15 00:08
EPA 6020
Lead
12.9
mg/kg
6.7
04/22/15 00:08
EPA 6020
Vanadium
48.6
mg/kg
6.7
04/22/15 00:08
EPA 7471
Mercury
0.020
mg/kg
0.011
04/17/15 13:07
ASTM D2974-87
Percent Moisture
26.3
%
0.10
04/16/15 16:02
EPA 9045
pH at 25 Degrees C
6.4
Std. Units
0.10
04/16/15 10:45
EPA 9060
Total Organic Carbon
704J
mg/kg
810
04/23/15 11:43
EPA 9060
Mean Total Organic Carbon
442J
mg/kg
812
04/23/15 11:27
EPA 9060
RSD%
39.5
%
04/23/15 11:27
92245094005
2015010115
EPA 6010
Aluminum
21600
mg/kg
125
04/26/15 23:00
EPA 6010
Barium
36.4
mg/kg
12.5
04/26/15 23:00
EPA 6010
Beryllium
2.6
mg/kg
1.2
04/26/15 23:00
EPA 6010
Chromium
19.9
mg/kg
6.2
04/26/15 23:00
EPA 6010
Copper
192
mg/kg
6.2
04/26/15 23:00
EPA 6010
Iron
108000
mg/kg
49.8
04/26/15 23:00 D4
EPA 6010
Manganese
4000
mg/kg
6.2
04/26/15 23:00
EPA 6010
Nickel
34.8
mg/kg
6.2
04/26/15 23:00
EPA 6010
Zinc
109
mg/kg
24.9
04/26/15 23:00
EPA 6020
Cobalt
228
mg/kg
6.2
04/22/15 00:10
EPA 6020
Lead
12.5
mg/kg
6.2
04/22/15 00:10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Qualifiers
Page 9 of 87

aceAnaiXical
www.pacelabs.com
Project: J15040217
Pace Project No.: 92245094
Lab Sample ID Client Sample ID
Method Parameters
Pace Analytical Services, Inc.
9800Air6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92245094005
2015010115
EPA 6020
Selenium
4.5J
mg/kg
6.2
04/22/15 00:10
EPA 6020
Vanadium
15.8
mg/kg
6.2
04/22/15 00:10
EPA 7471
Mercury
0.0095J
mg/kg
0.010
04/17/15 13:09
ASTM D2974-87
Percent Moisture
16.0
%
0.10
04/16/15 16:03
EPA 9045
pH at 25 Degrees C
5.0
Std. Units
0.10
04/16/15 10:45
EPA 9060
Total Organic Carbon
9110
mg/kg
721
04/23/15 11:54
EPA 9060
Total Organic Carbon
9510
mg/kg
720
04/23/15 12:00
EPA 9060
Total Organic Carbon
8170
mg/kg
712
04/23/15 12:06
EPA 9060
Total Organic Carbon
10800
mg/kg
714
04/23/15 12:13
EPA 9060
Mean Total Organic Carbon
9390
mg/kg
717
04/23/15 11:54
EPA 9060
RSD%
11.5
%
04/23/15 11:54
92245094006
2015010116
EPA 6010
Aluminum
34800
mg/kg
33.9
04/25/15 17:51
EPA 6010
Barium
76.1
mg/kg
3.4
04/25/15 17:51
EPA 6010
Beryllium
1.9
mg/kg
0.34
04/25/15 17:51
EPA 6010
Chromium
20.1
mg/kg
1.7
04/25/15 17:51
EPA 6010
Copper
68.1
mg/kg
1.7
04/25/15 17:51
EPA 6010
Iron
53800
mg/kg
13.6
04/25/15 17:51
EPA 6010
Magnesium
2810
mg/kg
170
04/25/15 17:51
EPA 6010
Manganese
2070
mg/kg
1.7
04/25/15 17:51
EPA 6010
Nickel
41.3
mg/kg
1.7
04/25/15 17:51
EPA 6010
Potassium
2070
mg/kg
339
04/25/15 17:51
EPA 6010
Strontium
8.9
mg/kg
3.4
04/25/15 17:51
EPA 6010
Zinc
75.4
mg/kg
6.8
04/25/15 17:51
EPA 6020
Cobalt
85.7
mg/kg
6.8
04/22/15 00:12
EPA 6020
Lead
11.6
mg/kg
6.8
04/22/15 00:12
EPA 6020
Vanadium
35.3
mg/kg
6.8
04/22/15 00:12
ASTM D2974-87
Percent Moisture
29.7
%
0.10
04/16/15 16:03
EPA 9045
pH at 25 Degrees C
5.3
Std. Units
0.10
04/16/15 10:45
EPA 9060
Total Organic Carbon
1220
mg/kg
861
04/23/15 12:19
EPA 9060
Total Organic Carbon
1360
mg/kg
847
04/23/15 12:26
EPA 9060
Total Organic Carbon
1200
mg/kg
849
04/23/15 12:32
EPA 9060
Total Organic Carbon
1360
mg/kg
859
04/23/15 12:38
EPA 9060
Mean Total Organic Carbon
1290
mg/kg
854
04/23/15 12:19
EPA 9060
RSD%
6.8
%
04/23/15 12:19
92245094007
2015010117
EPA 6010
Aluminum
25900
mg/kg
36.4
04/25/15 18:11
EPA 6010
Barium
35.0
mg/kg
3.6
04/25/15 18:11
EPA 6010
Beryllium
2.4
mg/kg
0.36
04/25/15 18:11
EPA 6010
Chromium
21.7
mg/kg
1.8
04/25/15 18:11
EPA 6010
Copper
68.7
mg/kg
1.8
04/25/15 18:11
EPA 6010
Iron
62400
mg/kg
14.6
04/25/15 18:11
EPA 6010
Magnesium
3050
mg/kg
182
04/25/15 18:11
EPA 6010
Manganese
1530
mg/kg
1.8
04/25/15 18:11
EPA 6010
Nickel
14.9
mg/kg
1.8
04/25/15 18:11
EPA 6010
Potassium
2030
mg/kg
364
04/25/15 18:11
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 10 of 87

aceAnaiXical
www.pacelabs.com
Project: J15040217
Pace Project No.: 92245094
Lab Sample ID Client Sample ID
Method Parameters
Pace Analytical Services, Inc.
9800AirpyoAje. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92245094007
2015010117
EPA 6010
Strontium
1.8J
mg/kg
3.6
04/25/15 18:11
EPA 6010
Zinc
68.3
mg/kg
7.3
04/25/15 18:11
EPA 6020
Cobalt
41.8
mg/kg
7.3
04/22/15 00:14
EPA 6020
Lead
8.6
mg/kg
7.3
04/22/15 00:14
EPA 6020
Vanadium
34.7
mg/kg
7.3
04/22/15 00:14
ASTM D2974-87
Percent Moisture
34.6
%
0.10
04/16/15 16:04
EPA 9045
pH at 25 Degrees C
5.1
Std. Units
0.10
04/16/15 10:45
EPA 9060
Total Organic Carbon
1760
mg/kg
915
04/23/15 12:44
EPA 9060
Total Organic Carbon
1840
mg/kg
910
04/23/15 12:50
EPA 9060
Total Organic Carbon
1570
mg/kg
916
04/23/15 12:56
EPA 9060
Total Organic Carbon
1610
mg/kg
908
04/23/15 13:03
EPA 9060
Mean Total Organic Carbon
1700
mg/kg
912
04/23/15 12:44
EPA 9060
RSD%
7.5
%
04/23/15 12:44
92245094008
2015010118
EPA 6010
Aluminum
17500
mg/kg
32.7
04/25/15 18:15
EPA 6010
Barium
43.0
mg/kg
3.3
04/25/15 18:15
EPA 6010
Beryllium
1.3
mg/kg
0.33
04/25/15 18:15
EPA 6010
Calcium
1160
mg/kg
164
04/25/15 18:15
EPA 6010
Chromium
12.9
mg/kg
1.6
04/25/15 18:15
EPA 6010
Copper
76.7
mg/kg
1.6
04/25/15 18:15
EPA 6010
Iron
57600
mg/kg
13.1
04/25/15 18:15
EPA 6010
Magnesium
8750
mg/kg
164
04/25/15 18:15
EPA 6010
Manganese
179
mg/kg
1.6
04/25/15 18:15
EPA 6010
Nickel
25.2
mg/kg
1.6
04/25/15 18:15
EPA 6010
Potassium
4410
mg/kg
327
04/25/15 18:15
EPA 6010
Strontium
4.2
mg/kg
3.3
04/25/15 18:15
EPA 6010
Zinc
96.8
mg/kg
6.5
04/25/15 18:15
EPA 6020
Cobalt
25.6
mg/kg
6.5
04/22/15 00:17
EPA 6020
Lead
5.2J
mg/kg
6.5
04/22/15 00:17
EPA 6020
Vanadium
19.1
mg/kg
6.5
04/22/15 00:17
ASTM D2974-87
Percent Moisture
27.0
%
0.10
04/16/15 16:06
EPA 9045
pH at 25 Degrees C
4.3
Std. Units
0.10
04/16/15 10:45
EPA 9056
Sulfate
346
mg/kg
345
04/15/15 09:09 D3
EPA 9060
Total Organic Carbon
9700
mg/kg
1360
04/23/15 13:09
EPA 9060
Total Organic Carbon
7890
mg/kg
1370
04/23/15 13:15
EPA 9060
Total Organic Carbon
7430
mg/kg
1360
04/23/15 13:21
EPA 9060
Total Organic Carbon
7730
mg/kg
1370
04/23/15 13:28
EPA 9060
Mean Total Organic Carbon
8190
mg/kg
1360
04/23/15 13:09
EPA 9060
RSD%
12.5
%
04/23/15 13:09
92245094009
2015010119
EPA 6010
Aluminum
16000
mg/kg
32.9
04/25/15 18:20
EPA 6010
Barium
681
mg/kg
3.3
04/25/15 18:20
EPA 6010
Beryllium
4.4
mg/kg
0.33
04/25/15 18:20
EPA 6010
Boron
15.2J
mg/kg
16.4
04/25/15 18:20
EPA 6010
Calcium
2480
mg/kg
164
04/25/15 18:20
EPA 6010
Chromium
26.8
mg/kg
1.6
04/25/15 18:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Qualifiers
Page 11 of 87

aceAnaiXical
www.pacelabs.com
Project: J15040217
Pace Project No.: 92245094
Lab Sample ID Client Sample ID
Method Parameters
Pace Analytical Services, Inc.
9800�qrpyoAje. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92245094009
2015010119
EPA 6010
Copper
48.0
mg/kg
1.6
04/25/15 18:20
EPA 6010
Iron
14400
mg/kg
13.2
04/25/15 18:20
EPA 6010
Magnesium
1500
mg/kg
164
04/25/15 18:20
EPA 6010
Manganese
55.8
mg/kg
1.6
04/25/15 18:20
EPA 6010
Nickel
23.0
mg/kg
1.6
04/25/15 18:20
EPA 6010
Potassium
3490
mg/kg
329
04/25/15 18:20
EPA 6010
Sodium
487
mg/kg
329
04/25/15 18:20
EPA 6010
Strontium
223
mg/kg
3.3
04/25/15 18:20
EPA 6010
Zinc
40.5
mg/kg
6.6
04/25/15 18:20
EPA 6020
Arsenic
97.4
mg/kg
6.6
04/22/15 00:19
EPA 6020
Cobalt
12.5
mg/kg
6.6
04/22/15 00:19
EPA 6020
Lead
22.6
mg/kg
6.6
04/22/15 00:19
EPA 6020
Selenium
13.5
mg/kg
6.6
04/22/15 00:19
EPA 6020
Vanadium
68.0
mg/kg
6.6
04/22/15 00:19
EPA 7471
Mercury
0.34
mg/kg
0.011
04/17/15 13:18
ASTM D2974-87
Percent Moisture
23.4
%
0.10
04/16/15 16:07
EPA 9045
pH at 25 Degrees C
7.3
Std. Units
0.10
04/16/15 10:45
EPA 9060
Total Organic Carbon
81900
mg/kg
8740
04/27/15 14:20
EPA 9060
Total Organic Carbon
91700
mg/kg
8620
04/27/15 14:25
EPA 9060
Total Organic Carbon
89200
mg/kg
8770
04/27/15 14:31
EPA 9060
Total Organic Carbon
81400
mg/kg
8900
04/27/15 14:36
EPA 9060
Mean Total Organic Carbon
86000
mg/kg
8760
04/27/15 14:20
EPA 9060
RSD%
6.0
%
04/27/15 14:20
92245094010
2015010121
EPA 6010
Aluminum
32000
mg/kg
30.2
04/25/15 18:24
EPA 6010
Barium
62.8
mg/kg
3.0
04/25/15 18:24
EPA 6010
Beryllium
1.4
mg/kg
0.30
04/25/15 18:24
EPA 6010
Calcium
582
mg/kg
151
04/25/15 18:24
EPA 6010
Chromium
15.5
mg/kg
1.5
04/25/15 18:24
EPA 6010
Copper
65.3
mg/kg
1.5
04/25/15 18:24
EPA 6010
Iron
43100
mg/kg
12.1
04/25/15 18:24
EPA 6010
Magnesium
3230
mg/kg
151
04/25/15 18:24
EPA 6010
Manganese
344
mg/kg
1.5
04/25/15 18:24
EPA 6010
Molybdenum
6.4
mg/kg
3.0
04/25/15 18:24
EPA 6010
Nickel
13.9
mg/kg
1.5
04/25/15 18:24
EPA 6010
Potassium
2440
mg/kg
302
04/25/15 18:24
EPA 6010
Strontium
27.9
mg/kg
3.0
04/25/15 18:24
EPA 6010
Zinc
61.8
mg/kg
6.0
04/25/15 18:24
EPA 6020
Arsenic
25.5
mg/kg
6.0
04/22/15 00:21
EPA 6020
Cobalt
26.5
mg/kg
6.0
04/22/15 00:21
EPA 6020
Lead
11.4
mg/kg
6.0
04/22/15 00:21
EPA 6020
Vanadium
30.3
mg/kg
6.0
04/22/15 00:21
ASTM D2974-87
Percent Moisture
16.4
%
0.10
04/16/15 16:08
EPA 9045
pH at 25 Degrees C
7.0
Std. Units
0.10
04/16/15 10:45
EPA 9060
Total Organic Carbon
1650
mg/kg
718
04/27/15 14:42
EPA 9060
Total Organic Carbon
1230
mg/kg
711
04/27/15 14:48
EPA 9060
Total Organic Carbon
1270
mg/kg
720
04/27/15 14:55
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Qualifiers
Page 12 of 87

aceAnaiXical
www.pacelabs.com
Project: J15040217
Pace Project No.: 92245094
Lab Sample ID
Method
Client Sample ID
Parameters
92245094010
2015010121
EPA 9060
Total Organic Carbon
EPA 9060
Mean Total Organic Carbon
EPA 9060
RSD%
92245094011
2015010122
EPA 6010
Aluminum
EPA 6010
Barium
EPA 6010
Beryllium
EPA 6010
Calcium
EPA 6010
Chromium
EPA 6010
Copper
EPA 6010
Iron
EPA 6010
Magnesium
EPA 6010
Manganese
EPA 6010
Molybdenum
EPA 6010
Nickel
EPA 6010
Potassium
EPA 6010
Strontium
EPA 6010
Zinc
EPA 6020
Cobalt
EPA 6020
Lead
EPA 6020
Selenium
EPA 6020
Vanadium
ASTM D2974-87
Percent Moisture
EPA 9045
pH at 25 Degrees C
EPA 9060
Total Organic Carbon
EPA 9060
Total Organic Carbon
EPA 9060
Total Organic Carbon
EPA 9060
Total Organic Carbon
EPA 9060
Mean Total Organic Carbon
EPA 9060
RSD%
Pace Analytical Services, Inc.
9800Air6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Result
Units
Report Limit
Analyzed
Qualifiers
EPA 6010
Aluminum
1880
mg/kg
712
04/27/1515:01
D3
1510
mg/kg
715
04/27/1514:42
19.3
20.7
%
EPA 6010
04/27/1514:42
1.4
20700
mg/kg
34.8
04/25/1514:18
D3,M1
149
mg/kg
3.5
04/25/1514:18
D3,M1
2.3
mg/kg
0.35
04/25/1514:18
D3
525
mg/kg
174
04/25/1514:18
D3
47.5
mg/kg
1.7
04/25/1514:18
D3,M1
37.5
mg/kg
1.7
04/25/1514:18
D3,M1
60700
mg/kg
13.9
04/25/1514:18
D3,M1
5520
mg/kg
174
04/25/1514:18
D3,M1
942
mg/kg
1.7
04/25/1514:18
D3,M1
44.6
mg/kg
3.5
04/25/1514:18
D3
30.2
mg/kg
1.7
04/25/1514:18
D3,M1
4200
mg/kg
348
04/25/1514:18
D3,M1
27.4
mg/kg
3.5
04/25/1514:18
D3,M1
83.5
mg/kg
7.0
04/25/1514:18
D3,M1
39.7
mg/kg
7.0
04/22/15 01:49
EPA 6020
12.4
mg/kg
7.0
04/22/15 01:49
04/22/15 02:05
5.11
mg/kg
7.0
04/22/15 01:49
mg/kg
78.0
mg/kg
7.0
04/22/15 01:49
30.0
%
0.10
04/16/1516:08
7.0
Std. Units
0.10
04/16/15 10:45
1080
mg/kg
853
04/27/1515:08
1360
mg/kg
852
04/27/1515:14
1070
mg/kg
865
04/27/1515:21
1300
mg/kg
852
04/27/1515:27
1200
mg/kg
855
04/27/1515:08
12.2
%
04/27/1515:08
92245094012
2015010123
EPA 6010
Aluminum
21200
mg/kg
193
04/25/15 14:47
D3
EPA 6010
Barium
86.7
mg/kg
19.3
04/25/15 14:47
D3
EPA 6010
Beryllium
1.4
mg/kg
0.39
04/25/15 14:43
EPA 6010
Calcium
152J
mg/kg
193
04/25/15 14:43
EPA 6010
Chromium
15.0
mg/kg
9.7
04/25/15 14:47
D3
EPA 6010
Copper
36.6
mg/kg
9.7
04/25/15 14:47
D3
EPA 6010
Iron
33600
mg/kg
77.2
04/25/15 14:47
D3
EPA 6010
Magnesium
4660
mg/kg
966
04/25/15 14:47
D3
EPA 6010
Manganese
352
mg/kg
9.7
04/25/15 14:47
D3
EPA 6010
Nickel
5.6
mg/kg
0.39
04/20/15 13:59
EPA 6010
Potassium
3270
mg/kg
386
04/25/15 14:43
EPA 6010
Strontium
12AJ
mg/kg
19.3
04/25/15 14:47
D3
EPA 6010
Zinc
76.0
mg/kg
38.6
04/25/15 14:47
D3
EPA 6020
Cobalt
17.2
mg/kg
7.7
04/22/15 02:05
M6, R1
EPA 6020
Lead
7.6J
mg/kg
7.7
04/22/15 02:05
M6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 13 of 87

aceAnaiXical
www.pacelabs.com
SUMMARY OF DETECTION
Pace Analytical Services, Inc.
9800AirpyoAle. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
J15040217
92245094
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
92245094012
2015010123
EPA 6020
Vanadium
29.1
mg/kg
7.7
04/22/15 02:05
M6, R1
ASTM D2974-87
Percent Moisture
33.2
%
0.10
04/16/15 16:09
EPA 9045
pH at 25 Degrees C
6.2
Std. Units
0.10
04/16/15 10:45
EPA 9060
Total Organic Carbon
1630
mg/kg
901
04/27/15 15:34
EPA 9060
Total Organic Carbon
1640
mg/kg
893
04/27/15 15:40
EPA 9060
Total Organic Carbon
1530
mg/kg
903
04/27/15 15:47
EPA 9060
Total Organic Carbon
1690
mg/kg
903
04/27/15 15:53
EPA 9060
Mean Total Organic Carbon
1620
mg/kg
900
04/27/15 15:34
EPA 9060
RSD%
4.2
%
04/27/15 15:34
92245094013
2015010120
EPA 6010
Aluminum
21000
mg/kg
36.1
04/25/15 14:55
D3
EPA 6010
Barium
545
mg/kg
3.6
04/25/15 14:55
D3
EPA 6010
Beryllium
4.9
mg/kg
0.36
04/25/15 14:55
D3
EPA 6010
Boron
16.3J
mg/kg
18.1
04/25/15 14:55
D3
EPA 6010
Calcium
3170
mg/kg
181
04/25/15 14:55
D3
EPA 6010
Chromium
40.3
mg/kg
1.8
04/25/15 14:55
D3
EPA 6010
Copper
63.9
mg/kg
1.8
04/25/15 14:55
D3
EPA 6010
Iron
18500
mg/kg
14.4
04/25/15 14:55
D3
EPA 6010
Magnesium
1470
mg/kg
181
04/25/15 14:55
D3
EPA 6010
Manganese
89.6
mg/kg
1.8
04/25/15 14:55
D3
EPA 6010
Molybdenum
2.8J
mg/kg
3.6
04/25/15 14:55
D3
EPA 6010
Nickel
35.7
mg/kg
1.8
04/25/15 14:55
D3
EPA 6010
Potassium
3200
mg/kg
361
04/25/15 14:55
D3
EPA 6010
Sodium
497
mg/kg
361
04/25/15 14:55
D3
EPA 6010
Strontium
327
mg/kg
3.6
04/25/15 14:55
D3
EPA 6010
Zinc
60.3
mg/kg
7.2
04/25/15 14:55
D3
EPA 6020
Arsenic
217
mg/kg
7.2
04/22/15 02:12
EPA 6020
Cadmium
0.56J
mg/kg
0.87
04/22/15 02:12
EPA 6020
Cobalt
19.8
mg/kg
7.2
04/22/15 02:12
EPA 6020
Lead
26.1
mg/kg
7.2
04/22/15 02:12
EPA 6020
Selenium
19.5
mg/kg
7.2
04/22/15 02:12
EPA 6020
Vanadium
103
mg/kg
7.2
04/22/15 02:12
EPA 7471
Mercury
0.24
mg/kg
0.011
04/20/15 20:58
ASTM D2974-87
Percent Moisture
31.6
%
0.10
04/16/15 16:10
EPA 9045
pH at 25 Degrees C
7.5
Std. Units
0.10
04/16/15 10:45
EPA 300.0
Sulfate
9.6
mg/L
2.9
04/19/15 16:46
B
EPA 9056
Sulfate
185J
mg/kg
365
04/15/15 10:56
D3
EPA 9060
Total Organic Carbon
26400
mg/kg
5700
04/27/15 16:00
EPA 9060
Total Organic Carbon
22100
mg/kg
5550
04/27/15 16:05
EPA 9060
Total Organic Carbon
22500
mg/kg
5710
04/27/15 16:11
EPA 9060
Total Organic Carbon
23300
mg/kg
5720
04/27/15 16:17
EPA 9060
Mean Total Organic Carbon
23600
mg/kg
5670
04/27/15 16:00
EPA 9060
RSD%
8.2
%
04/27/15 16:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 14 of 87

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980aq8r6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040217
Pace Project No.: 92245094
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: April 28, 2015
General Information:
10 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/23656
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245143001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1186029)
• Aluminum
• Barium
• Copper
• Iron
• Manganese
• MSD (Lab ID: 1186030)
• Aluminum
• Barium
• Copper
• Iron
• Magnesium
QC Batch: MPRP/23696
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245094011
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1188077)
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 15 of 87

aceAnaiXical
www.pacelabs.com
PROJECT NARRATIVE
Project: J15040217
Pace Project No.: 92245094
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: April 28, 2015
QC Batch: MPRP/23696
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245094011
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• Aluminum
• Barium
• Chromium
• Iron
• Magnesium
• Manganese
• Nickel
• Potassium
• Strontium
• Zinc
• MSD (Lab ID: 1188078)
• Aluminum
• Barium
• Chromium
• Copper
• Iron
• Magnesium
• Manganese
• Nickel
• Potassium
• Strontium
• Zinc
Additional Comments:
Batch Comments:
Pace Analytical Services, Inc.
980mirpyoAje. Suite 100
Huntersville, NC 28078
[phone]
Samples in this batch were diluted due to the presence of high levels of non -target analytes or other matrix interference, unless
otherwise flagged.
• QC Batch: ICP / 14455
Analyte Comments:
QC Batch: MPRP/23656
D4: Sample was diluted due to the presence of high levels of target analytes.
•2015010115 (Lab ID: 92245094005)
• Iron
P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank
or were below the reporting limit.
• BLANK (Lab ID: 1186027)
• Iron
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 16 of 87

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980agir6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040217
Pace Project No.: 92245094
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: April 28, 2015
Analyte Comments:
QC Batch: MPRP/23696
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015010120 (Lab ID: 92245094013)
• Aluminum
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Copper
• Iron
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
• Strontium
• Zinc
•2015010122 (Lab ID: 92245094011)
• Aluminum
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Copper
• Iron
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
• Strontium
• Zinc
•2015010123 (Lab ID: 92245094012)
• Aluminum
• Barium
• Chromium
• Copper
• Iron
• Magnesium
• Manganese
• Strontium
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 17 of 87

aceAnaiXical
www.pacelabs.com
PROJECT NARRATIVE
Project: J15040217
Pace Project No.: 92245094
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: April 28, 2015
Analyte Comments:
QC Batch: MPRP/23696
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015010123 (Lab ID: 92245094012)
• Zinc
• MS (Lab ID: 1188077)
• Aluminum
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Copper
• Iron
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
• Strontium
• Zinc
• MSD (Lab ID: 1188078)
• Aluminum
• Boron
• Barium
• Beryllium
• Calcium
• Chromium
• Copper
• Iron
• Potassium
• Magnesium
• Manganese
• Molybdenum
• Sodium
• Nickel
• Strontium
• Zinc
Pace Analytical Services, Inc.
980agir6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank
or were below the reporting limit.
• BLANK (Lab ID: 1188075)
• Iron
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 18 of 87

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
9800A'ir6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040217
Pace Project No.: 92245094
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: April 28, 2015
General Information:
10 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/23657
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245143002
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1186035)
• Antimony
• Arsenic
• Cadmium
• Cobalt
• Lead
• Selenium
• Thallium
• Vanadium
• MSD (Lab ID: 1186036)
• Antimony
• Arsenic
• Cadmium
• Cobalt
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 19 of 87

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980agir6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040217
Pace Project No.: 92245094
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: April 28, 2015
QC Batch: MPRP/23657
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245143002
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• Lead
• Selenium
• Thallium
• Vanadium
R1: RPD value was outside control limits.
• MSD (Lab ID: 1186036)
• Cobalt
• Vanadium
QC Batch: MPRP/23697
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92245094012
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1188081)
• Antimony
• Cobalt
• Lead
• MSD (Lab ID: 1188082)
• Antimony
• Cobalt
• Lead
• Vanadium
R1: RPD value was outside control limits.
• MSD (Lab ID: 1188082)
• Cobalt
• Vanadium
Additional Comments:
Batch Comments:
Batch was diluted due to the presence of high levels of non -target analytes or other matrix interference.
• QC Batch: ICPM / 9617
• QC Batch: ICPM / 9631
Analyte Comments:
QC Batch: MPRP/23657
N2: The lab does not hold TNI accreditation for this parameter.
•2015010113 (Lab ID:92245094004)
• Antimony
•2015010115 (Lab ID:92245094005)
• Antimony
•2015010116 (Lab ID:92245094006)
• Antimony
REPORT OF LABORATORY ANALYSIS
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980aq8r6fy0AJe. Suite 100
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[phone]
PROJECT NARRATIVE
Project: J15040217
Pace Project No.: 92245094
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: April 28, 2015
Analyte Comments:
QC Batch: MPRP/23657
N2: The lab does not hold TNI accreditation for this parameter.
•2015010117 (Lab ID:92245094007)
• Antimony
•2015010118 (Lab ID:92245094008)
• Antimony
•2015010119 (Lab ID:92245094009)
• Antimony
•2015010121 (Lab ID:92245094010)
• Antimony
• BLANK (Lab ID: 1186033)
• Antimony
• LCS (Lab ID: 1186034)
• Antimony
• MS (Lab ID: 1186035)
• Antimony
• MSD (Lab ID: 1186036)
• Antimony
QC Batch: MPRP/23697
N2: The lab does not hold TNI accreditation for this parameter.
•2015010120 (Lab ID:92245094013)
• Antimony
•2015010122 (Lab ID: 92245094011)
• Antimony
•2015010123 (Lab ID:92245094012)
• Antimony
• BLANK (Lab ID: 1188079)
• Antimony
• LCS (Lab ID: 1188080)
• Antimony
• MS (Lab ID: 1188081)
• Antimony
• MSD (Lab ID: 1188082)
• Antimony
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J15040217
Pace Project No.: 92245094
Method: EPA 6020A
Description: 6020A MET ICPMS
Client: Duke Energy
Date: April 28, 2015
General Information:
3 samples were analyzed for EPA 6020A. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3020 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/53618
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10302295001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1938833)
• Calcium
• Magnesium
• MSD (Lab ID: 1938834)
• Magnesium
QC Batch: MPRP/53815
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10303182004
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1945266)
• Boron
• Calcium
• Magnesium
• Potassium
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J15040217
Pace Project No.: 92245094
Method: EPA 6020A
Description: 6020A MET ICPMS
Client: Duke Energy
Date: April 28, 2015
QC Batch: MPRP/53815
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 10303182004
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• Sodium
• Strontium
• MSD (Lab ID: 1945267)
• Boron
• Calcium
• Magnesium
• Potassium
• Sodium
• Strontium
R1: RPD value was outside control limits.
• MSD (Lab ID: 1945267)
• Selenium
Additional Comments:
Analyte Comments:
QC Batch: MPRP/53815
E: Analyte concentration exceeded the calibration range. The reported result is estimated.
• MS (Lab ID: 1945266)
• Sodium
• MSD (Lab ID: 1945267)
• Sodium
Pace Analytical Services, Inc.
980a�grpyoAje. Suite 100
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[phone]
P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank
or were below the reporting limit.
• BLANK (Lab ID: 1945264)
• Manganese
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services, Inc.
980agir6fy0AJe. Suite 100
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[phone]
PROJECT NARRATIVE
Project: J15040217
Pace Project No.: 92245094
Method: EPA 7470
Description: 7470 Mercury
Client: Duke Energy
Date: April 28, 2015
General Information:
2 samples were analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7470 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 24 of 87

aceAnaiXical
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Pace Analytical Services, Inc.
98004tbirWY041e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040217
Pace Project No.: 92245094
Method: EPA 7470A
Description: 7470A Mercury
Client: Duke Energy
Date: April 28, 2015
General Information:
1 sample was analyzed for EPA 7470A. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7470A with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 25 of 87

aceAnaiXical
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Pace Analytical Services, Inc.
98004irWY041e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040217
Pace Project No.: 92245094
Method: EPA 7471
Description: 7471 Mercury
Client: Duke Energy
Date: April 28, 2015
General Information:
10 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7471 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 26 of 87

aceAnaiXical
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Pace Analytical Services, Inc.
98004K WeYO ie. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040217
Pace Project No.: 92245094
Method: EPA 9045
Description: 9045 pH Soil
Client: Duke Energy
Date: April 28, 2015
General Information:
10 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 27 of 87

aceAnaiXical
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Pace Analytical Services, Inc.
980041 WeY041e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040217
Pace Project No.: 92245094
Method: EPA 300.0
Description: 300.0 IC Anions, SPLP
Client: Duke Energy
Date: April 28, 2015
General Information:
1 sample was analyzed for EPA 300.0. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
QC Batch: WETA/22607
B: Analyte was detected in the associated method blank.
• BLANK for HBN 260035 [WETA/226 (Lab ID: 1437291)
• Sulfate
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 28 of 87

aceAnaiXical
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Pace Analytical Services, Inc.
98004t�irWY041e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040217
Pace Project No.: 92245094
Method: EPA 353.2
Description: 353.2 Nitrogen, NO2/NO3, SPLP
Client: Duke Energy
Date: April 28, 2015
General Information:
1 sample was analyzed for EPA 353.2. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-11: Analysis conducted outside the EPA method holding time.
•2015010120 (Lab ID: 92245094013)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 29 of 87

aceAnaiXical
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Pace Analytical Services, Inc.
980041 WeY041e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040217
Pace Project No.: 92245094
Method: SM 4500 -CI -E
Description: 4500 Chloride, SPLP
Client: Duke Energy
Date: April 28, 2015
General Information:
1 sample was analyzed for SM 4500 -CI -E. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 30 of 87

aceAnaiXical
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Pace Analytical Services, Inc.
980041 WeY0A1e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040217
Pace Project No.: 92245094
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: April 28, 2015
General Information:
10 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/45407
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015010113 (Lab ID:92245094004)
• Chloride
• Sulfate
•2015010115 (Lab ID:92245094005)
• Chloride
• Sulfate
•2015010116 (Lab ID:92245094006)
• Chloride
• Sulfate
•2015010117 (Lab ID:92245094007)
• Chloride
• Sulfate
•2015010118 (Lab ID:92245094008)
• Chloride
• Sulfate
•2015010119 (Lab ID:92245094009)
• Chloride
• Sulfate
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 31 of 87

aceAnaiXical
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Pace Analytical Services, Inc.
980041 WeY0A1e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040217
Pace Project No.: 92245094
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: April 28, 2015
Analyte Comments:
QC Batch: WETA/45407
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015010120 (Lab ID: 92245094013)
• Chloride
• Sulfate
•2015010121 (Lab ID: 92245094010)
• Chloride
• Sulfate
•2015010122 (Lab ID: 92245094011)
• Chloride
• Sulfate
•2015010123 (Lab ID: 92245094012)
• Chloride
• Sulfate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 32 of 87

aceAnaiXical
www.pacelabs.com
Pace Analytical Services, Inc.
980041 WeY041e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040217
Pace Project No.: 92245094
Method: EPA 9056
Description: 9056 IC Anions 48hr
Client: Duke Energy
Date: April 28, 2015
General Information:
10 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-13: Sample was received or analysis requested beyond the recognized method holding time.
•2015010113 (Lab ID:92245094004)
•2015010115 (Lab ID:92245094005)
•2015010116 (Lab ID:92245094006)
•2015010117 (Lab ID:92245094007)
•2015010118 (Lab ID:92245094008)
•2015010119 (Lab ID:92245094009)
•2015010120 (Lab ID:92245094013)
•2015010121 (Lab ID:92245094010)
•2015010122 (Lab ID: 92245094011)
•2015010123 (Lab ID:92245094012)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 33 of 87

aceAnaiXical
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Pace Analytical Services, Inc.
980041 WeY041e. Suite 100
Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J15040217
Pace Project No.: 92245094
Method: EPA 9060
Description: Total Organic Carbon Quad
Client: Duke Energy
Date: April 28, 2015
General Information:
10 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J15040217
Pace Project No.: 92245094
Pace Analytical Services, Inc.
9800d8'6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015010112 Lab ID: 92245094001 Collected: 03/31/15 14:00 Received: 04/10/15 16:35 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\�i,I=11 l[99�r 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 04/28/2015 01:02 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
198
ug/L
10.0
3.0
1
04/15/15 08:27
04/15/15 16:29
7429-90-5
ND
ug/L
0.50
0.15
1
04/15/15 08:27
04/15/15 16:29
7440-36-0
ND
ug/L
0.50
0.11
1
04/15/15 08:27
04/15/15 16:29
7440-38-2
4.7
ug/L
0.30
0.081
1
04/15/15 08:27
04/15/15 16:29
7440-39-3
ND
ug/L
0.20
0.067
1
04/15/15 08:27
04/16/15 10:47
7440-41-7
ND
ug/L
5.0
1.1
1
04/15/15 08:27
04/16/15 10:47
7440-42-8
ND
ug/L
0.080
0.024
1
04/15/15 08:27
04/15/15 16:29
7440-43-9
913
ug/L
40.0
16.0
1
04/15/15 08:27
04/15/15 16:29
7440-70-2
3.0
ug/L
0.50
0.17
1
04/15/15 08:27
04/15/15 16:29
7440-47-3
5.0
ug/L
0.50
0.13
1
04/15/15 08:27
04/15/15 16:29
7440-48-4
3.4
ug/L
1.0
0.21
1
04/15/15 08:27
04/15/15 16:29
7440-50-8
2430
ug/L
50.0
13.7
1
04/15/15 08:27
04/15/15 16:29
7439-89-6
0.38
ug/L
0.10
0.046
1
04/15/15 08:27
04/16/15 10:47
7439-92-1
176
ug/L
10.0
3.2
1
04/15/15 08:27
04/16/15 10:47
7439-95-4
27.9
ug/L
0.50
0.24
1
04/15/15 08:27
04/15/15 16:29
7439-96-5
1.5
ug/L
0.50
0.094
1
04/15/15 08:27
04/15/15 16:29
7439-98-7
2.6
ug/L
0.50
0.16
1
04/15/15 08:27
04/15/15 16:29
7440-02-0
127
ug/L
50.0
11.7
1
04/15/15 08:27
04/15/15 16:29
7440-09-7
ND
ug/L
0.50
0.20
1
04/15/15 08:27
04/15/15 16:29
7782-49-2
226
ug/L
50.0
16.3
1
04/15/15 08:27
04/15/15 16:29
7440-23-5
2.4
ug/L
0.50
0.13
1
04/15/15 08:27
04/15/15 16:29
7440-24-6
ND
ug/L
0.10
0.015
1
04/15/15 08:27
04/15/15 16:29
7440-28-0
ND
ug/L
1.0
0.28
1
04/15/15 08:27
04/15/15 16:29
7440-62-2
9.5
ug/L
5.0
2.4
1
04/15/15 08:27
04/15/15 16:29
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.022 1 04/15/1510:10 04/15/1518:22 7439-97-6
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J15040217
Pace Project No.: 92245094
Pace Analytical Services, Inc.
9800q�irpyoAje. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015010114 Lab ID: 92245094002 Collected: 04/02/15 09:25 Received: 04/10/15 16:35 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;I➢ZI7c\ri,I=11 l[99�r 6?
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470 Mercury
Mercury
Date: 04/28/2015 01:02 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
511
ug/L
10.0
3.0
1
04/15/15 08:27
04/15/15 16:35
7429-90-5
ND
ug/L
0.50
0.15
1
04/15/15 08:27
04/15/15 16:35
7440-36-0
ND
ug/L
0.50
0.11
1
04/15/15 08:27
04/15/15 16:35
7440-38-2
7.6
ug/L
0.30
0.081
1
04/15/15 08:27
04/15/15 16:35
7440-39-3
ND
ug/L
0.20
0.067
1
04/15/15 08:27
04/16/15 10:50
7440-41-7
ND
ug/L
5.0
1.1
1
04/15/15 08:27
04/16/15 10:50
7440-42-8
ND
ug/L
0.080
0.024
1
04/15/15 08:27
04/15/15 16:35
7440-43-9
505
ug/L
40.0
16.0
1
04/15/15 08:27
04/15/15 16:35
7440-70-2
1.8
ug/L
0.50
0.17
1
04/15/15 08:27
04/15/15 16:35
7440-47-3
0.69
ug/L
0.50
0.13
1
04/15/15 08:27
04/15/15 16:35
7440-48-4
1.1
ug/L
1.0
0.21
1
04/15/15 08:27
04/15/15 16:35
7440-50-8
689
ug/L
50.0
13.7
1
04/15/15 08:27
04/15/15 16:35
7439-89-6
0.55
ug/L
0.10
0.046
1
04/15/15 08:27
04/15/15 16:35
7439-92-1
106
ug/L
10.0
3.2
1
04/15/15 08:27
04/16/15 10:50
7439-95-4
18.7
ug/L
0.50
0.24
1
04/15/15 08:27
04/15/15 16:35
7439-96-5
ND
ug/L
0.50
0.094
1
04/15/15 08:27
04/15/15 16:35
7439-98-7
ND
ug/L
0.50
0.16
1
04/15/15 08:27
04/15/15 16:35
7440-02-0
146
ug/L
50.0
11.7
1
04/15/15 08:27
04/15/15 16:35
7440-09-7
ND
ug/L
0.50
0.20
1
04/15/15 08:27
04/15/15 16:35
7782-49-2
234
ug/L
50.0
16.3
1
04/15/15 08:27
04/15/15 16:35
7440-23-5
2.2
ug/L
0.50
0.13
1
04/15/15 08:27
04/15/15 16:35
7440-24-6
ND
ug/L
0.10
0.015
1
04/15/15 08:27
04/15/15 16:35
7440-28-0
ND
ug/L
1.0
0.28
1
04/15/15 08:27
04/15/15 16:35
7440-62-2
5.6
ug/L
5.0
2.4
1
04/15/15 08:27
04/15/15 16:35
7440-66-6
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L 0.20 0.022 1 04/15/1510:10 04/15/1518:24 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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aceAnaiXical
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ANALYTICAL RESULTS
Project: J15040217
Pace Project No.: 92245094
Pace Analytical Services, Inc.
98005kf 6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015010120 SPLP Lab ID: 92245094003 Collected: 04/06/15 16:10 Received: 04/10/15 16:35 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
;T➢Z17c\�iil=11 a
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Strontium
Thallium
Vanadium
Zinc
7470A Mercury
Mercury
Date: 04/28/2015 01:02 PM
Analytical Method: EPA 6020A Preparation Method: EPA 3020
1640
ug/L
10.0
3.0
1
04/22/1514:54
04/23/1515:04
7429-90-5
4.2
ug/L
0.50
0.15
1
04/22/1514:54
04/23/1515:04
7440-36-0
270
ug/L
0.50
0.11
1
04/22/1514:54
04/23/1515:04
7440-38-2
369
ug/L
0.30
0.081
1
04/22/1514:54
04/23/1515:04
7440-39-3
0.89
ug/L
0.20
0.067
1
04/22/1514:54
04/23/1515:04
7440-41-7
60.8
ug/L
5.0
1.1
1
04/22/1514:54
04/23/1515:04
7440-42-8
0.56
ug/L
0.080
0.024
1
04/22/1514:54
04/23/1515:04
7440-43-9
2750
ug/L
40.0
16.0
1
04/22/1514:54
04/23/1515:04
7440-70-2
11.9
ug/L
0.50
0.17
1
04/22/1514:54
04/23/1515:04
7440-47-3
1.3
ug/L
0.50
0.13
1
04/22/1514:54
04/23/1515:04
7440-48-4
13.2
ug/L
1.0
0.21
1
04/22/1514:54
04/23/1515:04
7440-50-8
899
ug/L
50.0
13.7
1
04/22/1514:54
04/23/1515:04
7439-89-6
4.6
ug/L
0.10
0.046
1
04/22/1514:54
04/23/1515:04
7439-92-1
418
ug/L
10.0
3.2
1
04/22/1514:54
04/23/1515:04
7439-95-4
27.1
ug/L
0.50
0.24
1
04/22/1514:54
04/23/1515:04
7439-96-5
2.9
ug/L
0.50
0.094
1
04/22/1514:54
04/23/1515:04
7439-98-7
2.4
ug/L
0.50
0.16
1
04/22/1514:54
04/23/1515:04
7440-02-0
731
ug/L
50.0
11.7
1
04/22/1514:54
04/23/1515:04
7440-09-7
11.4
ug/L
0.50
0.20
1
04/22/1514:54
04/23/1515:04
7782-49-2
1140
ug/L
50.0
16.3
1
04/22/1514:54
04/23/1515:04
7440-23-5
143
ug/L
0.50
0.13
1
04/22/1514:54
04/23/1515:04
7440-24-6
1.2
ug/L
0.10
0.015
1
04/22/1514:54
04/23/1515:04
7440-28-0
139
ug/L
1.0
0.28
1
04/22/1514:54
04/23/1515:04
7440-62-2
47.8
ug/L
5.0
2.4
1
04/22/1514:54
04/23/1515:04
7440-66-6
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
0.030J ug/L 0.20 0.022 1 04/22/1517:55 04/23/1519:57 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 37 of 87

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
98005kf 6fY04Je. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
Sample: 2015010113
Lab ID:
92245094004 Collected:
03/31/15 14:50
Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
34200
mg/kg
33.5
16.7
5
04/16/15 21:15
04/25/15 17:42
7429-90-5
Barium
75.2
mg/kg
3.3
1.7
5
04/16/15 21:15
04/25/15 17:42
7440-39-3
Beryllium
0.82
mg/kg
0.33
0.17
5
04/16/15 21:15
04/25/15 17:42
7440-41-7
Boron
ND
mg/kg
16.7
8.4
5
04/16/15 21:15
04/25/15 17:42
7440-42-8
Calcium
102J
mg/kg
167
83.6
5
04/16/15 21:15
04/25/15 17:42
7440-70-2
Chromium
17.8
mg/kg
1.7
0.84
5
04/16/15 21:15
04/25/15 17:42
7440-47-3
Copper
33.0
mg/kg
1.7
0.84
5
04/16/15 21:15
04/25/15 17:42
7440-50-8
Iron
39200
mg/kg
13.4
6.7
5
04/16/15 21:15
04/25/15 17:42
7439-89-6
Magnesium
3000
mg/kg
167
83.6
5
04/16/15 21:15
04/25/15 17:42
7439-95-4
Manganese
548
mg/kg
1.7
0.84
5
04/16/15 21:15
04/25/15 17:42
7439-96-5
Molybdenum
ND
mg/kg
3.3
1.7
5
04/16/15 21:15
04/25/15 17:42
7439-98-7
Nickel
10.2
mg/kg
1.7
0.84
5
04/16/15 21:15
04/25/15 17:42
7440-02-0
Potassium
2740
mg/kg
335
167
5
04/16/15 21:15
04/25/15 17:42
7440-09-7
Sodium
ND
mg/kg
335
167
5
04/16/15 21:15
04/25/15 17:42
7440-23-5
Strontium
2AJ
mg/kg
3.3
1.7
5
04/16/15 21:15
04/25/15 17:42
7440-24-6
Zinc
55.7
mg/kg
6.7
3.3
5
04/16/15 21:15
04/25/15 17:42
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
6.7
3.3
100
04/16/15 21:15
04/22/15 00:08
7440-36-0
N2
Arsenic
ND
mg/kg
6.7
3.3
100
04/16/15 21:15
04/22/15 00:08
7440-38-2
Cadmium
ND
mg/kg
0.80
0.40
100
04/16/15 21:15
04/22/15 00:08
7440-43-9
Cobalt
29.6
mg/kg
6.7
3.3
100
04/16/15 21:15
04/22/15 00:08
7440-48-4
Lead
12.9
mg/kg
6.7
3.3
100
04/16/15 21:15
04/22/15 00:08
7439-92-1
Selenium
ND
mg/kg
6.7
3.3
100
04/16/15 21:15
04/22/15 00:08
7782-49-2
Thallium
ND
mg/kg
6.7
3.3
100
04/16/15 21:15
04/22/15 00:08
7440-28-0
Vanadium
48.6
mg/kg
6.7
3.3
100
04/16/15 21:15
04/22/15 00:08
7440-62-2
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
0.020
mg/kg
0.011
0.0057
1
04/16/15 22:25
04/17/15 13:07
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
26.3
%
0.10
0.10
1
04/16/15 16:02
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
6.4
Std. Units
0.10
0.10
1
04/16/15 10:45
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
338
169
5
04/15/15 07:43
16887-00-6
D3
Sulfate
ND
mg/kg
338
169
5
04/15/15 07:43
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
33.8
16.9
5
04/15/15 07:43
14797-55-8
H3
Date: 04/28/2015 01:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 38 of 87

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15040217
Pace Project No.: 92245094
Pace Analytical Services, Inc.
9800�ir6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015010113
Lab ID:
92245094004
Collected:
03/31/15 14:50
Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
ND
mg/kg
809
404
1
04/23/15 11:27
7440-44-0
Total Organic Carbon
ND
mg/kg
817
409
1
04/23/15 11:32
7440-44-0
Total Organic Carbon
ND
mg/kg
810
405
1
04/23/15 11:37
7440-44-0
Total Organic Carbon
704J
mg/kg
810
405
1
04/23/15 11:43
7440-44-0
Mean Total Organic Carbon
442J
mg/kg
812
406
1
04/23/15 11:27
7440-44-0
Surrogates
RSD%
39.5
%
1
04/23/1511:27
Date: 04/28/2015 01:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 39 of 87

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 ppyoAje. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
Sample: 2015010115
Lab ID:
92245094005 Collected:
04/02/15 09:50
Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
21600
mg/kg
125
62.3
20
04/16/15 21:15
04/26/15 23:00
7429-90-5
Barium
36.4
mg/kg
12.5
6.2
20
04/16/15 21:15
04/26/15 23:00
7440-39-3
Beryllium
2.6
mg/kg
1.2
0.62
20
04/16/15 21:15
04/26/15 23:00
7440-41-7
Boron
ND
mg/kg
62.3
31.2
20
04/16/15 21:15
04/26/15 23:00
7440-42-8
Calcium
ND
mg/kg
623
312
20
04/16/15 21:15
04/26/15 23:00
7440-70-2
Chromium
19.9
mg/kg
6.2
3.1
20
04/16/15 21:15
04/26/15 23:00
7440-47-3
Copper
192
mg/kg
6.2
3.1
20
04/16/15 21:15
04/26/15 23:00
7440-50-8
Iron
108000
mg/kg
49.8
24.9
20
04/16/15 21:15
04/26/15 23:00
7439-89-6
D4
Magnesium
ND
mg/kg
623
312
20
04/16/15 21:15
04/26/15 23:00
7439-95-4
Manganese
4000
mg/kg
6.2
3.1
20
04/16/15 21:15
04/26/15 23:00
7439-96-5
Molybdenum
ND
mg/kg
12.5
6.2
20
04/16/15 21:15
04/26/15 23:00
7439-98-7
Nickel
34.8
mg/kg
6.2
3.1
20
04/16/15 21:15
04/26/15 23:00
7440-02-0
Potassium
ND
mg/kg
1250
623
20
04/16/15 21:15
04/26/15 23:00
7440-09-7
Sodium
ND
mg/kg
1250
623
20
04/16/15 21:15
04/26/15 23:00
7440-23-5
Strontium
ND
mg/kg
12.5
6.2
20
04/16/15 21:15
04/26/15 23:00
7440-24-6
Zinc
109
mg/kg
24.9
12.5
20
04/16/15 21:15
04/26/15 23:00
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
6.2
3.1
100
04/16/15 21:15
04/22/15 00:10
7440-36-0
N2
Arsenic
ND
mg/kg
6.2
3.1
100
04/16/15 21:15
04/22/15 00:10
7440-38-2
Cadmium
ND
mg/kg
0.75
0.37
100
04/16/15 21:15
04/22/15 00:10
7440-43-9
Cobalt
228
mg/kg
6.2
3.1
100
04/16/15 21:15
04/22/15 00:10
7440-48-4
Lead
12.5
mg/kg
6.2
3.1
100
04/16/15 21:15
04/22/15 00:10
7439-92-1
Selenium
4.5J
mg/kg
6.2
3.1
100
04/16/15 21:15
04/22/15 00:10
7782-49-2
Thallium
ND
mg/kg
6.2
3.1
100
04/16/15 21:15
04/22/15 00:10
7440-28-0
Vanadium
15.8
mg/kg
6.2
3.1
100
04/16/15 21:15
04/22/15 00:10
7440-62-2
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
0.00951
mg/kg 0.010
0.0050
1
04/16/15 22:25
04/17/15 13:09
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
16.0
%
0.10
0.10
1
04/16/15 16:03
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
5.0
Std. Units
0.10
0.10
1
04/16/15 10:45
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
296
148
5
04/15/15 08:04
16887-00-6
D3
Sulfate
ND
mg/kg
296
148
5
04/15/15 08:04
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
29.6
14.8
5
04/15/15 08:04
14797-55-8
H3
Date: 04/28/2015 01:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 40 of 87

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15040217
Pace Project No.: 92245094
Pace Analytical Services, Inc.
980%�rpyoAje. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015010115
Lab ID:
92245094005
Collected:
04/02/15 09:50
Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
9110
mg/kg
721
361
1
04/23/15 11:54
7440-44-0
Total Organic Carbon
9510
mg/kg
720
360
1
04/23/15 12:00
7440-44-0
Total Organic Carbon
8170
mg/kg
712
356
1
04/23/15 12:06
7440-44-0
Total Organic Carbon
10800
mg/kg
714
357
1
04/23/15 12:13
7440-44-0
Mean Total Organic Carbon
9390
mg/kg
717
358
1
04/23/15 11:54
7440-44-0
Surrogates
RSD%
11.5
%
1
04/23/1511:54
Date: 04/28/2015 01:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 41 of 87

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800*r6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
Sample: 2015010116
Lab ID:
92245094006 Collected:
04/02/15 13:20
Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
34800
mg/kg
33.9
17.0
5
04/16/15 21:15
04/25/15 17:51
7429-90-5
Barium
76.1
mg/kg
3.4
1.7
5
04/16/15 21:15
04/25/15 17:51
7440-39-3
Beryllium
1.9
mg/kg
0.34
0.17
5
04/16/15 21:15
04/25/15 17:51
7440-41-7
Boron
ND
mg/kg
17.0
8.5
5
04/16/15 21:15
04/25/15 17:51
7440-42-8
Calcium
ND
mg/kg
170
84.8
5
04/16/15 21:15
04/25/15 17:51
7440-70-2
Chromium
20.1
mg/kg
1.7
0.85
5
04/16/15 21:15
04/25/15 17:51
7440-47-3
Copper
68.1
mg/kg
1.7
0.85
5
04/16/15 21:15
04/25/15 17:51
7440-50-8
Iron
53800
mg/kg
13.6
6.8
5
04/16/15 21:15
04/25/15 17:51
7439-89-6
Magnesium
2810
mg/kg
170
84.8
5
04/16/15 21:15
04/25/15 17:51
7439-95-4
Manganese
2070
mg/kg
1.7
0.85
5
04/16/15 21:15
04/25/15 17:51
7439-96-5
Molybdenum
ND
mg/kg
3.4
1.7
5
04/16/15 21:15
04/25/15 17:51
7439-98-7
Nickel
41.3
mg/kg
1.7
0.85
5
04/16/15 21:15
04/25/15 17:51
7440-02-0
Potassium
2070
mg/kg
339
170
5
04/16/15 21:15
04/25/15 17:51
7440-09-7
Sodium
ND
mg/kg
339
170
5
04/16/15 21:15
04/25/15 17:51
7440-23-5
Strontium
8.9
mg/kg
3.4
1.7
5
04/16/15 21:15
04/25/15 17:51
7440-24-6
Zinc
75.4
mg/kg
6.8
3.4
5
04/16/15 21:15
04/25/15 17:51
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
6.8
3.4
100
04/16/15 21:15
04/22/15 00:12
7440-36-0
N2
Arsenic
ND
mg/kg
6.8
3.4
100
04/16/15 21:15
04/22/15 00:12
7440-38-2
Cadmium
ND
mg/kg
0.81
0.41
100
04/16/15 21:15
04/22/15 00:12
7440-43-9
Cobalt
85.7
mg/kg
6.8
3.4
100
04/16/15 21:15
04/22/15 00:12
7440-48-4
Lead
11.6
mg/kg
6.8
3.4
100
04/16/15 21:15
04/22/15 00:12
7439-92-1
Selenium
ND
mg/kg
6.8
3.4
100
04/16/15 21:15
04/22/15 00:12
7782-49-2
Thallium
ND
mg/kg
6.8
3.4
100
04/16/15 21:15
04/22/15 00:12
7440-28-0
Vanadium
35.3
mg/kg
6.8
3.4
100
04/16/15 21:15
04/22/15 00:12
7440-62-2
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
ND
mg/kg
0.011
0.0056
1
04/16/15 22:25
04/17/15 13:11
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
29.7
%
0.10
0.10
1
04/16/15 16:03
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
5.3
Std. Units
0.10
0.10
1
04/16/15 10:45
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
354
177
5
04/15/15 08:26
16887-00-6
D3
Sulfate
ND
mg/kg
354
177
5
04/15/15 08:26
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
35.4
17.7
5
04/15/15 08:26
14797-55-8
H3
Date: 04/28/2015 01:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 42 of 87

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15040217
Pace Project No.: 92245094
Pace Analytical Services, Inc.
980%5 rpyoAje. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015010116
Lab ID:
92245094006
Collected:
04/02/15 13:20
Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
1220
mg/kg
861
431
1
04/23/15 12:19
7440-44-0
Total Organic Carbon
1360
mg/kg
847
424
1
04/23/15 12:26
7440-44-0
Total Organic Carbon
1200
mg/kg
849
425
1
04/23/15 12:32
7440-44-0
Total Organic Carbon
1360
mg/kg
859
430
1
04/23/15 12:38
7440-44-0
Mean Total Organic Carbon
1290
mg/kg
854
427
1
04/23/15 12:19
7440-44-0
Surrogates
RSD%
6.8
%
1
04/23/1512:19
Date: 04/28/2015 01:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 43 of 87

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800�rpyoAje. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
Sample: 2015010117
Lab ID:
92245094007 Collected:
04/02/15 13:30
Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
25900
mg/kg
36.4
18.2
5
04/16/15 21:15
04/25/15 18:11
7429-90-5
Barium
35.0
mg/kg
3.6
1.8
5
04/16/15 21:15
04/25/15 18:11
7440-39-3
Beryllium
2.4
mg/kg
0.36
0.18
5
04/16/15 21:15
04/25/15 18:11
7440-41-7
Boron
ND
mg/kg
18.2
9.1
5
04/16/15 21:15
04/25/15 18:11
7440-42-8
Calcium
ND
mg/kg
182
91.0
5
04/16/15 21:15
04/25/15 18:11
7440-70-2
Chromium
21.7
mg/kg
1.8
0.91
5
04/16/15 21:15
04/25/15 18:11
7440-47-3
Copper
68.7
mg/kg
1.8
0.91
5
04/16/15 21:15
04/25/15 18:11
7440-50-8
Iron
62400
mg/kg
14.6
7.3
5
04/16/15 21:15
04/25/15 18:11
7439-89-6
Magnesium
3050
mg/kg
182
91.0
5
04/16/15 21:15
04/25/15 18:11
7439-95-4
Manganese
1530
mg/kg
1.8
0.91
5
04/16/15 21:15
04/25/15 18:11
7439-96-5
Molybdenum
ND
mg/kg
3.6
1.8
5
04/16/15 21:15
04/25/15 18:11
7439-98-7
Nickel
14.9
mg/kg
1.8
0.91
5
04/16/15 21:15
04/25/15 18:11
7440-02-0
Potassium
2030
mg/kg
364
182
5
04/16/15 21:15
04/25/15 18:11
7440-09-7
Sodium
ND
mg/kg
364
182
5
04/16/15 21:15
04/25/15 18:11
7440-23-5
Strontium
1.8J
mg/kg
3.6
1.8
5
04/16/15 21:15
04/25/15 18:11
7440-24-6
Zinc
68.3
mg/kg
7.3
3.6
5
04/16/15 21:15
04/25/15 18:11
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
7.3
3.6
100
04/16/15 21:15
04/22/15 00:14
7440-36-0
N2
Arsenic
ND
mg/kg
7.3
3.6
100
04/16/15 21:15
04/22/15 00:14
7440-38-2
Cadmium
ND
mg/kg
0.87
0.44
100
04/16/15 21:15
04/22/15 00:14
7440-43-9
Cobalt
41.8
mg/kg
7.3
3.6
100
04/16/15 21:15
04/22/15 00:14
7440-48-4
Lead
8.6
mg/kg
7.3
3.6
100
04/16/15 21:15
04/22/15 00:14
7439-92-1
Selenium
ND
mg/kg
7.3
3.6
100
04/16/15 21:15
04/22/15 00:14
7782-49-2
Thallium
ND
mg/kg
7.3
3.6
100
04/16/15 21:15
04/22/15 00:14
7440-28-0
Vanadium
34.7
mg/kg
7.3
3.6
100
04/16/15 21:15
04/22/15 00:14
7440-62-2
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
ND
mg/kg 0.012
0.0060
1
04/16/15 22:25
04/17/15 13:14
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
34.6
%
0.10
0.10
1
04/16/15 16:04
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
5.1
Std. Units
0.10
0.10
1
04/16/15 10:45
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
385
193
5
04/15/15 08:47
16887-00-6
D3
Sulfate
ND
mg/kg
385
193
5
04/15/15 08:47
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
38.5
19.3
5
04/15/15 08:47
14797-55-8
H3
Date: 04/28/2015 01:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 44 of 87

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15040217
Pace Project No.: 92245094
Pace Analytical Services, Inc.
980%48r6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015010117
Lab ID:
92245094007
Collected:
04/02/15 13:30
Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
1760
mg/kg
915
457
1
04/23/15 12:44
7440-44-0
Total Organic Carbon
1840
mg/kg
910
455
1
04/23/15 12:50
7440-44-0
Total Organic Carbon
1570
mg/kg
916
458
1
04/23/15 12:56
7440-44-0
Total Organic Carbon
1610
mg/kg
908
454
1
04/23/15 13:03
7440-44-0
Mean Total Organic Carbon
1700
mg/kg
912
456
1
04/23/15 12:44
7440-44-0
Surrogates
RSD%
7.5
%
1
04/23/1512:44
Date: 04/28/2015 01:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 45 of 87

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800-)ir6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
Sample: 2015010118
Lab ID:
92245094008 Collected:
04/02/15 13:40
Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
17500
mg/kg
32.7
16.4
5
04/16/15 21:15
04/25/15 18:15
7429-90-5
Barium
43.0
mg/kg
3.3
1.6
5
04/16/15 21:15
04/25/15 18:15
7440-39-3
Beryllium
1.3
mg/kg
0.33
0.16
5
04/16/15 21:15
04/25/15 18:15
7440-41-7
Boron
ND
mg/kg
16.4
8.2
5
04/16/15 21:15
04/25/15 18:15
7440-42-8
Calcium
1160
mg/kg
164
81.8
5
04/16/15 21:15
04/25/15 18:15
7440-70-2
Chromium
12.9
mg/kg
1.6
0.82
5
04/16/15 21:15
04/25/15 18:15
7440-47-3
Copper
76.7
mg/kg
1.6
0.82
5
04/16/15 21:15
04/25/15 18:15
7440-50-8
Iron
57600
mg/kg
13.1
6.5
5
04/16/15 21:15
04/25/15 18:15
7439-89-6
Magnesium
8750
mg/kg
164
81.8
5
04/16/15 21:15
04/25/15 18:15
7439-95-4
Manganese
179
mg/kg
1.6
0.82
5
04/16/15 21:15
04/25/15 18:15
7439-96-5
Molybdenum
ND
mg/kg
3.3
1.6
5
04/16/15 21:15
04/25/15 18:15
7439-98-7
Nickel
25.2
mg/kg
1.6
0.82
5
04/16/15 21:15
04/25/15 18:15
7440-02-0
Potassium
4410
mg/kg
327
164
5
04/16/15 21:15
04/25/15 18:15
7440-09-7
Sodium
ND
mg/kg
327
164
5
04/16/15 21:15
04/25/15 18:15
7440-23-5
Strontium
4.2
mg/kg
3.3
1.6
5
04/16/15 21:15
04/25/15 18:15
7440-24-6
Zinc
96.8
mg/kg
6.5
3.3
5
04/16/15 21:15
04/25/15 18:15
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
6.5
3.3
100
04/16/15 21:15
04/22/15 00:17
7440-36-0
N2
Arsenic
ND
mg/kg
6.5
3.3
100
04/16/15 21:15
04/22/15 00:17
7440-38-2
Cadmium
ND
mg/kg
0.79
0.39
100
04/16/15 21:15
04/22/15 00:17
7440-43-9
Cobalt
25.6
mg/kg
6.5
3.3
100
04/16/15 21:15
04/22/15 00:17
7440-48-4
Lead
5.2J
mg/kg
6.5
3.3
100
04/16/15 21:15
04/22/15 00:17
7439-92-1
Selenium
ND
mg/kg
6.5
3.3
100
04/16/15 21:15
04/22/15 00:17
7782-49-2
Thallium
ND
mg/kg
6.5
3.3
100
04/16/15 21:15
04/22/15 00:17
7440-28-0
Vanadium
19.1
mg/kg
6.5
3.3
100
04/16/15 21:15
04/22/15 00:17
7440-62-2
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
ND
mg/kg
0.011
0.0054
1
04/16/15 22:25
04/17/15 13:16
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
27.0
%
0.10
0.10
1
04/16/15 16:06
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
4.3
Std. Units
0.10
0.10
1
04/16/15 10:45
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
345
172
5
04/15/15 09:09
16887-00-6
D3
Sulfate
346
mg/kg
345
172
5
04/15/15 09:09
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
34.5
17.2
5
04/15/15 09:09
14797-55-8
H3
Date: 04/28/2015 01:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 46 of 87

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15040217
Pace Project No.: 92245094
Pace Analytical Services, Inc.
98006Jf 6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015010118
Lab ID:
92245094008
Collected:
04/02/15 13:40
Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
9700
mg/kg
1360
680
1
04/23/15 13:09
7440-44-0
Total Organic Carbon
7890
mg/kg
1370
683
1
04/23/15 13:15
7440-44-0
Total Organic Carbon
7430
mg/kg
1360
678
1
04/23/15 13:21
7440-44-0
Total Organic Carbon
7730
mg/kg
1370
683
1
04/23/15 13:28
7440-44-0
Mean Total Organic Carbon
8190
mg/kg
1360
681
1
04/23/15 13:09
7440-44-0
Surrogates
RSD%
12.5
%
1
04/23/1513:09
Date: 04/28/2015 01:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 47 of 87

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
980%4Sr6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
Sample: 2015010119
Lab ID:
92245094009 Collected:
04/06/15 16:00
Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
16000
mg/kg
32.9
16.4
5
04/16/15 21:15
04/25/15 18:20
7429-90-5
Barium
681
mg/kg
3.3
1.6
5
04/16/15 21:15
04/25/15 18:20
7440-39-3
Beryllium
4.4
mg/kg
0.33
0.16
5
04/16/15 21:15
04/25/15 18:20
7440-41-7
Boron
15.2J
mg/kg
16.4
8.2
5
04/16/15 21:15
04/25/15 18:20
7440-42-8
Calcium
2480
mg/kg
164
82.2
5
04/16/15 21:15
04/25/15 18:20
7440-70-2
Chromium
26.8
mg/kg
1.6
0.82
5
04/16/15 21:15
04/25/15 18:20
7440-47-3
Copper
48.0
mg/kg
1.6
0.82
5
04/16/15 21:15
04/25/15 18:20
7440-50-8
Iron
14400
mg/kg
13.2
6.6
5
04/16/15 21:15
04/25/15 18:20
7439-89-6
Magnesium
1500
mg/kg
164
82.2
5
04/16/15 21:15
04/25/15 18:20
7439-95-4
Manganese
55.8
mg/kg
1.6
0.82
5
04/16/15 21:15
04/25/15 18:20
7439-96-5
Molybdenum
ND
mg/kg
3.3
1.6
5
04/16/15 21:15
04/25/15 18:20
7439-98-7
Nickel
23.0
mg/kg
1.6
0.82
5
04/16/15 21:15
04/25/15 18:20
7440-02-0
Potassium
3490
mg/kg
329
164
5
04/16/15 21:15
04/25/15 18:20
7440-09-7
Sodium
487
mg/kg
329
164
5
04/16/15 21:15
04/25/15 18:20
7440-23-5
Strontium
223
mg/kg
3.3
1.6
5
04/16/15 21:15
04/25/15 18:20
7440-24-6
Zinc
40.5
mg/kg
6.6
3.3
5
04/16/15 21:15
04/25/15 18:20
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
6.6
3.3
100
04/16/15 21:15
04/22/15 00:19
7440-36-0
N2
Arsenic
97.4
mg/kg
6.6
3.3
100
04/16/15 21:15
04/22/15 00:19
7440-38-2
Cadmium
ND
mg/kg
0.79
0.39
100
04/16/15 21:15
04/22/15 00:19
7440-43-9
Cobalt
12.5
mg/kg
6.6
3.3
100
04/16/15 21:15
04/22/15 00:19
7440-48-4
Lead
22.6
mg/kg
6.6
3.3
100
04/16/15 21:15
04/22/15 00:19
7439-92-1
Selenium
13.5
mg/kg
6.6
3.3
100
04/16/15 21:15
04/22/15 00:19
7782-49-2
Thallium
ND
mg/kg
6.6
3.3
100
04/16/15 21:15
04/22/15 00:19
7440-28-0
Vanadium
68.0
mg/kg
6.6
3.3
100
04/16/15 21:15
04/22/15 00:19
7440-62-2
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
0.34
mg/kg
0.011
0.0053
1
04/16/15 22:25
04/17/15 13:18
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
23.4
%
0.10
0.10
1
04/16/15 16:07
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
7.3
Std. Units
0.10
0.10
1
04/16/15 10:45
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
321
160
5
04/15/15 09:30
16887-00-6
D3
Sulfate
ND
mg/kg
321
160
5
04/15/15 09:30
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
32.1
16.0
5
04/15/15 09:30
14797-55-8
H3
Date: 04/28/2015 01:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 48 of 87

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15040217
Pace Project No.: 92245094
Pace Analytical Services, Inc.
98006}�ir6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015010119
Lab ID:
92245094009
Collected:
04/06/15 16:00
Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
81900
mg/kg
8740
4370
1
04/27/15 14:20
7440-44-0
Total Organic Carbon
91700
mg/kg
8620
4310
1
04/27/15 14:25
7440-44-0
Total Organic Carbon
89200
mg/kg
8770
4390
1
04/27/15 14:31
7440-44-0
Total Organic Carbon
81400
mg/kg
8900
4450
1
04/27/15 14:36
7440-44-0
Mean Total Organic Carbon
86000
mg/kg
8760
4380
1
04/27/15 14:20
7440-44-0
Surrogates
RSD%
6.0
%
1
04/27/1514:20
Date: 04/28/2015 01:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 49 of 87

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
980%48r6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
Sample: 2015010121
Lab ID:
92245094010 Collected:
04/06/15 16:45
Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
32000
mg/kg
30.2
15.1
5
04/16/15 21:15
04/25/15 18:24
7429-90-5
Barium
62.8
mg/kg
3.0
1.5
5
04/16/15 21:15
04/25/15 18:24
7440-39-3
Beryllium
1.4
mg/kg
0.30
0.15
5
04/16/15 21:15
04/25/15 18:24
7440-41-7
Boron
ND
mg/kg
15.1
7.6
5
04/16/15 21:15
04/25/15 18:24
7440-42-8
Calcium
582
mg/kg
151
75.5
5
04/16/15 21:15
04/25/15 18:24
7440-70-2
Chromium
15.5
mg/kg
1.5
0.76
5
04/16/15 21:15
04/25/15 18:24
7440-47-3
Copper
65.3
mg/kg
1.5
0.76
5
04/16/15 21:15
04/25/15 18:24
7440-50-8
Iron
43100
mg/kg
12.1
6.0
5
04/16/15 21:15
04/25/15 18:24
7439-89-6
Magnesium
3230
mg/kg
151
75.5
5
04/16/15 21:15
04/25/15 18:24
7439-95-4
Manganese
344
mg/kg
1.5
0.76
5
04/16/15 21:15
04/25/15 18:24
7439-96-5
Molybdenum
6.4
mg/kg
3.0
1.5
5
04/16/15 21:15
04/25/15 18:24
7439-98-7
Nickel
13.9
mg/kg
1.5
0.76
5
04/16/15 21:15
04/25/15 18:24
7440-02-0
Potassium
2440
mg/kg
302
151
5
04/16/15 21:15
04/25/15 18:24
7440-09-7
Sodium
ND
mg/kg
302
151
5
04/16/15 21:15
04/25/15 18:24
7440-23-5
Strontium
27.9
mg/kg
3.0
1.5
5
04/16/15 21:15
04/25/15 18:24
7440-24-6
Zinc
61.8
mg/kg
6.0
3.0
5
04/16/15 21:15
04/25/15 18:24
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
6.0
3.0
100
04/16/15 21:15
04/22/15 00:21
7440-36-0
N2
Arsenic
25.5
mg/kg
6.0
3.0
100
04/16/15 21:15
04/22/15 00:21
7440-38-2
Cadmium
ND
mg/kg
0.73
0.36
100
04/16/15 21:15
04/22/15 00:21
7440-43-9
Cobalt
26.5
mg/kg
6.0
3.0
100
04/16/15 21:15
04/22/15 00:21
7440-48-4
Lead
11.4
mg/kg
6.0
3.0
100
04/16/15 21:15
04/22/15 00:21
7439-92-1
Selenium
ND
mg/kg
6.0
3.0
100
04/16/15 21:15
04/22/15 00:21
7782-49-2
Thallium
ND
mg/kg
6.0
3.0
100
04/16/15 21:15
04/22/15 00:21
7440-28-0
Vanadium
30.3
mg/kg
6.0
3.0
100
04/16/15 21:15
04/22/15 00:21
7440-62-2
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
ND
mg/kg 0.0097
0.0049
1
04/16/15 22:25
04/17/15 13:20
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
16.4
%
0.10
0.10
1
04/16/15 16:08
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
7.0
Std. Units
0.10
0.10
1
04/16/15 10:45
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
297
148
5
04/15/15 09:51
16887-00-6
D3
Sulfate
ND
mg/kg
297
148
5
04/15/15 09:51
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
29.7
14.8
5
04/15/15 09:51
14797-55-8
H3
Date: 04/28/2015 01:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 50 of 87

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15040217
Pace Project No.: 92245094
Pace Analytical Services, Inc.
980%48r6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015010121
Lab ID:
92245094010
Collected:
04/06/15 16:45
Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
1650
mg/kg
718
359
1
04/27/15 14:42
7440-44-0
Total Organic Carbon
1230
mg/kg
711
356
1
04/27/15 14:48
7440-44-0
Total Organic Carbon
1270
mg/kg
720
360
1
04/27/15 14:55
7440-44-0
Total Organic Carbon
1880
mg/kg
712
356
1
04/27/15 15:01
7440-44-0
Mean Total Organic Carbon
1510
mg/kg
715
358
1
04/27/15 14:42
7440-44-0
Surrogates
RSD%
20.7
%
1
04/27/1514:42
Date: 04/28/2015 01:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 51 of 87

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
98004?r6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
Sample: 2015010122
Lab ID:
92245094011 Collected:
04/06/15 17:00
Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
20700
mg/kg
34.8
17.4
5
04/19/15 05:38
04/25/15 14:18
7429-90-5
D3,M1
Barium
149
mg/kg
3.5
1.7
5
04/19/15 05:38
04/25/15 14:18
7440-39-3
D3,M1
Beryllium
2.3
mg/kg
0.35
0.17
5
04/19/15 05:38
04/25/15 14:18
7440-41-7
D3
Boron
ND
mg/kg
17.4
8.7
5
04/19/15 05:38
04/25/15 14:18
7440-42-8
D3
Calcium
525
mg/kg
174
87.0
5
04/19/15 05:38
04/25/15 14:18
7440-70-2
D3
Chromium
47.5
mg/kg
1.7
0.87
5
04/19/15 05:38
04/25/15 14:18
7440-47-3
D3,M1
Copper
37.5
mg/kg
1.7
0.87
5
04/19/15 05:38
04/25/15 14:18
7440-50-8
D3,M1
Iron
60700
mg/kg
13.9
7.0
5
04/19/15 05:38
04/25/15 14:18
7439-89-6
D3,M1
Magnesium
5520
mg/kg
174
87.0
5
04/19/15 05:38
04/25/15 14:18
7439-95-4
D3,M1
Manganese
942
mg/kg
1.7
0.87
5
04/19/15 05:38
04/25/15 14:18
7439-96-5
D3,M1
Molybdenum
44.6
mg/kg
3.5
1.7
5
04/19/15 05:38
04/25/15 14:18
7439-98-7
D3
Nickel
30.2
mg/kg
1.7
0.87
5
04/19/15 05:38
04/25/15 14:18
7440-02-0
D3,M1
Potassium
4200
mg/kg
348
174
5
04/19/15 05:38
04/25/15 14:18
7440-09-7
D3,M1
Sodium
ND
mg/kg
348
174
5
04/19/15 05:38
04/25/15 14:18
7440-23-5
D3
Strontium
27.4
mg/kg
3.5
1.7
5
04/19/15 05:38
04/25/15 14:18
7440-24-6
D3,M1
Zinc
83.5
mg/kg
7.0
3.5
5
04/19/15 05:38
04/25/15 14:18
7440-66-6
D3,M1
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
7.0
3.5
100
04/19/15 05:38
04/22/15 01:49
7440-36-0
N2
Arsenic
ND
mg/kg
7.0
3.5
100
04/19/15 05:38
04/22/15 01:49
7440-38-2
Cadmium
ND
mg/kg
0.84
0.42
100
04/19/15 05:38
04/22/15 01:49
7440-43-9
Cobalt
39.7
mg/kg
7.0
3.5
100
04/19/15 05:38
04/22/15 01:49
7440-48-4
Lead
12.4
mg/kg
7.0
3.5
100
04/19/15 05:38
04/22/15 01:49
7439-92-1
Selenium
5.1J
mg/kg
7.0
3.5
100
04/19/15 05:38
04/22/15 01:49
7782-49-2
Thallium
ND
mg/kg
7.0
3.5
100
04/19/15 05:38
04/22/15 01:49
7440-28-0
Vanadium
78.0
mg/kg
7.0
3.5
100
04/19/15 05:38
04/22/15 01:49
7440-62-2
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
ND
mg/kg
0.011
0.0055
1
04/19/15 05:30
04/20/15 20:42
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
30.0
%
0.10
0.10
1
04/16/15 16:08
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
7.0
Std. Units
0.10
0.10
1
04/16/15 10:45
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
356
178
5
04/15/1510:13
16887-00-6
D3
Sulfate
ND
mg/kg
356
178
5
04/15/1510:13
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
35.6
17.8
5
04/15/15 10:13
14797-55-8
H3
Date: 04/28/2015 01:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 52 of 87

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15040217
Pace Project No.: 92245094
Pace Analytical Services, Inc.
980%4gr6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015010122
Lab ID:
92245094011
Collected:
04/06/15 17:00
Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
1080
mg/kg
853
426
1
04/27/15 15:08
7440-44-0
Total Organic Carbon
1360
mg/kg
852
426
1
04/27/15 15:14
7440-44-0
Total Organic Carbon
1070
mg/kg
865
433
1
04/27/15 15:21
7440-44-0
Total Organic Carbon
1300
mg/kg
852
426
1
04/27/15 15:27
7440-44-0
Mean Total Organic Carbon
1200
mg/kg
855
428
1
04/27/15 15:08
7440-44-0
Surrogates
RSD%
12.2
%
1
04/27/1515:08
Date: 04/28/2015 01:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 53 of 87

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
98006r6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
Sample: 2015010123
Lab ID:
92245094012 Collected:
04/06/15 17:05
Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical
Method: EPA 6010
Preparation
Method: EPA
3050
Aluminum
21200
mg/kg
193
96.6
25
04/19/15 05:38
04/25/15 14:47
7429-90-5
D3
Barium
86.7
mg/kg
19.3
9.7
25
04/19/15 05:38
04/25/15 14:47
7440-39-3
D3
Beryllium
1.4
mg/kg
0.39
0.19
5
04/19/15 05:38
04/25/15 14:43
7440-41-7
Boron
ND
mg/kg
19.3
9.7
5
04/19/15 05:38
04/25/15 14:43
7440-42-8
Calcium
152J
mg/kg
193
96.6
5
04/19/15 05:38
04/25/15 14:43
7440-70-2
Chromium
15.0
mg/kg
9.7
4.8
25
04/19/15 05:38
04/25/15 14:47
7440-47-3
D3
Copper
36.6
mg/kg
9.7
4.8
25
04/19/15 05:38
04/25/15 14:47
7440-50-8
D3
Iron
33600
mg/kg
77.2
38.6
25
04/19/15 05:38
04/25/15 14:47
7439-89-6
D3
Magnesium
4660
mg/kg
966
483
25
04/19/15 05:38
04/25/15 14:47
7439-95-4
D3
Manganese
352
mg/kg
9.7
4.8
25
04/19/15 05:38
04/25/15 14:47
7439-96-5
D3
Molybdenum
ND
mg/kg
0.77
0.39
1
04/19/15 05:38
04/20/15 13:59
7439-98-7
Nickel
5.6
mg/kg
0.39
0.19
1
04/19/15 05:38
04/20/15 13:59
7440-02-0
Potassium
3270
mg/kg
386
193
5
04/19/15 05:38
04/25/15 14:43
7440-09-7
Sodium
ND
mg/kg
386
193
5
04/19/15 05:38
04/25/15 14:43
7440-23-5
Strontium
12AJ
mg/kg
19.3
9.7
25
04/19/15 05:38
04/25/15 14:47
7440-24-6
D3
Zinc
76.0
mg/kg
38.6
19.3
25
04/19/15 05:38
04/25/15 14:47
7440-66-6
D3
6020 MET ICPMS
Analytical
Method: EPA 6020
Preparation
Method: EPA
3050
Antimony
ND
mg/kg
7.7
3.9
100
04/19/15 05:38
04/22/15 02:05
7440-36-0
M6, N2
Arsenic
ND
mg/kg
7.7
3.9
100
04/19/15 05:38
04/22/15 02:05
7440-38-2
Cadmium
ND
mg/kg
0.93
0.46
100
04/19/15 05:38
04/22/15 02:05
7440-43-9
Cobalt
17.2
mg/kg
7.7
3.9
100
04/19/15 05:38
04/22/15 02:05
7440-48-4
M6, R1
Lead
7.6J
mg/kg
7.7
3.9
100
04/19/15 05:38
04/22/15 02:05
7439-92-1
M6
Selenium
ND
mg/kg
7.7
3.9
100
04/19/15 05:38
04/22/15 02:05
7782-49-2
Thallium
ND
mg/kg
7.7
3.9
100
04/19/15 05:38
04/22/15 02:05
7440-28-0
Vanadium
29.1
mg/kg
7.7
3.9
100
04/19/15 05:38
04/22/15 02:05
7440-62-2
M6, R1
7471 Mercury
Analytical
Method: EPA 7471
Preparation
Method: EPA
7471
Mercury
ND
mg/kg 0.012
0.0059
1
04/19/15 05:30
04/20/15 20:53
7439-97-6
Percent Moisture
Analytical
Method: ASTM D2974-87
Percent Moisture
33.2
%
0.10
0.10
1
04/16/15 16:09
9045 pH Soil
Analytical
Method: EPA 9045
pH at 25 Degrees C
6.2
Std. Units
0.10
0.10
1
04/16/15 10:45
9056 IC Anions
Analytical
Method: EPA 9056
Chloride
ND
mg/kg
373
186
5
04/15/1510:34
16887-00-6
D3
Sulfate
ND
mg/kg
373
186
5
04/15/1510:34
14808-79-8
D3
9056 IC Anions 48hr
Analytical
Method: EPA 9056
Nitrate as N
ND
mg/kg
37.3
18.6
5
04/15/15 10:34
14797-55-8
H3
Date: 04/28/2015 01:02 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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ANALYTICAL RESULTS
Project: J15040217
Pace Project No.: 92245094
Pace Analytical Services, Inc.
98007tbirpyoAle. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015010123
Lab ID:
92245094012
Collected:
04/06/15 17:05
Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
1630
mg/kg
901
451
1
04/27/15 15:34
7440-44-0
Total Organic Carbon
1640
mg/kg
893
446
1
04/27/15 15:40
7440-44-0
Total Organic Carbon
1530
mg/kg
903
452
1
04/27/15 15:47
7440-44-0
Total Organic Carbon
1690
mg/kg
903
452
1
04/27/15 15:53
7440-44-0
Mean Total Organic Carbon
1620
mg/kg
900
450
1
04/27/15 15:34
7440-44-0
Surrogates
RSD%
4.2
%
1
04/27/1515:34
Date: 04/28/2015 01:02 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J15040217
Pace Project No.: 92245094
Pace Analytical Services, Inc.
9800AirpyoAle. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015010120 Lab ID: 92245094013 Collected: 04/06/15 16:10 Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
300.0 IC Anions, SPLP
Sulfate
353.2 Nitrogen, NO2/NO3, SPLP
Nitrogen, Nitrate
4500 Chloride, SPLP
Chloride
Date: 04/28/2015 01:02 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
21000
mg/kg
36.1
18.1
5
04/19/15 05:38
04/25/15 14:55
7429-90-5
545
mg/kg
3.6
1.8
5
04/19/15 05:38
04/25/15 14:55
7440-39-3
4.9
mg/kg
0.36
0.18
5
04/19/15 05:38
04/25/15 14:55
7440-41-7
16.3J
mg/kg
18.1
9.0
5
04/19/15 05:38
04/25/15 14:55
7440-42-8
3170
mg/kg
181
90.3
5
04/19/15 05:38
04/25/15 14:55
7440-70-2
40.3
mg/kg
1.8
0.90
5
04/19/15 05:38
04/25/15 14:55
7440-47-3
63.9
mg/kg
1.8
0.90
5
04/19/15 05:38
04/25/15 14:55
7440-50-8
18500
mg/kg
14.4
7.2
5
04/19/15 05:38
04/25/15 14:55
7439-89-6
1470
mg/kg
181
90.3
5
04/19/15 05:38
04/25/15 14:55
7439-95-4
89.6
mg/kg
1.8
0.90
5
04/19/15 05:38
04/25/15 14:55
7439-96-5
2.8J
mg/kg
3.6
1.8
5
04/19/15 05:38
04/25/15 14:55
7439-98-7
35.7
mg/kg
1.8
0.90
5
04/19/15 05:38
04/25/15 14:55
7440-02-0
3200
mg/kg
361
181
5
04/19/15 05:38
04/25/15 14:55
7440-09-7
497
mg/kg
361
181
5
04/19/15 05:38
04/25/15 14:55
7440-23-5
327
mg/kg
3.6
1.8
5
04/19/15 05:38
04/25/15 14:55
7440-24-6
60.3
mg/kg
7.2
3.6
5
04/19/15 05:38
04/25/15 14:55
7440-66-6
Analytical
Method: EPA 6020 Preparation
Method: EPA 3050
ND
mg/kg
7.2
3.6
100
04/19/15 05:38
04/22/15 02:12
7440-36-0
217
mg/kg
7.2
3.6
100
04/19/15 05:38
04/22/15 02:12
7440-38-2
0.56J
mg/kg
0.87
0.43
100
04/19/15 05:38
04/22/15 02:12
7440-43-9
19.8
mg/kg
7.2
3.6
100
04/19/15 05:38
04/22/15 02:12
7440-48-4
26.1
mg/kg
7.2
3.6
100
04/19/15 05:38
04/22/15 02:12
7439-92-1
19.5
mg/kg
7.2
3.6
100
04/19/15 05:38
04/22/15 02:12
7782-49-2
ND
mg/kg
7.2
3.6
100
04/19/15 05:38
04/22/15 02:12
7440-28-0
103
mg/kg
7.2
3.6
100
04/19/15 05:38
04/22/15 02:12
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.24 mg/kg 0.011 0.0056 1 04/19/15 05:30 04/20/15 20:58 7439-97-6
Analytical Method: ASTM D2974-87
31.6 % 0.10 0.10 1 04/16/1516:10
Analytical Method: EPA 9045
7.5 Std. Units 0.10 0.10 1 04/16/15 10:45
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
D3
N2
Analytical Method: EPA 300.0 Leachate Method/Date: EPA 1312; 04/15/15 00:55
9.6 mg/L 2.9 1.5 1 04/19/1516:46 14808-79-8 B
Analytical Method: EPA 353.2 Leachate Method/Date: EPA 1312; 04/15/15 00:55
ND mg/L 0.29 0.29 1 04/22/1517:42 H1
Analytical Method: SM 4500 -CI -E Leachate Method/Date: EPA 1312; 04/15/15 00:55
ND mg/L 7.3 3.7 1 04/17/15 05:42 16887-00-6
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
Page 56 of 87

aceAnaiXical
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ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800hirpyoAle. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
Sample: 2015010120 Lab ID: 92245094013 Collected: 04/06/15 16:10 Received: 04/10/15 16:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056
Chloride
ND mg/kg
365
182
5
04/15/1510:56
16887-00-6 D3
Sulfate
185J mg/kg
365
182
5
04/15/1510:56
14808-79-8 D3
9056 IC Anions 48hr
Analytical Method: EPA 9056
Nitrate as N
ND mg/kg
36.5
18.2
5
04/15/15 10:56
14797-55-8 H3
Total Organic Carbon Quad
Analytical Method: EPA 9060
Total Organic Carbon
26400 mg/kg
5700
2850
1
04/27/15 16:00
7440-44-0
Total Organic Carbon
22100 mg/kg
5550
2780
1
04/27/15 16:05
7440-44-0
Total Organic Carbon
22500 mg/kg
5710
2850
1
04/27/15 16:11
7440-44-0
Total Organic Carbon
23300 mg/kg
5720
2860
1
04/27/15 16:17
7440-44-0
Mean Total Organic Carbon
23600 mg/kg
5670
2830
1
04/27/15 16:00
7440-44-0
Surrogates
RSD%
8.2 %
1
04/27/1516:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/28/2015 01:02 PM without the written consent of Pace Analytical Services, Inc..
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QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800h,pyoAle. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
QC Batch: MERP/13223
Analysis Method: EPA 7470
QC Batch Method: EPA 7470
Analysis Description: 7470 Mercury
Associated Lab Samples: 92245094001, 92245094002
METHOD BLANK: 1938836
Matrix: Water
Associated Lab Samples: 92245094001, 92245094002
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ug/L
ND 0.20
04/15/1518:09
LABORATORY CONTROL SAMPLE: 1938837
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury ug/L
5 4.7
95 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1938838 1938839
MS MSD
92245128001
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND
5 5 4.7
4.7 94 94 75-125 0 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/28/2015 01:02 PM without the written consent of Pace Analytical Services, Inc..
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QUALITY CONTROL DATA
Pace Analytical Services, Inc.
98007V6fY0A1e. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
QC Batch: MERP/13312
Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A
Analysis Description: 7470A Mercury Water
Associated Lab Samples: 92245094003
METHOD BLANK: 1945562
Matrix: Water
Associated Lab Samples: 92245094003
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ug/L
ND 0.20
04/23/1519:26
LABORATORY CONTROL SAMPLE: 1945563
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury ug/L
5 5.2
104 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1945564 1945565
MS MSD
92246088001
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND
5 5 5.0
5.1 100 102 80-120 2 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/28/2015 01:02 PM without the written consent of Pace Analytical Services, Inc..
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QUALITY CONTROL DATA
Pace Analytical Services, Inc.
98008r6fY04Je. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
QC Batch: MERP/5597
Analysis Method: EPA 7471
QC Batch Method: EPA 7471
Analysis Description: 7471 Mercury
Associated Lab Samples: 92245094004,92245094005,92245094006,92245094007,92245094008,92245094009,92245094010
METHOD BLANK: 1186051
Matrix: Solid
Associated Lab Samples: 92245094004, 92245094005,
92245094006, 92245094007, 92245094008, 92245094009, 92245094010
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Mercury mg/kg
ND 0.0080 04/17/1512:20
LABORATORY CONTROL SAMPLE: 1186052
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Mercury mg/kg
.083 0.081 98 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1186053 1186054
MS MSD
92245143001
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury mg/kg 0.011
.0868 .0914 0.083 0.088 83 84 80-120 5 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/28/2015 01:02 PM without the written consent of Pace Analytical Services, Inc..
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QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 ,6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
QC Batch: MERP/5604
Analysis Method: EPA 7471
QC Batch Method: EPA 7471
Analysis Description: 7471
Mercury
Associated Lab Samples: 92245094011, 92245094012,
92245094013
METHOD BLANK: 1188083
Matrix: Solid
Associated Lab Samples: 92245094011, 92245094012,
92245094013
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury mg/kg
ND 0.0081
04/20/15 20:38
LABORATORY CONTROL SAMPLE: 1188084
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury mg/kg
.082 0.066
81 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1188085 1188086
MS MSD
92245094011
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Mercury mg/kg ND
.12 .117 0.11
0.10 89 86 80-120 6 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/28/2015 01:02 PM without the written consent of Pace Analytical Services, Inc..
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QUALITY CONTROL DATA
Project: J15040217
Pace Project No.: 92245094
Pace Analytical Services, Inc.
9800firpyoAje. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: MPRP/23656 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid
Associated Lab Samples: 92245094004, 92245094005, 92245094006, 92245094007, 92245094008, 92245094009, 92245094010
METHOD BLANK: 1186027 Matrix: Solid
Associated Lab Samples: 92245094004, 92245094005, 92245094006, 92245094007, 92245094008, 92245094009, 92245094010
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Aluminum
mg/kg
ND
5.2
04/25/1516:01
Barium
mg/kg
ND
0.52
04/25/1516:01
Beryllium
mg/kg
ND
0.052
04/25/1516:01
Boron
mg/kg
ND
2.6
04/25/1516:01
Calcium
mg/kg
ND
26.2
04/25/1516:01
Chromium
mg/kg
ND
0.26
04/25/1516:01
Copper
mg/kg
ND
0.26
04/25/1516:01
Iron
mg/kg
2.1
2.1
04/25/1516:01 P8
Magnesium
mg/kg
ND
26.2
04/25/1516:01
Manganese
mg/kg
ND
0.26
04/25/1516:01
Molybdenum
mg/kg
ND
0.52
04/25/1516:01
Nickel
mg/kg
ND
0.26
04/25/1516:01
Potassium
mg/kg
ND
52.3
04/25/1516:01
Sodium
mg/kg
ND
52.3
04/25/1516:01
Strontium
mg/kg
ND
0.52
04/25/1516:01
Zinc
mg/kg
ND
1.0
04/25/1516:01
LABORATORY CONTROL SAMPLE:
Parameter
1186028
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
mg/kg
130
134
103
80-120
Barium
mg/kg
13
13.4
102
80-120
Beryllium
mg/kg
1.3
1.3
101
80-120
Boron
mg/kg
130
127
97
80-120
Calcium
mg/kg
652
681
104
80-120
Chromium
mg/kg
13
12.6
96
80-120
Copper
mg/kg
13
12.6
97
80-120
Iron
mg/kg
130
134
102
80-120
Magnesium
mg/kg
652
661
101
80-120
Manganese
mg/kg
13
13.0
99
80-120
Molybdenum
mg/kg
13
12.8
98
80-120
Nickel
mg/kg
13
13.3
102
80-120
Potassium
mg/kg
652
659
101
80-120
Sodium
mg/kg
652
685
105
80-120
Strontium
mg/kg
13
13.3
102
80-120
Zinc
mg/kg
65.2
66.4
102
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/28/2015 01:02 PM without the written consent of Pace Analytical Services, Inc.. Page 62 of 87

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QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800&6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1186029
1186030
MS
MSD
92245143001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Aluminum
mg/kg
13100
139
143
15700
16800
1880
2580
75-125
7
20 M1
Barium
mg/kg
43.3
13.9
14.3
62.2
64.3
137
146
75-125
3
20 M1
Beryllium
mg/kg
ND
1.35
1.47
1.5
1.6
100
101
75-125
4
20
Boron
mg/kg
ND
139
143
128
132
93
92
75-125
3
20
Calcium
mg/kg
356
693
717
1050
1080
100
101
75-125
3
20
Chromium
mg/kg
4.7
13.9
14.3
16.4
17.8
85
92
75-125
8
20
Copper
mg/kg
33.0
13.9
14.3
35.7
37.0
19
28
75-125
4
20 M1
Iron
mg/kg
13800
139
143
12500
13000
-956
-556
75-125
4
20 M1
Magnesium
mg/kg
2010
693
717
2820
3010
116
139
75-125
7
20 M1
Manganese
mg/kg
70.1
13.9
14.3
78.6
88.0
61
125
75-125
11
20 M1
Molybdenum
mg/kg
ND
13.9
14.3
12.9
12.8
90
87
75-125
0
20
Nickel
mg/kg
1.3J
13.9
14.3
15.4
15.9
102
101
75-125
3
20
Potassium
mg/kg
995
693
717
1810
1890
118
125
75-125
4
20
Sodium
mg/kg
184J
693
717
1000
956
118
108
75-125
5
20
Strontium
mg/kg
6.0
13.9
14.3
21.2
21.0
110
105
75-125
1
20
Zinc
mg/kg
16.5
69.3
71.7
87.7
90.7
103
104
75-125
3
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/28/2015 01:02 PM without the written consent of Pace Analytical Services, Inc..
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QUALITY CONTROL DATA
Project: J15040217
Pace Project No.: 92245094
QC Batch: MPRP/23696 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid
Associated Lab Samples: 92245094011, 92245094012, 92245094013
METHOD BLANK: 1188075 Matrix:
Associated Lab Samples: 92245094011, 92245094012, 92245094013
Blank
Parameter Units Result
Solid
Reporting
Limit
Analyzed
Aluminum
mg/kg
ND
5.2
04/25/1514:10
Barium
mg/kg
ND
0.52
04/25/1514:10
Beryllium
mg/kg
ND
0.052
04/25/1514:10
Boron
mg/kg
ND
2.6
04/25/1514:10
Calcium
mg/kg
ND
25.8
04/25/1514:10
Chromium
mg/kg
ND
0.26
04/25/1514:10
Copper
mg/kg
ND
0.26
04/25/1514:10
Iron
mg/kg
1 AJ
2.1
04/25/15 14:10 P8
Magnesium
mg/kg
ND
25.8
04/25/1514:10
Manganese
mg/kg
ND
0.26
04/25/1514:10
Molybdenum
mg/kg
ND
0.52
04/25/1514:10
Nickel
mg/kg
ND
0.26
04/25/1514:10
Potassium
mg/kg
ND
51.7
04/25/1514:10
Sodium
mg/kg
ND
51.7
04/25/1514:10
Strontium
mg/kg
ND
0.52
04/25/1514:10
Zinc
mg/kg
ND
1.0
04/25/1514:10
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1188076
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
mg/kg
122
126
103
80-120
Barium
mg/kg
12.2
12.6
103
80-120
Beryllium
mg/kg
1.2
1.3
105
80-120
Boron
mg/kg
122
122
100
80-120
Calcium
mg/kg
608
644
106
80-120
Chromium
mg/kg
12.2
12.1
100
80-120
Copper
mg/kg
12.2
11.9
98
80-120
Iron
mg/kg
122
127
105
80-120
Magnesium
mg/kg
608
627
103
80-120
Manganese
mg/kg
12.2
12.5
103
80-120
Molybdenum
mg/kg
12.2
12.2
101
80-120
Nickel
mg/kg
12.2
12.7
104
80-120
Potassium
mg/kg
608
626
103
80-120
Sodium
mg/kg
608
640
105
80-120
Strontium
mg/kg
12.2
12.5
103
80-120
Zinc
mg/kg
60.8
63.3
104
80-120
Pace Analytical Services, Inc.
9800?gr6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/28/2015 01:02 PM without the written consent of Pace Analytical Services, Inc.. Page 64 of 87

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
980V,6fY04Je. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1188077
1188078
MS
MSD
92245094011
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qua]
Aluminum
mg/kg
20700
186
174
31300
33500
5680
7350
75-125
7
20 D3,M1
Barium
mg/kg
149
18.6
17.4
269
274
643
715
75-125
2
20 D3,M1
Beryllium
mg/kg
2.3
1.86
1.72
4.1
4.3
97
116
75-125
5
20 D3
Boron
mg/kg
ND
186
174
144
136
77
78
75-125
6
20 D3
Calcium
mg/kg
525
929
872
1560
1500
111
112
75-125
4
20 D3
Chromium
mg/kg
47.5
18.6
17.4
122
119
401
412
75-125
2
20 D3,M1
Copper
mg/kg
37.5
18.6
17.4
55.6
61.2
98
136
75-125
10
20 D3,M1
Iron
mg/kg
60700
186
174
64600
63300
2070
1460
75-125
2
20 D3,M1
Magnesium
mg/kg
5520
929
872
11300
12100
616
749
75-125
7
20 D3,M1
Manganese
mg/kg
942
18.6
17.4
1120
1040
975
538
75-125
8
20 D3,M1
Molybdenum
mg/kg
44.6
18.6
17.4
62.9
65.7
98
121
75-125
4
20 D3
Nickel
mg/kg
30.2
18.6
17.4
74.8
81.5
240
294
75-125
8
20 D3,M1
Potassium
mg/kg
4200
929
872
8300
9180
441
571
75-125
10
20 D3,M1
Sodium
mg/kg
ND
929
872
943
886
101
102
75-125
6
20 D3
Strontium
mg/kg
27.4
18.6
17.4
51.2
49.6
128
128
75-125
3
20 D3,M1
Zinc
mg/kg
83.5
92.9
87.2
202
201
128
135
75-125
0
20 D3,M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/28/2015 01:02 PM without the written consent of Pace Analytical Services, Inc..
Page 65 of 87

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Project: J15040217
Pace Project No.: 92245094
Pace Analytical Services, Inc.
980mirpyoAje. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: MPRP/23657 Analysis Method: EPA 6020
QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID
Associated Lab Samples: 92245094004,92245094005,92245094006,92245094007,92245094008,92245094009,92245094010
METHOD BLANK: 1186033
Matrix:
Solid
Associated Lab Samples:
92245094004, 92245094005,
92245094006, 92245094007, 92245094008,
92245094009, 92245094010
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Antimony
mg/kg
ND
0.052
04/21/15 23:09 N2
Arsenic
mg/kg
ND
0.052
04/21/15 23:09
Cadmium
mg/kg
ND
0.0062
04/21/15 23:09
Cobalt
mg/kg
ND
0.052
04/21/15 23:09
Lead
mg/kg
ND
0.052
04/21/15 23:09
Selenium
mg/kg
ND
0.052
04/21/15 23:09
Thallium
mg/kg
ND
0.052
04/21/15 23:09
Vanadium
mg/kg
ND
0.052
04/21/15 23:09
LABORATORY CONTROL SAMPLE: 1186034
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Antimony
mg/kg
2.6
2.7
104
80-120
N2
Arsenic
mg/kg
2.6
2.7
105
80-120
Cadmium
mg/kg
.26
0.27
106
80-120
Cobalt
mg/kg
2.6
2.7
105
80-120
Lead
mg/kg
2.6
2.6
102
80-120
Selenium
mg/kg
2.6
2.6
103
80-120
Thallium
mg/kg
2.6
2.7
105
80-120
Vanadium
mg/kg
2.6
2.7
105
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1186035
1186036
MS
MSD
92245143002
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD RPD Qual
Antimony
mg/kg
ND
2.98
2.87
ND
ND
-5
-64
75-125
20 M6, N2
Arsenic
mg/kg
3.9J
2.98
2.87
3.8J
ND
-3
-113
75-125
20 M6
Cadmium
mg/kg
ND
.298
.287
ND
ND
39
-64
75-125
20 M6
Cobalt
mg/kg
27.7
2.98
2.87
51.3
26.2
787
-55
75-125
65 20 M6,R1
Lead
mg/kg
3.9J
2.98
2.87
3.8J
ND
-2
-102
75-125
20 M6
Selenium
mg/kg
5.2J
2.98
2.87
ND
ND
-79
-161
75-125
20 M6
Thallium
mg/kg
3.9J
2.98
2.87
3.3J
ND
-21
-127
75-125
20 M6
Vanadium
mg/kg
87.3
2.98
2.87
103
78.7
539
-299
75-125
27 20 M6, R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/28/2015 01:02 PM without the written consent of Pace Analytical Services, Inc..
Page 66 of 87

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Project: J15040217
Pace Project No.: 92245094
QC Batch: MPRP/23697 Analysis Method: EPA 6020
QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID
Associated Lab Samples: 92245094011, 92245094012, 92245094013
METHOD BLANK: 1188079
Matrix:
Solid
LCS
Result
Associated Lab Samples:
92245094011, 92245094012,
92245094013
mg/kg
2.5
2.5
101
Blank
Reporting
mg/kg
Parameter
Units
Result
Limit
Analyzed Qualifiers
Antimony
mg/kg
ND
0.052
04/22/15 01:45 N2
Arsenic
mg/kg
ND
0.052
04/22/15 01:45
Cadmium
mg/kg
ND
0.0063
04/22/15 01:45
Cobalt
mg/kg
ND
0.052
04/22/15 01:45
Lead
mg/kg
ND
0.052
04/22/15 01:45
Selenium
mg/kg
ND
0.052
04/22/15 01:45
Thallium
mg/kg
ND
0.052
04/22/15 01:45
Vanadium
mg/kg
ND
0.052
04/22/15 01:45
Pace Analytical Services, Inc.
980%y6fY04Je. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
Parameter
1188080
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Antimony
mg/kg
2.5
2.5
101
80-120 N2
Arsenic
mg/kg
2.5
2.6
106
80-120
Cadmium
mg/kg
.25
0.26
104
80-120
Cobalt
mg/kg
2.5
2.6
106
80-120
Lead
mg/kg
2.5
2.5
101
80-120
Selenium
mg/kg
2.5
2.5
103
80-120
Thallium
mg/kg
2.5
2.6
103
80-120
Vanadium
mg/kg
2.5
2.6
106
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1188081
1188082
MS
MSD
92245094012
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD RPD Qual
Antimony
mg/kg
ND
3.59
3.89
ND
ND
51
71
75-125
20 M6, N2
Arsenic
mg/kg
ND
3.59
3.89
5.1J
4.7J
107
92
75-125
20
Cadmium
mg/kg
ND
.359
.389
ND
ND
88
76
75-125
20
Cobalt
mg/kg
17.2
3.59
3.89
23.3
35.9
166
487
75-125
43 20 M6,R1
Lead
mg/kg
7.6J
3.59
3.89
12.7
14.7
139
183
75-125
14 20 M6
Selenium
mg/kg
ND
3.59
3.89
6.OJ
5.9J
90
84
75-125
20
Thallium
mg/kg
ND
3.59
3.89
4.5J
4.6J
106
103
75-125
20
Vanadium
mg/kg
29.1
3.59
3.89
33.5
57.3
119
732
75-125
52 20 M6, R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/28/2015 01:02 PM without the written consent of Pace Analytical Services, Inc..
Page 67 of 87

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Project: J15040217
Pace Project No.: 92245094
QC Batch: MPRP/53618 Analysis Method: EPA 6020A
QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4
Associated Lab Samples: 92245094001, 92245094002
METHOD BLANK: 1938831
Associated Lab Samples: 92245094001, 92245094002
Parameter
Units
Aluminum
ug/L
Antimony
ug/L
Arsenic
ug/L
Barium
ug/L
Beryllium
ug/L
Boron
ug/L
Cadmium
ug/L
Calcium
ug/L
Chromium
ug/L
Cobalt
ug/L
Copper
ug/L
Iron
ug/L
Lead
ug/L
Magnesium
ug/L
Manganese
ug/L
Molybdenum
ug/L
Nickel
ug/L
Potassium
ug/L
Selenium
ug/L
Sodium
ug/L
Strontium
ug/L
Thallium
ug/L
Vanadium
ug/L
Zinc
ug/L
Matrix: Water
Blank
Result
Reporting
Limit
Analyzed
ND
10.0
04/15/1515:27
ND
0.50
04/15/1515:27
ND
0.50
04/15/1515:27
ND
0.30
04/15/1515:27
ND
0.20
04/15/1515:27
ND
5.0
04/15/1515:27
ND
0.080
04/15/1515:27
ND
40.0
04/15/1515:27
ND
0.50
04/15/1515:27
ND
0.50
04/15/1515:27
ND
1.0
04/15/1515:27
ND
50.0
04/15/1515:27
ND
0.10
04/15/1515:27
ND
10.0
04/15/1515:27
ND
0.50
04/15/1515:27
ND
0.50
04/15/1515:27
ND
0.50
04/15/1515:27
ND
50.0
04/15/1515:27
ND
0.50
04/15/1515:27
ND
50.0
04/15/1515:27
ND
0.50
04/15/1515:27
ND
0.10
04/15/1515:27
ND
1.0
04/15/1515:27
ND
5.0
04/15/1515:27
Qualifiers
Pace Analytical Services, Inc.
9800Air6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
Parameter
1938832
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
ug/L
80
82.5
103
80-120
Antimony
ug/L
80
75.0
94
80-120
Arsenic
ug/L
80
76.1
95
80-120
Barium
ug/L
80
78.4
98
80-120
Beryllium
ug/L
80
77.1
96
80-120
Boron
ug/L
80
80.0
100
80-120
Cadmium
ug/L
80
81.3
102
80-120
Calcium
ug/L
1000
1040
104
80-120
Chromium
ug/L
80
79.9
100
80-120
Cobalt
ug/L
80
78.4
98
80-120
Copper
ug/L
80
80.9
101
80-120
Iron
ug/L
1000
1030
103
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/28/2015 01:02 PM without the written consent of Pace Analytical Services, Inc..
Page 68 of 87

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800&6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
LABORATORY CONTROL SAMPLE:
1938832
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Lead
ug/L
80
79.1
99
80-120
Magnesium
ug/L
1000
991
99
80-120
Manganese
ug/L
80
81.6
102
80-120
Molybdenum
ug/L
80
77.9
97
80-120
Nickel
ug/L
80
78.7
98
80-120
Potassium
ug/L
1000
1010
101
80-120
Selenium
ug/L
80
79.1
99
80-120
Sodium
ug/L
1000
1020
102
80-120
Strontium
ug/L
80
78.1
98
80-120
Thallium
ug/L
80
80.1
100
80-120
Vanadium
ug/L
80
78.8
98
80-120
Zinc
ug/L
80
79.6
99
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1938833
1938834
MS
MSD
10302295001
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
Aluminum
ug/L
ND
80
80
93.5
89.0
111
105
75-125
5
20
Antimony
ug/L
ND
80
80
77.1
75.6
96
94
75-125
2
20
Arsenic
ug/L
3.4
80
80
80.9
79.3
97
95
75-125
2
20
Barium
ug/L
36.4
80
80
117
115
101
98
75-125
2
20
Beryllium
ug/L
ND
80
80
75.6
77.0
94
96
75-125
2
20
Boron
ug/L
25.0
80
80
101
108
95
103
75-125
7
20
Cadmium
ug/L
ND
80
80
83.7
83.1
105
104
75-125
1
20
Calcium
ug/L
43.4 mg/L
1000
1000
44800
44300
140
94
75-125
1
20 M1
Chromium
ug/L
ND
80
80
81.8
79.7
102
99
75-125
3
20
Cobalt
ug/L
ND
80
80
78.7
76.8
98
96
75-125
2
20
Copper
ug/L
ND
80
80
79.6
78.2
99
98
75-125
2
20
Iron
ug/L
273
1000
1000
1310
1280
104
100
75-125
2
20
Lead
ug/L
ND
80
80
79.2
77.1
99
96
75-125
3
20
Magnesium
ug/L
21.4 mg/L
1000
1000
23600
23700
225
235
75-125
0
20 M1
Manganese
ug/L
197
80
80
285
280
110
103
75-125
2
20
Molybdenum
ug/L
1.7
80
80
81.8
80.5
100
98
75-125
2
20
Nickel
ug/L
ND
80
80
78.2
76.6
98
95
75-125
2
20
Potassium
ug/L
1.5 mg/L
1000
1000
2540
2500
108
103
75-125
2
20
Selenium
ug/L
ND
80
80
78.2
78.7
98
98
75-125
1
20
Sodium
ug/L
7.4 mg/L
1000
1000
8440
8320
101
88
75-125
1
20
Strontium
ug/L
166
80
80
250
246
105
100
75-125
2
20
Thallium
ug/L
ND
80
80
80.4
78.0
101
98
75-125
3
20
Vanadium
ug/L
ND
80
80
80.8
79.0
101
98
75-125
2
20
Zinc
ug/L
ND
80
80
79.8
79.0
98
97
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/28/2015 01:02 PM without the written consent of Pace Analytical Services, Inc..
Page 69 of 87

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Project: J15040217
Pace Project No.: 92245094
QC Batch: MPRP/53815 Analysis Method: EPA 6020A
QC Batch Method: EPA 3020 Analysis Description: 6020A Water UPD4
Associated Lab Samples: 92245094003
METHOD BLANK: 1945264
Associated Lab Samples: 92245094003
Parameter
Units
Aluminum
ug/L
Antimony
ug/L
Arsenic
ug/L
Barium
ug/L
Beryllium
ug/L
Boron
ug/L
Cadmium
ug/L
Calcium
ug/L
Chromium
ug/L
Cobalt
ug/L
Copper
ug/L
Iron
ug/L
Lead
ug/L
Magnesium
ug/L
Manganese
ug/L
Molybdenum
ug/L
Nickel
ug/L
Potassium
ug/L
Selenium
ug/L
Sodium
ug/L
Strontium
ug/L
Thallium
ug/L
Vanadium
ug/L
Zinc
ug/L
Matrix: Water
Blank
Result
Reporting
Limit
Analyzed
4.7J
10.0
04/24/1511:23
ND
0.50
04/24/1511:23
ND
0.50
04/24/1511:23
ND
0.30
04/24/1511:23
ND
0.20
04/24/1511:23
ND
5.0
04/24/1511:23
ND
0.080
04/24/1511:23
ND
40.0
04/24/1511:23
ND
0.50
04/24/1511:23
ND
0.50
04/24/1511:23
ND
1.0
04/24/1511:23
ND
50.0
04/24/1511:23
ND
0.10
04/24/1511:23
4.2J
10.0
04/24/1511:23
0.67
0.50
04/24/1511:23
ND
0.50
04/24/1511:23
ND
0.50
04/24/1511:23
ND
50.0
04/24/1511:23
ND
0.50
04/24/1511:23
ND
50.0
04/24/1511:23
ND
0.50
04/24/1511:23
ND
0.10
04/24/1511:23
ND
1.0
04/24/1511:23
ND
5.0
04/24/1511:23
P8
Qualifiers
Pace Analytical Services, Inc.
980%�rpyoAje. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
Parameter
1945265
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
ug/L
80
89.9
112
80-120
Antimony
ug/L
80
82.0
102
80-120
Arsenic
ug/L
80
80.0
100
80-120
Barium
ug/L
80
82.2
103
80-120
Beryllium
ug/L
80
81.5
102
80-120
Boron
ug/L
80
84.7
106
80-120
Cadmium
ug/L
80
82.4
103
80-120
Calcium
ug/L
1000
991
99
80-120
Chromium
ug/L
80
81.7
102
80-120
Cobalt
ug/L
80
83.5
104
80-120
Copper
ug/L
80
82.1
103
80-120
Iron
ug/L
1000
1030
103
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J15040217
Pace Project No.: 92245094
LABORATORY CONTROL SAMPLE:
Parameter
1945265
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Lead
ug/L
80
78.2
98
80-120
Magnesium
ug/L
1000
1010
101
80-120
Manganese
ug/L
80
81.5
102
80-120
Molybdenum
ug/L
80
80.0
100
80-120
Nickel
ug/L
80
84.3
105
80-120
Potassium
ug/L
1000
1010
101
80-120
Selenium
ug/L
80
80.3
100
80-120
Sodium
ug/L
1000
1050
105
80-120
Strontium
ug/L
80
78.4
98
80-120
Thallium
ug/L
80
83.3
104
80-120
Vanadium
ug/L
80
79.6
100
80-120
Zinc
ug/L
80
82.9
104
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1945266 1945267
Pace Analytical Services, Inc.
980vr6fY04Je. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
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MS
MSD
10303182004
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Aluminum
ug/L
<59.6
80
80
ND
ND
108
86
75-125
20
Antimony
ug/L
<2.9
80
80
85.8
74.4
107
93
75-125
14
20
Arsenic
ug/L
<2.3
80
80
82.5
72.6
101
89
75-125
13
20
Barium
ug/L
7.8
80
80
93.2
79.4
107
90
75-125
16
20
Beryllium
ug/L
<1.3
80
80
84.0
70.8
105
89
75-125
17
20
Boron
ug/L
2730
80
80
3340
2940
760
267
75-125
13
20 M6
Cadmium
ug/L
<0.49
80
80
75.0
65.4
94
82
75-125
14
20
Calcium
ug/L
300000
1000
1000
316000
273000
1520
-2740
75-125
14
20 M6
Chromium
ug/L
<0.0034
80
80
85.4
74.1
105
90
75-125
14
20
mg/L
Cobalt
ug/L
3.5J
80
80
87.8
76.6
105
91
75-125
14
20
Copper
ug/L
0.0053J
80
80
84.4
72.0
99
83
75-125
16
20
mg/L
Iron
ug/L
0.63J
1000
1000
1700J
1480J
107
85
75-125
20
mg/L
Lead
ug/L
<0.00092
80
80
72.2
63.2
90
79
75-125
13
20
mg/L
Magnesium
ug/L
793000
1000
1000
978000
856000
18500
6270
75-125
13
20 M6
Manganese
ug/L
54.4
80
80
139
120
106
81
75-125
15
20
Molybdenum
ug/L
10.5
80
80
95.9
80.6
107
88
75-125
17
20
Nickel
ug/L
0.020
80
80
106
88.6
107
86
75-125
18
20
mg/L
Potassium
ug/L
289000
1000
1000
300000
264000
1070
-2520
75-125
13
20 M6
Selenium
ug/L
<4.0
80
80
85.8
68.9
106
85
75-125
22
20 R1
Sodium
ug/L
6790000
1000
1000
8250000
7260000
145000
46300
75-125
13
20 E,M6
Strontium
ug/L
4640
80
80
5540
4860
1120
278
75-125
13
20 M6
Thallium
ug/L
<0.31
80
80
79.9
68.4
100
85
75-125
16
20
Vanadium
ug/L
<5.6
80
80
90.0
81.5
110
99
75-125
10
20
Zinc
ug/L
<0.048
80
80
ND
ND
92
76
75-125
20
mg/L
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
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QUALITY CONTROL DATA
Pace Analytical Services, Inc.
980Vr6fY04Je. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
QC Batch: PMST/3452
Analysis Method:
ASTM D2974-87
QC Batch Method: ASTM D2974-87
Analysis Description:
Dry Weight/Percent Moisture
Associated Lab Samples: 92245094004,
92245094005, 92245094006, 92245094007,
92245094008, 92245094009,
92245094010,
92245094011,92245094012,92245094013
SAMPLE DUPLICATE: 1185592
35183639002
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
13.8
14.2 3
10
SAMPLE DUPLICATE: 1185593
92245092006
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
15.8
16.1 2
10
SAMPLE DUPLICATE: 1185594
92245094007
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
34.6
35.1 1
10
SAMPLE DUPLICATE: 1185595
92245118003
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
38.1
38.1 0
10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J15040217
Pace Project No.: 92245094
Pace Analytical Services, Inc.
9800�rpyoAje. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: WET/36839 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92245094004, 92245094005, 92245094006, 92245094007, 92245094008, 92245094009, 92245094010,
92245094011,92245094012,92245094013
SAMPLE DUPLICATE: 1434730
92245092011 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 6.0 6.0 0 10
SAMPLE DUPLICATE: 1434731
92245094013 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 7.5 7.5 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
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QUALITY CONTROL DATA
Pace Analytical Services, Inc.
980089r6fY04Je. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
QC Batch: WETA/22607
Analysis Method: EPA 300.0
QC Batch Method: EPA 300.0
Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92245094013
METHOD BLANK: 1437291
Matrix: Water
Associated Lab Samples: 92245094013
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Sulfate mg/L
3.1 2.0
04/19/1512:14
LABORATORY CONTROL SAMPLE: 1437292
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Sulfate mg/L
20 18.9
94 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1437293 1437294
MS MSD
92244130003
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Sulfate mg/L 275
22.7 22.7 294
295 83 85 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1437295 1437296
MS MSD
92245087001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate mg/L 4.0 26.6 26.6 26.5 26.2 85 83 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
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QUALITY CONTROL DATA
Pace Analytical Services, Inc.
980vr6fY04Je. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
QC Batch: WETA/22655
Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92245094013
METHOD BLANK: 1440999
Matrix: Water
Associated Lab Samples: 92245094013
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate mg/L
0.16 0.020
04/22/15 17:09 Z2
LABORATORY CONTROL SAMPLE: 1441000
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Nitrogen, Nitrate mg/L
2.5 2.5
101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1441001 1441002
MS MSD
92244130003
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L ND
2.8 2.8 3.1
3.1 104 104 90-110 0 10 H1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1441003 1441004
MS MSD
92244130004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate mg/L ND 2.9 2.9 3.1 3.1 100 100 90-110 0 10 H1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, Inc.
980mirpyoAje. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
QC Batch: WETA/22603
Analysis Method: SM 4500 -CI -E
QC Batch Method: SM 4500 -CI -E
Analysis Description: 4500 Chloride
Associated Lab Samples: 92245094013
METHOD BLANK: 1437036
Matrix: Water
Associated Lab Samples: 92245094013
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Chloride mg/L
ND 1.0
04/17/15 05:27
LABORATORY CONTROL SAMPLE: 1437037
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Chloride mg/L
20 20.3
101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1437038 1437039
MS MSD
92244130003
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L ND
22.7 22.7 23.0
23.4 101 102 90-110 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1437040 1437041
MS MSD
92244130004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride mg/L ND 23.2 23.2 23.9 23.5 103 101 90-110 2 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
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QUALITY CONTROL DATA
Project: J15040217
Pace Project No.: 92245094
Pace Analytical Services, Inc.
980C&6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: WETA/45407 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Associated Lab Samples: 92245094004, 92245094005, 92245094006, 92245094007, 92245094008, 92245094009, 92245094010,
92245094011,92245094012,92245094013
METHOD BLANK: 1183130 Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/kg ND 49.2 04/15/15 02:00
Sulfate mg/kg ND 49.2 04/15/15 02:00
LABORATORY CONTROL SAMPLE:
1183131
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
MATRIX SPIKE SAMPLE:
1183133
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
501 483 96 80-120
501 481 96 80-120
92245087001 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 675 623 75 80-120 M1
ND 675 638 94 80-120
SAMPLE DUPLICATE: 1183132
92245087001 Dup
Parameter Units Result Result
Chloride mg/kg ND ND
Sulfate mg/kg ND ND
Max
RPD RPD Qualifiers
20
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
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QUALITY CONTROL DATA
Pace Analytical Services, Inc.
98006r6fY04Je. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
QC Batch: WETA/45406
Analysis Method: EPA 9056
QC Batch Method: EPA 9056
Analysis Description: 9056 IC Anions
Associated Lab Samples: 92245094004, 92245094005, 92245094006, 92245094007, 92245094008, 92245094009, 92245094010,
92245094011,92245094012,92245094013
METHOD BLANK: 1183126
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Nitrate as N
mg/kg
ND 4.9 04/15/15 02:00
LABORATORY CONTROL SAMPLE:
1183127
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits Qualifiers
Nitrate as N
mg/kg
50.1 49.7 99
80-120
MATRIX SPIKE SAMPLE:
1183129
92245087001 Spike MS
MS % Rec
Parameter
Units
Result Conc. Result
% Rec Limits Qualifiers
Nitrate as N
mg/kg
ND 67.5 62.4
92 80-120 H3
SAMPLE DUPLICATE: 1183128
92245087001 Dup
Max
Parameter
Units
Result Result RPD
RPD Qualifiers
Nitrate as N
mg/kg
ND ND
20 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
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QUALITY CONTROL DATA
Pace Analytical Services, Inc.
980C�ir6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
QC Batch: WETA/28151
Analysis Method: EPA 9060
QC Batch Method: EPA 9060
Analysis Description: 9060 TOC Average
Associated Lab Samples: 92245094004, 92245094005,
92245094006, 92245094007, 92245094008
METHOD BLANK: 1145152
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Mean Total Organic Carbon mg/kg
ND 600 04/23/15 05:54
LABORATORY CONTROL SAMPLE: 1145153
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Mean Total Organic Carbon mg/kg
120000 120000 100 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1145154 1145155
MS MSD
92243924001
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 1600
7540 7530 9560 9110 106 100 50-150 5 30
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1145156 1145157
MS MSD
92244371001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 62300 286000 280000 332000 328000 94 95 50-150 1 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
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QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800AirpyoAle. Suite 100
Huntersville, NC 28078
[phone]
Project: J15040217
Pace Project No.: 92245094
QC Batch: WETA/28177
Analysis Method: EPA 9060
QC Batch Method: EPA 9060
Analysis Description: 9060 TOC Average
Associated Lab Samples: 92245094009, 92245094010,
92245094011, 92245094012, 92245094013
METHOD BLANK: 1146317
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Mean Total Organic Carbon mg/kg
ND 600 04/27/15 08:23
LABORATORY CONTROL SAMPLE: 1146318
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Mean Total Organic Carbon mg/kg
120000 125000 104 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1146319 1146320
MS MSD
92245086007
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 538J
8770 8830 8890 9840 95 105 50-150 10 30
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1146321 1146322
MS MSD
92245086008 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 54200 65100 65300 131000 152000 117 150 50-150 15 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALIFIERS
Project: J15040217
Pace Project No.: 92245094
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
Pace Analytical Services, Inc.
9800AirpyoAle. Suite 100
Huntersville, NC 28078
[phone]
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A
Pace Analytical Services - Asheville
PASI-G
Pace Analytical Services - Green Bay
PASI-M
Pace Analytical Services - Minneapolis
PASI-O
Pace Analytical Services - Ormond Beach
BATCH QUALIFIERS
Batch: ICPM/9617
[1] Batch was diluted due to the presence of high levels of non -target analytes or other matrix interference.
Batch: ICP/14455
[1j Samples in this batch were diluted due to the presence of high levels of non -target analytes or other matrix interference,
unless otherwise flagged.
Batch: ICPM/9631
[1] Batch was diluted due to the presence of high levels of non -target analytes or other matrix interference.
ANALYTE QUALIFIERS
B Analyte was detected in the associated method blank.
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
D4 Sample was diluted due to the presence of high levels of target analytes.
E Analyte concentration exceeded the calibration range. The reported result is estimated.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/28/2015 01:02 PM without the written consent of Pace Analytical Services, Inc.. Page 81 of 87

aceAnaiXical
www.pacelabs.com
QUALIFIERS
Project: J15040217
Pace Project No.: 92245094
ANALYTE QUALIFIERS
Pace Analytical Services, Inc.
9800*r6fy0AJe. Suite 100
Huntersville, INC 28078
[phone]
H1 Analysis conducted outside the EPA method holding time.
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
N2 The lab does not hold TNI accreditation for this parameter.
P8 Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than
the blank or were below the reporting limit.
R1 RPD value was outside control limits.
Z2 Analyte present in the associated method blank above the detection limit.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/28/2015 01:02 PM without the written consent of Pace Analytical Services, Inc.. Page 82 of 87

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, Inc.
9800AirpyoAle. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
J15040217
92245094
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92245094004
2015010113
EPA 3050
MPRP/23656
EPA 6010
ICP/14455
92245094005
2015010115
EPA 3050
MPRP/23656
EPA 6010
ICP/14455
92245094006
2015010116
EPA 3050
MPRP/23656
EPA 6010
ICP/14455
92245094007
2015010117
EPA 3050
MPRP/23656
EPA 6010
ICP/14455
92245094008
2015010118
EPA 3050
MPRP/23656
EPA 6010
ICP/14455
92245094009
2015010119
EPA 3050
MPRP/23656
EPA6010
ICP/14455
92245094010
2015010121
EPA 3050
MPRP/23656
EPA6010
ICP/14455
92245094011
2015010122
EPA 3050
MPRP/23696
EPA6010
ICP/14483
92245094012
2015010123
EPA 3050
MPRP/23696
EPA6010
ICP/14483
92245094013
2015010120
EPA 3050
MPRP/23696
EPA 6010
ICP/14483
92245094004
2015010113
EPA 3050
MPRP/23657
EPA 6020
ICPM/9617
92245094005
2015010115
EPA 3050
MPRP/23657
EPA 6020
ICPM/9617
92245094006
2015010116
EPA 3050
MPRP/23657
EPA 6020
ICPM/9617
92245094007
2015010117
EPA 3050
MPRP/23657
EPA 6020
ICPM/9617
92245094008
2015010118
EPA 3050
MPRP/23657
EPA 6020
ICPM/9617
92245094009
2015010119
EPA 3050
MPRP/23657
EPA 6020
ICPM/9617
92245094010
2015010121
EPA 3050
MPRP/23657
EPA 6020
ICPM/9617
92245094011
2015010122
EPA 3050
MPRP/23697
EPA 6020
ICPM/9631
92245094012
2015010123
EPA 3050
MPRP/23697
EPA 6020
ICPM/9631
92245094013
2015010120
EPA 3050
MPRP/23697
EPA 6020
ICPM/9631
92245094001
2015010112
EPA 3020
MPRP/53618
EPA 6020A
ICPM/23802
92245094002
2015010114
EPA 3020
MPRP/53618
EPA 6020A
ICPM/23802
92245094003
2015010120 SPLP
EPA 3020
MPRP/53815
EPA 6020A
ICPM/23916
92245094001
2015010112
EPA 7470
MERP/13223
EPA 7470
MERC/15377
92245094002
2015010114
EPA 7470
MERP/13223
EPA 7470
MERC/15377
92245094003
2015010120 SPLP
EPA 7470A
MERP/13312
EPA 7470A
MERC/15482
92245094004
2015010113
EPA 7471
MERP/5597
EPA 7471
MERC/5585
92245094005
2015010115
EPA 7471
MERP/5597
EPA 7471
MERC/5585
92245094006
2015010116
EPA 7471
MERP/5597
EPA 7471
MERC/5585
92245094007
2015010117
EPA 7471
MERP/5597
EPA 7471
MERC/5585
92245094008
2015010118
EPA 7471
MERP/5597
EPA 7471
MERC/5585
92245094009
2015010119
EPA 7471
MERP/5597
EPA 7471
MERC/5585
92245094010
2015010121
EPA 7471
MERP/5597
EPA 7471
MERC/5585
92245094011
2015010122
EPA 7471
MERP/5604
EPA 7471
MERC/5594
92245094012
2015010123
EPA 7471
MERP/5604
EPA 7471
MERC/5594
92245094013
2015010120
EPA 7471
MERP/5604
EPA 7471
MERC/5594
92245094004
2015010113
ASTM D2974-87
PMST/3452
92245094005
2015010115
ASTM D2974-87
PMST/3452
92245094006
2015010116
ASTM D2974-87
PMST/3452
92245094007
2015010117
ASTM D2974-87
PMST/3452
92245094008
2015010118
ASTM D2974-87
PMST/3452
92245094009
2015010119
ASTM D2974-87
PMST/3452
92245094010
2015010121
ASTM D2974-87
PMST/3452
92245094011
2015010122
ASTM D2974-87
PMST/3452
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/28/2015 01:02 PM without the written consent of Pace Analytical Services, Inc.. Page 83 of 87

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15040217
Pace Project No.: 92245094
Lab ID Sample ID QC Batch Method QC Batch
92245094012
2015010123
ASTM D2974-87
PMST/3452
92245094013
2015010120
ASTM D2974-87
PMST/3452
92245094004
2015010113
EPA 9045
WET/36839
92245094005
2015010115
EPA 9045
WET/36839
92245094006
2015010116
EPA 9045
WET/36839
92245094007
2015010117
EPA 9045
WET/36839
92245094008
2015010118
EPA 9045
WET/36839
92245094009
2015010119
EPA 9045
WET/36839
92245094010
2015010121
EPA 9045
WET/36839
92245094011
2015010122
EPA 9045
WET/36839
92245094012
2015010123
EPA 9045
WET/36839
92245094013
2015010120
EPA 9045
WET/36839
92245094013
2015010120
EPA 300.0
WETA/22607
92245094013
2015010120
EPA 353.2
WETA/22655
92245094013
2015010120
SM 4500 -CI -E
WETA/22603
92245094004
2015010113
EPA 9056
WETA/45407
92245094005
2015010115
EPA 9056
WETA/45407
92245094006
2015010116
EPA 9056
WETA/45407
92245094007
2015010117
EPA 9056
WETA/45407
92245094008
2015010118
EPA 9056
WETA/45407
92245094009
2015010119
EPA 9056
WETA/45407
92245094010
2015010121
EPA 9056
WETA/45407
92245094011
2015010122
EPA 9056
WETA/45407
92245094012
2015010123
EPA 9056
WETA/45407
92245094013
2015010120
EPA 9056
WETA/45407
92245094004
2015010113
EPA 9056
WETA/45406
92245094005
2015010115
EPA 9056
WETA/45406
92245094006
2015010116
EPA 9056
WETA/45406
92245094007
2015010117
EPA 9056
WETA/45406
92245094008
2015010118
EPA 9056
WETA/45406
92245094009
2015010119
EPA 9056
WETA/45406
92245094010
2015010121
EPA 9056
WETA/45406
92245094011
2015010122
EPA 9056
WETA/45406
92245094012
2015010123
EPA 9056
WETA/45406
92245094013
2015010120
EPA 9056
WETA/45406
92245094004
2015010113
EPA 9060 WETA/28151
92245094004
2015010113
EPA 9060 WETA/28152
92245094005
2015010115
EPA 9060 WETA/28151
92245094005
2015010115
EPA 9060 WETA/28152
92245094006
2015010116
EPA 9060 WETA/28151
92245094006
2015010116
EPA 9060 WETA/28152
92245094007
2015010117
EPA 9060 WETA/28151
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/28/2015 01:02
PM
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800q6r6fy0AJe. Suite 100
Huntersville, NC 28078
[phone]
Analytical
Analytical Method Batch
Page 84 of 87

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15040217
Pace Project No.: 92245094
Lab ID
Sample ID
QC Batch Method
QC Batch
92245094007
2015010117
EPA
9060
WETA/28152
92245094008
2015010118
EPA
9060
WETA/28151
92245094008
2015010118
EPA
9060
WETA/28152
92245094009
2015010119
EPA
9060
WETA/28177
92245094009
2015010119
EPA
9060
WETA/28179
92245094010
2015010121
EPA
9060
WETA/28177
92245094010
2015010121
EPA
9060
WETA/28179
92245094011
2015010122
EPA
9060
WETA/28177
92245094011
2015010122
EPA
9060
WETA/28179
92245094012
2015010123
EPA
9060
WETA/28177
92245094012
2015010123
EPA
9060
WETA/28179
92245094013
2015010120
EPA
9060
WETA/28177
92245094013
2015010120
EPA
9060
WETA/28179
Date: 04/28/2015 01:02 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
980MIr6fY04Je. Suite 100
Huntersville, NC 28078
[phone]
Analytical Method
Analytical
Batch
Page 85 of 87

Document Name: Document Revised: September 22. ZU14
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Sample Condition Upon Receipt SCUR Pae 1 of 2
1- Document Number: Issuing Auth YQ
f F-CHR-CS-003-rev.15 Pace Huntersville Quality Office
Client Name: PLA � C- f'�1t4;1,
Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client❑mmercial❑ a Other
Custody Seal on Cooler/Box Present: ❑ yes ❑ no Seals intact: ❑ yes ❑ no
Packing Material: ❑ Bubble VDD ) Bubble Bags ❑ None ❑ Other
Thermometer Used: IR Gun 140 Type of ice: a Blue None Samples on ice, cooling process has begun
Temp Correction Factor T1401 No Correction
Date and Initials of erso examining
Temp.: A
Corrected Cooler Tem •C Biological Tissue is Frozen: Yes No contents:_14
Temp should be above freezing to 6°C Comments:
Chain of Custody Present: E res o ❑NIA 1.
Chain of Custody Filled Out: Yes ❑ ❑NIA 2.
Chain of Custody Relinquished: s ❑N NIA 3.
Sampler Name & Signature on COC:
t1&sif- UN
UN/A 4.
Samples Arrived within Hold Time:
es ❑No
5.
Short Hold Time Analysis (<72hr):
❑Yes 3<
A 6.
Rush Turn Around Time Requested:
[]Yes 9C
❑NIA 7.
Sufficient Volume:
Ex"'—Ilwo
❑NIA 8.
Correct Containers Used:
Yes ❑No
9.
-Pace Containers Used:
❑Yes
❑NIA
Containers Intact:
Ele, ❑No
❑NIA 1 .
Filtered volume received for Dissolved tests
❑Yes ❑❑N!A
11.
Sample Labels match COC:
-es CINo
❑NIA 12.
-Includes dateltimellDlAnalysis Matrix:
All containers needing preservation have been checked.
❑ es ❑No
❑NIA 13.
All containers needing preservation are found to be in
"e,No
❑NIA
compliance with EPA recommendation.
exceptions: VOA, coliform, TOC, 0&G, W -DRO (water)
Dyes LtNo
Samples checked for dechlorination:
❑Yes ❑No
❑ rA
Headspace in VOA Vials >6mm :
DYes ❑No
IA 15.
Trip Blank Present: ❑Yes ❑No IA110.
Trip Blank Custody Seals Present ❑Yes ❑No IA
Pace Trip Blank Lot ## (if purchased):
Client Notification/ Resolution: f=ield Data Required? Y 1 N
Person Contacted: Date/time:
Comments/ Resolution:
SCURF Review:1 PtK jDate: I ljl(III,
SRF Review: k L/V Date: I,>
Note: Whenever there is a discrepancy affecting North Carolina compliance
samples, a copy of this form will be sent to the North Carolina DEHNR
Certification Office ( Le out of hold, incorrect preservative, out of temp,
incorrect containers)
wo#:92245094
92245094iimixuuii
Page 86 of 87

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