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Home My WebLink AboutNC0000396_J15040126 Surface Seep report_20150823DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Order Number: J15040126 Project Name: AB GW ASSESSMENT WATER Customer Name(s): Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker Customer Address: 200 CP and L Drive Arden,NC 28704 Lab Contact: Mary Ann Ogle Phone: 980-875-5274 Mary Ann Ogle Report Authorized By: % " lj �b ✓ 2015.04.23 13:28:17 Date: (Signature) -04'00' Mary Ann Ogle Program Comments: Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report. Data Flags & Calculations: 4/23/2015 Page 1 of 62 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015009715 ASHEVILLE 06 -Apr -15 12:05 PM Matt Huddleston M-01 2015009719 ASHEVILLE 06 -Apr -15 11:45 AM Matt Huddleston K-01 2015009720 ASHEVILLE 06 -Apr -15 12:55 PM Matt Huddleston C-02 2015009721 ASHEVILLE 06 -Apr -15 1:45 PM Matt Huddleston SW -05 2015009722 ASHEVILLE 06 -Apr -15 1:56 PM Matt Huddleston SW -05 Dup 2015009723 ASHEVILLE 06 -Apr -15 1:33 PM Matt Huddleston FIELD BLANK 6 Total Samples Page 2 of 62 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes No All laboratory QA/QC requirements are acceptable. (] Yes ❑ No Report Sections Included: LU Job Summary Report ❑ Sample Identification P/1 Technical Validation of Data Package J❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Page 3 of 62 LVI Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries d❑ Chain of Custody LVI Electronic Data Deliverable (EDD) Sent Separately Reviewed By: DBA Account Date: 4/23/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040126 Site: M-01 Collection Date: 06 -Apr -15 12:05 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) EPA 353.2 Vendor Parameter Complete 20 EPA 300.0 NITRITE + NITRATE (COLORIMETRIC) JAHERMA 20 Nitrite + Nitrate (Colorimetric) 1.5 mg-N/L 0.01 INORGANIC IONS BY IC V_SHEALY 1 Chloride 13 mg/L 2 Sulfate 170 mg/L 2 MERCURY IN WATER - (Analysis Performed by Shealy Labs) MHALL3 Vendor Parameter Complete 04/08/2015 12:08 MHALL3 DISSOLVED METALS BY ICP EPA 200.7 04/08/2015 12:08 MHALL3 Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) 0.039 mg/L 0.005 Boron (B) 0.855 mg/L 0.05 Iron (Fe) 0.016 mg/L 0.01 Manganese (Mn) 0.050 mg/L 0.005 Strontium (Sr) 0.351 mg/L 0.005 Zinc (Zn) 0.108 mg/L 0.005 UNDIGESTED METALS BY ICP EPA 200.7 04/08/2015 15:36 MHALL3 Calcium (Ca) 38.0 mg/L 0.01 Magnesium (Mg) 12.8 mg/L 0.005 Potassium (K) 4.23 mg/L 0.1 Sodium (Na) 17.9 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP EPA 200.7 04/08/2015 15:36 Aluminum (AI) 0.026 mg/L 0.005 Barium (Ba) 0.044 mg/L 0.005 Boron (B) 0.775 mg/L 0.05 Iron (Fe) 0.145 mg/L 0.01 Manganese (Mn) 0.135 mg/L 0.005 Strontium (Sr) 0.297 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Page 4 of 62 Sample #: 2015009715 Matrix: GW -WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 04/15/2015 09:19 BGN9034 20 EPA 300.0 04/09/2015 14:15 JAHERMA 20 EPA 300.0 04/09/2015 14:15 JAHERMA Vendor Method V_SHEALY 1 EPA 200.7 04/08/2015 12:08 MHALL3 1 EPA 200.7 04/08/2015 12:08 MHALL3 1 EPA 200.7 04/08/2015 12:08 MHALL3 1 EPA 200.7 04/08/2015 12:08 MHALL3 1 EPA 200.7 04/08/2015 12:08 MHALL3 1 EPA 200.7 04/08/2015 12:08 MHALL3 1 EPA 200.7 04/08/2015 12:08 MHALL3 1 EPA 200.7 04/08/2015 13:16 MHALL3 1 EPA 200.7 04/08/2015 13:16 MHALL3 1 EPA 200.7 04/08/2015 13:16 MHALL3 1 EPA 200.7 04/08/2015 13:16 MHALL3 1 EPA 200.7 04/08/2015 15:36 MHALL3 1 EPA 200.7 04/08/2015 15:36 MHALL3 1 EPA 200.7 04/08/2015 15:36 MHALL3 1 EPA 200.7 04/08/2015 15:36 MHALL3 1 EPA 200.7 04/08/2015 15:36 MHALL3 1 EPA 200.7 04/08/2015 15:36 MHALL3 1 EPA 200.7 04/08/2015 15:36 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040126 Site: M-01 Collection Date: 06 -Apr -15 12:05 PM Analyte Result DISSOLVED METALS BY ICP -MS Sample #: Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) < 1 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 1.75 Selenium (Se) 2.37 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) <1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) < 1 Copper (Cu) <1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 2.15 Selenium (Se) 2.25 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS ug/L TDS 280 Total Carbon 04/20/2015 13:01 TOC 0.666 TOTAL SUSPENDED SOLIDS 1 TSS < 5 Page 5 of 62 ug/L 1 1 Sample #: 2015009715 DJSULL1 ug/L 1 1 Matrix: GW -WW DJSULL1 Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 04/20/2015 13:01 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:01 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:01 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:01 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:01 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:01 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:01 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:01 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:01 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:01 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:01 DJSULL1 ug/L 0.2 1 EPA 200.8 04/20/2015 13:01 DJSULL1 ug/L 0.3 1 EPA 200.8 04/20/2015 13:01 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:22 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:22 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:22 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:22 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:22 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:22 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:22 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:22 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:22 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:22 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:22 DJSULL1 ug/L 0.2 1 EPA 200.8 04/19/2015 14:22 DJSULL1 ug/L 0.3 1 EPA 200.8 04/19/2015 14:22 DJSULL1 Vendor Method V SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 04/09/2015 02:27 AGIBBS5 mg/L 0.1 1 SM5310C/EPA9060A 04/14/201516:23 GHUTCHI mg/L 5 1 SM2540D 04/08/2015 09:44 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040126 Site: K-01 Collection Date: 06 -Apr -15 11:45 AM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) EPA 353.2 Vendor Parameter Complete 20 EPA 300.0 NITRITE + NITRATE (COLORIMETRIC) JAHERMA 20 Nitrite + Nitrate (Colorimetric) 0.110 mg-N/L 0.01 INORGANIC IONS BY IC V_SHEALY 1 Chloride 13 mg/L 2 Sulfate 140 mg/L 2 MERCURY IN WATER - (Analysis Performed by Shealy Labs) MHALL3 Vendor Parameter Complete 04/08/2015 11:49 MHALL3 DISSOLVED METALS BY ICP EPA 200.7 04/08/2015 11:49 MHALL3 Aluminum (AI) 0.016 mg/L 0.005 Barium (Ba) 0.047 mg/L 0.005 Boron (B) 0.991 mg/L 0.05 Iron (Fe) 0.153 mg/L 0.01 Manganese (Mn) 0.630 mg/L 0.005 Strontium (Sr) 0.272 mg/L 0.005 Zinc (Zn) 0.007 mg/L 0.005 UNDIGESTED METALS BY ICP EPA 200.7 04/08/2015 15:24 MHALL3 Calcium (Ca) 30.0 mg/L 0.01 Magnesium (Mg) 11.0 mg/L 0.005 Potassium (K) 2.28 mg/L 0.1 Sodium (Na) 16.6 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP EPA 200.7 04/08/2015 15:24 Aluminum (AI) 0.117 mg/L 0.005 Barium (Ba) 0.047 mg/L 0.005 Boron (B) 0.967 mg/L 0.05 Iron (Fe) 0.356 mg/L 0.01 Manganese (Mn) 0.618 mg/L 0.005 Strontium (Sr) 0.268 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Page 6 of 62 Sample #: 2015009719 Matrix: GW -WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 04/15/2015 09:20 BGN9034 20 EPA 300.0 04/09/2015 14:34 JAHERMA 20 EPA 300.0 04/09/2015 14:34 JAHERMA Vendor Method V_SHEALY 1 EPA 200.7 04/08/2015 11:49 MHALL3 1 EPA 200.7 04/08/2015 11:49 MHALL3 1 EPA 200.7 04/08/2015 11:49 MHALL3 1 EPA 200.7 04/08/2015 11:49 MHALL3 1 EPA 200.7 04/08/2015 11:49 MHALL3 1 EPA 200.7 04/08/2015 11:49 MHALL3 1 EPA 200.7 04/08/2015 11:49 MHALL3 1 EPA 200.7 04/08/2015 13:13 MHALL3 1 EPA 200.7 04/08/2015 13:13 MHALL3 1 EPA 200.7 04/08/2015 13:13 MHALL3 1 EPA 200.7 04/08/2015 13:13 MHALL3 1 EPA 200.7 04/08/2015 15:24 MHALL3 1 EPA 200.7 04/08/2015 15:24 MHALL3 1 EPA 200.7 04/08/2015 15:24 MHALL3 1 EPA 200.7 04/08/2015 15:24 MHALL3 1 EPA 200.7 04/08/2015 15:24 MHALL3 1 EPA 200.7 04/08/2015 15:24 MHALL3 1 EPA 200.7 04/08/2015 15:24 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040126 Site: K-01 Collection Date: 06 -Apr -15 11:45 AM Analyte Result DISSOLVED METALS BY ICP -MS Sample #: Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 1.45 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) < 1 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) <1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 1.41 Copper (Cu) <1 Lead (Pb) < 1 Molybdenum (Mo) < 1 Nickel (Ni) 1.02 Selenium (Se) < 1 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level 0.343 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS ug/L TDS 250 Total Carbon 04/20/2015 13:06 TOC 0.935 TOTAL SUSPENDED SOLIDS 1 TSS < 5 Page 7 of 62 ug/L 1 1 Sample #: 2015009719 DJSULL1 ug/L 1 1 Matrix: GW -WW DJSULL1 Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 04/20/2015 13:06 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:06 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:06 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:06 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:06 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:06 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:06 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:06 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:06 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:06 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:06 DJSULL1 ug/L 0.2 1 EPA 200.8 04/20/2015 13:06 DJSULL1 ug/L 0.3 1 EPA 200.8 04/20/2015 13:06 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:36 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:36 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:36 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:36 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:36 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:36 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:36 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:36 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:36 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:36 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:36 DJSULL1 ug/L 0.2 1 EPA 200.8 04/19/2015 14:36 DJSULL1 ug/L 0.3 1 EPA 200.8 04/19/2015 14:36 DJSULL1 Vendor Method V SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 04/09/2015 02:27 AGIBBS5 mg/L 0.1 1 SM5310C/EPA9060A 04/14/201516:23 GHUTCHI mg/L 5 1 SM2540D 04/08/2015 09:44 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040126 Site: C-02 Collection Date: 06 -Apr -15 12:55 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) EPA 353.2 Vendor Parameter Complete 20 EPA 300.0 NITRITE + NITRATE (COLORIMETRIC) JAHERMA 100 Nitrite + Nitrate (Colorimetric) 0.225 mg-N/L 0.01 INORGANIC IONS BY IC V_SHEALY 1 Chloride 130 mg/L 2 Sulfate 400 mg/L 10 MERCURY IN WATER - (Analysis Performed by Shealy Labs) MHALL3 Vendor Parameter Complete 04/08/2015 11:53 MHALL3 DISSOLVED METALS BY ICP EPA 200.7 04/08/2015 11:53 MHALL3 Aluminum (AI) 0.007 mg/L 0.005 Barium (Ba) 0.040 mg/L 0.005 Boron (B) 1.88 mg/L 0.05 Iron (Fe) 0.042 mg/L 0.01 Manganese (Mn) 8.47 mg/L 0.005 Strontium (Sr) 2.13 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 UNDIGESTED METALS BY ICP EPA 200.7 04/08/2015 15:40 MHALL3 Calcium (Ca) 164 mg/L 0.1 Magnesium (Mg) 41.1 mg/L 0.005 Potassium (K) 7.78 mg/L 0.1 Sodium (Na) 22.7 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP EPA 200.7 04/08/2015 15:40 Aluminum (AI) 0.137 mg/L 0.005 Barium (Ba) 0.044 mg/L 0.005 Boron (B) 1.86 mg/L 0.05 Iron (Fe) 0.308 mg/L 0.01 Manganese (Mn) 8.39 mg/L 0.005 Strontium (Sr) 2.15 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Page 8 of 62 Sample #: 2015009720 Matrix: GW -WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 04/15/2015 09:21 BGN9034 20 EPA 300.0 04/09/2015 14:54 JAHERMA 100 EPA 300.0 04/09/2015 14:54 JAHERMA Vendor Method V_SHEALY 1 EPA 200.7 04/08/2015 11:53 MHALL3 1 EPA 200.7 04/08/2015 11:53 MHALL3 1 EPA 200.7 04/08/2015 11:53 MHALL3 1 EPA 200.7 04/08/2015 11:53 MHALL3 1 EPA 200.7 04/08/2015 11:53 MHALL3 1 EPA 200.7 04/08/2015 11:53 MHALL3 1 EPA 200.7 04/08/2015 11:53 MHALL3 10 EPA 200.7 04/08/2015 13:24 MHALL3 1 EPA 200.7 04/08/2015 13:24 MHALL3 1 EPA 200.7 04/08/2015 13:24 MHALL3 1 EPA 200.7 04/08/2015 13:24 MHALL3 1 EPA 200.7 04/08/2015 15:40 MHALL3 1 EPA 200.7 04/08/2015 15:40 MHALL3 1 EPA 200.7 04/08/2015 15:40 MHALL3 1 EPA 200.7 04/08/2015 15:40 MHALL3 1 EPA 200.7 04/08/2015 15:40 MHALL3 1 EPA 200.7 04/08/2015 15:40 MHALL3 1 EPA 200.7 04/08/2015 15:40 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040126 Site: C-02 Collection Date: 06 -Apr -15 12:55 PM Analyte Result DISSOLVED METALS BY ICP -MS Sample #: Antimony (Sb) < 1 Arsenic (As) < 1 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 22.2 Copper (Cu) < 1 Lead (Pb) < 1 Molybdenum (Mo) 133 Nickel (Ni) 12.3 Selenium (Se) 2.87 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level < 0.3 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) <1 Arsenic (As) 2.02 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) < 1 Cobalt (Co) 21.7 Copper (Cu) <1 Lead (Pb) < 1 Molybdenum (Mo) 133 Nickel (Ni) 12.4 Selenium (Se) 2.56 Thallium (TI) Low Level < 0.2 Vanadium (V) Low Level 1.26 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS ug/L TDS 920 Total Carbon 04/20/2015 13:10 TOC 0.535 TOTAL SUSPENDED SOLIDS 1 TSS 6.0 Page 9 of 62 ug/L 1 1 Sample #: 2015009720 DJSULL1 ug/L 1 1 Matrix: GW -WW DJSULL1 Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 04/20/2015 13:10 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:10 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:10 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:10 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:10 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:10 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:10 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:10 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:10 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:10 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:10 DJSULL1 ug/L 0.2 1 EPA 200.8 04/20/2015 13:10 DJSULL1 ug/L 0.3 1 EPA 200.8 04/20/2015 13:10 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:40 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:40 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:40 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:40 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:40 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:40 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:40 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:40 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:40 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:40 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:40 DJSULL1 ug/L 0.2 1 EPA 200.8 04/19/2015 14:40 DJSULL1 ug/L 0.3 1 EPA 200.8 04/19/2015 14:40 DJSULL1 Vendor Method V SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 04/09/2015 02:27 AGIBBS5 mg/L 0.1 1 SM5310C/EPA9060A 04/14/201516:23 GHUTCHI mg/L 5 1 SM2540D 04/08/2015 09:44 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040126 Site: SW -05 Collection Date: 06 -Apr -15 1:45 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) EPA 353.2 Vendor Parameter Complete 20 EPA 300.0 NITRITE + NITRATE (COLORIMETRIC) JAHERMA 20 Nitrite + Nitrate (Colorimetric) 0.986 mg-N/L 0.01 INORGANIC IONS BY IC V_SHEALY 1 Chloride 13 mg/L 2 Sulfate 170 mg/L 2 MERCURY IN WATER - (Analysis Performed by Shealy Labs) MHALL3 Vendor Parameter Complete 04/08/2015 11:42 MHALL3 DISSOLVED METALS BY ICP EPA 200.7 04/08/2015 11:42 MHALL3 Aluminum (AI) 0.272 mg/L 0.005 Barium (Ba) 0.225 mg/L 0.005 Boron (B) 1.15 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.130 mg/L 0.005 Strontium (Sr) 0.385 mg/L 0.005 Zinc (Zn) 0.065 mg/L 0.005 UNDIGESTED METALS BY ICP EPA 200.7 04/08/2015 15:43 MHALL3 Calcium (Ca) 64.1 mg/L 0.01 Magnesium (Mg) 4.14 mg/L 0.005 Potassium (K) 10.9 mg/L 0.1 Sodium (Na) 10.9 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP EPA 200.7 04/08/2015 15:43 Aluminum (AI) 3.18 mg/L 0.005 Barium (Ba) 0.280 mg/L 0.005 Boron (B) 1.18 mg/L 0.05 Iron (Fe) 1.52 mg/L 0.01 Manganese (Mn) 0.716 mg/L 0.005 Strontium (Sr) 0.416 mg/L 0.005 Zinc (Zn) 0.037 mg/L 0.005 Page 10 of 62 Sample #: 2015009721 Matrix: GW -WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 04/15/2015 09:22 BGN9034 20 EPA 300.0 04/09/2015 15:13 JAHERMA 20 EPA 300.0 04/09/2015 15:13 JAHERMA Vendor Method V_SHEALY 1 EPA 200.7 04/08/2015 11:42 MHALL3 1 EPA 200.7 04/08/2015 11:42 MHALL3 1 EPA 200.7 04/08/2015 11:42 MHALL3 1 EPA 200.7 04/08/2015 11:42 MHALL3 1 EPA 200.7 04/08/2015 11:42 MHALL3 1 EPA 200.7 04/08/2015 11:42 MHALL3 1 EPA 200.7 04/08/2015 11:42 MHALL3 1 EPA 200.7 04/08/2015 13:01 MHALL3 1 EPA 200.7 04/08/2015 13:01 MHALL3 1 EPA 200.7 04/08/2015 13:01 MHALL3 1 EPA 200.7 04/08/2015 13:01 MHALL3 1 EPA 200.7 04/08/2015 15:43 MHALL3 1 EPA 200.7 04/08/2015 15:43 MHALL3 1 EPA 200.7 04/08/2015 15:43 MHALL3 1 EPA 200.7 04/08/2015 15:43 MHALL3 1 EPA 200.7 04/08/2015 15:43 MHALL3 1 EPA 200.7 04/08/2015 15:43 MHALL3 1 EPA 200.7 04/08/2015 15:43 MHALL3 Certificate of Laboratory Analysis Page 11 of 62 This report shall not be reproduced, except in full. Order # J15040126 Site: SW -05 Sample #: 2015009721 Collection Date: 06 -Apr -15 1:45 PM Matrix: GW -WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DISSOLVED METALS BY ICP -MS Antimony (Sb) 6.47 ug/L 1 1 EPA 200.8 04/20/2015 13:28 DJSULL1 Arsenic (As) 50.6 ug/L 1 1 EPA 200.8 04/20/2015 13:28 DJSULL1 Beryllium (Be) < 1 ug/L 1 1 EPA 200.8 04/20/2015 13:28 DJSULL1 Cadmium (Cd) < 1 ug/L 1 1 EPA 200.8 04/20/2015 13:28 DJSULL1 Chromium (Cr) 8.98 ug/L 1 1 EPA 200.8 04/20/2015 13:28 DJSULL1 Cobalt (Co) 4.90 ug/L 1 1 EPA 200.8 04/20/2015 13:28 DJSULL1 Copper (Cu) 1.57 ug/L 1 1 EPA 200.8 04/20/2015 13:28 DJSULL1 Lead (Pb) < 1 ug/L 1 1 EPA 200.8 04/20/2015 13:28 DJSULL1 Molybdenum (Mo) 94.0 ug/L 1 1 EPA 200.8 04/20/2015 13:28 DJSULL1 Nickel (Ni) 9.26 ug/L 1 1 EPA 200.8 04/20/2015 13:28 DJSULL1 Selenium (Se) 24.8 ug/L 1 1 EPA 200.8 04/20/2015 13:28 DJSULL1 Thallium (TI) Low Level 0.572 ug/L 0.2 1 EPA 200.8 04/20/2015 13:28 DJSULL1 Vanadium (V) Low Level 29.2 ug/L 0.3 1 EPA 200.8 04/20/2015 13:28 DJSULL1 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) 7.11 ug/L 1 1 EPA 200.8 04/19/2015 14:45 DJSULL1 Arsenic (As) 81.1 ug/L 1 1 EPA 200.8 04/19/2015 14:45 DJSULL1 Beryllium (Be) < 1 ug/L 1 1 EPA 200.8 04/19/2015 14:45 DJSULL1 Cadmium (Cd) < 1 ug/L 1 1 EPA 200.8 04/19/2015 14:45 DJSULL1 Chromium (Cr) 11.2 ug/L 1 1 EPA 200.8 04/19/2015 14:45 DJSULL1 Cobalt (Co) 8.37 ug/L 1 1 EPA 200.8 04/19/2015 14:45 DJSULL1 Copper (Cu) 7.89 ug/L 1 1 EPA 200.8 04/19/2015 14:45 DJSULL1 Lead (Pb) 2.50 ug/L 1 1 EPA 200.8 04/19/2015 14:45 DJSULL1 Molybdenum (Mo) 93.7 ug/L 1 1 EPA 200.8 04/19/2015 14:45 DJSULL1 Nickel (Ni) 13.0 ug/L 1 1 EPA 200.8 04/19/2015 14:45 DJSULL1 Selenium (Se) 25.4 ug/L 1 1 EPA 200.8 04/19/2015 14:45 DJSULL1 Thallium (TI) Low Level 0.574 ug/L 0.2 1 EPA 200.8 04/19/2015 14:45 DJSULL1 Vanadium (V) Low Level 37.1 ug/L 0.3 1 EPA 200.8 04/19/2015 14:45 DJSULL1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS 320 mg/L 25 1 SM2540C 04/09/2015 02:27 AGIBBS5 Total Carbon TOC 1.0 mg/L 0.1 1 SM5310C/EPA9060A 04/14/201516:23 GHUTCHI TOTAL SUSPENDED SOLIDS TSS 71 mg/L 5 1 SM2540D 04/08/2015 09:44 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040126 Site: SW -05 Dup Collection Date: 06 -Apr -15 1:56 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) EPA 353.2 Vendor Parameter Complete 20 EPA 300.0 NITRITE + NITRATE (COLORIMETRIC) JAHERMA 20 Nitrite + Nitrate (Colorimetric) 0.995 mg-N/L 0.01 INORGANIC IONS BY IC V_SHEALY 1 Chloride 13 mg/L 2 Sulfate 170 mg/L 2 MERCURY IN WATER - (Analysis Performed by Shealy Labs) MHALL3 Vendor Parameter Complete 04/08/2015 11:45 MHALL3 DISSOLVED METALS BY ICP EPA 200.7 04/08/2015 11:45 MHALL3 Aluminum (AI) 0.279 mg/L 0.005 Barium (Ba) 0.221 mg/L 0.005 Boron (B) 1.16 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) 0.119 mg/L 0.005 Strontium (Sr) 0.389 mg/L 0.005 Zinc (Zn) 0.010 mg/L 0.005 UNDIGESTED METALS BY ICP EPA 200.7 04/08/2015 15:48 MHALL3 Calcium (Ca) 63.7 mg/L 0.01 Magnesium (Mg) 4.08 mg/L 0.005 Potassium (K) 10.8 mg/L 0.1 Sodium (Na) 10.8 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP EPA 200.7 04/08/2015 15:48 Aluminum (AI) 1.38 mg/L 0.005 Barium (Ba) 0.246 mg/L 0.005 Boron (B) 1.17 mg/L 0.05 Iron (Fe) 0.423 mg/L 0.01 Manganese (Mn) 0.308 mg/L 0.005 Strontium (Sr) 0.402 mg/L 0.005 Zinc (Zn) 0.012 mg/L 0.005 Page 12 of 62 Sample #: 2015009722 Matrix: GW -WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 04/15/2015 09:24 BGN9034 20 EPA 300.0 04/09/2015 15:33 JAHERMA 20 EPA 300.0 04/09/2015 15:33 JAHERMA Vendor Method V_SHEALY 1 EPA 200.7 04/08/2015 11:45 MHALL3 1 EPA 200.7 04/08/2015 11:45 MHALL3 1 EPA 200.7 04/08/2015 11:45 MHALL3 1 EPA 200.7 04/08/2015 11:45 MHALL3 1 EPA 200.7 04/08/2015 11:45 MHALL3 1 EPA 200.7 04/08/2015 11:45 MHALL3 1 EPA 200.7 04/08/2015 11:45 MHALL3 1 EPA 200.7 04/08/2015 13:05 MHALL3 1 EPA 200.7 04/08/2015 13:05 MHALL3 1 EPA 200.7 04/08/2015 13:05 MHALL3 1 EPA 200.7 04/08/2015 13:05 MHALL3 1 EPA 200.7 04/08/2015 15:48 MHALL3 1 EPA 200.7 04/08/2015 15:48 MHALL3 1 EPA 200.7 04/08/2015 15:48 MHALL3 1 EPA 200.7 04/08/2015 15:48 MHALL3 1 EPA 200.7 04/08/2015 15:48 MHALL3 1 EPA 200.7 04/08/2015 15:48 MHALL3 1 EPA 200.7 04/08/2015 15:48 MHALL3 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040126 Site: SW -05 Dup Collection Date: 06 -Apr -15 1:56 PM Analyte Result DISSOLVED METALS BY ICP -MS Sample #: Antimony (Sb) 6.54 Arsenic (As) 51.5 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) 8.89 Cobalt (Co) 4.53 Copper(Cu) 1.87 Lead (Pb) < 1 Molybdenum (Mo) 92.0 Nickel (Ni) 8.31 Selenium (Se) 25.7 Thallium (TI) Low Level 0.402 Vanadium (V) Low Level 29.5 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) 7.09 Arsenic (As) 77.9 Beryllium (Be) < 1 Cadmium (Cd) < 1 Chromium (Cr) 10.1 Cobalt (Co) 5.89 Copper (Cu) 5.33 Lead (Pb) < 1 Molybdenum (Mo) 94.3 Nickel (Ni) 10.7 Selenium (Se) 26.9 Thallium (TI) Low Level 0.505 Vanadium (V) Low Level 33.5 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete TOTAL DISSOLVED SOLIDS ug/L TDS 310 Total Carbon 04/20/2015 13:42 TOC 1.1 TOTAL SUSPENDED SOLIDS 1 TSS 30 Page 13 of 62 ug/L 1 1 Sample #: 2015009722 DJSULL1 ug/L 1 1 Matrix: GW -WW DJSULL1 Units Qualifiers RDL DF Method Analysis Date/Time Analyst ug/L 1 1 EPA 200.8 04/20/2015 13:42 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:42 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:42 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:42 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:42 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:42 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:42 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:42 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:42 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:42 DJSULL1 ug/L 1 1 EPA 200.8 04/20/2015 13:42 DJSULL1 ug/L 0.2 1 EPA 200.8 04/20/2015 13:42 DJSULL1 ug/L 0.3 1 EPA 200.8 04/20/2015 13:42 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:49 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:49 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:49 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:49 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:49 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:49 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:49 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:49 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:49 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:49 DJSULL1 ug/L 1 1 EPA 200.8 04/19/2015 14:49 DJSULL1 ug/L 0.2 1 EPA 200.8 04/19/2015 14:49 DJSULL1 ug/L 0.3 1 EPA 200.8 04/19/2015 14:49 DJSULL1 Vendor Method V SHEALY Vendor Method V_ELE1 mg/L 25 1 SM2540C 04/09/2015 02:27 AGIBBS5 mg/L 0.1 1 SM5310C/EPA9060A 04/14/201516:23 GHUTCHI mg/L 5 1 SM2540D 04/08/2015 09:44 AGIBBS5 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040126 Site: FIELD BLANK Collection Date: 06 -Apr -15 1:33 PM Analyte Result Units Qualifiers RDL ALKALINITY - (Analysis Performed by Shealy Labs) BGN9034 Vendor Parameter Complete JAHERMA 1 EPA 300.0 NITRITE + NITRATE (COLORIMETRIC) JAHERMA Vendor Method Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01 INORGANIC IONS BY IC 1 EPA 200.7 04/08/2015 11:57 MHALL3 Chloride < 0.1 mg/L 0.1 Sulfate < 0.1 mg/L 0.1 MERCURY IN WATER - (Analysis Performed by Shealy Labs) 04/08/2015 11:57 Vendor Parameter Complete 04/08/2015 11:57 MHALL3 DISSOLVED METALS BY ICP 04/08/2015 13:32 MHALL3 1 EPA 200.7 Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) 0.012 mg/L 0.005 UNDIGESTED METALS BY ICP Calcium (Ca) 0.017 mg/L 0.01 Magnesium (Mg) < 0.005 mg/L 0.005 Potassium (K) < 0.1 mg/L 0.1 Sodium (Na) 0.090 mg/L 0.05 TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) < 0.005 mg/L 0.005 Barium (Ba) < 0.005 mg/L 0.005 Boron (B) < 0.05 mg/L 0.05 Iron (Fe) < 0.01 mg/L 0.01 Manganese (Mn) < 0.005 mg/L 0.005 Strontium (Sr) < 0.005 mg/L 0.005 Zinc (Zn) < 0.005 mg/L 0.005 Page 14 of 62 Sample #: 2015009723 Matrix: GW -WW DF Method Analysis Date/Time Analyst Vendor Method V_SHEALY 1 EPA 353.2 04/15/2015 09:25 BGN9034 1 EPA 300.0 04/09/2015 15:52 JAHERMA 1 EPA 300.0 04/09/2015 15:52 JAHERMA Vendor Method V_SHEALY 1 EPA 200.7 04/08/2015 11:57 MHALL3 1 EPA 200.7 04/08/2015 11:57 MHALL3 1 EPA 200.7 04/08/2015 11:57 MHALL3 1 EPA 200.7 04/08/2015 11:57 MHALL3 1 EPA 200.7 04/08/2015 11:57 MHALL3 1 EPA 200.7 04/08/2015 11:57 MHALL3 1 EPA 200.7 04/08/2015 11:57 MHALL3 1 EPA 200.7 04/08/2015 13:32 MHALL3 1 EPA 200.7 04/08/2015 13:32 MHALL3 1 EPA 200.7 04/08/2015 13:32 MHALL3 1 EPA 200.7 04/08/2015 13:32 MHALL3 1 EPA 200.7 04/08/2015 15:51 MHALL3 1 EPA 200.7 04/08/2015 15:51 MHALL3 1 EPA 200.7 04/08/2015 15:51 MHALL3 1 EPA 200.7 04/08/2015 15:51 MHALL3 1 EPA 200.7 04/08/2015 15:51 MHALL3 1 EPA 200.7 04/08/2015 15:51 MHALL3 1 EPA 200.7 04/08/2015 15:51 MHALL3 Certificate of Laboratory Analysis Page 15 of 62 This report shall not be reproduced, except in full. Order # J15040126 Site: FIELD BLANK Sample #: 2015009723 Collection Date: 06 -Apr -15 1:33 PM Matrix: GW -WW Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst DISSOLVED METALS BY ICP -MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 04/20/2015 12:39 DJSULL1 Arsenic (As) < 1 ug/L 1 1 EPA 200.8 04/20/2015 12:39 DJSULL1 Beryllium (Be) < 1 ug/L 1 1 EPA 200.8 04/20/2015 12:39 DJSULL1 Cadmium (Cd) < 1 ug/L 1 1 EPA 200.8 04/20/2015 12:39 DJSULL1 Chromium (Cr) < 1 ug/L 1 1 EPA 200.8 04/20/2015 12:39 DJSULL1 Cobalt (Co) < 1 ug/L 1 1 EPA 200.8 04/20/2015 12:39 DJSULL1 Copper (Cu) < 1 ug/L 1 1 EPA 200.8 04/20/2015 12:39 DJSULL1 Lead (Pb) < 1 ug/L 1 1 EPA 200.8 04/20/2015 12:39 DJSULL1 Molybdenum (Mo) < 1 ug/L 1 1 EPA 200.8 04/20/2015 12:39 DJSULL1 Nickel (Ni) < 1 ug/L 1 1 EPA 200.8 04/20/2015 12:39 DJSULL1 Selenium (Se) < 1 ug/L 1 1 EPA 200.8 04/20/2015 12:39 DJSULL1 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 04/20/2015 12:39 DJSULL1 Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 04/20/2015 12:39 DJSULL1 TOTAL RECOVERABLE METALS BY ICP -MS Antimony (Sb) <1 ug/L 1 1 EPA 200.8 04/19/2015 14:54 DJSULL1 Arsenic (As) < 1 ug/L 1 1 EPA 200.8 04/19/2015 14:54 DJSULL1 Beryllium (Be) < 1 ug/L 1 1 EPA 200.8 04/19/2015 14:54 DJSULL1 Cadmium (Cd) < 1 ug/L 1 1 EPA 200.8 04/19/2015 14:54 DJSULL1 Chromium (Cr) < 1 ug/L 1 1 EPA 200.8 04/19/2015 14:54 DJSULL1 Cobalt (Co) < 1 ug/L 1 1 EPA 200.8 04/19/2015 14:54 DJSULL1 Copper (Cu) < 1 ug/L 1 1 EPA 200.8 04/19/2015 14:54 DJSULL1 Lead (Pb) < 1 ug/L 1 1 EPA 200.8 04/19/2015 14:54 DJSULL1 Molybdenum (Mo) < 1 ug/L 1 1 EPA 200.8 04/19/2015 14:54 DJSULL1 Nickel (Ni) < 1 ug/L 1 1 EPA 200.8 04/19/2015 14:54 DJSULL1 Selenium (Se) < 1 ug/L 1 1 EPA 200.8 04/19/2015 14:54 DJSULL1 Thallium (TI) Low Level < 0.2 ug/L 0.2 1 EPA 200.8 04/19/2015 14:54 DJSULL1 Vanadium (V) Low Level < 0.3 ug/L 0.3 1 EPA 200.8 04/19/2015 14:54 DJSULL1 METHANE - (Analysis Performed by Shealy Labs) Methane (CH4) Complete Vendor Method V_SHEALY SULFIDE - (Analysis Performed by Element One) Vendor Parameter Complete Vendor Method V_ELE1 TOTAL DISSOLVED SOLIDS TDS < 25 mg/L 25 1 SM2540C 04/09/2015 02:27 AGIBBS5 Total Carbon TOC <0.1 mg/L 0.1 1 SM5310C/EPA9060A 04/14/201516:23 GHUTCHI TOTAL SUSPENDED SOLIDS TSS < 5 mg/L 5 1 SM2540D 04/08/2015 09:44 AGIBBS5 el, elementOne Duke Energy Laboratory Services 13339 Hagers Ferry Road Bld. MG03A Huntersville, NC 28078 Page 16 of 62 Element One Inc. 6319-D Carolina Beach Rd. Wilmington, NC 28412 Phone: 910 793-0128 Fax: 910 792-6853 ellab@ellab.com REPORT OF ANALYSES April 10, 2015 Client Project Name AB GW Assessment Water — Synterra Client Project Number J15040126 PO Number Sample Matrix GW WW Sample Type Grab Date Received 04/09/2015 Date Analyzed 04/09/2015 Method SM 4500 S2- D Time Received 1015 Delivered by FedEx Received by JRC eOne ID Duke Energy ID Parameter Result Unit Dil DL Date Time Sampled Sampled 24477-1 M-01 Sulfide < 0.1 mg/L 1 0.1 04/06/15 1205 24477-2 K-01 Sulfide < 0.1 mg/L 1 0.1 04/06/15 1145 24477-3* C-02 Sulfide < 0.5 mg/L 5 0.1 04/06/15 1255 24477-4 SW -05 Sulfide < 0.1 mg/L 1 0.1 04/06/15 1345 24477-5 SW -05 Dup Sulfide < 0.1 mg/L 1 0.1 04/06/15 1356 24477-6 Field Blank Sulfide < 0.1 mg/L 1 0.1 04/06/15 1333 Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits. ,LL------- Dap ne Woodman, QA Officer 24477 Duke Report Packet Compiled by -&5 5 NC Certifications: DW 37788 and DWQ DENR 604 I of n Page 17 of 62 W d W N CL= 0 i. 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U V d 0 p A y E X tu 0 h 'w w O H W W � 'O C 9 MA 1A elementOne SAMPLE SUBMISSION FORM Lab fDe 114477 TAT 7 BD Hold Time Expiration 04.13.15 @ 1145 AM Client: Duke Energy LIMS No J15040126 Project ID AB GW Assessment Water — Synterra Asheville Analysis Due Date 04.10.15 Report Due Date 04.20.15 H >9 Yes No Date Rec: 04.09.15 If No, Record Time Rec: 1015 1205 PM Rec By JRC H >9 Yes No Temp <_ 6°C Yes No Ref. Method: SM4500 S2 D If No, Record If No, Record Samnle Identification & Collection Information Lab ID Client ID Collection Date Collection Time Analysis Requested 1 M-01 04.06.15 1205 PM ulfid 2 K-01 04.06.15 1145 AM uficR 3 C-02 04.06.15 1255 PM Sulfige 4 SW -05 04.06.15 1345 PM Sulfide 5 SW -05 Dup 04.06.15 1356 PM ulfi 6 Field Blank 04.06.15 1333 PM ulfide NOTE RL is 0.1 NOTE for Sulfide The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected at 100 pg/L spike the sample to render the final spike concentration at — 500 tag/L Lab Communications SS Page 1 of 1 SS by 4/9/2015 11:14:56 AM Prep By / Date L� - C1, 1 S PAY,-,, Labeled By / Date ID Verification By/Date kA!4 n '-(-� ( S METHOD : I SM 4500 S2- D I ELEMENT ONE ELEMENT ASSAY: Date: Time Wave Length 664 Page 19 of 62 Na2S•9H2O Lot # ISTANDARD conc(ppm) 40721 1 Cal Std Lot: ug STD STD new SOLUTION ABS 0.074567033 Correlation - m 0.00 0.000 1.00 0:099 ALI in mL ANALYZED PREP VOL in mL 2.50 0.206 o2w LESS THAN % SPK REC SPIKE LEVEL Std. B. 0.00 5.00 0.416 10 10 7.50 0.592 0 Sloe 0.074567033 Correlation 0.998070804 SAMPLE I.D. SAMP ABS ug PER ALIQUOT ALI in mL ANALYZED PREP VOL in mL ALI in mL TAKEN RESULTS ug/mL LESS THAN % SPK REC SPIKE LEVEL Std. B. 0.00 0 10 10 10 0 Std. B. 1.00 0.096 0.8256 10 10 10 82.56% 1.00 Std. B. 2.50 0.206 2.3899 10 10 10 95.59% 2.50 Std. B. 5.00 0.392 5.0349 10 10 10 100.70% 5.00 Std. B. 7.50 0.584 7.7652 10 10 10 103.54% 7.50 Std. B. 10.00 0.754 10.1827 10 10 10 101.83% 10.00 LRB -0.002 0.0000 10 10 10 < 0 LRB SPK 0.404 5.2055 10 10 10 0.521 104% 5.0 QC 0.411 5.3051 10 10 10 0.531 106% 5.0 24476 0.007 -0.4400 10 10 10 < 24476 s k 0.01 -0.3973 10 10 10 < -8% 5.0 24477-1 -0.004 10 10 10 < 24477-1 du 0.01 -0.3973 10 10 10 < 24477-1 5 k 0.399 5.1344 10 10 10 0.513 103% 5.0 24477-2 0.001 -0.5253 10 10 10 777 24477-2 s k 0.346 4.3807 10 10 10 0.438 88% 5.0 24477-3 0.002 -0.5111 10 10 10 < 24477-3 s k 0.279 3.4280 10 10 10 0.343 69% 5.0 24477-4 0.01 -0.3973 10 10 10 <0,1 " 24477-4 S k 0.347 4.3950 10 10 10 0.439 88% 5.0 24477-5 0.013 -0.3547 10 10 10 <0.1 24477-5 s k 0.365 4.6509 10 10 10 0.465 93% 5.0 24477-6 0.001 -0.5253 10 1 10 10 <0.1 24477-6 s k 0.425 5.5041 10 10 10 0.550 110% 5.0 24477-1 0 0.0000 10 10 10 24477-1 du 0.002 -0.5111 10 10 10 < 24477-1 s k 0.398 5.1202 10 10 10 0.512 102% 5.0 24476 0.001 -0.5253 10 10 5 < 24476 s k 0.084 0.6550 10 10 5 < 13% 5.0 Blank 0 0.0000 10 10 10 < QC 0.413 5.3335 10 10 10 0.533 107% 5.0 24477-3 -0.001 0.0000 10 10 5 < 24477-3 s k 0.327 4.1105 10 10 5 0.822 82% 5.0 24476 0.009 -0.4116 10 10 2 < 24476 s k 0.181 2.0344 10 10 2 1.017 41% 5.0 24477-3 0.001 -0.5253 10 10 2 <0.5 24477-3 s k 0.373 4.7647 10 10 2 2.382 95% 5.0 24476 0.000 0.0000 10 10 1 < 24476 s k 0.251 3.0298 10 10 1 3.030 61% 5.0 24476 0.003 -0.4969 10 10 0.5 <2 24476 s k 0.376 4.8073 10 10 0.5 9.615 96% 5.0 Blank 0.000 1 0.0000 10 10 10 < QC 0.411 5.3051 10 10 10 0.531 11% 5.0 Submitted for QA/QC- Date: 4/9/15 By: (Print) KAM (sign • f.. SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Duke Energy 13339 Hagers Ferry Rd Bldg 7405 Huntersville, NC 28078 Attention: Mary Ann Ogle Project Name: AB GW Assessment Water - Synterra Project Number:J15040126 Lot Number:QD09095 Date Completed:04/22/2015 Grant Wilton Project Manager This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist. *QD09095* Shealy Environmental Services, Inc. Page: 1 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Duke Energy Lot Number: QD09095 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPS or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page Shealy Environmental Services, Inc. Page: 2 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary Duke Energy Lot Number: QD09095 Sample Number Sample ID Matrix Date Sampled Date Received 001 2015009715 Aqueous 04/06/20151205 04/09/2015 002 2015009719 Aqueous 04/06/20151145 04/09/2015 003 2015009720 Aqueous 04/06/20151255 04/09/2015 004 2015009721 Aqueous 04/06/20151345 04/09/2015 005 2015009722 Aqueous 04/06/20151356 04/09/2015 006 2015009723 Aqueous 04/06/20151333 04/09/2015 (6 samples) Shealy Environmental Services, Inc. Page: 3 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 (13 detections) Shealy Environmental Services, Inc. Page: 4 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Executive Summary Duke Energy Lot Number: QD09095 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 2015009715 Aqueous Alkalinity SM 2320B- 11 mg/L 5 001 2015009715 Aqueous Bicarbonate Alkalinity SM 2320B- 11 mg/L 5 001 2015009715 Aqueous Mercury (CVAFS) 1631E 6.7 ng/L 7 002 2015009719 Aqueous Mercury (CVAFS) 1631E 2.8 ng/L 10 003 2015009720 Aqueous Alkalinity SM 2320B- 80 mg/L 11 003 2015009720 Aqueous Bicarbonate Alkalinity SM 2320B- 80 mg/L 11 003 2015009720 Aqueous Mercury (CVAFS) 1631E 1.54 ng/L 13 004 2015009721 Aqueous Alkalinity SM 2320B- 29 mg/L 14 004 2015009721 Aqueous Bicarbonate Alkalinity SM 2320B- 29 mg/L 14 004 2015009721 Aqueous Mercury (CVAFS) 1631E 1.12 ng/L 16 005 2015009722 Aqueous Alkalinity SM 2320B- 28 mg/L 17 005 2015009722 Aqueous Bicarbonate Alkalinity SM 2320B- 28 mg/L 17 005 2015009722 Aqueous Mercury (CVAFS) 1631E 2.16 ng/L 19 (13 detections) Shealy Environmental Services, Inc. Page: 4 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QD09095-001 Description: 2015009715 Matrix: Aqueous Date Sampled:04/06/2015 1205 Date Received: 04/09/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/11/2015 1153 HMA 72336 1 (Bicarbonate ) SM 2320B-2011 1 04/14/2015 1153 HMA 04/14/2015 1153 1 (Carbonate Al) SM 2320B-2011 1 04/14/2015 1153 HMA 04/14/2015 1153 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 5 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 11 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 11 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 5 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QD09095-001 Description: 2015009715 Matrix: Aqueous Date Sampled:04/06/2015 1205 Date Received: 04/09/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 04/13/2015 1449 DCS 72404 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 6 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) Client: Duke Energy Laboratory ID: QD09095-001 Description: 2015009715 Matrix: Aqueous Date Sampled:04/06/2015 1205 Date Received: 04/09/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 04/14/2015 1359 COH 04/10/2015 1733 72330 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631E 6.7 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 7 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QD09095-002 Description: 2015009719 Matrix: Aqueous Date Sampled:04/06/2015 1145 Date Received: 04/09/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/11/2015 1157 HMA 72336 1 (Bicarbonate ) SM 2320B-2011 1 04/14/2015 1157 HMA 04/14/2015 1157 1 (Carbonate Al) SM 2320B-2011 1 04/14/2015 1157 HMA 04/14/2015 1157 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 8 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 8 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QD09095-002 Description: 2015009719 Matrix: Aqueous Date Sampled:04/06/2015 1145 Date Received: 04/09/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 04/13/2015 1504 DCS 72404 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 9 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) Client: Duke Energy Laboratory ID: QD09095-002 Description: 2015009719 Matrix: Aqueous Date Sampled:04/06/2015 1145 Date Received: 04/09/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 04/14/2015 1413 COH 04/10/2015 1733 72330 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631E 2.8 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 10 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QD09095-003 Description: 2015009720 Matrix: Aqueous Date Sampled:04/06/2015 1255 Date Received: 04/09/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/11/2015 1214 HMA 72336 1 (Bicarbonate ) SM 2320B-2011 1 04/14/2015 1214 HMA 04/14/2015 1214 1 (Carbonate Al) SM 2320B-2011 1 04/14/2015 1214 HMA 04/14/2015 1214 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 11 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 80 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 80 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 11 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QD09095-003 Description: 2015009720 Matrix: Aqueous Date Sampled:04/06/2015 1255 Date Received: 04/09/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 04/13/2015 1528 DCS 72404 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 12 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) Client: Duke Energy Laboratory ID: QD09095-003 Description: 2015009720 Matrix: Aqueous Date Sampled:04/06/2015 1255 Date Received: 04/09/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 04/14/2015 1418 COH 04/10/2015 1733 72330 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631E 1.54 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 13 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QD09095-004 Description: 2015009721 Matrix: Aqueous Date Sampled:04/06/2015 1345 Date Received: 04/09/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/11/2015 1220 HMA 72336 1 (Bicarbonate ) SM 2320B-2011 1 04/14/2015 1220 HMA 04/14/2015 1220 1 (Carbonate Al) SM 2320B-2011 1 04/14/2015 1220 HMA 04/14/2015 1220 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 14 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 29 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 29 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 14 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QD09095-004 Description: 2015009721 Matrix: Aqueous Date Sampled:04/06/2015 1345 Date Received: 04/09/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 RSK - 175 1 04/20/2015 1411 DCS 72959 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 2 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 15 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) Client: Duke Energy Laboratory ID: QD09095-004 Description: 2015009721 Matrix: Aqueous Date Sampled:04/06/2015 1345 Date Received: 04/09/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 1631 E 1 04/21/2015 2331 COH 04/10/2015 1733 72330 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631E 1.12 0.500 ng/L 2 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 16 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QD09095-005 Description: 2015009722 Matrix: Aqueous Date Sampled:04/06/2015 1356 Date Received: 04/09/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/11/2015 1239 HMA 72336 1 (Bicarbonate ) SM 2320B-2011 1 04/14/2015 1239 HMA 04/14/2015 1239 1 (Carbonate Al) SM 2320B-2011 1 04/14/2015 1239 HMA 04/14/2015 1239 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 17 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 28 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 28 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 17 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QD09095-005 Description: 2015009722 Matrix: Aqueous Date Sampled:04/06/2015 1356 Date Received: 04/09/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 04/13/2015 2311 JJG 72436 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 18 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) Client: Duke Energy Laboratory ID: QD09095-005 Description: 2015009722 Matrix: Aqueous Date Sampled:04/06/2015 1356 Date Received: 04/09/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 1631 E 1 04/21/2015 2354 COH 04/10/2015 1733 72330 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631E 2.16 0.500 ng/L 2 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 19 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals Client: Duke Energy Laboratory ID: QD09095-006 Description: 2015009723 Matrix: Aqueous Date Sampled:04/06/2015 1333 Date Received: 04/09/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 04/11/2015 1244 HMA 72336 1 (Bicarbonate ) SM 2320B-2011 1 04/14/2015 1244 HMA 04/14/2015 1244 1 (Carbonate Al) SM 2320B-2011 1 04/14/2015 1244 HMA 04/14/2015 1244 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 20 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 CAS Analytical Parameter Number Method Result Q PQL Units Run Alkalinity SM 2320B-20 ND 10 mg/L 1 Bicarbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 Carbonate Alkalinity SM 2320B-20 ND 10 mg/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 20 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane Client: Duke Energy Laboratory ID: QD09095-006 Description: 2015009723 Matrix: Aqueous Date Sampled:04/06/2015 1333 Date Received: 04/09/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 RSK - 175 1 04/14/2015 1638 DCS 72503 CAS Analytical Parameter Number Method Result Q PQL Units Run Methane 74-82-8 RSK - 175 ND 10 ug/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 21 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) Client: Duke Energy Laboratory ID: QD09095-006 Description: 2015009723 Matrix: Aqueous Date Sampled:04/06/2015 1333 Date Received: 04/09/2015 Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 1631 E 1 04/14/2015 1432 COH 04/10/2015 1733 72330 CAS Analytical Parameter Number Method Result Q PQL Units Run Mercury (CVAFS) 7439-97-6 1631 E ND 0.500 ng/L 1 PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time NO = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Shealy Environmental Services, Inc. Page: 22 of 22 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 QC Summary Shealy Environmental Services, Inc. QC Data for Lot Number: QD09095 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - Ii Sample ID: QQ72336-001 Matrix: Aqueous Batch: 72336 Analytical Method: SM 2320B-2011 Parameter Result Q Dil PQL Units Analysis Date Alkalinity ND 1 10 mg/L 04/11/20151118 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD09095 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - LCS Sample ID: QQ72336-002 Matrix: Aqueous Batch: 72336 Analytical Method: SM 2320B-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 100 96 1 96 90-110 04/11/20151125 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD09095 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - MS Sample ID: QD09095-002MS Matrix: Aqueous Batch: 72336 Analytical Method: SM 2320B-2011 Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity ND 100 94 1 94 70-130 04/11/20151204 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD09095 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Inorganic non-metals - MSD Sample ID: QD09095-002MD Matrix: Aqueous Batch: 72336 Analytical Method: SM 2320B-2011 Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Alkalinity ND 100 100 1 100 6.1 70-130 20 04/11/20151209 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD09095 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - MB Sample ID: QQ72404-001 Matrix: Aqueous Batch: 72404 Analytical Method: RSK - 175 Parameter Result Q Dil PQL Units Analysis Date Methane ND 1 10 ug/L 04/13/2015 0933 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD09095 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCS Sample ID: QQ72404-002 Matrix: Aqueous Batch: 72404 Analytical Method: RSK - 175 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Methane 150 130 1 89 70-130 04/13/2015 0903 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD09095 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCSD Sample ID: QQ72404-003 Matrix: Aqueous Batch: 72404 Analytical Method: RSK - 175 Spike Amount Result % Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Methane 150 140 1 95 6.9 70-130 30 04/13/2015 0921 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD09095 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - MB Sample ID: QQ72436-001 Matrix: Aqueous Batch: 72436 Analytical Method: RSK - 175 Parameter Result Q Dil PQL Units Analysis Date Methane ND 1 10 ug/L 04/13/2015 2038 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD09095 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCS Sample ID: QQ72436-002 Matrix: Aqueous Batch: 72436 Analytical Method: RSK - 175 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Methane 150 130 1 85 70-130 04/13/20151730 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD09095 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCSD Sample ID: QQ72436-003 Matrix: Aqueous Batch: 72436 Analytical Method: RSK - 175 Spike Amount Result % Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Methane 150 140 1 90 6.4 70-130 30 04/13/20151752 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD09095 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - MB Sample ID: QQ72503-001 Matrix: Aqueous Batch: 72503 Analytical Method: RSK - 175 Parameter Result Q Dil PQL Units Analysis Date Methane ND 1 10 ug/L 04/14/20151535 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD09095 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCS Sample ID: QQ72503-002 Matrix: Aqueous Batch: 72503 Analytical Method: RSK - 175 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Methane 150 130 1 88 70-130 04/14/20151456 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD09095 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCSD Sample ID: QQ72503-003 Matrix: Aqueous Batch: 72503 Analytical Method: RSK - 175 Spike Amount Result % Rec % RPD Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Methane 150 140 1 91 4.1 70-130 30 04/14/20151507 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD09095 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - MB Sample ID: QQ72959-001 Matrix: Aqueous Batch: 72959 Analytical Method: RSK - 175 Parameter Result Q Dil PQL Units Analysis Date Methane ND 1 10 ug/L 04/20/20151357 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD09095 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Methane - LCS Sample ID: QQ72959-002 Matrix: Aqueous Batch: 72959 Analytical Method: RSK - 175 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Methane 150 110 1 73 70-130 04/20/20151313 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD09095 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) - MB Sample ID: QQ72330-001 Matrix: Aqueous Batch: 72330 Prep Method: 1631E Analytical Method: 1631E Prep Date: 04/10/2015 1733 Parameter Result Q Dil PQL Units Analysis Date Mercury (CVAFS) ND 1 0.500 ng/L 04/14/2015 1321 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD09095 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 Mercury (CVAFS) - LCS Sample ID: QQ72330-002 Matrix: Aqueous Batch: 72330 Prep Method: 1631E Analytical Method: 1631E Prep Date: 04/10/2015 1733 Spike Amount Result % Rec Parameter (ng/L) (ng/L) Q Dil % Rec Limit Analysis Date Mercury (CVAFS) 5.00 4.33 1 87 75-125 04/14/2015 1327 PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. QC Data for Lot Number: QD09095 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 SHEALY ENVIRONMENTAL SERVICES, INC. Shab'Eovinmwatal Serwwod, loc page I Of DovamutNunnF- 16 Pj*am EW -K 0711 5f14 R,isicnN&mbw- tb Effoctivc Datec i Id47f14 S11mple Receipt Checklist (SRC) Chent: � Cooler Inspected hy/date:lzx � * -,f-� Mearis ofrecelpC Qr SE SI ❑ Client ❑ UPS ❑ FodEx ❑ Al tome Exp U Other Yas ❑ I No 1. Were custody seals prestnt on the cooleO Yes ❑ I No ❑ I NA:Vj 12. If c:u5tody seals were Lresent, Fere they intact and unbrok=? Cooler IDX)YiZinial temperature upon receipb'Derived (cormeted) teaperawre upon rt ipt, 11C cc i 0C Method_ 2rTomperature Blank ❑ Against Dottl.es III iron ID;, L IR Gun Corr+eotiom Factor: � $_ Method of coolant= Z1Vvt1w Blue, 1r � %ctr ❑ N=c Yw ❑ No ❑ 3- If temperature of any cooler exceeded WC, was Project Manager notffi,ed? NA I'M notified by SRC, phone, note (Circle orae), ether:` (For coolers received %-La commercial courier, FMs are to be netted i>Zin,cdiatel , Yo ❑I No ❑ Yea No NAZ.. 4, Ts the commercial c(tnfer's pa-Gkimg-shp attached to this form? 5. Were propeycustad rocM ores relm sbedlre,ceiv followed? Yto ❑ Nn ❑ NA Sit V41CTCsem Ics re ' wished 0 to commercial courier' Yes No ❑ b° W=- sample IM lis[W on the CHC? Yes No ❑ 7. Were mxVla IIs listed on all Sam le containers? Yes Na $, Wars'Ulu Ghon date time listed on the CDC? Yes No ❑ 9. Was collection date & time listed on all sample containcrs? Yes No 10, Did all cowainer label information (ID, date, time) agree with the COC? Yes No ❑ 1.1. WIC tests to be arfbilawd Gsted on the COC? Yes N -D ❑ 12. Did gall sa,m les arrive in the EMer coaWliam for caah test'? Yes �Ta Q Yes N-3 [] 13° Pid all QovqaL3=q arrive in good conditirm Ounbi -- 1:4° Was adygitate samle vohwe available? YesQ No 15. VWcrc all samples rcL%nvud within 1Atha holding time or 4$ hLkLm, whichever Comes first? 'Yea NQ Ur 16° Were an • sem lis =taimers mts ? YeA ❑ No V1 Yes El Ma 17° were th= any excess sampim not listed On COC? M. El18. Were bubbles re eilt a -size" i"or 6rrr�tx la �d ametor iii any VOA vials? I Yes No ❑ N 19° Were all mietal$. GI&GYHEM+natricot samples rcceiv d at a pH -of X2.7 Ycs No ❑ NA [;?' 24° Were all cyanide mdicir sulfide sampilcs iowiacd at a pH X127 Yea ❑ No ❑ NA 21. lVere all applicable NH3rT'KIRT cyanide,'phenol (<0.7xil:WL) samples fret of residu�d ohlonxic? Y -us ❑ '± Ni ❑ NA ° 22. W= colkctivn tmperal ores documented on the Coc. fc)r I'+TC sam lcs? Yes. d No ❑ N. -IL 23. W= client rcnmrks{regwcsts (i.e. requested dilutions, MSMSD designabons, ctu. ° .) -cx=d1y transcribod from the COC into Lb -e uoEftment section in L -IM S? Yes El No " 24- Was flit quatt ry11 Timber umd tabm frost the Container label's sample Pr ervittion (Mwt be cmple d for any samples) incorrectly preserved or with headspace_) Samglu(s) acorrrdinly in sxmpic wcrc reseiiwd Luourr+ 3y preserved and'were adi"1:w roscir mg wifh (SHt,HI+13},H1,141a3C1F4ut SIS Sam le(s) 4xrere received with bubbles : mm in diameter. Sam 1 O were rx iv+eTl with TRC' 4.2 m+L f 921 is No)-- -- ... SC DrvYklag Water Vroj= Sample(s) pl1 vended to be> 2 by Tate,. sampl s were not received ata vH of <2 and wen a °useed alccordin l , u.zin SR.# Sample labels lied 1}y Verified b . bate; Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 J 1 1.11—a rr SHEALY ENVIRONMENTAL SERVICES, INC. / P7fL � � "4 � � 4 O 4 4 ■ d G } I#�!!or i G r � iSwxlM'�71 ti �I��IS h IiJL R �yi Fl aiayla8 - p-1 Ra+K+P tIIJa�.Puh+�P� alJayodwp lawa�� I Z � ,�I Idp r-1 M s: u I I { 1 k MINMRaff � G ti R - p-1 Ra+K+P tIIJa�.Puh+�P� alJayodwp lawa�� I i Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Level 1 Report v2.1 R-3 CHAIN Of CUSTODY RECORD— .- �; .r:ST FORM --------.---- puke Energy Analytical Laboratory Duke Energy asm Code secosna Ietdld" 74081 Analytical laboratory 13339 Hag— Fe y Rd Chad, of Custody a IW —11., N. C, 2ae79 i Sample Log (7gel $76-5245_ rp:, arsadas ► ^a'"�' ._ ---- -AB CiW Assessment water PfN—NO: ClientJV.� ga0 675-6032 Business Unit: f Pis: tram. C.A. To: Prgam m: - Aeaway to - MCa03A3 Sample Description or I CPS Location Sample i Ih-O/ ` -dl I.i — u Analytical Laboratory Use Only Page of Order Matrix GW WW a� �,roM NC sc_ —1— _i_ DISTRIBUTION I.wg>'d Byfl�� Date a Time tf. J� ,t,p� 1iJJ J / /" SAMPLE PROGRAM ; ORIGINAL to LAB, COPY to CLIENT P O SYN��iA�SD SHEALYcool. Grwnd Water _X_ NPM � VST_ DR kingMterrC RA Waste COC REV DATE 1/2212015 —.I9)_..___ _.._.___..-._.._._.._.___....._.._.._..-........... rrrw r� F� PO 1142089 =filtration (0.45 um) Unfiltered Li fift-1 7 "14 Days `f i PregeryatlVe ke Ice ke Uat keice H2AW_ �25O Collection Information a Rainer Volume (ml-) 2000 40 ml 300 +as $Ott 500 40 ml 500 { m �y s1 lenient 1 Container Type PET glass PET PET PET PET Gla- U MOPE HOPE Hr PO 1142133 D 1 (� -- v x in m o rrrw r� F� 0don Uj in 7 "14 Days `f i note� Collection Information a rA ... .� �W { m �y s1 0 = c 'E Date Time Sl mature u° a FN— U Z a m ?I N L Hr ^O e x 12 1 1 1 1 2 "Add. Cost WillAPPIy 1 1 11 tir hi 14457 f f t 1 # X t JK Ir t Z f l + I t I V .e' (r ).1 Y rS X ! 2( r ( ( R I .a- I f Field Blank (Itsample) Trip Blank (11day) Filter Blank (Ilday) D&WTama TOTAL a 1'1r1 � C'p - €Li=..;,B.TS t,y =P_MS (F:.� f�.S, So. Cd. Co. Cr. Cu. `Mo. K Pb. S``. Se. r ILL 1. V ILL' ELEMENTS by ICP ITRMI: At, Bay B, Fe, Mn, Sr, Zn ICP Undtgested Ga, Mg, K, Na Dis d re Ism* all metals ICIP, IMS, Relinguished By. Date/Time: . Received By: Date/Time. _ 1 (� rrrw r� I Requested Turnaround 7 "14 Days `f i note� � ✓ m c a� n 0 = c 7 hays R � o a '46 Tame ae Hr ^O e o 'Other ASAP 3 "Add. Cost WillAPPIy L)