The URL can be used to link to this page

Home My WebLink AboutNC0000396_J15040116 Report_20150823+ DUKE Analytical Laboratory ENERGY 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone: 980-875-5245 Fax: 980-875-4349 Order Summary Report Order Number: J15040116 Project Name: ASHEVILLE - AB GW ASSESSMENT SOIL Customer Name(s): Todd Plating, Kathy Webb, John Toepfer, Tim Hunsucker Customer Address: 200 CP and L Drive Arden, NC 28704 Lab Contact: Margaret Galvin -Karr Phone: 980-875-5219 MXG4644 (101161) Report Authorized By: 2015.05.19 15:05:24 Date: (Signature) -04'00' Margaret Galvin -Karr Program Comments: Please contact the Program Manager (Margaret Galvin -Karr) with any questions regarding this report. Data Flags & Calculations: 5/19/2015 1 of 65 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: 2 of 65 Collection Sample ID Plant/Station Date and Time Collected By Sample Description 2015009648 ASHEVILLE 02 -Apr -15 11:30 AM Matt Huddleston A-01 2015009649 ASHEVILLE 02 -Apr -15 2:35 PM Matt Huddleston P-01 2015009650 ASHEVILLE 02 -Apr -15 2:45 PM Matt Huddleston P-01 Dup 2015009651 ASHEVILLE 02 -Apr -15 12:30 PM Matt Huddleston SW -01 2015009652 ASHEVILLE 02 -Apr -15 10:45 AM Matt Huddleston SW -04 5 Total Samples Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals Yes No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes F./] No All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No Report Sections Included: U Job Summary Report ❑ Sample Identification n Technical Validation of Data Package ❑ Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report 3of65 Sub -contracted Laboratory Results ❑ Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries 66 Chain of Custody [I/0] Electronic Data Deliverable (EDD) Sent Separately Reviewed By: Margaret Galvin -Karr Date: 5/19/2015 Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040116 Site: A-01 Collection Date: 02 -Apr -15 11:30 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 4 of 65 Sample #: 2015009648 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040116 Site: P-01 Collection Date: 02 -Apr -15 2:35 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 5 of 65 Sample #: 2015009649 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040116 Site: P-01 Dup Collection Date: 02 -Apr -15 2:45 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 6 of 65 Sample #: 2015009650 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040116 Site: SW -01 Collection Date: 02 -Apr -15 12:30 PM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 7 of 65 Sample #: 2015009651 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE Certificate of Laboratory Analysis This report shall not be reproduced, except in full. Order # J15040116 Site: SW -04 Collection Date: 02 -Apr -15 10:45 AM Analyte Result Units Qualifiers RDL DF PERCENT SOLIDS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete PH IN SOIL - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SEDIMENT ANALYSIS - (Analysis Performed by Access Analytical) Vendor Parameter Complete TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete 8 of 65 Sample #: 2015009652 Matrix: SOIL Method Analysis Date/Time Analyst Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_PACE Vendor Method V_A.Analytical Vendor Method V_PACE aceAnaiXical www.pacelabs.com April 27, 2015 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg. 7405 MG30A2 Huntersville, NC 28078 RE: Project: J15040116 Pace Project No.: 92244371 Pace Analytical Services, Inc. 9800 Kigc8y60�e. Suite 100 Huntersville, INC 28078 (704)875-9092 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on April 07, 2015. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Marge Galvin -Karr, Duke Energy Program Manager, Duke Energy Rodney Wilke, Duke Energy HiQ p«FO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, lqe� �� without the written consent of Pace Analytical Services, Inc.. BRAT, Page 1 of 42 aceAnaiXical www.pacelabs.com Project: J15040116 Pace Project No.: 92244371 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Alabama Certification #: 41320 Connecticut Certification M PH -0216 Delaware Certification: FL NELAC Reciprocity Florida Certification #: E83079 Georgia Certification #: 955 Guam Certification: FL NELAC Reciprocity Hawaii Certification: FL NELAC Reciprocity Illinois Certification #: 200068 Indiana Certification: FL NELAC Reciprocity Kansas Certification #: E-10383 Kentucky Certification #: 90050 Louisiana Certification #: FL NELAC Reciprocity Louisiana Environmental Certificate M 05007 Maryland Certification: #346 Massachusetts Certification #: M-FL1264 Michigan Certification #: 9911 Mississippi Certification: FL NELAC Reciprocity Missouri Certification #: 236 Green Bay Certification IDs 1241 Bellevue Street, Green Bay, WI 54302 Florida/NELAP Certification #: E87948 Illinois Certification #: 200050 Kentucky Certification #: 82 Louisiana Certification #: 04168 Minnesota Certification #: 055-999-334 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification M E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 Pace Analytical Services, Inc. 9800 Kli6c8y.O�e. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Montana Certification #: Cert 0074 Nebraska Certification: NE -OS -28-14 Nevada Certification: FL NELAC Reciprocity New Hampshire Certification #: 2958 New Jersey Certification #: FL765 New York Certification #: 11608 North Carolina Environmental Certificate #: 667 Pennsylvania Certification #: 68-00547 Puerto Rico Certification M FLO1264 South Carolina Certification: #96042001 Tennessee Certification #: TN02974 Texas Certification: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Virginia Environmental Certification #: 460165 Washington Certification #: C955 West Virginia Certification #: 9962C Wisconsin Certification #: 399079670 Wyoming (EPA Region 8): FL NELAC Reciprocity North Dakota Certification #: R-150 South Carolina Certification #: 83006001 Texas Certification #: T104704529-14-1 US Dept of Agriculture #: S-76505 Wisconsin Certification #: 405132750 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 West Virginia Certification M 356 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 2 of 42 aceAnaiXical www.pacelabs.com SAMPLE SUMMARY Project: J15040116 Pace Project No.: 92244371 Lab ID Sample ID Matrix Date Collected Date Received 92244371001 2015009648 Solid 04/02/1511:30 04/07/1516:20 92244371002 2015009649 Solid 04/02/1514:35 04/07/1516:20 92244371003 2015009650 Solid 04/02/1514:45 04/07/1516:20 92244371004 2015009651 Solid 04/02/1512:30 04/07/1516:20 92244371005 2015009652 Solid 04/02/1510:45 04/07/1516:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 f iy'8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 42 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 9800 ffli�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J15040116 92244371 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92244371001 2015009648 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AIS 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92244371002 2015009649 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AIS 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92244371003 2015009650 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AIS 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92244371004 2015009651 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AIS 1 PASI-O EPA 9045 MLS 1 PASI-A EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G 92244371005 2015009652 EPA 6010 CKJ 16 PASI-0 EPA 6020 CRT 8 PASI-O EPA 7471 CKJ 1 PASI-O ASTM D2974-87 AIS 1 PASI-O EPA 9045 MLS 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 42 aceAnaiXical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 9800 f igc8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040116 Pace Project No.: 92244371 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 9056 AIS 2 PASI-O EPA 9056 AIS 1 PASI-O EPA 9060 TJJ 6 PASI-G REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 5 of 42 aceAnaiXical www.pacelabs.com Project: J15040116 Pace Project No.: 92244371 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 9800 ffli '8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 92244371001 2015009648 EPA 6010 Aluminum 10900 mg/kg 114 04/25/15 19:16 EPA 6010 Barium 97.9 mg/kg 11.4 04/25/15 19:16 EPA 6010 Beryllium 1.9 mg/kg 1.1 04/25/15 19:16 EPA 6010 Calcium 1420 mg/kg 571 04/25/15 19:16 EPA 6010 Chromium 12.0 mg/kg 5.7 04/25/15 19:16 EPA 6010 Copper 6.1 mg/kg 5.7 04/25/15 19:16 EPA 6010 Iron 17900 mg/kg 45.6 04/25/15 19:16 EPA 6010 Magnesium 2410 mg/kg 571 04/25/15 19:16 EPA 6010 Manganese 238 mg/kg 5.7 04/25/15 19:16 EPA 6010 Nickel 6.4 mg/kg 5.7 04/25/15 19:16 EPA 6010 Potassium 1280 mg/kg 1140 04/25/15 19:16 EPA 6010 Strontium 12.3 mg/kg 11.4 04/25/15 19:16 EPA 6010 Zinc 46.5 mg/kg 22.8 04/25/15 19:16 EPA 6020 Vanadium 17.6J mg/kg 22.8 04/22/15 00:53 EPA 7471 Mercury 0.16 mg/kg 0.036 04/20/15 19:53 ASTM D2974-87 Percent Moisture 77.4 % 0.10 04/17/15 09:30 EPA 9045 pH at 25 Degrees C 6.2 Std. Units 0.10 04/13/15 16:20 EPA 9056 Chloride 5911 mg/kg 1110 04/16/15 00:08 D3 EPA 9060 Total Organic Carbon 64400 mg/kg 28800 04/23/15 08:33 EPA 9060 Total Organic Carbon 62400 mg/kg 28900 04/23/15 08:39 EPA 9060 Total Organic Carbon 64400 mg/kg 27100 04/23/15 08:46 EPA 9060 Total Organic Carbon 58000 mg/kg 29200 04/23/15 08:51 EPA 9060 Mean Total Organic Carbon 62300 mg/kg 28500 04/23/15 08:33 EPA 9060 RSD% 4.8 % 04/23/15 08:33 92244371002 2015009649 EPA 6010 Aluminum 31900 mg/kg 112 04/25/15 19:21 EPA 6010 Barium 300 mg/kg 11.2 04/25/15 19:21 EPA 6010 Beryllium 2.5 mg/kg 1.1 04/25/15 19:21 EPA 6010 Calcium 2640 mg/kg 558 04/25/15 19:21 EPA 6010 Chromium 44.5 mg/kg 5.6 04/25/15 19:21 EPA 6010 Copper 39.0 mg/kg 5.6 04/25/15 19:21 EPA 6010 Iron 62000 mg/kg 44.7 04/25/15 19:21 EPA 6010 Magnesium 5840 mg/kg 558 04/25/15 19:21 EPA 6010 Manganese 3320 mg/kg 5.6 04/25/15 19:21 EPA 6010 Nickel 22.6 mg/kg 5.6 04/25/15 19:21 EPA 6010 Potassium 4310 mg/kg 1120 04/25/15 19:21 EPA 6010 Strontium 35.7 mg/kg 11.2 04/25/15 19:21 EPA 6010 Zinc 197 mg/kg 22.3 04/25/15 19:21 EPA 6020 Cobalt 58.1 mg/kg 22.3 04/22/15 00:55 EPA 6020 Lead 21.9J mg/kg 22.3 04/22/15 00:55 EPA 6020 Vanadium 57.1 mg/kg 22.3 04/22/15 00:55 EPA 7471 Mercury 0.082 mg/kg 0.035 04/20/15 19:59 ASTM D2974-87 Percent Moisture 77.4 % 0.10 04/17/15 09:30 EPA 9045 pH at 25 Degrees C 6.8 Std. Units 0.10 04/13/15 16:20 EPA 9060 Total Organic Carbon 58200 mg/kg 7500 04/23/15 09:54 EPA 9060 Total Organic Carbon 58700 mg/kg 7490 04/23/15 09:59 EPA 9060 Total Organic Carbon 61800 mg/kg 7410 04/23/15 10:06 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 42 aceAnaiXical www.pacelabs.com Project: J15040116 Pace Project No.: 92244371 Lab Sample ID Method Client Sample ID Parameters 92244371002 2015009649 EPA 9060 Total Organic Carbon EPA 9060 Mean Total Organic Carbon EPA 9060 RSD% 92244371003 2015009650 EPA 6010 Aluminum EPA 6010 Barium EPA 6010 Beryllium EPA 6010 Calcium EPA 6010 Chromium EPA 6010 Copper EPA 6010 Iron EPA 6010 Magnesium EPA 6010 Manganese EPA 6010 Nickel EPA 6010 Potassium EPA 6010 Strontium EPA 6010 Zinc EPA 6020 Cobalt EPA 6020 Lead EPA 6020 Vanadium EPA 7471 Mercury ASTM D2974-87 Percent Moisture EPA 9045 pH at 25 Degrees C EPA 9060 Total Organic Carbon EPA 9060 Total Organic Carbon EPA 9060 Total Organic Carbon EPA 9060 Total Organic Carbon EPA 9060 Mean Total Organic Carbon EPA 9060 RSD% Pace Analytical Services, Inc. 9800 f igc8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed Qualifiers 46400 mg/kg 7500 04/23/1510:11 56300 mg/kg 7480 04/23/15 09:54 12.1 % 5.0 04/23/15 09:54 9900 mg/kg 37.3 04/25/1519:25 96.0 mg/kg 3.7 04/25/1519:25 0.80 mg/kg 0.37 04/25/1519:25 870 mg/kg 187 04/25/1519:25 20.6 mg/kg 1.9 04/25/1519:25 11.8 mg/kg 1.9 04/25/1519:25 21000 mg/kg 14.9 04/25/1519:25 1680 mg/kg 187 04/25/1519:25 960 mg/kg 1.9 04/25/1519:25 7.7 mg/kg 1.9 04/25/1519:25 1270 mg/kg 373 04/25/1519:25 12.0 mg/kg 3.7 04/25/1519:25 61.2 mg/kg 7.5 04/25/1519:25 16.5 mg/kg 7.5 04/22/15 00:57 6.6J mg/kg 7.5 04/22/15 00:57 18.5 mg/kg 7.5 04/22/15 00:57 0.030 mg/kg 0.013 04/20/15 20:01 35.8 % 0.10 04/17/15 09:30 6.4 Std. Units 0.10 04/13/15 16:20 12400 mg/kg 2230 04/23/1510:18 16200 mg/kg 2220 04/23/1510:23 16200 mg/kg 2190 04/23/1510:29 18300 mg/kg 2180 04/23/1510:34 15800 mg/kg 2210 04/23/1510:18 15.7 % 04/23/1510:18 92244371004 2015009651 EPA 6010 Aluminum 11900 mg/kg 49.7 04/25/15 19:29 EPA 6010 Barium 113 mg/kg 5.0 04/25/15 19:29 EPA 6010 Beryllium 0.80 mg/kg 0.50 04/25/15 19:29 EPA 6010 Calcium 698 mg/kg 249 04/25/15 19:29 EPA 6010 Chromium 27.2 mg/kg 2.5 04/25/15 19:29 EPA 6010 Copper 13.0 mg/kg 2.5 04/25/15 19:29 EPA 6010 Iron 23400 mg/kg 19.9 04/25/15 19:29 EPA 6010 Magnesium 3480 mg/kg 249 04/25/15 19:29 EPA 6010 Manganese 375 mg/kg 2.5 04/25/15 19:29 EPA 6010 Nickel 9.6 mg/kg 2.5 04/25/15 19:29 EPA 6010 Potassium 2870 mg/kg 497 04/25/15 19:29 EPA 6010 Strontium 5.3 mg/kg 5.0 04/25/15 19:29 EPA 6010 Zinc 83.4 mg/kg 9.9 04/25/15 19:29 EPA 6020 Cadmium 2.7 mg/kg 1.2 04/22/15 01:07 EPA 6020 Cobalt 10.5 mg/kg 9.9 04/22/15 01:07 EPA 6020 Lead 9AJ mg/kg 9.9 04/22/15 01:07 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 42 aceAnaiXical www.pacelabs.com Project: J15040116 Pace Project No.: 92244371 Lab Sample ID Client Sample ID Method Parameters Pace Analytical Services, Inc. 9800 ffli '8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Result Units Report Limit Analyzed 92244371004 2015009651 EPA 6020 Vanadium 21.8 mg/kg 9.9 04/22/15 01:07 EPA 7471 Mercury 0.033 mg/kg 0.016 04/20/15 20:04 ASTM D2974-87 Percent Moisture 52.2 % 0.10 04/17/15 09:30 EPA 9045 pH at 25 Degrees C 4.3 Std. Units 0.10 04/13/15 16:20 EPA 9060 Total Organic Carbon 7670 mg/kg 3060 04/23/15 10:40 EPA 9060 Total Organic Carbon 7050 mg/kg 3050 04/23/15 10:46 EPA 9060 Total Organic Carbon 6180 mg/kg 3100 04/23/15 10:51 EPA 9060 Total Organic Carbon 4560 mg/kg 3100 04/23/15 10:58 EPA 9060 Mean Total Organic Carbon 6370 mg/kg 3080 04/23/15 10:40 EPA 9060 RSD% 21.2 % 04/23/15 10:40 92244371005 2015009652 EPA 6010 Aluminum 17600 mg/kg 143 04/25/15 19:33 EPA 6010 Barium 204 mg/kg 14.3 04/25/15 19:33 EPA 6010 Beryllium 2.8 mg/kg 1.4 04/25/15 19:33 EPA 6010 Calcium 5250 mg/kg 714 04/25/15 19:33 EPA 6010 Chromium 19.2 mg/kg 7.1 04/25/15 19:33 EPA 6010 Copper 22.1 mg/kg 7.1 04/25/15 19:33 EPA 6010 Iron 43800 mg/kg 57.1 04/25/15 19:33 EPA 6010 Magnesium 3480 mg/kg 714 04/25/15 19:33 EPA 6010 Manganese 345 mg/kg 7.1 04/25/15 19:33 EPA 6010 Nickel 10.8 mg/kg 7.1 04/25/15 19:33 EPA 6010 Potassium 2140 mg/kg 1430 04/25/15 19:33 EPA 6010 Strontium 40.4 mg/kg 14.3 04/25/15 19:33 EPA 6010 Zinc 93.9 mg/kg 28.6 04/25/15 19:33 EPA 6020 Cobalt 20.11J mg/kg 28.6 04/22/15 01:09 EPA 6020 Lead 19.11 mg/kg 28.6 04/22/15 01:09 EPA 6020 Selenium 28.7 mg/kg 28.6 04/22/15 01:09 EPA 6020 Vanadium 35.5 mg/kg 28.6 04/22/15 01:09 EPA 7471 Mercury 0.32 mg/kg 0.048 04/20/15 20:06 ASTM D2974-87 Percent Moisture 83.3 % 0.10 04/17/15 09:30 EPA 9045 pH at 25 Degrees C 6.1 Std. Units 0.10 04/13/15 16:20 EPA 9056 Chloride 962J mg/kg 1480 04/16/15 02:16 EPA 9060 Total Organic Carbon 116000 mg/kg 43100 04/23/15 11:03 EPA 9060 Total Organic Carbon 134000 mg/kg 40400 04/23/15 11:09 EPA 9060 Total Organic Carbon 125000 mg/kg 40500 04/23/15 11:14 EPA 9060 Total Organic Carbon 150000 mg/kg 43100 04/23/15 11:20 EPA 9060 Mean Total Organic Carbon 131000 mg/kg 41800 04/23/15 11:03 EPA 9060 RSD% 11.2 % 04/23/15 11:03 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Qualifiers Page 8 of 42 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli .8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040116 Pace Project No.: 92244371 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 27, 2015 General Information: 5 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23698 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92244973001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1188089) • Aluminum • Barium • Copper • Iron • Magnesium • Manganese • Potassium • Strontium • MSD (Lab ID: 1188090) • Aluminum • Barium • Copper • Iron • Magnesium • Manganese REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 9 of 42 aceAnaiXical www.pacelabs.com PROJECT NARRATIVE Project: J15040116 Pace Project No.: 92244371 Method: EPA 6010 Description: 6010 MET ICP Client: Duke Energy Date: April 27, 2015 QC Batch: MPRP/23698 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92244973001 R1: RPD value was outside control limits. • MSD (Lab ID: 1188090) • Strontium Additional Comments: Batch Comments: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICP / 14482 Analyte Comments: QC Batch: MPRP/23698 Pace Analytical Services, Inc. 9800 ffli '8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 P8: Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. • BLANK (Lab ID: 1188087) • Iron REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 10 of 42 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 ffli�c&)e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040116 Pace Project No.: 92244371 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 27, 2015 General Information: 5 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 3050 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Internal Standards: All internal standards were within QC limits with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MPRP/23699 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92244973002 M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. • MS (Lab ID: 1188093) • Antimony • Cobalt • MSD (Lab ID: 1188094) • Selenium • Vanadium Additional Comments: Batch Comments: Batch was diluted due to the presence of high levels of non -target analytes or other matrix interference. • QC Batch: ICPM / 9630 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 11 of 42 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPi '8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040116 Pace Project No.: 92244371 Method: EPA 6020 Description: 6020 MET ICPMS Client: Duke Energy Date: April 27, 2015 Analyte Comments: QC Batch: MPRP/23699 N2: The lab does not hold TNI accreditation for this parameter. •2015009648 (Lab ID:92244371001) • Antimony •2015009649 (Lab ID:92244371002) • Antimony •2015009650 (Lab ID:92244371003) • Antimony •2015009651 (Lab ID:92244371004) • Antimony •2015009652 (Lab ID:92244371005) • Antimony • BLANK (Lab ID: 1188091) • Antimony • LCS (Lab ID: 1188092) • Antimony • MS (Lab ID: 1188093) • Antimony • MSD (Lab ID: 1188094) • Antimony REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 42 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 tf�nic&)r6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040116 Pace Project No.: 92244371 Method: EPA 7471 Description: 7471 Mercury Client: Duke Energy Date: April 27, 2015 General Information: 5 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 7471 with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. QC Batch: MERP/5605 A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92244973001 M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. • MS (Lab ID: 1188097) • Mercury Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 13 of 42 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K2'8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040116 Pace Project No.: 92244371 Method: EPA 9045 Description: 9045 pH Soil Client: Duke Energy Date: April 27, 2015 General Information: 5 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Duplicate Sample: All duplicate sample results were within method acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 14 of 42 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KS'8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040116 Pace Project No.: 92244371 Method: EPA 9056 Description: 9056 IC Anions Client: Duke Energy Date: April 27, 2015 General Information: 5 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: Analyte Comments: QC Batch: WETA/45422 D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. •2015009648 (Lab ID:92244371001) • Chloride • Sulfate •2015009649 (Lab ID:92244371002) • Chloride • Sulfate •2015009650 (Lab ID:92244371003) • Chloride • Sulfate •2015009651 (Lab ID:92244371004) • Chloride • Sulfate •2015009652 (Lab ID:92244371005) • Sulfate REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 15 of 42 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 K4'8)r6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040116 Pace Project No.: 92244371 Method: EPA 9056 Description: 9056 IC Anions 48hr Client: Duke Energy Date: April 27, 2015 General Information: 5 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. 1-13: Sample was received or analysis requested beyond the recognized method holding time. •2015009648 (Lab ID: 92244371001) •2015009649 (Lab ID: 92244371002) •2015009650 (Lab ID: 92244371003) •2015009651 (Lab ID: 92244371004) •2015009652 (Lab ID: 92244371005) Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 16 of 42 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 KPi '8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 PROJECT NARRATIVE Project: J15040116 Pace Project No.: 92244371 Method: EPA 9060 Description: Total Organic Carbon Quad Client: Duke Energy Date: April 27, 2015 General Information: 5 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below. Continuing Calibration: All criteria were within method requirements with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments: This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 42 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 tf� '8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040116 Pace Project No.: 92244371 Sample: 2015009648 Lab ID: 92244371001 Collected: 04/02/15 11:30 Received: 04/07/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 10900 mg/kg 114 57.1 5 04/19/15 05:38 04/25/15 19:16 7429-90-5 Barium 97.9 mg/kg 11.4 5.7 5 04/19/15 05:38 04/25/15 19:16 7440-39-3 Beryllium 1.9 mg/kg 1.1 0.57 5 04/19/15 05:38 04/25/15 19:16 7440-41-7 Boron ND mg/kg 57.1 28.5 5 04/19/15 05:38 04/25/15 19:16 7440-42-8 Calcium 1420 mg/kg 571 285 5 04/19/15 05:38 04/25/15 19:16 7440-70-2 Chromium 12.0 mg/kg 5.7 2.9 5 04/19/15 05:38 04/25/15 19:16 7440-47-3 Copper 6.1 mg/kg 5.7 2.9 5 04/19/15 05:38 04/25/15 19:16 7440-50-8 Iron 17900 mg/kg 45.6 22.8 5 04/19/15 05:38 04/25/15 19:16 7439-89-6 Magnesium 2410 mg/kg 571 285 5 04/19/15 05:38 04/25/15 19:16 7439-95-4 Manganese 238 mg/kg 5.7 2.9 5 04/19/15 05:38 04/25/15 19:16 7439-96-5 Molybdenum ND mg/kg 11.4 5.7 5 04/19/15 05:38 04/25/15 19:16 7439-98-7 Nickel 6.4 mg/kg 5.7 2.9 5 04/19/15 05:38 04/25/15 19:16 7440-02-0 Potassium 1280 mg/kg 1140 571 5 04/19/15 05:38 04/25/15 19:16 7440-09-7 Sodium ND mg/kg 1140 571 5 04/19/15 05:38 04/25/15 19:16 7440-23-5 Strontium 12.3 mg/kg 11.4 5.7 5 04/19/15 05:38 04/25/15 19:16 7440-24-6 Zinc 46.5 mg/kg 22.8 11.4 5 04/19/15 05:38 04/25/15 19:16 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 22.8 11.4 100 04/19/15 05:38 04/22/15 00:53 7440-36-0 N2 Arsenic ND mg/kg 22.8 11.4 100 04/19/15 05:38 04/22/15 00:53 7440-38-2 Cadmium ND mg/kg 2.7 1.4 100 04/19/15 05:38 04/22/15 00:53 7440-43-9 Cobalt ND mg/kg 22.8 11.4 100 04/19/15 05:38 04/22/15 00:53 7440-48-4 Lead ND mg/kg 22.8 11.4 100 04/19/15 05:38 04/22/15 00:53 7439-92-1 Selenium ND mg/kg 22.8 11.4 100 04/19/15 05:38 04/22/15 00:53 7782-49-2 Thallium ND mg/kg 22.8 11.4 100 04/19/15 05:38 04/22/15 00:53 7440-28-0 Vanadium 17.6J mg/kg 22.8 11.4 100 04/19/15 05:38 04/22/15 00:53 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.16 mg/kg 0.036 0.018 1 04/19/15 05:30 04/20/15 19:53 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 77.4 % 0.10 0.10 1 04/17/15 09:30 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.2 Std. Units 0.10 0.10 1 04/13/15 16:20 9056 IC Anions Analytical Method: EPA 9056 Chloride 591J mg/kg 1110 555 5 04/16/15 00:08 16887-00-6 D3 Sulfate ND mg/kg 1110 555 5 04/16/15 00:08 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 111 55.5 5 04/16/15 00:08 14797-55-8 H3 Date: 04/27/2015 10:25 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 18 of 42 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040116 Pace Project No.: 92244371 Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015009648 Lab ID: 92244371001 Collected: 04/02/15 11:30 Received: 04/07/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 64400 mg/kg 28800 14400 1 04/23/15 08:33 7440-44-0 Total Organic Carbon 62400 mg/kg 28900 14400 1 04/23/15 08:39 7440-44-0 Total Organic Carbon 64400 mg/kg 27100 13500 1 04/23/15 08:46 7440-44-0 Total Organic Carbon 58000 mg/kg 29200 14600 1 04/23/15 08:51 7440-44-0 Mean Total Organic Carbon 62300 mg/kg 28500 14200 1 04/23/15 08:33 7440-44-0 Surrogates RSD% 4.8 % 1 04/23/15 08:33 Date: 04/27/2015 10:25 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 19 of 42 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 tf�%c&y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040116 Pace Project No.: 92244371 Sample: 2015009649 Lab ID: 92244371002 Collected: 04/02/15 14:35 Received: 04/07/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 31900 mg/kg 112 55.8 5 04/19/15 05:38 04/25/15 19:21 7429-90-5 Barium 300 mg/kg 11.2 5.6 5 04/19/15 05:38 04/25/15 19:21 7440-39-3 Beryllium 2.5 mg/kg 1.1 0.56 5 04/19/15 05:38 04/25/15 19:21 7440-41-7 Boron ND mg/kg 55.8 27.9 5 04/19/15 05:38 04/25/15 19:21 7440-42-8 Calcium 2640 mg/kg 558 279 5 04/19/15 05:38 04/25/15 19:21 7440-70-2 Chromium 44.5 mg/kg 5.6 2.8 5 04/19/15 05:38 04/25/15 19:21 7440-47-3 Copper 39.0 mg/kg 5.6 2.8 5 04/19/15 05:38 04/25/15 19:21 7440-50-8 Iron 62000 mg/kg 44.7 22.3 5 04/19/15 05:38 04/25/15 19:21 7439-89-6 Magnesium 5840 mg/kg 558 279 5 04/19/15 05:38 04/25/15 19:21 7439-95-4 Manganese 3320 mg/kg 5.6 2.8 5 04/19/15 05:38 04/25/15 19:21 7439-96-5 Molybdenum ND mg/kg 11.2 5.6 5 04/19/15 05:38 04/25/15 19:21 7439-98-7 Nickel 22.6 mg/kg 5.6 2.8 5 04/19/15 05:38 04/25/15 19:21 7440-02-0 Potassium 4310 mg/kg 1120 558 5 04/19/15 05:38 04/25/15 19:21 7440-09-7 Sodium ND mg/kg 1120 558 5 04/19/15 05:38 04/25/15 19:21 7440-23-5 Strontium 35.7 mg/kg 11.2 5.6 5 04/19/15 05:38 04/25/15 19:21 7440-24-6 Zinc 197 mg/kg 22.3 11.2 5 04/19/15 05:38 04/25/15 19:21 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 22.3 11.2 100 04/19/15 05:38 04/22/15 00:55 7440-36-0 N2 Arsenic ND mg/kg 22.3 11.2 100 04/19/15 05:38 04/22/15 00:55 7440-38-2 Cadmium ND mg/kg 2.7 1.3 100 04/19/15 05:38 04/22/15 00:55 7440-43-9 Cobalt 58.1 mg/kg 22.3 11.2 100 04/19/15 05:38 04/22/15 00:55 7440-48-4 Lead 21.9J mg/kg 22.3 11.2 100 04/19/15 05:38 04/22/15 00:55 7439-92-1 Selenium ND mg/kg 22.3 11.2 100 04/19/15 05:38 04/22/15 00:55 7782-49-2 Thallium ND mg/kg 22.3 11.2 100 04/19/15 05:38 04/22/15 00:55 7440-28-0 Vanadium 57.1 mg/kg 22.3 11.2 100 04/19/15 05:38 04/22/15 00:55 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.082 mg/kg 0.035 0.018 1 04/19/15 05:30 04/20/15 19:59 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 77.4 % 0.10 0.10 1 04/17/15 09:30 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.8 Std. Units 0.10 0.10 1 04/13/15 16:20 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 1090 544 5 04/16/15 01:12 16887-00-6 D3 Sulfate ND mg/kg 1090 544 5 04/16/15 01:12 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 109 54.4 5 04/16/15 01:12 14797-55-8 H3 Date: 04/27/2015 10:25 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 20 of 42 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040116 Pace Project No.: 92244371 Pace Analytical Services, Inc. 9800 tf� '8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015009649 Lab ID: 92244371002 Collected: 04/02/15 14:35 Received: 04/07/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 58200 mg/kg 7500 3750 1 04/23/15 09:54 7440-44-0 Total Organic Carbon 58700 mg/kg 7490 3750 1 04/23/15 09:59 7440-44-0 Total Organic Carbon 61800 mg/kg 7410 3710 1 04/23/15 10:06 7440-44-0 Total Organic Carbon 46400 mg/kg 7500 3750 1 04/23/15 10:11 7440-44-0 Mean Total Organic Carbon 56300 mg/kg 7480 3740 1 04/23/15 09:54 7440-44-0 Surrogates RSD% 12.1 % 1 04/23/15 09:54 Date: 04/27/2015 10:25 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 21 of 42 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 %'8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040116 Pace Project No.: 92244371 Sample: 2015009650 Lab ID: 92244371003 Collected: 04/02/15 14:45 Received: 04/07/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 9900 mg/kg 37.3 18.7 5 04/19/15 05:38 04/25/15 19:25 7429-90-5 Barium 96.0 mg/kg 3.7 1.9 5 04/19/15 05:38 04/25/15 19:25 7440-39-3 Beryllium 0.80 mg/kg 0.37 0.19 5 04/19/15 05:38 04/25/15 19:25 7440-41-7 Boron ND mg/kg 18.7 9.3 5 04/19/15 05:38 04/25/15 19:25 7440-42-8 Calcium 870 mg/kg 187 93.3 5 04/19/15 05:38 04/25/15 19:25 7440-70-2 Chromium 20.6 mg/kg 1.9 0.93 5 04/19/15 05:38 04/25/15 19:25 7440-47-3 Copper 11.8 mg/kg 1.9 0.93 5 04/19/15 05:38 04/25/15 19:25 7440-50-8 Iron 21000 mg/kg 14.9 7.5 5 04/19/15 05:38 04/25/15 19:25 7439-89-6 Magnesium 1680 mg/kg 187 93.3 5 04/19/15 05:38 04/25/15 19:25 7439-95-4 Manganese 960 mg/kg 1.9 0.93 5 04/19/15 05:38 04/25/15 19:25 7439-96-5 Molybdenum ND mg/kg 3.7 1.9 5 04/19/15 05:38 04/25/15 19:25 7439-98-7 Nickel 7.7 mg/kg 1.9 0.93 5 04/19/15 05:38 04/25/15 19:25 7440-02-0 Potassium 1270 mg/kg 373 187 5 04/19/15 05:38 04/25/15 19:25 7440-09-7 Sodium ND mg/kg 373 187 5 04/19/15 05:38 04/25/15 19:25 7440-23-5 Strontium 12.0 mg/kg 3.7 1.9 5 04/19/15 05:38 04/25/15 19:25 7440-24-6 Zinc 61.2 mg/kg 7.5 3.7 5 04/19/15 05:38 04/25/15 19:25 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 7.5 3.7 100 04/19/15 05:38 04/22/15 00:57 7440-36-0 N2 Arsenic ND mg/kg 7.5 3.7 100 04/19/15 05:38 04/22/15 00:57 7440-38-2 Cadmium ND mg/kg 0.90 0.45 100 04/19/15 05:38 04/22/15 00:57 7440-43-9 Cobalt 16.5 mg/kg 7.5 3.7 100 04/19/15 05:38 04/22/15 00:57 7440-48-4 Lead 6.6J mg/kg 7.5 3.7 100 04/19/15 05:38 04/22/15 00:57 7439-92-1 Selenium ND mg/kg 7.5 3.7 100 04/19/15 05:38 04/22/15 00:57 7782-49-2 Thallium ND mg/kg 7.5 3.7 100 04/19/15 05:38 04/22/15 00:57 7440-28-0 Vanadium 18.5 mg/kg 7.5 3.7 100 04/19/15 05:38 04/22/15 00:57 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.030 mg/kg 0.013 0.0063 1 04/19/15 05:30 04/20/15 20:01 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 35.8 % 0.10 0.10 1 04/17/15 09:30 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.4 Std. Units 0.10 0.10 1 04/13/15 16:20 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 387 194 5 04/16/15 01:33 16887-00-6 D3 Sulfate ND mg/kg 387 194 5 04/16/15 01:33 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 38.7 19.4 5 04/16/15 01:33 14797-55-8 H3 Date: 04/27/2015 10:25 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 22 of 42 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040116 Pace Project No.: 92244371 Pace Analytical Services, Inc. 9800 �nic8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015009650 Lab ID: 92244371003 Collected: 04/02/15 14:45 Received: 04/07/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 12400 mg/kg 2230 1120 1 04/23/15 10:18 7440-44-0 Total Organic Carbon 16200 mg/kg 2220 1110 1 04/23/15 10:23 7440-44-0 Total Organic Carbon 16200 mg/kg 2190 1100 1 04/23/15 10:29 7440-44-0 Total Organic Carbon 18300 mg/kg 2180 1090 1 04/23/15 10:34 7440-44-0 Mean Total Organic Carbon 15800 mg/kg 2210 1100 1 04/23/15 10:18 7440-44-0 Surrogates RSD% 15.7 % 1 04/23/1510:18 Date: 04/27/2015 10:25 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 23 of 42 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 �Q%Y60�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040116 Pace Project No.: 92244371 Sample: 2015009651 Lab ID: 92244371004 Collected: 04/02/15 12:30 Received: 04/07/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 11900 mg/kg 49.7 24.9 5 04/19/15 05:38 04/25/15 19:29 7429-90-5 Barium 113 mg/kg 5.0 2.5 5 04/19/15 05:38 04/25/15 19:29 7440-39-3 Beryllium 0.80 mg/kg 0.50 0.25 5 04/19/15 05:38 04/25/15 19:29 7440-41-7 Boron ND mg/kg 24.9 12.4 5 04/19/15 05:38 04/25/15 19:29 7440-42-8 Calcium 698 mg/kg 249 124 5 04/19/15 05:38 04/25/15 19:29 7440-70-2 Chromium 27.2 mg/kg 2.5 1.2 5 04/19/15 05:38 04/25/15 19:29 7440-47-3 Copper 13.0 mg/kg 2.5 1.2 5 04/19/15 05:38 04/25/15 19:29 7440-50-8 Iron 23400 mg/kg 19.9 9.9 5 04/19/15 05:38 04/25/15 19:29 7439-89-6 Magnesium 3480 mg/kg 249 124 5 04/19/15 05:38 04/25/15 19:29 7439-95-4 Manganese 375 mg/kg 2.5 1.2 5 04/19/15 05:38 04/25/15 19:29 7439-96-5 Molybdenum ND mg/kg 5.0 2.5 5 04/19/15 05:38 04/25/15 19:29 7439-98-7 Nickel 9.6 mg/kg 2.5 1.2 5 04/19/15 05:38 04/25/15 19:29 7440-02-0 Potassium 2870 mg/kg 497 249 5 04/19/15 05:38 04/25/15 19:29 7440-09-7 Sodium ND mg/kg 497 249 5 04/19/15 05:38 04/25/15 19:29 7440-23-5 Strontium 5.3 mg/kg 5.0 2.5 5 04/19/15 05:38 04/25/15 19:29 7440-24-6 Zinc 83.4 mg/kg 9.9 5.0 5 04/19/15 05:38 04/25/15 19:29 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 9.9 5.0 100 04/19/15 05:38 04/22/15 01:07 7440-36-0 N2 Arsenic ND mg/kg 9.9 5.0 100 04/19/15 05:38 04/22/15 01:07 7440-38-2 Cadmium 2.7 mg/kg 1.2 0.60 100 04/19/15 05:38 04/22/15 01:07 7440-43-9 Cobalt 10.5 mg/kg 9.9 5.0 100 04/19/15 05:38 04/22/15 01:07 7440-48-4 Lead 9AJ mg/kg 9.9 5.0 100 04/19/15 05:38 04/22/15 01:07 7439-92-1 Selenium ND mg/kg 9.9 5.0 100 04/19/15 05:38 04/22/15 01:07 7782-49-2 Thallium ND mg/kg 9.9 5.0 100 04/19/15 05:38 04/22/15 01:07 7440-28-0 Vanadium 21.8 mg/kg 9.9 5.0 100 04/19/15 05:38 04/22/15 01:07 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.033 mg/kg 0.016 0.0082 1 04/19/15 05:30 04/20/15 20:04 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 52.2 % 0.10 0.10 1 04/17/15 09:30 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 4.3 Std. Units 0.10 0.10 1 04/13/15 16:20 9056 IC Anions Analytical Method: EPA 9056 Chloride ND mg/kg 527 264 5 04/16/15 01:55 16887-00-6 D3 Sulfate ND mg/kg 527 264 5 04/16/15 01:55 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 52.7 26.4 5 04/16/15 01:55 14797-55-8 H3 Date: 04/27/2015 10:25 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 24 of 42 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040116 Pace Project No.: 92244371 Pace Analytical Services, Inc. 9800 t S'8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015009651 Lab ID: 92244371004 Collected: 04/02/15 12:30 Received: 04/07/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 7670 mg/kg 3060 1530 1 04/23/15 10:40 7440-44-0 Total Organic Carbon 7050 mg/kg 3050 1520 1 04/23/15 10:46 7440-44-0 Total Organic Carbon 6180 mg/kg 3100 1550 1 04/23/15 10:51 7440-44-0 Total Organic Carbon 4560 mg/kg 3100 1550 1 04/23/15 10:58 7440-44-0 Mean Total Organic Carbon 6370 mg/kg 3080 1540 1 04/23/15 10:40 7440-44-0 Surrogates RSD% 21.2 % 1 04/23/1510:40 Date: 04/27/2015 10:25 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 25 of 42 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 t 4'8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040116 Pace Project No.: 92244371 Sample: 2015009652 Lab ID: 92244371005 Collected: 04/02/15 10:45 Received: 04/07/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050 Aluminum 17600 mg/kg 143 71.4 5 04/19/15 05:38 04/25/15 19:33 7429-90-5 Barium 204 mg/kg 14.3 7.1 5 04/19/15 05:38 04/25/15 19:33 7440-39-3 Beryllium 2.8 mg/kg 1.4 0.71 5 04/19/15 05:38 04/25/15 19:33 7440-41-7 Boron ND mg/kg 71.4 35.7 5 04/19/15 05:38 04/25/15 19:33 7440-42-8 Calcium 5250 mg/kg 714 357 5 04/19/15 05:38 04/25/15 19:33 7440-70-2 Chromium 19.2 mg/kg 7.1 3.6 5 04/19/15 05:38 04/25/15 19:33 7440-47-3 Copper 22.1 mg/kg 7.1 3.6 5 04/19/15 05:38 04/25/15 19:33 7440-50-8 Iron 43800 mg/kg 57.1 28.6 5 04/19/15 05:38 04/25/15 19:33 7439-89-6 Magnesium 3480 mg/kg 714 357 5 04/19/15 05:38 04/25/15 19:33 7439-95-4 Manganese 345 mg/kg 7.1 3.6 5 04/19/15 05:38 04/25/15 19:33 7439-96-5 Molybdenum ND mg/kg 14.3 7.1 5 04/19/15 05:38 04/25/15 19:33 7439-98-7 Nickel 10.8 mg/kg 7.1 3.6 5 04/19/15 05:38 04/25/15 19:33 7440-02-0 Potassium 2140 mg/kg 1430 714 5 04/19/15 05:38 04/25/15 19:33 7440-09-7 Sodium ND mg/kg 1430 714 5 04/19/15 05:38 04/25/15 19:33 7440-23-5 Strontium 40.4 mg/kg 14.3 7.1 5 04/19/15 05:38 04/25/15 19:33 7440-24-6 Zinc 93.9 mg/kg 28.6 14.3 5 04/19/15 05:38 04/25/15 19:33 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3050 Antimony ND mg/kg 28.6 14.3 100 04/19/15 05:38 04/22/15 01:09 7440-36-0 N2 Arsenic ND mg/kg 28.6 14.3 100 04/19/15 05:38 04/22/15 01:09 7440-38-2 Cadmium ND mg/kg 3.4 1.7 100 04/19/15 05:38 04/22/15 01:09 7440-43-9 Cobalt 20.1J mg/kg 28.6 14.3 100 04/19/15 05:38 04/22/15 01:09 7440-48-4 Lead 19.11 mg/kg 28.6 14.3 100 04/19/15 05:38 04/22/15 01:09 7439-92-1 Selenium 28.7 mg/kg 28.6 14.3 100 04/19/15 05:38 04/22/15 01:09 7782-49-2 Thallium ND mg/kg 28.6 14.3 100 04/19/15 05:38 04/22/15 01:09 7440-28-0 Vanadium 35.5 mg/kg 28.6 14.3 100 04/19/15 05:38 04/22/15 01:09 7440-62-2 7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471 Mercury 0.32 mg/kg 0.048 0.024 1 04/19/15 05:30 04/20/15 20:06 7439-97-6 Percent Moisture Analytical Method: ASTM D2974-87 Percent Moisture 83.3 % 0.10 0.10 1 04/17/15 09:30 9045 pH Soil Analytical Method: EPA 9045 pH at 25 Degrees C 6.1 Std. Units 0.10 0.10 1 04/13/15 16:20 9056 IC Anions Analytical Method: EPA 9056 Chloride 962J mg/kg 1480 740 5 04/16/15 02:16 16887-00-6 Sulfate ND mg/kg 1480 740 5 04/16/15 02:16 14808-79-8 D3 9056 IC Anions 48hr Analytical Method: EPA 9056 Nitrate as N ND mg/kg 148 74.0 5 04/16/15 02:16 14797-55-8 H3 Date: 04/27/2015 10:25 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 26 of 42 aceAnaiXical www.pacelabs.com ANALYTICAL RESULTS Project: J15040116 Pace Project No.: 92244371 Pace Analytical Services, Inc. 9800 %'8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: 2015009652 Lab ID: 92244371005 Collected: 04/02/15 10:45 Received: 04/07/15 16:20 Matrix: Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Total Organic Carbon Quad Analytical Method: EPA 9060 Total Organic Carbon 116000 mg/kg 43100 21500 1 04/23/15 11:03 7440-44-0 Total Organic Carbon 134000 mg/kg 40400 20200 1 04/23/15 11:09 7440-44-0 Total Organic Carbon 125000 mg/kg 40500 20300 1 04/23/15 11:14 7440-44-0 Total Organic Carbon 150000 mg/kg 43100 21600 1 04/23/15 11:20 7440-44-0 Mean Total Organic Carbon 131000 mg/kg 41800 20900 1 04/23/15 11:03 7440-44-0 Surrogates RSD% 11.2 % 1 04/23/1511:03 Date: 04/27/2015 10:25 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 27 of 42 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040116 Pace Project No.: 92244371 QC Batch: MERP/5605 Analysis Method: EPA 7471 QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury Associated Lab Samples: 92244371001, 92244371002, 92244371003, 92244371004, 92244371005 METHOD BLANK: 1188095 Matrix: Solid Associated Lab Samples: 92244371001, 92244371002, 92244371003, 92244371004, 92244371005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/kg ND 0.0083 04/20/1519:36 LABORATORY CONTROL SAMPLE: 1188096 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/kg .081 0.074 90 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1188097 1188098 MS MSD 92244973001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/kg ND .0961 .0961 0.078 0.086 79 87 80-120 10 20 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 10:25 AM without the written consent of Pace Analytical Services, Inc.. Page 28 of 42 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040116 Pace Project No.: 92244371 QC Batch: MPRP/23698 Analysis Method: EPA 6010 QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid Associated Lab Samples: 92244371001, 92244371002, 92244371003, 92244371004, 92244371005 METHOD BLANK: 1188087 Matrix: Solid Associated Lab Samples: 92244371001, 92244371002, 92244371003, 92244371004, 92244371005 Blank Reporting Parameter Units Result Limit Analyzed Aluminum mg/kg ND 5.1 04/25/1518:28 Barium mg/kg ND 0.51 04/25/1518:28 Beryllium mg/kg ND 0.051 04/25/1518:28 Boron mg/kg ND 2.5 04/25/1518:28 Calcium mg/kg ND 25.3 04/25/1518:28 Chromium mg/kg ND 0.25 04/25/1518:28 Copper mg/kg ND 0.25 04/25/1518:28 Iron mg/kg 3.1 2.0 04/25/1518:28 P8 Magnesium mg/kg ND 25.3 04/25/1518:28 Manganese mg/kg ND 0.25 04/25/1518:28 Molybdenum mg/kg ND 0.51 04/25/1518:28 Nickel mg/kg ND 0.25 04/25/1518:28 Potassium mg/kg ND 50.7 04/25/1518:28 Sodium mg/kg ND 50.7 04/25/1518:28 Strontium mg/kg ND 0.51 04/25/1518:28 Zinc mg/kg ND 1.0 04/25/1518:28 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 1188088 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Aluminum mg/kg 120 125 104 80-120 Barium mg/kg 12 12.5 104 80-120 Beryllium mg/kg 1.2 1.2 103 80-120 Boron mg/kg 120 119 99 80-120 Calcium mg/kg 600 635 106 80-120 Chromium mg/kg 12 11.8 98 80-120 Copper mg/kg 12 11.8 98 80-120 Iron mg/kg 120 126 105 80-120 Magnesium mg/kg 600 619 103 80-120 Manganese mg/kg 12 12.1 101 80-120 Molybdenum mg/kg 12 12.0 100 80-120 Nickel mg/kg 12 12.4 103 80-120 Potassium mg/kg 600 615 102 80-120 Sodium mg/kg 600 644 107 80-120 Strontium mg/kg 12 12.4 103 80-120 Zinc mg/kg 60 61.7 103 80-120 Pace Analytical Services, Inc. 9800 K�c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 10:25 AM without the written consent of Pace Analytical Services, Inc.. Page 29 of 42 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 K�gc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040116 Pace Project No.: 92244371 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1188089 1188090 MS MSD 92244973001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Aluminum mg/kg 13500 142 150 16700 15300 2250 1240 75-125 8 20 M1 Barium mg/kg 210 14.2 15 248 205 263 -35 75-125 19 20 M1 Beryllium mg/kg 0.43 1.37 1.49 1.9 1.9 104 101 75-125 2 20 Boron mg/kg ND 142 150 127 135 89 90 75-125 7 20 Calcium mg/kg 1530 711 750 2370 2100 119 76 75-125 12 20 Chromium mg/kg 10.6 14.2 15 26.5 25.6 112 100 75-125 4 20 Copper mg/kg 84.1 14.2 15 102 87.6 127 23 75-125 15 20 M1 Iron mg/kg 23700 142 150 25600 21900 1360 -1150 75-125 15 20 M1 Magnesium mg/kg 6440 711 750 7920 6680 209 32 75-125 17 20 M1 Manganese mg/kg 168 14.2 15 160 139 -57 -192 75-125 14 20 M1 Molybdenum mg/kg ND 14.2 15 12.4 13.3 86 88 75-125 7 20 Nickel mg/kg 9.1 14.2 15 24.4 23.7 108 98 75-125 3 20 Potassium mg/kg 1970 711 750 2940 2660 138 92 75-125 10 20 M1 Sodium mg/kg 250J 711 750 1040 1050 111 106 75-125 1 20 Strontium mg/kg 23.2 14.2 15 45.6 36.4 158 88 75-125 22 20 M1,R1 Zinc mg/kg 41.3 71.1 75 120 117 111 101 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 10:25 AM without the written consent of Pace Analytical Services, Inc.. Page 30 of 42 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040116 Pace Project No.: 92244371 QC Batch: MPRP/23699 Analysis Method: EPA 6020 QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID Associated Lab Samples: 92244371001, 92244371002, 92244371003, 92244371004, 92244371005 METHOD BLANK: 1188091 Matrix: Solid LCS Result Associated Lab Samples: 92244371001, 92244371002, 92244371003, 92244371004, 92244371005 mg/kg 2.5 2.6 Blank Reporting Arsenic Parameter Units Result Limit Analyzed Qualifiers Antimony mg/kg ND 0.051 04/22/15 00:23 N2 Arsenic mg/kg ND 0.051 04/22/15 00:23 Cadmium mg/kg ND 0.0061 04/22/15 00:23 Cobalt mg/kg ND 0.051 04/22/15 00:23 Lead mg/kg ND 0.051 04/22/15 00:23 Selenium mg/kg ND 0.051 04/22/15 00:23 Thallium mg/kg ND 0.051 04/22/15 00:23 Vanadium mg/kg ND 0.051 04/22/15 00:23 Pace Analytical Services, Inc. 9800 K��c&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 1188092 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony mg/kg 2.5 2.6 103 80-120 N2 Arsenic mg/kg 2.5 2.6 105 80-120 Cadmium mg/kg .25 0.26 104 80-120 Cobalt mg/kg 2.5 2.7 106 80-120 Lead mg/kg 2.5 2.6 101 80-120 Selenium mg/kg 2.5 2.6 102 80-120 Thallium mg/kg 2.5 2.6 103 80-120 Vanadium mg/kg 2.5 2.7 106 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1188093 1188094 MS MSD 92244973002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony mg/kg ND 3.61 3.61 ND ND 66 75 75-125 20 M6, N2 Arsenic mg/kg ND 3.61 3.61 5.3J 5.01 88 84 75-125 20 Cadmium mg/kg ND .361 .361 ND ND 88 80 75-125 20 Cobalt mg/kg 5.6J 3.61 3.61 11.7 10 167 122 75-125 16 20 M6 Lead mg/kg 6.7J 3.61 3.61 10.5 10.2 104 98 75-125 3 20 Selenium mg/kg ND 3.61 3.61 5.9J 4.9J 78 52 75-125 20 M6 Thallium mg/kg ND 3.61 3.61 4.2J 4.1J 90 90 75-125 20 Vanadium mg/kg 94.7 3.61 3.61 98.2 92.0 96 -76 75-125 7 20 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 10:25 AM without the written consent of Pace Analytical Services, Inc.. Page 31 of 42 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040116 Pace Project No.: 92244371 QC Batch: PMST/3453 Analysis Method: ASTM D2974-87 QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture Associated Lab Samples: 92244371001, 92244371002, 92244371003, 92244371004, 92244371005 SAMPLE DUPLICATE: 1186463 35183573001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 32.5 38.8 18 10 D6 SAMPLE DUPLICATE: 1186496 35183605001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 83.8 83.0 1 10 SAMPLE DUPLICATE: 1186497 35183605002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 83.7 83.7 0 10 SAMPLE DUPLICATE: 1186498 35183608001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Percent Moisture % 95.2 94.8 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 10:25 AM without the written consent of Pace Analytical Services, Inc.. Page 32 of 42 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040116 Pace Project No.: 92244371 QC Batch: WET/36789 Analysis Method: EPA 9045 QC Batch Method: EPA 9045 Analysis Description: 9045 pH Associated Lab Samples: 92244371001, 92244371002, 92244371003, 92244371004, 92244371005 Pace Analytical Services, Inc. 9800 1inlc&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE DUPLICATE: 1432813 92244052001 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 8.6 8.6 0 10 SAMPLE DUPLICATE: 1432814 92244371005 Dup Max Parameter Units Result Result RPD RPD Qualifiers pH at 25 Degrees C Std. Units 6.1 6.1 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 10:25 AM without the written consent of Pace Analytical Services, Inc.. Page 33 of 42 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Project: J15040116 Pace Project No.: 92244371 QC Batch: WETA/45422 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92244371001, 92244371002, 92244371003, 92244371004, 92244371005 METHOD BLANK: 1183715 1183716 Matrix: Solid Units Associated Lab Samples: mg/kg Sulfate mg/kg Blank Reporting 1183718 Parameter Units Result Limit Analyzed Qualifiers Chloride mg/kg ND 49.8 04/15/15 20:34 Sulfate mg/kg ND 49.8 04/15/15 20:34 LABORATORY CONTROL SAMPLE: 1183716 Parameter Units Chloride mg/kg Sulfate mg/kg MATRIX SPIKE SAMPLE: 1183718 Parameter Units Chloride mg/kg Sulfate mg/kg SAMPLE DUPLICATE: 1183717 Parameter Chloride Sulfate Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 503 484 96 80-120 503 473 94 80-120 92245118001 Spike MS MS % Rec Result Conc. Result % Rec Limits Qualifiers ND 722 634 88 80-120 ND 722 649 90 80-120 92245118001 Dup Units Result Result mg/kg ND ND mg/kg ND ND Max RPD RPD Qualifiers 20 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 10:25 AM without the written consent of Pace Analytical Services, Inc.. Page 34 of 42 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040116 Pace Project No.: 92244371 QC Batch: WETA/45423 Analysis Method: EPA 9056 QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions Associated Lab Samples: 92244371001, 92244371002, 92244371003, 92244371004, 92244371005 METHOD BLANK: 1183719 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N mg/kg ND 5.0 04/15/15 20:34 LABORATORY CONTROL SAMPLE: 1183720 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg 50.3 48.1 96 80-120 MATRIX SPIKE SAMPLE: 1183722 92245118001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N mg/kg ND 72.2 64.5 89 80-120 H3 SAMPLE DUPLICATE: 1183721 92245118001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Nitrate as N mg/kg ND ND 20 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 10:25 AM without the written consent of Pace Analytical Services, Inc.. Page 35 of 42 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040116 Pace Project No.: 92244371 QC Batch: WETA/28151 Analysis Method: EPA 9060 QC Batch Method: EPA 9060 Analysis Description: 9060 TOC Average Associated Lab Samples: 92244371001, 92244371002, 92244371003, 92244371004, 92244371005 METHOD BLANK: 1145152 Matrix: Solid Associated Lab Samples: Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon mg/kg ND 600 04/23/15 05:54 LABORATORY CONTROL SAMPLE: 1145153 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon mg/kg 120000 120000 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1145154 1145155 MS MSD 92243924001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 1600 7540 7530 9560 9110 106 100 50-150 5 30 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1145156 1145157 MS MSD 92244371001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon mg/kg 62300 286000 280000 332000 328000 94 95 50-150 1 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 10:25 AM without the written consent of Pace Analytical Services, Inc.. Page 36 of 42 aceAnaiXical www.pacelabs.com QUALIFIERS Project: J15040116 Pace Project No.: 92244371 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. Pace Analytical Services, Inc. 9800 %'8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-G Pace Analytical Services - Green Bay PASI-O Pace Analytical Services - Ormond Beach BATCH QUALIFIERS Batch: ICPM/9630 [1] Batch was diluted due to the presence of high levels of non -target analytes or other matrix interference. Batch: ICP/14482 [1] Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. ANALYTE QUALIFIERS D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold TNI accreditation for this parameter. P8 Analyte was detected in the method blank. All associated samples had concentrations of at least ten times greater than the blank or were below the reporting limit. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 10:25 AM without the written consent of Pace Analytical Services, Inc.. Page 37 of 42 aceAnaiXical www.pacelabs.com Pace Analytical Services, Inc. 9800 %'8y6o�e. Suite 100 Huntersville, INC 28078 (704)875-9092 QUALIFIERS Project: J15040116 Pace Project No.: 92244371 ANALYTE QUALIFIERS R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 10:25 AM without the written consent of Pace Analytical Services, Inc.. Page 38 of 42 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, Inc. 9800 Iic&fie. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J15040116 Pace Project No.: 92244371 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92244371001 2015009648 EPA 3050 MPRP/23698 EPA 6010 ICP/14482 92244371002 2015009649 EPA 3050 MPRP/23698 EPA 6010 ICP/14482 92244371003 2015009650 EPA 3050 MPRP/23698 EPA 6010 ICP/14482 92244371004 2015009651 EPA 3050 MPRP/23698 EPA 6010 ICP/14482 92244371005 2015009652 EPA 3050 MPRP/23698 EPA 6010 ICP/14482 92244371001 2015009648 EPA 3050 MPRP/23699 EPA 6020 ICPM/9630 92244371002 2015009649 EPA 3050 MPRP/23699 EPA 6020 ICPM/9630 92244371003 2015009650 EPA 3050 MPRP/23699 EPA 6020 ICPM/9630 92244371004 2015009651 EPA 3050 MPRP/23699 EPA 6020 ICPM/9630 92244371005 2015009652 EPA 3050 MPRP/23699 EPA 6020 ICPM/9630 92244371001 2015009648 EPA 7471 MERP/5605 EPA 7471 MERC/5593 92244371002 2015009649 EPA 7471 MERP/5605 EPA 7471 MERC/5593 92244371003 2015009650 EPA 7471 MERP/5605 EPA 7471 MERC/5593 92244371004 2015009651 EPA 7471 MERP/5605 EPA 7471 MERC/5593 92244371005 2015009652 EPA 7471 MERP/5605 EPA 7471 MERC/5593 92244371001 2015009648 ASTM D2974-87 PMST/3453 92244371002 2015009649 ASTM D2974-87 PMST/3453 92244371003 2015009650 ASTM D2974-87 PMST/3453 92244371004 2015009651 ASTM D2974-87 PMST/3453 92244371005 2015009652 ASTM D2974-87 PMST/3453 92244371001 2015009648 EPA 9045 WET/36789 92244371002 2015009649 EPA 9045 WET/36789 92244371003 2015009650 EPA 9045 WET/36789 92244371004 2015009651 EPA 9045 WET/36789 92244371005 2015009652 EPA 9045 WET/36789 92244371001 2015009648 EPA 9056 WETA/45422 92244371002 2015009649 EPA 9056 WETA/45422 92244371003 2015009650 EPA 9056 WETA/45422 92244371004 2015009651 EPA 9056 WETA/45422 92244371005 2015009652 EPA 9056 WETA/45422 92244371001 2015009648 EPA 9056 WETA/45423 92244371002 2015009649 EPA 9056 WETA/45423 92244371003 2015009650 EPA 9056 WETA/45423 92244371004 2015009651 EPA 9056 WETA/45423 92244371005 2015009652 EPA 9056 WETA/45423 92244371001 2015009648 EPA 9060 WETA/28151 92244371001 2015009648 EPA 9060 WETA/28152 92244371002 2015009649 EPA 9060 WETA/28151 92244371002 2015009649 EPA 9060 WETA/28152 92244371003 2015009650 EPA 9060 WETA/28151 92244371003 2015009650 EPA 9060 WETA/28152 92244371004 2015009651 EPA 9060 WETA/28151 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/27/2015 10:25 AM without the written consent of Pace Analytical Services, Inc.. Page 39 of 42 aceAnaiXical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: J15040116 Pace Project No.: 92244371 Lab ID Sample ID QC Batch Method QC Batch 92244371004 2015009651 EPA 9060 WETA/28152 92244371005 2015009652 EPA 9060 WETA/28151 92244371005 2015009652 EPA 9060 WETA/28152 Date: 04/27/2015 10:25 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 %'8y6o�e. Suite 100 Huntersville, NC 28078 (704)875-9092 Analytical Method Analytical Batch Page 40 of 42 _. aceAr��lyticala f Client Name:��i�.. Document Name: le Condition Upon Recei Document Number: F-CHR-CS-003-rev.15 Courier: ❑ Fed Ex ❑ UPS❑ USPS[:] Client❑ Commercial❑ Pace Other, Custody Seal on Cooler/Box Present: ❑ yes K no Seals intact: ❑ yes Document Revised: September 22. 2U14 Page 1 of 2 Issuing Authorltp of 65 Pace Huntersville Quality Office ❑ no Packing Material: ❑ Bubble V❑tp ❑ Bubble Bags ❑ None ❑ Other Thermometer Used: IR Gun T1401 Type of Ice: Wet Blue None m Sampies on ice, cooling process has begun Temp Correction Factor T1401 No Correction-� Corrected Cooler Tem - p.: i:� C BiS tcal Tissue is Frozen: Yes No N1A Date Cate and Initials of per on etaminjrlg 1_ J� contents: Temp should be above freezing to 6*C Comments: -4' Chain of Custody Present: Ves -❑No ❑NIA 1. Chain of Custody Filled Out: QYes El No ❑NIA 2. Chain of Custody Relinquished: es ONO ❑NIA 3. Sampler Name & Signature on COC: ❑Yes No L1 NIA 4. Samples Arrived within Hold Time: Q es ONO ❑NIA 5. Short Hold Time Analysis (<72hr): ❑Yes . No ❑NIA 6. Rush Turn Around Time Requested: ❑Yes &No ❑NIA 7. Sufficient Volume: uYes ❑No ❑NIA 8. Correct Containers Used: Wes ❑No ❑NIA 9. -Pace Containers Used: ❑Yes dNo ❑NIA Containers Intact: V Yes ONO ❑NIA 1fl. Filtered volume received for Dissolved tests Oyes 'ONO ! IA 11 • Sample Labels match COC: Q es ONO ❑NIA 12, -Includes dateltime/ID/Analysis Matrix: I. 1 All containers needing preservation have been checked. ❑Yes ONO KN/A 13. All containers needing preservation are found to be in ❑Yes ONO �N/A compliance with EPA recommendation. exceptions: VOA, coliform, TOC, O&G, W1 -DRO (water) ❑Yes ONO Samples checked for dechlorination: Oyes ONO lV IA 14. Headspace in VOA Vials (>6mm): ❑Yes ONO gN1A 15. Trip Blank Present: ❑Yes ONO ,4N/A 16. Trip Blank Custody Seals Present ❑Yes ❑No ONIA Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: Field Data Required? Y 1 N Person Contacted: Comments/ Resolution: Date/Time: SCURF Review: fie- Date: SRF Review: le Date: jl Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (Le out of hold, incorrect preservative, out of temp, incorrect containers) WO#:92244371 11111111111111111111111141 Page 41 of 42 119 a �J mp f ti Customer must co lets 50 O 65 J.�I .. D _ a I n m C c ` Customer to complete appropriate columns to right _ n a D rn F -H 4 °° j r n �; � Dmm o n 6�-- 3 � c m C a � M .3 3 13 m y 4� 0 o no >z UO I I L m 1 ? _° m 2 D. H j DI J ; 3 3 O G N w nID m 3 N i a m i i 3 I m -U v 1 d � i r�S ni D ws III 1t T jm nwm p'I _ o mdm3 21 -i �iI 1 a n M1 .: Y 51! i CO i.�. 1 1 6 7 to 00 ° D � , 44411 � D = a =i—.,zap or Z `iZ a n I gni ro I t 0 o m y ! N W' -n In 0 I i C D i1i O C n ._.- _._. -- 10 Z rD 110 i 3 to rt o I N yy 3 0 R C ao' dzIZ Iti � 3 » Q M n to I m m in I � C Y trComp. 7BA al S 3 n u c 13? X 'X X, 1 Crab Req Ire 4—o m CI K a i r I Total Metals , Anions, d pH U7 — 7 - 8 oz jar (PACE) e { +�_Isir �� o ; � TOC t- 4 oz jar4 3 3 i aim (PACE)I v m i ((� ° o ! -i SPi_P -Total Metals0 9 i -Z1 H�, and Anions 3 10 2- 8 oz jars (PACE) 5 3 a o a Sediment specific i ja V tests 2- 8 oz jar (ACCESS i ANALYTICAL) 5 I' i EF a i n z i D I N I Oo 0 z v 1 a _{ZA r rM M - D r-- lD , r'[7 royo 70 13 zS; J D N �mz rnn -�. 20Tota1 9 of Containers a Pageof 42 100 95 90 85 80 75 70 65 H 2 60 w >- 55 m ry Z 50 LL z 45 w W 40 w CL 35 30 25 20 15 10 5 0 GRAIN SIZE DISTRIBUTION ASTM D422 51 of 65 U.S. SIEVE OPENING IN INCHES I U.S. SIEVE NUMBERS I HYDROMETER a 4 z 2 1 r 1 qid 1/2z/Q 3 d 6 A10 1416 on 30 An 50 an 1001An200 100 10 1 0.1 GRAIN SIZE IN MILLIMETERS 0.01 0.001 I COBBLES GRAVEL SAND SILT OR CLAY i coarse I fine coarse I medium I fine Boring ID Depth AASHTO Classification LL PL PI Cc Cu • A-01 0 () 2.29 34.76 Boring ID Depthl D,00 D60 D30 1310 9/Gravel %Sand %Silt %Clay 1 • A-01 0 2 0.121 0.031 0.003 0.0 52.9 34.7 12.4 PROJECT: AB GW Assessment - Asheville Sediment PROJECT NUMBER: 73075016 SITE: Asheville, North Carolina 1 rerracon CLIENT: Access Analytial 521 Clemson Road Columbia, South Carolina GRAIN SIZE DISTRIBUTION 52 of 65 ASTM D422 U.S. SIEVE OPENING IN INCHES U.S. SIEVE NUMBERS I HYDROMETER 6 4 3 2 1.5 13/4 1/23/8 3 4 6 810 1416 20 30 40 50 60 100 140 200 100 SILT OR CLAY coarse fine coarse medium fine 95 90 85--- 80 75 70 65 H 2 60 w >- 55 m Z 50 LL z 45 w 40 w 0 35 30--- 25 20 15 10 5 0 100 10 1 0.1 0.01 0.001 GRAIN SIZE IN MILLIMETERS Boring ID Depth AASHTO Classification LL PL PI Cc Cu • P-01 0 () 0.77 59.91 Boring ID Depth D,00 D60 D30 D,o %Gravel %Sand %Silt %Clay 0 P-01 0 25 11.613 1.317 0.194 53.7 39.5 4.2 2.6 PROJECT: AB GW Assessment - Asheville Sediment PROJECT NUMBER: 73075016 SITE: Asheville, North Carolina 1 rerracon CLIENT: Access Analytial 521 Clemson Road Columbia, South Carolina COBBLES GRAVEL SAND SILT OR CLAY coarse fine coarse medium fine 100 95 90 85 80 75 70 65 H 2 60 w >- 55 m ry Z 50 LL z 45 w 40 w CL 35 30 25 20 15 10 5 0 GRAIN SIZE DISTRIBUTION 53 of 65 ASTM D422 U.S. SIEVE OPENING IN INCHES U.S. SIEVE NUMBERS I HYDROMETER A i iii z a in 1 In Gn inn Onn I■III11i■■miiiil®■m■■II111®■■■■III 100 10 1 0.1 GRAIN SIZE IN MILLIMETERS 0.01 J 0.001 COBBLES GRAVEL SAND SILT OR CLAY coarse I fine coarse I medium I fine Boring ID Depth AASHTO Classification LL PL PI Cc Cu • P-01 DUP 0 () 0.46 263.31 Boring ID Depthl D,oe D60 Dao D,o -/.Gravel %Sand %Silt I %Clay 10 P-01 DUP 0 19 3.003 0.126 0.011 36.2 46.0 10.5 7.2 PROJECT: AB GW Assessment - Asheville Sediment PROJECT NUMBER: 73075016 SITE: Asheville, North Carolina 1 rerracon CLIENT: Access Analytial 521 Clemson Road Columbia, South Carolina 100 95 90 85 80 75 70 65 T 60 w >- 55 M Z 50 LL z 45 LU ry 40 LU o_ 35 30 25 20 15 10 5 0 GRAIN SIZE DISTRIBUTION 54 of 65 ASTM D422 U.S. SIEVE OPENING IN INCHES U.S. SIEVE NUMBERS I HYDROMETER A 7 i i/7 Z F in I 4n 1;n inn )nn Ur ■111111■■�IVIIYII■11■■IY1111■■■■II 100 10 1 0.1 GRAIN SIZE IN MILLIMETERS 0.01 J 0.001 COBBLES GRAVEL SAND SILT OR CLAY coarse I fine coarse medium I fine Boring ID Depth AASHTO Classification LL PL PI Cc Cu • SW -01 0 Q 3.29 15.69 Boring ID Depthl D,00 D60 D30 D,0 %Gravel %Sand °/oSilt I %Clay W• SW -01 0 19 0.245 0.112 0.016 14.4 65.8 14.1 5.7 PROJECT: AB GW Assessment - Asheville Sediment PROJECT NUMBER: 73075016 SITE: Asheville, North Carolina Irerracon CLIENT: Access Analytial 521 Clemson Road Columbia, South Carolina GRAIN SIZE DISTRIBUTION 55 of 65 ASTM D422 U.S. SIEVE OPENING IN INCHES U.S. SIEVE NUMBERS I HYDROMETER 6 4 3 2 1.5 1 3/4 1/23/8 3 4 6 810 1416 20 30 40 50 60 100140200 100 SILT OR CLAY coarse fine coarse medium fine 95 90 85 80 75 70 65 cD 60 w >- 55 m Z 50 L t-- 45 LU 40 LU o_ 35 30 25 20 15 10 5 0 100 10 1 0.1 0.01 0.001 GRAIN SIZE IN MILLIMETERS Boring ID Depth AASHTO Classification LL PL PI Cc Cu • SW -04 0 Q 2.20 20.24 Boring ID Depth D,00 D60 Dao D,o %Gravel %Sand °/oSilt %Clay 0 SW -04 0 2 0.079 0.026 0.004 0.0 42.1 46.3 11.6 PROJECT: AB GW Assessment - Asheville Sediment PROJECT NUMBER: 73075016 SITE: Asheville, North Carolina Irerracon CLIENT: Access Analytial 521 Clemson Road Columbia, South Carolina COBBLES GRAVEL SAND SILT OR CLAY coarse fine coarse medium fine ACCESS ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Duke Energy 13339 Hagers Ferry Rd. Huntersville NC 28078 ATTENTION Marge Galvin -Karr PROJECT ID J15040116 LABORATORY REPORT NUMBER 1504945 DATE April 28, 2015 Primary Data Review By Secondary Data Review By Ashley Amick Chantelle Kanhai Project Manager, Access Analytical Project Manager, AES aamick@axs-inc.com PLEASE NOTE: 56 of 65 - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL -E87582, NELAP certified laboratory # E87582 - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 1 of 9 7iMall Coft - _ CHAIN CUSTODY RECORD AND 57 ANALYSIS of 65 s DUKE -OF REQUEST FORM Analytical Laboratory Services ----I -------•-------------------------------------------- - - - - ----------------------------------- I LAB USE ONLY i Matrix I U .Ea. Mail Code MG03A2 (Building 7405) i 1 Work Order I t Analytical Laboratory Use Only SYNTERRA EDD 1y ENERGY:. 13339 Hage Ferry Rd Huntersville, , 511 // �% I I L N N F-- MaMx: SOIL x 1 of 1 „ N.C. 28078 (980) 875-5245i I !Lopped By Data a TI u I Sam les ori inatl From Ot{ i — DISTRIBUTION tlProlaet Nama AB Groundwater Fax (9801875-0349 _ _ _ _ _ Assessment 2iPhone i /� _ J� I - �� 2 I SAMPLE 1 ORIGINAL to LAB. COPY to CLIENT - Soil NO: �he, Ra«i.eesediment Access Analytical PROGRAM Grountl Water_ - Other_ Plant NPDES Date/Time: _ ED - 5111 Received By: Date/Time: �/y ��1�Y "L `'Fad No: AB GW PO Number 1142057 Cooler Tem C ] REV DATE 2/1012015 �i "Pr serv.:1=H 7iMall Coft - W - •vrrKsaa lU 'MRQ .kaW: When sPeciryc accounting has been established and Is not Indicated above we need the following: 1 i Enter correct accounting in all 5 accounting fields above, or 2 Provlds correct account)3 for Operating Unit and Process ID, I LAB USE ONLY i Matrix I U .Ea. i t "Lob ID Poll. Sediment, Ash) ,2:5&0 74/ 13 Sam le Description or ID I t O to La C M CO U F- a -� N N F-- Wa o E w� w U cc a a �n � N u iw 2 -- L_ J i Relinguished By:, Date/Time: Received By: Date/Time: i WATER I EQUIPMENT BLANK (1 PER DAY) Ba, Be, B, cd, Ca, Cr, Co, Cu, Fe, P , Mg, Mn, Mo, L. - _ .. _ PACE PO 1142081 Preservatives when used must be added within 15 minutes of sample coll"tlon "Collection Information In I -r 1 '01 17 � 23 711 1!we 47�1,1 )—/ 3 J pH "Requested Turnaround 14 Days '7 Days PaLEr-' 9 - 24 ►Tr�"' 'Add. Cost Will Apply W V Q U .Ea. a CL 0 J O to La C M CO U F- a -� N N F-- Wa o E w� w U cc a a ��az � N Q 2 "Requested Turnaround 14 Days '7 Days PaLEr-' 9 - 24 ►Tr�"' 'Add. Cost Will Apply Analytical Environmental Services, Inc Date: 28 -Apr -1558 of 65 Client: Duke Energy Project: J15040116 Case Narrative Lab ID: 1504945 ;IN1161az•II0:1.II F.11x 1504945-001 200.7 mV 234.2 mV 222.6 mV I►.IZIMMISI P 142.6 mV 168.2 mV 157.7 mV 1504945-003 80.4 mV 81.4 mV 78.6 mV 1504945-004 94.1 mV 95.2 mV 80.1 mV 1504945-005 132.7 mV 114.0 mV 102.6 mV LCS TRUE VALUE: 240mV LCS: 252.4 mV 105.16% Recovery Page 3 of 9 Analytical Environmental Services, Inc Date: 28 -Apr -15 II!Z.9 W Client: Duke Energy Client Sample ID: A-01 Project Name: J15040116 Collection Date: 4/2/2015 11:30:00 AM Lab ID: 1504945-001 Matrix: Soil Reporting Dilution Analyses Result Qual Units BatchID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity Qualifiers: x Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value (SW9081) 58 1.0 meq/100g 205884 1 04/16/2015 22:41 JL E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 4 of 9 Analytical Environmental Services, Inc 11-1IZ$ -V Date: 28 -Apr -15 Client: Duke Energy Client Sample ID: P-01 Project Name: J15040116 Collection Date: 4/2/2015 2:35:00 PM Lab ID: 1504945-002 Matrix: Soil Reporting Dilution Analyses Result Qual Units BatchID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity Qualifiers: z Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value (SW9081) 16 1.0 meq/100g 205884 1 04/16/2015 22:45 JL E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 5 of 9 Analytical Environmental Services, Inc Date: 28 -Apr -15 Client: Duke Energy Client Sample ID: P-01 DUP Project Name: J15040116 Collection Date: 4/2/2015 2:45:00 PM Lab ID: 1504945-003 Matrix: Soil Reporting Dilution Analyses Result Qual Units BatchID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity Qualifiers: z Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value (SW9081) 3.3 1.0 meq/100g 205884 1 04/16/2015 22:48 JL E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 6 of 9 Analytical Environmental Services, Inc Date: 28 -Apr -15 62 of 65 Client: Duke Energy Client Sample ID: SW -01 Project Name: J15040116 Collection Date: 4/2/2015 12:30:00 PM Lab ID: 1504945-004 Matrix: Soil Reporting Dilution Analyses Result Qual Units BatchID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity Qualifiers: z Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value (SW9081) 5.2 1.0 meq/100g 205884 1 04/16/2015 22:59 JL E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 7 of 9 Analytical Environmental Services, Inc GICZ.9 W Date: 28 -Apr -15 Client: Duke Energy Client Sample ID: SW -04 Project Name: J15040116 Collection Date: 4/2/2015 10:45:00 AM Lab ID: 1504945-005 Matrix: Soil Reporting Dilution Analyses Result Qual Units BatchID Date Analyzed Analyst Limit Factor CEC of Soils (Na Saturation) SW9081 Cation Exchange Capacity Qualifiers: " Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value (SW9081) 53 1.0 meq/100g 205884 1 04/16/2015 23:02 JL E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Nair See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 8 of 9 64 of 65 Analytical Environmental Services, Inc. Sample/Cooler Receipt Checklist Client ACC Work Order Number Checklist completed byAt�4 1e0/6— Signature Date Carrier name: FedEx -,/UPS _ Courier _ Client _ US Mail Other Shipping container/cooler in good condition? Yes ✓ No Custody seals intact on shipping container/cooler? Yes No Custody seals intact on sample bottles? Yes No Container/Temp Blank temperature in compliance? (00<60C* Yes _� No _ Cooler #1 3-5 Cooler #o C Not Present Not Present tl Not Present V--," ooler #3 Cooler #4 Cooler#5 Chain of custody present? Yes ✓ No Chain of custody signed when relinquished and received? Yes sl No Chain of custody agrees with sample labels? Yes �l No Samples in proper containerlbottle? Yes f No Sample containers intact? Yes ✓ No Sufficient sample volume for indicated test? Yes No All samples received within holding time? Yes U/ No _ Was TAT marked on the COC? Yes ✓ No Proceed with Standard TAT as per project history? Yes _ /No _ Water - VOA vials have zero headspace? No VOA vials submitted J Yes _ Water - pH acceptable upon receipt? Yes No / Adjusted? Sample Condition: Good ✓ Other(Explain) (For diffusive samples or AIHA lead) fs a known blank included? See Case Narrative for resolution of the Non -Conformance. Checked by Not Applicable No Not Applicable Yes No 11-11, Cooler #6 ' Samples do not have to comply with the given range for certain parameters. \\Aes_server\l\Sample Receipt\My Documents\COCs and pH Adjustment Sheet\Sample_Cooler_Recipt Checklist_Revl.rtf Page 9 of 9 siouiquoo jo # lelo4z I �1 E O S N ' w f 0. -------------- N l 0i a. 9 a UL I I j S o 0 �! !—i0 o iU iD M E J j 0 , D O U 1 t I tin nl j � rq i U;00�®o I0 Q W I ! C o U t 'i I } `� 1 �� Q .0 = � a- vfly Q d i i Q N L7 0 1 I N in d Iq Ut c o s Z!� C O Q� I um e o' y` i 1 11 C (111�11h"ItINb ss3aad) aef zo 9 - Z sisal Ci ci al;loads luawlpaS (3DVd) saef zo a - Z I '� tl suolurd pue slelew 19101 - d-ldS (30Vd) je[zo y- l ow (30Vd) je[ zo g - 6 Fid suolud i slelaW 19401 I baa geJ`Jet X X X sc. sAle V,, i dwo�u z 1 c' 0 0 N hQ 0. -------------- N l 1 O a I UUU) I j o 0 �! y nl p j 0 , QI p ro m lj ry ,q! LL U 1 t I tin nl j � rq j V i0 U;00�®o LU Q W I ! C o U t 'i I } `� 1 �� Q .0 = � a- a- 0— 1 c' 0 0 hQ 0. -------------- N l 1 O I UUU) I j LL I .0 e E o 8+ QI p ro m lj ry ,q! LL a` n a tin nl j � o U;00�®o 1J 0 Q LL• C o I r l r u y I E +_ GI E o of i i Q N L7 0 1 I N a` 4 :r, E C >� = C O =, G E3r.�1 81 y a G c' 0 0 � E 1= O i E o 8+ m o J3 0 G w p_ (' Q o w o 3no of z d a 4) :r, E M rill = = e o' m iu �. IL m o 8 m ..._ LUQ wnloo a;eudojdde e;eldwoa of jawo;sno ee V N ; su _ E ti u I C a 5, a wcl I J • 7r TAFF - 01a1®wu� i Isnw xau�olenr) 6 IL c' 0 0 O i 9 m o J3 0 G w p_ (' Q o w o z d a = =SmZ LU LE Y 7 CY m a W p „ co A A G sa L { C I c ° O x € W u m E - uw5 m ..._ LUQ wnloo a;eudojdde e;eldwoa of jawo;sno ee V N ; su _ E ti u I C a 5, a wcl I J • 7r TAFF - 01a1®wu� i Isnw xau�olenr) 6 IL